# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a
_database_code_depnum_ccdc_archive 'CCDC 1420786'
_audit_update_record             
;
2015-08-27 deposited with the CCDC.
2016-09-05 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C33 H23 F N2'
_chemical_formula_weight         466.53

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   'P2(1)/c  '

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   26.426(7)
_cell_length_b                   6.8665(17)
_cell_length_c                   13.432(4)
_cell_angle_alpha                90.00
_cell_angle_beta                 93.450(5)
_cell_angle_gamma                90.00
_cell_volume                     2432.8(11)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    2206
_cell_measurement_theta_min      3.04
_cell_measurement_theta_max      22.13

_exptl_crystal_description       ?
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.274
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             976
_exptl_absorpt_coefficient_mu    0.080
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.9874
_exptl_absorpt_correction_T_max  0.9921
_exptl_absorpt_process_details   SADABS

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            11708
_diffrn_reflns_av_R_equivalents  0.0365
_diffrn_reflns_av_sigmaI/netI    0.0395
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_h_max       31
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_theta_min         2.32
_diffrn_reflns_theta_max         25.00
_reflns_number_total             4251
_reflns_number_gt                2733
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0646P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.0087(10)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         4251
_refine_ls_number_parameters     326
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0785
_refine_ls_R_factor_gt           0.0451
_refine_ls_wR_factor_ref         0.1230
_refine_ls_wR_factor_gt          0.1091
_refine_ls_goodness_of_fit_ref   1.004
_refine_ls_restrained_S_all      1.004
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
N1 N 0.85402(5) 0.0713(2) 0.09766(13) 0.0620(5) Uani 1 1 d . . .
N2 N 0.47853(6) 0.8521(3) 0.12505(14) 0.0724(5) Uani 1 1 d . . .
C1 C 0.85561(7) -0.0675(3) 0.01919(16) 0.0576(5) Uani 1 1 d . . .
C2 C 0.88325(7) -0.2366(3) 0.0313(2) 0.0746(6) Uani 1 1 d . . .
H2 H 0.9014 -0.2621 0.0914 0.090 Uiso 1 1 calc R . .
C3 C 0.88378(9) -0.3709(3) -0.0479(3) 0.0879(8) Uani 1 1 d U . .
H3 H 0.9024 -0.4855 -0.0404 0.105 Uiso 1 1 calc R . .
C4 C 0.85683(10) -0.3320(4) -0.1357(2) 0.0921(8) Uani 1 1 d U . .
H4 H 0.8574 -0.4202 -0.1882 0.110 Uiso 1 1 calc R . .
C5 C 0.82956(9) -0.1680(4) -0.1469(2) 0.0872(7) Uani 1 1 d . . .
H5 H 0.8110 -0.1441 -0.2067 0.105 Uiso 1 1 calc R . .
C6 C 0.82879(8) -0.0349(3) -0.07056(17) 0.0696(6) Uani 1 1 d . . .
H6 H 0.8099 0.0787 -0.0796 0.084 Uiso 1 1 calc R . .
C7 C 0.89826(6) 0.1774(3) 0.12785(16) 0.0581(5) Uani 1 1 d . . .
C8 C 0.94036(7) 0.1765(3) 0.07138(18) 0.0729(6) Uani 1 1 d . . .
H8 H 0.9398 0.1061 0.0122 0.087 Uiso 1 1 calc R . .
C9 C 0.98303(8) 0.2795(4) 0.1027(2) 0.0920(8) Uani 1 1 d . . .
H9 H 1.0113 0.2757 0.0648 0.110 Uiso 1 1 calc R . .
C10 C 0.98466(9) 0.3868(4) 0.1881(3) 0.1007(9) Uani 1 1 d . . .
H10 H 1.0134 0.4587 0.2076 0.121 Uiso 1 1 calc R . .
C11 C 0.94328(9) 0.3873(3) 0.2450(2) 0.0857(7) Uani 1 1 d . . .
H11 H 0.9441 0.4586 0.3039 0.103 Uiso 1 1 calc R . .
