# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2b
_database_code_depnum_ccdc_archive 'CCDC 1871894'
_audit_update_record             
;
2018-10-08 deposited with the CCDC.
2018-11-29 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C32 H53 B10 Cl2 Ir2 N2 O'
_chemical_formula_weight         1045.16

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ir Ir -1.4442 7.9887 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   8.3378(11)
_cell_length_b                   12.0979(16)
_cell_length_c                   20.336(3)
_cell_angle_alpha                75.448(2)
_cell_angle_beta                 79.942(2)
_cell_angle_gamma                85.845(2)
_cell_volume                     1954.1(4)
_cell_formula_units_Z            2
_cell_measurement_temperature    203(2)
_cell_measurement_reflns_used    9916
_cell_measurement_theta_min      2.24
_cell_measurement_theta_max      28.33

_exptl_crystal_description       sheet
_exptl_crystal_colour            black
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.776
_exptl_crystal_F_000             1010
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.350
_exptl_crystal_size_mid          0.220
_exptl_crystal_size_min          0.080
_exptl_absorpt_coefficient_mu    6.969
_shelx_estimated_absorpt_T_min   0.194
_shelx_estimated_absorpt_T_max   0.606
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.274
_exptl_absorpt_correction_T_max  0.563
_exptl_absorpt_process_details   sadabs
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      203(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            13592
_diffrn_reflns_av_unetI/netI     0.0497
_diffrn_reflns_av_R_equivalents  0.0325
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_theta_min         1.740
_diffrn_reflns_theta_max         26.998
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measured_fraction_theta_full 0.986
_diffrn_reflns_Laue_measured_fraction_max 0.986
_diffrn_reflns_Laue_measured_fraction_full 0.986
_diffrn_reflns_point_group_measured_fraction_max 0.986
_diffrn_reflns_point_group_measured_fraction_full 0.986
_reflns_number_total             8432
_reflns_number_gt                7217
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0564P)²+5.4744P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         8432
_refine_ls_number_parameters     458
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0423
_refine_ls_R_factor_gt           0.0346
_refine_ls_wR_factor_ref         0.1099
_refine_ls_wR_factor_gt          0.1034
_refine_ls_goodness_of_fit_ref   1.098
_refine_ls_restrained_S_all      1.098
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ir1 Ir 0.20259(2) 0.34890(2) 0.17265(2) 0.02151(8) Uani 1 1 d . . . . .
Ir2 Ir 0.42187(2) -0.03932(2) 0.26135(2) 0.01948(8) Uani 1 1 d . . . . .
Cl1 Cl 0.43128(19) 0.46698(14) 0.15573(8) 0.0336(3) Uani 1 1 d . . . . .
Cl2 Cl 0.15922(18) -0.05281(15) 0.23385(8) 0.0324(3) Uani 1 1 d . . . . .
N1 N 0.3473(6) 0.1293(4) 0.2563(2) 0.0218(10) Uani 1 1 d . . . . .
N2 N 0.3489(6) 0.2004(4) 0.1948(2) 0.0196(9) Uani 1 1 d . . . . .
O1 O 0.7323(8) 0.0120(4) 0.0005(3) 0.0504(15) Uani 1 1 d . . . . .
C1 C 0.2660(7) 0.1807(5) 0.3100(3) 0.0214(11) Uani 1 1 d . . . . .
B2 B 0.0567(8) 0.1927(6) 0.3235(3) 0.0277(14) Uani 1 1 d . . . . .
H2 H -0.0264 0.1585 0.2968 0.033 Uiso 1 1 calc R U . . .
B3 B 0.1653(9) 0.0997(7) 0.3857(4) 0.0313(15) Uani 1 1 d . . . . .
H3 H 0.1544 0.0055 0.3988 0.038 Uiso 1 1 calc R U . . .
B4 B 0.3539(9) 0.1655(7) 0.3819(4) 0.0306(15) Uani 1 1 d . . . . .
H4 H 0.4658 0.1132 0.3924 0.037 Uiso 1 1 calc R U . . .
B5 B 0.3632(9) 0.2942(6) 0.3179(4) 0.0295(14) Uani 1 1 d . . . . .
H5 H 0.4815 0.3262 0.2871 0.035 Uiso 1 1 calc R U . . .
B6 B 0.1799(8) 0.3154(6) 0.2775(4) 0.0256(13) Uani 1 1 d . . . . .
C7 C 0.0252(9) 0.3210(7) 0.3469(4) 0.0386(16) Uani 1 1 d . . . . .
B8 B 0.0050(11) 0.1935(8) 0.4114(4) 0.044(2) Uani 1 1 d . . . . .
H8 H -0.1128 0.1611 0.4424 0.053 Uiso 1 1 calc R U . . .
B9 B 0.1894(11) 0.1771(8) 0.4473(4) 0.042(2) Uani 1 1 d . . . . .
H9 H 0.1915 0.1330 0.5020 0.051 Uiso 1 1 calc R U . . .
B10 B 0.3107(12) 0.2947(8) 0.4063(4) 0.0418(19) Uani 1 1 d . . . . .
H10 H 0.3922 0.3277 0.4342 0.050 Uiso 1 1 calc R U . . .
B11 B 0.2042(10) 0.3841(7) 0.3429(4) 0.0351(16) Uani 1 1 d . . . . .
H11 H 0.2167 0.4782 0.3289 0.042 Uiso 1 1 calc R U . . .
B12 B 0.0984(12) 0.3151(8) 0.4217(4) 0.043(2) Uani 1 1 d . . . . .
H12 H 0.0394 0.3635 0.4597 0.051 Uiso 1 1 calc R U . . .
C2 C 0.4447(7) 0.1555(5) 0.1439(3) 0.0234(11) Uani 1 1 d . . . . .
C3 C 0.4944(7) 0.0397(5) 0.1621(3) 0.0246(12) Uani 1 1 d . . . . .
C4 C 0.5840(8) -0.0051(5) 0.1107(3) 0.0288(13) Uani 1 1 d . . . . .
H4A H 0.6113 -0.0837 0.1197 0.035 Uiso 1 1 calc R U . . .
C5 C 0.6354(9) 0.0664(6) 0.0443(3) 0.0349(15) Uani 1 1 d . . . . .
C6 C 0.5920(8) 0.1814(6) 0.0290(3) 0.0330(14) Uani 1 1 d . . . . .
H6 H 0.6284 0.2282 -0.0148 0.040 Uiso 1 1 calc R U . . .
C8 C 0.4945(8) 0.2270(6) 0.0787(3) 0.0297(13) Uani 1 1 d . . . . .
H8A H 0.4621 0.3047 0.0688 0.036 Uiso 1 1 calc R U . . .
C9 C 0.8067(14) 0.0775(8) -0.0640(4) 0.065(3) Uani 1 1 d . . . . .
H9A H 0.7233 0.1146 -0.0905 0.097 Uiso 1 1 calc R U . . .
H9B H 0.8751 0.0279 -0.0888 0.097 Uiso 1 1 calc R U . . .
H9C H 0.8729 0.1349 -0.0570 0.097 Uiso 1 1 calc R U . . .
C10 C -0.0242(9) 0.3071(7) 0.1433(4) 0.0428(19) Uani 1 1 d . . . . .
C11 C -0.0492(8) 0.4073(8) 0.1653(4) 0.0434(18) Uani 1 1 d . . . . .
C12 C 0.0607(8) 0.4893(6) 0.1189(4) 0.0358(15) Uani 1 1 d . . . . .
C13 C 0.1429(8) 0.4391(6) 0.0639(3) 0.0341(15) Uani 1 1 d . . . . .
C14 C 0.0948(10) 0.3271(7) 0.0792(4) 0.0428(17) Uani 1 1 d . . . . .
C15 C -0.1206(14) 0.1993(9) 0.1676(6) 0.087(4) Uani 1 1 d . . . . .
H15A H -0.1865 0.1982 0.2121 0.130 Uiso 1 1 calc R U . . .
H15B H -0.0463 0.1333 0.1718 0.130 Uiso 1 1 calc R U . . .
H15C H -0.1908 0.1972 0.1347 0.130 Uiso 1 1 calc R U . . .
C16 C -0.1841(11) 0.4316(12) 0.2191(5) 0.085(4) Uani 1 1 d . . . . .
H16A H -0.2823 0.4542 0.1990 0.128 Uiso 1 1 calc R U . . .
H16B H -0.1537 0.4929 0.2370 0.128 Uiso 1 1 calc R U . . .
H16C H -0.2039 0.3635 0.2563 0.128 Uiso 1 1 calc R U . . .
C17 C 0.0684(14) 0.6116(8) 0.1225(6) 0.071(3) Uani 1 1 d . . . . .
H17A H 0.1800 0.6363 0.1080 0.106 Uiso 1 1 calc R U . . .
H17B H 0.0310 0.6176 0.1694 0.106 Uiso 1 1 calc R U . . .
H17C H -0.0006 0.6596 0.0924 0.106 Uiso 1 1 calc R U . . .
C18 C 0.2564(10) 0.5038(8) 0.0045(4) 0.058(2) Uani 1 1 d . . . . .
H18A H 0.3530 0.5209 0.0203 0.087 Uiso 1 1 calc R U . . .
