# Electronic Supplementary Material (ESI) for CrystEngComm.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_SAVE_a
_audit_block_doi                 10.5517/ccdc.csd.cc2024js
_database_code_depnum_ccdc_archive 'CCDC 1849104'
_audit_update_record             
;
2018-06-13 deposited with the CCDC.	2019-04-26 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          N/A
_chemical_formula_moiety         ?
_chemical_formula_sum            'C26 Eu2 N2 O18'
_chemical_formula_weight         932.20

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.1075(8)
_cell_length_b                   11.8822(11)
_cell_length_c                   15.5502(14)
_cell_angle_alpha                80.532(3)
_cell_angle_beta                 74.179(3)
_cell_angle_gamma                74.763(3)
_cell_volume                     1554.3(2)
_cell_formula_units_Z            2
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    7212
_cell_measurement_theta_min      2.138
_cell_measurement_theta_max      27.630

_exptl_crystal_description       bulk
_exptl_crystal_colour            'light yellow'
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.992
_exptl_crystal_F_000             880
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_absorpt_coefficient_mu    4.082
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'BRUKER apex II'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            72714
_diffrn_reflns_av_unetI/netI     0.0327
_diffrn_reflns_av_R_equivalents  0.0977
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_theta_min         2.138
_diffrn_reflns_theta_max         27.630
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             7212
_reflns_number_gt                6711
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0527P)²+3.8550P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   .
_refine_ls_hydrogen_treatment    undef
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         7212
_refine_ls_number_parameters     433
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0353
_refine_ls_R_factor_gt           0.0305
_refine_ls_wR_factor_ref         0.1001
_refine_ls_wR_factor_gt          0.0882
_refine_ls_goodness_of_fit_ref   1.196
_refine_ls_restrained_S_all      1.196
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu2 Eu 0.80651(2) 0.93305(2) 0.01262(2) 0.01163(7) Uani 1 1 d . . . . .
Eu1 Eu 0.71231(2) 0.54792(2) 0.47227(2) 0.01259(7) Uani 1 1 d . . . . .
O17 O 1.0967(3) 0.6586(3) 0.2213(2) 0.0173(6) Uani 1 1 d . . . . .
O16 O 0.4331(3) 0.8383(3) 0.26843(19) 0.0167(6) Uani 1 1 d . . . . .
O15 O 0.2132(4) 0.7434(3) 0.75216(19) 0.0208(6) Uani 1 1 d . . . . .
O14 O 1.0029(4) 0.8057(3) 0.0807(2) 0.0230(7) Uani 1 1 d . . . . .
O13 O 0.3546(4) 1.0484(3) 0.0864(2) 0.0205(6) Uani 1 1 d . . . . .
O12 O 0.5356(4) 0.6604(3) 0.3860(2) 0.0246(7) Uani 1 1 d . . . . .
O11 O -0.0230(4) 0.8347(3) 0.8819(2) 0.0313(8) Uani 1 1 d . . . . .
O10 O 1.1773(4) 0.4573(3) 0.4075(2) 0.0256(7) Uani 1 1 d . . . . .
O9 O 0.5805(4) 0.9654(3) 0.1255(2) 0.0230(7) Uani 1 1 d . . . . .
O8 O 0.2888(4) 0.6432(3) 0.4504(2) 0.0205(6) Uani 1 1 d . . . . .
O7 O 0.1008(4) 0.9575(3) 0.9051(2) 0.0273(7) Uani 1 1 d . . . . .
O6 O 1.2235(4) 0.8703(3) 0.0522(2) 0.0239(7) Uani 1 1 d . . . . .
O5 O 0.2294(4) 0.5855(3) 0.6433(2) 0.0297(7) Uani 1 1 d . . . . .
O4 O 0.4789(4) 0.5823(3) 0.5803(2) 0.0272(7) Uani 1 1 d . . . . .
O3 O 0.9518(4) 0.5580(4) 0.3765(2) 0.0336(9) Uani 1 1 d . . . . .
O2 O 0.7423(5) 0.7496(3) 0.0399(3) 0.0314(8) Uani 1 1 d . . . . .
C26 C 0.1919(5) 0.9382(4) 0.2602(3) 0.0210(9) Uani 1 1 d . . . . .
C25 C 0.3276(5) 0.7943(4) 0.3375(3) 0.0159(8) Uani 1 1 d . . . . .