C12 C 0.90041(8) 0.2830(3) 0.21546(17) 0.0681(6) Uani 1 1 d . . .
H12 H 0.8727 0.2837 0.2549 0.082 Uiso 1 1 calc R . .
C13 C 0.80477(6) 0.1385(3) 0.11900(14) 0.0530(5) Uani 1 1 d . . .
C14 C 0.76769(7) 0.0026(3) 0.13597(15) 0.0590(5) Uani 1 1 d . . .
H14 H 0.7762 -0.1287 0.1404 0.071 Uiso 1 1 calc R . .
C15 C 0.71842(7) 0.0585(3) 0.14637(14) 0.0561(5) Uani 1 1 d . . .
H15 H 0.6942 -0.0364 0.1570 0.067 Uiso 1 1 calc R . .
C16 C 0.70359(6) 0.2521(3) 0.14152(13) 0.0471(4) Uani 1 1 d . . .
C17 C 0.74152(7) 0.3880(3) 0.12842(14) 0.0570(5) Uani 1 1 d . . .
H17 H 0.7334 0.5197 0.1274 0.068 Uiso 1 1 calc R . .
C18 C 0.79113(7) 0.3325(3) 0.11682(15) 0.0587(5) Uani 1 1 d . . .
H18 H 0.8156 0.4271 0.1074 0.070 Uiso 1 1 calc R . .
C19 C 0.64964(6) 0.3102(3) 0.14341(13) 0.0458(4) Uani 1 1 d . . .
C20 C 0.61096(6) 0.1783(3) 0.11989(14) 0.0563(5) Uani 1 1 d . . .
H20 H 0.6193 0.0496 0.1068 0.068 Uiso 1 1 calc R . .
C21 C 0.56074(6) 0.2317(3) 0.11529(15) 0.0557(5) Uani 1 1 d . . .
H21 H 0.5360 0.1388 0.0990 0.067 Uiso 1 1 calc R . .
C22 C 0.54634(6) 0.4207(2) 0.13443(13) 0.0459(4) Uani 1 1 d . . .
C23 C 0.58465(7) 0.5534(3) 0.15886(15) 0.0581(5) Uani 1 1 d . . .
H23 H 0.5763 0.6821 0.1719 0.070 Uiso 1 1 calc R . .
C24 C 0.63488(7) 0.4980(3) 0.16424(15) 0.0596(5) Uani 1 1 d . . .
H24 H 0.6596 0.5899 0.1824 0.072 Uiso 1 1 calc R . .
C25 C 0.49226(6) 0.4809(2) 0.12772(13) 0.0462(4) Uani 1 1 d . . .
C26 C 0.48390(6) 0.6877(3) 0.12715(14) 0.0519(5) Uani 1 1 d . . .
C27 C 0.45302(6) 0.3559(3) 0.12082(13) 0.0508(5) Uani 1 1 d . . .
H27 H 0.4626 0.2255 0.1218 0.061 Uiso 1 1 calc R . .
C28 C 0.39808(6) 0.3864(2) 0.11206(13) 0.0474(5) Uani 1 1 d . . .
C29 C 0.37362(7) 0.5656(3) 0.11779(14) 0.0527(5) Uani 1 1 d . . .
H29 H 0.3923 0.6796 0.1276 0.063 Uiso 1 1 calc R . .
C30 C 0.32217(7) 0.5715(3) 0.10891(14) 0.0539(5) Uani 1 1 d . . .
C31 C 0.29207(7) 0.4104(3) 0.09586(15) 0.0617(5) Uani 1 1 d . . .
H31 H 0.2569 0.4206 0.0909 0.074 Uiso 1 1 calc R . .
C32 C 0.31562(7) 0.2338(3) 0.09040(16) 0.0672(6) Uani 1 1 d . . .
H32 H 0.2963 0.1213 0.0813 0.081 Uiso 1 1 calc R . .
C33 C 0.36792(7) 0.2211(3) 0.09821(15) 0.0598(5) Uani 1 1 d . . .
H33 H 0.3833 0.0998 0.0941 0.072 Uiso 1 1 calc R . .
