Issue 0, 1970
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Reactions of zirconium isopropoxide with β-diketones and β-keto-esters

U. B. Saxena,   A. K. Rai,   V. K. Mathur,   R. C. Mehrotra  and  D. Radford  

Abstract

The reactions of zirconium isopropoxide with acetylacetone, benzoylacetone, dibenzoylmethane, and ethyl benzoylacetate have been studied and a number of new derivatives of the type M(OPri)4–xLx(where M = Zr, L = acetylacetone, benzoylacetone, dibenzoylmethane, or ethyl benzoylacetate, x= 1–4) have been isolated. These derivatives interchange their isopropoxy- for t-butoxy-groups when heated under reflux with t-butyl alcohol. Structures of these derivatives have been discussed on the basis of analysis, molecular weight, and i.r. spectral studies.

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Article information

DOI
https://doi.org/10.1039/J19700000904
Article type
Paper

J. Chem. Soc. A, 1970, 904-907

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Reactions of zirconium isopropoxide with β-diketones and β-keto-esters

U. B. Saxena, A. K. Rai, V. K. Mathur, R. C. Mehrotra and D. Radford, J. Chem. Soc. A, 1970, 904 DOI: 10.1039/J19700000904

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