# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_complex_3
_database_code_depnum_ccdc_archive 'CCDC 1846539'
_audit_update_record             
;
2018-05-31 deposited with the CCDC.
2018-08-02 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2016/6
_shelx_SHELXL_version_number     2016/6
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C110 H96 Ag3 Cl3 N2 O8 P8 Pt'
_chemical_formula_weight         2446.69

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   15.977(4)
_cell_length_b                   20.660(6)
_cell_length_c                   21.585(6)
_cell_angle_alpha                87.716(8)
_cell_angle_beta                 78.525(7)
_cell_angle_gamma                69.014(5)
_cell_volume                     6515(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    19581
_cell_measurement_theta_min      2.0734
_cell_measurement_theta_max      27.4700

_exptl_crystal_description       Bloc
_exptl_crystal_colour            Yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.247
_exptl_crystal_F_000             2448
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.42
_exptl_crystal_size_mid          0.36
_exptl_crystal_size_min          0.22
_exptl_absorpt_coefficient_mu    1.720
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.490
_exptl_absorpt_correction_T_max  0.685
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  
;
Saturn724+ (2x2 bin mode)
;
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            64623
_diffrn_reflns_av_unetI/netI     0.1036
_diffrn_reflns_av_R_equivalents  0.0634
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_theta_min         2.189
_diffrn_reflns_theta_max         27.409
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.951
_diffrn_measured_fraction_theta_full 0.969
_diffrn_reflns_Laue_measured_fraction_max 0.951
_diffrn_reflns_Laue_measured_fraction_full 0.969
_diffrn_reflns_point_group_measured_fraction_max 0.951
_diffrn_reflns_point_group_measured_fraction_full 0.969
_reflns_number_total             28214
_reflns_number_gt                17399
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 -0.010 0.008 -0.008 1645 269 ' '
2 0.164 0.958 0.503 7 0 ' '
3 0.500 0.500 1.000 154 44 ' '
4 0.836 0.042 0.497 6 0 ' '
_platon_squeeze_void_probe_radius 1.20
_platon_squeeze_details          
;
The unit cell contains highly disordered CH2Cl2 molecules which have been treated as 
a diffuse contribution to the overall scattering without specific atom 
positions by SQUEEZE/PLATON. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0423P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         28214
_refine_ls_number_parameters     1243
_refine_ls_number_restraints     366
_refine_ls_R_factor_all          0.0607
_refine_ls_R_factor_gt           0.0466
_refine_ls_wR_factor_ref         0.1172
_refine_ls_wR_factor_gt          0.1117
_refine_ls_goodness_of_fit_ref   0.942
_refine_ls_restrained_S_all      0.947
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.23825(2) 0.25557(2) 0.25419(2) 0.03944(6) Uani 1 1 d . . . . .
Ag1 Ag 0.40694(3) 0.17596(2) 0.17104(2) 0.07074(13) Uani 1 1 d . . . . .
Ag2 Ag 0.03733(2) 0.35072(2) 0.27146(2) 0.05879(11) Uani 1 1 d . . . . .
Ag3 Ag 0.20454(2) 0.27514(2) 0.39811(2) 0.05307(10) Uani 1 1 d . . . . .
Cl2 Cl 0.1185(2) 0.96230(14) 0.27252(15) 0.1520(10) Uani 1 1 d . U . . .
Cl3 Cl 0.03641(8) 0.35309(7) 0.39372(6) 0.0639(3) Uani 1 1 d . . . . .
P1 P 0.08103(9) 0.45388(6) 0.24952(6) 0.0517(3) Uani 1 1 d . . . . .
P2 P 0.45164(9) 0.27582(7) 0.14781(6) 0.0556(3) Uani 1 1 d . . . . .
P3 P 0.30385(8) 0.34352(6) 0.39150(6) 0.0485(3) Uani 1 1 d . . . . .
P4 P 0.28488(8) 0.34901(6) 0.25184(5) 0.0424(3) Uani 1 1 d . . . . .
P5 P -0.01496(9) 0.25886(7) 0.24637(6) 0.0544(3) Uani 1 1 d . . . . .
P6 P 0.35094(10) 0.08195(7) 0.16738(6) 0.0606(4) Uani 1 1 d . . . . .
P7 P 0.16961(8) 0.16659(6) 0.41468(6) 0.0477(3) Uani 1 1 d . . . . .
P8 P 0.17907(8) 0.16826(6) 0.26491(5) 0.0430(3) Uani 1 1 d . . . . .
Cl1 Cl 0.3769(2) 0.54830(13) 0.21983(13) 0.1333(8) Uani 0.280(15) 1 d D U P A 1
O1 O 0.380(2) 0.4816(7) 0.2397(12) 0.181(13) Uani 0.280(15) 1 d D U P A 1
O2 O 0.4645(12) 0.5532(18) 0.2152(14) 0.235(14) Uani 0.280(15) 1 d D U P A 1
O3 O 0.3112(19) 0.5996(10) 0.2666(12) 0.232(15) Uani 0.280(15) 1 d D U P A 1
O4 O 0.342(2) 0.563(2) 0.1618(8) 0.266(17) Uani 0.280(15) 1 d D U P A 1
Cl1' Cl 0.3769(2) 0.54830(13) 0.21983(13) 0.1333(8) Uani 0.720(15) 1 d D . P A
2
O1' O 0.4393(8) 0.5063(8) 0.2586(6) 0.251(7) Uani 0.720(15) 1 d D U P A 2
O2' O 0.3901(10) 0.6064(4) 0.1946(5) 0.190(6) Uani 0.720(15) 1 d D U P A 2
O3' O 0.2844(6) 0.5663(8) 0.2576(6) 0.247(7) Uani 0.720(15) 1 d D U P A 2
O4' O 0.3796(9) 0.5017(5) 0.1711(6) 0.223(6) Uani 0.720(15) 1 d D U P A 2
O5 O 0.0806(5) 0.9122(3) 0.2738(3) 0.186(3) Uani 1 1 d . U . . .
O6 O 0.0879(7) 1.0154(4) 0.2322(4) 0.263(4) Uani 1 1 d . U . . .
O7 O 0.0894(7) 1.0023(5) 0.3307(5) 0.271(4) Uani 1 1 d . U . . .
O8 O 0.2131(7) 0.9396(4) 0.2573(7) 0.386(8) Uani 1 1 d . U . . .
N1 N 0.7154(3) -0.0497(3) 0.3722(2) 0.0898(16) Uani 1 1 d . . . . .
N2 N 0.1375(4) 0.3336(3) -0.1286(2) 0.0895(16) Uani 1 1 d . . . . .
C1 C 0.3581(3) 0.3471(2) 0.30751(19) 0.0462(11) Uani 1 1 d . . . . .
H1A H 0.374487 0.388172 0.302473 0.055 Uiso 1 1 calc R U . . .
H1B H 0.414026 0.306971 0.297173 0.055 Uiso 1 1 calc R U . . .
C2 C 0.1919(3) 0.4329(2) 0.2736(2) 0.0500(11) Uani 1 1 d . . . . .
H2A H 0.215846 0.468580 0.257431 0.060 Uiso 1 1 calc R U . . .
H2B H 0.179315 0.437758 0.319405 0.060 Uiso 1 1 calc R U . . .
C3 C 0.3514(3) 0.3560(2) 0.1750(2) 0.0494(11) Uani 1 1 d . . . . .
H3A H 0.372701 0.394203 0.176982 0.059 Uiso 1 1 calc R U . . .
H3B H 0.312109 0.366825 0.144201 0.059 Uiso 1 1 calc R U . . .
C4 C 0.2664(3) 0.0836(2) 0.2395(2) 0.0521(12) Uani 1 1 d . . . . .
H4A H 0.235993 0.052148 0.232588 0.063 Uiso 1 1 calc R U . . .
H4B H 0.298743 0.065770 0.273640 0.063 Uiso 1 1 calc R U . . .
C5 C 0.1234(3) 0.1551(2) 0.3456(2) 0.0518(12) Uani 1 1 d . . . . .
H5A H 0.122705 0.108298 0.346191 0.062 Uiso 1 1 calc R U . . .
H5B H 0.060165 0.186380 0.352187 0.062 Uiso 1 1 calc R U . . .
C6 C 0.0875(3) 0.1799(2) 0.2213(2) 0.0525(12) Uani 1 1 d . . . . .
H6A H 0.069404 0.139615 0.226859 0.063 Uiso 1 1 calc R U . . .
H6B H 0.111257 0.182125 0.176559 0.063 Uiso 1 1 calc R U . . .
C7 C 0.0143(4) 0.5310(3) 0.3010(3) 0.0672(14) Uani 1 1 d . U . . .
C8 C -0.0643(4) 0.5312(3) 0.3408(3) 0.097(2) Uani 1 1 d . U . . .
H8A H -0.084699 0.494525 0.339424 0.117 Uiso 1 1 calc R U . . .
C9 C -0.1139(6) 0.5881(4) 0.3839(3) 0.126(3) Uani 1 1 d . U . . .
H9A H -0.168140 0.589392 0.410380 0.151 Uiso 1 1 calc R U . . .
C10 C -0.0837(7) 0.6390(4) 0.3867(4) 0.141(4) Uani 1 1 d . U . . .
H10F H -0.116428 0.675436 0.415969 0.169 Uiso 1 1 calc R U . . .
C11 C -0.0052(7) 0.6400(4) 0.3476(5) 0.156(4) Uani 1 1 d . U . . .
H11A H 0.014901 0.676611 0.350709 0.187 Uiso 1 1 calc R U . . .
C12 C 0.0441(5) 0.5862(3) 0.3033(4) 0.113(2) Uani 1 1 d . U . . .
H12A H 0.096309 0.587018 0.275641 0.135 Uiso 1 1 calc R U . . .
C13 C 0.0938(4) 0.4882(2) 0.1700(2) 0.0611(14) Uani 1 1 d . . . . .
C14 C 0.0289(4) 0.4877(3) 0.1368(3) 0.0870(19) Uani 1 1 d . . . . .
H14A H -0.014368 0.468445 0.154689 0.104 Uiso 1 1 calc R U . . .
C15 C 0.0266(6) 0.5163(4) 0.0755(3) 0.110(3) Uani 1 1 d . . . . .
H15A H -0.017440 0.517050 0.052705 0.132 Uiso 1 1 calc R U . . .
C16 C 0.0937(7) 0.5425(4) 0.0527(3) 0.121(3) Uani 1 1 d . . . . .
H16A H 0.093594 0.562681 0.013422 0.145 Uiso 1 1 calc R U . . .
C17 C 0.1625(6) 0.5409(4) 0.0846(4) 0.117(3) Uani 1 1 d . . . . .
H17A H 0.208595 0.557226 0.066199 0.140 Uiso 1 1 calc R U . . .
C18 C 0.1596(4) 0.5139(3) 0.1450(3) 0.0806(17) Uani 1 1 d . . . . .
H18A H 0.202989 0.513670 0.168131 0.097 Uiso 1 1 calc R U . . .
C19 C 0.5405(3) 0.2808(3) 0.1862(3) 0.0642(14) Uani 1 1 d . . . . .
C20 C 0.5938(4) 0.2200(4) 0.2120(3) 0.101(2) Uani 1 1 d . . . . .
H20A H 0.582755 0.179026 0.209684 0.121 Uiso 1 1 calc R U . . .
C21 C 0.6644(6) 0.2221(5) 0.2414(4) 0.125(3) Uani 1 1 d . . . . .
H21A H 0.701790 0.181860 0.257084 0.150 Uiso 1 1 calc R U . . .
C22 C 0.6778(5) 0.2841(6) 0.2468(4) 0.135(4) Uani 1 1 d . . . . .
H22A H 0.723311 0.285382 0.267216 0.162 Uiso 1 1 calc R U . . .
C23 C 0.6241(6) 0.3444(5) 0.2221(4) 0.115(3) Uani 1 1 d . . . . .
H23A H 0.633163 0.385920 0.226003 0.138 Uiso 1 1 calc R U . . .
C24 C 0.5569(4) 0.3414(4) 0.1918(3) 0.0899(19) Uani 1 1 d . . . . .
H24A H 0.521630 0.381521 0.174577 0.108 Uiso 1 1 calc R U . . .
C25 C 0.4831(4) 0.2887(3) 0.0637(2) 0.0641(13) Uani 1 1 d . U . . .
C26 C 0.4302(4) 0.2829(3) 0.0238(3) 0.0776(16) Uani 1 1 d . U . . .
H26A H 0.379777 0.270731 0.040416 0.093 Uiso 1 1 calc R U . . .
C27 C 0.4465(5) 0.2937(3) -0.0375(3) 0.106(2) Uani 1 1 d . U . . .
H27A H 0.404824 0.292259 -0.061484 0.127 Uiso 1 1 calc R U . . .
C28 C 0.5226(6) 0.3071(4) -0.0667(4) 0.119(3) Uani 1 1 d . U . . .
H28A H 0.536081 0.311979 -0.110221 0.143 Uiso 1 1 calc R U . . .
C29 C 0.5759(6) 0.3125(4) -0.0287(4) 0.122(3) Uani 1 1 d . U . . .
H29A H 0.627329 0.322785 -0.046865 0.147 Uiso 1 1 calc R U . . .
C30 C 0.5603(4) 0.3037(3) 0.0369(3) 0.093(2) Uani 1 1 d . U . . .
H30A H 0.599958 0.307848 0.061370 0.112 Uiso 1 1 calc R U . . .
C31 C 0.4048(3) 0.3076(3) 0.4279(2) 0.0571(13) Uani 1 1 d . . . . .
C32 C 0.3991(4) 0.2668(3) 0.4800(3) 0.0827(17) Uani 1 1 d . . . . .
H32A H 0.344396 0.259714 0.495238 0.099 Uiso 1 1 calc R U . . .
C33 C 0.4713(6) 0.2363(4) 0.5100(3) 0.112(3) Uani 1 1 d . . . . .
H33A H 0.465955 0.209377 0.545096 0.135 Uiso 1 1 calc R U . . .
C34 C 0.5511(6) 0.2470(4) 0.4866(4) 0.118(3) Uani 1 1 d . . . . .
H34A H 0.601101 0.225747 0.505661 0.141 Uiso 1 1 calc R U . . .
C35 C 0.5600(5) 0.2883(4) 0.4355(4) 0.109(2) Uani 1 1 d . . . . .
H35A H 0.614232 0.296174 0.420940 0.130 Uiso 1 1 calc R U . . .
C36 C 0.4849(4) 0.3177(3) 0.4065(3) 0.0824(18) Uani 1 1 d . . . . .
H36A H 0.489808 0.344974 0.371537 0.099 Uiso 1 1 calc R U . . .
C37 C 0.2509(4) 0.4344(2) 0.4199(2) 0.0571(13) Uani 1 1 d . . . . .
C38 C 0.1618(4) 0.4555(3) 0.4545(3) 0.0777(17) Uani 1 1 d . . . . .
H38A H 0.131121 0.424364 0.460443 0.093 Uiso 1 1 calc R U . . .
C39 C 0.1178(5) 0.5231(3) 0.4805(3) 0.099(2) Uani 1 1 d . . . . .
H39A H 0.058670 0.537465 0.504442 0.119 Uiso 1 1 calc R U . . .
C42 C 0.2937(5) 0.4821(3) 0.4084(3) 0.104(2) Uani 1 1 d . . . . .
H42A H 0.352999 0.468218 0.384800 0.124 Uiso 1 1 calc R U . . .
C43 C -0.0722(3) 0.2709(3) 0.1800(2) 0.0658(14) Uani 1 1 d . . . . .
C44 C -0.1176(4) 0.3384(3) 0.1639(3) 0.0824(18) Uani 1 1 d . . . . .
H44A H -0.115522 0.375171 0.186208 0.099 Uiso 1 1 calc R U . . .
C45 C -0.1668(5) 0.3524(4) 0.1145(4) 0.111(3) Uani 1 1 d . . . . .
H45A H -0.199765 0.397967 0.106178 0.133 Uiso 1 1 calc R U . . .
C46 C -0.1661(6) 0.2974(6) 0.0776(4) 0.135(3) Uani 1 1 d . U . . .
H46A H -0.195953 0.305682 0.043596 0.161 Uiso 1 1 calc R U . . .
C47 C -0.1194(5) 0.2308(5) 0.0937(4) 0.124(3) Uani 1 1 d . U . . .
H47A H -0.117541 0.193999 0.069352 0.148 Uiso 1 1 calc R U . . .
C48 C -0.0745(4) 0.2159(4) 0.1452(3) 0.0897(19) Uani 1 1 d . . . . .
H48A H -0.046701 0.170203 0.156057 0.108 Uiso 1 1 calc R U . . .
C49 C -0.0844(4) 0.2304(3) 0.3096(3) 0.0721(14) Uani 1 1 d . U . . .
C50 C -0.1251(4) 0.2721(4) 0.3644(3) 0.0930(17) Uani 1 1 d . U . . .
H50A H -0.119479 0.315223 0.365915 0.112 Uiso 1 1 calc R U . . .
C51 C -0.1737(5) 0.2510(5) 0.4168(4) 0.119(2) Uani 1 1 d . U . . .
H51A H -0.199454 0.279460 0.453109 0.143 Uiso 1 1 calc R U . . .
C52 C -0.1834(5) 0.1890(5) 0.4147(4) 0.127(2) Uani 1 1 d . U . . .
H52A H -0.216743 0.175699 0.449985 0.152 Uiso 1 1 calc R U . . .
C53 C -0.1469(5) 0.1459(4) 0.3639(4) 0.123(2) Uani 1 1 d . U . . .
H53A H -0.154642 0.103429 0.363872 0.147 Uiso 1 1 calc R U . . .
C54 C -0.0946(4) 0.1666(4) 0.3084(3) 0.0997(19) Uani 1 1 d . U . . .
H54A H -0.068430 0.137261 0.272685 0.120 Uiso 1 1 calc R U . . .
C55 C 0.4358(4) -0.0069(3) 0.1645(3) 0.0689(15) Uani 1 1 d . . . . .
C56 C 0.5224(5) -0.0169(3) 0.1671(3) 0.102(2) Uani 1 1 d . . . . .
H56A H 0.540228 0.020880 0.169921 0.123 Uiso 1 1 calc R U . . .
C57 C 0.5853(6) -0.0836(4) 0.1655(4) 0.135(3) Uani 1 1 d . . . . .
H57A H 0.645253 -0.090186 0.167899 0.162 Uiso 1 1 calc R U . . .
C58 C 0.5619(6) -0.1395(4) 0.1604(4) 0.133(3) Uani 1 1 d . . . . .
H58A H 0.605844 -0.183926 0.156697 0.160 Uiso 1 1 calc R U . . .
C59 C 0.4780(7) -0.1304(4) 0.1609(4) 0.132(3) Uani 1 1 d . . . . .
H59A H 0.461369 -0.169006 0.159803 0.158 Uiso 1 1 calc R U . . .
C60 C 0.4110(5) -0.0644(3) 0.1628(4) 0.128(3) Uani 1 1 d . . . . .
H60A H 0.350647 -0.059127 0.163060 0.154 Uiso 1 1 calc R U . . .
C61 C 0.2912(5) 0.0873(3) 0.1017(3) 0.0764(17) Uani 1 1 d . . . . .
C62 C 0.2229(5) 0.0622(3) 0.1026(3) 0.091(2) Uani 1 1 d . . . . .
H62A H 0.205411 0.039360 0.137984 0.109 Uiso 1 1 calc R U . . .
C66 C 0.3156(6) 0.1227(4) 0.0496(3) 0.119(3) Uani 1 1 d . . . . .
H66A H 0.360107 0.142058 0.048818 0.143 Uiso 1 1 calc R U . . .
C67 C 0.0734(3) 0.1634(3) 0.4776(2) 0.0545(12) Uani 1 1 d . . . . .
C68 C 0.0252(4) 0.2211(3) 0.5166(2) 0.0777(17) Uani 1 1 d . . . . .
H68A H 0.040051 0.260768 0.510268 0.093 Uiso 1 1 calc R U . . .
C69 C -0.0452(5) 0.2205(4) 0.5651(3) 0.104(2) Uani 1 1 d . . . . .
H69A H -0.077386 0.259162 0.592042 0.125 Uiso 1 1 calc R U . . .
C70 C -0.0672(5) 0.1609(5) 0.5731(3) 0.109(2) Uani 1 1 d . . . . .
H70A H -0.112767 0.159088 0.606696 0.130 Uiso 1 1 calc R U . . .
C71 C -0.0230(5) 0.1056(4) 0.5326(4) 0.107(2) Uani 1 1 d . . . . .
H71A H -0.040737 0.067192 0.535988 0.128 Uiso 1 1 calc R U . . .
C72 C 0.0494(4) 0.1073(3) 0.4857(3) 0.0886(19) Uani 1 1 d . . . . .
H72A H 0.082273 0.068392 0.459172 0.106 Uiso 1 1 calc R U . . .
C73 C 0.2608(3) 0.0851(3) 0.4236(2) 0.0589(13) Uani 1 1 d . U . . .
C74 C 0.2663(4) 0.0209(3) 0.4034(3) 0.0776(16) Uani 1 1 d . U . . .
H74A H 0.226187 0.016961 0.379176 0.093 Uiso 1 1 calc R U . . .
C75 C 0.3352(5) -0.0391(3) 0.4205(3) 0.102(2) Uani 1 1 d . U . . .
H75A H 0.340816 -0.082703 0.406322 0.122 Uiso 1 1 calc R U . . .
C76 C 0.3934(5) -0.0340(4) 0.4576(4) 0.109(3) Uani 1 1 d . U . . .
H76A H 0.439331 -0.073322 0.467559 0.131 Uiso 1 1 calc R U . . .
C77 C 0.3825(4) 0.0282(4) 0.4788(3) 0.100(2) Uani 1 1 d . U . . .
H77A H 0.418252 0.031398 0.506781 0.120 Uiso 1 1 calc R U . . .
C78 C 0.3206(3) 0.0885(3) 0.4614(3) 0.0739(15) Uani 1 1 d . U . . .
H78A H 0.318711 0.131335 0.474861 0.089 Uiso 1 1 calc R U . . .
C79 C 0.3318(3) 0.1993(2) 0.30414(18) 0.0388(9) Uani 1 1 d . . . . .
C80 C 0.4016(3) 0.1583(2) 0.3178(2) 0.0485(11) Uani 1 1 d . . . . .
C81 C 0.4835(3) 0.1069(2) 0.3325(2) 0.0528(12) Uani 1 1 d . . . . .
C82 C 0.5485(3) 0.1277(3) 0.3535(2) 0.0668(14) Uani 1 1 d . . . . .
H82A H 0.537837 0.174739 0.358065 0.080 Uiso 1 1 calc R U . . .
C83 C 0.6286(4) 0.0789(3) 0.3676(3) 0.0809(17) Uani 1 1 d . . . . .
