# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_masa1129
_database_code_depnum_ccdc_archive 'CCDC 1587996'
_audit_update_record             
;
2017-11-28 deposited with the CCDC.
2018-05-09 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         
'C44 H64 Rh2 Si2 Sn, C44 H64 Rh2 Si2 Sn, 0.5(C6 H6)'
_chemical_formula_sum            'C91 H131 Rh4 Si4 Sn2'
_chemical_formula_weight         1986.38

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_symmetry_space_group_name_Hall  '-P 1'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.3200(8)
_cell_length_b                   19.1507(13)
_cell_length_c                   21.3105(15)
_cell_angle_alpha                103.8010(10)
_cell_angle_beta                 93.3040(10)
_cell_angle_gamma                106.7550(10)
_cell_volume                     4256.1(5)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9767
_cell_measurement_theta_min      2.25
_cell_measurement_theta_max      27.47

_exptl_crystal_description       cube
_exptl_crystal_colour            orange
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.550
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2026
_exptl_absorpt_coefficient_mu    1.436
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.806
_exptl_absorpt_correction_T_max  0.866
_exptl_absorpt_process_details   'XPREP; Bruker AXS 2008'

_exptl_special_details           
; 
'SADABS-2008/1 - Bruker AXS 2008'
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'Bruker TXS fine-focus rotating anode'
_diffrn_radiation_monochromator  'Bruker Helios multilayer confocal mirror'
_diffrn_measurement_device_type  'Bruker APEXII CCD area-detector'
_diffrn_measurement_method       'φ and ω'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            46038
_diffrn_reflns_av_R_equivalents  0.0204
_diffrn_reflns_av_sigmaI/netI    0.0233
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_theta_min         0.99
_diffrn_reflns_theta_max         26.50
_reflns_number_total             17507
_reflns_number_gt                16333
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEX2 (Bruker 2008)'
_computing_cell_refinement       'Bruker SAINT (Bruker 2008)'
_computing_data_reduction        'Bruker SAINT and XPREP (Bruker 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_molecular_graphics    'XSHEL (Bruker, 2002)'
_computing_publication_material  'XCIF (Bruker, 2001)'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0181P)²+4.4922P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         17507
_refine_ls_number_parameters     938
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0210
_refine_ls_R_factor_gt           0.0190
_refine_ls_wR_factor_ref         0.0478
_refine_ls_wR_factor_gt          0.0464
_refine_ls_goodness_of_fit_ref   1.008
_refine_ls_restrained_S_all      1.008
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Sn1 Sn 1.384480(11) 1.315603(7) 0.440986(6) 0.01150(3) Uani 1 1 d . . .
C1 C 1.31057(17) 1.18978(11) 0.39150(9) 0.0116(4) Uani 1 1 d . . .
C2 C 1.19263(17) 1.16555(11) 0.35022(8) 0.0112(4) Uani 1 1 d . . .
C3 C 1.13532(17) 1.22517(11) 0.34334(9) 0.0113(4) Uani 1 1 d . . .
C4 C 1.21079(17) 1.30304(11) 0.37256(9) 0.0126(4) Uani 1 1 d . . .
Si1 Si 1.39597(5) 1.12287(3) 0.40982(2) 0.01249(10) Uani 1 1 d . . .
C5 C 1.31722(19) 1.06526(12) 0.46534(10) 0.0185(4) Uani 1 1 d . . .
H5A H 1.2622 1.0175 0.4394 0.028 Uiso 1 1 calc R . .
H5B H 1.2704 1.0922 0.4919 0.028 Uiso 1 1 calc R . .
H5C H 1.3792 1.0569 0.4928 0.028 Uiso 1 1 calc R . .
C6 C 1.40670(19) 1.05119(11) 0.33408(10) 0.0174(4) Uani 1 1 d . . .
H6A H 1.4294 1.0112 0.3463 0.026 Uiso 1 1 calc R . .
H6B H 1.4687 1.0753 0.3105 0.026 Uiso 1 1 calc R . .
H6C H 1.3275 1.0306 0.3069 0.026 Uiso 1 1 calc R . .
C7 C 1.56224(18) 1.17516(12) 0.45501(9) 0.0161(4) Uani 1 1 d . . .
C8 C 1.6266(2) 1.11484(13) 0.45871(11) 0.0232(5) Uani 1 1 d . . .
H8A H 1.6338 1.0886 0.4154 0.035 Uiso 1 1 calc R . .
H8B H 1.5778 1.0794 0.4797 0.035 Uiso 1 1 calc R . .
H8C H 1.7080 1.1391 0.4833 0.035 Uiso 1 1 calc R . .
C9 C 1.55929(19) 1.21843(12) 0.52545(10) 0.0199(4) Uani 1 1 d . . .
H9A H 1.6427 1.2407 0.5480 0.030 Uiso 1 1 calc R . .
H9B H 1.5110 1.1841 0.5475 0.030 Uiso 1 1 calc R . .
H9C H 1.5223 1.2576 0.5248 0.030 Uiso 1 1 calc R . .
C10 C 1.64515(19) 1.23052(13) 0.42179(10) 0.0203(4) Uani 1 1 d . . .
H10A H 1.6058 1.2673 0.4163 0.031 Uiso 1 1 calc R . .
H10B H 1.6570 1.2031 0.3799 0.031 Uiso 1 1 calc R . .
H10C H 1.7244 1.2558 0.4484 0.031 Uiso 1 1 calc R . .
C11 C 1.12625(17) 1.08382(11) 0.31532(9) 0.0127(4) Uani 1 1 d . . .
C12 C 1.09129(18) 1.03019(11) 0.35057(9) 0.0146(4) Uani 1 1 d . . .
H12A H 1.1011 1.0461 0.3959 0.017 Uiso 1 1 calc R . .
C13 C 1.04220(19) 0.95353(12) 0.31944(10) 0.0182(4) Uani 1 1 d . . .
H13A H 1.0202 0.9188 0.3440 0.022 Uiso 1 1 calc R . .
C14 C 1.02584(19) 0.92856(12) 0.25207(10) 0.0191(4) Uani 1 1 d . . .
H14A H 0.9951 0.8771 0.2313 0.023 Uiso 1 1 calc R . .
C15 C 1.05580(19) 0.98112(12) 0.21581(10) 0.0179(4) Uani 1 1 d . . .
H15A H 1.0433 0.9649 0.1705 0.022 Uiso 1 1 calc R . .
C16 C 1.10443(18) 1.05795(11) 0.24698(9) 0.0149(4) Uani 1 1 d . . .
H16A H 1.1228 1.0927 0.2222 0.018 Uiso 1 1 calc R . .
C17 C 1.01854(18) 1.20128(11) 0.29494(9) 0.0129(4) Uani 1 1 d . . .
C18 C 0.89999(18) 1.16421(11) 0.30727(10) 0.0161(4) Uani 1 1 d . . .
H18A H 0.8901 1.1552 0.3480 0.019 Uiso 1 1 calc R . .
C19 C 0.79630(19) 1.14042(12) 0.25976(10) 0.0196(4) Uani 1 1 d . . .
H19A H 0.7181 1.1164 0.2692 0.024 Uiso 1 1 calc R . .
C20 C 0.8093(2) 1.15248(12) 0.19869(10) 0.0224(5) Uani 1 1 d . . .
H20A H 0.7403 1.1364 0.1669 0.027 Uiso 1 1 calc R . .
C21 C 0.9262(2) 1.18875(12) 0.18537(10) 0.0216(4) Uani 1 1 d . . .
H21A H 0.9356 1.1971 0.1444 0.026 Uiso 1 1 calc R . .
C22 C 1.02940(19) 1.21272(11) 0.23285(9) 0.0173(4) Uani 1 1 d . . .
H22A H 1.1072 1.2368 0.2231 0.021 Uiso 1 1 calc R . .
Si2 Si 1.14696(5) 1.38553(3) 0.37441(3) 0.01398(11) Uani 1 1 d . . .
C23 C 1.1204(2) 1.40496(12) 0.29267(10) 0.0202(4) Uani 1 1 d . . .
H23A H 1.0787 1.3582 0.2605 0.030 Uiso 1 1 calc R . .
H23B H 1.1991 1.4286 0.2802 0.030 Uiso 1 1 calc R . .
H23C H 1.0701 1.4380 0.2959 0.030 Uiso 1 1 calc R . .
C24 C 0.9902(2) 1.36509(12) 0.40361(11) 0.0224(4) Uani 1 1 d . . .
H24A H 0.9577 1.4062 0.4035 0.034 Uiso 1 1 calc R . .
H24B H 0.9985 1.3595 0.4471 0.034 Uiso 1 1 calc R . .
H24C H 0.9344 1.3192 0.3751 0.034 Uiso 1 1 calc R . .
C25 C 1.2500(2) 1.48089(11) 0.43117(10) 0.0190(4) Uani 1 1 d . . .
C26 C 1.3829(2) 1.50429(12) 0.41392(11) 0.0230(5) Uani 1 1 d . . .
H26A H 1.4270 1.5549 0.4394 0.035 Uiso 1 1 calc R . .
H26B H 1.3797 1.5024 0.3684 0.035 Uiso 1 1 calc R . .
H26C H 1.4251 1.4703 0.4231 0.035 Uiso 1 1 calc R . .
C27 C 1.2563(2) 1.48083(13) 0.50345(10) 0.0258(5) Uani 1 1 d . . .
H27A H 1.2903 1.4422 0.5099 0.039 Uiso 1 1 calc R . .
H27B H 1.1741 1.4710 0.5158 0.039 Uiso 1 1 calc R . .
H27C H 1.3085 1.5292 0.5298 0.039 Uiso 1 1 calc R . .
C28 C 1.1916(2) 1.54280(13) 0.42319(12) 0.0307(5) Uani 1 1 d . . .
H28A H 1.2382 1.5902 0.4533 0.046 Uiso 1 1 calc R . .
H28B H 1.1069 1.5289 0.4319 0.046 Uiso 1 1 calc R . .
H28C H 1.1936 1.5476 0.3794 0.046 Uiso 1 1 calc R . .
Rh1 Rh 1.154555(13) 1.228248(8) 0.451131(7) 0.01014(3) Uani 1 1 d . . .
C29 C 1.19675(18) 1.29382(12) 0.55223(9) 0.0160(4) Uani 1 1 d . . .
H29A H 1.2613 1.3284 0.5401 0.019 Uiso 1 1 calc R . .
C30 C 1.20565(18) 1.22092(12) 0.54748(9) 0.0158(4) Uani 1 1 d . . .
H30A H 1.2719 1.2084 0.5292 0.019 Uiso 1 1 calc R . .
C31 C 1.11122(19) 1.16184(12) 0.57107(10) 0.0183(4) Uani 1 1 d . . .
H31A H 1.0744 1.1872 0.6059 0.022 Uiso 1 1 calc R . .
H31B H 1.1537 1.1320 0.5887 0.022 Uiso 1 1 calc R . .
C32 C 1.00743(19) 1.10895(12) 0.51636(10) 0.0186(4) Uani 1 1 d . . .
H32A H 1.0293 1.0638 0.4973 0.022 Uiso 1 1 calc R . .
H32B H 0.9308 1.0936 0.5348 0.022 Uiso 1 1 calc R . .
C33 C 0.98599(17) 1.14608(12) 0.46326(9) 0.0155(4) Uani 1 1 d . . .
H33A H 0.9851 1.1202 0.4203 0.019 Uiso 1 1 calc R . .
C34 C 0.96744(17) 1.21722(11) 0.47502(9) 0.0147(4) Uani 1 1 d . . .
H34A H 0.9583 1.2370 0.4399 0.018 Uiso 1 1 calc R . .
C35 C 0.96163(19) 1.26331(12) 0.54312(10) 0.0189(4) Uani 1 1 d . . .
H35A H 0.9316 1.2292 0.5699 0.023 Uiso 1 1 calc R . .
H35B H 0.9027 1.2909 0.5402 0.023 Uiso 1 1 calc R . .
C36 C 1.08873(19) 1.31943(12) 0.57591(10) 0.0192(4) Uani 1 1 d . . .
H36A H 1.0959 1.3680 0.5675 0.023 Uiso 1 1 calc R . .
H36B H 1.0935 1.3264 0.6227 0.023 Uiso 1 1 calc R . .
Rh2 Rh 1.337204(14) 1.254423(8) 0.310641(7) 0.01079(3) Uani 1 1 d . . .
C37 C 1.3758(2) 1.17672(12) 0.22921(9) 0.0179(4) Uani 1 1 d . . .
H37A H 1.3171 1.1386 0.2410 0.021 Uiso 1 1 calc R . .
C38 C 1.3435(2) 1.19336(13) 0.16548(10) 0.0232(5) Uani 1 1 d . . .
H38A H 1.2560 1.1675 0.1496 0.028 Uiso 1 1 calc R . .
H38B H 1.3914 1.1738 0.1333 0.028 Uiso 1 1 calc R . .
C39 C 1.3705(2) 1.27847(13) 0.17306(10) 0.0238(5) Uani 1 1 d . . .
H39A H 1.4548 1.2998 0.1646 0.029 Uiso 1 1 calc R . .
H39B H 1.3140 1.2859 0.1411 0.029 Uiso 1 1 calc R . .
C40 C 1.3554(2) 1.31988(12) 0.24124(10) 0.0188(4) Uani 1 1 d . . .
H40A H 1.2764 1.3220 0.2492 0.023 Uiso 1 1 calc R . .
C41 C 1.4542(2) 1.35515(11) 0.29286(10) 0.0186(4) Uani 1 1 d . . .
H41A H 1.4364 1.3814 0.3319 0.022 Uiso 1 1 calc R . .
C42 C 1.5870(2) 1.35383(12) 0.28995(11) 0.0244(5) Uani 1 1 d . . .
H42A H 1.6318 1.3720 0.3338 0.029 Uiso 1 1 calc R . .
H42B H 1.6276 1.3880 0.2651 0.029 Uiso 1 1 calc R . .
C43 C 1.5942(2) 1.27485(12) 0.25884(11) 0.0222(4) Uani 1 1 d . . .
H43A H 1.5935 1.2676 0.2122 0.027 Uiso 1 1 calc R . .
H43B H 1.6719 1.2704 0.2764 0.027 Uiso 1 1 calc R . .
C44 C 1.48633(19) 1.21401(12) 0.27154(10) 0.0171(4) Uani 1 1 d . . .
H44A H 1.4945 1.2006 0.3104 0.021 Uiso 1 1 calc R . .
Sn2 Sn 0.354526(11) 0.613220(7) 0.085754(6) 0.01079(3) Uani 1 1 d . . .
C45 C 0.35894(17) 0.72587(11) 0.06555(9) 0.0110(4) Uani 1 1 d . . .
C46 C 0.41931(17) 0.79202(11) 0.11991(9) 0.0109(4) Uani 1 1 d . . .
C47 C 0.48990(17) 0.77953(11) 0.17506(9) 0.0113(4) Uani 1 1 d . . .
C48 C 0.48257(17) 0.70237(11) 0.17225(9) 0.0109(4) Uani 1 1 d . . .
Si3 Si 0.25479(5) 0.72958(3) -0.00583(2) 0.01207(10) Uani 1 1 d . . .
C49 C 0.3417(2) 0.78089(13) -0.06290(10) 0.0218(4) Uani 1 1 d . . .
H49A H 0.2831 0.7851 -0.0951 0.033 Uiso 1 1 calc R . .
H49B H 0.3932 0.7531 -0.0841 0.033 Uiso 1 1 calc R . .
H49C H 0.3929 0.8305 -0.0385 0.033 Uiso 1 1 calc R . .
C50 C 0.14223(19) 0.78126(12) 0.02435(10) 0.0193(4) Uani 1 1 d . . .
H50A H 0.1876 0.8310 0.0511 0.029 Uiso 1 1 calc R . .
H50B H 0.0883 0.7539 0.0495 0.029 Uiso 1 1 calc R . .
H50C H 0.0933 0.7852 -0.0122 0.029 Uiso 1 1 calc R . .
C51 C 0.15486(19) 0.63238(12) -0.06049(9) 0.0169(4) Uani 1 1 d . . .
C52 C 0.2329(2) 0.58367(13) -0.09248(10) 0.0232(5) Uani 1 1 d . . .
H52A H 0.2802 0.5728 -0.0593 0.035 Uiso 1 1 calc R . .
H52B H 0.2886 0.6106 -0.1172 0.035 Uiso 1 1 calc R . .
H52C H 0.1787 0.5372 -0.1209 0.035 Uiso 1 1 calc R . .
C53 C 0.0766(2) 0.64471(13) -0.11638(10) 0.0252(5) Uani 1 1 d . . .
H53A H 0.0236 0.5966 -0.1430 0.038 Uiso 1 1 calc R . .
H53B H 0.1311 0.6699 -0.1426 0.038 Uiso 1 1 calc R . .
H53C H 0.0264 0.6752 -0.0983 0.038 Uiso 1 1 calc R . .
C54 C 0.0630(2) 0.58750(13) -0.02333(11) 0.0231(5) Uani 1 1 d . . .
H54A H 0.0100 0.6162 -0.0056 0.035 Uiso 1 1 calc R . .
H54B H 0.1083 0.5780 0.0115 0.035 Uiso 1 1 calc R . .
H54C H 0.0132 0.5403 -0.0526 0.035 Uiso 1 1 calc R . .
C55 C 0.43638(17) 0.87262(11) 0.11730(9) 0.0127(4) Uani 1 1 d . . .
C56 C 0.37556(19) 0.91884(12) 0.15316(10) 0.0178(4) Uani 1 1 d . . .
H56A H 0.3206 0.9001 0.1804 0.021 Uiso 1 1 calc R . .
C57 C 0.3955(2) 0.99274(12) 0.14893(11) 0.0228(5) Uani 1 1 d . . .
H57A H 0.3528 1.0224 0.1728 0.027 Uiso 1 1 calc R . .
C58 C 0.4784(2) 1.02236(12) 0.10961(11) 0.0234(5) Uani 1 1 d . . .
H58A H 0.4910 1.0715 0.1065 0.028 Uiso 1 1 calc R . .
C59 C 0.5421(2) 0.97778(12) 0.07495(11) 0.0231(5) Uani 1 1 d . . .
H59A H 0.5989 0.9973 0.0488 0.028 Uiso 1 1 calc R . .
C60 C 0.52166(19) 0.90416(12) 0.07892(10) 0.0181(4) Uani 1 1 d . . .
H60A H 0.5657 0.8750 0.0555 0.022 Uiso 1 1 calc R . .
C61 C 0.56594(17) 0.84639(11) 0.22971(9) 0.0117(4) Uani 1 1 d . . .
C62 C 0.53628(18) 0.85486(11) 0.29300(9) 0.0151(4) Uani 1 1 d . . .
H62A H 0.4656 0.8208 0.3011 0.018 Uiso 1 1 calc R . .
C63 C 0.6110(2) 0.91370(12) 0.34446(10) 0.0197(4) Uani 1 1 d . . .
H63A H 0.5902 0.9185 0.3865 0.024 Uiso 1 1 calc R . .
C64 C 0.7159(2) 0.96484(12) 0.33306(10) 0.0223(5) Uani 1 1 d . . .
H64A H 0.7669 1.0034 0.3675 0.027 Uiso 1 1 calc R . .
C65 C 0.74498(19) 0.95861(12) 0.27016(11) 0.0193(4) Uani 1 1 d . . .
H65A H 0.8147 0.9936 0.2623 0.023 Uiso 1 1 calc R . .
