# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
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data_1
_database_code_depnum_ccdc_archive 'CCDC 1813488'
_audit_update_record             
;
2018-09-27 deposited with the CCDC.
2018-10-02 downloaded from the CCDC.
;
_audit_creation_date             2018-09-27
_audit_creation_method           
;
Olex2 1.2
(compiled 2017.08.10 svn.r3458 for OlexSys, GUI svn.r5381)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C32 H32 Cl2 Dy2 N4 O14, 2(C H4 O)'
_chemical_formula_sum            'C34 H40 Cl2 Dy2 N4 O16'
_chemical_formula_weight         1156.60
_chemical_absolute_configuration rmad
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           30
_space_group_name_H-M_alt        'P n c 2'
_space_group_name_Hall           'P 2 -2bc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, z'
'x, -y+1/2, z+1/2'
'-x, y+1/2, z+1/2'

_cell_length_a                   12.2620(4)
_cell_length_b                   18.1554(6)
_cell_length_c                   9.4626(3)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     2106.58(12)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9991
_cell_measurement_temperature    223
_cell_measurement_theta_max      27.532
_cell_measurement_theta_min      2.427
_shelx_estimated_absorpt_T_max   0.707
_shelx_estimated_absorpt_T_min   0.318
_exptl_absorpt_coefficient_mu    3.719
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.3335
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2014/5 (Bruker,2014/5) was used for absorption correction.
wR2(int) was 0.1272 before and 0.0435 after correction.
The Ratio of minimum to maximum transmission is 0.4473.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.823
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1132
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.4
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0392
_diffrn_reflns_av_unetI/netI     0.0403
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       9
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            17596
_diffrn_reflns_point_group_measured_fraction_full 0.938
_diffrn_reflns_point_group_measured_fraction_max 0.919
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.532
_diffrn_reflns_theta_min         2.244
_diffrn_ambient_temperature      223
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.735
_reflns_Friedel_fraction_full    0.870
_reflns_Friedel_fraction_max     0.831
_reflns_number_gt                3903
_reflns_number_total             4474
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences. Completness statistics refer to single and
 composite reflections containing twin component 1 only.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v8.37A (Bruker, 2015)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v8.37A (Bruker, 2015)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         0.518
_refine_diff_density_min         -0.395
_refine_diff_density_rms         0.078
_refine_ls_abs_structure_details 
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.004(14)
_refine_ls_extinction_coef       0.0057(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.062
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     273
_refine_ls_number_reflns         4474
_refine_ls_number_restraints     6
_refine_ls_R_factor_all          0.0286
_refine_ls_R_factor_gt           0.0213
_refine_ls_restrained_S_all      1.061
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+0.0801P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0411
_refine_ls_wR_factor_ref         0.0427
_refine_special_details          
;
 Refined as a 2-component inversion twin.
;
_olex2_refinement_description    
;
1. Twinned data refinement
 Scales: 0.996(14)
 0.004(14)
2. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H) groups
3. Restrained distances
 O7-H7
 0.85 with sigma of 0.01
 H8-O6_$1
 2.2 with sigma of 0.02
 H8-O8
 0.85 with sigma of 0.02
 C16-H7
 1.88643 with sigma of 0.02
 Dy1-H7
 2.915855 with sigma of 0.02
4.a Secondary CH2 refined with riding coordinates:
 C8(H8A,H8B)
4.b Aromatic/amide H refined with riding coordinates:
 C4(H4), C5(H5), C6(H6), C9(H9), C11(H11), C13(H13), C14(H14)
4.c Idealised Me refined as rotating group:
 C3(H3A,H3B,H3C), C16(H16A,H16B,H16C), C17(H17A,H17B,H17C)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.37459(2) 0.55838(2) 0.53474(5) 0.02067(7) Uani 1 1 d D . . . .
Cl1 Cl 0.01194(11) 0.90523(7) 0.48643(15) 0.0438(4) Uani 1 1 d . . . . .
O1 O 0.5566(3) 0.55797(15) 0.4800(3) 0.0222(7) Uani 1 1 d . . . . .
O3 O 0.2312(3) 0.62289(18) 0.5944(4) 0.0287(8) Uani 1 1 d . . . . .
O4 O 0.4593(3) 0.63055(19) 0.7313(4) 0.0356(8) Uani 1 1 d . . . . .
O5 O 0.3845(3) 0.5267(2) 0.7845(4) 0.0383(9) Uani 1 1 d . . . . .
O6 O 0.4433(4) 0.5985(3) 0.9505(4) 0.0608(13) Uani 1 1 d D . . . .
O2 O 0.7528(3) 0.54665(17) 0.5875(4) 0.0317(8) Uani 1 1 d . . . . .
O7 O 0.2853(3) 0.5333(2) 0.3216(4) 0.0412(9) Uani 1 1 d D . . . .
H7 H 0.313(3) 0.508(3) 0.254(3) 0.062 Uiso 1 1 d DR . . . .
N1 N 0.3960(3) 0.6738(2) 0.4042(4) 0.0258(9) Uani 1 1 d . . . . .
N2 N 0.4298(4) 0.5860(3) 0.8257(5) 0.0350(10) Uani 1 1 d . . . . .
C3 C 0.8507(5) 0.5439(3) 0.6693(8) 0.0498(17) Uani 1 1 d . . . . .
H3A H 0.852577 0.498376 0.722901 0.075 Uiso 1 1 calc GR . . . .
H3B H 0.852645 0.585444 0.733624 0.075 Uiso 1 1 calc GR . . . .
H3C H 0.913321 0.545953 0.606743 0.075 Uiso 1 1 calc GR . . . .
C2 C 0.7312(4) 0.6114(2) 0.5128(6) 0.0283(13) Uani 1 1 d . . . . .
C4 C 0.8058(4) 0.6669(3) 0.4888(6) 0.0405(15) Uani 1 1 d . . . . .
H4 H 0.876452 0.663828 0.527051 0.049 Uiso 1 1 calc R . . . .
C5 C 0.7759(5) 0.7276(3) 0.4076(7) 0.0467(15) Uani 1 1 d . . . . .
H5 H 0.825722 0.766038 0.392077 0.056 Uiso 1 1 calc R . . . .
C6 C 0.6720(4) 0.7309(3) 0.3498(6) 0.0374(13) Uani 1 1 d . . . . .
H6 H 0.652074 0.771644 0.294087 0.045 Uiso 1 1 calc R . . . .
C7 C 0.5965(4) 0.6744(3) 0.3734(5) 0.0279(11) Uani 1 1 d . . . . .
