# Electronic Supplementary Material (ESI) for Faraday Discussions.
# This journal is © The Royal Society of Chemistry 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_SLTim1
_database_code_depnum_ccdc_archive 'CCDC 1874734'
_audit_update_record             
;
2018-10-22 deposited with the CCDC.
2018-11-23 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        '[(H)2Rh(PNMeP)2]'
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C23 H56 F3 N2 O3 P4 Rh S'
_chemical_formula_sum            'C23 H56 F3 N2 O3 P4 Rh S'
_chemical_formula_weight         724.54

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   10.1497(4)
_cell_length_b                   11.3546(4)
_cell_length_c                   29.0077(11)
_cell_angle_alpha                90
_cell_angle_beta                 95.690(2)
_cell_angle_gamma                90
_cell_volume                     3326.5(2)
_cell_formula_units_Z            4
_cell_measurement_temperature    140(2)
_cell_measurement_reflns_used    9915
_cell_measurement_theta_min      2.74
_cell_measurement_theta_max      30.75

_exptl_crystal_description       prism
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_density_diffrn    1.447
_exptl_crystal_F_000             1520
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.351
_exptl_crystal_size_mid          0.213
_exptl_crystal_size_min          0.067
_exptl_absorpt_coefficient_mu    0.812
_shelx_estimated_absorpt_T_min   0.764
_shelx_estimated_absorpt_T_max   0.948
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.7637
_exptl_absorpt_correction_T_max  0.9476
_exptl_absorpt_process_details   sadabs
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      140(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            89174
_diffrn_reflns_av_unetI/netI     0.0323
_diffrn_reflns_av_R_equivalents  0.0414
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -42
_diffrn_reflns_limit_l_max       42
_diffrn_reflns_theta_min         1.927
_diffrn_reflns_theta_max         31.606
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measured_fraction_theta_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.990
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.990
_diffrn_reflns_point_group_measured_fraction_full 0.997
_reflns_number_total             11055
_reflns_number_gt                9000
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0278P)²+2.6569P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         11055
_refine_ls_number_parameters     346
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0434
_refine_ls_R_factor_gt           0.0299
_refine_ls_wR_factor_ref         0.0705
_refine_ls_wR_factor_gt          0.0650
_refine_ls_goodness_of_fit_ref   1.026
_refine_ls_restrained_S_all      1.026
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 1.03706(18) 1.02097(16) 0.14167(6) 0.0221(3) Uani 1 1 d . . . . .
H1A H 1.088526 0.972991 0.121298 0.026 Uiso 1 1 calc R U . . .
H1B H 1.072675 1.102179 0.142084 0.026 Uiso 1 1 calc R U . . .
C2 C 1.05654(17) 0.84395(16) 0.18891(7) 0.0218(3) Uani 1 1 d . . . . .
H2A H 1.103578 0.816835 0.218542 0.026 Uiso 1 1 calc R U . . .
H2B H 1.106942 0.815779 0.163545 0.026 Uiso 1 1 calc R U . . .
C3 C 1.1748(2) 1.01962(18) 0.21417(7) 0.0296(4) Uani 1 1 d . . . . .
H3A H 1.184529 0.986131 0.245464 0.044 Uiso 1 1 calc R U . . .
H3B H 1.251967 0.998405 0.198112 0.044 Uiso 1 1 calc R U . . .
H3C H 1.168411 1.105553 0.216147 0.044 Uiso 1 1 calc R U . . .
C4 C 0.93057(18) 0.61990(15) 0.18130(6) 0.0211(3) Uani 1 1 d . . . . .
H4A H 0.846661 0.575146 0.180507 0.025 Uiso 1 1 calc R U . . .
H4B H 0.969101 0.603274 0.151935 0.025 Uiso 1 1 calc R U . . .
C5 C 1.0251(2) 0.57089(19) 0.22089(7) 0.0308(4) Uani 1 1 d . . . . .