C24 C 1.2006(5) 0.7069(4) 0.1541(3) 0.0147(8) Uani 1 1 d . . . . .
C23 C 0.3473(5) 0.9255(4) 0.2211(3) 0.0150(8) Uani 1 1 d . . . . .
C22 C 1.1360(5) 0.8020(3) 0.0908(3) 0.0154(8) Uani 1 1 d . . . . .
C21 C 1.3385(5) 0.5740(4) 0.2373(3) 0.0210(9) Uani 1 1 d . . . . .
C20 C 1.3498(5) 0.6573(4) 0.1611(3) 0.0207(9) Uani 1 1 d . . . . .
C19 C 0.1787(5) 0.8526(4) 0.3354(3) 0.0229(9) Uani 1 1 d . . . . .
C18 C 0.2390(5) 0.8148(4) 0.8038(3) 0.0208(8) Uani 1 1 d . . . . .
C17 C 1.1839(5) 0.5788(4) 0.2722(3) 0.0158(8) Uani 1 1 d . . . . .
C16 C 0.4329(5) 0.9833(4) 0.1378(3) 0.0154(8) Uani 1 1 d . . . . .
C15 C 0.3898(5) 0.6914(4) 0.3962(3) 0.0161(8) Uani 1 1 d . . . . .
O1 O 0.7137(5) 0.7470(3) 0.4765(3) 0.0394(10) Uani 1 1 d . . . . .
C14 C 0.3539(5) 0.6960(4) 0.7004(3) 0.0220(9) Uani 1 1 d . . . . .
N2 N 0.7422(10) 0.9277(5) 0.4732(4) 0.0608(18) Uani 1 1 d . . . . .
C13 C 1.0977(5) 0.5267(4) 0.3581(3) 0.0172(8) Uani 1 1 d . . . . .
C12 C 0.3952(6) 0.8107(4) 0.7862(4) 0.0296(10) Uani 1 1 d . . . . .
C11 C 0.7359(7) 0.8419(4) 0.4307(4) 0.0331(12) Uani 1 1 d . . . . .
N1 N 0.7605(10) 0.5632(5) 0.0302(6) 0.081(3) Uani 1 1 d . . . . .
C10 C 0.0978(5) 0.8734(4) 0.8676(3) 0.0190(8) Uani 1 1 d . . . . .
C9 C 0.4710(6) 0.7333(4) 0.7187(4) 0.0306(10) Uani 1 1 d . . . . .
C8 C 0.7622(7) 0.6450(6) 0.0702(5) 0.0501(17) Uani 1 1 d . . . . .
C7 C 0.3545(5) 0.6161(4) 0.6368(3) 0.0198(9) Uani 1 1 d . . . . .
C6 C 0.7772(15) 0.4393(6) 0.0549(7) 0.087(3) Uani 1 1 d . . . . .
C5 C 0.7555(9) 0.8576(6) 0.3316(5) 0.0477(16) Uani 1 1 d . . . . .
C4 C 0.7944(12) 0.6024(9) 0.1620(5) 0.081(3) Uani 1 1 d . . . . .
C3 C 0.7590(14) 1.0446(6) 0.4293(6) 0.077(3) Uani 1 1 d . . . . .
C2 C 0.710(2) 0.6147(12) -0.0650(6) 0.118(5) Uani 1 1 d . . . . .
C1 C 0.733(2) 0.9065(11) 0.5714(6) 0.138(7) Uani 1 1 d . . . . .
O18 O -0.1026(9) 0.7160(8) 0.7379(5) 0.111(3) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu2 O9 2.303(3) . ?
Eu2 O2 2.346(3) . ?
Eu2 O13 2.350(3) 2_675 ?
Eu2 O6 2.365(3) 2_775 ?
Eu2 O14 2.386(3) . ?
Eu2 O7 2.398(3) 2_676 ?
Eu2 O11 2.453(3) 1_654 ?
Eu2 O7 2.806(4) 1_654 ?
Eu2 C10 2.984(4) 1_654 ?
Eu2 Eu2 4.1346(5) 2_775 ?
Eu1 O3 2.301(3) . ?
Eu1 O4 2.308(3) . ?
Eu1 O10 2.337(3) 2_766 ?
Eu1 O12 2.374(3) . ?
Eu1 O1 2.380(3) . ?
Eu1 O8 2.390(3) 2_666 ?
Eu1 O5 2.450(3) 2_666 ?
