# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_2
_database_code_depnum_ccdc_archive 'CCDC 1822415'
_audit_update_record             
;
2018-02-06 deposited with the CCDC.
2018-04-24 downloaded from the CCDC.
;
_audit_creation_date             2016-12-22
_audit_creation_method           
;
Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C44 H48 Cl2 O2 P4 Rh2 Si2, C6 H6'
_chemical_formula_sum            'C50 H54 Cl2 O2 P4 Rh2 Si2'
_chemical_formula_weight         1143.71
_chemical_absolute_configuration ?
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           19
_space_group_name_H-M_alt        'P 21 21 21'
_space_group_name_Hall           'P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'

_cell_length_a                   13.6107(5)
_cell_length_b                   19.3024(5)
_cell_length_c                   19.5658(7)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     5140.3(3)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9908
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      28.25
_cell_measurement_theta_min      2.33
_shelx_estimated_absorpt_T_max   0.981
_shelx_estimated_absorpt_T_min   0.832
_exptl_absorpt_coefficient_mu    0.955
_exptl_absorpt_correction_T_max  0.8894
_exptl_absorpt_correction_T_min  0.8392
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2014/5 (Bruker,2014/5) was used for absorption correction.
wR2(int) was 0.0623 before and 0.0560 after correction.
The Ratio of minimum to maximum transmission is 0.9436.
The λ/2 correction factor is 0.00150.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.478
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       Plate
_exptl_crystal_F_000             2328
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.02
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0496
_diffrn_reflns_av_unetI/netI     0.0464
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            62167
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_theta_full        26.000
_diffrn_reflns_theta_max         28.320
_diffrn_reflns_theta_min         2.564
_diffrn_ambient_temperature      100
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.823
_reflns_Friedel_fraction_full    1.000
_reflns_Friedel_fraction_max     0.993
_reflns_number_gt                11553
_reflns_number_total             12732
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v8.34A (Bruker, 2013)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v8.34A (Bruker, 2013)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         0.434
_refine_diff_density_min         -0.380
_refine_diff_density_rms         0.070
_refine_ls_abs_structure_details 
;
 Flack x determined using 4794 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   -0.015(10)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     623
_refine_ls_number_reflns         12732
_refine_ls_number_restraints     18
_refine_ls_R_factor_all          0.0350
_refine_ls_R_factor_gt           0.0280
_refine_ls_restrained_S_all      1.024
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0212P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0504
_refine_ls_wR_factor_ref         0.0523
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Rigid body (RIGU) restrains
 Rh2, C44A, O2A
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
 Rh2, C44B, O2B
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
3. Others
 Sof(Cl1B)=Sof(O1B)=Sof(C43B)=1-FVAR(1)
 Sof(Cl1A)=Sof(O1A)=Sof(C43A)=FVAR(1)
 Sof(Cl2B)=Sof(O2B)=Sof(C44B)=1-FVAR(2)
 Sof(Cl2A)=Sof(O2A)=Sof(C44A)=FVAR(2)
4.a Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C8(H8), C9(H9), C10(H10), C11(H11), C12(H12), C14(H14),
 C15(H15), C16(H16), C17(H17), C18(H18), C24(H24), C25(H25), C29(H29), C30(H30),
  C31(H31), C32(H32), C33(H33), C35(H35), C36(H36), C37(H37), C38(H38),
 C39(H39), C45(H45), C46(H46), C47(H47), C48(H48), C49(H49), C50(H50)
4.b Idealised Me refined as rotating group:
 C6(H6A,H6B,H6C), C19(H19A,H19B,H19C), C20(H20A,H20B,H20C), C21(H21A,H21B,
 H21C), C27(H27A,H27B,H27C), C40(H40A,H40B,H40C), C41(H41A,H41B,H41C), C42(H42A,
 H42B,H42C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.40607(2) 0.53880(2) 0.36690(2) 0.01181(6) Uani 1 1 d . . . . .
Rh2 Rh 0.44974(2) 0.68137(2) 0.32925(2) 0.01154(6) Uani 1 1 d . U . . .
Cl1A Cl 0.3969(2) 0.49522(15) 0.25244(15) 0.0175(10) Uani 0.619(15) 1 d . . P A
1
Cl1B Cl 0.4206(3) 0.5724(3) 0.4857(2) 0.0182(15) Uani 0.381(15) 1 d . . P A -1
Cl2A Cl 0.51377(19) 0.70011(18) 0.44151(13) 0.0192(10) Uani 0.577(12) 1 d . . P
B 1
Cl2B Cl 0.3781(3) 0.67706(19) 0.21739(19) 0.0180(14) Uani 0.423(12) 1 d . . P B
-1
P1 P 0.57175(6) 0.52042(4) 0.36229(5) 0.01327(19) Uani 1 1 d . . . . .
P2 P 0.60750(7) 0.65665(4) 0.29111(5) 0.01260(19) Uani 1 1 d . . . . .
P3 P 0.29439(6) 0.70638(4) 0.36726(5) 0.01260(18) Uani 1 1 d . . . . .
P4 P 0.23753(7) 0.55532(4) 0.37257(5) 0.01249(18) Uani 1 1 d . . . . .
Si1 Si 0.56624(8) 0.37525(5) 0.43676(6) 0.0220(2) Uani 1 1 d . . . . .
Si2 Si 0.31949(8) 0.86943(5) 0.36703(6) 0.0199(2) Uani 1 1 d . . . . .
O1A O 0.4173(4) 0.5567(4) 0.5161(6) 0.0245(15) Uani 0.619(15) 1 d . . P A 1
O1B O 0.3939(13) 0.4768(8) 0.2319(8) 0.028(3) Uani 0.381(15) 1 d . . P A -1
O2A O 0.3643(7) 0.6801(5) 0.1899(5) 0.0219(19) Uani 0.577(12) 1 d . U P B 1
O2B O 0.5370(8) 0.7253(7) 0.4593(5) 0.028(2) Uani 0.423(12) 1 d . U P B -1
C1 C 0.6562(3) 0.57260(16) 0.32040(19) 0.0143(7) Uani 1 1 d . . . . .
C2 C 0.7531(3) 0.54993(17) 0.30800(18) 0.0161(8) Uani 1 1 d . . . . .
C3 C 0.7871(3) 0.48683(17) 0.3345(2) 0.0195(8) Uani 1 1 d . . . . .
H3 H 0.8538 0.4752 0.3261 0.023 Uiso 1 1 calc R . . . .
C4 C 0.7316(3) 0.43998(17) 0.3718(2) 0.0205(8) Uani 1 1 d . . . . .
H4 H 0.7645 0.3999 0.3882 0.025 Uiso 1 1 calc R . . . .
C5 C 0.6321(3) 0.44615(17) 0.38761(18) 0.0156(8) Uani 1 1 d . . . . .
C6 C 0.8245(3) 0.58957(18) 0.2637(2) 0.0209(8) Uani 1 1 d . . . . .
H6A H 0.8028 0.5877 0.2160 0.031 Uiso 1 1 calc GR . . . .
H6B H 0.8900 0.5688 0.2676 0.031 Uiso 1 1 calc GR . . . .
H6C H 0.8272 0.6379 0.2789 0.031 Uiso 1 1 calc GR . . . .
C7 C 0.6907(3) 0.72262(15) 0.32471(19) 0.0151(7) Uani 1 1 d . . . . .
C8 C 0.6872(3) 0.78961(17) 0.29702(19) 0.0179(8) Uani 1 1 d . . . . .
H8 H 0.6456 0.7991 0.2592 0.022 Uiso 1 1 calc R . . . .
C9 C 0.7443(3) 0.84195(17) 0.3249(2) 0.0241(9) Uani 1 1 d . . . . .
H9 H 0.7441 0.8867 0.3047 0.029 Uiso 1 1 calc R . . . .
C10 C 0.8014(3) 0.82909(18) 0.3817(2) 0.0244(9) Uani 1 1 d . . . . .
H10 H 0.8409 0.8650 0.4003 0.029 Uiso 1 1 calc R . . . .
C11 C 0.8013(3) 0.76434(18) 0.4116(2) 0.0211(8) Uani 1 1 d . . . . .
H11 H 0.8381 0.7564 0.4521 0.025 Uiso 1 1 calc R . . . .
C12 C 0.7472(3) 0.71059(17) 0.38248(18) 0.0162(8) Uani 1 1 d . . . . .
H12 H 0.7491 0.6657 0.4022 0.019 Uiso 1 1 calc R . . . .
C13 C 0.6277(3) 0.65187(16) 0.19873(18) 0.0140(7) Uani 1 1 d . . . . .
C14 C 0.5742(3) 0.60195(16) 0.16274(19) 0.0170(8) Uani 1 1 d . . . . .
H14 H 0.5275 0.5742 0.1863 0.020 Uiso 1 1 calc R . . . .
C15 C 0.5881(3) 0.59232(18) 0.09300(19) 0.0205(8) Uani 1 1 d . . . . .
H15 H 0.5511 0.5582 0.0692 0.025 Uiso 1 1 calc R . . . .
C16 C 0.6559(3) 0.63236(19) 0.0583(2) 0.0243(9) Uani 1 1 d . . . . .
H16 H 0.6659 0.6258 0.0107 0.029 Uiso 1 1 calc R . . . .
C17 C 0.7097(3) 0.6827(2) 0.0938(2) 0.0266(9) Uani 1 1 d . . . . .
H17 H 0.7564 0.7104 0.0702 0.032 Uiso 1 1 calc R . . . .
C18 C 0.6950(3) 0.69222(17) 0.1628(2) 0.0210(8) Uani 1 1 d . . . . .
H18 H 0.7313 0.7269 0.1862 0.025 Uiso 1 1 calc R . . . .
C19 C 0.6442(3) 0.29609(17) 0.4324(2) 0.0240(9) Uani 1 1 d . . . . .
H19A H 0.6548 0.2833 0.3845 0.036 Uiso 1 1 calc GR . . . .
H19B H 0.6112 0.2579 0.4562 0.036 Uiso 1 1 calc GR . . . .
H19C H 0.7077 0.3053 0.4543 0.036 Uiso 1 1 calc GR . . . .
C20 C 0.5514(4) 0.4038(2) 0.5272(2) 0.0415(12) Uani 1 1 d . . . . .
H20A H 0.6154 0.4180 0.5454 0.062 Uiso 1 1 calc GR . . . .
H20B H 0.5254 0.3654 0.5545 0.062 Uiso 1 1 calc GR . . . .
H20C H 0.5058 0.4430 0.5291 0.062 Uiso 1 1 calc GR . . . .
C21 C 0.4476(3) 0.3538(2) 0.3953(3) 0.0435(13) Uani 1 1 d . . . . .
H21A H 0.4053 0.3949 0.3950 0.065 Uiso 1 1 calc GR . . . .
H21B H 0.4152 0.3165 0.4207 0.065 Uiso 1 1 calc GR . . . .
H21C H 0.4596 0.3387 0.3482 0.065 Uiso 1 1 calc GR . . . .
C22 C 0.2007(3) 0.64670(16) 0.37826(17) 0.0127(7) Uani 1 1 d . . . . .
C23 C 0.1025(3) 0.66814(17) 0.38879(17) 0.0163(8) Uani 1 1 d . . . . .
C24 C 0.0781(3) 0.73752(18) 0.3966(2) 0.0220(9) Uani 1 1 d . . . . .
H24 H 0.0112 0.7482 0.4057 0.026 Uiso 1 1 calc R . . . .
C25 C 0.1436(3) 0.79255(18) 0.3922(2) 0.0222(9) Uani 1 1 d . . . . .
H25 H 0.1183 0.8376 0.4005 0.027 Uiso 1 1 calc R . . . .
C26 C 0.2435(3) 0.78744(16) 0.37653(18) 0.0153(8) Uani 1 1 d . . . . .
C27 C 0.0181(3) 0.61738(18) 0.3902(2) 0.0211(9) Uani 1 1 d . . . . .
H27A H -0.0426 0.6418 0.4023 0.032 Uiso 1 1 calc GR . . . .
H27B H 0.0313 0.5813 0.4242 0.032 Uiso 1 1 calc GR . . . .
H27C H 0.0107 0.5961 0.3450 0.032 Uiso 1 1 calc GR . . . .
C28 C 0.1626(3) 0.52221(16) 0.30215(18) 0.0135(7) Uani 1 1 d . . . . .
C29 C 0.1745(3) 0.55320(18) 0.23833(19) 0.0190(8) Uani 1 1 d . . . . .
H29 H 0.2206 0.5898 0.2331 0.023 Uiso 1 1 calc R . . . .
C30 C 0.1203(3) 0.53135(19) 0.18258(19) 0.0214(8) Uani 1 1 d . . . . .
H30 H 0.1286 0.5534 0.1395 0.026 Uiso 1 1 calc R . . . .
C31 C 0.0537(3) 0.47732(17) 0.18936(19) 0.0214(8) Uani 1 1 d . . . . .
H31 H 0.0167 0.4621 0.1510 0.026 Uiso 1 1 calc R . . . .
C32 C 0.0417(3) 0.44587(17) 0.2522(2) 0.0193(8) Uani 1 1 d . . . . .
H32 H -0.0039 0.4089 0.2569 0.023 Uiso 1 1 calc R . . . .
C33 C 0.0951(3) 0.46749(17) 0.30859(18) 0.0173(8) Uani 1 1 d . . . . .
H33 H 0.0862 0.4454 0.3515 0.021 Uiso 1 1 calc R . . . .
C34 C 0.1961(3) 0.51383(17) 0.45114(18) 0.0160(8) Uani 1 1 d . . . . .
C35 C 0.2097(3) 0.44226(18) 0.4569(2) 0.0216(9) Uani 1 1 d . . . . .
H35 H 0.2308 0.4161 0.4185 0.026 Uiso 1 1 calc R . . . .
C36 C 0.1923(3) 0.4093(2) 0.5190(2) 0.0281(10) Uani 1 1 d . . . . .
H36 H 0.2006 0.3605 0.5226 0.034 Uiso 1 1 calc R . . . .
C37 C 0.1632(3) 0.4469(2) 0.5754(2) 0.0301(10) Uani 1 1 d . . . . .
H37 H 0.1518 0.4242 0.6178 0.036 Uiso 1 1 calc R . . . .
C38 C 0.1506(3) 0.5175(2) 0.5701(2) 0.0264(9) Uani 1 1 d . . . . .
H38 H 0.1305 0.5435 0.6088 0.032 Uiso 1 1 calc R . . . .
C39 C 0.1670(3) 0.5507(2) 0.50847(19) 0.0206(8) Uani 1 1 d . . . . .
H39 H 0.1583 0.5994 0.5054 0.025 Uiso 1 1 calc R . . . .
C40 C 0.2323(3) 0.94358(17) 0.3592(2) 0.0312(10) Uani 1 1 d . . . . .
H40A H 0.1883 0.9357 0.3203 0.047 Uiso 1 1 calc GR . . . .
H40B H 0.2693 0.9865 0.3519 0.047 Uiso 1 1 calc GR . . . .
H40C H 0.1934 0.9475 0.4011 0.047 Uiso 1 1 calc GR . . . .
C41 C 0.3970(3) 0.8646(2) 0.2892(2) 0.0365(11) Uani 1 1 d . . . . .
H41A H 0.4474 0.8288 0.2953 0.055 Uiso 1 1 calc GR . . . .
H41B H 0.4287 0.9094 0.2814 0.055 Uiso 1 1 calc GR . . . .