H83A H 0.671304 0.092417 0.381783 0.097 Uiso 1 1 calc R U . . .
C84 C 0.6418(4) 0.0088(3) 0.3594(3) 0.0745(17) Uani 1 1 d . . . . .
C85 C 0.5792(4) -0.0131(3) 0.3409(2) 0.0613(14) Uani 1 1 d . . . . .
C86 C 0.4999(3) 0.0349(3) 0.3274(2) 0.0618(14) Uani 1 1 d . . . . .
H86A H 0.457056 0.020155 0.314833 0.074 Uiso 1 1 calc R U . . .
C95 C 0.1809(3) 0.2941(2) 0.1805(2) 0.0440(10) Uani 1 1 d . . . . .
C96 C 0.1664(3) 0.3067(2) 0.1271(2) 0.0510(11) Uani 1 1 d . . . . .
C97 C 0.1526(3) 0.3167(3) 0.0628(2) 0.0535(12) Uani 1 1 d . . . . .
C102 C 0.1940(4) 0.3544(3) 0.0212(3) 0.0674(14) Uani 1 1 d . . . . .
H10B H 0.227586 0.377278 0.035572 0.081 Uiso 1 1 calc R U . . .
C98 C 0.0977(4) 0.2855(3) 0.0400(2) 0.0699(15) Uani 1 1 d . . . . .
H98A H 0.067855 0.261528 0.067819 0.084 Uiso 1 1 calc R U . . .
C87 C 0.6979(4) -0.1083(4) 0.3588(3) 0.090(2) Uani 1 1 d . . . . .
C93 C 0.7968(5) -0.0482(4) 0.3916(4) 0.125(3) Uani 1 1 d . . . . .
H93A H 0.779653 -0.006142 0.417144 0.150 Uiso 1 1 calc R U . . .
H93B H 0.817433 -0.087096 0.418432 0.150 Uiso 1 1 calc R U . . .
C88 C 0.7524(5) -0.1795(4) 0.3647(3) 0.116(3) Uani 1 1 d . . . . .
H88A H 0.808414 -0.193354 0.377358 0.140 Uiso 1 1 calc R U . . .
C91 C 0.5793(5) -0.1395(3) 0.3259(3) 0.090(2) Uani 1 1 d . . . . .
H91A H 0.522666 -0.126659 0.314296 0.108 Uiso 1 1 calc R U . . .
C63 C 0.1778(6) 0.0699(4) 0.0512(4) 0.136(3) Uani 1 1 d . . . . .
H63A H 0.131290 0.052817 0.051193 0.163 Uiso 1 1 calc R U . . .
C94 C 0.8694(6) -0.0505(6) 0.3438(5) 0.203(5) Uani 1 1 d . . . . .
H94A H 0.919075 -0.049229 0.361883 0.305 Uiso 1 1 calc R U . . .
H94B H 0.888827 -0.092647 0.318826 0.305 Uiso 1 1 calc R U . . .
H94C H 0.850928 -0.011439 0.317534 0.305 Uiso 1 1 calc R U . . .
C89 C 0.7125(7) -0.2274(4) 0.3491(4) 0.127(3) Uani 1 1 d . . . . .
H89A H 0.744368 -0.274510 0.352576 0.152 Uiso 1 1 calc R U . . .
C90 C 0.6318(6) -0.2087(4) 0.3299(4) 0.117(3) Uani 1 1 d . . . . .
H90A H 0.611347 -0.242819 0.319174 0.140 Uiso 1 1 calc R U . . .
C92 C 0.6134(4) -0.0892(3) 0.3397(3) 0.083(2) Uani 1 1 d . . . . .
C101 C 0.1853(4) 0.3582(3) -0.0428(2) 0.0673(15) Uani 1 1 d . . . . .
C100 C 0.1329(4) 0.3249(3) -0.0628(2) 0.0698(15) Uani 1 1 d . . . . .
C99 C 0.0875(4) 0.2901(3) -0.0233(2) 0.0786(17) Uani 1 1 d . . . . .
H99A H 0.050896 0.270065 -0.037746 0.094 Uiso 1 1 calc R U . . .
C103 C 0.2214(4) 0.3888(3) -0.0974(3) 0.0876(18) Uani 1 1 d . U . . .
C104 C 0.1896(5) 0.3727(4) -0.1481(3) 0.094(2) Uani 1 1 d . U . . .
C105 C 0.2124(6) 0.3954(5) -0.2100(3) 0.143(3) Uani 1 1 d . U . . .
H10A H 0.191582 0.385086 -0.244327 0.172 Uiso 1 1 calc R U . . .
C106 C 0.2706(8) 0.4359(6) -0.2151(5) 0.176(4) Uani 1 1 d . U . . .
H10C H 0.289329 0.451658 -0.254496 0.211 Uiso 1 1 calc R U . . .
C107 C 0.2984(7) 0.4515(5) -0.1653(5) 0.168(4) Uani 1 1 d . U . . .
H10D H 0.334145 0.479021 -0.171148 0.201 Uiso 1 1 calc R U . . .
C108 C 0.2769(6) 0.4291(4) -0.1064(3) 0.118(2) Uani 1 1 d . U . . .
H10E H 0.298453 0.440190 -0.072834 0.141 Uiso 1 1 calc R U . . .
C109 C 0.0931(6) 0.3029(5) -0.1663(3) 0.128(3) Uani 1 1 d . . . . .
H10H H 0.081903 0.329710 -0.203704 0.153 Uiso 1 1 calc R U . . .
H10I H 0.034755 0.304099 -0.141651 0.153 Uiso 1 1 calc R U . . .
C110 C 0.1538(7) 0.2286(5) -0.1857(4) 0.173(4) Uani 1 1 d . . . . .
H11B H 0.124454 0.208891 -0.210310 0.260 Uiso 1 1 calc R U . . .
H11C H 0.211261 0.227676 -0.210480 0.260 Uiso 1 1 calc R U . . .
H11D H 0.164221 0.202125 -0.148570 0.260 Uiso 1 1 calc R U . . .
C133 C 0.1672(6) 0.5687(3) 0.4689(4) 0.117(3) Uani 1 1 d . U . . .
H13A H 0.141321 0.612879 0.487897 0.141 Uiso 1 1 calc R U . . .
C134 C 0.2511(6) 0.5498(4) 0.4308(4) 0.123(3) Uani 1 1 d . U . . .
H13B H 0.279380 0.582036 0.419985 0.147 Uiso 1 1 calc R U . . .
C64 C 0.2088(7) 0.1055(5) 0.0001(5) 0.144(3) Uiso 1 1 d . . . . .
H64A H 0.180068 0.111979 -0.034325 0.173 Uiso 1 1 calc R U . . .
C65 C 0.2712(6) 0.1291(5) -0.0034(5) 0.146(3) Uiso 1 1 d . . . . .
H65B H 0.288811 0.150530 -0.039705 0.175 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C95 1.989(4) . ?
Pt1 C79 2.012(4) . ?
Pt1 P4 2.3003(13) . ?
Pt1 P8 2.3029(13) . ?
Pt1 Ag1 2.8853(7) . ?
Pt1 Ag2 3.0611(8) . ?
Pt1 Ag3 3.0632(9) . ?
Ag1 P2 2.4184(14) . ?
Ag1 P6 2.4217(15) . ?
Ag2 P5 2.4476(15) . ?
Ag2 P1 2.4714(15) . ?
Ag2 C95 2.637(4) . ?
Ag2 Cl3 2.6383(14) . ?
Ag3 P3 2.4563(14) . ?
Ag3 P7 2.4944(14) . ?
Ag3 Cl3 2.6093(14) . ?
Ag3 C79 2.653(4) . ?
Cl2 O5 1.371(5) . ?
Cl2 O6 1.381(8) . ?
Cl2 O8 1.386(9) . ?
Cl2 O7 1.431(9) . ?
P1 C13 1.832(5) . ?
P1 C7 1.833(5) . ?
P1 C2 1.843(4) . ?
P2 C19 1.814(6) . ?
P2 C25 1.820(5) . ?
P2 C3 1.860(4) . ?
P3 C37 1.833(5) . ?
P3 C31 1.836(5) . ?
P3 C1 1.858(4) . ?
P4 C3 1.813(4) . ?
P4 C1 1.826(4) . ?
P4 C2 1.836(4) . ?
P5 C49 1.801(6) . ?
P5 C43 1.812(5) . ?
P5 C6 1.855(5) . ?
P6 C4 1.839(5) . ?
P6 C61 1.840(6) . ?
P6 C55 1.845(5) . ?
P7 C73 1.823(5) . ?
P7 C5 1.849(4) . ?
P7 C67 1.857(5) . ?
P8 C4 1.826(4) . ?
P8 C6 1.834(4) . ?
P8 C5 1.848(4) . ?
Cl1 O1 1.413(8) . ?
Cl1 O2 1.422(9) . ?
Cl1 O4 1.445(9) . ?
Cl1 O3 1.453(9) . ?
Cl1' O2' 1.366(6) . ?
Cl1' O4' 1.437(7) . ?
Cl1' O1' 1.450(7) . ?
Cl1' O3' 1.462(7) . ?
N1 C87 1.388(8) . ?
N1 C84 1.416(6) . ?
N1 C93 1.454(8) . ?
N2 C104 1.355(8) . ?
N2 C100 1.415(6) . ?
N2 C109 1.470(8) . ?
C7 C8 1.372(8) . ?
C7 C12 1.390(8) . ?
C8 C9 1.414(8) . ?
C9 C10 1.313(11) . ?
C10 C11 1.371(12) . ?
C11 C12 1.389(10) . ?
C13 C18 1.353(7) . ?
C13 C14 1.375(7) . ?
C14 C15 1.431(8) . ?
C15 C16 1.367(10) . ?
C16 C17 1.399(10) . ?
C17 C18 1.396(8) . ?
C19 C24 1.382(7) . ?
C19 C20 1.407(7) . ?
C20 C21 1.414(9) . ?
C21 C22 1.385(11) . ?
C22 C23 1.391(10) . ?
C23 C24 1.385(8) . ?
C25 C26 1.357(7) . ?
C25 C30 1.388(7) . ?
C26 C27 1.322(8) . ?
C27 C28 1.369(9) . ?
C28 C29 1.329(10) . ?
C29 C30 1.404(8) . ?
C31 C36 1.358(7) . ?
C31 C32 1.387(7) . ?
C32 C33 1.375(8) . ?
C33 C34 1.365(9) . ?
C34 C35 1.385(9) . ?
C35 C36 1.396(7) . ?
C37 C42 1.377(7) . ?
C37 C38 1.390(7) . ?
C38 C39 1.402(7) . ?
C39 C133 1.417(9) . ?
C42 C134 1.376(8) . ?
C43 C44 1.389(7) . ?
C43 C48 1.401(7) . ?
C44 C45 1.409(8) . ?
C45 C46 1.409(10) . ?
C46 C47 1.378(10) . ?
C47 C48 1.407(8) . ?
C49 C54 1.386(8) . ?
C49 C50 1.391(8) . ?
C50 C51 1.388(8) . ?
C51 C52 1.347(10) . ?
C52 C53 1.338(10) . ?
C53 C54 1.459(9) . ?
C55 C56 1.335(8) . ?
C55 C60 1.384(8) . ?
C56 C57 1.382(9) . ?
C57 C58 1.349(10) . ?
C58 C59 1.282(10) . ?
C59 C60 1.396(9) . ?
C61 C62 1.362(8) . ?
C61 C66 1.385(8) . ?
C62 C63 1.412(9) . ?
C66 C65 1.439(10) . ?
C67 C72 1.340(7) . ?
C67 C68 1.374(7) . ?
C68 C69 1.379(7) . ?
C69 C70 1.392(9) . ?
C70 C71 1.351(9) . ?
C71 C72 1.386(7) . ?
C73 C74 1.380(7) . ?
C73 C78 1.394(7) . ?
C74 C75 1.427(8) . ?
C75 C76 1.376(9) . ?
C76 C77 1.320(9) . ?
C77 C78 1.378(7) . ?
C79 C80 1.216(5) . ?
C80 C81 1.444(6) . ?
C81 C82 1.411(6) . ?
C81 C86 1.420(6) . ?
C82 C83 1.397(7) . ?
C83 C84 1.399(7) . ?
C84 C85 1.365(7) . ?
C85 C86 1.378(6) . ?
C85 C92 1.468(7) . ?
C95 C96 1.220(6) . ?
C96 C97 1.444(6) . ?
C97 C102 1.389(6) . ?
C97 C98 1.423(6) . ?
C102 C101 1.413(7) . ?
C98 C99 1.405(7) . ?
C87 C92 1.406(8) . ?
C87 C88 1.432(8) . ?
C93 C94 1.378(10) . ?
C88 C89 1.437(10) . ?
C91 C90 1.385(8) . ?
C91 C92 1.399(8) . ?
C63 C64 1.409(10) . ?
C89 C90 1.352(10) . ?
C101 C100 1.393(7) . ?
C101 C103 1.432(7) . ?
C100 C99 1.359(7) . ?
C103 C104 1.393(8) . ?
C103 C108 1.401(8) . ?
C104 C105 1.421(8) . ?
C105 C106 1.445(12) . ?
C106 C107 1.333(12) . ?
C107 C108 1.357(10) . ?
C109 C110 1.516(10) . ?
C133 C134 1.355(9) . ?
C64 C65 1.245(10) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C95 Pt1 C79 160.12(16) . . ?
C95 Pt1 P4 87.97(12) . . ?
C79 Pt1 P4 92.88(12) . . ?
C95 Pt1 P8 92.95(12) . . ?
C79 Pt1 P8 88.28(12) . . ?
P4 Pt1 P8 173.99(4) . . ?
C95 Pt1 Ag1 90.94(12) . . ?
C79 Pt1 Ag1 69.20(11) . . ?
P4 Pt1 Ag1 90.69(3) . . ?
P8 Pt1 Ag1 95.23(4) . . ?
C95 Pt1 Ag2 58.45(12) . . ?
C79 Pt1 Ag2 141.28(11) . . ?
P4 Pt1 Ag2 91.61(4) . . ?
P8 Pt1 Ag2 83.83(4) . . ?
Ag1 Pt1 Ag2 149.175(16) . . ?
C95 Pt1 Ag3 140.98(12) . . ?
C79 Pt1 Ag3 58.75(11) . . ?
P4 Pt1 Ag3 84.61(3) . . ?
P8 Pt1 Ag3 90.97(3) . . ?
Ag1 Pt1 Ag3 127.326(16) . . ?
Ag2 Pt1 Ag3 83.485(14) . . ?
P2 Ag1 P6 164.90(5) . . ?
P2 Ag1 Pt1 92.99(4) . . ?
P6 Ag1 Pt1 89.99(4) . . ?
P5 Ag2 P1 155.18(5) . . ?
P5 Ag2 C95 86.34(10) . . ?
P1 Ag2 C95 82.40(10) . . ?
P5 Ag2 Cl3 109.47(5) . . ?
P1 Ag2 Cl3 94.96(4) . . ?
C95 Ag2 Cl3 126.53(10) . . ?
P5 Ag2 Pt1 94.26(4) . . ?
P1 Ag2 Pt1 91.23(4) . . ?
C95 Ag2 Pt1 40.00(10) . . ?
Cl3 Ag2 Pt1 87.03(3) . . ?
P3 Ag3 P7 153.85(4) . . ?
P3 Ag3 Cl3 111.86(5) . . ?
P7 Ag3 Cl3 94.05(5) . . ?
P3 Ag3 C79 84.38(9) . . ?
P7 Ag3 C79 82.51(9) . . ?
Cl3 Ag3 C79 127.29(10) . . ?
P3 Ag3 Pt1 93.04(3) . . ?
P7 Ag3 Pt1 91.51(3) . . ?
Cl3 Ag3 Pt1 87.50(3) . . ?
C79 Ag3 Pt1 40.42(9) . . ?
O5 Cl2 O6 114.4(6) . . ?
O5 Cl2 O8 116.2(5) . . ?
O6 Cl2 O8 105.7(6) . . ?
O5 Cl2 O7 112.5(5) . . ?
O6 Cl2 O7 98.8(6) . . ?
O8 Cl2 O7 107.7(8) . . ?
Ag3 Cl3 Ag2 101.97(4) . . ?
C13 P1 C7 104.1(2) . . ?
C13 P1 C2 106.5(2) . . ?
C7 P1 C2 99.0(2) . . ?
C13 P1 Ag2 121.73(18) . . ?
C7 P1 Ag2 116.6(2) . . ?
C2 P1 Ag2 106.15(14) . . ?
C19 P2 C25 108.3(2) . . ?
C19 P2 C3 105.0(2) . . ?
C25 P2 C3 103.0(2) . . ?
C19 P2 Ag1 116.09(19) . . ?
C25 P2 Ag1 114.06(18) . . ?
C3 P2 Ag1 109.19(15) . . ?
C37 P3 C31 104.8(2) . . ?
C37 P3 C1 104.7(2) . . ?
C31 P3 C1 101.2(2) . . ?
C37 P3 Ag3 117.82(18) . . ?
C31 P3 Ag3 116.95(17) . . ?
C1 P3 Ag3 109.44(15) . . ?
C3 P4 C1 104.5(2) . . ?
C3 P4 C2 108.3(2) . . ?
C1 P4 C2 101.3(2) . . ?
C3 P4 Pt1 111.72(15) . . ?
C1 P4 Pt1 115.24(15) . . ?
C2 P4 Pt1 114.73(16) . . ?
C49 P5 C43 105.6(2) . . ?
C49 P5 C6 103.9(2) . . ?
C43 P5 C6 102.5(2) . . ?
C49 P5 Ag2 117.5(2) . . ?
C43 P5 Ag2 117.6(2) . . ?
C6 P5 Ag2 107.79(15) . . ?
C4 P6 C61 105.2(3) . . ?
C4 P6 C55 103.0(2) . . ?
C61 P6 C55 107.0(3) . . ?
C4 P6 Ag1 110.70(15) . . ?
C61 P6 Ag1 113.3(2) . . ?
C55 P6 Ag1 116.6(2) . . ?
C73 P7 C5 107.4(2) . . ?
C73 P7 C67 102.5(2) . . ?
C5 P7 C67 98.0(2) . . ?
C73 P7 Ag3 119.46(18) . . ?
C5 P7 Ag3 106.31(15) . . ?
C67 P7 Ag3 120.59(17) . . ?
C4 P8 C6 106.4(2) . . ?
C4 P8 C5 104.3(2) . . ?
C6 P8 C5 101.1(2) . . ?
C4 P8 Pt1 112.26(16) . . ?
C6 P8 Pt1 114.87(15) . . ?
C5 P8 Pt1 116.61(15) . . ?
O1 Cl1 O2 109.5(12) . . ?
O1 Cl1 O4 109.6(12) . . ?
O2 Cl1 O4 113.8(12) . . ?
O1 Cl1 O3 108.8(11) . . ?
O2 Cl1 O3 108.8(11) . . ?
O4 Cl1 O3 106.2(12) . . ?
O2' Cl1' O4' 111.0(6) . . ?
O2' Cl1' O1' 118.3(7) . . ?
O4' Cl1' O1' 105.5(7) . . ?
O2' Cl1' O3' 110.3(7) . . ?
O4' Cl1' O3' 103.6(6) . . ?
O1' Cl1' O3' 107.0(8) . . ?
C87 N1 C84 107.3(5) . . ?
C87 N1 C93 126.8(5) . . ?
C84 N1 C93 125.8(6) . . ?
C104 N2 C100 107.9(5) . . ?
C104 N2 C109 128.6(5) . . ?
C100 N2 C109 123.4(6) . . ?
P4 C1 P3 113.6(2) . . ?
P4 C2 P1 121.5(2) . . ?
P4 C3 P2 113.5(2) . . ?
P8 C4 P6 115.9(2) . . ?
P8 C5 P7 120.2(2) . . ?
P8 C6 P5 113.8(2) . . ?
C8 C7 C12 120.0(6) . . ?
C8 C7 P1 117.9(5) . . ?
C12 C7 P1 122.0(5) . . ?
C7 C8 C9 119.1(7) . . ?
C10 C9 C8 120.2(9) . . ?
C9 C10 C11 122.0(8) . . ?
C10 C11 C12 119.6(9) . . ?
C11 C12 C7 119.1(8) . . ?
C18 C13 C14 121.1(5) . . ?
C18 C13 P1 124.1(4) . . ?
C14 C13 P1 114.7(5) . . ?
C13 C14 C15 121.4(7) . . ?
C16 C15 C14 115.1(7) . . ?
C15 C16 C17 124.3(7) . . ?
C18 C17 C16 117.7(7) . . ?
C13 C18 C17 120.2(6) . . ?
C24 C19 C20 119.2(6) . . ?
C24 C19 P2 123.0(4) . . ?
C20 C19 P2 117.8(5) . . ?
C19 C20 C21 119.1(7) . . ?
C22 C21 C20 120.0(9) . . ?
C21 C22 C23 120.8(9) . . ?
C24 C23 C22 118.9(8) . . ?
C19 C24 C23 122.0(7) . . ?
C26 C25 C30 116.8(5) . . ?
C26 C25 P2 119.7(4) . . ?
C30 C25 P2 123.5(5) . . ?
C27 C26 C25 123.6(6) . . ?
C26 C27 C28 122.1(8) . . ?
C29 C28 C27 115.3(7) . . ?
C28 C29 C30 124.8(8) . . ?
C25 C30 C29 117.3(7) . . ?
C36 C31 C32 118.2(5) . . ?
C36 C31 P3 124.1(4) . . ?
C32 C31 P3 117.8(4) . . ?
C33 C32 C31 122.4(6) . . ?
C34 C33 C32 117.8(7) . . ?
C33 C34 C35 122.2(7) . . ?
C34 C35 C36 117.8(7) . . ?
C31 C36 C35 121.6(6) . . ?
C42 C37 C38 118.9(5) . . ?
C42 C37 P3 124.0(4) . . ?
C38 C37 P3 117.0(4) . . ?
C37 C38 C39 120.8(6) . . ?
C38 C39 C133 117.2(6) . . ?
C134 C42 C37 121.9(6) . . ?
C44 C43 C48 118.7(5) . . ?
C44 C43 P5 117.8(5) . . ?
C48 C43 P5 123.4(4) . . ?
C43 C44 C45 121.5(7) . . ?
C46 C45 C44 120.1(7) . . ?
C47 C46 C45 117.5(8) . . ?
C46 C47 C48 123.2(8) . . ?
C43 C48 C47 118.9(6) . . ?
C54 C49 C50 117.9(6) . . ?
C54 C49 P5 123.3(5) . . ?
C50 C49 P5 118.7(5) . . ?
C51 C50 C49 121.8(7) . . ?
C52 C51 C50 119.6(8) . . ?
C53 C52 C51 122.4(9) . . ?
C52 C53 C54 119.0(8) . . ?
C49 C54 C53 119.3(7) . . ?
C56 C55 C60 118.4(6) . . ?
C56 C55 P6 120.1(5) . . ?
C60 C55 P6 121.4(5) . . ?
C55 C56 C57 119.7(7) . . ?
C58 C57 C56 121.6(8) . . ?
C59 C58 C57 119.0(8) . . ?
C58 C59 C60 122.2(8) . . ?
C55 C60 C59 118.9(8) . . ?
C62 C61 C66 119.0(6) . . ?
C62 C61 P6 124.7(5) . . ?
C66 C61 P6 116.2(6) . . ?
C61 C62 C63 121.9(7) . . ?
C61 C66 C65 119.1(8) . . ?
C72 C67 C68 119.4(5) . . ?
C72 C67 P7 122.3(4) . . ?
C68 C67 P7 118.3(4) . . ?
C67 C68 C69 120.3(6) . . ?
C68 C69 C70 118.8(7) . . ?
C71 C70 C69 120.7(6) . . ?
C70 C71 C72 118.7(7) . . ?
C67 C72 C71 121.9(6) . . ?
C74 C73 C78 118.9(5) . . ?
C74 C73 P7 124.5(4) . . ?
C78 C73 P7 115.9(4) . . ?
C73 C74 C75 118.2(6) . . ?
C76 C75 C74 121.4(7) . . ?
C77 C76 C75 118.2(7) . . ?
C76 C77 C78 123.3(7) . . ?
C77 C78 C73 119.7(6) . . ?
C80 C79 Pt1 162.0(4) . . ?
C80 C79 Ag3 117.2(3) . . ?
Pt1 C79 Ag3 80.83(14) . . ?
C79 C80 C81 177.1(5) . . ?
C82 C81 C86 118.6(4) . . ?
C82 C81 C80 120.2(4) . . ?
C86 C81 C80 121.3(4) . . ?
C83 C82 C81 121.1(5) . . ?
C82 C83 C84 117.2(5) . . ?
C85 C84 C83 123.1(5) . . ?
C85 C84 N1 109.0(6) . . ?
C83 C84 N1 127.7(6) . . ?
C84 C85 C86 119.8(5) . . ?
C84 C85 C92 108.6(5) . . ?
C86 C85 C92 131.7(6) . . ?
C85 C86 C81 120.1(5) . . ?
C96 C95 Pt1 163.8(4) . . ?
C96 C95 Ag2 114.5(3) . . ?
Pt1 C95 Ag2 81.55(14) . . ?
C95 C96 C97 176.0(5) . . ?
C102 C97 C98 118.4(4) . . ?
C102 C97 C96 121.7(5) . . ?
C98 C97 C96 119.9(4) . . ?
C97 C102 C101 120.1(5) . . ?
C99 C98 C97 121.7(5) . . ?
N1 C87 C92 110.5(6) . . ?
N1 C87 C88 128.0(7) . . ?
C92 C87 C88 121.5(8) . . ?
C94 C93 N1 116.5(8) . . ?
C87 C88 C89 113.7(7) . . ?
C90 C91 C92 118.5(7) . . ?
C64 C63 C62 114.7(8) . . ?
C90 C89 C88 124.4(8) . . ?
C89 C90 C91 120.9(8) . . ?
C91 C92 C87 121.0(6) . . ?
C91 C92 C85 134.4(6) . . ?
C87 C92 C85 104.6(6) . . ?
C100 C101 C102 118.8(5) . . ?
C100 C101 C103 106.7(5) . . ?
C102 C101 C103 134.4(6) . . ?
C99 C100 C101 123.3(5) . . ?
C99 C100 N2 128.4(6) . . ?
C101 C100 N2 108.3(5) . . ?
C100 C99 C98 117.6(5) . . ?
C104 C103 C108 120.1(6) . . ?
C104 C103 C101 107.0(6) . . ?
C108 C103 C101 132.9(6) . . ?
N2 C104 C103 110.0(5) . . ?
N2 C104 C105 128.1(7) . . ?
C103 C104 C105 121.9(8) . . ?
C104 C105 C106 114.2(8) . . ?
C107 C106 C105 122.3(9) . . ?
C106 C107 C108 123.1(10) . . ?
C107 C108 C103 118.4(8) . . ?
N2 C109 C110 109.9(7) . . ?
C134 C133 C39 121.9(6) . . ?
C133 C134 C42 119.0(7) . . ?
C65 C64 C63 126.1(10) . . ?
C64 C65 C66 119.1(10) . . ?