Eu1 O4 2.950(4) 2_666 ?
Eu1 C7 3.053(4) 2_666 ?
Eu1 Eu1 4.1436(5) 2_666 ?
O17 C17 1.362(5) . ?
O17 C24 1.366(5) . ?
O16 C23 1.365(5) . ?
O16 C25 1.366(5) . ?
O15 C14 1.347(5) . ?
O15 C18 1.360(5) . ?
O14 C22 1.252(5) . ?
O13 C16 1.250(5) . ?
O13 Eu2 2.350(3) 2_675 ?
O12 C15 1.253(5) . ?
O11 C10 1.253(6) . ?
O11 Eu2 2.453(3) 1_456 ?
O10 C13 1.256(5) . ?
O10 Eu1 2.337(3) 2_766 ?
O9 C16 1.269(5) . ?
O8 C15 1.256(5) . ?
O8 Eu1 2.390(3) 2_666 ?
O7 C10 1.248(5) . ?
O7 Eu2 2.398(3) 2_676 ?
O7 Eu2 2.806(4) 1_456 ?
O6 C22 1.254(5) . ?
O6 Eu2 2.364(3) 2_775 ?
O5 C7 1.258(6) . ?
O5 Eu1 2.450(3) 2_666 ?
O4 C7 1.245(5) . ?
O4 Eu1 2.950(4) 2_666 ?
O3 C13 1.247(6) . ?
O2 C8 1.240(7) . ?
C26 C23 1.358(6) . ?
C26 C19 1.419(6) . ?
C25 C19 1.358(6) . ?
C25 C15 1.483(6) . ?
C24 C20 1.358(6) . ?
C24 C22 1.481(5) . ?
C23 C16 1.481(6) . ?
C21 C17 1.354(6) . ?
C21 C20 1.413(6) . ?
C18 C12 1.363(7) . ?
C18 C10 1.478(6) . ?
C17 C13 1.481(5) . ?
O1 C11 1.263(6) . ?
C14 C9 1.368(7) . ?
C14 C7 1.477(6) . ?
N2 C11 1.323(8) . ?
N2 C3 1.471(8) . ?
N2 C1 1.489(10) . ?
C12 C9 1.418(7) . ?
C11 C5 1.489(9) . ?
N1 C8 1.243(10) . ?
N1 C6 1.437(9) . ?
N1 C2 1.642(14) . ?
C10 Eu2 2.984(4) 1_456 ?
C8 C4 1.515(10) . ?
C7 Eu1 3.052(4) 2_666 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O9 Eu2 O2 78.12(13) . . ?
O9 Eu2 O13 87.21(11) . 2_675 ?
O2 Eu2 O13 77.71(11) . 2_675 ?
O9 Eu2 O6 95.84(12) . 2_775 ?
O2 Eu2 O6 152.29(12) . 2_775 ?
O13 Eu2 O6 74.98(11) 2_675 2_775 ?
O9 Eu2 O14 106.00(12) . . ?
O2 Eu2 O14 74.87(11) . . ?
O13 Eu2 O14 146.11(11) 2_675 . ?
O6 Eu2 O14 132.28(11) 2_775 . ?
O9 Eu2 O7 84.48(12) . 2_676 ?
O2 Eu2 O7 134.47(12) . 2_676 ?
O13 Eu2 O7 143.38(11) 2_675 2_676 ?
O6 Eu2 O7 70.50(11) 2_775 2_676 ?
O14 Eu2 O7 70.08(11) . 2_676 ?
O9 Eu2 O11 152.42(12) . 1_654 ?
O2 Eu2 O11 77.78(13) . 1_654 ?
O13 Eu2 O11 74.72(11) 2_675 1_654 ?
O6 Eu2 O11 99.26(12) 2_775 1_654 ?
O14 Eu2 O11 80.30(12) . 1_654 ?
O7 Eu2 O11 122.33(12) 2_676 1_654 ?
O9 Eu2 O7 158.93(11) . 1_654 ?
O2 Eu2 O7 120.05(12) . 1_654 ?
O13 Eu2 O7 106.22(10) 2_675 1_654 ?
O6 Eu2 O7 72.87(11) 2_775 1_654 ?
O14 Eu2 O7 71.89(10) . 1_654 ?
O7 Eu2 O7 75.05(12) 2_676 1_654 ?
O11 Eu2 O7 48.65(10) 1_654 1_654 ?