H41C H 0.3559 0.8528 0.2498 0.055 Uiso 1 1 calc GR . . . .
C42 C 0.3953(4) 0.8809(2) 0.4449(2) 0.0359(11) Uani 1 1 d . . . . .
H42A H 0.3523 0.8852 0.4849 0.054 Uiso 1 1 calc GR . . . .
H42B H 0.4354 0.9228 0.4404 0.054 Uiso 1 1 calc GR . . . .
H42C H 0.4384 0.8406 0.4507 0.054 Uiso 1 1 calc GR . . . .
C43A C 0.4119(6) 0.5523(5) 0.4587(6) 0.0182(18) Uani 0.619(15) 1 d . . P A 1
C43B C 0.3959(13) 0.5050(8) 0.2859(12) 0.025(3) Uani 0.381(15) 1 d . . P A -1
C44A C 0.4010(9) 0.6769(6) 0.2447(6) 0.0147(19) Uani 0.577(12) 1 d . U P B 1
C44B C 0.5043(10) 0.7067(7) 0.4112(9) 0.019(3) Uani 0.423(12) 1 d . U P B -1
C45 C 0.0684(3) 0.29037(19) 0.3448(3) 0.0408(13) Uani 1 1 d . . . . .
H45 H 0.1314 0.3114 0.3427 0.049 Uiso 1 1 calc R . . . .
C46 C 0.0141(4) 0.2932(2) 0.4042(3) 0.0387(12) Uani 1 1 d . . . . .
H46 H 0.0397 0.3165 0.4431 0.046 Uiso 1 1 calc R . . . .
C47 C -0.0768(3) 0.2626(2) 0.4075(2) 0.0337(11) Uani 1 1 d . . . . .
H47 H -0.1139 0.2645 0.4486 0.040 Uiso 1 1 calc R . . . .
C48 C -0.1138(3) 0.2291(2) 0.3509(2) 0.0348(11) Uani 1 1 d . . . . .
H48 H -0.1764 0.2073 0.3532 0.042 Uiso 1 1 calc R . . . .
C49 C -0.0606(4) 0.2270(2) 0.2912(2) 0.0397(12) Uani 1 1 d . . . . .
H49 H -0.0871 0.2048 0.2520 0.048 Uiso 1 1 calc R . . . .
C50 C 0.0309(4) 0.2570(2) 0.2884(3) 0.0424(13) Uani 1 1 d . . . . .
H50 H 0.0682 0.2548 0.2474 0.051 Uiso 1 1 calc R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 Rh2 2.9103(4) . ?
Rh1 Cl1A 2.396(3) . ?
Rh1 Cl1B 2.422(4) . ?
Rh1 P1 2.2845(9) . ?
Rh1 P4 2.3188(10) . ?
Rh1 C43A 1.816(13) . ?
Rh1 C43B 1.72(2) . ?
Rh2 Cl2A 2.391(3) . ?
Rh2 Cl2B 2.398(4) . ?
Rh2 P2 2.3228(10) . ?
Rh2 P3 2.2928(9) . ?
Rh2 C44A 1.785(12) . ?
Rh2 C44B 1.834(17) . ?
Cl1A O1B 0.538(16) . ?
Cl1A C43B 0.68(2) . ?
Cl1B O1A 0.668(8) . ?
Cl1B C43A 0.668(12) . ?
Cl2A O2B 0.675(14) . ?
Cl2A C44B 0.619(16) . ?
Cl2B O2A 0.572(8) . ?
Cl2B C44A 0.618(12) . ?
P1 C1 1.734(4) . ?
P1 C5 1.725(3) . ?
P2 C1 1.844(3) . ?
P2 C7 1.827(3) . ?
P2 C13 1.831(4) . ?
P3 C22 1.732(3) . ?
P3 C26 1.721(3) . ?
P4 C22 1.837(3) . ?
P4 C28 1.829(4) . ?
P4 C34 1.823(4) . ?
Si1 C5 1.898(4) . ?
Si1 C19 1.863(4) . ?
Si1 C20 1.863(4) . ?
Si1 C21 1.854(5) . ?
Si2 C26 1.900(3) . ?
Si2 C40 1.866(4) . ?
Si2 C41 1.855(4) . ?
Si2 C42 1.854(4) . ?
O1A C43A 1.13(2) . ?
O1B C43B 1.19(4) . ?
O2A C44A 1.183(18) . ?
O2B C44B 1.10(3) . ?
C1 C2 1.411(5) . ?
C2 C3 1.402(5) . ?
C2 C6 1.511(5) . ?
C3 H3 0.9500 . ?
C3 C4 1.386(5) . ?
C4 H4 0.9500 . ?
C4 C5 1.394(5) . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 C8 1.403(5) . ?
C7 C12 1.387(5) . ?
C8 H8 0.9500 . ?
C8 C9 1.386(5) . ?
C9 H9 0.9500 . ?
C9 C10 1.379(6) . ?
C10 H10 0.9500 . ?
C10 C11 1.380(5) . ?
C11 H11 0.9500 . ?
C11 C12 1.394(5) . ?
C12 H12 0.9500 . ?
C13 C14 1.399(5) . ?
C13 C18 1.393(5) . ?
C14 H14 0.9500 . ?
C14 C15 1.390(5) . ?
C15 H15 0.9500 . ?
C15 C16 1.382(5) . ?
C16 H16 0.9500 . ?
C16 C17 1.401(5) . ?
C17 H17 0.9500 . ?
C17 C18 1.377(5) . ?
C18 H18 0.9500 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C22 C23 1.414(5) . ?
C23 C24 1.388(5) . ?
C23 C27 1.510(5) . ?
C24 H24 0.9500 . ?
C24 C25 1.390(5) . ?
C25 H25 0.9500 . ?
C25 C26 1.397(5) . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C28 C29 1.394(5) . ?
C28 C33 1.405(5) . ?
C29 H29 0.9500 . ?
C29 C30 1.383(5) . ?
C30 H30 0.9500 . ?
C30 C31 1.388(5) . ?
C31 H31 0.9500 . ?
C31 C32 1.382(5) . ?
C32 H32 0.9500 . ?
C32 C33 1.385(5) . ?
C33 H33 0.9500 . ?
C34 C35 1.398(5) . ?
C34 C39 1.386(5) . ?
C35 H35 0.9500 . ?
C35 C36 1.392(5) . ?
C36 H36 0.9500 . ?
C36 C37 1.379(6) . ?
C37 H37 0.9500 . ?
C37 C38 1.377(6) . ?
C38 H38 0.9500 . ?
C38 C39 1.383(5) . ?
C39 H39 0.9500 . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?
C41 H41A 0.9800 . ?
C41 H41B 0.9800 . ?
C41 H41C 0.9800 . ?
C42 H42A 0.9800 . ?
C42 H42B 0.9800 . ?
C42 H42C 0.9800 . ?
C45 H45 0.9500 . ?
C45 C46 1.379(7) . ?
C45 C50 1.375(7) . ?
C46 H46 0.9500 . ?
C46 C47 1.372(6) . ?
C47 H47 0.9500 . ?
C47 C48 1.378(6) . ?
C48 H48 0.9500 . ?
C48 C49 1.374(6) . ?
C49 H49 0.9500 . ?
C49 C50 1.375(7) . ?
C50 H50 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Cl1A Rh1 Rh2 96.09(7) . . ?
Cl1A Rh1 Cl1B 174.75(14) . . ?
Cl1B Rh1 Rh2 88.44(15) . . ?
P1 Rh1 Rh2 86.29(2) . . ?
P1 Rh1 Cl1A 87.73(8) . . ?
P1 Rh1 Cl1B 89.94(9) . . ?
P1 Rh1 P4 178.87(3) . . ?
P4 Rh1 Rh2 94.82(2) . . ?
P4 Rh1 Cl1A 92.36(8) . . ?
P4 Rh1 Cl1B 89.88(9) . . ?
C43A Rh1 Rh2 96.1(3) . . ?
C43A Rh1 Cl1A 167.7(3) . . ?
C43A Rh1 Cl1B 7.7(3) . . ?
C43A Rh1 P1 91.0(3) . . ?
C43A Rh1 P4 88.7(3) . . ?
C43B Rh1 Rh2 98.2(5) . . ?
C43B Rh1 Cl1A 2.4(5) . . ?
C43B Rh1 Cl1B 173.2(5) . . ?
C43B Rh1 P1 89.1(6) . . ?
C43B Rh1 P4 91.0(6) . . ?
C43B Rh1 C43A 165.7(5) . . ?
Cl2A Rh2 Rh1 89.14(9) . . ?
Cl2A Rh2 Cl2B 172.88(12) . . ?
Cl2B Rh2 Rh1 96.61(9) . . ?
P2 Rh2 Rh1 94.35(2) . . ?
P2 Rh2 Cl2A 89.39(6) . . ?
P2 Rh2 Cl2B 94.34(9) . . ?
P3 Rh2 Rh1 85.91(2) . . ?
P3 Rh2 Cl2A 90.36(6) . . ?
P3 Rh2 Cl2B 85.88(9) . . ?
P3 Rh2 P2 179.63(4) . . ?
C44A Rh2 Rh1 96.5(4) . . ?
C44A Rh2 Cl2A 174.1(4) . . ?
C44A Rh2 Cl2B 2.3(4) . . ?
C44A Rh2 P2 92.1(4) . . ?
C44A Rh2 P3 88.2(4) . . ?
C44A Rh2 C44B 167.0(6) . . ?
C44B Rh2 Rh1 96.5(4) . . ?
C44B Rh2 Cl2A 7.4(5) . . ?
C44B Rh2 Cl2B 166.5(4) . . ?
C44B Rh2 P2 87.8(4) . . ?
C44B Rh2 P3 91.9(4) . . ?
O1B Cl1A Rh1 159.1(19) . . ?
O1B Cl1A C43B 154(2) . . ?
C43B Cl1A Rh1 6.1(14) . . ?
O1A Cl1B Rh1 136.5(9) . . ?
C43A Cl1B Rh1 21.3(9) . . ?
C43A Cl1B O1A 115.3(15) . . ?
O2B Cl2A Rh2 138.7(9) . . ?
C44B Cl2A Rh2 22.6(14) . . ?
C44B Cl2A O2B 116.2(19) . . ?
O2A Cl2B Rh2 170.8(13) . . ?
O2A Cl2B C44A 167.6(15) . . ?
C44A Cl2B Rh2 6.7(12) . . ?
C1 P1 Rh1 125.62(12) . . ?
C5 P1 Rh1 126.01(13) . . ?
C5 P1 C1 107.64(17) . . ?
C1 P2 Rh2 114.38(12) . . ?
C7 P2 Rh2 108.32(11) . . ?
C7 P2 C1 106.20(16) . . ?
C7 P2 C13 107.29(17) . . ?
C13 P2 Rh2 117.82(12) . . ?
C13 P2 C1 102.04(15) . . ?
C22 P3 Rh2 125.40(11) . . ?
C26 P3 Rh2 126.64(13) . . ?
C26 P3 C22 107.19(17) . . ?
C22 P4 Rh1 113.88(12) . . ?
C28 P4 Rh1 117.86(11) . . ?
C28 P4 C22 103.25(15) . . ?
C34 P4 Rh1 106.60(12) . . ?
C34 P4 C22 106.65(16) . . ?
C34 P4 C28 108.03(16) . . ?
C19 Si1 C5 107.40(18) . . ?
C19 Si1 C20 110.32(19) . . ?
C20 Si1 C5 108.60(18) . . ?
C21 Si1 C5 110.53(18) . . ?
C21 Si1 C19 107.06(19) . . ?
C21 Si1 C20 112.8(3) . . ?
C40 Si2 C26 107.51(17) . . ?
C41 Si2 C26 110.34(18) . . ?
C41 Si2 C40 109.4(2) . . ?
C42 Si2 C26 108.77(18) . . ?
C42 Si2 C40 109.3(2) . . ?
C42 Si2 C41 111.4(2) . . ?
Cl1B O1A C43A 32.3(7) . . ?
Cl1A O1B C43B 14.5(12) . . ?
Cl2B O2A C44A 6.4(8) . . ?
Cl2A O2B C44B 30.4(9) . . ?
P1 C1 P2 114.85(19) . . ?
C2 C1 P1 121.4(2) . . ?
C2 C1 P2 123.7(3) . . ?
C1 C2 C6 122.9(3) . . ?
C3 C2 C1 121.0(3) . . ?
C3 C2 C6 116.1(3) . . ?
C2 C3 H3 117.2 . . ?
C4 C3 C2 125.6(3) . . ?
C4 C3 H3 117.2 . . ?
C3 C4 H4 116.9 . . ?
C3 C4 C5 126.1(3) . . ?
C5 C4 H4 116.9 . . ?
P1 C5 Si1 121.3(2) . . ?
C4 C5 P1 118.0(3) . . ?
C4 C5 Si1 120.6(3) . . ?
C2 C6 H6A 109.5 . . ?
C2 C6 H6B 109.5 . . ?
C2 C6 H6C 109.5 . . ?
H6A C6 H6B 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C8 C7 P2 118.8(3) . . ?
C12 C7 P2 121.4(3) . . ?
C12 C7 C8 119.2(3) . . ?
C7 C8 H8 120.0 . . ?
C9 C8 C7 120.0(4) . . ?
C9 C8 H8 120.0 . . ?
C8 C9 H9 120.0 . . ?
C10 C9 C8 120.1(3) . . ?
C10 C9 H9 120.0 . . ?
C9 C10 H10 119.8 . . ?
C9 C10 C11 120.3(3) . . ?
C11 C10 H10 119.8 . . ?
C10 C11 H11 120.0 . . ?
C10 C11 C12 120.0(4) . . ?
C12 C11 H11 120.0 . . ?
C7 C12 C11 120.1(3) . . ?
C7 C12 H12 119.9 . . ?
C11 C12 H12 119.9 . . ?
C14 C13 P2 117.0(3) . . ?
C18 C13 P2 124.7(3) . . ?
C18 C13 C14 118.3(3) . . ?
C13 C14 H14 119.5 . . ?
C15 C14 C13 121.0(3) . . ?
C15 C14 H14 119.5 . . ?
C14 C15 H15 120.0 . . ?
C16 C15 C14 119.9(4) . . ?
C16 C15 H15 120.0 . . ?
C15 C16 H16 120.2 . . ?
C15 C16 C17 119.6(4) . . ?
C17 C16 H16 120.2 . . ?
C16 C17 H17 119.9 . . ?
C18 C17 C16 120.1(4) . . ?
C18 C17 H17 119.9 . . ?
C13 C18 H18 119.5 . . ?
C17 C18 C13 121.1(4) . . ?
C17 C18 H18 119.5 . . ?
Si1 C19 H19A 109.5 . . ?
Si1 C19 H19B 109.5 . . ?
Si1 C19 H19C 109.5 . . ?
H19A C19 H19B 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
Si1 C20 H20A 109.5 . . ?
Si1 C20 H20B 109.5 . . ?
Si1 C20 H20C 109.5 . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
Si1 C21 H21A 109.5 . . ?
Si1 C21 H21B 109.5 . . ?
Si1 C21 H21C 109.5 . . ?
H21A C21 H21B 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
P3 C22 P4 115.50(19) . . ?
C23 C22 P3 121.3(2) . . ?
C23 C22 P4 123.2(2) . . ?
C22 C23 C27 122.1(3) . . ?
C24 C23 C22 121.6(3) . . ?
C24 C23 C27 116.2(3) . . ?
