Issue 3, 1992
From the journal:

Journal of the Chemical Society, Chemical Communications

Deportonation of nitroalkanes by bicyclic amidine and guanidine bases; evidence for molecular recognition within a catalytic cycle for C–C bond formation

Peter H. Boyle,   Máire A. Convery,   Anthony P. Davis,   Gladys D. Hosken  and  Brian A. Murray  

Abstract

Evidence from 1H NMR spectroscopy supported by X-ray crystallography, suggests that the bicyclic amidine and guanidine bases 2 and 3 react with nitroalkanes in non-polar organic solvents to give tightly-bound ion pairs 5; it is argued that homochiral analogues of these complexes may prove valuable as intermediates in enantioselective catalytic C–C bond-forming reactions.

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Article information

DOI
https://doi.org/10.1039/C39920000239
Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 239-242

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Deportonation of nitroalkanes by bicyclic amidine and guanidine bases; evidence for molecular recognition within a catalytic cycle for C–C bond formation

P. H. Boyle, M. A. Convery, A. P. Davis, G. D. Hosken and B. A. Murray, J. Chem. Soc., Chem. Commun., 1992, 239 DOI: 10.1039/C39920000239

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