C66 C 0.67017(18) 0.90020(11) 0.21881(10) 0.0147(4) Uani 1 1 d . . .
H66A H 0.6897 0.8969 0.1766 0.018 Uiso 1 1 calc R . .
Si4 Si 0.55635(5) 0.67334(3) 0.24036(2) 0.01148(10) Uani 1 1 d . . .
C67 C 0.72609(18) 0.72860(12) 0.26485(9) 0.0164(4) Uani 1 1 d . . .
H67A H 0.7724 0.7126 0.2310 0.025 Uiso 1 1 calc R . .
H67B H 0.7557 0.7199 0.3045 0.025 Uiso 1 1 calc R . .
H67C H 0.7369 0.7816 0.2716 0.025 Uiso 1 1 calc R . .
C68 C 0.4826(2) 0.68946(12) 0.31768(9) 0.0183(4) Uani 1 1 d . . .
H68A H 0.4748 0.6476 0.3362 0.027 Uiso 1 1 calc R . .
H68B H 0.4016 0.6938 0.3078 0.027 Uiso 1 1 calc R . .
H68C H 0.5339 0.7352 0.3483 0.027 Uiso 1 1 calc R . .
C69 C 0.54291(19) 0.56783(11) 0.21913(10) 0.0169(4) Uani 1 1 d . . .
C70 C 0.6209(2) 0.55627(13) 0.27557(11) 0.0265(5) Uani 1 1 d . . .
H70A H 0.6098 0.5033 0.2690 0.040 Uiso 1 1 calc R . .
H70B H 0.5940 0.5755 0.3162 0.040 Uiso 1 1 calc R . .
H70C H 0.7073 0.5828 0.2765 0.040 Uiso 1 1 calc R . .
C71 C 0.5924(2) 0.53771(12) 0.15594(10) 0.0212(4) Uani 1 1 d . . .
H71A H 0.6800 0.5635 0.1597 0.032 Uiso 1 1 calc R . .
H71B H 0.5494 0.5464 0.1199 0.032 Uiso 1 1 calc R . .
H71C H 0.5789 0.4844 0.1488 0.032 Uiso 1 1 calc R . .
C72 C 0.4072(2) 0.51813(12) 0.21484(11) 0.0206(4) Uani 1 1 d . . .
H72A H 0.3578 0.5221 0.1785 0.031 Uiso 1 1 calc R . .
H72B H 0.3748 0.5350 0.2543 0.031 Uiso 1 1 calc R . .
H72C H 0.4045 0.4664 0.2090 0.031 Uiso 1 1 calc R . .
Rh3 Rh 0.558167(13) 0.725939(8) 0.078303(7) 0.00946(3) Uani 1 1 d . . .
C73 C 0.72113(17) 0.69130(11) 0.09085(9) 0.0143(4) Uani 1 1 d . . .
H73A H 0.6770 0.6646 0.1178 0.017 Uiso 1 1 calc R . .
C74 C 0.75523(17) 0.77018(11) 0.11102(9) 0.0134(4) Uani 1 1 d . . .
H74A H 0.7350 0.7921 0.1511 0.016 Uiso 1 1 calc R . .
C75 C 0.82282(18) 0.82262(12) 0.07234(10) 0.0170(4) Uani 1 1 d . . .
H75A H 0.9094 0.8242 0.0747 0.020 Uiso 1 1 calc R . .
H75B H 0.8204 0.8734 0.0916 0.020 Uiso 1 1 calc R . .
C76 C 0.76424(19) 0.79677(12) 0.00046(10) 0.0193(4) Uani 1 1 d . . .
H76A H 0.7784 0.8404 -0.0170 0.023 Uiso 1 1 calc R . .
H76B H 0.8042 0.7628 -0.0244 0.023 Uiso 1 1 calc R . .
C77 C 0.62451(18) 0.75644(12) -0.00722(9) 0.0156(4) Uani 1 1 d . . .
H77A H 0.574(2) 0.7829(13) -0.0215(10) 0.014(5) Uiso 1 1 d . . .
C78 C 0.57070(18) 0.67739(12) -0.02107(9) 0.0150(4) Uani 1 1 d . . .
H78A H 0.492(2) 0.6574(12) -0.0438(10) 0.008(5) Uiso 1 1 d . . .
C79 C 0.64257(19) 0.62124(12) -0.02730(9) 0.0185(4) Uani 1 1 d . . .
H79A H 0.6754 0.6160 -0.0686 0.022 Uiso 1 1 calc R . .
H79B H 0.5865 0.5722 -0.0273 0.022 Uiso 1 1 calc R . .
C80 C 0.75044(19) 0.64560(12) 0.02834(10) 0.0178(4) Uani 1 1 d . . .
H80A H 0.7664 0.6010 0.0361 0.021 Uiso 1 1 calc R . .
H80B H 0.8251 0.6758 0.0157 0.021 Uiso 1 1 calc R . .
Rh4 Rh 0.280525(13) 0.718607(8) 0.170174(7) 0.01005(3) Uani 1 1 d . . .
C81 C 0.18746(19) 0.64525(12) 0.22649(10) 0.0174(4) Uani 1 1 d . . .
H81A H 0.2625 0.6347 0.2291 0.021 Uiso 1 1 calc R . .
C82 C 0.1474(2) 0.68427(13) 0.28905(10) 0.0212(4) Uani 1 1 d . . .
H82A H 0.1755 0.6673 0.3249 0.025 Uiso 1 1 calc R . .
H82B H 0.0572 0.6694 0.2843 0.025 Uiso 1 1 calc R . .
C83 C 0.1993(2) 0.77082(13) 0.30572(10) 0.0202(4) Uani 1 1 d . . .
H83A H 0.1383 0.7924 0.3256 0.024 Uiso 1 1 calc R . .
H83B H 0.2737 0.7880 0.3374 0.024 Uiso 1 1 calc R . .
C84 C 0.23097(18) 0.79934(11) 0.24626(9) 0.0154(4) Uani 1 1 d . . .
H84A H 0.3104 0.8320 0.2476 0.019 Uiso 1 1 calc R . .
C85 C 0.14596(18) 0.77872(11) 0.18924(9) 0.0152(4) Uani 1 1 d . . .
H85A H 0.1717 0.7967 0.1538 0.018 Uiso 1 1 calc R . .
C86 C 0.01320(19) 0.72783(13) 0.18394(11) 0.0213(4) Uani 1 1 d . . .
H86A H -0.0416 0.7441 0.1580 0.026 Uiso 1 1 calc R . .
H86B H -0.0118 0.7333 0.2272 0.026 Uiso 1 1 calc R . .
C87 C -0.00237(19) 0.64419(13) 0.15290(11) 0.0230(5) Uani 1 1 d . . .
H87A H -0.0686 0.6131 0.1705 0.028 Uiso 1 1 calc R . .
H87B H -0.0267 0.6326 0.1063 0.028 Uiso 1 1 calc R . .
C88 C 0.11541(18) 0.62455(12) 0.16494(10) 0.0177(4) Uani 1 1 d . . .
H88A H 0.1420 0.5971 0.1295 0.021 Uiso 1 1 calc R . .
C89 C 1.9102(2) 1.03334(15) 0.01935(12) 0.0324(5) Uani 1 1 d . . .
H89A H 1.8499 1.0560 0.0323 0.039 Uiso 1 1 calc R . .
C90 C 1.9047(3) 0.99574(15) -0.04543(12) 0.0355(6) Uani 1 1 d . . .
H90A H 1.8402 0.9927 -0.0760 0.043 Uiso 1 1 calc R . .
C91 C 1.9944(3) 0.96296(15) -0.06460(12) 0.0357(6) Uani 1 1 d . . .
H91A H 1.9908 0.9382 -0.1082 0.043 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sn1 C1 2.2675(19) . ?
Sn1 C4 2.2978(19) . ?
Sn1 Rh2 2.6999(3) . ?
Sn1 Rh1 2.7105(2) . ?
C1 C2 1.444(3) . ?
C1 Si1 1.9076(19) . ?
C1 Rh2 2.3355(18) . ?
C1 Rh1 2.4163(18) . ?
C2 C3 1.497(3) . ?
C2 C11 1.507(3) . ?
C2 Rh1 2.3293(18) . ?
C2 Rh2 2.3504(18) . ?
C3 C4 1.450(3) . ?
C3 C17 1.513(3) . ?
C3 Rh1 2.2799(18) . ?
C3 Rh2 2.3777(18) . ?
C4 Si2 1.911(2) . ?
C4 Rh2 2.2484(19) . ?
C4 Rh1 2.4499(18) . ?
Si1 C6 1.888(2) . ?
Si1 C5 1.894(2) . ?
Si1 C7 1.928(2) . ?
C5 H5A 0.9600 . ?
C5 H5B 0.9600 . ?
C5 H5C 0.9600 . ?
C6 H6A 0.9600 . ?
C6 H6B 0.9600 . ?
C6 H6C 0.9600 . ?
C7 C10 1.538(3) . ?
C7 C9 1.539(3) . ?
C7 C8 1.547(3) . ?
C8 H8A 0.9600 . ?
C8 H8B 0.9600 . ?
C8 H8C 0.9600 . ?
C9 H9A 0.9600 . ?
C9 H9B 0.9600 . ?
C9 H9C 0.9600 . ?
C10 H10A 0.9600 . ?
C10 H10B 0.9600 . ?
C10 H10C 0.9600 . ?
C11 C12 1.394(3) . ?
C11 C16 1.404(3) . ?
C12 C13 1.388(3) . ?
C12 H12A 0.9300 . ?
C13 C14 1.384(3) . ?
C13 H13A 0.9300 . ?
C14 C15 1.389(3) . ?
C14 H14A 0.9300 . ?
C15 C16 1.391(3) . ?
C15 H15A 0.9300 . ?
C16 H16A 0.9300 . ?
C17 C22 1.398(3) . ?
C17 C18 1.398(3) . ?
C18 C19 1.395(3) . ?
C18 H18A 0.9300 . ?
C19 C20 1.384(3) . ?
C19 H19A 0.9300 . ?
C20 C21 1.386(3) . ?
C20 H20A 0.9300 . ?
C21 C22 1.390(3) . ?
C21 H21A 0.9300 . ?
C22 H22A 0.9300 . ?
Si2 C24 1.879(2) . ?
Si2 C23 1.891(2) . ?
Si2 C25 1.927(2) . ?
C23 H23A 0.9600 . ?
C23 H23B 0.9600 . ?
C23 H23C 0.9600 . ?
C24 H24A 0.9600 . ?
C24 H24B 0.9600 . ?
C24 H24C 0.9600 . ?
C25 C26 1.534(3) . ?
C25 C27 1.538(3) . ?
C25 C28 1.551(3) . ?
C26 H26A 0.9600 . ?
C26 H26B 0.9600 . ?
C26 H26C 0.9600 . ?
C27 H27A 0.9600 . ?
C27 H27B 0.9600 . ?
C27 H27C 0.9600 . ?
C28 H28A 0.9600 . ?
C28 H28B 0.9600 . ?
C28 H28C 0.9600 . ?
Rh1 C30 2.1487(18) . ?
Rh1 C29 2.1660(19) . ?
Rh1 C33 2.1688(19) . ?
Rh1 C34 2.1698(19) . ?
C29 C30 1.408(3) . ?
C29 C36 1.513(3) . ?
C29 H29A 0.9300 . ?
C30 C31 1.521(3) . ?
C30 H30A 0.9300 . ?
C31 C32 1.536(3) . ?
C31 H31A 0.9700 . ?
C31 H31B 0.9700 . ?
C32 C33 1.515(3) . ?
C32 H32A 0.9700 . ?
C32 H32B 0.9700 . ?
C33 C34 1.404(3) . ?
C33 H33A 0.9300 . ?
C34 C35 1.524(3) . ?
C34 H34A 0.9300 . ?
C35 C36 1.532(3) . ?
C35 H35A 0.9700 . ?
C35 H35B 0.9700 . ?
C36 H36A 0.9700 . ?
C36 H36B 0.9700 . ?
Rh2 C41 2.134(2) . ?
Rh2 C40 2.1382(19) . ?
Rh2 C37 2.1556(19) . ?
Rh2 C44 2.180(2) . ?
C37 C44 1.392(3) . ?
C37 C38 1.515(3) . ?
C37 H37A 0.9300 . ?
C38 C39 1.536(3) . ?
C38 H38A 0.9700 . ?
C38 H38B 0.9700 . ?
C39 C40 1.525(3) . ?
C39 H39A 0.9700 . ?
C39 H39B 0.9700 . ?
C40 C41 1.409(3) . ?
C40 H40A 0.9300 . ?
C41 C42 1.516(3) . ?
C41 H41A 0.9300 . ?
C42 C43 1.527(3) . ?
C42 H42A 0.9700 . ?
C42 H42B 0.9700 . ?
C43 C44 1.514(3) . ?
C43 H43A 0.9700 . ?
C43 H43B 0.9700 . ?
C44 H44A 0.9300 . ?
Sn2 C48 2.2753(18) . ?
Sn2 C45 2.2859(18) . ?
Sn2 Rh3 2.7084(2) . ?
Sn2 Rh4 2.7254(2) . ?
C45 C46 1.457(3) . ?
C45 Si3 1.8980(19) . ?
C45 Rh3 2.2555(18) . ?
C45 Rh4 2.4664(18) . ?
C46 C47 1.488(2) . ?
C46 C55 1.514(3) . ?
C46 Rh4 2.2872(18) . ?
C46 Rh3 2.3730(18) . ?
C47 C48 1.442(3) . ?
C47 C61 1.508(3) . ?
C47 Rh4 2.3041(18) . ?
C47 Rh3 2.3523(18) . ?
C48 Si4 1.9043(18) . ?
C48 Rh3 2.3131(18) . ?
C48 Rh4 2.3947(18) . ?
Si3 C50 1.880(2) . ?
Si3 C49 1.888(2) . ?
Si3 C51 1.924(2) . ?
C49 H49A 0.9600 . ?
C49 H49B 0.9600 . ?
C49 H49C 0.9600 . ?
C50 H50A 0.9600 . ?
C50 H50B 0.9600 . ?
C50 H50C 0.9600 . ?
C51 C54 1.533(3) . ?
C51 C52 1.535(3) . ?
C51 C53 1.547(3) . ?
C52 H52A 0.9600 . ?
C52 H52B 0.9600 . ?
C52 H52C 0.9600 . ?
C53 H53A 0.9600 . ?
C53 H53B 0.9600 . ?
C53 H53C 0.9600 . ?
C54 H54A 0.9600 . ?
C54 H54B 0.9600 . ?
C54 H54C 0.9600 . ?
C55 C56 1.389(3) . ?
C55 C60 1.399(3) . ?
C56 C57 1.393(3) . ?
C56 H56A 0.9300 . ?
C57 C58 1.383(3) . ?
C57 H57A 0.9300 . ?
C58 C59 1.382(3) . ?
C58 H58A 0.9300 . ?
C59 C60 1.386(3) . ?
C59 H59A 0.9300 . ?
C60 H60A 0.9300 . ?
C61 C62 1.392(3) . ?
C61 C66 1.397(3) . ?
C62 C63 1.394(3) . ?
C62 H62A 0.9300 . ?
C63 C64 1.380(3) . ?
C63 H63A 0.9300 . ?
C64 C65 1.384(3) . ?
C64 H64A 0.9300 . ?
C65 C66 1.389(3) . ?
C65 H65A 0.9300 . ?
C66 H66A 0.9300 . ?
Si4 C67 1.880(2) . ?
Si4 C68 1.890(2) . ?
Si4 C69 1.921(2) . ?
C67 H67A 0.9600 . ?
C67 H67B 0.9600 . ?
C67 H67C 0.9600 . ?
C68 H68A 0.9600 . ?
C68 H68B 0.9600 . ?
C68 H68C 0.9600 . ?
C69 C71 1.537(3) . ?
C69 C72 1.540(3) . ?
C69 C70 1.547(3) . ?
C70 H70A 0.9600 . ?
C70 H70B 0.9600 . ?
C70 H70C 0.9600 . ?
C71 H71A 0.9600 . ?
C71 H71B 0.9600 . ?
C71 H71C 0.9600 . ?
C72 H72A 0.9600 . ?
C72 H72B 0.9600 . ?
C72 H72C 0.9600 . ?
Rh3 C78 2.1309(19) . ?
Rh3 C74 2.1516(18) . ?
Rh3 C77 2.1540(19) . ?
Rh3 C73 2.1559(18) . ?
C73 C74 1.397(3) . ?
C73 C80 1.521(3) . ?
C73 H73A 0.9300 . ?
C74 C75 1.516(3) . ?
C74 H74A 0.9300 . ?
C75 C76 1.537(3) . ?
C75 H75A 0.9700 . ?
C75 H75B 0.9700 . ?
C76 C77 1.527(3) . ?
C76 H76A 0.9700 . ?
C76 H76B 0.9700 . ?
C77 C78 1.409(3) . ?
C77 H77A 0.94(2) . ?
C78 C79 1.512(3) . ?
C78 H78A 0.92(2) . ?
C79 C80 1.535(3) . ?
C79 H79A 0.9700 . ?
C79 H79B 0.9700 . ?
C80 H80A 0.9700 . ?
C80 H80B 0.9700 . ?
Rh4 C81 2.1495(19) . ?
Rh4 C85 2.1610(19) . ?
Rh4 C88 2.166(2) . ?
Rh4 C84 2.1778(19) . ?
C81 C88 1.409(3) . ?
C81 C82 1.527(3) . ?
C81 H81A 0.9300 . ?
C82 C83 1.534(3) . ?
C82 H82A 0.9700 . ?
C82 H82B 0.9700 . ?
C83 C84 1.517(3) . ?
C83 H83A 0.9700 . ?
C83 H83B 0.9700 . ?
C84 C85 1.406(3) . ?
C84 H84A 0.9300 . ?
C85 C86 1.518(3) . ?
C85 H85A 0.9300 . ?
C86 C87 1.534(3) . ?
C86 H86A 0.9700 . ?
C86 H86B 0.9700 . ?
C87 C88 1.510(3) . ?
C87 H87A 0.9700 . ?
C87 H87B 0.9700 . ?
C88 H88A 0.9300 . ?
C89 C91 1.380(4) 2_975 ?
C89 C90 1.385(4) . ?
C89 H89A 0.9300 . ?
C90 C91 1.372(4) . ?
C90 H90A 0.9300 . ?
C91 C89 1.380(4) 2_975 ?
C91 H91A 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Sn1 C4 76.11(7) . . ?
C1 Sn1 Rh2 55.27(4) . . ?
C4 Sn1 Rh2 52.73(5) . . ?
C1 Sn1 Rh1 57.25(5) . . ?
C4 Sn1 Rh1 57.87(5) . . ?
Rh2 Sn1 Rh1 88.770(6) . . ?
C2 C1 Si1 124.25(14) . . ?
C2 C1 Sn1 114.89(13) . . ?
Si1 C1 Sn1 120.71(9) . . ?
C2 C1 Rh2 72.62(10) . . ?
Si1 C1 Rh2 128.18(9) . . ?
Sn1 C1 Rh2 71.81(6) . . ?
C2 C1 Rh1 69.03(10) . . ?
Si1 C1 Rh1 126.23(9) . . ?
Sn1 C1 Rh1 70.64(5) . . ?
Rh2 C1 Rh1 105.56(7) . . ?
C1 C2 C3 117.47(16) . . ?
C1 C2 C11 122.69(16) . . ?
C3 C2 C11 119.84(16) . . ?