H18B H 0.2031 0.5746 -0.0165 0.087 Uiso 1 1 calc R U . . .
H18C H 0.2874 0.4583 -0.0290 0.087 Uiso 1 1 calc R U . . .
C19 C 0.1481(15) 0.2397(10) 0.0352(6) 0.080(4) Uani 1 1 d . . . . .
H19A H 0.2399 0.2685 0.0001 0.121 Uiso 1 1 calc R U . . .
H19B H 0.0582 0.2279 0.0134 0.121 Uiso 1 1 calc R U . . .
H19C H 0.1795 0.1678 0.0644 0.121 Uiso 1 1 calc R U . . .
C20 C 0.6295(7) -0.1588(5) 0.2714(3) 0.0261(12) Uani 1 1 d . . . . .
C21 C 0.6125(7) -0.1011(5) 0.3258(3) 0.0257(12) Uani 1 1 d . . . . .
C22 C 0.4643(8) -0.1393(5) 0.3731(3) 0.0273(13) Uani 1 1 d . . . . .
C23 C 0.3839(8) -0.2073(5) 0.3443(3) 0.0297(13) Uani 1 1 d . . . . .
C24 C 0.4834(8) -0.2195(5) 0.2796(3) 0.0308(13) Uani 1 1 d . . . . .
C25 C 0.7816(8) -0.1646(7) 0.2219(4) 0.0389(16) Uani 1 1 d . . . . .
H25A H 0.8706 -0.1941 0.2469 0.058 Uiso 1 1 calc R U . . .
H25B H 0.8064 -0.0887 0.1933 0.058 Uiso 1 1 calc R U . . .
H25C H 0.7670 -0.2147 0.1930 0.058 Uiso 1 1 calc R U . . .
C26 C 0.7449(8) -0.0383(6) 0.3401(3) 0.0332(14) Uani 1 1 d . . . . .
H26A H 0.8096 -0.0911 0.3702 0.050 Uiso 1 1 calc R U . . .
H26B H 0.6973 0.0213 0.3623 0.050 Uiso 1 1 calc R U . . .
H26C H 0.8140 -0.0043 0.2972 0.050 Uiso 1 1 calc R U . . .
C27 C 0.4206(9) -0.1244(6) 0.4451(3) 0.0373(15) Uani 1 1 d . . . . .
H27A H 0.3029 -0.1212 0.4577 0.056 Uiso 1 1 calc R U . . .
H27B H 0.4650 -0.0540 0.4477 0.056 Uiso 1 1 calc R U . . .
H27C H 0.4654 -0.1884 0.4766 0.056 Uiso 1 1 calc R U . . .
C28 C 0.2238(9) -0.2636(7) 0.3749(4) 0.0476(19) Uani 1 1 d . . . . .
H28A H 0.2431 -0.3383 0.4043 0.071 Uiso 1 1 calc R U . . .
H28B H 0.1688 -0.2721 0.3382 0.071 Uiso 1 1 calc R U . . .
H28C H 0.1562 -0.2168 0.4018 0.071 Uiso 1 1 calc R U . . .
C29 C 0.4469(10) -0.2966(6) 0.2376(4) 0.0474(19) Uani 1 1 d . . . . .
H29A H 0.5181 -0.2799 0.1934 0.071 Uiso 1 1 calc R U . . .
H29B H 0.3343 -0.2844 0.2305 0.071 Uiso 1 1 calc R U . . .
H29C H 0.4646 -0.3754 0.2615 0.071 Uiso 1 1 calc R U . . .
C30 C 0.8017(14) 0.5988(8) 0.3857(6) 0.077(3) Uani 1 1 d . . . . .
H30A H 0.7336 0.6116 0.3502 0.116 Uiso 1 1 calc R U . . .
H30B H 0.9078 0.5688 0.3690 0.116 Uiso 1 1 calc R U . . .
H30C H 0.8144 0.6705 0.3972 0.116 Uiso 1 1 calc R U . . .
C31 C 0.7233(12) 0.5146(8) 0.4487(5) 0.060(2) Uani 1 1 d . . . . .
H31A H 0.7777 0.5161 0.4874 0.072 Uiso 1 1 calc R U . . .
H31B H 0.7395 0.4377 0.4407 0.072 Uiso 1 1 calc R U . . .
C32 C 0.5417(10) 0.5384(6) 0.4680(4) 0.0471(19) Uani 1 1 d . . . . .
H32A H 0.5263 0.6171 0.4730 0.056 Uiso 1 1 calc R U . . .
H32B H 0.4878 0.5334 0.4298 0.056 Uiso 1 1 calc R U . . .
H7 H -0.074(9) 0.366(6) 0.340(3) 0.025(17) Uiso 1 1 d . . . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ir1 B6 2.046(7) . ?
Ir1 N2 2.094(5) . ?
Ir1 C12 2.170(6) . ?
Ir1 C11 2.184(7) . ?
Ir1 C10 2.207(6) . ?
Ir1 C14 2.318(7) . ?
Ir1 C13 2.328(6) . ?
Ir1 Cl1 2.3904(15) . ?
Ir2 C3 2.010(6) . ?
Ir2 N1 2.072(5) . ?
Ir2 C24 2.157(6) . ?
Ir2 C20 2.178(6) . ?
Ir2 C21 2.205(6) . ?
Ir2 C23 2.293(6) . ?
Ir2 C22 2.364(6) . ?
Ir2 Cl2 2.3792(15) . ?
N1 N2 1.326(6) . ?
N1 C1 1.434(7) . ?
N2 C2 1.392(7) . ?
O1 C5 1.360(8) . ?
O1 C9 1.413(9) . ?
C1 B5 1.700(9) . ?
C1 B4 1.713(9) . ?
C1 B3 1.717(9) . ?
C1 B2 1.720(9) . ?
C1 B6 1.750(9) . ?
B2 C7 1.724(11) . ?
B2 B8 1.767(11) . ?
B2 B3 1.796(10) . ?
B2 B6 1.822(10) . ?
B2 H2 1.1100 . ?
B3 B8 1.784(12) . ?
B3 B9 1.785(12) . ?
B3 B4 1.794(11) . ?
B3 H3 1.1100 . ?
B4 B10 1.751(11) . ?
B4 B5 1.758(10) . ?
B4 B9 1.760(11) . ?
B4 H4 1.1100 . ?
B5 B11 1.742(11) . ?
B5 B10 1.776(11) . ?
B5 B6 1.831(10) . ?
B5 H5 1.1100 . ?
B6 C7 1.749(10) . ?
B6 B11 1.782(10) . ?
C7 B11 1.706(11) . ?
C7 B12 1.720(11) . ?
C7 B8 1.753(12) . ?
C7 H7 0.97(7) . ?
B8 B12 1.786(14) . ?
B8 B9 1.791(13) . ?
B8 H8 1.1100 . ?
B9 B10 1.749(14) . ?
B9 B12 1.775(12) . ?
B9 H9 1.1100 . ?
B10 B12 1.754(13) . ?
B10 B11 1.783(11) . ?
B10 H10 1.1100 . ?
B11 B12 1.728(12) . ?
B11 H11 1.1100 . ?
B12 H12 1.1100 . ?
C2 C8 1.402(8) . ?
C2 C3 1.407(9) . ?
C3 C4 1.376(8) . ?
C4 C5 1.422(8) . ?
C4 H4A 0.9400 . ?
C5 C6 1.382(10) . ?
C6 C8 1.383(9) . ?
C6 H6 0.9400 . ?
C8 H8A 0.9400 . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C9 H9C 0.9700 . ?
C10 C11 1.384(12) . ?
C10 C14 1.472(11) . ?
C10 C15 1.510(10) . ?
C11 C12 1.440(10) . ?
C11 C16 1.495(13) . ?
C12 C13 1.449(10) . ?
C12 C17 1.506(12) . ?
C13 C14 1.385(11) . ?
C13 C18 1.483(9) . ?
C14 C19 1.544(13) . ?
C15 H15A 0.9700 . ?
C15 H15B 0.9700 . ?
C15 H15C 0.9700 . ?
C16 H16A 0.9700 . ?
C16 H16B 0.9700 . ?
C16 H16C 0.9700 . ?
C17 H17A 0.9700 . ?
C17 H17B 0.9700 . ?
C17 H17C 0.9700 . ?
C18 H18A 0.9700 . ?
C18 H18B 0.9700 . ?
C18 H18C 0.9700 . ?
C19 H19A 0.9700 . ?
C19 H19B 0.9700 . ?
C19 H19C 0.9700 . ?
C20 C21 1.431(9) . ?
C20 C24 1.432(9) . ?
C20 C25 1.485(9) . ?
C21 C22 1.452(8) . ?
C21 C26 1.492(9) . ?
C22 C23 1.389(9) . ?
C22 C27 1.500(9) . ?
C23 C24 1.462(9) . ?
C23 C28 1.504(9) . ?
C24 C29 1.491(10) . ?
C25 H25A 0.9700 . ?
C25 H25B 0.9700 . ?
C25 H25C 0.9700 . ?
C26 H26A 0.9700 . ?
C26 H26B 0.9700 . ?