C1 C 0.6266(4) 0.6145(2) 0.4566(5) 0.0244(10) Uani 1 1 d . . . . .
C8 C 0.4872(4) 0.6748(3) 0.3024(5) 0.0280(10) Uani 1 1 d . . . . .
H8A H 0.481209 0.718860 0.243134 0.034 Uiso 1 1 calc R . . . .
H8B H 0.481502 0.631627 0.240563 0.034 Uiso 1 1 calc R . . . .
C9 C 0.3305(4) 0.7295(3) 0.3988(5) 0.0267(10) Uani 1 1 d . . . . .
H9 H 0.348805 0.767020 0.334503 0.032 Uiso 1 1 calc R . . . .
C10 C 0.2318(4) 0.7407(2) 0.4809(5) 0.0231(10) Uani 1 1 d . . . . .
C11 C 0.1777(4) 0.8081(3) 0.4561(5) 0.0290(11) Uani 1 1 d . . . . .
H11 H 0.208089 0.843101 0.394408 0.035 Uiso 1 1 calc R . . . .
C12 C 0.0800(4) 0.8223(2) 0.5231(9) 0.0310(10) Uani 1 1 d . . . . .
C13 C 0.0340(4) 0.7714(3) 0.6132(5) 0.0303(11) Uani 1 1 d . . . . .
H13 H -0.032297 0.781881 0.658766 0.036 Uiso 1 1 calc R . . . .
C14 C 0.0856(4) 0.7050(3) 0.6364(5) 0.0256(10) Uani 1 1 d . . . . .
H14 H 0.052937 0.670383 0.696866 0.031 Uiso 1 1 calc R . . . .
C15 C 0.1859(4) 0.6877(2) 0.5720(4) 0.0219(10) Uani 1 1 d . . . . .
C16 C 0.1782(9) 0.5544(5) 0.2827(11) 0.117(5) Uani 1 1 d D . . A 1
H16A H 0.132896 0.557462 0.366543 0.176 Uiso 1 1 calc GR . . A 1
H16B H 0.147993 0.518206 0.218334 0.176 Uiso 1 1 calc GR . . A 1
H16C H 0.180350 0.602135 0.236569 0.176 Uiso 1 1 calc GR . . A 1
O8 O 0.6397(5) 0.5333(3) 1.1044(6) 0.0748(16) Uani 1 1 d D . . . .
H8 H 0.628(6) 0.504(3) 1.035(6) 0.112 Uiso 1 1 d DR . . . .
C17 C 0.6977(6) 0.5939(4) 1.0450(10) 0.074(2) Uani 1 1 d . . . . .
H17A H 0.647275 0.625479 0.994201 0.110 Uiso 1 1 calc GR . . . .
H17B H 0.752875 0.575745 0.980392 0.110 Uiso 1 1 calc GR . . . .
H17C H 0.732329 0.621843 1.119999 0.110 Uiso 1 1 calc GR . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 Dy1 3.7354(3) 2_665 ?
Dy1 O1 2.333(3) 2_665 ?
Dy1 O1 2.291(3) . ?
Dy1 O3 2.187(3) . ?
Dy1 O4 2.501(4) . ?
Dy1 O5 2.435(4) . ?
Dy1 O2 2.515(3) 2_665 ?
Dy1 O7 2.339(4) . ?
Dy1 N1 2.447(4) . ?
Cl1 C12 1.756(4) . ?
O1 C1 1.356(5) . ?
O3 C15 1.318(5) . ?
O4 N2 1.258(6) . ?
O5 N2 1.273(6) . ?
O6 N2 1.214(5) . ?
O2 C3 1.429(6) . ?
O2 C2 1.396(6) . ?
O7 C16 1.417(9) . ?
N1 C8 1.476(6) . ?
N1 C9 1.293(6) . ?
C2 C4 1.381(7) . ?
C2 C1 1.390(6) . ?
C4 C5 1.392(8) . ?
C5 C6 1.388(8) . ?
C6 C7 1.401(7) . ?
C7 C1 1.392(7) . ?
C7 C8 1.499(7) . ?
C9 C10 1.452(7) . ?
C10 C11 1.412(6) . ?
C10 C15 1.409(6) . ?
C11 C12 1.380(8) . ?
C12 C13 1.378(8) . ?
C13 C14 1.378(7) . ?
C14 C15 1.409(6) . ?
O8 C17 1.426(8) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Dy1 Dy1 36.50(7) . 2_665 ?
O1 Dy1 Dy1 35.75(8) 2_665 2_665 ?
O1 Dy1 O1 66.09(12) . 2_665 ?
O1 Dy1 O4 119.29(11) 2_665 . ?
O1 Dy1 O4 76.41(11) . . ?
O1 Dy1 O5 99.79(13) . . ?
O1 Dy1 O5 89.05(12) 2_665 . ?
O1 Dy1 O2 65.30(11) 2_665 2_665 ?
O1 Dy1 O2 130.36(10) . 2_665 ?
O1 Dy1 O7 105.10(14) . . ?
O1 Dy1 O7 78.56(12) 2_665 . ?
O1 Dy1 N1 77.53(11) . . ?
O1 Dy1 N1 128.66(12) 2_665 . ?
O3 Dy1 Dy1 165.00(9) . 2_665 ?
O3 Dy1 O1 147.49(11) . . ?
O3 Dy1 O1 146.42(12) . 2_665 ?
O3 Dy1 O4 82.03(13) . . ?
O3 Dy1 O5 85.18(13) . . ?
O3 Dy1 O2 81.69(11) . 2_665 ?
O3 Dy1 O7 87.17(14) . . ?
O3 Dy1 N1 75.99(12) . . ?
O4 Dy1 Dy1 87.43(8) . 2_665 ?
O4 Dy1 O2 120.51(12) . 2_665 ?
O5 Dy1 Dy1 79.91(9) . 2_665 ?
O5 Dy1 O4 51.79(12) . . ?
O5 Dy1 O2 70.08(13) . 2_665 ?
O5 Dy1 N1 133.39(13) . . ?
O2 Dy1 Dy1 94.66(8) 2_665 2_665 ?
O7 Dy1 Dy1 105.96(10) . 2_665 ?
O7 Dy1 O4 159.61(12) . . ?
O7 Dy1 O5 144.48(14) . . ?
O7 Dy1 O2 74.51(14) . 2_665 ?
O7 Dy1 N1 77.39(14) . . ?
N1 Dy1 Dy1 113.43(9) . 2_665 ?
