Peterson olefination
Definition: A carbon-carbon coupling reaction in which an alpha-silyl carbanion reacts with an aldehyde or a ketone to give an alkene, proceeding via a beta-hydroxysilane. The stereochemistry of the alkene can be controlled by treating the intermediate with acid or base.
ID: RXNO:0000080
Synonyms:
More about the RSC Name Reaction Ontology (RXNO)
Articles referencing this term
Takashi Okitsu, Kinya Iwatsuka and Akimori Wada, Chem. Commun., 2008
, 6330
DOI: 10.1039/b813760a
Gerhard Hilt and Jonas Treutwein, Chem. Commun., 2009
, 1395
DOI: 10.1039/b822023a
Tongqiang Wang, Yuanyuan Hu and Songlin Zhang, Org. Biomol. Chem., 2010
, 8
, 2312
DOI: 10.1039/c001931c