C26 H26C 0.9700 . ?
C27 H27A 0.9700 . ?
C27 H27B 0.9700 . ?
C27 H27C 0.9700 . ?
C28 H28A 0.9700 . ?
C28 H28B 0.9700 . ?
C28 H28C 0.9700 . ?
C29 H29A 0.9700 . ?
C29 H29B 0.9700 . ?
C29 H29C 0.9700 . ?
C30 C31 1.501(14) . ?
C30 H30A 0.9700 . ?
C30 H30B 0.9700 . ?
C30 H30C 0.9700 . ?
C31 C32 1.522(12) . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C32 C32 1.486(17) 2_666 ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
B6 Ir1 N2 78.2(2) . . ?
B6 Ir1 C12 119.2(3) . . ?
N2 Ir1 C12 162.1(2) . . ?
B6 Ir1 C11 96.9(3) . . ?
N2 Ir1 C11 142.2(3) . . ?
C12 Ir1 C11 38.6(3) . . ?
B6 Ir1 C10 110.0(3) . . ?
N2 Ir1 C10 109.4(3) . . ?
C12 Ir1 C10 62.5(3) . . ?
C11 Ir1 C10 36.7(3) . . ?
B6 Ir1 C14 146.8(3) . . ?
N2 Ir1 C14 102.3(2) . . ?
C12 Ir1 C14 61.1(3) . . ?
C11 Ir1 C14 62.1(3) . . ?
C10 Ir1 C14 37.9(3) . . ?
B6 Ir1 C13 156.5(3) . . ?
N2 Ir1 C13 125.0(2) . . ?
C12 Ir1 C13 37.4(3) . . ?
C11 Ir1 C13 62.5(3) . . ?
C10 Ir1 C13 61.2(2) . . ?
C14 Ir1 C13 34.7(3) . . ?
B6 Ir1 Cl1 92.7(2) . . ?
N2 Ir1 Cl1 91.40(13) . . ?
C12 Ir1 Cl1 91.91(19) . . ?
C11 Ir1 Cl1 126.4(2) . . ?
C10 Ir1 Cl1 151.64(18) . . ?
C14 Ir1 Cl1 120.4(2) . . ?
C13 Ir1 Cl1 91.27(18) . . ?
C3 Ir2 N1 76.5(2) . . ?
C3 Ir2 C24 110.6(3) . . ?
N1 Ir2 C24 172.9(2) . . ?
C3 Ir2 C20 96.5(2) . . ?
N1 Ir2 C20 143.7(2) . . ?
C24 Ir2 C20 38.6(2) . . ?
C3 Ir2 C21 117.5(2) . . ?
N1 Ir2 C21 114.0(2) . . ?
C24 Ir2 C21 64.0(2) . . ?
C20 Ir2 C21 38.1(2) . . ?
C3 Ir2 C23 148.3(2) . . ?
N1 Ir2 C23 134.7(2) . . ?
C24 Ir2 C23 38.2(2) . . ?
C20 Ir2 C23 62.6(2) . . ?
C21 Ir2 C23 61.4(2) . . ?
C3 Ir2 C22 154.3(2) . . ?
N1 Ir2 C22 112.5(2) . . ?
C24 Ir2 C22 61.5(2) . . ?
C20 Ir2 C22 61.6(2) . . ?
C21 Ir2 C22 36.9(2) . . ?
C23 Ir2 C22 34.6(2) . . ?
C3 Ir2 Cl2 88.19(17) . . ?
N1 Ir2 Cl2 83.15(13) . . ?
C24 Ir2 Cl2 96.00(18) . . ?
C20 Ir2 Cl2 132.71(17) . . ?
C21 Ir2 Cl2 151.16(16) . . ?
C23 Ir2 Cl2 89.89(17) . . ?
C22 Ir2 Cl2 116.24(16) . . ?
N2 N1 C1 111.2(5) . . ?
N2 N1 Ir2 118.5(4) . . ?
C1 N1 Ir2 129.4(4) . . ?
N1 N2 C2 110.8(5) . . ?
N1 N2 Ir1 125.8(4) . . ?
C2 N2 Ir1 122.8(4) . . ?
C5 O1 C9 118.8(6) . . ?
N1 C1 B5 113.9(5) . . ?
N1 C1 B4 118.5(5) . . ?
B5 C1 B4 62.0(4) . . ?
N1 C1 B3 121.4(5) . . ?
B5 C1 B3 115.0(5) . . ?
B4 C1 B3 63.1(4) . . ?
N1 C1 B2 119.2(5) . . ?
B5 C1 B2 115.2(5) . . ?
B4 C1 B2 114.9(5) . . ?
B3 C1 B2 63.0(4) . . ?
N1 C1 B6 112.3(4) . . ?
B5 C1 B6 64.1(4) . . ?
B4 C1 B6 116.4(5) . . ?
B3 C1 B6 116.9(5) . . ?
B2 C1 B6 63.3(4) . . ?
C1 B2 C7 101.4(5) . . ?
C1 B2 B8 104.1(5) . . ?
C7 B2 B8 60.3(5) . . ?
C1 B2 B3 58.4(4) . . ?
C7 B2 B3 106.6(5) . . ?
B8 B2 B3 60.1(4) . . ?
C1 B2 B6 59.1(4) . . ?
C7 B2 B6 59.0(4) . . ?
B8 B2 B6 109.8(6) . . ?
B3 B2 B6 109.5(5) . . ?
C1 B2 H2 126.2 . . ?
C7 B2 H2 124.5 . . ?
B8 B2 H2 121.5 . . ?
B3 B2 H2 121.3 . . ?
B6 B2 H2 120.1 . . ?
C1 B3 B8 103.5(5) . . ?
C1 B3 B9 103.2(6) . . ?
B8 B3 B9 60.3(5) . . ?
C1 B3 B4 58.3(4) . . ?
B8 B3 B4 107.1(6) . . ?
B9 B3 B4 58.9(5) . . ?
C1 B3 B2 58.6(4) . . ?
B8 B3 B2 59.2(4) . . ?
B9 B3 B2 107.1(5) . . ?
B4 B3 B2 107.4(5) . . ?
C1 B3 H3 125.5 . . ?
B8 B3 H3 122.9 . . ?
B9 B3 H3 123.1 . . ?
B4 B3 H3 122.0 . . ?
B2 B3 H3 121.9 . . ?
C1 B4 B10 105.2(5) . . ?
C1 B4 B5 58.6(4) . . ?
B10 B4 B5 60.8(4) . . ?
C1 B4 B9 104.4(5) . . ?
B10 B4 B9 59.8(5) . . ?
B5 B4 B9 108.2(6) . . ?
C1 B4 B3 58.6(4) . . ?
B10 B4 B3 108.7(6) . . ?
B5 B4 B3 108.4(5) . . ?
B9 B4 B3 60.3(5) . . ?
C1 B4 H4 125.0 . . ?
B10 B4 H4 121.8 . . ?
B5 B4 H4 121.1 . . ?
B9 B4 H4 122.5 . . ?
B3 B4 H4 121.1 . . ?
C1 B5 B11 103.4(5) . . ?
C1 B5 B4 59.3(4) . . ?
B11 B5 B4 107.8(5) . . ?
C1 B5 B10 104.6(5) . . ?
B11 B5 B10 60.9(5) . . ?
B4 B5 B10 59.4(4) . . ?
C1 B5 B6 59.3(4) . . ?
B11 B5 B6 59.8(4) . . ?
B4 B5 B6 110.2(5) . . ?
B10 B5 B6 110.1(5) . . ?
C1 B5 H5 125.2 . . ?
B11 B5 H5 123.0 . . ?
B4 B5 H5 121.0 . . ?
B10 B5 H5 121.7 . . ?
B6 B5 H5 119.9 . . ?
C7 B6 C1 99.2(5) . . ?
C7 B6 B11 57.8(4) . . ?
C1 B6 B11 99.8(5) . . ?
C7 B6 B2 57.7(4) . . ?
C1 B6 B2 57.5(4) . . ?
B11 B6 B2 104.1(5) . . ?
C7 B6 B5 102.4(5) . . ?
C1 B6 B5 56.6(3) . . ?
B11 B6 B5 57.6(4) . . ?
B2 B6 B5 104.4(5) . . ?
C7 B6 Ir1 137.3(5) . . ?
C1 B6 Ir1 110.2(4) . . ?
B11 B6 Ir1 139.8(5) . . ?
B2 B6 Ir1 114.3(4) . . ?
B5 B6 Ir1 119.5(4) . . ?
B11 C7 B12 60.6(5) . . ?
B11 C7 B2 111.9(5) . . ?
B12 C7 B2 111.6(6) . . ?
B11 C7 B6 62.1(4) . . ?
B12 C7 B6 112.9(6) . . ?
B2 C7 B6 63.3(4) . . ?
B11 C7 B8 111.2(6) . . ?
B12 C7 B8 61.9(5) . . ?
B2 C7 B8 61.1(5) . . ?
B6 C7 B8 114.0(5) . . ?
B11 C7 H7 121(4) . . ?
B12 C7 H7 117(4) . . ?
B2 C7 H7 120(4) . . ?
B6 C7 H7 120(4) . . ?