F1 F 0.29897(4) 0.74833(16) 0.11394(10) 0.0787(4) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
N1 C7 1.416(2) . ?
N1 C1 1.423(2) . ?
N1 C13 1.426(2) . ?
N2 C26 1.138(2) . ?
C1 C2 1.377(3) . ?
C1 C6 1.380(3) . ?
C2 C3 1.408(3) . ?
C2 H2 0.9300 . ?
C3 C4 1.367(4) . ?
C3 H3 0.9300 . ?
C4 C5 1.341(3) . ?
C4 H4 0.9300 . ?
C5 C6 1.375(3) . ?
C5 H5 0.9300 . ?
C6 H6 0.9300 . ?
C7 C12 1.380(3) . ?
C7 C8 1.384(3) . ?
C8 C9 1.375(3) . ?
C8 H8 0.9300 . ?
C9 C10 1.362(4) . ?
C9 H9 0.9300 . ?
C10 C11 1.371(4) . ?
C10 H10 0.9300 . ?
C11 C12 1.378(3) . ?
C11 H11 0.9300 . ?
C12 H12 0.9300 . ?
C13 C18 1.380(3) . ?
C13 C14 1.382(2) . ?
C14 C15 1.373(2) . ?
C14 H14 0.9300 . ?
C15 C16 1.387(2) . ?
C15 H15 0.9300 . ?
C16 C17 1.388(2) . ?
C16 C19 1.482(2) . ?
C17 C18 1.383(2) . ?
C17 H17 0.9300 . ?
C18 H18 0.9300 . ?
C19 C24 1.380(2) . ?
C19 C20 1.388(2) . ?
C20 C21 1.375(2) . ?
C20 H20 0.9300 . ?
C21 C22 1.381(2) . ?
C21 H21 0.9300 . ?
C22 C23 1.387(2) . ?
C22 C25 1.485(2) . ?
C23 C24 1.379(2) . ?
C23 H23 0.9300 . ?
C24 H24 0.9300 . ?
C25 C27 1.345(2) . ?
C25 C26 1.437(3) . ?
C27 C28 1.465(2) . ?
C27 H27 0.9300 . ?
C28 C33 1.393(2) . ?
C28 C29 1.394(2) . ?
C29 C30 1.358(2) . ?
C29 H29 0.9300 . ?
C30 F1 1.364(2) . ?
C30 C31 1.367(3) . ?
C31 C32 1.367(3) . ?
C31 H31 0.9300 . ?
C32 C33 1.382(3) . ?
C32 H32 0.9300 . ?
C33 H33 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C7 N1 C1 119.74(15) . . ?
C7 N1 C13 121.55(16) . . ?
C1 N1 C13 115.69(14) . . ?
C2 C1 C6 118.8(2) . . ?
C2 C1 N1 121.1(2) . . ?
C6 C1 N1 120.15(18) . . ?
C1 C2 C3 119.5(2) . . ?
C1 C2 H2 120.3 . . ?
C3 C2 H2 120.3 . . ?
C4 C3 C2 119.7(2) . . ?
C4 C3 H3 120.1 . . ?
C2 C3 H3 120.1 . . ?
C5 C4 C3 120.6(3) . . ?
C5 C4 H4 119.7 . . ?
C3 C4 H4 119.7 . . ?
C4 C5 C6 120.5(3) . . ?
C4 C5 H5 119.8 . . ?
C6 C5 H5 119.8 . . ?
C5 C6 C1 120.9(2) . . ?
C5 C6 H6 119.5 . . ?
C1 C6 H6 119.5 . . ?
C12 C7 C8 118.46(19) . . ?
C12 C7 N1 120.36(17) . . ?
C8 C7 N1 121.2(2) . . ?
C9 C8 C7 120.1(2) . . ?
C9 C8 H8 120.0 . . ?
C7 C8 H8 120.0 . . ?
C10 C9 C8 121.3(2) . . ?
C10 C9 H9 119.3 . . ?
C8 C9 H9 119.3 . . ?
C9 C10 C11 119.0(2) . . ?