H5A H 1.038038 0.486407 0.216100 0.046 Uiso 1 1 calc R U . . .
H5B H 1.110452 0.611531 0.221635 0.046 Uiso 1 1 calc R U . . .
H5C H 0.987446 0.583274 0.250340 0.046 Uiso 1 1 calc R U . . .
C6 C 0.8393(2) 0.79531(18) 0.24083(6) 0.0260(4) Uani 1 1 d . . . . .
H6A H 0.758338 0.748064 0.243299 0.031 Uiso 1 1 calc R U . . .
H6B H 0.909852 0.762537 0.263200 0.031 Uiso 1 1 calc R U . . .
C7 C 0.8120(2) 0.9218(2) 0.25495(8) 0.0372(5) Uani 1 1 d . . . . .
H7A H 0.785975 0.922672 0.286586 0.056 Uiso 1 1 calc R U . . .
H7B H 0.892226 0.969278 0.253634 0.056 Uiso 1 1 calc R U . . .
H7C H 0.740357 0.954772 0.233686 0.056 Uiso 1 1 calc R U . . .
C8 C 0.8835(2) 1.08697(17) 0.06070(7) 0.0274(4) Uani 1 1 d . . . . .
H8A H 0.938767 1.158695 0.065196 0.033 Uiso 1 1 calc R U . . .
H8B H 0.932212 1.029884 0.042936 0.033 Uiso 1 1 calc R U . . .
C9 C 0.7547(3) 1.1191(2) 0.03209(8) 0.0411(6) Uani 1 1 d . . . . .
H9A H 0.774415 1.152275 0.002345 0.062 Uiso 1 1 calc R U . . .
H9B H 0.700153 1.048340 0.026600 0.062 Uiso 1 1 calc R U . . .
H9C H 0.706719 1.177378 0.048900 0.062 Uiso 1 1 calc R U . . .
C10 C 0.7979(2) 1.14664(17) 0.14922(8) 0.0322(4) Uani 1 1 d . . . . .
H10A H 0.815250 1.129892 0.182769 0.039 Uiso 0.65 1 calc R U P A 1
H10B H 0.849160 1.217921 0.142806 0.039 Uiso 0.65 1 calc R U P A 1
H10C H 0.703791 1.155912 0.137073 0.039 Uiso 0.35 1 calc R U P B 2
H10D H 0.798293 1.120788 0.181833 0.039 Uiso 0.35 1 calc R U P B 2
C11 C 0.6575(4) 1.1744(4) 0.13945(15) 0.0505(10) Uani 0.65 1 d . . P C 1
H11A H 0.635346 1.241547 0.158464 0.076 Uiso 0.65 1 calc R U P C 1
H11B H 0.638542 1.194404 0.106596 0.076 Uiso 0.65 1 calc R U P C 1
H11C H 0.604495 1.106019 0.146720 0.076 Uiso 0.65 1 calc R U P C 1
C12 C 0.60246(18) 0.57103(15) 0.10186(6) 0.0205(3) Uani 1 1 d . . . . .
H12A H 0.670676 0.531682 0.123287 0.025 Uiso 1 1 calc R U . . .
H12B H 0.519210 0.525818 0.102359 0.025 Uiso 1 1 calc R U . . .
C13 C 0.78414(17) 0.59370(15) 0.05331(6) 0.0186(3) Uani 1 1 d . . . . .
H13A H 0.811267 0.564497 0.023510 0.022 Uiso 1 1 calc R U . . .
H13B H 0.836175 0.549962 0.078423 0.022 Uiso 1 1 calc R U . . .
C14 C 0.6198(2) 0.44681(17) 0.03684(7) 0.0290(4) Uani 1 1 d . . . . .
H14A H 0.647191 0.442246 0.005426 0.043 Uiso 1 1 calc R U . . .
H14B H 0.670991 0.390140 0.056838 0.043 Uiso 1 1 calc R U . . .