B8 C7 H7 116(4) . . ?
C7 B8 B2 58.6(4) . . ?
C7 B8 B3 105.9(5) . . ?
B2 B8 B3 60.8(4) . . ?
C7 B8 B12 58.1(5) . . ?
B2 B8 B12 106.5(6) . . ?
B3 B8 B12 107.1(6) . . ?
C7 B8 B9 105.1(6) . . ?
B2 B8 B9 108.1(6) . . ?
B3 B8 B9 59.9(5) . . ?
B12 B8 B9 59.5(5) . . ?
C7 B8 H8 124.2 . . ?
B2 B8 H8 121.7 . . ?
B3 B8 H8 121.9 . . ?
B12 B8 H8 122.8 . . ?
B9 B8 H8 122.3 . . ?
B10 B9 B4 59.9(5) . . ?
B10 B9 B12 59.7(5) . . ?
B4 B9 B12 106.7(6) . . ?
B10 B9 B3 109.2(6) . . ?
B4 B9 B3 60.8(4) . . ?
B12 B9 B3 107.5(6) . . ?
B10 B9 B8 108.9(6) . . ?
B4 B9 B8 108.3(5) . . ?
B12 B9 B8 60.1(5) . . ?
B3 B9 B8 59.8(5) . . ?
B10 B9 H9 121.1 . . ?
B4 B9 H9 121.9 . . ?
B12 B9 H9 122.6 . . ?
B3 B9 H9 121.3 . . ?
B8 B9 H9 121.3 . . ?
B9 B10 B4 60.4(5) . . ?
B9 B10 B12 60.9(5) . . ?
B4 B10 B12 108.1(6) . . ?
B9 B10 B5 107.9(6) . . ?
B4 B10 B5 59.8(4) . . ?
B12 B10 B5 106.1(6) . . ?
B9 B10 B11 107.1(6) . . ?
B4 B10 B11 106.3(5) . . ?
B12 B10 B11 58.5(5) . . ?
B5 B10 B11 58.6(4) . . ?
B9 B10 H10 121.1 . . ?
B4 B10 H10 121.8 . . ?
B12 B10 H10 122.2 . . ?
B5 B10 H10 122.7 . . ?
B11 B10 H10 123.4 . . ?
C7 B11 B12 60.1(5) . . ?
C7 B11 B5 108.0(6) . . ?
B12 B11 B5 108.8(6) . . ?
C7 B11 B6 60.1(4) . . ?
B12 B11 B6 110.9(6) . . ?
B5 B11 B6 62.6(4) . . ?
C7 B11 B10 107.6(6) . . ?
B12 B11 B10 59.9(5) . . ?
B5 B11 B10 60.5(4) . . ?
B6 B11 B10 112.0(5) . . ?
C7 B11 H11 122.7 . . ?
B12 B11 H11 121.0 . . ?
B5 B11 H11 121.0 . . ?
B6 B11 H11 118.6 . . ?
B10 B11 H11 120.9 . . ?
C7 B12 B11 59.3(4) . . ?
C7 B12 B10 108.3(6) . . ?
B11 B12 B10 61.6(5) . . ?
C7 B12 B9 107.2(6) . . ?
B11 B12 B9 108.4(6) . . ?
B10 B12 B9 59.4(5) . . ?
C7 B12 B8 59.9(5) . . ?
B11 B12 B8 108.6(6) . . ?
B10 B12 B8 108.9(6) . . ?
B9 B12 B8 60.4(5) . . ?
C7 B12 H12 122.4 . . ?
B11 B12 H12 121.1 . . ?
B10 B12 H12 121.0 . . ?
B9 B12 H12 122.1 . . ?
B8 B12 H12 121.1 . . ?
N2 C2 C8 119.6(6) . . ?
N2 C2 C3 117.5(5) . . ?
C8 C2 C3 122.8(6) . . ?
C4 C3 C2 117.1(5) . . ?
C4 C3 Ir2 128.4(5) . . ?
C2 C3 Ir2 114.5(4) . . ?
C3 C4 C5 120.5(6) . . ?
C3 C4 H4A 119.7 . . ?
C5 C4 H4A 119.7 . . ?
O1 C5 C6 125.1(6) . . ?
O1 C5 C4 113.9(6) . . ?
C6 C5 C4 121.0(6) . . ?
C5 C6 C8 119.5(6) . . ?
C5 C6 H6 120.2 . . ?
C8 C6 H6 120.2 . . ?
C6 C8 C2 118.9(6) . . ?
C6 C8 H8A 120.6 . . ?
C2 C8 H8A 120.6 . . ?
O1 C9 H9A 109.5 . . ?
O1 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
O1 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C11 C10 C14 108.9(6) . . ?
C11 C10 C15 129.1(9) . . ?
C14 C10 C15 120.9(9) . . ?
C11 C10 Ir1 70.7(4) . . ?
C14 C10 Ir1 75.2(4) . . ?
C15 C10 Ir1 130.0(5) . . ?
C10 C11 C12 107.1(7) . . ?
C10 C11 C16 126.0(9) . . ?
C12 C11 C16 126.1(9) . . ?
C10 C11 Ir1 72.5(4) . . ?
C12 C11 Ir1 70.2(4) . . ?
C16 C11 Ir1 130.4(5) . . ?
C11 C12 C13 108.5(7) . . ?
C11 C12 C17 124.6(8) . . ?
C13 C12 C17 126.4(7) . . ?
C11 C12 Ir1 71.2(4) . . ?
C13 C12 Ir1 77.2(4) . . ?
C17 C12 Ir1 124.2(5) . . ?
C14 C13 C12 107.4(6) . . ?
C14 C13 C18 130.1(8) . . ?
C12 C13 C18 122.5(7) . . ?
C14 C13 Ir1 72.3(4) . . ?
C12 C13 Ir1 65.4(3) . . ?
C18 C13 Ir1 126.9(5) . . ?
C13 C14 C10 107.9(7) . . ?
C13 C14 C19 126.6(9) . . ?
C10 C14 C19 125.5(8) . . ?
C13 C14 Ir1 73.0(4) . . ?
C10 C14 Ir1 67.0(4) . . ?
C19 C14 Ir1 127.9(5) . . ?
C10 C15 H15A 109.5 . . ?
C10 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C10 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C11 C16 H16A 109.5 . . ?
C11 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C11 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C12 C17 H17A 109.5 . . ?
C12 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C12 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C13 C18 H18A 109.5 . . ?
C13 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C13 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C14 C19 H19A 109.5 . . ?
C14 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C14 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C21 C20 C24 107.7(5) . . ?
C21 C20 C25 124.6(6) . . ?
C24 C20 C25 127.3(6) . . ?
C21 C20 Ir2 72.0(3) . . ?
C24 C20 Ir2 69.9(4) . . ?
C25 C20 Ir2 129.4(5) . . ?
C20 C21 C22 107.8(5) . . ?
C20 C21 C26 124.6(6) . . ?
C22 C21 C26 125.8(6) . . ?
C20 C21 Ir2 69.9(3) . . ?
C22 C21 Ir2 77.5(4) . . ?
C26 C21 Ir2 130.2(4) . . ?
C23 C22 C21 108.0(6) . . ?
C23 C22 C27 125.6(6) . . ?
C21 C22 C27 125.6(6) . . ?
C23 C22 Ir2 69.9(3) . . ?
C21 C22 Ir2 65.6(3) . . ?
C27 C22 Ir2 137.7(4) . . ?
C22 C23 C24 108.9(5) . . ?
C22 C23 C28 126.4(7) . . ?
C24 C23 C28 124.7(6) . . ?
C22 C23 Ir2 75.5(3) . . ?
C24 C23 Ir2 65.8(3) . . ?
C28 C23 Ir2 126.1(5) . . ?
C20 C24 C23 107.0(6) . . ?
C20 C24 C29 127.6(6) . . ?
C23 C24 C29 124.7(6) . . ?
C20 C24 Ir2 71.5(3) . . ?
C23 C24 Ir2 76.0(4) . . ?
C29 C24 Ir2 125.3(5) . . ?
C20 C25 H25A 109.5 . . ?
C20 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C20 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C21 C26 H26A 109.5 . . ?
C21 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C21 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C22 C27 H27A 109.5 . . ?
C22 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
C22 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C23 C28 H28A 109.5 . . ?
C23 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C23 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C24 C29 H29A 109.5 . . ?
C24 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C24 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C31 C30 H30A 109.5 . . ?
C31 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C31 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C30 C31 C32 113.4(8) . . ?
C30 C31 H31A 108.9 . . ?
C32 C31 H31A 108.9 . . ?
C30 C31 H31B 108.9 . . ?
C32 C31 H31B 108.9 . . ?
H31A C31 H31B 107.7 . . ?
C32 C32 C31 116.1(8) 2_666 . ?
C32 C32 H32A 108.3 2_666 . ?
C31 C32 H32A 108.3 . . ?
C32 C32 H32B 108.3 2_666 . ?
C31 C32 H32B 108.3 . . ?
H32A C32 H32B 107.4 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 N1 N2 C2 172.7(5) . . . . ?
Ir2 N1 N2 C2 -16.9(5) . . . . ?