O9 Eu2 C10 175.91(12) . 1_654 ?
O2 Eu2 C10 97.79(13) . 1_654 ?
O13 Eu2 C10 92.13(11) 2_675 1_654 ?
O6 Eu2 C10 87.88(12) 2_775 1_654 ?
O14 Eu2 C10 72.46(11) . 1_654 ?
O7 Eu2 C10 98.40(12) 2_676 1_654 ?
O11 Eu2 C10 24.22(12) 1_654 1_654 ?
O7 Eu2 C10 24.64(11) 1_654 1_654 ?
O9 Eu2 Eu2 125.27(9) . 2_775 ?
O2 Eu2 Eu2 138.26(9) . 2_775 ?
O13 Eu2 Eu2 130.92(8) 2_675 2_775 ?
O6 Eu2 Eu2 66.83(8) 2_775 2_775 ?
O14 Eu2 Eu2 65.88(7) . 2_775 ?
O7 Eu2 Eu2 40.97(9) 2_676 2_775 ?
O11 Eu2 Eu2 82.06(8) 1_654 2_775 ?
O7 Eu2 Eu2 34.09(7) 1_654 2_775 ?
C10 Eu2 Eu2 57.85(9) 1_654 2_775 ?
O3 Eu1 O4 164.80(14) . . ?
O3 Eu1 O10 88.40(13) . 2_766 ?
O4 Eu1 O10 83.54(13) . 2_766 ?
O3 Eu1 O12 101.98(12) . . ?
O4 Eu1 O12 78.29(12) . . ?
O10 Eu1 O12 145.91(12) 2_766 . ?
O3 Eu1 O1 79.24(15) . . ?
O4 Eu1 O1 86.29(14) . . ?
O10 Eu1 O1 75.82(12) 2_766 . ?
O12 Eu1 O1 74.45(12) . . ?
O3 Eu1 O8 112.32(13) . 2_666 ?
O4 Eu1 O8 78.13(12) . 2_666 ?
O10 Eu1 O8 75.54(11) 2_766 2_666 ?
O12 Eu1 O8 127.24(11) . 2_666 ?
O1 Eu1 O8 148.67(12) . 2_666 ?
O3 Eu1 O5 71.14(13) . 2_666 ?
O4 Eu1 O5 123.56(12) . 2_666 ?
O10 Eu1 O5 132.21(12) 2_766 2_666 ?
O12 Eu1 O5 81.64(12) . 2_666 ?
O1 Eu1 O5 136.79(13) . 2_666 ?
O8 Eu1 O5 73.56(11) 2_666 2_666 ?
O3 Eu1 O4 117.37(12) . 2_666 ?
O4 Eu1 O4 76.69(12) . 2_666 ?
O10 Eu1 O4 138.21(10) 2_766 2_666 ?
O12 Eu1 O4 64.33(10) . 2_666 ?
O1 Eu1 O4 137.66(12) . 2_666 ?
O8 Eu1 O4 64.62(10) 2_666 2_666 ?
O5 Eu1 O4 47.17(10) 2_666 2_666 ?
O3 Eu1 C7 93.97(13) . 2_666 ?
O4 Eu1 C7 100.43(13) . 2_666 ?
O10 Eu1 C7 140.71(11) 2_766 2_666 ?
O12 Eu1 C7 71.61(12) . 2_666 ?
O1 Eu1 C7 143.11(12) . 2_666 ?
O8 Eu1 C7 67.31(11) 2_666 2_666 ?
O5 Eu1 C7 23.30(12) 2_666 2_666 ?
O4 Eu1 C7 23.87(10) 2_666 2_666 ?
O3 Eu1 Eu1 149.88(10) . 2_666 ?
O4 Eu1 Eu1 43.86(9) . 2_666 ?
O10 Eu1 Eu1 117.92(8) 2_766 2_666 ?
O12 Eu1 Eu1 65.07(8) . 2_666 ?
O1 Eu1 Eu1 119.36(11) . 2_666 ?
O8 Eu1 Eu1 65.18(8) 2_666 2_666 ?
O5 Eu1 Eu1 79.86(8) 2_666 2_666 ?
O4 Eu1 Eu1 32.83(6) 2_666 2_666 ?
C7 Eu1 Eu1 56.62(8) 2_666 2_666 ?
C17 O17 C24 106.3(3) . . ?
C23 O16 C25 106.4(3) . . ?