N1 Dy1 O4 83.22(13) . . ?
N1 Dy1 O2 144.71(13) . 2_665 ?
Dy1 O1 Dy1 107.75(12) . 2_665 ?
C1 O1 Dy1 119.5(3) . 2_665 ?
C1 O1 Dy1 130.6(3) . . ?
C15 O3 Dy1 140.8(3) . . ?
N2 O4 Dy1 94.1(3) . . ?
N2 O5 Dy1 96.8(3) . . ?
C3 O2 Dy1 127.1(3) . 2_665 ?
C2 O2 Dy1 114.8(3) . 2_665 ?
C2 O2 C3 117.6(4) . . ?
C16 O7 Dy1 127.2(4) . . ?
C8 N1 Dy1 114.9(3) . . ?
C9 N1 Dy1 128.6(3) . . ?
C9 N1 C8 115.8(4) . . ?
O4 N2 O5 116.9(4) . . ?
O6 N2 O4 122.1(5) . . ?
O6 N2 O5 121.1(5) . . ?
C4 C2 O2 124.9(4) . . ?
C4 C2 C1 121.2(5) . . ?
C1 C2 O2 113.8(4) . . ?
C2 C4 C5 119.6(5) . . ?
C6 C5 C4 119.7(5) . . ?
C5 C6 C7 120.8(5) . . ?
C6 C7 C8 121.1(5) . . ?
C1 C7 C6 119.1(5) . . ?
C1 C7 C8 119.7(4) . . ?
O1 C1 C2 119.3(4) . . ?
O1 C1 C7 121.0(4) . . ?
C2 C1 C7 119.6(4) . . ?
N1 C8 C7 112.6(4) . . ?
N1 C9 C10 127.3(4) . . ?
C11 C10 C9 115.1(4) . . ?
C15 C10 C9 124.4(4) . . ?
C15 C10 C11 120.4(4) . . ?
C12 C11 C10 119.6(5) . . ?
C11 C12 Cl1 118.8(5) . . ?
C13 C12 Cl1 120.2(4) . . ?
C13 C12 C11 120.9(4) . . ?
C12 C13 C14 119.8(4) . . ?
C13 C14 C15 121.8(5) . . ?
O3 C15 C10 122.7(4) . . ?
O3 C15 C14 119.8(4) . . ?
C10 C15 C14 117.4(4) . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
O7 H7 O8 0.858(12) 1.705(16) 2.556(7) 172(5) 2_664 yes
C9 H9 O4 0.94 2.50 3.385(6) 157.1 3_564 yes
O8 H8 O5 0.86(3) 2.44(5) 3.231(7) 154(6) 2_665 yes
O8 H8 O6 0.86(3) 2.21(3) 2.980(7) 150(6) 2_665 yes
C17 H17A O6 0.97 2.58 3.246(9) 125.8 . yes

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy1 O1 C1 C2 138.3(4) . . . . ?
Dy1 O1 C1 C2 -23.0(6) 2_665 . . . ?
Dy1 O1 C1 C7 -44.0(6) . . . . ?
Dy1 O1 C1 C7 154.7(4) 2_665 . . . ?
Dy1 O3 C15 C10 1.2(7) . . . . ?
Dy1 O3 C15 C14 178.9(3) . . . . ?
Dy1 O4 N2 O5 6.1(4) . . . . ?
Dy1 O4 N2 O6 -173.7(5) . . . . ?
Dy1 O5 N2 O4 -6.3(4) . . . . ?
Dy1 O5 N2 O6 173.5(4) . . . . ?
Dy1 O2 C2 C4 -158.5(4) 2_665 . . . ?
Dy1 O2 C2 C1 18.6(5) 2_665 . . . ?
Dy1 N1 C8 C7 -69.3(4) . . . . ?
Dy1 N1 C9 C10 6.8(7) . . . . ?
Cl1 C12 C13 C14 177.1(4) . . . . ?
O2 C2 C4 C5 177.3(5) . . . . ?
O2 C2 C1 O1 1.2(7) . . . . ?
O2 C2 C1 C7 -176.6(4) . . . . ?
N1 C9 C10 C11 178.1(5) . . . . ?
N1 C9 C10 C15 -6.4(8) . . . . ?
C3 O2 C2 C4 13.5(8) . . . . ?
C3 O2 C2 C1 -169.4(5) . . . . ?
C2 C4 C5 C6 -1.1(9) . . . . ?
C4 C2 C1 O1 178.5(5) . . . . ?
C4 C2 C1 C7 0.7(8) . . . . ?
C4 C5 C6 C7 0.7(9) . . . . ?
C5 C6 C7 C1 0.4(8) . . . . ?
C5 C6 C7 C8 -175.3(5) . . . . ?
C6 C7 C1 O1 -178.8(4) . . . . ?
C6 C7 C1 C2 -1.0(7) . . . . ?
C6 C7 C8 N1 -121.7(5) . . . . ?
C1 C2 C4 C5 0.4(8) . . . . ?
C1 C7 C8 N1 62.7(6) . . . . ?
C8 N1 C9 C10 176.5(5) . . . . ?
C8 C7 C1 O1 -3.1(7) . . . . ?
C8 C7 C1 C2 174.7(4) . . . . ?
C9 N1 C8 C7 119.5(5) . . . . ?
C9 C10 C11 C12 176.5(5) . . . . ?
C9 C10 C15 O3 2.2(7) . . . . ?
C9 C10 C15 C14 -175.5(4) . . . . ?
C10 C11 C12 Cl1 -178.0(4) . . . . ?
C10 C11 C12 C13 -0.4(9) . . . . ?
C11 C10 C15 O3 177.4(4) . . . . ?
C11 C10 C15 C14 -0.3(6) . . . . ?
C11 C12 C13 C14 -0.5(9) . . . . ?
C12 C13 C14 C15 1.0(8) . . . . ?
C13 C14 C15 O3 -178.4(4) . . . . ?
C13 C14 C15 C10 -0.6(7) . . . . ?
C15 C10 C11 C12 0.8(8) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
loop_
_twin_individual_id
_twin_individual_mass_fraction_refined
1 0.996(14)
2 0.004(14)

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_database_code_depnum_ccdc_archive 'CCDC 1813547'
_audit_update_record             
;
2018-09-27 deposited with the CCDC.
2018-10-02 downloaded from the CCDC.