C1 N1 N2 Ir1 -15.9(6) . . . . ?
Ir2 N1 N2 Ir1 154.4(3) . . . . ?
N2 N1 C1 B5 -65.4(6) . . . . ?
Ir2 N1 C1 B5 125.6(5) . . . . ?
N2 N1 C1 B4 -135.3(5) . . . . ?
Ir2 N1 C1 B4 55.7(7) . . . . ?
N2 N1 C1 B3 150.5(5) . . . . ?
Ir2 N1 C1 B3 -18.5(7) . . . . ?
N2 N1 C1 B2 76.0(6) . . . . ?
Ir2 N1 C1 B2 -93.0(6) . . . . ?
N2 N1 C1 B6 5.1(6) . . . . ?
Ir2 N1 C1 B6 -163.9(4) . . . . ?
N1 C1 B2 C7 -144.8(5) . . . . ?
B5 C1 B2 C7 -3.9(6) . . . . ?
B4 C1 B2 C7 65.4(6) . . . . ?
B3 C1 B2 C7 102.6(5) . . . . ?
B6 C1 B2 C7 -43.0(4) . . . . ?
N1 C1 B2 B8 153.3(5) . . . . ?
B5 C1 B2 B8 -65.8(6) . . . . ?
B4 C1 B2 B8 3.5(7) . . . . ?
B3 C1 B2 B8 40.7(5) . . . . ?
B6 C1 B2 B8 -104.9(6) . . . . ?
N1 C1 B2 B3 112.6(6) . . . . ?
B5 C1 B2 B3 -106.5(5) . . . . ?
B4 C1 B2 B3 -37.2(5) . . . . ?
B6 C1 B2 B3 -145.6(5) . . . . ?
N1 C1 B2 B6 -101.8(5) . . . . ?
B5 C1 B2 B6 39.1(5) . . . . ?
B4 C1 B2 B6 108.4(5) . . . . ?
B3 C1 B2 B6 145.6(5) . . . . ?
N1 C1 B3 B8 -149.5(6) . . . . ?
B5 C1 B3 B8 66.7(7) . . . . ?
B4 C1 B3 B8 102.0(6) . . . . ?
B2 C1 B3 B8 -40.1(5) . . . . ?
B6 C1 B3 B8 -5.6(7) . . . . ?
N1 C1 B3 B9 148.4(5) . . . . ?
B5 C1 B3 B9 4.6(7) . . . . ?
B4 C1 B3 B9 39.9(5) . . . . ?
B2 C1 B3 B9 -102.2(5) . . . . ?
B6 C1 B3 B9 -67.7(6) . . . . ?
N1 C1 B3 B4 108.5(6) . . . . ?
B5 C1 B3 B4 -35.3(5) . . . . ?
B2 C1 B3 B4 -142.1(5) . . . . ?
B6 C1 B3 B4 -107.6(5) . . . . ?
N1 C1 B3 B2 -109.4(6) . . . . ?
B5 C1 B3 B2 106.8(6) . . . . ?
B4 C1 B3 B2 142.1(5) . . . . ?
B6 C1 B3 B2 34.5(5) . . . . ?
C7 B2 B3 C1 -93.4(5) . . . . ?
B8 B2 B3 C1 -133.2(6) . . . . ?
B6 B2 B3 C1 -31.0(4) . . . . ?
C1 B2 B3 B8 133.2(6) . . . . ?
C7 B2 B3 B8 39.8(5) . . . . ?
B6 B2 B3 B8 102.1(6) . . . . ?
C1 B2 B3 B9 95.2(6) . . . . ?
C7 B2 B3 B9 1.9(7) . . . . ?
B8 B2 B3 B9 -37.9(6) . . . . ?
B6 B2 B3 B9 64.2(6) . . . . ?
C1 B2 B3 B4 33.2(4) . . . . ?
C7 B2 B3 B4 -60.1(6) . . . . ?
B8 B2 B3 B4 -99.9(6) . . . . ?
B6 B2 B3 B4 2.2(7) . . . . ?
N1 C1 B4 B10 144.3(6) . . . . ?
B5 C1 B4 B10 40.8(5) . . . . ?
B3 C1 B4 B10 -102.9(6) . . . . ?
B2 C1 B4 B10 -65.7(7) . . . . ?
B6 C1 B4 B10 5.5(7) . . . . ?
N1 C1 B4 B5 103.5(6) . . . . ?
B3 C1 B4 B5 -143.7(5) . . . . ?
B2 C1 B4 B5 -106.5(6) . . . . ?
B6 C1 B4 B5 -35.3(5) . . . . ?
N1 C1 B4 B9 -153.7(5) . . . . ?
B5 C1 B4 B9 102.8(6) . . . . ?
B3 C1 B4 B9 -40.8(5) . . . . ?
B2 C1 B4 B9 -3.7(7) . . . . ?
B6 C1 B4 B9 67.5(7) . . . . ?
N1 C1 B4 B3 -112.9(6) . . . . ?
B5 C1 B4 B3 143.7(5) . . . . ?
B2 C1 B4 B3 37.1(5) . . . . ?
B6 C1 B4 B3 108.4(5) . . . . ?
B8 B3 B4 C1 -95.6(5) . . . . ?
B9 B3 B4 C1 -133.2(5) . . . . ?
B2 B3 B4 C1 -33.3(4) . . . . ?
C1 B3 B4 B10 96.8(5) . . . . ?
B8 B3 B4 B10 1.2(7) . . . . ?
B9 B3 B4 B10 -36.4(5) . . . . ?
B2 B3 B4 B10 63.4(6) . . . . ?
C1 B3 B4 B5 32.2(5) . . . . ?
B8 B3 B4 B5 -63.4(6) . . . . ?
B9 B3 B4 B5 -101.0(6) . . . . ?
B2 B3 B4 B5 -1.1(7) . . . . ?
C1 B3 B4 B9 133.2(5) . . . . ?
B8 B3 B4 B9 37.6(5) . . . . ?
B2 B3 B4 B9 99.8(6) . . . . ?
N1 C1 B5 B11 146.2(5) . . . . ?
B4 C1 B5 B11 -102.9(5) . . . . ?
B3 C1 B5 B11 -67.3(6) . . . . ?
B2 C1 B5 B11 3.2(6) . . . . ?
B6 C1 B5 B11 42.0(5) . . . . ?
N1 C1 B5 B4 -110.9(5) . . . . ?
B3 C1 B5 B4 35.7(5) . . . . ?
B2 C1 B5 B4 106.1(5) . . . . ?
B6 C1 B5 B4 144.9(5) . . . . ?
N1 C1 B5 B10 -150.8(5) . . . . ?
B4 C1 B5 B10 -39.9(5) . . . . ?
B3 C1 B5 B10 -4.3(7) . . . . ?
B2 C1 B5 B10 66.2(6) . . . . ?
B6 C1 B5 B10 104.9(5) . . . . ?
N1 C1 B5 B6 104.2(5) . . . . ?
B4 C1 B5 B6 -144.9(5) . . . . ?
B3 C1 B5 B6 -109.2(5) . . . . ?
B2 C1 B5 B6 -38.8(5) . . . . ?
B10 B4 B5 C1 -133.8(6) . . . . ?
B9 B4 B5 C1 -96.1(6) . . . . ?
B3 B4 B5 C1 -32.2(5) . . . . ?
C1 B4 B5 B11 95.4(5) . . . . ?
B10 B4 B5 B11 -38.4(6) . . . . ?
B9 B4 B5 B11 -0.7(7) . . . . ?
B3 B4 B5 B11 63.2(6) . . . . ?
C1 B4 B5 B10 133.8(6) . . . . ?
B9 B4 B5 B10 37.7(6) . . . . ?
B3 B4 B5 B10 101.6(6) . . . . ?
C1 B4 B5 B6 31.8(4) . . . . ?
B10 B4 B5 B6 -102.0(6) . . . . ?
B9 B4 B5 B6 -64.3(7) . . . . ?
B3 B4 B5 B6 -0.4(7) . . . . ?
N1 C1 B6 C7 154.5(5) . . . . ?
B5 C1 B6 C7 -98.8(5) . . . . ?
B4 C1 B6 C7 -64.2(6) . . . . ?
B3 C1 B6 C7 7.4(7) . . . . ?
B2 C1 B6 C7 41.9(4) . . . . ?
N1 C1 B6 B11 -146.9(5) . . . . ?
B5 C1 B6 B11 -40.2(5) . . . . ?
B4 C1 B6 B11 -5.6(6) . . . . ?
B3 C1 B6 B11 66.1(6) . . . . ?
B2 C1 B6 B11 100.5(5) . . . . ?
N1 C1 B6 B2 112.6(5) . . . . ?
B5 C1 B6 B2 -140.7(5) . . . . ?
B4 C1 B6 B2 -106.1(5) . . . . ?
B3 C1 B6 B2 -34.4(5) . . . . ?
N1 C1 B6 B5 -106.7(5) . . . . ?
B4 C1 B6 B5 34.6(5) . . . . ?
B3 C1 B6 B5 106.2(6) . . . . ?
B2 C1 B6 B5 140.7(5) . . . . ?
N1 C1 B6 Ir1 6.0(6) . . . . ?
