# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_ag_ag_85_0m_a
_database_code_depnum_ccdc_archive 'CCDC 1902309'
loop_
_audit_author_name
_audit_author_address
'Andreas Orthaber'
;Uppsala University
Sweden
;
_audit_update_record             
;
2019-03-11 deposited with the CCDC.	2019-10-14 downloaded from the CCDC.
;
# start Validation Reply Form
_vrf_PLAT364_ag_ag_85_0m_a       
;
PROBLEM: Short  C(sp3)-C(sp)  Bond  C1       - C2       .       1.22 Ang.
RESPONSE: This bond is mistakenly identified as an Csp2-Csp3 bond but is rather an Csp-Csp thus the bond distance is in the expected range.
;
# Added during the CSD deposition process: Monday 11 March 2019 09:19 AM
# end Validation Reply Form

_audit_creation_date             2019-03-01
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/1
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C112 H184 Ag13 N4 O8 Si8, Cl O4'
_chemical_formula_sum            'C112 H184 Ag13 Cl N4 O12 Si8'
_chemical_formula_weight         3441.10
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   29.1488(6)
_cell_length_b                   16.3089(4)
_cell_length_c                   28.5179(6)
_cell_angle_alpha                90
_cell_angle_beta                 91.7990(10)
_cell_angle_gamma                90
_cell_volume                     13550.3(5)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9935
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      27.39
_cell_measurement_theta_min      2.52
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    1.975
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.6140
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            Colourless
_exptl_crystal_density_diffrn    1.687
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       Prism
_exptl_crystal_F_000             6880
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.16
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0354
_diffrn_reflns_av_unetI/netI     0.0293
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       34
_diffrn_reflns_limit_h_min       -34
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            56034
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        24.998
_diffrn_reflns_theta_max         24.998
_diffrn_reflns_theta_min         2.007
_diffrn_ambient_temperature      150.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                9652
_reflns_number_total             11916
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         0.734
_refine_diff_density_min         -0.747
_refine_diff_density_rms         0.096
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.049
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     754
_refine_ls_number_reflns         11916
_refine_ls_number_restraints     115
_refine_ls_R_factor_all          0.0473
_refine_ls_R_factor_gt           0.0335
_refine_ls_restrained_S_all      1.064
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0348P)²+63.2492P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0776
_refine_ls_wR_factor_ref         0.0859
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 C81-C82 = C81-C83
 1.58 with sigma of 0.02
 Si3-C81 \\sim Si3-C81A
 with sigma of 0.02
 C81-C82 \\sim C81A-C82A
 with sigma of 0.02
 C81-C83 \\sim C81A-C83A
 with sigma of 0.02
 Si3-C82 \\sim Si3-C82A
 with sigma of 0.04
 Si3-C83 \\sim Si3-C83A
 with sigma of 0.04
 C82-C83 \\sim C82A-C83A
 with sigma of 0.04
 Cl2-O5 \\sim Cl2-O6 \\sim Cl2-O7 \\sim Cl2-O8
 with sigma of 0.02
 O5-O7 \\sim O6-O8 \\sim O5-O8 \\sim O6-O7 \\sim O5-O6 \\sim O7-O8
 with sigma of 0.04
3. Uiso/Uaniso restraints and constraints
Cl2 \\sim O5 \\sim O6 \\sim O7 \\sim O8: within 2A with sigma of 0.04 and sigma
for terminal atoms of 0.08
Uanis(C82) \\sim Ueq, Uanis(C83) \\sim Ueq: with sigma of 0.002 and sigma for
terminal atoms of 0.004
Uanis(O6) \\sim Ueq, Uanis(O5) \\sim Ueq, Uanis(O7) \\sim Ueq, Uanis(O8) \\sim
Ueq: with sigma of 0.02 and sigma for terminal atoms of 0.06
4. Rigid body (RIGU) restrains
 Cl2, O5, O6, O7, O8
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
 O6, Cl2, O5, O7, O8
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
5. Others
 Sof(C82A)=Sof(H82D)=Sof(H82E)=Sof(H82F)=Sof(C81A)=Sof(H81A)=Sof(C83A)=
 Sof(H83D)=Sof(H83E)=Sof(H83F)=1-FVAR(1)
 Sof(C81)=Sof(H81)=Sof(C82)=Sof(H82A)=Sof(H82B)=Sof(H82C)=Sof(C83)=Sof(H83A)=
 Sof(H83B)=Sof(H83C)=FVAR(1)
 Fixed Sof: Cl2(0.5) O5(0.5) O6(0.5) O7(0.5) O8(0.5)
6.a Ternary CH refined with riding coordinates:
 C11(H11), C21(H21), C31(H31), C41(H41), C51(H51), C61(H61), C71(H71),
 C81(H81), C91(H91), C101(H101), C111(H111), C121(H121), C81A(H81A)
6.b Aromatic/amide H refined with riding coordinates:
 C3L(H3L), C4L(H4L), C5L(H5L), C6L(H6L), C9L(H9L), C10L(H10L), C11L(H11L),
 C12L(H12L)
6.c Idealised Me refined as rotating group:
 C12(H12A,H12B,H12C), C13(H13A,H13B,H13C), C22(H22A,H22B,H22C), C23(H23A,H23B,
 H23C), C32(H32A,H32B,H32C), C33(H33A,H33B,H33C), C42(H42A,H42B,H42C), C43(H43A,
 H43B,H43C), C52(H52A,H52B,H52C), C53(H53A,H53B,H53C), C62(H62A,H62B,H62C),
 C63(H63A,H63B,H63C), C72(H72A,H72B,H72C), C73(H73A,H73B,H73C), C92(H92A,H92B,
 H92C), C93(H93A,H93B,H93C), C102(H10A,H10B,H10C), C103(H10D,H10E,H10F),
 C112(H11A,H11B,H11C), C113(H11D,H11E,H11F), C122(H12D,H12E,H12F), C123(H12G,
 H12H,H12I), C82(H82A,H82B,H82C), C83(H83A,H83B,H83C), C82A(H82D,H82E,H82F),
 C83A(H83D,H83E,H83F)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.66433(2) 0.16976(2) 0.44808(2) 0.04636(11) Uani 1 1 d . . . . .
Ag2 Ag 0.74166(2) 0.10894(2) 0.38217(2) 0.03027(9) Uani 1 1 d . . . . .
Ag3 Ag 0.70481(2) 0.27324(2) 0.35018(2) 0.04058(10) Uani 1 1 d . . . . .
Ag4 Ag 0.77966(2) 0.33702(2) 0.41769(2) 0.03924(10) Uani 1 1 d . . . . .
Ag5 Ag 0.750000 0.250000 0.500000 0.05010(16) Uani 1 2 d S T P . .
Ag6 Ag 0.69898(2) 0.39765(2) 0.52494(2) 0.04030(10) Uani 1 1 d . . . . .
Ag7 Ag 0.66431(2) 0.30750(2) 0.62122(2) 0.04598(11) Uani 1 1 d . . . . .
Si1 Si 0.57257(4) 0.15571(8) 0.34054(5) 0.0375(3) Uani 1 1 d . . . . .
C1 C 0.67416(14) 0.1424(3) 0.36937(16) 0.0314(10) Uani 1 1 d . . . . .
C2 C 0.63320(15) 0.1525(3) 0.36243(17) 0.0336(10) Uani 1 1 d . . . . .
C11 C 0.54270(17) 0.0637(3) 0.3646(2) 0.0507(14) Uani 1 1 d . . . . .
H11 H 0.563981 0.016253 0.360646 0.061 Uiso 1 1 calc R . . . .
C12 C 0.4981(2) 0.0424(4) 0.3362(3) 0.0717(19) Uani 1 1 d . . . . .
H12A H 0.483696 -0.005807 0.349997 0.108 Uiso 1 1 calc GR . . . .
H12B H 0.505504 0.030613 0.303592 0.108 Uiso 1 1 calc GR . . . .
H12C H 0.476898 0.088982 0.337036 0.108 Uiso 1 1 calc GR . . . .
C13 C 0.5333(2) 0.0690(4) 0.4174(2) 0.0728(19) Uani 1 1 d . . . . .
H13A H 0.510043 0.111094 0.422603 0.109 Uiso 1 1 calc GR . . . .
H13B H 0.561714 0.083276 0.434720 0.109 Uiso 1 1 calc GR . . . .
H13C H 0.522136 0.015829 0.428313 0.109 Uiso 1 1 calc GR . . . .
C21 C 0.57551(16) 0.1458(3) 0.27449(19) 0.0455(13) Uani 1 1 d . . . . .
H21 H 0.543143 0.143603 0.261844 0.055 Uiso 1 1 calc R . . . .
C22 C 0.5985(2) 0.0660(4) 0.2602(2) 0.0631(17) Uani 1 1 d . . . . .
H22A H 0.598787 0.062496 0.225915 0.095 Uiso 1 1 calc GR . . . .
H22B H 0.581349 0.019385 0.272513 0.095 Uiso 1 1 calc GR . . . .
H22C H 0.630060 0.064696 0.273035 0.095 Uiso 1 1 calc GR . . . .
C23 C 0.59799(19) 0.2187(4) 0.2517(2) 0.0551(15) Uani 1 1 d . . . . .
H23A H 0.629711 0.223862 0.263760 0.083 Uiso 1 1 calc GR . . . .
H23B H 0.580948 0.268681 0.258978 0.083 Uiso 1 1 calc GR . . . .
H23C H 0.597852 0.210763 0.217643 0.083 Uiso 1 1 calc GR . . . .
C31 C 0.54874(16) 0.2587(3) 0.35517(19) 0.0432(12) Uani 1 1 d . . . . .
H31 H 0.570175 0.299413 0.341452 0.052 Uiso 1 1 calc R . . . .
C32 C 0.50176(19) 0.2747(4) 0.3307(3) 0.073(2) Uani 1 1 d . . . . .
H32A H 0.478588 0.239232 0.344486 0.110 Uiso 1 1 calc GR . . . .
H32B H 0.503601 0.262672 0.297159 0.110 Uiso 1 1 calc GR . . . .
H32C H 0.493167 0.332210 0.334956 0.110 Uiso 1 1 calc GR . . . .
C33 C 0.5477(2) 0.2793(4) 0.4077(2) 0.0589(16) Uani 1 1 d . . . . .
H33A H 0.539047 0.336881 0.411637 0.088 Uiso 1 1 calc GR . . . .
H33B H 0.578147 0.269944 0.422279 0.088 Uiso 1 1 calc GR . . . .
H33C H 0.525199 0.244111 0.422780 0.088 Uiso 1 1 calc GR . . . .
Si2 Si 0.89492(4) -0.03090(8) 0.42288(4) 0.0304(3) Uani 1 1 d . . . . .
C3 C 0.80655(14) 0.0629(3) 0.39698(15) 0.0281(9) Uani 1 1 d . . . . .
C4 C 0.84164(14) 0.0305(3) 0.41157(15) 0.0301(10) Uani 1 1 d . . . . .
C41 C 0.89833(17) -0.1034(3) 0.37186(17) 0.0433(12) Uani 1 1 d . . . . .
H41 H 0.927387 -0.135467 0.376310 0.052 Uiso 1 1 calc R . . . .
C42 C 0.9013(2) -0.0579(4) 0.32592(18) 0.0598(16) Uani 1 1 d . . . . .
H42A H 0.906903 -0.096999 0.300640 0.090 Uiso 1 1 calc GR . . . .
H42B H 0.926554 -0.018258 0.328072 0.090 Uiso 1 1 calc GR . . . .
H42C H 0.872391 -0.028880 0.319239 0.090 Uiso 1 1 calc GR . . . .
C43 C 0.8588(2) -0.1650(4) 0.3699(2) 0.0713(18) Uani 1 1 d . . . . .
H43A H 0.829540 -0.135516 0.367899 0.107 Uiso 1 1 calc GR . . . .
H43B H 0.860014 -0.198862 0.398329 0.107 Uiso 1 1 calc GR . . . .
H43C H 0.861577 -0.200201 0.342291 0.107 Uiso 1 1 calc GR . . . .
C51 C 0.94304(15) 0.0456(3) 0.42377(19) 0.0414(12) Uani 1 1 d . . . . .
