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Paper b507002n
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Fig. 1′: The Al
n
core of the metalloid clusters [Al
7
R
6
]
−
, [Al
12
R
6
]
−
, [Al
14
R
6
I
6
]
2−
(R = N(SiMe
3
)
2
). Fig. 2′: The Al
n
core of the metalloid clusters [Al
69
R
18
]
3−
and [Al
77
R
20
]
2−
(R = N(SiMe
2
)
2
) and the different arrangements of the central Al
13
units. Fig. 3′: The Al
22
core of the halides Al
22
X
20
·12D (X = Br, Cl; D = THF). Fig. 4′: Section of the normal-pressure (α, β, γ, δ) and the high-pressure modifications (GaII, GaIII) of solid Ga. The fcc high-pressure modification GaIV is not shown. Fig. 5′: Ga
n
core of the clusters Ga
18
R
8
and Ga
22
R
8
(R = Si
t
Bu
3
)
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