_refine_diff_density_max         1.390
_refine_diff_density_min         -1.269
_refine_diff_density_rms         0.095

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_complex_12
_database_code_depnum_ccdc_archive 'CCDC 1846541'
_audit_update_record             
;
2018-05-31 deposited with the CCDC.
2018-08-02 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2016/6
_shelx_SHELXL_version_number     2016/6
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C164 H106 Au2 B2 Cl6 F60 N0 P8 Pt'
_chemical_formula_weight         4287.58

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0090 0.0039 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -4.5932 6.9264 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -4.4197 7.2980 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   16.1494(5)
_cell_length_b                   16.6691(4)
_cell_length_c                   17.1465(5)
_cell_angle_alpha                89.757(2)
_cell_angle_beta                 84.078(2)
_cell_angle_gamma                64.064(2)
_cell_volume                     4124.4(2)
_cell_formula_units_Z            1
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    26458
_cell_measurement_theta_min      2.698
_cell_measurement_theta_max      73.375

_exptl_crystal_description       Bloc
_exptl_crystal_colour            Green
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.726
_exptl_crystal_F_000             2098
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.34
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.23
_exptl_absorpt_coefficient_mu    7.527
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.120
_exptl_absorpt_correction_T_max  0.177
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     1.54178
_diffrn_radiation_type           CuK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'multiwire proportional'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            26458
_diffrn_reflns_av_unetI/netI     0.0371
_diffrn_reflns_av_R_equivalents  0.0335
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_theta_min         3.784
_diffrn_reflns_theta_max         73.375
_diffrn_reflns_theta_full        67.679
_diffrn_measured_fraction_theta_max 0.961
_diffrn_measured_fraction_theta_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.961
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.961
_diffrn_reflns_point_group_measured_fraction_full 0.995
_reflns_number_total             15951
_reflns_number_gt                14820
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0809P)²+23.2012P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         15951
_refine_ls_number_parameters     1124
_refine_ls_number_restraints     98
_refine_ls_R_factor_all          0.0522
_refine_ls_R_factor_gt           0.0495
_refine_ls_wR_factor_ref         0.1371
_refine_ls_wR_factor_gt          0.1343
_refine_ls_goodness_of_fit_ref   1.042
_refine_ls_restrained_S_all      1.072
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.53723(2) 0.65445(2) 0.52141(2) 0.01311(7) Uani 1 1 d . . . . .
Pt1 Pt 0.500000 0.500000 0.500000 0.00965(8) Uani 1 2 d S . P . .
P1 P 0.58910(8) 0.64864(8) 0.39034(7) 0.0128(2) Uani 1 1 d . . . . .
P2 P 0.52248(8) 0.50345(8) 0.36518(7) 0.0117(2) Uani 1 1 d . . . . .
P3 P 0.46985(8) 0.68585(8) 0.64963(7) 0.0134(2) Uani 1 1 d . . . . .
P4 P 0.40952(9) 0.62528(8) 0.22712(7) 0.0157(2) Uani 1 1 d . . . . .
Cl1 Cl -0.0687(2) 0.5328(2) 0.88603(17) 0.0847(8) Uani 1 1 d . . . . .
Cl01 Cl 0.02939(18) -0.06361(17) -0.06779(16) 0.0682(6) Uani 1 1 d . . . . .
Cl2 Cl 0.0967(2) 0.5461(3) 0.9181(2) 0.1107(13) Uani 1 1 d . . . . .
F1 F 0.1891(2) 0.5296(2) 0.5357(2) 0.0292(7) Uani 1 1 d . . . . .
F2 F 0.2214(2) 0.5521(2) 0.4150(2) 0.0289(7) Uani 1 1 d . . . . .
F3 F 0.0846(2) 0.5690(2) 0.4563(2) 0.0320(8) Uani 1 1 d . . . . .
F4 F -0.1105(4) 0.9751(4) 0.5187(7) 0.139(4) Uani 1 1 d . U . . .
F5 F -0.1371(7) 0.9036(7) 0.5930(6) 0.128(3) Uani 1 1 d . U . . .
F6 F -0.1364(4) 0.8800(5) 0.4722(6) 0.136(4) Uani 1 1 d . . . . .
F7 F 0.6349(3) 0.0128(6) 0.1464(3) 0.111(3) Uani 1 1 d . . . . .
F8 F 0.5548(4) 0.0689(5) 0.0550(4) 0.090(2) Uani 1 1 d . . . . .
F9 F 0.5852(4) -0.0602(4) 0.0820(4) 0.087(2) Uani 1 1 d . . . . .
F10 F 0.4826(4) 0.0294(6) 0.4089(3) 0.106(3) Uani 1 1 d . . . . .
F11 F 0.3910(10) 0.1558(6) 0.4156(4) 0.171(5) Uani 1 1 d . . . . .
F12 F 0.3438(5) 0.0591(8) 0.4266(3) 0.145(5) Uani 1 1 d . . . . .
F13 F 0.0103(3) 0.1892(3) -0.0908(2) 0.0419(10) Uani 1 1 d . . . . .
F14 F 0.1314(3) 0.0708(3) -0.1300(2) 0.0446(10) Uani 1 1 d . . . . .
F15 F 0.1009(3) 0.1929(3) -0.1894(2) 0.0446(10) Uani 1 1 d . . . . .
F16 F 0.2825(3) 0.3416(3) -0.1289(2) 0.0392(9) Uani 1 1 d . . . . .
F17 F 0.3908(3) 0.2567(4) -0.0640(4) 0.0776(19) Uani 1 1 d . . . . .
F18 F 0.2817(5) 0.3723(4) -0.0087(2) 0.0733(19) Uani 1 1 d . . . . .
F22 F 0.0260(3) -0.1172(3) 0.2510(3) 0.0460(10) Uani 1 1 d . . . . .
F23 F 0.1080(3) -0.1122(3) 0.3381(2) 0.0498(11) Uani 1 1 d . . . . .
F24 F -0.0039(3) 0.0080(3) 0.3075(3) 0.0480(11) Uani 1 1 d . . . . .
F25 F -0.1501(3) 0.2728(3) 0.1733(3) 0.0501(12) Uani 1 1 d . . . . .
F26 F -0.2041(3) 0.3988(3) 0.2347(4) 0.0656(16) Uani 1 1 d . . . . .
F27 F -0.1736(4) 0.2814(5) 0.2968(3) 0.083(2) Uani 1 1 d . . . . .
F28 F 0.1498(3) 0.3780(3) 0.3782(2) 0.0393(9) Uani 1 1 d . . . . .
F29 F 0.0724(3) 0.4831(2) 0.3058(2) 0.0350(8) Uani 1 1 d . . . . .
F30 F 0.0020(3) 0.4527(3) 0.4053(3) 0.0515(12) Uani 1 1 d . . . . .
C1 C 0.6081(3) 0.5458(3) 0.3373(3) 0.0146(9) Uani 1 1 d . . . . .
H1A H 0.608596 0.556387 0.281602 0.017 Uiso 1 1 calc R U . . .
H1B H 0.668880 0.499829 0.345534 0.017 Uiso 1 1 calc R U . . .
C01 C -0.0215(6) 0.5944(6) 0.9322(5) 0.055(2) Uani 1 1 d . . . . .
H01A H -0.045139 0.653852 0.912039 0.066 Uiso 1 1 calc R U . . .
H01B H -0.041528 0.600376 0.988051 0.066 Uiso 1 1 calc R U . . .
C2 C 0.5806(4) 0.3905(3) 0.3181(3) 0.0159(10) Uani 1 1 d . . . . .
H2A H 0.645000 0.363856 0.328227 0.019 Uiso 1 1 calc R U . . .
H2B H 0.579539 0.395674 0.261855 0.019 Uiso 1 1 calc R U . . .
C3 C 0.4165(3) 0.5651(3) 0.3203(3) 0.0159(10) Uani 1 1 d . . . . .
H3A H 0.373780 0.609202 0.359905 0.019 Uiso 1 1 calc R U . . .
H3B H 0.390989 0.523256 0.312274 0.019 Uiso 1 1 calc R U . . .
C4 C 0.6965(4) 0.6575(4) 0.3686(3) 0.0188(10) Uani 1 1 d . . . . .
C5 C 0.7618(4) 0.6122(4) 0.3051(3) 0.0234(11) Uani 1 1 d . . . . .
H5A H 0.751695 0.574013 0.272020 0.028 Uiso 1 1 calc R U . . .
C6 C 0.8422(4) 0.6241(4) 0.2911(4) 0.0327(14) Uani 1 1 d . . . . .
H6A H 0.885389 0.594493 0.248329 0.039 Uiso 1 1 calc R U . . .
C7 C 0.8577(5) 0.6799(6) 0.3408(5) 0.0490(19) Uani 1 1 d . . . . .
H7A H 0.911294 0.687945 0.331417 0.059 Uiso 1 1 calc R U . . .
C8 C 0.7943(7) 0.7231(7) 0.4038(6) 0.068(3) Uani 1 1 d . . . . .
H8A H 0.805219 0.760305 0.437378 0.081 Uiso 1 1 calc R U . . .
C9 C 0.7141(5) 0.7122(6) 0.4181(5) 0.048(2) Uani 1 1 d . . . . .
H9A H 0.671674 0.741774 0.461279 0.057 Uiso 1 1 calc R U . . .
C10 C 0.5014(4) 0.7397(3) 0.3448(3) 0.0164(10) Uani 1 1 d . . . . .
C11 C 0.4108(4) 0.7754(4) 0.3802(3) 0.0220(11) Uani 1 1 d . . . . .
H11A H 0.396365 0.753829 0.427201 0.026 Uiso 1 1 calc R U . . .
C12 C 0.3412(4) 0.8444(4) 0.3445(4) 0.0335(14) Uani 1 1 d . . . . .
H12A H 0.280053 0.868310 0.367368 0.040 Uiso 1 1 calc R U . . .
C13 C 0.3634(5) 0.8767(4) 0.2755(4) 0.0366(15) Uani 1 1 d . . . . .
H13A H 0.317212 0.923247 0.252576 0.044 Uiso 1 1 calc R U . . .
C14 C 0.4541(5) 0.8403(4) 0.2398(4) 0.0361(15) Uani 1 1 d . . . . .
H14A H 0.468343 0.861840 0.192666 0.043 Uiso 1 1 calc R U . . .
C15 C 0.5231(4) 0.7721(4) 0.2744(3) 0.0234(11) Uani 1 1 d . . . . .
H15A H 0.583977 0.747847 0.250726 0.028 Uiso 1 1 calc R U . . .
C16 C 0.4976(4) 0.5374(3) 0.1599(3) 0.0164(10) Uani 1 1 d . . . . .
C17 C 0.4976(4) 0.4563(4) 0.1406(3) 0.0197(10) Uani 1 1 d . . . . .
H17A H 0.446431 0.446382 0.157527 0.024 Uiso 1 1 calc R U . . .
C18 C 0.5736(4) 0.3899(4) 0.0961(3) 0.0247(12) Uani 1 1 d . . . . .
H18A H 0.572601 0.336435 0.082461 0.030 Uiso 1 1 calc R U . . .
C19 C 0.6513(4) 0.4040(4) 0.0720(3) 0.0280(12) Uani 1 1 d . . . . .
H19A H 0.703325 0.358921 0.044257 0.034 Uiso 1 1 calc R U . . .
C20 C 0.6505(4) 0.4852(4) 0.0894(3) 0.0288(13) Uani 1 1 d . . . . .
H20A H 0.701678 0.495158 0.072607 0.035 Uiso 1 1 calc R U . . .
C21 C 0.5739(4) 0.5515(4) 0.1319(3) 0.0223(11) Uani 1 1 d . . . . .
H21A H 0.573301 0.606521 0.141893 0.027 Uiso 1 1 calc R U . . .
C22 C 0.2997(4) 0.6266(4) 0.2058(3) 0.0201(10) Uani 1 1 d . . . . .
C23 C 0.2237(4) 0.6634(4) 0.2638(3) 0.0250(11) Uani 1 1 d . . . . .
H23A H 0.230415 0.684988 0.311460 0.030 Uiso 1 1 calc R U . . .
C24 C 0.1388(4) 0.6678(4) 0.2506(4) 0.0319(13) Uani 1 1 d . . . . .
H24A H 0.089020 0.691731 0.289678 0.038 Uiso 1 1 calc R U . . .
C25 C 0.1272(4) 0.6366(4) 0.1787(4) 0.0358(15) Uani 1 1 d . . . . .
H25A H 0.070523 0.638447 0.170055 0.043 Uiso 1 1 calc R U . . .
C26 C 0.2009(5) 0.6034(5) 0.1216(4) 0.0360(15) Uani 1 1 d . . . . .
H26A H 0.193158 0.583976 0.073357 0.043 Uiso 1 1 calc R U . . .
C27 C 0.2871(4) 0.5979(4) 0.1336(3) 0.0269(12) Uani 1 1 d . . . . .
H27A H 0.336055 0.575157 0.093670 0.032 Uiso 1 1 calc R U . . .
C28 C 0.5495(3) 0.6789(3) 0.7184(3) 0.0151(9) Uani 1 1 d . . . . .
C29 C 0.6418(4) 0.6157(4) 0.7009(3) 0.0186(10) Uani 1 1 d . . . . .
H29A H 0.661524 0.585291 0.652147 0.022 Uiso 1 1 calc R U . . .
C30 C 0.7037(4) 0.5982(4) 0.7558(3) 0.0232(11) Uani 1 1 d . . . . .
H30A H 0.764470 0.554667 0.744659 0.028 Uiso 1 1 calc R U . . .
C31 C 0.6753(4) 0.6456(4) 0.8276(3) 0.0258(12) Uani 1 1 d . . . . .
H31A H 0.716643 0.632999 0.865044 0.031 Uiso 1 1 calc R U . . .
C32 C 0.5847(4) 0.7122(4) 0.8437(3) 0.0231(11) Uani 1 1 d . . . . .
H32A H 0.566582 0.746047 0.890782 0.028 Uiso 1 1 calc R U . . .
C33 C 0.5221(4) 0.7280(4) 0.7898(3) 0.0194(10) Uani 1 1 d . . . . .
H33A H 0.461345 0.771448 0.801187 0.023 Uiso 1 1 calc R U . . .
C34 C 0.3735(3) 0.7954(3) 0.6637(3) 0.0174(10) Uani 1 1 d . . . . .
C35 C 0.3031(4) 0.8173(4) 0.7257(3) 0.0240(11) Uani 1 1 d . . . . .
H35A H 0.303735 0.774114 0.760511 0.029 Uiso 1 1 calc R U . . .
C36 C 0.2322(4) 0.9033(4) 0.7355(4) 0.0310(13) Uani 1 1 d . . . . .
H36A H 0.185427 0.917668 0.776901 0.037 Uiso 1 1 calc R U . . .
C37 C 0.2308(4) 0.9675(4) 0.6843(4) 0.0359(15) Uani 1 1 d . . . . .
H37A H 0.183429 1.025205 0.691802 0.043 Uiso 1 1 calc R U . . .
C38 C 0.2993(4) 0.9471(4) 0.6217(4) 0.0327(14) Uani 1 1 d . . . . .
H38A H 0.297144 0.990530 0.586716 0.039 Uiso 1 1 calc R U . . .
C39 C 0.3710(4) 0.8613(4) 0.6116(3) 0.0249(11) Uani 1 1 d . . . . .
H39A H 0.417581 0.847546 0.570060 0.030 Uiso 1 1 calc R U . . .
C40 C 0.3676(4) 0.5925(3) 0.5079(3) 0.0161(10) Uani 1 1 d . . . . .
C41 C 0.2881(3) 0.6468(3) 0.5126(3) 0.0162(10) Uani 1 1 d . . . . .
C42 C 0.1920(4) 0.7083(4) 0.5151(3) 0.0178(10) Uani 1 1 d . . . . .
C43 C 0.1627(4) 0.7984(4) 0.5346(3) 0.0248(12) Uani 1 1 d . . . . .
H43A H 0.205818 0.818501 0.545611 0.030 Uiso 1 1 calc R U . . .
C44 C 0.0696(4) 0.8586(4) 0.5379(4) 0.0287(13) Uani 1 1 d . . . . .
H44A H 0.050500 0.918551 0.551370 0.034 Uiso 1 1 calc R U . . .
C45 C 0.0052(4) 0.8288(4) 0.5211(4) 0.0273(12) Uani 1 1 d . . . . .
C46 C 0.0332(4) 0.7391(4) 0.5011(3) 0.0240(11) Uani 1 1 d . . . . .
H46A H -0.010301 0.719414 0.490207 0.029 Uiso 1 1 calc R U . . .
C47 C 0.1258(3) 0.6792(4) 0.4976(3) 0.0171(10) Uani 1 1 d . . . . .
C48 C 0.1547(4) 0.5829(4) 0.4763(3) 0.0217(11) Uani 1 1 d . . . . .
C49 C -0.0950(4) 0.8935(5) 0.5244(4) 0.0346(14) Uani 1 1 d . . . . .
C50 C 0.3075(3) 0.1081(3) 0.1898(3) 0.0163(10) Uani 1 1 d . . . . .
C51 C 0.3911(4) 0.0780(4) 0.1416(3) 0.0196(10) Uani 1 1 d . . . . .
H51A H 0.390477 0.076470 0.087451 0.023 Uiso 1 1 calc R U . . .
C52 C 0.4766(4) 0.0497(4) 0.1723(3) 0.0230(11) Uani 1 1 d . . . . .
C53 C 0.4806(4) 0.0509(4) 0.2521(3) 0.0255(12) Uani 1 1 d . . . . .
H53A H 0.536917 0.033556 0.272309 0.031 Uiso 1 1 calc R U . . .
C54 C 0.3995(4) 0.0782(4) 0.3011(3) 0.0250(12) Uani 1 1 d . . . . .
C55 C 0.3142(4) 0.1060(4) 0.2711(3) 0.0199(10) Uani 1 1 d . . . . .
H55A H 0.260473 0.123514 0.305773 0.024 Uiso 1 1 calc R U . . .
C56 C 0.5636(4) 0.0178(5) 0.1159(4) 0.0347(15) Uani 1 1 d . . . . .
C57 C 0.4018(5) 0.0790(6) 0.3882(4) 0.0405(17) Uani 1 1 d . . . . .
C58 C 0.2070(3) 0.1682(3) 0.0654(3) 0.0144(9) Uani 1 1 d . . . . .
C59 C 0.1575(3) 0.1504(3) 0.0110(3) 0.0158(10) Uani 1 1 d . . . . .
H59A H 0.126296 0.116271 0.025717 0.019 Uiso 1 1 calc R U . . .
C60 C 0.1535(4) 0.1825(3) -0.0645(3) 0.0171(10) Uani 1 1 d . . . . .
C61 C 0.1985(4) 0.2337(3) -0.0893(3) 0.0182(10) Uani 1 1 d . . . . .
H61A H 0.195947 0.254855 -0.139649 0.022 Uiso 1 1 calc R U . . .
C62 C 0.2478(4) 0.2524(4) -0.0359(3) 0.0183(10) Uani 1 1 d . . . . .
C63 C 0.2509(4) 0.2209(3) 0.0396(3) 0.0168(10) Uani 1 1 d . . . . .
H63A H 0.283430 0.235577 0.074168 0.020 Uiso 1 1 calc R U . . .
C64 C 0.0991(4) 0.1594(4) -0.1187(3) 0.0265(12) Uani 1 1 d . . . . .
C65 C 0.3005(5) 0.3049(5) -0.0599(3) 0.0311(14) Uani 1 1 d . . . . .
C66 C 0.1941(3) 0.0428(3) 0.1580(3) 0.0161(10) Uani 1 1 d . . . . .
C67 C 0.2480(5) -0.0272(4) 0.1033(3) 0.0289(13) Uani 1 1 d . . . . .
H67A H 0.288080 -0.019071 0.064600 0.035 Uiso 1 1 calc R U . . .
C68 C 0.2435(7) -0.1080(4) 0.1048(4) 0.0468(18) Uani 1 1 d . U . . .
C69 C 0.1846(6) -0.1233(4) 0.1612(4) 0.0376(17) Uani 1 1 d . . . . .
H69A H 0.181652 -0.177811 0.161981 0.045 Uiso 1 1 calc R U . . .
C70 C 0.1304(4) -0.0553(4) 0.2161(3) 0.0206(11) Uani 1 1 d . . . . .
C71 C 0.1367(3) 0.0260(3) 0.2154(3) 0.0152(9) Uani 1 1 d . . . . .
H71A H 0.101561 0.069918 0.254256 0.018 Uiso 1 1 calc R U . . .
C72 C 0.3020(5) -0.1805(4) 0.0434(4) 0.064(2) Uani 0.535(11) 1 d D U P A 1
F19 F 0.2848(7) -0.1566(8) -0.0269(4) 0.058(3) Uani 0.535(11) 1 d D U P A 1
F20 F 0.3971(6) -0.1872(6) 0.0400(7) 0.080(4) Uani 0.535(11) 1 d D U P A 1
F21 F 0.3288(8) -0.2615(6) 0.0662(8) 0.056(3) Uani 0.535(11) 1 d D U P A 1
C72' C 0.3020(5) -0.1805(4) 0.0434(4) 0.064(2) Uani 0.465(11) 1 d D U P A 2
F19' F 0.2396(7) -0.2193(6) 0.0207(6) 0.064(3) Uani 0.465(11) 1 d D U P A 2
F20' F 0.3666(9) -0.2507(9) 0.0641(10) 0.075(4) Uani 0.465(11) 1 d D U P A 2
F21' F 0.3138(10) -0.1523(10) -0.0265(6) 0.053(3) Uani 0.465(11) 1 d D U P A 2
C73 C 0.0652(4) -0.0689(4) 0.2773(4) 0.0267(12) Uani 1 1 d . . . . .
C74 C 0.1211(3) 0.2178(3) 0.2072(3) 0.0151(9) Uani 1 1 d . . . . .
C75 C 0.0295(3) 0.2329(3) 0.2003(3) 0.0165(10) Uani 1 1 d . . . . .
H75A H 0.019218 0.194840 0.167415 0.020 Uiso 1 1 calc R U . . .
C76 C -0.0460(4) 0.3030(3) 0.2411(3) 0.0186(10) Uani 1 1 d . . . . .
C77 C -0.0341(4) 0.3620(4) 0.2908(3) 0.0220(11) Uani 1 1 d . . . . .
H77A H -0.084533 0.408084 0.319244 0.026 Uiso 1 1 calc R U . . .
C78 C 0.0553(4) 0.3498(4) 0.2963(3) 0.0208(11) Uani 1 1 d . . . . .
C79 C 0.1310(4) 0.2800(3) 0.2551(3) 0.0181(10) Uani 1 1 d . . . . .
H79A H 0.190179 0.274545 0.259609 0.022 Uiso 1 1 calc R U . . .
C80 C -0.1415(4) 0.3135(4) 0.2348(4) 0.0281(12) Uani 1 1 d . . . . .
C81 C 0.0698(4) 0.4153(4) 0.3468(4) 0.0287(13) Uani 1 1 d . . . . .
B1 B 0.2077(4) 0.1350(4) 0.1560(3) 0.0139(10) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P1 2.3031(12) . ?
Au1 P3 2.3043(12) . ?
Au1 Pt1 2.92097(19) . ?
Pt1 C40 2.007(5) 2_666 ?
Pt1 C40 2.007(5) . ?
Pt1 P2 2.3071(11) 2_666 ?
Pt1 P2 2.3071(11) . ?
P1 C10 1.804(5) . ?
P1 C4 1.806(5) . ?
P1 C1 1.832(5) . ?
P2 C3 1.817(5) . ?
P2 C1 1.831(5) . ?
P2 C2 1.841(5) . ?
P3 C28 1.801(5) . ?
P3 C34 1.804(5) . ?
P3 C2 1.843(5) 2_666 ?
P4 C16 1.830(5) . ?
P4 C22 1.839(5) . ?
P4 C3 1.870(5) . ?
Cl1 C01 1.755(10) . ?
Cl2 C01 1.707(9) . ?
F1 C48 1.346(7) . ?
F2 C48 1.349(6) . ?
F3 C48 1.328(6) . ?
F4 C49 1.275(10) . ?
F5 C49 1.270(11) . ?
F6 C49 1.247(9) . ?
F7 C56 1.283(8) . ?
F8 C56 1.325(9) . ?
F9 C56 1.311(9) . ?
F10 C57 1.289(9) . ?
F11 C57 1.298(11) . ?
F12 C57 1.250(9) . ?
F13 C64 1.330(7) . ?
F14 C64 1.342(7) . ?
F15 C64 1.335(6) . ?
F16 C65 1.329(7) . ?
F17 C65 1.316(8) . ?
F18 C65 1.334(8) . ?
F22 C73 1.328(7) . ?
F23 C73 1.337(7) . ?
F24 C73 1.338(7) . ?
F25 C80 1.308(7) . ?
F26 C80 1.337(7) . ?
F27 C80 1.345(8) . ?
F28 C81 1.334(7) . ?
F29 C81 1.342(7) . ?
F30 C81 1.333(7) . ?
C4 C9 1.384(8) . ?
C4 C5 1.392(8) . ?
C5 C6 1.395(8) . ?
C6 C7 1.381(11) . ?
C7 C8 1.367(12) . ?
C8 C9 1.383(10) . ?
C10 C11 1.386(8) . ?
C10 C15 1.396(7) . ?
C11 C12 1.403(8) . ?
C12 C13 1.375(10) . ?
C13 C14 1.390(10) . ?
C14 C15 1.382(8) . ?
C16 C21 1.390(7) . ?
C16 C17 1.394(7) . ?
C17 C18 1.392(8) . ?
C18 C19 1.396(8) . ?
C19 C20 1.381(9) . ?
C20 C21 1.381(9) . ?
C22 C27 1.395(8) . ?
C22 C23 1.402(8) . ?
C23 C24 1.382(8) . ?
C24 C25 1.400(10) . ?
C25 C26 1.368(10) . ?
C26 C27 1.391(8) . ?
C28 C33 1.394(7) . ?
C28 C29 1.400(7) . ?
C29 C30 1.381(7) . ?
C30 C31 1.388(8) . ?
C31 C32 1.396(9) . ?
C32 C33 1.381(7) . ?
C34 C35 1.395(8) . ?
C34 C39 1.404(8) . ?
C35 C36 1.386(8) . ?
C36 C37 1.375(10) . ?
C37 C38 1.385(10) . ?
C38 C39 1.388(9) . ?
C40 C41 1.198(7) . ?
C41 C42 1.434(7) . ?
C42 C43 1.394(8) . ?
C42 C47 1.409(7) . ?
C43 C44 1.391(8) . ?
C44 C45 1.387(8) . ?
C45 C46 1.393(8) . ?
C45 C49 1.497(8) . ?
C46 C47 1.383(8) . ?
C47 C48 1.498(7) . ?
C50 C51 1.392(7) . ?
C50 C55 1.408(7) . ?
C50 B1 1.640(7) . ?
C51 C52 1.408(7) . ?
C52 C53 1.378(8) . ?
C52 C56 1.504(8) . ?
C53 C54 1.373(8) . ?
C54 C55 1.401(8) . ?
C54 C57 1.498(8) . ?
C58 C63 1.395(7) . ?
C58 C59 1.399(7) . ?
C58 B1 1.647(7) . ?
C59 C60 1.396(7) . ?
C60 C61 1.384(7) . ?
C60 C64 1.500(7) . ?
C61 C62 1.391(7) . ?
C62 C63 1.393(7) . ?
C62 C65 1.495(7) . ?
C66 C71 1.393(7) . ?
C66 C67 1.398(7) . ?
C66 B1 1.646(7) . ?
C67 C68 1.380(9) . ?
C68 C69 1.388(10) . ?
C68 C72' 1.506(9) . ?
C68 C72 1.506(9) . ?
C69 C70 1.382(8) . ?
C70 C71 1.402(7) . ?
C70 C73 1.497(8) . ?
C72 F19 1.286(8) . ?
C72 F21 1.297(8) . ?
C72 F20 1.486(8) . ?
C72' F20' 1.261(9) . ?
C72' F21' 1.311(8) . ?
C72' F19' 1.497(8) . ?
C74 C79 1.399(7) . ?
C74 C75 1.405(7) . ?
C74 B1 1.642(7) . ?
C75 C76 1.388(7) . ?
C76 C77 1.392(7) . ?
C76 C80 1.490(8) . ?
C77 C78 1.381(8) . ?
C78 C79 1.389(7) . ?
C78 C81 1.508(7) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Au1 P3 170.17(4) . . ?
P1 Au1 Pt1 91.83(3) . . ?
P3 Au1 Pt1 94.54(3) . . ?
C40 Pt1 C40 180.0 2_666 . ?
C40 Pt1 P2 93.84(14) 2_666 2_666 ?
C40 Pt1 P2 86.16(14) . 2_666 ?
C40 Pt1 P2 86.16(14) 2_666 . ?
C40 Pt1 P2 93.84(14) . . ?
P2 Pt1 P2 180.0 2_666 . ?
C40 Pt1 Au1 83.50(14) 2_666 2_666 ?
C40 Pt1 Au1 96.50(14) . 2_666 ?
P2 Pt1 Au1 91.81(3) 2_666 2_666 ?
P2 Pt1 Au1 88.19(3) . 2_666 ?
C40 Pt1 Au1 96.50(14) 2_666 . ?
C40 Pt1 Au1 83.50(14) . . ?
P2 Pt1 Au1 88.19(3) 2_666 . ?
P2 Pt1 Au1 91.81(3) . . ?
Au1 Pt1 Au1 180.0 2_666 . ?
C10 P1 C4 107.3(2) . . ?
C10 P1 C1 106.8(2) . . ?
C4 P1 C1 104.6(2) . . ?
C10 P1 Au1 107.99(18) . . ?
C4 P1 Au1 116.00(17) . . ?
C1 P1 Au1 113.67(16) . . ?
C3 P2 C1 111.3(2) . . ?
C3 P2 C2 107.8(2) . . ?
C1 P2 C2 101.2(2) . . ?
C3 P2 Pt1 114.00(16) . . ?
C1 P2 Pt1 109.93(16) . . ?
C2 P2 Pt1 111.92(17) . . ?
C28 P3 C34 107.4(2) . . ?
C28 P3 C2 106.8(2) . 2_666 ?
C34 P3 C2 104.1(2) . 2_666 ?
C28 P3 Au1 113.33(17) . . ?
C34 P3 Au1 112.52(18) . . ?
C2 P3 Au1 112.09(16) 2_666 . ?
C16 P4 C22 104.2(2) . . ?
C16 P4 C3 101.7(2) . . ?
C22 P4 C3 95.4(2) . . ?
P2 C1 P1 115.4(3) . . ?
Cl2 C01 Cl1 112.8(6) . . ?
P2 C2 P3 115.4(3) . 2_666 ?
P2 C3 P4 124.7(3) . . ?
C9 C4 C5 119.0(5) . . ?
C9 C4 P1 117.7(4) . . ?
C5 C4 P1 123.4(4) . . ?
C4 C5 C6 119.9(6) . . ?
C7 C6 C5 120.1(6) . . ?
C8 C7 C6 119.9(6) . . ?
C7 C8 C9 120.6(7) . . ?
C8 C9 C4 120.5(7) . . ?
C11 C10 C15 120.3(5) . . ?
C11 C10 P1 118.5(4) . . ?
C15 C10 P1 121.2(4) . . ?
C10 C11 C12 119.3(5) . . ?
C13 C12 C11 120.0(6) . . ?
C12 C13 C14 120.6(6) . . ?
C15 C14 C13 119.8(6) . . ?
C14 C15 C10 119.9(6) . . ?
C21 C16 C17 118.5(5) . . ?
C21 C16 P4 115.7(4) . . ?
C17 C16 P4 125.5(4) . . ?
C18 C17 C16 120.6(5) . . ?
C17 C18 C19 119.7(5) . . ?
C20 C19 C18 119.7(5) . . ?
C19 C20 C21 120.1(5) . . ?
C20 C21 C16 121.2(5) . . ?
C27 C22 C23 118.8(5) . . ?
C27 C22 P4 123.3(4) . . ?
C23 C22 P4 117.8(4) . . ?
C24 C23 C22 120.5(6) . . ?
C23 C24 C25 120.5(6) . . ?
C26 C25 C24 118.7(6) . . ?
C25 C26 C27 122.0(6) . . ?
C26 C27 C22 119.6(6) . . ?
C33 C28 C29 119.4(5) . . ?
C33 C28 P3 123.2(4) . . ?
C29 C28 P3 117.2(4) . . ?
C30 C29 C28 120.3(5) . . ?
C29 C30 C31 120.0(5) . . ?
C30 C31 C32 120.0(5) . . ?
C33 C32 C31 120.0(5) . . ?
C32 C33 C28 120.2(5) . . ?
C35 C34 C39 119.1(5) . . ?
C35 C34 P3 122.3(4) . . ?
C39 C34 P3 118.5(4) . . ?
C36 C35 C34 120.1(5) . . ?
C37 C36 C35 120.3(6) . . ?
C36 C37 C38 120.7(6) . . ?
C37 C38 C39 119.6(6) . . ?
C38 C39 C34 120.2(5) . . ?
C41 C40 Pt1 179.1(4) . . ?
C40 C41 C42 176.5(5) . . ?
C43 C42 C47 118.9(5) . . ?
C43 C42 C41 120.1(5) . . ?
C47 C42 C41 121.0(5) . . ?
C44 C43 C42 120.7(5) . . ?
C45 C44 C43 119.7(6) . . ?
C44 C45 C46 120.5(5) . . ?
C44 C45 C49 119.8(6) . . ?
C46 C45 C49 119.8(5) . . ?
C47 C46 C45 119.8(5) . . ?
C46 C47 C42 120.4(5) . . ?
C46 C47 C48 119.1(5) . . ?
C42 C47 C48 120.5(5) . . ?
F3 C48 F1 107.2(4) . . ?
F3 C48 F2 106.5(4) . . ?
F1 C48 F2 106.1(4) . . ?
F3 C48 C47 112.0(4) . . ?
F1 C48 C47 112.3(4) . . ?
F2 C48 C47 112.3(4) . . ?
F4 C49 F6 104.6(8) . . ?
F4 C49 F5 95.5(8) . . ?
F6 C49 F5 113.8(8) . . ?
F4 C49 C45 114.8(6) . . ?
F6 C49 C45 114.5(6) . . ?
F5 C49 C45 112.0(7) . . ?
C51 C50 C55 115.8(5) . . ?
C51 C50 B1 123.1(4) . . ?
C55 C50 B1 120.8(4) . . ?
C50 C51 C52 122.0(5) . . ?
C53 C52 C51 120.8(5) . . ?
C53 C52 C56 120.6(5) . . ?
C51 C52 C56 118.5(5) . . ?
C54 C53 C52 118.4(5) . . ?
C53 C54 C55 121.2(5) . . ?
C53 C54 C57 119.6(5) . . ?
C55 C54 C57 119.3(5) . . ?
C54 C55 C50 121.8(5) . . ?
F7 C56 F9 107.9(7) . . ?
F7 C56 F8 106.3(7) . . ?
F9 C56 F8 102.1(7) . . ?
F7 C56 C52 114.4(6) . . ?
F9 C56 C52 112.4(6) . . ?
F8 C56 C52 112.9(5) . . ?
F12 C57 F10 108.6(8) . . ?
F12 C57 F11 108.1(9) . . ?
F10 C57 F11 99.2(8) . . ?
F12 C57 C54 115.0(6) . . ?
F10 C57 C54 113.2(6) . . ?
F11 C57 C54 111.6(7) . . ?
C63 C58 C59 115.8(4) . . ?
C63 C58 B1 121.8(4) . . ?
C59 C58 B1 122.3(4) . . ?
C60 C59 C58 122.0(5) . . ?
C61 C60 C59 121.3(5) . . ?
C61 C60 C64 120.6(5) . . ?
C59 C60 C64 118.1(5) . . ?
C60 C61 C62 117.5(5) . . ?
C61 C62 C63 120.9(5) . . ?
C61 C62 C65 120.2(5) . . ?
C63 C62 C65 118.9(5) . . ?
C62 C63 C58 122.5(5) . . ?
F13 C64 F15 106.6(5) . . ?
F13 C64 F14 105.7(5) . . ?
F15 C64 F14 107.0(5) . . ?
F13 C64 C60 112.5(5) . . ?
F15 C64 C60 112.8(5) . . ?
F14 C64 C60 111.7(5) . . ?
F17 C65 F16 107.0(5) . . ?
F17 C65 F18 104.9(6) . . ?
F16 C65 F18 105.7(5) . . ?
F17 C65 C62 112.7(5) . . ?
F16 C65 C62 113.5(5) . . ?
F18 C65 C62 112.4(5) . . ?
C71 C66 C67 116.3(5) . . ?
C71 C66 B1 124.2(4) . . ?
C67 C66 B1 119.3(5) . . ?
C68 C67 C66 122.0(6) . . ?
C67 C68 C69 121.2(6) . . ?
C67 C68 C72' 119.7(6) . . ?
C69 C68 C72' 119.1(6) . . ?
C67 C68 C72 119.7(6) . . ?
C69 C68 C72 119.1(6) . . ?
C70 C69 C68 118.1(5) . . ?
C69 C70 C71 120.5(5) . . ?
C69 C70 C73 119.7(5) . . ?
C71 C70 C73 119.8(5) . . ?
C66 C71 C70 121.8(5) . . ?
F19 C72 F21 124.6(9) . . ?
F19 C72 F20 99.3(8) . . ?
F21 C72 F20 92.3(8) . . ?
F19 C72 C68 112.9(7) . . ?
F21 C72 C68 115.3(7) . . ?
F20 C72 C68 106.0(7) . . ?
F20' C72' F21' 118.0(11) . . ?
F20' C72' F19' 98.8(9) . . ?
F21' C72' F19' 95.0(8) . . ?
F20' C72' C68 118.8(10) . . ?
F21' C72' C68 115.1(8) . . ?
F19' C72' C68 105.0(7) . . ?
F22 C73 F23 105.4(5) . . ?
F22 C73 F24 106.6(5) . . ?
F23 C73 F24 106.1(5) . . ?
F22 C73 C70 113.3(5) . . ?
F23 C73 C70 112.0(5) . . ?
F24 C73 C70 112.8(5) . . ?
C79 C74 C75 115.7(5) . . ?
C79 C74 B1 124.3(4) . . ?
C75 C74 B1 119.9(4) . . ?
C76 C75 C74 122.1(5) . . ?
C75 C76 C77 121.1(5) . . ?
C75 C76 C80 119.9(5) . . ?
C77 C76 C80 118.9(5) . . ?
C78 C77 C76 117.6(5) . . ?
C77 C78 C79 121.4(5) . . ?
C77 C78 C81 118.6(5) . . ?
C79 C78 C81 119.9(5) . . ?
C78 C79 C74 122.1(5) . . ?
F25 C80 F26 106.7(5) . . ?
F25 C80 F27 105.2(6) . . ?
F26 C80 F27 103.8(6) . . ?
F25 C80 C76 115.1(5) . . ?
F26 C80 C76 113.2(5) . . ?
F27 C80 C76 112.0(5) . . ?
F28 C81 F30 107.8(5) . . ?
F28 C81 F29 105.8(5) . . ?
F30 C81 F29 105.9(5) . . ?
F28 C81 C78 112.5(5) . . ?
F30 C81 C78 112.4(5) . . ?
F29 C81 C78 112.0(5) . . ?
C50 B1 C74 113.1(4) . . ?
C50 B1 C66 105.0(4) . . ?
C74 B1 C66 111.8(4) . . ?
C50 B1 C58 112.4(4) . . ?
C74 B1 C58 105.3(4) . . ?
C66 B1 C58 109.4(4) . . ?