C23 C24 H24 117.4 . . ?
C23 C24 C25 125.2(4) . . ?
C25 C24 H24 117.4 . . ?
C24 C25 H25 117.1 . . ?
C24 C25 C26 125.8(3) . . ?
C26 C25 H25 117.1 . . ?
P3 C26 Si2 121.9(2) . . ?
C25 C26 P3 118.6(3) . . ?
C25 C26 Si2 119.5(2) . . ?
C23 C27 H27A 109.5 . . ?
C23 C27 H27B 109.5 . . ?
C23 C27 H27C 109.5 . . ?
H27A C27 H27B 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C29 C28 P4 117.4(3) . . ?
C29 C28 C33 118.6(3) . . ?
C33 C28 P4 124.0(3) . . ?
C28 C29 H29 119.6 . . ?
C30 C29 C28 120.9(3) . . ?
C30 C29 H29 119.6 . . ?
C29 C30 H30 119.9 . . ?
C29 C30 C31 120.2(3) . . ?
C31 C30 H30 119.9 . . ?
C30 C31 H31 120.2 . . ?
C32 C31 C30 119.5(3) . . ?
C32 C31 H31 120.2 . . ?
C31 C32 H32 119.5 . . ?
C31 C32 C33 120.9(3) . . ?
C33 C32 H32 119.5 . . ?
C28 C33 H33 120.1 . . ?
C32 C33 C28 119.9(3) . . ?
C32 C33 H33 120.1 . . ?
C35 C34 P4 117.5(3) . . ?
C39 C34 P4 123.1(3) . . ?
C39 C34 C35 118.6(3) . . ?
C34 C35 H35 120.0 . . ?
C36 C35 C34 120.0(4) . . ?
C36 C35 H35 120.0 . . ?
C35 C36 H36 119.8 . . ?
C37 C36 C35 120.4(4) . . ?
C37 C36 H36 119.8 . . ?
C36 C37 H37 120.1 . . ?
C38 C37 C36 119.7(4) . . ?
C38 C37 H37 120.1 . . ?
C37 C38 H38 119.9 . . ?
C37 C38 C39 120.3(4) . . ?
C39 C38 H38 119.9 . . ?
C34 C39 H39 119.5 . . ?
C38 C39 C34 120.9(4) . . ?
C38 C39 H39 119.5 . . ?
Si2 C40 H40A 109.5 . . ?
Si2 C40 H40B 109.5 . . ?
Si2 C40 H40C 109.5 . . ?
H40A C40 H40B 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
Si2 C41 H41A 109.5 . . ?
Si2 C41 H41B 109.5 . . ?
Si2 C41 H41C 109.5 . . ?
H41A C41 H41B 109.5 . . ?
H41A C41 H41C 109.5 . . ?
H41B C41 H41C 109.5 . . ?
Si2 C42 H42A 109.5 . . ?
Si2 C42 H42B 109.5 . . ?
Si2 C42 H42C 109.5 . . ?
H42A C42 H42B 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
Cl1B C43A Rh1 151.1(11) . . ?
Cl1B C43A O1A 32.4(9) . . ?
O1A C43A Rh1 175.9(7) . . ?
Cl1A C43B Rh1 171.5(19) . . ?
Cl1A C43B O1B 11.4(9) . . ?
O1B C43B Rh1 174.2(18) . . ?
Cl2B C44A Rh2 171.0(15) . . ?
Cl2B C44A O2A 6.0(7) . . ?
O2A C44A Rh2 173.4(13) . . ?
Cl2A C44B Rh2 150.0(18) . . ?
Cl2A C44B O2B 33.5(11) . . ?
O2B C44B Rh2 176.4(12) . . ?
C46 C45 H45 120.1 . . ?
C50 C45 H45 120.1 . . ?
C50 C45 C46 119.7(4) . . ?
C45 C46 H46 119.8 . . ?
C47 C46 C45 120.4(4) . . ?
C47 C46 H46 119.8 . . ?
C46 C47 H47 120.2 . . ?
C46 C47 C48 119.6(4) . . ?
C48 C47 H47 120.2 . . ?
C47 C48 H48 119.9 . . ?
C49 C48 C47 120.2(4) . . ?
C49 C48 H48 119.9 . . ?
C48 C49 H49 120.0 . . ?
C48 C49 C50 120.0(4) . . ?
C50 C49 H49 120.0 . . ?
C45 C50 C49 120.1(5) . . ?
C45 C50 H50 120.0 . . ?
C49 C50 H50 120.0 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Rh1 Rh2 C44B Cl2A -8(3) . . . . ?
Rh1 Cl1A O1B C43B 9(4) . . . . ?
Rh1 Cl1A C43B O1B -150(13) . . . . ?
Rh1 Cl1B O1A C43A -2.2(9) . . . . ?
Rh1 Cl1B C43A O1A 175.8(16) . . . . ?
Rh1 P1 C1 P2 11.2(3) . . . . ?
Rh1 P1 C1 C2 -166.4(2) . . . . ?
Rh1 P1 C5 Si1 -10.3(3) . . . . ?
Rh1 P1 C5 C4 170.7(2) . . . . ?
Rh1 P4 C22 P3 8.1(2) . . . . ?
Rh1 P4 C22 C23 -173.7(2) . . . . ?
Rh1 P4 C28 C29 -66.4(3) . . . . ?
Rh1 P4 C28 C33 113.0(3) . . . . ?
Rh1 P4 C34 C35 -62.4(3) . . . . ?
Rh1 P4 C34 C39 107.1(3) . . . . ?
Rh2 Rh1 C43A Cl1B -4(2) . . . . ?
Rh2 Cl2A O2B C44B -1.2(15) . . . . ?
Rh2 Cl2A C44B O2B 178(3) . . . . ?
Rh2 Cl2B C44A O2A -133(10) . . . . ?
Rh2 P2 C1 P1 7.9(2) . . . . ?
Rh2 P2 C1 C2 -174.6(3) . . . . ?
Rh2 P2 C7 C8 -72.6(3) . . . . ?
Rh2 P2 C7 C12 98.6(3) . . . . ?
Rh2 P2 C13 C14 -60.3(3) . . . . ?
Rh2 P2 C13 C18 122.4(3) . . . . ?
Rh2 P3 C22 P4 10.9(3) . . . . ?
Rh2 P3 C22 C23 -167.3(2) . . . . ?
Rh2 P3 C26 Si2 -8.7(3) . . . . ?
Rh2 P3 C26 C25 172.0(2) . . . . ?
Cl1A Rh1 C43A Cl1B 165.9(13) . . . . ?
Cl2B Rh2 C44B Cl2A 158.3(19) . . . . ?
P1 Rh1 C43A Cl1B 82(2) . . . . ?
P1 C1 C2 C3 -5.8(5) . . . . ?
P1 C1 C2 C6 171.6(3) . . . . ?
P2 Rh2 C44B Cl2A -102(3) . . . . ?
P2 C1 C2 C3 176.9(3) . . . . ?
P2 C1 C2 C6 -5.7(5) . . . . ?
P2 C7 C8 C9 175.3(3) . . . . ?
P2 C7 C12 C11 -172.5(3) . . . . ?
P2 C13 C14 C15 -176.9(3) . . . . ?
P2 C13 C18 C17 176.3(3) . . . . ?
P3 Rh2 C44B Cl2A 78(3) . . . . ?
P3 C22 C23 C24 -5.6(5) . . . . ?
P3 C22 C23 C27 172.6(3) . . . . ?
P4 Rh1 C43A Cl1B -99(2) . . . . ?
P4 C22 C23 C24 176.4(3) . . . . ?
P4 C22 C23 C27 -5.4(5) . . . . ?
P4 C28 C29 C30 -179.7(3) . . . . ?
P4 C28 C33 C32 -179.9(3) . . . . ?
P4 C34 C35 C36 171.1(3) . . . . ?
P4 C34 C39 C38 -170.1(3) . . . . ?
O1A Cl1B C43A Rh1 -175.8(16) . . . . ?
O2B Cl2A C44B Rh2 -178(3) . . . . ?
C1 P1 C5 Si1 179.1(2) . . . . ?
C1 P1 C5 C4 0.1(3) . . . . ?
C1 P2 C7 C8 164.1(3) . . . . ?
C1 P2 C7 C12 -24.7(3) . . . . ?
C1 P2 C13 C14 65.8(3) . . . . ?
C1 P2 C13 C18 -111.5(3) . . . . ?
C1 C2 C3 C4 2.7(6) . . . . ?
C2 C3 C4 C5 2.3(7) . . . . ?
C3 C4 C5 P1 -3.2(5) . . . . ?
C3 C4 C5 Si1 177.8(3) . . . . ?
C5 P1 C1 P2 -178.20(19) . . . . ?
C5 P1 C1 C2 4.2(3) . . . . ?
C6 C2 C3 C4 -174.9(4) . . . . ?
C7 P2 C1 P1 127.3(2) . . . . ?
C7 P2 C1 C2 -55.2(3) . . . . ?
C7 P2 C13 C14 177.2(3) . . . . ?
C7 P2 C13 C18 -0.1(3) . . . . ?
C7 C8 C9 C10 -2.9(6) . . . . ?
C8 C7 C12 C11 -1.3(5) . . . . ?
C8 C9 C10 C11 -0.6(6) . . . . ?
C9 C10 C11 C12 3.2(6) . . . . ?
C10 C11 C12 C7 -2.2(5) . . . . ?
C12 C7 C8 C9 3.9(5) . . . . ?
C13 P2 C1 P1 -120.4(2) . . . . ?
C13 P2 C1 C2 57.1(3) . . . . ?
C13 P2 C7 C8 55.6(3) . . . . ?
C13 P2 C7 C12 -133.2(3) . . . . ?
C13 C14 C15 C16 0.1(5) . . . . ?
C14 C13 C18 C17 -1.0(5) . . . . ?
C14 C15 C16 C17 -0.4(6) . . . . ?
C15 C16 C17 C18 0.0(6) . . . . ?
C16 C17 C18 C13 0.7(6) . . . . ?
C18 C13 C14 C15 0.6(5) . . . . ?
C19 Si1 C5 P1 164.3(2) . . . . ?
C19 Si1 C5 C4 -16.7(4) . . . . ?
C20 Si1 C5 P1 -76.4(3) . . . . ?
C20 Si1 C5 C4 102.6(3) . . . . ?
C21 Si1 C5 P1 47.8(3) . . . . ?
C21 Si1 C5 C4 -133.2(3) . . . . ?
C22 P3 C26 Si2 -178.9(2) . . . . ?
C22 P3 C26 C25 1.7(4) . . . . ?
C22 P4 C28 C29 60.1(3) . . . . ?
C22 P4 C28 C33 -120.5(3) . . . . ?
C22 P4 C34 C35 175.6(3) . . . . ?
C22 P4 C34 C39 -14.9(4) . . . . ?
C22 C23 C24 C25 2.9(6) . . . . ?
C23 C24 C25 C26 2.7(7) . . . . ?
C24 C25 C26 P3 -4.7(6) . . . . ?
C24 C25 C26 Si2 175.9(3) . . . . ?
C26 P3 C22 P4 -178.70(19) . . . . ?
C26 P3 C22 C23 3.1(3) . . . . ?
C27 C23 C24 C25 -175.4(4) . . . . ?
C28 P4 C22 P3 -120.8(2) . . . . ?
C28 P4 C22 C23 57.3(3) . . . . ?
C28 P4 C34 C35 65.2(3) . . . . ?
C28 P4 C34 C39 -125.3(3) . . . . ?
C28 C29 C30 C31 -0.8(5) . . . . ?
C29 C28 C33 C32 -0.5(5) . . . . ?
C29 C30 C31 C32 0.4(5) . . . . ?
C30 C31 C32 C33 0.0(5) . . . . ?
C31 C32 C33 C28 0.1(5) . . . . ?
C33 C28 C29 C30 0.9(5) . . . . ?
C34 P4 C22 P3 125.4(2) . . . . ?
C34 P4 C22 C23 -56.4(3) . . . . ?
C34 P4 C28 C29 172.8(3) . . . . ?
C34 P4 C28 C33 -7.8(3) . . . . ?
C34 C35 C36 C37 -1.0(6) . . . . ?
C35 C34 C39 C38 -0.7(6) . . . . ?
C35 C36 C37 C38 0.4(6) . . . . ?
C36 C37 C38 C39 0.0(6) . . . . ?
C37 C38 C39 C34 0.2(6) . . . . ?
C39 C34 C35 C36 1.2(6) . . . . ?
C40 Si2 C26 P3 166.1(2) . . . . ?
C40 Si2 C26 C25 -14.6(4) . . . . ?
C41 Si2 C26 P3 46.8(3) . . . . ?
C41 Si2 C26 C25 -133.9(3) . . . . ?
C42 Si2 C26 P3 -75.7(3) . . . . ?
C42 Si2 C26 C25 103.7(3) . . . . ?
C43B Rh1 C43A Cl1B 172(3) . . . . ?
C44A Rh2 C44B Cl2A 168(2) . . . . ?
C45 C46 C47 C48 -0.2(6) . . . . ?
C46 C45 C50 C49 0.4(6) . . . . ?
C46 C47 C48 C49 -0.8(6) . . . . ?
C47 C48 C49 C50 1.5(7) . . . . ?
C48 C49 C50 C45 -1.3(7) . . . . ?
C50 C45 C46 C47 0.4(6) . . . . ?

_shelx_SHELXL_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_3
_database_code_depnum_ccdc_archive 'CCDC 1822416'
_audit_update_record             
;
2018-02-06 deposited with the CCDC.
2018-04-24 downloaded from the CCDC.
;
_audit_creation_date             2017-07-19
_audit_creation_method           
;
Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C29 H36 P2 Rh Si, C32 H12 B F24'
_chemical_formula_sum            'C61 H48 B F24 P2 Rh Si'
_chemical_formula_weight         1440.74
_chemical_melting_point          ?