C1 C2 Rh1 75.61(10) . . ?
C3 C2 Rh1 69.27(10) . . ?
C11 C2 Rh1 124.72(12) . . ?
C1 C2 Rh2 71.50(10) . . ?
C3 C2 Rh2 72.53(10) . . ?
C11 C2 Rh2 127.16(12) . . ?
Rh1 C2 Rh2 107.94(8) . . ?
C4 C3 C2 116.48(16) . . ?
C4 C3 C17 124.40(16) . . ?
C2 C3 C17 117.65(16) . . ?
C4 C3 Rh1 78.68(10) . . ?
C2 C3 Rh1 72.84(10) . . ?
C17 C3 Rh1 129.18(13) . . ?
C4 C3 Rh2 66.94(10) . . ?
C2 C3 Rh2 70.55(10) . . ?
C17 C3 Rh2 121.86(12) . . ?
Rh1 C3 Rh2 108.67(7) . . ?
C3 C4 Si2 121.80(14) . . ?
C3 C4 Rh2 76.66(11) . . ?
Si2 C4 Rh2 133.46(9) . . ?
C3 C4 Sn1 113.81(13) . . ?
Si2 C4 Sn1 121.96(9) . . ?
Rh2 C4 Sn1 72.86(6) . . ?
C3 C4 Rh1 65.85(10) . . ?
Si2 C4 Rh1 119.31(9) . . ?
Rh2 C4 Rh1 107.23(7) . . ?
Sn1 C4 Rh1 69.54(5) . . ?
C6 Si1 C5 105.34(9) . . ?
C6 Si1 C1 112.79(8) . . ?
C5 Si1 C1 112.97(9) . . ?
C6 Si1 C7 107.94(9) . . ?
C5 Si1 C7 104.19(9) . . ?
C1 Si1 C7 112.94(9) . . ?
Si1 C5 H5A 109.5 . . ?
Si1 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
Si1 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
Si1 C6 H6A 109.5 . . ?
Si1 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
Si1 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C10 C7 C9 108.51(17) . . ?
C10 C7 C8 107.02(17) . . ?
C9 C7 C8 107.42(16) . . ?
C10 C7 Si1 114.94(13) . . ?
C9 C7 Si1 110.98(14) . . ?
C8 C7 Si1 107.64(14) . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C7 C9 H9A 109.5 . . ?
C7 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C7 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C7 C10 H10A 109.5 . . ?
C7 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C7 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C12 C11 C16 117.64(18) . . ?
C12 C11 C2 120.28(17) . . ?
C16 C11 C2 121.96(17) . . ?
C13 C12 C11 121.35(18) . . ?
C13 C12 H12A 119.3 . . ?
C11 C12 H12A 119.3 . . ?
C14 C13 C12 120.37(19) . . ?
C14 C13 H13A 119.8 . . ?
C12 C13 H13A 119.8 . . ?
C13 C14 C15 119.34(19) . . ?
C13 C14 H14A 120.3 . . ?
C15 C14 H14A 120.3 . . ?
C14 C15 C16 120.28(18) . . ?
C14 C15 H15A 119.9 . . ?
C16 C15 H15A 119.9 . . ?
C15 C16 C11 120.93(18) . . ?
C15 C16 H16A 119.5 . . ?
C11 C16 H16A 119.5 . . ?
C22 C17 C18 117.42(18) . . ?
C22 C17 C3 118.75(17) . . ?
C18 C17 C3 123.73(17) . . ?
C19 C18 C17 121.28(19) . . ?
C19 C18 H18A 119.4 . . ?
C17 C18 H18A 119.4 . . ?
C20 C19 C18 120.3(2) . . ?
C20 C19 H19A 119.9 . . ?
C18 C19 H19A 119.9 . . ?
C19 C20 C21 119.34(19) . . ?
C19 C20 H20A 120.3 . . ?
C21 C20 H20A 120.3 . . ?
C20 C21 C22 120.36(19) . . ?
C20 C21 H21A 119.8 . . ?
C22 C21 H21A 119.8 . . ?
C21 C22 C17 121.3(2) . . ?
C21 C22 H22A 119.3 . . ?
C17 C22 H22A 119.3 . . ?
C24 Si2 C23 105.10(10) . . ?
C24 Si2 C4 109.76(9) . . ?
C23 Si2 C4 115.07(9) . . ?
C24 Si2 C25 106.72(10) . . ?
C23 Si2 C25 105.19(9) . . ?
C4 Si2 C25 114.28(9) . . ?
Si2 C23 H23A 109.5 . . ?
Si2 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
Si2 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
Si2 C24 H24A 109.5 . . ?
Si2 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
Si2 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C26 C25 C27 108.89(18) . . ?
C26 C25 C28 107.26(18) . . ?
C27 C25 C28 107.36(18) . . ?
C26 C25 Si2 112.60(14) . . ?
C27 C25 Si2 112.37(15) . . ?
C28 C25 Si2 108.08(15) . . ?
C25 C26 H26A 109.5 . . ?
C25 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C25 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C25 C27 H27A 109.5 . . ?
C25 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
C25 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C25 C28 H28A 109.5 . . ?
C25 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C25 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C30 Rh1 C29 38.10(8) . . ?
C30 Rh1 C33 79.75(7) . . ?
C29 Rh1 C33 95.64(7) . . ?
C30 Rh1 C34 88.11(7) . . ?
C29 Rh1 C34 79.94(7) . . ?
C33 Rh1 C34 37.76(7) . . ?
C30 Rh1 C3 167.28(7) . . ?
C29 Rh1 C3 148.97(7) . . ?
C33 Rh1 C3 105.54(7) . . ?
C34 Rh1 C3 103.18(7) . . ?
C30 Rh1 C2 130.39(7) . . ?
C29 Rh1 C2 157.43(7) . . ?
C33 Rh1 C2 100.61(7) . . ?
C34 Rh1 C2 122.27(7) . . ?
C3 Rh1 C2 37.89(6) . . ?
C30 Rh1 C1 102.67(7) . . ?
C29 Rh1 C1 122.11(7) . . ?
C33 Rh1 C1 121.54(7) . . ?
C34 Rh1 C1 155.11(7) . . ?
C3 Rh1 C1 64.65(6) . . ?
C2 Rh1 C1 35.36(6) . . ?
C30 Rh1 C4 144.04(7) . . ?
C29 Rh1 C4 114.50(7) . . ?
C33 Rh1 C4 134.67(7) . . ?
C34 Rh1 C4 112.93(7) . . ?
C3 Rh1 C4 35.48(6) . . ?
C2 Rh1 C4 63.19(6) . . ?
C1 Rh1 C4 70.66(6) . . ?
C30 Rh1 Sn1 94.67(5) . . ?
C29 Rh1 Sn1 84.20(5) . . ?
C33 Rh1 Sn1 170.67(5) . . ?
C34 Rh1 Sn1 150.39(5) . . ?
C3 Rh1 Sn1 78.46(5) . . ?
C2 Rh1 Sn1 77.23(5) . . ?
C1 Rh1 Sn1 52.12(5) . . ?
C4 Rh1 Sn1 52.59(4) . . ?
C30 C29 C36 124.12(18) . . ?
C30 C29 Rh1 70.28(11) . . ?
C36 C29 Rh1 112.02(13) . . ?
C30 C29 H29A 117.9 . . ?
C36 C29 H29A 117.9 . . ?
Rh1 C29 H29A 87.7 . . ?
C29 C30 C31 122.62(18) . . ?
C29 C30 Rh1 71.62(11) . . ?
C31 C30 Rh1 115.36(13) . . ?
C29 C30 H30A 118.7 . . ?
C31 C30 H30A 118.7 . . ?
Rh1 C30 H30A 83.2 . . ?
C30 C31 C32 112.38(16) . . ?
C30 C31 H31A 109.1 . . ?
C32 C31 H31A 109.1 . . ?
C30 C31 H31B 109.1 . . ?
C32 C31 H31B 109.1 . . ?
H31A C31 H31B 107.9 . . ?
C33 C32 C31 112.37(17) . . ?
C33 C32 H32A 109.1 . . ?
C31 C32 H32A 109.1 . . ?
C33 C32 H32B 109.1 . . ?
C31 C32 H32B 109.1 . . ?
H32A C32 H32B 107.9 . . ?
C34 C33 C32 124.00(18) . . ?
C34 C33 Rh1 71.16(11) . . ?
C32 C33 Rh1 112.48(13) . . ?
C34 C33 H33A 118.0 . . ?
C32 C33 H33A 118.0 . . ?
Rh1 C33 H33A 86.4 . . ?
C33 C34 C35 122.61(17) . . ?
C33 C34 Rh1 71.08(11) . . ?
C35 C34 Rh1 114.50(13) . . ?
C33 C34 H34A 118.7 . . ?
C35 C34 H34A 118.7 . . ?
Rh1 C34 H34A 84.6 . . ?
C34 C35 C36 112.28(16) . . ?
C34 C35 H35A 109.1 . . ?
C36 C35 H35A 109.1 . . ?
C34 C35 H35B 109.1 . . ?
C36 C35 H35B 109.1 . . ?
H35A C35 H35B 107.9 . . ?
C29 C36 C35 113.06(17) . . ?
C29 C36 H36A 109.0 . . ?
C35 C36 H36A 109.0 . . ?
C29 C36 H36B 109.0 . . ?
C35 C36 H36B 109.0 . . ?
H36A C36 H36B 107.8 . . ?
C41 Rh2 C40 38.51(8) . . ?
C41 Rh2 C37 96.28(8) . . ?
C40 Rh2 C37 80.34(8) . . ?
C41 Rh2 C44 79.73(8) . . ?
C40 Rh2 C44 87.84(8) . . ?
C37 Rh2 C44 37.45(8) . . ?
C41 Rh2 C4 99.77(7) . . ?
C40 Rh2 C4 99.83(7) . . ?
C37 Rh2 C4 153.94(8) . . ?
C44 Rh2 C4 167.07(7) . . ?
C41 Rh2 C1 140.46(7) . . ?
C40 Rh2 C1 175.43(7) . . ?
C37 Rh2 C1 104.11(7) . . ?
C44 Rh2 C1 96.33(7) . . ?
C4 Rh2 C1 75.73(7) . . ?
C41 Rh2 C2 165.37(7) . . ?
C40 Rh2 C2 143.27(7) . . ?
C37 Rh2 C2 98.21(7) . . ?
C44 Rh2 C2 113.32(7) . . ?
C4 Rh2 C2 66.00(7) . . ?
C1 Rh2 C2 35.89(6) . . ?
C41 Rh2 C3 131.49(7) . . ?
C40 Rh2 C3 112.60(7) . . ?
C37 Rh2 C3 119.38(7) . . ?
C44 Rh2 C3 148.15(7) . . ?
C4 Rh2 C3 36.40(7) . . ?
C1 Rh2 C3 64.46(6) . . ?
C2 Rh2 C3 36.92(6) . . ?
C41 Rh2 Sn1 92.00(6) . . ?
C40 Rh2 Sn1 123.63(6) . . ?
C37 Rh2 Sn1 145.45(6) . . ?
C44 Rh2 Sn1 112.66(5) . . ?
C4 Rh2 Sn1 54.42(5) . . ?
C1 Rh2 Sn1 52.93(5) . . ?
C2 Rh2 Sn1 77.11(4) . . ?
C3 Rh2 Sn1 77.08(4) . . ?
C44 C37 C38 125.17(19) . . ?
C44 C37 Rh2 72.21(11) . . ?
C38 C37 Rh2 111.06(14) . . ?
C44 C37 H37A 117.4 . . ?
C38 C37 H37A 117.4 . . ?
Rh2 C37 H37A 86.6 . . ?
C37 C38 C39 112.10(17) . . ?
C37 C38 H38A 109.2 . . ?
C39 C38 H38A 109.2 . . ?
C37 C38 H38B 109.2 . . ?
C39 C38 H38B 109.2 . . ?
H38A C38 H38B 107.9 . . ?
C40 C39 C38 111.71(17) . . ?
C40 C39 H39A 109.3 . . ?
C38 C39 H39A 109.3 . . ?
C40 C39 H39B 109.3 . . ?
C38 C39 H39B 109.3 . . ?
H39A C39 H39B 107.9 . . ?
C41 C40 C39 123.82(19) . . ?
C41 C40 Rh2 70.56(11) . . ?
C39 C40 Rh2 114.69(14) . . ?
C41 C40 H40A 118.1 . . ?
C39 C40 H40A 118.1 . . ?
Rh2 C40 H40A 84.8 . . ?
C40 C41 C42 125.40(19) . . ?
C40 C41 Rh2 70.92(11) . . ?
C42 C41 Rh2 111.85(14) . . ?
C40 C41 H41A 117.3 . . ?
C42 C41 H41A 117.3 . . ?
Rh2 C41 H41A 87.2 . . ?
C41 C42 C43 112.60(18) . . ?
C41 C42 H42A 109.1 . . ?
C43 C42 H42A 109.1 . . ?
C41 C42 H42B 109.1 . . ?
C43 C42 H42B 109.1 . . ?
H42A C42 H42B 107.8 . . ?
C44 C43 C42 111.39(17) . . ?
C44 C43 H43A 109.3 . . ?
C42 C43 H43A 109.3 . . ?
C44 C43 H43B 109.3 . . ?
C42 C43 H43B 109.3 . . ?
H43A C43 H43B 108.0 . . ?
C37 C44 C43 124.59(18) . . ?
C37 C44 Rh2 70.34(11) . . ?
C43 C44 Rh2 114.31(13) . . ?
C37 C44 H44A 117.7 . . ?
C43 C44 H44A 117.7 . . ?
Rh2 C44 H44A 85.4 . . ?
C48 Sn2 C45 75.60(7) . . ?
C48 Sn2 Rh3 54.47(5) . . ?
C45 Sn2 Rh3 52.87(5) . . ?
C48 Sn2 Rh4 56.36(5) . . ?
C45 Sn2 Rh4 58.18(5) . . ?
Rh3 Sn2 Rh4 88.266(7) . . ?
C46 C45 Si3 122.41(13) . . ?
C46 C45 Rh3 76.09(10) . . ?
Si3 C45 Rh3 132.75(9) . . ?
C46 C45 Sn2 114.34(12) . . ?
Si3 C45 Sn2 121.19(9) . . ?
Rh3 C45 Sn2 73.22(5) . . ?
C46 C45 Rh4 65.55(10) . . ?
Si3 C45 Rh4 120.82(8) . . ?
Rh3 C45 Rh4 106.42(7) . . ?
Sn2 C45 Rh4 69.87(5) . . ?
C45 C46 C47 116.61(16) . . ?
C45 C46 C55 123.82(16) . . ?
C47 C46 C55 118.33(16) . . ?
C45 C46 Rh4 79.00(11) . . ?
C47 C46 Rh4 71.71(10) . . ?
C55 C46 Rh4 129.13(13) . . ?
C45 C46 Rh3 67.32(10) . . ?
C47 C46 Rh3 70.90(10) . . ?
C55 C46 Rh3 122.01(12) . . ?
Rh4 C46 Rh3 108.56(7) . . ?
C48 C47 C46 116.90(16) . . ?
C48 C47 C61 123.43(16) . . ?
C46 C47 C61 119.66(16) . . ?
C48 C47 Rh4 75.58(11) . . ?
C46 C47 Rh4 70.48(10) . . ?
C61 C47 Rh4 124.56(12) . . ?
C48 C47 Rh3 70.52(10) . . ?
C46 C47 Rh3 72.40(10) . . ?
C61 C47 Rh3 126.60(12) . . ?
Rh4 C47 Rh3 108.69(7) . . ?
C47 C48 Si4 123.63(13) . . ?
C47 C48 Sn2 115.39(12) . . ?
Si4 C48 Sn2 120.54(9) . . ?
C47 C48 Rh3 73.48(10) . . ?
Si4 C48 Rh3 129.65(9) . . ?
Sn2 C48 Rh3 72.35(5) . . ?
C47 C48 Rh4 68.73(10) . . ?
Si4 C48 Rh4 123.38(9) . . ?
Sn2 C48 Rh4 71.35(5) . . ?
Rh3 C48 Rh4 106.96(7) . . ?
C50 Si3 C49 105.89(10) . . ?
C50 Si3 C45 110.28(9) . . ?
C49 Si3 C45 113.96(9) . . ?
C50 Si3 C51 105.95(9) . . ?
C49 Si3 C51 105.28(9) . . ?
C45 Si3 C51 114.77(9) . . ?
Si3 C49 H49A 109.5 . . ?
Si3 C49 H49B 109.5 . . ?
H49A C49 H49B 109.5 . . ?
Si3 C49 H49C 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
Si3 C50 H50A 109.5 . . ?
Si3 C50 H50B 109.5 . . ?
H50A C50 H50B 109.5 . . ?
Si3 C50 H50C 109.5 . . ?
H50A C50 H50C 109.5 . . ?
H50B C50 H50C 109.5 . . ?
C54 C51 C52 108.90(18) . . ?
C54 C51 C53 106.99(17) . . ?
C52 C51 C53 106.91(17) . . ?
C54 C51 Si3 112.10(14) . . ?
C52 C51 Si3 113.00(14) . . ?
C53 C51 Si3 108.64(14) . . ?
C51 C52 H52A 109.5 . . ?
C51 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
C51 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
C51 C53 H53A 109.5 . . ?
C51 C53 H53B 109.5 . . ?
H53A C53 H53B 109.5 . . ?
C51 C53 H53C 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
C51 C54 H54A 109.5 . . ?
C51 C54 H54B 109.5 . . ?
H54A C54 H54B 109.5 . . ?
C51 C54 H54C 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
C56 C55 C60 117.38(18) . . ?
C56 C55 C46 123.70(17) . . ?
C60 C55 C46 118.87(17) . . ?
C55 C56 C57 121.1(2) . . ?
C55 C56 H56A 119.5 . . ?
C57 C56 H56A 119.5 . . ?
C58 C57 C56 120.6(2) . . ?
C58 C57 H57A 119.7 . . ?
C56 C57 H57A 119.7 . . ?
C59 C58 C57 119.0(2) . . ?
C59 C58 H58A 120.5 . . ?
C57 C58 H58A 120.5 . . ?
C58 C59 C60 120.3(2) . . ?
C58 C59 H59A 119.9 . . ?
C60 C59 H59A 119.9 . . ?
C59 C60 C55 121.56(19) . . ?
C59 C60 H60A 119.2 . . ?
C55 C60 H60A 119.2 . . ?
C62 C61 C66 118.11(17) . . ?
C62 C61 C47 120.70(17) . . ?
C66 C61 C47 121.16(17) . . ?
C61 C62 C63 120.95(19) . . ?
C61 C62 H62A 119.5 . . ?
C63 C62 H62A 119.5 . . ?
C64 C63 C62 120.06(19) . . ?
C64 C63 H63A 120.0 . . ?
C62 C63 H63A 120.0 . . ?
C63 C64 C65 119.82(19) . . ?
C63 C64 H64A 120.1 . . ?
C65 C64 H64A 120.1 . . ?
C64 C65 C66 120.13(19) . . ?
C64 C65 H65A 119.9 . . ?
C66 C65 H65A 119.9 . . ?
C65 C66 C61 120.87(18) . . ?
C65 C66 H66A 119.6 . . ?
C61 C66 H66A 119.6 . . ?
C67 Si4 C68 105.45(9) . . ?
C67 Si4 C48 112.05(9) . . ?
C68 Si4 C48 113.17(9) . . ?