_refine_diff_density_max         3.485
_refine_diff_density_min         -2.154
_refine_diff_density_rms         0.177

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_complex_6
_database_code_depnum_ccdc_archive 'CCDC 1846540'
_audit_update_record             
;
2018-05-31 deposited with the CCDC.
2018-08-02 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2016/6
_shelx_SHELXL_version_number     2016/6
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C118 H96 Au3 Cl3 N2 O8 P8 Pt'
_chemical_formula_weight         2810.06

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   19.075(4)
_cell_length_b                   20.069(4)
_cell_length_c                   20.257(4)
_cell_angle_alpha                100.71(3)
_cell_angle_beta                 96.56(3)
_cell_angle_gamma                116.03(3)
_cell_volume                     6676(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    16074
_cell_measurement_theta_min      2.0213
_cell_measurement_theta_max      27.5984

_exptl_crystal_description       needle
_exptl_crystal_colour            Yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.398
_exptl_crystal_F_000             2736
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.12
_exptl_absorpt_coefficient_mu    4.533
_shelx_estimated_absorpt_T_min   0.4939
_shelx_estimated_absorpt_T_max   1
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.447
_exptl_absorpt_correction_T_max  0.580
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  
;
Mercury70 (2x2 bin mode)
;
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            41783
_diffrn_reflns_av_unetI/netI     0.2175
_diffrn_reflns_av_R_equivalents  0.1286
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_theta_min         2.021
_diffrn_reflns_theta_max         25.000
_diffrn_reflns_theta_full        25.000
_diffrn_measured_fraction_theta_max 0.950
_diffrn_measured_fraction_theta_full 0.950
_diffrn_reflns_Laue_measured_fraction_max 0.950
_diffrn_reflns_Laue_measured_fraction_full 0.950
_diffrn_reflns_point_group_measured_fraction_max 0.950
_diffrn_reflns_point_group_measured_fraction_full 0.950
_reflns_number_total             22342
_reflns_number_gt                11711
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.000 0.500 1.000 1419 331 ' '
2 0.500 0.500 0.500 410 59 ' '
_platon_squeeze_void_probe_radius 1.20
_platon_squeeze_details          
;
The unit cell contains highly disordered CH2Cl2 molecules which have been treated as 
a diffuse contribution to the overall scattering without specific atom 
positions by SQUEEZE/PLATON. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0684P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         22342
_refine_ls_number_parameters     1216
_refine_ls_number_restraints     512
_refine_ls_R_factor_all          0.1165
_refine_ls_R_factor_gt           0.0902
_refine_ls_wR_factor_ref         0.2152
_refine_ls_wR_factor_gt          0.2027
_refine_ls_goodness_of_fit_ref   0.928
_refine_ls_restrained_S_all      0.923
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.25328(3) 1.00649(3) 0.73530(3) 0.03368(17) Uani 1 1 d . . . . .
Au2 Au 0.24224(4) 1.14998(4) 0.73930(3) 0.04489(19) Uani 1 1 d . . . . .
Au3 Au 0.18445(4) 0.90082(4) 0.59394(3) 0.04089(18) Uani 1 1 d . . . . .
Pt1 Pt 0.32189(3) 0.96686(3) 0.85130(3) 0.03394(17) Uani 1 1 d . . . . .
Cl1 Cl 0.6405(4) 0.2234(4) 0.6861(4) 0.0970(19) Uani 1 1 d . . . . .
Cl01 Cl 0.1759(2) 1.0471(2) 0.59941(17) 0.0458(10) Uani 1 1 d . . . . .
Cl2 Cl 0.8839(4) 0.8462(5) 0.8128(4) 0.103(2) Uani 1 1 d . . . . .
P1 P 0.0663(2) 0.8279(2) 0.62481(19) 0.0375(9) Uani 1 1 d . U . . .
P2 P 0.1145(2) 1.0963(2) 0.76091(19) 0.0389(10) Uani 1 1 d . . . . .
P3 P 0.2049(2) 0.9246(2) 0.89029(18) 0.0378(9) Uani 1 1 d . U . . .
P4 P 0.1318(2) 0.9514(2) 0.76196(18) 0.0338(9) Uani 1 1 d . U . . .
P5 P 0.3770(2) 1.2182(2) 0.73973(19) 0.0376(9) Uani 1 1 d . . . . .
P6 P 0.3046(2) 0.9602(2) 0.56130(18) 0.0380(10) Uani 1 1 d . . . . .
P7 P 0.4430(3) 1.0057(2) 0.81869(19) 0.0401(10) Uani 1 1 d . . . . .
P8 P 0.3754(2) 1.0625(2) 0.70938(18) 0.0348(9) Uani 1 1 d . . . . .
O1 O 0.6457(12) 0.2503(16) 0.6291(12) 0.203(12) Uani 1 1 d . . . . .
O2 O 0.7094(9) 0.2197(11) 0.7108(10) 0.139(7) Uani 1 1 d . . . . .
O3 O 0.5722(9) 0.1486(10) 0.6680(9) 0.124(6) Uani 1 1 d . . . . .
O4 O 0.6257(10) 0.2700(10) 0.7397(8) 0.121(6) Uani 1 1 d . . . . .
O5 O 0.9480(10) 0.8970(13) 0.8744(12) 0.184(10) Uani 1 1 d . . . . .
O6 O 0.8980(13) 0.7924(14) 0.7740(10) 0.163(9) Uani 1 1 d . . . . .
O7 O 0.8733(13) 0.8924(13) 0.7720(10) 0.164(9) Uani 1 1 d . . . . .
O8 O 0.8187(9) 0.8171(11) 0.8394(9) 0.140(7) Uani 1 1 d . . . . .
N1 N 0.4218(10) 1.3923(8) 1.1560(8) 0.073(5) Uani 1 1 d . . . . .
N2 N 0.2214(10) 0.5166(9) 0.5874(9) 0.081(5) Uani 1 1 d . . . . .
C1 C 0.0693(8) 0.9920(8) 0.7372(7) 0.032(3) Uani 1 1 d . . . . .
H1A H 0.022955 0.972219 0.757305 0.038 Uiso 1 1 calc R U . . .
H1B H 0.050238 0.973755 0.687495 0.038 Uiso 1 1 calc R U . . .
C2 C 0.1398(8) 0.9599(8) 0.8537(6) 0.034(3) Uani 1 1 d . U . . .
H2A H 0.086809 0.931439 0.861669 0.040 Uiso 1 1 calc R U . . .
H2B H 0.160197 1.013524 0.877658 0.040 Uiso 1 1 calc R U . . .
C3 C 0.0806(8) 0.8498(8) 0.7184(6) 0.034(3) Uani 1 1 d . U . . .
H3A H 0.028646 0.826711 0.729899 0.041 Uiso 1 1 calc R U . . .
H3B H 0.110910 0.826144 0.735839 0.041 Uiso 1 1 calc R U . . .
C4 C 0.3673(9) 1.0564(8) 0.6168(8) 0.043(4) Uani 1 1 d . . . . .
H4A H 0.345957 1.089687 0.605366 0.052 Uiso 1 1 calc R U . . .
H4B H 0.420513 1.075481 0.607511 0.052 Uiso 1 1 calc R U . . .
C5 C 0.4351(7) 1.0169(8) 0.7314(6) 0.028(3) Uani 1 1 d . U . . .
H5A H 0.488577 1.046897 0.725035 0.033 Uiso 1 1 calc R U . . .
H5B H 0.412348 0.966447 0.699377 0.033 Uiso 1 1 calc R U . . .
C6 C 0.4318(8) 1.1647(8) 0.7549(6) 0.031(3) Uani 1 1 d . . . . .
H6A H 0.481813 1.187194 0.740057 0.038 Uiso 1 1 calc R U . . .
H6B H 0.444610 1.169881 0.803898 0.038 Uiso 1 1 calc R U . . .
C7 C 0.0260(9) 0.7246(10) 0.5969(8) 0.046(4) Uani 1 1 d . . . . .
C8 C 0.0285(13) 0.6914(12) 0.5359(10) 0.091(7) Uani 1 1 d . . . . .
H8A H 0.052156 0.720761 0.506451 0.109 Uiso 1 1 calc R U . . .
C9 C -0.0053(15) 0.6097(14) 0.5150(12) 0.106(8) Uani 1 1 d . U . . .
H9A H -0.001859 0.585713 0.472403 0.128 Uiso 1 1 calc R U . . .
C10 C -0.0424(15) 0.5669(14) 0.5568(15) 0.108(8) Uani 1 1 d . U . . .
H10A H -0.065162 0.513688 0.541716 0.129 Uiso 1 1 calc R U . . .
C11 C -0.0470(14) 0.5958(12) 0.6139(14) 0.104(8) Uani 1 1 d . U . . .
H11A H -0.071744 0.564693 0.641769 0.125 Uiso 1 1 calc R U . . .
C12 C -0.0155(13) 0.6747(13) 0.6367(13) 0.097(8) Uani 1 1 d . . . . .
H12A H -0.021555 0.695735 0.679263 0.117 Uiso 1 1 calc R U . . .
C13 C -0.0171(5) 0.8430(6) 0.5911(5) 0.041(3) Uani 1 1 d G U . . .
C14 C -0.0103(5) 0.8765(6) 0.5363(5) 0.048(4) Uani 1 1 d G U . . .
H14A H 0.035306 0.890154 0.518350 0.058 Uiso 1 1 calc R U . . .
C15 C -0.0717(7) 0.8895(6) 0.5085(5) 0.055(4) Uani 1 1 d G U . . .
H15A H -0.067170 0.911935 0.471828 0.066 Uiso 1 1 calc R U . . .
C16 C -0.1399(6) 0.8691(7) 0.5354(5) 0.065(4) Uani 1 1 d G U . . .
H16A H -0.180936 0.877844 0.516709 0.078 Uiso 1 1 calc R U . . .
C17 C -0.1466(5) 0.8356(7) 0.5901(5) 0.067(4) Uani 1 1 d G U . . .
H17A H -0.192225 0.821973 0.608112 0.080 Uiso 1 1 calc R U . . .
C18 C -0.0852(6) 0.8226(6) 0.6180(4) 0.047(4) Uani 1 1 d G U . . .
H18A H -0.089749 0.800191 0.654635 0.056 Uiso 1 1 calc R U . . .
C19 C 0.0385(10) 1.1128(11) 0.7147(8) 0.059(5) Uani 1 1 d . . . . .
C20 C -0.0068(12) 1.0680(12) 0.6499(10) 0.076(6) Uani 1 1 d . . . . .
H20A H 0.001662 1.028381 0.627252 0.091 Uiso 1 1 calc R U . . .
C21 C -0.0640(11) 1.0825(11) 0.6195(8) 0.065(5) Uani 1 1 d . . . . .
H21A H -0.100001 1.049012 0.578783 0.078 Uiso 1 1 calc R U . . .
C22 C -0.0675(13) 1.1484(14) 0.6505(12) 0.092(7) Uani 1 1 d . U . . .
H22A H -0.100834 1.162288 0.625935 0.111 Uiso 1 1 calc R U . . .
C23 C -0.0272(15) 1.1917(16) 0.7117(14) 0.117(8) Uani 1 1 d . U . . .
H23A H -0.037477 1.230488 0.733416 0.140 Uiso 1 1 calc R U . . .
C24 C 0.0330(13) 1.1781(12) 0.7446(11) 0.097(8) Uani 1 1 d . . . . .
H24A H 0.068262 1.212272 0.785503 0.116 Uiso 1 1 calc R U . . .
C25 C 0.1125(7) 1.1223(7) 0.8520(4) 0.055(4) Uani 1 1 d G U . . .
C26 C 0.0455(6) 1.0832(7) 0.8773(6) 0.097(7) Uani 1 1 d G U . . .
H26A H -0.000802 1.043185 0.847462 0.116 Uiso 1 1 calc R U . . .
C27 C 0.0477(8) 1.1039(9) 0.9472(7) 0.123(8) Uani 1 1 d G U . . .
H27A H 0.002827 1.077675 0.964134 0.147 Uiso 1 1 calc R U . . .
C28 C 0.1168(10) 1.1636(9) 0.9918(4) 0.127(9) Uani 1 1 d G U . . .
H28A H 0.118300 1.177464 1.038536 0.153 Uiso 1 1 calc R U . . .
C29 C 0.1839(8) 1.2028(8) 0.9664(6) 0.106(7) Uani 1 1 d G U . . .
H29A H 0.230146 1.242764 0.996266 0.128 Uiso 1 1 calc R U . . .
C30 C 0.1817(6) 1.1821(7) 0.8965(6) 0.078(5) Uani 1 1 d G U . . .
H30A H 0.226519 1.208275 0.879594 0.093 Uiso 1 1 calc R U . . .
C31 C 0.2171(10) 0.9596(9) 0.9832(7) 0.048(4) Uani 1 1 d . . . . .
C32 C 0.1651(12) 0.9816(11) 1.0117(9) 0.069(6) Uani 1 1 d . . . . .
H32A H 0.123411 0.982561 0.983874 0.083 Uiso 1 1 calc R U . . .
C33 C 0.1772(13) 1.0022(14) 1.0829(9) 0.087(8) Uani 1 1 d . . . . .
H33A H 0.141507 1.014947 1.102508 0.104 Uiso 1 1 calc R U . . .
C34 C 0.2367(16) 1.0042(15) 1.1232(10) 0.106(8) Uani 1 1 d . U . . .
H34A H 0.242261 1.018344 1.170685 0.127 Uiso 1 1 calc R U . . .
C35 C 0.2899(13) 0.9866(14) 1.0981(10) 0.094(7) Uani 1 1 d . U . . .
H35A H 0.332385 0.988866 1.127772 0.113 Uiso 1 1 calc R U . . .
C36 C 0.2814(12) 0.9651(12) 1.0282(9) 0.079(6) Uani 1 1 d . . . . .
H36A H 0.319156 0.953996 1.010540 0.095 Uiso 1 1 calc R U . . .
C37 C 0.1445(7) 0.8244(5) 0.8770(6) 0.057(4) Uani 1 1 d G U . . .
C38 C 0.0617(7) 0.7915(8) 0.8674(7) 0.082(5) Uani 1 1 d G U . . .
H38A H 0.036579 0.821993 0.866693 0.099 Uiso 1 1 calc R U . . .
C39 C 0.0166(6) 0.7129(9) 0.8590(8) 0.126(8) Uani 1 1 d G U . . .
H39A H -0.038797 0.690836 0.852582 0.151 Uiso 1 1 calc R U . . .
C40 C 0.0541(10) 0.6673(5) 0.8600(9) 0.167(10) Uani 1 1 d G U . . .
H40A H 0.023917 0.614699 0.854388 0.200 Uiso 1 1 calc R U . . .
C41 C 0.1369(11) 0.7002(8) 0.8696(9) 0.158(9) Uani 1 1 d G U . . .
H41A H 0.162008 0.669719 0.870302 0.190 Uiso 1 1 calc R U . . .
C42 C 0.1820(7) 0.7788(8) 0.8780(8) 0.092(6) Uani 1 1 d G U . . .
H42A H 0.237385 0.800876 0.884413 0.111 Uiso 1 1 calc R U . . .
C43 C 0.4330(10) 1.3062(9) 0.8078(7) 0.047(4) Uani 1 1 d . . . . .
C44 C 0.3943(12) 1.3469(11) 0.8376(9) 0.069(5) Uani 1 1 d . . . . .
H44A H 0.339869 1.327602 0.820273 0.083 Uiso 1 1 calc R U . . .
C45 C 0.4338(13) 1.4146(11) 0.8918(9) 0.077(6) Uani 1 1 d . . . . .
H45A H 0.406887 1.439274 0.911505 0.092 Uiso 1 1 calc R U . . .
C46 C 0.5101(14) 1.4403(13) 0.9124(10) 0.078(6) Uani 1 1 d . U . . .
H46A H 0.537858 1.485858 0.947323 0.094 Uiso 1 1 calc R U . . .
C47 C 0.5528(12) 1.4064(12) 0.8874(10) 0.083(7) Uani 1 1 d . . . . .
H47A H 0.607228 1.427623 0.906001 0.100 Uiso 1 1 calc R U . . .
C48 C 0.5138(11) 1.3386(11) 0.8330(10) 0.070(6) Uani 1 1 d . . . . .
H48A H 0.542855 1.315904 0.814222 0.084 Uiso 1 1 calc R U . . .
C49 C 0.3952(10) 1.2450(8) 0.6586(8) 0.044(4) Uani 1 1 d . . . . .
C50 C 0.3327(11) 1.2441(9) 0.6150(9) 0.059(5) Uani 1 1 d . . . . .
H50A H 0.283213 1.228454 0.626711 0.071 Uiso 1 1 calc R U . . .
C51 C 0.3429(14) 1.2659(11) 0.5552(10) 0.080(6) Uani 1 1 d . U . . .
H51A H 0.302542 1.268808 0.527560 0.097 Uiso 1 1 calc R U . . .
C52 C 0.4175(15) 1.2837(12) 0.5373(10) 0.088(7) Uani 1 1 d . U . . .
H52A H 0.425765 1.295874 0.495751 0.105 Uiso 1 1 calc R U . . .
C53 C 0.4760(14) 1.2830(12) 0.5798(11) 0.082(6) Uani 1 1 d . . . . .
H53A H 0.524708 1.295056 0.567300 0.099 Uiso 1 1 calc R U . . .
C54 C 0.4662(11) 1.2644(10) 0.6432(9) 0.060(5) Uani 1 1 d . . . . .
H54A H 0.507911 1.265748 0.673003 0.072 Uiso 1 1 calc R U . . .
C55 C 0.3014(8) 0.9804(9) 0.4772(7) 0.039(4) Uani 1 1 d . . . . .
C56 C 0.3009(10) 0.9303(10) 0.4184(8) 0.058(5) Uani 1 1 d . . . . .
H56A H 0.303056 0.885626 0.421662 0.070 Uiso 1 1 calc R U . . .
C57 C 0.2974(13) 0.9473(14) 0.3579(9) 0.078(6) Uani 1 1 d . . . . .
H57A H 0.300134 0.914833 0.320222 0.094 Uiso 1 1 calc R U . . .
C58 C 0.2903(13) 1.0084(16) 0.3484(9) 0.090(7) Uani 1 1 d . U . . .
H58A H 0.286136 1.016312 0.304633 0.108 Uiso 1 1 calc R U . . .
C59 C 0.2891(13) 1.0571(14) 0.4007(9) 0.086(7) Uani 1 1 d . U . . .
H59A H 0.286677 1.100890 0.394627 0.103 Uiso 1 1 calc R U . . .
C60 C 0.2916(11) 1.0429(11) 0.4659(10) 0.066(6) Uani 1 1 d . . . . .
H60A H 0.286630 1.075373 0.502077 0.080 Uiso 1 1 calc R U . . .
C61 C 0.3611(10) 0.9095(10) 0.5616(7) 0.049(4) Uani 1 1 d . . . . .
C62 C 0.3281(11) 0.8356(10) 0.5691(9) 0.063(5) Uani 1 1 d . . . . .
H62A H 0.275897 0.811903 0.575021 0.076 Uiso 1 1 calc R U . . .
C63 C 0.3725(13) 0.7971(12) 0.5679(11) 0.087(7) Uani 1 1 d . . . . .
H63A H 0.348439 0.746709 0.571430 0.105 Uiso 1 1 calc R U . . .
C64 C 0.4508(14) 0.8295(14) 0.5618(10) 0.083(6) Uani 1 1 d . U . . .
H64A H 0.479372 0.801964 0.562166 0.100 Uiso 1 1 calc R U . . .
C65 C 0.4856(12) 0.9022(14) 0.5551(10) 0.081(6) Uani 1 1 d . U . . .
H65A H 0.538104 0.924375 0.549781 0.097 Uiso 1 1 calc R U . . .
C66 C 0.4440(10) 0.9442(10) 0.5562(9) 0.056(5) Uani 1 1 d . . . . .
H66A H 0.469412 0.994861 0.553512 0.067 Uiso 1 1 calc R U . . .
C67 C 0.4789(7) 0.9348(6) 0.8132(5) 0.045(4) Uani 1 1 d G U . . .
C68 C 0.5065(7) 0.9124(6) 0.7570(4) 0.064(4) Uani 1 1 d G U . . .
H68A H 0.505832 0.932763 0.719415 0.077 Uiso 1 1 calc R U . . .
C69 C 0.5352(7) 0.8595(7) 0.7569(5) 0.081(5) Uani 1 1 d G U . . .
H69A H 0.553677 0.844570 0.719281 0.097 Uiso 1 1 calc R U . . .
C70 C 0.5362(8) 0.8291(6) 0.8131(6) 0.091(6) Uani 1 1 d G U . . .
H70A H 0.555393 0.793717 0.813009 0.109 Uiso 1 1 calc R U . . .
C71 C 0.5086(8) 0.8514(7) 0.8693(5) 0.081(5) Uani 1 1 d G U . . .
H71A H 0.509265 0.831058 0.906870 0.097 Uiso 1 1 calc R U . . .
C72 C 0.4799(7) 0.9043(7) 0.8694(4) 0.064(4) Uani 1 1 d G U . . .
H72A H 0.461419 0.919252 0.907005 0.076 Uiso 1 1 calc R U . . .
C73 C 0.5287(10) 1.0929(10) 0.8698(8) 0.052(4) Uani 1 1 d . U . . .
C74 C 0.5912(12) 1.1341(12) 0.8431(10) 0.081(6) Uani 1 1 d . U . . .
H74A H 0.589450 1.117621 0.796633 0.098 Uiso 1 1 calc R U . . .
C75 C 0.6582(13) 1.2008(14) 0.8841(12) 0.105(8) Uani 1 1 d . U . . .
H75A H 0.694996 1.233690 0.863443 0.125 Uiso 1 1 calc R U . . .
C76 C 0.6700(14) 1.2182(14) 0.9554(12) 0.119(9) Uani 1 1 d . U . . .
H76A H 0.718778 1.256370 0.983396 0.143 Uiso 1 1 calc R U . . .
C77 C 0.6054(12) 1.1760(13) 0.9842(10) 0.090(6) Uani 1 1 d . U . . .
H77A H 0.608317 1.192306 1.030992 0.108 Uiso 1 1 calc R U . . .