_chemical_oxdiff_formula         'C61 H98 B F24 P2 Rh Si'
_chemical_oxdiff_usercomment     '@ 120 K RJN342'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   13.2396(4)
_cell_length_b                   14.6179(4)
_cell_length_c                   18.0412(5)
_cell_angle_alpha                98.298(2)
_cell_angle_beta                 102.651(2)
_cell_angle_gamma                110.657(3)
_cell_volume                     3092.50(16)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    21520
_cell_measurement_temperature    120.00(10)
_cell_measurement_theta_max      28.6590
_cell_measurement_theta_min      3.5230
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    0.459
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.543
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)
Numerical absorption correction based on gaussian integration over
			a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'dark orange'
_exptl_crystal_density_diffrn    1.547
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1448
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
4 1 5 0.0946
-4 -1 -5 0.0946
-2 4 -5 0.1017
1 5 -3 0.1152
1 -5 5 0.1090
-2 -5 1 0.1218
-4 -5 3 0.1166
0 0 -1 0.0612
1 1 -5 0.0728
4 5 -5 0.0970
0 1 5 0.0993
-2 -2 5 0.1026
-3 5 5 0.1070
-5 3 4 0.1159
1 -5 -3 0.1064
5 0 -3 0.0907
-5 -2 1 0.1144
-2 -3 5 0.0946
1 0 5 0.0846
-2 5 1 0.1168
-5 4 1 0.1155
1 -5 3 0.1108

_exptl_crystal_size_max          0.288
_exptl_crystal_size_mid          0.223
_exptl_crystal_size_min          0.165
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
4.0001 1.0000 4.9929 0.2012 0.0292 0.3261
-4.0001 -1.0000 -4.9929 -0.2012 -0.0292 -0.3261
-2.0016 3.9965 -4.9935 -0.2670 -0.0659 -0.0015
0.9976 4.9963 -2.9972 -0.1795 -0.0200 0.2236
1.0022 -4.9959 4.9940 0.2724 0.0533 -0.0923
-1.9980 -4.9965 0.9997 0.0994 0.0200 -0.3070
-3.9957 -4.9970 2.9993 0.1410 -0.0800 -0.3676
-0.0005 0.0000 -0.9991 -0.0336 0.0167 -0.0177
0.9967 0.9996 -4.9961 -0.1737 0.0960 0.0053
3.9946 4.9971 -4.9975 -0.2083 0.1133 0.3322
0.0026 0.9990 4.9957 0.1499 -0.1041 0.1342
-1.9960 -1.9990 4.9966 0.1791 -0.1087 -0.0990
-2.9957 4.9951 4.9985 0.0384 -0.2867 0.1731
-4.9949 2.9963 4.0004 0.0157 -0.2953 -0.0320
0.9980 -4.9956 -2.9989 0.0033 0.1867 -0.2337
4.9953 0.0013 -3.0008 -0.0368 0.2166 0.1869
-4.9962 -1.9996 1.0023 0.0061 -0.1419 -0.3138
-1.9960 -2.9982 4.9964 0.1974 -0.0880 -0.1448
1.0020 0.0001 4.9948 0.1810 -0.0501 0.1364
-1.9984 4.9955 1.0013 -0.0834 -0.1867 0.1504
-4.9965 3.9955 1.0033 -0.1036 -0.2659 -0.0393
1.0012 -4.9958 2.9958 0.2051 0.0866 -0.1276

_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0487
_diffrn_reflns_av_unetI/netI     0.0479
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.891
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            69611
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.891
_diffrn_reflns_theta_full        26.000
_diffrn_reflns_theta_max         29.749
_diffrn_reflns_theta_min         2.879
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      120.00(10)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 5.1574
_diffrn_detector_type            Atlas
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.891
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -80.00  17.00   1.00   15.00    --   -9.43 -57.00  60.00   97
  2  ω    -88.00  27.00   1.00   15.00    --   -9.43 -19.00 150.00  115
  3  ω    -83.00  22.00   1.00   15.00    --   -9.43 -77.00-120.00  105
  4  ω    -86.00 -42.00   1.00   15.00    --   -9.43 159.00  13.00   44
  5  ω    -12.00  83.00   1.00   15.00    --   10.84  38.00  60.00   95
  6  ω    -16.00  81.00   1.00   15.00    --   10.84  57.00-180.00   97
  7  ω    -48.00  -2.00   1.00   15.00    --   10.84 -38.00-180.00   46
  8  ω      9.00  83.00   1.00   15.00    --   10.84  38.00 -90.00   74
  9  ω    -43.00  34.00   1.00   15.00    --   10.84 -57.00  90.00   77
 10  ω     -1.00  26.00   1.00   15.00    --   10.84-117.00  -9.61   27
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0128547000
_diffrn_orient_matrix_UB_12      -0.0182950000
_diffrn_orient_matrix_UB_13      0.0336659000
_diffrn_orient_matrix_UB_21      0.0333294000
_diffrn_orient_matrix_UB_22      -0.0206810000
_diffrn_orient_matrix_UB_23      -0.0167127000
_diffrn_orient_matrix_UB_31      0.0480260000
_diffrn_orient_matrix_UB_32      0.0457709000
_diffrn_orient_matrix_UB_33      0.0176776000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                13163
_reflns_number_total             15721
_reflns_odcompleteness_completeness 99.85
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         1.463
_refine_diff_density_min         -0.960
_refine_diff_density_rms         0.093
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     896
_refine_ls_number_reflns         15721
_refine_ls_number_restraints     78
_refine_ls_R_factor_all          0.0695
_refine_ls_R_factor_gt           0.0550
_refine_ls_restrained_S_all      1.041
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0560P)²+6.0540P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1258
_refine_ls_wR_factor_ref         0.1340
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Rigid bond restraints
 C61, F22A, F22B, F23A, F23B, F24A, F24B
 with sigma for 1-2 distances of 0.005 and sigma for 1-3 distances of 0.005
3. Uiso/Uaniso restraints and constraints
Uanis(F18A) \\sim Ueq: with sigma of 0.02 and sigma for terminal atoms of 0.02
Uanis(F18B) \\sim Ueq: with sigma of 0.02 and sigma for terminal atoms of 0.02
4. Rigid body (RIGU) restrains
 C61, F22A, F22B, F23A, F23B, F24A, F24B
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
 C45, F10, F11, F12
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
5. Others
 Sof(F22B)=Sof(F23B)=Sof(F24B)=1-FVAR(1)
 Sof(F22A)=Sof(F23A)=Sof(F24A)=FVAR(1)
 Sof(F16A)=Sof(F17A)=Sof(F18A)=1-FVAR(2)
 Sof(F16B)=Sof(F17B)=Sof(F18B)=FVAR(2)
 Sof(C19B)=Sof(H19D)=Sof(H19E)=Sof(H19F)=Sof(C20B)=Sof(H20D)=Sof(H20E)=
 Sof(H20F)=Sof(C21B)=Sof(H21D)=Sof(H21E)=Sof(H21F)=1-FVAR(3)
 Sof(C19A)=Sof(H19A)=Sof(H19B)=Sof(H19C)=Sof(C20A)=Sof(H20A)=Sof(H20B)=
 Sof(H20C)=Sof(C21A)=Sof(H21A)=Sof(H21B)=Sof(H21C)=FVAR(3)
6.a Ternary CH refined with riding coordinates:
 C22(H22), C23(H23), C26(H26), C27(H27)
6.b Secondary CH2 refined with riding coordinates:
 C24(H24A,H24B), C25(H25A,H25B), C28(H28A,H28B), C29(H29A,H29B)
6.c Me refined with riding coordinates:
 C19A(H19A,H19B,H19C), C19B(H19D,H19E,H19F), C20A(H20A,H20B,H20C), C20B(H20D,
 H20E,H20F), C21A(H21A,H21B,H21C), C21B(H21D,H21E,H21F)
6.d Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C8(H8), C9(H9), C10(H10), C11(H11), C12(H12), C14(H14),
 C15(H15), C16(H16), C17(H17), C18(H18), C31(H31), C33(H33), C35(H35), C39(H39),
  C41(H41), C43(H43), C47(H47), C49(H49), C51(H51), C55(H55), C57(H57), C59(H59)
6.e Idealised Me refined as rotating group:
 C6(H6A,H6B,H6C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.72088(2) 0.91742(2) 0.25677(2) 0.01765(7) Uani 1 1 d . . . . .
P1 P 0.72539(6) 0.92984(5) 0.13217(4) 0.02020(15) Uani 1 1 d . . . . .
P2 P 0.64623(6) 1.03025(5) 0.22221(4) 0.01992(15) Uani 1 1 d . . . . .
Si1 Si 0.82880(8) 0.81845(7) 0.02449(5) 0.0300(2) Uani 1 1 d . . . . .
C1 C 0.6699(2) 1.0206(2) 0.12735(18) 0.0230(6) Uani 1 1 d . . . . .
C2 C 0.6551(3) 1.0645(2) 0.06416(19) 0.0271(6) Uani 1 1 d . . . . .
C3 C 0.6894(3) 1.0349(3) 0.0001(2) 0.0322(7) Uani 1 1 d . . . . .
H3 H 0.6793 1.0657 -0.0423 0.039 Uiso 1 1 calc R . . . .
C4 C 0.7368(3) 0.9646(3) -0.00695(19) 0.0315(7) Uani 1 1 d . . . . .
H4 H 0.7560 0.9528 -0.0541 0.038 Uiso 1 1 calc R . . . .
C5 C 0.7603(3) 0.9084(2) 0.04663(18) 0.0255(6) Uani 1 1 d . . . . .
C6 C 0.6065(3) 1.1435(3) 0.0654(2) 0.0355(8) Uani 1 1 d . . . . .
H6A H 0.5449 1.1253 0.0895 0.053 Uiso 1 1 calc GR . . . .
H6B H 0.5774 1.1476 0.0117 0.053 Uiso 1 1 calc GR . . . .
H6C H 0.6655 1.2090 0.0958 0.053 Uiso 1 1 calc GR . . . .
C7 C 0.7203(3) 1.1609(2) 0.2753(2) 0.0282(7) Uani 1 1 d . . . . .
C8 C 0.8062(3) 1.2246(2) 0.2518(2) 0.0326(7) Uani 1 1 d . . . . .
H8 H 0.8226 1.2007 0.2059 0.039 Uiso 1 1 calc R . . . .
C9 C 0.8683(3) 1.3237(3) 0.2952(3) 0.0466(10) Uani 1 1 d . . . . .
H9 H 0.9270 1.3676 0.2789 0.056 Uiso 1 1 calc R . . . .
C10 C 0.8447(3) 1.3579(3) 0.3616(3) 0.0523(11) Uani 1 1 d . . . . .
H10 H 0.8862 1.4259 0.3904 0.063 Uiso 1 1 calc R . . . .
C11 C 0.7616(4) 1.2946(3) 0.3870(3) 0.0534(11) Uani 1 1 d . . . . .
H11 H 0.7472 1.3189 0.4337 0.064 Uiso 1 1 calc R . . . .
C12 C 0.6988(3) 1.1956(3) 0.3445(2) 0.0393(8) Uani 1 1 d . . . . .
H12 H 0.6420 1.1517 0.3621 0.047 Uiso 1 1 calc R . . . .
C13 C 0.4971(2) 0.9946(2) 0.21121(17) 0.0239(6) Uani 1 1 d . . . . .
C14 C 0.4491(3) 1.0650(3) 0.2214(2) 0.0343(7) Uani 1 1 d . . . . .
H14 H 0.4945 1.1351 0.2334 0.041 Uiso 1 1 calc R . . . .
C15 C 0.3343(3) 1.0317(4) 0.2138(2) 0.0453(10) Uani 1 1 d . . . . .
H15 H 0.3018 1.0794 0.2219 0.054 Uiso 1 1 calc R . . . .
C16 C 0.2678(3) 0.9312(4) 0.1948(2) 0.0473(11) Uani 1 1 d . . . . .
H16 H 0.1894 0.9095 0.1895 0.057 Uiso 1 1 calc R . . . .
C17 C 0.3139(3) 0.8598(3) 0.1832(2) 0.0408(9) Uani 1 1 d . . . . .
H17 H 0.2671 0.7899 0.1691 0.049 Uiso 1 1 calc R . . . .
C18 C 0.4288(3) 0.8921(3) 0.19232(18) 0.0288(7) Uani 1 1 d . . . . .
H18 H 0.4611 0.8439 0.1857 0.035 Uiso 1 1 calc R . . . .
C19A C 0.9669(5) 0.8635(5) 0.0935(4) 0.0337(17) Uani 0.514(6) 1 d . . P A 3
H19A H 0.9606 0.8739 0.1469 0.051 Uiso 0.514(6) 1 calc R . P A 3
H19B H 0.9997 0.8137 0.0855 0.051 Uiso 0.514(6) 1 calc R . P A 3
H19C H 1.0154 0.9274 0.0856 0.051 Uiso 0.514(6) 1 calc R . P A 3
C19B C 0.9789(7) 0.9024(6) 0.0197(6) 0.049(2) Uani 0.486(6) 1 d . . P A -3
H19D H 0.9711 0.9398 -0.0206 0.073 Uiso 0.486(6) 1 calc R . P A -3
H19E H 1.0225 0.9500 0.0706 0.073 Uiso 0.486(6) 1 calc R . P A -3
H19F H 1.0181 0.8594 0.0067 0.073 Uiso 0.486(6) 1 calc R . P A -3
C20A C 0.8279(7) 0.7956(6) -0.0785(4) 0.043(2) Uani 0.514(6) 1 d . . P A 3
H20A H 0.7503 0.7714 -0.1123 0.065 Uiso 0.514(6) 1 calc R . P A 3
H20B H 0.8743 0.8585 -0.0889 0.065 Uiso 0.514(6) 1 calc R . P A 3
H20C H 0.8586 0.7448 -0.0890 0.065 Uiso 0.514(6) 1 calc R . P A 3
C20B C 0.7455(8) 0.7372(7) -0.0698(6) 0.057(3) Uani 0.486(6) 1 d . . P A -3
H20D H 0.7396 0.7778 -0.1080 0.086 Uiso 0.486(6) 1 calc R . P A -3
H20E H 0.7812 0.6923 -0.0856 0.086 Uiso 0.486(6) 1 calc R . P A -3
H20F H 0.6699 0.6969 -0.0674 0.086 Uiso 0.486(6) 1 calc R . P A -3
C21A C 0.7364(6) 0.6879(5) 0.0383(5) 0.0398(18) Uani 0.514(6) 1 d . . P A 3
H21A H 0.6608 0.6623 0.0011 0.060 Uiso 0.514(6) 1 calc R . P A 3
H21B H 0.7715 0.6402 0.0289 0.060 Uiso 0.514(6) 1 calc R . P A 3
H21C H 0.7305 0.6958 0.0919 0.060 Uiso 0.514(6) 1 calc R . P A 3
C21B C 0.8441(11) 0.7510(9) 0.0978(6) 0.069(4) Uani 0.486(6) 1 d . . P A -3
H21D H 0.8902 0.7988 0.1482 0.104 Uiso 0.486(6) 1 calc R . P A -3
H21E H 0.7695 0.7109 0.1019 0.104 Uiso 0.486(6) 1 calc R . P A -3
H21F H 0.8809 0.7063 0.0837 0.104 Uiso 0.486(6) 1 calc R . P A -3
C22 C 0.6442(3) 0.8920(3) 0.3513(2) 0.0334(7) Uani 1 1 d . . . . .
H22 H 0.5848 0.9194 0.3508 0.040 Uiso 1 1 calc R . . . .
C23 C 0.7519(3) 0.9640(3) 0.38315(19) 0.0359(8) Uani 1 1 d . . . . .
H23 H 0.7568 1.0336 0.4024 0.043 Uiso 1 1 calc R . . . .
C24 C 0.8495(4) 0.9421(5) 0.4265(3) 0.0770(18) Uani 1 1 d . . . . .
H24A H 0.9062 1.0056 0.4635 0.092 Uiso 1 1 calc R . . . .
H24B H 0.8208 0.8944 0.4583 0.092 Uiso 1 1 calc R . . . .
C25 C 0.9066(4) 0.9007(3) 0.3800(3) 0.0544(12) Uani 1 1 d . . . . .
H25A H 0.9288 0.8524 0.4056 0.065 Uiso 1 1 calc R . . . .
H25B H 0.9769 0.9563 0.3812 0.065 Uiso 1 1 calc R . . . .
C26 C 0.8428(3) 0.8488(2) 0.2970(2) 0.0322(7) Uani 1 1 d . . . . .
H26 H 0.8919 0.8470 0.2623 0.039 Uiso 1 1 calc R . . . .
C27 C 0.7371(3) 0.7726(2) 0.26959(19) 0.0279(7) Uani 1 1 d . . . . .
H27 H 0.7234 0.7253 0.2190 0.033 Uiso 1 1 calc R . . . .
C28 C 0.6667(4) 0.7272(3) 0.3205(2) 0.0449(9) Uani 1 1 d . . . . .