C67 Si4 C69 107.42(9) . . ?
C68 Si4 C69 104.27(9) . . ?
C48 Si4 C69 113.80(9) . . ?
Si4 C67 H67A 109.5 . . ?
Si4 C67 H67B 109.5 . . ?
H67A C67 H67B 109.5 . . ?
Si4 C67 H67C 109.5 . . ?
H67A C67 H67C 109.5 . . ?
H67B C67 H67C 109.5 . . ?
Si4 C68 H68A 109.5 . . ?
Si4 C68 H68B 109.5 . . ?
H68A C68 H68B 109.5 . . ?
Si4 C68 H68C 109.5 . . ?
H68A C68 H68C 109.5 . . ?
H68B C68 H68C 109.5 . . ?
C71 C69 C72 107.83(17) . . ?
C71 C69 C70 106.87(17) . . ?
C72 C69 C70 107.88(17) . . ?
C71 C69 Si4 115.74(14) . . ?
C72 C69 Si4 111.29(14) . . ?
C70 C69 Si4 106.89(14) . . ?
C69 C70 H70A 109.5 . . ?
C69 C70 H70B 109.5 . . ?
H70A C70 H70B 109.5 . . ?
C69 C70 H70C 109.5 . . ?
H70A C70 H70C 109.5 . . ?
H70B C70 H70C 109.5 . . ?
C69 C71 H71A 109.5 . . ?
C69 C71 H71B 109.5 . . ?
H71A C71 H71B 109.5 . . ?
C69 C71 H71C 109.5 . . ?
H71A C71 H71C 109.5 . . ?
H71B C71 H71C 109.5 . . ?
C69 C72 H72A 109.5 . . ?
C69 C72 H72B 109.5 . . ?
H72A C72 H72B 109.5 . . ?
C69 C72 H72C 109.5 . . ?
H72A C72 H72C 109.5 . . ?
H72B C72 H72C 109.5 . . ?
C78 Rh3 C74 96.71(7) . . ?
C78 Rh3 C77 38.38(8) . . ?
C74 Rh3 C77 79.86(7) . . ?
C78 Rh3 C73 80.21(7) . . ?
C74 Rh3 C73 37.84(7) . . ?
C77 Rh3 C73 87.53(7) . . ?
C78 Rh3 C45 98.15(7) . . ?
C74 Rh3 C45 157.67(7) . . ?
C77 Rh3 C45 101.96(7) . . ?
C73 Rh3 C45 162.67(7) . . ?
C78 Rh3 C48 145.40(7) . . ?
C74 Rh3 C48 100.99(7) . . ?
C77 Rh3 C48 175.24(7) . . ?
C73 Rh3 C48 96.00(7) . . ?
C45 Rh3 C48 75.45(6) . . ?
C78 Rh3 C47 163.86(7) . . ?
C74 Rh3 C47 98.06(7) . . ?
C77 Rh3 C47 139.32(7) . . ?
C73 Rh3 C47 115.65(7) . . ?
C45 Rh3 C47 65.84(6) . . ?
C48 Rh3 C47 36.01(6) . . ?
C78 Rh3 C46 128.00(7) . . ?
C74 Rh3 C46 121.75(7) . . ?
C77 Rh3 C46 111.14(7) . . ?
C73 Rh3 C46 151.28(7) . . ?
C45 Rh3 C46 36.59(6) . . ?
C48 Rh3 C46 64.39(6) . . ?
C47 Rh3 C46 36.70(6) . . ?
C78 Rh3 Sn2 95.21(6) . . ?
C74 Rh3 Sn2 140.71(5) . . ?
C77 Rh3 Sn2 128.55(6) . . ?
C73 Rh3 Sn2 108.88(5) . . ?
C45 Rh3 Sn2 53.91(5) . . ?
C48 Rh3 Sn2 53.18(5) . . ?
C47 Rh3 Sn2 77.32(5) . . ?
C46 Rh3 Sn2 77.09(5) . . ?
C74 C73 C80 125.14(18) . . ?
C74 C73 Rh3 70.91(11) . . ?
C80 C73 Rh3 114.26(12) . . ?
C74 C73 H73A 117.4 . . ?
C80 C73 H73A 117.4 . . ?
Rh3 C73 H73A 84.8 . . ?
C73 C74 C75 124.74(17) . . ?
C73 C74 Rh3 71.24(11) . . ?
C75 C74 Rh3 112.06(12) . . ?
C73 C74 H74A 117.6 . . ?
C75 C74 H74A 117.6 . . ?
Rh3 C74 H74A 86.7 . . ?
C74 C75 C76 111.79(16) . . ?
C74 C75 H75A 109.3 . . ?
C76 C75 H75A 109.3 . . ?
C74 C75 H75B 109.3 . . ?
C76 C75 H75B 109.3 . . ?
H75A C75 H75B 107.9 . . ?
C77 C76 C75 111.53(16) . . ?
C77 C76 H76A 109.3 . . ?
C75 C76 H76A 109.3 . . ?
C77 C76 H76B 109.3 . . ?
C75 C76 H76B 109.3 . . ?
H76A C76 H76B 108.0 . . ?
C78 C77 C76 124.21(18) . . ?
C78 C77 Rh3 69.92(11) . . ?
C76 C77 Rh3 114.80(13) . . ?
C78 C77 H77A 116.1(14) . . ?
C76 C77 H77A 114.2(14) . . ?
Rh3 C77 H77A 108.0(13) . . ?
C77 C78 C79 125.07(18) . . ?
C77 C78 Rh3 71.70(11) . . ?
C79 C78 Rh3 111.60(13) . . ?
C77 C78 H78A 116.4(13) . . ?
C79 C78 H78A 113.6(13) . . ?
Rh3 C78 H78A 108.8(13) . . ?
C78 C79 C80 112.20(16) . . ?
C78 C79 H79A 109.2 . . ?
C80 C79 H79A 109.2 . . ?
C78 C79 H79B 109.2 . . ?
C80 C79 H79B 109.2 . . ?
H79A C79 H79B 107.9 . . ?
C73 C80 C79 111.41(16) . . ?
C73 C80 H80A 109.3 . . ?
C79 C80 H80A 109.3 . . ?
C73 C80 H80B 109.3 . . ?
C79 C80 H80B 109.3 . . ?
H80A C80 H80B 108.0 . . ?
C81 Rh4 C85 88.22(8) . . ?
C81 Rh4 C88 38.11(8) . . ?
C85 Rh4 C88 80.20(8) . . ?
C81 Rh4 C84 79.60(8) . . ?
C85 Rh4 C84 37.80(7) . . ?
C88 Rh4 C84 95.68(8) . . ?
C81 Rh4 C46 166.86(7) . . ?
C85 Rh4 C46 102.70(7) . . ?
C88 Rh4 C46 150.34(7) . . ?
C84 Rh4 C46 104.50(7) . . ?
C81 Rh4 C47 129.55(7) . . ?
C85 Rh4 C47 122.66(7) . . ?
C88 Rh4 C47 156.67(7) . . ?
C84 Rh4 C47 100.71(7) . . ?
C46 Rh4 C47 37.81(6) . . ?
C81 Rh4 C48 102.78(7) . . ?
C85 Rh4 C48 156.65(7) . . ?
C88 Rh4 C48 120.98(7) . . ?
C84 Rh4 C48 123.39(7) . . ?
C46 Rh4 C48 64.42(6) . . ?
C47 Rh4 C48 35.69(6) . . ?
C81 Rh4 C45 145.87(7) . . ?
C85 Rh4 C45 111.45(7) . . ?
C88 Rh4 C45 115.67(7) . . ?
C84 Rh4 C45 132.92(7) . . ?
C46 Rh4 C45 35.45(6) . . ?
C47 Rh4 C45 63.26(6) . . ?
C48 Rh4 C45 70.20(6) . . ?
C81 Rh4 Sn2 96.59(6) . . ?
C85 Rh4 Sn2 147.78(5) . . ?
C88 Rh4 Sn2 84.14(6) . . ?
C84 Rh4 Sn2 173.68(5) . . ?
C46 Rh4 Sn2 78.13(5) . . ?
C47 Rh4 Sn2 77.75(5) . . ?
C48 Rh4 Sn2 52.28(4) . . ?
C45 Rh4 Sn2 51.95(4) . . ?
C88 C81 C82 122.73(18) . . ?
C88 C81 Rh4 71.56(11) . . ?
C82 C81 Rh4 115.56(14) . . ?
C88 C81 H81A 118.6 . . ?
C82 C81 H81A 118.6 . . ?
Rh4 C81 H81A 83.1 . . ?
C81 C82 C83 112.86(16) . . ?
C81 C82 H82A 109.0 . . ?
C83 C82 H82A 109.0 . . ?
C81 C82 H82B 109.0 . . ?
C83 C82 H82B 109.0 . . ?
H82A C82 H82B 107.8 . . ?
C84 C83 C82 112.55(17) . . ?
C84 C83 H83A 109.1 . . ?
C82 C83 H83A 109.1 . . ?
C84 C83 H83B 109.1 . . ?
C82 C83 H83B 109.1 . . ?
H83A C83 H83B 107.8 . . ?
C85 C84 C83 123.12(18) . . ?
C85 C84 Rh4 70.45(11) . . ?
C83 C84 Rh4 113.18(14) . . ?
C85 C84 H84A 118.4 . . ?
C83 C84 H84A 118.4 . . ?
Rh4 C84 H84A 86.4 . . ?
C84 C85 C86 121.73(18) . . ?
C84 C85 Rh4 71.75(11) . . ?
C86 C85 Rh4 114.17(14) . . ?
C84 C85 H85A 119.1 . . ?
C86 C85 H85A 119.1 . . ?
Rh4 C85 H85A 84.3 . . ?
C85 C86 C87 112.78(17) . . ?
C85 C86 H86A 109.0 . . ?
C87 C86 H86A 109.0 . . ?
C85 C86 H86B 109.0 . . ?
C87 C86 H86B 109.0 . . ?
H86A C86 H86B 107.8 . . ?
C88 C87 C86 112.50(17) . . ?
C88 C87 H87A 109.1 . . ?
C86 C87 H87A 109.1 . . ?
C88 C87 H87B 109.1 . . ?
C86 C87 H87B 109.1 . . ?
H87A C87 H87B 107.8 . . ?
C81 C88 C87 124.06(19) . . ?
C81 C88 Rh4 70.33(11) . . ?
C87 C88 Rh4 111.85(14) . . ?
C81 C88 H88A 118.0 . . ?
C87 C88 H88A 118.0 . . ?
Rh4 C88 H88A 87.8 . . ?
C91 C89 C90 119.6(2) 2_975 . ?
C91 C89 H89A 120.2 2_975 . ?
C90 C89 H89A 120.2 . . ?
C91 C90 C89 120.2(2) . . ?
C91 C90 H90A 119.9 . . ?
C89 C90 H90A 119.9 . . ?
C90 C91 C89 120.2(2) . 2_975 ?
C90 C91 H91A 119.9 . . ?
C89 C91 H91A 119.9 2_975 . ?

_diffrn_measured_fraction_theta_max 0.993
_diffrn_reflns_theta_full        26.50
_diffrn_measured_fraction_theta_full 0.993
_refine_diff_density_max         0.691
_refine_diff_density_min         -0.659
_refine_diff_density_rms         0.073
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_mm876
_database_code_depnum_ccdc_archive 'CCDC 1587997'
_audit_update_record             
;
2017-11-28 deposited with the CCDC.
2018-05-09 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         '2(C46 H67 Rh Ru Si2 Sn), C4 H10 O'
_chemical_formula_sum            'C96 H144 O Rh2 Ru2 Si4 Sn2'
_chemical_formula_weight         2071.85

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 21/n'
_symmetry_space_group_name_Hall  '-P 2yn'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   11.5013(16)
_cell_length_b                   33.864(5)
_cell_length_c                   11.9402(16)
_cell_angle_alpha                90.00
_cell_angle_beta                 104.666(2)
_cell_angle_gamma                90.00
_cell_volume                     4499.0(11)
_cell_formula_units_Z            2
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    6904
_cell_measurement_theta_min      2.28
_cell_measurement_theta_max      28.18

_exptl_crystal_description       cube
_exptl_crystal_colour            red
_exptl_crystal_size_max          0.06
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.04
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.529
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2124
_exptl_absorpt_coefficient_mu    1.331
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.938
_exptl_absorpt_correction_T_max  0.948
_exptl_absorpt_process_details   'XPREP; Bruker AXS 2008'

_exptl_special_details           
; 
'SADABS-2008/1 - Bruker AXS 2008'
;

_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'Bruker TXS fine-focus rotating anode'
_diffrn_radiation_monochromator  'Bruker Helios multilayer confocal mirror'
_diffrn_measurement_device_type  'Bruker APEXII CCD area-detector'
_diffrn_measurement_method       'φ and ω'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            24960
_diffrn_reflns_av_R_equivalents  0.0373
_diffrn_reflns_av_sigmaI/netI    0.0495
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -41
_diffrn_reflns_limit_k_max       43
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_theta_min         1.20
_diffrn_reflns_theta_max         27.00
_reflns_number_total             9828
_reflns_number_gt                7709
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEX2 (Bruker 2008)'
_computing_cell_refinement       'Bruker SAINT (Bruker 2008)'
_computing_data_reduction        'Bruker SAINT and XPREP (Bruker 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_molecular_graphics    'XSHEL (Bruker, 2002)'
_computing_publication_material  'XCIF (Bruker, 2001)'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0261P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    Constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         9828
_refine_ls_number_parameters     519
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0480
_refine_ls_R_factor_gt           0.0306
_refine_ls_wR_factor_ref         0.0635
_refine_ls_wR_factor_gt          0.0580
_refine_ls_goodness_of_fit_ref   1.002
_refine_ls_restrained_S_all      1.002
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Sn1 Sn 0.994260(18) 0.172180(6) 0.748266(17) 0.01628(5) Uani 1 1 d . . .
C1 C 0.9053(3) 0.11402(8) 0.7632(2) 0.0148(6) Uani 1 1 d . . .
C2 C 0.8059(3) 0.10429(8) 0.6659(2) 0.0157(6) Uani 1 1 d . . .
C3 C 0.7671(3) 0.13566(8) 0.5730(2) 0.0160(6) Uani 1 1 d . . .
C4 C 0.8383(3) 0.17089(8) 0.5877(2) 0.0163(6) Uani 1 1 d . . .
Rh1 Rh 0.96041(2) 0.115078(7) 0.576927(19) 0.01564(6) Uani 1 1 d . . .
C5 C 0.9914(3) 0.05665(9) 0.5189(3) 0.0226(7) Uani 1 1 d . . .
H5A H 0.9449 0.0360 0.5455 0.027 Uiso 1 1 calc R . .
C6 C 1.1228(3) 0.04584(10) 0.5326(3) 0.0295(8) Uani 1 1 d . . .
H6A H 1.1382 0.0436 0.4567 0.035 Uiso 1 1 calc R . .
H6B H 1.1387 0.0203 0.5704 0.035 Uiso 1 1 calc R . .
C7 C 1.2077(3) 0.07669(10) 0.6039(3) 0.0278(8) Uani 1 1 d . . .
H7A H 1.2321 0.0681 0.6839 0.033 Uiso 1 1 calc R . .
H7B H 1.2793 0.0785 0.5753 0.033 Uiso 1 1 calc R . .
C8 C 1.1508(3) 0.11690(9) 0.5987(3) 0.0237(7) Uani 1 1 d . . .
H8A H 1.1928 0.1349 0.6600 0.028 Uiso 1 1 calc R . .
C9 C 1.0920(3) 0.13613(10) 0.4947(3) 0.0237(7) Uani 1 1 d . . .
H9A H 1.1014 0.1649 0.4983 0.028 Uiso 1 1 calc R . .
C10 C 1.0882(3) 0.11899(10) 0.3759(3) 0.0319(8) Uani 1 1 d . . .
H10A H 1.1589 0.1028 0.3811 0.038 Uiso 1 1 calc R . .
H10B H 1.0900 0.1404 0.3223 0.038 Uiso 1 1 calc R . .
C11 C 0.9752(3) 0.09392(10) 0.3287(3) 0.0305(8) Uani 1 1 d . . .
H11A H 0.9146 0.1099 0.2769 0.037 Uiso 1 1 calc R . .
H11B H 0.9948 0.0720 0.2845 0.037 Uiso 1 1 calc R . .
C12 C 0.9251(3) 0.07817(9) 0.4246(2) 0.0235(7) Uani 1 1 d . . .
H12A H 0.8411 0.0697 0.3985 0.028 Uiso 1 1 calc R . .
C13 C 0.7488(3) 0.19872(10) 0.8871(3) 0.0278(8) Uani 1 1 d . . .
C14 C 0.7001(3) 0.16130(9) 0.9058(3) 0.0206(7) Uani 1 1 d . . .
C15 C 0.5964(3) 0.15447(9) 0.8147(3) 0.0211(7) Uani 1 1 d . . .
C16 C 0.5802(3) 0.18748(10) 0.7386(3) 0.0263(7) Uani 1 1 d . . .
C17 C 0.6724(3) 0.21496(9) 0.7845(3) 0.0301(8) Uani 1 1 d . . .
Si1 Si 0.98409(8) 0.07716(2) 0.87786(7) 0.01996(19) Uani 1 1 d . . .
C18 C 0.9003(3) 0.05564(10) 0.9806(3) 0.0307(8) Uani 1 1 d . . .
H18A H 0.8239 0.0457 0.9373 0.046 Uiso 1 1 calc R . .
H18B H 0.8880 0.0758 1.0331 0.046 Uiso 1 1 calc R . .
H18C H 0.9464 0.0345 1.0237 0.046 Uiso 1 1 calc R . .
C19 C 1.0265(3) 0.03314(9) 0.8022(3) 0.0277(7) Uani 1 1 d . . .
H19A H 1.0731 0.0152 0.8583 0.042 Uiso 1 1 calc R . .
H19B H 1.0731 0.0415 0.7502 0.042 Uiso 1 1 calc R . .
H19C H 0.9550 0.0201 0.7592 0.042 Uiso 1 1 calc R . .
C20 C 1.1286(3) 0.09714(9) 0.9819(3) 0.0245(7) Uani 1 1 d . . .
C21 C 1.1050(3) 0.13411(10) 1.0468(3) 0.0326(8) Uani 1 1 d . . .
H21A H 1.1784 0.1424 1.1000 0.049 Uiso 1 1 calc R . .
H21B H 1.0462 0.1282 1.0889 0.049 Uiso 1 1 calc R . .
H21C H 1.0757 0.1549 0.9924 0.049 Uiso 1 1 calc R . .
C22 C 1.2281(3) 0.10628(10) 0.9216(3) 0.0309(8) Uani 1 1 d . . .
H22A H 1.2018 0.1269 0.8656 0.046 Uiso 1 1 calc R . .
H22B H 1.2460 0.0830 0.8834 0.046 Uiso 1 1 calc R . .
H22C H 1.2989 0.1148 0.9780 0.046 Uiso 1 1 calc R . .
C23 C 1.1784(3) 0.06489(10) 1.0728(3) 0.0380(9) Uani 1 1 d . . .
H23A H 1.1830 0.0403 1.0343 0.057 Uiso 1 1 calc R . .
H23B H 1.1260 0.0620 1.1234 0.057 Uiso 1 1 calc R . .
H23C H 1.2572 0.0723 1.1172 0.057 Uiso 1 1 calc R . .
