# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_database_code_depnum_ccdc_archive 'CCDC 1873237'
_audit_update_record             
;
2018-10-15 deposited with the CCDC.
2018-11-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/1
_shelx_SHELXL_version_number     2018/1
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         '(C12 H24 K N6 O19 Pt3), C14 H32 K O8, 2(H2 O)'
_chemical_formula_sum            'C26 H60 K2 N6 O29 Pt3'
_chemical_formula_weight         1584.27

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.3868 1.0657 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -4.5932 6.9264 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   8.2798(2)
_cell_length_b                   17.4801(5)
_cell_length_c                   18.1002(5)
_cell_angle_alpha                95.484(7)
_cell_angle_beta                 100.669(7)
_cell_angle_gamma                90.825(6)
_cell_volume                     2561.22(14)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    19652
_cell_measurement_theta_min      3.38
_cell_measurement_theta_max      68.25

_exptl_crystal_description       rod
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.054
_exptl_crystal_F_000             1524
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.170
_exptl_crystal_size_mid          0.090
_exptl_crystal_size_min          0.090
_exptl_absorpt_coefficient_mu    17.275
_shelx_estimated_absorpt_T_min   0.157
_shelx_estimated_absorpt_T_max   0.305
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.3373
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_process_details   'abscor (Rigaku, 2010)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     1.54187
_diffrn_radiation_type           CuK\a
_diffrn_source                   'rotating-anode X-ray tube'
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean 10.000
_diffrn_reflns_number            28428
_diffrn_reflns_av_unetI/netI     0.1257
_diffrn_reflns_av_R_equivalents  0.1130
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_theta_min         3.380
_diffrn_reflns_theta_max         68.226
_diffrn_reflns_theta_full        67.687
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measured_fraction_theta_full 0.982
_diffrn_reflns_Laue_measured_fraction_max 0.980
_diffrn_reflns_Laue_measured_fraction_full 0.982
_diffrn_reflns_point_group_measured_fraction_max 0.980
_diffrn_reflns_point_group_measured_fraction_full 0.982
_reflns_number_total             9169
_reflns_number_gt                6432
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'RAPID AUTO (Rigaku, 2015)'
_computing_cell_refinement       'RAPID AUTO (Rigaku, 2015)'
_computing_data_reduction        'RAPID AUTO (Rigaku, 2015)'
_computing_structure_solution    'SIR2004 (Spagna, 2004)'
_computing_structure_refinement  'SHELXL-2018/1 (Sheldrick, 2018)'
_computing_molecular_graphics    'ORTEP-3 (Farrugia, 2012)'
_computing_publication_material  'SHELXL-2018/1 (Sheldrick, 2018)'
_refine_special_details          SQUEEZE
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0980P)²+36.2855P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         9169
_refine_ls_number_parameters     578
_refine_ls_number_restraints     160
_refine_ls_R_factor_all          0.1158
_refine_ls_R_factor_gt           0.0859
_refine_ls_wR_factor_ref         0.2337
_refine_ls_wR_factor_gt          0.2145
_refine_ls_goodness_of_fit_ref   1.050
_refine_ls_restrained_S_all      1.047
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.62152(9) 0.14913(4) 0.18752(4) 0.0477(2) Uani 1 1 d . . . . .
Pt2 Pt 0.71442(9) 0.27360(4) 0.07719(4) 0.0485(2) Uani 1 1 d . . . . .
Pt3 Pt 0.63485(10) 0.33080(4) 0.24261(4) 0.0559(3) Uani 1 1 d . . . . .
K1 K 0.2587(5) 0.26334(19) 0.07268(19) 0.0481(8) Uani 1 1 d . . . . .
K2 K 0.1096(7) 0.8036(3) 0.3827(2) 0.0878(16) Uani 1 1 d D . . . .
O1 O 0.5713(13) 0.2536(6) 0.1544(7) 0.058(3) Uani 1 1 d . . . . .
O2 O 0.6737(15) 0.1129(6) 0.0860(6) 0.055(3) Uani 1 1 d . . . . .
O3 O 0.7226(17) 0.1363(8) -0.0220(7) 0.068(4) Uani 1 1 d . . . . .
O4 O 0.7204(16) 0.3861(6) 0.1097(7) 0.057(3) Uani 1 1 d . . . . .
O5 O 0.697(2) 0.4767(7) 0.1977(8) 0.080(4) Uani 1 1 d . . . . .
O6 O 0.5652(16) 0.2536(8) 0.3069(7) 0.068(4) Uani 1 1 d . . . . .
O7 O 0.5058(19) 0.1383(9) 0.3243(7) 0.079(4) Uani 1 1 d . . . . .
O8 O 0.5583(18) -0.0053(8) 0.2121(9) 0.079(4) Uani 1 1 d . . . . .
O9 O 0.8128(18) 0.0259(8) 0.2402(10) 0.095(5) Uani 1 1 d . . . . .
O10 O 0.8103(18) 0.3592(8) -0.0312(9) 0.077(4) Uani 1 1 d . . . . .
O11 O 0.9612(16) 0.2618(8) -0.0099(7) 0.069(4) Uani 1 1 d . . . . .
O12 O 0.581(3) 0.4137(13) 0.3731(10) 0.130(8) Uani 1 1 d . . . . .
O13 O 0.826(2) 0.4357(9) 0.3528(9) 0.095(5) Uani 1 1 d . . . . .
O14 O 0.1665(18) 0.1108(9) 0.0774(8) 0.079(4) Uani 1 1 d . . . . .
O15 O 0.3192(15) 0.1564(6) -0.0423(7) 0.056(3) Uani 1 1 d . . . . .
O16 O 0.3133(14) 0.3119(6) -0.0653(6) 0.051(3) Uani 1 1 d . . . . .
O17 O 0.2887(17) 0.4211(6) 0.0592(7) 0.062(3) Uani 1 1 d . . . . .
O18 O 0.1531(18) 0.3700(8) 0.1795(7) 0.073(4) Uani 1 1 d . . . . .
O19 O 0.1833(17) 0.2143(9) 0.2077(8) 0.076(4) Uani 1 1 d . . . . .
O20 O 0.028(3) 0.6523(12) 0.3136(13) 0.182(11) Uani 1 1 d D U . . .
O21 O 0.0871(16) 0.7695(8) 0.2284(7) 0.069(3) Uani 1 1 d . . . . .
O22 O 0.2499(19) 0.9048(9) 0.3044(8) 0.083(4) Uani 1 1 d . . . . .
O23 O 0.207(3) 0.9561(11) 0.4494(8) 0.118(7) Uani 1 1 d D . . . .
O24 O 0.142(2) 0.8452(13) 0.5393(9) 0.111(5) Uani 1 1 d D . . . .
O25 O -0.009(4) 0.7051(18) 0.4722(12) 0.194(12) Uani 1 1 d D U . . .
O26 O 0.403(3) 0.7332(13) 0.4298(11) 0.133(7) Uani 1 1 d D . . . .
O27 O -0.182(3) 0.8832(13) 0.3298(12) 0.152(9) Uani 1 1 d D . . . .
N1 N 0.7033(18) 0.1684(11) 0.0438(8) 0.068(5) Uani 1 1 d . . . . .
N2 N 0.697(2) 0.4085(9) 0.1791(9) 0.069(5) Uani 1 1 d . . . . .
N3 N 0.562(2) 0.1817(9) 0.2827(10) 0.069(5) Uani 1 1 d . . . . .
N4 N 0.672(2) 0.0453(9) 0.2169(8) 0.063(4) Uani 1 1 d . . . . .
N5 N 0.8468(19) 0.3006(9) 0.0016(8) 0.058(4) Uani 1 1 d . . . . .
N6 N 0.689(3) 0.4055(10) 0.3345(11) 0.077(5) Uani 1 1 d . . . . .
C1 C 0.233(3) 0.0580(12) 0.0295(13) 0.080(7) Uani 1 1 d . . . . .
H1 H 0.176415 0.007172 0.025767 0.096 Uiso 1 1 calc R U . . .
H2 H 0.351348 0.052299 0.049713 0.096 Uiso 1 1 calc R U . . .
C2 C 0.211(3) 0.0881(11) -0.0506(12) 0.080(7) Uani 1 1 d . . . . .
H3 H 0.241265 0.048354 -0.087810 0.096 Uiso 1 1 calc R U . . .
H4 H 0.094923 0.101390 -0.067921 0.096 Uiso 1 1 calc R U . . .
C3 C 0.314(3) 0.1813(11) -0.1148(10) 0.071(6) Uani 1 1 d . . . . .
H5 H 0.198858 0.184717 -0.140784 0.085 Uiso 1 1 calc R U . . .
H6 H 0.369673 0.144046 -0.145731 0.085 Uiso 1 1 calc R U . . .
C4 C 0.401(2) 0.2594(9) -0.1056(9) 0.049(4) Uani 1 1 d . . . . .
H7 H 0.515167 0.256490 -0.077711 0.059 Uiso 1 1 calc R U . . .
H8 H 0.405241 0.276562 -0.155826 0.059 Uiso 1 1 calc R U . . .
C5 C 0.382(2) 0.3874(10) -0.0580(9) 0.056(4) Uani 1 1 d . . . . .
H9 H 0.386380 0.404159 -0.108408 0.067 Uiso 1 1 calc R U . . .
H10 H 0.495447 0.389567 -0.028073 0.067 Uiso 1 1 calc R U . . .
C6 C 0.272(2) 0.4388(9) -0.0181(10) 0.060(5) Uani 1 1 d . . . . .
H11 H 0.303433 0.493503 -0.019208 0.073 Uiso 1 1 calc R U . . .
H12 H 0.156027 0.430321 -0.044156 0.073 Uiso 1 1 calc R U . . .
C7 C 0.186(3) 0.4647(10) 0.0970(11) 0.074(6) Uani 1 1 d . . . . .
H13 H 0.070550 0.454073 0.071584 0.089 Uiso 1 1 calc R U . . .
H14 H 0.212249 0.520006 0.095940 0.089 Uiso 1 1 calc R U . . .
C8 C 0.208(3) 0.4461(13) 0.1764(12) 0.083(7) Uani 1 1 d . . . . .
H15 H 0.325433 0.452568 0.200359 0.100 Uiso 1 1 calc R U . . .
H16 H 0.144841 0.482137 0.204817 0.100 Uiso 1 1 calc R U . . .
C9 C 0.181(3) 0.3478(15) 0.2528(12) 0.090(7) Uani 1 1 d . U . . .
H17 H 0.134767 0.385857 0.286501 0.108 Uiso 1 1 calc R U . . .
H18 H 0.300992 0.346297 0.271882 0.108 Uiso 1 1 calc R U . . .
C10 C 0.107(3) 0.2741(16) 0.2535(13) 0.090(7) Uani 1 1 d . U . . .
H19 H -0.011903 0.275289 0.232858 0.108 Uiso 1 1 calc R U . . .
H20 H 0.120905 0.260848 0.306214 0.108 Uiso 1 1 calc R U . . .
C11 C 0.095(2) 0.1398(15) 0.1951(13) 0.088(8) Uani 1 1 d . . . . .
H21 H -0.020062 0.145972 0.169363 0.105 Uiso 1 1 calc R U . . .
H22 H 0.091773 0.119938 0.244313 0.105 Uiso 1 1 calc R U . . .
C12 C 0.178(2) 0.0829(12) 0.1472(12) 0.070(6) Uani 1 1 d . . . . .
H23 H 0.294734 0.078362 0.171018 0.084 Uiso 1 1 calc R U . . .
H24 H 0.122681 0.031518 0.141664 0.084 Uiso 1 1 calc R U . . .
C13 C -0.055(3) 0.6496(15) 0.2397(16) 0.113(8) Uani 1 1 d . . . . .
H25 H -0.157704 0.678242 0.236226 0.135 Uiso 1 1 calc R U . . .
H26 H -0.081219 0.595843 0.217593 0.135 Uiso 1 1 calc R U . . .
C14 C 0.071(3) 0.6890(14) 0.1995(16) 0.103(6) Uani 1 1 d . . . . .
H27 H 0.178748 0.664514 0.210083 0.123 Uiso 1 1 calc R U . . .
H28 H 0.030947 0.683700 0.144159 0.123 Uiso 1 1 calc R U . . .
C15 C 0.204(3) 0.8073(14) 0.2012(12) 0.083(6) Uani 1 1 d . . . . .
H29 H 0.183193 0.798170 0.145370 0.099 Uiso 1 1 calc R U . . .
H30 H 0.313482 0.787493 0.220792 0.099 Uiso 1 1 calc R U . . .
C16 C 0.202(3) 0.8904(13) 0.2243(11) 0.079(5) Uani 1 1 d . . . . .
H31 H 0.278908 0.918312 0.199608 0.095 Uiso 1 1 calc R U . . .
H32 H 0.090396 0.909371 0.208127 0.095 Uiso 1 1 calc R U . . .
C17 C 0.245(3) 0.9806(13) 0.3313(14) 0.091(6) Uani 1 1 d . . . . .
H33 H 0.309031 1.012039 0.303600 0.110 Uiso 1 1 calc R U . . .
H34 H 0.129433 0.996833 0.320837 0.110 Uiso 1 1 calc R U . . .
C18 C 0.305(5) 0.9950(18) 0.4064(17) 0.134(10) Uani 1 1 d . . . . .
H35 H 0.305707 1.051078 0.421086 0.161 Uiso 1 1 calc R U . . .
H36 H 0.419157 0.977820 0.417631 0.161 Uiso 1 1 calc R U . . .
C19 C 0.257(5) 0.965(2) 0.5295(11) 0.164(13) Uani 1 1 d D . . . .
H37 H 0.262749 1.020067 0.548976 0.197 Uiso 1 1 calc R U . . .
H38 H 0.367240 0.943435 0.544273 0.197 Uiso 1 1 calc R U . . .
C20 C 0.128(5) 0.921(2) 0.561(2) 0.167(13) Uani 1 1 d D . . . .
H39 H 0.147770 0.930818 0.616453 0.200 Uiso 1 1 calc R U . . .
H40 H 0.016948 0.938298 0.540144 0.200 Uiso 1 1 calc R U . . .
C21 C 0.049(4) 0.8053(19) 0.5806(18) 0.163(11) Uani 1 1 d D . . . .
H41 H -0.066523 0.820787 0.571247 0.195 Uiso 1 1 calc R U . . .
H42 H 0.094747 0.814578 0.635364 0.195 Uiso 1 1 calc R U . . .
C22 C 0.063(4) 0.7198(18) 0.5516(11) 0.146(10) Uani 1 1 d D U . . .
H43 H 0.180529 0.706353 0.559226 0.176 Uiso 1 1 calc R U . . .
H44 H 0.006757 0.686788 0.581089 0.176 Uiso 1 1 calc R U . . .
C23 C 0.048(5) 0.633(2) 0.443(2) 0.210(17) Uani 1 1 d D U . . .
H45 H 0.031977 0.591940 0.475691 0.252 Uiso 1 1 calc R U . . .
H46 H 0.166810 0.637247 0.441471 0.252 Uiso 1 1 calc R U . . .
C24 C -0.052(7) 0.612(3) 0.362(2) 0.32(3) Uani 1 1 d D U . . .
H47 H -0.052830 0.555601 0.348020 0.379 Uiso 1 1 calc R U . . .
H48 H -0.167145 0.627877 0.359200 0.379 Uiso 1 1 calc R U . . .
C25 C 0.518(4) 0.7678(17) 0.4952(16) 0.136(12) Uani 1 1 d D . . . .
H49 H 0.577259 0.811266 0.481014 0.204 Uiso 1 1 calc R U . . .
H50 H 0.596028 0.729554 0.514206 0.204 Uiso 1 1 calc R U . . .
H51 H 0.456918 0.786045 0.534744 0.204 Uiso 1 1 calc R U . . .
C26 C -0.327(4) 0.840(3) 0.3309(19) 0.30(4) Uani 1 1 d D U . . .
H52 H -0.423184 0.870045 0.312311 0.452 Uiso 1 1 calc R U . . .
H53 H -0.329761 0.791984 0.298343 0.452 Uiso 1 1 calc R U . . .
H54 H -0.329623 0.829063 0.382690 0.452 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 N3 1.916(19) . ?
Pt1 N4 1.968(15) . ?
Pt1 O1 2.001(11) . ?
Pt1 O2 2.012(12) . ?
Pt2 N1 1.875(19) . ?
Pt2 N5 1.990(16) . ?
Pt2 O4 1.995(12) . ?
Pt2 O1 2.043(13) . ?
Pt3 O1 1.977(11) . ?
Pt3 N2 1.981(18) . ?
Pt3 N6 1.991(19) . ?
Pt3 O6 2.008(14) . ?
K1 O11 2.632(13) 1_455 ?
K1 O1 2.750(10) . ?
K1 O14 2.777(14) . ?
K1 O15 2.783(12) . ?
K1 O17 2.803(11) . ?
K1 O18 2.823(13) . ?
K1 O16 2.825(11) . ?
K1 O19 2.836(13) . ?
K2 O22 2.742(16) . ?
K2 O25 2.76(2) . ?
K2 O21 2.770(14) . ?
K2 O26 2.77(2) . ?
K2 O24 2.821(18) . ?
K2 O20 2.83(2) . ?
K2 O23 2.86(2) . ?
K2 O27 2.862(15) . ?
O2 N1 1.338(19) . ?
O3 N1 1.305(19) . ?
O4 N2 1.329(19) . ?
O5 N2 1.208(18) . ?
O6 N3 1.290(19) . ?
