Issue 8, 1996
From the journal:

Journal of the Chemical Society, Faraday Transactions

Investigation of transport across an immiscible liquid/liquid interface. Electrochemical and second harmonic generation studies

Michael J. Crawford,   Jeremy G. Frey,   T. J. VanderNoot  and  Yuguang Zhao  

Abstract

An electrochemical investigation of the transport of the crown ether 4′-nitrobenzo-15-crown-5 across a water/1,2-dichloroethane interface showed that the crown ether did not cross the interface but the complex formed by the crown ether with Na+ did transfer, the peak transfer current increased with increasing [Na+] until all the crown ether was complexed. The in situ interfacial second harmonic generation experiment indicates that, in the absence of Na+, the crown ether is oriented and ordered by the electric field at the interface. The sodium coronate shows a more complex behaviour at the interface.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/FT9969201369
Article type
Paper

J. Chem. Soc., Faraday Trans., 1996,92, 1369-1373

Permissions

Request permissions

Investigation of transport across an immiscible liquid/liquid interface. Electrochemical and second harmonic generation studies

M. J. Crawford, J. G. Frey, T. J. VanderNoot and Y. Zhao, J. Chem. Soc., Faraday Trans., 1996, 92, 1369 DOI: 10.1039/FT9969201369

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements