# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_10a
_database_code_depnum_ccdc_archive 'CCDC 1543568'
_audit_update_record             
;
2017-04-12 deposited with the CCDC.
2017-09-13 downloaded from the CCDC.
;
_audit_creation_date             2017-04-11
_audit_creation_method           
;
Olex2 1.2
(compiled 2017.03.28 svn.r3405 for OlexSys, GUI svn.r5335)
;
_shelx_SHELXL_version_number     2014/7
# start Validation Reply Form
_vrf_DIFMX02_10a                 
;
PROBLEM: The maximum difference density is > 0.1*ZMAX*0.75
RESPONSE: 
The nearest atom to the maximum is carbon C2;
the C2-maximum distance is 0.841 Ang.
;
# CHEMICAL DATA 

_chemical_name_common            ?
_chemical_name_systematic        
5-(N-benzyl)amino-5-deoxy-1,2-O-isopropylidene-3-O-methyl-a-D-xylo-furanosyl)-(R,S)-2,3,3,3-tetrafluoropropanamide
_chemical_formula_moiety         'C19 H23 F4 N O5'
_chemical_formula_sum            'C19 H23 F4 N O5'
_chemical_formula_weight         421.38
_chemical_absolute_configuration syn
_chemical_melting_point          ?
_chemical_oxdiff_formula         'C19 H22 O5 F4 N1'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

# CRYSTAL DATA

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           1
_space_group_name_H-M_alt        'P 1'
_space_group_name_Hall           'P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'

_cell_length_a                   6.0766(4)
_cell_length_b                   9.4360(3)
_cell_length_c                   9.7318(4)
_cell_angle_alpha                73.389(3)
_cell_angle_beta                 72.298(4)
_cell_angle_gamma                84.890(4)
_cell_volume                     509.41(4)
_cell_formula_units_Z            1
_cell_measurement_reflns_used    5511
_cell_measurement_temperature    295(2)
_cell_measurement_theta_max      73.9380
_cell_measurement_theta_min      4.8680
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    1.062
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.84806
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.31 (release 14-01-2014 CrysAlis171 .NET)
(compiled Jan 14 2014,18:38:05)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.374
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       irregular
_exptl_crystal_F_000             220
_exptl_crystal_recrystallization_method ?
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.03
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0222
_diffrn_reflns_av_unetI/netI     0.0163
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       6
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            12459
_diffrn_reflns_point_group_measured_fraction_full 0.968
_diffrn_reflns_point_group_measured_fraction_max 0.958
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         74.489
_diffrn_reflns_theta_min         4.891
_diffrn_ambient_temperature      295(2)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 10.5357
_diffrn_detector_type            Atlas
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_details      
;
#__ type_ start__ end____ width___ exp.time_
  1 omega    0.00   25.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       38.0000   90.0000  -54.0860 25

#__ type_ start__ end____ width___ exp.time_
  2 omega  -51.00  -11.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      -40.5879  -57.0000   90.0000 40

#__ type_ start__ end____ width___ exp.time_
  3 omega  -97.00   -3.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      -40.5879  125.0000  -90.0000 94

#__ type_ start__ end____ width___ exp.time_
  4 omega -115.00  -57.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      -40.5879  -57.0000   90.0000 58

#__ type_ start__ end____ width___ exp.time_
  5 omega   49.00  115.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       40.5879   37.0000 -120.0000 66

#__ type_ start__ end____ width___ exp.time_
  6 omega   14.00   45.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       40.5879   37.0000 -120.0000 31

#__ type_ start__ end____ width___ exp.time_
  7 omega  -38.00   74.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       40.5879  -77.0000  120.0000 112

#__ type_ start__ end____ width___ exp.time_
  8 omega   12.00   39.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       40.5879   57.0000 -150.0000 27

#__ type_ start__ end____ width___ exp.time_
  9 omega   10.00   35.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       46.0000   84.0000  -56.4379 25

#__ type_ start__ end____ width___ exp.time_
 10 omega   11.00   36.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       46.0000   82.0000    2.4383 25

#__ type_ start__ end____ width___ exp.time_
 11 omega   10.00   36.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       46.0000   85.0000   56.3038 26

#__ type_ start__ end____ width___ exp.time_
 12 omega   11.00   38.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       46.0000   84.0000  -33.7212 27

#__ type_ start__ end____ width___ exp.time_
 13 omega   16.00   45.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       46.0000   81.0000 -142.7281 29

#__ type_ start__ end____ width___ exp.time_
 14 omega   10.00   35.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       46.0000   84.0000  139.4277 25

#__ type_ start__ end____ width___ exp.time_
 15 omega  -87.00  -39.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -70.0000  -75.0000  -37.4201 48

#__ type_ start__ end____ width___ exp.time_
 16 omega  -82.00  -37.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -70.0000  -74.0000   37.6717 45

#__ type_ start__ end____ width___ exp.time_
 17 omega -122.00  -89.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -70.0000  -74.0000   37.6717 33

#__ type_ start__ end____ width___ exp.time_
 18 omega -122.00  -95.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -70.0000  -77.0000 -165.2800 27

#__ type_ start__ end____ width___ exp.time_
 19 omega  -66.00  -36.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -70.0000  -77.0000 -165.2800 30

#__ type_ start__ end____ width___ exp.time_
 20 omega  -66.00  -41.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -74.0000  -72.0000  148.0633 25

#__ type_ start__ end____ width___ exp.time_
 21 omega  -67.00  -41.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -74.0000  -73.0000  105.3391 26

#__ type_ start__ end____ width___ exp.time_
 22 omega -150.00 -114.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -74.0000  -73.0000  105.3391 36

#__ type_ start__ end____ width___ exp.time_
 23 omega  -71.00  -45.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -78.0000  -72.0000 -101.0152 26

#__ type_ start__ end____ width___ exp.time_
 24 omega  -78.00  -45.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -78.0000  -72.0000  -71.4933 33

#__ type_ start__ end____ width___ exp.time_
 25 omega  -77.00  -45.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -78.0000  -72.0000    4.8705 32

#__ type_ start__ end____ width___ exp.time_
 26 omega  -86.00  -50.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -83.0000  -77.0000  120.0000 36

#__ type_ start__ end____ width___ exp.time_
 27 omega  -84.00  -50.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -83.0000  -77.0000   30.0000 34

#__ type_ start__ end____ width___ exp.time_
 28 omega  -77.00  -50.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -83.0000  -74.0000 -113.7276 27

#__ type_ start__ end____ width___ exp.time_
 29 omega  -77.00  -50.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -83.0000  -75.0000  -54.8740 27

#__ type_ start__ end____ width___ exp.time_
 30 omega  -78.00  -51.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -83.0000  -75.0000  -84.6393 27

#__ type_ start__ end____ width___ exp.time_
 31 omega  -76.00  -27.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -83.0000   45.0000  120.0000 49

#__ type_ start__ end____ width___ exp.time_
 32 omega  -78.00  -51.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -83.0000  -68.0000   86.0731 27

#__ type_ start__ end____ width___ exp.time_
 33 omega  -90.00  -49.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -83.0000  -77.0000  150.0000 41

#__ type_ start__ end____ width___ exp.time_
 34 omega  -76.00  -51.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -83.0000  -69.0000   57.5236 25

#__ type_ start__ end____ width___ exp.time_
 35 omega  -81.00  -50.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -83.0000  -77.0000 -150.0000 31

#__ type_ start__ end____ width___ exp.time_
 36 omega  -85.00  -49.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -83.0000  -77.0000 -180.0000 36

#__ type_ start__ end____ width___ exp.time_
 37 omega  -74.00  -49.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -83.0000  -77.0000   90.0000 25

#__ type_ start__ end____ width___ exp.time_
 38 omega -144.00 -117.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -83.0000  -69.0000   57.5236 27

#__ type_ start__ end____ width___ exp.time_
 39 omega -102.00  -50.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -83.0000  -75.0000   -7.8796 52

#__ type_ start__ end____ width___ exp.time_
 40 omega  -83.00  -50.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -83.0000  -73.0000   38.9362 33

#__ type_ start__ end____ width___ exp.time_
 41 omega  -77.00  -50.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -83.0000  -77.0000 -120.0000 27

#__ type_ start__ end____ width___ exp.time_
 42 omega   38.00   63.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000  -45.0000   90.0000 25

#__ type_ start__ end____ width___ exp.time_
 43 omega   42.00   69.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000  -30.0000   30.0000 27

#__ type_ start__ end____ width___ exp.time_
 44 omega   79.00  156.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   77.0000 -150.0000 77

#__ type_ start__ end____ width___ exp.time_
 45 omega   82.00  137.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   77.0000  120.0000 55

#__ type_ start__ end____ width___ exp.time_
 46 omega  121.00  149.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   77.0000    0.0000 28

#__ type_ start__ end____ width___ exp.time_
 47 omega   83.00  110.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   77.0000    0.0000 27

#__ type_ start__ end____ width___ exp.time_
 48 omega   85.00  112.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000 -111.0000 -150.0000 27

#__ type_ start__ end____ width___ exp.time_
 49 omega   53.00   81.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000 -111.0000 -150.0000 28

#__ type_ start__ end____ width___ exp.time_
 50 omega   80.00  136.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   77.0000  -90.0000 56

#__ type_ start__ end____ width___ exp.time_
 51 omega   36.00   86.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000 -111.0000   60.0000 50

#__ type_ start__ end____ width___ exp.time_
 52 omega   83.00  115.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   61.0000  -30.0000 32

#__ type_ start__ end____ width___ exp.time_
 53 omega   80.00  110.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   77.0000  150.0000 30

#__ type_ start__ end____ width___ exp.time_
 54 omega  114.00  152.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   77.0000  150.0000 38

#__ type_ start__ end____ width___ exp.time_
 55 omega  109.00  136.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000  -61.0000 -150.0000 27

#__ type_ start__ end____ width___ exp.time_
 56 omega   90.00  116.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000 -111.0000 -180.0000 26

#__ type_ start__ end____ width___ exp.time_
 57 omega  119.00  155.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   61.0000  -90.0000 36

#__ type_ start__ end____ width___ exp.time_
 58 omega   88.00  115.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   61.0000  -90.0000 27

#__ type_ start__ end____ width___ exp.time_
 59 omega   37.00   85.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000 -111.0000 -180.0000 48

#__ type_ start__ end____ width___ exp.time_
 60 omega   79.00  135.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   77.0000 -120.0000 56

#__ type_ start__ end____ width___ exp.time_
 61 omega   61.00   91.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000  -61.0000 -150.0000 30

#__ type_ start__ end____ width___ exp.time_
 62 omega   85.00  112.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   61.0000  -60.0000 27

#__ type_ start__ end____ width___ exp.time_
 63 omega   36.00   64.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000  -30.0000 -150.0000 28

#__ type_ start__ end____ width___ exp.time_
 64 omega   88.00  115.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   45.0000  -30.0000 27

#__ type_ start__ end____ width___ exp.time_
 65 omega   45.00   79.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000 -111.0000   30.0000 34

#__ type_ start__ end____ width___ exp.time_
 66 omega   36.00   68.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000  -30.0000  120.0000 32

#__ type_ start__ end____ width___ exp.time_
 67 omega   41.00   68.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000  -30.0000  -90.0000 27

#__ type_ start__ end____ width___ exp.time_
 68 omega   29.00  109.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000  -94.0000 -120.0000 80

#__ type_ start__ end____ width___ exp.time_
 69 omega   89.00  125.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   61.0000  150.0000 36

#__ type_ start__ end____ width___ exp.time_
 70 omega   85.00  121.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   61.0000   90.0000 36

#__ type_ start__ end____ width___ exp.time_
 71 omega  125.00  152.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   77.0000   30.0000 27

#__ type_ start__ end____ width___ exp.time_
 72 omega   80.00  105.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   77.0000   30.0000 25

#__ type_ start__ end____ width___ exp.time_
 73 omega   35.00   60.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000  -30.0000   60.0000 25

#__ type_ start__ end____ width___ exp.time_
 74 omega   68.00  114.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000 -111.0000    0.0000 46

#__ type_ start__ end____ width___ exp.time_
 75 omega  120.00  157.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   77.0000 -180.0000 37

#__ type_ start__ end____ width___ exp.time_
 76 omega   44.00   83.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000  -94.0000  120.0000 39

#__ type_ start__ end____ width___ exp.time_
 77 omega   85.00  111.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   45.0000   30.0000 26

#__ type_ start__ end____ width___ exp.time_
 78 omega  129.00  156.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   45.0000   30.0000 27

#__ type_ start__ end____ width___ exp.time_
 79 omega  133.00  158.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   61.0000   30.0000 25

#__ type_ start__ end____ width___ exp.time_
 80 omega   79.00  105.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   77.0000 -180.0000 26

#__ type_ start__ end____ width___ exp.time_
 81 omega   87.00  114.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   61.0000   30.0000 27

#__ type_ start__ end____ width___ exp.time_
 82 omega   91.00  116.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000 -111.0000   90.0000 25

#__ type_ start__ end____ width___ exp.time_
 83 omega  114.00  157.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   77.0000   90.0000 43

#__ type_ start__ end____ width___ exp.time_
 84 omega   38.00   83.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000 -111.0000   90.0000 45

#__ type_ start__ end____ width___ exp.time_
 85 omega  125.00  158.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   77.0000   60.0000 33

#__ type_ start__ end____ width___ exp.time_
 86 omega   80.00  113.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   77.0000   90.0000 33

#__ type_ start__ end____ width___ exp.time_
 87 omega   82.00  121.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   77.0000   60.0000 39

#__ type_ start__ end____ width___ exp.time_
 88 omega   87.00  122.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   61.0000 -150.0000 35

#__ type_ start__ end____ width___ exp.time_
 89 omega   35.00   63.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000  -30.0000  -60.0000 28

#__ type_ start__ end____ width___ exp.time_
 90 omega  120.00  151.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   77.0000  -30.0000 31

#__ type_ start__ end____ width___ exp.time_
 91 omega   49.00  108.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000  -94.0000   90.0000 59

#__ type_ start__ end____ width___ exp.time_
 92 omega  116.00  154.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   45.0000    0.0000 38

#__ type_ start__ end____ width___ exp.time_
 93 omega   87.00  114.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   61.0000 -180.0000 27

#__ type_ start__ end____ width___ exp.time_
 94 omega  120.00  150.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   61.0000 -180.0000 30

#__ type_ start__ end____ width___ exp.time_
 95 omega   81.00  118.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   77.0000  -30.0000 37

#__ type_ start__ end____ width___ exp.time_
 96 omega  127.00  157.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   61.0000  -60.0000 30

#__ type_ start__ end____ width___ exp.time_
 97 omega   87.00  114.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   61.0000   60.0000 27

#__ type_ start__ end____ width___ exp.time_
 98 omega   87.00  112.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   61.0000  120.0000 25

#__ type_ start__ end____ width___ exp.time_
 99 omega   33.00   77.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000  -94.0000 -150.0000 44

#__ type_ start__ end____ width___ exp.time_
100 omega   36.00   99.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000  -94.0000  -60.0000 63

#__ type_ start__ end____ width___ exp.time_
101 omega    1.00   34.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       38.0000   87.0000 -176.3199 33

#__ type_ start__ end____ width___ exp.time_
102 omega    0.00   32.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       38.0000   90.0000   92.5541 32

#__ type_ start__ end____ width___ exp.time_
103 omega -119.00   -7.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      -40.5879  -77.0000    0.0000 112

#__ type_ start__ end____ width___ exp.time_
104 omega -113.00  -66.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      -40.5879 -137.0000  144.0000 47

#__ type_ start__ end____ width___ exp.time_
105 omega  -33.00   70.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       40.5879  -57.0000   30.0000 103

#__ type_ start__ end____ width___ exp.time_
106 omega  -41.00   87.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       40.5879  -19.0000 -180.0000 128

#__ type_ start__ end____ width___ exp.time_
107 omega   10.00   36.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       46.0000   85.0000   56.3038 26

#__ type_ start__ end____ width___ exp.time_
108 omega   10.00   38.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       46.0000   84.0000  -56.4379 28

#__ type_ start__ end____ width___ exp.time_
109 omega   10.00   38.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       46.0000   84.0000  139.4277 28

#__ type_ start__ end____ width___ exp.time_
110 omega   11.00   46.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       46.0000   81.0000 -142.7281 35

#__ type_ start__ end____ width___ exp.time_
111 omega   36.00  149.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       70.0000   77.0000 -126.7031 113
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Single source at offset, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      -0.0000932000
_diffrn_orient_matrix_UB_12      -0.1699439000
_diffrn_orient_matrix_UB_13      0.0583768000
_diffrn_orient_matrix_UB_21      -0.0823643000
_diffrn_orient_matrix_UB_22      0.0116597000
_diffrn_orient_matrix_UB_23      0.1625530000
_diffrn_orient_matrix_UB_31      -0.2530572000
_diffrn_orient_matrix_UB_32      -0.0033111000
_diffrn_orient_matrix_UB_33      0.0000909000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'sealed X-ray tube'
_diffrn_source_type              'SuperNova (Cu) X-ray Source'
_reflns_Friedel_coverage         0.918
_reflns_Friedel_fraction_full    0.936
_reflns_Friedel_fraction_max     0.917
_reflns_number_gt                3480
_reflns_number_total             4002
_reflns_odcompleteness_completeness 99.90
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     74.33
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.31 (release 14-01-2014 CrysAlis171 .NET)
(compiled Jan 14 2014,18:38:05)
;
_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.31 (release 14-01-2014 CrysAlis171 .NET)
(compiled Jan 14 2014,18:38:05)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.31 (release 14-01-2014 CrysAlis171 .NET)
(compiled Jan 14 2014,18:38:05)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'

# REFINEMENT DATA

_refine_diff_density_max         0.690
_refine_diff_density_min         -0.585
_refine_diff_density_rms         0.058
_refine_ls_abs_structure_details 
;
 Flack x determined using 1460 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.16(6)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.106
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     251
_refine_ls_number_reflns         4002
_refine_ls_number_restraints     8
_refine_ls_R_factor_all          0.0838
_refine_ls_R_factor_gt           0.0782
_refine_ls_restrained_S_all      1.139
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1830P)²+0.0340P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2411
_refine_ls_wR_factor_ref         0.2534
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 F1-C2
 1.32 with sigma of 0.005
 F4-C3
 1.32 with sigma of 0.005
 F2-C3
 1.32 with sigma of 0.005
 F3-C3
 1.32 with sigma of 0.005
 C1-C2
 1.5 with sigma of 0.02
3. Others
 Fixed U11: C2(0.324227) C3(0.309125)
4.a Ternary CH refined with riding coordinates:
 C2(H2), C12(H12), C13(H13), C14(H14), C15(H15)
4.b Secondary CH2 refined with riding coordinates:
 C4(H4A,H4B), C11(H11A,H11B)
4.c Aromatic/amide H refined with riding coordinates:
 C6(H6), C7(H7), C8(H8), C9(H9), C10(H10)
4.d Fitted hexagon refined as free rotating group:
 C5(C6,C7,C8,C9,C10)
4.e Idealised Me refined as rotating group:
 C17(H17A,H17B,H17C), C18(H18A,H18B,H18C), C19(H19A,H19B,H19C)
;

# ATOMIC COORDINATES AND DISPLACEMENT PARAMETERS

_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.0648(19) 0.6636(6) -0.1021(7) 0.111(3) Uani 1 1 d D . . . .
C2 C -0.0271(16) 0.6456(9) -0.2344(10) 0.1616(14) Uani 1 1 d D . . . .
H2 H -0.0058 0.5436 -0.2416 0.194 Uiso 1 1 calc R . . . .
C3 C 0.1226(17) 0.7502(8) -0.3755(10) 0.177(2) Uani 1 1 d D . . . .
C4 C 0.2733(17) 0.6061(9) 0.0838(8) 0.102(2) Uani 1 1 d . . . . .
H4A H 0.2427 0.7101 0.0771 0.123 Uiso 1 1 calc R . . . .
H4B H 0.4380 0.5905 0.0684 0.123 Uiso 1 1 calc R . . . .
C5 C 0.1499(7) 0.5184(5) 0.2386(4) 0.0797(14) Uani 1 1 d . . . . .
C6 C -0.0872(8) 0.5362(7) 0.2944(5) 0.101(2) Uani 1 1 d G . . . .
H6 H -0.1685 0.5983 0.2336 0.121 Uiso 1 1 calc R . . . .
C7 C -0.2028(8) 0.4610(9) 0.4410(6) 0.126(3) Uani 1 1 d G . . . .
H7 H -0.3614 0.4729 0.4783 0.151 Uiso 1 1 calc R . . . .
C8 C -0.0813(13) 0.3682(8) 0.5317(5) 0.126(3) Uani 1 1 d G . . . .
H8 H -0.1586 0.3179 0.6298 0.151 Uiso 1 1 calc R . . . .
C9 C 0.1558(13) 0.3505(8) 0.4759(6) 0.140(4) Uani 1 1 d G . . . .
H9 H 0.2371 0.2883 0.5367 0.168 Uiso 1 1 calc R . . . .
C10 C 0.2714(8) 0.4256(7) 0.3294(6) 0.112(2) Uani 1 1 d G . . . .
H10 H 0.4301 0.4137 0.2920 0.134 Uiso 1 1 calc R . . . .
C11 C 0.3118(13) 0.4352(7) -0.0784(7) 0.0870(16) Uani 1 1 d . . . . .
H11A H 0.4571 0.4136 -0.0544 0.104 Uiso 1 1 calc R . . . .
H11B H 0.3436 0.4497 -0.1854 0.104 Uiso 1 1 calc R . . . .
C12 C 0.1504(10) 0.3047(5) 0.0055(5) 0.0690(11) Uani 1 1 d . . . . .
H12 H 0.1135 0.2928 0.1135 0.083 Uiso 1 1 calc R . . . .
C13 C 0.2405(9) 0.1590(5) -0.0270(5) 0.0667(11) Uani 1 1 d . . . . .
H13 H 0.3401 0.1093 0.0351 0.080 Uiso 1 1 calc R . . . .
C14 C 0.0175(9) 0.0736(5) 0.0170(5) 0.0644(10) Uani 1 1 d . . . . .
H14 H 0.0268 0.0018 -0.0402 0.077 Uiso 1 1 calc R . . . .
C15 C -0.1634(9) 0.1937(5) -0.0055(5) 0.0684(11) Uani 1 1 d . . . . .
H15 H -0.2199 0.1901 -0.0887 0.082 Uiso 1 1 calc R . . . .
C16 C -0.2895(10) 0.0333(6) 0.2307(6) 0.0735(12) Uani 1 1 d . . . . .
C17 C -0.3382(19) 0.0592(12) 0.3831(10) 0.112(2) Uani 1 1 d . . . . .
H17A H -0.2904 -0.0258 0.4495 0.169 Uiso 1 1 calc GR . . . .
H17B H -0.5007 0.0754 0.4224 0.169 Uiso 1 1 calc GR . . . .
H17C H -0.2544 0.1445 0.3744 0.169 Uiso 1 1 calc GR . . . .
C18 C -0.4273(14) -0.0950(7) 0.2372(9) 0.0940(18) Uani 1 1 d . . . . .
H18A H -0.3898 -0.1102 0.1393 0.141 Uiso 1 1 calc GR . . . .
H18B H -0.5892 -0.0738 0.2708 0.141 Uiso 1 1 calc GR . . . .
H18C H -0.3905 -0.1826 0.3058 0.141 Uiso 1 1 calc GR . . . .
C19 C 0.4737(15) 0.0547(10) -0.2168(9) 0.103(2) Uani 1 1 d . . . . .
H19A H 0.5550 0.0778 -0.3218 0.155 Uiso 1 1 calc GR . . . .
H19B H 0.3614 -0.0208 -0.1926 0.155 Uiso 1 1 calc GR . . . .
H19C H 0.5813 0.0200 -0.1597 0.155 Uiso 1 1 calc GR . . . .
F1 F -0.2496(9) 0.6917(13) -0.2292(8) 0.165(3) Uani 1 1 d D . . . .
F2 F 0.0623(14) 0.8900(5) -0.3707(6) 0.140(2) Uani 1 1 d D . . . .
F3 F 0.0413(19) 0.7393(8) -0.4855(7) 0.170(3) Uani 1 1 d D . . . .
F4 F 0.3380(9) 0.6953(11) -0.3782(7) 0.149(3) Uani 1 1 d D . . . .
N1 N 0.2129(11) 0.5723(5) -0.0400(5) 0.0889(15) Uani 1 1 d . . . . .
O1 O -0.0356(18) 0.7633(6) -0.0527(8) 0.143(3) Uani 1 1 d . . . . .
O2 O -0.0588(7) 0.3317(4) -0.0370(5) 0.0808(10) Uani 1 1 d . . . . .
O3 O -0.3448(7) 0.1645(4) 0.1294(4) 0.0779(9) Uani 1 1 d . . . . .
O4 O -0.0510(7) 0.0100(4) 0.1742(4) 0.0759(9) Uani 1 1 d . . . . .
O5 O 0.3596(8) 0.1844(5) -0.1813(4) 0.0838(11) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.605(10) . ?
C1 N1 1.346(11) . ?
C1 O1 1.211(10) . ?
C2 H2 0.9800 . ?
C2 C3 1.521(14) . ?
C2 F1 1.373(7) . ?
C3 F2 1.347(6) . ?
C3 F3 1.340(6) . ?
C3 F4 1.360(7) . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
C4 C5 1.492(8) . ?
C4 N1 1.482(8) . ?
C5 C6 1.3900 . ?
C5 C10 1.3900 . ?
C6 H6 0.9300 . ?
C6 C7 1.3900 . ?
C7 H7 0.9300 . ?
C7 C8 1.3900 . ?
C8 H8 0.9300 . ?
C8 C9 1.3900 . ?
C9 H9 0.9300 . ?
C9 C10 1.3900 . ?
C10 H10 0.9300 . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C11 C12 1.516(7) . ?
C11 N1 1.476(8) . ?
C12 H12 0.9800 . ?
C12 C13 1.516(7) . ?
C12 O2 1.433(7) . ?
C13 H13 0.9800 . ?
C13 C14 1.521(7) . ?
C13 O5 1.414(6) . ?
C14 H14 0.9800 . ?
C14 C15 1.525(7) . ?
C14 O4 1.417(6) . ?
C15 H15 0.9800 . ?
C15 O2 1.412(6) . ?
C15 O3 1.407(7) . ?
C16 C17 1.508(10) . ?
C16 C18 1.508(9) . ?
C16 O3 1.431(6) . ?
C16 O4 1.407(7) . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C19 H19A 0.9600 . ?
C19 H19B 0.9600 . ?
C19 H19C 0.9600 . ?
C19 O5 1.429(9) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 C1 C2 126.1(5) . . ?
O1 C1 C2 110.7(7) . . ?
O1 C1 N1 122.8(6) . . ?
C1 C2 H2 110.3 . . ?
C3 C2 C1 104.5(7) . . ?
C3 C2 H2 110.3 . . ?
F1 C2 C1 116.2(7) . . ?
F1 C2 H2 110.3 . . ?
F1 C2 C3 104.8(6) . . ?
F2 C3 C2 108.2(7) . . ?
F2 C3 F4 122.7(9) . . ?
F3 C3 C2 104.6(8) . . ?
F3 C3 F2 101.3(6) . . ?
F3 C3 F4 116.7(9) . . ?
F4 C3 C2 102.0(6) . . ?
H4A C4 H4B 107.4 . . ?
C5 C4 H4A 108.3 . . ?
C5 C4 H4B 108.3 . . ?
N1 C4 H4A 108.3 . . ?
N1 C4 H4B 108.3 . . ?
N1 C4 C5 116.1(5) . . ?
C6 C5 C4 119.3(5) . . ?
C6 C5 C10 120.0 . . ?
C10 C5 C4 120.6(5) . . ?
C5 C6 H6 120.0 . . ?
C5 C6 C7 120.0 . . ?
C7 C6 H6 120.0 . . ?
C6 C7 H7 120.0 . . ?
C8 C7 C6 120.0 . . ?
C8 C7 H7 120.0 . . ?
C7 C8 H8 120.0 . . ?
C7 C8 C9 120.0 . . ?
C9 C8 H8 120.0 . . ?
C8 C9 H9 120.0 . . ?
C10 C9 C8 120.0 . . ?
C10 C9 H9 120.0 . . ?
C5 C10 H10 120.0 . . ?
C9 C10 C5 120.0 . . ?
C9 C10 H10 120.0 . . ?
H11A C11 H11B 107.9 . . ?
C12 C11 H11A 109.2 . . ?
C12 C11 H11B 109.2 . . ?
N1 C11 H11A 109.2 . . ?
N1 C11 H11B 109.2 . . ?
N1 C11 C12 111.9(5) . . ?
C11 C12 H12 109.1 . . ?
C13 C12 C11 115.2(5) . . ?
C13 C12 H12 109.1 . . ?
O2 C12 C11 109.5(4) . . ?
O2 C12 H12 109.1 . . ?
O2 C12 C13 104.8(4) . . ?
C12 C13 H13 111.1 . . ?
C12 C13 C14 101.6(4) . . ?
C14 C13 H13 111.1 . . ?
O5 C13 C12 109.4(4) . . ?
O5 C13 H13 111.1 . . ?
O5 C13 C14 112.1(4) . . ?
C13 C14 H14 113.3 . . ?
C13 C14 C15 104.0(4) . . ?
C15 C14 H14 113.3 . . ?