O7 N3 1.26(2) . ?
O8 N4 1.27(2) . ?
O9 N4 1.225(19) . ?
O10 N5 1.246(18) . ?
O11 N5 1.211(18) . ?
O12 N6 1.23(2) . ?
O13 N6 1.22(2) . ?
O14 C12 1.39(2) . ?
O14 C1 1.39(3) . ?
O15 C3 1.42(2) . ?
O15 C2 1.46(2) . ?
O16 C4 1.411(19) . ?
O16 C5 1.41(2) . ?
O17 C7 1.38(2) . ?
O17 C6 1.44(2) . ?
O18 C9 1.40(2) . ?
O18 C8 1.41(3) . ?
O19 C11 1.46(3) . ?
O19 C10 1.49(3) . ?
O20 C13 1.38(3) . ?
O20 C24 1.429(19) . ?
O21 C15 1.36(2) . ?
O21 C14 1.45(3) . ?
O22 C17 1.37(2) . ?
O22 C16 1.43(2) . ?
O23 C19 1.426(17) . ?
O23 C18 1.43(4) . ?
O24 C20 1.36(4) . ?
O24 C21 1.386(18) . ?
O25 C22 1.448(18) . ?
O25 C23 1.448(19) . ?
O26 C25 1.447(18) . ?
O27 C26 1.410(19) . ?
C1 C2 1.57(3) . ?
C1 H1 0.9900 . ?
C1 H2 0.9900 . ?
C2 H3 0.9900 . ?
C2 H4 0.9900 . ?
C3 C4 1.51(2) . ?
C3 H5 0.9900 . ?
C3 H6 0.9900 . ?
C4 H7 0.9900 . ?
C4 H8 0.9900 . ?
C5 C6 1.52(2) . ?
C5 H9 0.9900 . ?
C5 H10 0.9900 . ?
C6 H11 0.9900 . ?
C6 H12 0.9900 . ?
C7 C8 1.48(3) . ?
C7 H13 0.9900 . ?
C7 H14 0.9900 . ?
C8 H15 0.9900 . ?
C8 H16 0.9900 . ?
C9 C10 1.42(3) . ?
C9 H17 0.9900 . ?
C9 H18 0.9900 . ?
C10 H19 0.9900 . ?
C10 H20 0.9900 . ?
C11 C12 1.51(3) . ?
C11 H21 0.9900 . ?
C11 H22 0.9900 . ?
C12 H23 0.9900 . ?
C12 H24 0.9900 . ?
C13 C14 1.56(4) . ?
C13 H25 0.9900 . ?
C13 H26 0.9900 . ?
C14 H27 0.9900 . ?
C14 H28 0.9900 . ?
C15 C16 1.47(3) . ?
C15 H29 0.9900 . ?
C15 H30 0.9900 . ?
C16 H31 0.9900 . ?
C16 H32 0.9900 . ?
C17 C18 1.35(3) . ?
C17 H33 0.9900 . ?
C17 H34 0.9900 . ?
C18 H35 0.9900 . ?
C18 H36 0.9900 . ?
C19 C20 1.525(19) . ?
C19 H37 0.9900 . ?
C19 H38 0.9900 . ?
C20 H39 0.9900 . ?
C20 H40 0.9900 . ?
C21 C22 1.550(19) . ?
C21 H41 0.9900 . ?
C21 H42 0.9900 . ?
C22 H43 0.9900 . ?
C22 H44 0.9900 . ?
C23 C24 1.548(19) . ?
C23 H45 0.9900 . ?
C23 H46 0.9900 . ?
C24 H47 0.9900 . ?
C24 H48 0.9900 . ?
C25 H49 0.9800 . ?
C25 H50 0.9800 . ?
C25 H51 0.9800 . ?
C26 H52 0.9800 . ?
C26 H53 0.9800 . ?
C26 H54 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N3 Pt1 N4 92.4(6) . . ?
N3 Pt1 O1 89.5(6) . . ?
N4 Pt1 O1 178.2(6) . . ?
N3 Pt1 O2 177.4(6) . . ?
N4 Pt1 O2 87.3(5) . . ?
O1 Pt1 O2 90.8(5) . . ?
N3 Pt1 Pt3 61.3(5) . . ?
N4 Pt1 Pt3 146.1(4) . . ?
O1 Pt1 Pt3 35.4(3) . . ?
O2 Pt1 Pt3 119.9(3) . . ?
N1 Pt2 N5 93.5(7) . . ?
N1 Pt2 O4 178.1(5) . . ?
N5 Pt2 O4 86.1(6) . . ?
N1 Pt2 O1 90.1(6) . . ?
N5 Pt2 O1 175.8(5) . . ?
O4 Pt2 O1 90.2(5) . . ?
O1 Pt3 N2 92.2(6) . . ?
O1 Pt3 N6 176.5(8) . . ?
N2 Pt3 N6 90.9(7) . . ?
O1 Pt3 O6 88.1(5) . . ?
N2 Pt3 O6 178.2(6) . . ?
N6 Pt3 O6 88.8(7) . . ?
O1 Pt3 Pt1 35.9(3) . . ?
N2 Pt3 Pt1 121.5(5) . . ?
N6 Pt3 Pt1 142.3(5) . . ?
O6 Pt3 Pt1 59.4(4) . . ?
O11 K1 O1 175.6(4) 1_455 . ?
O11 K1 O14 80.7(4) 1_455 . ?
O1 K1 O14 95.6(4) . . ?
O11 K1 O15 83.9(4) 1_455 . ?
O1 K1 O15 92.2(4) . . ?
O14 K1 O15 62.2(4) . . ?
O11 K1 O17 89.0(4) 1_455 . ?
O1 K1 O17 94.7(4) . . ?
O14 K1 O17 169.3(4) . . ?
O15 K1 O17 120.1(4) . . ?
O11 K1 O18 88.5(4) 1_455 . ?
O1 K1 O18 95.3(4) . . ?
O14 K1 O18 115.6(5) . . ?
O15 K1 O18 172.4(4) . . ?
O17 K1 O18 60.6(4) . . ?
O11 K1 O16 76.6(4) 1_455 . ?
O1 K1 O16 103.3(4) . . ?
O14 K1 O16 119.0(4) . . ?
O15 K1 O16 59.7(3) . . ?
O17 K1 O16 60.9(3) . . ?
O18 K1 O16 119.5(4) . . ?
O11 K1 O19 100.0(4) 1_455 . ?
O1 K1 O19 80.1(4) . . ?
O14 K1 O19 60.1(5) . . ?
O15 K1 O19 120.5(4) . . ?
O17 K1 O19 119.3(4) . . ?
O18 K1 O19 59.9(4) . . ?
O16 K1 O19 176.6(4) . . ?
O22 K2 O25 175.0(6) . . ?
O22 K2 O21 61.3(4) . . ?
O25 K2 O21 122.8(7) . . ?
O22 K2 O26 93.4(6) . . ?
O25 K2 O26 83.2(8) . . ?
O21 K2 O26 98.1(5) . . ?
O22 K2 O24 115.8(6) . . ?
O25 K2 O24 60.1(7) . . ?
O21 K2 O24 177.1(6) . . ?
O26 K2 O24 81.9(6) . . ?
O22 K2 O20 118.3(6) . . ?
O25 K2 O20 64.9(8) . . ?
O21 K2 O20 59.2(5) . . ?
O26 K2 O20 80.0(7) . . ?
O24 K2 O20 123.5(7) . . ?
O22 K2 O23 59.5(5) . . ?
O25 K2 O23 117.1(8) . . ?
O21 K2 O23 119.1(5) . . ?
O26 K2 O23 98.2(6) . . ?
O24 K2 O23 58.1(6) . . ?
O20 K2 O23 177.1(8) . . ?
O22 K2 O27 82.9(6) . . ?
O25 K2 O27 100.4(8) . . ?
O21 K2 O27 80.5(5) . . ?
O26 K2 O27 176.3(7) . . ?
O24 K2 O27 99.4(6) . . ?
O20 K2 O27 102.0(7) . . ?
O23 K2 O27 79.7(6) . . ?
Pt3 O1 Pt1 108.6(5) . . ?
Pt3 O1 Pt2 108.0(5) . . ?
Pt1 O1 Pt2 107.7(5) . . ?
Pt3 O1 K1 115.8(5) . . ?
Pt1 O1 K1 113.7(5) . . ?
Pt2 O1 K1 102.4(4) . . ?
N1 O2 Pt1 115.5(10) . . ?
N2 O4 Pt2 118.3(10) . . ?
N3 O6 Pt3 118.5(12) . . ?
N5 O11 K1 127.9(11) . 1_655 ?
C12 O14 C1 109.1(16) . . ?
C12 O14 K1 118.5(13) . . ?
C1 O14 K1 114.9(12) . . ?
C3 O15 C2 108.1(14) . . ?
C3 O15 K1 118.1(10) . . ?
C2 O15 K1 111.3(11) . . ?
C4 O16 C5 111.7(13) . . ?
C4 O16 K1 113.7(8) . . ?
C5 O16 K1 113.5(9) . . ?
C7 O17 C6 111.1(13) . . ?
C7 O17 K1 113.2(11) . . ?
C6 O17 K1 113.3(9) . . ?
C9 O18 C8 113.0(18) . . ?
C9 O18 K1 113.8(13) . . ?
C8 O18 K1 113.3(12) . . ?
C11 O19 C10 113.7(17) . . ?
C11 O19 K1 112.5(12) . . ?
C10 O19 K1 114.1(11) . . ?
C13 O20 C24 115(3) . . ?
C13 O20 K2 113.6(15) . . ?
C24 O20 K2 108(2) . . ?
C15 O21 C14 111.8(19) . . ?
C15 O21 K2 112.6(12) . . ?
C14 O21 K2 117.1(14) . . ?
C17 O22 C16 114.0(17) . . ?
C17 O22 K2 114.6(15) . . ?
C16 O22 K2 113.9(11) . . ?
C19 O23 C18 117(3) . . ?
C19 O23 K2 116.0(18) . . ?
C18 O23 K2 112.1(15) . . ?
C20 O24 C21 107(3) . . ?
C20 O24 K2 116.0(17) . . ?
C21 O24 K2 119.4(18) . . ?
C22 O25 C23 109(3) . . ?
C22 O25 K2 113.4(16) . . ?
C23 O25 K2 100(2) . . ?
C25 O26 K2 119.4(18) . . ?
C26 O27 K2 113(2) . . ?
O3 N1 O2 108.4(16) . . ?
O3 N1 Pt2 127.7(12) . . ?
O2 N1 Pt2 123.9(12) . . ?
O5 N2 O4 117.8(16) . . ?
O5 N2 Pt3 122.3(14) . . ?
O4 N2 Pt3 119.4(11) . . ?
O7 N3 O6 113.7(18) . . ?
O7 N3 Pt1 125.3(13) . . ?
O6 N3 Pt1 120.8(13) . . ?
O9 N4 O8 116.7(15) . . ?
O9 N4 Pt1 122.8(14) . . ?
O8 N4 Pt1 120.6(12) . . ?
O11 N5 O10 122.1(16) . . ?
O11 N5 Pt2 120.1(12) . . ?
O10 N5 Pt2 117.8(13) . . ?
O13 N6 O12 124(2) . . ?
O13 N6 Pt3 120.2(17) . . ?
O12 N6 Pt3 116.0(17) . . ?
O14 C1 C2 108.6(17) . . ?
O14 C1 H1 110.0 . . ?
C2 C1 H1 110.0 . . ?
O14 C1 H2 110.0 . . ?
C2 C1 H2 110.0 . . ?
H1 C1 H2 108.3 . . ?
O15 C2 C1 106.3(16) . . ?
O15 C2 H3 110.5 . . ?
C1 C2 H3 110.5 . . ?
O15 C2 H4 110.5 . . ?
C1 C2 H4 110.5 . . ?
H3 C2 H4 108.7 . . ?
O15 C3 C4 108.6(14) . . ?
O15 C3 H5 110.0 . . ?
C4 C3 H5 110.0 . . ?
O15 C3 H6 110.0 . . ?
C4 C3 H6 110.0 . . ?
H5 C3 H6 108.4 . . ?
O16 C4 C3 108.4(15) . . ?
O16 C4 H7 110.0 . . ?
C3 C4 H7 110.0 . . ?
O16 C4 H8 110.0 . . ?
C3 C4 H8 110.0 . . ?
H7 C4 H8 108.4 . . ?
O16 C5 C6 106.5(14) . . ?
O16 C5 H9 110.4 . . ?
C6 C5 H9 110.4 . . ?
O16 C5 H10 110.4 . . ?
C6 C5 H10 110.4 . . ?
H9 C5 H10 108.6 . . ?
O17 C6 C5 109.1(13) . . ?
O17 C6 H11 109.9 . . ?
C5 C6 H11 109.9 . . ?
O17 C6 H12 109.9 . . ?
C5 C6 H12 109.9 . . ?
H11 C6 H12 108.3 . . ?
O17 C7 C8 109.9(16) . . ?
O17 C7 H13 109.7 . . ?
C8 C7 H13 109.7 . . ?
O17 C7 H14 109.7 . . ?
C8 C7 H14 109.7 . . ?
H13 C7 H14 108.2 . . ?
O18 C8 C7 110.7(17) . . ?
O18 C8 H15 109.5 . . ?
C7 C8 H15 109.5 . . ?
O18 C8 H16 109.5 . . ?
C7 C8 H16 109.5 . . ?
H15 C8 H16 108.1 . . ?
O18 C9 C10 110(2) . . ?
O18 C9 H17 109.6 . . ?
C10 C9 H17 109.6 . . ?
O18 C9 H18 109.6 . . ?
C10 C9 H18 109.6 . . ?
H17 C9 H18 108.1 . . ?
C9 C10 O19 111.0(18) . . ?
C9 C10 H19 109.4 . . ?
O19 C10 H19 109.4 . . ?
C9 C10 H20 109.4 . . ?
O19 C10 H20 109.4 . . ?
H19 C10 H20 108.0 . . ?
O19 C11 C12 110.3(16) . . ?
O19 C11 H21 109.6 . . ?
C12 C11 H21 109.6 . . ?
O19 C11 H22 109.6 . . ?
C12 C11 H22 109.6 . . ?
H21 C11 H22 108.1 . . ?
O14 C12 C11 106.8(16) . . ?
O14 C12 H23 110.4 . . ?
C11 C12 H23 110.4 . . ?
O14 C12 H24 110.4 . . ?
C11 C12 H24 110.4 . . ?
H23 C12 H24 108.6 . . ?
O20 C13 C14 103(2) . . ?
O20 C13 H25 111.2 . . ?
C14 C13 H25 111.2 . . ?
O20 C13 H26 111.2 . . ?
C14 C13 H26 111.2 . . ?
H25 C13 H26 109.1 . . ?
O21 C14 C13 108(2) . . ?
O21 C14 H27 110.2 . . ?
C13 C14 H27 110.2 . . ?
O21 C14 H28 110.2 . . ?
C13 C14 H28 110.2 . . ?
H27 C14 H28 108.5 . . ?
O21 C15 C16 110.0(19) . . ?
O21 C15 H29 109.7 . . ?
C16 C15 H29 109.7 . . ?
O21 C15 H30 109.7 . . ?
C16 C15 H30 109.7 . . ?
H29 C15 H30 108.2 . . ?
O22 C16 C15 110.0(17) . . ?
O22 C16 H31 109.7 . . ?
C15 C16 H31 109.7 . . ?
O22 C16 H32 109.7 . . ?
C15 C16 H32 109.7 . . ?
H31 C16 H32 108.2 . . ?
C18 C17 O22 114(2) . . ?
C18 C17 H33 108.8 . . ?
O22 C17 H33 108.8 . . ?
C18 C17 H34 108.8 . . ?
O22 C17 H34 108.8 . . ?
H33 C17 H34 107.7 . . ?
C17 C18 O23 111(3) . . ?
C17 C18 H35 109.4 . . ?
O23 C18 H35 109.4 . . ?
C17 C18 H36 109.4 . . ?
O23 C18 H36 109.4 . . ?
H35 C18 H36 108.0 . . ?
O23 C19 C20 106(2) . . ?
O23 C19 H37 110.6 . . ?
C20 C19 H37 110.6 . . ?
O23 C19 H38 110.6 . . ?
C20 C19 H38 110.6 . . ?
H37 C19 H38 108.7 . . ?
O24 C20 C19 107(3) . . ?
O24 C20 H39 110.2 . . ?
C19 C20 H39 110.2 . . ?
O24 C20 H40 110.2 . . ?
C19 C20 H40 110.2 . . ?
H39 C20 H40 108.5 . . ?
O24 C21 C22 104(3) . . ?
O24 C21 H41 110.9 . . ?
C22 C21 H41 110.9 . . ?
O24 C21 H42 110.9 . . ?
C22 C21 H42 110.9 . . ?
H41 C21 H42 108.9 . . ?
O25 C22 C21 111(3) . . ?
O25 C22 H43 109.4 . . ?
C21 C22 H43 109.4 . . ?
O25 C22 H44 109.4 . . ?
C21 C22 H44 109.4 . . ?
H43 C22 H44 108.0 . . ?
O25 C23 C24 108(4) . . ?
O25 C23 H45 110.2 . . ?
C24 C23 H45 110.2 . . ?
O25 C23 H46 110.2 . . ?
C24 C23 H46 110.2 . . ?
H45 C23 H46 108.5 . . ?
O20 C24 C23 106(3) . . ?
O20 C24 H47 110.6 . . ?
C23 C24 H47 110.6 . . ?
O20 C24 H48 110.6 . . ?
C23 C24 H48 110.6 . . ?
H47 C24 H48 108.7 . . ?
O26 C25 H49 109.5 . . ?
O26 C25 H50 109.5 . . ?
H49 C25 H50 109.5 . . ?
O26 C25 H51 109.5 . . ?
H49 C25 H51 109.5 . . ?
H50 C25 H51 109.5 . . ?
O27 C26 H52 109.5 . . ?
O27 C26 H53 109.5 . . ?
H52 C26 H53 109.5 . . ?
O27 C26 H54 109.5 . . ?
H52 C26 H54 109.5 . . ?
H53 C26 H54 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Pt1 O2 N1 O3 -175.3(9) . . . . ?
Pt1 O2 N1 Pt2 5.0(15) . . . . ?
N5 Pt2 N1 O3 -21.7(14) . . . . ?
O1 Pt2 N1 O3 156.2(14) . . . . ?
N5 Pt2 N1 O2 157.9(12) . . . . ?
O1 Pt2 N1 O2 -24.2(12) . . . . ?
Pt2 O4 N2 O5 -178.2(13) . . . . ?
Pt2 O4 N2 Pt3 -6.2(17) . . . . ?
Pt3 O6 N3 O7 -175.3(11) . . . . ?
Pt3 O6 N3 Pt1 -0.2(17) . . . . ?
K1 O11 N5 O10 99.5(18) 1_655 . . . ?
K1 O11 N5 Pt2 -78.6(16) 1_655 . . . ?
C12 O14 C1 C2 177.0(16) . . . . ?
K1 O14 C1 C2 -47(2) . . . . ?
C3 O15 C2 C1 174.6(17) . . . . ?
K1 O15 C2 C1 -54.2(19) . . . . ?
O14 C1 C2 O15 69(2) . . . . ?
C2 O15 C3 C4 169.9(16) . . . . ?
K1 O15 C3 C4 42.5(19) . . . . ?
C5 O16 C4 C3 -176.8(13) . . . . ?
K1 O16 C4 C3 53.2(14) . . . . ?
O15 C3 C4 O16 -63.1(19) . . . . ?
C4 O16 C5 C6 176.7(12) . . . . ?
K1 O16 C5 C6 -53.1(14) . . . . ?
C7 O17 C6 C5 -178.0(16) . . . . ?
K1 O17 C6 C5 -49.2(17) . . . . ?
O16 C5 C6 O17 69.1(17) . . . . ?
C6 O17 C7 C8 -179.2(17) . . . . ?
K1 O17 C7 C8 52(2) . . . . ?
C9 O18 C8 C7 175.8(19) . . . . ?
K1 O18 C8 C7 44(2) . . . . ?
O17 C7 C8 O18 -66(2) . . . . ?
C8 O18 C9 C10 173.5(19) . . . . ?
K1 O18 C9 C10 -55(2) . . . . ?
O18 C9 C10 O19 63(2) . . . . ?
C11 O19 C10 C9 -169.9(17) . . . . ?
K1 O19 C10 C9 -39(2) . . . . ?
C10 O19 C11 C12 179.1(15) . . . . ?
K1 O19 C11 C12 47.4(16) . . . . ?
C1 O14 C12 C11 -176.5(17) . . . . ?
K1 O14 C12 C11 49.4(18) . . . . ?
O19 C11 C12 O14 -64(2) . . . . ?
C24 O20 C13 C14 -173(4) . . . . ?
K2 O20 C13 C14 61(3) . . . . ?
C15 O21 C14 C13 175.0(18) . . . . ?
K2 O21 C14 C13 43(2) . . . . ?
O20 C13 C14 O21 -68(3) . . . . ?
C14 O21 C15 C16 173.0(18) . . . . ?
K2 O21 C15 C16 -53(2) . . . . ?
C17 O22 C16 C15 -177(2) . . . . ?
K2 O22 C16 C15 -43(2) . . . . ?
O21 C15 C16 O22 66(2) . . . . ?
C16 O22 C17 C18 -174(3) . . . . ?
K2 O22 C17 C18 52(3) . . . . ?
O22 C17 C18 O23 -64(4) . . . . ?
K2 C17 C18 O23 -30(2) . . . . ?
C19 O23 C18 C17 179(3) . . . . ?
K2 O23 C18 C17 41(3) . . . . ?
C18 O23 C19 C20 177(3) . . . . ?
K2 O23 C19 C20 -47(3) . . . . ?
C21 O24 C20 C19 168(2) . . . . ?
K2 O24 C20 C19 -57(3) . . . . ?
O23 C19 C20 O24 68(3) . . . . ?
C20 O24 C21 C22 178(2) . . . . ?
K2 O24 C21 C22 44(3) . . . . ?
C23 O25 C22 C21 163(3) . . . . ?
K2 O25 C22 C21 53(3) . . . . ?
O24 C21 C22 O25 -63(3) . . . . ?
C22 O25 C23 C24 171(2) . . . . ?
K2 O25 C23 C24 -70(3) . . . . ?
C13 O20 C24 C23 -172(3) . . . . ?
K2 O20 C24 C23 -43(5) . . . . ?
O25 C23 C24 O20 84(5) . . . . ?