C9 C10 H10 120.5 . . ?
C11 C10 H10 120.5 . . ?
C10 C11 C12 120.5(2) . . ?
C10 C11 H11 119.7 . . ?
C12 C11 H11 119.7 . . ?
C11 C12 C7 120.6(2) . . ?
C11 C12 H12 119.7 . . ?
C7 C12 H12 119.7 . . ?
C18 C13 C14 117.95(16) . . ?
C18 C13 N1 123.28(16) . . ?
C14 C13 N1 118.61(16) . . ?
C15 C14 C13 120.93(18) . . ?
C15 C14 H14 119.5 . . ?
C13 C14 H14 119.5 . . ?
C14 C15 C16 122.05(17) . . ?
C14 C15 H15 119.0 . . ?
C16 C15 H15 119.0 . . ?
C15 C16 C17 116.49(16) . . ?
C15 C16 C19 121.78(15) . . ?
C17 C16 C19 121.60(16) . . ?
C18 C17 C16 121.74(18) . . ?
C18 C17 H17 119.1 . . ?
C16 C17 H17 119.1 . . ?
C13 C18 C17 120.76(17) . . ?
C13 C18 H18 119.6 . . ?
C17 C18 H18 119.6 . . ?
C24 C19 C20 116.27(15) . . ?
C24 C19 C16 122.60(15) . . ?
C20 C19 C16 121.08(16) . . ?
C21 C20 C19 122.12(17) . . ?
C21 C20 H20 118.9 . . ?
C19 C20 H20 118.9 . . ?
C20 C21 C22 121.23(17) . . ?
C20 C21 H21 119.4 . . ?
C22 C21 H21 119.4 . . ?
C21 C22 C23 117.15(16) . . ?
C21 C22 C25 121.68(15) . . ?
C23 C22 C25 121.16(16) . . ?
C24 C23 C22 121.19(17) . . ?
C24 C23 H23 119.4 . . ?
C22 C23 H23 119.4 . . ?
C23 C24 C19 122.02(17) . . ?
C23 C24 H24 119.0 . . ?
C19 C24 H24 119.0 . . ?
C27 C25 C26 120.83(15) . . ?
C27 C25 C22 124.16(15) . . ?
C26 C25 C22 115.00(15) . . ?
N2 C26 C25 177.9(2) . . ?
C25 C27 C28 132.12(17) . . ?
C25 C27 H27 113.9 . . ?
C28 C27 H27 113.9 . . ?
C33 C28 C29 117.58(16) . . ?
C33 C28 C27 116.80(16) . . ?
C29 C28 C27 125.62(16) . . ?
C30 C29 C28 119.09(17) . . ?
C30 C29 H29 120.5 . . ?
C28 C29 H29 120.5 . . ?
C29 C30 F1 118.20(17) . . ?
C29 C30 C31 123.98(18) . . ?
F1 C30 C31 117.81(16) . . ?
C32 C31 C30 117.45(18) . . ?
C32 C31 H31 121.3 . . ?
C30 C31 H31 121.3 . . ?
C31 C32 C33 120.54(19) . . ?
C31 C32 H32 119.7 . . ?
C33 C32 H32 119.7 . . ?
C32 C33 C28 121.35(18) . . ?
C32 C33 H33 119.3 . . ?
C28 C33 H33 119.3 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C7 N1 C1 C2 68.0(2) . . . . ?
C13 N1 C1 C2 -131.33(18) . . . . ?
C7 N1 C1 C6 -112.7(2) . . . . ?
C13 N1 C1 C6 48.0(2) . . . . ?
C6 C1 C2 C3 0.5(3) . . . . ?
N1 C1 C2 C3 179.77(17) . . . . ?
C1 C2 C3 C4 -0.1(3) . . . . ?
C2 C3 C4 C5 -0.5(4) . . . . ?
C3 C4 C5 C6 0.8(4) . . . . ?
C4 C5 C6 C1 -0.5(3) . . . . ?
C2 C1 C6 C5 -0.2(3) . . . . ?
N1 C1 C6 C5 -179.48(17) . . . . ?