H28A H 0.6131 0.6581 0.2912 0.054 Uiso 1 1 calc R . . . .
H28B H 0.7172 0.7215 0.3673 0.054 Uiso 1 1 calc R . . . .
C29 C 0.6026(5) 0.7817(4) 0.3467(4) 0.0788(18) Uani 1 1 d . . . . .
H29A H 0.5984 0.7721 0.3993 0.095 Uiso 1 1 calc R . . . .
H29B H 0.5246 0.7495 0.3111 0.095 Uiso 1 1 calc R . . . .
F1 F 0.5622(3) 0.7678(2) 0.61958(14) 0.0797(10) Uani 1 1 d . . . . .
F2 F 0.5187(3) 0.6154(2) 0.57007(18) 0.1000(14) Uani 1 1 d . . . . .
F3 F 0.6410(3) 0.7265(4) 0.5405(2) 0.1229(18) Uani 1 1 d . . . . .
F4 F 0.24101(19) 0.87319(16) 0.37220(16) 0.0550(7) Uani 1 1 d . . . . .
F5 F 0.4154(2) 0.95236(14) 0.38457(13) 0.0431(5) Uani 1 1 d . . . . .
F6 F 0.3596(2) 0.94607(16) 0.48696(13) 0.0499(6) Uani 1 1 d . . . . .
F7 F -0.1385(3) 0.2758(2) 0.02804(19) 0.1019(13) Uani 1 1 d . . . . .
F8 F 0.0078(2) 0.3563(2) -0.00187(14) 0.0736(9) Uani 1 1 d . . . . .
F9 F -0.1281(3) 0.3983(3) -0.02483(16) 0.0818(10) Uani 1 1 d . . . . .
F10 F -0.2090(2) 0.5777(2) 0.19459(17) 0.0595(7) Uani 1 1 d . U . . .
F11 F -0.0500(3) 0.6996(2) 0.2546(3) 0.1305(19) Uani 1 1 d . U . . .
F12 F -0.1187(3) 0.5874(4) 0.3089(2) 0.1093(14) Uani 1 1 d . U . . .
F13 F 0.0555(3) 0.4122(2) 0.51378(14) 0.0608(7) Uani 1 1 d . . . . .
F14 F 0.0451(4) 0.2677(2) 0.5166(3) 0.1269(19) Uani 1 1 d . . . . .
F15 F 0.2023(3) 0.3909(5) 0.55949(19) 0.137(2) Uani 1 1 d . . . . .
F16A F 0.1222(15) 0.0703(7) 0.2896(7) 0.092(5) Uani 0.347(14) 1 d . . P B 2
F16B F 0.1500(4) 0.1189(4) 0.2331(6) 0.071(3) Uani 0.653(14) 1 d . . P B -2
F17A F 0.1359(8) 0.1310(6) 0.1894(5) 0.036(2) Uani 0.347(14) 1 d . . P B 2
F17B F -0.0129(4) 0.1185(5) 0.1874(4) 0.065(2) Uani 0.653(14) 1 d . . P B -2
F18A F -0.0179(8) 0.0815(9) 0.2326(14) 0.090(6) Uani 0.347(14) 1 d . U P B 2
F18B F 0.0266(10) 0.0592(4) 0.2875(6) 0.123(4) Uani 0.653(14) 1 d . U P B -2
F19 F 0.4817(3) 0.3008(2) 0.2325(2) 0.0821(10) Uani 1 1 d . . . . .
F20 F 0.5975(3) 0.3802(2) 0.17524(19) 0.0778(9) Uani 1 1 d . . . . .
F21 F 0.6234(3) 0.4342(3) 0.2953(2) 0.0922(11) Uani 1 1 d . . . . .
F22A F 0.3577(5) 0.5443(4) -0.0005(2) 0.0531(13) Uani 0.607(8) 1 d . U P C 1
F22B F 0.4362(10) 0.5660(5) 0.0131(5) 0.067(3) Uani 0.393(8) 1 d . U P C -1
F23A F 0.5291(4) 0.6363(5) 0.0551(3) 0.074(2) Uani 0.607(8) 1 d . U P C 1
F23B F 0.5133(5) 0.6997(4) 0.0998(4) 0.046(2) Uani 0.393(8) 1 d . U P C -1
F24A F 0.4006(7) 0.6851(4) 0.0756(3) 0.0633(17) Uani 0.607(8) 1 d . U P C 1
F24B F 0.3385(7) 0.6398(11) 0.0534(6) 0.078(3) Uani 0.393(8) 1 d . U P C -1
C30 C 0.3142(2) 0.6195(2) 0.35962(16) 0.0192(5) Uani 1 1 d . . . . .
C31 C 0.3939(2) 0.6205(2) 0.42598(17) 0.0209(6) Uani 1 1 d . . . . .
H31 H 0.4062 0.5608 0.4290 0.025 Uiso 1 1 calc R . . . .
C32 C 0.4554(2) 0.7057(2) 0.48714(17) 0.0239(6) Uani 1 1 d . . . . .
C33 C 0.4396(3) 0.7944(2) 0.48558(18) 0.0267(6) Uani 1 1 d . . . . .
H33 H 0.4801 0.8522 0.5280 0.032 Uiso 1 1 calc R . . . .
C34 C 0.3630(3) 0.7962(2) 0.42026(18) 0.0245(6) Uani 1 1 d . . . . .
C35 C 0.3035(3) 0.7110(2) 0.35802(17) 0.0225(6) Uani 1 1 d . . . . .
H35 H 0.2540 0.7154 0.3131 0.027 Uiso 1 1 calc R . . . .
C36 C 0.5429(3) 0.7038(3) 0.5545(2) 0.0389(8) Uani 1 1 d . . . . .
C37 C 0.3442(3) 0.8908(2) 0.4162(2) 0.0324(7) Uani 1 1 d . . . . .
C38 C 0.1271(2) 0.5122(2) 0.23191(17) 0.0200(5) Uani 1 1 d . . . . .
C39 C 0.0814(2) 0.4511(2) 0.15568(18) 0.0244(6) Uani 1 1 d . . . . .
H39 H 0.1240 0.4188 0.1355 0.029 Uiso 1 1 calc R . . . .
C40 C -0.0243(3) 0.4359(2) 0.10809(19) 0.0286(7) Uani 1 1 d . . . . .
C41 C -0.0877(3) 0.4839(3) 0.1342(2) 0.0323(7) Uani 1 1 d . . . . .
H41 H -0.1589 0.4753 0.1016 0.039 Uiso 1 1 calc R . . . .
C42 C -0.0443(3) 0.5446(2) 0.2092(2) 0.0274(6) Uani 1 1 d . . . . .
C43 C 0.0599(2) 0.5573(2) 0.25748(18) 0.0226(6) Uani 1 1 d . . . . .
H43 H 0.0860 0.5980 0.3094 0.027 Uiso 1 1 calc R . . . .
C44 C -0.0706(3) 0.3657(3) 0.0284(2) 0.0453(9) Uani 1 1 d . . . . .
C45 C -0.1057(3) 0.6017(3) 0.2411(3) 0.0515(10) Uani 1 1 d . U . . .
C46 C 0.1987(2) 0.4177(2) 0.32574(18) 0.0220(6) Uani 1 1 d . . . . .
C47 C 0.1762(2) 0.4236(2) 0.39751(19) 0.0247(6) Uani 1 1 d . . . . .
H47 H 0.1963 0.4883 0.4300 0.030 Uiso 1 1 calc R . . . .
C48 C 0.1252(3) 0.3383(3) 0.4242(2) 0.0339(8) Uani 1 1 d . . . . .
C49 C 0.0935(3) 0.2434(3) 0.3783(3) 0.0409(9) Uani 1 1 d . . . . .
H49 H 0.0585 0.1852 0.3959 0.049 Uiso 1 1 calc R . . . .
C50 C 0.1138(3) 0.2344(2) 0.3063(2) 0.0383(8) Uani 1 1 d . . . . .
C51 C 0.1659(3) 0.3195(2) 0.2806(2) 0.0294(7) Uani 1 1 d . . . . .
H51 H 0.1797 0.3110 0.2311 0.035 Uiso 1 1 calc R . . . .
C52 C 0.1072(4) 0.3521(3) 0.5029(3) 0.0485(10) Uani 1 1 d . . . . .
C53 C 0.0757(4) 0.1322(3) 0.2530(4) 0.0643(14) Uani 1 1 d . . . . .
C54 C 0.3313(2) 0.5085(2) 0.23844(16) 0.0194(5) Uani 1 1 d . . . . .
C55 C 0.3998(3) 0.4555(2) 0.25283(17) 0.0243(6) Uani 1 1 d . . . . .
H55 H 0.3957 0.4207 0.2934 0.029 Uiso 1 1 calc R . . . .
C56 C 0.4744(3) 0.4518(2) 0.20931(19) 0.0274(6) Uani 1 1 d . . . . .
C57 C 0.4841(3) 0.5017(2) 0.15031(18) 0.0276(6) Uani 1 1 d . . . . .
H57 H 0.5346 0.4990 0.1208 0.033 Uiso 1 1 calc R . . . .
C58 C 0.4178(3) 0.5561(2) 0.13536(17) 0.0251(6) Uani 1 1 d . . . . .
C59 C 0.3433(2) 0.5591(2) 0.17837(17) 0.0231(6) Uani 1 1 d . . . . .
H59 H 0.2988 0.5968 0.1667 0.028 Uiso 1 1 calc R . . . .
C60 C 0.5438(4) 0.3916(3) 0.2278(3) 0.0463(10) Uani 1 1 d . . . . .
C61 C 0.4255(3) 0.6093(3) 0.0710(2) 0.0379(7) Uani 1 1 d . U . . .
B1 B 0.2443(3) 0.5160(2) 0.28919(18) 0.0187(6) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 P1 2.2932(8) . ?
Rh1 P2 2.2941(7) . ?
Rh1 C22 2.179(3) . ?
Rh1 C23 2.185(3) . ?
Rh1 C26 2.231(3) . ?
Rh1 C27 2.241(3) . ?
P1 P2 2.6522(10) . ?
P1 C1 1.732(3) . ?
P1 C5 1.723(3) . ?
P2 C1 1.801(3) . ?
P2 C7 1.807(3) . ?
P2 C13 1.811(3) . ?
Si1 C5 1.886(3) . ?
Si1 C19A 1.801(6) . ?
Si1 C19B 1.962(8) . ?
Si1 C20A 1.836(7) . ?
Si1 C20B 1.786(8) . ?
Si1 C21A 1.956(7) . ?
Si1 C21B 1.778(9) . ?
C1 C2 1.397(4) . ?
C2 C3 1.397(5) . ?
C2 C6 1.507(4) . ?
C3 H3 0.9500 . ?
C3 C4 1.385(5) . ?
C4 H4 0.9500 . ?
C4 C5 1.409(4) . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 C8 1.386(5) . ?
C7 C12 1.404(5) . ?
C8 H8 0.9500 . ?
C8 C9 1.392(5) . ?
C9 H9 0.9500 . ?
C9 C10 1.372(6) . ?
C10 H10 0.9500 . ?
C10 C11 1.380(7) . ?
C11 H11 0.9500 . ?
C11 C12 1.388(5) . ?
C12 H12 0.9500 . ?
C13 C14 1.399(4) . ?
C13 C18 1.393(5) . ?
C14 H14 0.9500 . ?
C14 C15 1.390(5) . ?
C15 H15 0.9500 . ?
C15 C16 1.364(6) . ?
C16 H16 0.9500 . ?
C16 C17 1.395(6) . ?
C17 H17 0.9500 . ?
C17 C18 1.388(5) . ?
C18 H18 0.9500 . ?
C19A H19A 0.9800 . ?
C19A H19B 0.9800 . ?
C19A H19C 0.9800 . ?
C19A C19B 1.540(12) . ?
C19A C21B 1.886(14) . ?
C19B H19D 0.9800 . ?
C19B H19E 0.9800 . ?
C19B H19F 0.9800 . ?
C20A H20A 0.9800 . ?
C20A H20B 0.9800 . ?
C20A H20C 0.9800 . ?
C20A C20B 1.184(12) . ?
C20B H20D 0.9800 . ?
C20B H20E 0.9800 . ?
C20B H20F 0.9800 . ?
C21A H21A 0.9800 . ?
C21A H21B 0.9800 . ?
C21A H21C 0.9800 . ?
C21A C21B 1.467(15) . ?
C21B H21D 0.9800 . ?
C21B H21E 0.9800 . ?
C21B H21F 0.9800 . ?
C22 H22 1.0000 . ?
C22 C23 1.371(5) . ?
C22 C29 1.492(6) . ?
C23 H23 1.0000 . ?
C23 C24 1.519(6) . ?
C24 H24A 0.9900 . ?
C24 H24B 0.9900 . ?
C24 C25 1.447(7) . ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?
C25 C26 1.483(5) . ?
C26 H26 1.0000 . ?
C26 C27 1.371(5) . ?
C27 H27 1.0000 . ?
C27 C28 1.506(5) . ?
C28 H28A 0.9900 . ?
C28 H28B 0.9900 . ?
C28 C29 1.456(6) . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
F1 C36 1.305(4) . ?
F2 C36 1.305(5) . ?
F3 C36 1.313(5) . ?
F4 C37 1.334(4) . ?
F5 C37 1.345(4) . ?
F6 C37 1.340(4) . ?
F7 C44 1.303(5) . ?
F8 C44 1.312(5) . ?
F9 C44 1.340(5) . ?
F10 C45 1.331(5) . ?
F11 C45 1.315(5) . ?
F12 C45 1.308(6) . ?
F13 C52 1.308(5) . ?
F14 C52 1.312(5) . ?
F15 C52 1.310(5) . ?
F16A F16B 1.367(13) . ?
F16A F18B 1.208(13) . ?
F16A C53 1.422(12) . ?
F16B F17A 0.828(8) . ?
F16B C53 1.186(7) . ?
F17A C53 1.536(9) . ?
F17B F18A 1.04(2) . ?
F17B C53 1.405(8) . ?
F18A F18B 1.19(2) . ?
F18A C53 1.138(10) . ?
F18B C53 1.352(8) . ?
F19 C60 1.318(5) . ?
F20 C60 1.328(4) . ?
F21 C60 1.318(5) . ?
F22A F22B 0.935(10) . ?
F22A F24B 1.711(14) . ?
F22A C61 1.382(6) . ?
F22B F23A 1.272(11) . ?
F22B C61 1.202(8) . ?
F23A F23B 1.244(8) . ?
F23A C61 1.393(6) . ?
F23B F24A 1.387(9) . ?
F23B C61 1.349(6) . ?
F24A F24B 0.819(9) . ?
F24A C61 1.260(6) . ?
F24B C61 1.368(9) . ?
C30 C31 1.407(4) . ?
C30 C35 1.398(4) . ?
C30 B1 1.644(4) . ?
C31 H31 0.9500 . ?
C31 C32 1.388(4) . ?
C32 C33 1.387(4) . ?
C32 C36 1.495(4) . ?
C33 H33 0.9500 . ?
C33 C34 1.387(4) . ?
C34 C35 1.396(4) . ?
C34 C37 1.498(4) . ?
C35 H35 0.9500 . ?
C38 C39 1.398(4) . ?
C38 C43 1.395(4) . ?
C38 B1 1.642(4) . ?
C39 H39 0.9500 . ?
C39 C40 1.393(4) . ?