H14C H 0.525324 0.428317 0.036034 0.043 Uiso 1 1 calc R U . . .
C15 C 1.00853(17) 0.74150(16) 0.05858(6) 0.0198(3) Uani 1 1 d . . . . .
H15A H 1.041959 0.821397 0.052576 0.024 Uiso 1 1 calc R U . . .
H15B H 1.046399 0.718478 0.090052 0.024 Uiso 1 1 calc R U . . .
C16 C 1.06280(19) 0.65692(16) 0.02394(7) 0.0238(4) Uani 1 1 d . . . . .
H16A H 1.159764 0.660249 0.027312 0.036 Uiso 1 1 calc R U . . .
H16B H 1.033919 0.576517 0.029988 0.036 Uiso 1 1 calc R U . . .
H16C H 1.029460 0.679866 -0.007645 0.036 Uiso 1 1 calc R U . . .
C17 C 0.77797(18) 0.80637(16) 0.00025(6) 0.0219(3) Uani 1 1 d . . . . .
H17A H 0.817824 0.885223 -0.002794 0.026 Uiso 1 1 calc R U . . .
H17B H 0.815485 0.753686 -0.022297 0.026 Uiso 1 1 calc R U . . .
C18 C 0.6286(2) 0.81612(18) -0.01286(7) 0.0268(4) Uani 1 1 d . . . . .
H18A H 0.611896 0.846328 -0.044546 0.040 Uiso 1 1 calc R U . . .
H18B H 0.587926 0.738200 -0.010989 0.040 Uiso 1 1 calc R U . . .
H18C H 0.590271 0.870057 0.008562 0.040 Uiso 1 1 calc R U . . .
C19 C 0.41916(18) 0.75879(17) 0.09028(7) 0.0237(4) Uani 1 1 d . . . . .
H19A H 0.428341 0.744949 0.057053 0.028 Uiso 1 1 calc R U . . .
H19B H 0.349776 0.704670 0.099382 0.028 Uiso 1 1 calc R U . . .
C20 C 0.3717(2) 0.8850(2) 0.09590(8) 0.0327(5) Uani 1 1 d . . . . .
H20A H 0.287598 0.896698 0.076796 0.049 Uiso 1 1 calc R U . . .
H20B H 0.359204 0.899489 0.128482 0.049 Uiso 1 1 calc R U . . .
H20C H 0.437988 0.939881 0.086035 0.049 Uiso 1 1 calc R U . . .
C21 C 0.52695(19) 0.67807(16) 0.18039(6) 0.0230(4) Uani 1 1 d . . . . .
H21A H 0.458690 0.615780 0.175683 0.028 Uiso 1 1 calc R U . . .
H21B H 0.604912 0.642968 0.198557 0.028 Uiso 1 1 calc R U . . .
C22 C 0.4730(2) 0.77562(19) 0.20937(7) 0.0321(4) Uani 1 1 d . . . . .
H22A H 0.450363 0.742880 0.238824 0.048 Uiso 1 1 calc R U . . .
H22B H 0.540427 0.836991 0.215429 0.048 Uiso 1 1 calc R U . . .
H22C H 0.393682 0.809706 0.192474 0.048 Uiso 1 1 calc R U . . .
C23 C 0.2945(2) 0.33163(19) 0.15026(8) 0.0358(5) Uani 1 1 d . . . . .
C11A C 0.8551(5) 1.2624(4) 0.15042(15) 0.0142(8) Uiso 0.35 1 d . . P C 2
H11D H 0.804996 1.314366 0.169261 0.021 Uiso 0.35 1 calc R U P C 2
H11E H 0.947341 1.258224 0.163981 0.021 Uiso 0.35 1 calc R U P C 2
H11F H 0.852033 1.293649 0.118839 0.021 Uiso 0.35 1 calc R U P C 2
F1 F 0.30385(18) 0.22457(12) 0.13214(6) 0.0550(4) Uani 1 1 d . . . . .