C78 C 0.5351(11) 1.1078(11) 0.9421(8) 0.070(5) Uani 1 1 d . U . . .
H78A H 0.496027 1.075471 0.961373 0.085 Uiso 1 1 calc R U . . .
C79 C 0.3523(8) 1.0672(10) 0.9121(7) 0.045(4) Uani 1 1 d . . . . .
C80 C 0.3655(9) 1.1341(9) 0.9509(7) 0.047(4) Uani 1 1 d . . . . .
C81 C 0.3772(9) 1.1990(9) 0.9995(6) 0.037(4) Uani 1 1 d . . . . .
C82 C 0.3352(10) 1.1884(9) 1.0518(7) 0.051(4) Uani 1 1 d . . . . .
H82A H 0.297933 1.139530 1.052696 0.062 Uiso 1 1 calc R U . . .
C83 C 0.3510(11) 1.2537(10) 1.1032(8) 0.056(5) Uani 1 1 d . . . . .
H83A H 0.325259 1.248097 1.139704 0.067 Uiso 1 1 calc R U . . .
C84 C 0.4046(10) 1.3265(8) 1.1002(7) 0.045(4) Uani 1 1 d . . . . .
C85 C 0.4472(13) 1.3358(11) 1.0494(9) 0.079(6) Uani 1 1 d . . . . .
H85A H 0.486620 1.384148 1.049506 0.095 Uiso 1 1 calc R U . . .
C86 C 0.4302(12) 1.2719(11) 0.9987(8) 0.070(6) Uani 1 1 d . . . . .
H86A H 0.455628 1.278231 0.962095 0.084 Uiso 1 1 calc R U . . .
C87 C 0.3642(13) 1.4148(11) 1.1716(9) 0.071(6) Uani 1 1 d . . . . .
C88 C 0.2867(14) 1.3856(13) 1.1400(14) 0.105(8) Uani 1 1 d . . . . .
H88A H 0.262019 1.342317 1.102615 0.125 Uiso 1 1 calc R U . . .
C89 C 0.2432(19) 1.4251(17) 1.1672(18) 0.179(13) Uani 1 1 d . U . . .
H89A H 0.189450 1.407043 1.148053 0.215 Uiso 1 1 calc R U . . .
C90 C 0.2834(19) 1.4886(16) 1.2210(16) 0.151(10) Uani 1 1 d . U . . .
H90A H 0.255162 1.513321 1.237716 0.182 Uiso 1 1 calc R U . . .
C91 C 0.3603(18) 1.5185(14) 1.2519(14) 0.119(8) Uani 1 1 d . U . . .
H91A H 0.384254 1.563810 1.287208 0.143 Uiso 1 1 calc R U . . .
C92 C 0.4052(16) 1.4815(11) 1.2311(11) 0.090(6) Uani 1 1 d . U . . .
C93 C 0.4900(13) 1.4979(10) 1.2463(9) 0.072(6) Uani 1 1 d . . . . .
C94 C 0.5550(14) 1.5526(12) 1.2958(10) 0.086(7) Uani 1 1 d . . . . .
H94A H 0.550878 1.589750 1.327798 0.103 Uiso 1 1 calc R U . . .
C95 C 0.6261(14) 1.5515(12) 1.2971(12) 0.107(9) Uani 1 1 d . . . . .
H95A H 0.670841 1.589198 1.330193 0.128 Uiso 1 1 calc R U . . .
C96 C 0.6342(14) 1.4958(16) 1.2506(15) 0.140(12) Uani 1 1 d . . . . .
H96A H 0.683470 1.496142 1.254628 0.168 Uiso 1 1 calc R U . . .
C97 C 0.5697(15) 1.4396(13) 1.1984(12) 0.106(8) Uani 1 1 d . . . . .
H97A H 0.574489 1.404018 1.165197 0.127 Uiso 1 1 calc R U . . .
C98 C 0.4976(12) 1.4411(10) 1.1999(9) 0.066(5) Uani 1 1 d . . . . .
C99 C 0.2917(9) 0.8695(10) 0.7852(7) 0.050(4) Uani 1 1 d . U . . .
C100 C 0.2734(10) 0.8058(10) 0.7439(9) 0.062(5) Uani 1 1 d . . . . .
C101 C 0.2567(7) 0.7306(5) 0.7074(6) 0.053(4) Uani 1 1 d G U . . .
C102 C 0.3140(7) 0.7065(7) 0.7191(7) 0.108(7) Uani 1 1 d G U . . .
H10B H 0.359854 0.736836 0.753873 0.129 Uiso 1 1 calc R U . . .
C103 C 0.3027(8) 0.6370(7) 0.6788(8) 0.121(8) Uani 1 1 d G U . . .
H10C H 0.341032 0.620825 0.686603 0.145 Uiso 1 1 calc R U . . .
C104 C 0.2342(9) 0.5916(6) 0.6268(8) 0.096(7) Uani 1 1 d G U . . .
C105 C 0.1769(8) 0.6157(7) 0.6151(8) 0.170(11) Uani 1 1 d G U . . .
H10D H 0.131029 0.585381 0.580323 0.204 Uiso 1 1 calc R U . . .
C106 C 0.1882(7) 0.6852(7) 0.6554(8) 0.145(10) Uani 1 1 d G U . . .
H10E H 0.149850 0.701392 0.647593 0.173 Uiso 1 1 calc R U . . .
C107 C 0.1897(8) 0.4497(5) 0.6058(7) 0.076(5) Uani 1 1 d G U . . .
C108 C 0.1622(9) 0.4327(7) 0.6644(6) 0.094(6) Uani 1 1 d G U . . .
H10F H 0.161964 0.470891 0.698207 0.112 Uiso 1 1 calc R U . . .
C109 C 0.1351(9) 0.3588(9) 0.6724(7) 0.126(8) Uani 1 1 d G U . . .
H10G H 0.116688 0.347414 0.711513 0.151 Uiso 1 1 calc R U . . .
C110 C 0.1355(9) 0.3017(6) 0.6218(8) 0.115(7) Uani 1 1 d G U . . .
H11B H 0.117319 0.252238 0.627128 0.138 Uiso 1 1 calc R U . . .
C111 C 0.1630(8) 0.3187(6) 0.5633(7) 0.094(6) Uani 1 1 d G U . . .
H11C H 0.163226 0.280539 0.529437 0.113 Uiso 1 1 calc R U . . .
C112 C 0.1901(8) 0.3927(7) 0.5553(6) 0.078(5) Uani 1 1 d G U . . .
C113 C 0.2202(13) 0.4247(12) 0.5036(12) 0.094(6) Uani 1 1 d . U . . .
C114 C 0.2287(18) 0.3947(16) 0.4376(14) 0.137(9) Uani 1 1 d . U . . .
H11D H 0.211899 0.342556 0.420303 0.165 Uiso 1 1 calc R U . . .
C115 C 0.263(2) 0.4465(18) 0.4005(16) 0.167(11) Uani 1 1 d . U . . .
H11E H 0.278915 0.430214 0.361849 0.200 Uiso 1 1 calc R U . . .
C116 C 0.276(2) 0.5261(17) 0.4177(15) 0.173(11) Uani 1 1 d . U . . .
H11F H 0.284783 0.555786 0.386258 0.208 Uiso 1 1 calc R U . . .
C117 C 0.2726(19) 0.5534(16) 0.4863(14) 0.156(10) Uani 1 1 d . U . . .
H11H H 0.294349 0.605905 0.506078 0.187 Uiso 1 1 calc R U . . .
C118 C 0.2388(16) 0.5040(13) 0.5219(13) 0.110(7) Uani 1 1 d . U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P4 2.268(4) . ?
Au1 P8 2.272(4) . ?
Au1 Pt1 2.9619(10) . ?
Au1 Au2 2.9653(10) . ?
Au1 Au3 2.9769(16) . ?
Au2 P5 2.320(4) . ?
Au2 P2 2.325(4) . ?
Au3 P6 2.313(4) . ?
Au3 P1 2.320(4) . ?
Pt1 C79 1.950(16) . ?
Pt1 C99 1.952(18) . ?
Pt1 P3 2.305(4) . ?
Pt1 P7 2.310(4) . ?
Cl1 O1 1.358(18) . ?
Cl1 O2 1.390(15) . ?
Cl1 O4 1.434(17) . ?
Cl1 O3 1.434(16) . ?
Cl2 O8 1.344(14) . ?
Cl2 O6 1.36(2) . ?
Cl2 O7 1.41(2) . ?
Cl2 O5 1.48(2) . ?
P1 C7 1.809(17) . ?
P1 C3 1.825(13) . ?
P1 C13 1.828(8) . ?
P2 C1 1.818(14) . ?
P2 C19 1.819(14) . ?
P2 C25 1.831(9) . ?
P3 C37 1.772(10) . ?
P3 C2 1.829(13) . ?
P3 C31 1.832(15) . ?
P4 C1 1.789(12) . ?
P4 C3 1.810(14) . ?
P4 C2 1.816(13) . ?
P5 C43 1.808(15) . ?
P5 C6 1.837(13) . ?
P5 C49 1.846(15) . ?
P6 C61 1.777(16) . ?
P6 C4 1.811(16) . ?
P6 C55 1.823(14) . ?
P7 C73 1.799(17) . ?
P7 C5 1.820(12) . ?
P7 C67 1.823(8) . ?
P8 C5 1.813(12) . ?
P8 C6 1.830(14) . ?
P8 C4 1.841(15) . ?
N1 C87 1.41(2) . ?
N1 C98 1.41(2) . ?
N1 C84 1.453(18) . ?
N2 C107 1.354(18) . ?
N2 C118 1.41(3) . ?
N2 C104 1.466(16) . ?
C7 C8 1.31(2) . ?
C7 C12 1.43(2) . ?
C8 C9 1.43(3) . ?
C9 C10 1.35(3) . ?
C10 C11 1.22(3) . ?
C11 C12 1.38(3) . ?
C13 C14 1.3900 . ?
C13 C18 1.3900 . ?
C14 C15 1.3900 . ?
C15 C16 1.3900 . ?
C16 C17 1.3900 . ?
C17 C18 1.3900 . ?
C19 C20 1.38(2) . ?
C19 C24 1.39(2) . ?
C20 C21 1.36(2) . ?
C21 C22 1.39(3) . ?
C22 C23 1.30(3) . ?
C23 C24 1.42(3) . ?
C25 C26 1.3900 . ?
C25 C30 1.3900 . ?
C26 C27 1.3900 . ?
C27 C28 1.3900 . ?
C28 C29 1.3900 . ?
C29 C30 1.3900 . ?
C31 C32 1.39(2) . ?
C31 C36 1.39(2) . ?
C32 C33 1.39(2) . ?
C33 C34 1.30(3) . ?
C34 C35 1.34(3) . ?
C35 C36 1.37(2) . ?
C37 C38 1.3900 . ?
C37 C42 1.3900 . ?
C38 C39 1.3900 . ?
C39 C40 1.3900 . ?
C40 C41 1.3900 . ?
C41 C42 1.3900 . ?
C43 C48 1.37(2) . ?
C43 C44 1.42(2) . ?
C44 C45 1.41(2) . ?
C45 C46 1.30(3) . ?
C46 C47 1.35(3) . ?
C47 C48 1.41(2) . ?
C49 C54 1.33(2) . ?
C49 C50 1.39(2) . ?
C50 C51 1.37(2) . ?
C51 C52 1.42(3) . ?
C52 C53 1.34(3) . ?
C53 C54 1.41(2) . ?
C55 C60 1.40(2) . ?
C55 C56 1.41(2) . ?
C56 C57 1.33(2) . ?
C57 C58 1.34(3) . ?
C58 C59 1.31(3) . ?
C59 C60 1.40(2) . ?
C61 C62 1.38(2) . ?
C61 C66 1.45(2) . ?
C62 C63 1.37(2) . ?
C63 C64 1.37(3) . ?
C64 C65 1.35(3) . ?
C65 C66 1.39(2) . ?
C67 C68 1.3900 . ?
C67 C72 1.3900 . ?
C68 C69 1.3900 . ?
C69 C70 1.3900 . ?
C70 C71 1.3900 . ?
C71 C72 1.3900 . ?
C73 C74 1.36(2) . ?
C73 C78 1.42(2) . ?
C74 C75 1.40(3) . ?
C75 C76 1.39(3) . ?
C76 C77 1.42(3) . ?
C77 C78 1.45(2) . ?
C79 C80 1.32(2) . ?
C80 C81 1.392(18) . ?
C81 C86 1.37(2) . ?
C81 C82 1.392(19) . ?
C82 C83 1.40(2) . ?
C83 C84 1.39(2) . ?
C84 C85 1.37(2) . ?
C85 C86 1.37(2) . ?
C87 C88 1.35(3) . ?
C87 C92 1.46(3) . ?
C88 C89 1.46(3) . ?
C89 C90 1.36(4) . ?
C90 C91 1.33(4) . ?
C91 C92 1.41(3) . ?
C92 C93 1.48(3) . ?
C93 C94 1.36(3) . ?
C93 C98 1.41(2) . ?
C94 C95 1.36(3) . ?
C95 C96 1.40(3) . ?
C96 C97 1.39(3) . ?
C97 C98 1.39(3) . ?
C99 C100 1.26(2) . ?
C100 C101 1.427(17) . ?
C101 C102 1.3900 . ?
C101 C106 1.3900 . ?
C102 C103 1.3900 . ?
C103 C104 1.3900 . ?
C104 C105 1.3900 . ?
C105 C106 1.3900 . ?
C107 C108 1.3900 . ?
C107 C112 1.3900 . ?
C108 C109 1.3900 . ?
C109 C110 1.3900 . ?
C110 C111 1.3900 . ?
C111 C112 1.3900 . ?
C112 C113 1.38(2) . ?
C113 C114 1.42(3) . ?
C113 C118 1.43(3) . ?
C114 C115 1.37(4) . ?
C115 C116 1.47(4) . ?
C116 C117 1.41(3) . ?
C117 C118 1.32(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P4 Au1 P8 179.52(14) . . ?
P4 Au1 Pt1 89.62(10) . . ?
P8 Au1 Pt1 90.24(9) . . ?
P4 Au1 Au2 90.53(10) . . ?
P8 Au1 Au2 89.19(10) . . ?
Pt1 Au1 Au2 127.15(4) . . ?
P4 Au1 Au3 90.05(10) . . ?
P8 Au1 Au3 90.41(10) . . ?
Pt1 Au1 Au3 122.34(3) . . ?
Au2 Au1 Au3 110.51(3) . . ?
P5 Au2 P2 168.79(13) . . ?
P5 Au2 Au1 91.92(10) . . ?
P2 Au2 Au1 92.01(10) . . ?
P6 Au3 P1 172.87(13) . . ?
P6 Au3 Au1 91.67(10) . . ?
P1 Au3 Au1 91.30(10) . . ?
C79 Pt1 C99 176.1(6) . . ?
C79 Pt1 P3 85.9(4) . . ?
C99 Pt1 P3 95.9(5) . . ?
C79 Pt1 P7 94.6(4) . . ?
C99 Pt1 P7 84.0(5) . . ?
P3 Pt1 P7 175.49(13) . . ?
C79 Pt1 Au1 90.6(4) . . ?
C99 Pt1 Au1 85.9(4) . . ?
P3 Pt1 Au1 92.38(9) . . ?
P7 Pt1 Au1 92.10(9) . . ?
O1 Cl1 O2 111.5(13) . . ?
O1 Cl1 O4 111.4(15) . . ?
O2 Cl1 O4 109.5(11) . . ?
O1 Cl1 O3 107.8(14) . . ?
O2 Cl1 O3 110.4(12) . . ?
O4 Cl1 O3 106.0(11) . . ?
O8 Cl2 O6 114.4(14) . . ?
O8 Cl2 O7 107.4(14) . . ?
O6 Cl2 O7 109.3(13) . . ?
O8 Cl2 O5 102.8(11) . . ?
O6 Cl2 O5 114.2(15) . . ?
O7 Cl2 O5 108.2(15) . . ?
C7 P1 C3 104.7(7) . . ?
C7 P1 C13 103.3(6) . . ?
C3 P1 C13 107.6(6) . . ?
C7 P1 Au3 116.4(5) . . ?
C3 P1 Au3 110.3(5) . . ?
C13 P1 Au3 113.7(4) . . ?
C1 P2 C19 102.3(7) . . ?
C1 P2 C25 104.7(6) . . ?
C19 P2 C25 105.3(7) . . ?
C1 P2 Au2 110.5(4) . . ?
C19 P2 Au2 118.7(6) . . ?
C25 P2 Au2 113.8(4) . . ?
C37 P3 C2 106.3(6) . . ?
C37 P3 C31 101.3(7) . . ?
C2 P3 C31 102.8(7) . . ?
C37 P3 Pt1 118.6(5) . . ?
C2 P3 Pt1 111.1(5) . . ?
C31 P3 Pt1 115.2(6) . . ?
C1 P4 C3 108.1(7) . . ?
C1 P4 C2 107.0(6) . . ?
C3 P4 C2 107.2(6) . . ?
C1 P4 Au1 113.2(5) . . ?
C3 P4 Au1 109.1(5) . . ?
C2 P4 Au1 112.2(5) . . ?
C43 P5 C6 102.0(7) . . ?
C43 P5 C49 106.0(7) . . ?
C6 P5 C49 106.8(7) . . ?
C43 P5 Au2 115.2(6) . . ?
C6 P5 Au2 112.6(5) . . ?
C49 P5 Au2 113.4(6) . . ?
C61 P6 C4 107.7(7) . . ?
C61 P6 C55 104.7(7) . . ?
C4 P6 C55 100.4(7) . . ?
C61 P6 Au3 113.9(6) . . ?
C4 P6 Au3 111.2(5) . . ?
C55 P6 Au3 117.7(5) . . ?
C73 P7 C5 105.0(7) . . ?
C73 P7 C67 103.1(7) . . ?
C5 P7 C67 102.5(5) . . ?
C73 P7 Pt1 119.4(6) . . ?
C5 P7 Pt1 111.7(4) . . ?
C67 P7 Pt1 113.5(4) . . ?
C5 P8 C6 107.9(6) . . ?
C5 P8 C4 106.7(6) . . ?
C6 P8 C4 106.7(6) . . ?
C5 P8 Au1 111.8(5) . . ?
C6 P8 Au1 111.6(4) . . ?
C4 P8 Au1 111.9(5) . . ?
C87 N1 C98 112.4(15) . . ?
C87 N1 C84 123.3(16) . . ?
C98 N1 C84 124.3(15) . . ?
C107 N2 C118 109.9(16) . . ?
C107 N2 C104 126.7(15) . . ?
C118 N2 C104 123.4(18) . . ?
P4 C1 P2 116.7(7) . . ?
P4 C2 P3 114.0(7) . . ?
P4 C3 P1 114.6(7) . . ?
P6 C4 P8 114.1(7) . . ?
P8 C5 P7 115.5(6) . . ?
P8 C6 P5 112.9(7) . . ?
C8 C7 C12 116.2(19) . . ?
C8 C7 P1 120.8(16) . . ?
C12 C7 P1 122.7(13) . . ?
C7 C8 C9 119(2) . . ?
C10 C9 C8 120(2) . . ?
C11 C10 C9 122(3) . . ?
C10 C11 C12 120(3) . . ?
C11 C12 C7 122(2) . . ?
C14 C13 C18 120.0 . . ?
C14 C13 P1 117.3(6) . . ?
C18 C13 P1 122.7(6) . . ?
C15 C14 C13 120.0 . . ?
C14 C15 C16 120.0 . . ?
C17 C16 C15 120.0 . . ?
C18 C17 C16 120.0 . . ?
C17 C18 C13 120.0 . . ?
C20 C19 C24 120.1(15) . . ?
C20 C19 P2 122.6(13) . . ?
C24 C19 P2 117.0(13) . . ?
C21 C20 C19 119.2(17) . . ?
C20 C21 C22 118.6(18) . . ?
C23 C22 C21 124(2) . . ?
C22 C23 C24 118(2) . . ?
C19 C24 C23 119(2) . . ?
C26 C25 C30 120.0 . . ?
C26 C25 P2 122.2(7) . . ?
C30 C25 P2 117.8(7) . . ?
C27 C26 C25 120.0 . . ?
C26 C27 C28 120.0 . . ?
C27 C28 C29 120.0 . . ?
C28 C29 C30 120.0 . . ?
C29 C30 C25 120.0 . . ?
C32 C31 C36 117.6(17) . . ?
C32 C31 P3 123.2(13) . . ?
C36 C31 P3 119.2(14) . . ?
C33 C32 C31 118.0(19) . . ?
C34 C33 C32 122(2) . . ?
C33 C34 C35 121.6(19) . . ?
C34 C35 C36 119.3(19) . . ?
C35 C36 C31 121(2) . . ?
C38 C37 C42 120.0 . . ?
C38 C37 P3 121.7(8) . . ?
C42 C37 P3 118.3(8) . . ?
C37 C38 C39 120.0 . . ?
C38 C39 C40 120.0 . . ?
C39 C40 C41 120.0 . . ?
C42 C41 C40 120.0 . . ?
C41 C42 C37 120.0 . . ?
C48 C43 C44 116.0(16) . . ?
C48 C43 P5 123.3(14) . . ?
C44 C43 P5 120.7(14) . . ?
C45 C44 C43 123.6(19) . . ?
C46 C45 C44 115.6(19) . . ?
C45 C46 C47 125(2) . . ?
C46 C47 C48 119(2) . . ?
C43 C48 C47 119.8(17) . . ?
C54 C49 C50 121.8(16) . . ?
C54 C49 P5 120.2(13) . . ?
C50 C49 P5 118.0(13) . . ?
C51 C50 C49 121.1(19) . . ?
C50 C51 C52 117.2(19) . . ?
C53 C52 C51 120(2) . . ?
C52 C53 C54 122(2) . . ?
C49 C54 C53 117.5(17) . . ?
C60 C55 C56 115.7(14) . . ?
C60 C55 P6 122.1(12) . . ?
C56 C55 P6 122.0(13) . . ?
C57 C56 C55 119.6(18) . . ?
C56 C57 C58 123.8(19) . . ?
C59 C58 C57 120.0(19) . . ?
C58 C59 C60 120(2) . . ?
C55 C60 C59 121.0(17) . . ?
C62 C61 C66 117.0(15) . . ?
C62 C61 P6 121.0(14) . . ?
C66 C61 P6 122.0(13) . . ?
C63 C62 C61 120.0(19) . . ?
C62 C63 C64 123(2) . . ?
C65 C64 C63 118.6(19) . . ?
C64 C65 C66 121(2) . . ?
C65 C66 C61 120.2(18) . . ?
C68 C67 C72 120.0 . . ?
C68 C67 P7 122.9(6) . . ?
C72 C67 P7 117.1(6) . . ?
C67 C68 C69 120.0 . . ?
C70 C69 C68 120.0 . . ?
C69 C70 C71 120.0 . . ?
C70 C71 C72 120.0 . . ?
C71 C72 C67 120.0 . . ?
C74 C73 C78 120.7(17) . . ?
C74 C73 P7 122.3(13) . . ?
C78 C73 P7 115.7(14) . . ?
C73 C74 C75 121(2) . . ?
C76 C75 C74 120(2) . . ?
C75 C76 C77 118(2) . . ?
C76 C77 C78 121.1(19) . . ?
C73 C78 C77 116.5(19) . . ?
C80 C79 Pt1 174.2(11) . . ?
C79 C80 C81 171.6(17) . . ?
C86 C81 C80 122.3(14) . . ?
C86 C81 C82 119.6(14) . . ?
C80 C81 C82 118.1(15) . . ?
C81 C82 C83 117.9(15) . . ?
C84 C83 C82 120.6(15) . . ?
C85 C84 C83 120.7(14) . . ?
C85 C84 N1 120.2(15) . . ?
C83 C84 N1 118.8(15) . . ?
C86 C85 C84 118.1(18) . . ?
C85 C86 C81 122.8(17) . . ?
C88 C87 N1 130.4(18) . . ?
C88 C87 C92 124(2) . . ?
N1 C87 C92 105.9(19) . . ?
C87 C88 C89 117(2) . . ?
C90 C89 C88 118(3) . . ?
C91 C90 C89 125(3) . . ?
C90 C91 C92 120(3) . . ?
C91 C92 C87 116(2) . . ?
C91 C92 C93 137(2) . . ?
C87 C92 C93 106.5(17) . . ?
C94 C93 C98 119(2) . . ?
C94 C93 C92 132.4(18) . . ?
C98 C93 C92 108.2(17) . . ?
C93 C94 C95 118(2) . . ?
C94 C95 C96 122.5(19) . . ?
C97 C96 C95 121(2) . . ?
C98 C97 C96 115(2) . . ?
C97 C98 N1 129.1(17) . . ?
C97 C98 C93 123.7(19) . . ?
N1 C98 C93 107.0(18) . . ?
C100 C99 Pt1 178.0(13) . . ?
C99 C100 C101 170.4(18) . . ?
C102 C101 C106 120.0 . . ?
C102 C101 C100 119.1(10) . . ?
C106 C101 C100 120.5(10) . . ?
C103 C102 C101 120.0 . . ?
C102 C103 C104 120.0 . . ?
C105 C104 C103 120.0 . . ?
C105 C104 N2 120.9(11) . . ?
C103 C104 N2 119.1(11) . . ?
C104 C105 C106 120.0 . . ?
C105 C106 C101 120.0 . . ?
N2 C107 C108 131.3(11) . . ?
N2 C107 C112 108.7(11) . . ?
C108 C107 C112 120.0 . . ?
C107 C108 C109 120.0 . . ?
C110 C109 C108 120.0 . . ?
C109 C110 C111 120.0 . . ?
C110 C111 C112 120.0 . . ?
C113 C112 C111 131.9(12) . . ?
C113 C112 C107 108.1(12) . . ?
C111 C112 C107 120.0 . . ?
C112 C113 C114 134(2) . . ?
C112 C113 C118 108.3(17) . . ?
C114 C113 C118 117(2) . . ?
C115 C114 C113 117(2) . . ?
C114 C115 C116 125(2) . . ?
C117 C116 C115 114(3) . . ?
C118 C117 C116 120(3) . . ?
C117 C118 N2 130(2) . . ?
C117 C118 C113 125(2) . . ?
N2 C118 C113 105(2) . . ?