C14 O15 C18 106.9(4) . . ?
C22 O14 Eu2 139.7(3) . . ?
C16 O13 Eu2 148.4(3) . 2_675 ?
C15 O12 Eu1 136.7(3) . . ?
C10 O11 Eu2 102.4(3) . 1_456 ?
C13 O10 Eu1 141.8(3) . 2_766 ?
C16 O9 Eu2 140.6(3) . . ?
C15 O8 Eu1 135.5(3) . 2_666 ?
C10 O7 Eu2 158.3(3) . 2_676 ?
C10 O7 Eu2 85.7(3) . 1_456 ?
Eu2 O7 Eu2 104.95(12) 2_676 1_456 ?
C22 O6 Eu2 137.2(3) . 2_775 ?
C7 O5 Eu1 106.3(3) . 2_666 ?
C7 O4 Eu1 171.6(3) . . ?
C7 O4 Eu1 82.7(3) . 2_666 ?
Eu1 O4 Eu1 103.31(12) . 2_666 ?
C13 O3 Eu1 150.0(3) . . ?
C8 O2 Eu2 152.6(4) . . ?
C23 C26 C19 106.8(4) . . ?
C19 C25 O16 110.6(4) . . ?
C19 C25 C15 131.6(4) . . ?
O16 C25 C15 117.6(4) . . ?
C20 C24 O17 110.3(4) . . ?
C20 C24 C22 131.9(4) . . ?
O17 C24 C22 117.7(4) . . ?
C26 C23 O16 110.1(4) . . ?
C26 C23 C16 132.0(4) . . ?
O16 C23 C16 117.8(4) . . ?
O14 C22 O6 127.1(4) . . ?
O14 C22 C24 117.8(4) . . ?
O6 C22 C24 115.2(4) . . ?
C17 C21 C20 106.7(4) . . ?
C24 C20 C21 106.3(4) . . ?
C25 C19 C26 106.0(4) . . ?
O15 C18 C12 110.1(4) . . ?
O15 C18 C10 115.2(4) . . ?
C12 C18 C10 134.7(4) . . ?
C21 C17 O17 110.4(4) . . ?
C21 C17 C13 132.0(4) . . ?
O17 C17 C13 117.1(4) . . ?
O13 C16 O9 125.0(4) . . ?
O13 C16 C23 117.9(4) . . ?
O9 C16 C23 117.1(4) . . ?
O12 C15 O8 126.9(4) . . ?
O12 C15 C25 117.5(4) . . ?
O8 C15 C25 115.6(4) . . ?
C11 O1 Eu1 145.9(4) . . ?
O15 C14 C9 110.9(4) . . ?
O15 C14 C7 116.5(4) . . ?
C9 C14 C7 132.6(4) . . ?
C11 N2 C3 124.0(6) . . ?
C11 N2 C1 119.1(6) . . ?
C3 N2 C1 116.9(6) . . ?
O3 C13 O10 125.3(4) . . ?
O3 C13 C17 117.1(4) . . ?
O10 C13 C17 117.5(4) . . ?
C18 C12 C9 106.6(4) . . ?
O1 C11 N2 118.2(5) . . ?
O1 C11 C5 121.4(5) . . ?
N2 C11 C5 120.4(5) . . ?
C8 N1 C6 133.0(9) . . ?
C8 N1 C2 110.2(7) . . ?
C6 N1 C2 116.5(8) . . ?
O7 C10 O11 122.2(4) . . ?
O7 C10 C18 120.6(4) . . ?
O11 C10 C18 117.1(4) . . ?
O7 C10 Eu2 69.7(3) . 1_456 ?
O11 C10 Eu2 53.4(2) . 1_456 ?
C18 C10 Eu2 166.3(3) . 1_456 ?
C14 C9 C12 105.5(4) . . ?
O2 C8 N1 125.4(8) . . ?
O2 C8 C4 122.6(7) . . ?
N1 C8 C4 112.1(7) . . ?
O4 C7 O5 123.8(4) . . ?
O4 C7 C14 118.2(4) . . ?
O5 C7 C14 118.0(4) . . ?
O4 C7 Eu1 73.5(3) . 2_666 ?
O5 C7 Eu1 50.4(2) . 2_666 ?
C14 C7 Eu1 168.3(3) . 2_666 ?

_refine_diff_density_max         2.321
_refine_diff_density_min         -3.298
_refine_diff_density_rms         0.464