_refine_diff_density_max         3.136
_refine_diff_density_min         -2.054
_refine_diff_density_rms         0.267


####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_3
_database_code_depnum_ccdc_archive 'CCDC 1873238'
_audit_update_record             
;
2018-10-15 deposited with the CCDC.
2018-11-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/1
_shelx_SHELXL_version_number     2018/1
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C24 H48 Ag2 N6 O25 Pt3, C3 H6 O'
_chemical_formula_sum            'C27 H54 Ag2 N6 O26 Pt3'
_chemical_formula_weight         1679.77

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -4.5932 6.9264 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   15.8083(3)
_cell_length_b                   16.2005(3)
_cell_length_c                   18.9885(3)
_cell_angle_alpha                68.585(5)
_cell_angle_beta                 84.549(6)
_cell_angle_gamma                87.459(6)
_cell_volume                     4506.5(2)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    45735
_cell_measurement_theta_min      3.09
_cell_measurement_theta_max      68.33

_exptl_crystal_description       rod
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.476
_exptl_crystal_F_000             3176
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.050
_exptl_crystal_size_min          0.050
_exptl_absorpt_coefficient_mu    24.676
_shelx_estimated_absorpt_T_min   0.083
_shelx_estimated_absorpt_T_max   0.372
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.3868
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_process_details   'ABSCOR (Rigaku, 2010)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     1.54187
_diffrn_radiation_type           CuK\a
_diffrn_source                   'rotating-anode X-ray tube'
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean 10.000
_diffrn_reflns_number            80654
_diffrn_reflns_av_unetI/netI     0.1119
_diffrn_reflns_av_R_equivalents  0.1174
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         3.090
_diffrn_reflns_theta_max         68.252
_diffrn_reflns_theta_full        67.687
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measured_fraction_theta_full 0.985
_diffrn_reflns_Laue_measured_fraction_max 0.984
_diffrn_reflns_Laue_measured_fraction_full 0.985
_diffrn_reflns_point_group_measured_fraction_max 0.984
_diffrn_reflns_point_group_measured_fraction_full 0.985
_reflns_number_total             16233
_reflns_number_gt                10191
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'RAPID AUTO (Rigaku, 2015)'
_computing_cell_refinement       'RAPID AUTO (Rigaku, 2015)'
_computing_data_reduction        'RAPID AUTO (Rigaku, 2015)'
_computing_structure_solution    'SHELXT-2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2018/1 (Sheldrick, 2018)'
_computing_molecular_graphics    'ORTEP-3 (Farrugia, 2012)'
_computing_publication_material  'SHELXL-2018/1 (Sheldrick, 2018)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0651P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         16233
_refine_ls_number_parameters     1157
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0994
_refine_ls_R_factor_gt           0.0644
_refine_ls_wR_factor_ref         0.1673
_refine_ls_wR_factor_gt          0.1474
_refine_ls_goodness_of_fit_ref   0.986
_refine_ls_restrained_S_all      0.986
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.39806(3) 0.77415(3) 0.27368(3) 0.03074(15) Uani 1 1 d . . . . .
Pt2 Pt 0.24401(3) 0.67248(3) 0.39511(3) 0.03201(15) Uani 1 1 d . . . . .
Pt3 Pt 0.20569(3) 0.81607(3) 0.23013(3) 0.03372(15) Uani 1 1 d . . . . .
Pt4 Pt 0.39881(3) 0.29050(3) 0.27571(3) 0.03114(15) Uani 1 1 d . . . . .
Pt5 Pt 0.25136(3) 0.17856(3) 0.39400(3) 0.03112(15) Uani 1 1 d . . . . .
Pt6 Pt 0.20506(3) 0.32003(3) 0.23217(3) 0.03230(15) Uani 1 1 d . . . . .
Ag1 Ag 0.24976(6) 0.89363(7) 0.38587(5) 0.0452(3) Uani 1 1 d . . . . .
Ag2 Ag 0.68002(5) 0.70905(6) 0.16102(5) 0.0375(2) Uani 1 1 d . . . . .
Ag3 Ag 0.24458(6) 0.40536(6) 0.38802(5) 0.0423(3) Uani 1 1 d . . . . .
Ag4 Ag 0.67926(5) 0.21254(6) 0.16570(5) 0.0366(2) Uani 1 1 d . . . . .
O1 O 0.2807(4) 0.7904(5) 0.3174(4) 0.0339(19) Uani 1 1 d . . . . .
O2 O 0.4239(5) 0.6775(5) 0.3707(5) 0.043(2) Uani 1 1 d . . . . .
O3 O 0.3800(5) 0.5900(5) 0.4819(4) 0.037(2) Uani 1 1 d . . . . .
O4 O 0.1222(5) 0.7012(6) 0.3703(5) 0.042(2) Uani 1 1 d . . . . .
O5 O 0.0364(5) 0.7641(6) 0.2880(5) 0.050(2) Uani 1 1 d . . . . .
O6 O 0.3012(5) 0.8873(5) 0.1573(5) 0.044(2) Uani 1 1 d . . . . .
O7 O 0.4337(5) 0.9149(5) 0.1358(4) 0.038(2) Uani 1 1 d . . . . .
O8 O 0.5765(5) 0.7526(6) 0.2673(5) 0.045(2) Uani 1 1 d . . . . .
O9 O 0.5245(5) 0.7364(6) 0.1738(5) 0.048(2) Uani 1 1 d . . . . .
O10 O 0.1410(7) 0.5570(6) 0.5176(6) 0.078(4) Uani 1 1 d . . . . .
O11 O 0.2374(6) 0.4859(6) 0.4793(5) 0.061(3) Uani 1 1 d . . . . .
O12 O 0.1358(6) 0.9177(7) 0.0934(6) 0.062(3) Uani 1 1 d . . . . .
O13 O 0.1001(6) 0.7794(7) 0.1331(6) 0.070(3) Uani 1 1 d . . . . .
O14 O 0.4119(5) 0.9584(6) 0.3310(5) 0.049(2) Uani 1 1 d . . . . .
O15 O 0.3911(5) 0.7960(5) 0.4590(5) 0.046(2) Uani 1 1 d . . . . .
O16 O 0.2288(6) 0.7994(6) 0.5321(5) 0.050(2) Uani 1 1 d . . . . .
O17 O 0.0889(5) 0.8642(6) 0.4470(6) 0.054(3) Uani 1 1 d . . . . .
O18 O 0.1062(7) 0.9677(8) 0.2916(6) 0.092(4) Uani 1 1 d . . . . .
O19 O 0.2666(6) 1.0440(6) 0.2634(5) 0.065(3) Uani 1 1 d . . . . .
O20 O 0.7808(5) 0.6724(5) 0.2645(5) 0.039(2) Uani 1 1 d . . . . .
O21 O 0.6565(5) 0.5500(5) 0.2660(5) 0.043(2) Uani 1 1 d . . . . .
O22 O 0.6595(5) 0.5516(6) 0.1190(5) 0.043(2) Uani 1 1 d . . . . .
O23 O 0.6189(5) 0.7222(5) 0.0278(5) 0.043(2) Uani 1 1 d . . . . .
O24 O 0.6757(5) 0.8691(5) 0.0580(4) 0.038(2) Uani 1 1 d . . . . .
O25 O 0.8202(5) 0.8132(6) 0.1323(5) 0.041(2) Uani 1 1 d . . . . .
O26 O 0.2796(4) 0.3016(5) 0.3181(4) 0.0331(19) Uani 1 1 d . . . . .
O27 O 0.4290(5) 0.2069(5) 0.3768(4) 0.044(2) Uani 1 1 d . . . . .
O28 O 0.3871(5) 0.1103(5) 0.4843(4) 0.042(2) Uani 1 1 d . . . . .
O29 O 0.1293(5) 0.1938(5) 0.3692(5) 0.039(2) Uani 1 1 d . . . . .
O30 O 0.0380(5) 0.2634(6) 0.2940(5) 0.044(2) Uani 1 1 d . . . . .
O31 O 0.2976(5) 0.3911(5) 0.1567(4) 0.039(2) Uani 1 1 d . . . . .
O32 O 0.4293(5) 0.4254(5) 0.1332(4) 0.038(2) Uani 1 1 d . . . . .
O33 O 0.5780(5) 0.2739(6) 0.2706(5) 0.048(2) Uani 1 1 d . . . . .
O34 O 0.5275(5) 0.2521(6) 0.1790(5) 0.048(2) Uani 1 1 d . . . . .
O35 O 0.1617(6) 0.0457(6) 0.5142(6) 0.066(3) Uani 1 1 d . . . . .
O36 O 0.2656(6) -0.0078(6) 0.4620(5) 0.058(3) Uani 1 1 d . . . . .
O37 O 0.1327(6) 0.4172(7) 0.0948(6) 0.061(3) Uani 1 1 d . . . . .
O38 O 0.0993(6) 0.2777(6) 0.1385(5) 0.057(3) Uani 1 1 d . . . . .
O39 O 0.3994(5) 0.4703(5) 0.3650(5) 0.044(2) Uani 1 1 d . . . . .
O40 O 0.3585(5) 0.3128(5) 0.4948(5) 0.042(2) Uani 1 1 d . . . . .
O41 O 0.1845(5) 0.2949(6) 0.5229(5) 0.050(2) Uani 1 1 d . . . . .
O42 O 0.0681(5) 0.3635(6) 0.4083(5) 0.056(3) Uani 1 1 d . . . . .
O43 O 0.1338(6) 0.5321(7) 0.3136(6) 0.080(4) Uani 1 1 d . . . . .
O44 O 0.2943(5) 0.5227(6) 0.2474(5) 0.048(2) Uani 1 1 d . . . . .
O45 O 0.7840(5) 0.1834(5) 0.2650(4) 0.040(2) Uani 1 1 d . . . . .
O46 O 0.6542(5) 0.0601(5) 0.2823(4) 0.038(2) Uani 1 1 d . . . . .
O47 O 0.6523(5) 0.0439(5) 0.1429(5) 0.042(2) Uani 1 1 d . . . . .
O48 O 0.6148(5) 0.2083(6) 0.0387(4) 0.041(2) Uani 1 1 d . . . . .
O49 O 0.6783(5) 0.3658(5) 0.0517(4) 0.036(2) Uani 1 1 d . . . . .
O50 O 0.8231(4) 0.3133(5) 0.1251(4) 0.036(2) Uani 1 1 d . . . . .
N1 N 0.3598(6) 0.6423(7) 0.4215(6) 0.041(3) Uani 1 1 d . . . . .
N2 N 0.1114(6) 0.7553(7) 0.3006(6) 0.040(3) Uani 1 1 d . . . . .
N3 N 0.3771(6) 0.8695(6) 0.1789(5) 0.029(2) Uani 1 1 d . . . . .
N4 N 0.5154(6) 0.7534(6) 0.2328(6) 0.030(2) Uani 1 1 d . . . . .
N5 N 0.2019(6) 0.5561(7) 0.4736(6) 0.041(3) Uani 1 1 d . . . . .
N6 N 0.1370(7) 0.8414(8) 0.1410(6) 0.047(3) Uani 1 1 d . . . . .
N7 N 0.3675(6) 0.1630(7) 0.4238(6) 0.042(3) Uani 1 1 d . . . . .
N8 N 0.1132(6) 0.2547(7) 0.3038(6) 0.042(3) Uani 1 1 d . . . . .
N9 N 0.3758(6) 0.3777(6) 0.1783(6) 0.038(3) Uani 1 1 d . . . . .
N10 N 0.5172(6) 0.2707(7) 0.2373(6) 0.035(3) Uani 1 1 d . . . . .
N11 N 0.2225(7) 0.0549(7) 0.4659(6) 0.044(3) Uani 1 1 d . . . . .
N12 N 0.1358(6) 0.3416(8) 0.1441(6) 0.043(3) Uani 1 1 d . . . . .
C1 C 0.4652(7) 0.9340(9) 0.3930(8) 0.045(4) Uani 1 1 d . . . . .
H1 H 0.440190 0.956304 0.432588 0.054 Uiso 1 1 calc R U . . .
H2 H 0.522375 0.959889 0.374855 0.054 Uiso 1 1 calc R U . . .
C2 C 0.4711(8) 0.8387(8) 0.4235(7) 0.049(4) Uani 1 1 d . . . . .
H3 H 0.513706 0.820566 0.461438 0.059 Uiso 1 1 calc R U . . .
H4 H 0.491493 0.817629 0.381984 0.059 Uiso 1 1 calc R U . . .
C3 C 0.3761(9) 0.7895(9) 0.5347(8) 0.057(4) Uani 1 1 d . . . . .
H5 H 0.374649 0.849504 0.537222 0.068 Uiso 1 1 calc R U . . .
H6 H 0.422880 0.755368 0.564122 0.068 Uiso 1 1 calc R U . . .
C4 C 0.2955(8) 0.7454(9) 0.5679(7) 0.045(4) Uani 1 1 d . . . . .
H7 H 0.294666 0.687648 0.561254 0.055 Uiso 1 1 calc R U . . .
H8 H 0.288693 0.734355 0.622964 0.055 Uiso 1 1 calc R U . . .
C5 C 0.1464(9) 0.7630(9) 0.5552(7) 0.055(4) Uani 1 1 d . . . . .
H9 H 0.138438 0.736103 0.611229 0.065 Uiso 1 1 calc R U . . .
H10 H 0.138976 0.716300 0.534277 0.065 Uiso 1 1 calc R U . . .
C6 C 0.0845(8) 0.8334(10) 0.5274(8) 0.059(4) Uani 1 1 d . . . . .
H11 H 0.026786 0.811173 0.548695 0.071 Uiso 1 1 calc R U . . .
H12 H 0.096030 0.882877 0.543876 0.071 Uiso 1 1 calc R U . . .
C7 C 0.0355(8) 0.9375(10) 0.4158(8) 0.063(4) Uani 1 1 d . . . . .
H13 H 0.060289 0.991820 0.417235 0.075 Uiso 1 1 calc R U . . .
H14 H -0.020925 0.928059 0.444747 0.075 Uiso 1 1 calc R U . . .
C8 C 0.0276(8) 0.9461(11) 0.3382(9) 0.072(5) Uani 1 1 d . . . . .
H15 H 0.006511 0.889650 0.337839 0.087 Uiso 1 1 calc R U . . .
H16 H -0.014983 0.992942 0.316272 0.087 Uiso 1 1 calc R U . . .
C9 C 0.1203(9) 1.0545(10) 0.2541(10) 0.078(6) Uani 1 1 d . . . . .
H17 H 0.114852 1.085446 0.290661 0.094 Uiso 1 1 calc R U . . .