_refine_diff_density_max         4.525
_refine_diff_density_min         -3.182
_refine_diff_density_rms         0.257


# start Validation Reply Form
_vrf_PLAT973_z                   
;
PROBLEM: Check Calcd Positive Resid. Density on       Au1       3.23 eA-3
PROBLEM: Check Calcd Positive Resid. Density on       Pt1       2.93 eA-3  
RESPONSE: Residual electron density does not make chemical sence. Residual electron
resides too close to heavy metal atom center.
;
# END Validation Reply Form
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_complex_11
_database_code_depnum_ccdc_archive 'CCDC 1846542'
_audit_update_record             
;
2018-05-31 deposited with the CCDC.
2018-08-02 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2016/6
_shelx_SHELXL_version_number     2016/6
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C202 H152 Ag2 B2 Cl0 F48 O0 P10 Pt'
_chemical_formula_weight         4233.38

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   19.1023(4)
_cell_length_b                   21.5915(5)
_cell_length_c                   27.3560(6)
_cell_angle_alpha                90
_cell_angle_beta                 109.8870(10)
_cell_angle_gamma                90
_cell_volume                     10610.1(4)
_cell_formula_units_Z            2
_cell_measurement_temperature    110(2)
_cell_measurement_reflns_used    9918
_cell_measurement_theta_min      2.33
_cell_measurement_theta_max      26.76

_exptl_crystal_description       Bloc
_exptl_crystal_colour            Yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.325
_exptl_crystal_F_000             4256
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.42
_exptl_crystal_size_mid          0.34
_exptl_crystal_size_min          0.30
_exptl_absorpt_coefficient_mu    1.005
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.67
_exptl_absorpt_correction_T_max  0.74
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      110(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker D8 Venture '
_diffrn_measurement_method       'Bruker D8 Venture '
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            121336
_diffrn_reflns_av_unetI/netI     0.0518
_diffrn_reflns_av_R_equivalents  0.0624
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_l_min       -35
_diffrn_reflns_limit_l_max       35
_diffrn_reflns_theta_min         2.201
_diffrn_reflns_theta_max         27.494
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             24324
_reflns_number_gt                17337
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.000 0.000 0.000 894 283 ' '
2 0.000 0.694 0.492 8 0 ' '
3 0.000 0.306 0.508 8 0 ' '
4 0.068 0.269 0.835 19 0 ' '
5 0.500 0.500 0.500 893 282 ' '
6 0.432 0.769 0.665 20 0 ' '
7 0.504 0.197 0.007 7 0 ' '
8 0.496 0.803 0.993 7 0 ' '
9 0.568 0.231 0.335 19 0 ' '
10 0.932 0.731 0.165 20 0 ' '
_platon_squeeze_void_probe_radius 1.20
_platon_squeeze_details          
;
The unit cell contains highly disordered CH2Cl2 molecules which have been treated as 
a diffuse contribution to the overall scattering without specific atom 
positions by SQUEEZE/PLATON. 
;