H51 H 0.935619 0.085076 0.397778 0.050 Uiso 1 1 calc R . . . .
C52 C 0.94418(18) 0.0961(3) 0.4686(2) 0.0600(17) Uani 1 1 d . . . . .
H52A H 0.953666 0.061224 0.495115 0.090 Uiso 1 1 calc GR . . . .
H52B H 0.913539 0.118371 0.473814 0.090 Uiso 1 1 calc GR . . . .
H52C H 0.966072 0.141293 0.465651 0.090 Uiso 1 1 calc GR . . . .
C53 C 0.99022(17) 0.0110(4) 0.4136(2) 0.0590(16) Uani 1 1 d . . . . .
H53A H 1.012422 0.055903 0.411892 0.088 Uiso 1 1 calc GR . . . .
H53B H 0.988769 -0.018475 0.383639 0.088 Uiso 1 1 calc GR . . . .
H53C H 0.999826 -0.026859 0.438753 0.088 Uiso 1 1 calc GR . . . .
C61 C 0.89222(17) -0.0865(3) 0.48049(17) 0.0415(12) Uani 1 1 d . . . . .
H61 H 0.899933 -0.045004 0.505309 0.050 Uiso 1 1 calc R . . . .
C62 C 0.8460(2) -0.1205(4) 0.4921(2) 0.0657(17) Uani 1 1 d . . . . .
H62A H 0.837328 -0.163577 0.469509 0.099 Uiso 1 1 calc GR . . . .
H62B H 0.823065 -0.076495 0.490420 0.099 Uiso 1 1 calc GR . . . .
H62C H 0.847326 -0.143568 0.523809 0.099 Uiso 1 1 calc GR . . . .
C63 C 0.92903(19) -0.1531(4) 0.4852(2) 0.0588(16) Uani 1 1 d . . . . .
H63A H 0.927146 -0.179687 0.515901 0.088 Uiso 1 1 calc GR . . . .
H63B H 0.959437 -0.128359 0.482308 0.088 Uiso 1 1 calc GR . . . .
H63C H 0.924078 -0.194061 0.460380 0.088 Uiso 1 1 calc GR . . . .
Si3 Si 0.80177(6) 0.26959(10) 0.24425(5) 0.0475(4) Uani 1 1 d D . . . .
C5 C 0.78353(17) 0.2935(3) 0.34853(17) 0.0395(11) Uani 1 1 d . . . . .
C6 C 0.79079(16) 0.2796(3) 0.30807(18) 0.0379(11) Uani 1 1 d . . . . .
C71 C 0.8647(2) 0.2675(5) 0.2370(2) 0.075(2) Uani 1 1 d . . . . .
H71 H 0.876209 0.218735 0.255022 0.090 Uiso 1 1 calc R . . . .
C72 C 0.8773(3) 0.2519(7) 0.1850(3) 0.123(4) Uani 1 1 d . . . . .
H72A H 0.870627 0.301149 0.166339 0.184 Uiso 1 1 calc GR . . . .
H72B H 0.859183 0.205836 0.172399 0.184 Uiso 1 1 calc GR . . . .
H72C H 0.910058 0.238827 0.183608 0.184 Uiso 1 1 calc GR . . . .
C73 C 0.8893(2) 0.3408(5) 0.2583(3) 0.104(3) Uani 1 1 d . . . . .
H73A H 0.922533 0.331350 0.258433 0.156 Uiso 1 1 calc GR . . . .
H73B H 0.879544 0.348769 0.290535 0.156 Uiso 1 1 calc GR . . . .
H73C H 0.881872 0.389872 0.239709 0.156 Uiso 1 1 calc GR . . . .
C81 C 0.7685(5) 0.3469(10) 0.2085(7) 0.057(6) Uani 0.477(11) 1 d D . . A 1
H81 H 0.760869 0.321997 0.177166 0.068 Uiso 0.477(11) 1 calc R . . A 1
C91 C 0.7774(3) 0.1693(4) 0.2235(2) 0.075(2) Uani 1 1 d . . . . .
H91 H 0.783529 0.165623 0.189220 0.090 Uiso 1 1 calc R . . . .
C92 C 0.7251(3) 0.1618(5) 0.2281(3) 0.093(3) Uani 1 1 d . . . . .
H92A H 0.715074 0.107079 0.217968 0.140 Uiso 1 1 calc GR . . . .
H92B H 0.709671 0.203323 0.208349 0.140 Uiso 1 1 calc GR . . . .
H92C H 0.717174 0.170336 0.260882 0.140 Uiso 1 1 calc GR . . . .
C93 C 0.8026(3) 0.0978(5) 0.2469(3) 0.111(3) Uani 1 1 d . . . . .
H93A H 0.795511 0.096215 0.280271 0.167 Uiso 1 1 calc GR . . . .
H93B H 0.835723 0.104595 0.243634 0.167 Uiso 1 1 calc GR . . . .
H93C H 0.792676 0.046376 0.231927 0.167 Uiso 1 1 calc GR . . . .
Si4 Si 0.81229(5) 0.53967(8) 0.46443(6) 0.0455(4) Uani 1 1 d . . . . .
C7 C 0.77266(15) 0.3725(3) 0.49475(15) 0.0302(10) Uani 1 1 d . . . . .
C8 C 0.78983(14) 0.4363(3) 0.48138(16) 0.0313(10) Uani 1 1 d . . . . .
C101 C 0.7628(2) 0.5880(3) 0.4315(2) 0.0579(16) Uani 1 1 d . . . . .
H101 H 0.737172 0.589912 0.454069 0.070 Uiso 1 1 calc R . . . .
C102 C 0.7440(2) 0.5414(4) 0.3893(3) 0.081(2) Uani 1 1 d . . . . .
H10A H 0.715073 0.566338 0.378266 0.122 Uiso 1 1 calc GR . . . .
H10B H 0.738669 0.484199 0.398033 0.122 Uiso 1 1 calc GR . . . .
H10C H 0.766254 0.543559 0.364241 0.122 Uiso 1 1 calc GR . . . .
C103 C 0.7713(3) 0.6769(4) 0.4176(3) 0.113(3) Uani 1 1 d . . . . .
H10D H 0.795636 0.678924 0.394693 0.169 Uiso 1 1 calc GR . . . .
H10E H 0.780575 0.708646 0.445429 0.169 Uiso 1 1 calc GR . . . .
H10F H 0.743016 0.700175 0.403563 0.169 Uiso 1 1 calc GR . . . .
C111 C 0.8248(2) 0.5974(3) 0.5202(3) 0.0662(19) Uani 1 1 d . . . . .
H111 H 0.835236 0.653195 0.510672 0.079 Uiso 1 1 calc R . . . .
C112 C 0.7831(3) 0.6101(5) 0.5489(3) 0.098(3) Uani 1 1 d . . . . .
H11A H 0.772859 0.557277 0.561101 0.147 Uiso 1 1 calc GR . . . .
H11B H 0.758515 0.634382 0.529177 0.147 Uiso 1 1 calc GR . . . .
H11C H 0.790729 0.647055 0.575083 0.147 Uiso 1 1 calc GR . . . .
C113 C 0.8634(3) 0.5611(5) 0.5498(3) 0.101(3) Uani 1 1 d . . . . .
H11D H 0.870161 0.597049 0.576664 0.151 Uiso 1 1 calc GR . . . .
H11E H 0.890733 0.555843 0.530933 0.151 Uiso 1 1 calc GR . . . .
H11F H 0.854272 0.506910 0.561045 0.151 Uiso 1 1 calc GR . . . .
C121 C 0.8669(2) 0.5252(4) 0.4328(3) 0.073(2) Uani 1 1 d . . . . .
H121 H 0.887096 0.491069 0.454019 0.088 Uiso 1 1 calc R . . . .
C122 C 0.8640(2) 0.4806(5) 0.3872(3) 0.090(2) Uani 1 1 d . . . . .
H12D H 0.848323 0.515054 0.363528 0.135 Uiso 1 1 calc GR . . . .
H12E H 0.846700 0.429564 0.390973 0.135 Uiso 1 1 calc GR . . . .
H12F H 0.894984 0.467756 0.377069 0.135 Uiso 1 1 calc GR . . . .
C123 C 0.8925(3) 0.6061(5) 0.4262(5) 0.162(6) Uani 1 1 d . . . . .
H12G H 0.923512 0.594727 0.415549 0.243 Uiso 1 1 calc GR . . . .
H12H H 0.894497 0.635688 0.456111 0.243 Uiso 1 1 calc GR . . . .
H12I H 0.875942 0.639653 0.402746 0.243 Uiso 1 1 calc GR . . . .
C1L C 0.61586(17) 0.2128(3) 0.53372(19) 0.0414(12) Uani 1 1 d . . . . .
C2L C 0.58016(17) 0.2140(3) 0.5718(2) 0.0465(13) Uani 1 1 d . . . . .
C3L C 0.53804(19) 0.1766(4) 0.5642(2) 0.0668(17) Uani 1 1 d . . . . .
H3L H 0.531601 0.147205 0.535980 0.080 Uiso 1 1 calc R . . . .
C4L C 0.5055(2) 0.1824(5) 0.5980(3) 0.085(2) Uani 1 1 d . . . . .
H4L H 0.476264 0.157563 0.593361 0.102 Uiso 1 1 calc R . . . .
C5L C 0.5159(2) 0.2240(5) 0.6380(3) 0.077(2) Uani 1 1 d . . . . .
H5L H 0.493869 0.229268 0.661693 0.093 Uiso 1 1 calc R . . . .
C6L C 0.55864(19) 0.2586(4) 0.6439(2) 0.0549(15) Uani 1 1 d . . . . .
H6L H 0.565648 0.286873 0.672394 0.066 Uiso 1 1 calc R . . . .
C7L C 0.66127(15) 0.3874(3) 0.42736(15) 0.0328(10) Uani 1 1 d . . . . .
C8L C 0.64101(14) 0.4185(3) 0.38185(15) 0.0297(10) Uani 1 1 d . . . . .
C9L C 0.60903(16) 0.4816(3) 0.38153(17) 0.0431(12) Uani 1 1 d . . . . .
H9L H 0.600480 0.505957 0.410216 0.052 Uiso 1 1 calc R . . . .
C10L C 0.58968(17) 0.5088(3) 0.33972(18) 0.0474(13) Uani 1 1 d . . . . .
H10L H 0.567118 0.550900 0.339135 0.057 Uiso 1 1 calc R . . . .
C11L C 0.60389(18) 0.4736(3) 0.29879(18) 0.0469(13) Uani 1 1 d . . . . .
H11L H 0.591532 0.491326 0.269283 0.056 Uiso 1 1 calc R . . . .
C12L C 0.63621(17) 0.4124(3) 0.30130(16) 0.0404(12) Uani 1 1 d . . . . .
H12L H 0.646215 0.389049 0.272853 0.049 Uiso 1 1 calc R . . . .
N1 N 0.59093(13) 0.2544(3) 0.61169(15) 0.0426(10) Uani 1 1 d . . . . .
N2 N 0.65442(12) 0.3837(2) 0.34207(13) 0.0323(8) Uani 1 1 d . . . . .
O1 O 0.65143(11) 0.2555(2) 0.54005(12) 0.0436(8) Uani 1 1 d . . . . .
O2 O 0.60665(12) 0.1684(3) 0.49911(13) 0.0563(10) Uani 1 1 d . . . . .
O3 O 0.65483(12) 0.4322(2) 0.46225(12) 0.0540(10) Uani 1 1 d . . . . .
O4 O 0.68356(10) 0.32225(19) 0.42809(10) 0.0346(7) Uani 1 1 d . . . . .