B5 C1 B6 Ir1 112.7(5) . . . . ?
B4 C1 B6 Ir1 147.3(4) . . . . ?
B3 C1 B6 Ir1 -141.1(4) . . . . ?
B2 C1 B6 Ir1 -106.6(5) . . . . ?
C1 B2 B6 C7 -128.8(5) . . . . ?
B8 B2 B6 C7 -33.8(5) . . . . ?
B3 B2 B6 C7 -98.0(6) . . . . ?
C7 B2 B6 C1 128.8(5) . . . . ?
B8 B2 B6 C1 95.0(6) . . . . ?
B3 B2 B6 C1 30.7(4) . . . . ?
C1 B2 B6 B11 -92.8(5) . . . . ?
C7 B2 B6 B11 36.0(5) . . . . ?
B8 B2 B6 B11 2.2(7) . . . . ?
B3 B2 B6 B11 -62.0(6) . . . . ?
C1 B2 B6 B5 -33.1(4) . . . . ?
C7 B2 B6 B5 95.7(5) . . . . ?
B8 B2 B6 B5 61.8(6) . . . . ?
B3 B2 B6 B5 -2.4(6) . . . . ?
C1 B2 B6 Ir1 99.3(4) . . . . ?
C7 B2 B6 Ir1 -131.9(5) . . . . ?
B8 B2 B6 Ir1 -165.7(5) . . . . ?
B3 B2 B6 Ir1 130.1(5) . . . . ?
C1 B5 B6 C7 92.9(5) . . . . ?
B11 B5 B6 C7 -38.3(5) . . . . ?
B4 B5 B6 C7 61.1(6) . . . . ?
B10 B5 B6 C7 -2.5(7) . . . . ?
B11 B5 B6 C1 -131.2(5) . . . . ?
B4 B5 B6 C1 -31.8(4) . . . . ?
B10 B5 B6 C1 -95.5(6) . . . . ?
C1 B5 B6 B11 131.2(5) . . . . ?
B4 B5 B6 B11 99.4(6) . . . . ?
B10 B5 B6 B11 35.7(5) . . . . ?
C1 B5 B6 B2 33.5(4) . . . . ?
B11 B5 B6 B2 -97.7(5) . . . . ?
B4 B5 B6 B2 1.7(6) . . . . ?
B10 B5 B6 B2 -62.0(6) . . . . ?
C1 B5 B6 Ir1 -95.9(5) . . . . ?
B11 B5 B6 Ir1 132.9(6) . . . . ?
B4 B5 B6 Ir1 -127.7(5) . . . . ?
B10 B5 B6 Ir1 168.6(5) . . . . ?
C1 B2 C7 B11 3.1(6) . . . . ?
B8 B2 C7 B11 103.0(6) . . . . ?
B3 B2 C7 B11 63.2(6) . . . . ?
B6 B2 C7 B11 -40.0(5) . . . . ?
C1 B2 C7 B12 -62.7(6) . . . . ?
B8 B2 C7 B12 37.2(6) . . . . ?
B3 B2 C7 B12 -2.5(7) . . . . ?
B6 B2 C7 B12 -105.7(6) . . . . ?
C1 B2 C7 B6 43.0(4) . . . . ?
B8 B2 C7 B6 142.9(6) . . . . ?
B3 B2 C7 B6 103.2(5) . . . . ?
C1 B2 C7 B8 -99.9(5) . . . . ?
B3 B2 C7 B8 -39.7(5) . . . . ?
B6 B2 C7 B8 -142.9(6) . . . . ?
C1 B6 C7 B11 95.8(5) . . . . ?
B2 B6 C7 B11 137.6(5) . . . . ?
B5 B6 C7 B11 38.2(5) . . . . ?
Ir1 B6 C7 B11 -130.5(7) . . . . ?
C1 B6 C7 B12 61.7(7) . . . . ?
B11 B6 C7 B12 -34.1(6) . . . . ?
B2 B6 C7 B12 103.5(6) . . . . ?
B5 B6 C7 B12 4.1(7) . . . . ?
Ir1 B6 C7 B12 -164.6(6) . . . . ?
C1 B6 C7 B2 -41.8(4) . . . . ?
B11 B6 C7 B2 -137.6(5) . . . . ?
B5 B6 C7 B2 -99.4(5) . . . . ?
Ir1 B6 C7 B2 91.9(7) . . . . ?
C1 B6 C7 B8 -6.5(7) . . . . ?
B11 B6 C7 B8 -102.3(7) . . . . ?
B2 B6 C7 B8 35.3(6) . . . . ?
B5 B6 C7 B8 -64.1(7) . . . . ?
Ir1 B6 C7 B8 127.2(7) . . . . ?
B11 C7 B8 B2 -104.0(6) . . . . ?
B12 C7 B8 B2 -140.4(6) . . . . ?
B6 C7 B8 B2 -36.1(6) . . . . ?
B11 C7 B8 B3 -64.1(7) . . . . ?
B12 C7 B8 B3 -100.5(7) . . . . ?
B2 C7 B8 B3 39.9(5) . . . . ?
B6 C7 B8 B3 3.7(8) . . . . ?
B11 C7 B8 B12 36.4(6) . . . . ?
B2 C7 B8 B12 140.4(6) . . . . ?
B6 C7 B8 B12 104.3(7) . . . . ?
B11 C7 B8 B9 -1.7(7) . . . . ?
B12 C7 B8 B9 -38.1(5) . . . . ?
B2 C7 B8 B9 102.3(6) . . . . ?
B6 C7 B8 B9 66.1(7) . . . . ?
C1 B2 B8 C7 95.2(5) . . . . ?
B3 B2 B8 C7 135.0(6) . . . . ?
B6 B2 B8 C7 33.3(5) . . . . ?
C1 B2 B8 B3 -39.8(5) . . . . ?
C7 B2 B8 B3 -135.0(6) . . . . ?
B6 B2 B8 B3 -101.7(6) . . . . ?
C1 B2 B8 B12 60.8(7) . . . . ?
C7 B2 B8 B12 -34.4(5) . . . . ?
B3 B2 B8 B12 100.6(6) . . . . ?
B6 B2 B8 B12 -1.1(8) . . . . ?
C1 B2 B8 B9 -1.8(8) . . . . ?
C7 B2 B8 B9 -97.0(7) . . . . ?
B3 B2 B8 B9 38.0(6) . . . . ?
B6 B2 B8 B9 -63.7(7) . . . . ?
C1 B3 B8 C7 1.0(7) . . . . ?
B9 B3 B8 C7 98.6(7) . . . . ?
B4 B3 B8 C7 61.6(7) . . . . ?
B2 B3 B8 C7 -38.8(5) . . . . ?
C1 B3 B8 B2 39.8(5) . . . . ?
B9 B3 B8 B2 137.4(6) . . . . ?
B4 B3 B8 B2 100.4(5) . . . . ?
C1 B3 B8 B12 -59.9(7) . . . . ?
B9 B3 B8 B12 37.7(6) . . . . ?
B4 B3 B8 B12 0.7(7) . . . . ?
B2 B3 B8 B12 -99.7(6) . . . . ?
C1 B3 B8 B9 -97.6(6) . . . . ?
B4 B3 B8 B9 -37.0(5) . . . . ?
B2 B3 B8 B9 -137.4(6) . . . . ?
C1 B4 B9 B10 -99.4(6) . . . . ?
B5 B4 B9 B10 -38.2(5) . . . . ?
B3 B4 B9 B10 -139.4(6) . . . . ?
C1 B4 B9 B12 -61.1(7) . . . . ?
B10 B4 B9 B12 38.4(6) . . . . ?
B5 B4 B9 B12 0.2(8) . . . . ?
B3 B4 B9 B12 -101.0(6) . . . . ?
C1 B4 B9 B3 40.0(5) . . . . ?
B10 B4 B9 B3 139.4(6) . . . . ?
B5 B4 B9 B3 101.2(5) . . . . ?
C1 B4 B9 B8 2.3(8) . . . . ?
B10 B4 B9 B8 101.7(7) . . . . ?
B5 B4 B9 B8 63.5(7) . . . . ?
B3 B4 B9 B8 -37.7(6) . . . . ?
C1 B3 B9 B10 -3.0(7) . . . . ?
B8 B3 B9 B10 -101.3(7) . . . . ?
B4 B3 B9 B10 36.6(5) . . . . ?
B2 B3 B9 B10 -63.8(7) . . . . ?
C1 B3 B9 B4 -39.6(5) . . . . ?
B8 B3 B9 B4 -137.8(6) . . . . ?
B2 B3 B9 B4 -100.4(5) . . . . ?
C1 B3 B9 B12 60.2(7) . . . . ?
B8 B3 B9 B12 -38.1(6) . . . . ?
B4 B3 B9 B12 99.8(7) . . . . ?
B2 B3 B9 B12 -0.6(8) . . . . ?
C1 B3 B9 B8 98.2(6) . . . . ?
B4 B3 B9 B8 137.8(6) . . . . ?
B2 B3 B9 B8 37.4(5) . . . . ?
C7 B8 B9 B10 1.8(7) . . . . ?
B2 B8 B9 B10 63.2(8) . . . . ?