C24 C 0.7350(3) 0.06646(8) 0.6588(2) 0.0168(6) Uani 1 1 d . . .
C25 C 0.6873(3) 0.05671(9) 0.7510(3) 0.0226(7) Uani 1 1 d . . .
H25A H 0.6964 0.0742 0.8126 0.027 Uiso 1 1 calc R . .
C26 C 0.6263(3) 0.02146(10) 0.7534(3) 0.0345(9) Uani 1 1 d . . .
H26A H 0.5971 0.0153 0.8171 0.041 Uiso 1 1 calc R . .
C27 C 0.6093(3) -0.00428(10) 0.6619(3) 0.0338(8) Uani 1 1 d . . .
H27A H 0.5688 -0.0280 0.6631 0.041 Uiso 1 1 calc R . .
C28 C 0.6530(3) 0.00550(10) 0.5679(3) 0.0297(8) Uani 1 1 d . . .
H28A H 0.6406 -0.0116 0.5051 0.036 Uiso 1 1 calc R . .
C29 C 0.7151(3) 0.04043(9) 0.5659(3) 0.0220(7) Uani 1 1 d . . .
H29A H 0.7437 0.0465 0.5018 0.026 Uiso 1 1 calc R . .
C30 C 0.6575(3) 0.12822(8) 0.4757(2) 0.0175(6) Uani 1 1 d . . .
C31 C 0.5467(3) 0.12255(9) 0.4984(3) 0.0268(7) Uani 1 1 d . . .
H31A H 0.5415 0.1212 0.5748 0.032 Uiso 1 1 calc R . .
C32 C 0.4431(3) 0.11878(11) 0.4094(3) 0.0411(9) Uani 1 1 d . . .
H32A H 0.3692 0.1156 0.4265 0.049 Uiso 1 1 calc R . .
C33 C 0.4496(3) 0.11979(11) 0.2962(3) 0.0412(10) Uani 1 1 d . . .
H33A H 0.3800 0.1176 0.2365 0.049 Uiso 1 1 calc R . .
C34 C 0.5582(3) 0.12408(10) 0.2715(3) 0.0342(8) Uani 1 1 d . . .
H34A H 0.5629 0.1243 0.1949 0.041 Uiso 1 1 calc R . .
C35 C 0.6618(3) 0.12819(9) 0.3601(3) 0.0256(7) Uani 1 1 d . . .
H35A H 0.7355 0.1310 0.3422 0.031 Uiso 1 1 calc R . .
Si2 Si 0.81934(8) 0.21333(3) 0.48101(7) 0.02044(19) Uani 1 1 d . . .
C36 C 0.6609(3) 0.23120(10) 0.4406(3) 0.0318(8) Uani 1 1 d . . .
H36A H 0.6073 0.2090 0.4319 0.048 Uiso 1 1 calc R . .
H36B H 0.6462 0.2455 0.3689 0.048 Uiso 1 1 calc R . .
H36C H 0.6475 0.2483 0.5003 0.048 Uiso 1 1 calc R . .
C37 C 0.8555(3) 0.19854(11) 0.3401(3) 0.0338(8) Uani 1 1 d . . .
H37A H 0.7826 0.1917 0.2840 0.051 Uiso 1 1 calc R . .
H37B H 0.9086 0.1762 0.3535 0.051 Uiso 1 1 calc R . .
H37C H 0.8935 0.2202 0.3117 0.051 Uiso 1 1 calc R . .
C38 C 0.9246(3) 0.25752(9) 0.5328(3) 0.0269(7) Uani 1 1 d . . .
C39 C 0.9132(3) 0.27559(10) 0.6477(3) 0.0358(9) Uani 1 1 d . . .
H39A H 0.9225 0.2552 0.7052 0.054 Uiso 1 1 calc R . .
H39B H 0.8355 0.2876 0.6367 0.054 Uiso 1 1 calc R . .
H39C H 0.9744 0.2952 0.6728 0.054 Uiso 1 1 calc R . .
C40 C 0.8889(3) 0.29040(10) 0.4414(3) 0.0405(9) Uani 1 1 d . . .
H40A H 0.9384 0.3132 0.4660 0.061 Uiso 1 1 calc R . .
H40B H 0.8061 0.2973 0.4325 0.061 Uiso 1 1 calc R . .
H40C H 0.8999 0.2812 0.3687 0.061 Uiso 1 1 calc R . .
C41 C 1.0569(3) 0.24772(10) 0.5445(3) 0.0341(8) Uani 1 1 d . . .
H41A H 1.0660 0.2368 0.4730 0.051 Uiso 1 1 calc R . .
H41B H 1.0836 0.2288 0.6055 0.051 Uiso 1 1 calc R . .
H41C H 1.1041 0.2714 0.5622 0.051 Uiso 1 1 calc R . .
C42 C 0.8482(3) 0.21963(12) 0.9708(3) 0.0487(11) Uani 1 1 d . . .
H42A H 0.8158 0.2346 1.0242 0.073 Uiso 1 1 calc R . .
H42B H 0.8882 0.2371 0.9294 0.073 Uiso 1 1 calc R . .
H42C H 0.9047 0.2006 1.0127 0.073 Uiso 1 1 calc R . .
C43 C 0.7389(3) 0.13829(12) 1.0163(3) 0.0386(9) Uani 1 1 d . . .
H43A H 0.7052 0.1500 1.0742 0.058 Uiso 1 1 calc R . .
H43B H 0.8250 0.1386 1.0424 0.058 Uiso 1 1 calc R . .
H43C H 0.7114 0.1115 1.0031 0.058 Uiso 1 1 calc R . .
C44 C 0.5047(3) 0.12236(10) 0.8092(3) 0.0303(8) Uani 1 1 d . . .
H44A H 0.5345 0.1036 0.8699 0.045 Uiso 1 1 calc R . .
H44B H 0.4898 0.1093 0.7355 0.045 Uiso 1 1 calc R . .
H44C H 0.4313 0.1337 0.8186 0.045 Uiso 1 1 calc R . .
C45 C 0.4699(3) 0.19594(12) 0.6423(3) 0.0443(10) Uani 1 1 d . . .
H45A H 0.4249 0.2170 0.6653 0.066 Uiso 1 1 calc R . .
H45B H 0.4208 0.1727 0.6264 0.066 Uiso 1 1 calc R . .
H45C H 0.4937 0.2036 0.5740 0.066 Uiso 1 1 calc R . .
C46 C 0.6704(4) 0.25776(10) 0.7506(4) 0.0578(13) Uani 1 1 d . . .
H46A H 0.6491 0.2599 0.6677 0.087 Uiso 1 1 calc R . .
H46B H 0.7485 0.2691 0.7813 0.087 Uiso 1 1 calc R . .
H46C H 0.6124 0.2716 0.7811 0.087 Uiso 1 1 calc R . .
C47 C 0.6559(19) 0.0198(7) 0.160(2) 0.057(6) Uani 0.50 1 d P A 2
H47A H 0.6370 -0.0019 0.2040 0.086 Uiso 0.50 1 calc PR A 2
H47B H 0.6827 0.0419 0.2104 0.086 Uiso 0.50 1 calc PR A 2
H47C H 0.7183 0.0121 0.1242 0.086 Uiso 0.50 1 calc PR A 2
C48 C 0.5464(8) 0.0313(2) 0.0686(8) 0.047(2) Uani 0.50 1 d P A 2
H48A H 0.4861 0.0415 0.1050 0.057 Uiso 0.50 1 calc PR A 2
H48B H 0.5668 0.0521 0.0212 0.057 Uiso 0.50 1 calc PR A 2
O1 O 0.5000 0.0000 0.0000 0.0438(9) Uani 1 2 d S . .
C49 C 0.645(2) 0.0320(7) 0.156(2) 0.070(8) Uani 0.50 1 d P A 1
H49A H 0.6515 0.0533 0.1048 0.105 Uiso 0.50 1 calc PR A 1
H49B H 0.7223 0.0276 0.2089 0.105 Uiso 0.50 1 calc PR A 1
H49C H 0.5876 0.0386 0.1984 0.105 Uiso 0.50 1 calc PR A 1
C50 C 0.6047(9) -0.0060(3) 0.0841(9) 0.054(2) Uani 0.50 1 d P A 1
H50A H 0.6674 -0.0143 0.0481 0.065 Uiso 0.50 1 calc PR A 1
H50B H 0.5927 -0.0270 0.1353 0.065 Uiso 0.50 1 calc PR A 1
Ru1 Ru 0.75893(2) 0.160266(7) 0.74258(2) 0.01511(6) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sn1 C1 2.247(3) . ?
Sn1 C4 2.270(3) . ?
Sn1 Ru1 2.7203(5) . ?
Sn1 Rh1 2.7700(4) . ?
C1 C2 1.447(4) . ?
C1 Si1 1.904(3) . ?
C1 Ru1 2.267(3) . ?
C1 Rh1 2.463(3) . ?
C2 C24 1.509(4) . ?
C2 C3 1.519(4) . ?
C2 Ru1 2.230(3) . ?
C2 Rh1 2.319(3) . ?
C3 C4 1.432(4) . ?
C3 C30 1.504(4) . ?
C3 Ru1 2.213(3) . ?
C3 Rh1 2.319(3) . ?
C4 Si2 1.896(3) . ?
C4 Ru1 2.288(3) . ?
C4 Rh1 2.378(3) . ?
Rh1 C9 2.125(3) . ?
Rh1 C8 2.139(3) . ?
Rh1 C5 2.156(3) . ?
Rh1 C12 2.159(3) . ?
C5 C12 1.395(4) . ?
C5 C6 1.522(4) . ?
C5 H5A 0.9800 . ?
C6 C7 1.532(4) . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 C8 1.505(4) . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C8 C9 1.413(4) . ?
C8 H8A 0.9800 . ?
C9 C10 1.524(4) . ?
C9 H9A 0.9800 . ?
C10 C11 1.535(5) . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C11 C12 1.504(4) . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C12 H12A 0.9800 . ?
C13 C17 1.425(5) . ?
C13 C14 1.426(4) . ?
C13 C42 1.493(5) . ?
C13 Ru1 2.188(3) . ?
C14 C15 1.415(4) . ?
C14 C43 1.499(4) . ?
C14 Ru1 2.220(3) . ?
C15 C16 1.422(4) . ?
C15 C44 1.505(4) . ?
C15 Ru1 2.256(3) . ?
C16 C17 1.413(5) . ?
C16 C45 1.509(5) . ?
C16 Ru1 2.242(3) . ?
C17 C46 1.504(5) . ?
C17 Ru1 2.219(3) . ?
Si1 C19 1.871(3) . ?
Si1 C18 1.888(3) . ?
Si1 C20 1.928(3) . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C19 H19A 0.9600 . ?
C19 H19B 0.9600 . ?
C19 H19C 0.9600 . ?
C20 C22 1.530(4) . ?
C20 C21 1.533(4) . ?
C20 C23 1.544(4) . ?
C21 H21A 0.9600 . ?
C21 H21B 0.9600 . ?
C21 H21C 0.9600 . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?
C23 H23A 0.9600 . ?
C23 H23B 0.9600 . ?
C23 H23C 0.9600 . ?
C24 C25 1.388(4) . ?
C24 C29 1.390(4) . ?
C25 C26 1.388(4) . ?
C25 H25A 0.9300 . ?
C26 C27 1.373(5) . ?
C26 H26A 0.9300 . ?
C27 C28 1.381(5) . ?
C27 H27A 0.9300 . ?
C28 C29 1.385(4) . ?
C28 H28A 0.9300 . ?
C29 H29A 0.9300 . ?
C30 C31 1.382(4) . ?
C30 C35 1.394(4) . ?
C31 C32 1.387(5) . ?
C31 H31A 0.9300 . ?
C32 C33 1.373(5) . ?
C32 H32A 0.9300 . ?
C33 C34 1.362(5) . ?
C33 H33A 0.9300 . ?
C34 C35 1.386(4) . ?
C34 H34A 0.9300 . ?
C35 H35A 0.9300 . ?
Si2 C36 1.864(3) . ?
Si2 C37 1.899(3) . ?
Si2 C38 1.926(3) . ?
C36 H36A 0.9600 . ?
C36 H36B 0.9600 . ?
C36 H36C 0.9600 . ?
C37 H37A 0.9600 . ?
C37 H37B 0.9600 . ?
C37 H37C 0.9600 . ?
C38 C41 1.529(5) . ?
C38 C39 1.538(4) . ?
C38 C40 1.540(4) . ?
C39 H39A 0.9600 . ?
C39 H39B 0.9600 . ?
C39 H39C 0.9600 . ?
C40 H40A 0.9600 . ?
C40 H40B 0.9600 . ?
C40 H40C 0.9600 . ?
C41 H41A 0.9600 . ?
C41 H41B 0.9600 . ?
C41 H41C 0.9600 . ?
C42 H42A 0.9600 . ?
C42 H42B 0.9600 . ?
C42 H42C 0.9600 . ?
C43 H43A 0.9600 . ?
C43 H43B 0.9600 . ?
C43 H43C 0.9600 . ?
C44 H44A 0.9600 . ?
C44 H44B 0.9600 . ?
C44 H44C 0.9600 . ?
C45 H45A 0.9600 . ?
C45 H45B 0.9600 . ?
C45 H45C 0.9600 . ?
C46 H46A 0.9600 . ?
C46 H46B 0.9600 . ?
C46 H46C 0.9600 . ?
C47 C48 1.49(3) . ?
C47 H47A 0.9600 . ?
C47 H47B 0.9600 . ?
C47 H47C 0.9600 . ?
C48 O1 1.363(9) . ?
C48 H48A 0.9700 . ?
C48 H48B 0.9700 . ?
O1 C48 1.363(9) 3_655 ?
O1 C50 1.374(10) 3_655 ?
O1 C50 1.374(10) . ?
C49 C50 1.55(3) . ?
C49 H49A 0.9600 . ?
C49 H49B 0.9600 . ?
C49 H49C 0.9600 . ?
C50 H50A 0.9700 . ?
C50 H50B 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Sn1 C4 76.82(10) . . ?
C1 Sn1 Ru1 53.27(7) . . ?
C4 Sn1 Ru1 53.67(7) . . ?
C1 Sn1 Rh1 57.67(7) . . ?
C4 Sn1 Rh1 55.23(7) . . ?
Ru1 Sn1 Rh1 85.707(9) . . ?
C2 C1 Si1 124.3(2) . . ?
C2 C1 Sn1 114.77(18) . . ?
Si1 C1 Sn1 119.25(14) . . ?
C2 C1 Ru1 69.85(16) . . ?
Si1 C1 Ru1 137.42(13) . . ?
Sn1 C1 Ru1 74.11(9) . . ?
C2 C1 Rh1 67.04(14) . . ?
Si1 C1 Rh1 118.34(13) . . ?
Sn1 C1 Rh1 71.89(7) . . ?
Ru1 C1 Rh1 104.22(10) . . ?
C1 C2 C24 123.0(2) . . ?
C1 C2 C3 116.9(2) . . ?
C24 C2 C3 119.9(2) . . ?
C1 C2 Ru1 72.62(15) . . ?
C24 C2 Ru1 124.12(19) . . ?
C3 C2 Ru1 69.42(15) . . ?
C1 C2 Rh1 77.89(16) . . ?
C24 C2 Rh1 125.02(19) . . ?
C3 C2 Rh1 70.87(14) . . ?
Ru1 C2 Rh1 110.33(12) . . ?
C4 C3 C30 125.1(2) . . ?
C4 C3 C2 116.1(2) . . ?
C30 C3 C2 118.7(2) . . ?
C4 C3 Ru1 74.32(16) . . ?
C30 C3 Ru1 123.23(19) . . ?
C2 C3 Ru1 70.60(14) . . ?
C4 C3 Rh1 74.51(16) . . ?
C30 C3 Rh1 125.27(19) . . ?
C2 C3 Rh1 70.89(15) . . ?
Ru1 C3 Rh1 110.94(12) . . ?
C3 C4 Si2 125.8(2) . . ?
C3 C4 Sn1 115.10(19) . . ?
Si2 C4 Sn1 118.98(14) . . ?
C3 C4 Ru1 68.63(15) . . ?
Si2 C4 Ru1 131.35(14) . . ?
Sn1 C4 Ru1 73.27(8) . . ?
C3 C4 Rh1 70.01(16) . . ?
Si2 C4 Rh1 122.34(13) . . ?
Sn1 C4 Rh1 73.11(8) . . ?
Ru1 C4 Rh1 106.30(11) . . ?
C9 Rh1 C8 38.72(11) . . ?
C9 Rh1 C5 87.96(12) . . ?
C8 Rh1 C5 79.52(12) . . ?
C9 Rh1 C12 79.01(12) . . ?
C8 Rh1 C12 95.04(12) . . ?
C5 Rh1 C12 37.73(11) . . ?
C9 Rh1 C3 132.94(11) . . ?
C8 Rh1 C3 160.08(11) . . ?
C5 Rh1 C3 120.34(11) . . ?
C12 Rh1 C3 100.48(11) . . ?
C9 Rh1 C2 169.34(11) . . ?
C8 Rh1 C2 145.92(11) . . ?
C5 Rh1 C2 102.18(11) . . ?
C12 Rh1 C2 106.98(11) . . ?
C3 Rh1 C2 38.24(9) . . ?
C9 Rh1 C4 104.95(11) . . ?
C8 Rh1 C4 124.82(11) . . ?
C5 Rh1 C4 153.51(11) . . ?
C12 Rh1 C4 121.19(11) . . ?
C3 Rh1 C4 35.48(10) . . ?
C2 Rh1 C4 64.44(10) . . ?
C9 Rh1 C1 142.98(11) . . ?
C8 Rh1 C1 112.33(11) . . ?
C5 Rh1 C1 112.23(10) . . ?
C12 Rh1 C1 135.71(11) . . ?
C3 Rh1 C1 63.77(9) . . ?
C2 Rh1 C1 35.07(9) . . ?
C4 Rh1 C1 70.86(9) . . ?
C9 Rh1 Sn1 97.10(8) . . ?
C8 Rh1 Sn1 86.67(8) . . ?
C5 Rh1 Sn1 150.97(8) . . ?
C12 Rh1 Sn1 170.97(9) . . ?
C3 Rh1 Sn1 76.10(7) . . ?
C2 Rh1 Sn1 75.66(7) . . ?
C4 Rh1 Sn1 51.66(7) . . ?
C1 Rh1 Sn1 50.45(6) . . ?
C12 C5 C6 122.5(3) . . ?
C12 C5 Rh1 71.25(17) . . ?
C6 C5 Rh1 115.2(2) . . ?
C12 C5 H5A 113.7 . . ?
C6 C5 H5A 113.7 . . ?
Rh1 C5 H5A 113.7 . . ?
C5 C6 C7 111.8(3) . . ?
C5 C6 H6A 109.3 . . ?
C7 C6 H6A 109.3 . . ?
C5 C6 H6B 109.3 . . ?
C7 C6 H6B 109.3 . . ?
H6A C6 H6B 107.9 . . ?
C8 C7 C6 112.6(3) . . ?
C8 C7 H7A 109.1 . . ?
C6 C7 H7A 109.1 . . ?
C8 C7 H7B 109.1 . . ?
C6 C7 H7B 109.1 . . ?
H7A C7 H7B 107.8 . . ?
C9 C8 C7 124.0(3) . . ?
C9 C8 Rh1 70.08(17) . . ?
C7 C8 Rh1 113.6(2) . . ?
C9 C8 H8A 113.9 . . ?
C7 C8 H8A 113.9 . . ?