C82 C 0.7240(4) 0.3696(7) 0.2312(4) 0.053(4) Uani 0.477(11) 1 d D U . A 1
H82A H 0.703496 0.321937 0.230810 0.080 Uiso 0.477(11) 1 calc GR . . A 1
H82B H 0.709308 0.414713 0.213710 0.080 Uiso 0.477(11) 1 calc GR . . A 1
H82C H 0.730405 0.386671 0.263656 0.080 Uiso 0.477(11) 1 calc GR . . A 1
C83 C 0.7954(5) 0.4259(8) 0.2005(6) 0.075(5) Uani 0.477(11) 1 d D U . A 1
H83A H 0.804195 0.450516 0.230785 0.112 Uiso 0.477(11) 1 calc GR . . A 1
H83B H 0.776190 0.464538 0.182281 0.112 Uiso 0.477(11) 1 calc GR . . A 1
H83C H 0.823078 0.413435 0.183149 0.112 Uiso 0.477(11) 1 calc GR . . A 1
C82A C 0.7790(9) 0.4411(9) 0.2452(8) 0.168(12) Uani 0.523(11) 1 d D . . A 2
H82D H 0.773458 0.433426 0.278600 0.252 Uiso 0.523(11) 1 calc GR . . A 2
H82E H 0.757363 0.481799 0.232111 0.252 Uiso 0.523(11) 1 calc GR . . A 2
H82F H 0.810468 0.460406 0.241299 0.252 Uiso 0.523(11) 1 calc GR . . A 2
C81A C 0.7724(8) 0.3632(10) 0.2205(6) 0.073(8) Uani 0.523(11) 1 d D . . A 2
H81A H 0.739317 0.350893 0.225455 0.087 Uiso 0.523(11) 1 calc R . . A 2
C83A C 0.7741(5) 0.3711(9) 0.1678(4) 0.084(5) Uani 0.523(11) 1 d D . . A 2
H83D H 0.805744 0.381641 0.158899 0.127 Uiso 0.523(11) 1 calc GR . . A 2
H83E H 0.754437 0.416684 0.157285 0.127 Uiso 0.523(11) 1 calc GR . . A 2
H83F H 0.763171 0.320120 0.153110 0.127 Uiso 0.523(11) 1 calc GR . . A 2
Cl2 Cl 1.0018(4) 0.1265(2) 0.2524(5) 0.0713(13) Uani 0.5 1 d D U . B -1
O5 O 1.0173(6) 0.2051(8) 0.2546(7) 0.227(10) Uani 0.5 1 d D U . B -1
O6 O 1.0014(5) 0.1041(10) 0.2983(4) 0.143(6) Uani 0.5 1 d D U . B -1
O7 O 1.0165(6) 0.0713(11) 0.2212(6) 0.182(9) Uani 0.5 1 d D U . B -1
O8 O 0.9549(3) 0.1349(7) 0.2422(6) 0.124(5) Uani 0.5 1 d D U . B -1


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Ag2 3.1407(5) . ?
Ag1 Ag5 3.1478(4) . ?
Ag1 C1 2.315(5) . ?
Ag1 C2 2.594(5) . ?
Ag1 C7 2.514(4) 7_656 ?
Ag1 O2 2.258(4) . ?
Ag2 Ag3 3.0174(5) . ?
Ag2 Ag6 3.1200(5) 7_656 ?
Ag2 Ag7 3.0653(5) 7_656 ?
Ag2 C1 2.063(4) . ?
Ag2 C3 2.066(4) . ?
Ag3 Ag4 3.0472(5) . ?
Ag3 C1 2.383(4) . ?
Ag3 C5 2.320(5) . ?
Ag3 N2 2.332(4) . ?
Ag3 O4 2.459(3) . ?
Ag4 Ag5 2.8980(4) . ?
Ag4 Ag7 3.0933(5) 7_656 ?
Ag4 C5 2.102(5) . ?
Ag4 C7 2.288(4) . ?
Ag4 C8 2.445(4) . ?
Ag5 Ag6 2.9297(4) . ?
Ag5 Ag6 2.9296(4) 7_656 ?
Ag5 C7 2.112(4) . ?
Ag5 C7 2.112(4) 7_656 ?
Ag6 Ag7 3.3008(6) . ?
Ag6 C3 2.328(4) 7_656 ?
Ag6 C4 2.488(4) 7_656 ?
Ag6 C7 2.374(4) . ?
Ag6 O3 2.242(3) . ?
Ag7 C3 2.342(4) 7_656 ?
Ag7 C5 2.385(5) 7_656 ?
Ag7 N1 2.315(4) . ?
Ag7 O1 2.483(4) . ?
Si1 C2 1.856(4) . ?
Si1 C11 1.875(6) . ?
Si1 C21 1.895(6) . ?
Si1 C31 1.870(5) . ?
C1 C2 1.215(6) . ?
C11 H11 1.0000 . ?
C11 C12 1.549(7) . ?
C11 C13 1.541(9) . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C21 H21 1.0000 . ?
C21 C22 1.526(7) . ?
C21 C23 1.514(8) . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C31 H31 1.0000 . ?
C31 C32 1.539(7) . ?
C31 C33 1.537(8) . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C33 H33A 0.9800 . ?
C33 H33B 0.9800 . ?
C33 H33C 0.9800 . ?
Si2 C4 1.867(4) . ?
Si2 C41 1.880(5) . ?
Si2 C51 1.877(5) . ?
Si2 C61 1.880(5) . ?
C3 C4 1.213(6) . ?
C41 H41 1.0000 . ?
C41 C42 1.511(7) . ?
C41 C43 1.528(8) . ?
C42 H42A 0.9800 . ?
C42 H42B 0.9800 . ?
C42 H42C 0.9800 . ?
C43 H43A 0.9800 . ?
C43 H43B 0.9800 . ?
C43 H43C 0.9800 . ?
C51 H51 1.0000 . ?
C51 C52 1.519(8) . ?
C51 C53 1.523(7) . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?
C53 H53A 0.9800 . ?
C53 H53B 0.9800 . ?
C53 H53C 0.9800 . ?
C61 H61 1.0000 . ?
C61 C62 1.504(8) . ?
C61 C63 1.530(7) . ?
C62 H62A 0.9800 . ?
C62 H62B 0.9800 . ?
C62 H62C 0.9800 . ?
C63 H63A 0.9800 . ?
C63 H63B 0.9800 . ?
C63 H63C 0.9800 . ?
Si3 C6 1.865(5) . ?
Si3 C71 1.853(7) . ?
Si3 C81 1.873(13) . ?
Si3 C91 1.871(7) . ?
Si3 C81A 1.866(13) . ?
C5 C6 1.201(7) . ?
C71 H71 1.0000 . ?
C71 C72 1.559(10) . ?
C71 C73 1.513(11) . ?
C72 H72A 0.9800 . ?
C72 H72B 0.9800 . ?
C72 H72C 0.9800 . ?
C73 H73A 0.9800 . ?
C73 H73B 0.9800 . ?
C73 H73C 0.9800 . ?
C81 H81 1.0000 . ?
C81 C82 1.514(15) . ?
C81 C83 1.529(14) . ?
C91 H91 1.0000 . ?
C91 C92 1.541(10) . ?
C91 C93 1.521(10) . ?
C92 H92A 0.9800 . ?
C92 H92B 0.9800 . ?
C92 H92C 0.9800 . ?
C93 H93A 0.9800 . ?
C93 H93B 0.9800 . ?
C93 H93C 0.9800 . ?
Si4 C8 1.877(5) . ?
Si4 C101 1.871(6) . ?
Si4 C111 1.873(7) . ?
Si4 C121 1.869(6) . ?
C7 C8 1.221(6) . ?
C101 H101 1.0000 . ?
C101 C102 1.511(9) . ?
C101 C103 1.525(8) . ?
C102 H10A 0.9800 . ?
C102 H10B 0.9800 . ?
C102 H10C 0.9800 . ?
C103 H10D 0.9800 . ?
C103 H10E 0.9800 . ?
C103 H10F 0.9800 . ?
C111 H111 1.0000 . ?
C111 C112 1.500(10) . ?
C111 C113 1.506(9) . ?
C112 H11A 0.9800 . ?
C112 H11B 0.9800 . ?
C112 H11C 0.9800 . ?
C113 H11D 0.9800 . ?
C113 H11E 0.9800 . ?
C113 H11F 0.9800 . ?
C121 H121 1.0000 . ?
C121 C122 1.490(10) . ?
C121 C123 1.531(9) . ?
C122 H12D 0.9800 . ?
C122 H12E 0.9800 . ?
C122 H12F 0.9800 . ?
C123 H12G 0.9800 . ?
C123 H12H 0.9800 . ?
C123 H12I 0.9800 . ?
C1L C2L 1.528(7) . ?
C1L O1 1.257(6) . ?
C1L O2 1.247(6) . ?
C2L C3L 1.382(8) . ?
C2L N1 1.344(7) . ?
C3L H3L 0.9500 . ?
C3L C4L 1.376(9) . ?
C4L H4L 0.9500 . ?
C4L C5L 1.353(10) . ?
C5L H5L 0.9500 . ?
C5L C6L 1.373(9) . ?
C6L H6L 0.9500 . ?
C6L N1 1.338(7) . ?
C7L C8L 1.497(6) . ?
C7L O3 1.253(5) . ?
C7L O4 1.245(5) . ?
C8L C9L 1.388(6) . ?
C8L N2 1.338(6) . ?
C9L H9L 0.9500 . ?
C9L C10L 1.377(7) . ?
C10L H10L 0.9500 . ?
C10L C11L 1.377(7) . ?
C11L H11L 0.9500 . ?
C11L C12L 1.373(7) . ?
C12L H12L 0.9500 . ?
C12L N2 1.346(6) . ?
C82 H82A 0.9800 . ?
C82 H82B 0.9800 . ?
C82 H82C 0.9800 . ?
C83 H83A 0.9800 . ?
C83 H83B 0.9800 . ?
C83 H83C 0.9800 . ?
C82A H82D 0.9800 . ?
C82A H82E 0.9800 . ?
C82A H82F 0.9800 . ?
C82A C81A 1.462(19) . ?
C81A H81A 1.0000 . ?
C81A C83A 1.511(16) . ?
C83A H83D 0.9800 . ?
C83A H83E 0.9800 . ?
C83A H83F 0.9800 . ?
Cl2 O5 1.361(10) . ?
Cl2 O6 1.360(13) . ?
Cl2 O7 1.344(12) . ?
Cl2 O8 1.394(12) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag2 Ag1 Ag5 80.740(12) . . ?
C1 Ag1 Ag2 41.05(10) . . ?
C1 Ag1 Ag5 114.56(11) . . ?
C1 Ag1 C2 27.93(14) . . ?
C1 Ag1 C7 117.76(15) . 7_656 ?
C2 Ag1 Ag2 68.81(10) . . ?
C2 Ag1 Ag5 137.47(10) . . ?
C7 Ag1 Ag2 77.17(10) 7_656 . ?
C7 Ag1 Ag5 41.96(10) 7_656 . ?
C7 Ag1 C2 143.86(14) 7_656 . ?
O2 Ag1 Ag2 161.00(11) . . ?
O2 Ag1 Ag5 107.26(10) . . ?
O2 Ag1 C1 137.76(14) . . ?
O2 Ag1 C2 111.11(14) . . ?
O2 Ag1 C7 97.07(14) . 7_656 ?
Ag3 Ag2 Ag1 69.216(12) . . ?
Ag3 Ag2 Ag6 118.033(15) . 7_656 ?
Ag3 Ag2 Ag7 84.595(14) . 7_656 ?
Ag6 Ag2 Ag1 83.805(13) 7_656 . ?
Ag7 Ag2 Ag1 122.533(15) 7_656 . ?
Ag7 Ag2 Ag6 64.502(12) 7_656 7_656 ?
C1 Ag2 Ag1 47.47(13) . . ?
C1 Ag2 Ag3 51.91(13) . . ?
C1 Ag2 Ag6 131.27(13) . 7_656 ?
C1 Ag2 Ag7 136.50(13) . 7_656 ?
C1 Ag2 C3 173.71(18) . . ?
C3 Ag2 Ag1 131.45(12) . . ?
C3 Ag2 Ag3 134.38(12) . . ?
C3 Ag2 Ag6 48.26(12) . 7_656 ?
C3 Ag2 Ag7 49.78(12) . 7_656 ?
Ag2 Ag3 Ag4 82.594(13) . . ?
C1 Ag3 Ag2 42.95(10) . . ?
C1 Ag3 Ag4 115.25(10) . . ?
C1 Ag3 O4 88.66(13) . . ?
C5 Ag3 Ag2 77.88(12) . . ?
C5 Ag3 Ag4 43.55(12) . . ?
C5 Ag3 C1 120.70(16) . . ?
C5 Ag3 N2 120.53(15) . . ?
C5 Ag3 O4 104.43(14) . . ?
N2 Ag3 Ag2 158.98(9) . . ?
N2 Ag3 Ag4 103.60(9) . . ?
N2 Ag3 C1 118.36(14) . . ?
N2 Ag3 O4 70.28(11) . . ?
O4 Ag3 Ag2 96.48(7) . . ?
O4 Ag3 Ag4 60.90(7) . . ?
Ag3 Ag4 Ag7 83.617(14) . 7_656 ?
Ag5 Ag4 Ag3 96.816(13) . . ?
Ag5 Ag4 Ag7 95.264(13) . 7_656 ?
C5 Ag4 Ag3 49.49(13) . . ?
C5 Ag4 Ag5 128.38(13) . . ?
C5 Ag4 Ag7 50.35(13) . 7_656 ?
C5 Ag4 C7 174.59(17) . . ?
C5 Ag4 C8 155.74(17) . . ?
C7 Ag4 Ag3 127.56(11) . . ?
C7 Ag4 Ag5 46.23(11) . . ?
C7 Ag4 Ag7 126.98(11) . 7_656 ?
C7 Ag4 C8 29.66(15) . . ?
C8 Ag4 Ag3 139.75(10) . . ?
C8 Ag4 Ag5 75.82(11) . . ?
C8 Ag4 Ag7 135.92(10) . 7_656 ?
Ag1 Ag5 Ag1 180.0 7_656 . ?
Ag4 Ag5 Ag1 94.307(11) 7_656 7_656 ?
Ag4 Ag5 Ag1 85.693(11) . 7_656 ?
Ag4 Ag5 Ag1 94.306(11) . . ?
Ag4 Ag5 Ag1 85.693(11) 7_656 . ?
Ag4 Ag5 Ag4 180.0 . 7_656 ?
Ag4 Ag5 Ag6 92.250(10) . 7_656 ?
Ag4 Ag5 Ag6 87.751(10) . . ?
Ag4 Ag5 Ag6 92.248(10) 7_656 . ?
Ag4 Ag5 Ag6 87.751(10) 7_656 7_656 ?
Ag6 Ag5 Ag1 86.870(10) . 7_656 ?
Ag6 Ag5 Ag1 86.868(10) 7_656 . ?
Ag6 Ag5 Ag1 93.132(10) 7_656 7_656 ?
Ag6 Ag5 Ag1 93.131(10) . . ?
Ag6 Ag5 Ag6 180.0 7_656 . ?
C7 Ag5 Ag1 52.74(12) 7_656 . ?
C7 Ag5 Ag1 127.26(12) . . ?
C7 Ag5 Ag1 127.26(12) 7_656 7_656 ?
C7 Ag5 Ag1 52.74(12) . 7_656 ?
C7 Ag5 Ag4 51.48(12) 7_656 7_656 ?
C7 Ag5 Ag4 128.52(12) 7_656 . ?
C7 Ag5 Ag4 128.52(12) . 7_656 ?
C7 Ag5 Ag4 51.48(12) . . ?
C7 Ag5 Ag6 53.24(12) 7_656 7_656 ?
C7 Ag5 Ag6 53.24(12) . . ?
C7 Ag5 Ag6 126.76(12) 7_656 . ?
C7 Ag5 Ag6 126.76(12) . 7_656 ?
C7 Ag5 C7 180.0 . 7_656 ?
Ag2 Ag6 Ag7 56.945(12) 7_656 . ?
Ag5 Ag6 Ag2 84.582(11) . 7_656 ?
Ag5 Ag6 Ag7 90.392(12) . . ?
C3 Ag6 Ag2 41.48(10) 7_656 7_656 ?
C3 Ag6 Ag5 120.68(10) 7_656 . ?
C3 Ag6 Ag7 45.20(11) 7_656 . ?
C3 Ag6 C4 28.94(14) 7_656 7_656 ?
C3 Ag6 C7 119.02(15) 7_656 . ?
C4 Ag6 Ag2 70.26(10) 7_656 7_656 ?
C4 Ag6 Ag5 145.17(10) 7_656 . ?
C4 Ag6 Ag7 55.90(11) 7_656 . ?
C7 Ag6 Ag2 79.52(10) . 7_656 ?
C7 Ag6 Ag5 45.44(10) . . ?
C7 Ag6 Ag7 121.93(10) . . ?
C7 Ag6 C4 143.30(14) . 7_656 ?
O3 Ag6 Ag2 167.16(10) . 7_656 ?
O3 Ag6 Ag5 107.21(9) . . ?
O3 Ag6 Ag7 126.31(11) . . ?
O3 Ag6 C3 129.65(13) . 7_656 ?
O3 Ag6 C4 100.83(13) . 7_656 ?
O3 Ag6 C7 104.91(14) . . ?
Ag2 Ag7 Ag4 81.070(13) 7_656 7_656 ?
Ag2 Ag7 Ag6 58.554(11) 7_656 . ?
Ag4 Ag7 Ag6 82.077(14) 7_656 . ?
C3 Ag7 Ag2 42.35(10) 7_656 7_656 ?
C3 Ag7 Ag4 114.14(10) 7_656 7_656 ?
C3 Ag7 Ag6 44.85(10) 7_656 . ?
C3 Ag7 C5 118.18(16) 7_656 7_656 ?
C3 Ag7 O1 98.45(13) 7_656 . ?
C5 Ag7 Ag2 76.00(12) 7_656 7_656 ?
C5 Ag7 Ag4 42.74(12) 7_656 7_656 ?
C5 Ag7 Ag6 113.60(12) 7_656 . ?
C5 Ag7 O1 100.21(14) 7_656 . ?
N1 Ag7 Ag2 170.44(10) . 7_656 ?
N1 Ag7 Ag4 99.74(10) . 7_656 ?
N1 Ag7 Ag6 112.01(11) . . ?
N1 Ag7 C3 130.65(14) . 7_656 ?
N1 Ag7 C5 111.11(16) . 7_656 ?
N1 Ag7 O1 69.56(13) . . ?
O1 Ag7 Ag2 103.39(8) . 7_656 ?
O1 Ag7 Ag4 58.08(7) . 7_656 ?
O1 Ag7 Ag6 54.40(8) . . ?
C2 Si1 C11 107.6(2) . . ?
C2 Si1 C21 105.0(2) . . ?
C2 Si1 C31 107.9(2) . . ?
C11 Si1 C21 109.3(2) . . ?
C31 Si1 C11 117.2(3) . . ?
C31 Si1 C21 109.1(2) . . ?
Ag1 C1 Ag3 96.26(15) . . ?
Ag2 C1 Ag1 91.48(16) . . ?
Ag2 C1 Ag3 85.14(15) . . ?
C2 C1 Ag1 88.9(3) . . ?
C2 C1 Ag2 172.3(4) . . ?
C2 C1 Ag3 102.4(3) . . ?
Si1 C2 Ag1 127.9(2) . . ?
C1 C2 Ag1 63.2(3) . . ?
C1 C2 Si1 168.2(4) . . ?
Si1 C11 H11 106.4 . . ?
C12 C11 Si1 112.4(4) . . ?
C12 C11 H11 106.4 . . ?
C13 C11 Si1 114.3(4) . . ?
C13 C11 H11 106.4 . . ?
C13 C11 C12 110.5(5) . . ?
C11 C12 H12A 109.5 . . ?
C11 C12 H12B 109.5 . . ?
C11 C12 H12C 109.5 . . ?
H12A C12 H12B 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C11 C13 H13A 109.5 . . ?
C11 C13 H13B 109.5 . . ?
C11 C13 H13C 109.5 . . ?
H13A C13 H13B 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
Si1 C21 H21 106.9 . . ?
C22 C21 Si1 111.8(4) . . ?
C22 C21 H21 106.9 . . ?
C23 C21 Si1 113.2(4) . . ?
C23 C21 H21 106.9 . . ?
C23 C21 C22 110.9(5) . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22B 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C21 C23 H23A 109.5 . . ?
C21 C23 H23B 109.5 . . ?
C21 C23 H23C 109.5 . . ?
H23A C23 H23B 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
Si1 C31 H31 105.6 . . ?
C32 C31 Si1 112.5(4) . . ?
C32 C31 H31 105.6 . . ?
C33 C31 Si1 115.6(4) . . ?
C33 C31 H31 105.6 . . ?
C33 C31 C32 111.1(5) . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32B 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C31 C33 H33A 109.5 . . ?
C31 C33 H33B 109.5 . . ?
C31 C33 H33C 109.5 . . ?
H33A C33 H33B 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
C4 Si2 C41 105.5(2) . . ?
C4 Si2 C51 105.2(2) . . ?
C4 Si2 C61 110.6(2) . . ?
C41 Si2 C61 112.2(2) . . ?
C51 Si2 C41 111.8(2) . . ?
C51 Si2 C61 111.1(2) . . ?
Ag2 C3 Ag6 90.26(16) . 7_656 ?
Ag2 C3 Ag7 87.86(15) . 7_656 ?
Ag6 C3 Ag7 89.95(15) 7_656 7_656 ?
C4 C3 Ag2 170.0(4) . . ?
C4 C3 Ag6 82.9(3) . 7_656 ?
C4 C3 Ag7 99.3(3) . 7_656 ?
Si2 C4 Ag6 122.6(2) . 7_656 ?
C3 C4 Ag6 68.2(3) . 7_656 ?
C3 C4 Si2 168.7(4) . . ?
Si2 C41 H41 107.2 . . ?
C42 C41 Si2 111.6(4) . . ?
C42 C41 H41 107.2 . . ?
C42 C41 C43 110.8(5) . . ?
C43 C41 Si2 112.6(4) . . ?
C43 C41 H41 107.2 . . ?
C41 C42 H42A 109.5 . . ?
C41 C42 H42B 109.5 . . ?
C41 C42 H42C 109.5 . . ?
H42A C42 H42B 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
C41 C43 H43A 109.5 . . ?
C41 C43 H43B 109.5 . . ?
C41 C43 H43C 109.5 . . ?
H43A C43 H43B 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
Si2 C51 H51 105.9 . . ?
C52 C51 Si2 111.6(4) . . ?
C52 C51 H51 105.9 . . ?
C52 C51 C53 111.4(4) . . ?
C53 C51 Si2 115.4(4) . . ?
C53 C51 H51 105.9 . . ?
C51 C52 H52A 109.5 . . ?
C51 C52 H52B 109.5 . . ?
C51 C52 H52C 109.5 . . ?
H52A C52 H52B 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
C51 C53 H53A 109.5 . . ?
C51 C53 H53B 109.5 . . ?
C51 C53 H53C 109.5 . . ?
H53A C53 H53B 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
Si2 C61 H61 106.1 . . ?
C62 C61 Si2 115.6(4) . . ?
C62 C61 H61 106.1 . . ?
C62 C61 C63 110.5(5) . . ?
C63 C61 Si2 111.8(4) . . ?
C63 C61 H61 106.1 . . ?
C61 C62 H62A 109.5 . . ?
C61 C62 H62B 109.5 . . ?
C61 C62 H62C 109.5 . . ?
H62A C62 H62B 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?
C61 C63 H63A 109.5 . . ?
C61 C63 H63B 109.5 . . ?
C61 C63 H63C 109.5 . . ?
H63A C63 H63B 109.5 . . ?
H63A C63 H63C 109.5 . . ?
H63B C63 H63C 109.5 . . ?
C6 Si3 C81 111.8(6) . . ?
C6 Si3 C91 108.1(3) . . ?
C6 Si3 C81A 101.0(6) . . ?
C71 Si3 C6 108.2(3) . . ?
C71 Si3 C81 116.6(5) . . ?
C71 Si3 C91 108.4(4) . . ?
C71 Si3 C81A 114.7(8) . . ?
C91 Si3 C81 103.4(7) . . ?
C81A Si3 C91 115.8(8) . . ?
Ag3 C5 Ag7 120.9(2) . 7_656 ?
Ag4 C5 Ag3 86.96(17) . . ?
Ag4 C5 Ag7 86.91(18) . 7_656 ?
C6 C5 Ag3 101.3(4) . . ?
C6 C5 Ag4 168.9(4) . . ?