H18 H 0.076601 1.079304 0.217660 0.094 Uiso 1 1 calc R U . . .
C10 C 0.2049(9) 1.0711(9) 0.2128(7) 0.052(4) Uani 1 1 d . . . . .
H19 H 0.211784 1.038348 0.177557 0.062 Uiso 1 1 calc R U . . .
H20 H 0.211121 1.135148 0.182416 0.062 Uiso 1 1 calc R U . . .
C11 C 0.3497(9) 1.0726(9) 0.2341(8) 0.056(4) Uani 1 1 d . . . . .
H21 H 0.349336 1.137864 0.208280 0.067 Uiso 1 1 calc R U . . .
H22 H 0.369637 1.046225 0.195817 0.067 Uiso 1 1 calc R U . . .
C12 C 0.4077(9) 1.0481(10) 0.2925(9) 0.060(4) Uani 1 1 d . . . . .
H23 H 0.465056 1.069821 0.269292 0.072 Uiso 1 1 calc R U . . .
H24 H 0.389522 1.077501 0.329004 0.072 Uiso 1 1 calc R U . . .
C13 C 0.7820(8) 0.5841(9) 0.3159(7) 0.048(4) Uani 1 1 d . . . . .
H25 H 0.805141 0.581184 0.363433 0.058 Uiso 1 1 calc R U . . .
H26 H 0.818517 0.547065 0.293610 0.058 Uiso 1 1 calc R U . . .
C14 C 0.6930(7) 0.5508(8) 0.3323(6) 0.038(3) Uani 1 1 d . . . . .
H27 H 0.692397 0.489856 0.370675 0.045 Uiso 1 1 calc R U . . .
H28 H 0.657390 0.588731 0.354216 0.045 Uiso 1 1 calc R U . . .
C15 C 0.6818(8) 0.4745(8) 0.2435(7) 0.047(4) Uani 1 1 d . . . . .
H29 H 0.743659 0.476775 0.228602 0.056 Uiso 1 1 calc R U . . .
H30 H 0.669843 0.418526 0.287042 0.056 Uiso 1 1 calc R U . . .
C16 C 0.6353(8) 0.4766(9) 0.1799(7) 0.047(4) Uani 1 1 d . . . . .
H31 H 0.649004 0.423118 0.167326 0.056 Uiso 1 1 calc R U . . .
H32 H 0.573350 0.478194 0.193202 0.056 Uiso 1 1 calc R U . . .
C17 C 0.6056(8) 0.5697(9) 0.0588(7) 0.048(4) Uani 1 1 d . . . . .
H33 H 0.545640 0.572928 0.078218 0.058 Uiso 1 1 calc R U . . .
H34 H 0.611064 0.521467 0.038330 0.058 Uiso 1 1 calc R U . . .
C18 C 0.6298(8) 0.6539(8) -0.0011(7) 0.044(3) Uani 1 1 d . . . . .
H35 H 0.689890 0.650824 -0.020216 0.053 Uiso 1 1 calc R U . . .
H36 H 0.594063 0.665818 -0.043953 0.053 Uiso 1 1 calc R U . . .
C19 C 0.6268(9) 0.8068(9) -0.0298(8) 0.055(4) Uani 1 1 d . . . . .
H37 H 0.583898 0.814878 -0.066557 0.065 Uiso 1 1 calc R U . . .
H38 H 0.683976 0.813070 -0.057407 0.065 Uiso 1 1 calc R U . . .
C20 C 0.6140(8) 0.8738(8) 0.0056(7) 0.045(3) Uani 1 1 d . . . . .
H39 H 0.616095 0.933446 -0.034760 0.054 Uiso 1 1 calc R U . . .
H40 H 0.556625 0.866455 0.032904 0.054 Uiso 1 1 calc R U . . .
C21 C 0.7547(8) 0.9032(8) 0.0221(7) 0.044(3) Uani 1 1 d . . . . .
H41 H 0.747857 0.964301 -0.014838 0.053 Uiso 1 1 calc R U . . .
H42 H 0.781272 0.865989 -0.005436 0.053 Uiso 1 1 calc R U . . .
C22 C 0.8093(8) 0.9033(8) 0.0831(7) 0.044(3) Uani 1 1 d . . . . .
H43 H 0.865147 0.929910 0.060017 0.053 Uiso 1 1 calc R U . . .
H44 H 0.781401 0.938412 0.112019 0.053 Uiso 1 1 calc R U . . .
C23 C 0.8568(7) 0.8060(9) 0.1998(7) 0.046(4) Uani 1 1 d . . . . .
H45 H 0.820671 0.837130 0.227907 0.056 Uiso 1 1 calc R U . . .
H46 H 0.913813 0.833044 0.187247 0.056 Uiso 1 1 calc R U . . .
C24 C 0.8634(8) 0.7100(8) 0.2468(7) 0.040(3) Uani 1 1 d . . . . .
H47 H 0.900036 0.679244 0.218572 0.048 Uiso 1 1 calc R U . . .
H48 H 0.889426 0.702475 0.294182 0.048 Uiso 1 1 calc R U . . .
C25 C 0.4592(7) 0.4156(9) 0.4121(7) 0.040(3) Uani 1 1 d . . . . .
H49 H 0.509166 0.451171 0.410754 0.048 Uiso 1 1 calc R U . . .
H50 H 0.478856 0.368010 0.393240 0.048 Uiso 1 1 calc R U . . .
C26 C 0.4205(9) 0.3755(9) 0.4919(8) 0.061(4) Uani 1 1 d . . . . .
H51 H 0.465049 0.345723 0.526177 0.073 Uiso 1 1 calc R U . . .
H52 H 0.393517 0.422382 0.508552 0.073 Uiso 1 1 calc R U . . .
C27 C 0.3146(7) 0.2783(7) 0.5685(6) 0.034(3) Uani 1 1 d . . . . .
H53 H 0.352465 0.236778 0.604268 0.040 Uiso 1 1 calc R U . . .
H54 H 0.299085 0.327433 0.586648 0.040 Uiso 1 1 calc R U . . .
C28 C 0.2398(8) 0.2332(8) 0.5677(7) 0.047(4) Uani 1 1 d . . . . .
H55 H 0.254099 0.186221 0.546637 0.057 Uiso 1 1 calc R U . . .
H56 H 0.212927 0.205173 0.619981 0.057 Uiso 1 1 calc R U . . .
C29 C 0.1001(8) 0.2671(9) 0.5296(7) 0.049(4) Uani 1 1 d . . . . .
H57 H 0.077961 0.244951 0.583704 0.059 Uiso 1 1 calc R U . . .
H58 H 0.098151 0.218102 0.510443 0.059 Uiso 1 1 calc R U . . .
C30 C 0.0476(8) 0.3407(8) 0.4865(8) 0.050(4) Uani 1 1 d . . . . .
H59 H -0.013001 0.324003 0.498985 0.059 Uiso 1 1 calc R U . . .
H60 H 0.056099 0.392533 0.500682 0.059 Uiso 1 1 calc R U . . .
C31 C 0.0199(8) 0.4323(10) 0.3587(10) 0.072(5) Uani 1 1 d . . . . .
H61 H 0.024297 0.427196 0.308070 0.086 Uiso 1 1 calc R U . . .
H62 H -0.040694 0.426141 0.378465 0.086 Uiso 1 1 calc R U . . .
C32 C 0.0481(9) 0.5144(12) 0.3517(11) 0.102(7) Uani 1 1 d . . . . .
H63 H 0.047756 0.517574 0.402789 0.122 Uiso 1 1 calc R U . . .
H64 H 0.008605 0.560646 0.322416 0.122 Uiso 1 1 calc R U . . .
C33 C 0.1470(9) 0.5467(10) 0.2364(8) 0.062(5) Uani 1 1 d . . . . .
H65 H 0.104215 0.589773 0.208582 0.075 Uiso 1 1 calc R U . . .
H66 H 0.139983 0.490405 0.228413 0.075 Uiso 1 1 calc R U . . .
C34 C 0.2301(8) 0.5801(8) 0.2077(7) 0.044(3) Uani 1 1 d . . . . .
H67 H 0.238978 0.588064 0.153292 0.052 Uiso 1 1 calc R U . . .
H68 H 0.234980 0.638848 0.211745 0.052 Uiso 1 1 calc R U . . .
C35 C 0.3722(8) 0.5683(8) 0.2430(8) 0.050(4) Uani 1 1 d . . . . .
H69 H 0.360237 0.618820 0.260045 0.061 Uiso 1 1 calc R U . . .
H70 H 0.397397 0.591733 0.189772 0.061 Uiso 1 1 calc R U . . .
C36 C 0.4314(8) 0.5071(9) 0.2907(7) 0.044(3) Uani 1 1 d . . . . .
H71 H 0.446111 0.459172 0.270886 0.052 Uiso 1 1 calc R U . . .
H72 H 0.484324 0.538942 0.288185 0.052 Uiso 1 1 calc R U . . .
C37 C 0.7797(8) 0.1006(8) 0.3240(7) 0.045(4) Uani 1 1 d . . . . .
H73 H 0.803920 0.104676 0.368803 0.054 Uiso 1 1 calc R U . . .
H74 H 0.813942 0.056839 0.307969 0.054 Uiso 1 1 calc R U . . .
C38 C 0.6905(7) 0.0704(8) 0.3448(7) 0.040(3) Uani 1 1 d . . . . .
H75 H 0.688751 0.012998 0.388098 0.048 Uiso 1 1 calc R U . . .
H76 H 0.656497 0.114054 0.361057 0.048 Uiso 1 1 calc R U . . .
C39 C 0.6798(8) -0.0186(8) 0.2691(7) 0.051(4) Uani 1 1 d . . . . .
H77 H 0.669259 -0.070664 0.316534 0.061 Uiso 1 1 calc R U . . .
H78 H 0.741393 -0.016503 0.253328 0.061 Uiso 1 1 calc R U . . .
C40 C 0.6318(8) -0.0278(9) 0.2089(8) 0.052(4) Uani 1 1 d . . . . .
H79 H 0.647649 -0.083977 0.201358 0.062 Uiso 1 1 calc R U . . .
H80 H 0.569917 -0.028184 0.223434 0.062 Uiso 1 1 calc R U . . .
C41 C 0.5961(7) 0.0539(8) 0.0875(7) 0.041(3) Uani 1 1 d . . . . .
H81 H 0.537475 0.063363 0.106733 0.049 Uiso 1 1 calc R U . . .
H82 H 0.597065 -0.000220 0.074779 0.049 Uiso 1 1 calc R U . . .
C42 C 0.6231(7) 0.1315(8) 0.0189(7) 0.041(3) Uani 1 1 d . . . . .
H83 H 0.682883 0.123718 0.001376 0.049 Uiso 1 1 calc R U . . .
H84 H 0.586999 0.137586 -0.022545 0.049 Uiso 1 1 calc R U . . .
C43 C 0.6268(8) 0.2882(8) -0.0249(7) 0.047(4) Uani 1 1 d . . . . .
H85 H 0.584543 0.292963 -0.061486 0.056 Uiso 1 1 calc R U . . .
H86 H 0.684287 0.288466 -0.050706 0.056 Uiso 1 1 calc R U . . .
C44 C 0.6169(7) 0.3649(8) 0.0008(7) 0.041(3) Uani 1 1 d . . . . .
H87 H 0.621853 0.420439 -0.044312 0.049 Uiso 1 1 calc R U . . .
H88 H 0.559237 0.363715 0.026435 0.049 Uiso 1 1 calc R U . . .
C45 C 0.7584(7) 0.3991(8) 0.0145(7) 0.043(3) Uani 1 1 d . . . . .
H89 H 0.751797 0.459269 -0.023998 0.052 Uiso 1 1 calc R U . . .
H90 H 0.784860 0.360013 -0.011273 0.052 Uiso 1 1 calc R U . . .
C46 C 0.8136(7) 0.4022(8) 0.0748(6) 0.037(3) Uani 1 1 d . . . . .
H91 H 0.869671 0.427795 0.051258 0.044 Uiso 1 1 calc R U . . .
H92 H 0.785986 0.439001 0.102322 0.044 Uiso 1 1 calc R U . . .
O51 O 0.9161(7) 0.5301(7) 0.1698(6) 0.070(3) Uani 1 1 d . . . . .
C47 C 0.8540(8) 0.6457(10) 0.0707(8) 0.069(5) Uani 1 1 d . . . . .
H97 H 0.850532 0.646125 0.019307 0.104 Uiso 1 1 calc R U . . .
H98 H 0.863318 0.706116 0.068235 0.104 Uiso 1 1 calc R U . . .
H99 H 0.800710 0.623235 0.101455 0.104 Uiso 1 1 calc R U . . .
C48 C 0.9262(10) 0.5870(10) 0.1060(9) 0.058(4) Uani 1 1 d . . . . .
C49 C 1.0101(8) 0.6113(11) 0.0644(8) 0.084(6) Uani 1 1 d . . . . .
H100 H 1.027252 0.667992 0.065907 0.126 Uiso 1 1 calc R U . . .
H101 H 1.007214 0.616901 0.011529 0.126 Uiso 1 1 calc R U . . .
H102 H 1.051745 0.565227 0.088042 0.126 Uiso 1 1 calc R U . . .
O52 O 0.9124(6) 0.0280(6) 0.1722(6) 0.065(3) Uani 1 1 d . . . . .
C50 C 0.8492(8) 0.1393(10) 0.0720(8) 0.062(4) Uani 1 1 d . . . . .
H103 H 0.843016 0.133904 0.022981 0.092 Uiso 1 1 calc R U . . .
H104 H 0.859078 0.201457 0.064165 0.092 Uiso 1 1 calc R U . . .
H105 H 0.797138 0.119063 0.105455 0.092 Uiso 1 1 calc R U . . .
C51 C 0.9229(9) 0.0836(10) 0.1076(9) 0.055(4) Uani 1 1 d . . . . .
C52 C 1.0068(9) 0.1034(12) 0.0640(8) 0.090(6) Uani 1 1 d . . . . .
H106 H 1.027685 0.159300 0.064283 0.135 Uiso 1 1 calc R U . . .
H107 H 1.001445 0.108537 0.011559 0.135 Uiso 1 1 calc R U . . .
H108 H 1.046901 0.055369 0.087245 0.135 Uiso 1 1 calc R U . . .
C53 C 0.8680(8) 0.3057(9) 0.1886(7) 0.047(4) Uani 1 1 d . . . . .
H93 H 0.839888 0.342793 0.215658 0.056 Uiso 1 1 calc R U . . .
H94 H 0.926823 0.327068 0.171159 0.056 Uiso 1 1 calc R U . . .
C54 C 0.8697(7) 0.2120(8) 0.2406(7) 0.037(3) Uani 1 1 d . . . . .
H95 H 0.898970 0.174860 0.214169 0.045 Uiso 1 1 calc R U . . .
H96 H 0.900904 0.206234 0.285033 0.045 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 N3 1.942(9) . ?
Pt1 O2 1.998(8) . ?
Pt1 O1 2.006(7) . ?
Pt1 N4 2.005(9) . ?
Pt1 Pt3 3.2058(7) . ?
Pt1 Pt2 3.2365(7) . ?
Pt2 N1 1.938(10) . ?
Pt2 O1 2.010(7) . ?
Pt2 N5 2.022(10) . ?
Pt2 O4 2.020(8) . ?
Pt3 N2 1.942(9) . ?
Pt3 N6 2.004(11) . ?
Pt3 O6 2.030(8) . ?
Pt3 O1 2.037(7) . ?
Pt4 N9 1.929(10) . ?
Pt4 O27 1.992(8) . ?
Pt4 O26 2.004(7) . ?
Pt4 N10 1.999(9) . ?
Pt4 Pt5 3.1895(7) . ?
Pt4 Pt6 3.2179(7) . ?
Pt5 N7 1.951(10) . ?
Pt5 O29 2.012(8) . ?
Pt5 N11 2.013(11) . ?
Pt5 O26 2.027(7) . ?
Pt5 Pt6 3.2196(7) . ?
Pt6 N8 1.946(10) . ?
Pt6 N12 2.000(10) . ?
Pt6 O31 2.017(7) . ?
Pt6 O26 2.030(7) . ?
Ag1 O1 2.475(7) . ?
Ag1 O36 2.548(9) 1_565 ?
Ag2 O9 2.484(8) . ?
Ag2 O20 2.532(8) . ?
Ag3 O26 2.510(7) . ?
Ag3 O11 2.514(9) . ?
Ag4 O34 2.470(7) . ?
Ag4 O45 2.528(8) . ?
O2 N1 1.322(11) . ?
O3 N1 1.213(11) . ?
O4 N2 1.315(12) . ?
O5 N2 1.225(11) . ?
O6 N3 1.291(11) . ?
O7 N3 1.221(10) . ?
O8 N4 1.216(10) . ?
O9 N4 1.241(11) . ?
O10 N5 1.217(11) . ?