Rh1 C8 H8A 113.9 . . ?
C8 C9 C10 122.5(3) . . ?
C8 C9 Rh1 71.20(16) . . ?
C10 C9 Rh1 116.5(2) . . ?
C8 C9 H9A 113.4 . . ?
C10 C9 H9A 113.4 . . ?
Rh1 C9 H9A 113.4 . . ?
C9 C10 C11 112.0(3) . . ?
C9 C10 H10A 109.2 . . ?
C11 C10 H10A 109.2 . . ?
C9 C10 H10B 109.2 . . ?
C11 C10 H10B 109.2 . . ?
H10A C10 H10B 107.9 . . ?
C12 C11 C10 111.6(3) . . ?
C12 C11 H11A 109.3 . . ?
C10 C11 H11A 109.3 . . ?
C12 C11 H11B 109.3 . . ?
C10 C11 H11B 109.3 . . ?
H11A C11 H11B 108.0 . . ?
C5 C12 C11 124.2(3) . . ?
C5 C12 Rh1 71.02(16) . . ?
C11 C12 Rh1 114.2(2) . . ?
C5 C12 H12A 113.5 . . ?
C11 C12 H12A 113.5 . . ?
Rh1 C12 H12A 113.5 . . ?
C17 C13 C14 107.3(3) . . ?
C17 C13 C42 126.4(3) . . ?
C14 C13 C42 125.5(3) . . ?
C17 C13 Ru1 72.30(18) . . ?
C14 C13 Ru1 72.34(17) . . ?
C42 C13 Ru1 128.7(2) . . ?
C15 C14 C13 108.2(3) . . ?
C15 C14 C43 126.7(3) . . ?
C13 C14 C43 123.9(3) . . ?
C15 C14 Ru1 72.94(16) . . ?
C13 C14 Ru1 69.93(16) . . ?
C43 C14 Ru1 132.5(2) . . ?
C14 C15 C16 108.1(3) . . ?
C14 C15 C44 126.6(3) . . ?
C16 C15 C44 124.3(3) . . ?
C14 C15 Ru1 70.19(16) . . ?
C16 C15 Ru1 71.06(16) . . ?
C44 C15 Ru1 133.3(2) . . ?
C17 C16 C15 107.8(3) . . ?
C17 C16 C45 125.0(3) . . ?
C15 C16 C45 125.8(3) . . ?
C17 C16 Ru1 70.63(19) . . ?
C15 C16 Ru1 72.08(17) . . ?
C45 C16 Ru1 133.1(2) . . ?
C16 C17 C13 108.5(3) . . ?
C16 C17 C46 124.9(4) . . ?
C13 C17 C46 124.6(4) . . ?
C16 C17 Ru1 72.45(18) . . ?
C13 C17 Ru1 69.97(18) . . ?
C46 C17 Ru1 136.1(2) . . ?
C19 Si1 C18 104.17(15) . . ?
C19 Si1 C1 108.05(13) . . ?
C18 Si1 C1 119.48(14) . . ?
C19 Si1 C20 107.66(15) . . ?
C18 Si1 C20 102.44(14) . . ?
C1 Si1 C20 114.12(13) . . ?
Si1 C18 H18A 109.5 . . ?
Si1 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
Si1 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
Si1 C19 H19A 109.5 . . ?
Si1 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
Si1 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C22 C20 C21 108.8(3) . . ?
C22 C20 C23 106.6(3) . . ?
C21 C20 C23 107.7(3) . . ?
C22 C20 Si1 113.2(2) . . ?
C21 C20 Si1 112.3(2) . . ?
C23 C20 Si1 108.1(2) . . ?
C20 C21 H21A 109.5 . . ?
C20 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
C20 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C20 C22 H22A 109.5 . . ?
C20 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C20 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C20 C23 H23A 109.5 . . ?
C20 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C20 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C25 C24 C29 117.6(3) . . ?
C25 C24 C2 118.3(3) . . ?
C29 C24 C2 124.1(2) . . ?
C24 C25 C26 121.6(3) . . ?
C24 C25 H25A 119.2 . . ?
C26 C25 H25A 119.2 . . ?
C27 C26 C25 120.0(3) . . ?
C27 C26 H26A 120.0 . . ?
C25 C26 H26A 120.0 . . ?
C26 C27 C28 119.1(3) . . ?
C26 C27 H27A 120.4 . . ?
C28 C27 H27A 120.4 . . ?
C27 C28 C29 120.9(3) . . ?
C27 C28 H28A 119.5 . . ?
C29 C28 H28A 119.5 . . ?
C28 C29 C24 120.6(3) . . ?
C28 C29 H29A 119.7 . . ?
C24 C29 H29A 119.7 . . ?
C31 C30 C35 117.4(3) . . ?
C31 C30 C3 120.4(3) . . ?
C35 C30 C3 122.1(3) . . ?
C30 C31 C32 121.2(3) . . ?
C30 C31 H31A 119.4 . . ?
C32 C31 H31A 119.4 . . ?
C33 C32 C31 120.2(4) . . ?
C33 C32 H32A 119.9 . . ?
C31 C32 H32A 119.9 . . ?
C34 C33 C32 119.8(3) . . ?
C34 C33 H33A 120.1 . . ?
C32 C33 H33A 120.1 . . ?
C33 C34 C35 120.3(3) . . ?
C33 C34 H34A 119.9 . . ?
C35 C34 H34A 119.9 . . ?
C34 C35 C30 121.1(3) . . ?
C34 C35 H35A 119.4 . . ?
C30 C35 H35A 119.4 . . ?
C36 Si2 C4 110.99(14) . . ?
C36 Si2 C37 105.99(16) . . ?
C4 Si2 C37 112.43(14) . . ?
C36 Si2 C38 108.94(16) . . ?
C4 Si2 C38 114.67(14) . . ?
C37 Si2 C38 103.23(15) . . ?
Si2 C36 H36A 109.5 . . ?
Si2 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
Si2 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
Si2 C37 H37A 109.5 . . ?
Si2 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
Si2 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
C41 C38 C39 108.2(3) . . ?
C41 C38 C40 107.6(3) . . ?
C39 C38 C40 106.1(3) . . ?
C41 C38 Si2 113.0(2) . . ?
C39 C38 Si2 114.0(2) . . ?
C40 C38 Si2 107.5(2) . . ?
C38 C39 H39A 109.5 . . ?
C38 C39 H39B 109.5 . . ?
H39A C39 H39B 109.5 . . ?
C38 C39 H39C 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
C38 C40 H40A 109.5 . . ?
C38 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
C38 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
C38 C41 H41A 109.5 . . ?
C38 C41 H41B 109.5 . . ?
H41A C41 H41B 109.5 . . ?
C38 C41 H41C 109.5 . . ?
H41A C41 H41C 109.5 . . ?
H41B C41 H41C 109.5 . . ?
C13 C42 H42A 109.5 . . ?
C13 C42 H42B 109.5 . . ?
H42A C42 H42B 109.5 . . ?
C13 C42 H42C 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
C14 C43 H43A 109.5 . . ?
C14 C43 H43B 109.5 . . ?
H43A C43 H43B 109.5 . . ?
C14 C43 H43C 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
C15 C44 H44A 109.5 . . ?
C15 C44 H44B 109.5 . . ?
H44A C44 H44B 109.5 . . ?
C15 C44 H44C 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
C16 C45 H45A 109.5 . . ?
C16 C45 H45B 109.5 . . ?
H45A C45 H45B 109.5 . . ?
C16 C45 H45C 109.5 . . ?
H45A C45 H45C 109.5 . . ?
H45B C45 H45C 109.5 . . ?
C17 C46 H46A 109.5 . . ?
C17 C46 H46B 109.5 . . ?
H46A C46 H46B 109.5 . . ?
C17 C46 H46C 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
C48 C47 H47A 109.5 . . ?
C48 C47 H47B 109.5 . . ?
H47A C47 H47B 109.5 . . ?
C48 C47 H47C 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
O1 C48 C47 111.4(11) . . ?
O1 C48 H48A 109.3 . . ?
C47 C48 H48A 109.3 . . ?
O1 C48 H48B 109.3 . . ?
C47 C48 H48B 109.3 . . ?
H48A C48 H48B 108.0 . . ?
C48 O1 C48 180.0(9) . 3_655 ?
C48 O1 C50 117.5(5) . 3_655 ?
C48 O1 C50 62.5(5) 3_655 3_655 ?
C48 O1 C50 62.5(5) . . ?
C48 O1 C50 117.5(5) 3_655 . ?
C50 O1 C50 180.0(12) 3_655 . ?
O1 C50 C49 111.5(12) . . ?
O1 C50 H50A 109.3 . . ?
C49 C50 H50A 109.3 . . ?
O1 C50 H50B 109.3 . . ?
C49 C50 H50B 109.3 . . ?
H50A C50 H50B 108.0 . . ?
C13 Ru1 C3 165.57(12) . . ?
C13 Ru1 C17 37.73(12) . . ?
C3 Ru1 C17 130.23(12) . . ?
C13 Ru1 C14 37.73(11) . . ?
C3 Ru1 C14 154.46(11) . . ?
C17 Ru1 C14 62.29(11) . . ?
C13 Ru1 C2 153.67(12) . . ?
C3 Ru1 C2 39.98(10) . . ?
C17 Ru1 C2 166.20(12) . . ?
C14 Ru1 C2 122.22(10) . . ?
C13 Ru1 C16 62.64(12) . . ?
C3 Ru1 C16 112.74(11) . . ?
C17 Ru1 C16 36.92(12) . . ?
C14 Ru1 C16 61.99(11) . . ?
C2 Ru1 C16 131.04(12) . . ?
C13 Ru1 C15 62.36(11) . . ?
C3 Ru1 C15 123.20(11) . . ?
C17 Ru1 C15 61.60(11) . . ?
C14 Ru1 C15 36.86(11) . . ?
C2 Ru1 C15 113.13(11) . . ?
C16 Ru1 C15 36.86(11) . . ?
C13 Ru1 C1 120.78(12) . . ?
C3 Ru1 C1 68.70(10) . . ?
C17 Ru1 C1 156.27(12) . . ?
C14 Ru1 C1 107.38(10) . . ?
C2 Ru1 C1 37.53(10) . . ?
C16 Ru1 C1 159.72(11) . . ?
C15 Ru1 C1 124.26(10) . . ?
C13 Ru1 C4 130.96(11) . . ?
C3 Ru1 C4 37.05(10) . . ?
C17 Ru1 C4 110.14(11) . . ?
C14 Ru1 C4 168.48(11) . . ?
C2 Ru1 C4 67.32(10) . . ?
C16 Ru1 C4 117.99(11) . . ?
C15 Ru1 C4 149.37(11) . . ?
C1 Ru1 C4 76.07(10) . . ?
C13 Ru1 Sn1 98.25(8) . . ?
C3 Ru1 Sn1 78.82(7) . . ?
C17 Ru1 Sn1 111.76(9) . . ?
C14 Ru1 Sn1 119.90(8) . . ?
C2 Ru1 Sn1 78.09(7) . . ?
C16 Ru1 Sn1 147.20(9) . . ?
C15 Ru1 Sn1 156.75(8) . . ?
C1 Ru1 Sn1 52.61(7) . . ?
C4 Ru1 Sn1 53.07(7) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C4 Sn1 C1 C2 4.05(19) . . . . ?
Ru1 Sn1 C1 C2 58.28(18) . . . . ?
Rh1 Sn1 C1 C2 -52.92(17) . . . . ?
C4 Sn1 C1 Si1 169.88(16) . . . . ?
Ru1 Sn1 C1 Si1 -135.89(17) . . . . ?
Rh1 Sn1 C1 Si1 112.90(15) . . . . ?
C4 Sn1 C1 Ru1 -54.23(8) . . . . ?
Rh1 Sn1 C1 Ru1 -111.21(8) . . . . ?
C4 Sn1 C1 Rh1 56.97(8) . . . . ?
Ru1 Sn1 C1 Rh1 111.21(8) . . . . ?
Si1 C1 C2 C24 14.5(4) . . . . ?
Sn1 C1 C2 C24 179.5(2) . . . . ?
Ru1 C1 C2 C24 -119.8(3) . . . . ?
Rh1 C1 C2 C24 124.1(3) . . . . ?
Si1 C1 C2 C3 -170.56(19) . . . . ?
Sn1 C1 C2 C3 -5.5(3) . . . . ?
Ru1 C1 C2 C3 55.1(2) . . . . ?
Rh1 C1 C2 C3 -61.0(2) . . . . ?
Si1 C1 C2 Ru1 134.4(2) . . . . ?
Sn1 C1 C2 Ru1 -60.63(14) . . . . ?
Rh1 C1 C2 Ru1 -116.07(9) . . . . ?
Si1 C1 C2 Rh1 -109.58(19) . . . . ?
Sn1 C1 C2 Rh1 55.44(14) . . . . ?
Ru1 C1 C2 Rh1 116.07(9) . . . . ?
C1 C2 C3 C4 3.8(4) . . . . ?
C24 C2 C3 C4 178.9(2) . . . . ?
Ru1 C2 C3 C4 60.5(2) . . . . ?
Rh1 C2 C3 C4 -61.0(2) . . . . ?
C1 C2 C3 C30 -174.7(2) . . . . ?
C24 C2 C3 C30 0.4(4) . . . . ?
Ru1 C2 C3 C30 -118.0(2) . . . . ?
Rh1 C2 C3 C30 120.5(2) . . . . ?
C1 C2 C3 Ru1 -56.7(2) . . . . ?
C24 C2 C3 Ru1 118.4(2) . . . . ?
Rh1 C2 C3 Ru1 -121.53(10) . . . . ?
C1 C2 C3 Rh1 64.8(2) . . . . ?
C24 C2 C3 Rh1 -120.1(2) . . . . ?
Ru1 C2 C3 Rh1 121.53(10) . . . . ?
C30 C3 C4 Si2 -6.4(4) . . . . ?
C2 C3 C4 Si2 175.13(19) . . . . ?
Ru1 C3 C4 Si2 -126.3(2) . . . . ?
Rh1 C3 C4 Si2 116.1(2) . . . . ?
C30 C3 C4 Sn1 178.3(2) . . . . ?
C2 C3 C4 Sn1 -0.2(3) . . . . ?
Ru1 C3 C4 Sn1 58.36(14) . . . . ?
Rh1 C3 C4 Sn1 -59.23(14) . . . . ?
C30 C3 C4 Ru1 119.9(3) . . . . ?
C2 C3 C4 Ru1 -58.5(2) . . . . ?
Rh1 C3 C4 Ru1 -117.58(9) . . . . ?
C30 C3 C4 Rh1 -122.5(3) . . . . ?
C2 C3 C4 Rh1 59.1(2) . . . . ?
Ru1 C3 C4 Rh1 117.58(9) . . . . ?
C1 Sn1 C4 C3 -2.0(2) . . . . ?
Ru1 Sn1 C4 C3 -55.88(18) . . . . ?
Rh1 Sn1 C4 C3 57.54(18) . . . . ?
C1 Sn1 C4 Si2 -177.69(17) . . . . ?
Ru1 Sn1 C4 Si2 128.48(17) . . . . ?
Rh1 Sn1 C4 Si2 -118.10(16) . . . . ?
C1 Sn1 C4 Ru1 53.83(8) . . . . ?
Rh1 Sn1 C4 Ru1 113.42(8) . . . . ?
C1 Sn1 C4 Rh1 -59.59(8) . . . . ?
Ru1 Sn1 C4 Rh1 -113.42(8) . . . . ?
C4 C3 Rh1 C9 -45.7(2) . . . . ?
C30 C3 Rh1 C9 76.7(3) . . . . ?
C2 C3 Rh1 C9 -171.12(16) . . . . ?
Ru1 C3 Rh1 C9 -111.72(15) . . . . ?
C4 C3 Rh1 C8 10.2(4) . . . . ?
C30 C3 Rh1 C8 132.6(3) . . . . ?
C2 C3 Rh1 C8 -115.2(3) . . . . ?
Ru1 C3 Rh1 C8 -55.8(4) . . . . ?
C4 C3 Rh1 C5 -164.92(16) . . . . ?
C30 C3 Rh1 C5 -42.6(3) . . . . ?
C2 C3 Rh1 C5 69.65(18) . . . . ?
Ru1 C3 Rh1 C5 129.05(13) . . . . ?
C4 C3 Rh1 C12 -130.38(17) . . . . ?
C30 C3 Rh1 C12 -8.0(2) . . . . ?
C2 C3 Rh1 C12 104.19(16) . . . . ?
Ru1 C3 Rh1 C12 163.60(13) . . . . ?
C4 C3 Rh1 C2 125.4(2) . . . . ?
C30 C3 Rh1 C2 -112.2(3) . . . . ?
Ru1 C3 Rh1 C2 59.41(14) . . . . ?
C30 C3 Rh1 C4 122.4(3) . . . . ?
C2 C3 Rh1 C4 -125.4(2) . . . . ?
Ru1 C3 Rh1 C4 -66.02(16) . . . . ?
C4 C3 Rh1 C1 93.53(17) . . . . ?
C30 C3 Rh1 C1 -144.1(3) . . . . ?
C2 C3 Rh1 C1 -31.90(14) . . . . ?
Ru1 C3 Rh1 C1 27.51(10) . . . . ?
C4 C3 Rh1 Sn1 41.07(14) . . . . ?
C30 C3 Rh1 Sn1 163.4(2) . . . . ?
C2 C3 Rh1 Sn1 -84.36(14) . . . . ?
Ru1 C3 Rh1 Sn1 -24.95(9) . . . . ?
C1 C2 Rh1 C9 -86.8(6) . . . . ?
C24 C2 Rh1 C9 151.3(5) . . . . ?
C3 C2 Rh1 C9 37.6(7) . . . . ?
Ru1 C2 Rh1 C9 -20.7(7) . . . . ?
C1 C2 Rh1 C8 22.2(3) . . . . ?
C24 C2 Rh1 C8 -99.8(3) . . . . ?
C3 C2 Rh1 C8 146.6(2) . . . . ?
Ru1 C2 Rh1 C8 88.3(2) . . . . ?
C1 C2 Rh1 C5 111.47(17) . . . . ?
C24 C2 Rh1 C5 -10.5(3) . . . . ?
C3 C2 Rh1 C5 -124.13(16) . . . . ?
Ru1 C2 Rh1 C5 177.56(12) . . . . ?
C1 C2 Rh1 C12 150.20(17) . . . . ?
C24 C2 Rh1 C12 28.2(3) . . . . ?
C3 C2 Rh1 C12 -85.40(17) . . . . ?
Ru1 C2 Rh1 C12 -143.71(13) . . . . ?
C1 C2 Rh1 C3 -124.4(2) . . . . ?
C24 C2 Rh1 C3 113.6(3) . . . . ?
Ru1 C2 Rh1 C3 -58.31(15) . . . . ?
C1 C2 Rh1 C4 -92.79(17) . . . . ?
C24 C2 Rh1 C4 145.2(3) . . . . ?
C3 C2 Rh1 C4 31.61(15) . . . . ?
Ru1 C2 Rh1 C4 -26.70(11) . . . . ?
C24 C2 Rh1 C1 -122.0(3) . . . . ?
C3 C2 Rh1 C1 124.4(2) . . . . ?
Ru1 C2 Rh1 C1 66.09(16) . . . . ?
C1 C2 Rh1 Sn1 -38.76(14) . . . . ?
C24 C2 Rh1 Sn1 -160.7(2) . . . . ?