;
_audit_creation_date             2018-09-27
_audit_creation_method           
;
Olex2 1.2
(compiled 2017.08.10 svn.r3458 for OlexSys, GUI svn.r5381)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C32 H34 Dy2 N4 O14'
_chemical_formula_sum            'C32 H34 Dy2 N4 O14'
_chemical_formula_weight         1023.63
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   16.996(2)
_cell_length_b                   13.699(2)
_cell_length_c                   15.727(2)
_cell_angle_alpha                90
_cell_angle_beta                 96.623(5)
_cell_angle_gamma                90
_cell_volume                     3637.2(9)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9056
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      2.24
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    4.148
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.3961
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.1566 before and 0.0859 after correction. The Ratio of minimum to maximum transmission is 0.5312. The λ/2 correction factor is Not present.'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.869
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1992
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.22
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0736
_diffrn_reflns_av_unetI/netI     0.0612
_diffrn_reflns_Laue_measured_fraction_full 0.994
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            29096
_diffrn_reflns_point_group_measured_fraction_full 0.994
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_theta_full        24.997
_diffrn_reflns_theta_max         24.997
_diffrn_reflns_theta_min         2.608
_diffrn_ambient_temperature      119.99
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'D8 VENTURE'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                5392
_reflns_number_total             6387
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve (Bourhis et al., 2015)'
_refine_diff_density_max         1.126
_refine_diff_density_min         -0.974
_refine_diff_density_rms         0.172
_refine_ls_extinction_coef       0.00065(6)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.149
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     480
_refine_ls_number_reflns         6387
_refine_ls_number_restraints     554
_refine_ls_R_factor_all          0.0573
_refine_ls_R_factor_gt           0.0437
_refine_ls_restrained_S_all      1.103
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+17.4546P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0739
_refine_ls_wR_factor_ref         0.0786
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H) groups
2. Restrained distances
 O14-H14
 0.87 with sigma of 0.01
 O8-H8
 0.87 with sigma of 0.01
 C32-H14
 1.956713 with sigma of 0.02
 Dy2-H14
 2.9118 with sigma of 0.02
 C31-H8
 1.949719 with sigma of 0.02
 Dy1-H8
 2.963593 with sigma of 0.02
3. Rigid body (RIGU) restrains
 All non-hydrogen atoms
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
4.a Secondary CH2 refined with riding coordinates:
 C23(H23A,H23B), C8(H8A,H8B)
4.b Aromatic/amide H refined with riding coordinates:
 C11(H11), C4(H4), C14(H14A), C6(H6), C13(H13), C24(H24), C12(H12), C26(H26),
 C29(H29), C5(H5), C9(H9), C21(H21), C27(H27), C28(H28), C20(H20), C19(H19)
4.c Idealised Me refined as rotating group:
 C3(H3A,H3B,H3C), C18(H18A,H18B,H18C), C31(H31A,H31B,H31C), C32(H32A,H32B,H32C)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.75204(2) 0.51492(2) 0.37877(2) 0.01194(10) Uani 1 1 d D U . . .
Dy2 Dy 0.75458(2) 0.78697(2) 0.32036(2) 0.01053(10) Uani 1 1 d D U . . .
O9 O 0.7425(3) 0.9424(3) 0.3030(3) 0.0151(10) Uani 1 1 d . U . . .
O6 O 0.7644(3) 0.4829(4) 0.2286(3) 0.0201(11) Uani 1 1 d . U . . .
O7 O 0.8722(3) 0.4343(4) 0.1797(3) 0.0313(14) Uani 1 1 d . U . . .
O10 O 0.6284(3) 0.8100(3) 0.3808(3) 0.0147(10) Uani 1 1 d . U . . .
O12 O 0.7672(3) 0.7393(4) 0.1716(3) 0.0203(11) Uani 1 1 d . U . . .
O5 O 0.8670(3) 0.4459(4) 0.3172(3) 0.0199(11) Uani 1 1 d . U . . .
O13 O 0.6737(3) 0.7452(4) 0.0637(3) 0.0252(12) Uani 1 1 d . U . . .
O3 O 0.7493(3) 0.3778(3) 0.4466(3) 0.0169(11) Uani 1 1 d . U . . .
O1 O 0.6774(3) 0.6459(3) 0.3214(3) 0.0121(10) Uani 1 1 d . U . . .
O14 O 0.7895(3) 0.8233(4) 0.4679(3) 0.0224(12) Uani 1 1 d D U . . .
H14 H 0.757(3) 0.805(5) 0.5040(13) 0.034 Uiso 1 1 d DR . . . .
O11 O 0.6516(3) 0.7961(4) 0.1905(3) 0.0189(11) Uani 1 1 d . U . . .
O4 O 0.8542(3) 0.5491(4) 0.4990(3) 0.0205(11) Uani 1 1 d . U . . .
O8 O 0.6773(3) 0.5668(3) 0.4926(3) 0.0220(12) Uani 1 1 d D U . . .
H8 H 0.675(4) 0.6289(10) 0.505(3) 0.033 Uiso 1 1 d DR . . . .
O2 O 0.8305(3) 0.6511(3) 0.3581(3) 0.0128(10) Uani 1 1 d . U . . .
N3 N 0.8363(4) 0.4541(4) 0.2399(4) 0.0190(13) Uani 1 1 d . U . . .
N4 N 0.6967(4) 0.7601(4) 0.1416(4) 0.0184(13) Uani 1 1 d . U . . .
N2 N 0.8865(3) 0.8469(4) 0.2990(3) 0.0137(12) Uani 1 1 d . U . . .
N1 N 0.6258(3) 0.4352(4) 0.3252(3) 0.0146(12) Uani 1 1 d . U . . .
C25 C 0.8657(4) 1.0232(5) 0.2943(4) 0.0124(14) Uani 1 1 d . U . . .
C11 C 0.5862(4) 0.2030(5) 0.4288(4) 0.0200(16) Uani 1 1 d . U . . .
H11 H 0.535525 0.193336 0.397705 0.024 Uiso 1 1 calc R . . . .
C4 C 0.4901(4) 0.7548(5) 0.3619(4) 0.0146(14) Uani 1 1 d . U . . .
H4 H 0.471755 0.813198 0.385647 0.017 Uiso 1 1 calc R . . . .
C10 C 0.6298(4) 0.2870(5) 0.4125(4) 0.0168(14) Uani 1 1 d . U . . .
C14 C 0.7324(4) 0.2317(5) 0.5225(5) 0.0215(16) Uani 1 1 d . U . . .
H14A H 0.781972 0.241010 0.556087 0.026 Uiso 1 1 calc R . . . .
C6 C 0.4643(4) 0.5956(5) 0.2985(4) 0.0178(15) Uani 1 1 d . U . . .
H6 H 0.428004 0.545492 0.279009 0.021 Uiso 1 1 calc R . . . .
C13 C 0.6877(4) 0.1497(5) 0.5354(5) 0.0224(16) Uani 1 1 d . U . . .
H13 H 0.707568 0.103050 0.577205 0.027 Uiso 1 1 calc R . . . .
C2 C 0.5697(4) 0.7409(5) 0.3557(4) 0.0129(14) Uani 1 1 d . U . . .
C24 C 0.9119(4) 0.9356(5) 0.2927(4) 0.0148(14) Uani 1 1 d . U . . .
H24 H 0.966490 0.943323 0.286350 0.018 Uiso 1 1 calc R . . . .
C12 C 0.6149(4) 0.1343(5) 0.4886(4) 0.0203(16) Uani 1 1 d . U . . .
H12 H 0.585016 0.077321 0.497465 0.024 Uiso 1 1 calc R . . . .
C7 C 0.5452(4) 0.5835(5) 0.2931(4) 0.0138(14) Uani 1 1 d . U . . .
C1 C 0.5989(4) 0.6560(5) 0.3231(4) 0.0123(14) Uani 1 1 d . U . . .
C23 C 0.9468(4) 0.7697(5) 0.2935(4) 0.0172(15) Uani 1 1 d . U . . .
H23A H 0.996531 0.799314 0.278464 0.021 Uiso 1 1 calc R . . . .
H23B H 0.927753 0.722578 0.248011 0.021 Uiso 1 1 calc R . . . .
C26 C 0.9055(4) 1.1126(5) 0.2892(5) 0.0187(16) Uani 1 1 d . U . . .
H26 H 0.960950 1.112457 0.286076 0.022 Uiso 1 1 calc R . . . .
C29 C 0.7446(4) 1.1135(5) 0.3000(4) 0.0173(16) Uani 1 1 d . U . . .
H29 H 0.689489 1.115287 0.305068 0.021 Uiso 1 1 calc R . . . .
C5 C 0.4372(4) 0.6811(5) 0.3324(4) 0.0194(16) Uani 1 1 d . U . . .
H5 H 0.382165 0.689498 0.335600 0.023 Uiso 1 1 calc R . . . .
C9 C 0.5953(4) 0.3544(5) 0.3479(4) 0.0161(15) Uani 1 1 d . U . . .
H9 H 0.544875 0.337486 0.319280 0.019 Uiso 1 1 calc R . . . .
C3 C 0.6056(4) 0.8983(5) 0.4205(4) 0.0161(16) Uani 1 1 d . U . . .
H3A H 0.652705 0.938089 0.437327 0.024 Uiso 1 1 calc GR . . . .
H3B H 0.579795 0.882121 0.471274 0.024 Uiso 1 1 calc GR . . . .
H3C H 0.568653 0.934883 0.379889 0.024 Uiso 1 1 calc GR . . . .
C30 C 0.7832(4) 1.0238(5) 0.2992(4) 0.0152(14) Uani 1 1 d . U . . .
C8 C 0.5764(4) 0.4905(5) 0.2578(4) 0.0183(15) Uani 1 1 d . U . . .
H8A H 0.531298 0.449319 0.233798 0.022 Uiso 1 1 calc R . . . .
H8B H 0.608295 0.506530 0.210857 0.022 Uiso 1 1 calc R . . . .
C22 C 0.9625(4) 0.7173(5) 0.3782(4) 0.0173(14) Uani 1 1 d . U . . .
C15 C 0.7053(4) 0.3019(5) 0.4600(4) 0.0151(14) Uani 1 1 d . U . . .
C21 C 1.0334(4) 0.7276(5) 0.4315(5) 0.0229(17) Uani 1 1 d . U . . .
H21 H 1.074255 0.767763 0.414110 0.027 Uiso 1 1 calc R . . . .
C27 C 0.8656(4) 1.2006(5) 0.2887(5) 0.0238(17) Uani 1 1 d . U . . .
H27 H 0.893335 1.260452 0.285159 0.029 Uiso 1 1 calc R . . . .
C28 C 0.7855(4) 1.2003(5) 0.2934(5) 0.0199(16) Uani 1 1 d . U . . .
H28 H 0.757628 1.260428 0.292120 0.024 Uiso 1 1 calc R . . . .
C17 C 0.9169(4) 0.6086(5) 0.4832(4) 0.0165(15) Uani 1 1 d . U . . .
C18 C 0.8558(5) 0.5108(6) 0.5851(4) 0.0264(19) Uani 1 1 d . U . . .
H18A H 0.810192 0.467711 0.588102 0.040 Uiso 1 1 calc GR . . . .
H18B H 0.853530 0.564892 0.625516 0.040 Uiso 1 1 calc GR . . . .
H18C H 0.904854 0.473790 0.599945 0.040 Uiso 1 1 calc GR . . . .
C16 C 0.9027(4) 0.6587(5) 0.4049(4) 0.0136(14) Uani 1 1 d . U . . .
C20 C 1.0449(5) 0.6804(6) 0.5087(5) 0.0258(17) Uani 1 1 d . U . . .
H20 H 1.093040 0.689933 0.544807 0.031 Uiso 1 1 calc R . . . .
C19 C 0.9876(4) 0.6189(6) 0.5351(5) 0.0258(18) Uani 1 1 d . U . . .
H19 H 0.996857 0.584555 0.587842 0.031 Uiso 1 1 calc R . . . .
C31 C 0.6259(6) 0.5129(6) 0.5441(6) 0.048(3) Uani 1 1 d D U . . .
H31A H 0.571427 0.536879 0.531756 0.071 Uiso 1 1 calc GR . . . .
H31B H 0.644097 0.522364 0.604916 0.071 Uiso 1 1 calc GR . . . .
H31C H 0.627593 0.443303 0.530069 0.071 Uiso 1 1 calc GR . . . .
C32 C 0.8506(7) 0.8874(8) 0.5118(6) 0.071(4) Uani 1 1 d D U . . .
H32A H 0.899496 0.850178 0.526424 0.107 Uiso 1 1 calc GR . . . .
H32B H 0.832187 0.913030 0.564256 0.107 Uiso 1 1 calc GR . . . .
H32C H 0.860715 0.941744 0.474050 0.107 Uiso 1 1 calc GR . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O6 2.435(4) . ?
Dy1 O5 2.466(5) . ?
Dy1 O3 2.164(5) . ?
Dy1 O1 2.319(4) . ?