F2 F 0.41632(16) 0.36801(15) 0.16434(6) 0.0640(5) Uani 1 1 d . . . . .
F3 F 0.23117(19) 0.31938(14) 0.18837(5) 0.0576(4) Uani 1 1 d . . . . .
H1 H 0.669(2) 0.918(2) 0.1577(8) 0.036(6) Uiso 1 1 d . . . . .
H2 H 0.648(2) 0.914(2) 0.0840(8) 0.033(6) Uiso 1 1 d . . . . .
N1 N 1.05458(15) 0.97290(13) 0.18845(5) 0.0215(3) Uani 1 1 d . . . . .
N2 N 0.64379(14) 0.56618(13) 0.05514(5) 0.0190(3) Uani 1 1 d . . . . .
O1 O 0.29096(17) 0.43462(15) 0.07184(5) 0.0401(4) Uani 1 1 d . . . . .
O2 O 0.08213(18) 0.3821(2) 0.09971(7) 0.0631(6) Uani 1 1 d . . . . .
O3 O 0.21257(19) 0.54232(15) 0.13567(6) 0.0446(4) Uani 1 1 d . . . . .
P1 P 0.86273(4) 1.02349(4) 0.11758(2) 0.01676(8) Uani 1 1 d . . . . .
P2 P 0.88971(4) 0.77740(4) 0.18209(2) 0.01571(8) Uani 1 1 d . . . . .
P3 P 0.57587(4) 0.72009(4) 0.12354(2) 0.01561(8) Uani 1 1 d . . . . .
P4 P 0.82762(4) 0.75085(4) 0.05886(2) 0.01502(8) Uani 1 1 d . . . . .
Rh1 Rh 0.74558(2) 0.85209(2) 0.12078(2) 0.01290(3) Uani 1 1 d . . . . .
S1 S 0.20981(5) 0.43441(5) 0.10954(2) 0.02989(11) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N1 1.457(2) . ?
C1 P1 1.8371(18) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
C2 N1 1.464(2) . ?
C2 P2 1.8469(18) . ?
C2 H2A 0.9900 . ?
C2 H2B 0.9900 . ?
C3 N1 1.465(2) . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?
C4 C5 1.527(3) . ?
C4 P2 1.8365(18) . ?
C4 H4A 0.9900 . ?
C4 H4B 0.9900 . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C6 C7 1.527(3) . ?
C6 P2 1.8383(18) . ?
C6 H6A 0.9900 . ?
C6 H6B 0.9900 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 C9 1.522(3) . ?
C8 P1 1.8319(19) . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 C11A 1.436(5) . ?
C10 C11 1.459(5) . ?
C10 P1 1.831(2) . ?
C10 H10A 0.9900 . ?
C10 H10B 0.9900 . ?
C10 H10C 0.9900 . ?
C10 H10D 0.9900 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 N2 1.459(2) . ?
C12 P3 1.8349(18) . ?
C12 H12A 0.9900 . ?
C12 H12B 0.9900 . ?
C13 N2 1.464(2) . ?
C13 P4 1.8414(17) . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C14 N2 1.467(2) . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 C16 1.531(2) . ?
C15 P4 1.8401(18) . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 C18 1.530(3) . ?
C17 P4 1.8363(18) . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 C20 1.526(3) . ?
C19 P3 1.8302(18) . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 C22 1.525(3) . ?
C21 P3 1.8318(18) . ?
C21 H21A 0.9900 . ?
C21 H21B 0.9900 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 F2 1.329(3) . ?
C23 F1 1.331(3) . ?
C23 F3 1.340(3) . ?
C23 S1 1.815(2) . ?
C11A H11D 0.9800 . ?
C11A H11E 0.9800 . ?
C11A H11F 0.9800 . ?
O1 S1 1.4328(16) . ?
O2 S1 1.4284(19) . ?