C40 C41 1.383(5) . ?
C40 C44 1.497(5) . ?
C41 H41 0.9500 . ?
C41 C42 1.379(5) . ?
C42 C43 1.393(4) . ?
C42 C45 1.494(5) . ?
C43 H43 0.9500 . ?
C46 C47 1.388(4) . ?
C46 C51 1.407(4) . ?
C46 B1 1.643(4) . ?
C47 H47 0.9500 . ?
C47 C48 1.401(4) . ?
C48 C49 1.375(5) . ?
C48 C52 1.488(6) . ?
C49 H49 0.9500 . ?
C49 C50 1.381(6) . ?
C50 C51 1.392(5) . ?
C50 C53 1.500(5) . ?
C51 H51 0.9500 . ?
C54 C55 1.394(4) . ?
C54 C59 1.403(4) . ?
C54 B1 1.643(4) . ?
C55 H55 0.9500 . ?
C55 C56 1.401(4) . ?
C56 C57 1.379(5) . ?
C56 C60 1.501(5) . ?
C57 H57 0.9500 . ?
C57 C58 1.387(5) . ?
C58 C59 1.391(4) . ?
C58 C61 1.490(4) . ?
C59 H59 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Rh1 P2 70.64(3) . . ?
C22 Rh1 P1 156.27(10) . . ?
C22 Rh1 P2 94.83(10) . . ?
C22 Rh1 C23 36.61(14) . . ?
C22 Rh1 C26 93.91(13) . . ?
C22 Rh1 C27 81.31(13) . . ?
C23 Rh1 P1 159.19(11) . . ?
C23 Rh1 P2 97.31(10) . . ?
C23 Rh1 C26 80.81(13) . . ?
C23 Rh1 C27 90.29(13) . . ?
C26 Rh1 P1 105.39(10) . . ?
C26 Rh1 P2 162.32(9) . . ?
C26 Rh1 C27 35.72(12) . . ?
C27 Rh1 P1 106.40(8) . . ?
C27 Rh1 P2 161.59(9) . . ?
Rh1 P1 P2 54.69(2) . . ?
C1 P1 Rh1 96.99(10) . . ?
C1 P1 P2 42.33(10) . . ?
C5 P1 Rh1 155.77(11) . . ?
C5 P1 P2 149.20(11) . . ?
C5 P1 C1 106.90(15) . . ?
Rh1 P2 P1 54.66(2) . . ?
C1 P2 Rh1 94.99(10) . . ?
C1 P2 P1 40.37(9) . . ?
C1 P2 C7 107.41(15) . . ?
C1 P2 C13 109.80(13) . . ?
C7 P2 Rh1 118.26(10) . . ?
C7 P2 P1 125.04(11) . . ?
C7 P2 C13 108.29(14) . . ?
C13 P2 Rh1 116.74(10) . . ?
C13 P2 P1 123.22(10) . . ?
C5 Si1 C19B 105.6(3) . . ?
C5 Si1 C21A 107.7(2) . . ?
C19A Si1 C5 109.2(2) . . ?
C19A Si1 C19B 48.1(4) . . ?
C19A Si1 C20A 114.1(4) . . ?
C19A Si1 C21A 108.5(3) . . ?
C20A Si1 C5 111.5(3) . . ?
C20A Si1 C19B 72.2(4) . . ?
C20A Si1 C21A 105.5(4) . . ?
C20B Si1 C5 106.5(3) . . ?
C20B Si1 C19A 142.1(4) . . ?
C20B Si1 C19B 109.8(4) . . ?
C20B Si1 C20A 38.1(4) . . ?
C20B Si1 C21A 71.4(4) . . ?
C21A Si1 C19B 144.6(3) . . ?
C21B Si1 C5 113.0(3) . . ?
C21B Si1 C19A 63.6(5) . . ?
C21B Si1 C19B 109.0(5) . . ?
C21B Si1 C20A 133.0(4) . . ?
C21B Si1 C20B 112.6(5) . . ?
C21B Si1 C21A 46.0(5) . . ?
P1 C1 P2 97.30(14) . . ?
C2 C1 P1 125.1(2) . . ?
C2 C1 P2 137.6(2) . . ?
C1 C2 C3 118.0(3) . . ?
C1 C2 C6 121.3(3) . . ?
C3 C2 C6 120.6(3) . . ?
C2 C3 H3 117.2 . . ?
C4 C3 C2 125.7(3) . . ?
C4 C3 H3 117.2 . . ?
C3 C4 H4 115.7 . . ?
C3 C4 C5 128.6(3) . . ?
C5 C4 H4 115.7 . . ?
P1 C5 Si1 123.60(18) . . ?
C4 C5 P1 115.7(2) . . ?
C4 C5 Si1 120.7(2) . . ?
C2 C6 H6A 109.5 . . ?
C2 C6 H6B 109.5 . . ?
C2 C6 H6C 109.5 . . ?
H6A C6 H6B 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C8 C7 P2 119.6(3) . . ?
C8 C7 C12 119.7(3) . . ?
C12 C7 P2 120.3(3) . . ?
C7 C8 H8 120.0 . . ?
C7 C8 C9 120.0(4) . . ?
C9 C8 H8 120.0 . . ?
C8 C9 H9 120.1 . . ?
C10 C9 C8 119.8(4) . . ?
C10 C9 H9 120.1 . . ?
C9 C10 H10 119.6 . . ?
C9 C10 C11 120.9(3) . . ?
C11 C10 H10 119.6 . . ?
C10 C11 H11 120.0 . . ?
C10 C11 C12 120.1(4) . . ?
C12 C11 H11 120.0 . . ?
C7 C12 H12 120.3 . . ?
C11 C12 C7 119.4(4) . . ?
C11 C12 H12 120.3 . . ?
C14 C13 P2 122.9(3) . . ?
C18 C13 P2 117.6(2) . . ?
C18 C13 C14 119.5(3) . . ?
C13 C14 H14 120.2 . . ?
C15 C14 C13 119.5(4) . . ?
C15 C14 H14 120.2 . . ?
C14 C15 H15 119.7 . . ?
C16 C15 C14 120.7(4) . . ?
C16 C15 H15 119.7 . . ?
C15 C16 H16 119.7 . . ?
C15 C16 C17 120.6(3) . . ?
C17 C16 H16 119.7 . . ?
C16 C17 H17 120.3 . . ?
C18 C17 C16 119.3(4) . . ?
C18 C17 H17 120.3 . . ?
C13 C18 H18 119.8 . . ?
C17 C18 C13 120.4(3) . . ?
C17 C18 H18 119.8 . . ?
Si1 C19A H19A 109.5 . . ?
Si1 C19A H19B 109.5 . . ?
Si1 C19A H19C 109.5 . . ?
Si1 C19A C21B 57.6(4) . . ?
H19A C19A H19B 109.5 . . ?
H19A C19A H19C 109.5 . . ?
H19B C19A H19C 109.5 . . ?
C19B C19A Si1 71.5(4) . . ?
C19B C19A H19A 150.2 . . ?
C19B C19A H19B 97.4 . . ?
C19B C19A H19C 47.2 . . ?
C19B C19A C21B 125.3(6) . . ?
C21B C19A H19A 72.0 . . ?
C21B C19A H19B 82.9 . . ?
C21B C19A H19C 165.3 . . ?
Si1 C19B H19D 109.5 . . ?
Si1 C19B H19E 109.5 . . ?
Si1 C19B H19F 109.5 . . ?
C19A C19B Si1 60.5(4) . . ?
C19A C19B H19D 159.5 . . ?
C19A C19B H19E 62.6 . . ?
C19A C19B H19F 91.0 . . ?
H19D C19B H19E 109.5 . . ?
H19D C19B H19F 109.5 . . ?
H19E C19B H19F 109.5 . . ?
Si1 C20A H20A 109.5 . . ?
Si1 C20A H20B 109.5 . . ?
Si1 C20A H20C 109.5 . . ?
H20A C20A H20B 109.5 . . ?
H20A C20A H20C 109.5 . . ?
H20B C20A H20C 109.5 . . ?
C20B C20A Si1 68.7(5) . . ?
C20B C20A H20A 52.6 . . ?
C20B C20A H20B 155.6 . . ?
C20B C20A H20C 93.4 . . ?
Si1 C20B H20D 109.5 . . ?
Si1 C20B H20E 109.5 . . ?
Si1 C20B H20F 109.5 . . ?
C20A C20B Si1 73.2(5) . . ?
C20A C20B H20D 59.7 . . ?
C20A C20B H20E 79.2 . . ?
C20A C20B H20F 168.5 . . ?
H20D C20B H20E 109.5 . . ?
H20D C20B H20F 109.5 . . ?
H20E C20B H20F 109.5 . . ?
Si1 C21A H21A 109.5 . . ?
Si1 C21A H21B 109.5 . . ?
Si1 C21A H21C 109.5 . . ?
H21A C21A H21B 109.5 . . ?
H21A C21A H21C 109.5 . . ?
H21B C21A H21C 109.5 . . ?
C21B C21A Si1 60.6(4) . . ?
C21B C21A H21A 164.6 . . ?
C21B C21A H21B 85.6 . . ?
C21B C21A H21C 66.6 . . ?
Si1 C21B C19A 58.8(4) . . ?
Si1 C21B H21D 109.5 . . ?
Si1 C21B H21E 109.5 . . ?
Si1 C21B H21F 109.5 . . ?
C19A C21B H21D 64.6 . . ?
C19A C21B H21E 159.7 . . ?
C19A C21B H21F 90.6 . . ?
C21A C21B Si1 73.4(5) . . ?
C21A C21B C19A 130.4(7) . . ?
C21A C21B H21D 153.4 . . ?
C21A C21B H21E 47.9 . . ?
C21A C21B H21F 93.5 . . ?
H21D C21B H21E 109.5 . . ?
H21D C21B H21F 109.5 . . ?
H21E C21B H21F 109.5 . . ?
Rh1 C22 H22 113.4 . . ?
C23 C22 Rh1 71.94(19) . . ?
C23 C22 H22 113.4 . . ?
C23 C22 C29 128.5(4) . . ?
C29 C22 Rh1 106.9(3) . . ?
C29 C22 H22 113.4 . . ?
Rh1 C23 H23 114.7 . . ?
C22 C23 Rh1 71.46(19) . . ?
C22 C23 H23 114.7 . . ?
C22 C23 C24 123.1(4) . . ?
C24 C23 Rh1 110.2(3) . . ?
C24 C23 H23 114.7 . . ?
C23 C24 H24A 108.0 . . ?
C23 C24 H24B 108.0 . . ?
H24A C24 H24B 107.2 . . ?
C25 C24 C23 117.4(4) . . ?
C25 C24 H24A 108.0 . . ?
C25 C24 H24B 108.0 . . ?
C24 C25 H25A 108.1 . . ?
C24 C25 H25B 108.1 . . ?
C24 C25 C26 116.9(3) . . ?
H25A C25 H25B 107.3 . . ?
C26 C25 H25A 108.1 . . ?
C26 C25 H25B 108.1 . . ?
Rh1 C26 H26 113.8 . . ?
C25 C26 Rh1 108.1(2) . . ?
C25 C26 H26 113.8 . . ?
C27 C26 Rh1 72.54(18) . . ?
C27 C26 C25 126.7(4) . . ?
C27 C26 H26 113.8 . . ?
Rh1 C27 H27 114.5 . . ?
C26 C27 Rh1 71.74(18) . . ?
C26 C27 H27 114.5 . . ?
C26 C27 C28 124.7(3) . . ?
C28 C27 Rh1 108.6(2) . . ?
C28 C27 H27 114.5 . . ?
C27 C28 H28A 108.2 . . ?
C27 C28 H28B 108.2 . . ?
H28A C28 H28B 107.4 . . ?
C29 C28 C27 116.2(3) . . ?
C29 C28 H28A 108.2 . . ?
C29 C28 H28B 108.2 . . ?
C22 C29 H29A 107.8 . . ?
C22 C29 H29B 107.8 . . ?
C28 C29 C22 118.1(4) . . ?
C28 C29 H29A 107.8 . . ?
C28 C29 H29B 107.8 . . ?
H29A C29 H29B 107.1 . . ?
F16B F16A C53 50.3(5) . . ?
F18B F16A F16B 107.7(11) . . ?
F18B F16A C53 61.2(7) . . ?
F17A F16B F16A 153.5(13) . . ?
F17A F16B C53 97.8(10) . . ?
C53 F16B F16A 67.3(6) . . ?
F16B F17A C53 49.9(6) . . ?
F18A F17B C53 52.9(6) . . ?
F17B F18A F18B 150.2(12) . . ?
F17B F18A C53 80.1(12) . . ?
C53 F18A F18B 71.1(10) . . ?
F16A F18B C53 67.2(7) . . ?
F18A F18B F16A 112.2(12) . . ?
F18A F18B C53 52.8(6) . . ?
F22B F22A F24B 103.2(7) . . ?
F22B F22A C61 58.8(5) . . ?
C61 F22A F24B 51.1(4) . . ?
F22A F22B F23A 144.4(10) . . ?
F22A F22B C61 79.5(8) . . ?
C61 F22B F23A 68.5(5) . . ?
F22B F23A C61 53.4(4) . . ?
F23B F23A F22B 111.3(6) . . ?
F23B F23A C61 61.3(4) . . ?
F23A F23B F24A 109.0(5) . . ?
F23A F23B C61 64.8(4) . . ?
C61 F23B F24A 54.8(3) . . ?
F24B F24A F23B 140.0(11) . . ?
F24B F24A C61 79.2(9) . . ?
C61 F24A F23B 61.1(4) . . ?
F24A F24B F22A 108.0(10) . . ?
F24A F24B C61 64.8(7) . . ?
C61 F24B F22A 51.9(4) . . ?
C31 C30 B1 119.9(2) . . ?
C35 C30 C31 115.6(3) . . ?
C35 C30 B1 124.5(2) . . ?
C30 C31 H31 118.8 . . ?
C32 C31 C30 122.4(3) . . ?
C32 C31 H31 118.8 . . ?
C31 C32 C36 120.0(3) . . ?
C33 C32 C31 120.9(3) . . ?
C33 C32 C36 119.1(3) . . ?
C32 C33 H33 121.0 . . ?
C32 C33 C34 118.1(3) . . ?
C34 C33 H33 121.0 . . ?
C33 C34 C35 120.8(3) . . ?
C33 C34 C37 119.7(3) . . ?
C35 C34 C37 119.5(3) . . ?
C30 C35 H35 118.9 . . ?
C34 C35 C30 122.2(3) . . ?
C34 C35 H35 118.9 . . ?
F1 C36 F2 106.7(3) . . ?
F1 C36 F3 105.3(4) . . ?
F1 C36 C32 113.9(3) . . ?
F2 C36 F3 105.1(4) . . ?
F2 C36 C32 113.3(3) . . ?
F3 C36 C32 111.7(3) . . ?
F4 C37 F5 105.2(3) . . ?
F4 C37 F6 107.4(3) . . ?
F4 C37 C34 112.9(3) . . ?
F5 C37 C34 112.7(3) . . ?
F6 C37 F5 105.4(3) . . ?
F6 C37 C34 112.6(3) . . ?
C39 C38 B1 120.4(2) . . ?
C43 C38 C39 115.5(3) . . ?
C43 C38 B1 123.6(3) . . ?
C38 C39 H39 118.7 . . ?
C40 C39 C38 122.6(3) . . ?
C40 C39 H39 118.7 . . ?