_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1285P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     'SHELXL-2016/6 (Sheldrick 2016)'
_refine_ls_extinction_coef       0.00229(19)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         24324
_refine_ls_number_parameters     1197
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0856
_refine_ls_R_factor_gt           0.0638
_refine_ls_wR_factor_ref         0.2033
_refine_ls_wR_factor_gt          0.1857
_refine_ls_goodness_of_fit_ref   1.087
_refine_ls_restrained_S_all      1.087
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 1.000000 0.500000 0.500000 0.04315(11) Uani 1 2 d S . P . .
Ag1 Ag 0.75792(2) 0.55074(2) 0.29499(2) 0.03580(11) Uani 1 1 d . . . . .
P1 P 0.91166(7) 0.52573(5) 0.42224(4) 0.0381(3) Uani 1 1 d . . . . .
P2 P 0.85155(6) 0.63356(5) 0.34148(4) 0.0330(2) Uani 1 1 d . . . . .
P3 P 0.73328(7) 0.53142(6) 0.37750(4) 0.0422(3) Uani 1 1 d . . . . .
P4 P 0.84730(7) 0.45994(5) 0.31283(4) 0.0378(3) Uani 1 1 d . . . . .
P5 P 0.66657(6) 0.56104(5) 0.20845(4) 0.0353(2) Uani 1 1 d . . . . .
F1 F 0.5729(5) 0.2963(2) 0.6511(3) 0.171(3) Uani 1 1 d . . . . .
F2 F 0.6067(3) 0.2162(3) 0.6977(2) 0.138(2) Uani 1 1 d . . . . .
F3 F 0.5050(3) 0.2198(2) 0.6436(2) 0.1184(18) Uani 1 1 d . . . . .
F4 F 0.5490(3) 0.2843(3) 0.4649(2) 0.143(3) Uani 1 1 d . . . . .
F5 F 0.6355(6) 0.2415(6) 0.4532(3) 0.263(7) Uani 1 1 d . . . . .
F6 F 0.5376(12) 0.2034(5) 0.4398(3) 0.409(14) Uani 1 1 d . . . . .
F7 F 0.9933(4) 0.1767(3) 0.5391(4) 0.203(4) Uani 1 1 d . . . . .
F8 F 0.9059(5) 0.1831(3) 0.4797(2) 0.178(4) Uani 1 1 d . . . . .
F9 F 0.9110(6) 0.2255(2) 0.5466(4) 0.220(5) Uani 1 1 d . . . . .
F10 F 0.8978(2) -0.0729(2) 0.50103(17) 0.0995(16) Uani 1 1 d . . . . .
F11 F 1.00086(18) -0.04617(16) 0.55629(14) 0.0646(9) Uani 1 1 d . . . . .
F12 F 0.9210(2) -0.09172(16) 0.58210(18) 0.0805(12) Uani 1 1 d . . . . .
F13 F 0.5483(6) -0.0590(4) 0.4306(2) 0.253(7) Uani 1 1 d . . . . .
F14 F 0.6473(4) -0.0935(4) 0.4523(3) 0.178(4) Uani 1 1 d . . . . .
F15 F 0.5716(6) -0.1432(3) 0.4637(2) 0.193(4) Uani 1 1 d . . . . .
F16 F 0.4696(3) -0.0821(3) 0.6075(2) 0.131(2) Uani 1 1 d . . . . .
F17 F 0.5687(3) -0.1215(2) 0.6575(2) 0.121(2) Uani 1 1 d . . . . .
F18 F 0.5387(3) -0.0292(2) 0.66667(19) 0.0989(15) Uani 1 1 d . . . . .
F19 F 0.9459(2) 0.19995(17) 0.77290(16) 0.0748(10) Uani 1 1 d . . . . .
F20 F 0.8343(2) 0.22763(18) 0.75749(18) 0.0879(13) Uani 1 1 d . . . . .
F21 F 0.8930(3) 0.1749(2) 0.82621(17) 0.0970(14) Uani 1 1 d . . . . .
F22 F 0.9003(6) -0.0880(3) 0.7430(3) 0.184(4) Uani 1 1 d . . . . .
F23 F 0.8188(5) -0.0851(3) 0.7675(4) 0.192(4) Uani 1 1 d . . . . .
F24 F 0.9118(8) -0.0486(3) 0.8153(3) 0.303(8) Uani 1 1 d . . . . .
C1 C 0.7073(3) 0.5986(3) 0.4087(2) 0.0553(14) Uani 1 1 d . . . . .
C2 C 0.6727(4) 0.6496(3) 0.3780(3) 0.0750(18) Uani 1 1 d . . . . .
H2A H 0.665829 0.649670 0.341945 0.090 Uiso 1 1 calc R U . . .
C3 C 0.6483(5) 0.7004(4) 0.3997(4) 0.088(2) Uani 1 1 d . . . . .
H3A H 0.621853 0.732983 0.377915 0.105 Uiso 1 1 calc R U . . .
C4 C 0.6613(5) 0.7032(4) 0.4493(3) 0.099(3) Uani 1 1 d . . . . .
H4A H 0.641390 0.736097 0.463543 0.118 Uiso 1 1 calc R U . . .
C5 C 0.7021(4) 0.6604(4) 0.4796(4) 0.104(3) Uani 1 1 d . . . . .
H5A H 0.715263 0.665036 0.516192 0.125 Uiso 1 1 calc R U . . .
C6 C 0.7268(4) 0.6088(4) 0.4606(3) 0.084(2) Uani 1 1 d . . . . .
H6A H 0.757986 0.579819 0.484280 0.101 Uiso 1 1 calc R U . . .
C7 C 0.6684(4) 0.4708(3) 0.3791(2) 0.074(2) Uani 1 1 d . . . . .
C8 C 0.6632(8) 0.4493(6) 0.4242(3) 0.177(7) Uani 1 1 d . . . . .
H8A H 0.694036 0.465827 0.456503 0.213 Uiso 1 1 calc R U . . .
C9 C 0.6120(9) 0.4027(7) 0.4227(4) 0.220(10) Uani 1 1 d . . . . .
H9A H 0.604842 0.389677 0.453796 0.264 Uiso 1 1 calc R U . . .
C10 C 0.5727(7) 0.3763(5) 0.3771(3) 0.164(6) Uani 1 1 d . . . . .
H10A H 0.541338 0.342070 0.376957 0.197 Uiso 1 1 calc R U . . .
C11 C 0.5766(5) 0.3973(4) 0.3310(3) 0.102(3) Uani 1 1 d . . . . .
H11A H 0.547273 0.379101 0.298995 0.122 Uiso 1 1 calc R U . . .
C12 C 0.6248(3) 0.4459(3) 0.3324(2) 0.0720(19) Uani 1 1 d . . . . .
H12A H 0.627738 0.462083 0.300850 0.086 Uiso 1 1 calc R U . . .
C13 C 0.9263(3) 0.6502(2) 0.31630(19) 0.0415(10) Uani 1 1 d . . . . .
C14 C 0.9806(3) 0.6953(3) 0.3374(2) 0.0551(13) Uani 1 1 d . . . . .
H14A H 0.978650 0.719567 0.365864 0.066 Uiso 1 1 calc R U . . .
C15 C 1.0365(4) 0.7050(3) 0.3177(4) 0.083(2) Uani 1 1 d . . . . .
H15A H 1.073501 0.735481 0.332685 0.100 Uiso 1 1 calc R U . . .
C16 C 1.0390(4) 0.6698(3) 0.2753(3) 0.082(2) Uani 1 1 d . . . . .
H16A H 1.077896 0.676238 0.261599 0.099 Uiso 1 1 calc R U . . .
C17 C 0.9852(4) 0.6257(3) 0.2534(3) 0.076(2) Uani 1 1 d . . . . .
H17A H 0.986090 0.602594 0.224128 0.091 Uiso 1 1 calc R U . . .
C18 C 0.9303(3) 0.6156(2) 0.2744(2) 0.0519(13) Uani 1 1 d . . . . .
H18A H 0.894208 0.584268 0.259979 0.062 Uiso 1 1 calc R U . . .
C19 C 0.8155(2) 0.7099(2) 0.35044(18) 0.0373(10) Uani 1 1 d . . . . .
C20 C 0.8433(3) 0.7450(2) 0.39558(19) 0.0467(12) Uani 1 1 d . . . . .
H20A H 0.885619 0.730810 0.423189 0.056 Uiso 1 1 calc R U . . .
C21 C 0.8100(4) 0.8006(3) 0.4008(2) 0.0590(14) Uani 1 1 d . . . . .
H21A H 0.827715 0.823152 0.432417 0.071 Uiso 1 1 calc R U . . .
C22 C 0.7513(3) 0.8228(3) 0.3600(3) 0.0659(16) Uani 1 1 d . . . . .
H22A H 0.728435 0.860803 0.363451 0.079 Uiso 1 1 calc R U . . .
C23 C 0.7252(3) 0.7900(3) 0.3136(3) 0.0632(16) Uani 1 1 d . . . . .
H23A H 0.685820 0.806261 0.284938 0.076 Uiso 1 1 calc R U . . .
C24 C 0.7567(3) 0.7337(2) 0.3092(2) 0.0493(12) Uani 1 1 d . . . . .
H24A H 0.738022 0.710917 0.277735 0.059 Uiso 1 1 calc R U . . .
C25 C 0.8914(3) 0.4351(2) 0.26708(17) 0.0386(10) Uani 1 1 d . . . . .
C26 C 0.8697(3) 0.4624(2) 0.21782(16) 0.0383(10) Uani 1 1 d . . . . .
H26A H 0.830773 0.492139 0.208548 0.046 Uiso 1 1 calc R U . . .
C27 C 0.9038(3) 0.4469(2) 0.18244(19) 0.0473(12) Uani 1 1 d . . . . .
H27A H 0.888360 0.465886 0.149123 0.057 Uiso 1 1 calc R U . . .
C28 C 0.9604(3) 0.4038(3) 0.1957(2) 0.0546(13) Uani 1 1 d . . . . .
H28A H 0.984111 0.393134 0.171462 0.065 Uiso 1 1 calc R U . . .
C29 C 0.9827(3) 0.3760(3) 0.2441(2) 0.0571(14) Uani 1 1 d . . . . .
H29A H 1.021505 0.346083 0.252844 0.068 Uiso 1 1 calc R U . . .
C30 C 0.9492(3) 0.3913(2) 0.2798(2) 0.0517(13) Uani 1 1 d . . . . .
H30A H 0.965161 0.372168 0.313046 0.062 Uiso 1 1 calc R U . . .
C31 C 0.8258(3) 0.3868(2) 0.33907(17) 0.0447(11) Uani 1 1 d . . . . .
C32 C 0.7613(4) 0.3575(3) 0.3119(2) 0.0685(17) Uani 1 1 d . . . . .
H32A H 0.729041 0.374621 0.280261 0.082 Uiso 1 1 calc R U . . .
C33 C 0.7427(5) 0.3025(4) 0.3307(3) 0.091(2) Uani 1 1 d . . . . .
H33A H 0.698848 0.280785 0.311038 0.109 Uiso 1 1 calc R U . . .
C34 C 0.7873(5) 0.2794(3) 0.3773(3) 0.081(2) Uani 1 1 d . . . . .
H34A H 0.772766 0.243040 0.390874 0.097 Uiso 1 1 calc R U . . .
C35 C 0.8509(4) 0.3073(3) 0.4040(2) 0.0697(19) Uani 1 1 d . . . . .
H35A H 0.881685 0.290200 0.436108 0.084 Uiso 1 1 calc R U . . .
C36 C 0.8726(4) 0.3607(2) 0.3855(2) 0.0567(14) Uani 1 1 d . . . . .
H36A H 0.918874 0.379607 0.404110 0.068 Uiso 1 1 calc R U . . .
C37 C 0.9037(3) 0.60939(19) 0.40931(17) 0.0375(10) Uani 1 1 d . . . . .
H37A H 0.954551 0.626801 0.419268 0.045 Uiso 1 1 calc R U . . .
H37B H 0.879317 0.628377 0.432323 0.045 Uiso 1 1 calc R U . . .
C38 C 0.8215(3) 0.5029(2) 0.42618(19) 0.0448(12) Uani 1 1 d . . . . .
H38A H 0.821146 0.515579 0.460877 0.054 Uiso 1 1 calc R U . . .
H38B H 0.819534 0.457083 0.425214 0.054 Uiso 1 1 calc R U . . .
C39 C 0.9278(3) 0.4902(2) 0.36623(18) 0.0418(11) Uani 1 1 d . . . . .
H39A H 0.963275 0.455631 0.379305 0.050 Uiso 1 1 calc R U . . .
H39B H 0.952788 0.521336 0.351296 0.050 Uiso 1 1 calc R U . . .
C40 C 0.6030(3) 0.6258(2) 0.19781(19) 0.0408(10) Uani 1 1 d . . . . .
C41 C 0.5726(4) 0.6393(3) 0.2358(2) 0.0660(17) Uani 1 1 d . . . . .
H41A H 0.586107 0.615458 0.266844 0.079 Uiso 1 1 calc R U . . .
C42 C 0.5215(4) 0.6885(3) 0.2285(3) 0.0734(18) Uani 1 1 d . . . . .
H42A H 0.498866 0.697109 0.253751 0.088 Uiso 1 1 calc R U . . .
C43 C 0.5051(3) 0.7235(3) 0.1847(3) 0.0649(17) Uani 1 1 d . . . . .
H43A H 0.471680 0.757305 0.180044 0.078 Uiso 1 1 calc R U . . .
C44 C 0.5349(3) 0.7116(3) 0.1479(3) 0.0705(18) Uani 1 1 d . . . . .
H44A H 0.522244 0.736822 0.117665 0.085 Uiso 1 1 calc R U . . .
C45 C 0.5842(3) 0.6625(3) 0.1537(2) 0.0564(14) Uani 1 1 d . . . . .
H45A H 0.605001 0.654063 0.127419 0.068 Uiso 1 1 calc R U . . .
C46 C 0.7079(3) 0.5682(2) 0.15834(18) 0.0427(11) Uani 1 1 d . . . . .
C47 C 0.7651(3) 0.6122(3) 0.1672(2) 0.0499(12) Uani 1 1 d . . . . .
H47A H 0.777180 0.638102 0.196996 0.060 Uiso 1 1 calc R U . . .
C48 C 0.8047(3) 0.6183(3) 0.1324(2) 0.0609(15) Uani 1 1 d . . . . .
H48A H 0.843505 0.647976 0.138643 0.073 Uiso 1 1 calc R U . . .
C49 C 0.7862(3) 0.5801(3) 0.0887(2) 0.0641(17) Uani 1 1 d . . . . .
H49A H 0.812348 0.583813 0.064862 0.077 Uiso 1 1 calc R U . . .
C50 C 0.7296(3) 0.5368(4) 0.0800(2) 0.0651(17) Uani 1 1 d . . . . .
H50A H 0.717293 0.511002 0.050124 0.078 Uiso 1 1 calc R U . . .
C51 C 0.6908(3) 0.5308(3) 0.11436(19) 0.0521(13) Uani 1 1 d . . . . .
H51A H 0.652191 0.500964 0.107809 0.063 Uiso 1 1 calc R U . . .
C52 C 0.6069(3) 0.4921(2) 0.19174(18) 0.0395(10) Uani 1 1 d . . . . .
C53 C 0.5322(3) 0.4936(2) 0.1868(2) 0.0443(11) Uani 1 1 d . . . . .
H53A H 0.508696 0.532062 0.187879 0.053 Uiso 1 1 calc R U . . .
C54 C 0.4917(3) 0.4388(2) 0.18010(19) 0.0462(11) Uani 1 1 d . . . . .
H54A H 0.440608 0.440143 0.176992 0.055 Uiso 1 1 calc R U . . .
C55 C 0.5247(3) 0.3826(2) 0.1780(2) 0.0504(12) Uani 1 1 d . . . . .
H55A H 0.496343 0.345495 0.173073 0.061 Uiso 1 1 calc R U . . .
C56 C 0.5995(3) 0.3803(2) 0.1830(2) 0.0498(12) Uani 1 1 d . . . . .
H56A H 0.622485 0.341781 0.181185 0.060 Uiso 1 1 calc R U . . .
C57 C 0.6401(3) 0.4348(2) 0.1908(2) 0.0460(11) Uani 1 1 d . . . . .
H57A H 0.691716 0.433040 0.195493 0.055 Uiso 1 1 calc R U . . .
C58 C 0.9539(3) 0.5671(2) 0.52992(17) 0.0463(12) Uani 1 1 d . . . . .
C59 C 0.9244(3) 0.6061(2) 0.54660(17) 0.0432(11) Uani 1 1 d . . . . .
C60 C 0.8868(3) 0.6522(2) 0.56717(18) 0.0409(10) Uani 1 1 d . . . . .
C61 C 0.8536(4) 0.6361(2) 0.6031(2) 0.0601(15) Uani 1 1 d . . . . .
H61A H 0.858046 0.594774 0.615789 0.072 Uiso 1 1 calc R U . . .
C62 C 0.8139(3) 0.6791(3) 0.6210(2) 0.0568(14) Uani 1 1 d . . . . .
H62A H 0.791595 0.666499 0.645567 0.068 Uiso 1 1 calc R U . . .
C63 C 0.8060(3) 0.7397(2) 0.60404(19) 0.0421(10) Uani 1 1 d . . . . .
C64 C 0.8411(3) 0.7564(2) 0.56930(19) 0.0422(10) Uani 1 1 d . . . . .
H64A H 0.837987 0.798085 0.557646 0.051 Uiso 1 1 calc R U . . .
C65 C 0.8806(3) 0.7139(2) 0.55110(19) 0.0436(11) Uani 1 1 d . . . . .
H65A H 0.903899 0.726927 0.527224 0.052 Uiso 1 1 calc R U . . .
C66 C 0.7589(3) 0.7853(2) 0.6227(2) 0.0490(12) Uani 1 1 d . . . . .
C67 C 0.6767(3) 0.7668(3) 0.5974(3) 0.0646(16) Uani 1 1 d . . . . .
H67A H 0.669846 0.724046 0.606829 0.097 Uiso 1 1 calc R U . . .
H67B H 0.645653 0.794519 0.609800 0.097 Uiso 1 1 calc R U . . .
H67C H 0.662224 0.770241 0.559545 0.097 Uiso 1 1 calc R U . . .
C68 C 0.7674(3) 0.8517(2) 0.6072(2) 0.0535(13) Uani 1 1 d . . . . .
H68A H 0.753502 0.854372 0.569352 0.080 Uiso 1 1 calc R U . . .
H68B H 0.734837 0.878704 0.618800 0.080 Uiso 1 1 calc R U . . .
H68C H 0.819218 0.864859 0.623584 0.080 Uiso 1 1 calc R U . . .
C69 C 0.7808(4) 0.7823(3) 0.6817(2) 0.0643(16) Uani 1 1 d . . . . .
H69A H 0.775657 0.739672 0.692267 0.096 Uiso 1 1 calc R U . . .
H69B H 0.832598 0.795752 0.697726 0.096 Uiso 1 1 calc R U . . .
H69C H 0.748218 0.809596 0.692942 0.096 Uiso 1 1 calc R U . . .
C70 C 0.6833(3) 0.1351(2) 0.5891(2) 0.0457(11) Uani 1 1 d . . . . .
C71 C 0.6544(3) 0.1608(2) 0.6246(2) 0.0502(12) Uani 1 1 d . . . . .
H71A H 0.668184 0.144068 0.658654 0.060 Uiso 1 1 calc R U . . .
C72 C 0.6045(3) 0.2116(3) 0.6108(3) 0.0620(15) Uani 1 1 d . . . . .
C73 C 0.5819(4) 0.2354(3) 0.5613(3) 0.0683(17) Uani 1 1 d . . . . .
H73A H 0.547674 0.268948 0.551991 0.082 Uiso 1 1 calc R U . . .
C74 C 0.6095(4) 0.2101(3) 0.5256(3) 0.0667(17) Uani 1 1 d . . . . .
C75 C 0.6596(3) 0.1600(2) 0.5393(2) 0.0524(13) Uani 1 1 d . . . . .
H75A H 0.677521 0.142731 0.513894 0.063 Uiso 1 1 calc R U . . .
C76 C 0.5754(4) 0.2382(4) 0.6510(3) 0.084(2) Uani 1 1 d . . . . .
C77 C 0.5845(6) 0.2344(3) 0.4718(3) 0.094(3) Uani 1 1 d . . . . .
C78 C 0.6771(3) 0.0154(2) 0.58433(19) 0.0404(10) Uani 1 1 d . . . . .
C79 C 0.6368(3) -0.0049(2) 0.6151(2) 0.0476(12) Uani 1 1 d . . . . .
H79A H 0.646689 0.012764 0.648578 0.057 Uiso 1 1 calc R U . . .
C80 C 0.5821(3) -0.0508(2) 0.5980(2) 0.0506(12) Uani 1 1 d . . . . .
C81 C 0.5656(3) -0.0772(2) 0.5496(2) 0.0503(12) Uani 1 1 d . . . . .
H81A H 0.528028 -0.107991 0.537908 0.060 Uiso 1 1 calc R U . . .
C82 C 0.6053(3) -0.0575(2) 0.5183(2) 0.0475(12) Uani 1 1 d . . . . .
C83 C 0.6595(3) -0.0120(2) 0.5356(2) 0.0425(11) Uani 1 1 d . . . . .
H83A H 0.685489 0.000933 0.513353 0.051 Uiso 1 1 calc R U . . .
C84 C 0.5428(4) -0.0725(3) 0.6340(3) 0.0707(19) Uani 1 1 d . . . . .
C85 C 0.5893(4) -0.0855(3) 0.4661(2) 0.0622(15) Uani 1 1 d . . . . .
C86 C 0.8003(3) 0.0711(2) 0.57570(18) 0.0392(10) Uani 1 1 d . . . . .
C87 C 0.8307(3) 0.1236(2) 0.56152(18) 0.0445(11) Uani 1 1 d . . . . .
H87A H 0.810152 0.162934 0.564443 0.053 Uiso 1 1 calc R U . . .
C88 C 0.8901(3) 0.1208(2) 0.54321(19) 0.0504(13) Uani 1 1 d . . . . .
C89 C 0.9232(3) 0.0649(3) 0.53874(19) 0.0474(12) Uani 1 1 d . . . . .
H89A H 0.963666 0.062912 0.526058 0.057 Uiso 1 1 calc R U . . .
C90 C 0.8943(3) 0.0119(2) 0.55372(19) 0.0420(11) Uani 1 1 d . . . . .
C91 C 0.8344(3) 0.0150(2) 0.57110(19) 0.0402(10) Uani 1 1 d . . . . .
H91A H 0.815683 -0.022317 0.580290 0.048 Uiso 1 1 calc R U . . .
C92 C 0.9177(4) 0.1787(3) 0.5267(2) 0.0636(16) Uani 1 1 d . . . . .
C93 C 0.9286(3) -0.0497(3) 0.5485(2) 0.0525(13) Uani 1 1 d . . . . .
C94 C 0.7854(3) 0.0693(2) 0.66574(19) 0.0417(10) Uani 1 1 d . . . . .
C95 C 0.8122(3) 0.1228(2) 0.6952(2) 0.0448(11) Uani 1 1 d . . . . .
H95A H 0.799907 0.162040 0.678830 0.054 Uiso 1 1 calc R U . . .
C96 C 0.8560(3) 0.1207(3) 0.7473(2) 0.0521(13) Uani 1 1 d . . . . .
C97 C 0.8770(3) 0.0650(3) 0.7725(2) 0.0546(13) Uani 1 1 d . . . . .
H97A H 0.907029 0.063676 0.808149 0.065 Uiso 1 1 calc R U . . .
C98 C 0.8533(4) 0.0108(3) 0.7445(2) 0.0571(14) Uani 1 1 d . . . . .
C99 C 0.8074(3) 0.0140(2) 0.6921(2) 0.0471(12) Uani 1 1 d . . . . .
H99A H 0.790628 -0.023618 0.673859 0.056 Uiso 1 1 calc R U . . .
C100 C 0.8822(3) 0.1802(3) 0.7761(3) 0.0641(16) Uani 1 1 d . . . . .
C101 C 0.8772(6) -0.0490(3) 0.7698(3) 0.086(2) Uani 1 1 d . . . . .
B1 B 0.7364(3) 0.0728(3) 0.6036(2) 0.0421(12) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C58 2.009(4) 3_766 ?
Pt1 C58 2.009(4) . ?
Pt1 P1 2.2888(10) . ?
Pt1 P1 2.2889(10) 3_766 ?
Ag1 P5 2.4265(11) . ?
Ag1 P3 2.4926(13) . ?
Ag1 P4 2.5359(12) . ?
Ag1 P2 2.5428(12) . ?