Dy1 O4 2.461(5) . ?
Dy1 O8 2.419(5) . ?
Dy1 O2 2.337(4) . ?
Dy1 N1 2.467(6) . ?
Dy2 O9 2.154(4) . ?
Dy2 O10 2.464(4) . ?
Dy2 O12 2.462(5) . ?
Dy2 O1 2.337(4) . ?
Dy2 O14 2.380(5) . ?
Dy2 O11 2.535(4) . ?
Dy2 O2 2.303(4) . ?
Dy2 N2 2.447(6) . ?
O9 C30 1.317(8) . ?
O6 N3 1.277(7) . ?
O7 N3 1.214(7) . ?
O10 C2 1.398(8) . ?
O10 C3 1.435(7) . ?
O12 N4 1.269(7) . ?
O5 N3 1.271(7) . ?
O13 N4 1.259(7) . ?
O3 C15 1.312(8) . ?
O1 C1 1.345(8) . ?
O14 H14 0.874(9) . ?
O14 C32 1.470(10) . ?
O11 N4 1.249(7) . ?
O4 C17 1.386(8) . ?
O4 C18 1.450(8) . ?
O8 H8 0.874(9) . ?
O8 C31 1.458(9) . ?
O2 C16 1.361(8) . ?
N2 C24 1.296(9) . ?
N2 C23 1.483(8) . ?
N1 C9 1.290(8) . ?
N1 C8 1.483(8) . ?
C25 C24 1.437(9) . ?
C25 C26 1.405(9) . ?
C25 C30 1.413(9) . ?
C11 H11 0.9500 . ?
C11 C10 1.408(10) . ?
C11 C12 1.378(10) . ?
C4 H4 0.9500 . ?
C4 C2 1.381(9) . ?
C4 C5 1.395(10) . ?
C10 C9 1.446(9) . ?
C10 C15 1.423(9) . ?
C14 H14A 0.9500 . ?
C14 C13 1.385(10) . ?
C14 C15 1.414(9) . ?
C6 H6 0.9500 . ?
C6 C7 1.397(9) . ?
C6 C5 1.387(10) . ?
C13 H13 0.9500 . ?
C13 C12 1.382(10) . ?
C2 C1 1.386(9) . ?
C24 H24 0.9500 . ?
C12 H12 0.9500 . ?
C7 C1 1.394(9) . ?
C7 C8 1.511(9) . ?
C23 H23A 0.9900 . ?
C23 H23B 0.9900 . ?
C23 C22 1.510(9) . ?
C26 H26 0.9500 . ?
C26 C27 1.383(10) . ?
C29 H29 0.9500 . ?
C29 C30 1.394(9) . ?
C29 C28 1.386(9) . ?
C5 H5 0.9500 . ?
C9 H9 0.9500 . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
C22 C21 1.394(9) . ?
C22 C16 1.397(9) . ?
C21 H21 0.9500 . ?
C21 C20 1.369(10) . ?
C27 H27 0.9500 . ?
C27 C28 1.372(10) . ?
C28 H28 0.9500 . ?
C17 C16 1.406(9) . ?
C17 C19 1.380(9) . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C20 H20 0.9500 . ?
C20 C19 1.387(10) . ?
C19 H19 0.9500 . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O6 Dy1 O5 52.38(15) . . ?
O6 Dy1 O4 130.36(16) . . ?
O6 Dy1 N1 75.97(17) . . ?
O5 Dy1 N1 113.13(17) . . ?
O3 Dy1 O6 109.34(17) . . ?
O3 Dy1 O5 85.61(17) . . ?
O3 Dy1 O1 145.26(16) . . ?
O3 Dy1 O4 80.77(16) . . ?
O3 Dy1 O8 81.22(17) . . ?
O3 Dy1 O2 143.77(16) . . ?
O3 Dy1 N1 73.56(18) . . ?
O1 Dy1 O6 82.32(15) . . ?
O1 Dy1 O5 124.50(15) . . ?
O1 Dy1 O4 117.23(16) . . ?
O1 Dy1 O8 75.51(16) . . ?
O1 Dy1 O2 67.88(15) . . ?
O1 Dy1 N1 78.15(17) . . ?
O4 Dy1 O5 81.60(16) . . ?
O4 Dy1 N1 148.84(17) . . ?
O8 Dy1 O6 151.91(17) . . ?
O8 Dy1 O5 155.61(16) . . ?
O8 Dy1 O4 76.10(17) . . ?
O8 Dy1 N1 82.69(17) . . ?
O2 Dy1 O6 83.95(16) . . ?
O2 Dy1 O5 76.20(16) . . ?
O2 Dy1 O4 65.89(15) . . ?
O2 Dy1 O8 103.00(16) . . ?
O2 Dy1 N1 142.47(17) . . ?
O9 Dy2 O10 81.25(16) . . ?
O9 Dy2 O12 99.17(17) . . ?
O9 Dy2 O1 140.66(16) . . ?
O9 Dy2 O14 85.79(18) . . ?
O9 Dy2 O11 78.58(16) . . ?
O9 Dy2 O2 150.95(16) . . ?
O9 Dy2 N2 74.11(17) . . ?
O10 Dy2 O11 75.73(15) . . ?
O12 Dy2 O10 125.15(15) . . ?
O12 Dy2 O11 51.36(15) . . ?
O1 Dy2 O10 65.73(15) . . ?
O1 Dy2 O12 84.13(15) . . ?
O1 Dy2 O14 104.05(16) . . ?
O1 Dy2 O11 73.19(15) . . ?
O1 Dy2 N2 143.35(17) . . ?
O14 Dy2 O10 74.19(15) . . ?
O14 Dy2 O12 160.46(16) . . ?
O14 Dy2 O11 147.82(16) . . ?
O14 Dy2 N2 86.23(17) . . ?
O2 Dy2 O10 119.37(15) . . ?
O2 Dy2 O12 85.57(16) . . ?
O2 Dy2 O1 68.14(15) . . ?
O2 Dy2 O14 81.27(17) . . ?
O2 Dy2 O11 124.18(15) . . ?
O2 Dy2 N2 79.15(17) . . ?
N2 Dy2 O10 149.54(17) . . ?
N2 Dy2 O12 77.11(17) . . ?
N2 Dy2 O11 115.56(16) . . ?
C30 O9 Dy2 143.1(4) . . ?
N3 O6 Dy1 96.2(4) . . ?
C2 O10 Dy2 115.4(4) . . ?
C2 O10 C3 118.2(5) . . ?