C39 C40 C44 119.8(3) . . ?
C41 C40 C39 120.6(3) . . ?
C41 C40 C44 119.6(3) . . ?
C40 C41 H41 121.1 . . ?
C42 C41 C40 117.9(3) . . ?
C42 C41 H41 121.1 . . ?
C41 C42 C43 121.4(3) . . ?
C41 C42 C45 121.2(3) . . ?
C43 C42 C45 117.4(3) . . ?
C38 C43 H43 119.0 . . ?
C42 C43 C38 122.0(3) . . ?
C42 C43 H43 119.0 . . ?
F7 C44 F8 107.8(4) . . ?
F7 C44 F9 106.9(4) . . ?
F7 C44 C40 112.3(4) . . ?
F8 C44 F9 103.1(4) . . ?
F8 C44 C40 113.4(3) . . ?
F9 C44 C40 112.7(3) . . ?
F10 C45 C42 113.5(4) . . ?
F11 C45 F10 107.9(4) . . ?
F11 C45 C42 111.9(3) . . ?
F12 C45 F10 105.6(4) . . ?
F12 C45 F11 104.1(5) . . ?
F12 C45 C42 113.2(4) . . ?
C47 C46 C51 115.4(3) . . ?
C47 C46 B1 123.3(3) . . ?
C51 C46 B1 120.8(3) . . ?
C46 C47 H47 118.6 . . ?
C46 C47 C48 122.9(3) . . ?
C48 C47 H47 118.6 . . ?
C47 C48 C52 119.0(3) . . ?
C49 C48 C47 120.2(3) . . ?
C49 C48 C52 120.7(3) . . ?
C48 C49 H49 120.7 . . ?
C48 C49 C50 118.6(3) . . ?
C50 C49 H49 120.7 . . ?
C49 C50 C51 120.9(3) . . ?
C49 C50 C53 120.2(4) . . ?
C51 C50 C53 118.9(4) . . ?
C46 C51 H51 119.0 . . ?
C50 C51 C46 122.1(3) . . ?
C50 C51 H51 119.0 . . ?
F13 C52 F14 104.8(4) . . ?
F13 C52 F15 105.7(4) . . ?
F13 C52 C48 113.6(3) . . ?
F14 C52 C48 113.1(4) . . ?
F15 C52 F14 106.7(4) . . ?
F15 C52 C48 112.3(3) . . ?
F16A C53 F17A 92.6(6) . . ?
F16A C53 C50 111.7(6) . . ?
F16B C53 F16A 62.5(6) . . ?
F16B C53 F17A 32.3(5) . . ?
F16B C53 F17B 110.4(7) . . ?
F16B C53 F18B 110.1(7) . . ?
F16B C53 C50 112.7(4) . . ?
F17B C53 F16A 136.9(6) . . ?
F17B C53 F17A 80.6(5) . . ?
F17B C53 C50 109.8(4) . . ?
F18A C53 F16A 101.3(10) . . ?
F18A C53 F16B 128.4(7) . . ?
F18A C53 F17A 114.5(11) . . ?
F18A C53 F17B 47.0(12) . . ?
F18A C53 F18B 56.1(11) . . ?
F18A C53 C50 118.6(6) . . ?
F18B C53 F16A 51.6(6) . . ?
F18B C53 F17A 131.0(6) . . ?
F18B C53 F17B 102.8(6) . . ?
F18B C53 C50 110.5(5) . . ?
C50 C53 F17A 114.0(4) . . ?
C55 C54 C59 115.6(3) . . ?
C55 C54 B1 123.4(3) . . ?
C59 C54 B1 121.0(2) . . ?
C54 C55 H55 119.0 . . ?
C54 C55 C56 122.0(3) . . ?
C56 C55 H55 119.0 . . ?
C55 C56 C60 118.6(3) . . ?
C57 C56 C55 121.1(3) . . ?
C57 C56 C60 120.3(3) . . ?
C56 C57 H57 121.0 . . ?
C56 C57 C58 118.0(3) . . ?
C58 C57 H57 121.0 . . ?
C57 C58 C59 120.7(3) . . ?
C57 C58 C61 118.9(3) . . ?
C59 C58 C61 120.4(3) . . ?
C54 C59 H59 118.8 . . ?
C58 C59 C54 122.5(3) . . ?
C58 C59 H59 118.8 . . ?
F19 C60 F20 107.4(3) . . ?
F19 C60 C56 111.7(3) . . ?
F20 C60 C56 113.1(3) . . ?
F21 C60 F19 106.4(4) . . ?
F21 C60 F20 105.3(4) . . ?
F21 C60 C56 112.4(3) . . ?
F22A C61 F23A 98.6(4) . . ?
F22A C61 C58 110.9(3) . . ?
F22B C61 F22A 41.7(5) . . ?
F22B C61 F23A 58.1(6) . . ?
F22B C61 F23B 108.8(6) . . ?
F22B C61 F24A 124.9(6) . . ?
F22B C61 F24B 111.7(7) . . ?
F22B C61 C58 116.1(5) . . ?
F23A C61 C58 114.0(3) . . ?
F23B C61 F22A 139.3(4) . . ?
F23B C61 F23A 53.9(4) . . ?
F23B C61 F24B 100.0(7) . . ?
F23B C61 C58 108.1(4) . . ?
F24A C61 F22A 106.1(4) . . ?
F24A C61 F23A 107.7(5) . . ?
F24A C61 F23B 64.1(4) . . ?
F24A C61 F24B 36.0(5) . . ?
F24A C61 C58 117.7(4) . . ?
F24B C61 F22A 77.0(6) . . ?
F24B C61 F23A 133.4(5) . . ?
F24B C61 C58 110.8(4) . . ?
C38 B1 C30 114.2(2) . . ?
C38 B1 C46 102.5(2) . . ?
C38 B1 C54 110.5(2) . . ?
C46 B1 C30 110.6(2) . . ?
C46 B1 C54 112.9(2) . . ?
C54 B1 C30 106.3(2) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Rh1 P1 C1 P2 -2.37(12) . . . . ?
Rh1 P1 C1 C2 177.3(3) . . . . ?
Rh1 P1 C5 Si1 7.9(4) . . . . ?
Rh1 P1 C5 C4 -170.77(19) . . . . ?
Rh1 P2 C1 P1 2.36(12) . . . . ?
Rh1 P2 C1 C2 -177.2(3) . . . . ?
Rh1 P2 C7 C8 86.4(3) . . . . ?
Rh1 P2 C7 C12 -87.4(3) . . . . ?
Rh1 P2 C13 C14 153.8(2) . . . . ?
Rh1 P2 C13 C18 -25.7(3) . . . . ?
Rh1 C22 C23 C24 -102.5(4) . . . . ?
Rh1 C22 C29 C28 33.6(6) . . . . ?
Rh1 C23 C24 C25 2.8(7) . . . . ?
Rh1 C26 C27 C28 -100.4(3) . . . . ?
Rh1 C27 C28 C29 2.3(5) . . . . ?
P1 P2 C1 C2 -179.6(4) . . . . ?
P1 P2 C7 C8 21.5(3) . . . . ?
P1 P2 C7 C12 -152.3(2) . . . . ?
P1 P2 C13 C14 -142.6(2) . . . . ?
P1 P2 C13 C18 37.9(3) . . . . ?
P1 C1 C2 C3 -1.2(4) . . . . ?
P1 C1 C2 C6 -179.7(2) . . . . ?
P2 P1 C1 C2 179.6(4) . . . . ?
P2 P1 C5 Si1 175.67(8) . . . . ?
P2 P1 C5 C4 -3.0(4) . . . . ?
P2 C1 C2 C3 178.2(3) . . . . ?
P2 C1 C2 C6 -0.2(5) . . . . ?
P2 C7 C8 C9 -176.0(3) . . . . ?
P2 C7 C12 C11 176.1(3) . . . . ?
P2 C13 C14 C15 -178.5(3) . . . . ?
P2 C13 C18 C17 179.9(3) . . . . ?
Si1 C19A C21B C21A 17.5(7) . . . . ?
Si1 C21A C21B C19A -15.5(6) . . . . ?
C1 P1 C5 Si1 177.93(18) . . . . ?
C1 P1 C5 C4 -0.7(3) . . . . ?
C1 P2 C7 C8 -19.4(3) . . . . ?
C1 P2 C7 C12 166.8(3) . . . . ?
C1 P2 C13 C14 -99.7(3) . . . . ?
C1 P2 C13 C18 80.8(3) . . . . ?
C1 C2 C3 C4 0.4(5) . . . . ?
C2 C3 C4 C5 0.3(6) . . . . ?
C3 C4 C5 P1 0.0(5) . . . . ?
C3 C4 C5 Si1 -178.6(3) . . . . ?
C5 P1 C1 P2 -178.28(13) . . . . ?
C5 P1 C1 C2 1.4(3) . . . . ?
C5 Si1 C19A C19B -94.0(4) . . . . ?
C5 Si1 C19A C21B 106.8(3) . . . . ?
C5 Si1 C20A C20B -89.7(7) . . . . ?
C5 Si1 C20B C20A 103.9(6) . . . . ?
C5 Si1 C21B C19A -100.9(3) . . . . ?
C5 Si1 C21B C21A 92.9(4) . . . . ?
C6 C2 C3 C4 178.8(3) . . . . ?
C7 P2 C1 P1 124.07(14) . . . . ?
C7 P2 C1 C2 -55.5(4) . . . . ?
C7 P2 C13 C14 17.3(3) . . . . ?
C7 P2 C13 C18 -162.2(2) . . . . ?
C7 C8 C9 C10 0.3(5) . . . . ?
C8 C7 C12 C11 2.3(5) . . . . ?
C8 C9 C10 C11 1.4(6) . . . . ?
C9 C10 C11 C12 -1.3(7) . . . . ?
C10 C11 C12 C7 -0.6(6) . . . . ?
C12 C7 C8 C9 -2.1(5) . . . . ?
C13 P2 C1 P1 -118.40(14) . . . . ?
C13 P2 C1 C2 62.0(4) . . . . ?
C13 P2 C7 C8 -137.9(3) . . . . ?
C13 P2 C7 C12 48.3(3) . . . . ?
C13 C14 C15 C16 -1.4(5) . . . . ?
C14 C13 C18 C17 0.4(5) . . . . ?
C14 C15 C16 C17 0.4(6) . . . . ?
C15 C16 C17 C18 1.1(5) . . . . ?
C16 C17 C18 C13 -1.5(5) . . . . ?
C18 C13 C14 C15 1.0(5) . . . . ?
C19A Si1 C5 P1 -64.3(3) . . . . ?
C19A Si1 C5 C4 114.3(4) . . . . ?
C19A Si1 C20A C20B 146.0(7) . . . . ?
C19A Si1 C20B C20A -56.1(10) . . . . ?
C19A Si1 C21B C21A -166.2(5) . . . . ?
C19B Si1 C5 P1 -114.7(4) . . . . ?
C19B Si1 C5 C4 63.9(4) . . . . ?
C19B Si1 C19A C21B -159.2(5) . . . . ?
C19B Si1 C20A C20B 170.1(7) . . . . ?
C19B Si1 C20B C20A -10.0(8) . . . . ?
C19B Si1 C21B C19A 16.2(4) . . . . ?
C19B Si1 C21B C21A -150.0(4) . . . . ?
C19B C19A C21B Si1 -24.3(6) . . . . ?
C19B C19A C21B C21A -6.9(11) . . . . ?
C20A Si1 C5 P1 168.6(3) . . . . ?
C20A Si1 C5 C4 -12.8(4) . . . . ?
C20A Si1 C19A C19B 31.5(5) . . . . ?
C20A Si1 C19A C21B -127.7(4) . . . . ?
C20A Si1 C21B C19A 99.3(6) . . . . ?
C20A Si1 C21B C21A -66.9(7) . . . . ?
C20B Si1 C5 P1 128.6(4) . . . . ?
C20B Si1 C5 C4 -52.9(5) . . . . ?
C20B Si1 C19A C19B 65.7(8) . . . . ?
C20B Si1 C19A C21B -93.5(7) . . . . ?
C20B Si1 C21B C19A 138.3(4) . . . . ?
C20B Si1 C21B C21A -27.9(6) . . . . ?
C21A Si1 C5 P1 53.3(3) . . . . ?
C21A Si1 C5 C4 -128.1(4) . . . . ?
C21A Si1 C19A C19B 148.8(4) . . . . ?
C21A Si1 C19A C21B -10.4(4) . . . . ?
C21A Si1 C20A C20B 27.0(7) . . . . ?
C21A Si1 C20B C20A -152.5(7) . . . . ?
C21A Si1 C21B C19A 166.2(5) . . . . ?
C21B Si1 C5 P1 4.4(5) . . . . ?
C21B Si1 C5 C4 -177.0(5) . . . . ?
C21B Si1 C19A C19B 159.2(5) . . . . ?
C21B Si1 C20A C20B 70.3(9) . . . . ?
C21B Si1 C20B C20A -131.7(7) . . . . ?
C21B C19A C19B Si1 21.5(5) . . . . ?
C22 C23 C24 C25 83.3(6) . . . . ?
C23 C22 C29 C28 -46.5(7) . . . . ?
C23 C24 C25 C26 -22.0(8) . . . . ?
C24 C25 C26 Rh1 28.7(5) . . . . ?
C24 C25 C26 C27 -52.7(6) . . . . ?
C25 C26 C27 Rh1 99.9(3) . . . . ?
C25 C26 C27 C28 -0.5(5) . . . . ?
C26 C27 C28 C29 82.6(5) . . . . ?
C27 C28 C29 C22 -24.9(7) . . . . ?
C29 C22 C23 Rh1 97.6(4) . . . . ?
C29 C22 C23 C24 -4.9(6) . . . . ?
F16A F16B F17A C53 53.2(18) . . . . ?
F16A F16B C53 F17A -157.2(11) . . . . ?
F16A F16B C53 F17B -133.2(7) . . . . ?
F16A F16B C53 F18A -82.5(16) . . . . ?
F16A F16B C53 F18B -20.4(9) . . . . ?
F16A F16B C53 C50 103.5(8) . . . . ?
F16A F18B C53 F16B 23.2(10) . . . . ?
F16A F18B C53 F17A 52.2(11) . . . . ?
F16A F18B C53 F17B 140.9(8) . . . . ?
F16A F18B C53 F18A 146.6(12) . . . . ?
F16A F18B C53 C50 -102.0(8) . . . . ?
F16B F16A F18B F18A 8.5(12) . . . . ?
F16B F16A F18B C53 -19.7(7) . . . . ?
F16B F16A C53 F17A 12.0(6) . . . . ?
F16B F16A C53 F17B 91.1(11) . . . . ?
F16B F16A C53 F18A 127.5(10) . . . . ?
F16B F16A C53 F18B 155.3(10) . . . . ?
F16B F16A C53 C50 -105.2(6) . . . . ?
F16B F17A C53 F16A -20.1(10) . . . . ?
F16B F17A C53 F17B -157.3(9) . . . . ?
F16B F17A C53 F18A -123.8(14) . . . . ?
F16B F17A C53 F18B -58.4(13) . . . . ?
F16B F17A C53 C50 95.1(9) . . . . ?
F17A F16B C53 F16A 157.2(11) . . . . ?
F17A F16B C53 F17B 24.0(9) . . . . ?
F17A F16B C53 F18A 74.7(19) . . . . ?
F17A F16B C53 F18B 136.8(9) . . . . ?
