# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_n1311120c
_database_code_depnum_ccdc_archive 'CCDC 1408698'
_audit_update_record             
;
2017-03-29 deposited with the CCDC.
2017-04-19 downloaded from the CCDC.
;
_audit_creation_date             2015-06-04
_audit_creation_method           
;
Olex2 1.2
(compiled 2015.01.26 svn.r3150 for OlexSys, GUI svn.r4998)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         '2(C46 H36 Ag N4 O4), 2(F6 P)'
_chemical_formula_sum            'C92 H72 Ag2 F12 N8 O8 P2'
_chemical_formula_weight         1923.25
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   15.1732(11)
_cell_length_b                   15.5680(11)
_cell_length_c                   22.2494(16)
_cell_angle_alpha                78.0530(10)
_cell_angle_beta                 83.1270(10)
_cell_angle_gamma                62.7450(10)
_cell_volume                     4569.1(6)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9771
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      28.34
_cell_measurement_theta_min      2.37
_shelx_estimated_absorpt_T_max   0.918
_shelx_estimated_absorpt_T_min   0.908
_exptl_absorpt_coefficient_mu    0.546
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.5786
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2012/1 (Bruker,2012) was used for absorption correction.
wR2(int) was 0.1247 before and 0.0378 after correction.
The Ratio of minimum to maximum transmission is 0.7759.
The λ/2 correction factor is 0.0015.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.398
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1952
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.16
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0261
_diffrn_reflns_av_unetI/netI     0.0453
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            26585
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        25.009
_diffrn_reflns_theta_max         25.009
_diffrn_reflns_theta_min         1.494
_diffrn_ambient_temperature      173.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                12025
_reflns_number_total             16089
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
The unit cell contains 4 dichloroethane molecules 
which have been treated as a diffuse contribution to 
the overall scattering without specific atom positions by SQUEEZE/PLATON.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2008)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_refine_diff_density_max         3.120
_refine_diff_density_min         -1.249
_refine_diff_density_rms         0.140
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.156
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1105
_refine_ls_number_reflns         16089
_refine_ls_number_restraints     517
_refine_ls_R_factor_all          0.1152
_refine_ls_R_factor_gt           0.0949
_refine_ls_restrained_S_all      1.210
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1684P)²+8.8106P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2722
_refine_ls_wR_factor_ref         0.2908
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2. Restrained distances
 C53-C47
 1.53 with sigma of 0.01
3. Rigid bond restraints
 All non-hydrogen atoms
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
4. Uiso/Uaniso restraints and constraints
Uanis(C31) \\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.01
Uanis(Ag2) \\sim Ueq, Uanis(F1) \\sim Ueq, Uanis(F7) \\sim Ueq, Uanis(F8) \\sim
Ueq, Uanis(N5) \\sim Ueq, Uanis(N7) \\sim Ueq, Uanis(C44) \\sim Ueq, Uanis(C45)
\\sim Ueq, Uanis(C50) \\sim Ueq, Uanis(C54) \\sim Ueq, Uanis(C56) \\sim Ueq,
Uanis(C59) \\sim Ueq, Uanis(C60) \\sim Ueq, Uanis(C66) \\sim Ueq, Uanis(C68)
\\sim Ueq, Uanis(C70) \\sim Ueq, Uanis(C71) \\sim Ueq, Uanis(C77) \\sim Ueq,
Uanis(C78) \\sim Ueq, Uanis(C81) \\sim Ueq, Uanis(C83) \\sim Ueq, Uanis(C84)
\\sim Ueq, Uanis(C85) \\sim Ueq: with sigma of 0.01 and sigma for terminal
atoms of 0.02
Uanis(C53) \\sim Ueq, Uanis(N5) \\sim Ueq, Uanis(C47) \\sim Ueq, Uanis(C52)
\\sim Ueq, Uanis(C51) \\sim Ueq: with sigma of 0.005 and sigma for terminal
atoms of 0.01
5.a Secondary CH2 refined with riding coordinates:
 C7(H7A,H7B), C15(H15A,H15B), C16(H16A,H16B), C31(H31A,H31B), C32(H32A,H32B),
 C40(H40A,H40B), C53(H53A,H53B), C61(H61A,H61B), C62(H62A,H62B), C77(H77A,H77B),
  C78(H78A,H78B), C86(H86A,H86B)
5.b Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3), C4(H4), C5(H5), C6(H6), C11(H11), C12(H12), C13(H13),
 C14(H14), C21(H21), C22(H22), C23(H23), C24(H24), C29(H29), C30(H30), C35(H35),
  C36(H36), C37(H37), C38(H38), C42(H42), C43(H43), C44(H44), C45(H45),
 C46(H46), C48(H48), C49(H49), C50(H50), C51(H51), C52(H52), C56(H56), C57(H57),
  C58(H58), C59(H59), C67(H67), C68(H68), C69(H69), C70(H70), C75(H75),
 C76(H76), C81(H81), C82(H82), C83(H83), C84(H84), C88(H88), C89(H89), C90(H90),
  C91(H91), C92(H92)
5.c Fitted hexagon refined as free rotating group:
 C47(C48,C49,C50,C51,C52)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.18253(3) 0.14065(4) 0.42324(2) 0.04324(19) Uani 1 1 d . U . . .
Ag2 Ag 0.00037(7) 0.28443(4) 0.77950(3) 0.0913(3) Uani 1 1 d . U . . .
P1 P 0.45708(18) 0.32924(18) 0.24475(12) 0.0790(7) Uani 1 1 d . U . . .
P2 P 0.0889(3) 0.89908(19) 0.35526(13) 0.0899(8) Uani 1 1 d . U . . .
F1 F 0.4494(6) 0.4092(7) 0.1872(4) 0.155(3) Uani 1 1 d . U . . .
F2 F 0.5672(5) 0.3060(6) 0.2462(4) 0.136(2) Uani 1 1 d . U . . .
F3 F 0.4687(8) 0.2519(8) 0.3003(5) 0.173(3) Uani 1 1 d . U . . .
F4 F 0.3441(4) 0.3548(4) 0.2409(3) 0.1019(16) Uani 1 1 d . U . . .
F5 F 0.4237(6) 0.4097(7) 0.2841(5) 0.156(3) Uani 1 1 d . U . . .
F6 F 0.4848(7) 0.2556(8) 0.1991(5) 0.170(3) Uani 1 1 d . U . . .
F7 F 0.1460(10) 0.9418(6) 0.3817(5) 0.200(3) Uani 1 1 d . U . . .
F8 F 0.0205(9) 0.9260(9) 0.4084(4) 0.209(3) Uani 1 1 d . U . . .
F9 F 0.0317(5) 0.8549(5) 0.3266(3) 0.1041(17) Uani 1 1 d . U . . .
F10 F 0.1691(5) 0.8666(6) 0.2978(3) 0.1216(19) Uani 1 1 d . U . . .
F11 F 0.1590(4) 0.7946(4) 0.3931(2) 0.0798(12) Uani 1 1 d . U . . .
F12 F 0.0356(7) 0.9985(4) 0.3114(4) 0.142(2) Uani 1 1 d . U . . .
O1 O 0.2495(3) 0.3370(3) 0.4737(2) 0.0483(10) Uani 1 1 d . U . . .
O2 O 0.1217(5) 0.2970(4) 0.5429(3) 0.088(2) Uani 1 1 d . U . . .
O3 O -0.0138(6) 0.6232(4) 0.6362(2) 0.0836(18) Uani 1 1 d . U . . .
O4 O 0.0793(7) 0.6910(5) 0.5560(3) 0.098(2) Uani 1 1 d . U . . .
O5 O 0.0218(5) 0.5397(4) 0.8690(2) 0.0652(13) Uani 1 1 d . U . . .
O6 O -0.1533(5) 0.6688(4) 0.8894(3) 0.0742(13) Uani 1 1 d . U . . .
O7 O -0.0563(6) 0.7186(6) 1.0959(3) 0.095(2) Uani 1 1 d . U . . .
O8 O 0.1216(6) 0.5954(4) 1.0837(2) 0.0870(17) Uani 1 1 d . U . . .
N1 N 0.3024(4) 0.0480(4) 0.5427(3) 0.0462(9) Uani 1 1 d . U . . .
N2 N 0.3597(4) 0.1375(4) 0.4797(3) 0.0433(8) Uani 1 1 d . U . . .
N3 N 0.0120(4) 0.8224(4) 0.6305(2) 0.0404(9) Uani 1 1 d . U . . .
N4 N -0.0836(4) 0.7916(4) 0.7025(2) 0.0432(9) Uani 1 1 d . U . . .
N5 N 0.1803(8) 0.2758(7) 0.7007(4) 0.1012(15) Uani 1 1 d . U . . .
N6 N 0.1134(6) 0.4108(5) 0.7394(3) 0.0769(12) Uani 1 1 d . U . . .
N7 N 0.1994(7) 0.6730(6) 1.1561(3) 0.0870(16) Uani 1 1 d . U . . .
N8 N 0.1238(6) 0.8269(5) 1.1607(3) 0.0759(14) Uani 1 1 d . U . . .
C1 C 0.2951(6) -0.1098(6) 0.5544(4) 0.0611(14) Uani 1 1 d . U . . .
C2 C 0.3579(7) -0.1877(7) 0.5970(5) 0.0805(19) Uani 1 1 d . U . . .
H2 H 0.3673 -0.1764 0.6356 0.097 Uiso 1 1 calc R . . . .
C3 C 0.4068(8) -0.2821(8) 0.5827(6) 0.094(2) Uani 1 1 d . U . . .
H3 H 0.4500 -0.3349 0.6114 0.113 Uiso 1 1 calc R . . . .
C4 C 0.3925(7) -0.2985(7) 0.5272(6) 0.095(3) Uani 1 1 d . U . . .
H4 H 0.4270 -0.3626 0.5172 0.114 Uiso 1 1 calc R . . . .
C5 C 0.3282(7) -0.2227(7) 0.4858(6) 0.084(2) Uani 1 1 d . U . . .
H5 H 0.3172 -0.2351 0.4480 0.101 Uiso 1 1 calc R . . . .
C6 C 0.2790(6) -0.1274(7) 0.4993(4) 0.0662(16) Uani 1 1 d . U . . .
H6 H 0.2348 -0.0753 0.4707 0.079 Uiso 1 1 calc R . . . .
C7 C 0.2443(6) -0.0051(7) 0.5676(4) 0.0653(14) Uani 1 1 d . U . . .
H7A H 0.1780 0.0299 0.5492 0.078 Uiso 1 1 calc R . . . .
H7B H 0.2348 -0.0069 0.6126 0.078 Uiso 1 1 calc R . . . .
C8 C 0.2895(4) 0.1052(5) 0.4872(3) 0.0415(10) Uani 1 1 d . U . . .
C9 C 0.4181(4) 0.1003(5) 0.5319(3) 0.0441(10) Uani 1 1 d . U . . .
C10 C 0.3816(5) 0.0424(5) 0.5718(3) 0.0468(11) Uani 1 1 d . U . . .
C11 C 0.4233(5) -0.0059(6) 0.6290(4) 0.0572(13) Uani 1 1 d . U . . .
H11 H 0.3985 -0.0453 0.6570 0.069 Uiso 1 1 calc R . . . .
C12 C 0.5028(5) 0.0068(6) 0.6428(4) 0.0630(15) Uani 1 1 d . U . . .
H12 H 0.5332 -0.0247 0.6814 0.076 Uiso 1 1 calc R . . . .
C13 C 0.5399(5) 0.0650(6) 0.6015(4) 0.0622(15) Uani 1 1 d . U . . .
H13 H 0.5948 0.0713 0.6128 0.075 Uiso 1 1 calc R . . . .
C14 C 0.4983(5) 0.1129(5) 0.5451(4) 0.0536(13) Uani 1 1 d . U . . .
H14 H 0.5229 0.1522 0.5169 0.064 Uiso 1 1 calc R . . . .
C15 C 0.3677(5) 0.2055(5) 0.4276(3) 0.0472(11) Uani 1 1 d . U . . .
H15A H 0.3221 0.2150 0.3958 0.057 Uiso 1 1 calc R . . . .
H15B H 0.4361 0.1772 0.4100 0.057 Uiso 1 1 calc R . . . .
C16 C 0.3432(5) 0.3048(5) 0.4432(4) 0.0519(15) Uani 1 1 d . U . . .
H16A H 0.3940 0.2985 0.4702 0.062 Uiso 1 1 calc R . . . .
H16B H 0.3411 0.3520 0.4053 0.062 Uiso 1 1 calc R . . . .
C17 C 0.2147(5) 0.4227(5) 0.4960(3) 0.0496(12) Uani 1 1 d . U . . .
C18 C 0.1309(6) 0.4462(5) 0.5362(3) 0.0516(13) Uani 1 1 d . U . . .
C19 C 0.0855(6) 0.3788(5) 0.5560(3) 0.0539(14) Uani 1 1 d . U . . .
C20 C -0.0066(6) 0.4088(5) 0.5965(3) 0.0530(13) Uani 1 1 d . U . . .
C21 C -0.0531(5) 0.3501(5) 0.6118(3) 0.0544(13) Uani 1 1 d . U . . .
H21 H -0.0270 0.2901 0.5966 0.065 Uiso 1 1 calc R . . . .
C22 C -0.1388(6) 0.3768(7) 0.6495(4) 0.0683(18) Uani 1 1 d . U . . .
H22 H -0.1698 0.3346 0.6606 0.082 Uiso 1 1 calc R . . . .
C23 C -0.1779(6) 0.4652(7) 0.6704(4) 0.0706(17) Uani 1 1 d . U . . .
H23 H -0.2378 0.4851 0.6945 0.085 Uiso 1 1 calc R . . . .
C24 C -0.1314(6) 0.5234(6) 0.6568(3) 0.0622(14) Uani 1 1 d . U . . .
H24 H -0.1577 0.5825 0.6729 0.075 Uiso 1 1 calc R . . . .
C25 C -0.0441(6) 0.4977(5) 0.6188(3) 0.0566(13) Uani 1 1 d . U . . .
C26 C 0.0081(7) 0.5583(5) 0.6061(3) 0.0624(15) Uani 1 1 d . U . . .
C27 C 0.0908(7) 0.5367(5) 0.5585(3) 0.0625(16) Uani 1 1 d . U . . .
C28 C 0.1314(9) 0.6001(6) 0.5398(3) 0.076(2) Uani 1 1 d . U . . .
C29 C 0.2165(8) 0.5738(6) 0.5016(4) 0.0698(18) Uani 1 1 d . U . . .
H29 H 0.2460 0.6173 0.4895 0.084 Uiso 1 1 calc R . . . .
C30 C 0.2584(7) 0.4837(5) 0.4810(4) 0.0600(15) Uani 1 1 d . U . . .
H30 H 0.3178 0.4651 0.4565 0.072 Uiso 1 1 calc R . . . .
C31 C 0.1194(7) 0.7525(6) 0.5452(4) 0.0675(17) Uani 1 1 d . U . . .
H31A H 0.1318 0.7678 0.5005 0.081 Uiso 1 1 calc R . . . .
H31B H 0.1836 0.7220 0.5659 0.081 Uiso 1 1 calc R . . . .
C32 C 0.0506(5) 0.8445(5) 0.5688(3) 0.0421(11) Uani 1 1 d . U . . .
H32A H 0.0862 0.8838 0.5699 0.050 Uiso 1 1 calc R . . . .
H32B H -0.0053 0.8838 0.5406 0.050 Uiso 1 1 calc R . . . .
C33 C 0.0663(5) 0.7856(4) 0.6829(3) 0.0412(10) Uani 1 1 d . U . . .
C34 C 0.0046(5) 0.7667(4) 0.7307(3) 0.0422(10) Uani 1 1 d . U . . .
C35 C 0.0357(6) 0.7304(5) 0.7898(3) 0.0557(13) Uani 1 1 d . U . . .
H35 H -0.0067 0.7185 0.8220 0.067 Uiso 1 1 calc R . . . .
C36 C 0.1304(7) 0.7117(6) 0.8011(4) 0.0674(17) Uani 1 1 d . U . . .
H36 H 0.1543 0.6858 0.8416 0.081 Uiso 1 1 calc R . . . .
C37 C 0.1914(6) 0.7300(6) 0.7545(4) 0.0642(16) Uani 1 1 d . U . . .
H37 H 0.2564 0.7161 0.7642 0.077 Uiso 1 1 calc R . . . .
C38 C 0.1622(5) 0.7676(5) 0.6945(3) 0.0528(14) Uani 1 1 d . U . . .
H38 H 0.2048 0.7804 0.6630 0.063 Uiso 1 1 calc R . . . .
C39 C -0.0780(5) 0.8243(4) 0.6422(3) 0.0380(10) Uani 1 1 d . U . . .
C40 C -0.1659(6) 0.7764(6) 0.7346(3) 0.0586(15) Uani 1 1 d . U . . .
H40A H -0.1403 0.7243 0.7710 0.070 Uiso 1 1 calc R . . . .
H40B H -0.1933 0.7525 0.7071 0.070 Uiso 1 1 calc R . . . .
C41 C -0.2480(5) 0.8659(6) 0.7551(3) 0.0541(14) Uani 1 1 d . U . . .
C42 C -0.2423(7) 0.9509(7) 0.7521(5) 0.080(3) Uani 1 1 d . U . . .
H42 H -0.1833 0.9558 0.7366 0.096 Uiso 1 1 calc R . . . .
C43 C -0.3227(8) 1.0317(9) 0.7717(6) 0.102(3) Uani 1 1 d . U . . .
H43 H -0.3199 1.0922 0.7684 0.122 Uiso 1 1 calc R . . . .
C44 C -0.4072(8) 1.0217(10) 0.7962(5) 0.103(3) Uani 1 1 d . U . . .
H44 H -0.4625 1.0755 0.8101 0.124 Uiso 1 1 calc R . . . .
C45 C -0.4102(8) 0.9387(11) 0.7999(6) 0.112(3) Uani 1 1 d . U . . .
H45 H -0.4679 0.9323 0.8168 0.135 Uiso 1 1 calc R . . . .
C46 C -0.3321(6) 0.8606(8) 0.7801(5) 0.086(2) Uani 1 1 d . U . . .
H46 H -0.3365 0.8007 0.7839 0.104 Uiso 1 1 calc R . . . .
C47 C 0.2252(5) 0.0958(4) 0.7349(3) 0.0852(18) Uani 1 1 d D U . . .
C48 C 0.2922(5) 0.0870(4) 0.7760(3) 0.079(2) Uani 1 1 d G U . . .
H48 H 0.3144 0.1361 0.7719 0.094 Uiso 1 1 calc R . . . .
C49 C 0.3268(5) 0.0066(5) 0.8232(3) 0.093(2) Uani 1 1 d G U . . .
H49 H 0.3726 0.0005 0.8513 0.112 Uiso 1 1 calc R . . . .
C50 C 0.2943(6) -0.0652(4) 0.8293(3) 0.099(2) Uani 1 1 d G U . . .
H50 H 0.3179 -0.1202 0.8615 0.118 Uiso 1 1 calc R . . . .
C51 C 0.2273(6) -0.0564(5) 0.7882(4) 0.108(2) Uani 1 1 d G U . . .
H51 H 0.2051 -0.1054 0.7924 0.130 Uiso 1 1 calc R . . . .
C52 C 0.1927(5) 0.0241(6) 0.7410(3) 0.097(2) Uani 1 1 d G U . . .
H52 H 0.1469 0.0301 0.7129 0.117 Uiso 1 1 calc R . . . .
C53 C 0.1933(9) 0.1828(6) 0.6835(4) 0.1004(18) Uani 1 1 d D U . . .
H53A H 0.2433 0.1667 0.6494 0.120 Uiso 1 1 calc R . . . .
H53B H 0.1298 0.1940 0.6679 0.120 Uiso 1 1 calc R . . . .
C54 C 0.1060(8) 0.3256(6) 0.7371(4) 0.0852(15) Uani 1 1 d . U . . .
C55 C 0.1936(8) 0.4141(7) 0.7053(4) 0.0830(16) Uani 1 1 d . U . . .
C56 C 0.2267(8) 0.4825(8) 0.6933(4) 0.0871(16) Uani 1 1 d . U . . .
H56 H 0.1949 0.5420 0.7093 0.104 Uiso 1 1 calc R . . . .
C57 C 0.3122(9) 0.4591(10) 0.6550(5) 0.110(2) Uani 1 1 d . U . . .
H57 H 0.3428 0.5017 0.6441 0.132 Uiso 1 1 calc R . . . .
C58 C 0.3522(9) 0.3655(11) 0.6328(5) 0.112(2) Uani 1 1 d . U . . .
H58 H 0.4101 0.3507 0.6070 0.135 Uiso 1 1 calc R . . . .
C59 C 0.3181(10) 0.2993(11) 0.6439(5) 0.119(3) Uani 1 1 d . U . . .
H59 H 0.3480 0.2411 0.6265 0.142 Uiso 1 1 calc R . . . .
C60 C 0.2353(8) 0.3214(8) 0.6828(4) 0.0890(15) Uani 1 1 d . U . . .
C61 C 0.0462(8) 0.4831(6) 0.7762(3) 0.0701(18) Uani 1 1 d . U . . .
H61A H -0.0133 0.4722 0.7886 0.084 Uiso 1 1 calc R . . . .
H61B H 0.0244 0.5497 0.7516 0.084 Uiso 1 1 calc R . . . .
C62 C 0.0965(7) 0.4755(5) 0.8323(3) 0.0625(19) Uani 1 1 d . U . . .
H62A H 0.1253 0.4073 0.8551 0.075 Uiso 1 1 calc R . . . .
H62B H 0.1503 0.4956 0.8209 0.075 Uiso 1 1 calc R . . . .
C63 C 0.0500(8) 0.5528(5) 0.9215(3) 0.0659(15) Uani 1 1 d . U . . .
C64 C -0.0230(8) 0.6239(5) 0.9539(3) 0.0657(14) Uani 1 1 d . U . . .
C65 C -0.1227(8) 0.6854(6) 0.9318(3) 0.0796(19) Uani 1 1 d . U . . .
C66 C -0.1789(9) 0.7745(7) 0.9589(5) 0.092(3) Uani 1 1 d . U . . .
C67 C -0.2604(9) 0.8460(8) 0.9294(5) 0.099(3) Uani 1 1 d . U . . .
H67 H -0.2775 0.8398 0.8914 0.119 Uiso 1 1 calc R . . . .
C68 C -0.3183(10) 0.9280(9) 0.9555(6) 0.110(3) Uani 1 1 d . U . . .
H68 H -0.3752 0.9785 0.9346 0.132 Uiso 1 1 calc R . . . .
C69 C -0.2957(12) 0.9391(10) 1.0120(6) 0.128(5) Uani 1 1 d . U . . .
H69 H -0.3379 0.9950 1.0301 0.154 Uiso 1 1 calc R . . . .
C70 C -0.2121(10) 0.8678(8) 1.0400(6) 0.103(3) Uani 1 1 d . U . . .
H70 H -0.1928 0.8749 1.0771 0.123 Uiso 1 1 calc R . . . .
C71 C -0.1552(10) 0.7849(8) 1.0143(5) 0.098(3) Uani 1 1 d . U . . .
C72 C -0.0717(8) 0.7143(6) 1.0439(3) 0.0751(19) Uani 1 1 d . U . . .
C73 C 0.0043(8) 0.6376(5) 1.0088(3) 0.0699(16) Uani 1 1 d . U . . .
C74 C 0.0981(9) 0.5808(6) 1.0299(3) 0.0774(19) Uani 1 1 d . U . . .
C75 C 0.1698(9) 0.5143(6) 0.9953(3) 0.0748(18) Uani 1 1 d . U . . .
H75 H 0.2362 0.4783 1.0086 0.090 Uiso 1 1 calc R . . . .
C76 C 0.1444(8) 0.5007(6) 0.9420(3) 0.0697(16) Uani 1 1 d . U . . .
H76 H 0.1933 0.4543 0.9191 0.084 Uiso 1 1 calc R . . . .
C77 C 0.2186(10) 0.5386(8) 1.1038(5) 0.103(3) Uani 1 1 d . U . . .
H77A H 0.2661 0.5510 1.0730 0.124 Uiso 1 1 calc R . . . .
H77B H 0.2355 0.4680 1.1103 0.124 Uiso 1 1 calc R . . . .
C78 C 0.2227(10) 0.5687(7) 1.1644(5) 0.103(2) Uani 1 1 d . U . . .
H78A H 0.1748 0.5558 1.1946 0.124 Uiso 1 1 calc R . . . .
H78B H 0.2899 0.5283 1.1811 0.124 Uiso 1 1 calc R . . . .
C79 C 0.1150(8) 0.7434(6) 1.1773(3) 0.0800(17) Uani 1 1 d . U . . .
C80 C 0.2131(8) 0.8087(8) 1.1314(4) 0.0850(17) Uani 1 1 d . U . . .
C81 C 0.2528(8) 0.8710(10) 1.1079(5) 0.099(2) Uani 1 1 d . U . . .
H81 H 0.2180 0.9388 1.1102 0.119 Uiso 1 1 calc R . . . .
C82 C 0.3519(10) 0.8293(11) 1.0786(7) 0.121(3) Uani 1 1 d . U . . .
H82 H 0.3857 0.8675 1.0614 0.146 Uiso 1 1 calc R . . . .
C83 C 0.3940(11) 0.7247(12) 1.0783(7) 0.123(3) Uani 1 1 d . U . . .
H83 H 0.4579 0.6961 1.0593 0.148 Uiso 1 1 calc R . . . .
C84 C 0.3562(10) 0.6672(11) 1.1001(6) 0.113(3) Uani 1 1 d . U . . .
H84 H 0.3896 0.5993 1.0977 0.135 Uiso 1 1 calc R . . . .
C85 C 0.2593(8) 0.7107(8) 1.1288(5) 0.0912(18) Uani 1 1 d . U . . .
C86 C 0.0496(8) 0.9209(6) 1.1770(4) 0.0745(19) Uani 1 1 d . U . . .
H86A H 0.0832 0.9495 1.1963 0.089 Uiso 1 1 calc R . . . .
H86B H 0.0019 0.9089 1.2078 0.089 Uiso 1 1 calc R . . . .
C87 C -0.0065(6) 0.9938(6) 1.1225(3) 0.0609(15) Uani 1 1 d . U . . .
C88 C -0.0565(7) 0.9704(6) 1.0867(4) 0.0699(19) Uani 1 1 d . U . . .
H88 H -0.0528 0.9065 1.0944 0.084 Uiso 1 1 calc R . . . .
C89 C -0.1135(8) 1.0410(7) 1.0385(4) 0.084(2) Uani 1 1 d . U . . .
H89 H -0.1470 1.0244 1.0128 0.100 Uiso 1 1 calc R . . . .
C90 C -0.1207(7) 1.1326(7) 1.0288(4) 0.080(2) Uani 1 1 d . U . . .
H90 H -0.1609 1.1807 0.9969 0.096 Uiso 1 1 calc R . . . .
C91 C -0.0716(8) 1.1566(7) 1.0639(4) 0.086(2) Uani 1 1 d . U . . .
H91 H -0.0772 1.2212 1.0563 0.103 Uiso 1 1 calc R . . . .
C92 C -0.0124(7) 1.0869(6) 1.1114(4) 0.0734(19) Uani 1 1 d . U . . .
H92 H 0.0231 1.1034 1.1356 0.088 Uiso 1 1 calc R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C8 2.090(7) . ?
Ag1 C39 2.089(7) 2_566 ?
Ag2 C54 2.049(13) . ?
Ag2 C79 2.073(12) 2_567 ?
P1 F1 1.564(7) . ?
P1 F2 1.542(7) . ?
P1 F3 1.499(8) . ?
P1 F4 1.582(7) . ?
P1 F5 1.537(8) . ?
P1 F6 1.568(8) . ?
P2 F7 1.534(8) . ?
P2 F8 1.470(10) . ?
P2 F9 1.578(6) . ?
P2 F10 1.643(8) . ?
P2 F11 1.597(6) . ?
P2 F12 1.556(7) . ?
O1 C16 1.411(8) . ?
O1 C17 1.367(8) . ?
O2 C19 1.218(8) . ?
O3 C26 1.226(8) . ?
O4 C28 1.369(10) . ?
O4 C31 1.321(10) . ?
O5 C62 1.424(9) . ?
O5 C63 1.374(10) . ?
O6 C65 1.221(11) . ?
O7 C72 1.229(10) . ?
O8 C74 1.380(10) . ?
O8 C77 1.395(14) . ?
N1 C7 1.460(9) . ?
N1 C8 1.342(9) . ?
N1 C10 1.391(9) . ?
N2 C8 1.352(8) . ?
N2 C9 1.403(9) . ?
N2 C15 1.434(9) . ?
N3 C32 1.464(8) . ?
N3 C33 1.373(9) . ?
N3 C39 1.347(8) . ?
N4 C34 1.399(9) . ?
N4 C39 1.341(8) . ?
N4 C40 1.453(8) . ?
N5 C53 1.493(13) . ?
N5 C54 1.330(13) . ?
N5 C60 1.306(15) . ?
N6 C54 1.394(13) . ?
N6 C55 1.371(14) . ?
N6 C61 1.452(10) . ?
N7 C78 1.471(14) . ?
N7 C79 1.358(11) . ?
N7 C85 1.323(15) . ?
N8 C79 1.339(13) . ?
N8 C80 1.361(14) . ?
N8 C86 1.468(10) . ?
C1 C2 1.399(12) . ?
C1 C6 1.383(12) . ?
C1 C7 1.526(12) . ?
C2 H2 0.9500 . ?
C2 C3 1.396(16) . ?
C3 H3 0.9500 . ?
C3 C4 1.373(17) . ?
C4 H4 0.9500 . ?
C4 C5 1.379(15) . ?
C5 H5 0.9500 . ?
C5 C6 1.402(13) . ?
C6 H6 0.9500 . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C9 C10 1.384(10) . ?
C9 C14 1.390(9) . ?
C10 C11 1.396(11) . ?
C11 H11 0.9500 . ?
C11 C12 1.387(11) . ?
C12 H12 0.9500 . ?
C12 C13 1.406(12) . ?
C13 H13 0.9500 . ?
C13 C14 1.380(12) . ?
C14 H14 0.9500 . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?
C15 C16 1.521(9) . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C17 C18 1.411(11) . ?
C17 C30 1.359(11) . ?
C18 C19 1.473(11) . ?
C18 C27 1.426(9) . ?
C19 C20 1.503(10) . ?
C20 C21 1.362(11) . ?
C20 C25 1.408(9) . ?
C21 H21 0.9500 . ?
C21 C22 1.398(11) . ?
C22 H22 0.9500 . ?
C22 C23 1.382(11) . ?
C23 H23 0.9500 . ?
C23 C24 1.354(13) . ?
C24 H24 0.9500 . ?
C24 C25 1.419(11) . ?
C25 C26 1.454(12) . ?
C26 C27 1.500(12) . ?
C27 C28 1.360(12) . ?
C28 C29 1.399(13) . ?
C29 H29 0.9500 . ?
C29 C30 1.401(10) . ?
C30 H30 0.9500 . ?
C31 H31A 0.9900 . ?
C31 H31B 0.9900 . ?
C31 C32 1.492(9) . ?
C32 H32A 0.9900 . ?
C32 H32B 0.9900 . ?
C33 C34 1.406(9) . ?
C33 C38 1.397(10) . ?
C34 C35 1.368(10) . ?
C35 H35 0.9500 . ?
C35 C36 1.373(12) . ?
C36 H36 0.9500 . ?
C36 C37 1.379(12) . ?
C37 H37 0.9500 . ?
C37 C38 1.378(11) . ?
C38 H38 0.9500 . ?
C39 Ag1 2.089(7) 2_566 ?
C40 H40A 0.9900 . ?
C40 H40B 0.9900 . ?
C40 C41 1.497(11) . ?
C41 C42 1.353(12) . ?
C41 C46 1.362(11) . ?
C42 H42 0.9500 . ?
C42 C43 1.398(13) . ?
C43 H43 0.9500 . ?
C43 C44 1.395(17) . ?
C44 H44 0.9500 . ?
C44 C45 1.298(18) . ?
C45 H45 0.9500 . ?
C45 C46 1.361(16) . ?
C46 H46 0.9500 . ?
C47 C48 1.3900 . ?
C47 C52 1.3900 . ?
C47 C53 1.506(8) . ?
C48 H48 0.9500 . ?
C48 C49 1.3900 . ?
C49 H49 0.9500 . ?
C49 C50 1.3900 . ?
C50 H50 0.9500 . ?
C50 C51 1.3900 . ?
C51 H51 0.9500 . ?
C51 C52 1.3900 . ?
C52 H52 0.9500 . ?
C53 H53A 0.9900 . ?
C53 H53B 0.9900 . ?
C55 C56 1.341(16) . ?
C55 C60 1.456(12) . ?
C56 H56 0.9500 . ?
C56 C57 1.404(16) . ?
C57 H57 0.9500 . ?
C57 C58 1.468(19) . ?
C58 H58 0.9500 . ?
C58 C59 1.32(2) . ?
C59 H59 0.9500 . ?
C59 C60 1.384(17) . ?
C61 H61A 0.9900 . ?
C61 H61B 0.9900 . ?
C61 C62 1.497(12) . ?
C62 H62A 0.9900 . ?
C62 H62B 0.9900 . ?
C63 C64 1.409(11) . ?
C63 C76 1.361(13) . ?
C64 C65 1.450(14) . ?
C64 C73 1.421(11) . ?
C65 C66 1.468(12) . ?
C66 C67 1.353(15) . ?
C66 C71 1.385(15) . ?
C67 H67 0.9500 . ?
C67 C68 1.375(14) . ?
C68 H68 0.9500 . ?
C68 C69 1.407(17) . ?
C69 H69 0.9500 . ?
C69 C70 1.358(17) . ?
C70 H70 0.9500 . ?
C70 C71 1.380(13) . ?
C71 C72 1.368(15) . ?
C72 C73 1.508(11) . ?
C73 C74 1.365(14) . ?
C74 C75 1.396(12) . ?
C75 H75 0.9500 . ?
C75 C76 1.374(12) . ?
C76 H76 0.9500 . ?
C77 H77A 0.9900 . ?
C77 H77B 0.9900 . ?
C77 C78 1.532(13) . ?
C78 H78A 0.9900 . ?
C78 H78B 0.9900 . ?
C79 Ag2 2.073(12) 2_567 ?
C80 C81 1.352(17) . ?
C80 C85 1.368(14) . ?
C81 H81 0.9500 . ?
C81 C82 1.467(18) . ?
C82 H82 0.9500 . ?
C82 C83 1.45(2) . ?
C83 H83 0.9500 . ?
C83 C84 1.26(2) . ?
C84 H84 0.9500 . ?
C84 C85 1.438(17) . ?
C86 H86A 0.9900 . ?
C86 H86B 0.9900 . ?
C86 C87 1.509(11) . ?
C87 C88 1.364(12) . ?
C87 C92 1.381(12) . ?
C88 H88 0.9500 . ?
C88 C89 1.403(12) . ?
C89 H89 0.9500 . ?
C89 C90 1.353(14) . ?
C90 H90 0.9500 . ?
C90 C91 1.348(15) . ?
C91 H91 0.9500 . ?
C91 C92 1.400(13) . ?
C92 H92 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C8 Ag1 C39 178.8(2) . 2_566 ?
C54 Ag2 C79 174.6(3) . 2_567 ?
F1 P1 F4 91.3(4) . . ?
F1 P1 F6 87.3(6) . . ?
F2 P1 F1 86.8(5) . . ?
F2 P1 F4 178.0(5) . . ?
F2 P1 F6 89.9(5) . . ?
F3 P1 F1 177.6(5) . . ?
F3 P1 F2 90.8(5) . . ?
F3 P1 F4 91.0(5) . . ?
F3 P1 F5 92.2(7) . . ?
F3 P1 F6 93.0(7) . . ?
F5 P1 F1 87.6(6) . . ?
F5 P1 F2 92.7(5) . . ?
F5 P1 F4 87.9(4) . . ?
F5 P1 F6 174.1(7) . . ?
F6 P1 F4 89.4(5) . . ?
F7 P2 F9 178.6(7) . . ?
F7 P2 F10 93.3(7) . . ?
F7 P2 F11 87.8(4) . . ?
F7 P2 F12 89.5(4) . . ?
F8 P2 F7 85.2(8) . . ?
F8 P2 F9 96.1(7) . . ?
F8 P2 F10 177.7(5) . . ?
F8 P2 F11 92.3(5) . . ?
F8 P2 F12 96.4(6) . . ?
F9 P2 F10 85.3(4) . . ?
F9 P2 F11 92.4(3) . . ?
F11 P2 F10 85.8(3) . . ?
F12 P2 F9 90.1(4) . . ?
F12 P2 F10 85.4(5) . . ?
F12 P2 F11 170.7(5) . . ?
C17 O1 C16 117.1(5) . . ?
C31 O4 C28 119.3(8) . . ?
C63 O5 C62 118.1(7) . . ?
C74 O8 C77 117.8(7) . . ?
C8 N1 C7 124.2(6) . . ?
C8 N1 C10 110.9(5) . . ?
C10 N1 C7 124.8(6) . . ?
C8 N2 C9 110.1(6) . . ?
C8 N2 C15 124.3(6) . . ?
C9 N2 C15 125.5(5) . . ?
C33 N3 C32 124.8(5) . . ?
C39 N3 C32 123.9(6) . . ?
C39 N3 C33 110.8(5) . . ?
C34 N4 C40 123.5(6) . . ?
C39 N4 C34 110.7(5) . . ?
C39 N4 C40 125.7(6) . . ?
C54 N5 C53 122.6(12) . . ?
C54 N5 C60 109.9(9) . . ?
C60 N5 C53 127.5(9) . . ?
C54 N6 C61 122.9(9) . . ?
C55 N6 C54 111.4(7) . . ?
C55 N6 C61 125.6(8) . . ?
C79 N7 C78 124.8(11) . . ?
C85 N7 C78 124.5(9) . . ?
C85 N7 C79 110.6(9) . . ?
C79 N8 C80 109.8(8) . . ?
C79 N8 C86 123.3(9) . . ?
C80 N8 C86 126.8(9) . . ?
C2 C1 C7 121.1(9) . . ?
C6 C1 C2 119.7(9) . . ?
C6 C1 C7 119.2(8) . . ?
C1 C2 H2 120.0 . . ?
C3 C2 C1 119.9(11) . . ?
C3 C2 H2 120.0 . . ?
C2 C3 H3 120.0 . . ?
C4 C3 C2 120.0(10) . . ?
C4 C3 H3 120.0 . . ?
C3 C4 H4 119.8 . . ?
C3 C4 C5 120.4(11) . . ?
C5 C4 H4 119.8 . . ?
C4 C5 H5 119.9 . . ?
C4 C5 C6 120.3(10) . . ?
C6 C5 H5 119.9 . . ?
C1 C6 C5 119.6(9) . . ?
C1 C6 H6 120.2 . . ?
C5 C6 H6 120.2 . . ?
N1 C7 C1 111.5(6) . . ?
N1 C7 H7A 109.3 . . ?
N1 C7 H7B 109.3 . . ?
C1 C7 H7A 109.3 . . ?
C1 C7 H7B 109.3 . . ?
H7A C7 H7B 108.0 . . ?
N1 C8 Ag1 128.0(4) . . ?
N1 C8 N2 106.7(6) . . ?
N2 C8 Ag1 125.3(5) . . ?
C10 C9 N2 106.0(5) . . ?
C10 C9 C14 123.1(7) . . ?
C14 C9 N2 130.8(7) . . ?
N1 C10 C11 132.7(7) . . ?
C9 C10 N1 106.3(6) . . ?
C9 C10 C11 120.9(7) . . ?
C10 C11 H11 121.8 . . ?
C12 C11 C10 116.4(8) . . ?
C12 C11 H11 121.8 . . ?
C11 C12 H12 119.0 . . ?
C11 C12 C13 122.1(8) . . ?
C13 C12 H12 119.0 . . ?
C12 C13 H13 119.3 . . ?
C14 C13 C12 121.4(7) . . ?
C14 C13 H13 119.3 . . ?
C9 C14 H14 122.0 . . ?
C13 C14 C9 116.1(7) . . ?
C13 C14 H14 122.0 . . ?
N2 C15 H15A 109.0 . . ?
N2 C15 H15B 109.0 . . ?
N2 C15 C16 113.1(6) . . ?
H15A C15 H15B 107.8 . . ?
C16 C15 H15A 109.0 . . ?
C16 C15 H15B 109.0 . . ?
O1 C16 C15 106.5(5) . . ?
O1 C16 H16A 110.4 . . ?
O1 C16 H16B 110.4 . . ?
C15 C16 H16A 110.4 . . ?
C15 C16 H16B 110.4 . . ?
H16A C16 H16B 108.6 . . ?
O1 C17 C18 117.5(6) . . ?
C30 C17 O1 122.4(7) . . ?
C30 C17 C18 120.1(6) . . ?
C17 C18 C19 121.3(6) . . ?
C17 C18 C27 118.8(7) . . ?
C27 C18 C19 119.9(7) . . ?
O2 C19 C18 122.7(7) . . ?
O2 C19 C20 117.7(7) . . ?
C18 C19 C20 119.5(6) . . ?
C21 C20 C19 120.2(6) . . ?
C21 C20 C25 120.3(7) . . ?
C25 C20 C19 119.6(7) . . ?
C20 C21 H21 119.5 . . ?
C20 C21 C22 120.9(7) . . ?
C22 C21 H21 119.5 . . ?
C21 C22 H22 120.3 . . ?
C23 C22 C21 119.4(9) . . ?
C23 C22 H22 120.3 . . ?
C22 C23 H23 119.8 . . ?
C24 C23 C22 120.4(8) . . ?
C24 C23 H23 119.8 . . ?
C23 C24 H24 119.4 . . ?
C23 C24 C25 121.3(7) . . ?
C25 C24 H24 119.4 . . ?
C20 C25 C24 117.7(8) . . ?
C20 C25 C26 120.9(7) . . ?
C24 C25 C26 121.3(6) . . ?
O3 C26 C25 119.2(7) . . ?
O3 C26 C27 121.4(8) . . ?
C25 C26 C27 119.3(6) . . ?
C18 C27 C26 119.3(7) . . ?
C28 C27 C18 120.3(8) . . ?
C28 C27 C26 120.2(6) . . ?
O4 C28 C29 123.7(8) . . ?
C27 C28 O4 116.1(9) . . ?
C27 C28 C29 119.9(7) . . ?
C28 C29 H29 119.9 . . ?
C28 C29 C30 120.2(8) . . ?
C30 C29 H29 119.9 . . ?
C17 C30 C29 120.5(8) . . ?
C17 C30 H30 119.8 . . ?
C29 C30 H30 119.8 . . ?
O4 C31 H31A 109.8 . . ?
O4 C31 H31B 109.8 . . ?
O4 C31 C32 109.3(7) . . ?
H31A C31 H31B 108.3 . . ?
C32 C31 H31A 109.8 . . ?
C32 C31 H31B 109.8 . . ?
N3 C32 C31 111.0(5) . . ?
N3 C32 H32A 109.4 . . ?
N3 C32 H32B 109.4 . . ?
C31 C32 H32A 109.4 . . ?
C31 C32 H32B 109.4 . . ?
H32A C32 H32B 108.0 . . ?
N3 C33 C34 106.5(6) . . ?
N3 C33 C38 132.8(6) . . ?
C38 C33 C34 120.6(6) . . ?
N4 C34 C33 105.0(5) . . ?
C35 C34 N4 133.3(6) . . ?
C35 C34 C33 121.7(7) . . ?
C34 C35 H35 121.2 . . ?
C34 C35 C36 117.5(7) . . ?
C36 C35 H35 121.2 . . ?
C35 C36 H36 119.4 . . ?
C35 C36 C37 121.2(8) . . ?
C37 C36 H36 119.4 . . ?
C36 C37 H37 118.6 . . ?
C38 C37 C36 122.8(8) . . ?
C38 C37 H37 118.6 . . ?
C33 C38 H38 122.0 . . ?
C37 C38 C33 116.1(7) . . ?
C37 C38 H38 122.0 . . ?
N3 C39 Ag1 125.9(4) . 2_566 ?
N4 C39 Ag1 126.9(4) . 2_566 ?
N4 C39 N3 107.0(6) . . ?
N4 C40 H40A 108.7 . . ?
N4 C40 H40B 108.7 . . ?
N4 C40 C41 114.4(6) . . ?
H40A C40 H40B 107.6 . . ?
C41 C40 H40A 108.7 . . ?
C41 C40 H40B 108.7 . . ?
C42 C41 C40 123.8(7) . . ?
C42 C41 C46 118.0(9) . . ?
C46 C41 C40 118.1(8) . . ?
C41 C42 H42 119.9 . . ?
C41 C42 C43 120.3(9) . . ?
C43 C42 H42 119.9 . . ?
C42 C43 H43 120.6 . . ?
C44 C43 C42 118.7(12) . . ?
C44 C43 H43 120.6 . . ?
C43 C44 H44 120.1 . . ?
C45 C44 C43 119.9(11) . . ?
C45 C44 H44 120.1 . . ?
C44 C45 H45 119.4 . . ?
C44 C45 C46 121.3(11) . . ?
C46 C45 H45 119.4 . . ?
C41 C46 H46 119.1 . . ?
C45 C46 C41 121.8(11) . . ?
C45 C46 H46 119.1 . . ?
C48 C47 C52 120.0 . . ?
C48 C47 C53 117.5(7) . . ?
C52 C47 C53 122.5(7) . . ?
C47 C48 H48 120.0 . . ?
C49 C48 C47 120.0 . . ?
C49 C48 H48 120.0 . . ?
C48 C49 H49 120.0 . . ?
C48 C49 C50 120.0 . . ?
C50 C49 H49 120.0 . . ?
C49 C50 H50 120.0 . . ?
C49 C50 C51 120.0 . . ?
C51 C50 H50 120.0 . . ?
C50 C51 H51 120.0 . . ?
C52 C51 C50 120.0 . . ?
C52 C51 H51 120.0 . . ?
C47 C52 H52 120.0 . . ?
C51 C52 C47 120.0 . . ?
C51 C52 H52 120.0 . . ?
N5 C53 C47 114.8(7) . . ?
N5 C53 H53A 108.6 . . ?
N5 C53 H53B 108.6 . . ?
C47 C53 H53A 108.6 . . ?
C47 C53 H53B 108.6 . . ?
H53A C53 H53B 107.5 . . ?
N5 C54 Ag2 125.9(8) . . ?
N5 C54 N6 106.7(11) . . ?
N6 C54 Ag2 127.4(7) . . ?
N6 C55 C60 100.9(10) . . ?
C56 C55 N6 131.6(8) . . ?
C56 C55 C60 127.5(11) . . ?
C55 C56 H56 122.8 . . ?
C55 C56 C57 114.5(11) . . ?
C57 C56 H56 122.8 . . ?
C56 C57 H57 121.6 . . ?
C56 C57 C58 116.8(14) . . ?
C58 C57 H57 121.6 . . ?
C57 C58 H58 115.8 . . ?
C59 C58 C57 128.4(13) . . ?
C59 C58 H58 115.8 . . ?
C58 C59 H59 122.7 . . ?
C58 C59 C60 114.6(12) . . ?
C60 C59 H59 122.7 . . ?
N5 C60 C55 111.0(10) . . ?
N5 C60 C59 130.7(11) . . ?
C59 C60 C55 118.1(14) . . ?
N6 C61 H61A 109.6 . . ?
N6 C61 H61B 109.6 . . ?
N6 C61 C62 110.3(7) . . ?
H61A C61 H61B 108.1 . . ?
C62 C61 H61A 109.6 . . ?
C62 C61 H61B 109.6 . . ?
O5 C62 C61 106.1(7) . . ?
O5 C62 H62A 110.5 . . ?
O5 C62 H62B 110.5 . . ?
C61 C62 H62A 110.5 . . ?
C61 C62 H62B 110.5 . . ?
H62A C62 H62B 108.7 . . ?
O5 C63 C64 117.2(9) . . ?
C76 C63 O5 122.3(7) . . ?
C76 C63 C64 120.5(8) . . ?
C63 C64 C65 122.4(8) . . ?
C63 C64 C73 118.1(9) . . ?
C73 C64 C65 119.5(7) . . ?
O6 C65 C64 121.8(7) . . ?
O6 C65 C66 122.6(10) . . ?
C64 C65 C66 115.2(9) . . ?
C67 C66 C65 117.4(10) . . ?
C67 C66 C71 119.7(9) . . ?
C71 C66 C65 122.8(10) . . ?
C66 C67 H67 120.5 . . ?
C66 C67 C68 119.0(11) . . ?
C68 C67 H67 120.5 . . ?
C67 C68 H68 119.0 . . ?
C67 C68 C69 121.9(12) . . ?
C69 C68 H68 119.0 . . ?
C68 C69 H69 120.9 . . ?
C70 C69 C68 118.2(11) . . ?
C70 C69 H69 120.9 . . ?
C69 C70 H70 120.2 . . ?
C69 C70 C71 119.6(11) . . ?
C71 C70 H70 120.2 . . ?
C70 C71 C66 121.5(11) . . ?
C72 C71 C66 120.4(9) . . ?
C72 C71 C70 118.0(10) . . ?
O7 C72 C71 120.2(8) . . ?
O7 C72 C73 121.4(10) . . ?
C71 C72 C73 118.2(8) . . ?
C64 C73 C72 119.4(9) . . ?
C74 C73 C64 120.1(7) . . ?
C74 C73 C72 120.5(8) . . ?
O8 C74 C75 121.2(10) . . ?
C73 C74 O8 118.5(7) . . ?
C73 C74 C75 120.1(8) . . ?
C74 C75 H75 120.0 . . ?
C76 C75 C74 120.1(10) . . ?
C76 C75 H75 120.0 . . ?
C63 C76 C75 120.9(8) . . ?
C63 C76 H76 119.6 . . ?
C75 C76 H76 119.6 . . ?
O8 C77 H77A 110.4 . . ?
O8 C77 H77B 110.4 . . ?
O8 C77 C78 106.5(8) . . ?
H77A C77 H77B 108.6 . . ?
C78 C77 H77A 110.4 . . ?
C78 C77 H77B 110.4 . . ?
N7 C78 C77 111.8(8) . . ?
N7 C78 H78A 109.3 . . ?
N7 C78 H78B 109.3 . . ?
C77 C78 H78A 109.3 . . ?
C77 C78 H78B 109.3 . . ?
H78A C78 H78B 107.9 . . ?
N7 C79 Ag2 122.8(8) . 2_567 ?
N8 C79 Ag2 131.4(7) . 2_567 ?
N8 C79 N7 105.6(10) . . ?
N8 C80 C85 106.5(11) . . ?
C81 C80 N8 129.6(10) . . ?
C81 C80 C85 123.9(12) . . ?
C80 C81 H81 121.5 . . ?
C80 C81 C82 117.1(13) . . ?
C82 C81 H81 121.5 . . ?
C81 C82 H82 122.8 . . ?
C83 C82 C81 114.4(15) . . ?
C83 C82 H82 122.8 . . ?
C82 C83 H83 116.0 . . ?
C84 C83 C82 128.0(15) . . ?
C84 C83 H83 116.0 . . ?
C83 C84 H84 122.1 . . ?
C83 C84 C85 115.9(14) . . ?
C85 C84 H84 122.1 . . ?
N7 C85 C80 107.4(10) . . ?
N7 C85 C84 132.0(12) . . ?
C80 C85 C84 120.7(14) . . ?
N8 C86 H86A 109.0 . . ?
N8 C86 H86B 109.0 . . ?
N8 C86 C87 113.0(6) . . ?
H86A C86 H86B 107.8 . . ?
C87 C86 H86A 109.0 . . ?
C87 C86 H86B 109.0 . . ?
C88 C87 C86 120.4(8) . . ?
C88 C87 C92 119.9(8) . . ?
C92 C87 C86 119.5(8) . . ?
C87 C88 H88 120.1 . . ?
C87 C88 C89 119.9(9) . . ?
C89 C88 H88 120.1 . . ?
C88 C89 H89 120.1 . . ?
C90 C89 C88 119.8(10) . . ?
C90 C89 H89 120.1 . . ?
C89 C90 H90 119.6 . . ?
C91 C90 C89 120.9(9) . . ?
C91 C90 H90 119.6 . . ?
C90 C91 H91 119.8 . . ?
C90 C91 C92 120.4(10) . . ?
C92 C91 H91 119.8 . . ?
C87 C92 C91 119.1(10) . . ?
C87 C92 H92 120.5 . . ?
C91 C92 H92 120.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 C17 C18 C19 3.1(10) . . . . ?
O1 C17 C18 C27 -177.9(6) . . . . ?
O1 C17 C30 C29 175.7(7) . . . . ?
O2 C19 C20 C21 -7.1(11) . . . . ?
O2 C19 C20 C25 172.4(8) . . . . ?
O3 C26 C27 C18 163.7(8) . . . . ?
O3 C26 C27 C28 -12.2(13) . . . . ?
O4 C28 C29 C30 -172.0(9) . . . . ?
O4 C31 C32 N3 45.8(10) . . . . ?
O5 C63 C64 C65 -3.4(11) . . . . ?
O5 C63 C64 C73 179.2(6) . . . . ?
O5 C63 C76 C75 -178.8(7) . . . . ?
O6 C65 C66 C67 -9.7(16) . . . . ?
O6 C65 C66 C71 166.3(11) . . . . ?
O7 C72 C73 C64 168.8(8) . . . . ?
O7 C72 C73 C74 -10.2(13) . . . . ?
O8 C74 C75 C76 179.8(8) . . . . ?
O8 C77 C78 N7 -61.0(14) . . . . ?
N1 C10 C11 C12 -179.1(6) . . . . ?
N2 C9 C10 N1 -0.9(6) . . . . ?
N2 C9 C10 C11 -179.7(6) . . . . ?
N2 C9 C14 C13 -179.7(6) . . . . ?
N2 C15 C16 O1 -52.8(8) . . . . ?
N3 C33 C34 N4 1.6(6) . . . . ?
N3 C33 C34 C35 -179.1(6) . . . . ?
N3 C33 C38 C37 179.5(7) . . . . ?
N4 C34 C35 C36 178.3(7) . . . . ?
N4 C40 C41 C42 -8.5(12) . . . . ?
N4 C40 C41 C46 173.7(8) . . . . ?
N6 C55 C56 C57 -179.2(9) . . . . ?
N6 C55 C60 N5 2.8(10) . . . . ?
N6 C55 C60 C59 177.9(9) . . . . ?
N6 C61 C62 O5 -172.8(7) . . . . ?
N8 C80 C81 C82 179.9(10) . . . . ?
N8 C80 C85 N7 -0.5(10) . . . . ?
N8 C80 C85 C84 179.8(9) . . . . ?
N8 C86 C87 C88 56.4(12) . . . . ?
N8 C86 C87 C92 -127.9(9) . . . . ?
C1 C2 C3 C4 -0.6(13) . . . . ?
C2 C1 C6 C5 -2.0(11) . . . . ?
C2 C1 C7 N1 93.2(8) . . . . ?
C2 C3 C4 C5 -1.5(14) . . . . ?
C3 C4 C5 C6 1.8(14) . . . . ?
C4 C5 C6 C1 -0.1(12) . . . . ?
C6 C1 C2 C3 2.4(11) . . . . ?
C6 C1 C7 N1 -86.5(8) . . . . ?
C7 N1 C8 Ag1 3.3(9) . . . . ?
C7 N1 C8 N2 -177.1(6) . . . . ?
C7 N1 C10 C9 177.6(6) . . . . ?
C7 N1 C10 C11 -3.8(11) . . . . ?
C7 C1 C2 C3 -177.3(7) . . . . ?
C7 C1 C6 C5 177.7(7) . . . . ?
C8 N1 C7 C1 93.6(8) . . . . ?
C8 N1 C10 C9 0.8(7) . . . . ?
C8 N1 C10 C11 179.3(7) . . . . ?
C8 N2 C9 C10 0.8(6) . . . . ?
C8 N2 C9 C14 179.7(6) . . . . ?
C8 N2 C15 C16 111.5(7) . . . . ?
C9 N2 C8 Ag1 179.2(4) . . . . ?
C9 N2 C8 N1 -0.3(6) . . . . ?
C9 N2 C15 C16 -63.7(8) . . . . ?
C9 C10 C11 C12 -0.7(10) . . . . ?
C10 N1 C7 C1 -82.8(8) . . . . ?
C10 N1 C8 Ag1 -179.8(4) . . . . ?
C10 N1 C8 N2 -0.3(7) . . . . ?
C10 C9 C14 C13 -1.0(9) . . . . ?
C10 C11 C12 C13 -0.1(10) . . . . ?
C11 C12 C13 C14 0.4(11) . . . . ?
C12 C13 C14 C9 0.1(10) . . . . ?
C14 C9 C10 N1 -179.9(6) . . . . ?
C14 C9 C10 C11 1.3(9) . . . . ?
C15 N2 C8 Ag1 3.4(8) . . . . ?
C15 N2 C8 N1 -176.2(5) . . . . ?
C15 N2 C9 C10 176.6(5) . . . . ?
C15 N2 C9 C14 -4.5(10) . . . . ?
C16 O1 C17 C18 -168.4(6) . . . . ?
C16 O1 C17 C30 11.1(10) . . . . ?
C17 O1 C16 C15 175.8(6) . . . . ?
C17 C18 C19 O2 5.8(12) . . . . ?
C17 C18 C19 C20 -177.1(6) . . . . ?
C17 C18 C27 C26 -174.0(7) . . . . ?
C17 C18 C27 C28 1.9(12) . . . . ?
C18 C17 C30 C29 -4.8(11) . . . . ?
C18 C19 C20 C21 175.6(7) . . . . ?
C18 C19 C20 C25 -4.9(10) . . . . ?
C18 C27 C28 O4 170.3(8) . . . . ?
C18 C27 C28 C29 -4.0(13) . . . . ?
C19 C18 C27 C26 5.0(11) . . . . ?
C19 C18 C27 C28 -179.1(8) . . . . ?
C19 C20 C21 C22 179.8(7) . . . . ?
C19 C20 C25 C24 179.9(6) . . . . ?
C19 C20 C25 C26 -3.4(10) . . . . ?
C20 C21 C22 C23 1.4(12) . . . . ?
C20 C25 C26 O3 -164.6(7) . . . . ?
C20 C25 C26 C27 12.4(11) . . . . ?
C21 C20 C25 C24 -0.6(10) . . . . ?
C21 C20 C25 C26 176.1(7) . . . . ?
C21 C22 C23 C24 -2.9(13) . . . . ?
C22 C23 C24 C25 2.6(12) . . . . ?
C23 C24 C25 C20 -0.9(11) . . . . ?
C23 C24 C25 C26 -177.6(7) . . . . ?
C24 C25 C26 O3 12.0(11) . . . . ?
C24 C25 C26 C27 -171.0(7) . . . . ?
C25 C20 C21 C22 0.3(11) . . . . ?
C25 C26 C27 C18 -13.2(11) . . . . ?
C25 C26 C27 C28 170.9(8) . . . . ?
C26 C27 C28 O4 -13.9(12) . . . . ?
C26 C27 C28 C29 171.8(8) . . . . ?
C27 C18 C19 O2 -173.2(8) . . . . ?
C27 C18 C19 C20 3.9(11) . . . . ?
C27 C28 C29 C30 1.9(14) . . . . ?
C28 O4 C31 C32 -177.9(8) . . . . ?
C28 C29 C30 C17 2.6(13) . . . . ?
C30 C17 C18 C19 -176.4(7) . . . . ?
C30 C17 C18 C27 2.6(11) . . . . ?
C31 O4 C28 C27 172.7(8) . . . . ?
C31 O4 C28 C29 -13.2(14) . . . . ?
C32 N3 C33 C34 -174.7(5) . . . . ?
C32 N3 C33 C38 6.3(11) . . . . ?
C32 N3 C39 Ag1 -0.5(8) . . . 2_566 ?
C32 N3 C39 N4 174.4(5) . . . . ?
C33 N3 C32 C31 72.1(8) . . . . ?
C33 N3 C39 Ag1 -173.0(4) . . . 2_566 ?
C33 N3 C39 N4 1.8(7) . . . . ?
C33 C34 C35 C36 -0.7(10) . . . . ?
C34 N4 C39 Ag1 174.1(4) . . . 2_566 ?
C34 N4 C39 N3 -0.7(6) . . . . ?
C34 N4 C40 C41 98.8(8) . . . . ?
C34 C33 C38 C37 0.6(10) . . . . ?
C34 C35 C36 C37 0.7(12) . . . . ?
C35 C36 C37 C38 0.0(13) . . . . ?
C36 C37 C38 C33 -0.6(12) . . . . ?
C38 C33 C34 N4 -179.2(6) . . . . ?
C38 C33 C34 C35 0.0(9) . . . . ?
C39 N3 C32 C31 -99.5(8) . . . . ?
C39 N3 C33 C34 -2.2(7) . . . . ?
C39 N3 C33 C38 178.8(7) . . . . ?
C39 N4 C34 C33 -0.6(6) . . . . ?
C39 N4 C34 C35 -179.7(7) . . . . ?
C39 N4 C40 C41 -86.0(8) . . . . ?
C40 N4 C34 C33 175.2(6) . . . . ?
C40 N4 C34 C35 -3.9(10) . . . . ?
C40 N4 C39 Ag1 -1.6(9) . . . 2_566 ?
C40 N4 C39 N3 -176.4(6) . . . . ?
C40 C41 C42 C43 179.4(10) . . . . ?
C40 C41 C46 C45 180.0(10) . . . . ?
C41 C42 C43 C44 2.1(17) . . . . ?
C42 C41 C46 C45 2.1(15) . . . . ?
C42 C43 C44 C45 -0.5(19) . . . . ?
C43 C44 C45 C46 0(2) . . . . ?
C44 C45 C46 C41 -1(2) . . . . ?
C46 C41 C42 C43 -2.9(15) . . . . ?
C47 C48 C49 C50 0.0 . . . . ?
C48 C47 C52 C51 0.0 . . . . ?
C48 C47 C53 N5 -37.4(12) . . . . ?
C48 C49 C50 C51 0.0 . . . . ?
C49 C50 C51 C52 0.0 . . . . ?
C50 C51 C52 C47 0.0 . . . . ?
C52 C47 C48 C49 0.0 . . . . ?
C52 C47 C53 N5 144.8(8) . . . . ?
C53 N5 C54 Ag2 3.0(13) . . . . ?
C53 N5 C54 N6 -175.8(8) . . . . ?
C53 N5 C60 C55 175.0(8) . . . . ?
C53 N5 C60 C59 0.7(18) . . . . ?
C53 C47 C48 C49 -177.8(7) . . . . ?
C53 C47 C52 C51 177.7(7) . . . . ?
C54 N5 C53 C47 -70.7(13) . . . . ?
C54 N5 C60 C55 -3.7(11) . . . . ?
C54 N5 C60 C59 -178.0(10) . . . . ?
C54 N6 C55 C56 177.8(10) . . . . ?
C54 N6 C55 C60 -0.9(9) . . . . ?
C54 N6 C61 C62 104.8(9) . . . . ?
C55 N6 C54 Ag2 -179.9(6) . . . . ?
C55 N6 C54 N5 -1.1(10) . . . . ?
C55 N6 C61 C62 -71.9(10) . . . . ?
C55 C56 C57 C58 1.1(14) . . . . ?
C56 C55 C60 N5 -176.0(10) . . . . ?
C56 C55 C60 C59 -0.9(15) . . . . ?
C56 C57 C58 C59 0.1(18) . . . . ?
C57 C58 C59 C60 -1.7(19) . . . . ?
C58 C59 C60 N5 175.9(11) . . . . ?
C58 C59 C60 C55 1.9(15) . . . . ?
C60 N5 C53 C47 110.7(12) . . . . ?
C60 N5 C54 Ag2 -178.2(7) . . . . ?
C60 N5 C54 N6 3.0(11) . . . . ?
C60 C55 C56 C57 -0.7(14) . . . . ?
C61 N6 C54 Ag2 3.0(11) . . . . ?
C61 N6 C54 N5 -178.2(7) . . . . ?
C61 N6 C55 C56 -5.2(15) . . . . ?
C61 N6 C55 C60 176.1(7) . . . . ?
C62 O5 C63 C64 173.9(6) . . . . ?
C62 O5 C63 C76 -5.6(10) . . . . ?
C63 O5 C62 C61 -174.9(6) . . . . ?
C63 C64 C65 O6 11.8(13) . . . . ?
C63 C64 C65 C66 -161.3(8) . . . . ?
C63 C64 C73 C72 179.0(7) . . . . ?
C63 C64 C73 C74 -2.0(11) . . . . ?
C64 C63 C76 C75 1.7(12) . . . . ?
C64 C65 C66 C67 163.4(10) . . . . ?
C64 C65 C66 C71 -20.7(16) . . . . ?
C64 C73 C74 O8 -179.3(7) . . . . ?
C64 C73 C74 C75 5.1(13) . . . . ?
C65 C64 C73 C72 1.5(11) . . . . ?
C65 C64 C73 C74 -179.5(8) . . . . ?
C65 C66 C67 C68 176.1(12) . . . . ?
C65 C66 C71 C70 -177.0(12) . . . . ?
C65 C66 C71 C72 6(2) . . . . ?
C66 C67 C68 C69 -1(2) . . . . ?
C66 C71 C72 O7 -172.4(11) . . . . ?
C66 C71 C72 C73 13.3(17) . . . . ?
C67 C66 C71 C70 -1(2) . . . . ?
C67 C66 C71 C72 -178.4(12) . . . . ?
C67 C68 C69 C70 2(2) . . . . ?
C68 C69 C70 C71 -4(2) . . . . ?
C69 C70 C71 C66 3(2) . . . . ?
C69 C70 C71 C72 -179.7(13) . . . . ?
C70 C71 C72 O7 10.2(18) . . . . ?
C70 C71 C72 C73 -164.1(11) . . . . ?
C71 C66 C67 C68 0(2) . . . . ?
C71 C72 C73 C64 -17.0(13) . . . . ?
C71 C72 C73 C74 164.0(10) . . . . ?
C72 C73 C74 O8 -0.3(13) . . . . ?
C72 C73 C74 C75 -176.0(8) . . . . ?
C73 C64 C65 O6 -170.9(8) . . . . ?
C73 C64 C65 C66 16.0(12) . . . . ?
C73 C74 C75 C76 -4.7(13) . . . . ?
C74 O8 C77 C78 -178.9(9) . . . . ?
C74 C75 C76 C63 1.3(13) . . . . ?
C76 C63 C64 C65 176.0(8) . . . . ?
C76 C63 C64 C73 -1.4(11) . . . . ?
C77 O8 C74 C73 -178.2(9) . . . . ?
C77 O8 C74 C75 -2.7(13) . . . . ?
C78 N7 C79 Ag2 -4.3(11) . . . 2_567 ?
C78 N7 C79 N8 179.3(8) . . . . ?
C78 N7 C85 C80 -178.4(8) . . . . ?
C78 N7 C85 C84 1.3(17) . . . . ?
C79 N7 C78 C77 109.6(11) . . . . ?
C79 N7 C85 C80 -0.6(10) . . . . ?
C79 N7 C85 C84 179.0(10) . . . . ?
C79 N8 C80 C81 -179.1(10) . . . . ?
C79 N8 C80 C85 1.5(10) . . . . ?
C79 N8 C86 C87 -110.4(9) . . . . ?
C80 N8 C79 Ag2 -177.8(6) . . . 2_567 ?
C80 N8 C79 N7 -1.8(9) . . . . ?
C80 N8 C86 C87 74.7(11) . . . . ?
C80 C81 C82 C83 0.8(17) . . . . ?
C81 C80 C85 N7 180.0(9) . . . . ?
C81 C80 C85 C84 0.3(15) . . . . ?
C81 C82 C83 C84 0(2) . . . . ?
C82 C83 C84 C85 0(2) . . . . ?
C83 C84 C85 N7 -179.6(12) . . . . ?
C83 C84 C85 C80 0.0(17) . . . . ?
C85 N7 C78 C77 -72.9(14) . . . . ?
C85 N7 C79 Ag2 178.0(6) . . . 2_567 ?
C85 N7 C79 N8 1.5(10) . . . . ?
C85 C80 C81 C82 -0.7(16) . . . . ?
C86 N8 C79 Ag2 6.5(12) . . . 2_567 ?
C86 N8 C79 N7 -177.5(7) . . . . ?
C86 N8 C80 C81 -3.6(15) . . . . ?
C86 N8 C80 C85 176.9(7) . . . . ?
C86 C87 C88 C89 176.0(8) . . . . ?
C86 C87 C92 C91 -174.6(8) . . . . ?
C87 C88 C89 C90 -1.7(14) . . . . ?
C88 C87 C92 C91 1.2(13) . . . . ?
C88 C89 C90 C91 1.8(15) . . . . ?
C89 C90 C91 C92 -0.3(15) . . . . ?
C90 C91 C92 C87 -1.2(14) . . . . ?
C92 C87 C88 C89 0.3(13) . . . . ?

_shelx_SHELXL_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'
_platon_squeeze_details          
;
 ?
;
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
1 0.500 0.500 1.000 796.7 190.8

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_n130823a
_database_code_depnum_ccdc_archive 'CCDC 1408696'
_audit_update_record             
;
2017-03-29 deposited with the CCDC.
2017-04-19 downloaded from the CCDC.
;
_audit_creation_date             2016-10-25
_audit_creation_method           
;
Olex2 1.2-beta
(compiled 2016.09.09 svn.r3337 for OlexSys, GUI svn.r5227)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         '0.5(C152 H128 Ag4 N16 O16), 2(F6 P)'
_chemical_formula_sum            'C76 H64 Ag2 F12 N8 O8 P2'
_chemical_formula_weight         1723.03
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   11.1719(4)
_cell_length_b                   11.2926(4)
_cell_length_c                   28.5875(10)
_cell_angle_alpha                90
_cell_angle_beta                 98.4540(10)
_cell_angle_gamma                90
_cell_volume                     3567.4(2)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    7179
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      26.37
_cell_measurement_theta_min      2.31
_shelx_estimated_absorpt_T_max   0.904
_shelx_estimated_absorpt_T_min   0.886
_exptl_absorpt_coefficient_mu    0.689
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.6769
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2012/1 (Bruker,2012) was used for absorption correction.
wR2(int) was 0.0819 before and 0.0335 after correction.
The Ratio of minimum to maximum transmission is 0.9077.
The λ/2 correction factor is 0.0015.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.604
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1744
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.15
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0304
_diffrn_reflns_av_unetI/netI     0.0300
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_number            20079
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        25.009
_diffrn_reflns_theta_max         25.009
_diffrn_reflns_theta_min         1.440
_diffrn_ambient_temperature      296.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                5413
_reflns_number_total             6287
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_refine_diff_density_max         1.473
_refine_diff_density_min         -1.544
_refine_diff_density_rms         0.106
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.031
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     620
_refine_ls_number_reflns         6287
_refine_ls_number_restraints     467
_refine_ls_R_factor_all          0.0693
_refine_ls_R_factor_gt           0.0600
_refine_ls_restrained_S_all      1.083
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0580P)²+20.6740P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1420
_refine_ls_wR_factor_ref         0.1498
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups, All C(H,H,H,H) groups
2. Restrained distances
 C24'-C25 = C18-C19 = C18-C19'
 1.5 with sigma of 0.01
 C1-C7 = C1'-C7 = C32-C33 = C32-C33' = C24-C25
 1.5 with sigma of 0.01
 F3'-F4' = F3'-F5' = F3'-F6' = F4'-F5' = F4'-F6'
 2.23 with sigma of 0.001
 P1'-F1' = P1'-F2' = P1'-F3' = P1'-F4' = P1'-F5' = P1'-F6'
 1.57 with sigma of 0.01
 F3-F4 = F3-F5 = F3-F6 = F4-F5 = F4-F6
 2.23 with sigma of 0.001
 F1-F2 = F1-F4 = F1-F5 = F1-F6 = F2-F3 = F2-F5 = F2-F6
 2.23 with sigma of 0.001
 P1-F1 = P1-F2 = P1-F3 = P1-F4 = P1-F5 = P1-F6
 1.57 with sigma of 0.01
 F1'-F2' \\sim F1'-F4' \\sim F1'-F5' \\sim F1'-F6' \\sim F2'-F3' \\sim F2'-F5'
\\sim F2'-F6'
 with sigma of 0.001
3. Rigid bond restraints
 All non-hydrogen atoms
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
4. Uiso/Uaniso restraints and constraints
C1 \\sim C2 \\sim C3 \\sim C4 \\sim C5 \\sim C6: within 2A with sigma of 0.001
and sigma for terminal atoms of 0.002
C1' \\sim C2' \\sim C3' \\sim C4' \\sim C5' \\sim C6': within 2A with sigma of
0.001 and sigma for terminal atoms of 0.002
C33' \\sim C34' \\sim C35' \\sim C36' \\sim C37' \\sim C38': within 2A with
sigma of 0.001 and sigma for terminal atoms of 0.002
Uanis(C1') \\sim Ueq, Uanis(C1) \\sim Ueq: with sigma of 0.005 and sigma for
terminal atoms of 0.002
Uanis(O3) \\sim Ueq, Uanis(C21) \\sim Ueq, Uanis(C22) \\sim Ueq, Uanis(C23)
\\sim Ueq, Uanis(C20') \\sim Ueq, Uanis(C21') \\sim Ueq, Uanis(C22') \\sim Ueq,
Uanis(C23') \\sim Ueq, Uanis(C20) \\sim Ueq: with sigma of 0.005 and sigma for
terminal atoms of 0.002
Uanis(C36') \\sim Ueq, Uanis(C36) \\sim Ueq: with sigma of 0.005 and sigma for
terminal atoms of 0.002
Uanis(C38) = Uanis(C38')
Uanis(C37) = Uanis(C37')
Uanis(C36) = Uanis(C36')
Uanis(C35) = Uanis(C35')
Uanis(C34) = Uanis(C34')
Uanis(C33) = Uanis(C33')
Uanis(C20) = Uanis(C20')
Uanis(C21) = Uanis(C21')
Uanis(C22) = Uanis(C22')
Uanis(C23) = Uanis(C23')
5. Others
 Sof(P1')=Sof(F1')=Sof(F2')=Sof(F3')=Sof(F4')=Sof(F5')=Sof(F6')=1-FVAR(1)
 Sof(P1)=Sof(F1)=Sof(F2)=Sof(F3)=Sof(F4)=Sof(F5)=Sof(F6)=FVAR(1)
 Sof(C1')=Sof(C2')=Sof(H2')=Sof(C3')=Sof(H3')=Sof(C4')=Sof(H4')=Sof(C5')=
 Sof(H5')=Sof(C6')=Sof(H6')=Sof(H7BC)=Sof(H7BD)=1-FVAR(2)
 Sof(C1)=Sof(C2)=Sof(H2)=Sof(C3)=Sof(H3)=Sof(C4)=Sof(H4)=Sof(C5)=Sof(H5)=
 Sof(C6)=Sof(H6)=Sof(H7AA)=Sof(H7AB)=FVAR(2)
 Sof(C19')=Sof(C20')=Sof(H20')=Sof(C21')=Sof(H21')=Sof(C22')=Sof(H22')=
 Sof(C23')=Sof(H23')=Sof(C24')=1-FVAR(3)
 Sof(C19)=Sof(C20)=Sof(H20)=Sof(C21)=Sof(H21)=Sof(C22)=Sof(H22)=Sof(C23)=
 Sof(H23)=Sof(C24)=FVAR(3)
 Sof(H32C)=Sof(H32D)=Sof(C33')=Sof(C34')=Sof(H34')=Sof(C35')=Sof(H35')=
 Sof(C36')=Sof(H36')=Sof(C37')=Sof(H37')=Sof(C38')=Sof(H38')=1-FVAR(4)
 Sof(H32A)=Sof(H32B)=Sof(C33)=Sof(C34)=Sof(H34)=Sof(C35)=Sof(H35)=Sof(C36)=
 Sof(H36)=Sof(C37)=Sof(H37)=Sof(C38)=Sof(H38)=FVAR(4)
6.a Secondary CH2 refined with riding coordinates:
 C7(H7AA,H7AB), C7(H7BC,H7BD), C11(H11A,H11B), C12(H12A,H12B), C27(H27A,H27B),
 C28(H28A,H28B), C32(H32A,H32B), C32(H32C,H32D)
6.b Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3), C4(H4), C5(H5), C6(H6), C2'(H2'), C3'(H3'), C4'(H4'),
 C5'(H5'), C6'(H6'), C9(H9), C10(H10), C14(H14), C15(H15), C20(H20), C21(H21),
 C22(H22), C23(H23), C20'(H20'), C21'(H21'), C22'(H22'), C23'(H23'), C30(H30),
 C31(H31), C34(H34), C35(H35), C36(H36), C37(H37), C38(H38), C34'(H34'),
 C35'(H35'), C36'(H36'), C37'(H37'), C38'(H38')
6.c Fitted hexagon refined as free rotating group:
 C1(C2,C3,C4,C5,C6), C19(C20,C21,C22,C23,C24), C33(C34,C35,C36,C37,C38)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.91502(3) 0.19498(4) 1.09338(2) 0.03361(15) Uani 1 1 d . U . . .
P1 P 0.1196(5) 0.8453(4) 0.17987(19) 0.0246(11) Uani 0.531(14) 1 d D U P A 1
F1 F -0.0102(5) 0.8852(6) 0.1885(2) 0.0453(18) Uani 0.531(14) 1 d D U P A 1
F2 F 0.1168(7) 0.9413(5) 0.1394(2) 0.050(2) Uani 0.531(14) 1 d D U P A 1
F3 F 0.2496(6) 0.8051(8) 0.1705(2) 0.069(2) Uani 0.531(14) 1 d D U P A 1
F4 F 0.1227(8) 0.7490(5) 0.21968(17) 0.046(2) Uani 0.531(14) 1 d D U P A 1
F5 F 0.0607(8) 0.7522(5) 0.14188(18) 0.049(2) Uani 0.531(14) 1 d D U P A 1
F6 F 0.1787(6) 0.9381(5) 0.2172(3) 0.046(2) Uani 0.531(14) 1 d D U P A 1
P1' P 0.1547(7) 0.8257(7) 0.1777(2) 0.0386(16) Uani 0.469(14) 1 d D U P A 2
F1' F 0.0178(7) 0.8263(12) 0.1872(2) 0.080(4) Uani 0.469(14) 1 d D U P A 2
F2' F 0.1221(8) 0.9227(8) 0.1374(3) 0.055(3) Uani 0.469(14) 1 d D U P A 2
F3' F 0.2904(7) 0.8244(8) 0.1681(3) 0.064(3) Uani 0.469(14) 1 d D U P A 2
F4' F 0.1870(10) 0.7288(7) 0.2175(2) 0.060(3) Uani 0.469(14) 1 d D U P A 2
F5' F 0.1237(11) 0.7237(8) 0.1398(2) 0.066(3) Uani 0.469(14) 1 d D U P A 2
F6' F 0.1870(8) 0.9262(7) 0.2157(3) 0.068(4) Uani 0.469(14) 1 d D U P A 2
N1 N 0.8406(4) -0.0414(4) 1.04201(17) 0.0360(7) Uani 1 1 d . U . . .
N2 N 0.8676(3) 0.0919(4) 0.99179(14) 0.0281(6) Uani 1 1 d . U . . .
N3 N 0.0026(4) 0.5667(4) 0.85982(17) 0.0361(8) Uani 1 1 d . U . . .
N4 N -0.0352(4) 0.7041(4) 0.80894(16) 0.0355(8) Uani 1 1 d . U . . .
O1 O 0.7010(3) 0.2841(3) 0.98765(11) 0.0286(7) Uani 1 1 d . U . . .
O2 O 0.6782(3) 0.3015(4) 1.07595(13) 0.0393(9) Uani 1 1 d . U . . .
O3 O 0.2122(4) 0.4078(5) 1.03590(17) 0.0653(10) Uani 1 1 d . U . . .
O4 O 0.2174(3) 0.4098(4) 0.94638(13) 0.0400(9) Uani 1 1 d . U . . .
C1 C 0.6931(6) -0.0829(8) 1.0961(3) 0.0579(12) Uani 0.631(7) 1 d D U P B 1
C2 C 0.6717(5) -0.1217(7) 1.1403(3) 0.0584(12) Uani 0.631(7) 1 d G U P B 1
H2 H 0.7338 -0.1562 1.1611 0.070 Uiso 0.631(7) 1 calc R . P B 1
C3 C 0.5574(6) -0.1091(7) 1.1534(2) 0.0588(13) Uani 0.631(7) 1 d G U P B 1
H3 H 0.5431 -0.1351 1.1830 0.071 Uiso 0.631(7) 1 calc R . P B 1
C4 C 0.4645(5) -0.0576(7) 1.1224(3) 0.0586(13) Uani 0.631(7) 1 d G U P B 1
H4 H 0.3880 -0.0491 1.1312 0.070 Uiso 0.631(7) 1 calc R . P B 1
C5 C 0.4859(7) -0.0187(8) 1.0782(3) 0.0580(13) Uani 0.631(7) 1 d G U P B 1
H5 H 0.4237 0.0158 1.0575 0.070 Uiso 0.631(7) 1 calc R . P B 1
C6 C 0.6002(8) -0.0314(9) 1.0651(3) 0.0574(12) Uani 0.631(7) 1 d G U P B 1
H6 H 0.6145 -0.0054 1.0356 0.069 Uiso 0.631(7) 1 calc R . P B 1
C1' C 0.6970(12) -0.0538(17) 1.0987(7) 0.0518(16) Uani 0.369(7) 1 d D U P B 2
C2' C 0.6723(16) 0.0130(17) 1.1419(6) 0.0522(16) Uani 0.369(7) 1 d . U P B 2
H2' H 0.7384 0.0294 1.1647 0.063 Uiso 0.369(7) 1 calc R . P B 2
C3' C 0.5606(15) 0.0524(17) 1.1506(6) 0.0523(16) Uani 0.369(7) 1 d . U P B 2
H3' H 0.5528 0.0887 1.1792 0.063 Uiso 0.369(7) 1 calc R . P B 2
C4' C 0.4607(16) 0.0374(18) 1.1165(6) 0.0523(16) Uani 0.369(7) 1 d . U P B 2
H4' H 0.3827 0.0494 1.1232 0.063 Uiso 0.369(7) 1 calc R . P B 2
C5' C 0.4813(19) 0.005(2) 1.0730(7) 0.0522(16) Uani 0.369(7) 1 d . U P B 2
H5' H 0.4211 0.0144 1.0472 0.063 Uiso 0.369(7) 1 calc R . P B 2
C6' C 0.5954(19) -0.045(2) 1.0666(7) 0.0522(16) Uani 0.369(7) 1 d . U P B 2
H6' H 0.6005 -0.0758 1.0367 0.063 Uiso 0.369(7) 1 calc R . P B 2
C7 C 0.8179(5) -0.0967(6) 1.0858(2) 0.0535(11) Uani 1 1 d D U . . .
H7AA H 0.8731 -0.0631 1.1118 0.064 Uiso 0.631(7) 1 calc R . P B 1
H7AB H 0.8358 -0.1805 1.0843 0.064 Uiso 0.631(7) 1 calc R . P B 1
H7BC H 0.8827 -0.0770 1.1110 0.064 Uiso 0.369(7) 1 calc R . P B 2
H7BD H 0.8160 -0.1821 1.0821 0.064 Uiso 0.369(7) 1 calc R . P B 2
C8 C 0.8689(4) 0.0746(5) 1.03873(18) 0.0289(7) Uani 1 1 d . U . . .
C9 C 0.8213(5) -0.0947(5) 0.9981(2) 0.0401(9) Uani 1 1 d . U . . .
H9 H 0.8003 -0.1733 0.9916 0.048 Uiso 1 1 calc R . . . .
C10 C 0.8388(4) -0.0113(5) 0.9668(2) 0.0350(8) Uani 1 1 d . U . . .
H10 H 0.8327 -0.0209 0.9342 0.042 Uiso 1 1 calc R . . . .
C11 C 0.8864(4) 0.2070(5) 0.97092(18) 0.0299(8) Uani 1 1 d . U . . .
H11A H 0.9376 0.1975 0.9466 0.036 Uiso 1 1 calc R . . . .
H11B H 0.9277 0.2590 0.9951 0.036 Uiso 1 1 calc R . . . .
C12 C 0.7677(4) 0.2631(5) 0.94952(16) 0.0275(9) Uani 1 1 d . U . . .
H12A H 0.7823 0.3370 0.9340 0.033 Uiso 1 1 calc R . . . .
H12B H 0.7231 0.2104 0.9264 0.033 Uiso 1 1 calc R . . . .
C13 C 0.5838(4) 0.3200(4) 0.97675(17) 0.0250(8) Uani 1 1 d . U . . .
C14 C 0.5306(4) 0.3432(5) 0.93039(18) 0.0315(10) Uani 1 1 d . U . . .
H14 H 0.5770 0.3378 0.9060 0.038 Uiso 1 1 calc R . . . .
C15 C 0.4102(4) 0.3742(5) 0.92033(18) 0.0335(10) Uani 1 1 d . U . . .
H15 H 0.3764 0.3891 0.8892 0.040 Uiso 1 1 calc R . . . .
C16 C 0.3386(4) 0.3834(4) 0.95580(18) 0.0305(9) Uani 1 1 d . U . . .
C17 C 0.3896(4) 0.3638(4) 1.00312(17) 0.0272(8) Uani 1 1 d . U . . .
C18 C 0.3150(4) 0.3762(4) 1.04206(17) 0.0333(9) Uani 1 1 d D U . . .
C19 C 0.3695(5) 0.3253(6) 1.08903(14) 0.0300(16) Uani 0.605(5) 1 d D U P C 1
C20 C 0.2945(4) 0.3129(6) 1.12343(19) 0.0465(12) Uani 0.605(5) 1 d G U P C 1
H20 H 0.2135 0.3350 1.1169 0.056 Uiso 0.605(5) 1 calc R . P C 1
C21 C 0.3403(5) 0.2675(7) 1.16763(18) 0.0546(14) Uani 0.605(5) 1 d G U P C 1
H21 H 0.2901 0.2592 1.1907 0.065 Uiso 0.605(5) 1 calc R . P C 1
C22 C 0.4613(5) 0.2344(7) 1.17743(15) 0.0539(14) Uani 0.605(5) 1 d G U P C 1
H22 H 0.4920 0.2040 1.2070 0.065 Uiso 0.605(5) 1 calc R . P C 1
C23 C 0.5363(4) 0.2468(6) 1.14303(18) 0.0462(12) Uani 0.605(5) 1 d G U P C 1
H23 H 0.6172 0.2246 1.1496 0.055 Uiso 0.605(5) 1 calc R . P C 1
C24 C 0.4904(4) 0.2922(6) 1.09883(16) 0.0277(14) Uani 0.605(5) 1 d DG U P C 1
C19' C 0.3708(12) 0.3883(15) 1.0921(3) 0.039(3) Uani 0.395(5) 1 d D U P C 2
C20' C 0.3030(14) 0.4310(15) 1.1249(5) 0.0465(12) Uani 0.395(5) 1 d . U P C 2
H20' H 0.2205 0.4443 1.1168 0.056 Uiso 0.395(5) 1 calc R . P C 2
C21' C 0.3613(15) 0.4537(17) 1.1706(6) 0.0546(14) Uani 0.395(5) 1 d . U P C 2
H21' H 0.3186 0.4854 1.1933 0.065 Uiso 0.395(5) 1 calc R . P C 2
C22' C 0.4857(15) 0.4279(17) 1.1821(5) 0.0539(14) Uani 0.395(5) 1 d . U P C 2
H22' H 0.5266 0.4434 1.2122 0.065 Uiso 0.395(5) 1 calc R . P C 2
C23' C 0.5454(14) 0.3797(15) 1.1480(5) 0.0462(12) Uani 0.395(5) 1 d . U P C 2
H23' H 0.6261 0.3588 1.1568 0.055 Uiso 0.395(5) 1 calc R . P C 2
C24' C 0.4933(11) 0.3589(13) 1.1001(4) 0.035(3) Uani 0.395(5) 1 d D U P C 2
C25 C 0.5707(4) 0.3145(5) 1.06382(16) 0.0293(9) Uani 1 1 d D U . . .
C26 C 0.5137(4) 0.3312(4) 1.01364(16) 0.0235(7) Uani 1 1 d . U . . .
C27 C 0.1725(4) 0.4538(5) 0.90046(19) 0.0348(11) Uani 1 1 d . U . . .
H27A H 0.1669 0.3904 0.8773 0.042 Uiso 1 1 calc R . . . .
H27B H 0.2256 0.5148 0.8913 0.042 Uiso 1 1 calc R . . . .
C28 C 0.0485(5) 0.5043(5) 0.9036(2) 0.0421(12) Uani 1 1 d . U . . .
H28A H -0.0066 0.4408 0.9088 0.050 Uiso 1 1 calc R . . . .
H28B H 0.0534 0.5585 0.9301 0.050 Uiso 1 1 calc R . . . .
C29 C 0.0143(4) 0.6843(5) 0.85447(18) 0.0309(8) Uani 1 1 d . U . . .
C30 C -0.0516(5) 0.5136(5) 0.8185(2) 0.0487(13) Uani 1 1 d . U . . .
H30 H -0.0687 0.4335 0.8139 0.058 Uiso 1 1 calc R . . . .
C31 C -0.0746(4) 0.6004(5) 0.7867(2) 0.0394(10) Uani 1 1 d . U . . .
H31 H -0.1105 0.5922 0.7554 0.047 Uiso 1 1 calc R . . . .
C32 C -0.0339(5) 0.8181(5) 0.7848(2) 0.0494(10) Uani 1 1 d D U . . .
H32A H -0.0391 0.8822 0.8070 0.059 Uiso 0.447(5) 1 calc R . P D 1
H32B H -0.1025 0.8237 0.7598 0.059 Uiso 0.447(5) 1 calc R . P D 1
H32C H -0.0427 0.8804 0.8074 0.059 Uiso 0.553(5) 1 calc R . P D 2
H32D H -0.1038 0.8218 0.7604 0.059 Uiso 0.553(5) 1 calc R . P D 2
C33 C 0.0848(8) 0.8271(11) 0.7639(4) 0.0597(10) Uani 0.447(5) 1 d D U P D 1
C34 C 0.1780(10) 0.9013(9) 0.7837(3) 0.0599(10) Uani 0.447(5) 1 d G U P D 1
H34 H 0.1691 0.9469 0.8100 0.072 Uiso 0.447(5) 1 calc R . P D 1
C35 C 0.2845(8) 0.9072(9) 0.7640(3) 0.0604(10) Uani 0.447(5) 1 d G U P D 1
H35 H 0.3469 0.9568 0.7772 0.072 Uiso 0.447(5) 1 calc R . P D 1
C36 C 0.2978(7) 0.8389(10) 0.7246(3) 0.0606(10) Uani 0.447(5) 1 d G U P D 1
H36 H 0.3690 0.8429 0.7115 0.073 Uiso 0.447(5) 1 calc R . P D 1
C37 C 0.2045(9) 0.7647(9) 0.7049(3) 0.0605(10) Uani 0.447(5) 1 d G U P D 1
H37 H 0.2134 0.7191 0.6786 0.073 Uiso 0.447(5) 1 calc R . P D 1
C38 C 0.0980(8) 0.7588(10) 0.7246(4) 0.0598(10) Uani 0.447(5) 1 d G U P D 1
H38 H 0.0356 0.7092 0.7114 0.072 Uiso 0.447(5) 1 calc R . P D 1
C33' C 0.0777(11) 0.8432(14) 0.7626(5) 0.0597(10) Uani 0.553(5) 1 d D U P D 2
C34' C 0.0804(13) 0.9486(12) 0.7355(4) 0.0599(10) Uani 0.553(5) 1 d . U P D 2
H34' H 0.0134 0.9982 0.7301 0.072 Uiso 0.553(5) 1 calc R . P D 2
C35' C 0.1893(12) 0.9759(12) 0.7169(4) 0.0604(10) Uani 0.553(5) 1 d . U P D 2
H35' H 0.1934 1.0471 0.7009 0.072 Uiso 0.553(5) 1 calc R . P D 2
C36' C 0.2797(13) 0.9084(13) 0.7213(4) 0.0606(10) Uani 0.553(5) 1 d . U P D 2
H36' H 0.3491 0.9325 0.7095 0.073 Uiso 0.553(5) 1 calc R . P D 2
C37' C 0.2782(13) 0.7923(12) 0.7443(4) 0.0605(10) Uani 0.553(5) 1 d . U P D 2
H37' H 0.3424 0.7394 0.7455 0.073 Uiso 0.553(5) 1 calc R . P D 2
C38' C 0.1753(12) 0.7663(12) 0.7643(4) 0.0598(10) Uani 0.553(5) 1 d . U P D 2
H38' H 0.1715 0.6940 0.7796 0.072 Uiso 0.553(5) 1 calc R . P D 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C8 2.078(5) . ?
Ag1 C29 2.088(6) 3_667 ?
P1 F1 1.573(4) . ?
P1 F2 1.583(4) . ?
P1 F3 1.581(4) . ?
P1 F4 1.572(4) . ?
P1 F5 1.584(5) . ?
P1 F6 1.570(5) . ?
P1' F1' 1.593(6) . ?
P1' F2' 1.592(6) . ?
P1' F3' 1.580(5) . ?
P1' F4' 1.582(6) . ?
P1' F5' 1.584(5) . ?
P1' F6' 1.577(5) . ?
N1 C7 1.454(7) . ?
N1 C8 1.353(7) . ?
N1 C9 1.381(8) . ?
N2 C8 1.354(6) . ?
N2 C10 1.380(7) . ?
N2 C11 1.458(6) . ?
N3 C28 1.462(7) . ?
N3 C29 1.345(7) . ?
N3 C30 1.382(8) . ?
N4 C29 1.356(7) . ?
N4 C31 1.374(7) . ?
N4 C32 1.461(7) . ?
O1 C12 1.428(6) . ?
O1 C13 1.362(6) . ?
O2 C25 1.209(6) . ?
O3 C18 1.191(6) . ?
O4 C16 1.374(6) . ?
O4 C27 1.424(6) . ?
C1 C2 1.3900 . ?
C1 C6 1.3900 . ?
C1 C7 1.476(7) . ?
C2 H2 0.9300 . ?
C2 C3 1.3900 . ?
C3 H3 0.9300 . ?
C3 C4 1.3900 . ?
C4 H4 0.9300 . ?
C4 C5 1.3900 . ?
C5 H5 0.9300 . ?
C5 C6 1.3900 . ?
C6 H6 0.9300 . ?
C1' C2' 1.51(2) . ?
C1' C6' 1.35(2) . ?
C1' C7 1.531(9) . ?
C2' H2' 0.9300 . ?
C2' C3' 1.38(2) . ?
C3' H3' 0.9300 . ?
C3' C4' 1.38(2) . ?
C4' H4' 0.9300 . ?
C4' C5' 1.35(3) . ?
C5' H5' 0.9300 . ?
C5' C6' 1.43(3) . ?
C6' H6' 0.9300 . ?
C7 H7AA 0.9700 . ?
C7 H7AB 0.9700 . ?
C7 H7BC 0.9700 . ?
C7 H7BD 0.9700 . ?
C9 H9 0.9300 . ?
C9 C10 1.333(8) . ?
C10 H10 0.9300 . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C11 C12 1.515(6) . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C13 C14 1.395(7) . ?
C13 C26 1.408(7) . ?
C14 H14 0.9300 . ?
C14 C15 1.379(7) . ?
C15 H15 0.9300 . ?
C15 C16 1.385(7) . ?
C16 C17 1.406(7) . ?
C17 C18 1.492(7) . ?
C17 C26 1.423(6) . ?
C18 C19 1.505(6) . ?
C18 C19' 1.479(9) . ?
C19 C20 1.3900 . ?
C19 C24 1.3900 . ?
C20 H20 0.9300 . ?
C20 C21 1.3900 . ?
C21 H21 0.9300 . ?
C21 C22 1.3900 . ?
C22 H22 0.9300 . ?
C22 C23 1.3900 . ?
C23 H23 0.9300 . ?
C23 C24 1.3900 . ?
C24 C25 1.460(5) . ?
C19' C20' 1.38(2) . ?
C19' C24' 1.395(19) . ?
C20' H20' 0.9300 . ?
C20' C21' 1.40(2) . ?
C21' H21' 0.9300 . ?
C21' C22' 1.41(2) . ?
C22' H22' 0.9300 . ?
C22' C23' 1.37(2) . ?
C23' H23' 0.9300 . ?
C23' C24' 1.43(2) . ?
C24' C25 1.530(9) . ?
C25 C26 1.493(6) . ?
C27 H27A 0.9700 . ?
C27 H27B 0.9700 . ?
C27 C28 1.513(7) . ?
C28 H28A 0.9700 . ?
C28 H28B 0.9700 . ?
C29 Ag1 2.088(5) 3_667 ?
C30 H30 0.9300 . ?
C30 C31 1.338(8) . ?
C31 H31 0.9300 . ?
C32 H32A 0.9700 . ?
C32 H32B 0.9700 . ?
C32 H32C 0.9700 . ?
C32 H32D 0.9700 . ?
C32 C33 1.535(7) . ?
C32 C33' 1.508(9) . ?
C33 C34 1.3900 . ?
C33 C38 1.3900 . ?
C34 H34 0.9300 . ?
C34 C35 1.3900 . ?
C35 H35 0.9300 . ?
C35 C36 1.3900 . ?
C36 H36 0.9300 . ?
C36 C37 1.3900 . ?
C37 H37 0.9300 . ?
C37 C38 1.3900 . ?
C38 H38 0.9300 . ?
C33' C34' 1.421(19) . ?
C33' C38' 1.39(2) . ?
C34' H34' 0.9300 . ?
C34' C35' 1.431(18) . ?
C35' H35' 0.9300 . ?
C35' C36' 1.257(19) . ?
C36' H36' 0.9300 . ?
C36' C37' 1.468(18) . ?
C37' H37' 0.9300 . ?
C37' C38' 1.388(18) . ?
C38' H38' 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C8 Ag1 C29 171.93(18) . 3_667 ?
F1 P1 F2 89.9(2) . . ?
F1 P1 F3 179.4(3) . . ?
F1 P1 F5 89.9(2) . . ?
F2 P1 F5 89.5(2) . . ?
F3 P1 F2 89.7(2) . . ?
F3 P1 F5 89.6(2) . . ?
F4 P1 F1 90.4(2) . . ?
F4 P1 F2 179.4(3) . . ?
F4 P1 F3 90.0(2) . . ?
F4 P1 F5 89.9(2) . . ?
F6 P1 F1 90.4(2) . . ?
F6 P1 F2 90.1(2) . . ?
F6 P1 F3 90.1(2) . . ?
F6 P1 F4 90.5(2) . . ?
F6 P1 F5 179.5(3) . . ?
F2' P1' F1' 89.8(3) . . ?
F3' P1' F1' 179.7(4) . . ?
F3' P1' F2' 90.3(3) . . ?
F3' P1' F4' 89.7(3) . . ?
F3' P1' F5' 89.7(3) . . ?
F4' P1' F1' 90.2(3) . . ?
F4' P1' F2' 179.8(4) . . ?
F4' P1' F5' 89.6(3) . . ?
F5' P1' F1' 90.1(3) . . ?
F5' P1' F2' 90.2(3) . . ?
F6' P1' F1' 90.3(3) . . ?
F6' P1' F2' 90.4(3) . . ?
F6' P1' F3' 89.9(3) . . ?
F6' P1' F4' 89.8(3) . . ?
F6' P1' F5' 179.3(5) . . ?
C8 N1 C7 123.2(5) . . ?
C8 N1 C9 111.5(5) . . ?
C9 N1 C7 124.9(5) . . ?
C8 N2 C10 111.0(4) . . ?
C8 N2 C11 123.6(4) . . ?
C10 N2 C11 125.3(4) . . ?
C29 N3 C28 123.1(5) . . ?
C29 N3 C30 111.7(5) . . ?
C30 N3 C28 125.2(5) . . ?
C29 N4 C31 111.2(4) . . ?
C29 N4 C32 124.6(5) . . ?
C31 N4 C32 123.8(5) . . ?
C13 O1 C12 117.8(4) . . ?
C16 O4 C27 117.4(4) . . ?
C2 C1 C6 120.0 . . ?
C2 C1 C7 116.3(6) . . ?
C6 C1 C7 123.7(6) . . ?
C1 C2 H2 120.0 . . ?
C1 C2 C3 120.0 . . ?
C3 C2 H2 120.0 . . ?
C2 C3 H3 120.0 . . ?
C4 C3 C2 120.0 . . ?
C4 C3 H3 120.0 . . ?
C3 C4 H4 120.0 . . ?
C3 C4 C5 120.0 . . ?
C5 C4 H4 120.0 . . ?
C4 C5 H5 120.0 . . ?
C6 C5 C4 120.0 . . ?
C6 C5 H5 120.0 . . ?
C1 C6 H6 120.0 . . ?
C5 C6 C1 120.0 . . ?
C5 C6 H6 120.0 . . ?
C2' C1' C7 129.1(15) . . ?
C6' C1' C2' 106.6(14) . . ?
C6' C1' C7 122.6(16) . . ?
C1' C2' H2' 117.0 . . ?
C3' C2' C1' 126.1(16) . . ?
C3' C2' H2' 117.0 . . ?
C2' C3' H3' 120.3 . . ?
C4' C3' C2' 119.4(17) . . ?
C4' C3' H3' 120.3 . . ?
C3' C4' H4' 121.5 . . ?
C5' C4' C3' 117.1(17) . . ?
C5' C4' H4' 121.5 . . ?
C4' C5' H5' 119.9 . . ?
C4' C5' C6' 120.2(18) . . ?
C6' C5' H5' 119.9 . . ?
C1' C6' C5' 127.8(18) . . ?
C1' C6' H6' 116.1 . . ?
C5' C6' H6' 116.1 . . ?
N1 C7 C1 114.6(6) . . ?
N1 C7 C1' 110.1(9) . . ?
N1 C7 H7AA 108.6 . . ?
N1 C7 H7AB 108.6 . . ?
N1 C7 H7BC 109.6 . . ?
N1 C7 H7BD 109.6 . . ?
C1 C7 H7AA 108.6 . . ?
C1 C7 H7AB 108.6 . . ?
C1' C7 H7BC 109.6 . . ?
C1' C7 H7BD 109.6 . . ?
H7AA C7 H7AB 107.6 . . ?
H7BC C7 H7BD 108.2 . . ?
N1 C8 Ag1 128.0(4) . . ?
N1 C8 N2 103.9(5) . . ?
N2 C8 Ag1 128.0(4) . . ?
N1 C9 H9 126.8 . . ?
C10 C9 N1 106.5(5) . . ?
C10 C9 H9 126.8 . . ?
N2 C10 H10 126.4 . . ?
C9 C10 N2 107.2(5) . . ?
C9 C10 H10 126.4 . . ?
N2 C11 H11A 109.3 . . ?
N2 C11 H11B 109.3 . . ?
N2 C11 C12 111.6(4) . . ?
H11A C11 H11B 108.0 . . ?
C12 C11 H11A 109.3 . . ?
C12 C11 H11B 109.3 . . ?
O1 C12 C11 106.6(4) . . ?
O1 C12 H12A 110.4 . . ?
O1 C12 H12B 110.4 . . ?
C11 C12 H12A 110.4 . . ?
C11 C12 H12B 110.4 . . ?
H12A C12 H12B 108.6 . . ?
O1 C13 C14 122.3(4) . . ?
O1 C13 C26 118.5(4) . . ?
C14 C13 C26 119.2(4) . . ?
C13 C14 H14 119.6 . . ?
C15 C14 C13 120.8(5) . . ?
C15 C14 H14 119.6 . . ?
C14 C15 H15 119.4 . . ?
C14 C15 C16 121.1(5) . . ?
C16 C15 H15 119.4 . . ?
O4 C16 C15 122.1(4) . . ?
O4 C16 C17 118.1(4) . . ?
C15 C16 C17 119.8(4) . . ?
C16 C17 C18 120.7(4) . . ?
C16 C17 C26 119.3(4) . . ?
C26 C17 C18 120.0(4) . . ?
O3 C18 C17 123.4(5) . . ?
O3 C18 C19 120.1(5) . . ?
O3 C18 C19' 112.0(7) . . ?
C17 C18 C19 115.6(4) . . ?
C19' C18 C17 121.8(7) . . ?
C20 C19 C18 117.6(4) . . ?
C20 C19 C24 120.0 . . ?
C24 C19 C18 122.4(4) . . ?
C19 C20 H20 120.0 . . ?
C21 C20 C19 120.0 . . ?
C21 C20 H20 120.0 . . ?
C20 C21 H21 120.0 . . ?
C20 C21 C22 120.0 . . ?
C22 C21 H21 120.0 . . ?
C21 C22 H22 120.0 . . ?
C23 C22 C21 120.0 . . ?
C23 C22 H22 120.0 . . ?
C22 C23 H23 120.0 . . ?
C22 C23 C24 120.0 . . ?
C24 C23 H23 120.0 . . ?
C19 C24 C25 119.5(4) . . ?
C23 C24 C19 120.0 . . ?
C23 C24 C25 120.3(4) . . ?
C20' C19' C18 119.7(12) . . ?
C20' C19' C24' 126.5(11) . . ?
C24' C19' C18 113.7(10) . . ?
C19' C20' H20' 120.8 . . ?
C19' C20' C21' 118.4(14) . . ?
C21' C20' H20' 120.8 . . ?
C20' C21' H21' 120.4 . . ?
C20' C21' C22' 119.2(14) . . ?
C22' C21' H21' 120.4 . . ?
C21' C22' H22' 120.6 . . ?
C23' C22' C21' 118.8(15) . . ?
C23' C22' H22' 120.6 . . ?
C22' C23' H23' 117.4 . . ?
C22' C23' C24' 125.1(14) . . ?
C24' C23' H23' 117.4 . . ?
C19' C24' C23' 111.8(10) . . ?
C19' C24' C25 127.2(11) . . ?
C23' C24' C25 120.9(11) . . ?
O2 C25 C24 117.8(4) . . ?
O2 C25 C24' 118.8(7) . . ?
O2 C25 C26 123.8(4) . . ?
C24 C25 C26 117.5(4) . . ?
C26 C25 C24' 114.0(7) . . ?
C13 C26 C17 119.8(4) . . ?
C13 C26 C25 120.2(4) . . ?
C17 C26 C25 120.0(4) . . ?
O4 C27 H27A 110.5 . . ?
O4 C27 H27B 110.5 . . ?
O4 C27 C28 106.2(4) . . ?
H27A C27 H27B 108.7 . . ?
C28 C27 H27A 110.5 . . ?
C28 C27 H27B 110.5 . . ?
N3 C28 C27 109.9(5) . . ?
N3 C28 H28A 109.7 . . ?
N3 C28 H28B 109.7 . . ?
C27 C28 H28A 109.7 . . ?
C27 C28 H28B 109.7 . . ?
H28A C28 H28B 108.2 . . ?
N3 C29 Ag1 126.6(4) . 3_667 ?
N3 C29 N4 103.9(5) . . ?
N4 C29 Ag1 129.5(4) . 3_667 ?
N3 C30 H30 126.9 . . ?
C31 C30 N3 106.2(5) . . ?
C31 C30 H30 126.9 . . ?
N4 C31 H31 126.5 . . ?
C30 C31 N4 107.0(5) . . ?
C30 C31 H31 126.5 . . ?
N4 C32 H32A 110.1 . . ?
N4 C32 H32B 110.1 . . ?
N4 C32 H32C 108.4 . . ?
N4 C32 H32D 108.4 . . ?
N4 C32 C33 108.1(7) . . ?
N4 C32 C33' 115.5(8) . . ?
H32A C32 H32B 108.4 . . ?
H32C C32 H32D 107.5 . . ?
C33 C32 H32A 110.1 . . ?
C33 C32 H32B 110.1 . . ?
C33' C32 H32C 108.4 . . ?
C33' C32 H32D 108.4 . . ?
C34 C33 C32 121.4(7) . . ?
C34 C33 C38 120.0 . . ?
C38 C33 C32 118.6(7) . . ?
C33 C34 H34 120.0 . . ?
C33 C34 C35 120.0 . . ?
C35 C34 H34 120.0 . . ?
C34 C35 H35 120.0 . . ?
C36 C35 C34 120.0 . . ?
C36 C35 H35 120.0 . . ?
C35 C36 H36 120.0 . . ?
C35 C36 C37 120.0 . . ?
C37 C36 H36 120.0 . . ?
C36 C37 H37 120.0 . . ?
C36 C37 C38 120.0 . . ?
C38 C37 H37 120.0 . . ?
C33 C38 H38 120.0 . . ?
C37 C38 C33 120.0 . . ?
C37 C38 H38 120.0 . . ?
C34' C33' C32 118.2(12) . . ?
C38' C33' C32 124.1(12) . . ?
C38' C33' C34' 117.6(10) . . ?
C33' C34' H34' 121.0 . . ?
C33' C34' C35' 118.0(13) . . ?
C35' C34' H34' 121.0 . . ?
C34' C35' H35' 118.4 . . ?
C36' C35' C34' 123.2(13) . . ?
C36' C35' H35' 118.4 . . ?
C35' C36' H36' 119.2 . . ?
C35' C36' C37' 121.6(13) . . ?
C37' C36' H36' 119.2 . . ?
C36' C37' H37' 122.0 . . ?
C38' C37' C36' 116.0(14) . . ?
C38' C37' H37' 122.0 . . ?
C33' C38' H38' 118.4 . . ?
C37' C38' C33' 123.1(12) . . ?
C37' C38' H38' 118.4 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 C9 C10 N2 -0.4(5) . . . . ?
N2 C11 C12 O1 63.9(5) . . . . ?
N3 C30 C31 N4 -0.4(6) . . . . ?
N4 C32 C33 C34 -106.9(8) . . . . ?
N4 C32 C33 C38 72.9(8) . . . . ?
N4 C32 C33' C34' 175.3(10) . . . . ?
N4 C32 C33' C38' -0.5(17) . . . . ?
O1 C13 C14 C15 177.0(5) . . . . ?
O1 C13 C26 C17 -177.4(4) . . . . ?
O1 C13 C26 C25 5.4(7) . . . . ?
O2 C25 C26 C13 6.8(8) . . . . ?
O2 C25 C26 C17 -170.4(5) . . . . ?
O3 C18 C19 C20 2.4(8) . . . . ?
O3 C18 C19 C24 -176.9(5) . . . . ?
O3 C18 C19' C20' 0.7(17) . . . . ?
O3 C18 C19' C24' -176.3(10) . . . . ?
O4 C16 C17 C18 -2.4(7) . . . . ?
O4 C16 C17 C26 177.3(4) . . . . ?
O4 C27 C28 N3 171.9(5) . . . . ?
C1 C2 C3 C4 0.0 . . . . ?
C2 C1 C6 C5 0.0 . . . . ?
C2 C1 C7 N1 -172.4(5) . . . . ?
C2 C3 C4 C5 0.0 . . . . ?
C3 C4 C5 C6 0.0 . . . . ?
C4 C5 C6 C1 0.0 . . . . ?
C6 C1 C2 C3 0.0 . . . . ?
C6 C1 C7 N1 5.8(9) . . . . ?
C1' C2' C3' C4' -4(3) . . . . ?
C2' C1' C6' C5' -7(3) . . . . ?
C2' C1' C7 N1 -118.6(18) . . . . ?
C2' C3' C4' C5' -12(3) . . . . ?
C3' C4' C5' C6' 18(3) . . . . ?
C4' C5' C6' C1' -8(3) . . . . ?
C6' C1' C2' C3' 13(3) . . . . ?
C6' C1' C7 N1 44(2) . . . . ?
C7 N1 C8 Ag1 11.0(7) . . . . ?
C7 N1 C8 N2 -172.8(4) . . . . ?
C7 N1 C9 C10 172.7(5) . . . . ?
C7 C1 C2 C3 178.3(7) . . . . ?
C7 C1 C6 C5 -178.1(8) . . . . ?
C7 C1' C2' C3' 177.8(16) . . . . ?
C7 C1' C6' C5' -172.9(17) . . . . ?
C8 N1 C7 C1 84.0(7) . . . . ?
C8 N1 C7 C1' 71.1(10) . . . . ?
C8 N1 C9 C10 0.5(6) . . . . ?
C8 N2 C10 C9 0.2(5) . . . . ?
C8 N2 C11 C12 -100.2(5) . . . . ?
C9 N1 C7 C1 -87.3(8) . . . . ?
C9 N1 C7 C1' -100.2(10) . . . . ?
C9 N1 C8 Ag1 -176.7(3) . . . . ?
C9 N1 C8 N2 -0.4(5) . . . . ?
C10 N2 C8 Ag1 176.4(3) . . . . ?
C10 N2 C8 N1 0.2(5) . . . . ?
C10 N2 C11 C12 75.4(6) . . . . ?
C11 N2 C8 Ag1 -7.5(6) . . . . ?
C11 N2 C8 N1 176.3(4) . . . . ?
C11 N2 C10 C9 -175.9(4) . . . . ?
C12 O1 C13 C14 -3.9(7) . . . . ?
C12 O1 C13 C26 174.6(4) . . . . ?
C13 O1 C12 C11 -171.5(4) . . . . ?
C13 C14 C15 C16 0.1(8) . . . . ?
C14 C13 C26 C17 1.2(7) . . . . ?
C14 C13 C26 C25 -176.0(5) . . . . ?
C14 C15 C16 O4 -177.6(5) . . . . ?
C14 C15 C16 C17 1.6(8) . . . . ?
C15 C16 C17 C18 178.4(5) . . . . ?
C15 C16 C17 C26 -1.9(7) . . . . ?
C16 O4 C27 C28 -165.8(5) . . . . ?
C16 C17 C18 O3 -3.4(8) . . . . ?
C16 C17 C18 C19 165.8(5) . . . . ?
C16 C17 C18 C19' -163.2(9) . . . . ?
C16 C17 C26 C13 0.5(7) . . . . ?
C16 C17 C26 C25 177.7(4) . . . . ?
C17 C18 C19 C20 -167.2(4) . . . . ?
C17 C18 C19 C24 13.5(7) . . . . ?
C17 C18 C19' C20' 162.5(11) . . . . ?
C17 C18 C19' C24' -14.5(15) . . . . ?
C18 C17 C26 C13 -179.8(4) . . . . ?
C18 C17 C26 C25 -2.6(7) . . . . ?
C18 C19 C20 C21 -179.3(6) . . . . ?
C18 C19 C24 C23 179.3(6) . . . . ?
C18 C19 C24 C25 4.3(7) . . . . ?
C18 C19' C20' C21' -173.1(14) . . . . ?
C18 C19' C24' C23' 176.0(13) . . . . ?
C18 C19' C24' C25 -1.5(19) . . . . ?
C19 C20 C21 C22 0.0 . . . . ?
C19 C24 C25 O2 169.0(5) . . . . ?
C19 C24 C25 C26 -21.3(7) . . . . ?
C20 C19 C24 C23 0.0 . . . . ?
C20 C19 C24 C25 -175.0(6) . . . . ?
C20 C21 C22 C23 0.0 . . . . ?
C21 C22 C23 C24 0.0 . . . . ?
C22 C23 C24 C19 0.0 . . . . ?
C22 C23 C24 C25 175.0(6) . . . . ?
C23 C24 C25 O2 -6.0(7) . . . . ?
C23 C24 C25 C26 163.7(4) . . . . ?
C24 C19 C20 C21 0.0 . . . . ?
C24 C25 C26 C13 -162.2(5) . . . . ?
C24 C25 C26 C17 20.6(7) . . . . ?
C19' C20' C21' C22' -2(3) . . . . ?
C19' C24' C25 O2 174.4(12) . . . . ?
C19' C24' C25 C26 14.5(16) . . . . ?
C20' C19' C24' C23' -1(2) . . . . ?
C20' C19' C24' C25 -178.3(14) . . . . ?
C20' C21' C22' C23' -1(3) . . . . ?
C21' C22' C23' C24' 4(3) . . . . ?
C22' C23' C24' C19' -3(2) . . . . ?
C22' C23' C24' C25 174.7(15) . . . . ?
C23' C24' C25 O2 -2.9(17) . . . . ?
C23' C24' C25 C26 -162.8(12) . . . . ?
C24' C19' C20' C21' 3(3) . . . . ?
C24' C25 C26 C13 165.6(7) . . . . ?
C24' C25 C26 C17 -11.6(8) . . . . ?
C26 C13 C14 C15 -1.5(8) . . . . ?
C26 C17 C18 O3 176.9(6) . . . . ?
C26 C17 C18 C19 -13.9(7) . . . . ?
C26 C17 C18 C19' 17.1(10) . . . . ?
C27 O4 C16 C15 -13.8(7) . . . . ?
C27 O4 C16 C17 167.0(5) . . . . ?
C28 N3 C29 Ag1 -5.2(7) . . . 3_667 ?
C28 N3 C29 N4 177.6(4) . . . . ?
C28 N3 C30 C31 -177.0(5) . . . . ?
C29 N3 C28 C27 -95.4(6) . . . . ?
C29 N3 C30 C31 -0.2(7) . . . . ?
C29 N4 C31 C30 0.9(6) . . . . ?
C29 N4 C32 C33 86.7(7) . . . . ?
C29 N4 C32 C33' 85.8(9) . . . . ?
C30 N3 C28 C27 81.0(7) . . . . ?
C30 N3 C29 Ag1 177.9(4) . . . 3_667 ?
C30 N3 C29 N4 0.7(6) . . . . ?
C31 N4 C29 Ag1 -178.0(4) . . . 3_667 ?
C31 N4 C29 N3 -1.0(6) . . . . ?
C31 N4 C32 C33 -85.6(7) . . . . ?
C31 N4 C32 C33' -86.4(9) . . . . ?
C32 N4 C29 Ag1 8.9(7) . . . 3_667 ?
C32 N4 C29 N3 -174.1(5) . . . . ?
C32 N4 C31 C30 174.0(5) . . . . ?
C32 C33 C34 C35 179.8(11) . . . . ?
C32 C33 C38 C37 -179.8(11) . . . . ?
C32 C33' C34' C35' 176.1(11) . . . . ?
C32 C33' C38' C37' -178.7(11) . . . . ?
C33 C34 C35 C36 0.0 . . . . ?
C34 C33 C38 C37 0.0 . . . . ?
C34 C35 C36 C37 0.0 . . . . ?
C35 C36 C37 C38 0.0 . . . . ?
C36 C37 C38 C33 0.0 . . . . ?
C38 C33 C34 C35 0.0 . . . . ?
C33' C34' C35' C36' 4(2) . . . . ?
C34' C33' C38' C37' 5(2) . . . . ?
C34' C35' C36' C37' 3(2) . . . . ?
C35' C36' C37' C38' -5.0(19) . . . . ?
C36' C37' C38' C33' 0.7(19) . . . . ?
C38' C33' C34' C35' -7.8(19) . . . . ?

_shelx_SHELXL_version_number     2014/7

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_n130912a
_database_code_depnum_ccdc_archive 'CCDC 1408699'
_audit_update_record             
;
2017-03-29 deposited with the CCDC.
2017-04-19 downloaded from the CCDC.
;
_audit_creation_date             2017-03-17
_audit_creation_method           
;
Olex2 1.2-beta
(compiled 2017.03.02 svn.r3394 for OlexSys, GUI svn.r5328)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         
'2(C96 H80 Ag2 N8 O8), 4(F6 P), 0.7(C2 H4 Cl2), C2 H3 N'
_chemical_formula_sum            'C195.40 H165.80 Ag4 Cl1.40 F24 N17 O16 P4'
_chemical_formula_weight         4069.03
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.3833(6)
_cell_length_b                   20.3902(13)
_cell_length_c                   25.4603(16)
_cell_angle_alpha                82.3880(10)
_cell_angle_beta                 80.0310(10)
_cell_angle_gamma                85.566(2)
_cell_volume                     4748.0(5)
_cell_formula_units_Z            1
_cell_measurement_reflns_used    6562
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      25.33
_cell_measurement_theta_min      2.22
_shelx_estimated_absorpt_T_max   0.922
_shelx_estimated_absorpt_T_min   0.908
_exptl_absorpt_coefficient_mu    0.549
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.6752
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
'SADABS-2012/1 (Bruker,2012) was used for absorption correction. wR2(int) was 0.0678 before and 0.0387 after correction. The Ratio of minimum to maximum transmission is 0.9055. The λ/2 correction factor is 0.0015.'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.423
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             2073
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.15
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0324
_diffrn_reflns_av_unetI/netI     0.0664
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            27661
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.010
_diffrn_reflns_theta_max         25.010
_diffrn_reflns_theta_min         1.374
_diffrn_ambient_temperature      173.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                12059
_reflns_number_total             16715
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_refine_diff_density_max         2.293
_refine_diff_density_min         -0.984
_refine_diff_density_rms         0.135
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.043
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1259
_refine_ls_number_reflns         16715
_refine_ls_number_restraints     335
_refine_ls_R_factor_all          0.1133
_refine_ls_R_factor_gt           0.0840
_refine_ls_restrained_S_all      1.113
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1319P)²+19.0061P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2218
_refine_ls_wR_factor_ref         0.2501
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 N9-C97
 1.11 with sigma of 0.01
 C97-C98
 1.47 with sigma of 0.01
 N9-C98
 2.59 with sigma of 0.01
 P2-F7 = P2-F8 = P2-F9 = P2-F10 = P2-F11 = P2-F12
 1.6 with sigma of 0.01
 F7-F8 = F7-F10 = F7-F11 = F7-F12 = F8-F9 = F8-F11
 2.23 with sigma of 0.01
 F8-F12 = F9-F10 = F9-F11 = F9-F12 = F10-F11 = F10-F12
 2.23 with sigma of 0.01
 P2'-F7' = P2'-F8' = P2'-F9' = P2'-F10' = P2'-F11' = P2'-F12'
 1.6 with sigma of 0.01
 F7'-F8' = F7'-F10' = F7'-F11' = F7'-F12' = F8'-F9' = F8'-F11'
 2.23 with sigma of 0.01
 F8'-F12' = F9'-F10' = F9'-F11' = F9'-F12' = F10'-F11' = F10'-F12'
 2.23 with sigma of 0.01
 N2-C15
 1.47 with sigma of 0.01
 C15-C16 = C16-C17
 1.51 with sigma of 0.01
 C17-O1
 1.45 with sigma of 0.01
 N2-C15'
 1.47 with sigma of 0.01
 C15'-C16' = C16'-C17'
 1.51 with sigma of 0.01
 C17'-O1
 1.45 with sigma of 0.01
 Cl1-C99 = Cl2-C100
 1.75 with sigma of 0.01
 C99-C100
 1.42 with sigma of 0.01
 Cl1-C100 = Cl2-C99
 2.7 with sigma of 0.01
3. Rigid bond restraints
 F5, P1
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.005
4. Uiso/Uaniso restraints and constraints
Cl2 \\sim C100 \\sim C99 \\sim Cl1: within 2A with sigma of 0.005 and sigma for
terminal atoms of 0.005
Uanis(C98) \\sim Ueq, Uanis(N6) \\sim Ueq, Uanis(C62) \\sim Ueq: with sigma of
0.01 and sigma for terminal atoms of 0.01
Uanis(C62) \\sim Ueq, Uanis(C57) \\sim Ueq, Uanis(C58) \\sim Ueq, Uanis(C59)
\\sim Ueq, Uanis(C60) \\sim Ueq, Uanis(C61) \\sim Ueq, Uanis(C56) \\sim Ueq,
Uanis(C97) \\sim Ueq, Uanis(C98) \\sim Ueq, Uanis(N9) \\sim Ueq, Uanis(C1)
\\sim Ueq, Uanis(C2) \\sim Ueq, Uanis(C3) \\sim Ueq, Uanis(C4) \\sim Ueq,
Uanis(C5) \\sim Ueq, Uanis(C6) \\sim Ueq, Uanis(C63) \\sim Ueq, Uanis(C64)
\\sim Ueq, Uanis(C65) \\sim Ueq, Uanis(C66) \\sim Ueq, Uanis(C67) \\sim Ueq,
Uanis(C69) \\sim Ueq, Uanis(C70) \\sim Ueq, Uanis(C79) \\sim Ueq, Uanis(C78)
\\sim Ueq, Uanis(C77) \\sim Ueq, Uanis(C76) \\sim Ueq, Uanis(C75) \\sim Ueq,
Uanis(C74) \\sim Ueq, Uanis(C73) \\sim Ueq, Uanis(C72) \\sim Ueq: with sigma of
0.01 and sigma for terminal atoms of 0.01
Uanis(O6) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.01
Uanis(O5) \\sim Ueq, Uanis(N2) \\sim Ueq, Uanis(C55) \\sim Ueq, Uanis(F5) \\sim
Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.002
Uanis(C13) \\sim Ueq, Uanis(C8) \\sim Ueq, Uanis(C14) \\sim Ueq, Uanis(N1)
\\sim Ueq, Uanis(N2) \\sim Ueq, Uanis(C9) \\sim Ueq, Uanis(C10) \\sim Ueq: with
sigma of 0.005 and sigma for terminal atoms of 0.002
Uanis(N5) \\sim Ueq, Uanis(N6) \\sim Ueq, Uanis(C62) \\sim Ueq: with sigma of
0.005 and sigma for terminal atoms of 0.002
Uanis(F12) = Uanis(F12')
Uanis(F11) = Uanis(F11')
Uanis(F10) = Uanis(F10')
Uanis(F9) = Uanis(F9')
Uanis(F8) = Uanis(F8')
Uanis(F7) = Uanis(F7')
Uanis(P2) = Uanis(P2')
Uanis(Ag2) = Uanis(Ag2')
5. Others
 Sof(Ag2')=1-FVAR(1)
 Sof(Ag2)=FVAR(1)
 Sof(C15')=Sof(H15C)=Sof(H15D)=Sof(C16')=Sof(H16C)=Sof(H16D)=Sof(C17')=
 Sof(H17C)=Sof(H17D)=1-FVAR(2)
 Sof(C15)=Sof(H15A)=Sof(H15B)=Sof(C16)=Sof(H16A)=Sof(H16B)=Sof(C17)=Sof(H17A)=
 Sof(H17B)=FVAR(2)
 Sof(P2')=Sof(F7')=Sof(F8')=Sof(F9')=Sof(F10')=Sof(F11')=Sof(F12')=1-FVAR(3)
 Sof(P2)=Sof(F7)=Sof(F8)=Sof(F9)=Sof(F10)=Sof(F11)=Sof(F12)=FVAR(3)
 Fixed Sof: Cl1(0.35) Cl2(0.35) C99(0.35) H99A(0.35) H99B(0.35) C100(0.35)
 H10A(0.35) H10B(0.35) C97(0.5) C98(0.5) H98A(0.5) H98B(0.5) H98C(0.5) N9(0.5)
6.a Secondary CH2 refined with riding coordinates:
 C7(H7A,H7B), C15(H15A,H15B), C16(H16A,H16B), C17(H17A,H17B), C15'(H15C,H15D),
 C16'(H16C,H16D), C17'(H17C,H17D), C32(H32A,H32B), C33(H33A,H33B), C34(H34A,
 H34B), C42(H42A,H42B), C55(H55A,H55B), C63(H63A,H63B), C64(H64A,H64B),
 C65(H65A,H65B), C80(H80A,H80B), C81(H81A,H81B), C82(H82A,H82B), C90(H90A,H90B),
  C99(H99A,H99B), C100(H10A,H10B)
6.b Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3), C4(H4), C5(H5), C6(H6), C10(H10), C11(H11), C12(H12),
 C13(H13), C19(H19), C20(H20), C25(H25), C26(H26), C27(H27), C28(H28), C37(H37),
  C38(H38), C39(H39), C40(H40), C44(H44), C45(H45), C46(H46), C47(H47),
 C48(H48), C50(H50), C51(H51), C52(H52), C53(H53), C54(H54), C58(H58), C59(H59),
  C60(H60), C61(H61), C67(H67), C68(H68), C73(H73), C74(H74), C75(H75),
 C76(H76), C85(H85), C86(H86), C87(H87), C88(H88), C92(H92), C93(H93), C94(H94),
  C95(H95), C96(H96)
6.c Fitted hexagon refined as free rotating group:
 C1(C2,C3,C4,C5,C6)
6.d Idealised Me refined as rotating group:
 C98(H98A,H98B,H98C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.31948(5) 0.27137(2) 0.96172(2) 0.02682(16) Uani 1 1 d . . . . .
Ag2 Ag 0.07966(13) 0.14212(7) 0.55915(4) 0.0414(3) Uani 0.5559(13) 1 d . . P A
1
Ag2' Ag 0.02882(17) 0.17160(9) 0.56880(6) 0.0414(3) Uani 0.4441(13) 1 d . . P A
2
O1 O 0.4087(6) 0.2267(3) 0.7242(2) 0.0584(16) Uani 1 1 d D . . . .
O2 O 0.4416(8) 0.3491(3) 0.7172(3) 0.079(2) Uani 1 1 d . . . . .
O3 O 0.6603(5) 0.3206(2) 0.90016(19) 0.0371(11) Uani 1 1 d . . . . .
O4 O 0.6251(5) 0.1963(2) 0.91416(17) 0.0336(10) Uani 1 1 d . . . . .
O5 O -0.2894(9) 0.1425(4) 0.6470(3) 0.087(2) Uani 1 1 d . U . . .
O6 O -0.3114(9) 0.2546(4) 0.5906(3) 0.092(2) Uani 1 1 d . U . . .
O7 O -0.0285(6) 0.3673(3) 0.7143(2) 0.0525(14) Uani 1 1 d . . . . .
O8 O -0.0687(5) 0.2694(2) 0.79057(18) 0.0365(11) Uani 1 1 d . . . . .
N1 N 0.0646(7) 0.3076(4) 0.5350(3) 0.0597(18) Uani 1 1 d . U . . .
N2 N 0.1999(10) 0.2695(5) 0.5947(3) 0.089(3) Uani 1 1 d D U . . .
N3 N 0.4485(5) 0.1694(2) 1.04516(19) 0.0268(11) Uani 1 1 d . . . . .
N4 N 0.2233(5) 0.1529(3) 1.04599(19) 0.0277(11) Uani 1 1 d . . . . .
N5 N 0.1127(10) 0.0032(5) 0.5766(3) 0.077(2) Uani 1 1 d . U . . .
N6 N -0.1049(10) 0.0264(5) 0.5624(3) 0.075(2) Uani 1 1 d . U . . .
N7 N 0.2224(5) 0.3546(2) 0.86245(18) 0.0239(11) Uani 1 1 d . . . . .
N8 N 0.3195(5) 0.4170(3) 0.90680(19) 0.0263(11) Uani 1 1 d . . . . .
C1 C 0.0062(8) 0.3300(4) 0.4421(2) 0.078(3) Uani 1 1 d . U . . .
C2 C -0.1021(7) 0.3505(5) 0.4115(3) 0.104(4) Uani 1 1 d G U . . .
H2 H -0.2009 0.3509 0.4281 0.125 Uiso 1 1 calc R . . . .
C3 C -0.0657(10) 0.3703(5) 0.3567(3) 0.132(5) Uani 1 1 d G U . . .
H3 H -0.1397 0.3842 0.3359 0.159 Uiso 1 1 calc R . . . .
C4 C 0.0789(12) 0.3696(5) 0.3325(2) 0.114(4) Uani 1 1 d G U . . .
H4 H 0.1037 0.3831 0.2950 0.137 Uiso 1 1 calc R . . . .
C5 C 0.1871(9) 0.3492(5) 0.3630(3) 0.120(5) Uani 1 1 d G U . . .
H5 H 0.2860 0.3487 0.3464 0.144 Uiso 1 1 calc R . . . .
C6 C 0.1508(7) 0.3294(4) 0.4178(3) 0.089(3) Uani 1 1 d G U . . .
H6 H 0.2248 0.3154 0.4387 0.107 Uiso 1 1 calc R . . . .
C7 C -0.0386(11) 0.3062(7) 0.4978(3) 0.092(4) Uani 1 1 d . . . . .
H7A H -0.0655 0.2598 0.4998 0.110 Uiso 1 1 calc R . . . .
H7B H -0.1275 0.3325 0.5111 0.110 Uiso 1 1 calc R . . . .
C8 C 0.1183(10) 0.3615(5) 0.5479(3) 0.059(2) Uani 1 1 d . U . . .
C9 C 0.2001(11) 0.3400(5) 0.5882(4) 0.068(3) Uani 1 1 d . U . . .
C10 C 0.2670(12) 0.3811(6) 0.6123(4) 0.076(3) Uani 1 1 d . U . . .
H10 H 0.3222 0.3642 0.6395 0.092 Uiso 1 1 calc R . . . .
C11 C 0.2529(12) 0.4491(6) 0.5961(4) 0.081(3) Uani 1 1 d . . . . .
H11 H 0.2954 0.4798 0.6129 0.097 Uiso 1 1 calc R . . . .
C12 C 0.1737(14) 0.4714(7) 0.5538(4) 0.096(4) Uani 1 1 d . . . . .
H12 H 0.1681 0.5173 0.5412 0.116 Uiso 1 1 calc R . . . .
C13 C 0.1053(12) 0.4289(6) 0.5306(4) 0.079(3) Uani 1 1 d . U . . .
H13 H 0.0500 0.4451 0.5032 0.095 Uiso 1 1 calc R . . . .
C14 C 0.1091(12) 0.2513(6) 0.5636(4) 0.078(3) Uani 1 1 d . U . . .
C15 C 0.2931(13) 0.2206(8) 0.6248(4) 0.036(4) Uani 0.572(14) 1 d D . P B 1
H15A H 0.3862 0.2396 0.6260 0.043 Uiso 0.572(14) 1 calc R . P B 1
H15B H 0.3139 0.1798 0.6070 0.043 Uiso 0.572(14) 1 calc R . P B 1
C16 C 0.2103(10) 0.2051(6) 0.6808(4) 0.031(3) Uani 0.572(14) 1 d D . P B 1
H16A H 0.1356 0.1737 0.6798 0.038 Uiso 0.572(14) 1 calc R . P B 1
H16B H 0.1595 0.2464 0.6925 0.038 Uiso 0.572(14) 1 calc R . P B 1
C17 C 0.3034(10) 0.1756(5) 0.7219(4) 0.028(3) Uani 0.572(14) 1 d D . P B 1
H17A H 0.2426 0.1652 0.7575 0.033 Uiso 0.572(14) 1 calc R . P B 1
H17B H 0.3560 0.1342 0.7111 0.033 Uiso 0.572(14) 1 calc R . P B 1
C15' C 0.1960(14) 0.2473(9) 0.6527(4) 0.037(5) Uani 0.428(14) 1 d D . P B 2
H15C H 0.1162 0.2181 0.6687 0.045 Uiso 0.428(14) 1 calc R . P B 2
H15D H 0.1978 0.2839 0.6745 0.045 Uiso 0.428(14) 1 calc R . P B 2
C16' C 0.3413(16) 0.2104(9) 0.6398(6) 0.031(5) Uani 0.428(14) 1 d D . P B 2
H16C H 0.3324 0.1759 0.6167 0.037 Uiso 0.428(14) 1 calc R . P B 2
H16D H 0.4125 0.2417 0.6194 0.037 Uiso 0.428(14) 1 calc R . P B 2
C17' C 0.396(2) 0.1782(7) 0.6901(6) 0.044(5) Uani 0.428(14) 1 d D . P B 2
H17C H 0.3275 0.1450 0.7095 0.053 Uiso 0.428(14) 1 calc R . P B 2
H17D H 0.4912 0.1549 0.6802 0.053 Uiso 0.428(14) 1 calc R . P B 2
C18 C 0.4631(7) 0.2180(4) 0.7708(3) 0.0349(15) Uani 1 1 d . . . . .
C19 C 0.4659(7) 0.1570(4) 0.8020(3) 0.0406(17) Uani 1 1 d . . . . .
H19 H 0.4305 0.1200 0.7903 0.049 Uiso 1 1 calc R . . . .
C20 C 0.5193(7) 0.1490(4) 0.8499(3) 0.0359(15) Uani 1 1 d . . . . .
H20 H 0.5204 0.1067 0.8707 0.043 Uiso 1 1 calc R . . . .
C21 C 0.5714(6) 0.2024(3) 0.8678(2) 0.0273(13) Uani 1 1 d . . . . .
C22 C 0.5685(6) 0.2655(3) 0.8372(2) 0.0306(14) Uani 1 1 d . . . . .
C23 C 0.6226(6) 0.3238(3) 0.8559(3) 0.0308(14) Uani 1 1 d . . . . .
C24 C 0.6256(7) 0.3872(3) 0.8208(3) 0.0357(15) Uani 1 1 d . . . . .
C25 C 0.6893(8) 0.4410(4) 0.8353(3) 0.0466(18) Uani 1 1 d . . . . .
H25 H 0.7351 0.4356 0.8662 0.056 Uiso 1 1 calc R . . . .
C26 C 0.6845(10) 0.5023(4) 0.8036(4) 0.065(3) Uani 1 1 d . . . . .
H26 H 0.7288 0.5387 0.8127 0.078 Uiso 1 1 calc R . . . .
C27 C 0.6159(11) 0.5104(4) 0.7593(4) 0.063(2) Uani 1 1 d . . . . .
H27 H 0.6101 0.5527 0.7388 0.075 Uiso 1 1 calc R . . . .
C28 C 0.5566(9) 0.4583(4) 0.7449(3) 0.055(2) Uani 1 1 d . . . . .
H28 H 0.5104 0.4642 0.7141 0.066 Uiso 1 1 calc R . . . .
C29 C 0.5627(7) 0.3962(4) 0.7748(3) 0.0377(16) Uani 1 1 d . . . . .
C30 C 0.4999(8) 0.3399(4) 0.7571(3) 0.0412(17) Uani 1 1 d . . . . .
C31 C 0.5137(6) 0.2733(3) 0.7881(2) 0.0291(14) Uani 1 1 d . . . . .
C32 C 0.6354(7) 0.1320(3) 0.9452(3) 0.0366(16) Uani 1 1 d . . . . .
H32A H 0.7025 0.1012 0.9245 0.044 Uiso 1 1 calc R . . . .
H32B H 0.5390 0.1129 0.9548 0.044 Uiso 1 1 calc R . . . .
C33 C 0.6916(7) 0.1430(4) 0.9947(3) 0.0369(16) Uani 1 1 d . . . . .
H33A H 0.7903 0.1594 0.9843 0.044 Uiso 1 1 calc R . . . .
H33B H 0.6986 0.1002 1.0178 0.044 Uiso 1 1 calc R . . . .
C34 C 0.5960(7) 0.1923(3) 1.0268(3) 0.0342(15) Uani 1 1 d . . . . .
H34A H 0.6397 0.1987 1.0584 0.041 Uiso 1 1 calc R . . . .
H34B H 0.5909 0.2356 1.0043 0.041 Uiso 1 1 calc R . . . .
C35 C 0.4136(7) 0.1171(3) 1.0848(2) 0.0302(14) Uani 1 1 d . . . . .
C36 C 0.2709(7) 0.1055(3) 1.0854(2) 0.0305(14) Uani 1 1 d . . . . .
C37 C 0.1997(8) 0.0557(3) 1.1200(3) 0.0399(16) Uani 1 1 d . . . . .
H37 H 0.1015 0.0477 1.1198 0.048 Uiso 1 1 calc R . . . .
C38 C 0.2805(9) 0.0183(4) 1.1550(3) 0.050(2) Uani 1 1 d . . . . .
H38 H 0.2363 -0.0163 1.1797 0.060 Uiso 1 1 calc R . . . .
C39 C 0.4247(9) 0.0300(4) 1.1550(3) 0.049(2) Uani 1 1 d . . . . .
H39 H 0.4757 0.0034 1.1800 0.059 Uiso 1 1 calc R . . . .
C40 C 0.4957(8) 0.0789(4) 1.1199(3) 0.0388(16) Uani 1 1 d . . . . .
H40 H 0.5946 0.0862 1.1196 0.047 Uiso 1 1 calc R . . . .
C41 C 0.3316(6) 0.1908(3) 1.0217(2) 0.0273(13) Uani 1 1 d . . . . .
C42 C 0.0757(7) 0.1592(3) 1.0339(3) 0.0320(14) Uani 1 1 d . . . . .
H42A H 0.0386 0.1145 1.0369 0.038 Uiso 1 1 calc R . . . .
H42B H 0.0777 0.1799 0.9964 0.038 Uiso 1 1 calc R . . . .
C43 C -0.0267(7) 0.2005(3) 1.0711(3) 0.0338(15) Uani 1 1 d . . . . .
C44 C -0.1086(8) 0.1725(4) 1.1167(3) 0.0437(18) Uani 1 1 d . . . . .
H44 H -0.1019 0.1257 1.1253 0.052 Uiso 1 1 calc R . . . .
C45 C -0.2026(10) 0.2105(4) 1.1514(3) 0.059(2) Uani 1 1 d . . . . .
H45 H -0.2595 0.1898 1.1829 0.070 Uiso 1 1 calc R . . . .
C46 C -0.2110(10) 0.2778(5) 1.1391(4) 0.067(3) Uani 1 1 d . . . . .
H46 H -0.2693 0.3045 1.1633 0.080 Uiso 1 1 calc R . . . .
C47 C -0.1346(11) 0.3071(5) 1.0913(5) 0.076(3) Uani 1 1 d . . . . .
H47 H -0.1460 0.3536 1.0816 0.092 Uiso 1 1 calc R . . . .
C48 C -0.0408(9) 0.2685(4) 1.0574(4) 0.062(2) Uani 1 1 d . . . . .
H48 H 0.0130 0.2888 1.0250 0.074 Uiso 1 1 calc R . . . .
C49 C 0.2592(12) -0.0033(7) 0.6498(4) 0.079(4) Uani 1 1 d . . . . .
C50 C 0.1660(11) 0.0308(6) 0.6850(3) 0.075(3) Uani 1 1 d . . . . .
H50 H 0.0981 0.0630 0.6717 0.090 Uiso 1 1 calc R . . . .
C51 C 0.1682(11) 0.0192(6) 0.7402(3) 0.070(3) Uani 1 1 d . . . . .
H51 H 0.0998 0.0422 0.7644 0.084 Uiso 1 1 calc R . . . .
C52 C 0.2692(11) -0.0251(6) 0.7592(4) 0.071(3) Uani 1 1 d . . . . .
H52 H 0.2735 -0.0319 0.7966 0.085 Uiso 1 1 calc R . . . .
C53 C 0.3645(13) -0.0600(7) 0.7245(4) 0.084(3) Uani 1 1 d . . . . .
H53 H 0.4337 -0.0915 0.7377 0.100 Uiso 1 1 calc R . . . .
C54 C 0.3591(13) -0.0488(7) 0.6693(4) 0.086(4) Uani 1 1 d . . . . .
H54 H 0.4250 -0.0728 0.6452 0.103 Uiso 1 1 calc R . . . .
C55 C 0.2596(12) 0.0094(6) 0.5895(4) 0.084(3) Uani 1 1 d . U . . .
H55A H 0.2919 0.0545 0.5759 0.101 Uiso 1 1 calc R . . . .
H55B H 0.3291 -0.0228 0.5713 0.101 Uiso 1 1 calc R . . . .
C56 C 0.0532(13) -0.0589(7) 0.5791(4) 0.083(3) Uani 1 1 d . U . . .
C57 C -0.0851(13) -0.0411(7) 0.5684(4) 0.085(3) Uani 1 1 d . U . . .
C58 C -0.1784(15) -0.0920(7) 0.5663(4) 0.092(3) Uani 1 1 d . U . . .
H58 H -0.2734 -0.0822 0.5582 0.110 Uiso 1 1 calc R . . . .
C59 C -0.1274(16) -0.1526(8) 0.5761(5) 0.103(4) Uani 1 1 d . U . . .
H59 H -0.1896 -0.1873 0.5765 0.124 Uiso 1 1 calc R . . . .
C60 C 0.0110(19) -0.1696(9) 0.5858(6) 0.119(5) Uani 1 1 d . U . . .
H60 H 0.0418 -0.2152 0.5912 0.143 Uiso 1 1 calc R . . . .
C61 C 0.1081(16) -0.1213(8) 0.5880(5) 0.103(4) Uani 1 1 d . U . . .
H61 H 0.2038 -0.1319 0.5951 0.123 Uiso 1 1 calc R . . . .
C62 C 0.0232(12) 0.0531(6) 0.5687(4) 0.074(3) Uani 1 1 d . U . . .
C63 C -0.2370(13) 0.0637(7) 0.5569(4) 0.088(3) Uani 1 1 d . U . . .
H63A H -0.2746 0.0510 0.5258 0.105 Uiso 1 1 calc R . . . .
H63B H -0.2178 0.1114 0.5492 0.105 Uiso 1 1 calc R . . . .
C64 C -0.3553(13) 0.0527(6) 0.6083(4) 0.085(3) Uani 1 1 d . U . . .
H64A H -0.4449 0.0793 0.6020 0.102 Uiso 1 1 calc R . . . .
H64B H -0.3782 0.0055 0.6150 0.102 Uiso 1 1 calc R . . . .
C65 C -0.3057(14) 0.0722(6) 0.6574(4) 0.088(3) Uani 1 1 d . U . . .
H65A H -0.3786 0.0614 0.6899 0.106 Uiso 1 1 calc R . . . .
H65B H -0.2124 0.0485 0.6629 0.106 Uiso 1 1 calc R . . . .
C66 C -0.2320(10) 0.1726(5) 0.6822(3) 0.063(2) Uani 1 1 d . U . . .
C67 C -0.1910(10) 0.1365(5) 0.7290(3) 0.061(2) Uani 1 1 d . U . . .
H67 H -0.2006 0.0899 0.7355 0.073 Uiso 1 1 calc R . . . .
C68 C -0.1365(8) 0.1685(4) 0.7661(3) 0.0442(18) Uani 1 1 d . . . . .
H68 H -0.1126 0.1442 0.7982 0.053 Uiso 1 1 calc R . . . .
C69 C -0.1178(7) 0.2356(4) 0.7557(3) 0.0349(15) Uani 1 1 d . U . . .
C70 C -0.1509(7) 0.2717(4) 0.7079(3) 0.0401(17) Uani 1 1 d . U . . .
C71 C -0.1155(8) 0.3419(4) 0.6934(3) 0.0437(18) Uani 1 1 d . . . . .
C72 C -0.1882(9) 0.3826(5) 0.6512(3) 0.054(2) Uani 1 1 d . U . . .
C73 C -0.1764(12) 0.4518(5) 0.6433(4) 0.072(3) Uani 1 1 d . U . . .
H73 H -0.1202 0.4722 0.6635 0.087 Uiso 1 1 calc R . . . .
C74 C -0.2481(14) 0.4897(6) 0.6054(4) 0.091(4) Uani 1 1 d . U . . .
H74 H -0.2400 0.5364 0.5996 0.109 Uiso 1 1 calc R . . . .
C75 C -0.3294(15) 0.4611(7) 0.5767(5) 0.098(4) Uani 1 1 d . U . . .
H75 H -0.3812 0.4882 0.5522 0.117 Uiso 1 1 calc R . . . .
C76 C -0.3379(11) 0.3946(7) 0.5821(4) 0.077(3) Uani 1 1 d . U . . .
H76 H -0.3932 0.3756 0.5607 0.093 Uiso 1 1 calc R . . . .
C77 C -0.2644(9) 0.3522(5) 0.6201(3) 0.060(2) Uani 1 1 d . U . . .
C78 C -0.2677(9) 0.2808(5) 0.6248(3) 0.060(2) Uani 1 1 d . U . . .
C79 C -0.2145(8) 0.2407(5) 0.6718(3) 0.049(2) Uani 1 1 d . U . . .
C80 C -0.0439(7) 0.2340(3) 0.8418(2) 0.0326(14) Uani 1 1 d . . . . .
H80A H 0.0279 0.1963 0.8364 0.039 Uiso 1 1 calc R . . . .
H80B H -0.1353 0.2169 0.8628 0.039 Uiso 1 1 calc R . . . .
C81 C 0.0126(6) 0.2842(3) 0.8702(2) 0.0260(13) Uani 1 1 d . . . . .
H81A H 0.0059 0.2678 0.9088 0.031 Uiso 1 1 calc R . . . .
H81B H -0.0471 0.3263 0.8667 0.031 Uiso 1 1 calc R . . . .
C82 C 0.1697(6) 0.2964(3) 0.8458(2) 0.0276(13) Uani 1 1 d . . . . .
H82A H 0.2315 0.2570 0.8564 0.033 Uiso 1 1 calc R . . . .
H82B H 0.1790 0.3020 0.8062 0.033 Uiso 1 1 calc R . . . .
C83 C 0.2098(7) 0.4182(3) 0.8360(2) 0.0310(14) Uani 1 1 d . . . . .
C84 C 0.2723(7) 0.4587(3) 0.8643(2) 0.0310(14) Uani 1 1 d . . . . .
C85 C 0.2811(9) 0.5264(4) 0.8478(3) 0.0441(18) Uani 1 1 d . . . . .
H85 H 0.3239 0.5543 0.8670 0.053 Uiso 1 1 calc R . . . .
C86 C 0.2247(10) 0.5507(4) 0.8023(3) 0.058(2) Uani 1 1 d . . . . .
H86 H 0.2313 0.5964 0.7891 0.070 Uiso 1 1 calc R . . . .
C87 C 0.1577(10) 0.5099(4) 0.7747(3) 0.056(2) Uani 1 1 d . . . . .
H87 H 0.1166 0.5293 0.7443 0.068 Uiso 1 1 calc R . . . .
C88 C 0.1493(8) 0.4432(4) 0.7900(3) 0.0423(17) Uani 1 1 d . . . . .
H88 H 0.1055 0.4156 0.7708 0.051 Uiso 1 1 calc R . . . .
C89 C 0.2875(6) 0.3537(3) 0.9059(2) 0.0263(13) Uani 1 1 d . . . . .
C90 C 0.3939(7) 0.4390(4) 0.9472(3) 0.0347(15) Uani 1 1 d . . . . .
H90A H 0.4719 0.4680 0.9288 0.042 Uiso 1 1 calc R . . . .
H90B H 0.4392 0.3999 0.9667 0.042 Uiso 1 1 calc R . . . .
C91 C 0.2910(7) 0.4762(4) 0.9869(3) 0.0365(15) Uani 1 1 d . . . . .
C92 C 0.1824(10) 0.4443(5) 1.0225(3) 0.062(2) Uani 1 1 d . . . . .
H92 H 0.1721 0.3984 1.0222 0.075 Uiso 1 1 calc R . . . .
C93 C 0.0885(11) 0.4790(6) 1.0588(4) 0.079(3) Uani 1 1 d . . . . .
H93 H 0.0150 0.4566 1.0835 0.095 Uiso 1 1 calc R . . . .
C94 C 0.1004(11) 0.5440(6) 1.0593(4) 0.076(3) Uani 1 1 d . . . . .
H94 H 0.0338 0.5671 1.0839 0.092 Uiso 1 1 calc R . . . .
C95 C 0.2071(11) 0.5779(5) 1.0250(4) 0.065(3) Uani 1 1 d . . . . .
H95 H 0.2162 0.6237 1.0261 0.078 Uiso 1 1 calc R . . . .
C96 C 0.3020(9) 0.5429(4) 0.9883(3) 0.0492(19) Uani 1 1 d . . . . .
H96 H 0.3756 0.5657 0.9640 0.059 Uiso 1 1 calc R . . . .
P1 P 0.8668(2) 0.94238(10) 0.09156(7) 0.0388(4) Uani 1 1 d . U . . .
F1 F 0.9685(7) 0.9311(3) 0.1368(2) 0.0783(17) Uani 1 1 d . . . . .
F2 F 0.8802(5) 1.0205(2) 0.0898(2) 0.0608(13) Uani 1 1 d . . . . .
F3 F 0.7676(7) 0.9537(3) 0.0471(2) 0.0793(17) Uani 1 1 d . . . . .
F4 F 0.8485(7) 0.8646(2) 0.0947(2) 0.0710(15) Uani 1 1 d . . . . .
F5 F 0.7277(6) 0.9492(3) 0.1358(2) 0.0827(14) Uani 1 1 d . U . . .
F6 F 1.0049(6) 0.9381(3) 0.0483(2) 0.0807(17) Uani 1 1 d . . . . .
P2 P 0.6008(6) 0.2788(3) 0.3156(2) 0.0781(12) Uani 0.496(3) 1 d D . P C 1
F7 F 0.7425(10) 0.3071(7) 0.2795(5) 0.149(5) Uani 0.496(3) 1 d D . P C 1
F8 F 0.5051(13) 0.3208(8) 0.2772(5) 0.186(7) Uani 0.496(3) 1 d D . P C 1
F9 F 0.4625(10) 0.2499(6) 0.3530(4) 0.112(3) Uani 0.496(3) 1 d D . P C 1
F10 F 0.6990(13) 0.2379(9) 0.3550(5) 0.246(11) Uani 0.496(3) 1 d D . P C 1
F11 F 0.6138(17) 0.2195(6) 0.2814(5) 0.180(7) Uani 0.496(3) 1 d D . P C 1
F12 F 0.5917(17) 0.3393(7) 0.3501(6) 0.253(11) Uani 0.496(3) 1 d D . P C 1
P2' P 0.5082(6) 0.1803(3) 0.4820(2) 0.0781(12) Uani 0.504(3) 1 d D . P C 2
F7' F 0.5187(15) 0.1071(5) 0.4682(5) 0.149(5) Uani 0.504(3) 1 d D . P C 2
F8' F 0.5325(17) 0.1524(7) 0.5411(4) 0.186(7) Uani 0.504(3) 1 d D . P C 2
F9' F 0.5038(13) 0.2530(4) 0.4958(5) 0.112(3) Uani 0.504(3) 1 d D . P C 2
F10' F 0.4877(18) 0.2069(8) 0.4224(4) 0.246(11) Uani 0.504(3) 1 d D . P C 2
F11' F 0.3407(9) 0.1762(7) 0.4992(5) 0.180(7) Uani 0.504(3) 1 d D . P C 2
F12' F 0.6799(9) 0.1833(8) 0.4645(7) 0.253(11) Uani 0.504(3) 1 d D . P C 2
Cl1 Cl 0.5713(10) 0.6607(5) 0.8984(4) 0.105(3) Uani 0.35 1 d D U P . .
Cl2 Cl 0.8828(11) 0.6709(7) 0.8133(5) 0.126(3) Uani 0.35 1 d D U P . .
C99 C 0.6138(18) 0.7227(12) 0.8446(10) 0.112(3) Uani 0.35 1 d D U P . .
H99A H 0.5835 0.7092 0.8124 0.134 Uiso 0.35 1 calc R . P . .
H99B H 0.5563 0.7639 0.8531 0.134 Uiso 0.35 1 calc R . P . .
C100 C 0.763(2) 0.7370(7) 0.8318(12) 0.121(3) Uani 0.35 1 d D U P . .
H10A H 0.7912 0.7529 0.8634 0.145 Uiso 0.35 1 calc R . P . .
H10B H 0.7739 0.7737 0.8021 0.145 Uiso 0.35 1 calc R . P . .
C97 C 0.126(2) 0.1077(10) 0.2779(8) 0.075(5) Uani 0.5 1 d D U P . .
C98 C 0.000(2) 0.1514(11) 0.2663(9) 0.088(7) Uani 0.5 1 d D U P . .
H98A H -0.0856 0.1383 0.2922 0.133 Uiso 0.5 1 calc GR . P . .
H98B H -0.0162 0.1478 0.2298 0.133 Uiso 0.5 1 calc GR . P . .
H98C H 0.0196 0.1973 0.2690 0.133 Uiso 0.5 1 calc GR . P . .
N9 N 0.216(2) 0.0730(11) 0.2893(8) 0.099(6) Uani 0.5 1 d D U P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C41 2.101(6) . ?
Ag1 C89 2.090(6) . ?
Ag2 C14 2.285(12) . ?
Ag2 C62 1.904(11) . ?
Ag2' C14 1.824(11) . ?
Ag2' C62 2.422(12) . ?
O1 C17 1.504(8) . ?
O1 C17' 1.426(9) . ?
O1 C18 1.358(8) . ?
O2 C30 1.220(9) . ?
O3 C23 1.232(8) . ?
O4 C21 1.349(7) . ?
O4 C32 1.444(8) . ?
O5 C65 1.438(13) . ?
O5 C66 1.354(10) . ?
O6 C78 1.222(11) . ?
O7 C71 1.228(9) . ?
O8 C69 1.352(8) . ?
O8 C80 1.451(8) . ?
N1 C7 1.472(11) . ?
N1 C8 1.346(12) . ?
N1 C14 1.353(12) . ?
N2 C9 1.425(14) . ?
N2 C14 1.360(13) . ?
N2 C15 1.498(9) . ?
N2 C15' 1.483(9) . ?
N3 C34 1.474(8) . ?
N3 C35 1.384(8) . ?
N3 C41 1.354(7) . ?
N4 C36 1.404(8) . ?
N4 C41 1.338(8) . ?
N4 C42 1.462(8) . ?
N5 C55 1.490(13) . ?
N5 C56 1.412(14) . ?
N5 C62 1.286(14) . ?
N6 C57 1.366(15) . ?
N6 C62 1.398(13) . ?
N6 C63 1.421(15) . ?
N7 C82 1.458(8) . ?
N7 C83 1.387(8) . ?
N7 C89 1.350(8) . ?
N8 C84 1.397(8) . ?
N8 C89 1.351(8) . ?
N8 C90 1.470(8) . ?
C1 C2 1.3900 . ?
C1 C6 1.3900 . ?
C1 C7 1.438(11) . ?
C2 H2 0.9500 . ?
C2 C3 1.3900 . ?
C3 H3 0.9500 . ?
C3 C4 1.3900 . ?
C4 H4 0.9500 . ?
C4 C5 1.3900 . ?
C5 H5 0.9500 . ?
C5 C6 1.3900 . ?
C6 H6 0.9500 . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C8 C9 1.390(12) . ?
C8 C13 1.389(14) . ?
C9 C10 1.350(14) . ?
C10 H10 0.9500 . ?
C10 C11 1.397(15) . ?
C11 H11 0.9500 . ?
C11 C12 1.419(14) . ?
C12 H12 0.9500 . ?
C12 C13 1.365(17) . ?
C13 H13 0.9500 . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?
C15 C16 1.507(9) . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C16 C17 1.514(8) . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C15' H15C 0.9900 . ?
C15' H15D 0.9900 . ?
C15' C16' 1.511(9) . ?
C16' H16C 0.9900 . ?
C16' H16D 0.9900 . ?
C16' C17' 1.511(10) . ?
C17' H17C 0.9900 . ?
C17' H17D 0.9900 . ?
C18 C19 1.384(10) . ?
C18 C31 1.406(10) . ?
C19 H19 0.9500 . ?
C19 C20 1.383(10) . ?
C20 H20 0.9500 . ?
C20 C21 1.386(10) . ?
C21 C22 1.414(9) . ?
C22 C23 1.491(10) . ?
C22 C31 1.417(9) . ?
C23 C24 1.471(9) . ?
C24 C25 1.407(10) . ?
C24 C29 1.385(10) . ?
C25 H25 0.9500 . ?
C25 C26 1.397(12) . ?
C26 H26 0.9500 . ?
C26 C27 1.378(14) . ?
C27 H27 0.9500 . ?
C27 C28 1.357(13) . ?
C28 H28 0.9500 . ?
C28 C29 1.390(10) . ?
C29 C30 1.483(11) . ?
C30 C31 1.488(10) . ?
C32 H32A 0.9900 . ?
C32 H32B 0.9900 . ?
C32 C33 1.498(10) . ?
C33 H33A 0.9900 . ?
C33 H33B 0.9900 . ?
C33 C34 1.519(10) . ?
C34 H34A 0.9900 . ?
C34 H34B 0.9900 . ?
C35 C36 1.375(9) . ?
C35 C40 1.401(9) . ?
C36 C37 1.386(10) . ?
C37 H37 0.9500 . ?
C37 C38 1.382(10) . ?
C38 H38 0.9500 . ?
C38 C39 1.392(11) . ?
C39 H39 0.9500 . ?
C39 C40 1.377(11) . ?
C40 H40 0.9500 . ?
C42 H42A 0.9900 . ?
C42 H42B 0.9900 . ?
C42 C43 1.516(9) . ?
C43 C44 1.359(10) . ?
C43 C48 1.387(10) . ?
C44 H44 0.9500 . ?
C44 C45 1.402(11) . ?
C45 H45 0.9500 . ?
C45 C46 1.366(12) . ?
C46 H46 0.9500 . ?
C46 C47 1.388(13) . ?
C47 H47 0.9500 . ?
C47 C48 1.396(12) . ?
C48 H48 0.9500 . ?
C49 C50 1.360(16) . ?
C49 C54 1.374(17) . ?
C49 C55 1.522(13) . ?
C50 H50 0.9500 . ?
C50 C51 1.398(12) . ?
C51 H51 0.9500 . ?
C51 C52 1.364(15) . ?
C52 H52 0.9500 . ?
C52 C53 1.371(15) . ?
C53 H53 0.9500 . ?
C53 C54 1.402(15) . ?
C54 H54 0.9500 . ?
C55 H55A 0.9900 . ?
C55 H55B 0.9900 . ?
C56 C57 1.384(17) . ?
C56 C61 1.341(18) . ?
C57 C58 1.419(15) . ?
C58 H58 0.9500 . ?
C58 C59 1.299(18) . ?
C59 H59 0.9500 . ?
C59 C60 1.37(2) . ?
C60 H60 0.9500 . ?
C60 C61 1.404(18) . ?
C61 H61 0.9500 . ?
C63 H63A 0.9900 . ?
C63 H63B 0.9900 . ?
C63 C64 1.566(14) . ?
C64 H64A 0.9900 . ?
C64 H64B 0.9900 . ?
C64 C65 1.517(13) . ?
C65 H65A 0.9900 . ?
C65 H65B 0.9900 . ?
C66 C67 1.411(13) . ?
C66 C79 1.397(13) . ?
C67 H67 0.9500 . ?
C67 C68 1.401(11) . ?
C68 H68 0.9500 . ?
C68 C69 1.376(11) . ?
C69 C70 1.407(10) . ?
C70 C71 1.479(11) . ?
C70 C79 1.416(11) . ?
C71 C72 1.494(11) . ?
C72 C73 1.409(14) . ?
C72 C77 1.386(13) . ?
C73 H73 0.9500 . ?
C73 C74 1.387(14) . ?
C74 H74 0.9500 . ?
C74 C75 1.354(18) . ?
C75 H75 0.9500 . ?
C75 C76 1.353(17) . ?
C76 H76 0.9500 . ?
C76 C77 1.439(13) . ?
C77 C78 1.447(14) . ?
C78 C79 1.493(12) . ?
C80 H80A 0.9900 . ?
C80 H80B 0.9900 . ?
C80 C81 1.504(9) . ?
C81 H81A 0.9900 . ?
C81 H81B 0.9900 . ?
C81 C82 1.522(8) . ?
C82 H82A 0.9900 . ?
C82 H82B 0.9900 . ?
C83 C84 1.387(10) . ?
C83 C88 1.408(9) . ?
C84 C85 1.394(10) . ?
C85 H85 0.9500 . ?
C85 C86 1.373(11) . ?
C86 H86 0.9500 . ?
C86 C87 1.403(13) . ?
C87 H87 0.9500 . ?
C87 C88 1.368(11) . ?
C88 H88 0.9500 . ?
C90 H90A 0.9900 . ?
C90 H90B 0.9900 . ?
C90 C91 1.510(9) . ?
C91 C92 1.382(11) . ?
C91 C96 1.380(11) . ?
C92 H92 0.9500 . ?
C92 C93 1.388(12) . ?
C93 H93 0.9500 . ?
C93 C94 1.339(15) . ?
C94 H94 0.9500 . ?
C94 C95 1.374(15) . ?
C95 H95 0.9500 . ?
C95 C96 1.400(11) . ?
C96 H96 0.9500 . ?
P1 F1 1.602(5) . ?
P1 F2 1.602(5) . ?
P1 F3 1.569(5) . ?
P1 F4 1.598(5) . ?
P1 F5 1.580(5) . ?
P1 F6 1.554(5) . ?
P2 F7 1.582(8) . ?
P2 F8 1.569(7) . ?
P2 F9 1.574(7) . ?
P2 F10 1.590(8) . ?
P2 F11 1.567(8) . ?
P2 F12 1.595(8) . ?
P2' F7' 1.570(8) . ?
P2' F8' 1.586(7) . ?
P2' F9' 1.565(7) . ?
P2' F10' 1.580(7) . ?
P2' F11' 1.562(8) . ?
P2' F12' 1.600(8) . ?
Cl1 C99 1.750(10) . ?
Cl2 C100 1.749(10) . ?
C99 H99A 0.9900 . ?
C99 H99B 0.9900 . ?
C99 C100 1.423(10) . ?
C100 H10A 0.9900 . ?
C100 H10B 0.9900 . ?
C97 C98 1.466(8) . ?
C97 N9 1.113(8) . ?
C98 H98A 0.9800 . ?
C98 H98B 0.9800 . ?
C98 H98C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C89 Ag1 C41 174.5(2) . . ?
C62 Ag2 C14 167.5(4) . . ?
C14 Ag2' C62 157.3(5) . . ?
C18 O1 C17 112.6(6) . . ?
C18 O1 C17' 128.0(7) . . ?
C21 O4 C32 119.7(5) . . ?
C66 O5 C65 118.8(8) . . ?
C69 O8 C80 118.2(5) . . ?
C8 N1 C7 126.9(9) . . ?
C8 N1 C14 111.9(8) . . ?
C14 N1 C7 121.1(10) . . ?
C9 N2 C15 128.2(10) . . ?
C9 N2 C15' 106.8(10) . . ?
C14 N2 C9 108.5(8) . . ?
C14 N2 C15 122.9(11) . . ?
C14 N2 C15' 125.7(10) . . ?
C35 N3 C34 124.4(5) . . ?
C41 N3 C34 125.1(5) . . ?
C41 N3 C35 110.1(5) . . ?
C36 N4 C42 124.2(5) . . ?
C41 N4 C36 110.3(5) . . ?
C41 N4 C42 125.6(5) . . ?
C56 N5 C55 122.2(11) . . ?
C62 N5 C55 123.2(10) . . ?
C62 N5 C56 114.1(10) . . ?
C57 N6 C63 126.3(10) . . ?
C62 N6 C57 108.4(10) . . ?
C62 N6 C63 125.0(10) . . ?
C83 N7 C82 124.1(5) . . ?
C89 N7 C82 124.6(5) . . ?
C89 N7 C83 111.3(5) . . ?
C84 N8 C90 124.6(5) . . ?
C89 N8 C84 110.8(5) . . ?
C89 N8 C90 124.5(5) . . ?
C2 C1 C6 120.0 . . ?
C2 C1 C7 117.4(6) . . ?
C6 C1 C7 122.5(6) . . ?
C1 C2 H2 120.0 . . ?
C1 C2 C3 120.0 . . ?
C3 C2 H2 120.0 . . ?
C2 C3 H3 120.0 . . ?
C4 C3 C2 120.0 . . ?
C4 C3 H3 120.0 . . ?
C3 C4 H4 120.0 . . ?
C3 C4 C5 120.0 . . ?
C5 C4 H4 120.0 . . ?
C4 C5 H5 120.0 . . ?
C6 C5 C4 120.0 . . ?
C6 C5 H5 120.0 . . ?
C1 C6 H6 120.0 . . ?
C5 C6 C1 120.0 . . ?
C5 C6 H6 120.0 . . ?
N1 C7 H7A 107.7 . . ?
N1 C7 H7B 107.7 . . ?
C1 C7 N1 118.2(9) . . ?
C1 C7 H7A 107.7 . . ?
C1 C7 H7B 107.7 . . ?
H7A C7 H7B 107.1 . . ?
N1 C8 C9 107.2(8) . . ?
N1 C8 C13 134.0(9) . . ?
C13 C8 C9 118.8(11) . . ?
C8 C9 N2 105.6(9) . . ?
C10 C9 N2 130.6(9) . . ?
C10 C9 C8 123.8(10) . . ?
C9 C10 H10 120.9 . . ?
C9 C10 C11 118.2(10) . . ?
C11 C10 H10 120.9 . . ?
C10 C11 H11 120.8 . . ?
C10 C11 C12 118.4(12) . . ?
C12 C11 H11 120.8 . . ?
C11 C12 H12 118.9 . . ?
C13 C12 C11 122.2(12) . . ?
C13 C12 H12 118.9 . . ?
C8 C13 H13 120.7 . . ?
C12 C13 C8 118.5(10) . . ?
C12 C13 H13 120.7 . . ?
N1 C14 Ag2 132.0(7) . . ?
N1 C14 Ag2' 124.5(8) . . ?
N1 C14 N2 106.5(9) . . ?
N2 C14 Ag2 121.0(8) . . ?
N2 C14 Ag2' 127.7(8) . . ?
N2 C15 H15A 110.3 . . ?
N2 C15 H15B 110.3 . . ?
N2 C15 C16 107.0(8) . . ?
H15A C15 H15B 108.6 . . ?
C16 C15 H15A 110.3 . . ?
C16 C15 H15B 110.3 . . ?
C15 C16 H16A 108.7 . . ?
C15 C16 H16B 108.7 . . ?
C15 C16 C17 114.2(8) . . ?
H16A C16 H16B 107.6 . . ?
C17 C16 H16A 108.7 . . ?
C17 C16 H16B 108.7 . . ?
O1 C17 C16 106.5(7) . . ?
O1 C17 H17A 110.4 . . ?
O1 C17 H17B 110.4 . . ?
C16 C17 H17A 110.4 . . ?
C16 C17 H17B 110.4 . . ?
H17A C17 H17B 108.6 . . ?
N2 C15' H15C 113.7 . . ?
N2 C15' H15D 113.7 . . ?
N2 C15' C16' 89.5(8) . . ?
H15C C15' H15D 111.0 . . ?
C16' C15' H15C 113.7 . . ?
C16' C15' H15D 113.7 . . ?
C15' C16' H16C 109.3 . . ?
C15' C16' H16D 109.3 . . ?
H16C C16' H16D 107.9 . . ?
C17' C16' C15' 111.7(13) . . ?
C17' C16' H16C 109.3 . . ?
C17' C16' H16D 109.3 . . ?
O1 C17' C16' 110.4(12) . . ?
O1 C17' H17C 109.6 . . ?
O1 C17' H17D 109.6 . . ?
C16' C17' H17C 109.6 . . ?
C16' C17' H17D 109.6 . . ?
H17C C17' H17D 108.1 . . ?
O1 C18 C19 121.7(7) . . ?
O1 C18 C31 118.4(6) . . ?
C19 C18 C31 119.9(6) . . ?
C18 C19 H19 119.4 . . ?
C20 C19 C18 121.2(7) . . ?
C20 C19 H19 119.4 . . ?
C19 C20 H20 119.8 . . ?
C19 C20 C21 120.3(6) . . ?
C21 C20 H20 119.8 . . ?
O4 C21 C20 121.9(6) . . ?
O4 C21 C22 118.2(6) . . ?
C20 C21 C22 119.9(6) . . ?
C21 C22 C23 120.9(6) . . ?
C21 C22 C31 119.5(6) . . ?
C31 C22 C23 119.6(6) . . ?
O3 C23 C22 121.8(6) . . ?
O3 C23 C24 119.6(6) . . ?
C24 C23 C22 118.5(6) . . ?
C25 C24 C23 119.2(7) . . ?
C29 C24 C23 121.7(6) . . ?
C29 C24 C25 119.1(7) . . ?
C24 C25 H25 120.4 . . ?
C26 C25 C24 119.2(8) . . ?
C26 C25 H25 120.4 . . ?
C25 C26 H26 119.8 . . ?
C27 C26 C25 120.4(8) . . ?
C27 C26 H26 119.8 . . ?
C26 C27 H27 119.8 . . ?
C28 C27 C26 120.3(8) . . ?
C28 C27 H27 119.8 . . ?
C27 C28 H28 119.7 . . ?
C27 C28 C29 120.7(8) . . ?
C29 C28 H28 119.7 . . ?
C24 C29 C28 120.3(7) . . ?
C24 C29 C30 120.5(6) . . ?
C28 C29 C30 119.2(7) . . ?
O2 C30 C29 119.6(7) . . ?
O2 C30 C31 122.1(7) . . ?
C29 C30 C31 118.3(6) . . ?
C18 C31 C22 119.2(6) . . ?
C18 C31 C30 120.0(6) . . ?
C22 C31 C30 120.6(6) . . ?
O4 C32 H32A 110.5 . . ?
O4 C32 H32B 110.5 . . ?
O4 C32 C33 106.1(6) . . ?
H32A C32 H32B 108.7 . . ?
C33 C32 H32A 110.5 . . ?
C33 C32 H32B 110.5 . . ?
C32 C33 H33A 109.0 . . ?
C32 C33 H33B 109.0 . . ?
C32 C33 C34 112.8(5) . . ?
H33A C33 H33B 107.8 . . ?
C34 C33 H33A 109.0 . . ?
C34 C33 H33B 109.0 . . ?
N3 C34 C33 111.5(6) . . ?
N3 C34 H34A 109.3 . . ?
N3 C34 H34B 109.3 . . ?
C33 C34 H34A 109.3 . . ?
C33 C34 H34B 109.3 . . ?
H34A C34 H34B 108.0 . . ?
N3 C35 C40 131.8(6) . . ?
C36 C35 N3 106.9(5) . . ?
C36 C35 C40 121.3(6) . . ?
C35 C36 N4 105.9(6) . . ?
C35 C36 C37 122.7(6) . . ?
C37 C36 N4 131.4(6) . . ?
C36 C37 H37 122.1 . . ?
C38 C37 C36 115.9(7) . . ?
C38 C37 H37 122.1 . . ?
C37 C38 H38 119.1 . . ?
C37 C38 C39 121.9(7) . . ?
C39 C38 H38 119.1 . . ?
C38 C39 H39 119.0 . . ?
C40 C39 C38 122.1(6) . . ?
C40 C39 H39 119.0 . . ?
C35 C40 H40 121.9 . . ?
C39 C40 C35 116.1(7) . . ?
C39 C40 H40 121.9 . . ?
N3 C41 Ag1 126.6(5) . . ?
N4 C41 Ag1 126.5(4) . . ?
N4 C41 N3 106.8(5) . . ?
N4 C42 H42A 109.1 . . ?
N4 C42 H42B 109.1 . . ?
N4 C42 C43 112.7(5) . . ?
H42A C42 H42B 107.8 . . ?
C43 C42 H42A 109.1 . . ?
C43 C42 H42B 109.1 . . ?
C44 C43 C42 121.9(6) . . ?
C44 C43 C48 119.0(7) . . ?
C48 C43 C42 119.1(6) . . ?
C43 C44 H44 119.0 . . ?
C43 C44 C45 122.1(7) . . ?
C45 C44 H44 119.0 . . ?
C44 C45 H45 120.6 . . ?
C46 C45 C44 118.8(8) . . ?
C46 C45 H45 120.6 . . ?
C45 C46 H46 120.0 . . ?
C45 C46 C47 120.0(8) . . ?
C47 C46 H46 120.0 . . ?
C46 C47 H47 119.9 . . ?
C46 C47 C48 120.2(8) . . ?
C48 C47 H47 119.9 . . ?
C43 C48 C47 119.7(8) . . ?
C43 C48 H48 120.1 . . ?
C47 C48 H48 120.1 . . ?
C50 C49 C54 118.9(9) . . ?
C50 C49 C55 121.8(12) . . ?
C54 C49 C55 119.3(11) . . ?
C49 C50 H50 119.4 . . ?
C49 C50 C51 121.2(11) . . ?
C51 C50 H50 119.4 . . ?
C50 C51 H51 120.2 . . ?
C52 C51 C50 119.7(10) . . ?
C52 C51 H51 120.2 . . ?
C51 C52 H52 120.0 . . ?
C53 C52 C51 120.1(9) . . ?
C53 C52 H52 120.0 . . ?
C52 C53 H53 120.2 . . ?
C52 C53 C54 119.5(12) . . ?
C54 C53 H53 120.2 . . ?
C49 C54 C53 120.6(11) . . ?
C49 C54 H54 119.7 . . ?
C53 C54 H54 119.7 . . ?
N5 C55 C49 111.2(9) . . ?
N5 C55 H55A 109.4 . . ?
N5 C55 H55B 109.4 . . ?
C49 C55 H55A 109.4 . . ?
C49 C55 H55B 109.4 . . ?
H55A C55 H55B 108.0 . . ?
C57 C56 N5 102.4(12) . . ?
C61 C56 N5 132.4(12) . . ?
C61 C56 C57 125.2(12) . . ?
N6 C57 C58 132.1(13) . . ?
C56 C57 N6 109.3(11) . . ?
C56 C57 C58 118.6(13) . . ?
C57 C58 H58 121.6 . . ?
C59 C58 C57 116.7(14) . . ?
C59 C58 H58 121.6 . . ?
C58 C59 H59 117.9 . . ?
C58 C59 C60 124.1(14) . . ?
C60 C59 H59 117.9 . . ?
C59 C60 H60 119.2 . . ?
C59 C60 C61 121.5(17) . . ?
C61 C60 H60 119.2 . . ?
C56 C61 C60 113.9(15) . . ?
C56 C61 H61 123.1 . . ?
C60 C61 H61 123.1 . . ?
N5 C62 Ag2 122.4(8) . . ?
N5 C62 Ag2' 134.8(8) . . ?
N5 C62 N6 105.7(10) . . ?
N6 C62 Ag2 131.4(10) . . ?
N6 C62 Ag2' 119.3(9) . . ?
N6 C63 H63A 109.0 . . ?
N6 C63 H63B 109.0 . . ?
N6 C63 C64 112.7(10) . . ?
H63A C63 H63B 107.8 . . ?
C64 C63 H63A 109.0 . . ?
C64 C63 H63B 109.0 . . ?
C63 C64 H64A 109.2 . . ?
C63 C64 H64B 109.2 . . ?
H64A C64 H64B 107.9 . . ?
C65 C64 C63 111.9(9) . . ?
C65 C64 H64A 109.2 . . ?
C65 C64 H64B 109.2 . . ?
O5 C65 C64 106.1(9) . . ?
O5 C65 H65A 110.5 . . ?
O5 C65 H65B 110.5 . . ?
C64 C65 H65A 110.5 . . ?
C64 C65 H65B 110.5 . . ?
H65A C65 H65B 108.7 . . ?
O5 C66 C67 121.3(9) . . ?
O5 C66 C79 118.8(8) . . ?
C79 C66 C67 119.9(8) . . ?
C66 C67 H67 119.6 . . ?
C68 C67 C66 120.7(9) . . ?
C68 C67 H67 119.6 . . ?
C67 C68 H68 120.3 . . ?
C69 C68 C67 119.5(8) . . ?
C69 C68 H68 120.3 . . ?
O8 C69 C68 122.1(6) . . ?
O8 C69 C70 117.4(7) . . ?
C68 C69 C70 120.5(7) . . ?
C69 C70 C71 121.0(7) . . ?
C69 C70 C79 120.4(7) . . ?
C79 C70 C71 118.6(7) . . ?
O7 C71 C70 122.3(7) . . ?
O7 C71 C72 119.6(8) . . ?
C70 C71 C72 118.1(7) . . ?
C73 C72 C71 119.2(8) . . ?
C77 C72 C71 120.1(9) . . ?
C77 C72 C73 120.7(8) . . ?
C72 C73 H73 120.5 . . ?
C74 C73 C72 119.1(11) . . ?
C74 C73 H73 120.5 . . ?
C73 C74 H74 119.6 . . ?
C75 C74 C73 120.9(13) . . ?
C75 C74 H74 119.6 . . ?
C74 C75 H75 119.4 . . ?
C74 C75 C76 121.1(11) . . ?
C76 C75 H75 119.4 . . ?
C75 C76 H76 119.6 . . ?
C75 C76 C77 120.8(11) . . ?
C77 C76 H76 119.6 . . ?
C72 C77 C76 117.2(10) . . ?
C72 C77 C78 121.3(8) . . ?
C76 C77 C78 121.5(9) . . ?
O6 C78 C77 120.1(9) . . ?
O6 C78 C79 121.5(10) . . ?
C77 C78 C79 118.3(8) . . ?
C66 C79 C70 118.7(8) . . ?
C66 C79 C78 120.8(8) . . ?
C70 C79 C78 120.4(8) . . ?
O8 C80 H80A 110.7 . . ?
O8 C80 H80B 110.7 . . ?
O8 C80 C81 105.2(5) . . ?
H80A C80 H80B 108.8 . . ?
C81 C80 H80A 110.7 . . ?
C81 C80 H80B 110.7 . . ?
C80 C81 H81A 109.7 . . ?
C80 C81 H81B 109.7 . . ?
C80 C81 C82 110.0(5) . . ?
H81A C81 H81B 108.2 . . ?
C82 C81 H81A 109.7 . . ?
C82 C81 H81B 109.7 . . ?
N7 C82 C81 113.3(5) . . ?
N7 C82 H82A 108.9 . . ?
N7 C82 H82B 108.9 . . ?
C81 C82 H82A 108.9 . . ?
C81 C82 H82B 108.9 . . ?
H82A C82 H82B 107.7 . . ?
N7 C83 C88 131.7(7) . . ?
C84 C83 N7 106.1(5) . . ?
C84 C83 C88 122.1(6) . . ?
C83 C84 N8 105.9(5) . . ?
C83 C84 C85 121.3(6) . . ?
C85 C84 N8 132.8(7) . . ?
C84 C85 H85 121.7 . . ?
C86 C85 C84 116.7(7) . . ?
C86 C85 H85 121.7 . . ?
C85 C86 H86 119.1 . . ?
C85 C86 C87 121.8(7) . . ?
C87 C86 H86 119.1 . . ?
C86 C87 H87 118.8 . . ?
C88 C87 C86 122.4(7) . . ?
C88 C87 H87 118.8 . . ?
C83 C88 H88 122.2 . . ?
C87 C88 C83 115.6(7) . . ?
C87 C88 H88 122.2 . . ?
N7 C89 Ag1 126.1(5) . . ?
N7 C89 N8 105.8(5) . . ?
N8 C89 Ag1 128.0(4) . . ?
N8 C90 H90A 109.2 . . ?
N8 C90 H90B 109.2 . . ?
N8 C90 C91 111.9(5) . . ?
H90A C90 H90B 107.9 . . ?
C91 C90 H90A 109.2 . . ?
C91 C90 H90B 109.2 . . ?
C92 C91 C90 120.9(7) . . ?
C96 C91 C90 121.0(7) . . ?
C96 C91 C92 118.1(7) . . ?
C91 C92 H92 119.8 . . ?
C91 C92 C93 120.4(9) . . ?
C93 C92 H92 119.8 . . ?
C92 C93 H93 119.7 . . ?
C94 C93 C92 120.6(10) . . ?
C94 C93 H93 119.7 . . ?
C93 C94 H94 119.3 . . ?
C93 C94 C95 121.4(9) . . ?
C95 C94 H94 119.3 . . ?
C94 C95 H95 120.9 . . ?
C94 C95 C96 118.2(9) . . ?
C96 C95 H95 120.9 . . ?
C91 C96 C95 121.4(8) . . ?
C91 C96 H96 119.3 . . ?
C95 C96 H96 119.3 . . ?
F1 P1 F2 88.3(3) . . ?
F3 P1 F1 179.8(4) . . ?
F3 P1 F2 91.6(3) . . ?
F3 P1 F4 88.2(3) . . ?
F3 P1 F5 89.4(4) . . ?
F4 P1 F1 91.9(3) . . ?
F4 P1 F2 178.1(3) . . ?
F5 P1 F1 90.8(4) . . ?
F5 P1 F2 87.3(3) . . ?
F5 P1 F4 90.8(3) . . ?
F6 P1 F1 88.8(4) . . ?
F6 P1 F2 90.8(3) . . ?
F6 P1 F3 91.1(4) . . ?
F6 P1 F4 91.1(3) . . ?
F6 P1 F5 178.1(3) . . ?
F7 P2 F10 89.1(5) . . ?
F7 P2 F12 89.0(5) . . ?
F8 P2 F7 90.3(5) . . ?
F8 P2 F9 91.3(5) . . ?
F8 P2 F10 178.5(7) . . ?
F8 P2 F12 89.9(5) . . ?
F9 P2 F7 178.4(6) . . ?
F9 P2 F10 89.3(5) . . ?
F9 P2 F12 90.6(5) . . ?
F10 P2 F12 88.6(5) . . ?
F11 P2 F7 89.8(5) . . ?
F11 P2 F8 90.7(5) . . ?
F11 P2 F9 90.6(5) . . ?
F11 P2 F10 90.8(5) . . ?
F11 P2 F12 178.6(6) . . ?
F7' P2' F8' 88.7(5) . . ?
F7' P2' F10' 90.2(5) . . ?
F7' P2' F12' 89.6(5) . . ?
F8' P2' F12' 89.0(5) . . ?
F9' P2' F7' 177.9(6) . . ?
F9' P2' F8' 90.5(5) . . ?
F9' P2' F10' 90.5(5) . . ?
F9' P2' F12' 88.4(5) . . ?
F10' P2' F8' 178.4(7) . . ?
F10' P2' F12' 89.7(5) . . ?
F11' P2' F7' 89.6(5) . . ?
F11' P2' F8' 90.6(5) . . ?
F11' P2' F9' 92.4(5) . . ?
F11' P2' F10' 90.6(5) . . ?
F11' P2' F12' 179.2(7) . . ?
Cl1 C99 H99A 108.5 . . ?
Cl1 C99 H99B 108.5 . . ?
H99A C99 H99B 107.5 . . ?
C100 C99 Cl1 115.1(10) . . ?
C100 C99 H99A 108.5 . . ?
C100 C99 H99B 108.5 . . ?
Cl2 C100 H10A 108.4 . . ?
Cl2 C100 H10B 108.4 . . ?
C99 C100 Cl2 115.7(10) . . ?
C99 C100 H10A 108.4 . . ?
C99 C100 H10B 108.4 . . ?
H10A C100 H10B 107.4 . . ?
N9 C97 C98 176(2) . . ?
C97 C98 H98A 109.5 . . ?
C97 C98 H98B 109.5 . . ?
C97 C98 H98C 109.5 . . ?
H98A C98 H98B 109.5 . . ?
H98A C98 H98C 109.5 . . ?
H98B C98 H98C 109.5 . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
C10 H10 O2 0.95 2.41 3.337(12) 164.8 .
C16' H16C F8' 0.99 2.51 3.14(2) 120.6 .
C16' H16D O6 0.99 2.59 3.427(19) 142.1 1_655
C17' H17D O5 0.99 2.09 3.04(2) 158.2 1_655
C19 H19 F5 0.95 2.53 3.033(10) 113.4 2_666
C37 H37 F2 0.95 2.46 3.373(9) 161.7 1_446
C42 H42A F2 0.99 2.60 3.496(8) 150.6 1_446
C42 H42B F4 0.99 2.57 3.320(8) 132.9 2_666
C55 H55B F7' 0.99 2.36 3.351(17) 174.9 2_656
C58 H58 F7' 0.95 2.61 3.502(18) 156.3 2_556
C61 H61 F10 0.95 2.55 3.22(2) 128.0 2_656
C64 H64A F8' 0.99 2.03 2.745(16) 127.2 1_455
C65 H65B N9 0.99 2.61 3.21(2) 118.6 2_556
C68 H68 F1 0.95 2.59 3.499(10) 160.5 2_666
C80 H80A F1 0.99 2.60 3.377(9) 135.9 2_666
C80 H80A F4 0.99 2.42 3.102(8) 125.3 2_666
C80 H80B O4 0.99 2.43 3.412(8) 169.5 1_455
C88 H88 O7 0.95 2.41 3.346(10) 167.9 .

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 C18 C19 C20 -178.9(6) . . . . ?
O1 C18 C31 C22 178.8(6) . . . . ?
O1 C18 C31 C30 3.1(9) . . . . ?
O2 C30 C31 C18 2.2(10) . . . . ?
O2 C30 C31 C22 -173.5(7) . . . . ?
O3 C23 C24 C25 8.3(9) . . . . ?
O3 C23 C24 C29 -169.4(6) . . . . ?
O4 C21 C22 C23 -0.3(8) . . . . ?
O4 C21 C22 C31 179.5(5) . . . . ?
O4 C32 C33 C34 57.6(7) . . . . ?
O5 C66 C67 C68 -177.8(8) . . . . ?
O5 C66 C79 C70 -178.3(8) . . . . ?
O5 C66 C79 C78 4.4(13) . . . . ?
O6 C78 C79 C66 -9.2(13) . . . . ?
O6 C78 C79 C70 173.6(8) . . . . ?
O7 C71 C72 C73 -11.5(11) . . . . ?
O7 C71 C72 C77 167.6(7) . . . . ?
O8 C69 C70 C71 7.7(9) . . . . ?
O8 C69 C70 C79 -174.5(6) . . . . ?
O8 C80 C81 C82 -75.2(6) . . . . ?
N1 C8 C9 N2 4.6(10) . . . . ?
N1 C8 C9 C10 -177.8(10) . . . . ?
N1 C8 C13 C12 178.4(10) . . . . ?
N2 C9 C10 C11 177.1(11) . . . . ?
N2 C15 C16 C17 -160.4(11) . . . . ?
N2 C15' C16' C17' 177.2(14) . . . . ?
N3 C35 C36 N4 -1.0(7) . . . . ?
N3 C35 C36 C37 179.1(6) . . . . ?
N3 C35 C40 C39 179.9(7) . . . . ?
N4 C36 C37 C38 -178.9(7) . . . . ?
N4 C42 C43 C44 -93.2(8) . . . . ?
N4 C42 C43 C48 88.9(8) . . . . ?
N5 C56 C57 N6 -2.3(10) . . . . ?
N5 C56 C57 C58 178.7(9) . . . . ?
N5 C56 C61 C60 -178.6(11) . . . . ?
N6 C57 C58 C59 -177.2(11) . . . . ?
N6 C63 C64 C65 59.6(14) . . . . ?
N7 C83 C84 N8 -0.2(6) . . . . ?
N7 C83 C84 C85 178.6(6) . . . . ?
N7 C83 C88 C87 -179.2(7) . . . . ?
N8 C84 C85 C86 178.4(7) . . . . ?
N8 C90 C91 C92 67.0(9) . . . . ?
N8 C90 C91 C96 -112.5(7) . . . . ?
C1 C2 C3 C4 0.0 . . . . ?
C2 C1 C6 C5 0.0 . . . . ?
C2 C1 C7 N1 -157.8(8) . . . . ?
C2 C3 C4 C5 0.0 . . . . ?
C3 C4 C5 C6 0.0 . . . . ?
C4 C5 C6 C1 0.0 . . . . ?
C6 C1 C2 C3 0.0 . . . . ?
C6 C1 C7 N1 26.2(15) . . . . ?
C7 N1 C8 C9 174.4(8) . . . . ?
C7 N1 C8 C13 -4.1(16) . . . . ?
C7 N1 C14 Ag2 9.8(14) . . . . ?
C7 N1 C14 Ag2' -10.6(14) . . . . ?
C7 N1 C14 N2 -178.6(8) . . . . ?
C7 C1 C2 C3 -176.1(10) . . . . ?
C7 C1 C6 C5 175.9(10) . . . . ?
C8 N1 C7 C1 63.8(13) . . . . ?
C8 N1 C14 Ag2 -174.0(7) . . . . ?
C8 N1 C14 Ag2' 165.6(8) . . . . ?
C8 N1 C14 N2 -2.5(12) . . . . ?
C8 C9 C10 C11 0.3(16) . . . . ?
C9 N2 C14 Ag2 178.1(7) . . . . ?
C9 N2 C14 Ag2' -162.2(9) . . . . ?
C9 N2 C14 N1 5.4(12) . . . . ?
C9 N2 C15 C16 93.2(15) . . . . ?
C9 N2 C15' C16' -117.9(12) . . . . ?
C9 C8 C13 C12 0.1(15) . . . . ?
C9 C10 C11 C12 -2.3(16) . . . . ?
C10 C11 C12 C13 3.4(17) . . . . ?
C11 C12 C13 C8 -2.3(17) . . . . ?
C13 C8 C9 N2 -176.6(9) . . . . ?
C13 C8 C9 C10 0.9(15) . . . . ?
C14 N1 C7 C1 -120.7(12) . . . . ?
C14 N1 C8 C9 -1.5(11) . . . . ?
C14 N1 C8 C13 -179.9(10) . . . . ?
C14 N2 C9 C8 -6.2(12) . . . . ?
C14 N2 C9 C10 176.5(12) . . . . ?
C14 N2 C15 C16 -94.2(14) . . . . ?
C14 N2 C15' C16' 113.4(15) . . . . ?
C15 N2 C9 C8 167.3(10) . . . . ?
C15 N2 C9 C10 -10.0(19) . . . . ?
C15 N2 C14 Ag2 4.1(15) . . . . ?
C15 N2 C14 N1 -168.6(9) . . . . ?
C15 C16 C17 O1 61.8(14) . . . . ?
C17 O1 C18 C19 23.1(10) . . . . ?
C17 O1 C18 C31 -155.1(7) . . . . ?
C15' N2 C9 C8 -144.2(9) . . . . ?
C15' N2 C9 C10 38.5(16) . . . . ?
C15' N2 C14 Ag2' -34.2(18) . . . . ?
C15' N2 C14 N1 133.3(11) . . . . ?
C15' C16' C17' O1 -59(2) . . . . ?
C17' O1 C18 C19 -24.2(15) . . . . ?
C17' O1 C18 C31 157.6(11) . . . . ?
C18 O1 C17 C16 158.3(7) . . . . ?
C18 O1 C17' C16' -175.0(10) . . . . ?
C18 C19 C20 C21 0.1(10) . . . . ?
C19 C18 C31 C22 0.7(9) . . . . ?
C19 C18 C31 C30 -175.0(6) . . . . ?
C19 C20 C21 O4 -179.6(6) . . . . ?
C19 C20 C21 C22 0.7(9) . . . . ?
C20 C21 C22 C23 179.4(5) . . . . ?
C20 C21 C22 C31 -0.7(8) . . . . ?
C21 O4 C32 C33 -177.3(5) . . . . ?
C21 C22 C23 O3 -6.0(9) . . . . ?
C21 C22 C23 C24 176.1(5) . . . . ?
C21 C22 C31 C18 0.1(8) . . . . ?
C21 C22 C31 C30 175.8(5) . . . . ?
C22 C23 C24 C25 -173.8(6) . . . . ?
C22 C23 C24 C29 8.5(9) . . . . ?
C23 C22 C31 C18 179.9(5) . . . . ?
C23 C22 C31 C30 -4.4(8) . . . . ?
C23 C24 C25 C26 -176.2(7) . . . . ?
C23 C24 C29 C28 174.6(6) . . . . ?
C23 C24 C29 C30 -4.9(10) . . . . ?
C24 C25 C26 C27 1.2(12) . . . . ?
C24 C29 C30 O2 178.1(7) . . . . ?
C24 C29 C30 C31 -3.4(9) . . . . ?
C25 C24 C29 C28 -3.1(10) . . . . ?
C25 C24 C29 C30 177.5(6) . . . . ?
C25 C26 C27 C28 -2.3(14) . . . . ?
C26 C27 C28 C29 0.7(14) . . . . ?
C27 C28 C29 C24 2.1(12) . . . . ?
C27 C28 C29 C30 -178.5(8) . . . . ?
C28 C29 C30 O2 -1.3(11) . . . . ?
C28 C29 C30 C31 177.2(6) . . . . ?
C29 C24 C25 C26 1.5(10) . . . . ?
C29 C30 C31 C18 -176.3(6) . . . . ?
C29 C30 C31 C22 8.0(9) . . . . ?
C31 C18 C19 C20 -0.8(10) . . . . ?
C31 C22 C23 O3 174.2(6) . . . . ?
C31 C22 C23 C24 -3.7(8) . . . . ?
C32 O4 C21 C20 2.9(8) . . . . ?
C32 O4 C21 C22 -177.4(5) . . . . ?
C32 C33 C34 N3 60.7(7) . . . . ?
C34 N3 C35 C36 -172.3(6) . . . . ?
C34 N3 C35 C40 7.3(11) . . . . ?
C34 N3 C41 Ag1 -10.0(9) . . . . ?
C34 N3 C41 N4 172.8(5) . . . . ?
C35 N3 C34 C33 71.1(7) . . . . ?
C35 N3 C41 Ag1 177.1(4) . . . . ?
C35 N3 C41 N4 -0.1(7) . . . . ?
C35 C36 C37 C38 1.0(11) . . . . ?
C36 N4 C41 Ag1 -177.7(4) . . . . ?
C36 N4 C41 N3 -0.6(7) . . . . ?
C36 N4 C42 C43 84.0(8) . . . . ?
C36 C35 C40 C39 -0.6(11) . . . . ?
C36 C37 C38 C39 -0.4(12) . . . . ?
C37 C38 C39 C40 -0.7(14) . . . . ?
C38 C39 C40 C35 1.2(12) . . . . ?
C40 C35 C36 N4 179.4(6) . . . . ?
C40 C35 C36 C37 -0.5(11) . . . . ?
C41 N3 C34 C33 -100.8(7) . . . . ?
C41 N3 C35 C36 0.7(7) . . . . ?
C41 N3 C35 C40 -179.8(7) . . . . ?
C41 N4 C36 C35 1.0(7) . . . . ?
C41 N4 C36 C37 -179.2(7) . . . . ?
C41 N4 C42 C43 -95.6(7) . . . . ?
C42 N4 C36 C35 -178.7(6) . . . . ?
C42 N4 C36 C37 1.2(11) . . . . ?
C42 N4 C41 Ag1 2.0(9) . . . . ?
C42 N4 C41 N3 179.1(5) . . . . ?
C42 C43 C44 C45 179.5(7) . . . . ?
C42 C43 C48 C47 -179.9(8) . . . . ?
C43 C44 C45 C46 -0.6(14) . . . . ?
C44 C43 C48 C47 2.2(14) . . . . ?
C44 C45 C46 C47 4.2(16) . . . . ?
C45 C46 C47 C48 -4.6(17) . . . . ?
C46 C47 C48 C43 1.3(16) . . . . ?
C48 C43 C44 C45 -2.6(12) . . . . ?
C49 C50 C51 C52 2.6(15) . . . . ?
C50 C49 C54 C53 0.2(16) . . . . ?
C50 C49 C55 N5 -54.3(14) . . . . ?
C50 C51 C52 C53 -2.4(15) . . . . ?
C51 C52 C53 C54 1.2(16) . . . . ?
C52 C53 C54 C49 -0.1(17) . . . . ?
C54 C49 C50 C51 -1.5(15) . . . . ?
C54 C49 C55 N5 128.0(11) . . . . ?
C55 N5 C56 C57 175.5(8) . . . . ?
C55 N5 C56 C61 -5.8(17) . . . . ?
C55 N5 C62 Ag2 12.2(13) . . . . ?
C55 N5 C62 Ag2' 0.3(15) . . . . ?
C55 N5 C62 N6 -175.1(8) . . . . ?
C55 C49 C50 C51 -179.1(9) . . . . ?
C55 C49 C54 C53 177.9(9) . . . . ?
C56 N5 C55 C49 -74.8(13) . . . . ?
C56 N5 C62 Ag2 -175.8(6) . . . . ?
C56 N5 C62 Ag2' 172.3(7) . . . . ?
C56 N5 C62 N6 -3.1(11) . . . . ?
C56 C57 C58 C59 1.6(16) . . . . ?
C57 N6 C62 Ag2 173.3(8) . . . . ?
C57 N6 C62 Ag2' -174.8(6) . . . . ?
C57 N6 C62 N5 1.5(11) . . . . ?
C57 N6 C63 C64 64.8(13) . . . . ?
C57 C56 C61 C60 -0.2(18) . . . . ?
C57 C58 C59 C60 -3(2) . . . . ?
C58 C59 C60 C61 3(2) . . . . ?
C59 C60 C61 C56 -0.9(19) . . . . ?
C61 C56 C57 N6 178.9(11) . . . . ?
C61 C56 C57 C58 -0.1(16) . . . . ?
C62 Ag2' C14 N1 133.9(10) . . . . ?
C62 Ag2' C14 N2 -60.7(17) . . . . ?
C62 N5 C55 C49 96.5(13) . . . . ?
C62 N5 C56 C57 3.4(11) . . . . ?
C62 N5 C56 C61 -177.9(12) . . . . ?
C62 N6 C57 C56 0.6(11) . . . . ?
C62 N6 C57 C58 179.5(10) . . . . ?
C62 N6 C63 C64 -107.4(11) . . . . ?
C63 N6 C57 C56 -172.7(9) . . . . ?
C63 N6 C57 C58 6.2(17) . . . . ?
C63 N6 C62 Ag2 -13.3(14) . . . . ?
C63 N6 C62 Ag2' -1.4(12) . . . . ?
C63 N6 C62 N5 174.9(8) . . . . ?
C63 C64 C65 O5 64.9(14) . . . . ?
C65 O5 C66 C67 -1.3(14) . . . . ?
C65 O5 C66 C79 179.2(9) . . . . ?
C66 O5 C65 C64 -173.6(9) . . . . ?
C66 C67 C68 C69 -2.4(12) . . . . ?
C67 C66 C79 C70 2.1(12) . . . . ?
C67 C66 C79 C78 -175.2(8) . . . . ?
C67 C68 C69 O8 178.4(7) . . . . ?
C67 C68 C69 C70 -1.0(10) . . . . ?
C68 C69 C70 C71 -172.9(6) . . . . ?
C68 C69 C70 C79 4.9(10) . . . . ?
C69 O8 C80 C81 178.7(5) . . . . ?
C69 C70 C71 O7 17.2(10) . . . . ?
C69 C70 C71 C72 -163.3(6) . . . . ?
C69 C70 C79 C66 -5.4(11) . . . . ?
C69 C70 C79 C78 171.9(6) . . . . ?
C70 C71 C72 C73 169.0(7) . . . . ?
C70 C71 C72 C77 -11.9(10) . . . . ?
C71 C70 C79 C66 172.4(7) . . . . ?
C71 C70 C79 C78 -10.3(10) . . . . ?
C71 C72 C73 C74 -177.8(8) . . . . ?
C71 C72 C77 C76 176.9(7) . . . . ?
C71 C72 C77 C78 -4.1(11) . . . . ?
C72 C73 C74 C75 0.5(17) . . . . ?
C72 C77 C78 O6 -166.2(8) . . . . ?
C72 C77 C78 C79 12.9(11) . . . . ?
C73 C72 C77 C76 -4.0(12) . . . . ?
C73 C72 C77 C78 175.0(8) . . . . ?
C73 C74 C75 C76 -3.0(19) . . . . ?
C74 C75 C76 C77 2.0(18) . . . . ?
C75 C76 C77 C72 1.5(14) . . . . ?
C75 C76 C77 C78 -177.4(9) . . . . ?
C76 C77 C78 O6 12.8(13) . . . . ?
C76 C77 C78 C79 -168.2(7) . . . . ?
C77 C72 C73 C74 3.1(13) . . . . ?
C77 C78 C79 C66 171.8(8) . . . . ?
C77 C78 C79 C70 -5.5(11) . . . . ?
C79 C66 C67 C68 1.8(13) . . . . ?
C79 C70 C71 O7 -160.6(7) . . . . ?
C79 C70 C71 C72 18.9(9) . . . . ?
C80 O8 C69 C68 -3.8(9) . . . . ?
C80 O8 C69 C70 175.6(5) . . . . ?
C80 C81 C82 N7 167.0(5) . . . . ?
C82 N7 C83 C84 179.9(5) . . . . ?
C82 N7 C83 C88 -0.2(10) . . . . ?
C82 N7 C89 Ag1 -3.3(8) . . . . ?
C82 N7 C89 N8 179.8(5) . . . . ?
C83 N7 C82 C81 -88.4(7) . . . . ?
C83 N7 C89 Ag1 175.7(4) . . . . ?
C83 N7 C89 N8 -1.2(6) . . . . ?
C83 C84 C85 C86 0.0(11) . . . . ?
C84 N8 C89 Ag1 -175.7(4) . . . . ?
C84 N8 C89 N7 1.1(6) . . . . ?
C84 N8 C90 C91 74.0(8) . . . . ?
C84 C83 C88 C87 0.7(10) . . . . ?
C84 C85 C86 C87 1.9(13) . . . . ?
C85 C86 C87 C88 -2.6(14) . . . . ?
C86 C87 C88 C83 1.3(12) . . . . ?
C88 C83 C84 N8 179.9(6) . . . . ?
C88 C83 C84 C85 -1.3(10) . . . . ?
C89 N7 C82 C81 90.5(7) . . . . ?
C89 N7 C83 C84 0.8(7) . . . . ?
C89 N7 C83 C88 -179.3(7) . . . . ?
C89 N8 C84 C83 -0.6(7) . . . . ?
C89 N8 C84 C85 -179.1(7) . . . . ?
C89 N8 C90 C91 -105.9(7) . . . . ?
C90 N8 C84 C83 179.5(5) . . . . ?
C90 N8 C84 C85 1.0(11) . . . . ?
C90 N8 C89 Ag1 4.2(8) . . . . ?
C90 N8 C89 N7 -179.0(5) . . . . ?
C90 C91 C92 C93 -179.9(8) . . . . ?
C90 C91 C96 C95 179.9(7) . . . . ?
C91 C92 C93 C94 0.9(16) . . . . ?
C92 C91 C96 C95 0.4(12) . . . . ?
C92 C93 C94 C95 -1.4(17) . . . . ?
C93 C94 C95 C96 1.3(15) . . . . ?
C94 C95 C96 C91 -0.9(13) . . . . ?
C96 C91 C92 C93 -0.4(13) . . . . ?
Cl1 C99 C100 Cl2 60(2) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_n130305a
_database_code_depnum_ccdc_archive 'CCDC 1408697'
_audit_update_record             
;
2017-03-29 deposited with the CCDC.
2017-04-19 downloaded from the CCDC.
;
_audit_creation_date             2016-10-25
_audit_creation_method           
;
Olex2 1.2-beta
(compiled 2016.09.09 svn.r3337 for OlexSys, GUI svn.r5227)
;
_chemical_name_common            ?
_chemical_name_systematic        
;
 ? 
;
_chemical_formula_moiety         'C80 H72 Ag2 N8 O8, 0.5(C H2 Cl2), 2(F6 P)'
_chemical_formula_sum            'C80.50 H73 Ag2 Cl F12 N8 O8 P2'
_chemical_formula_weight         1821.59
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   14.458(3)
_cell_length_b                   14.898(3)
_cell_length_c                   37.068(6)
_cell_angle_alpha                90
_cell_angle_beta                 97.327(3)
_cell_angle_gamma                90
_cell_volume                     7920(2)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9920
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.71
_cell_measurement_theta_min      2.46
_shelx_estimated_absorpt_T_max   0.902
_shelx_estimated_absorpt_T_min   0.837
_exptl_absorpt_coefficient_mu    0.658
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.6604
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2012/1 (Bruker,2012) was used for absorption correction.
wR2(int) was 0.1246 before and 0.0368 after correction.
The Ratio of minimum to maximum transmission is 0.8856.
The λ/2 correction factor is 0.0015.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.528
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             3700
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.16
_exptl_special_details           
;
 ? 
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0247
_diffrn_reflns_av_unetI/netI     0.0279
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       44
_diffrn_reflns_limit_l_min       -39
_diffrn_reflns_number            40239
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.009
_diffrn_reflns_theta_max         25.009
_diffrn_reflns_theta_min         1.108
_diffrn_ambient_temperature      296.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                11246
_reflns_number_total             13957
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_refine_diff_density_max         1.250
_refine_diff_density_min         -1.004
_refine_diff_density_rms         0.099
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.028
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1036
_refine_ls_number_reflns         13957
_refine_ls_number_restraints     71
_refine_ls_R_factor_all          0.0730
_refine_ls_R_factor_gt           0.0596
_refine_ls_restrained_S_all      1.193
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0934P)²+23.7293P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1683
_refine_ls_wR_factor_ref         0.1823
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2. Restrained distances
 Cl1-Cl2
 2.55 with sigma of 0.01
 Cl1-C81 = Cl2-C81
 1.78 with sigma of 0.01
 C69-C68
 1.46 with sigma of 0.01
3. Rigid bond restraints
 P1, F4
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
 P2, F7
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
 P2, F8
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
 P2, F9
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
 P2, F10
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
 P2, F11
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
 P2, F12
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
4. Uiso/Uaniso restraints and constraints
Uanis(C81) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(F4) \\sim Ueq, Uanis(F8) \\sim Ueq, Uanis(F9) \\sim Ueq, Uanis(F11) \\sim
Ueq, Uanis(F12) \\sim Ueq, Uanis(C4) \\sim Ueq, Uanis(C43) \\sim Ueq,
Uanis(C44) \\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.002
Uanis(F7) \\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.002
5. Others
 Fixed Sof: Cl1(0.5) Cl2(0.5) C81(0.5) H81A(0.5) H81B(0.5)
6.a Secondary CH2 refined with riding coordinates:
 C7(H7A,H7B), C11(H11A,H11B), C12(H12A,H12B), C13(H13A,H13B), C28(H28A,H28B),
 C29(H29A,H29B), C30(H30A,H30B), C34(H34A,H34B), C47(H47A,H47B), C51(H51A,H51B),
  C52(H52A,H52B), C53(H53A,H53B), C68(H68A,H68B), C69(H69A,H69B), C70(H70A,
 H70B), C74(H74A,H74B), C81(H81A,H81B)
6.b Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3), C4(H4), C5(H5), C6(H6), C8(H8), C9(H9), C18(H18), C19(H19),
 C20(H20), C21(H21), C26(H26), C27(H27), C31(H31), C32(H32), C36(H36), C37(H37),
  C38(H38), C39(H39), C40(H40), C42(H42), C43(H43), C44(H44), C45(H45),
 C46(H46), C49(H49), C50(H50), C55(H55), C56(H56), C61(H61), C62(H62), C63(H63),
  C64(H64), C72(H72), C73(H73), C76(H76), C77(H77), C78(H78), C79(H79), C80(H80)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.73106(3) 0.38114(2) 1.13369(2) 0.04213(13) Uani 1 1 d . . . . .
Ag2 Ag 0.73349(3) 0.11119(3) 0.84296(2) 0.04506(14) Uani 1 1 d . . . . .
Cl1 Cl 1.1210(8) 0.5716(8) 1.1512(3) 0.268(6) Uani 0.5 1 d D . P . .
Cl2 Cl 1.2662(7) 0.4737(7) 1.1496(2) 0.203(4) Uani 0.5 1 d D . P . .
P1 P 0.78512(10) 0.83984(9) 1.23534(4) 0.0491(3) Uani 1 1 d . U . . .
P2 P 0.00814(17) 0.2820(2) 1.06406(7) 0.1038(7) Uani 1 1 d . U . . .
F1 F 0.8371(4) 0.7615(4) 1.25715(19) 0.144(2) Uani 1 1 d . . . . .
F2 F 0.8572(4) 0.9050(4) 1.25567(17) 0.124(2) Uani 1 1 d . . . . .
F3 F 0.7325(5) 0.9195(4) 1.21556(18) 0.144(2) Uani 1 1 d . . . . .
F4 F 0.7120(4) 0.7760(4) 1.21470(15) 0.1182(14) Uani 1 1 d . U . . .
F5 F 0.7190(4) 0.8528(5) 1.26543(17) 0.130(2) Uani 1 1 d . . . . .
F6 F 0.8489(4) 0.8236(5) 1.20540(15) 0.138(2) Uani 1 1 d . . . . .
F7 F -0.0018(6) 0.1878(6) 1.0805(2) 0.180(2) Uani 1 1 d . U . . .
F8 F 0.0790(4) 0.3012(4) 1.09788(17) 0.1388(17) Uani 1 1 d . U . . .
F9 F 0.0222(7) 0.3697(6) 1.0448(3) 0.188(2) Uani 1 1 d . U . . .
F10 F -0.0668(5) 0.2596(6) 1.03186(19) 0.175(3) Uani 1 1 d . U . . .
F11 F -0.0731(4) 0.3211(5) 1.08248(18) 0.1392(17) Uani 1 1 d . U . . .
F12 F 0.0857(5) 0.2353(5) 1.04669(18) 0.1479(18) Uani 1 1 d . U . . .
O1 O 0.6945(3) -0.0971(3) 0.88014(10) 0.0534(9) Uani 1 1 d . . . . .
O2 O 0.5408(3) -0.0173(3) 0.85803(10) 0.0700(12) Uani 1 1 d . . . . .
O3 O 0.5115(3) 0.1040(4) 0.99147(12) 0.0851(17) Uani 1 1 d . . . . .
O4 O 0.6836(3) 0.0701(3) 1.01223(9) 0.0548(10) Uani 1 1 d . . . . .
O5 O 0.7108(4) 0.5865(3) 1.08835(13) 0.0816(14) Uani 1 1 d . . . . .
O6 O 0.5475(4) 0.5266(3) 1.09634(13) 0.0858(15) Uani 1 1 d . . . . .
O7 O 0.5400(5) 0.3293(5) 0.97578(16) 0.119(2) Uani 1 1 d . . . . .
O8 O 0.7106(6) 0.3539(5) 0.97428(19) 0.134(3) Uani 1 1 d . . . . .
N1 N 0.9329(3) 0.0608(4) 0.82870(13) 0.0559(12) Uani 1 1 d . . . . .
N2 N 0.8399(3) -0.0474(3) 0.81372(11) 0.0473(10) Uani 1 1 d . . . . .
N3 N 0.6253(3) 0.2422(3) 1.07969(11) 0.0452(10) Uani 1 1 d . . . . .
N4 N 0.5413(3) 0.2848(3) 1.11959(12) 0.0469(10) Uani 1 1 d . . . . .
N5 N 0.9118(3) 0.4315(3) 1.18334(13) 0.0483(10) Uani 1 1 d . . . . .
N6 N 0.8199(3) 0.5431(3) 1.17755(12) 0.0467(10) Uani 1 1 d . . . . .
N7 N 0.6172(4) 0.2255(3) 0.88956(14) 0.0588(13) Uani 1 1 d . . . . .
N8 N 0.5469(3) 0.2155(3) 0.83541(14) 0.0567(12) Uani 1 1 d . . . . .
C1 C 0.9898(4) 0.1353(5) 0.88687(19) 0.0635(16) Uani 1 1 d . . . . .
C2 C 1.0033(5) 0.2115(6) 0.9075(3) 0.089(2) Uani 1 1 d . . . . .
H2 H 1.0014 0.2671 0.8960 0.107 Uiso 1 1 calc R . . . .
C3 C 1.0197(6) 0.2077(7) 0.9451(3) 0.101(3) Uani 1 1 d . . . . .
H3 H 1.0292 0.2605 0.9585 0.121 Uiso 1 1 calc R . . . .
C4 C 1.0220(7) 0.1300(8) 0.9620(3) 0.101(3) Uani 1 1 d . U . . .
H4 H 1.0306 0.1283 0.9873 0.121 Uiso 1 1 calc R . . . .
C5 C 1.0116(6) 0.0506(7) 0.9424(2) 0.097(3) Uani 1 1 d . . . . .
H5 H 1.0157 -0.0046 0.9542 0.117 Uiso 1 1 calc R . . . .
C6 C 0.9950(5) 0.0552(6) 0.9051(2) 0.0772(19) Uani 1 1 d . . . . .
H6 H 0.9870 0.0022 0.8919 0.093 Uiso 1 1 calc R . . . .
C7 C 0.9708(5) 0.1429(5) 0.84628(19) 0.0712(18) Uani 1 1 d . . . . .
H7A H 0.9270 0.1915 0.8401 0.085 Uiso 1 1 calc R . . . .
H7B H 1.0283 0.1581 0.8368 0.085 Uiso 1 1 calc R . . . .
C8 C 0.9851(5) -0.0049(6) 0.81534(19) 0.0741(19) Uani 1 1 d . . . . .
H8 H 1.0485 -0.0024 0.8133 0.089 Uiso 1 1 calc R . . . .
C9 C 0.9275(4) -0.0733(5) 0.80583(17) 0.0673(18) Uani 1 1 d . . . . .
H9 H 0.9430 -0.1277 0.7959 0.081 Uiso 1 1 calc R . . . .
C10 C 0.8432(3) 0.0352(4) 0.82810(13) 0.0448(12) Uani 1 1 d . . . . .
C11 C 0.7578(4) -0.1032(4) 0.80889(15) 0.0519(13) Uani 1 1 d . . . . .
H11A H 0.7498 -0.1274 0.7844 0.062 Uiso 1 1 calc R . . . .
H11B H 0.7035 -0.0668 0.8117 0.062 Uiso 1 1 calc R . . . .
C12 C 0.7640(5) -0.1802(4) 0.83611(15) 0.0569(14) Uani 1 1 d . . . . .
H12A H 0.7077 -0.2161 0.8317 0.068 Uiso 1 1 calc R . . . .
H12B H 0.8162 -0.2183 0.8323 0.068 Uiso 1 1 calc R . . . .
C13 C 0.7760(4) -0.1485(4) 0.87525(15) 0.0557(14) Uani 1 1 d . . . . .
H13A H 0.7820 -0.1995 0.8917 0.067 Uiso 1 1 calc R . . . .
H13B H 0.8315 -0.1117 0.8802 0.067 Uiso 1 1 calc R . . . .
C14 C 0.6933(4) -0.0564(4) 0.91294(14) 0.0468(12) Uani 1 1 d . . . . .
C15 C 0.6124(4) -0.0096(4) 0.91941(13) 0.0435(11) Uani 1 1 d . . . . .
C16 C 0.5337(4) 0.0022(4) 0.88955(14) 0.0466(12) Uani 1 1 d . . . . .
C17 C 0.4459(4) 0.0424(3) 0.89829(14) 0.0454(12) Uani 1 1 d . . . . .
C18 C 0.3702(4) 0.0482(4) 0.87174(15) 0.0533(14) Uani 1 1 d . . . . .
H18 H 0.3750 0.0269 0.8485 0.064 Uiso 1 1 calc R . . . .
C19 C 0.2871(4) 0.0851(4) 0.87936(17) 0.0606(15) Uani 1 1 d . . . . .
H19 H 0.2363 0.0889 0.8613 0.073 Uiso 1 1 calc R . . . .
C20 C 0.2797(4) 0.1167(4) 0.91412(19) 0.0621(16) Uani 1 1 d . . . . .
H20 H 0.2236 0.1406 0.9195 0.075 Uiso 1 1 calc R . . . .
C21 C 0.3557(4) 0.1125(4) 0.94076(16) 0.0560(14) Uani 1 1 d . . . . .
H21 H 0.3510 0.1344 0.9640 0.067 Uiso 1 1 calc R . . . .
C22 C 0.4395(4) 0.0756(3) 0.93294(14) 0.0450(12) Uani 1 1 d . . . . .
C23 C 0.5199(4) 0.0720(4) 0.96232(15) 0.0515(13) Uani 1 1 d . . . . .
C24 C 0.6078(3) 0.0297(3) 0.95395(13) 0.0429(11) Uani 1 1 d . . . . .
C25 C 0.6867(4) 0.0274(4) 0.98036(13) 0.0482(13) Uani 1 1 d . . . . .
C26 C 0.7651(4) -0.0184(4) 0.97292(15) 0.0607(16) Uani 1 1 d . . . . .
H26 H 0.8173 -0.0208 0.9904 0.073 Uiso 1 1 calc R . . . .
C27 C 0.7670(4) -0.0607(4) 0.94003(15) 0.0595(15) Uani 1 1 d . . . . .
H27 H 0.8198 -0.0931 0.9361 0.071 Uiso 1 1 calc R . . . .
C28 C 0.7700(4) 0.0831(4) 1.03548(14) 0.0522(13) Uani 1 1 d . . . . .
H28A H 0.8129 0.1184 1.0232 0.063 Uiso 1 1 calc R . . . .
H28B H 0.7988 0.0258 1.0424 0.063 Uiso 1 1 calc R . . . .
C29 C 0.7450(4) 0.1322(4) 1.06860(15) 0.0550(14) Uani 1 1 d . . . . .
H29A H 0.8006 0.1387 1.0860 0.066 Uiso 1 1 calc R . . . .
H29B H 0.7005 0.0965 1.0799 0.066 Uiso 1 1 calc R . . . .
C30 C 0.7034(4) 0.2245(4) 1.05965(14) 0.0533(14) Uani 1 1 d . . . . .
H30A H 0.7510 0.2699 1.0657 0.064 Uiso 1 1 calc R . . . .
H30B H 0.6826 0.2282 1.0338 0.064 Uiso 1 1 calc R . . . .
C31 C 0.5414(4) 0.1973(4) 1.07286(17) 0.0594(15) Uani 1 1 d . . . . .
H31 H 0.5247 0.1562 1.0543 0.071 Uiso 1 1 calc R . . . .
C32 C 0.4893(4) 0.2237(4) 1.09757(17) 0.0563(14) Uani 1 1 d . . . . .
H32 H 0.4290 0.2048 1.0997 0.068 Uiso 1 1 calc R . . . .
C33 C 0.6261(3) 0.2970(3) 1.10867(13) 0.0416(11) Uani 1 1 d . . . . .
C34 C 0.5019(4) 0.3347(5) 1.14807(17) 0.0653(16) Uani 1 1 d . . . . .
H34A H 0.4564 0.2968 1.1578 0.078 Uiso 1 1 calc R . . . .
H34B H 0.4688 0.3865 1.1370 0.078 Uiso 1 1 calc R . . . .
C35 C 0.5701(4) 0.3665(4) 1.17885(15) 0.0492(13) Uani 1 1 d . . . . .
C36 C 0.6336(4) 0.3101(4) 1.19811(15) 0.0523(13) Uani 1 1 d . . . . .
H36 H 0.6373 0.2506 1.1909 0.063 Uiso 1 1 calc R . . . .
C37 C 0.6917(4) 0.3405(5) 1.22802(16) 0.0661(17) Uani 1 1 d . . . . .
H37 H 0.7337 0.3016 1.2411 0.079 Uiso 1 1 calc R . . . .
C38 C 0.6868(5) 0.4285(6) 1.23825(18) 0.078(2) Uani 1 1 d . . . . .
H38 H 0.7271 0.4498 1.2580 0.094 Uiso 1 1 calc R . . . .
C39 C 0.6234(6) 0.4851(5) 1.2198(2) 0.078(2) Uani 1 1 d . . . . .
H39 H 0.6202 0.5446 1.2272 0.094 Uiso 1 1 calc R . . . .
C40 C 0.5644(5) 0.4547(4) 1.19042(18) 0.0659(16) Uani 1 1 d . . . . .
H40 H 0.5205 0.4932 1.1782 0.079 Uiso 1 1 calc R . . . .
C41 C 0.9130(4) 0.2697(4) 1.19756(19) 0.0557(15) Uani 1 1 d . . . . .
C42 C 0.8574(5) 0.2065(4) 1.1788(3) 0.086(2) Uani 1 1 d . . . . .
H42 H 0.8436 0.2085 1.1537 0.104 Uiso 1 1 calc R . . . .
C43 C 0.8198(6) 0.1344(5) 1.2007(3) 0.086(2) Uani 1 1 d . U . . .
H43 H 0.7805 0.0904 1.1895 0.103 Uiso 1 1 calc R . . . .
C44 C 0.8425(6) 0.1338(6) 1.2352(3) 0.095(2) Uani 1 1 d . U . . .
H44 H 0.8184 0.0877 1.2481 0.114 Uiso 1 1 calc R . . . .
C45 C 0.8993(6) 0.1950(6) 1.2548(3) 0.094(3) Uani 1 1 d . . . . .
H45 H 0.9136 0.1909 1.2800 0.113 Uiso 1 1 calc R . . . .
C46 C 0.9334(5) 0.2623(5) 1.2352(2) 0.0728(19) Uani 1 1 d . . . . .
H46 H 0.9722 0.3051 1.2476 0.087 Uiso 1 1 calc R . . . .
C47 C 0.9537(4) 0.3433(4) 1.17800(18) 0.0566(14) Uani 1 1 d . . . . .
H47A H 1.0201 0.3464 1.1862 0.068 Uiso 1 1 calc R . . . .
H47B H 0.9459 0.3295 1.1522 0.068 Uiso 1 1 calc R . . . .
C48 C 0.8308(3) 0.4594(3) 1.16516(14) 0.0424(11) Uani 1 1 d . . . . .
C49 C 0.8930(4) 0.5661(4) 1.20349(18) 0.0635(16) Uani 1 1 d . . . . .
H49 H 0.9004 0.6204 1.2158 0.076 Uiso 1 1 calc R . . . .
C50 C 0.9501(4) 0.4973(4) 1.20763(18) 0.0649(16) Uani 1 1 d . . . . .
H50 H 1.0051 0.4932 1.2235 0.078 Uiso 1 1 calc R . . . .
C51 C 0.7444(4) 0.6042(4) 1.16436(17) 0.0549(14) Uani 1 1 d . . . . .
H51A H 0.7238 0.6356 1.1848 0.066 Uiso 1 1 calc R . . . .
H51B H 0.6921 0.5699 1.1525 0.066 Uiso 1 1 calc R . . . .
C52 C 0.7748(5) 0.6720(4) 1.13775(19) 0.0686(17) Uani 1 1 d . . . . .
H52A H 0.7255 0.7158 1.1319 0.082 Uiso 1 1 calc R . . . .
H52B H 0.8297 0.7034 1.1490 0.082 Uiso 1 1 calc R . . . .
C53 C 0.7960(6) 0.6285(5) 1.1040(2) 0.077(2) Uani 1 1 d . . . . .
H53A H 0.8162 0.6727 1.0874 0.092 Uiso 1 1 calc R . . . .
H53B H 0.8450 0.5842 1.1093 0.092 Uiso 1 1 calc R . . . .
C54 C 0.7130(6) 0.5272(4) 1.06066(17) 0.0703(18) Uani 1 1 d . . . . .
C55 C 0.7936(6) 0.5136(5) 1.0444(2) 0.085(2) Uani 1 1 d . . . . .
H55 H 0.8476 0.5452 1.0527 0.101 Uiso 1 1 calc R . . . .
C56 C 0.7938(7) 0.4547(6) 1.0167(2) 0.092(2) Uani 1 1 d . . . . .
H56 H 0.8490 0.4436 1.0071 0.111 Uiso 1 1 calc R . . . .
C57 C 0.7145(7) 0.4114(5) 1.00278(18) 0.084(2) Uani 1 1 d . . . . .
C58 C 0.6319(6) 0.4217(4) 1.01839(16) 0.0681(18) Uani 1 1 d . . . . .
C59 C 0.5464(6) 0.3741(5) 1.00367(17) 0.077(2) Uani 1 1 d . . . . .
C60 C 0.4651(6) 0.3801(5) 1.02270(18) 0.073(2) Uani 1 1 d . . . . .
C61 C 0.3864(7) 0.3326(6) 1.0101(2) 0.090(2) Uani 1 1 d . . . . .
H61 H 0.3867 0.2971 0.9895 0.108 Uiso 1 1 calc R . . . .
C62 C 0.3094(8) 0.3357(7) 1.0264(3) 0.112(3) Uani 1 1 d . . . . .
H62 H 0.2577 0.3014 1.0176 0.135 Uiso 1 1 calc R . . . .
C63 C 0.3065(7) 0.3930(7) 1.0580(3) 0.109(3) Uani 1 1 d . . . . .
H63 H 0.2536 0.3963 1.0698 0.131 Uiso 1 1 calc R . . . .
C64 C 0.3845(6) 0.4416(6) 1.0697(2) 0.093(3) Uani 1 1 d . . . . .
H64 H 0.3839 0.4798 1.0895 0.112 Uiso 1 1 calc R . . . .
C65 C 0.4650(6) 0.4358(5) 1.05285(17) 0.072(2) Uani 1 1 d . . . . .
C66 C 0.5486(5) 0.4851(4) 1.06775(17) 0.0665(18) Uani 1 1 d . . . . .
C67 C 0.6322(5) 0.4798(4) 1.04852(15) 0.0648(18) Uani 1 1 d . . . . .
C68 C 0.7844(8) 0.3458(8) 0.9538(2) 0.136(5) Uani 1 1 d D . . . .
H68A H 0.8338 0.3104 0.9670 0.164 Uiso 1 1 calc R . . . .
H68B H 0.8091 0.4047 0.9494 0.164 Uiso 1 1 calc R . . . .
C69 C 0.7525(7) 0.3033(7) 0.9199(2) 0.110(3) Uani 1 1 d D . . . .
H69A H 0.8069 0.2845 0.9090 0.133 Uiso 1 1 calc R . . . .
H69B H 0.7204 0.3481 0.9040 0.133 Uiso 1 1 calc R . . . .
C70 C 0.6886(6) 0.2230(5) 0.92060(18) 0.081(2) Uani 1 1 d . . . . .
H70A H 0.7245 0.1681 0.9201 0.097 Uiso 1 1 calc R . . . .
H70B H 0.6598 0.2235 0.9429 0.097 Uiso 1 1 calc R . . . .
C71 C 0.6251(4) 0.1907(4) 0.85657(15) 0.0501(13) Uani 1 1 d . . . . .
C72 C 0.4918(5) 0.2667(5) 0.8551(2) 0.081(2) Uani 1 1 d . . . . .
H72 H 0.4345 0.2921 0.8465 0.097 Uiso 1 1 calc R . . . .
C73 C 0.5356(6) 0.2731(5) 0.8887(2) 0.080(2) Uani 1 1 d . . . . .
H73 H 0.5150 0.3039 0.9080 0.096 Uiso 1 1 calc R . . . .
C74 C 0.5255(4) 0.1985(4) 0.79682(17) 0.0597(15) Uani 1 1 d . . . . .
H74A H 0.4624 0.1755 0.7919 0.072 Uiso 1 1 calc R . . . .
H74B H 0.5674 0.1526 0.7898 0.072 Uiso 1 1 calc R . . . .
C75 C 0.5342(4) 0.2811(4) 0.77393(17) 0.0546(14) Uani 1 1 d . . . . .
C76 C 0.6006(4) 0.3451(5) 0.78393(19) 0.0675(17) Uani 1 1 d . . . . .
H76 H 0.6396 0.3395 0.8058 0.081 Uiso 1 1 calc R . . . .
C77 C 0.6099(5) 0.4185(5) 0.7615(2) 0.0762(19) Uani 1 1 d . . . . .
H77 H 0.6539 0.4627 0.7687 0.091 Uiso 1 1 calc R . . . .
C78 C 0.5555(5) 0.4261(5) 0.7291(2) 0.0730(19) Uani 1 1 d . . . . .
H78 H 0.5632 0.4744 0.7138 0.088 Uiso 1 1 calc R . . . .
C79 C 0.4896(5) 0.3628(5) 0.71910(19) 0.0718(19) Uani 1 1 d . . . . .
H79 H 0.4521 0.3684 0.6969 0.086 Uiso 1 1 calc R . . . .
C80 C 0.4771(4) 0.2910(5) 0.74096(17) 0.0616(15) Uani 1 1 d . . . . .
H80 H 0.4308 0.2490 0.7338 0.074 Uiso 1 1 calc R . . . .
C81 C 1.1494(10) 0.4577(9) 1.1504(7) 0.131(7) Uani 0.5 1 d D U P . .
H81A H 1.1359 0.4261 1.1720 0.157 Uiso 0.5 1 calc R . P . .
H81B H 1.1198 0.4276 1.1287 0.157 Uiso 0.5 1 calc R . P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C33 2.092(5) . ?
Ag1 C48 2.091(5) . ?
Ag2 C10 2.080(5) . ?
Ag2 C71 2.077(5) . ?
Cl1 C81 1.746(10) . ?
Cl2 C81 1.709(10) . ?
P1 F1 1.558(5) . ?
P1 F2 1.548(5) . ?
P1 F3 1.544(5) . ?
P1 F4 1.550(5) . ?
P1 F5 1.570(5) . ?
P1 F6 1.549(5) . ?
P2 F7 1.545(8) . ?
P2 F8 1.541(6) . ?
P2 F9 1.515(9) . ?
P2 F10 1.543(6) . ?
P2 F11 1.546(6) . ?
P2 F12 1.530(6) . ?
O1 C13 1.436(7) . ?
O1 C14 1.360(6) . ?
O2 C16 1.221(6) . ?
O3 C23 1.201(6) . ?
O4 C25 1.348(6) . ?
O4 C28 1.437(6) . ?
O5 C53 1.436(9) . ?
O5 C54 1.358(8) . ?
O6 C66 1.229(7) . ?
O7 C59 1.224(8) . ?
O8 C57 1.356(9) . ?
O8 C68 1.392(11) . ?
N1 C7 1.459(9) . ?
N1 C8 1.367(8) . ?
N1 C10 1.350(7) . ?
N2 C9 1.390(7) . ?
N2 C10 1.339(7) . ?
N2 C11 1.442(7) . ?
N3 C30 1.454(7) . ?
N3 C31 1.380(7) . ?
N3 C33 1.348(6) . ?
N4 C32 1.379(7) . ?
N4 C33 1.352(7) . ?
N4 C34 1.466(7) . ?
N5 C47 1.471(7) . ?
N5 C48 1.340(7) . ?
N5 C50 1.397(7) . ?
N6 C48 1.346(6) . ?
N6 C49 1.378(7) . ?
N6 C51 1.457(7) . ?
N7 C70 1.445(9) . ?
N7 C71 1.347(7) . ?
N7 C73 1.374(8) . ?
N8 C71 1.344(7) . ?
N8 C72 1.378(8) . ?
N8 C74 1.447(8) . ?
C1 C2 1.369(10) . ?
C1 C6 1.369(10) . ?
C1 C7 1.499(10) . ?
C2 H2 0.9300 . ?
C2 C3 1.384(12) . ?
C3 H3 0.9300 . ?
C3 C4 1.315(13) . ?
C4 H4 0.9300 . ?
C4 C5 1.388(13) . ?
C5 H5 0.9300 . ?
C5 C6 1.372(11) . ?
C6 H6 0.9300 . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C8 H8 0.9300 . ?
C8 C9 1.335(10) . ?
C9 H9 0.9300 . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C11 C12 1.523(8) . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C12 C13 1.514(7) . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C14 C15 1.409(7) . ?
C14 C27 1.369(8) . ?
C15 C16 1.494(7) . ?
C15 C24 1.417(7) . ?
C16 C17 1.476(8) . ?
C17 C18 1.378(7) . ?
C17 C22 1.390(7) . ?
C18 H18 0.9300 . ?
C18 C19 1.384(8) . ?
C19 H19 0.9300 . ?
C19 C20 1.388(9) . ?
C20 H20 0.9300 . ?
C20 C21 1.382(9) . ?
C21 H21 0.9300 . ?
C21 C22 1.394(8) . ?
C22 C23 1.490(7) . ?
C23 C24 1.486(7) . ?
C24 C25 1.406(7) . ?
C25 C26 1.381(8) . ?
C26 H26 0.9300 . ?
C26 C27 1.375(8) . ?
C27 H27 0.9300 . ?
C28 H28A 0.9700 . ?
C28 H28B 0.9700 . ?
C28 C29 1.512(7) . ?
C29 H29A 0.9700 . ?
C29 H29B 0.9700 . ?
C29 C30 1.520(8) . ?
C30 H30A 0.9700 . ?
C30 H30B 0.9700 . ?
C31 H31 0.9300 . ?
C31 C32 1.318(9) . ?
C32 H32 0.9300 . ?
C34 H34A 0.9700 . ?
C34 H34B 0.9700 . ?
C34 C35 1.487(8) . ?
C35 C36 1.374(8) . ?
C35 C40 1.388(8) . ?
C36 H36 0.9300 . ?
C36 C37 1.379(9) . ?
C37 H37 0.9300 . ?
C37 C38 1.369(11) . ?
C38 H38 0.9300 . ?
C38 C39 1.364(11) . ?
C39 H39 0.9300 . ?
C39 C40 1.373(10) . ?
C40 H40 0.9300 . ?
C41 C42 1.368(9) . ?
C41 C46 1.394(10) . ?
C41 C47 1.478(9) . ?
C42 H42 0.9300 . ?
C42 C43 1.491(12) . ?
C43 H43 0.9300 . ?
C43 C44 1.277(12) . ?
C44 H44 0.9300 . ?
C44 C45 1.372(13) . ?
C45 H45 0.9300 . ?
C45 C46 1.367(10) . ?
C46 H46 0.9300 . ?
C47 H47A 0.9700 . ?
C47 H47B 0.9700 . ?
C49 H49 0.9300 . ?
C49 C50 1.313(9) . ?
C50 H50 0.9300 . ?
C51 H51A 0.9700 . ?
C51 H51B 0.9700 . ?
C51 C52 1.515(9) . ?
C52 H52A 0.9700 . ?
C52 H52B 0.9700 . ?
C52 C53 1.475(10) . ?
C53 H53A 0.9700 . ?
C53 H53B 0.9700 . ?
C54 C55 1.393(11) . ?
C54 C67 1.390(10) . ?
C55 H55 0.9300 . ?
C55 C56 1.350(10) . ?
C56 H56 0.9300 . ?
C56 C57 1.359(12) . ?
C57 C58 1.401(11) . ?
C58 C59 1.468(11) . ?
C58 C67 1.413(8) . ?
C59 C60 1.449(11) . ?
C60 C61 1.369(12) . ?
C60 C65 1.392(9) . ?
C61 H61 0.9300 . ?
C61 C62 1.334(13) . ?
C62 H62 0.9300 . ?
C62 C63 1.453(14) . ?
C63 H63 0.9300 . ?
C63 C64 1.364(13) . ?
C64 H64 0.9300 . ?
C64 C65 1.391(11) . ?
C65 C66 1.462(11) . ?
C66 C67 1.481(10) . ?
C68 H68A 0.9700 . ?
C68 H68B 0.9700 . ?
C68 C69 1.427(8) . ?
C69 H69A 0.9700 . ?
C69 H69B 0.9700 . ?
C69 C70 1.515(12) . ?
C70 H70A 0.9700 . ?
C70 H70B 0.9700 . ?
C72 H72 0.9300 . ?
C72 C73 1.325(11) . ?
C73 H73 0.9300 . ?
C74 H74A 0.9700 . ?
C74 H74B 0.9700 . ?
C74 C75 1.509(8) . ?
C75 C76 1.370(9) . ?
C75 C80 1.392(8) . ?
C76 H76 0.9300 . ?
C76 C77 1.392(10) . ?
C77 H77 0.9300 . ?
C77 C78 1.353(10) . ?
C78 H78 0.9300 . ?
C78 C79 1.359(11) . ?
C79 H79 0.9300 . ?
C79 C80 1.368(9) . ?
C80 H80 0.9300 . ?
C81 H81A 0.9700 . ?
C81 H81B 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C48 Ag1 C33 172.5(2) . . ?
C71 Ag2 C10 178.0(2) . . ?
F1 P1 F5 91.2(4) . . ?
F2 P1 F1 88.1(4) . . ?
F2 P1 F4 179.0(4) . . ?
F2 P1 F5 90.6(4) . . ?
F2 P1 F6 91.2(4) . . ?
F3 P1 F1 177.1(4) . . ?
F3 P1 F2 90.5(4) . . ?
F3 P1 F4 88.5(4) . . ?
F3 P1 F5 86.3(4) . . ?
F3 P1 F6 94.7(4) . . ?
F4 P1 F1 92.9(4) . . ?
F4 P1 F5 89.3(3) . . ?
F6 P1 F1 87.9(4) . . ?
F6 P1 F4 88.9(3) . . ?
F6 P1 F5 177.9(4) . . ?
F7 P2 F11 93.1(5) . . ?
F8 P2 F7 86.2(4) . . ?
F8 P2 F10 176.2(5) . . ?
F8 P2 F11 91.9(4) . . ?
F9 P2 F7 174.1(6) . . ?
F9 P2 F8 96.2(5) . . ?
F9 P2 F10 86.9(5) . . ?
F9 P2 F11 92.2(5) . . ?
F9 P2 F12 92.5(5) . . ?
F10 P2 F7 91.0(5) . . ?
F10 P2 F11 85.7(4) . . ?
F12 P2 F7 82.1(5) . . ?
F12 P2 F8 88.9(4) . . ?
F12 P2 F10 93.2(4) . . ?
F12 P2 F11 175.1(5) . . ?
C14 O1 C13 117.0(4) . . ?
C25 O4 C28 117.7(4) . . ?
C54 O5 C53 119.1(6) . . ?
C57 O8 C68 121.5(8) . . ?
C8 N1 C7 124.7(6) . . ?
C10 N1 C7 123.3(5) . . ?
C10 N1 C8 111.4(5) . . ?
C9 N2 C11 124.9(5) . . ?
C10 N2 C9 110.6(5) . . ?
C10 N2 C11 124.5(4) . . ?
C31 N3 C30 122.7(5) . . ?
C33 N3 C30 126.0(5) . . ?
C33 N3 C31 111.0(5) . . ?
C32 N4 C34 121.9(5) . . ?
C33 N4 C32 111.0(5) . . ?
C33 N4 C34 126.8(5) . . ?
C48 N5 C47 123.9(5) . . ?
C48 N5 C50 110.8(5) . . ?
C50 N5 C47 125.3(5) . . ?
C48 N6 C49 110.8(5) . . ?
C48 N6 C51 125.4(5) . . ?
C49 N6 C51 123.7(5) . . ?
C71 N7 C70 125.3(5) . . ?
C71 N7 C73 110.5(6) . . ?
C73 N7 C70 123.8(6) . . ?
C71 N8 C72 110.1(6) . . ?
C71 N8 C74 125.9(4) . . ?
C72 N8 C74 123.8(6) . . ?
C2 C1 C7 119.6(7) . . ?
C6 C1 C2 116.8(7) . . ?
C6 C1 C7 123.6(7) . . ?
C1 C2 H2 119.2 . . ?
C1 C2 C3 121.5(9) . . ?
C3 C2 H2 119.2 . . ?
C2 C3 H3 119.8 . . ?
C4 C3 C2 120.4(9) . . ?
C4 C3 H3 119.8 . . ?
C3 C4 H4 119.8 . . ?
C3 C4 C5 120.4(10) . . ?
C5 C4 H4 119.8 . . ?
C4 C5 H5 120.7 . . ?
C6 C5 C4 118.6(9) . . ?
C6 C5 H5 120.7 . . ?
C1 C6 C5 122.2(8) . . ?
C1 C6 H6 118.9 . . ?
C5 C6 H6 118.9 . . ?
N1 C7 C1 113.3(6) . . ?
N1 C7 H7A 108.9 . . ?
N1 C7 H7B 108.9 . . ?
C1 C7 H7A 108.9 . . ?
C1 C7 H7B 108.9 . . ?
H7A C7 H7B 107.7 . . ?
N1 C8 H8 126.6 . . ?
C9 C8 N1 106.7(5) . . ?
C9 C8 H8 126.6 . . ?
N2 C9 H9 126.6 . . ?
C8 C9 N2 106.7(5) . . ?
C8 C9 H9 126.6 . . ?
N1 C10 Ag2 127.3(4) . . ?
N2 C10 Ag2 128.0(4) . . ?
N2 C10 N1 104.6(4) . . ?
N2 C11 H11A 109.2 . . ?
N2 C11 H11B 109.2 . . ?
N2 C11 C12 112.0(5) . . ?
H11A C11 H11B 107.9 . . ?
C12 C11 H11A 109.2 . . ?
C12 C11 H11B 109.2 . . ?
C11 C12 H12A 109.0 . . ?
C11 C12 H12B 109.0 . . ?
H12A C12 H12B 107.8 . . ?
C13 C12 C11 112.9(5) . . ?
C13 C12 H12A 109.0 . . ?
C13 C12 H12B 109.0 . . ?
O1 C13 C12 106.9(5) . . ?
O1 C13 H13A 110.3 . . ?
O1 C13 H13B 110.3 . . ?
C12 C13 H13A 110.3 . . ?
C12 C13 H13B 110.3 . . ?
H13A C13 H13B 108.6 . . ?
O1 C14 C15 118.5(4) . . ?
O1 C14 C27 122.5(5) . . ?
C27 C14 C15 118.9(5) . . ?
C14 C15 C16 120.2(4) . . ?
C14 C15 C24 119.6(4) . . ?
C24 C15 C16 120.1(5) . . ?
O2 C16 C15 122.1(5) . . ?
O2 C16 C17 119.1(5) . . ?
C17 C16 C15 118.7(4) . . ?
C18 C17 C16 119.7(5) . . ?
C18 C17 C22 119.8(5) . . ?
C22 C17 C16 120.5(5) . . ?
C17 C18 H18 119.7 . . ?
C17 C18 C19 120.7(5) . . ?
C19 C18 H18 119.7 . . ?
C18 C19 H19 120.2 . . ?
C18 C19 C20 119.7(5) . . ?
C20 C19 H19 120.2 . . ?
C19 C20 H20 120.0 . . ?
C21 C20 C19 120.0(6) . . ?
C21 C20 H20 120.0 . . ?
C20 C21 H21 119.9 . . ?
C20 C21 C22 120.1(6) . . ?
C22 C21 H21 119.9 . . ?
C17 C22 C21 119.7(5) . . ?
C17 C22 C23 121.7(5) . . ?
C21 C22 C23 118.7(5) . . ?
O3 C23 C22 119.0(5) . . ?
O3 C23 C24 122.9(5) . . ?
C24 C23 C22 118.1(4) . . ?
C15 C24 C23 120.3(4) . . ?
C25 C24 C15 119.4(5) . . ?
C25 C24 C23 120.3(4) . . ?
O4 C25 C24 118.9(4) . . ?
O4 C25 C26 121.9(5) . . ?
C26 C25 C24 119.2(5) . . ?
C25 C26 H26 119.6 . . ?
C27 C26 C25 120.9(5) . . ?
C27 C26 H26 119.6 . . ?
C14 C27 C26 121.8(5) . . ?
C14 C27 H27 119.1 . . ?
C26 C27 H27 119.1 . . ?
O4 C28 H28A 110.6 . . ?
O4 C28 H28B 110.6 . . ?
O4 C28 C29 105.8(4) . . ?
H28A C28 H28B 108.7 . . ?
C29 C28 H28A 110.6 . . ?
C29 C28 H28B 110.6 . . ?
C28 C29 H29A 109.0 . . ?
C28 C29 H29B 109.0 . . ?
C28 C29 C30 112.9(5) . . ?
H29A C29 H29B 107.8 . . ?
C30 C29 H29A 109.0 . . ?
C30 C29 H29B 109.0 . . ?
N3 C30 C29 111.4(5) . . ?
N3 C30 H30A 109.4 . . ?
N3 C30 H30B 109.4 . . ?
C29 C30 H30A 109.4 . . ?
C29 C30 H30B 109.4 . . ?
H30A C30 H30B 108.0 . . ?
N3 C31 H31 126.4 . . ?
C32 C31 N3 107.1(5) . . ?
C32 C31 H31 126.4 . . ?
N4 C32 H32 126.5 . . ?
C31 C32 N4 106.9(5) . . ?
C31 C32 H32 126.5 . . ?
N3 C33 Ag1 130.4(4) . . ?
N3 C33 N4 103.9(4) . . ?
N4 C33 Ag1 125.6(4) . . ?
N4 C34 H34A 108.4 . . ?
N4 C34 H34B 108.4 . . ?
N4 C34 C35 115.7(5) . . ?
H34A C34 H34B 107.4 . . ?
C35 C34 H34A 108.4 . . ?
C35 C34 H34B 108.4 . . ?
C36 C35 C34 122.6(6) . . ?
C36 C35 C40 118.7(6) . . ?
C40 C35 C34 118.6(6) . . ?
C35 C36 H36 119.5 . . ?
C35 C36 C37 121.0(6) . . ?
C37 C36 H36 119.5 . . ?
C36 C37 H37 120.3 . . ?
C38 C37 C36 119.3(6) . . ?
C38 C37 H37 120.3 . . ?
C37 C38 H38 119.7 . . ?
C39 C38 C37 120.6(7) . . ?
C39 C38 H38 119.7 . . ?
C38 C39 H39 119.9 . . ?
C38 C39 C40 120.2(7) . . ?
C40 C39 H39 119.9 . . ?
C35 C40 H40 119.9 . . ?
C39 C40 C35 120.2(6) . . ?
C39 C40 H40 119.9 . . ?
C42 C41 C46 119.3(7) . . ?
C42 C41 C47 120.5(7) . . ?
C46 C41 C47 120.2(6) . . ?
C41 C42 H42 121.6 . . ?
C41 C42 C43 116.8(8) . . ?
C43 C42 H42 121.6 . . ?
C42 C43 H43 120.5 . . ?
C44 C43 C42 119.0(8) . . ?
C44 C43 H43 120.5 . . ?
C43 C44 H44 117.1 . . ?
C43 C44 C45 125.9(9) . . ?
C45 C44 H44 117.1 . . ?
C44 C45 H45 122.0 . . ?
C46 C45 C44 115.9(9) . . ?
C46 C45 H45 122.0 . . ?
C41 C46 H46 118.5 . . ?
C45 C46 C41 123.1(8) . . ?
C45 C46 H46 118.5 . . ?
N5 C47 C41 113.6(5) . . ?
N5 C47 H47A 108.9 . . ?
N5 C47 H47B 108.9 . . ?
C41 C47 H47A 108.9 . . ?
C41 C47 H47B 108.9 . . ?
H47A C47 H47B 107.7 . . ?
N5 C48 Ag1 127.2(4) . . ?
N5 C48 N6 104.4(4) . . ?
N6 C48 Ag1 127.2(4) . . ?
N6 C49 H49 126.2 . . ?
C50 C49 N6 107.6(5) . . ?
C50 C49 H49 126.2 . . ?
N5 C50 H50 126.9 . . ?
C49 C50 N5 106.3(5) . . ?
C49 C50 H50 126.9 . . ?
N6 C51 H51A 109.3 . . ?
N6 C51 H51B 109.3 . . ?
N6 C51 C52 111.6(5) . . ?
H51A C51 H51B 108.0 . . ?
C52 C51 H51A 109.3 . . ?
C52 C51 H51B 109.3 . . ?
C51 C52 H52A 109.3 . . ?
C51 C52 H52B 109.3 . . ?
H52A C52 H52B 108.0 . . ?
C53 C52 C51 111.6(5) . . ?
C53 C52 H52A 109.3 . . ?
C53 C52 H52B 109.3 . . ?
O5 C53 C52 105.8(6) . . ?
O5 C53 H53A 110.6 . . ?
O5 C53 H53B 110.6 . . ?
C52 C53 H53A 110.6 . . ?
C52 C53 H53B 110.6 . . ?
H53A C53 H53B 108.7 . . ?
O5 C54 C55 121.6(7) . . ?
O5 C54 C67 118.4(7) . . ?
C67 C54 C55 120.0(6) . . ?
C54 C55 H55 119.8 . . ?
C56 C55 C54 120.5(9) . . ?
C56 C55 H55 119.8 . . ?
C55 C56 H56 119.5 . . ?
C55 C56 C57 120.9(9) . . ?
C57 C56 H56 119.5 . . ?
O8 C57 C56 123.1(8) . . ?
O8 C57 C58 115.9(8) . . ?
C56 C57 C58 120.9(7) . . ?
C57 C58 C59 121.1(6) . . ?
C57 C58 C67 118.4(7) . . ?
C67 C58 C59 120.5(7) . . ?
O7 C59 C58 123.1(8) . . ?
O7 C59 C60 117.8(8) . . ?
C60 C59 C58 119.1(6) . . ?
C61 C60 C59 119.5(7) . . ?
C61 C60 C65 119.7(8) . . ?
C65 C60 C59 120.8(8) . . ?
C60 C61 H61 118.9 . . ?
C62 C61 C60 122.2(9) . . ?
C62 C61 H61 118.9 . . ?
C61 C62 H62 120.1 . . ?
C61 C62 C63 119.8(10) . . ?
C63 C62 H62 120.1 . . ?
C62 C63 H63 121.3 . . ?
C64 C63 C62 117.4(10) . . ?
C64 C63 H63 121.3 . . ?
C63 C64 H64 119.0 . . ?
C63 C64 C65 121.9(8) . . ?
C65 C64 H64 119.0 . . ?
C60 C65 C66 121.1(7) . . ?
C64 C65 C60 119.0(8) . . ?
C64 C65 C66 119.9(7) . . ?
O6 C66 C65 118.5(7) . . ?
O6 C66 C67 122.9(7) . . ?
C65 C66 C67 118.6(6) . . ?
C54 C67 C58 119.0(7) . . ?
C54 C67 C66 121.4(6) . . ?
C58 C67 C66 119.5(7) . . ?
O8 C68 H68A 109.8 . . ?
O8 C68 H68B 109.8 . . ?
O8 C68 C69 109.6(9) . . ?
H68A C68 H68B 108.2 . . ?
C69 C68 H68A 109.8 . . ?
C69 C68 H68B 109.8 . . ?
C68 C69 H69A 107.9 . . ?
C68 C69 H69B 107.9 . . ?
C68 C69 C70 117.7(8) . . ?
H69A C69 H69B 107.2 . . ?
C70 C69 H69A 107.9 . . ?
C70 C69 H69B 107.9 . . ?
N7 C70 C69 110.0(7) . . ?
N7 C70 H70A 109.7 . . ?
N7 C70 H70B 109.7 . . ?
C69 C70 H70A 109.7 . . ?
C69 C70 H70B 109.7 . . ?
H70A C70 H70B 108.2 . . ?
N7 C71 Ag2 126.5(4) . . ?
N8 C71 Ag2 128.3(4) . . ?
N8 C71 N7 105.1(5) . . ?
N8 C72 H72 126.3 . . ?
C73 C72 N8 107.4(6) . . ?
C73 C72 H72 126.3 . . ?
N7 C73 H73 126.5 . . ?
C72 C73 N7 106.9(6) . . ?
C72 C73 H73 126.5 . . ?
N8 C74 H74A 109.0 . . ?
N8 C74 H74B 109.0 . . ?
N8 C74 C75 113.0(5) . . ?
H74A C74 H74B 107.8 . . ?
C75 C74 H74A 109.0 . . ?
C75 C74 H74B 109.0 . . ?
C76 C75 C74 121.4(6) . . ?
C76 C75 C80 118.7(6) . . ?
C80 C75 C74 119.8(6) . . ?
C75 C76 H76 119.9 . . ?
C75 C76 C77 120.2(7) . . ?
C77 C76 H76 119.9 . . ?
C76 C77 H77 119.8 . . ?
C78 C77 C76 120.4(7) . . ?
C78 C77 H77 119.8 . . ?
C77 C78 H78 120.2 . . ?
C77 C78 C79 119.5(7) . . ?
C79 C78 H78 120.2 . . ?
C78 C79 H79 119.3 . . ?
C78 C79 C80 121.5(7) . . ?
C80 C79 H79 119.3 . . ?
C75 C80 H80 120.2 . . ?
C79 C80 C75 119.6(6) . . ?
C79 C80 H80 120.2 . . ?
Cl1 C81 H81A 112.6 . . ?
Cl1 C81 H81B 112.6 . . ?
Cl2 C81 Cl1 95.7(6) . . ?
Cl2 C81 H81A 112.6 . . ?
Cl2 C81 H81B 112.6 . . ?
H81A C81 H81B 110.1 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 C14 C15 C16 -5.9(8) . . . . ?
O1 C14 C15 C24 177.0(5) . . . . ?
O1 C14 C27 C26 179.3(6) . . . . ?
O2 C16 C17 C18 7.1(8) . . . . ?
O2 C16 C17 C22 -172.0(5) . . . . ?
O3 C23 C24 C15 177.8(6) . . . . ?
O3 C23 C24 C25 -1.4(9) . . . . ?
O4 C25 C26 C27 -179.3(6) . . . . ?
O4 C28 C29 C30 -62.8(7) . . . . ?
O5 C54 C55 C56 -179.5(7) . . . . ?
O5 C54 C67 C58 176.5(5) . . . . ?
O5 C54 C67 C66 -7.1(9) . . . . ?
O6 C66 C67 C54 -4.5(9) . . . . ?
O6 C66 C67 C58 172.0(6) . . . . ?
O7 C59 C60 C61 3.2(10) . . . . ?
O7 C59 C60 C65 -174.6(6) . . . . ?
O8 C57 C58 C59 -1.6(10) . . . . ?
O8 C57 C58 C67 179.1(7) . . . . ?
O8 C68 C69 C70 -43.3(15) . . . . ?
N1 C8 C9 N2 0.0(8) . . . . ?
N2 C11 C12 C13 59.2(6) . . . . ?
N3 C31 C32 N4 -0.1(7) . . . . ?
N4 C34 C35 C36 -52.3(8) . . . . ?
N4 C34 C35 C40 133.1(6) . . . . ?
N6 C49 C50 N5 0.8(8) . . . . ?
N6 C51 C52 C53 65.9(7) . . . . ?
N8 C72 C73 N7 -0.3(8) . . . . ?
N8 C74 C75 C76 34.6(8) . . . . ?
N8 C74 C75 C80 -148.8(5) . . . . ?
C1 C2 C3 C4 -0.6(14) . . . . ?
C2 C1 C6 C5 0.8(10) . . . . ?
C2 C1 C7 N1 -164.0(6) . . . . ?
C2 C3 C4 C5 2.5(15) . . . . ?
C3 C4 C5 C6 -2.7(14) . . . . ?
C4 C5 C6 C1 1.0(12) . . . . ?
C6 C1 C2 C3 -1.1(11) . . . . ?
C6 C1 C7 N1 16.1(9) . . . . ?
C7 N1 C8 C9 172.1(6) . . . . ?
C7 N1 C10 Ag2 11.3(8) . . . . ?
C7 N1 C10 N2 -172.5(5) . . . . ?
C7 C1 C2 C3 179.0(7) . . . . ?
C7 C1 C6 C5 -179.3(7) . . . . ?
C8 N1 C7 C1 -93.4(7) . . . . ?
C8 N1 C10 Ag2 -176.9(4) . . . . ?
C8 N1 C10 N2 -0.7(6) . . . . ?
C9 N2 C10 Ag2 176.9(4) . . . . ?
C9 N2 C10 N1 0.7(6) . . . . ?
C9 N2 C11 C12 69.9(7) . . . . ?
C10 N1 C7 C1 77.3(7) . . . . ?
C10 N1 C8 C9 0.4(8) . . . . ?
C10 N2 C9 C8 -0.5(7) . . . . ?
C10 N2 C11 C12 -106.7(6) . . . . ?
C11 N2 C9 C8 -177.5(5) . . . . ?
C11 N2 C10 Ag2 -6.1(7) . . . . ?
C11 N2 C10 N1 177.7(5) . . . . ?
C11 C12 C13 O1 62.2(7) . . . . ?
C13 O1 C14 C15 -176.5(5) . . . . ?
C13 O1 C14 C27 2.2(8) . . . . ?
C14 O1 C13 C12 -175.5(5) . . . . ?
C14 C15 C16 O2 -9.5(9) . . . . ?
C14 C15 C16 C17 173.1(5) . . . . ?
C14 C15 C24 C23 -174.4(5) . . . . ?
C14 C15 C24 C25 4.8(8) . . . . ?
C15 C14 C27 C26 -1.9(10) . . . . ?
C15 C16 C17 C18 -175.4(5) . . . . ?
C15 C16 C17 C22 5.5(8) . . . . ?
C15 C24 C25 O4 175.6(5) . . . . ?
C15 C24 C25 C26 -4.3(9) . . . . ?
C16 C15 C24 C23 8.5(8) . . . . ?
C16 C15 C24 C25 -172.3(5) . . . . ?
C16 C17 C18 C19 179.7(5) . . . . ?
C16 C17 C22 C21 -179.4(5) . . . . ?
C16 C17 C22 C23 0.0(8) . . . . ?
C17 C18 C19 C20 -0.1(9) . . . . ?
C17 C22 C23 O3 177.9(6) . . . . ?
C17 C22 C23 C24 -1.4(8) . . . . ?
C18 C17 C22 C21 1.5(8) . . . . ?
C18 C17 C22 C23 -179.1(5) . . . . ?
C18 C19 C20 C21 1.2(10) . . . . ?
C19 C20 C21 C22 -0.9(9) . . . . ?
C20 C21 C22 C17 -0.5(9) . . . . ?
C20 C21 C22 C23 -179.9(6) . . . . ?
C21 C22 C23 O3 -2.7(9) . . . . ?
C21 C22 C23 C24 178.0(5) . . . . ?
C22 C17 C18 C19 -1.2(9) . . . . ?
C22 C23 C24 C15 -2.9(8) . . . . ?
C22 C23 C24 C25 177.8(5) . . . . ?
C23 C24 C25 O4 -5.1(8) . . . . ?
C23 C24 C25 C26 175.0(6) . . . . ?
C24 C15 C16 O2 167.6(6) . . . . ?
C24 C15 C16 C17 -9.8(8) . . . . ?
C24 C25 C26 C27 0.7(10) . . . . ?
C25 O4 C28 C29 179.9(5) . . . . ?
C25 C26 C27 C14 2.5(11) . . . . ?
C27 C14 C15 C16 175.4(6) . . . . ?
C27 C14 C15 C24 -1.8(8) . . . . ?
C28 O4 C25 C24 -167.1(5) . . . . ?
C28 O4 C25 C26 12.8(8) . . . . ?
C28 C29 C30 N3 138.5(5) . . . . ?
C30 N3 C31 C32 174.8(5) . . . . ?
C30 N3 C33 Ag1 4.2(7) . . . . ?
C30 N3 C33 N4 -174.5(5) . . . . ?
C31 N3 C30 C29 -68.9(6) . . . . ?
C31 N3 C33 Ag1 178.8(4) . . . . ?
C31 N3 C33 N4 0.2(6) . . . . ?
C32 N4 C33 Ag1 -179.0(4) . . . . ?
C32 N4 C33 N3 -0.2(6) . . . . ?
C32 N4 C34 C35 154.9(6) . . . . ?
C33 N3 C30 C29 105.1(6) . . . . ?
C33 N3 C31 C32 -0.1(6) . . . . ?
C33 N4 C32 C31 0.2(6) . . . . ?
C33 N4 C34 C35 -32.3(9) . . . . ?
C34 N4 C32 C31 174.0(5) . . . . ?
C34 N4 C33 Ag1 7.6(8) . . . . ?
C34 N4 C33 N3 -173.7(5) . . . . ?
C34 C35 C36 C37 -175.7(5) . . . . ?
C34 C35 C40 C39 177.0(6) . . . . ?
C35 C36 C37 C38 -1.0(9) . . . . ?
C36 C35 C40 C39 2.2(9) . . . . ?
C36 C37 C38 C39 1.9(10) . . . . ?
C37 C38 C39 C40 -0.8(11) . . . . ?
C38 C39 C40 C35 -1.3(10) . . . . ?
C40 C35 C36 C37 -1.0(8) . . . . ?
C41 C42 C43 C44 -1.5(10) . . . . ?
C42 C41 C46 C45 -1.0(9) . . . . ?
C42 C41 C47 N5 108.8(6) . . . . ?
C42 C43 C44 C45 0.4(13) . . . . ?
C43 C44 C45 C46 0.3(13) . . . . ?
C44 C45 C46 C41 0.0(11) . . . . ?
C46 C41 C42 C43 1.7(9) . . . . ?
C46 C41 C47 N5 -73.4(7) . . . . ?
C47 N5 C48 Ag1 13.5(8) . . . . ?
C47 N5 C48 N6 -178.5(5) . . . . ?
C47 N5 C50 C49 178.5(6) . . . . ?
C47 C41 C42 C43 179.6(5) . . . . ?
C47 C41 C46 C45 -178.9(6) . . . . ?
C48 N5 C47 C41 -80.6(7) . . . . ?
C48 N5 C50 C49 -1.4(7) . . . . ?
C48 N6 C49 C50 0.0(7) . . . . ?
C48 N6 C51 C52 -99.6(6) . . . . ?
C49 N6 C48 Ag1 167.2(4) . . . . ?
C49 N6 C48 N5 -0.8(6) . . . . ?
C49 N6 C51 C52 76.9(7) . . . . ?
C50 N5 C47 C41 99.5(7) . . . . ?
C50 N5 C48 Ag1 -166.7(4) . . . . ?
C50 N5 C48 N6 1.3(6) . . . . ?
C51 N6 C48 Ag1 -15.9(8) . . . . ?
C51 N6 C48 N5 176.1(5) . . . . ?
C51 N6 C49 C50 -177.0(6) . . . . ?
C51 C52 C53 O5 61.1(8) . . . . ?
C53 O5 C54 C55 -7.2(9) . . . . ?
C53 O5 C54 C67 173.0(6) . . . . ?
C54 O5 C53 C52 -167.8(5) . . . . ?
C54 C55 C56 C57 3.8(13) . . . . ?
C55 C54 C67 C58 -3.3(9) . . . . ?
C55 C54 C67 C66 173.1(6) . . . . ?
C55 C56 C57 O8 177.9(8) . . . . ?
C55 C56 C57 C58 -4.7(13) . . . . ?
C56 C57 C58 C59 -179.2(7) . . . . ?
C56 C57 C58 C67 1.5(11) . . . . ?
C57 O8 C68 C69 -162.5(9) . . . . ?
C57 C58 C59 O7 -5.9(10) . . . . ?
C57 C58 C59 C60 174.3(6) . . . . ?
C57 C58 C67 C54 2.5(9) . . . . ?
C57 C58 C67 C66 -174.1(6) . . . . ?
C58 C59 C60 C61 -177.0(6) . . . . ?
C58 C59 C60 C65 5.2(9) . . . . ?
C59 C58 C67 C54 -176.8(5) . . . . ?
C59 C58 C67 C66 6.6(8) . . . . ?
C59 C60 C61 C62 -179.8(8) . . . . ?
C59 C60 C65 C64 178.1(6) . . . . ?
C59 C60 C65 C66 -4.2(9) . . . . ?
C60 C61 C62 C63 1.8(13) . . . . ?
C60 C65 C66 O6 -173.3(6) . . . . ?
C60 C65 C66 C67 4.3(9) . . . . ?
C61 C60 C65 C64 0.3(10) . . . . ?
C61 C60 C65 C66 177.9(6) . . . . ?
C61 C62 C63 C64 -0.1(14) . . . . ?
C62 C63 C64 C65 -1.5(13) . . . . ?
C63 C64 C65 C60 1.4(11) . . . . ?
C63 C64 C65 C66 -176.3(7) . . . . ?
C64 C65 C66 O6 4.4(9) . . . . ?
C64 C65 C66 C67 -178.1(6) . . . . ?
C65 C60 C61 C62 -1.9(12) . . . . ?
C65 C66 C67 C54 178.1(5) . . . . ?
C65 C66 C67 C58 -5.4(8) . . . . ?
C67 C54 C55 C56 0.3(11) . . . . ?
C67 C58 C59 O7 173.4(7) . . . . ?
C67 C58 C59 C60 -6.5(9) . . . . ?
C68 O8 C57 C56 -10.1(15) . . . . ?
C68 O8 C57 C58 172.4(9) . . . . ?
C68 C69 C70 N7 141.0(9) . . . . ?
C70 N7 C71 Ag2 8.1(9) . . . . ?
C70 N7 C71 N8 -174.3(6) . . . . ?
C70 N7 C73 C72 174.2(7) . . . . ?
C71 N7 C70 C69 87.7(8) . . . . ?
C71 N7 C73 C72 1.0(8) . . . . ?
C71 N8 C72 C73 -0.5(8) . . . . ?
C71 N8 C74 C75 -105.5(6) . . . . ?
C72 N8 C71 Ag2 178.6(5) . . . . ?
C72 N8 C71 N7 1.0(7) . . . . ?
C72 N8 C74 C75 68.9(7) . . . . ?
C73 N7 C70 C69 -84.5(8) . . . . ?
C73 N7 C71 Ag2 -178.8(4) . . . . ?
C73 N7 C71 N8 -1.2(7) . . . . ?
C74 N8 C71 Ag2 -6.3(8) . . . . ?
C74 N8 C71 N7 176.1(5) . . . . ?
C74 N8 C72 C73 -175.7(6) . . . . ?
C74 C75 C76 C77 177.0(6) . . . . ?
C74 C75 C80 C79 -175.5(6) . . . . ?
C75 C76 C77 C78 -1.9(11) . . . . ?
C76 C75 C80 C79 1.2(9) . . . . ?
C76 C77 C78 C79 1.9(11) . . . . ?
C77 C78 C79 C80 -0.3(11) . . . . ?
C78 C79 C80 C75 -1.3(10) . . . . ?
C80 C75 C76 C77 0.3(9) . . . . ?

_shelx_SHELXL_version_number     2014/7

_olex2_submission_special_instructions 'No special instructions were received'