O3 S1 1.4396(17) . ?
P1 Rh1 2.2874(4) . ?
P2 Rh1 2.3463(4) . ?
P3 Rh1 2.2906(4) . ?
P4 Rh1 2.3533(4) . ?
Rh1 H1 1.57(2) . ?
Rh1 H2 1.55(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 C1 P1 112.58(12) . . ?
N1 C1 H1A 109.1 . . ?
P1 C1 H1A 109.1 . . ?
N1 C1 H1B 109.1 . . ?
P1 C1 H1B 109.1 . . ?
H1A C1 H1B 107.8 . . ?
N1 C2 P2 113.37(12) . . ?
N1 C2 H2A 108.9 . . ?
P2 C2 H2A 108.9 . . ?
N1 C2 H2B 108.9 . . ?
P2 C2 H2B 108.9 . . ?
H2A C2 H2B 107.7 . . ?
N1 C3 H3A 109.5 . . ?
N1 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
N1 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
C5 C4 P2 118.13(14) . . ?
C5 C4 H4A 107.8 . . ?
P2 C4 H4A 107.8 . . ?
C5 C4 H4B 107.8 . . ?
P2 C4 H4B 107.8 . . ?
H4A C4 H4B 107.1 . . ?
C4 C5 H5A 109.5 . . ?
C4 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C4 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C7 C6 P2 115.30(14) . . ?
C7 C6 H6A 108.5 . . ?
P2 C6 H6A 108.5 . . ?
C7 C6 H6B 108.5 . . ?
P2 C6 H6B 108.5 . . ?
H6A C6 H6B 107.5 . . ?
C6 C7 H7A 109.5 . . ?
C6 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
C6 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C9 C8 P1 114.58(16) . . ?
C9 C8 H8A 108.6 . . ?
P1 C8 H8A 108.6 . . ?
C9 C8 H8B 108.6 . . ?
P1 C8 H8B 108.6 . . ?
H8A C8 H8B 107.6 . . ?
C8 C9 H9A 109.5 . . ?
C8 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C8 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C11A C10 P1 123.1(2) . . ?
C11 C10 P1 117.4(2) . . ?
C11 C10 H10A 107.9 . . ?
P1 C10 H10A 107.9 . . ?
C11 C10 H10B 107.9 . . ?
P1 C10 H10B 107.9 . . ?
H10A C10 H10B 107.2 . . ?
C11A C10 H10C 106.5 . . ?
P1 C10 H10C 106.5 . . ?
C11A C10 H10D 106.5 . . ?
P1 C10 H10D 106.5 . . ?
H10C C10 H10D 106.5 . . ?
C10 C11 H11A 109.5 . . ?
C10 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C10 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
N2 C12 P3 114.76(12) . . ?
N2 C12 H12A 108.6 . . ?
P3 C12 H12A 108.6 . . ?
N2 C12 H12B 108.6 . . ?
P3 C12 H12B 108.6 . . ?
H12A C12 H12B 107.6 . . ?
N2 C13 P4 115.41(12) . . ?
N2 C13 H13A 108.4 . . ?
P4 C13 H13A 108.4 . . ?
N2 C13 H13B 108.4 . . ?
P4 C13 H13B 108.4 . . ?
H13A C13 H13B 107.5 . . ?
N2 C14 H14A 109.5 . . ?
N2 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
N2 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C16 C15 P4 117.59(13) . . ?
C16 C15 H15A 107.9 . . ?
P4 C15 H15A 107.9 . . ?
C16 C15 H15B 107.9 . . ?
P4 C15 H15B 107.9 . . ?
H15A C15 H15B 107.2 . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C18 C17 P4 115.41(13) . . ?
C18 C17 H17A 108.4 . . ?
P4 C17 H17A 108.4 . . ?
C18 C17 H17B 108.4 . . ?
P4 C17 H17B 108.4 . . ?