C6 C5 Ag7 95.0(4) . 7_656 ?
C5 C6 Si3 174.1(4) . . ?
Si3 C71 H71 105.9 . . ?
C72 C71 Si3 111.9(5) . . ?
C72 C71 H71 105.9 . . ?
C73 C71 Si3 113.5(5) . . ?
C73 C71 H71 105.9 . . ?
C73 C71 C72 112.8(7) . . ?
C71 C72 H72A 109.5 . . ?
C71 C72 H72B 109.5 . . ?
C71 C72 H72C 109.5 . . ?
H72A C72 H72B 109.5 . . ?
H72A C72 H72C 109.5 . . ?
H72B C72 H72C 109.5 . . ?
C71 C73 H73A 109.5 . . ?
C71 C73 H73B 109.5 . . ?
C71 C73 H73C 109.5 . . ?
H73A C73 H73B 109.5 . . ?
H73A C73 H73C 109.5 . . ?
H73B C73 H73C 109.5 . . ?
Si3 C81 H81 108.1 . . ?
C82 C81 Si3 111.5(10) . . ?
C82 C81 H81 108.1 . . ?
C82 C81 C83 108.0(13) . . ?
C83 C81 Si3 113.0(12) . . ?
C83 C81 H81 108.1 . . ?
Si3 C91 H91 106.6 . . ?
C92 C91 Si3 114.1(5) . . ?
C92 C91 H91 106.6 . . ?
C93 C91 Si3 111.0(5) . . ?
C93 C91 H91 106.6 . . ?
C93 C91 C92 111.5(7) . . ?
C91 C92 H92A 109.5 . . ?
C91 C92 H92B 109.5 . . ?
C91 C92 H92C 109.5 . . ?
H92A C92 H92B 109.5 . . ?
H92A C92 H92C 109.5 . . ?
H92B C92 H92C 109.5 . . ?
C91 C93 H93A 109.5 . . ?
C91 C93 H93B 109.5 . . ?
C91 C93 H93C 109.5 . . ?
H93A C93 H93B 109.5 . . ?
H93A C93 H93C 109.5 . . ?
H93B C93 H93C 109.5 . . ?
C101 Si4 C8 103.8(2) . . ?
C101 Si4 C111 109.9(3) . . ?
C111 Si4 C8 107.0(3) . . ?
C121 Si4 C8 108.6(2) . . ?
C121 Si4 C101 117.8(3) . . ?
C121 Si4 C111 109.1(3) . . ?
Ag4 C7 Ag1 117.90(18) . 7_656 ?
Ag4 C7 Ag6 120.06(18) . . ?
Ag5 C7 Ag1 85.30(14) . 7_656 ?
Ag5 C7 Ag4 82.30(15) . . ?
Ag5 C7 Ag6 81.32(15) . . ?
Ag6 C7 Ag1 117.58(18) . 7_656 ?
C8 C7 Ag1 97.9(3) . 7_656 ?
C8 C7 Ag4 82.3(3) . . ?
C8 C7 Ag5 163.9(4) . . ?
C8 C7 Ag6 110.5(3) . . ?
Si4 C8 Ag4 116.0(2) . . ?
C7 C8 Ag4 68.0(3) . . ?
C7 C8 Si4 174.6(4) . . ?
Si4 C101 H101 105.6 . . ?
C102 C101 Si4 116.2(4) . . ?
C102 C101 H101 105.6 . . ?
C102 C101 C103 109.1(6) . . ?
C103 C101 Si4 113.7(5) . . ?
C103 C101 H101 105.6 . . ?
C101 C102 H10A 109.5 . . ?
C101 C102 H10B 109.5 . . ?
C101 C102 H10C 109.5 . . ?
H10A C102 H10B 109.5 . . ?
H10A C102 H10C 109.5 . . ?
H10B C102 H10C 109.5 . . ?
C101 C103 H10D 109.5 . . ?
C101 C103 H10E 109.5 . . ?
C101 C103 H10F 109.5 . . ?
H10D C103 H10E 109.5 . . ?
H10D C103 H10F 109.5 . . ?
H10E C103 H10F 109.5 . . ?
Si4 C111 H111 106.3 . . ?
C112 C111 Si4 113.2(4) . . ?
C112 C111 H111 106.3 . . ?
C112 C111 C113 110.6(7) . . ?
C113 C111 Si4 113.6(5) . . ?
C113 C111 H111 106.3 . . ?
C111 C112 H11A 109.5 . . ?
C111 C112 H11B 109.5 . . ?
C111 C112 H11C 109.5 . . ?
H11A C112 H11B 109.5 . . ?
H11A C112 H11C 109.5 . . ?
H11B C112 H11C 109.5 . . ?
C111 C113 H11D 109.5 . . ?
C111 C113 H11E 109.5 . . ?
C111 C113 H11F 109.5 . . ?
H11D C113 H11E 109.5 . . ?
H11D C113 H11F 109.5 . . ?
H11E C113 H11F 109.5 . . ?
Si4 C121 H121 105.8 . . ?
C122 C121 Si4 117.2(5) . . ?
C122 C121 H121 105.8 . . ?
C122 C121 C123 109.1(7) . . ?
C123 C121 Si4 112.1(5) . . ?
C123 C121 H121 105.8 . . ?
C121 C122 H12D 109.5 . . ?
C121 C122 H12E 109.5 . . ?
C121 C122 H12F 109.5 . . ?
H12D C122 H12E 109.5 . . ?
H12D C122 H12F 109.5 . . ?
H12E C122 H12F 109.5 . . ?
C121 C123 H12G 109.5 . . ?
C121 C123 H12H 109.5 . . ?
C121 C123 H12I 109.5 . . ?
H12G C123 H12H 109.5 . . ?
H12G C123 H12I 109.5 . . ?
H12H C123 H12I 109.5 . . ?
O1 C1L C2L 117.9(5) . . ?
O2 C1L C2L 115.8(5) . . ?
O2 C1L O1 126.3(5) . . ?
C3L C2L C1L 120.3(5) . . ?
N1 C2L C1L 117.5(4) . . ?
N1 C2L C3L 122.2(5) . . ?
C2L C3L H3L 120.4 . . ?
C4L C3L C2L 119.1(7) . . ?
C4L C3L H3L 120.4 . . ?
C3L C4L H4L 120.5 . . ?
C5L C4L C3L 119.0(6) . . ?
C5L C4L H4L 120.5 . . ?
C4L C5L H5L 120.4 . . ?
C4L C5L C6L 119.2(6) . . ?
C6L C5L H5L 120.4 . . ?
C5L C6L H6L 118.3 . . ?
N1 C6L C5L 123.3(6) . . ?
N1 C6L H6L 118.3 . . ?
O3 C7L C8L 115.2(4) . . ?
O4 C7L C8L 119.7(4) . . ?
O4 C7L O3 125.1(4) . . ?
C9L C8L C7L 120.2(4) . . ?
N2 C8L C7L 118.3(4) . . ?
N2 C8L C9L 121.5(4) . . ?
C8L C9L H9L 119.9 . . ?
C10L C9L C8L 120.1(5) . . ?
C10L C9L H9L 119.9 . . ?
C9L C10L H10L 120.9 . . ?
C11L C10L C9L 118.2(5) . . ?
C11L C10L H10L 120.9 . . ?
C10L C11L H11L 120.5 . . ?
C12L C11L C10L 118.9(5) . . ?
C12L C11L H11L 120.5 . . ?
C11L C12L H12L 118.4 . . ?
N2 C12L C11L 123.2(5) . . ?
N2 C12L H12L 118.4 . . ?
C2L N1 Ag7 118.3(3) . . ?
C6L N1 Ag7 124.6(4) . . ?
C6L N1 C2L 117.1(5) . . ?
C8L N2 Ag3 116.3(3) . . ?
C8L N2 C12L 117.9(4) . . ?
C12L N2 Ag3 125.7(3) . . ?
C1L O1 Ag7 115.0(3) . . ?
C1L O2 Ag1 111.0(3) . . ?
C7L O3 Ag6 113.0(3) . . ?
C7L O4 Ag3 114.1(3) . . ?
C81 C82 H82A 109.5 . . ?
C81 C82 H82B 109.5 . . ?
C81 C82 H82C 109.5 . . ?
H82A C82 H82B 109.5 . . ?
H82A C82 H82C 109.5 . . ?
H82B C82 H82C 109.5 . . ?
C81 C83 H83A 109.5 . . ?
C81 C83 H83B 109.5 . . ?
C81 C83 H83C 109.5 . . ?
H83A C83 H83B 109.5 . . ?
H83A C83 H83C 109.5 . . ?
H83B C83 H83C 109.5 . . ?
H82D C82A H82E 109.5 . . ?
H82D C82A H82F 109.5 . . ?
H82E C82A H82F 109.5 . . ?
C81A C82A H82D 109.5 . . ?
C81A C82A H82E 109.5 . . ?
C81A C82A H82F 109.5 . . ?
Si3 C81A H81A 102.6 . . ?
C82A C81A Si3 119.0(13) . . ?
C82A C81A H81A 102.6 . . ?
C82A C81A C83A 113.3(14) . . ?
C83A C81A Si3 113.7(11) . . ?
C83A C81A H81A 102.6 . . ?
C81A C83A H83D 109.5 . . ?
C81A C83A H83E 109.5 . . ?
C81A C83A H83F 109.5 . . ?
H83D C83A H83E 109.5 . . ?
H83D C83A H83F 109.5 . . ?
H83E C83A H83F 109.5 . . ?
O5 Cl2 O8 103.8(12) . . ?
O6 Cl2 O5 102.7(13) . . ?
O6 Cl2 O8 101.0(11) . . ?
O7 Cl2 O5 123.3(15) . . ?
O7 Cl2 O6 118.1(10) . . ?
O7 Cl2 O8 105.0(11) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_ag_ag_504_0m_a
_database_code_depnum_ccdc_archive 'CCDC 1953780'
loop_
_audit_author_name
_audit_author_address
'Andreas Orthaber'
;Uppsala University
Sweden
;
_audit_update_record             
;
2019-10-10 deposited with the CCDC.	2019-10-14 downloaded from the CCDC.
;
# start Validation Reply Form
_vrf_PLAT975_ag_ag_504_0m_a      
;
PROBLEM: Check Calcd Resid. Dens.  0.62A   From O1C             2.13 eA-3  
RESPONSE: Low data quality and unaccounted disorder has led to a high electron density
some of the ligands (including O1C)
;
_vrf_PLAT342_ag_ag_504_0m_a      
;
PROBLEM: Low Bond Precision on  C-C Bonds ...............    0.02815 Ang.  
RESPONSE: Due to the low data quality no higher bond precision could be achieved
;
# end Validation Reply Form
_audit_creation_date             2019-08-28
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C16 H18 Ag4 Cl0.5 N O4, 0.5(Cl O4)'
_chemical_formula_sum            'C16 H18 Ag4 Cl N O6'
_chemical_formula_weight         787.24
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   16.465(6)
_cell_length_b                   24.276(9)
_cell_length_c                   13.433(5)
_cell_angle_alpha                90
_cell_angle_beta                 126.986(6)
_cell_angle_gamma                90
_cell_volume                     4289(3)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    3133
_cell_measurement_temperature    150
_cell_measurement_theta_max      22.05
_cell_measurement_theta_min      2.53
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    3.755
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.3966
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    2.438
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       needle
_exptl_crystal_F_000             2992
_exptl_crystal_size_max          0.34
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.06
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1244
_diffrn_reflns_av_unetI/netI     0.0818
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            27979
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        24.998
_diffrn_reflns_theta_max         24.998
_diffrn_reflns_theta_min         1.678
_diffrn_ambient_temperature      150
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruke ApexII with microsource'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                2501
_reflns_number_total             3773
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'Bruker APEX2'
_computing_data_collection       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'XT (Sheldrick, 2015)'
_refine_diff_density_max         2.357
_refine_diff_density_min         -2.034
_refine_diff_density_rms         0.260
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.027
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     304
_refine_ls_number_reflns         3773
_refine_ls_number_restraints     95
_refine_ls_R_factor_all          0.1031
_refine_ls_R_factor_gt           0.0603
_refine_ls_restrained_S_all      1.029
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0773P)²+117.1800P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1460
_refine_ls_wR_factor_ref         0.1711
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 Cl1_1-O1_1 = Cl1_1-O2_1 = Cl1_1-O3_1 = Cl1_1-O4_1
 1.501 with sigma of 0.02
3. Uiso/Uaniso restraints and constraints
Uanis(O3C) \\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.01
Uanis(O1_1) \\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.01
Uanis(C15) \\sim Ueq, Uanis(C16) \\sim Ueq: with sigma of 0.005 and sigma for
terminal atoms of 0.01
Uanis(O1C) \\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.01
4. Rigid body (RIGU) restrains
 Cl1_1, O1_1, O2_1, O3_1, O4_1
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
 C15, C14, C16
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
 Cl1, O4C, O3C, O2C, O1C
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
5. Others
 Fixed Sof: Cl1(0.5) O1C(0.5) O2C(0.5) O3C(0.5) O4C(0.5) Cl1(0.5) O1(0.5)
 O2(0.5) O3(0.5) O4(0.5)
6.a Ternary CH refined with riding coordinates:
 C9(H9), C14(H14)
6.b Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C5(H5), C6(H6)
6.c Idealised Me refined as rotating group:
 C10(H10A,H10B,H10C), C11(H11A,H11B,H11C), C15(H15A,H15B,H15C), C16(H16A,H16B,
 H16C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.21485(8) 0.64125(4) 0.40280(11) 0.0366(3) Uani 1 1 d . . . . .