O11 N5 1.218(11) . ?
O12 N6 1.236(12) . ?
O13 N6 1.245(13) . ?
O14 C12 1.370(14) . ?
O14 C1 1.440(13) . ?
O15 C3 1.400(14) . ?
O15 C2 1.452(12) . ?
O16 C4 1.400(13) . ?
O16 C5 1.417(14) . ?
O17 C7 1.402(14) . ?
O17 C6 1.417(15) . ?
O18 C9 1.342(14) . ?
O18 C8 1.432(15) . ?
O19 C10 1.377(14) . ?
O19 C11 1.406(14) . ?
O20 C13 1.408(13) . ?
O20 C24 1.423(12) . ?
O21 C14 1.437(12) . ?
O21 C15 1.463(13) . ?
O22 C16 1.375(13) . ?
O22 C17 1.426(13) . ?
O23 C18 1.402(12) . ?
O23 C19 1.409(14) . ?
O24 C21 1.398(13) . ?
O24 C20 1.438(13) . ?
O25 C23 1.418(13) . ?
O25 C22 1.430(13) . ?
O27 N7 1.295(10) . ?
O28 N7 1.214(11) . ?
O29 N8 1.312(11) . ?
O30 N8 1.216(11) . ?
O31 N9 1.324(11) . ?
O32 N9 1.218(10) . ?
O33 N10 1.213(11) . ?
O34 N10 1.243(11) . ?
O35 N11 1.238(12) . ?
O36 N11 1.219(12) . ?
O37 N12 1.243(12) . ?
O38 N12 1.250(12) . ?
O39 C36 1.370(13) . ?
O39 C25 1.410(13) . ?
O40 C27 1.425(12) . ?
O40 C26 1.426(13) . ?
O41 C28 1.389(13) . ?
O41 C29 1.406(13) . ?
O42 C30 1.401(14) . ?
O42 C31 1.416(15) . ?
O43 C33 1.394(15) . ?
O43 C32 1.463(15) . ?
O44 C34 1.419(13) . ?
O44 C35 1.444(13) . ?
O45 C37 1.399(12) . ?
O45 C54 1.430(12) . ?
O46 C39 1.422(14) . ?
O46 C38 1.432(12) . ?
O47 C40 1.385(14) . ?
O47 C41 1.401(13) . ?
O48 C43 1.417(13) . ?
O48 C42 1.422(12) . ?
O49 C45 1.417(12) . ?
O49 C44 1.437(13) . ?
O50 C46 1.419(12) . ?
O50 C53 1.421(13) . ?
C1 C2 1.440(15) . ?
C1 H1 0.9900 . ?
C1 H2 0.9900 . ?
C2 H3 0.9900 . ?
C2 H4 0.9900 . ?
C3 C4 1.460(16) . ?
C3 H5 0.9900 . ?
C3 H6 0.9900 . ?
C4 H7 0.9900 . ?
C4 H8 0.9900 . ?
C5 C6 1.447(17) . ?
C5 H9 0.9900 . ?
C5 H10 0.9900 . ?
C6 H11 0.9900 . ?
C6 H12 0.9900 . ?
C7 C8 1.444(19) . ?
C7 H13 0.9900 . ?
C7 H14 0.9900 . ?
C8 H15 0.9900 . ?
C8 H16 0.9900 . ?
C9 C10 1.468(17) . ?
C9 H17 0.9900 . ?
C9 H18 0.9900 . ?
C10 H19 0.9900 . ?
C10 H20 0.9900 . ?
C11 C12 1.438(18) . ?
C11 H21 0.9900 . ?
C11 H22 0.9900 . ?
C12 H23 0.9900 . ?
C12 H24 0.9900 . ?
C13 C14 1.493(15) . ?
C13 H25 0.9900 . ?
C13 H26 0.9900 . ?
C14 H27 0.9900 . ?
C14 H28 0.9900 . ?
C15 C16 1.462(16) . ?
C15 H29 0.9900 . ?
C15 H30 0.9900 . ?
C16 H31 0.9900 . ?
C16 H32 0.9900 . ?
C17 C18 1.459(16) . ?
C17 H33 0.9900 . ?
C17 H34 0.9900 . ?
C18 H35 0.9900 . ?
C18 H36 0.9900 . ?
C19 C20 1.470(16) . ?
C19 H37 0.9900 . ?
C19 H38 0.9900 . ?
C20 H39 0.9900 . ?
C20 H40 0.9900 . ?
C21 C22 1.509(16) . ?
C21 H41 0.9900 . ?
C21 H42 0.9900 . ?
C22 H43 0.9900 . ?
C22 H44 0.9900 . ?
C23 C24 1.489(15) . ?
C23 H45 0.9900 . ?
C23 H46 0.9900 . ?
C24 H47 0.9900 . ?
C24 H48 0.9900 . ?
C25 C26 1.493(16) . ?
C25 H49 0.9900 . ?
C25 H50 0.9900 . ?
C26 H51 0.9900 . ?
C26 H52 0.9900 . ?
C27 C28 1.420(15) . ?
C27 H53 0.9900 . ?
C27 H54 0.9900 . ?
C28 H55 0.9900 . ?
C28 H56 0.9900 . ?
C29 C30 1.452(16) . ?
C29 H57 0.9900 . ?
C29 H58 0.9900 . ?
C30 H59 0.9900 . ?
C30 H60 0.9900 . ?
C31 C32 1.377(19) . ?
C31 H61 0.9900 . ?
C31 H62 0.9900 . ?
C32 H63 0.9900 . ?
C32 H64 0.9900 . ?
C33 C34 1.424(17) . ?
C33 H65 0.9900 . ?
C33 H66 0.9900 . ?
C34 H67 0.9900 . ?
C34 H68 0.9900 . ?
C35 C36 1.450(17) . ?
C35 H69 0.9900 . ?
C35 H70 0.9900 . ?
C36 H71 0.9900 . ?
C36 H72 0.9900 . ?
C37 C38 1.483(15) . ?
C37 H73 0.9900 . ?
C37 H74 0.9900 . ?
C38 H75 0.9900 . ?
C38 H76 0.9900 . ?
C39 C40 1.483(17) . ?
C39 H77 0.9900 . ?
C39 H78 0.9900 . ?
C40 H79 0.9900 . ?
C40 H80 0.9900 . ?
C41 C42 1.485(15) . ?
C41 H81 0.9900 . ?
C41 H82 0.9900 . ?
C42 H83 0.9900 . ?
C42 H84 0.9900 . ?
C43 C44 1.488(16) . ?
C43 H85 0.9900 . ?
C43 H86 0.9900 . ?
C44 H87 0.9900 . ?
C44 H88 0.9900 . ?
C45 C46 1.518(16) . ?
C45 H89 0.9900 . ?
C45 H90 0.9900 . ?
C46 H91 0.9900 . ?
C46 H92 0.9900 . ?
O51 C48 1.226(16) . ?
C47 C48 1.497(19) . ?
C47 H97 0.9800 . ?
C47 H98 0.9800 . ?
C47 H99 0.9800 . ?
C48 C49 1.469(17) . ?
C49 H100 0.9800 . ?
C49 H101 0.9800 . ?
C49 H102 0.9800 . ?
O52 C51 1.229(16) . ?
C50 C51 1.497(19) . ?
C50 H103 0.9800 . ?
C50 H104 0.9800 . ?
C50 H105 0.9800 . ?
C51 C52 1.478(17) . ?
C52 H106 0.9800 . ?
C52 H107 0.9800 . ?
C52 H108 0.9800 . ?
C53 C54 1.479(15) . ?
C53 H93 0.9900 . ?
C53 H94 0.9900 . ?
C54 H95 0.9900 . ?
C54 H96 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N3 Pt1 O2 177.9(3) . . ?
N3 Pt1 O1 90.3(3) . . ?
O2 Pt1 O1 91.4(3) . . ?
N3 Pt1 N4 91.7(4) . . ?
O2 Pt1 N4 86.7(3) . . ?
O1 Pt1 N4 177.9(3) . . ?
N3 Pt1 Pt3 61.6(3) . . ?
O2 Pt1 Pt3 120.4(2) . . ?
O1 Pt1 Pt3 37.9(2) . . ?
N4 Pt1 Pt3 143.1(3) . . ?
N3 Pt1 Pt2 121.7(3) . . ?
O2 Pt1 Pt2 60.3(2) . . ?
O1 Pt1 Pt2 36.3(2) . . ?
N4 Pt1 Pt2 141.6(3) . . ?
Pt3 Pt1 Pt2 60.413(15) . . ?
N1 Pt2 O1 91.3(4) . . ?
N1 Pt2 N5 91.1(4) . . ?
O1 Pt2 N5 177.5(3) . . ?
N1 Pt2 O4 178.4(4) . . ?
O1 Pt2 O4 90.2(3) . . ?
N5 Pt2 O4 87.4(4) . . ?
N1 Pt2 Pt1 61.4(3) . . ?
O1 Pt2 Pt1 36.26(19) . . ?
N5 Pt2 Pt1 146.2(3) . . ?
O4 Pt2 Pt1 120.2(2) . . ?
N2 Pt3 N6 91.8(5) . . ?
N2 Pt3 O6 176.1(4) . . ?
N6 Pt3 O6 88.2(4) . . ?
N2 Pt3 O1 90.7(4) . . ?
N6 Pt3 O1 177.2(4) . . ?
O6 Pt3 O1 89.4(3) . . ?
N2 Pt3 Pt1 121.0(3) . . ?
N6 Pt3 Pt1 140.0(3) . . ?
O6 Pt3 Pt1 60.7(2) . . ?
O1 Pt3 Pt1 37.21(19) . . ?
N9 Pt4 O27 175.6(4) . . ?
N9 Pt4 O26 91.1(3) . . ?
O27 Pt4 O26 90.8(3) . . ?
N9 Pt4 N10 91.9(4) . . ?
O27 Pt4 N10 86.4(4) . . ?
O26 Pt4 N10 176.2(4) . . ?
N9 Pt4 Pt5 122.1(3) . . ?
O27 Pt4 Pt5 61.3(2) . . ?
O26 Pt4 Pt5 38.0(2) . . ?
N10 Pt4 Pt5 138.2(3) . . ?
N9 Pt4 Pt6 61.8(3) . . ?
O27 Pt4 Pt6 121.6(2) . . ?
O26 Pt4 Pt6 37.4(2) . . ?
N10 Pt4 Pt6 143.4(3) . . ?
Pt5 Pt4 Pt6 60.327(15) . . ?
N7 Pt5 O29 176.8(4) . . ?
N7 Pt5 N11 90.6(4) . . ?
O29 Pt5 N11 87.9(4) . . ?
N7 Pt5 O26 90.3(4) . . ?
O29 Pt5 O26 91.2(3) . . ?
N11 Pt5 O26 177.8(4) . . ?
N7 Pt5 Pt4 61.3(3) . . ?
O29 Pt5 Pt4 121.2(2) . . ?
N11 Pt5 Pt4 142.0(3) . . ?
O26 Pt5 Pt4 37.46(19) . . ?
N7 Pt5 Pt6 121.5(3) . . ?
O29 Pt5 Pt6 61.0(2) . . ?
N11 Pt5 Pt6 140.6(3) . . ?
O26 Pt5 Pt6 37.5(2) . . ?
Pt4 Pt5 Pt6 60.274(16) . . ?
N8 Pt6 N12 91.7(4) . . ?
N8 Pt6 O31 178.1(4) . . ?
N12 Pt6 O31 87.2(4) . . ?
N8 Pt6 O26 90.9(4) . . ?
N12 Pt6 O26 177.3(4) . . ?
O31 Pt6 O26 90.1(3) . . ?
N8 Pt6 Pt4 120.8(3) . . ?
N12 Pt6 Pt4 141.0(3) . . ?
O31 Pt6 Pt4 60.8(2) . . ?
O26 Pt6 Pt4 36.82(19) . . ?
N8 Pt6 Pt5 61.4(3) . . ?
N12 Pt6 Pt5 144.8(4) . . ?
O31 Pt6 Pt5 120.2(2) . . ?
O26 Pt6 Pt5 37.4(2) . . ?
Pt4 Pt6 Pt5 59.399(16) . . ?
O1 Ag1 O36 162.6(3) . 1_565 ?
O9 Ag2 O20 126.8(3) . . ?
O26 Ag3 O11 165.4(3) . . ?
O34 Ag4 O45 126.3(3) . . ?
Pt1 O1 Pt2 107.4(3) . . ?
Pt1 O1 Pt3 104.9(3) . . ?
Pt2 O1 Pt3 106.5(3) . . ?
Pt1 O1 Ag1 122.2(3) . . ?
Pt2 O1 Ag1 103.2(3) . . ?
Pt3 O1 Ag1 111.6(3) . . ?
N1 O2 Pt1 118.0(7) . . ?
N2 O4 Pt2 115.8(6) . . ?
N3 O6 Pt3 116.6(7) . . ?
N4 O9 Ag2 102.3(7) . . ?
N5 O11 Ag3 128.3(8) . . ?
C12 O14 C1 113.0(11) . . ?
C3 O15 C2 112.5(10) . . ?
C4 O16 C5 115.8(10) . . ?
C7 O17 C6 112.9(10) . . ?
C9 O18 C8 115.7(12) . . ?
C10 O19 C11 116.3(11) . . ?
C13 O20 C24 111.8(9) . . ?
C13 O20 Ag2 116.8(7) . . ?
C24 O20 Ag2 119.4(7) . . ?
C14 O21 C15 115.1(9) . . ?
C16 O22 C17 112.0(10) . . ?
C18 O23 C19 112.3(10) . . ?
C21 O24 C20 113.2(9) . . ?
C23 O25 C22 112.6(10) . . ?
Pt4 O26 Pt6 105.8(3) . . ?
Pt4 O26 Pt5 104.6(3) . . ?
Pt6 O26 Pt5 105.0(3) . . ?
Pt4 O26 Ag3 120.7(3) . . ?
Pt6 O26 Ag3 113.4(3) . . ?
Pt5 O26 Ag3 105.8(3) . . ?
N7 O27 Pt4 117.2(7) . . ?
N8 O29 Pt5 116.8(6) . . ?
N9 O31 Pt6 116.5(7) . . ?
N10 O34 Ag4 106.2(7) . . ?
N11 O36 Ag1 130.3(8) . 1_545 ?
C36 O39 C25 112.5(9) . . ?
C27 O40 C26 110.8(9) . . ?
C28 O41 C29 115.8(10) . . ?
C30 O42 C31 117.5(11) . . ?
C33 O43 C32 119.6(13) . . ?
C34 O44 C35 112.8(10) . . ?
C37 O45 C54 112.0(9) . . ?
C37 O45 Ag4 116.6(7) . . ?
C54 O45 Ag4 118.6(7) . . ?
C39 O46 C38 114.4(9) . . ?
C40 O47 C41 112.1(10) . . ?
C43 O48 C42 113.0(9) . . ?
C45 O49 C44 113.7(9) . . ?
C46 O50 C53 113.2(9) . . ?
O3 N1 O2 115.0(9) . . ?
O3 N1 Pt2 125.1(8) . . ?
O2 N1 Pt2 119.9(8) . . ?
O5 N2 O4 112.0(9) . . ?
O5 N2 Pt3 125.7(9) . . ?
O4 N2 Pt3 122.2(7) . . ?
O7 N3 O6 116.0(9) . . ?
O7 N3 Pt1 123.0(7) . . ?
O6 N3 Pt1 121.0(7) . . ?
O8 N4 O9 120.2(10) . . ?
O8 N4 Pt1 120.6(8) . . ?
O9 N4 Pt1 119.2(7) . . ?
O11 N5 O10 119.4(11) . . ?
O11 N5 Pt2 121.8(8) . . ?
O10 N5 Pt2 118.7(9) . . ?
O12 N6 O13 121.8(12) . . ?
O12 N6 Pt3 118.9(9) . . ?
O13 N6 Pt3 119.2(9) . . ?
O28 N7 O27 116.5(10) . . ?
O28 N7 Pt5 123.2(8) . . ?
O27 N7 Pt5 120.2(8) . . ?
O30 N8 O29 113.4(9) . . ?
O30 N8 Pt6 125.8(9) . . ?
O29 N8 Pt6 120.8(7) . . ?
O32 N9 O31 114.8(10) . . ?
O32 N9 Pt4 124.4(8) . . ?
O31 N9 Pt4 120.8(7) . . ?
O33 N10 O34 120.0(10) . . ?
O33 N10 Pt4 121.6(8) . . ?
O34 N10 Pt4 118.4(8) . . ?
O36 N11 O35 122.2(11) . . ?
O36 N11 Pt5 119.8(9) . . ?
O35 N11 Pt5 118.0(9) . . ?
O37 N12 O38 121.3(11) . . ?
O37 N12 Pt6 119.6(9) . . ?
O38 N12 Pt6 119.0(9) . . ?
O14 C1 C2 107.3(10) . . ?
O14 C1 H1 110.2 . . ?
C2 C1 H1 110.2 . . ?
O14 C1 H2 110.2 . . ?
C2 C1 H2 110.2 . . ?
H1 C1 H2 108.5 . . ?
C1 C2 O15 113.5(10) . . ?
C1 C2 H3 108.9 . . ?
O15 C2 H3 108.9 . . ?
C1 C2 H4 108.9 . . ?
O15 C2 H4 108.9 . . ?
H3 C2 H4 107.7 . . ?
O15 C3 C4 110.3(11) . . ?
O15 C3 H5 109.6 . . ?
C4 C3 H5 109.6 . . ?
O15 C3 H6 109.6 . . ?
C4 C3 H6 109.6 . . ?
H5 C3 H6 108.1 . . ?
O16 C4 C3 109.2(12) . . ?
O16 C4 H7 109.8 . . ?
C3 C4 H7 109.8 . . ?
O16 C4 H8 109.8 . . ?
C3 C4 H8 109.8 . . ?
H7 C4 H8 108.3 . . ?
O16 C5 C6 108.5(11) . . ?
O16 C5 H9 110.0 . . ?
C6 C5 H9 110.0 . . ?
O16 C5 H10 110.0 . . ?
C6 C5 H10 110.0 . . ?
H9 C5 H10 108.4 . . ?
O17 C6 C5 109.8(11) . . ?
O17 C6 H11 109.7 . . ?
C5 C6 H11 109.7 . . ?
O17 C6 H12 109.7 . . ?
C5 C6 H12 109.7 . . ?
H11 C6 H12 108.2 . . ?
O17 C7 C8 107.0(13) . . ?
O17 C7 H13 110.3 . . ?
C8 C7 H13 110.3 . . ?
O17 C7 H14 110.3 . . ?
C8 C7 H14 110.3 . . ?
H13 C7 H14 108.6 . . ?
O18 C8 C7 112.9(13) . . ?
O18 C8 H15 109.0 . . ?
C7 C8 H15 109.0 . . ?
O18 C8 H16 109.0 . . ?
C7 C8 H16 109.0 . . ?
H15 C8 H16 107.8 . . ?
O18 C9 C10 112.1(13) . . ?
O18 C9 H17 109.2 . . ?
C10 C9 H17 109.2 . . ?
O18 C9 H18 109.2 . . ?
C10 C9 H18 109.2 . . ?
H17 C9 H18 107.9 . . ?
O19 C10 C9 109.9(12) . . ?
O19 C10 H19 109.7 . . ?
C9 C10 H19 109.7 . . ?