H17A C17 H17B 107.5 . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C17 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C20 C19 P3 115.85(14) . . ?
C20 C19 H19A 108.3 . . ?
P3 C19 H19A 108.3 . . ?
C20 C19 H19B 108.3 . . ?
P3 C19 H19B 108.3 . . ?
H19A C19 H19B 107.4 . . ?
C19 C20 H20A 109.5 . . ?
C19 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C19 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C22 C21 P3 116.82(13) . . ?
C22 C21 H21A 108.1 . . ?
P3 C21 H21A 108.1 . . ?
C22 C21 H21B 108.1 . . ?
P3 C21 H21B 108.1 . . ?
H21A C21 H21B 107.3 . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
F2 C23 F1 107.8(2) . . ?
F2 C23 F3 106.6(2) . . ?
F1 C23 F3 106.83(18) . . ?
F2 C23 S1 111.50(15) . . ?
F1 C23 S1 112.19(16) . . ?
F3 C23 S1 111.62(18) . . ?
C10 C11A H11D 109.5 . . ?
C10 C11A H11E 109.5 . . ?
H11D C11A H11E 109.5 . . ?
C10 C11A H11F 109.5 . . ?
H11D C11A H11F 109.5 . . ?
H11E C11A H11F 109.5 . . ?
C1 N1 C2 112.54(15) . . ?
C1 N1 C3 110.93(15) . . ?
C2 N1 C3 110.33(15) . . ?
C12 N2 C13 113.34(14) . . ?
C12 N2 C14 108.57(14) . . ?
C13 N2 C14 108.11(14) . . ?
C10 P1 C8 103.32(10) . . ?
C10 P1 C1 101.65(9) . . ?
C8 P1 C1 98.97(9) . . ?
C10 P1 Rh1 114.54(8) . . ?
C8 P1 Rh1 118.56(6) . . ?
C1 P1 Rh1 117.15(6) . . ?
C4 P2 C6 101.72(9) . . ?
C4 P2 C2 101.19(8) . . ?
C6 P2 C2 101.06(9) . . ?
C4 P2 Rh1 117.85(6) . . ?
C6 P2 Rh1 116.91(7) . . ?
C2 P2 Rh1 115.44(6) . . ?
C19 P3 C21 103.78(9) . . ?
C19 P3 C12 100.98(9) . . ?
C21 P3 C12 97.50(8) . . ?
C19 P3 Rh1 116.21(6) . . ?
C21 P3 Rh1 118.28(6) . . ?
C12 P3 Rh1 117.06(6) . . ?
C17 P4 C15 101.42(8) . . ?
C17 P4 C13 102.14(8) . . ?
C15 P4 C13 100.04(8) . . ?
C17 P4 Rh1 116.98(6) . . ?
C15 P4 Rh1 117.41(6) . . ?
C13 P4 Rh1 116.12(6) . . ?
P1 Rh1 P3 162.526(17) . . ?
P1 Rh1 P2 92.908(16) . . ?
P3 Rh1 P2 98.719(16) . . ?
P1 Rh1 P4 99.201(16) . . ?
P3 Rh1 P4 91.792(16) . . ?
P2 Rh1 P4 99.248(16) . . ?
P1 Rh1 H1 85.3(9) . . ?
P3 Rh1 H1 82.1(9) . . ?
P2 Rh1 H1 88.2(9) . . ?
P4 Rh1 H1 171.0(9) . . ?
P1 Rh1 H2 83.3(9) . . ?
P3 Rh1 H2 83.7(9) . . ?
P2 Rh1 H2 173.1(8) . . ?
P4 Rh1 H2 87.1(8) . . ?
H1 Rh1 H2 85.8(12) . . ?
O2 S1 O1 115.29(12) . . ?
O2 S1 O3 115.40(13) . . ?
O1 S1 O3 114.70(11) . . ?
O2 S1 C23 102.97(12) . . ?
O1 S1 C23 103.10(11) . . ?