O4 C14 C13 108.8(4) . . ?
O4 C14 H14 113.3 . . ?
O4 C14 C15 103.1(4) . . ?
C14 C15 H15 110.3 . . ?
O2 C15 C14 107.8(4) . . ?
O2 C15 H15 110.3 . . ?
O3 C15 C14 106.4(4) . . ?
O3 C15 H15 110.3 . . ?
O3 C15 O2 111.7(4) . . ?
C17 C16 C18 111.4(7) . . ?
O3 C16 C17 109.1(6) . . ?
O3 C16 C18 109.7(5) . . ?
O4 C16 C17 108.9(6) . . ?
O4 C16 C18 111.2(5) . . ?
O4 C16 O3 106.2(4) . . ?
C16 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
C16 C17 H17C 109.5 . . ?
H17A C17 H17B 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C16 C18 H18A 109.5 . . ?
C16 C18 H18B 109.5 . . ?
C16 C18 H18C 109.5 . . ?
H18A C18 H18B 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
H19A C19 H19B 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
O5 C19 H19A 109.5 . . ?
O5 C19 H19B 109.5 . . ?
O5 C19 H19C 109.5 . . ?
C1 N1 C4 118.0(6) . . ?
C1 N1 C11 125.6(5) . . ?
C11 N1 C4 116.3(6) . . ?
C15 O2 C12 107.9(4) . . ?
C15 O3 C16 108.5(4) . . ?
C16 O4 C14 108.7(4) . . ?
C13 O5 C19 112.4(5) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 C2 C3 F2 -70.6(8) . . . . ?
C1 C2 C3 F3 -178.0(7) . . . . ?
C1 C2 C3 F4 60.0(8) . . . . ?
C2 C1 N1 C4 -178.7(8) . . . . ?
C2 C1 N1 C11 -2.4(12) . . . . ?
C4 C5 C6 C7 -176.7(5) . . . . ?
C4 C5 C10 C9 176.7(5) . . . . ?
C5 C4 N1 C1 100.3(9) . . . . ?
C5 C4 N1 C11 -76.3(9) . . . . ?
C5 C6 C7 C8 0.0 . . . . ?
C6 C5 C10 C9 0.0 . . . . ?
C6 C7 C8 C9 0.0 . . . . ?
C7 C8 C9 C10 0.0 . . . . ?
C8 C9 C10 C5 0.0 . . . . ?
C10 C5 C6 C7 0.0 . . . . ?
C11 C12 C13 C14 -157.6(5) . . . . ?
C11 C12 C13 O5 -38.9(6) . . . . ?
C11 C12 O2 C15 158.0(4) . . . . ?
C12 C11 N1 C1 -83.8(8) . . . . ?
C12 C11 N1 C4 92.5(7) . . . . ?
C12 C13 C14 C15 26.8(4) . . . . ?
C12 C13 C14 O4 -82.6(4) . . . . ?
C12 C13 O5 C19 172.8(5) . . . . ?
C13 C12 O2 C15 33.9(5) . . . . ?
C13 C14 C15 O2 -7.8(5) . . . . ?
C13 C14 C15 O3 -127.8(4) . . . . ?
C13 C14 O4 C16 135.3(4) . . . . ?
C14 C13 O5 C19 -75.3(7) . . . . ?
C14 C15 O2 C12 -16.1(5) . . . . ?
C14 C15 O3 C16 -1.4(5) . . . . ?
C15 C14 O4 C16 25.3(5) . . . . ?
C17 C16 O3 C15 134.3(6) . . . . ?
C17 C16 O4 C14 -144.5(6) . . . . ?
C18 C16 O3 C15 -103.3(5) . . . . ?
C18 C16 O4 C14 92.3(5) . . . . ?
F1 C2 C3 F2 52.1(9) . . . . ?
F1 C2 C3 F3 -55.3(9) . . . . ?
F1 C2 C3 F4 -177.3(7) . . . . ?
N1 C1 C2 C3 -99.0(9) . . . . ?
N1 C1 C2 F1 146.1(9) . . . . ?
N1 C4 C5 C6 -65.8(9) . . . . ?
N1 C4 C5 C10 117.5(8) . . . . ?
N1 C11 C12 C13 -179.5(5) . . . . ?
N1 C11 C12 O2 62.7(6) . . . . ?
O1 C1 C2 C3 88.2(9) . . . . ?
O1 C1 C2 F1 -26.7(12) . . . . ?
O1 C1 N1 C4 -6.7(12) . . . . ?
O1 C1 N1 C11 169.6(8) . . . . ?
O2 C12 C13 C14 -37.2(5) . . . . ?
O2 C12 C13 O5 81.4(5) . . . . ?
O2 C15 O3 C16 -118.9(5) . . . . ?
O3 C15 O2 C12 100.5(5) . . . . ?
O3 C16 O4 C14 -27.0(5) . . . . ?
O4 C14 C15 O2 105.7(4) . . . . ?
O4 C14 C15 O3 -14.3(5) . . . . ?
O4 C16 O3 C15 17.0(6) . . . . ?
O5 C13 C14 C15 -89.9(5) . . . . ?
O5 C13 C14 O4 160.7(4) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