O19 C10 H20 109.7 . . ?
C9 C10 H20 109.7 . . ?
H19 C10 H20 108.2 . . ?
O19 C11 C12 112.0(11) . . ?
O19 C11 H21 109.2 . . ?
C12 C11 H21 109.2 . . ?
O19 C11 H22 109.2 . . ?
C12 C11 H22 109.2 . . ?
H21 C11 H22 107.9 . . ?
O14 C12 C11 112.8(13) . . ?
O14 C12 H23 109.0 . . ?
C11 C12 H23 109.0 . . ?
O14 C12 H24 109.0 . . ?
C11 C12 H24 109.0 . . ?
H23 C12 H24 107.8 . . ?
O20 C13 C14 108.1(10) . . ?
O20 C13 H25 110.1 . . ?
C14 C13 H25 110.1 . . ?
O20 C13 H26 110.1 . . ?
C14 C13 H26 110.1 . . ?
H25 C13 H26 108.4 . . ?
O21 C14 C13 113.1(9) . . ?
O21 C14 H27 109.0 . . ?
C13 C14 H27 109.0 . . ?
O21 C14 H28 109.0 . . ?
C13 C14 H28 109.0 . . ?
H27 C14 H28 107.8 . . ?
C16 C15 O21 110.2(10) . . ?
C16 C15 H29 109.6 . . ?
O21 C15 H29 109.6 . . ?
C16 C15 H30 109.6 . . ?
O21 C15 H30 109.6 . . ?
H29 C15 H30 108.1 . . ?
O22 C16 C15 107.6(11) . . ?
O22 C16 H31 110.2 . . ?
C15 C16 H31 110.2 . . ?
O22 C16 H32 110.2 . . ?
C15 C16 H32 110.2 . . ?
H31 C16 H32 108.5 . . ?
O22 C17 C18 109.3(11) . . ?
O22 C17 H33 109.8 . . ?
C18 C17 H33 109.8 . . ?
O22 C17 H34 109.8 . . ?
C18 C17 H34 109.8 . . ?
H33 C17 H34 108.3 . . ?
O23 C18 C17 109.3(10) . . ?
O23 C18 H35 109.8 . . ?
C17 C18 H35 109.8 . . ?
O23 C18 H36 109.8 . . ?
C17 C18 H36 109.8 . . ?
H35 C18 H36 108.3 . . ?
O23 C19 C20 108.4(10) . . ?
O23 C19 H37 110.0 . . ?
C20 C19 H37 110.0 . . ?
O23 C19 H38 110.0 . . ?
C20 C19 H38 110.0 . . ?
H37 C19 H38 108.4 . . ?
O24 C20 C19 113.8(10) . . ?
O24 C20 H39 108.8 . . ?
C19 C20 H39 108.8 . . ?
O24 C20 H40 108.8 . . ?
C19 C20 H40 108.8 . . ?
H39 C20 H40 107.7 . . ?
O24 C21 C22 107.2(10) . . ?
O24 C21 H41 110.3 . . ?
C22 C21 H41 110.3 . . ?
O24 C21 H42 110.3 . . ?
C22 C21 H42 110.3 . . ?
H41 C21 H42 108.5 . . ?
O25 C22 C21 107.6(10) . . ?
O25 C22 H43 110.2 . . ?
C21 C22 H43 110.2 . . ?
O25 C22 H44 110.2 . . ?
C21 C22 H44 110.2 . . ?
H43 C22 H44 108.5 . . ?
O25 C23 C24 107.7(11) . . ?
O25 C23 H45 110.2 . . ?
C24 C23 H45 110.2 . . ?
O25 C23 H46 110.2 . . ?
C24 C23 H46 110.2 . . ?
H45 C23 H46 108.5 . . ?
O20 C24 C23 109.3(10) . . ?
O20 C24 H47 109.8 . . ?
C23 C24 H47 109.8 . . ?
O20 C24 H48 109.8 . . ?
C23 C24 H48 109.8 . . ?
H47 C24 H48 108.3 . . ?
O39 C25 C26 110.3(10) . . ?
O39 C25 H49 109.6 . . ?
C26 C25 H49 109.6 . . ?
O39 C25 H50 109.6 . . ?
C26 C25 H50 109.6 . . ?
H49 C25 H50 108.1 . . ?
O40 C26 C25 108.7(11) . . ?
O40 C26 H51 110.0 . . ?
C25 C26 H51 110.0 . . ?
O40 C26 H52 110.0 . . ?
C25 C26 H52 110.0 . . ?
H51 C26 H52 108.3 . . ?
C28 C27 O40 111.3(10) . . ?
C28 C27 H53 109.4 . . ?
O40 C27 H53 109.4 . . ?
C28 C27 H54 109.4 . . ?
O40 C27 H54 109.4 . . ?
H53 C27 H54 108.0 . . ?
O41 C28 C27 108.0(11) . . ?
O41 C28 H55 110.1 . . ?
C27 C28 H55 110.1 . . ?
O41 C28 H56 110.1 . . ?
C27 C28 H56 110.1 . . ?
H55 C28 H56 108.4 . . ?
O41 C29 C30 110.0(11) . . ?
O41 C29 H57 109.7 . . ?
C30 C29 H57 109.7 . . ?
O41 C29 H58 109.7 . . ?
C30 C29 H58 109.7 . . ?
H57 C29 H58 108.2 . . ?
O42 C30 C29 111.0(11) . . ?
O42 C30 H59 109.4 . . ?
C29 C30 H59 109.4 . . ?
O42 C30 H60 109.4 . . ?
C29 C30 H60 109.4 . . ?
H59 C30 H60 108.0 . . ?
C32 C31 O42 111.1(15) . . ?
C32 C31 H61 109.4 . . ?
O42 C31 H61 109.4 . . ?
C32 C31 H62 109.4 . . ?
O42 C31 H62 109.4 . . ?
H61 C31 H62 108.0 . . ?
C31 C32 O43 112.1(14) . . ?
C31 C32 H63 109.2 . . ?
O43 C32 H63 109.2 . . ?
C31 C32 H64 109.2 . . ?
O43 C32 H64 109.2 . . ?
H63 C32 H64 107.9 . . ?
O43 C33 C34 110.3(12) . . ?
O43 C33 H65 109.6 . . ?
C34 C33 H65 109.6 . . ?
O43 C33 H66 109.6 . . ?
C34 C33 H66 109.6 . . ?
H65 C33 H66 108.1 . . ?
O44 C34 C33 112.3(11) . . ?
O44 C34 H67 109.2 . . ?
C33 C34 H67 109.1 . . ?
O44 C34 H68 109.1 . . ?
C33 C34 H68 109.1 . . ?
H67 C34 H68 107.9 . . ?
O44 C35 C36 109.4(10) . . ?
O44 C35 H69 109.8 . . ?
C36 C35 H69 109.8 . . ?
O44 C35 H70 109.8 . . ?
C36 C35 H70 109.8 . . ?
H69 C35 H70 108.2 . . ?
O39 C36 C35 112.7(11) . . ?
O39 C36 H71 109.0 . . ?
C35 C36 H71 109.0 . . ?
O39 C36 H72 109.0 . . ?
C35 C36 H72 109.0 . . ?
H71 C36 H72 107.8 . . ?
O45 C37 C38 110.8(10) . . ?
O45 C37 H73 109.5 . . ?
C38 C37 H73 109.5 . . ?
O45 C37 H74 109.5 . . ?
C38 C37 H74 109.5 . . ?
H73 C37 H74 108.1 . . ?
O46 C38 C37 111.3(10) . . ?
O46 C38 H75 109.4 . . ?
C37 C38 H75 109.4 . . ?
O46 C38 H76 109.4 . . ?
C37 C38 H76 109.4 . . ?
H75 C38 H76 108.0 . . ?
O46 C39 C40 110.2(10) . . ?
O46 C39 H77 109.6 . . ?
C40 C39 H77 109.6 . . ?
O46 C39 H78 109.6 . . ?
C40 C39 H78 109.6 . . ?
H77 C39 H78 108.1 . . ?
O47 C40 C39 107.3(10) . . ?
O47 C40 H79 110.3 . . ?
C39 C40 H79 110.3 . . ?
O47 C40 H80 110.3 . . ?
C39 C40 H80 110.3 . . ?
H79 C40 H80 108.5 . . ?
O47 C41 C42 108.4(10) . . ?
O47 C41 H81 110.0 . . ?
C42 C41 H81 110.0 . . ?
O47 C41 H82 110.0 . . ?
C42 C41 H82 110.0 . . ?
H81 C41 H82 108.4 . . ?
O48 C42 C41 107.9(9) . . ?
O48 C42 H83 110.1 . . ?
C41 C42 H83 110.1 . . ?
O48 C42 H84 110.1 . . ?
C41 C42 H84 110.1 . . ?
H83 C42 H84 108.4 . . ?
O48 C43 C44 109.4(10) . . ?
O48 C43 H85 109.8 . . ?
C44 C43 H85 109.8 . . ?
O48 C43 H86 109.8 . . ?
C44 C43 H86 109.8 . . ?
H85 C43 H86 108.2 . . ?
O49 C44 C43 113.8(10) . . ?
O49 C44 H87 108.8 . . ?
C43 C44 H87 108.8 . . ?
O49 C44 H88 108.8 . . ?
C43 C44 H88 108.8 . . ?
H87 C44 H88 107.7 . . ?
O49 C45 C46 107.3(9) . . ?
O49 C45 H89 110.3 . . ?
C46 C45 H89 110.3 . . ?
O49 C45 H90 110.3 . . ?
C46 C45 H90 110.3 . . ?
H89 C45 H90 108.5 . . ?
O50 C46 C45 106.4(10) . . ?
O50 C46 H91 110.4 . . ?
C45 C46 H91 110.4 . . ?
O50 C46 H92 110.4 . . ?
C45 C46 H92 110.4 . . ?
H91 C46 H92 108.6 . . ?
C48 C47 H97 109.5 . . ?
C48 C47 H98 109.5 . . ?
H97 C47 H98 109.5 . . ?
C48 C47 H99 109.5 . . ?
H97 C47 H99 109.5 . . ?
H98 C47 H99 109.5 . . ?
O51 C48 C49 123.1(16) . . ?
O51 C48 C47 120.8(14) . . ?
C49 C48 C47 115.4(14) . . ?
C48 C49 H100 109.5 . . ?
C48 C49 H101 109.5 . . ?
H100 C49 H101 109.5 . . ?
C48 C49 H102 109.5 . . ?
H100 C49 H102 109.5 . . ?
H101 C49 H102 109.5 . . ?
C51 C50 H103 109.5 . . ?
C51 C50 H104 109.5 . . ?
H103 C50 H104 109.5 . . ?
C51 C50 H105 109.5 . . ?
H103 C50 H105 109.5 . . ?
H104 C50 H105 109.5 . . ?
O52 C51 C52 123.2(15) . . ?
O52 C51 C50 119.6(13) . . ?
C52 C51 C50 117.0(14) . . ?
C51 C52 H106 109.5 . . ?
C51 C52 H107 109.5 . . ?
H106 C52 H107 109.5 . . ?
C51 C52 H108 109.5 . . ?
H106 C52 H108 109.5 . . ?
H107 C52 H108 109.5 . . ?
O50 C53 C54 109.6(11) . . ?
O50 C53 H93 109.8 . . ?
C54 C53 H93 109.8 . . ?
O50 C53 H94 109.8 . . ?
C54 C53 H94 109.8 . . ?
H93 C53 H94 108.2 . . ?
O45 C54 C53 108.3(9) . . ?
O45 C54 H95 110.0 . . ?
C53 C54 H95 110.0 . . ?
O45 C54 H96 110.0 . . ?
C53 C54 H96 110.0 . . ?
H95 C54 H96 108.4 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Pt1 O2 N1 O3 -173.4(7) . . . . ?
Pt1 O2 N1 Pt2 8.8(10) . . . . ?
Pt2 O4 N2 O5 174.7(8) . . . . ?
Pt2 O4 N2 Pt3 -7.9(11) . . . . ?
Pt3 O6 N3 O7 -177.5(7) . . . . ?
Pt3 O6 N3 Pt1 3.7(10) . . . . ?
Ag2 O9 N4 O8 -0.3(12) . . . . ?
Ag2 O9 N4 Pt1 -176.4(4) . . . . ?
Ag3 O11 N5 O10 113.4(12) . . . . ?
Ag3 O11 N5 Pt2 -68.9(12) . . . . ?
Pt4 O27 N7 O28 177.8(7) . . . . ?
Pt4 O27 N7 Pt5 1.0(11) . . . . ?
Pt5 O29 N8 O30 -176.6(7) . . . . ?
Pt5 O29 N8 Pt6 4.4(11) . . . . ?
Pt6 O31 N9 O32 -175.8(7) . . . . ?
Pt6 O31 N9 Pt4 2.5(10) . . . . ?
Ag4 O34 N10 O33 6.0(13) . . . . ?
Ag4 O34 N10 Pt4 -171.8(4) . . . . ?
Ag1 O36 N11 O35 90.9(14) 1_545 . . . ?
Ag1 O36 N11 Pt5 -90.6(10) 1_545 . . . ?
C12 O14 C1 C2 -174.3(10) . . . . ?
O14 C1 C2 O15 -66.4(13) . . . . ?
C3 O15 C2 C1 -84.9(13) . . . . ?
C2 O15 C3 C4 -179.5(10) . . . . ?
C5 O16 C4 C3 176.3(10) . . . . ?
O15 C3 C4 O16 -66.5(13) . . . . ?
C4 O16 C5 C6 166.3(11) . . . . ?
C7 O17 C6 C5 -175.1(12) . . . . ?
O16 C5 C6 O17 67.0(14) . . . . ?
C6 O17 C7 C8 -164.2(12) . . . . ?
C9 O18 C8 C7 -92.5(18) . . . . ?
O17 C7 C8 O18 -65.2(17) . . . . ?
C8 O18 C9 C10 175.3(14) . . . . ?
C11 O19 C10 C9 -166.8(12) . . . . ?
O18 C9 C10 O19 -64.1(19) . . . . ?
C10 O19 C11 C12 174.4(12) . . . . ?
C1 O14 C12 C11 -175.8(10) . . . . ?
O19 C11 C12 O14 59.0(16) . . . . ?
C24 O20 C13 C14 179.0(10) . . . . ?
Ag2 O20 C13 C14 -38.4(12) . . . . ?
C15 O21 C14 C13 79.9(13) . . . . ?
O20 C13 C14 O21 61.9(14) . . . . ?
C14 O21 C15 C16 175.1(10) . . . . ?
C17 O22 C16 C15 -168.0(9) . . . . ?
O21 C15 C16 O22 64.4(12) . . . . ?
C16 O22 C17 C18 175.1(10) . . . . ?
C19 O23 C18 C17 -169.7(10) . . . . ?
O22 C17 C18 O23 -61.6(12) . . . . ?
C18 O23 C19 C20 179.6(10) . . . . ?
C21 O24 C20 C19 75.8(13) . . . . ?
O23 C19 C20 O24 61.8(14) . . . . ?
C20 O24 C21 C22 173.8(9) . . . . ?
C23 O25 C22 C21 -168.8(9) . . . . ?
O24 C21 C22 O25 62.7(12) . . . . ?
C22 O25 C23 C24 178.9(9) . . . . ?
C13 O20 C24 C23 -173.4(10) . . . . ?
Ag2 O20 C24 C23 45.1(12) . . . . ?
O25 C23 C24 O20 -60.2(12) . . . . ?
C36 O39 C25 C26 -178.6(10) . . . . ?
C27 O40 C26 C25 -175.0(9) . . . . ?
O39 C25 C26 O40 69.2(13) . . . . ?
C26 O40 C27 C28 165.7(10) . . . . ?
C29 O41 C28 C27 -165.7(10) . . . . ?
O40 C27 C28 O41 -64.7(12) . . . . ?
C28 O41 C29 C30 173.8(11) . . . . ?
C31 O42 C30 C29 177.8(11) . . . . ?
O41 C29 C30 O42 69.6(14) . . . . ?
C30 O42 C31 C32 80.4(16) . . . . ?
O42 C31 C32 O43 66(2) . . . . ?
C33 O43 C32 C31 70(2) . . . . ?
C32 O43 C33 C34 168.2(12) . . . . ?
C35 O44 C34 C33 -155.5(12) . . . . ?
O43 C33 C34 O44 57.0(16) . . . . ?
C34 O44 C35 C36 174.5(10) . . . . ?
C25 O39 C36 C35 -175.9(11) . . . . ?
O44 C35 C36 O39 -57.8(14) . . . . ?
C54 O45 C37 C38 -176.6(10) . . . . ?
Ag4 O45 C37 C38 -35.4(12) . . . . ?
C39 O46 C38 C37 77.7(12) . . . . ?
O45 C37 C38 O46 61.5(13) . . . . ?
C38 O46 C39 C40 173.9(10) . . . . ?
C41 O47 C40 C39 -165.7(10) . . . . ?
O46 C39 C40 O47 62.5(12) . . . . ?
C40 O47 C41 C42 -179.6(10) . . . . ?
C43 O48 C42 C41 -171.3(10) . . . . ?
O47 C41 C42 O48 -63.8(12) . . . . ?
C42 O48 C43 C44 179.9(9) . . . . ?
C45 O49 C44 C43 80.2(12) . . . . ?
O48 C43 C44 O49 62.0(13) . . . . ?
C44 O49 C45 C46 175.8(9) . . . . ?
C53 O50 C46 C45 -175.4(9) . . . . ?
O49 C45 C46 O50 62.7(11) . . . . ?
C46 O50 C53 C54 176.1(9) . . . . ?
C37 O45 C54 C53 -169.9(10) . . . . ?
Ag4 O45 C54 C53 49.7(11) . . . . ?
O50 C53 C54 O45 -59.6(12) . . . . ?