C1 N1 C7 C12 -167.19(18) . . . . ?
C13 N1 C7 C12 33.3(3) . . . . ?
C1 N1 C7 C8 12.1(3) . . . . ?
C13 N1 C7 C8 -147.41(19) . . . . ?
C12 C7 C8 C9 -0.2(3) . . . . ?
N1 C7 C8 C9 -179.5(2) . . . . ?
C7 C8 C9 C10 -1.3(4) . . . . ?
C8 C9 C10 C11 1.8(4) . . . . ?
C9 C10 C11 C12 -0.9(4) . . . . ?
C10 C11 C12 C7 -0.5(3) . . . . ?
C8 C7 C12 C11 1.0(3) . . . . ?
N1 C7 C12 C11 -179.69(18) . . . . ?
C7 N1 C13 C18 37.1(3) . . . . ?
C1 N1 C13 C18 -123.1(2) . . . . ?
C7 N1 C13 C14 -147.51(18) . . . . ?
C1 N1 C13 C14 52.2(2) . . . . ?
C18 C13 C14 C15 2.5(3) . . . . ?
N1 C13 C14 C15 -173.06(18) . . . . ?
C13 C14 C15 C16 -0.7(3) . . . . ?
C14 C15 C16 C17 -1.8(3) . . . . ?
C14 C15 C16 C19 174.23(17) . . . . ?
C15 C16 C17 C18 2.5(3) . . . . ?
C19 C16 C17 C18 -173.54(17) . . . . ?
C14 C13 C18 C17 -1.8(3) . . . . ?
N1 C13 C18 C17 173.54(18) . . . . ?
C16 C17 C18 C13 -0.7(3) . . . . ?
C15 C16 C19 C24 162.98(19) . . . . ?
C17 C16 C19 C24 -21.2(3) . . . . ?
C15 C16 C19 C20 -19.8(3) . . . . ?
C17 C16 C19 C20 156.07(18) . . . . ?
C24 C19 C20 C21 1.4(3) . . . . ?
C16 C19 C20 C21 -176.01(17) . . . . ?
C19 C20 C21 C22 -0.3(3) . . . . ?
C20 C21 C22 C23 -0.3(3) . . . . ?
C20 C21 C22 C25 178.77(16) . . . . ?
C21 C22 C23 C24 -0.3(3) . . . . ?
C25 C22 C23 C24 -179.41(17) . . . . ?
C22 C23 C24 C19 1.6(3) . . . . ?
C20 C19 C24 C23 -2.1(3) . . . . ?
C16 C19 C24 C23 175.32(17) . . . . ?
C21 C22 C25 C27 12.4(3) . . . . ?
C23 C22 C25 C27 -168.54(18) . . . . ?
C21 C22 C25 C26 -166.43(18) . . . . ?
C23 C22 C25 C26 12.6(2) . . . . ?
C27 C25 C26 N2 -143(6) . . . . ?
C22 C25 C26 N2 36(6) . . . . ?
C26 C25 C27 C28 -0.1(3) . . . . ?
C22 C25 C27 C28 -178.89(17) . . . . ?
C25 C27 C28 C33 174.90(19) . . . . ?
C25 C27 C28 C29 -6.1(3) . . . . ?
C33 C28 C29 C30 -0.5(3) . . . . ?
C27 C28 C29 C30 -179.59(16) . . . . ?
C28 C29 C30 F1 -179.49(16) . . . . ?
C28 C29 C30 C31 1.0(3) . . . . ?
C29 C30 C31 C32 -0.8(3) . . . . ?
F1 C30 C31 C32 179.68(17) . . . . ?
C30 C31 C32 C33 0.2(3) . . . . ?
C31 C32 C33 C28 0.2(3) . . . . ?
C29 C28 C33 C32 0.0(3) . . . . ?
C27 C28 C33 C32 179.13(17) . . . . ?

_diffrn_measured_fraction_theta_max 0.996
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.996
_refine_diff_density_max         0.161
_refine_diff_density_min         -0.151
_refine_diff_density_rms         0.038