P1 C38 1.830(6) . ?
P1 C39 1.831(5) . ?
P1 C37 1.837(4) . ?
P2 C13 1.820(5) . ?
P2 C19 1.834(4) . ?
P2 C37 1.857(4) . ?
P3 C7 1.813(6) . ?
P3 C1 1.834(6) . ?
P3 C38 1.861(5) . ?
P4 C25 1.811(5) . ?
P4 C31 1.838(5) . ?
P4 C39 1.843(5) . ?
P5 C46 1.807(5) . ?
P5 C40 1.810(5) . ?
P5 C52 1.836(5) . ?
F1 C76 1.254(9) . ?
F2 C76 1.302(9) . ?
F3 C76 1.351(9) . ?
F4 C77 1.253(10) . ?
F5 C77 1.251(12) . ?
F6 C77 1.217(12) . ?
F7 C92 1.367(9) . ?
F8 C92 1.231(7) . ?
F9 C92 1.175(7) . ?
F10 C93 1.328(7) . ?
F11 C93 1.326(6) . ?
F12 C93 1.334(7) . ?
F13 C85 1.169(8) . ?
F14 C85 1.299(8) . ?
F15 C85 1.288(9) . ?
F16 C84 1.354(9) . ?
F17 C84 1.250(9) . ?
F18 C84 1.313(7) . ?
F19 C100 1.319(7) . ?
F20 C100 1.352(7) . ?
F21 C100 1.320(8) . ?
F22 C101 1.288(10) . ?
F23 C101 1.346(12) . ?
F24 C101 1.195(9) . ?
C1 C6 1.358(9) . ?
C1 C2 1.407(9) . ?
C2 C3 1.400(10) . ?
C2 H2A 0.9500 . ?
C3 C4 1.294(11) . ?
C3 H3A 0.9500 . ?
C4 C5 1.308(12) . ?
C4 H4A 0.9500 . ?
C5 C6 1.379(10) . ?
C5 H5A 0.9500 . ?
C6 H6A 0.9500 . ?
C7 C8 1.351(10) . ?
C7 C12 1.375(9) . ?
C8 C9 1.394(12) . ?
C8 H8A 0.9500 . ?
C9 C10 1.344(14) . ?
C9 H9A 0.9500 . ?
C10 C11 1.365(11) . ?
C10 H10A 0.9500 . ?
C11 C12 1.389(9) . ?
C11 H11A 0.9500 . ?
C12 H12A 0.9500 . ?
C13 C18 1.392(7) . ?
C13 C14 1.396(7) . ?
C14 C15 1.366(9) . ?
C14 H14A 0.9500 . ?
C15 C16 1.402(10) . ?
C15 H15A 0.9500 . ?
C16 C17 1.378(10) . ?
C16 H16A 0.9500 . ?
C17 C18 1.373(8) . ?
C17 H17A 0.9500 . ?
C18 H18A 0.9500 . ?
C19 C20 1.392(7) . ?
C19 C24 1.392(6) . ?
C20 C21 1.388(7) . ?
C20 H20A 0.9500 . ?
C21 C22 1.370(9) . ?
C21 H21A 0.9500 . ?
C22 C23 1.390(9) . ?
C22 H22A 0.9500 . ?
C23 C24 1.379(7) . ?
C23 H23A 0.9500 . ?
C24 H24A 0.9500 . ?
C25 C26 1.398(6) . ?
C25 C30 1.405(7) . ?
C26 C27 1.378(7) . ?
C26 H26A 0.9500 . ?
C27 C28 1.379(8) . ?
C27 H27A 0.9500 . ?
C28 C29 1.383(8) . ?
C28 H28A 0.9500 . ?
C29 C30 1.377(8) . ?
C29 H29A 0.9500 . ?
C30 H30A 0.9500 . ?
C31 C32 1.360(8) . ?
C31 C36 1.398(7) . ?
C32 C33 1.388(10) . ?
C32 H32A 0.9500 . ?
C33 C34 1.364(10) . ?
C33 H33A 0.9500 . ?
C34 C35 1.329(10) . ?
C34 H34A 0.9500 . ?
C35 C36 1.379(8) . ?
C35 H35A 0.9500 . ?
C36 H36A 0.9500 . ?
C37 H37A 0.9900 . ?
C37 H37B 0.9900 . ?
C38 H38A 0.9900 . ?
C38 H38B 0.9900 . ?
C39 H39A 0.9900 . ?
C39 H39B 0.9900 . ?
C40 C45 1.383(7) . ?
C40 C41 1.385(8) . ?
C41 C42 1.410(8) . ?
C41 H41A 0.9500 . ?
C42 C43 1.360(10) . ?
C42 H42A 0.9500 . ?
C43 C44 1.337(9) . ?
C43 H43A 0.9500 . ?
C44 C45 1.392(8) . ?
C44 H44A 0.9500 . ?
C45 H45A 0.9500 . ?
C46 C51 1.392(7) . ?
C46 C47 1.405(7) . ?
C47 C48 1.410(8) . ?
C47 H47A 0.9500 . ?
C48 C49 1.395(9) . ?
C48 H48A 0.9500 . ?
C49 C50 1.387(9) . ?
C49 H49A 0.9500 . ?
C50 C51 1.388(8) . ?
C50 H50A 0.9500 . ?
C51 H51A 0.9500 . ?
C52 C53 1.386(7) . ?
C52 C57 1.396(7) . ?
C53 C54 1.392(7) . ?
C53 H53A 0.9500 . ?
C54 C55 1.378(8) . ?
C54 H54A 0.9500 . ?
C55 C56 1.389(8) . ?
C55 H55A 0.9500 . ?
C56 C57 1.386(7) . ?
C56 H56A 0.9500 . ?
C57 H57A 0.9500 . ?
C58 C59 1.187(6) . ?
C59 C60 1.448(6) . ?
C60 C61 1.383(8) . ?
C60 C65 1.395(7) . ?
C61 C62 1.391(7) . ?
C61 H61A 0.9500 . ?
C62 C63 1.379(7) . ?
C62 H62A 0.9500 . ?
C63 C64 1.384(7) . ?
C63 C66 1.531(7) . ?
C64 C65 1.384(6) . ?
C64 H64A 0.9500 . ?
C65 H65A 0.9500 . ?
C66 C68 1.519(7) . ?
C66 C69 1.525(8) . ?
C66 C67 1.537(8) . ?
C67 H67A 0.9800 . ?
C67 H67B 0.9800 . ?
C67 H67C 0.9800 . ?
C68 H68A 0.9800 . ?
C68 H68B 0.9800 . ?
C68 H68C 0.9800 . ?
C69 H69A 0.9800 . ?
C69 H69B 0.9800 . ?
C69 H69C 0.9800 . ?
C70 C71 1.384(7) . ?
C70 C75 1.389(7) . ?
C70 B1 1.650(7) . ?
C71 C72 1.418(7) . ?
C71 H71A 0.9500 . ?
C72 C73 1.372(9) . ?
C72 C76 1.506(9) . ?
C73 C74 1.371(10) . ?
C73 H73A 0.9500 . ?
C74 C75 1.409(8) . ?
C74 C77 1.481(10) . ?
C75 H75A 0.9500 . ?
C78 C83 1.390(7) . ?
C78 C79 1.391(7) . ?
C78 B1 1.639(8) . ?
C79 C80 1.400(8) . ?
C79 H79A 0.9500 . ?
C80 C81 1.375(8) . ?
C80 C84 1.503(8) . ?
C81 C82 1.391(7) . ?
C81 H81A 0.9500 . ?
C82 C83 1.387(7) . ?
C82 C85 1.483(8) . ?
C83 H83A 0.9500 . ?
C86 C87 1.388(6) . ?
C86 C91 1.402(7) . ?
C86 B1 1.645(7) . ?
C87 C88 1.389(7) . ?
C87 H87A 0.9500 . ?
C88 C89 1.387(8) . ?
C88 C92 1.484(7) . ?
C89 C90 1.391(7) . ?
C89 H89A 0.9500 . ?
C90 C91 1.381(7) . ?
C90 C93 1.512(7) . ?
C91 H91A 0.9500 . ?
C94 C99 1.385(7) . ?
C94 C95 1.402(7) . ?
C94 B1 1.640(8) . ?
C95 C96 1.387(8) . ?
C95 H95A 0.9500 . ?
C96 C97 1.375(8) . ?
C96 C100 1.502(8) . ?
C97 C98 1.388(8) . ?
C97 H97A 0.9500 . ?
C98 C99 1.404(8) . ?
C98 C101 1.464(9) . ?
C99 H99A 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C58 Pt1 C58 180.0 3_766 . ?
C58 Pt1 P1 94.78(12) 3_766 . ?
C58 Pt1 P1 85.22(12) . . ?
C58 Pt1 P1 85.22(12) 3_766 3_766 ?
C58 Pt1 P1 94.78(12) . 3_766 ?
P1 Pt1 P1 180.0 . 3_766 ?
P5 Ag1 P3 127.17(4) . . ?
P5 Ag1 P4 118.18(4) . . ?
P3 Ag1 P4 91.06(4) . . ?
P5 Ag1 P2 125.00(4) . . ?
P3 Ag1 P2 88.97(4) . . ?
P4 Ag1 P2 97.73(4) . . ?
C38 P1 C39 111.5(2) . . ?
C38 P1 C37 104.9(2) . . ?
C39 P1 C37 106.1(2) . . ?
C38 P1 Pt1 106.93(16) . . ?
C39 P1 Pt1 113.29(15) . . ?
C37 P1 Pt1 113.85(14) . . ?
C13 P2 C19 104.6(2) . . ?
C13 P2 C37 102.2(2) . . ?
C19 P2 C37 102.5(2) . . ?
C13 P2 Ag1 117.29(16) . . ?
C19 P2 Ag1 117.82(15) . . ?
C37 P2 Ag1 110.43(15) . . ?
C7 P3 C1 105.3(3) . . ?
C7 P3 C38 101.7(3) . . ?
C1 P3 C38 104.5(2) . . ?
C7 P3 Ag1 119.0(2) . . ?
C1 P3 Ag1 116.95(18) . . ?
C38 P3 Ag1 107.42(18) . . ?
C25 P4 C31 103.5(2) . . ?
C25 P4 C39 101.2(2) . . ?
C31 P4 C39 103.4(2) . . ?
C25 P4 Ag1 122.46(15) . . ?
C31 P4 Ag1 120.95(18) . . ?
C39 P4 Ag1 101.76(14) . . ?
C46 P5 C40 104.7(2) . . ?
C46 P5 C52 106.0(2) . . ?
C40 P5 C52 105.1(2) . . ?
C46 P5 Ag1 113.15(16) . . ?
C40 P5 Ag1 116.62(16) . . ?
C52 P5 Ag1 110.39(15) . . ?
C6 C1 C2 113.8(6) . . ?
C6 C1 P3 126.4(5) . . ?
C2 C1 P3 119.2(5) . . ?
C3 C2 C1 121.1(7) . . ?
C3 C2 H2A 119.5 . . ?
C1 C2 H2A 119.5 . . ?
C4 C3 C2 120.6(8) . . ?
C4 C3 H3A 119.7 . . ?
C2 C3 H3A 119.7 . . ?
C3 C4 C5 119.5(8) . . ?
C3 C4 H4A 120.3 . . ?
C5 C4 H4A 120.3 . . ?
C4 C5 C6 122.6(9) . . ?
C4 C5 H5A 118.7 . . ?
C6 C5 H5A 118.7 . . ?
C1 C6 C5 121.2(7) . . ?
C1 C6 H6A 119.4 . . ?
C5 C6 H6A 119.4 . . ?
C8 C7 C12 120.3(6) . . ?
C8 C7 P3 122.2(6) . . ?
C12 C7 P3 117.5(4) . . ?
C7 C8 C9 119.3(8) . . ?
C7 C8 H8A 120.3 . . ?
C9 C8 H8A 120.3 . . ?
C10 C9 C8 119.9(9) . . ?
C10 C9 H9A 120.0 . . ?
C8 C9 H9A 120.0 . . ?
C9 C10 C11 121.8(8) . . ?
C9 C10 H10A 119.1 . . ?
C11 C10 H10A 119.1 . . ?
C10 C11 C12 118.1(7) . . ?
C10 C11 H11A 121.0 . . ?
C12 C11 H11A 121.0 . . ?
C7 C12 C11 120.4(6) . . ?
C7 C12 H12A 119.8 . . ?
C11 C12 H12A 119.8 . . ?
C18 C13 C14 118.3(5) . . ?
C18 C13 P2 118.4(4) . . ?
C14 C13 P2 123.3(4) . . ?
C15 C14 C13 121.0(6) . . ?
C15 C14 H14A 119.5 . . ?
C13 C14 H14A 119.5 . . ?
C14 C15 C16 119.6(6) . . ?
C14 C15 H15A 120.2 . . ?
C16 C15 H15A 120.2 . . ?
C17 C16 C15 120.3(6) . . ?
C17 C16 H16A 119.9 . . ?
C15 C16 H16A 119.9 . . ?
C18 C17 C16 119.4(6) . . ?
C18 C17 H17A 120.3 . . ?
C16 C17 H17A 120.3 . . ?
C17 C18 C13 121.4(6) . . ?
C17 C18 H18A 119.3 . . ?
C13 C18 H18A 119.3 . . ?
C20 C19 C24 118.4(4) . . ?
C20 C19 P2 124.2(3) . . ?
C24 C19 P2 117.4(4) . . ?
C21 C20 C19 120.8(5) . . ?
C21 C20 H20A 119.6 . . ?
C19 C20 H20A 119.6 . . ?
C22 C21 C20 119.7(5) . . ?
C22 C21 H21A 120.2 . . ?
C20 C21 H21A 120.2 . . ?
C21 C22 C23 120.4(5) . . ?
C21 C22 H22A 119.8 . . ?
C23 C22 H22A 119.8 . . ?
C24 C23 C22 119.8(5) . . ?
C24 C23 H23A 120.1 . . ?
C22 C23 H23A 120.1 . . ?
C23 C24 C19 120.8(5) . . ?
C23 C24 H24A 119.6 . . ?
C19 C24 H24A 119.6 . . ?
C26 C25 C30 118.2(4) . . ?
C26 C25 P4 119.1(3) . . ?
C30 C25 P4 122.6(4) . . ?
C27 C26 C25 121.3(4) . . ?
C27 C26 H26A 119.4 . . ?
C25 C26 H26A 119.4 . . ?
C26 C27 C28 119.6(5) . . ?
C26 C27 H27A 120.2 . . ?
C28 C27 H27A 120.2 . . ?
C27 C28 C29 120.3(5) . . ?
C27 C28 H28A 119.9 . . ?
C29 C28 H28A 119.9 . . ?
C30 C29 C28 120.5(5) . . ?
C30 C29 H29A 119.7 . . ?
C28 C29 H29A 119.7 . . ?
C29 C30 C25 120.1(5) . . ?
C29 C30 H30A 119.9 . . ?
C25 C30 H30A 119.9 . . ?
C32 C31 C36 119.2(5) . . ?
C32 C31 P4 117.9(4) . . ?
C36 C31 P4 122.9(4) . . ?
C31 C32 C33 119.7(6) . . ?
C31 C32 H32A 120.2 . . ?
C33 C32 H32A 120.2 . . ?
C34 C33 C32 120.1(7) . . ?
C34 C33 H33A 120.0 . . ?
C32 C33 H33A 120.0 . . ?
C35 C34 C33 120.8(7) . . ?
C35 C34 H34A 119.6 . . ?
C33 C34 H34A 119.6 . . ?
C34 C35 C36 120.6(6) . . ?
C34 C35 H35A 119.7 . . ?
C36 C35 H35A 119.7 . . ?
C35 C36 C31 119.5(6) . . ?
C35 C36 H36A 120.3 . . ?
C31 C36 H36A 120.3 . . ?
P1 C37 P2 116.7(2) . . ?
P1 C37 H37A 108.1 . . ?
P2 C37 H37A 108.1 . . ?
P1 C37 H37B 108.1 . . ?
P2 C37 H37B 108.1 . . ?
H37A C37 H37B 107.3 . . ?
P1 C38 P3 120.7(3) . . ?
P1 C38 H38A 107.2 . . ?
P3 C38 H38A 107.2 . . ?
P1 C38 H38B 107.2 . . ?
P3 C38 H38B 107.2 . . ?
H38A C38 H38B 106.8 . . ?
P1 C39 P4 118.7(3) . . ?
P1 C39 H39A 107.6 . . ?
P4 C39 H39A 107.6 . . ?
P1 C39 H39B 107.6 . . ?
P4 C39 H39B 107.6 . . ?
H39A C39 H39B 107.1 . . ?
C45 C40 C41 118.9(5) . . ?
C45 C40 P5 122.9(4) . . ?
C41 C40 P5 118.1(4) . . ?
C40 C41 C42 119.9(6) . . ?
C40 C41 H41A 120.1 . . ?
C42 C41 H41A 120.1 . . ?
C43 C42 C41 119.0(6) . . ?
C43 C42 H42A 120.5 . . ?
C41 C42 H42A 120.5 . . ?
C44 C43 C42 121.8(6) . . ?
C44 C43 H43A 119.1 . . ?
C42 C43 H43A 119.1 . . ?
C43 C44 C45 120.3(6) . . ?
C43 C44 H44A 119.9 . . ?
C45 C44 H44A 119.9 . . ?
C40 C45 C44 120.0(6) . . ?
C40 C45 H45A 120.0 . . ?
C44 C45 H45A 120.0 . . ?
C51 C46 C47 118.8(5) . . ?
C51 C46 P5 124.9(4) . . ?
C47 C46 P5 116.2(4) . . ?
C46 C47 C48 120.7(5) . . ?
C46 C47 H47A 119.6 . . ?
C48 C47 H47A 119.6 . . ?
C49 C48 C47 119.0(6) . . ?
C49 C48 H48A 120.5 . . ?
C47 C48 H48A 120.5 . . ?
C50 C49 C48 120.1(5) . . ?
C50 C49 H49A 120.0 . . ?
C48 C49 H49A 120.0 . . ?
C49 C50 C51 120.7(6) . . ?
C49 C50 H50A 119.6 . . ?
C51 C50 H50A 119.6 . . ?
C50 C51 C46 120.6(6) . . ?
C50 C51 H51A 119.7 . . ?
C46 C51 H51A 119.7 . . ?
C53 C52 C57 118.6(4) . . ?
C53 C52 P5 122.5(4) . . ?
C57 C52 P5 118.4(4) . . ?
C52 C53 C54 120.1(5) . . ?
C52 C53 H53A 119.9 . . ?
C54 C53 H53A 119.9 . . ?
C55 C54 C53 120.8(5) . . ?
C55 C54 H54A 119.6 . . ?
C53 C54 H54A 119.6 . . ?
C54 C55 C56 119.8(5) . . ?
C54 C55 H55A 120.1 . . ?
C56 C55 H55A 120.1 . . ?
C57 C56 C55 119.3(5) . . ?
C57 C56 H56A 120.3 . . ?
C55 C56 H56A 120.3 . . ?
C56 C57 C52 121.4(5) . . ?
C56 C57 H57A 119.3 . . ?
C52 C57 H57A 119.3 . . ?
C59 C58 Pt1 177.8(5) . . ?
C58 C59 C60 178.2(6) . . ?
C61 C60 C65 117.0(4) . . ?
C61 C60 C59 120.7(5) . . ?
C65 C60 C59 122.3(5) . . ?
C60 C61 C62 121.3(5) . . ?
C60 C61 H61A 119.4 . . ?
C62 C61 H61A 119.4 . . ?
C63 C62 C61 121.8(5) . . ?
C63 C62 H62A 119.1 . . ?
C61 C62 H62A 119.1 . . ?
C62 C63 C64 117.0(4) . . ?
C62 C63 C66 120.4(5) . . ?
C64 C63 C66 122.5(4) . . ?
C63 C64 C65 121.7(4) . . ?
C63 C64 H64A 119.2 . . ?
C65 C64 H64A 119.2 . . ?
C64 C65 C60 121.2(5) . . ?
C64 C65 H65A 119.4 . . ?
C60 C65 H65A 119.4 . . ?
C68 C66 C69 108.5(5) . . ?
C68 C66 C63 112.6(4) . . ?
C69 C66 C63 110.2(4) . . ?
C68 C66 C67 107.9(5) . . ?
C69 C66 C67 109.6(5) . . ?
C63 C66 C67 108.1(4) . . ?
C66 C67 H67A 109.5 . . ?
C66 C67 H67B 109.5 . . ?
H67A C67 H67B 109.5 . . ?
C66 C67 H67C 109.5 . . ?
H67A C67 H67C 109.5 . . ?
H67B C67 H67C 109.5 . . ?
C66 C68 H68A 109.5 . . ?
C66 C68 H68B 109.5 . . ?
H68A C68 H68B 109.5 . . ?
C66 C68 H68C 109.5 . . ?
H68A C68 H68C 109.5 . . ?
H68B C68 H68C 109.5 . . ?
C66 C69 H69A 109.5 . . ?
C66 C69 H69B 109.5 . . ?
H69A C69 H69B 109.5 . . ?
C66 C69 H69C 109.5 . . ?
H69A C69 H69C 109.5 . . ?
H69B C69 H69C 109.5 . . ?
C71 C70 C75 117.2(5) . . ?
C71 C70 B1 121.2(5) . . ?
C75 C70 B1 121.3(4) . . ?
C70 C71 C72 121.1(5) . . ?
C70 C71 H71A 119.5 . . ?
C72 C71 H71A 119.5 . . ?
C73 C72 C71 120.7(6) . . ?
C73 C72 C76 120.4(6) . . ?
C71 C72 C76 118.9(6) . . ?
C74 C73 C72 119.0(6) . . ?
C74 C73 H73A 120.5 . . ?
C72 C73 H73A 120.5 . . ?
C73 C74 C75 120.5(6) . . ?
C73 C74 C77 119.7(7) . . ?
C75 C74 C77 119.8(7) . . ?
C70 C75 C74 121.6(5) . . ?
C70 C75 H75A 119.2 . . ?
C74 C75 H75A 119.2 . . ?
F1 C76 F2 111.6(7) . . ?
F1 C76 F3 105.0(6) . . ?
F2 C76 F3 98.1(8) . . ?
F1 C76 C72 114.0(8) . . ?
F2 C76 C72 114.7(5) . . ?
F3 C76 C72 112.0(6) . . ?
F6 C77 F5 105.1(13) . . ?
F6 C77 F4 97.8(12) . . ?
F5 C77 F4 106.9(8) . . ?
F6 C77 C74 115.3(7) . . ?
F5 C77 C74 114.6(8) . . ?
F4 C77 C74 115.3(9) . . ?
C83 C78 C79 116.2(5) . . ?
C83 C78 B1 123.0(4) . . ?
C79 C78 B1 120.5(4) . . ?
C78 C79 C80 121.7(5) . . ?
C78 C79 H79A 119.2 . . ?
C80 C79 H79A 119.2 . . ?
C81 C80 C79 121.1(5) . . ?
C81 C80 C84 120.0(5) . . ?
C79 C80 C84 118.9(5) . . ?
C80 C81 C82 118.1(5) . . ?
C80 C81 H81A 121.0 . . ?
C82 C81 H81A 121.0 . . ?
C83 C82 C81 120.4(5) . . ?
C83 C82 C85 120.2(5) . . ?
C81 C82 C85 119.4(5) . . ?
C82 C83 C78 122.5(5) . . ?
C82 C83 H83A 118.7 . . ?
C78 C83 H83A 118.7 . . ?
F17 C84 F18 111.0(7) . . ?
F17 C84 F16 107.6(6) . . ?
F18 C84 F16 100.7(6) . . ?
F17 C84 C80 113.6(5) . . ?
F18 C84 C80 112.5(5) . . ?
F16 C84 C80 110.6(6) . . ?
F13 C85 F15 109.9(8) . . ?
F13 C85 F14 102.7(8) . . ?
F15 C85 F14 95.2(7) . . ?
F13 C85 C82 117.4(6) . . ?
F15 C85 C82 114.2(6) . . ?
F14 C85 C82 114.7(5) . . ?
C87 C86 C91 115.4(4) . . ?
C87 C86 B1 124.0(4) . . ?
C91 C86 B1 120.1(4) . . ?
C86 C87 C88 122.5(5) . . ?
C86 C87 H87A 118.8 . . ?
C88 C87 H87A 118.8 . . ?
C89 C88 C87 121.4(4) . . ?
C89 C88 C92 119.1(5) . . ?
C87 C88 C92 119.4(5) . . ?
C88 C89 C90 116.9(5) . . ?
C88 C89 H89A 121.6 . . ?
C90 C89 H89A 121.6 . . ?
C91 C90 C89 121.3(5) . . ?
C91 C90 C93 120.7(4) . . ?
C89 C90 C93 117.9(5) . . ?
C90 C91 C86 122.5(4) . . ?
C90 C91 H91A 118.8 . . ?
C86 C91 H91A 118.8 . . ?
F9 C92 F8 114.0(8) . . ?
F9 C92 F7 100.6(8) . . ?
F8 C92 F7 93.6(7) . . ?
F9 C92 C88 118.4(5) . . ?
F8 C92 C88 115.2(5) . . ?
F7 C92 C88 110.6(6) . . ?
F11 C93 F10 105.6(4) . . ?
F11 C93 F12 106.3(5) . . ?
F10 C93 F12 107.6(5) . . ?
F11 C93 C90 113.3(4) . . ?
F10 C93 C90 111.2(5) . . ?
F12 C93 C90 112.4(4) . . ?
C99 C94 C95 115.1(5) . . ?
C99 C94 B1 123.0(4) . . ?
C95 C94 B1 121.8(5) . . ?
C96 C95 C94 122.6(5) . . ?
C96 C95 H95A 118.7 . . ?
C94 C95 H95A 118.7 . . ?
C97 C96 C95 120.9(5) . . ?
C97 C96 C100 119.8(5) . . ?
C95 C96 C100 119.2(5) . . ?
C96 C97 C98 118.5(5) . . ?
C96 C97 H97A 120.8 . . ?
C98 C97 H97A 120.8 . . ?
C97 C98 C99 119.7(5) . . ?
C97 C98 C101 119.5(6) . . ?
C99 C98 C101 120.9(6) . . ?
C94 C99 C98 123.2(5) . . ?
C94 C99 H99A 118.4 . . ?
C98 C99 H99A 118.4 . . ?
F19 C100 F21 106.0(5) . . ?
F19 C100 F20 104.5(6) . . ?
F21 C100 F20 107.7(5) . . ?
F19 C100 C96 113.1(5) . . ?
F21 C100 C96 112.1(6) . . ?
F20 C100 C96 112.8(5) . . ?
F24 C101 F22 115.0(10) . . ?
F24 C101 F23 102.0(9) . . ?
F22 C101 F23 92.0(8) . . ?
F24 C101 C98 117.4(7) . . ?
F22 C101 C98 114.8(6) . . ?
F23 C101 C98 111.6(8) . . ?
C78 B1 C94 112.8(4) . . ?
C78 B1 C86 112.1(4) . . ?
C94 B1 C86 103.2(4) . . ?
C78 B1 C70 103.7(4) . . ?
C94 B1 C70 111.9(4) . . ?
C86 B1 C70 113.5(4) . . ?

_refine_diff_density_max         2.395
_refine_diff_density_min         -1.006
_refine_diff_density_rms         0.182