C3 C2 Rh1 Sn1 85.64(14) . . . . ?
Ru1 C2 Rh1 Sn1 27.32(9) . . . . ?
C3 C4 Rh1 C9 147.16(17) . . . . ?
Si2 C4 Rh1 C9 26.78(19) . . . . ?
Sn1 C4 Rh1 C9 -87.24(10) . . . . ?
Ru1 C4 Rh1 C9 -153.52(12) . . . . ?
C3 C4 Rh1 C8 -175.77(16) . . . . ?
Si2 C4 Rh1 C8 63.8(2) . . . . ?
Sn1 C4 Rh1 C8 -50.18(13) . . . . ?
Ru1 C4 Rh1 C8 -116.46(13) . . . . ?
C3 C4 Rh1 C5 30.2(3) . . . . ?
Si2 C4 Rh1 C5 -90.2(3) . . . . ?
Sn1 C4 Rh1 C5 155.8(2) . . . . ?
Ru1 C4 Rh1 C5 89.5(2) . . . . ?
C3 C4 Rh1 C12 61.12(19) . . . . ?
Si2 C4 Rh1 C12 -59.3(2) . . . . ?
Sn1 C4 Rh1 C12 -173.29(10) . . . . ?
Ru1 C4 Rh1 C12 120.43(13) . . . . ?
Si2 C4 Rh1 C3 -120.4(2) . . . . ?
Sn1 C4 Rh1 C3 125.60(17) . . . . ?
Ru1 C4 Rh1 C3 59.31(15) . . . . ?
C3 C4 Rh1 C2 -33.99(15) . . . . ?
Si2 C4 Rh1 C2 -154.4(2) . . . . ?
Sn1 C4 Rh1 C2 91.61(10) . . . . ?
Ru1 C4 Rh1 C2 25.33(10) . . . . ?
C3 C4 Rh1 C1 -71.39(16) . . . . ?
Si2 C4 Rh1 C1 168.22(19) . . . . ?
Sn1 C4 Rh1 C1 54.21(8) . . . . ?
Ru1 C4 Rh1 C1 -12.08(10) . . . . ?
C3 C4 Rh1 Sn1 -125.60(17) . . . . ?
Si2 C4 Rh1 Sn1 114.02(18) . . . . ?
Ru1 C4 Rh1 Sn1 -66.28(9) . . . . ?
C2 C1 Rh1 C9 162.14(19) . . . . ?
Si1 C1 Rh1 C9 -80.0(2) . . . . ?
Sn1 C1 Rh1 C9 34.0(2) . . . . ?
Ru1 C1 Rh1 C9 101.69(19) . . . . ?
C2 C1 Rh1 C8 -166.76(16) . . . . ?
Si1 C1 Rh1 C8 -48.93(18) . . . . ?
Sn1 C1 Rh1 C8 65.12(11) . . . . ?
Ru1 C1 Rh1 C8 132.79(12) . . . . ?
C2 C1 Rh1 C5 -79.32(18) . . . . ?
Si1 C1 Rh1 C5 38.51(18) . . . . ?
Sn1 C1 Rh1 C5 152.56(10) . . . . ?
Ru1 C1 Rh1 C5 -139.77(12) . . . . ?
C2 C1 Rh1 C12 -42.9(2) . . . . ?
Si1 C1 Rh1 C12 74.9(2) . . . . ?
Sn1 C1 Rh1 C12 -171.02(13) . . . . ?
Ru1 C1 Rh1 C12 -103.35(16) . . . . ?
C2 C1 Rh1 C3 34.70(16) . . . . ?
Si1 C1 Rh1 C3 152.53(18) . . . . ?
Sn1 C1 Rh1 C3 -93.42(10) . . . . ?
Ru1 C1 Rh1 C3 -25.75(10) . . . . ?
Si1 C1 Rh1 C2 117.8(2) . . . . ?
Sn1 C1 Rh1 C2 -128.12(18) . . . . ?
Ru1 C1 Rh1 C2 -60.45(15) . . . . ?
C2 C1 Rh1 C4 72.52(17) . . . . ?
Si1 C1 Rh1 C4 -169.65(17) . . . . ?
Sn1 C1 Rh1 C4 -55.60(9) . . . . ?
Ru1 C1 Rh1 C4 12.07(10) . . . . ?
C2 C1 Rh1 Sn1 128.12(18) . . . . ?
Si1 C1 Rh1 Sn1 -114.06(16) . . . . ?
Ru1 C1 Rh1 Sn1 67.67(8) . . . . ?
C1 Sn1 Rh1 C9 -160.15(12) . . . . ?
C4 Sn1 Rh1 C9 103.47(12) . . . . ?
Ru1 Sn1 Rh1 C9 151.31(9) . . . . ?
C1 Sn1 Rh1 C8 -122.80(12) . . . . ?
C4 Sn1 Rh1 C8 140.83(12) . . . . ?
Ru1 Sn1 Rh1 C8 -171.33(9) . . . . ?
C1 Sn1 Rh1 C5 -61.51(19) . . . . ?
C4 Sn1 Rh1 C5 -157.88(19) . . . . ?
Ru1 Sn1 Rh1 C5 -110.04(17) . . . . ?
C1 Sn1 Rh1 C12 136.0(5) . . . . ?
C4 Sn1 Rh1 C12 39.6(5) . . . . ?
Ru1 Sn1 Rh1 C12 87.4(5) . . . . ?
C1 Sn1 Rh1 C3 67.28(11) . . . . ?
C4 Sn1 Rh1 C3 -29.09(11) . . . . ?
Ru1 Sn1 Rh1 C3 18.75(7) . . . . ?
C1 Sn1 Rh1 C2 27.81(11) . . . . ?
C4 Sn1 Rh1 C2 -68.56(11) . . . . ?
Ru1 Sn1 Rh1 C2 -20.72(7) . . . . ?
C1 Sn1 Rh1 C4 96.37(12) . . . . ?
Ru1 Sn1 Rh1 C4 47.84(8) . . . . ?
C4 Sn1 Rh1 C1 -96.37(12) . . . . ?
Ru1 Sn1 Rh1 C1 -48.53(9) . . . . ?
C9 Rh1 C5 C12 -74.60(19) . . . . ?
C8 Rh1 C5 C12 -112.7(2) . . . . ?
C3 Rh1 C5 C12 65.7(2) . . . . ?
C2 Rh1 C5 C12 102.08(19) . . . . ?
C4 Rh1 C5 C12 45.9(3) . . . . ?
C1 Rh1 C5 C12 137.36(18) . . . . ?
Sn1 Rh1 C5 C12 -175.58(14) . . . . ?
C9 Rh1 C5 C6 43.3(2) . . . . ?
C8 Rh1 C5 C6 5.2(2) . . . . ?
C12 Rh1 C5 C6 117.9(3) . . . . ?
C3 Rh1 C5 C6 -176.4(2) . . . . ?
C2 Rh1 C5 C6 -140.0(2) . . . . ?
C4 Rh1 C5 C6 163.8(2) . . . . ?
C1 Rh1 C5 C6 -104.7(2) . . . . ?
Sn1 Rh1 C5 C6 -57.7(3) . . . . ?
C12 C5 C6 C7 92.5(4) . . . . ?
Rh1 C5 C6 C7 9.4(3) . . . . ?
C5 C6 C7 C8 -25.4(4) . . . . ?
C6 C7 C8 C9 -50.7(4) . . . . ?
C6 C7 C8 Rh1 30.4(3) . . . . ?
C5 Rh1 C8 C9 99.95(19) . . . . ?
C12 Rh1 C8 C9 65.42(19) . . . . ?
C3 Rh1 C8 C9 -75.8(4) . . . . ?
C2 Rh1 C8 C9 -163.76(19) . . . . ?
C4 Rh1 C8 C9 -68.6(2) . . . . ?
C1 Rh1 C8 C9 -150.18(17) . . . . ?
Sn1 Rh1 C8 C9 -105.70(17) . . . . ?
C9 Rh1 C8 C7 -119.4(3) . . . . ?
C5 Rh1 C8 C7 -19.4(2) . . . . ?
C12 Rh1 C8 C7 -54.0(2) . . . . ?
C3 Rh1 C8 C7 164.8(3) . . . . ?
C2 Rh1 C8 C7 76.9(3) . . . . ?
C4 Rh1 C8 C7 172.03(19) . . . . ?
C1 Rh1 C8 C7 90.4(2) . . . . ?
Sn1 Rh1 C8 C7 134.9(2) . . . . ?
C7 C8 C9 C10 -4.4(5) . . . . ?
Rh1 C8 C9 C10 -110.0(3) . . . . ?
C7 C8 C9 Rh1 105.6(3) . . . . ?
C5 Rh1 C9 C8 -75.73(19) . . . . ?
C12 Rh1 C9 C8 -112.7(2) . . . . ?
C3 Rh1 C9 C8 153.18(17) . . . . ?
C2 Rh1 C9 C8 122.1(6) . . . . ?
C4 Rh1 C9 C8 127.72(18) . . . . ?
C1 Rh1 C9 C8 49.8(3) . . . . ?
Sn1 Rh1 C9 C8 75.58(17) . . . . ?
C8 Rh1 C9 C10 117.7(3) . . . . ?
C5 Rh1 C9 C10 42.0(3) . . . . ?
C12 Rh1 C9 C10 5.0(2) . . . . ?
C3 Rh1 C9 C10 -89.1(3) . . . . ?
C2 Rh1 C9 C10 -120.2(6) . . . . ?
C4 Rh1 C9 C10 -114.6(2) . . . . ?
C1 Rh1 C9 C10 167.5(2) . . . . ?
Sn1 Rh1 C9 C10 -166.7(2) . . . . ?
C8 C9 C10 C11 92.8(4) . . . . ?
Rh1 C9 C10 C11 9.1(4) . . . . ?
C9 C10 C11 C12 -24.2(4) . . . . ?
C6 C5 C12 C11 -1.7(5) . . . . ?
Rh1 C5 C12 C11 106.8(3) . . . . ?
C6 C5 C12 Rh1 -108.5(3) . . . . ?
C10 C11 C12 C5 -53.8(4) . . . . ?
C10 C11 C12 Rh1 29.0(4) . . . . ?
C9 Rh1 C12 C5 101.0(2) . . . . ?
C8 Rh1 C12 C5 65.6(2) . . . . ?
C3 Rh1 C12 C5 -126.90(18) . . . . ?
C2 Rh1 C12 C5 -88.05(19) . . . . ?
C4 Rh1 C12 C5 -158.02(17) . . . . ?
C1 Rh1 C12 C5 -63.9(2) . . . . ?
Sn1 Rh1 C12 C5 166.2(4) . . . . ?
C9 Rh1 C12 C11 -18.8(2) . . . . ?
C8 Rh1 C12 C11 -54.2(2) . . . . ?
C5 Rh1 C12 C11 -119.9(3) . . . . ?
C3 Rh1 C12 C11 113.2(2) . . . . ?
C2 Rh1 C12 C11 152.1(2) . . . . ?
C4 Rh1 C12 C11 82.1(3) . . . . ?
C1 Rh1 C12 C11 176.2(2) . . . . ?
Sn1 Rh1 C12 C11 46.3(7) . . . . ?
C17 C13 C14 C15 1.0(3) . . . . ?
C42 C13 C14 C15 171.3(3) . . . . ?
Ru1 C13 C14 C15 -63.3(2) . . . . ?
C17 C13 C14 C43 -167.3(3) . . . . ?
C42 C13 C14 C43 3.0(5) . . . . ?
Ru1 C13 C14 C43 128.3(3) . . . . ?
C17 C13 C14 Ru1 64.3(2) . . . . ?
C42 C13 C14 Ru1 -125.4(3) . . . . ?
C13 C14 C15 C16 0.2(3) . . . . ?
C43 C14 C15 C16 168.1(3) . . . . ?
Ru1 C14 C15 C16 -61.2(2) . . . . ?
C13 C14 C15 C44 -168.8(3) . . . . ?
C43 C14 C15 C44 -0.9(5) . . . . ?
Ru1 C14 C15 C44 129.8(3) . . . . ?
C13 C14 C15 Ru1 61.4(2) . . . . ?
C43 C14 C15 Ru1 -130.7(3) . . . . ?
C14 C15 C16 C17 -1.3(3) . . . . ?
C44 C15 C16 C17 168.0(3) . . . . ?
Ru1 C15 C16 C17 -62.0(2) . . . . ?
C14 C15 C16 C45 -168.5(3) . . . . ?
C44 C15 C16 C45 0.7(5) . . . . ?
Ru1 C15 C16 C45 130.8(3) . . . . ?
C14 C15 C16 Ru1 60.7(2) . . . . ?
C44 C15 C16 Ru1 -130.0(3) . . . . ?
C15 C16 C17 C13 1.9(3) . . . . ?
C45 C16 C17 C13 169.3(3) . . . . ?
Ru1 C16 C17 C13 -61.0(2) . . . . ?
C15 C16 C17 C46 -162.6(3) . . . . ?
C45 C16 C17 C46 4.8(5) . . . . ?
Ru1 C16 C17 C46 134.5(3) . . . . ?
C15 C16 C17 Ru1 62.9(2) . . . . ?
C45 C16 C17 Ru1 -129.7(3) . . . . ?
C14 C13 C17 C16 -1.8(3) . . . . ?
C42 C13 C17 C16 -172.0(3) . . . . ?
Ru1 C13 C17 C16 62.6(2) . . . . ?
C14 C13 C17 C46 162.7(3) . . . . ?
C42 C13 C17 C46 -7.5(5) . . . . ?
Ru1 C13 C17 C46 -132.9(3) . . . . ?
C14 C13 C17 Ru1 -64.4(2) . . . . ?
C42 C13 C17 Ru1 125.5(3) . . . . ?
C2 C1 Si1 C19 51.0(3) . . . . ?
Sn1 C1 Si1 C19 -113.38(16) . . . . ?
Ru1 C1 Si1 C19 148.2(2) . . . . ?
Rh1 C1 Si1 C19 -29.28(18) . . . . ?
C2 C1 Si1 C18 -67.7(3) . . . . ?
Sn1 C1 Si1 C18 127.94(16) . . . . ?
Ru1 C1 Si1 C18 29.6(3) . . . . ?
Rh1 C1 Si1 C18 -147.96(15) . . . . ?
C2 C1 Si1 C20 170.7(2) . . . . ?
Sn1 C1 Si1 C20 6.3(2) . . . . ?
Ru1 C1 Si1 C20 -92.0(2) . . . . ?
Rh1 C1 Si1 C20 90.42(17) . . . . ?
C19 Si1 C20 C22 55.0(3) . . . . ?
C18 Si1 C20 C22 164.4(2) . . . . ?
C1 Si1 C20 C22 -65.0(3) . . . . ?
C19 Si1 C20 C21 178.6(2) . . . . ?
C18 Si1 C20 C21 -71.9(2) . . . . ?
C1 Si1 C20 C21 58.7(3) . . . . ?
C19 Si1 C20 C23 -62.8(2) . . . . ?
C18 Si1 C20 C23 46.7(3) . . . . ?
C1 Si1 C20 C23 177.3(2) . . . . ?
C1 C2 C24 C25 52.5(4) . . . . ?
C3 C2 C24 C25 -122.3(3) . . . . ?
Ru1 C2 C24 C25 -38.0(4) . . . . ?
Rh1 C2 C24 C25 151.1(2) . . . . ?
C1 C2 C24 C29 -126.9(3) . . . . ?
C3 C2 C24 C29 58.3(4) . . . . ?
Ru1 C2 C24 C29 142.5(2) . . . . ?
Rh1 C2 C24 C29 -28.3(4) . . . . ?
C29 C24 C25 C26 2.8(5) . . . . ?
C2 C24 C25 C26 -176.6(3) . . . . ?
C24 C25 C26 C27 -1.7(5) . . . . ?
C25 C26 C27 C28 -0.2(5) . . . . ?
C26 C27 C28 C29 1.0(5) . . . . ?
C27 C28 C29 C24 0.1(5) . . . . ?
C25 C24 C29 C28 -2.0(4) . . . . ?
C2 C24 C29 C28 177.4(3) . . . . ?
C4 C3 C30 C31 -117.6(3) . . . . ?
C2 C3 C30 C31 60.8(4) . . . . ?
Ru1 C3 C30 C31 -23.9(4) . . . . ?
Rh1 C3 C30 C31 146.8(2) . . . . ?
C4 C3 C30 C35 60.0(4) . . . . ?
C2 C3 C30 C35 -121.6(3) . . . . ?
Ru1 C3 C30 C35 153.7(2) . . . . ?
Rh1 C3 C30 C35 -35.6(4) . . . . ?
C35 C30 C31 C32 -2.9(5) . . . . ?
C3 C30 C31 C32 174.8(3) . . . . ?
C30 C31 C32 C33 1.4(5) . . . . ?
C31 C32 C33 C34 0.7(6) . . . . ?
C32 C33 C34 C35 -1.3(5) . . . . ?
C33 C34 C35 C30 -0.3(5) . . . . ?
C31 C30 C35 C34 2.3(5) . . . . ?
C3 C30 C35 C34 -175.3(3) . . . . ?
C3 C4 Si2 C36 52.5(3) . . . . ?
Sn1 C4 Si2 C36 -132.37(16) . . . . ?
Ru1 C4 Si2 C36 -39.6(2) . . . . ?
Rh1 C4 Si2 C36 140.05(17) . . . . ?
C3 C4 Si2 C37 -66.0(3) . . . . ?
Sn1 C4 Si2 C37 109.11(17) . . . . ?
Ru1 C4 Si2 C37 -158.08(19) . . . . ?
Rh1 C4 Si2 C37 21.5(2) . . . . ?
C3 C4 Si2 C38 176.5(2) . . . . ?
Sn1 C4 Si2 C38 -8.4(2) . . . . ?
Ru1 C4 Si2 C38 84.4(2) . . . . ?
Rh1 C4 Si2 C38 -95.98(18) . . . . ?
C36 Si2 C38 C41 -168.2(2) . . . . ?
C4 Si2 C38 C41 66.7(3) . . . . ?
C37 Si2 C38 C41 -55.9(3) . . . . ?
C36 Si2 C38 C39 67.6(3) . . . . ?
C4 Si2 C38 C39 -57.4(3) . . . . ?
C37 Si2 C38 C39 179.9(2) . . . . ?
C36 Si2 C38 C40 -49.7(3) . . . . ?
C4 Si2 C38 C40 -174.8(2) . . . . ?
C37 Si2 C38 C40 62.6(3) . . . . ?
C47 C48 O1 C48 -83(100) . . . 3_655 ?
C47 C48 O1 C50 176.7(11) . . . 3_655 ?
C47 C48 O1 C50 -3.3(11) . . . . ?
C48 O1 C50 C49 0.7(11) . . . . ?
C48 O1 C50 C49 -179.3(11) 3_655 . . . ?
C50 O1 C50 C49 -164(88) 3_655 . . . ?
C17 C13 Ru1 C3 38.0(5) . . . . ?
C14 C13 Ru1 C3 153.4(4) . . . . ?
C42 C13 Ru1 C3 -84.8(6) . . . . ?
C14 C13 Ru1 C17 115.4(3) . . . . ?
C42 C13 Ru1 C17 -122.9(4) . . . . ?
C17 C13 Ru1 C14 -115.4(3) . . . . ?
C42 C13 Ru1 C14 121.8(4) . . . . ?
C17 C13 Ru1 C2 -165.1(2) . . . . ?
C14 C13 Ru1 C2 -49.7(3) . . . . ?