_refine_diff_density_max         2.653
_refine_diff_density_min         -3.116
_refine_diff_density_rms         0.274

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_5
_database_code_depnum_ccdc_archive 'CCDC 1873240'
_audit_update_record             
;
2018-10-15 deposited with the CCDC.
2018-11-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C10.50 H21 Ag2 N6 O16.50 Pt3'
_chemical_formula_sum            'C10.50 H21 Ag2 N6 O16.50 Pt3'
_chemical_formula_weight         1296.34

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -4.5932 6.9264 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           60
_space_group_name_H-M_alt        'P b c n'
_space_group_name_Hall           '-P 2n 2ab'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y+1/2, z+1/2'
'x+1/2, -y+1/2, -z'
'-x, y, -z+1/2'
'-x, -y, -z'
'x-1/2, y-1/2, -z-1/2'
'-x-1/2, y-1/2, z'
'x, -y, z-1/2'

_cell_length_a                   17.5819(6)
_cell_length_b                   20.2747(8)
_cell_length_c                   15.0045(6)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     5348.6(4)
_cell_formula_units_Z            8
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    24181
_cell_measurement_theta_min      2.95
_cell_measurement_theta_max      68.44

_exptl_crystal_description       needle
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    3.220
_exptl_crystal_F_000             4688
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.120
_exptl_crystal_size_mid          0.070
_exptl_crystal_size_min          0.070
_exptl_absorpt_coefficient_mu    40.924
_shelx_estimated_absorpt_T_min   0.084
_shelx_estimated_absorpt_T_max   0.162
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.2350
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_process_details   'ABSCOR (Rigaku, 2010)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     1.54187
_diffrn_radiation_type           CuK\a
_diffrn_source                   'rotating-anode X-ray tube'
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean 10.000
_diffrn_reflns_number            56287
_diffrn_reflns_av_unetI/netI     0.0850
_diffrn_reflns_av_R_equivalents  0.1416
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_theta_min         3.327
_diffrn_reflns_theta_max         68.240
_diffrn_reflns_theta_full        67.687
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             4893
_reflns_number_gt                2921
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'RAPID AUTO (Rigaku, 2015)'
_computing_cell_refinement       'RAPID AUTO (Rigaku, 2015)'
_computing_data_reduction        'RAPID AUTO (Rigaku, 2015)'
_computing_structure_solution    'SIR2004 (Spagna, 2004)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'ORTEP-3 (Farrugia, 2012)'
_computing_publication_material  'SHELXL-2014/7 (Sheldrick, 2014)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0823P)²+103.3573P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         4893
_refine_ls_number_parameters     352
_refine_ls_number_restraints     25
_refine_ls_R_factor_all          0.1260
_refine_ls_R_factor_gt           0.0804
_refine_ls_wR_factor_ref         0.2232
_refine_ls_wR_factor_gt          0.1897
_refine_ls_goodness_of_fit_ref   1.075
_refine_ls_restrained_S_all      1.075
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.48767(6) 0.42515(6) 0.35394(8) 0.0762(4) Uani 1 1 d . . . . .
Pt2 Pt 0.46091(6) 0.26824(6) 0.37919(9) 0.0810(4) Uani 1 1 d . . . . .
Pt3 Pt 0.31741(6) 0.36672(6) 0.35440(8) 0.0791(4) Uani 1 1 d . . . . .
Ag1 Ag 0.42142(11) 0.37037(10) 0.51689(15) 0.0873(6) Uani 1 1 d . . . . .
Ag2 Ag 0.55926(12) 0.07472(11) 0.5417(2) 0.1318(11) Uani 1 1 d . . . . .
O1 O 0.4226(9) 0.3482(7) 0.3134(11) 0.079(4) Uani 1 1 d . . . . .
O2 O 0.5669(8) 0.3050(9) 0.3771(12) 0.089(5) Uani 1 1 d . . . . .
O3 O 0.2999(8) 0.2720(8) 0.3704(12) 0.085(5) Uani 1 1 d . . . . .
O4 O 0.3993(8) 0.4862(9) 0.3309(12) 0.087(5) Uani 1 1 d . . . . .
O5 O 0.6404(9) 0.3849(9) 0.3678(12) 0.091(5) Uani 1 1 d . . . . .
O6 O 0.3403(12) 0.1729(11) 0.389(2) 0.151(10) Uani 1 1 d . . . . .
O7 O 0.2827(13) 0.4991(12) 0.3089(19) 0.150(10) Uani 1 1 d . . . . .
O8 O 0.5850(10) 0.5019(10) 0.4635(15) 0.099(6) Uani 1 1 d . . . . .
O9 O 0.5345(14) 0.5564(12) 0.3557(16) 0.122(8) Uani 1 1 d . . . . .
O10 O 0.4769(18) 0.1690(15) 0.509(3) 0.192(15) Uani 1 1 d . . . . .
O11 O 0.5490(17) 0.1562(14) 0.403(2) 0.164(12) Uani 1 1 d . . . . .
O12 O 0.1955(19) 0.381(3) 0.468(3) 0.29(3) Uani 1 1 d . U . . .
O13 O 0.1594(14) 0.395(3) 0.350(2) 0.26(2) Uani 1 1 d . U . . .
O14 O 0.3303(12) 0.3017(12) 0.5753(16) 0.122(7) Uani 1 1 d . . . . .
O15 O 0.5041(18) 0.2987(14) 0.605(2) 0.168(11) Uani 1 1 d . . . . .
O16 O 0.4245(14) 0.0270(10) 0.5418(18) 0.134(8) Uani 1 1 d . . . . .
O17 O 0.497(3) 0.0422(19) 0.706(3) 0.140(16) Uani 0.5 1 d D U P . .
N1 N 0.5758(10) 0.3708(11) 0.3702(15) 0.080(6) Uani 1 1 d . . . . .
N2 N 0.3572(13) 0.2318(13) 0.3828(17) 0.105(8) Uani 1 1 d . . . . .
N3 N 0.3301(11) 0.4590(11) 0.3339(14) 0.083(6) Uani 1 1 d . . . . .
N4 N 0.5435(13) 0.5051(12) 0.3969(18) 0.088(7) Uani 1 1 d . . . . .
N5 N 0.5043(15) 0.1866(14) 0.442(2) 0.102(8) Uani 1 1 d . . . . .
N6 N 0.2084(13) 0.3851(13) 0.393(2) 0.110(8) Uani 1 1 d . U . . .
C1 C 0.219(2) 0.265(3) 0.649(4) 0.32(5) Uani 1 1 d D . . . .
H1 H 0.1809 0.2874 0.6870 0.478 Uiso 1 1 calc R U . . .
H2 H 0.1934 0.2470 0.5966 0.478 Uiso 1 1 calc R U . . .
H3 H 0.2427 0.2296 0.6831 0.478 Uiso 1 1 calc R U . . .
C2 C 0.2777(18) 0.314(2) 0.621(2) 0.149(19) Uani 1 1 d D . . . .
C3 C 0.271(3) 0.382(2) 0.661(4) 0.20(2) Uani 1 1 d D . . . .
H4 H 0.3203 0.3941 0.6876 0.307 Uiso 1 1 calc R U . . .
H5 H 0.2321 0.3815 0.7075 0.307 Uiso 1 1 calc R U . . .
H6 H 0.2577 0.4135 0.6147 0.307 Uiso 1 1 calc R U . . .
C4 C 0.596(3) 0.251(3) 0.696(4) 0.24(3) Uani 1 1 d . . . . .
H7 H 0.5615 0.2135 0.6938 0.354 Uiso 1 1 calc R U . . .
H8 H 0.5978 0.2687 0.7570 0.354 Uiso 1 1 calc R U . . .
H9 H 0.6471 0.2376 0.6779 0.354 Uiso 1 1 calc R U . . .
C5 C 0.568(2) 0.3036(19) 0.635(3) 0.150(17) Uani 1 1 d D . . . .
C6 C 0.628(4) 0.3513(19) 0.604(4) 0.25(4) Uani 1 1 d D . . . .
H10 H 0.6748 0.3448 0.6388 0.382 Uiso 1 1 calc R U . . .
H11 H 0.6392 0.3436 0.5406 0.382 Uiso 1 1 calc R U . . .
H12 H 0.6100 0.3966 0.6119 0.382 Uiso 1 1 calc R U . . .
C7 C 0.368(4) 0.113(2) 0.628(3) 0.26(4) Uani 1 1 d D . . . .
H13 H 0.4185 0.1133 0.6557 0.389 Uiso 1 1 calc R U . . .
H14 H 0.3290 0.1079 0.6741 0.389 Uiso 1 1 calc R U . . .
H15 H 0.3599 0.1540 0.5954 0.389 Uiso 1 1 calc R U . . .
C8 C 0.363(2) 0.0553(19) 0.564(3) 0.145(15) Uani 1 1 d D . . . .
C9 C 0.289(2) 0.044(2) 0.525(4) 0.21(2) Uani 1 1 d . . . . .
H16 H 0.2955 0.0223 0.4668 0.319 Uiso 1 1 calc R U . . .
H17 H 0.2637 0.0867 0.5159 0.319 Uiso 1 1 calc R U . . .
H18 H 0.2589 0.0164 0.5641 0.319 Uiso 1 1 calc R U . . .
C10 C 0.5668(16) -0.0518(14) 0.717(2) 0.118(10) Uani 1 1 d D U . . .
C11 C 0.5000 -0.010(2) 0.7500 0.119(12) Uani 1 2 d DS TU P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 N1 1.92(2) . ?
Pt1 N4 2.00(3) . ?
Pt1 O4 2.016(16) . ?
Pt1 O1 2.028(16) . ?
Pt1 Ag1 2.927(2) . ?
Pt1 Pt1 3.149(2) 4_655 ?
Pt1 Pt3 3.2194(14) . ?
Pt1 Pt2 3.2381(16) . ?
Pt2 N2 1.97(2) . ?
Pt2 O2 2.007(15) . ?
Pt2 O1 2.013(16) . ?
Pt2 N5 2.05(3) . ?
Pt2 Ag1 3.006(2) . ?
Pt2 Pt3 3.2390(15) . ?
Pt3 N3 1.91(2) . ?
Pt3 O3 1.959(17) . ?
Pt3 O1 1.985(16) . ?
Pt3 N6 2.04(3) . ?
Pt3 Ag1 3.049(2) . ?
Ag1 O14 2.30(2) . ?
Ag1 O15 2.45(3) . ?
Ag1 O9 2.54(2) 5_666 ?
Ag2 O16 2.43(2) 5_656 ?
Ag2 O10 2.45(3) . ?
Ag2 O13 2.47(3) 3_556 ?
Ag2 O16 2.56(2) . ?
Ag2 O12 2.56(3) 3_556 ?
O2 N1 1.35(2) . ?
O3 N2 1.31(3) . ?
O4 N3 1.34(2) . ?
O5 N1 1.17(2) . ?
O6 N2 1.23(3) . ?
O7 N3 1.22(2) . ?
O8 N4 1.24(3) . ?
O9 N4 1.22(3) . ?
O9 Ag1 2.54(2) 5_666 ?
O10 N5 1.17(3) . ?
O11 N5 1.15(3) . ?
O12 N6 1.16(4) . ?
O12 Ag2 2.56(3) 3_456 ?
O13 N6 1.09(3) . ?
O13 Ag2 2.47(3) 3_456 ?
O14 C2 1.18(4) . ?
O15 C5 1.21(4) . ?
O16 C8 1.27(4) . ?
O16 Ag2 2.43(2) 5_656 ?
O17 C11 1.247(19) . ?
O17 O17 1.34(8) 4_656 ?
C1 C2 1.494(19) . ?
C1 H1 0.9800 . ?
C1 H2 0.9800 . ?
C1 H3 0.9800 . ?
C2 C3 1.50(2) . ?
C3 H4 0.9800 . ?
C3 H5 0.9800 . ?
C3 H6 0.9800 . ?
C4 C5 1.48(5) . ?
C4 H7 0.9800 . ?
C4 H8 0.9800 . ?
C4 H9 0.9800 . ?
C5 C6 1.51(2) . ?
C6 H10 0.9800 . ?
C6 H11 0.9800 . ?
C6 H12 0.9800 . ?
C7 C8 1.51(2) . ?
C7 H13 0.9800 . ?
C7 H14 0.9800 . ?
C7 H15 0.9800 . ?
C8 C9 1.44(5) . ?
C9 H16 0.9800 . ?
C9 H17 0.9800 . ?
C9 H18 0.9800 . ?
C10 C11 1.532(18) . ?
C11 O17 1.247(19) 4_656 ?
C11 C10 1.532(18) 4_656 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Pt1 N4 91.6(9) . . ?
N1 Pt1 O4 176.0(8) . . ?
N4 Pt1 O4 86.3(9) . . ?
N1 Pt1 O1 92.9(8) . . ?
N4 Pt1 O1 175.0(7) . . ?
O4 Pt1 O1 89.2(7) . . ?
N1 Pt1 Ag1 89.8(6) . . ?
N4 Pt1 Ag1 103.5(7) . . ?
O4 Pt1 Ag1 94.0(5) . . ?
O1 Pt1 Ag1 74.6(4) . . ?
N1 Pt1 Pt1 90.9(7) . 4_655 ?
N4 Pt1 Pt1 104.6(7) . 4_655 ?
O4 Pt1 Pt1 86.3(5) . 4_655 ?
O1 Pt1 Pt1 77.3(4) . 4_655 ?
Ag1 Pt1 Pt1 151.90(6) . 4_655 ?
N1 Pt1 Pt3 122.6(6) . . ?
N4 Pt1 Pt3 138.9(6) . . ?
O4 Pt1 Pt3 60.6(4) . . ?
O1 Pt1 Pt3 36.2(4) . . ?
Ag1 Pt1 Pt3 59.24(5) . . ?
Pt1 Pt1 Pt3 97.48(5) 4_655 . ?
N1 Pt1 Pt2 62.4(6) . . ?
N4 Pt1 Pt2 146.0(8) . . ?
O4 Pt1 Pt2 120.7(5) . . ?
O1 Pt1 Pt2 36.6(5) . . ?
Ag1 Pt1 Pt2 58.11(5) . . ?
Pt1 Pt1 Pt2 97.81(3) 4_655 . ?
Pt3 Pt1 Pt2 60.21(3) . . ?
N2 Pt2 O2 179.2(10) . . ?
N2 Pt2 O1 90.4(9) . . ?
O2 Pt2 O1 90.2(7) . . ?
N2 Pt2 N5 91.6(11) . . ?
O2 Pt2 N5 87.8(9) . . ?
O1 Pt2 N5 177.2(10) . . ?
N2 Pt2 Ag1 91.5(8) . . ?
O2 Pt2 Ag1 88.3(5) . . ?
O1 Pt2 Ag1 72.9(4) . . ?
N5 Pt2 Ag1 109.1(9) . . ?
N2 Pt2 Pt1 120.5(8) . . ?
O2 Pt2 Pt1 59.9(5) . . ?
O1 Pt2 Pt1 36.9(5) . . ?
N5 Pt2 Pt1 142.5(7) . . ?
Ag1 Pt2 Pt1 55.76(5) . . ?
N2 Pt2 Pt3 60.9(8) . . ?
O2 Pt2 Pt3 119.5(5) . . ?
O1 Pt2 Pt3 35.6(5) . . ?
N5 Pt2 Pt3 147.1(9) . . ?
Ag1 Pt2 Pt3 58.29(5) . . ?
Pt1 Pt2 Pt3 59.61(3) . . ?
N3 Pt3 O3 176.8(8) . . ?
N3 Pt3 O1 91.5(7) . . ?
O3 Pt3 O1 89.9(6) . . ?
N3 Pt3 N6 88.6(9) . . ?
O3 Pt3 N6 89.8(9) . . ?
O1 Pt3 N6 178.4(10) . . ?
N3 Pt3 Ag1 92.0(6) . . ?
O3 Pt3 Ag1 91.1(5) . . ?
O1 Pt3 Ag1 72.2(5) . . ?
N6 Pt3 Ag1 109.4(9) . . ?
N3 Pt3 Pt1 62.0(6) . . ?
O3 Pt3 Pt1 120.5(4) . . ?
O1 Pt3 Pt1 37.1(4) . . ?
N6 Pt3 Pt1 143.9(8) . . ?
Ag1 Pt3 Pt1 55.60(4) . . ?
N3 Pt3 Pt2 122.1(6) . . ?
O3 Pt3 Pt2 60.3(4) . . ?
O1 Pt3 Pt2 36.2(5) . . ?
N6 Pt3 Pt2 144.4(8) . . ?
Ag1 Pt3 Pt2 57.03(5) . . ?
Pt1 Pt3 Pt2 60.18(3) . . ?
O14 Ag1 O15 81.2(9) . . ?
O14 Ag1 O9 106.3(8) . 5_666 ?
O15 Ag1 O9 76.0(9) . 5_666 ?
O14 Ag1 Pt1 145.7(6) . . ?
O15 Ag1 Pt1 116.2(8) . . ?
O9 Ag1 Pt1 106.6(5) 5_666 . ?
O14 Ag1 Pt2 90.3(7) . . ?
O15 Ag1 Pt2 80.0(8) . . ?
O9 Ag1 Pt2 148.1(6) 5_666 . ?
Pt1 Ag1 Pt2 66.13(5) . . ?
O14 Ag1 Pt3 82.6(5) . . ?
O15 Ag1 Pt3 140.9(8) . . ?
O9 Ag1 Pt3 143.0(6) 5_666 . ?
Pt1 Ag1 Pt3 65.16(5) . . ?
Pt2 Ag1 Pt3 64.67(5) . . ?
O16 Ag2 O10 129.0(12) 5_656 . ?
O16 Ag2 O13 117.7(13) 5_656 3_556 ?
O10 Ag2 O13 111.1(15) . 3_556 ?
O16 Ag2 O16 77.8(9) 5_656 . ?
O10 Ag2 O16 75.4(9) . . ?
O13 Ag2 O16 138.9(9) 3_556 . ?
O16 Ag2 O12 99.0(13) 5_656 3_556 ?
O10 Ag2 O12 105.6(15) . 3_556 ?
O13 Ag2 O12 44.4(10) 3_556 3_556 ?
O16 Ag2 O12 176.2(12) . 3_556 ?
Pt3 O1 Pt2 108.2(7) . . ?
Pt3 O1 Pt1 106.7(7) . . ?
Pt2 O1 Pt1 106.5(8) . . ?
N1 O2 Pt2 118.4(12) . . ?
N2 O3 Pt3 120.5(15) . . ?
N3 O4 Pt1 116.3(14) . . ?
N4 O9 Ag1 94.4(19) . 5_666 ?
N5 O10 Ag2 100(2) . . ?
N6 O12 Ag2 96(2) . 3_456 ?
N6 O13 Ag2 103(3) . 3_456 ?
C2 O14 Ag1 130(3) . . ?
C5 O15 Ag1 134(3) . . ?
C8 O16 Ag2 128(2) . 5_656 ?
C8 O16 Ag2 128(2) . . ?
Ag2 O16 Ag2 102.2(9) 5_656 . ?
C11 O17 O17 58(2) . 4_656 ?
O5 N1 O2 111(2) . . ?
O5 N1 Pt1 129.7(19) . . ?
O2 N1 Pt1 119.1(12) . . ?
O6 N2 O3 115(2) . . ?
O6 N2 Pt2 126(2) . . ?
O3 N2 Pt2 118.3(18) . . ?
O7 N3 O4 110(2) . . ?
O7 N3 Pt3 128.4(19) . . ?
O4 N3 Pt3 121.1(14) . . ?
O9 N4 O8 122(3) . . ?
O9 N4 Pt1 118(2) . . ?
O8 N4 Pt1 120.4(19) . . ?
O11 N5 O10 123(4) . . ?
O11 N5 Pt2 117(3) . . ?
O10 N5 Pt2 119(3) . . ?
O13 N6 O12 115(4) . . ?
O13 N6 Pt3 128(3) . . ?
O12 N6 Pt3 117(3) . . ?
C2 C1 H1 109.5 . . ?
C2 C1 H2 109.5 . . ?
H1 C1 H2 109.5 . . ?
C2 C1 H3 109.5 . . ?
H1 C1 H3 109.5 . . ?
H2 C1 H3 109.5 . . ?
O14 C2 C1 125(5) . . ?
O14 C2 C3 119(3) . . ?
C1 C2 C3 116(5) . . ?
C2 C3 H4 109.5 . . ?
C2 C3 H5 109.5 . . ?
H4 C3 H5 109.5 . . ?
C2 C3 H6 109.5 . . ?
H4 C3 H6 109.5 . . ?
H5 C3 H6 109.5 . . ?
C5 C4 H7 109.5 . . ?
C5 C4 H8 109.5 . . ?
H7 C4 H8 109.5 . . ?
C5 C4 H9 109.5 . . ?
H7 C4 H9 109.5 . . ?
H8 C4 H9 109.5 . . ?
O15 C5 C4 118(4) . . ?
O15 C5 C6 126(5) . . ?
C4 C5 C6 115(4) . . ?
C5 C6 H10 109.5 . . ?
C5 C6 H11 109.5 . . ?
H10 C6 H11 109.5 . . ?
C5 C6 H12 109.5 . . ?
H10 C6 H12 109.5 . . ?
H11 C6 H12 109.5 . . ?
C8 C7 H13 109.5 . . ?
C8 C7 H14 109.5 . . ?
H13 C7 H14 109.5 . . ?
C8 C7 H15 109.5 . . ?
H13 C7 H15 109.5 . . ?
H14 C7 H15 109.5 . . ?
O16 C8 C9 126(4) . . ?
O16 C8 C7 118(4) . . ?
C9 C8 C7 116(4) . . ?
C8 C9 H16 109.5 . . ?
C8 C9 H17 109.5 . . ?
H16 C9 H17 109.5 . . ?
C8 C9 H18 109.5 . . ?
H16 C9 H18 109.5 . . ?
H17 C9 H18 109.5 . . ?
O17 C11 O17 65(5) . 4_656 ?
O17 C11 C10 109(2) . . ?
O17 C11 C10 128(3) 4_656 . ?
O17 C11 C10 128(3) . 4_656 ?
O17 C11 C10 109(2) 4_656 4_656 ?
C10 C11 C10 112(3) . 4_656 ?

_refine_diff_density_max         2.074
_refine_diff_density_min         -3.155
_refine_diff_density_rms         0.282

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_4
_database_code_depnum_ccdc_archive 'CCDC 1873239'
_audit_update_record             
;
2018-10-15 deposited with the CCDC.
2018-11-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C15 H30 Ag2 N6 O20 Pt3'
_chemical_formula_sum            'C15 H30 Ag2 N6 O20 Pt3'
_chemical_formula_weight         1415.46

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -4.5932 6.9264 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   8.1780(2)
_cell_length_b                   21.7158(4)
_cell_length_c                   18.2590(4)
_cell_angle_alpha                90
_cell_angle_beta                 92.200(7)
_cell_angle_gamma                90
_cell_volume                     3240.26(12)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    30721
_cell_measurement_theta_min      3.16
_cell_measurement_theta_max      68.40