Ag2 Ag 0.250000 0.750000 0.500000 0.0282(4) Uani 1 2 d S T P . .
Ag3 Ag 0.44893(8) 0.76248(4) 0.52667(13) 0.0509(4) Uani 1 1 d . . . . .
Ag4 Ag 0.500000 0.81093(6) 0.750000 0.0481(5) Uani 1 2 d S T P . .
Ag5 Ag 0.63448(9) 0.72115(4) 0.74666(10) 0.0415(3) Uani 1 1 d . . . . .
C1 C 0.4650(10) 0.6346(5) 0.5961(12) 0.027(3) Uani 1 1 d . . . . .
C2 C 0.4267(9) 0.5759(5) 0.5699(12) 0.024(3) Uani 1 1 d . . . . .
C3 C 0.2905(11) 0.5158(5) 0.4715(13) 0.038(4) Uani 1 1 d . . . . .
H3 H 0.220712 0.509737 0.419599 0.046 Uiso 1 1 calc R . . . .
C4 C 0.3544(11) 0.4717(5) 0.5203(12) 0.040(4) Uani 1 1 d . . . . .
H4 H 0.328030 0.436175 0.502645 0.048 Uiso 1 1 calc R . . . .
C5 C 0.4586(11) 0.4797(5) 0.5962(12) 0.037(3) Uani 1 1 d . . . . .
H5 H 0.503172 0.449978 0.627601 0.044 Uiso 1 1 calc R . . . .
C6 C 0.4940(11) 0.5330(5) 0.6236(13) 0.037(3) Uani 1 1 d . . . . .
H6 H 0.563440 0.539910 0.678393 0.044 Uiso 1 1 calc R . . . .
C7 C 0.2928(9) 0.8115(5) 0.4312(12) 0.027(3) Uani 1 1 d . . . . .
C8 C 0.3309(10) 0.8457(5) 0.4056(13) 0.032(3) Uani 1 1 d . . . . .
C9 C 0.3642(15) 0.8919(6) 0.3661(18) 0.055(5) Uani 1 1 d . . . . .
H9 H 0.427816 0.906256 0.440895 0.066 Uiso 1 1 calc R . . . .
C10 C 0.386(2) 0.8725(9) 0.282(2) 0.109(10) Uani 1 1 d . . . . .
H10A H 0.422288 0.838106 0.311675 0.164 Uiso 1 1 calc GR . . . .
H10B H 0.427358 0.899193 0.277887 0.164 Uiso 1 1 calc GR . . . .
H10C H 0.323745 0.867281 0.199878 0.164 Uiso 1 1 calc GR . . . .
C11 C 0.2876(16) 0.9378(7) 0.3129(18) 0.074(6) Uani 1 1 d . . . . .
H11A H 0.223156 0.924446 0.242058 0.112 Uiso 1 1 calc GR . . . .
H11B H 0.310012 0.967485 0.287717 0.112 Uiso 1 1 calc GR . . . .
H11C H 0.280679 0.950670 0.375043 0.112 Uiso 1 1 calc GR . . . .
C12 C 0.6028(10) 0.8106(5) 0.7052(14) 0.043(4) Uani 1 1 d . . . . .
C13 C 0.6537(10) 0.8351(5) 0.6800(14) 0.038(3) Uani 1 1 d . . . . .
C14 C 0.7087(13) 0.8625(6) 0.6398(17) 0.052(4) Uani 1 1 d . U . . .
H14 H 0.715275 0.833876 0.593661 0.063 Uiso 1 1 calc R . . . .
C15 C 0.646(2) 0.9079(13) 0.542(3) 0.145(9) Uani 1 1 d . U . . .
H15A H 0.574897 0.900835 0.499091 0.218 Uiso 1 1 calc GR . . . .
H15B H 0.660994 0.907928 0.482898 0.218 Uiso 1 1 calc GR . . . .
H15C H 0.663155 0.943050 0.582405 0.218 Uiso 1 1 calc GR . . . .
C16 C 0.8115(18) 0.8793(12) 0.734(2) 0.111(7) Uani 1 1 d . U . . .
H16A H 0.812174 0.908198 0.783069 0.167 Uiso 1 1 calc GR . . . .
H16B H 0.841255 0.892367 0.695012 0.167 Uiso 1 1 calc GR . . . .
H16C H 0.849852 0.848435 0.786475 0.167 Uiso 1 1 calc GR . . . .
Cl1 Cl 0.6147(5) 0.7133(3) 0.4612(6) 0.0326(15) Uani 0.5 1 d . U . . .
N1 N 0.3256(8) 0.5687(4) 0.4962(9) 0.030(3) Uani 1 1 d . . . . .
O1 O 0.4035(7) 0.6718(3) 0.5311(9) 0.036(2) Uani 1 1 d . . . . .
O2 O 0.5582(7) 0.6400(3) 0.6798(9) 0.038(2) Uani 1 1 d . . . . .
O1C O 0.5086(17) 0.7449(9) 0.404(2) 0.054(5) Uani 0.5 1 d . U . . .
O2C O 0.6900(18) 0.7155(10) 0.590(2) 0.057(5) Uani 0.5 1 d . U . . .
O3C O 0.6374(19) 0.7424(10) 0.398(2) 0.058(5) Uani 0.5 1 d . U . . .
O4C O 0.5938(17) 0.6636(9) 0.4228(19) 0.053(5) Uani 0.5 1 d . U . . .
Cl1_1 Cl 0.9988(10) 0.5430(2) 0.2745(9) 0.030(3) Uani 0.5 1 d D U . A -1
O1_1 O 0.941(2) 0.5755(14) 0.158(2) 0.033(7) Uani 0.5 1 d D U . A -1
O2_1 O 1.086(2) 0.5740(15) 0.377(3) 0.047(8) Uani 0.5 1 d D U . A -1
O3_1 O 1.0363(17) 0.4946(8) 0.251(3) 0.070(7) Uani 0.5 1 d D U . A -1
O4_1 O 0.9320(15) 0.5282(11) 0.308(2) 0.062(6) Uani 0.5 1 d D U . A -1


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Ag2 2.8460(14) . ?
Ag1 Ag4 3.0558(16) 7_566 ?
Ag1 C7 2.577(13) 7_566 ?
Ag1 C12 2.434(14) 8_465 ?
Ag1 C13 2.584(15) 8_465 ?
Ag1 N1 2.290(11) . ?
Ag1 O1 2.594(9) . ?
Ag2 Ag3 3.0882(17) 7_566 ?
Ag2 Ag3 3.0882(17) . ?
Ag2 Ag5 2.8109(15) 8_465 ?
Ag2 Ag5 2.8109(15) 2_656 ?
Ag2 C7 2.089(13) 7_566 ?
Ag2 C7 2.089(13) . ?
Ag3 Ag4 2.8381(18) . ?
Ag3 Ag5 2.8653(18) . ?
Ag3 C7 2.388(12) . ?
Ag3 C8 2.589(13) . ?
Ag3 C12 2.495(14) . ?
Ag3 O1 2.337(8) . ?
Ag3 O1C 2.41(2) . ?
Ag4 Ag5 3.1264(18) 2_656 ?
Ag4 Ag5 3.1265(18) . ?
Ag4 C12 2.110(16) 2_656 ?
Ag4 C12 2.110(16) . ?
Ag5 C7 2.407(12) 8_566 ?
Ag5 C12 2.225(13) . ?
Ag5 O2 2.216(9) . ?
C1 C2 1.513(16) . ?
C1 O1 1.240(15) . ?
C1 O2 1.249(15) . ?
C2 C6 1.367(17) . ?
C2 N1 1.341(16) . ?
C3 C4 1.362(19) . ?
C3 N1 1.365(15) . ?
C4 C5 1.38(2) . ?
C5 C6 1.377(18) . ?
C7 C8 1.209(18) . ?
C8 C9 1.480(19) . ?
C9 C10 1.46(2) . ?
C9 C11 1.50(3) . ?
C12 C13 1.23(2) . ?
C13 C14 1.46(2) . ?
C14 C15 1.54(3) . ?
C14 C16 1.43(3) . ?
Cl1 O1C 1.62(2) . ?
Cl1 O2C 1.40(2) . ?
Cl1 O3C 1.32(2) . ?
Cl1 O4C 1.28(2) . ?
Cl1_1 O1_1 1.481(17) . ?
Cl1_1 O2_1 1.463(17) . ?
Cl1_1 O3_1 1.449(15) . ?
Cl1_1 O4_1 1.460(16) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag2 Ag1 Ag4 77.85(4) . 7_566 ?
C7 Ag1 Ag2 45.0(3) 7_566 . ?
C7 Ag1 Ag4 76.9(3) 7_566 7_566 ?
C7 Ag1 C13 135.7(4) 7_566 8_465 ?
C7 Ag1 O1 87.7(3) 7_566 . ?
C12 Ag1 Ag2 82.3(3) 8_465 . ?
C12 Ag1 Ag4 43.4(4) 8_465 7_566 ?
C12 Ag1 C7 109.3(5) 8_465 7_566 ?
C12 Ag1 C13 28.2(5) 8_465 8_465 ?
C12 Ag1 O1 114.0(4) 8_465 . ?
C13 Ag1 Ag2 98.9(3) 8_465 . ?
C13 Ag1 Ag4 69.5(3) 8_465 7_566 ?
C13 Ag1 O1 100.5(4) 8_465 . ?
N1 Ag1 Ag2 125.9(2) . . ?
N1 Ag1 Ag4 151.5(3) . 7_566 ?
N1 Ag1 C7 107.8(4) . 7_566 ?
N1 Ag1 C12 142.9(5) . 8_465 ?
N1 Ag1 C13 115.6(4) . 8_465 ?
N1 Ag1 O1 67.4(3) . . ?
O1 Ag1 Ag2 66.31(19) . . ?
O1 Ag1 Ag4 141.01(19) . 7_566 ?
Ag1 Ag2 Ag1 180.0 7_566 . ?
Ag1 Ag2 Ag3 93.04(3) . . ?
Ag1 Ag2 Ag3 86.96(3) . 7_566 ?
Ag1 Ag2 Ag3 86.96(3) 7_566 . ?
Ag1 Ag2 Ag3 93.04(3) 7_566 7_566 ?
Ag3 Ag2 Ag3 180.0 7_566 . ?
Ag5 Ag2 Ag1 82.70(4) 2_656 7_566 ?
Ag5 Ag2 Ag1 97.30(4) 8_465 7_566 ?
Ag5 Ag2 Ag1 82.70(4) 8_465 . ?
Ag5 Ag2 Ag1 97.30(4) 2_656 . ?
Ag5 Ag2 Ag3 90.80(4) 8_465 . ?
Ag5 Ag2 Ag3 89.20(4) 8_465 7_566 ?