C42 C13 Ru1 C2 72.1(4) . . . . ?
C17 C13 Ru1 C16 -36.66(18) . . . . ?
C14 C13 Ru1 C16 78.7(2) . . . . ?
C42 C13 Ru1 C16 -159.5(4) . . . . ?
C17 C13 Ru1 C15 -78.4(2) . . . . ?
C14 C13 Ru1 C15 36.96(18) . . . . ?
C42 C13 Ru1 C15 158.7(4) . . . . ?
C17 C13 Ru1 C1 166.26(17) . . . . ?
C14 C13 Ru1 C1 -78.4(2) . . . . ?
C42 C13 Ru1 C1 43.4(4) . . . . ?
C17 C13 Ru1 C4 67.9(2) . . . . ?
C14 C13 Ru1 C4 -176.76(17) . . . . ?
C42 C13 Ru1 C4 -55.0(4) . . . . ?
C17 C13 Ru1 Sn1 115.15(17) . . . . ?
C14 C13 Ru1 Sn1 -129.47(17) . . . . ?
C42 C13 Ru1 Sn1 -7.7(3) . . . . ?
C4 C3 Ru1 C13 38.6(5) . . . . ?
C30 C3 Ru1 C13 -83.5(5) . . . . ?
C2 C3 Ru1 C13 164.3(4) . . . . ?
Rh1 C3 Ru1 C13 104.7(4) . . . . ?
C4 C3 Ru1 C17 68.1(2) . . . . ?
C30 C3 Ru1 C17 -53.9(3) . . . . ?
C2 C3 Ru1 C17 -166.13(17) . . . . ?
Rh1 C3 Ru1 C17 134.29(14) . . . . ?
C4 C3 Ru1 C14 179.1(2) . . . . ?
C30 C3 Ru1 C14 57.1(4) . . . . ?
C2 C3 Ru1 C14 -55.2(3) . . . . ?
Rh1 C3 Ru1 C14 -114.7(2) . . . . ?
C4 C3 Ru1 C2 -125.7(2) . . . . ?
C30 C3 Ru1 C2 112.2(3) . . . . ?
Rh1 C3 Ru1 C2 -59.58(15) . . . . ?
C4 C3 Ru1 C16 106.81(18) . . . . ?
C30 C3 Ru1 C16 -15.2(3) . . . . ?
C2 C3 Ru1 C16 -127.46(16) . . . . ?
Rh1 C3 Ru1 C16 172.96(12) . . . . ?
C4 C3 Ru1 C15 147.14(17) . . . . ?
C30 C3 Ru1 C15 25.1(3) . . . . ?
C2 C3 Ru1 C15 -87.14(18) . . . . ?
Rh1 C3 Ru1 C15 -146.72(12) . . . . ?
C4 C3 Ru1 C1 -95.03(18) . . . . ?
C30 C3 Ru1 C1 142.9(2) . . . . ?
C2 C3 Ru1 C1 30.70(15) . . . . ?
Rh1 C3 Ru1 C1 -28.88(11) . . . . ?
C30 C3 Ru1 C4 -122.0(3) . . . . ?
C2 C3 Ru1 C4 125.7(2) . . . . ?
Rh1 C3 Ru1 C4 66.14(16) . . . . ?
C4 C3 Ru1 Sn1 -40.99(15) . . . . ?
C30 C3 Ru1 Sn1 -163.0(2) . . . . ?
C2 C3 Ru1 Sn1 84.73(14) . . . . ?
Rh1 C3 Ru1 Sn1 25.15(9) . . . . ?
C16 C17 Ru1 C13 -118.0(3) . . . . ?
C46 C17 Ru1 C13 119.5(5) . . . . ?
C16 C17 Ru1 C3 73.6(2) . . . . ?
C13 C17 Ru1 C3 -168.40(17) . . . . ?
C46 C17 Ru1 C3 -48.9(5) . . . . ?
C16 C17 Ru1 C14 -79.4(2) . . . . ?
C13 C17 Ru1 C14 38.65(18) . . . . ?
C46 C17 Ru1 C14 158.2(5) . . . . ?
C16 C17 Ru1 C2 33.3(5) . . . . ?
C13 C17 Ru1 C2 151.4(4) . . . . ?
C46 C17 Ru1 C2 -89.1(6) . . . . ?
C13 C17 Ru1 C16 118.0(3) . . . . ?
C46 C17 Ru1 C16 -122.4(5) . . . . ?
C16 C17 Ru1 C15 -37.40(18) . . . . ?
C13 C17 Ru1 C15 80.63(19) . . . . ?
C46 C17 Ru1 C15 -159.8(5) . . . . ?
C16 C17 Ru1 C1 -148.5(2) . . . . ?
C13 C17 Ru1 C1 -30.5(4) . . . . ?
C46 C17 Ru1 C1 89.1(5) . . . . ?
C16 C17 Ru1 C4 110.12(19) . . . . ?
C13 C17 Ru1 C4 -131.84(18) . . . . ?
C46 C17 Ru1 C4 -12.3(5) . . . . ?
C16 C17 Ru1 Sn1 167.25(16) . . . . ?
C13 C17 Ru1 Sn1 -74.71(18) . . . . ?
C46 C17 Ru1 Sn1 44.8(4) . . . . ?
C15 C14 Ru1 C13 117.4(3) . . . . ?
C43 C14 Ru1 C13 -118.1(4) . . . . ?
C15 C14 Ru1 C3 -47.6(3) . . . . ?
C13 C14 Ru1 C3 -165.0(2) . . . . ?
C43 C14 Ru1 C3 76.9(4) . . . . ?
C15 C14 Ru1 C17 78.7(2) . . . . ?
C13 C14 Ru1 C17 -38.6(2) . . . . ?
C43 C14 Ru1 C17 -156.8(4) . . . . ?
C15 C14 Ru1 C2 -86.2(2) . . . . ?
C13 C14 Ru1 C2 156.43(19) . . . . ?
C43 C14 Ru1 C2 38.3(4) . . . . ?
C15 C14 Ru1 C16 36.77(18) . . . . ?
C13 C14 Ru1 C16 -80.6(2) . . . . ?
C43 C14 Ru1 C16 161.2(4) . . . . ?
C13 C14 Ru1 C15 -117.4(3) . . . . ?
C43 C14 Ru1 C15 124.5(4) . . . . ?
C15 C14 Ru1 C1 -124.46(18) . . . . ?
C13 C14 Ru1 C1 118.15(19) . . . . ?
C43 C14 Ru1 C1 0.0(3) . . . . ?
C15 C14 Ru1 C4 129.7(5) . . . . ?
C13 C14 Ru1 C4 12.3(6) . . . . ?
C43 C14 Ru1 C4 -105.8(6) . . . . ?
C15 C14 Ru1 Sn1 179.18(14) . . . . ?
C13 C14 Ru1 Sn1 61.8(2) . . . . ?
C43 C14 Ru1 Sn1 -56.3(3) . . . . ?
C1 C2 Ru1 C13 -42.6(3) . . . . ?
C24 C2 Ru1 C13 75.9(4) . . . . ?
C3 C2 Ru1 C13 -171.2(2) . . . . ?
Rh1 C2 Ru1 C13 -112.1(2) . . . . ?
C1 C2 Ru1 C3 128.7(2) . . . . ?
C24 C2 Ru1 C3 -112.8(3) . . . . ?
Rh1 C2 Ru1 C3 59.18(14) . . . . ?
C1 C2 Ru1 C17 178.8(4) . . . . ?
C24 C2 Ru1 C17 -62.7(5) . . . . ?
C3 C2 Ru1 C17 50.1(5) . . . . ?
Rh1 C2 Ru1 C17 109.3(4) . . . . ?
C1 C2 Ru1 C14 -76.06(18) . . . . ?
C24 C2 Ru1 C14 42.4(3) . . . . ?
C3 C2 Ru1 C14 155.28(16) . . . . ?
Rh1 C2 Ru1 C14 -145.55(12) . . . . ?
C1 C2 Ru1 C16 -155.26(16) . . . . ?
C24 C2 Ru1 C16 -36.8(3) . . . . ?
C3 C2 Ru1 C16 76.08(19) . . . . ?
Rh1 C2 Ru1 C16 135.25(13) . . . . ?
C1 C2 Ru1 C15 -116.67(16) . . . . ?
C24 C2 Ru1 C15 1.8(3) . . . . ?
C3 C2 Ru1 C15 114.67(16) . . . . ?
Rh1 C2 Ru1 C15 173.84(11) . . . . ?
C24 C2 Ru1 C1 118.5(3) . . . . ?
C3 C2 Ru1 C1 -128.7(2) . . . . ?
Rh1 C2 Ru1 C1 -69.49(16) . . . . ?
C1 C2 Ru1 C4 96.65(17) . . . . ?
C24 C2 Ru1 C4 -144.9(3) . . . . ?
C3 C2 Ru1 C4 -32.01(15) . . . . ?
Rh1 C2 Ru1 C4 27.16(11) . . . . ?
C1 C2 Ru1 Sn1 41.92(14) . . . . ?
C24 C2 Ru1 Sn1 160.4(2) . . . . ?
C3 C2 Ru1 Sn1 -86.74(14) . . . . ?
Rh1 C2 Ru1 Sn1 -27.57(9) . . . . ?
C17 C16 Ru1 C13 37.45(19) . . . . ?
C15 C16 Ru1 C13 -79.6(2) . . . . ?
C45 C16 Ru1 C13 157.8(4) . . . . ?
C17 C16 Ru1 C3 -127.44(19) . . . . ?
C15 C16 Ru1 C3 115.51(18) . . . . ?
C45 C16 Ru1 C3 -7.1(4) . . . . ?
C15 C16 Ru1 C17 -117.1(3) . . . . ?
C45 C16 Ru1 C17 120.3(4) . . . . ?
C17 C16 Ru1 C14 80.3(2) . . . . ?
C15 C16 Ru1 C14 -36.77(17) . . . . ?
C45 C16 Ru1 C14 -159.4(4) . . . . ?
C17 C16 Ru1 C2 -169.99(18) . . . . ?
C15 C16 Ru1 C2 73.0(2) . . . . ?
C45 C16 Ru1 C2 -49.7(4) . . . . ?
C17 C16 Ru1 C15 117.1(3) . . . . ?
C45 C16 Ru1 C15 -122.6(4) . . . . ?
C17 C16 Ru1 C1 142.7(3) . . . . ?
C15 C16 Ru1 C1 25.6(4) . . . . ?
C45 C16 Ru1 C1 -97.0(4) . . . . ?
C17 C16 Ru1 C4 -86.7(2) . . . . ?
C15 C16 Ru1 C4 156.29(17) . . . . ?
C45 C16 Ru1 C4 33.7(4) . . . . ?
C17 C16 Ru1 Sn1 -22.2(3) . . . . ?
C15 C16 Ru1 Sn1 -139.28(16) . . . . ?
C45 C16 Ru1 Sn1 98.1(4) . . . . ?
C14 C15 Ru1 C13 -37.84(18) . . . . ?
C16 C15 Ru1 C13 80.4(2) . . . . ?
C44 C15 Ru1 C13 -159.9(4) . . . . ?
C14 C15 Ru1 C3 157.63(17) . . . . ?
C16 C15 Ru1 C3 -84.1(2) . . . . ?
C44 C15 Ru1 C3 35.5(4) . . . . ?
C14 C15 Ru1 C17 -80.8(2) . . . . ?
C16 C15 Ru1 C17 37.46(19) . . . . ?
C44 C15 Ru1 C17 157.1(4) . . . . ?
C16 C15 Ru1 C14 118.3(3) . . . . ?
C44 C15 Ru1 C14 -122.1(4) . . . . ?
C14 C15 Ru1 C2 113.38(18) . . . . ?
C16 C15 Ru1 C2 -128.36(19) . . . . ?
C44 C15 Ru1 C2 -8.7(3) . . . . ?
C14 C15 Ru1 C16 -118.3(3) . . . . ?
C44 C15 Ru1 C16 119.6(4) . . . . ?
C14 C15 Ru1 C1 72.2(2) . . . . ?
C16 C15 Ru1 C1 -169.56(18) . . . . ?
C44 C15 Ru1 C1 -49.9(3) . . . . ?
C14 C15 Ru1 C4 -162.4(2) . . . . ?
C16 C15 Ru1 C4 -44.2(3) . . . . ?
C44 C15 Ru1 C4 75.5(4) . . . . ?
C14 C15 Ru1 Sn1 -1.8(3) . . . . ?
C16 C15 Ru1 Sn1 116.5(2) . . . . ?
C44 C15 Ru1 Sn1 -123.9(3) . . . . ?
C2 C1 Ru1 C13 159.55(16) . . . . ?
Si1 C1 Ru1 C13 40.4(3) . . . . ?
Sn1 C1 Ru1 C13 -75.81(12) . . . . ?
Rh1 C1 Ru1 C13 -141.88(11) . . . . ?
C2 C1 Ru1 C3 -32.58(15) . . . . ?
Si1 C1 Ru1 C3 -151.8(2) . . . . ?
Sn1 C1 Ru1 C3 92.06(10) . . . . ?
Rh1 C1 Ru1 C3 25.99(10) . . . . ?
C2 C1 Ru1 C17 -179.3(2) . . . . ?
Si1 C1 Ru1 C17 61.5(4) . . . . ?
Sn1 C1 Ru1 C17 -54.6(3) . . . . ?
Rh1 C1 Ru1 C17 -120.7(2) . . . . ?
C2 C1 Ru1 C14 120.64(16) . . . . ?
Si1 C1 Ru1 C14 1.5(2) . . . . ?
Sn1 C1 Ru1 C14 -114.72(10) . . . . ?
Rh1 C1 Ru1 C14 179.21(10) . . . . ?
Si1 C1 Ru1 C2 -119.2(3) . . . . ?
Sn1 C1 Ru1 C2 124.64(17) . . . . ?
Rh1 C1 Ru1 C2 58.57(14) . . . . ?
C2 C1 Ru1 C16 65.6(4) . . . . ?
Si1 C1 Ru1 C16 -53.6(4) . . . . ?
Sn1 C1 Ru1 C16 -169.8(3) . . . . ?
Rh1 C1 Ru1 C16 124.2(3) . . . . ?
C2 C1 Ru1 C15 83.88(18) . . . . ?
Si1 C1 Ru1 C15 -35.3(3) . . . . ?
Sn1 C1 Ru1 C15 -151.48(10) . . . . ?
Rh1 C1 Ru1 C15 142.45(11) . . . . ?
C2 C1 Ru1 C4 -70.78(16) . . . . ?
Si1 C1 Ru1 C4 170.0(2) . . . . ?
Sn1 C1 Ru1 C4 53.86(9) . . . . ?
Rh1 C1 Ru1 C4 -12.21(10) . . . . ?
C2 C1 Ru1 Sn1 -124.64(17) . . . . ?
Si1 C1 Ru1 Sn1 116.2(2) . . . . ?
Rh1 C1 Ru1 Sn1 -66.07(8) . . . . ?
C3 C4 Ru1 C13 -168.13(18) . . . . ?
Si2 C4 Ru1 C13 -48.7(3) . . . . ?
Sn1 C4 Ru1 C13 65.48(16) . . . . ?
Rh1 C4 Ru1 C13 131.66(14) . . . . ?
Si2 C4 Ru1 C3 119.5(3) . . . . ?
Sn1 C4 Ru1 C3 -126.39(18) . . . . ?
Rh1 C4 Ru1 C3 -60.21(15) . . . . ?
C3 C4 Ru1 C17 -131.00(18) . . . . ?
Si2 C4 Ru1 C17 -11.5(2) . . . . ?
Sn1 C4 Ru1 C17 102.62(12) . . . . ?
Rh1 C4 Ru1 C17 168.79(12) . . . . ?
C3 C4 Ru1 C14 -178.1(5) . . . . ?
Si2 C4 Ru1 C14 -58.6(6) . . . . ?
Sn1 C4 Ru1 C14 55.5(6) . . . . ?
Rh1 C4 Ru1 C14 121.7(5) . . . . ?
C3 C4 Ru1 C2 34.42(16) . . . . ?
Si2 C4 Ru1 C2 153.9(2) . . . . ?
Sn1 C4 Ru1 C2 -91.96(10) . . . . ?
Rh1 C4 Ru1 C2 -25.78(11) . . . . ?
C3 C4 Ru1 C16 -91.30(19) . . . . ?
Si2 C4 Ru1 C16 28.2(2) . . . . ?
Sn1 C4 Ru1 C16 142.32(11) . . . . ?
Rh1 C4 Ru1 C16 -151.51(12) . . . . ?
C3 C4 Ru1 C15 -63.0(3) . . . . ?
Si2 C4 Ru1 C15 56.4(3) . . . . ?
Sn1 C4 Ru1 C15 170.58(16) . . . . ?
Rh1 C4 Ru1 C15 -123.24(18) . . . . ?
C3 C4 Ru1 C1 72.99(17) . . . . ?
Si2 C4 Ru1 C1 -167.6(2) . . . . ?
Sn1 C4 Ru1 C1 -53.40(9) . . . . ?
Rh1 C4 Ru1 C1 12.78(11) . . . . ?
C3 C4 Ru1 Sn1 126.39(18) . . . . ?
Si2 C4 Ru1 Sn1 -114.2(2) . . . . ?
Rh1 C4 Ru1 Sn1 66.18(9) . . . . ?
C1 Sn1 Ru1 C13 122.69(13) . . . . ?
C4 Sn1 Ru1 C13 -136.03(13) . . . . ?
Rh1 Sn1 Ru1 C13 174.87(9) . . . . ?
C1 Sn1 Ru1 C3 -71.65(11) . . . . ?
C4 Sn1 Ru1 C3 29.63(11) . . . . ?
Rh1 Sn1 Ru1 C3 -19.47(7) . . . . ?
C1 Sn1 Ru1 C17 159.30(13) . . . . ?
C4 Sn1 Ru1 C17 -99.42(13) . . . . ?
Rh1 Sn1 Ru1 C17 -148.52(10) . . . . ?
C1 Sn1 Ru1 C14 89.67(12) . . . . ?
C4 Sn1 Ru1 C14 -169.05(13) . . . . ?
Rh1 Sn1 Ru1 C14 141.85(9) . . . . ?
C1 Sn1 Ru1 C2 -30.81(11) . . . . ?
C4 Sn1 Ru1 C2 70.47(11) . . . . ?
Rh1 Sn1 Ru1 C2 21.37(7) . . . . ?
C1 Sn1 Ru1 C16 173.47(17) . . . . ?
C4 Sn1 Ru1 C16 -85.25(17) . . . . ?
Rh1 Sn1 Ru1 C16 -134.35(15) . . . . ?
C1 Sn1 Ru1 C15 90.9(2) . . . . ?
C4 Sn1 Ru1 C15 -167.8(2) . . . . ?
Rh1 Sn1 Ru1 C15 143.1(2) . . . . ?
C4 Sn1 Ru1 C1 101.28(12) . . . . ?
Rh1 Sn1 Ru1 C1 52.18(8) . . . . ?
C1 Sn1 Ru1 C4 -101.28(12) . . . . ?
Rh1 Sn1 Ru1 C4 -49.10(9) . . . . ?

_diffrn_measured_fraction_theta_max 0.992
_diffrn_reflns_theta_full        27.00
_diffrn_measured_fraction_theta_full 0.992
_refine_diff_density_max         0.548
_refine_diff_density_min         -0.522
_refine_diff_density_rms         0.094