C3 O10 Dy2 124.5(4) . . ?
N4 O12 Dy2 96.4(4) . . ?
N3 O5 Dy1 94.9(4) . . ?
C15 O3 Dy1 144.3(4) . . ?
Dy1 O1 Dy2 111.13(17) . . ?
C1 O1 Dy1 124.9(4) . . ?
C1 O1 Dy2 118.2(4) . . ?
Dy2 O14 H14 118.0(15) . . ?
C32 O14 Dy2 131.8(5) . . ?
C32 O14 H14 109.4(15) . . ?
N4 O11 Dy2 93.5(4) . . ?
C17 O4 Dy1 117.6(4) . . ?
C17 O4 C18 116.7(5) . . ?
C18 O4 Dy1 125.7(4) . . ?
Dy1 O8 H8 119.4(14) . . ?
C31 O8 Dy1 131.4(4) . . ?
C31 O8 H8 108.9(15) . . ?
Dy2 O2 Dy1 111.69(18) . . ?
C16 O2 Dy1 118.6(4) . . ?
C16 O2 Dy2 121.5(4) . . ?
O7 N3 O6 121.3(6) . . ?
O7 N3 O5 122.6(6) . . ?
O5 N3 O6 116.2(5) . . ?
O13 N4 O12 119.9(6) . . ?
O11 N4 O12 118.7(5) . . ?
O11 N4 O13 121.4(6) . . ?
C24 N2 Dy2 130.1(5) . . ?
C24 N2 C23 115.1(6) . . ?
C23 N2 Dy2 114.8(4) . . ?
C9 N1 Dy1 130.3(5) . . ?
C9 N1 C8 115.0(6) . . ?
C8 N1 Dy1 114.7(4) . . ?
C26 C25 C24 117.3(6) . . ?
C26 C25 C30 119.0(6) . . ?
C30 C25 C24 123.6(6) . . ?
C10 C11 H11 119.0 . . ?
C12 C11 H11 119.0 . . ?
C12 C11 C10 122.0(7) . . ?
C2 C4 H4 120.8 . . ?
C2 C4 C5 118.4(7) . . ?
C5 C4 H4 120.8 . . ?
C11 C10 C9 118.1(7) . . ?
C11 C10 C15 118.9(6) . . ?
C15 C10 C9 123.0(7) . . ?
C13 C14 H14A 119.5 . . ?
C13 C14 C15 120.9(7) . . ?
C15 C14 H14A 119.5 . . ?
C7 C6 H6 120.1 . . ?
C5 C6 H6 120.1 . . ?
C5 C6 C7 119.7(7) . . ?
C14 C13 H13 119.4 . . ?
C12 C13 C14 121.2(7) . . ?
C12 C13 H13 119.4 . . ?
C4 C2 O10 124.1(6) . . ?
C4 C2 C1 122.5(7) . . ?
C1 C2 O10 113.4(6) . . ?
N2 C24 C25 126.4(6) . . ?
N2 C24 H24 116.8 . . ?
C25 C24 H24 116.8 . . ?
C11 C12 C13 118.9(7) . . ?
C11 C12 H12 120.5 . . ?
C13 C12 H12 120.5 . . ?
C6 C7 C8 120.8(6) . . ?
C1 C7 C6 120.4(7) . . ?
C1 C7 C8 118.8(6) . . ?
O1 C1 C2 119.5(6) . . ?
O1 C1 C7 122.2(6) . . ?
C2 C1 C7 118.3(6) . . ?
N2 C23 H23A 109.7 . . ?
N2 C23 H23B 109.7 . . ?
N2 C23 C22 109.9(5) . . ?
H23A C23 H23B 108.2 . . ?
C22 C23 H23A 109.7 . . ?
C22 C23 H23B 109.7 . . ?
C25 C26 H26 119.3 . . ?
C27 C26 C25 121.5(7) . . ?
C27 C26 H26 119.3 . . ?
C30 C29 H29 119.5 . . ?
C28 C29 H29 119.5 . . ?
C28 C29 C30 121.0(7) . . ?
C4 C5 H5 119.7 . . ?
C6 C5 C4 120.6(7) . . ?
C6 C5 H5 119.7 . . ?
N1 C9 C10 126.8(7) . . ?
N1 C9 H9 116.6 . . ?
C10 C9 H9 116.6 . . ?
O10 C3 H3A 109.5 . . ?
O10 C3 H3B 109.5 . . ?
O10 C3 H3C 109.5 . . ?
H3A C3 H3B 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
O9 C30 C25 121.8(6) . . ?
O9 C30 C29 119.7(6) . . ?
C29 C30 C25 118.4(6) . . ?
N1 C8 C7 111.3(5) . . ?
N1 C8 H8A 109.4 . . ?
N1 C8 H8B 109.4 . . ?
C7 C8 H8A 109.4 . . ?
C7 C8 H8B 109.4 . . ?
H8A C8 H8B 108.0 . . ?
C21 C22 C23 122.3(7) . . ?
C21 C22 C16 119.1(7) . . ?
C16 C22 C23 118.6(6) . . ?
O3 C15 C10 121.8(6) . . ?
O3 C15 C14 120.2(6) . . ?
C14 C15 C10 118.0(6) . . ?
C22 C21 H21 119.7 . . ?
C20 C21 C22 120.7(7) . . ?
C20 C21 H21 119.7 . . ?
C26 C27 H27 120.5 . . ?
C28 C27 C26 119.0(7) . . ?
C28 C27 H27 120.5 . . ?
C29 C28 H28 119.5 . . ?
C27 C28 C29 121.1(7) . . ?
C27 C28 H28 119.5 . . ?
O4 C17 C16 112.8(6) . . ?
C19 C17 O4 126.0(6) . . ?
C19 C17 C16 121.2(7) . . ?
O4 C18 H18A 109.5 . . ?
O4 C18 H18B 109.5 . . ?
O4 C18 H18C 109.5 . . ?
H18A C18 H18B 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
O2 C16 C22 121.6(6) . . ?
O2 C16 C17 119.3(6) . . ?
C22 C16 C17 119.1(6) . . ?
C21 C20 H20 119.3 . . ?
C21 C20 C19 121.3(7) . . ?
C19 C20 H20 119.3 . . ?
C17 C19 C20 118.5(7) . . ?
C17 C19 H19 120.7 . . ?
C20 C19 H19 120.7 . . ?
O8 C31 H31A 109.5 . . ?
O8 C31 H31B 109.5 . . ?
O8 C31 H31C 109.5 . . ?
