Issue 1, 1977
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Thermodynamic functions of proton ionization of para-substituted benzenethiols

Paolo De Maria,   Adamo Fini  and  Francis M. Hall  

Abstract

ΔG025, ΔH025, and ΔS025 values for ionization of four para-substituted benzenethiols have been calculated from thermodynamic pKa values determined in water over a range of temperatures. These, together with earlier results for meta-substituted benzenethiols, show that effects on the free energy of ionization for benzenethiols are primarily related to changes in entropy and that these compounds cannot be considered as forming an isoenthalpic series.

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Article information

DOI
https://doi.org/10.1039/P29770000149
Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1977, 149-151

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Thermodynamic functions of proton ionization of para-substituted benzenethiols

P. De Maria, A. Fini and F. M. Hall, J. Chem. Soc., Perkin Trans. 2, 1977, 149 DOI: 10.1039/P29770000149

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