F17A F16B C53 C50 -99.3(9) . . . . ?
F17B F18A F18B F16A -18(3) . . . . ?
F17B F18A F18B C53 15(2) . . . . ?
F17B F18A C53 F16A -146.2(8) . . . . ?
F17B F18A C53 F16B -82.5(13) . . . . ?
F17B F18A C53 F17A -48.1(9) . . . . ?
F17B F18A C53 F18B -172.3(11) . . . . ?
F17B F18A C53 C50 91.1(12) . . . . ?
F18A F17B C53 F16A 52.9(12) . . . . ?
F18A F17B C53 F16B 123.9(9) . . . . ?
F18A F17B C53 F17A 136.7(9) . . . . ?
F18A F17B C53 F18B 6.5(9) . . . . ?
F18A F17B C53 C50 -111.1(9) . . . . ?
F18A F18B C53 F16A -146.6(12) . . . . ?
F18A F18B C53 F16B -123.4(9) . . . . ?
F18A F18B C53 F17A -94.4(12) . . . . ?
F18A F18B C53 F17B -5.7(9) . . . . ?
F18A F18B C53 C50 111.4(8) . . . . ?
F18B F16A F16B F17A -37(2) . . . . ?
F18B F16A F16B C53 22.6(7) . . . . ?
F18B F16A C53 F16B -155.3(10) . . . . ?
F18B F16A C53 F17A -143.4(8) . . . . ?
F18B F16A C53 F17B -64.3(11) . . . . ?
F18B F16A C53 F18A -27.8(12) . . . . ?
F18B F16A C53 C50 99.5(8) . . . . ?
F18B F18A C53 F16A 26.1(9) . . . . ?
F18B F18A C53 F16B 89.8(15) . . . . ?
F18B F18A C53 F17A 124.3(10) . . . . ?
F18B F18A C53 F17B 172.3(11) . . . . ?
F18B F18A C53 C50 -96.6(9) . . . . ?
F22A F22B F23A F23B 6.2(17) . . . . ?
F22A F22B F23A C61 27.3(12) . . . . ?
F22A F22B C61 F23A -164.3(8) . . . . ?
F22A F22B C61 F23B -145.2(6) . . . . ?
F22A F22B C61 F24A -74.1(8) . . . . ?
F22A F22B C61 F24B -35.7(9) . . . . ?
F22A F22B C61 C58 92.6(8) . . . . ?
F22A F24B C61 F22B 23.5(5) . . . . ?
F22A F24B C61 F23A 89.5(8) . . . . ?
F22A F24B C61 F23B 138.5(5) . . . . ?
F22A F24B C61 F24A 143.5(9) . . . . ?
F22A F24B C61 C58 -107.7(4) . . . . ?
F22B F22A F24B F24A 5.2(12) . . . . ?
F22B F22A F24B C61 -29.3(7) . . . . ?
F22B F22A C61 F23A 13.5(7) . . . . ?
F22B F22A C61 F23B 56.0(10) . . . . ?
F22B F22A C61 F24A 124.8(7) . . . . ?
F22B F22A C61 F24B 146.2(8) . . . . ?
F22B F22A C61 C58 -106.3(7) . . . . ?
F22B F23A F23B F24A -14.1(7) . . . . ?
F22B F23A F23B C61 19.3(5) . . . . ?
F22B F23A C61 F22A -10.5(6) . . . . ?
F22B F23A C61 F23B -157.5(7) . . . . ?
F22B F23A C61 F24A -120.6(6) . . . . ?
F22B F23A C61 F24B -90.6(10) . . . . ?
F22B F23A C61 C58 106.9(6) . . . . ?
F23A F22B C61 F22A 164.3(8) . . . . ?
F23A F22B C61 F23B 19.1(6) . . . . ?
F23A F22B C61 F24A 90.2(8) . . . . ?
F23A F22B C61 F24B 128.5(6) . . . . ?
F23A F22B C61 C58 -103.1(4) . . . . ?
F23A F23B F24A F24B 29.2(16) . . . . ?
F23A F23B F24A C61 37.5(4) . . . . ?
F23A F23B C61 F22A -55.7(8) . . . . ?
F23A F23B C61 F22B -20.1(7) . . . . ?
F23A F23B C61 F24A -140.5(5) . . . . ?
F23A F23B C61 F24B -137.3(5) . . . . ?
F23A F23B C61 C58 106.9(4) . . . . ?
F23B F23A C61 F22A 147.0(5) . . . . ?
F23B F23A C61 F22B 157.5(7) . . . . ?
F23B F23A C61 F24A 36.9(5) . . . . ?
F23B F23A C61 F24B 66.8(10) . . . . ?
F23B F23A C61 C58 -95.6(5) . . . . ?
F23B F24A F24B F22A -22.1(17) . . . . ?
F23B F24A F24B C61 7.4(12) . . . . ?
F23B F24A C61 F22A -137.4(5) . . . . ?
F23B F24A C61 F22B -95.7(8) . . . . ?
F23B F24A C61 F23A -32.6(4) . . . . ?
F23B F24A C61 F24B -174.6(9) . . . . ?
F23B F24A C61 C58 97.8(4) . . . . ?
F24A F23B C61 F22A 84.8(7) . . . . ?
F24A F23B C61 F22B 120.4(7) . . . . ?
F24A F23B C61 F23A 140.5(5) . . . . ?
F24A F23B C61 F24B 3.2(6) . . . . ?
F24A F23B C61 C58 -112.6(4) . . . . ?
F24A F24B C61 F22A -143.5(9) . . . . ?
F24A F24B C61 F22B -120.0(9) . . . . ?
F24A F24B C61 F23A -54.0(13) . . . . ?
F24A F24B C61 F23B -5.0(9) . . . . ?
F24A F24B C61 C58 108.9(8) . . . . ?
F24B F22A F22B F23A 0.7(16) . . . . ?
F24B F22A F22B C61 26.4(6) . . . . ?
F24B F22A C61 F22B -146.2(8) . . . . ?
F24B F22A C61 F23A -132.7(5) . . . . ?
F24B F22A C61 F23B -90.2(8) . . . . ?
F24B F22A C61 F24A -21.4(5) . . . . ?
F24B F22A C61 C58 107.5(5) . . . . ?
F24B F24A C61 F22A 37.1(9) . . . . ?
F24B F24A C61 F22B 78.9(11) . . . . ?
F24B F24A C61 F23A 141.9(9) . . . . ?
F24B F24A C61 F23B 174.6(9) . . . . ?
F24B F24A C61 C58 -87.6(9) . . . . ?
C30 C31 C32 C33 0.6(4) . . . . ?
C30 C31 C32 C36 -177.2(3) . . . . ?
C31 C30 C35 C34 -3.7(4) . . . . ?
C31 C30 B1 C38 160.1(3) . . . . ?
C31 C30 B1 C46 45.0(3) . . . . ?
C31 C30 B1 C54 -77.8(3) . . . . ?
C31 C32 C33 C34 -1.7(4) . . . . ?
C31 C32 C36 F1 -154.2(3) . . . . ?
C31 C32 C36 F2 -31.8(5) . . . . ?
C31 C32 C36 F3 86.6(5) . . . . ?
C32 C33 C34 C35 0.1(5) . . . . ?
C32 C33 C34 C37 -179.6(3) . . . . ?
C33 C32 C36 F1 28.0(5) . . . . ?
C33 C32 C36 F2 150.4(4) . . . . ?
C33 C32 C36 F3 -91.2(5) . . . . ?
C33 C34 C35 C30 2.8(5) . . . . ?
C33 C34 C37 F4 -152.1(3) . . . . ?
C33 C34 C37 F5 88.8(4) . . . . ?
C33 C34 C37 F6 -30.3(4) . . . . ?
C35 C30 C31 C32 2.1(4) . . . . ?
C35 C30 B1 C38 -22.2(4) . . . . ?
C35 C30 B1 C46 -137.3(3) . . . . ?
C35 C30 B1 C54 99.9(3) . . . . ?
C35 C34 C37 F4 28.2(4) . . . . ?
C35 C34 C37 F5 -90.9(4) . . . . ?
C35 C34 C37 F6 150.0(3) . . . . ?
C36 C32 C33 C34 176.1(3) . . . . ?
C37 C34 C35 C30 -177.5(3) . . . . ?
C38 C39 C40 C41 1.9(5) . . . . ?
C38 C39 C40 C44 -177.1(3) . . . . ?
C39 C38 C43 C42 -1.9(4) . . . . ?
C39 C38 B1 C30 156.3(3) . . . . ?
C39 C38 B1 C46 -84.0(3) . . . . ?
C39 C38 B1 C54 36.5(4) . . . . ?
C39 C40 C41 C42 -1.8(5) . . . . ?
C39 C40 C44 F7 96.3(4) . . . . ?
C39 C40 C44 F8 -26.2(5) . . . . ?
C39 C40 C44 F9 -142.8(4) . . . . ?
C40 C41 C42 C43 -0.1(5) . . . . ?
C40 C41 C42 C45 178.0(3) . . . . ?
C41 C40 C44 F7 -82.7(5) . . . . ?
C41 C40 C44 F8 154.7(4) . . . . ?
C41 C40 C44 F9 38.1(5) . . . . ?
C41 C42 C43 C38 2.0(5) . . . . ?
C41 C42 C45 F10 8.0(5) . . . . ?
C41 C42 C45 F11 -114.4(5) . . . . ?
C41 C42 C45 F12 128.4(4) . . . . ?
C43 C38 C39 C40 -0.1(4) . . . . ?
C43 C38 B1 C30 -32.2(4) . . . . ?
C43 C38 B1 C46 87.5(3) . . . . ?
C43 C38 B1 C54 -151.9(3) . . . . ?
C43 C42 C45 F10 -173.7(3) . . . . ?
C43 C42 C45 F11 63.9(5) . . . . ?
C43 C42 C45 F12 -53.4(5) . . . . ?
C44 C40 C41 C42 177.3(3) . . . . ?
C45 C42 C43 C38 -176.2(3) . . . . ?
C46 C47 C48 C49 -0.9(5) . . . . ?
C46 C47 C48 C52 178.4(3) . . . . ?
C47 C46 C51 C50 0.4(4) . . . . ?
C47 C46 B1 C30 26.9(4) . . . . ?
C47 C46 B1 C38 -95.3(3) . . . . ?
C47 C46 B1 C54 145.8(3) . . . . ?
C47 C48 C49 C50 0.4(5) . . . . ?
C47 C48 C52 F13 51.7(5) . . . . ?
C47 C48 C52 F14 171.0(4) . . . . ?
C47 C48 C52 F15 -68.2(5) . . . . ?
C48 C49 C50 C51 0.5(5) . . . . ?
C48 C49 C50 C53 -177.2(4) . . . . ?
C49 C48 C52 F13 -129.0(4) . . . . ?
C49 C48 C52 F14 -9.7(6) . . . . ?
C49 C48 C52 F15 111.1(5) . . . . ?
C49 C50 C51 C46 -0.9(5) . . . . ?
C49 C50 C53 F16A -57.5(8) . . . . ?
C49 C50 C53 F16B -125.6(8) . . . . ?
C49 C50 C53 F17A -160.8(5) . . . . ?
C49 C50 C53 F17B 110.8(6) . . . . ?
C49 C50 C53 F18A 59.8(17) . . . . ?
C49 C50 C53 F18B -1.9(9) . . . . ?
C51 C46 C47 C48 0.5(4) . . . . ?
C51 C46 B1 C30 -161.6(3) . . . . ?
C51 C46 B1 C38 76.2(3) . . . . ?
C51 C46 B1 C54 -42.7(4) . . . . ?
C51 C50 C53 F16A 124.8(8) . . . . ?
C51 C50 C53 F16B 56.7(9) . . . . ?
C51 C50 C53 F17A 21.5(7) . . . . ?
C51 C50 C53 F17B -66.9(6) . . . . ?
C51 C50 C53 F18A -117.9(17) . . . . ?
C51 C50 C53 F18B -179.6(7) . . . . ?
C52 C48 C49 C50 -178.9(3) . . . . ?
C53 F16A F16B F17A -59(2) . . . . ?
C53 F16A F18B F18A 28.3(8) . . . . ?
C53 F17B F18A F18B -15(2) . . . . ?
C53 F18A F18B F16A -33.2(9) . . . . ?
C53 C50 C51 C46 176.8(3) . . . . ?
C54 C55 C56 C57 0.6(5) . . . . ?
C54 C55 C56 C60 -179.1(3) . . . . ?
C55 C54 C59 C58 0.5(4) . . . . ?
C55 C54 B1 C30 93.2(3) . . . . ?
C55 C54 B1 C38 -142.4(3) . . . . ?
C55 C54 B1 C46 -28.2(4) . . . . ?
C55 C56 C57 C58 0.1(5) . . . . ?
C55 C56 C60 F19 48.5(5) . . . . ?
C55 C56 C60 F20 169.8(3) . . . . ?
C55 C56 C60 F21 -71.1(5) . . . . ?
C56 C57 C58 C59 -0.5(4) . . . . ?
C56 C57 C58 C61 -179.0(3) . . . . ?
C57 C56 C60 F19 -131.2(4) . . . . ?
C57 C56 C60 F20 -9.8(5) . . . . ?
C57 C56 C60 F21 109.2(4) . . . . ?
C57 C58 C59 C54 0.2(4) . . . . ?
C57 C58 C61 F22A 83.4(4) . . . . ?
C57 C58 C61 F22B 38.0(8) . . . . ?
C57 C58 C61 F23A -26.8(5) . . . . ?
C57 C58 C61 F23B -84.6(5) . . . . ?
C57 C58 C61 F24A -154.3(5) . . . . ?
C57 C58 C61 F24B 166.8(7) . . . . ?
C59 C54 C55 C56 -0.9(4) . . . . ?
C59 C54 B1 C30 -84.8(3) . . . . ?
C59 C54 B1 C38 39.6(3) . . . . ?
C59 C54 B1 C46 153.8(3) . . . . ?
C59 C58 C61 F22A -95.2(4) . . . . ?
C59 C58 C61 F22B -140.5(7) . . . . ?
C59 C58 C61 F23A 154.7(4) . . . . ?
C59 C58 C61 F23B 96.9(5) . . . . ?
C59 C58 C61 F24A 27.2(6) . . . . ?
C59 C58 C61 F24B -11.7(8) . . . . ?
C60 C56 C57 C58 179.8(3) . . . . ?
C61 F22A F22B F23A -25.7(12) . . . . ?
C61 F22A F24B F24A 34.5(8) . . . . ?
C61 F22B F23A F23B -21.1(6) . . . . ?
C61 F23A F23B F24A -33.3(4) . . . . ?
C61 F23B F24A F24B -8.3(14) . . . . ?
C61 F24A F24B F22A -29.5(6) . . . . ?
C61 C58 C59 C54 178.7(3) . . . . ?
B1 C30 C31 C32 180.0(3) . . . . ?
B1 C30 C35 C34 178.5(3) . . . . ?
B1 C38 C39 C40 172.1(3) . . . . ?
B1 C38 C43 C42 -173.7(3) . . . . ?
B1 C46 C47 C48 172.4(3) . . . . ?
B1 C46 C51 C50 -171.7(3) . . . . ?
B1 C54 C55 C56 -179.0(3) . . . . ?
B1 C54 C59 C58 178.7(3) . . . . ?

_shelx_SHELXL_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.279
_oxdiff_exptl_absorpt_empirical_full_min 0.727