H31A C31 H31B 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
O14 C32 H32A 109.5 . . ?
O14 C32 H32B 109.5 . . ?
O14 C32 H32C 109.5 . . ?
H32A C32 H32B 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
O14 H14 O13 0.874(9) 1.913(12) 2.775(7) 169(2) 4_576 yes
O8 H8 O13 0.874(9) 1.957(17) 2.810(7) 165(5) 4_576 yes

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy1 O6 N3 O7 -175.6(6) . . . . ?
Dy1 O6 N3 O5 5.7(6) . . . . ?
Dy1 O5 N3 O6 -5.6(6) . . . . ?
Dy1 O5 N3 O7 175.7(6) . . . . ?
Dy1 O3 C15 C10 7.4(11) . . . . ?
Dy1 O3 C15 C14 -173.0(5) . . . . ?
Dy1 O1 C1 C2 126.7(5) . . . . ?
Dy1 O1 C1 C7 -53.2(8) . . . . ?
Dy1 O4 C17 C16 13.9(7) . . . . ?
Dy1 O4 C17 C19 -164.6(6) . . . . ?
Dy1 O2 C16 C22 158.5(5) . . . . ?
Dy1 O2 C16 C17 -23.4(8) . . . . ?
Dy1 N1 C9 C10 -1.1(10) . . . . ?
Dy1 N1 C8 C7 -67.6(6) . . . . ?
Dy2 O9 C30 C25 10.7(11) . . . . ?
Dy2 O9 C30 C29 -169.3(5) . . . . ?
Dy2 O10 C2 C4 -161.1(5) . . . . ?
Dy2 O10 C2 C1 18.6(7) . . . . ?
Dy2 O12 N4 O13 -178.5(5) . . . . ?
Dy2 O12 N4 O11 2.2(6) . . . . ?
Dy2 O1 C1 C2 -24.2(7) . . . . ?
Dy2 O1 C1 C7 156.0(5) . . . . ?
Dy2 O11 N4 O12 -2.1(6) . . . . ?
Dy2 O11 N4 O13 178.6(5) . . . . ?
Dy2 O2 C16 C22 -55.6(7) . . . . ?
Dy2 O2 C16 C17 122.4(6) . . . . ?
Dy2 N2 C24 C25 -2.1(10) . . . . ?
Dy2 N2 C23 C22 -65.6(6) . . . . ?
O10 C2 C1 O1 2.5(8) . . . . ?
O10 C2 C1 C7 -177.6(6) . . . . ?
O4 C17 C16 O2 5.4(9) . . . . ?
O4 C17 C16 C22 -176.5(6) . . . . ?
O4 C17 C19 C20 178.7(7) . . . . ?
N2 C23 C22 C21 -109.6(7) . . . . ?
N2 C23 C22 C16 68.6(8) . . . . ?
C25 C26 C27 C28 0.1(11) . . . . ?
C11 C10 C9 N1 179.1(7) . . . . ?
C11 C10 C15 O3 178.7(6) . . . . ?
C11 C10 C15 C14 -0.9(10) . . . . ?
C4 C2 C1 O1 -177.8(6) . . . . ?
C4 C2 C1 C7 2.1(10) . . . . ?
C10 C11 C12 C13 1.6(10) . . . . ?
C14 C13 C12 C11 -0.8(11) . . . . ?
C6 C7 C1 O1 177.9(6) . . . . ?
C6 C7 C1 C2 -2.0(10) . . . . ?
C6 C7 C8 N1 -113.0(7) . . . . ?
C13 C14 C15 O3 -177.9(6) . . . . ?
C13 C14 C15 C10 1.7(10) . . . . ?
C2 C4 C5 C6 0.6(10) . . . . ?
C24 N2 C23 C22 113.7(7) . . . . ?
C24 C25 C26 C27 178.8(7) . . . . ?
C24 C25 C30 O9 0.3(10) . . . . ?
C24 C25 C30 C29 -179.7(6) . . . . ?
C12 C11 C10 C9 179.3(6) . . . . ?
C12 C11 C10 C15 -0.8(10) . . . . ?
C7 C6 C5 C4 -0.6(10) . . . . ?
C1 C7 C8 N1 64.7(8) . . . . ?
C23 N2 C24 C25 178.7(6) . . . . ?
C23 C22 C21 C20 178.7(7) . . . . ?
C23 C22 C16 O2 -2.6(10) . . . . ?
C23 C22 C16 C17 179.3(6) . . . . ?
C26 C25 C24 N2 178.0(7) . . . . ?
C26 C25 C30 O9 179.1(6) . . . . ?
C26 C25 C30 C29 -0.9(10) . . . . ?
C26 C27 C28 C29 1.0(11) . . . . ?
C5 C4 C2 O10 178.3(6) . . . . ?
C5 C4 C2 C1 -1.4(10) . . . . ?
C5 C6 C7 C1 1.3(10) . . . . ?
C5 C6 C7 C8 178.9(6) . . . . ?
C9 N1 C8 C7 110.7(7) . . . . ?
C9 C10 C15 O3 -1.4(10) . . . . ?
C9 C10 C15 C14 179.0(6) . . . . ?
C3 O10 C2 C4 4.1(9) . . . . ?
C3 O10 C2 C1 -176.2(5) . . . . ?
C30 C25 C24 N2 -3.1(11) . . . . ?
C30 C25 C26 C27 -0.2(10) . . . . ?
C30 C29 C28 C27 -2.1(11) . . . . ?
C8 N1 C9 C10 -179.2(6) . . . . ?
C8 C7 C1 O1 0.2(9) . . . . ?
C8 C7 C1 C2 -179.7(6) . . . . ?
C22 C21 C20 C19 1.9(12) . . . . ?
C15 C10 C9 N1 -0.8(11) . . . . ?
C15 C14 C13 C12 -0.9(11) . . . . ?
C21 C22 C16 O2 175.6(6) . . . . ?
C21 C22 C16 C17 -2.4(10) . . . . ?
C21 C20 C19 C17 -2.3(12) . . . . ?
C28 C29 C30 O9 -178.0(6) . . . . ?
C28 C29 C30 C25 2.0(10) . . . . ?
C18 O4 C17 C16 -167.4(6) . . . . ?
C18 O4 C17 C19 14.1(10) . . . . ?
C16 C22 C21 C20 0.5(11) . . . . ?
C16 C17 C19 C20 0.3(11) . . . . ?
C19 C17 C16 O2 -176.0(6) . . . . ?
C19 C17 C16 C22 2.0(10) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