O3 S1 C23 102.79(10) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P1 C1 N1 C2 82.15(16) . . . . ?
P1 C1 N1 C3 -153.70(13) . . . . ?
P2 C2 N1 C1 -81.55(17) . . . . ?
P2 C2 N1 C3 153.96(14) . . . . ?
P3 C12 N2 C13 77.98(17) . . . . ?
P3 C12 N2 C14 -161.88(13) . . . . ?
P4 C13 N2 C12 -76.09(17) . . . . ?
P4 C13 N2 C14 163.51(13) . . . . ?
C11A C10 P1 C8 -47.9(3) . . . . ?
C11 C10 P1 C8 78.7(3) . . . . ?
C11A C10 P1 C1 54.4(3) . . . . ?
C11 C10 P1 C1 -179.0(3) . . . . ?
C11A C10 P1 Rh1 -178.3(3) . . . . ?
C11 C10 P1 Rh1 -51.7(3) . . . . ?
C9 C8 P1 C10 -67.56(17) . . . . ?
C9 C8 P1 C1 -171.89(15) . . . . ?
C9 C8 P1 Rh1 60.39(17) . . . . ?
N1 C1 P1 C10 74.50(15) . . . . ?
N1 C1 P1 C8 -179.79(13) . . . . ?
N1 C1 P1 Rh1 -51.11(14) . . . . ?
C5 C4 P2 C6 -51.21(17) . . . . ?
C5 C4 P2 C2 52.71(16) . . . . ?
C5 C4 P2 Rh1 179.56(12) . . . . ?
C7 C6 P2 C4 173.79(16) . . . . ?
C7 C6 P2 C2 69.76(17) . . . . ?
C7 C6 P2 Rh1 -56.39(17) . . . . ?
N1 C2 P2 C4 177.26(13) . . . . ?
N1 C2 P2 C6 -78.28(15) . . . . ?
N1 C2 P2 Rh1 48.85(15) . . . . ?
C20 C19 P3 C21 85.28(16) . . . . ?
C20 C19 P3 C12 -174.09(15) . . . . ?
C20 C19 P3 Rh1 -46.35(17) . . . . ?
C22 C21 P3 C19 -67.49(17) . . . . ?
C22 C21 P3 C12 -170.79(15) . . . . ?
C22 C21 P3 Rh1 62.93(17) . . . . ?
N2 C12 P3 C19 74.02(14) . . . . ?
N2 C12 P3 C21 179.70(13) . . . . ?
N2 C12 P3 Rh1 -53.17(14) . . . . ?
C18 C17 P4 C15 175.57(14) . . . . ?
C18 C17 P4 C13 72.54(15) . . . . ?
C18 C17 P4 Rh1 -55.39(15) . . . . ?
C16 C15 P4 C17 -62.56(15) . . . . ?
C16 C15 P4 C13 42.13(15) . . . . ?
C16 C15 P4 Rh1 168.68(11) . . . . ?
N2 C13 P4 C17 -79.43(14) . . . . ?
N2 C13 P4 C15 176.46(13) . . . . ?
N2 C13 P4 Rh1 49.05(14) . . . . ?
F2 C23 S1 O2 -178.55(19) . . . . ?
F1 C23 S1 O2 60.5(2) . . . . ?
F3 C23 S1 O2 -59.39(19) . . . . ?
F2 C23 S1 O1 61.2(2) . . . . ?
F1 C23 S1 O1 -59.77(19) . . . . ?
F3 C23 S1 O1 -179.63(16) . . . . ?
F2 C23 S1 O3 -58.3(2) . . . . ?
F1 C23 S1 O3 -179.29(17) . . . . ?
F3 C23 S1 O3 60.85(18) . . . . ?

_refine_diff_density_max         0.923
_refine_diff_density_min         -0.736
_refine_diff_density_rms         0.083


_chemical_properties_physical    Air-sensitive