Ag5 Ag2 Ag3 90.80(4) 2_656 7_566 ?
Ag5 Ag2 Ag3 89.20(4) 2_656 . ?
Ag5 Ag2 Ag5 180.0 8_465 2_656 ?
C7 Ag2 Ag1 119.3(3) . . ?
C7 Ag2 Ag1 119.3(3) 7_566 7_566 ?
C7 Ag2 Ag1 60.7(3) 7_566 . ?
C7 Ag2 Ag1 60.7(3) . 7_566 ?
C7 Ag2 Ag3 129.4(3) 7_566 . ?
C7 Ag2 Ag3 129.5(3) . 7_566 ?
C7 Ag2 Ag3 50.6(3) 7_566 7_566 ?
C7 Ag2 Ag3 50.5(3) . . ?
C7 Ag2 Ag5 123.4(3) 7_566 8_465 ?
C7 Ag2 Ag5 56.6(3) . 8_465 ?
C7 Ag2 Ag5 123.4(3) . 2_656 ?
C7 Ag2 Ag5 56.6(3) 7_566 2_656 ?
C7 Ag2 C7 180.0 . 7_566 ?
Ag4 Ag3 Ag2 77.43(3) . . ?
Ag4 Ag3 Ag5 66.48(5) . . ?
Ag5 Ag3 Ag2 118.93(6) . . ?
C7 Ag3 Ag2 42.5(3) . . ?
C7 Ag3 Ag4 84.3(3) . . ?
C7 Ag3 Ag5 149.7(3) . . ?
C7 Ag3 C8 27.7(4) . . ?
C7 Ag3 C12 115.2(4) . . ?
C7 Ag3 O1C 118.1(6) . . ?
C8 Ag3 Ag2 70.2(3) . . ?
C8 Ag3 Ag4 88.5(3) . . ?
C8 Ag3 Ag5 148.5(3) . . ?
C12 Ag3 Ag2 123.4(4) . . ?
C12 Ag3 Ag4 46.1(4) . . ?
C12 Ag3 Ag5 48.4(3) . . ?
C12 Ag3 C8 100.5(4) . . ?
O1 Ag3 Ag2 65.0(2) . . ?
O1 Ag3 Ag4 105.0(3) . . ?
O1 Ag3 Ag5 78.6(2) . . ?
O1 Ag3 C7 103.0(4) . . ?
O1 Ag3 C8 128.4(4) . . ?
O1 Ag3 C12 124.9(4) . . ?
O1 Ag3 O1C 96.8(6) . . ?
O1C Ag3 Ag2 138.0(5) . . ?
O1C Ag3 Ag4 144.4(5) . . ?
O1C Ag3 Ag5 91.3(6) . . ?
O1C Ag3 C8 99.8(6) . . ?
O1C Ag3 C12 98.3(7) . . ?
Ag1 Ag4 Ag1 135.35(7) 8_566 7_566 ?
Ag1 Ag4 Ag5 74.38(4) 8_566 . ?
Ag1 Ag4 Ag5 143.02(4) 8_566 2_656 ?
Ag1 Ag4 Ag5 143.02(4) 7_566 . ?
Ag1 Ag4 Ag5 74.38(4) 7_566 2_656 ?
Ag3 Ag4 Ag1 110.76(3) . 8_566 ?
Ag3 Ag4 Ag1 87.73(3) 2_656 8_566 ?
Ag3 Ag4 Ag1 110.76(3) 2_656 7_566 ?
Ag3 Ag4 Ag1 87.73(3) . 7_566 ?
Ag3 Ag4 Ag3 131.04(8) 2_656 . ?
Ag3 Ag4 Ag5 57.18(4) . . ?
Ag3 Ag4 Ag5 57.18(4) 2_656 2_656 ?
Ag3 Ag4 Ag5 87.96(5) 2_656 . ?
Ag3 Ag4 Ag5 87.96(5) . 2_656 ?
Ag5 Ag4 Ag5 91.61(7) 2_656 . ?
C12 Ag4 Ag1 127.8(4) 2_656 8_566 ?
C12 Ag4 Ag1 52.4(4) . 8_566 ?
C12 Ag4 Ag1 127.8(4) . 7_566 ?
C12 Ag4 Ag1 52.4(4) 2_656 7_566 ?
C12 Ag4 Ag3 121.4(4) 2_656 . ?
C12 Ag4 Ag3 58.4(4) 2_656 2_656 ?
C12 Ag4 Ag3 58.4(4) . . ?
C12 Ag4 Ag3 121.4(4) . 2_656 ?
C12 Ag4 Ag5 134.3(4) . 2_656 ?
C12 Ag4 Ag5 45.3(4) . . ?
C12 Ag4 Ag5 45.3(4) 2_656 2_656 ?
C12 Ag4 Ag5 134.3(4) 2_656 . ?
C12 Ag4 C12 179.6(7) 2_656 . ?
Ag2 Ag5 Ag3 133.34(5) 2_656 . ?
Ag2 Ag5 Ag4 77.18(3) 2_656 . ?
Ag3 Ag5 Ag4 56.34(4) . . ?
C7 Ag5 Ag2 46.4(3) 8_566 2_656 ?
C7 Ag5 Ag3 178.4(3) 8_566 . ?
C7 Ag5 Ag4 123.5(3) 8_566 . ?
C12 Ag5 Ag2 86.9(4) . 2_656 ?
C12 Ag5 Ag3 57.0(4) . . ?
C12 Ag5 Ag4 42.4(4) . . ?
C12 Ag5 C7 121.7(5) . 8_566 ?
O2 Ag5 Ag2 121.2(3) . 2_656 ?
O2 Ag5 Ag3 84.3(2) . . ?
O2 Ag5 Ag4 113.1(3) . . ?
O2 Ag5 C7 97.1(4) . 8_566 ?
O2 Ag5 C12 140.9(4) . . ?
O1 C1 C2 118.2(11) . . ?
O1 C1 O2 126.8(11) . . ?
O2 C1 C2 114.9(11) . . ?
C6 C2 C1 120.2(12) . . ?
N1 C2 C1 116.9(10) . . ?
N1 C2 C6 122.9(11) . . ?
C4 C3 N1 122.1(13) . . ?
C3 C4 C5 120.0(12) . . ?
C6 C5 C4 117.8(13) . . ?
C2 C6 C5 119.7(13) . . ?
Ag2 C7 Ag1 74.3(4) . 7_566 ?
Ag2 C7 Ag3 86.9(4) . . ?
Ag2 C7 Ag5 77.0(4) . 8_465 ?
Ag3 C7 Ag1 110.7(5) . 7_566 ?
Ag3 C7 Ag5 122.5(5) . 8_465 ?
Ag5 C7 Ag1 116.8(5) 8_465 7_566 ?
C8 C7 Ag1 104.1(9) . 7_566 ?
C8 C7 Ag2 171.1(11) . . ?
C8 C7 Ag3 85.4(9) . . ?
C8 C7 Ag5 111.1(10) . 8_465 ?
C7 C8 Ag3 66.8(8) . . ?
C7 C8 C9 172.1(15) . . ?
C9 C8 Ag3 121.1(11) . . ?
C8 C9 C11 110.2(14) . . ?
C10 C9 C8 110.6(13) . . ?
C10 C9 C11 113.6(18) . . ?
Ag1 C12 Ag3 159.8(8) 8_566 . ?
Ag4 C12 Ag1 84.2(6) . 8_566 ?
Ag4 C12 Ag3 75.6(4) . . ?
Ag4 C12 Ag5 92.3(6) . . ?
Ag5 C12 Ag1 106.6(6) . 8_566 ?
Ag5 C12 Ag3 74.5(4) . . ?
C13 C12 Ag1 82.7(10) . 8_566 ?
C13 C12 Ag3 115.3(12) . . ?
C13 C12 Ag4 150.9(11) . . ?
C13 C12 Ag5 116.4(11) . . ?
C12 C13 Ag1 69.1(10) . 8_566 ?
C12 C13 C14 175.4(16) . . ?
C14 C13 Ag1 115.4(10) . 8_566 ?
C13 C14 C15 113.2(17) . . ?
C16 C14 C13 117.9(17) . . ?
C16 C14 C15 112.3(19) . . ?
O2C Cl1 O1C 118.2(13) . . ?
O3C Cl1 O1C 94.8(14) . . ?
O3C Cl1 O2C 113.2(15) . . ?
O4C Cl1 O1C 107.7(14) . . ?
O4C Cl1 O2C 111.0(14) . . ?
O4C Cl1 O3C 110.9(14) . . ?
C2 N1 Ag1 122.1(8) . . ?
C2 N1 C3 117.2(11) . . ?
C3 N1 Ag1 120.6(9) . . ?
Ag3 O1 Ag1 121.8(4) . . ?
C1 O1 Ag1 113.8(8) . . ?
C1 O1 Ag3 124.4(8) . . ?
C1 O2 Ag5 123.2(8) . . ?
Cl1 O1C Ag3 121.8(12) . . ?
O2_1 Cl1_1 O1_1 111.4(15) . . ?
O3_1 Cl1_1 O1_1 106.8(19) . . ?
O3_1 Cl1_1 O2_1 109(2) . . ?
O3_1 Cl1_1 O4_1 111.6(18) . . ?
O4_1 Cl1_1 O1_1 109.1(18) . . ?
O4_1 Cl1_1 O2_1 109.2(19) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1_a
_database_code_depnum_ccdc_archive 'CCDC 1902312'
loop_
_audit_author_name
_audit_author_address
'Andreas Orthaber'
;Uppsala University
Sweden
;
_audit_update_record             
;
2019-03-11 deposited with the CCDC.	2019-10-14 downloaded from the CCDC.
;
# start Validation Reply Form
_vrf_PLAT602_1_a                 
;
PROBLEM: VERY LARGE Solvent Accessible VOID(S) in Structure        ! Info
RESPONSE: Indeed this crystal has a large void, however no electron density was located therein. (attempts to mask the void gave 0 electron count thus did not change the refinement)
;
# Added during the CSD deposition process: Monday 11 March 2019 09:19 AM
# end Validation Reply Form

_audit_creation_date             2019-03-06
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/1
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C38 H50 Ag7 N2 O5, C F3 O3 S'
_chemical_formula_sum            'C39 H50 Ag7 F3 N2 O8 S'
_chemical_formula_weight         1518.96
_chemical_absolute_configuration ?