B3 B8 B9 B10 101.6(6) . . . . ?
B12 B8 B9 B10 -35.6(6) . . . . ?
C7 B8 B9 B4 -61.7(7) . . . . ?
B2 B8 B9 B4 -0.3(9) . . . . ?
B3 B8 B9 B4 38.1(6) . . . . ?
B12 B8 B9 B4 -99.2(7) . . . . ?
C7 B8 B9 B12 37.5(5) . . . . ?
B2 B8 B9 B12 98.9(6) . . . . ?
B3 B8 B9 B12 137.3(6) . . . . ?
C7 B8 B9 B3 -99.8(6) . . . . ?
B2 B8 B9 B3 -38.4(6) . . . . ?
B12 B8 B9 B3 -137.3(6) . . . . ?
B12 B9 B10 B4 -136.5(6) . . . . ?
B3 B9 B10 B4 -37.0(5) . . . . ?
B8 B9 B10 B4 -100.7(6) . . . . ?
B4 B9 B10 B12 136.5(6) . . . . ?
B3 B9 B10 B12 99.5(6) . . . . ?
B8 B9 B10 B12 35.8(5) . . . . ?
B4 B9 B10 B5 37.6(5) . . . . ?
B12 B9 B10 B5 -98.8(6) . . . . ?
B3 B9 B10 B5 0.7(8) . . . . ?
B8 B9 B10 B5 -63.0(7) . . . . ?
B4 B9 B10 B11 99.4(6) . . . . ?
B12 B9 B10 B11 -37.1(5) . . . . ?
B3 B9 B10 B11 62.4(7) . . . . ?
B8 B9 B10 B11 -1.3(7) . . . . ?
C1 B4 B10 B9 98.1(6) . . . . ?
B5 B4 B10 B9 137.8(6) . . . . ?
B3 B4 B10 B9 36.6(5) . . . . ?
C1 B4 B10 B12 58.8(7) . . . . ?
B5 B4 B10 B12 98.5(6) . . . . ?
B9 B4 B10 B12 -39.3(6) . . . . ?
B3 B4 B10 B12 -2.6(7) . . . . ?
C1 B4 B10 B5 -39.7(5) . . . . ?
B9 B4 B10 B5 -137.8(6) . . . . ?
B3 B4 B10 B5 -101.1(5) . . . . ?
C1 B4 B10 B11 -2.7(7) . . . . ?
B5 B4 B10 B11 37.0(5) . . . . ?
B9 B4 B10 B11 -100.7(7) . . . . ?
B3 B4 B10 B11 -64.1(7) . . . . ?
C1 B5 B10 B9 2.0(7) . . . . ?
B11 B5 B10 B9 99.5(7) . . . . ?
B4 B5 B10 B9 -37.9(5) . . . . ?
B6 B5 B10 B9 64.2(7) . . . . ?
C1 B5 B10 B4 39.9(5) . . . . ?
B11 B5 B10 B4 137.4(6) . . . . ?
B6 B5 B10 B4 102.1(6) . . . . ?
C1 B5 B10 B12 -62.0(7) . . . . ?
B11 B5 B10 B12 35.5(6) . . . . ?
B4 B5 B10 B12 -101.9(7) . . . . ?
B6 B5 B10 B12 0.2(8) . . . . ?
C1 B5 B10 B11 -97.5(6) . . . . ?
B4 B5 B10 B11 -137.4(6) . . . . ?
B6 B5 B10 B11 -35.3(5) . . . . ?
B2 C7 B11 B12 -103.2(6) . . . . ?
B6 C7 B11 B12 -143.7(6) . . . . ?
B8 C7 B11 B12 -36.9(6) . . . . ?
B12 C7 B11 B5 101.8(6) . . . . ?
B2 C7 B11 B5 -1.4(7) . . . . ?
B6 C7 B11 B5 -41.9(5) . . . . ?
B8 C7 B11 B5 64.9(7) . . . . ?
B12 C7 B11 B6 143.7(6) . . . . ?
B2 C7 B11 B6 40.5(5) . . . . ?
B8 C7 B11 B6 106.7(6) . . . . ?
B12 C7 B11 B10 37.9(5) . . . . ?
B2 C7 B11 B10 -65.3(7) . . . . ?
B6 C7 B11 B10 -105.7(6) . . . . ?
B8 C7 B11 B10 1.0(7) . . . . ?
C1 B5 B11 C7 -1.0(7) . . . . ?
B4 B5 B11 C7 -62.7(6) . . . . ?
B10 B5 B11 C7 -100.4(6) . . . . ?
B6 B5 B11 C7 40.7(5) . . . . ?
C1 B5 B11 B12 62.7(6) . . . . ?
B4 B5 B11 B12 1.0(7) . . . . ?
B10 B5 B11 B12 -36.7(6) . . . . ?
B6 B5 B11 B12 104.4(6) . . . . ?
C1 B5 B11 B6 -41.7(4) . . . . ?
B4 B5 B11 B6 -103.4(5) . . . . ?
B10 B5 B11 B6 -141.1(6) . . . . ?
C1 B5 B11 B10 99.4(6) . . . . ?
B4 B5 B11 B10 37.7(5) . . . . ?
B6 B5 B11 B10 141.1(6) . . . . ?
C1 B6 B11 C7 -94.7(5) . . . . ?
B2 B6 B11 C7 -36.0(5) . . . . ?
B5 B6 B11 C7 -134.4(6) . . . . ?
Ir1 B6 B11 C7 126.8(7) . . . . ?
C7 B6 B11 B12 33.4(5) . . . . ?
C1 B6 B11 B12 -61.4(6) . . . . ?
B2 B6 B11 B12 -2.6(7) . . . . ?
B5 B6 B11 B12 -101.0(6) . . . . ?
Ir1 B6 B11 B12 160.2(6) . . . . ?
C7 B6 B11 B5 134.4(6) . . . . ?
C1 B6 B11 B5 39.6(4) . . . . ?
B2 B6 B11 B5 98.4(5) . . . . ?
Ir1 B6 B11 B5 -98.8(7) . . . . ?
C7 B6 B11 B10 98.3(7) . . . . ?
C1 B6 B11 B10 3.5(7) . . . . ?
B2 B6 B11 B10 62.3(7) . . . . ?
B5 B6 B11 B10 -36.1(6) . . . . ?
Ir1 B6 B11 B10 -134.9(7) . . . . ?
B9 B10 B11 C7 0.2(7) . . . . ?
B4 B10 B11 C7 63.6(7) . . . . ?
B12 B10 B11 C7 -38.0(5) . . . . ?
B5 B10 B11 C7 101.1(6) . . . . ?
B9 B10 B11 B12 38.2(6) . . . . ?
B4 B10 B11 B12 101.6(7) . . . . ?
B5 B10 B11 B12 139.1(6) . . . . ?
B9 B10 B11 B5 -100.9(6) . . . . ?
B4 B10 B11 B5 -37.6(5) . . . . ?
B12 B10 B11 B5 -139.1(6) . . . . ?
B9 B10 B11 B6 -64.0(7) . . . . ?
B4 B10 B11 B6 -0.6(8) . . . . ?
B12 B10 B11 B6 -102.2(6) . . . . ?
B5 B10 B11 B6 36.9(6) . . . . ?
B2 C7 B12 B11 103.7(6) . . . . ?
B6 C7 B12 B11 34.7(5) . . . . ?
B8 C7 B12 B11 140.6(6) . . . . ?
B11 C7 B12 B10 -38.9(6) . . . . ?
B2 C7 B12 B10 64.8(8) . . . . ?
B6 C7 B12 B10 -4.2(8) . . . . ?
B8 C7 B12 B10 101.7(7) . . . . ?
B11 C7 B12 B9 -101.6(7) . . . . ?
B2 C7 B12 B9 2.1(8) . . . . ?
B6 C7 B12 B9 -66.9(8) . . . . ?
B8 C7 B12 B9 39.0(6) . . . . ?
B11 C7 B12 B8 -140.6(6) . . . . ?
B2 C7 B12 B8 -36.9(6) . . . . ?
B6 C7 B12 B8 -105.9(6) . . . . ?
B5 B11 B12 C7 -100.4(6) . . . . ?
B6 B11 B12 C7 -33.4(5) . . . . ?
B10 B11 B12 C7 -137.4(6) . . . . ?
C7 B11 B12 B10 137.4(6) . . . . ?
B5 B11 B12 B10 37.0(5) . . . . ?
B6 B11 B12 B10 104.0(6) . . . . ?
C7 B11 B12 B9 99.5(7) . . . . ?
B5 B11 B12 B9 -0.9(8) . . . . ?
B6 B11 B12 B9 66.1(7) . . . . ?
B10 B11 B12 B9 -37.9(6) . . . . ?
C7 B11 B12 B8 35.5(6) . . . . ?
B5 B11 B12 B8 -64.9(7) . . . . ?
B6 B11 B12 B8 2.1(8) . . . . ?
B10 B11 B12 B8 -101.9(6) . . . . ?
B9 B10 B12 C7 -99.6(7) . . . . ?
B4 B10 B12 C7 -60.5(8) . . . . ?