_exptl_crystal_description       rod
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.902
_exptl_crystal_F_000             2600
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.050
_exptl_crystal_size_min          0.050
_exptl_absorpt_coefficient_mu    33.959
_shelx_estimated_absorpt_T_min   0.056
_shelx_estimated_absorpt_T_max   0.282
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.3280
_exptl_absorpt_correction_T_max  0.6831
_exptl_absorpt_process_details   'NUMABS (Rigaku, 2011)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     1.54187
_diffrn_radiation_type           CuK\a
_diffrn_source                   'rotating-anode X-ray tube'
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean 10.000
_diffrn_reflns_number            58098
_diffrn_reflns_av_unetI/netI     0.0574
_diffrn_reflns_av_R_equivalents  0.0811
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_theta_min         3.164
_diffrn_reflns_theta_max         68.252
_diffrn_reflns_theta_full        67.687
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measured_fraction_theta_full 0.988
_diffrn_reflns_Laue_measured_fraction_max 0.987
_diffrn_reflns_Laue_measured_fraction_full 0.988
_diffrn_reflns_point_group_measured_fraction_max 0.987
_diffrn_reflns_point_group_measured_fraction_full 0.988
_reflns_number_total             5850
_reflns_number_gt                4467
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'RAPID AUTO (Rigaku, 2015)'
_computing_cell_refinement       'RAPID AUTO (Rigaku, 2015)'
_computing_data_reduction        'RAPID AUTO (Rigaku, 2015)'
_computing_structure_solution    'SIR2004 (Spagna, 2004)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'ORTEP-3 (Farrugia, 2012)'
_computing_publication_material  'SHELXL-2014/7 (Sheldrick, 2014)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0599P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         5850
_refine_ls_number_parameters     417
_refine_ls_number_restraints     31
_refine_ls_R_factor_all          0.0610
_refine_ls_R_factor_gt           0.0439
_refine_ls_wR_factor_ref         0.1251
_refine_ls_wR_factor_gt          0.1121
_refine_ls_goodness_of_fit_ref   1.165
_refine_ls_restrained_S_all      1.176
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.45375(6) 0.36072(2) 0.48253(2) 0.03713(16) Uani 1 1 d . . . . .
Pt2 Pt 0.44985(6) 0.41616(2) 0.31841(2) 0.03655(16) Uani 1 1 d . . . . .
Pt3 Pt 0.60078(6) 0.28114(2) 0.35091(3) 0.03560(16) Uani 1 1 d . . . . .
Ag1 Ag 0.13227(13) 0.29852(5) 0.36220(6) 0.0598(3) Uani 1 1 d . . . . .
Ag2 Ag 0.52386(11) 0.62663(4) 0.24321(5) 0.0406(2) Uani 1 1 d . . . . .
O1 O 0.4201(9) 0.3382(3) 0.3756(4) 0.0387(19) Uani 1 1 d . . . . .
O2 O 0.5453(11) 0.2756(4) 0.5053(4) 0.050(2) Uani 1 1 d . . . . .
O3 O 0.6544(12) 0.1949(4) 0.4663(5) 0.067(3) Uani 1 1 d . . . . .
O4 O 0.5999(11) 0.3147(4) 0.2486(4) 0.052(2) Uani 1 1 d . . . . .
O5 O 0.5481(13) 0.3862(5) 0.1755(5) 0.070(3) Uani 1 1 d . . . . .
O6 O 0.3526(10) 0.4656(4) 0.3990(4) 0.049(2) Uani 1 1 d . . . . .
O7 O 0.3099(11) 0.4763(4) 0.5103(5) 0.061(3) Uani 1 1 d . . . . .
O8 O 0.3737(14) 0.3630(6) 0.6308(6) 0.091(4) Uani 1 1 d . . . . .
O9 O 0.6171(13) 0.3931(5) 0.6160(5) 0.064(3) Uani 1 1 d . . . . .
O10 O 0.9071(16) 0.2195(7) 0.3373(12) 0.178(10) Uani 1 1 d . . . . .
O11 O 0.7325(15) 0.1818(6) 0.2792(10) 0.155(7) Uani 1 1 d . . . . .
O12 O 0.3554(13) 0.5233(4) 0.2387(5) 0.065(3) Uani 1 1 d . . . . .
O13 O 0.6114(12) 0.5201(4) 0.2634(6) 0.066(3) Uani 1 1 d . . . . .
O14 O 0.0259(14) 0.2893(5) 0.4972(6) 0.074(3) Uani 1 1 d . . . . .
O15 O 0.2305(11) 0.1934(4) 0.4420(4) 0.052(2) Uani 1 1 d . . . . .
O16 O 0.2371(10) 0.1816(4) 0.2892(4) 0.047(2) Uani 1 1 d . . . . .
O17 O 0.2019(13) 0.2967(4) 0.2139(5) 0.067(3) Uani 1 1 d . U . . .
O18 O -0.0270(15) 0.3819(7) 0.2759(6) 0.114(5) Uani 1 1 d . U . . .
O19 O 0.0060(10) 0.3987(4) 0.4219(5) 0.054(2) Uani 1 1 d . . . . .
N1 N 0.6007(12) 0.2453(4) 0.4504(6) 0.044(3) Uani 1 1 d . . . . .
N2 N 0.5416(13) 0.3692(4) 0.2392(5) 0.044(3) Uani 1 1 d . . . . .
N3 N 0.3606(12) 0.4433(5) 0.4641(5) 0.043(3) Uani 1 1 d . . . . .
N4 N 0.4878(15) 0.3765(5) 0.5902(5) 0.046(3) Uani 1 1 d . . . . .
N5 N 0.7696(15) 0.2208(5) 0.3195(6) 0.047(3) Uani 1 1 d . . . . .
N6 N 0.4735(15) 0.4956(5) 0.2644(5) 0.045(3) Uani 1 1 d . . . . .
C1 C 0.121(3) 0.2456(8) 0.5413(10) 0.099(6) Uani 1 1 d . U . . .
H1 H 0.2319 0.2622 0.5511 0.118 Uiso 1 1 calc R U . . .
H2 H 0.0686 0.2399 0.5889 0.118 Uiso 1 1 calc R U . . .
C2 C 0.131(2) 0.1890(7) 0.5062(8) 0.090(6) Uani 1 1 d . U . . .
H3 H 0.0202 0.1746 0.4912 0.108 Uiso 1 1 calc R U . . .
H4 H 0.1804 0.1584 0.5407 0.108 Uiso 1 1 calc R U . . .
C3 C 0.2415(17) 0.1373(5) 0.4049(7) 0.053(4) Uani 1 1 d . . . . .
H5 H 0.1300 0.1217 0.3926 0.064 Uiso 1 1 calc R U . . .
H6 H 0.2978 0.1067 0.4373 0.064 Uiso 1 1 calc R U . . .
C4 C 0.3313(15) 0.1442(5) 0.3377(7) 0.045(3) Uani 1 1 d . . . . .
H7 H 0.4390 0.1636 0.3488 0.054 Uiso 1 1 calc R U . . .
H8 H 0.3498 0.1034 0.3153 0.054 Uiso 1 1 calc R U . . .
C5 C 0.3163(15) 0.1953(6) 0.2219(6) 0.044(3) Uani 1 1 d . . . . .
H9 H 0.3312 0.1570 0.1935 0.053 Uiso 1 1 calc R U . . .
H10 H 0.4254 0.2136 0.2329 0.053 Uiso 1 1 calc R U . . .
C6 C 0.2124(16) 0.2395(5) 0.1784(6) 0.048(3) Uani 1 1 d . . . . .
H11 H 0.2593 0.2455 0.1297 0.058 Uiso 1 1 calc R U . . .
H12 H 0.1012 0.2221 0.1708 0.058 Uiso 1 1 calc R U . . .
C7 C 0.071(3) 0.3298(8) 0.1746(9) 0.139(8) Uani 1 1 d D U . . .
H13 H -0.0301 0.3046 0.1736 0.167 Uiso 1 1 calc R U . . .
H14 H 0.1016 0.3369 0.1233 0.167 Uiso 1 1 calc R U . . .
C8 C 0.040(3) 0.3880(9) 0.2091(10) 0.168(9) Uani 1 1 d D U . . .
H15 H 0.1444 0.4109 0.2151 0.202 Uiso 1 1 calc R U . . .
H16 H -0.0347 0.4125 0.1767 0.202 Uiso 1 1 calc R U . . .
C9 C -0.016(2) 0.4422(10) 0.3070(9) 0.100(7) Uani 1 1 d . . . . .
H17 H 0.0997 0.4556 0.3122 0.120 Uiso 1 1 calc R U . . .
H18 H -0.0772 0.4723 0.2759 0.120 Uiso 1 1 calc R U . . .
C10 C -0.0835(19) 0.4374(7) 0.3746(9) 0.072(5) Uani 1 1 d . . . . .
H19 H -0.1966 0.4215 0.3682 0.086 Uiso 1 1 calc R U . . .
H20 H -0.0894 0.4789 0.3968 0.086 Uiso 1 1 calc R U . . .
C11 C -0.0731(18) 0.3884(6) 0.4869(8) 0.059(4) Uani 1 1 d . . . . .
H21 H -0.0843 0.4279 0.5132 0.070 Uiso 1 1 calc R U . . .
H22 H -0.1844 0.3722 0.4754 0.070 Uiso 1 1 calc R U . . .
C12 C 0.011(2) 0.3471(7) 0.5316(8) 0.070(5) Uani 1 1 d . . . . .
H23 H -0.0474 0.3419 0.5778 0.083 Uiso 1 1 calc R U . . .
H24 H 0.1214 0.3636 0.5442 0.083 Uiso 1 1 calc R U . . .
O20 O 0.730(3) 0.0502(10) 0.4014(10) 0.237(11) Uani 1 1 d D . . . .
C13 C 0.648(2) -0.0350(7) 0.4597(11) 0.27(2) Uani 1 1 d D . . . .
H25 H 0.5847 -0.0397 0.5038 0.398 Uiso 1 1 calc R U . . .
H26 H 0.7297 -0.0680 0.4580 0.398 Uiso 1 1 calc R U . . .
H27 H 0.5747 -0.0372 0.4162 0.398 Uiso 1 1 calc R U . . .
C14 C 0.731(4) 0.0243(10) 0.4616(11) 0.24(2) Uani 1 1 d D . . . .
C15 C 0.782(3) 0.0447(9) 0.5369(11) 0.149(10) Uani 1 1 d D . . . .
H28 H 0.7379 0.0163 0.5729 0.224 Uiso 1 1 calc R U . . .
H29 H 0.7407 0.0863 0.5455 0.224 Uiso 1 1 calc R U . . .
H30 H 0.9020 0.0448 0.5420 0.224 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 N3 1.972(10) . ?
Pt1 N4 2.004(10) . ?
Pt1 O1 2.022(7) . ?
Pt1 O2 2.032(8) . ?
Pt1 Pt2 3.2285(6) . ?
Pt1 Pt3 3.2296(6) . ?
Pt2 N2 1.943(10) . ?
Pt2 N6 1.999(10) . ?
Pt2 O1 2.008(8) . ?
Pt2 O6 2.010(8) . ?
Pt2 Pt3 3.2274(7) . ?
Pt3 N1 1.976(10) . ?
Pt3 O1 1.993(7) . ?
Pt3 N5 2.003(10) . ?
Pt3 O4 2.006(8) . ?
Ag1 O1 2.510(8) . ?
Ag1 O10 2.545(14) 1_455 ?
Ag2 O11 2.373(11) 2_655 ?
Ag2 O8 2.428(10) 3_666 ?
Ag2 O13 2.445(9) . ?
Ag2 O16 2.496(9) 2 ?
Ag2 O10 2.572(13) 2_655 ?
O2 N1 1.296(12) . ?
O3 N1 1.210(11) . ?
O4 N2 1.285(11) . ?
O5 N2 1.222(12) . ?
O6 N3 1.284(12) . ?
O7 N3 1.194(11) . ?
O8 N4 1.249(14) . ?
O8 Ag2 2.428(10) 3_666 ?
O9 N4 1.197(13) . ?
O10 N5 1.159(15) . ?
O10 Ag1 2.545(14) 1_655 ?
O10 Ag2 2.572(13) 2_645 ?
O11 N5 1.155(14) . ?
O11 Ag2 2.373(11) 2_645 ?
O12 N6 1.217(12) . ?
O13 N6 1.248(12) . ?
O14 C12 1.411(16) . ?
O14 C1 1.45(2) . ?
O15 C3 1.398(13) . ?
O15 C2 1.454(15) . ?
O16 C4 1.409(13) . ?
O16 C5 1.441(13) . ?
O16 Ag2 2.496(9) 2_545 ?
O17 C6 1.405(13) . ?
O17 C7 1.458(17) . ?
O18 C8 1.36(2) . ?
O18 C9 1.43(2) . ?
O19 C10 1.394(16) . ?
O19 C11 1.392(15) . ?
C1 C2 1.39(2) . ?
C1 H1 0.9900 . ?
C1 H2 0.9900 . ?
C2 H3 0.9900 . ?
C2 H4 0.9900 . ?
C3 C4 1.462(17) . ?
C3 H5 0.9900 . ?
C3 H6 0.9900 . ?
C4 H7 0.9900 . ?
C4 H8 0.9900 . ?
C5 C6 1.491(16) . ?
C5 H9 0.9900 . ?
C5 H10 0.9900 . ?
C6 H11 0.9900 . ?
C6 H12 0.9900 . ?
C7 C8 1.439(16) . ?
C7 H13 0.9900 . ?
C7 H14 0.9900 . ?
C8 H15 0.9900 . ?
C8 H16 0.9900 . ?
C9 C10 1.37(2) . ?
C9 H17 0.9900 . ?
C9 H18 0.9900 . ?
C10 H19 0.9900 . ?
C10 H20 0.9900 . ?
C11 C12 1.379(19) . ?
C11 H21 0.9900 . ?
C11 H22 0.9900 . ?
C12 H23 0.9900 . ?
C12 H24 0.9900 . ?
O20 C14 1.235(16) . ?
C13 C14 1.453(18) . ?
C13 H25 0.9800 . ?
C13 H26 0.9800 . ?
C13 H27 0.9800 . ?
C14 C15 1.490(17) . ?
C15 H28 0.9800 . ?
C15 H29 0.9800 . ?
C15 H30 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N3 Pt1 N4 92.9(4) . . ?
N3 Pt1 O1 91.0(3) . . ?
N4 Pt1 O1 175.8(4) . . ?
N3 Pt1 O2 177.8(4) . . ?
N4 Pt1 O2 85.3(4) . . ?
O1 Pt1 O2 90.8(3) . . ?
N3 Pt1 Pt2 60.8(3) . . ?
N4 Pt1 Pt2 147.4(3) . . ?
O1 Pt1 Pt2 36.6(2) . . ?
O2 Pt1 Pt2 121.3(2) . . ?
N3 Pt1 Pt3 120.8(3) . . ?
N4 Pt1 Pt3 141.2(3) . . ?
O1 Pt1 Pt3 36.1(2) . . ?
O2 Pt1 Pt3 61.3(2) . . ?
Pt2 Pt1 Pt3 59.967(15) . . ?
N2 Pt2 N6 92.2(4) . . ?
N2 Pt2 O1 90.2(3) . . ?
N6 Pt2 O1 177.6(3) . . ?
N2 Pt2 O6 178.9(4) . . ?
N6 Pt2 O6 87.0(3) . . ?
O1 Pt2 O6 90.6(3) . . ?
N2 Pt2 Pt3 60.3(3) . . ?
N6 Pt2 Pt3 146.2(3) . . ?
O1 Pt2 Pt3 36.1(2) . . ?
O6 Pt2 Pt3 120.7(2) . . ?
N2 Pt2 Pt1 120.3(3) . . ?
N6 Pt2 Pt1 141.4(3) . . ?
O1 Pt2 Pt1 36.9(2) . . ?
O6 Pt2 Pt1 60.7(2) . . ?
Pt3 Pt2 Pt1 60.033(15) . . ?
N1 Pt3 O1 90.6(4) . . ?
N1 Pt3 N5 91.7(4) . . ?
O1 Pt3 N5 175.1(4) . . ?
N1 Pt3 O4 178.1(4) . . ?
O1 Pt3 O4 90.5(3) . . ?
N5 Pt3 O4 87.1(4) . . ?
N1 Pt3 Pt2 120.9(3) . . ?
O1 Pt3 Pt2 36.4(2) . . ?
N5 Pt3 Pt2 143.6(3) . . ?
O4 Pt3 Pt2 60.7(2) . . ?
N1 Pt3 Pt1 60.9(3) . . ?
O1 Pt3 Pt1 36.8(2) . . ?
N5 Pt3 Pt1 147.5(3) . . ?
O4 Pt3 Pt1 120.7(2) . . ?
Pt2 Pt3 Pt1 59.999(14) . . ?
O1 Ag1 O10 156.7(3) . 1_455 ?
O11 Ag2 O8 81.7(5) 2_655 3_666 ?
O11 Ag2 O13 105.1(4) 2_655 . ?
O8 Ag2 O13 81.8(4) 3_666 . ?
O11 Ag2 O16 115.7(4) 2_655 2 ?
O8 Ag2 O16 116.1(3) 3_666 2 ?
O13 Ag2 O16 136.9(3) . 2 ?
O11 Ag2 O10 45.7(4) 2_655 2_655 ?
O8 Ag2 O10 113.2(6) 3_666 2_655 ?
O13 Ag2 O10 139.3(5) . 2_655 ?
O16 Ag2 O10 72.2(3) 2 2_655 ?
Pt3 O1 Pt2 107.5(3) . . ?
Pt3 O1 Pt1 107.1(3) . . ?
Pt2 O1 Pt1 106.5(3) . . ?
Pt3 O1 Ag1 117.7(3) . . ?
Pt2 O1 Ag1 111.8(3) . . ?
Pt1 O1 Ag1 105.6(3) . . ?
N1 O2 Pt1 116.2(7) . . ?
N2 O4 Pt3 116.6(7) . . ?
N3 O6 Pt2 117.9(7) . . ?
N4 O8 Ag2 107.6(8) . 3_666 ?
N5 O10 Ag1 136.2(13) . 1_655 ?
N5 O10 Ag2 95.2(9) . 2_645 ?
Ag1 O10 Ag2 117.2(5) 1_655 2_645 ?
N5 O11 Ag2 106.2(10) . 2_645 ?
N6 O13 Ag2 98.4(7) . . ?
C12 O14 C1 112.9(13) . . ?
C3 O15 C2 112.4(10) . . ?
C4 O16 C5 113.7(9) . . ?
C4 O16 Ag2 108.4(7) . 2_545 ?
C5 O16 Ag2 107.8(7) . 2_545 ?
C6 O17 C7 105.4(10) . . ?
C8 O18 C9 104.2(16) . . ?
C10 O19 C11 112.1(11) . . ?
O3 N1 O2 114.1(9) . . ?
O3 N1 Pt3 124.3(9) . . ?
O2 N1 Pt3 121.6(7) . . ?
O5 N2 O4 112.0(10) . . ?
O5 N2 Pt2 125.6(9) . . ?
O4 N2 Pt2 122.4(7) . . ?
O7 N3 O6 114.8(10) . . ?
O7 N3 Pt1 124.7(9) . . ?
O6 N3 Pt1 120.5(7) . . ?
O9 N4 O8 120.4(11) . . ?
O9 N4 Pt1 121.7(9) . . ?
O8 N4 Pt1 117.6(9) . . ?
O11 N5 O10 112.9(13) . . ?
O11 N5 Pt3 119.7(11) . . ?
O10 N5 Pt3 127.3(10) . . ?
O12 N6 O13 119.2(11) . . ?
O12 N6 Pt2 121.8(9) . . ?
O13 N6 Pt2 118.7(8) . . ?
C2 C1 O14 111.5(17) . . ?
C2 C1 H1 109.3 . . ?
O14 C1 H1 109.3 . . ?
C2 C1 H2 109.3 . . ?
O14 C1 H2 109.3 . . ?
H1 C1 H2 108.0 . . ?
C1 C2 O15 111.1(14) . . ?
C1 C2 H3 109.4 . . ?
O15 C2 H3 109.4 . . ?
C1 C2 H4 109.4 . . ?
O15 C2 H4 109.4 . . ?
H3 C2 H4 108.0 . . ?
O15 C3 C4 111.1(10) . . ?
O15 C3 H5 109.4 . . ?
C4 C3 H5 109.4 . . ?
O15 C3 H6 109.4 . . ?
C4 C3 H6 109.4 . . ?
H5 C3 H6 108.0 . . ?
O16 C4 C3 107.9(10) . . ?
O16 C4 H7 110.1 . . ?
C3 C4 H7 110.1 . . ?
O16 C4 H8 110.1 . . ?
C3 C4 H8 110.1 . . ?
H7 C4 H8 108.4 . . ?
O16 C5 C6 108.7(10) . . ?
O16 C5 H9 109.9 . . ?
C6 C5 H9 109.9 . . ?
O16 C5 H10 109.9 . . ?
C6 C5 H10 109.9 . . ?
H9 C5 H10 108.3 . . ?
O17 C6 C5 111.5(10) . . ?
O17 C6 H11 109.3 . . ?
C5 C6 H11 109.3 . . ?
O17 C6 H12 109.3 . . ?
C5 C6 H12 109.3 . . ?
H11 C6 H12 108.0 . . ?
O17 C7 C8 110.8(16) . . ?
O17 C7 H13 109.5 . . ?
C8 C7 H13 109.5 . . ?
O17 C7 H14 109.5 . . ?
C8 C7 H14 109.5 . . ?
H13 C7 H14 108.1 . . ?
O18 C8 C7 113.0(19) . . ?
O18 C8 H15 109.0 . . ?
C7 C8 H15 109.0 . . ?
O18 C8 H16 109.0 . . ?
C7 C8 H16 109.0 . . ?
H15 C8 H16 107.8 . . ?
C10 C9 O18 105.4(18) . . ?
C10 C9 H17 110.7 . . ?
O18 C9 H17 110.7 . . ?
C10 C9 H18 110.7 . . ?
O18 C9 H18 110.7 . . ?
H17 C9 H18 108.8 . . ?
C9 C10 O19 112.4(14) . . ?
C9 C10 H19 109.1 . . ?
O19 C10 H19 109.1 . . ?
C9 C10 H20 109.1 . . ?
O19 C10 H20 109.1 . . ?
H19 C10 H20 107.8 . . ?
C12 C11 O19 111.9(13) . . ?
C12 C11 H21 109.2 . . ?
O19 C11 H21 109.2 . . ?
C12 C11 H22 109.2 . . ?
O19 C11 H22 109.2 . . ?
H21 C11 H22 107.9 . . ?
C11 C12 O14 111.4(13) . . ?
C11 C12 H23 109.4 . . ?
O14 C12 H23 109.4 . . ?
C11 C12 H24 109.4 . . ?
O14 C12 H24 109.4 . . ?
H23 C12 H24 108.0 . . ?
C14 C13 H25 109.5 . . ?
C14 C13 H26 109.5 . . ?
H25 C13 H26 109.5 . . ?
C14 C13 H27 109.5 . . ?
H25 C13 H27 109.5 . . ?
H26 C13 H27 109.5 . . ?
O20 C14 C13 113(2) . . ?
O20 C14 C15 133(2) . . ?
C13 C14 C15 113.5(17) . . ?
C14 C15 H28 109.5 . . ?
C14 C15 H29 109.5 . . ?
H28 C15 H29 109.5 . . ?
C14 C15 H30 109.5 . . ?
H28 C15 H30 109.5 . . ?
H29 C15 H30 109.5 . . ?

_refine_diff_density_max         1.653
_refine_diff_density_min         -2.010
_refine_diff_density_rms         0.258