B5 B10 B12 C7 2.3(8) . . . . ?
B11 B10 B12 C7 37.8(6) . . . . ?
B9 B10 B12 B11 -137.4(6) . . . . ?
B4 B10 B12 B11 -98.4(6) . . . . ?
B5 B10 B12 B11 -35.5(5) . . . . ?
B4 B10 B12 B9 39.0(5) . . . . ?
B5 B10 B12 B9 101.9(6) . . . . ?
B11 B10 B12 B9 137.4(6) . . . . ?
B9 B10 B12 B8 -35.9(6) . . . . ?
B4 B10 B12 B8 3.1(8) . . . . ?
B5 B10 B12 B8 65.9(7) . . . . ?
B11 B10 B12 B8 101.5(6) . . . . ?
B10 B9 B12 C7 101.5(7) . . . . ?
B4 B9 B12 C7 63.1(8) . . . . ?
B3 B9 B12 C7 -0.9(8) . . . . ?
B8 B9 B12 C7 -38.8(6) . . . . ?
B10 B9 B12 B11 38.9(6) . . . . ?
B4 B9 B12 B11 0.4(8) . . . . ?
B3 B9 B12 B11 -63.5(8) . . . . ?
B8 B9 B12 B11 -101.4(6) . . . . ?
B4 B9 B12 B10 -38.4(5) . . . . ?
B3 B9 B12 B10 -102.4(6) . . . . ?
B8 B9 B12 B10 -140.3(6) . . . . ?
B10 B9 B12 B8 140.3(6) . . . . ?
B4 B9 B12 B8 101.9(6) . . . . ?
B3 B9 B12 B8 37.9(6) . . . . ?
B2 B8 B12 C7 34.6(5) . . . . ?
B3 B8 B12 C7 98.4(6) . . . . ?
B9 B8 B12 C7 136.2(6) . . . . ?
C7 B8 B12 B11 -35.2(5) . . . . ?
B2 B8 B12 B11 -0.6(8) . . . . ?
B3 B8 B12 B11 63.2(7) . . . . ?
B9 B8 B12 B11 101.1(6) . . . . ?
C7 B8 B12 B10 -100.7(6) . . . . ?
B2 B8 B12 B10 -66.1(7) . . . . ?
B3 B8 B12 B10 -2.3(8) . . . . ?
B9 B8 B12 B10 35.5(6) . . . . ?
C7 B8 B12 B9 -136.2(6) . . . . ?
B2 B8 B12 B9 -101.6(6) . . . . ?
B3 B8 B12 B9 -37.9(5) . . . . ?
N1 N2 C2 C8 -164.7(5) . . . . ?
Ir1 N2 C2 C8 23.6(7) . . . . ?
N1 N2 C2 C3 12.0(7) . . . . ?
Ir1 N2 C2 C3 -159.6(4) . . . . ?
N2 C2 C3 C4 177.6(5) . . . . ?
C8 C2 C3 C4 -5.7(9) . . . . ?
N2 C2 C3 Ir2 -2.0(7) . . . . ?
C8 C2 C3 Ir2 174.7(5) . . . . ?
C2 C3 C4 C5 5.6(9) . . . . ?
Ir2 C3 C4 C5 -174.8(5) . . . . ?
C9 O1 C5 C6 5.5(12) . . . . ?
C9 O1 C5 C4 -172.4(8) . . . . ?
C3 C4 C5 O1 175.6(6) . . . . ?
C3 C4 C5 C6 -2.4(10) . . . . ?
O1 C5 C6 C8 -179.0(7) . . . . ?
C4 C5 C6 C8 -1.2(10) . . . . ?
C5 C6 C8 C2 1.2(10) . . . . ?
N2 C2 C8 C6 178.9(6) . . . . ?
C3 C2 C8 C6 2.3(9) . . . . ?
C14 C10 C11 C12 -4.0(7) . . . . ?
C15 C10 C11 C12 -171.5(7) . . . . ?
Ir1 C10 C11 C12 62.1(4) . . . . ?
C14 C10 C11 C16 166.3(7) . . . . ?
C15 C10 C11 C16 -1.3(12) . . . . ?
Ir1 C10 C11 C16 -127.7(7) . . . . ?
C14 C10 C11 Ir1 -66.0(5) . . . . ?
C15 C10 C11 Ir1 126.4(7) . . . . ?
C10 C11 C12 C13 5.3(7) . . . . ?
C16 C11 C12 C13 -165.0(7) . . . . ?
Ir1 C11 C12 C13 68.9(4) . . . . ?
C10 C11 C12 C17 177.3(7) . . . . ?
C16 C11 C12 C17 7.0(11) . . . . ?
Ir1 C11 C12 C17 -119.1(7) . . . . ?
C10 C11 C12 Ir1 -63.6(5) . . . . ?
C16 C11 C12 Ir1 126.1(7) . . . . ?
C11 C12 C13 C14 -4.5(7) . . . . ?
C17 C12 C13 C14 -176.4(7) . . . . ?
Ir1 C12 C13 C14 60.4(5) . . . . ?
C11 C12 C13 C18 175.7(6) . . . . ?
C17 C12 C13 C18 3.8(11) . . . . ?
Ir1 C12 C13 C18 -119.4(6) . . . . ?
C11 C12 C13 Ir1 -64.9(4) . . . . ?
C17 C12 C13 Ir1 123.2(8) . . . . ?
C12 C13 C14 C10 2.1(7) . . . . ?
C18 C13 C14 C10 -178.2(7) . . . . ?
Ir1 C13 C14 C10 58.1(4) . . . . ?
C12 C13 C14 C19 179.0(7) . . . . ?
C18 C13 C14 C19 -1.2(12) . . . . ?
Ir1 C13 C14 C19 -124.9(8) . . . . ?
C12 C13 C14 Ir1 -56.1(4) . . . . ?
C18 C13 C14 Ir1 123.7(7) . . . . ?
C11 C10 C14 C13 1.2(7) . . . . ?
C15 C10 C14 C13 170.0(6) . . . . ?
Ir1 C10 C14 C13 -61.9(5) . . . . ?
C11 C10 C14 C19 -175.8(7) . . . . ?
C15 C10 C14 C19 -7.0(11) . . . . ?
Ir1 C10 C14 C19 121.1(7) . . . . ?
C11 C10 C14 Ir1 63.2(5) . . . . ?
C15 C10 C14 Ir1 -128.1(7) . . . . ?
C24 C20 C21 C22 7.8(7) . . . . ?
C25 C20 C21 C22 -165.2(6) . . . . ?
Ir2 C20 C21 C22 69.0(4) . . . . ?
C24 C20 C21 C26 173.2(6) . . . . ?
C25 C20 C21 C26 0.2(10) . . . . ?
Ir2 C20 C21 C26 -125.7(6) . . . . ?
C24 C20 C21 Ir2 -61.1(4) . . . . ?
C25 C20 C21 Ir2 125.8(6) . . . . ?
C20 C21 C22 C23 -6.8(7) . . . . ?
C26 C21 C22 C23 -172.0(6) . . . . ?
Ir2 C21 C22 C23 57.0(4) . . . . ?
C20 C21 C22 C27 163.8(6) . . . . ?
C26 C21 C22 C27 -1.4(10) . . . . ?
Ir2 C21 C22 C27 -132.4(6) . . . . ?
C20 C21 C22 Ir2 -63.9(4) . . . . ?
C26 C21 C22 Ir2 131.0(6) . . . . ?
C21 C22 C23 C24 3.2(7) . . . . ?
C27 C22 C23 C24 -167.4(6) . . . . ?
Ir2 C22 C23 C24 57.6(4) . . . . ?
C21 C22 C23 C28 -178.9(6) . . . . ?
C27 C22 C23 C28 10.5(11) . . . . ?
Ir2 C22 C23 C28 -124.4(7) . . . . ?
C21 C22 C23 Ir2 -54.4(4) . . . . ?
C27 C22 C23 Ir2 134.9(6) . . . . ?
C21 C20 C24 C23 -5.8(7) . . . . ?
C25 C20 C24 C23 166.9(6) . . . . ?
Ir2 C20 C24 C23 -68.3(4) . . . . ?
C21 C20 C24 C29 -176.8(7) . . . . ?
C25 C20 C24 C29 -4.1(11) . . . . ?
Ir2 C20 C24 C29 120.7(7) . . . . ?
C21 C20 C24 Ir2 62.5(4) . . . . ?
C25 C20 C24 Ir2 -124.8(7) . . . . ?
C22 C23 C24 C20 1.6(7) . . . . ?
C28 C23 C24 C20 -176.3(6) . . . . ?
Ir2 C23 C24 C20 65.3(4) . . . . ?
C22 C23 C24 C29 172.9(6) . . . . ?
C28 C23 C24 C29 -5.0(11) . . . . ?
Ir2 C23 C24 C29 -123.4(7) . . . . ?
C22 C23 C24 Ir2 -63.6(4) . . . . ?
C28 C23 C24 Ir2 118.4(6) . . . . ?
C30 C31 C32 C32 -177.0(10) . . . 2_666 ?

_refine_diff_density_max         2.463
_refine_diff_density_min         -1.869
_refine_diff_density_rms         0.218