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           43
_space_group_name_H-M_alt        'F d d 2'
_space_group_name_Hall           'F 2 -2d'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, z'
'x+1/4, -y+1/4, z+1/4'
'-x+1/4, y+1/4, z+1/4'
'x, y+1/2, z+1/2'
'-x, -y+1/2, z+1/2'
'x+1/4, -y+3/4, z+3/4'
'-x+1/4, y+3/4, z+3/4'
'x+1/2, y, z+1/2'
'-x+1/2, -y, z+1/2'
'x+3/4, -y+1/4, z+3/4'
'-x+3/4, y+1/4, z+3/4'
'x+1/2, y+1/2, z'
'-x+1/2, -y+1/2, z'
'x+3/4, -y+3/4, z+1/4'
'-x+3/4, y+3/4, z+1/4'

_cell_length_a                   38.814(6)
_cell_length_b                   53.264(8)
_cell_length_c                   9.9806(15)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     20634(5)
_cell_formula_units_Z            16
_cell_measurement_reflns_used    7081
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      22.80
_cell_measurement_theta_min      2.23
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    2.697
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.5329
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.956
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       plate
_exptl_crystal_F_000             11744
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.02
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0880
_diffrn_reflns_av_unetI/netI     0.0717
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       46
_diffrn_reflns_limit_h_min       -46
_diffrn_reflns_limit_k_max       63
_diffrn_reflns_limit_k_min       -63
_diffrn_reflns_limit_l_max       9
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            41137
_diffrn_reflns_point_group_measured_fraction_full 0.935
_diffrn_reflns_point_group_measured_fraction_max 0.934
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.246
_diffrn_reflns_theta_min         1.529
_diffrn_ambient_temperature      150.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.759
_reflns_Friedel_fraction_full    0.861
_reflns_Friedel_fraction_max     0.860
_reflns_number_gt                7437
_reflns_number_total             8717
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'XT (Sheldrick, 2015)'
_refine_diff_density_max         1.382
_refine_diff_density_min         -1.133
_refine_diff_density_rms         0.207
_refine_ls_abs_structure_details 
;
 Flack x determined using 2565 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.07(3)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.119
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     558
_refine_ls_number_reflns         8717
_refine_ls_number_restraints     61
_refine_ls_R_factor_all          0.0768
_refine_ls_R_factor_gt           0.0645
_refine_ls_restrained_S_all      1.119
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0395P)²+944.1216P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1276
_refine_ls_wR_factor_ref         0.1321
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 O1S-C1S
 1.33 with sigma of 0.02
 C1S-C2S
 1.45 with sigma of 0.02
 O1S-H1S
 1.1 with sigma of 0.02
 S1-O1A \\sim S1-O2A \\sim S1-O3A
 with sigma of 0.02
3. Uiso/Uaniso restraints and constraints
Uanis(C1) \\sim Ueq, Uanis(C2) \\sim Ueq, Uanis(C7C) \\sim Ueq, Uanis(C24)
\\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.01
Uanis(C9) \\sim Ueq, Uanis(C6) \\sim Ueq: with sigma of 0.005 and sigma for
terminal atoms of 0.01
4.a Secondary CH2 refined with riding coordinates:
 C1S(H1SA,H1SB)
4.b Aromatic/amide H refined with riding coordinates:
 C1C(H1C), C2C(H2C), C3C(H3C), C4C(H4CA), C9C(H9C), C10C(H10D), C11C(H11D),
 C12C(H12D)
4.c Idealised Me refined as rotating group:
 C4(H4A,H4B,H4C), C5(H5A,H5B,H5C), C6(H6A,H6B,H6C), C10(H10A,H10B,H10C),
 C11(H11A,H11B,H11C), C12(H12A,H12B,H12C), C16(H16A,H16B,H16C), C17(H17A,H17B,
 H17C), C18(H18A,H18B,H18C), C22(H22A,H22B,H22C), C23(H23A,H23B,H23C), C24(H24A,
 H24B,H24C), C2S(H2SA,H2SB,H2SC)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.81435(4) 0.47217(3) 0.78773(17) 0.0307(4) Uani 1 1 d . . . . .
Ag2 Ag 0.76002(4) 0.54619(3) 1.16729(17) 0.0317(4) Uani 1 1 d . . . . .
Ag3 Ag 0.73957(4) 0.52805(3) 0.86838(18) 0.0281(4) Uani 1 1 d . . . . .
Ag4 Ag 0.77137(4) 0.50471(2) 0.61947(17) 0.0265(4) Uani 1 1 d . . . . .
Ag5 Ag 0.78641(4) 0.54907(3) 0.45408(18) 0.0331(4) Uani 1 1 d . . . . .
Ag6 Ag 0.70819(4) 0.53608(3) 0.57780(17) 0.0306(4) Uani 1 1 d . . . . .
Ag7 Ag 0.72119(4) 0.57254(3) 0.37293(19) 0.0328(4) Uani 1 1 d . . . . .
C1 C 0.7899(5) 0.4676(3) 0.571(2) 0.023(4) Uani 1 1 d . U . . .
C2 C 0.8091(5) 0.4528(4) 0.521(2) 0.029(5) Uani 1 1 d . U . . .
C3 C 0.8336(6) 0.4331(4) 0.479(3) 0.045(6) Uani 1 1 d . . . . .
C4 C 0.8305(6) 0.4105(4) 0.574(3) 0.048(7) Uani 1 1 d . . . . .
H4A H 0.835821 0.415802 0.666156 0.073 Uiso 1 1 calc GR . . . .
H4B H 0.846761 0.397412 0.546706 0.073 Uiso 1 1 calc GR . . . .
H4C H 0.806974 0.403846 0.571004 0.073 Uiso 1 1 calc GR . . . .
C5 C 0.8288(6) 0.4265(4) 0.335(3) 0.053(8) Uani 1 1 d . . . . .
H5A H 0.806452 0.418332 0.322655 0.080 Uiso 1 1 calc GR . . . .
H5B H 0.847235 0.415071 0.306771 0.080 Uiso 1 1 calc GR . . . .
H5C H 0.829747 0.441831 0.280516 0.080 Uiso 1 1 calc GR . . . .
C6 C 0.8704(5) 0.4445(4) 0.496(3) 0.042(6) Uani 1 1 d . U . . .
H6A H 0.869307 0.462719 0.485076 0.063 Uiso 1 1 calc GR . . . .
H6B H 0.885739 0.437298 0.428312 0.063 Uiso 1 1 calc GR . . . .
H6C H 0.879162 0.440456 0.585703 0.063 Uiso 1 1 calc GR . . . .
C7 C 0.7630(5) 0.5421(3) 0.675(2) 0.025(4) Uani 1 1 d . . . . .
C8 C 0.7688(5) 0.5634(4) 0.710(2) 0.032(5) Uani 1 1 d . . . . .
C9 C 0.7793(6) 0.5889(4) 0.767(2) 0.034(5) Uani 1 1 d . U . . .
C10 C 0.8186(6) 0.5905(4) 0.756(3) 0.057(8) Uani 1 1 d . . . . .
H10A H 0.827011 0.604541 0.809591 0.086 Uiso 1 1 calc GR . . . .
H10B H 0.824986 0.593087 0.661566 0.086 Uiso 1 1 calc GR . . . .
H10C H 0.828849 0.574802 0.787908 0.086 Uiso 1 1 calc GR . . . .
C11 C 0.7690(6) 0.5931(3) 0.905(2) 0.037(6) Uani 1 1 d . . . . .
H11A H 0.744120 0.590482 0.913797 0.055 Uiso 1 1 calc GR . . . .
H11B H 0.774788 0.610291 0.931391 0.055 Uiso 1 1 calc GR . . . .
H11C H 0.781194 0.581233 0.963658 0.055 Uiso 1 1 calc GR . . . .
C12 C 0.7617(6) 0.6077(3) 0.672(2) 0.038(6) Uani 1 1 d . . . . .
H12A H 0.739664 0.600767 0.641163 0.057 Uiso 1 1 calc GR . . . .
H12B H 0.776587 0.610880 0.594485 0.057 Uiso 1 1 calc GR . . . .
H12C H 0.757487 0.623540 0.719499 0.057 Uiso 1 1 calc GR . . . .
C13 C 0.6731(5) 0.5591(3) 0.441(3) 0.036(6) Uani 1 1 d . . . . .
C14 C 0.6429(5) 0.5608(3) 0.460(2) 0.024(5) Uani 1 1 d . . . . .
C15 C 0.6049(5) 0.5637(4) 0.489(2) 0.027(5) Uani 1 1 d . . . . .
C16 C 0.5923(6) 0.5424(6) 0.574(3) 0.073(10) Uani 1 1 d . . . . .
H16A H 0.572847 0.548046 0.629151 0.110 Uiso 1 1 calc GR . . . .
H16B H 0.610954 0.536596 0.632981 0.110 Uiso 1 1 calc GR . . . .
H16C H 0.584840 0.528499 0.516663 0.110 Uiso 1 1 calc GR . . . .
C17 C 0.5856(7) 0.5656(8) 0.371(4) 0.117(16) Uani 1 1 d . . . . .
H17A H 0.563885 0.574345 0.389138 0.176 Uiso 1 1 calc GR . . . .
H17B H 0.580572 0.548712 0.336351 0.176 Uiso 1 1 calc GR . . . .
H17C H 0.598715 0.574976 0.303396 0.176 Uiso 1 1 calc GR . . . .
C18 C 0.5965(8) 0.5886(6) 0.550(6) 0.15(2) Uani 1 1 d . . . . .
H18A H 0.571409 0.590888 0.550828 0.223 Uiso 1 1 calc GR . . . .
H18B H 0.607147 0.601970 0.497013 0.223 Uiso 1 1 calc GR . . . .
H18C H 0.605255 0.589194 0.641953 0.223 Uiso 1 1 calc GR . . . .
C19 C 0.7711(5) 0.5795(3) 0.303(2) 0.020(4) Uani 1 1 d . . . . .
C20 C 0.7947(5) 0.5938(4) 0.282(3) 0.039(6) Uani 1 1 d . . . . .
C21 C 0.8236(5) 0.6126(4) 0.259(3) 0.043(6) Uani 1 1 d . . . . .
C22 C 0.8492(8) 0.6007(7) 0.168(3) 0.092(12) Uani 1 1 d . . . . .
H22A H 0.839918 0.600143 0.076503 0.139 Uiso 1 1 calc GR . . . .
H22B H 0.854140 0.583642 0.198551 0.139 Uiso 1 1 calc GR . . . .
H22C H 0.870536 0.610616 0.168197 0.139 Uiso 1 1 calc GR . . . .
C23 C 0.8355(8) 0.6216(7) 0.394(3) 0.099(14) Uani 1 1 d . . . . .
H23A H 0.834667 0.607611 0.458087 0.149 Uiso 1 1 calc GR . . . .
H23B H 0.820388 0.635118 0.425274 0.149 Uiso 1 1 calc GR . . . .
H23C H 0.859185 0.627820 0.387467 0.149 Uiso 1 1 calc GR . . . .
C24 C 0.8068(9) 0.6350(6) 0.187(4) 0.099(12) Uani 1 1 d . U . . .
H24A H 0.821566 0.649859 0.196350 0.149 Uiso 1 1 calc GR . . . .
H24B H 0.784223 0.638421 0.226246 0.149 Uiso 1 1 calc GR . . . .
H24C H 0.804081 0.631071 0.091308 0.149 Uiso 1 1 calc GR . . . .
N1 N 0.8544(4) 0.5049(3) 0.8006(18) 0.030(4) Uani 1 1 d . . . . .
N2 N 0.6562(5) 0.4627(3) 0.9406(18) 0.032(4) Uani 1 1 d . . . . .
C1C C 0.8851(6) 0.5054(4) 0.741(3) 0.048(7) Uani 1 1 d . . . . .
H1C H 0.888281 0.493999 0.668454 0.058 Uiso 1 1 calc R . . . .
C2C C 0.9121(6) 0.5201(4) 0.770(3) 0.044(6) Uani 1 1 d . . . . .
H2C H 0.932804 0.519284 0.719541 0.053 Uiso 1 1 calc R . . . .
C3C C 0.9088(6) 0.5360(4) 0.873(3) 0.045(6) Uani 1 1 d . . . . .
H3C H 0.927655 0.546095 0.901100 0.055 Uiso 1 1 calc R . . . .
C4C C 0.8763(5) 0.5374(4) 0.938(2) 0.032(5) Uani 1 1 d . . . . .
H4CA H 0.872818 0.549240 1.008062 0.038 Uiso 1 1 calc R . . . .
C5C C 0.8496(5) 0.5214(3) 0.900(2) 0.032(6) Uani 1 1 d . . . . .
C6C C 0.8150(5) 0.5231(3) 0.962(2) 0.023(4) Uani 1 1 d . . . . .
C7C C 0.6791(4) 0.4950(3) 0.780(2) 0.018(4) Uani 1 1 d . U . . .
C8C C 0.6493(5) 0.4802(3) 0.839(2) 0.024(5) Uani 1 1 d . . . . .
C9C C 0.6151(6) 0.4848(4) 0.797(3) 0.042(6) Uani 1 1 d . . . . .
H9C H 0.610238 0.497608 0.733797 0.051 Uiso 1 1 calc R . . . .
C10C C 0.5892(6) 0.4704(4) 0.850(3) 0.045(6) Uani 1 1 d . . . . .
H10D H 0.566304 0.471777 0.816498 0.054 Uiso 1 1 calc R . . . .
C11C C 0.5968(6) 0.4541(6) 0.951(3) 0.066(9) Uani 1 1 d . . . . .
H11D H 0.578859 0.444862 0.993163 0.079 Uiso 1 1 calc R . . . .
C12C C 0.6299(6) 0.4510(4) 0.993(3) 0.049(7) Uani 1 1 d . . . . .
H12D H 0.634050 0.439665 1.064402 0.059 Uiso 1 1 calc R . . . .
O1S O 0.7065(4) 0.6179(3) 0.376(3) 0.095(9) Uani 1 1 d D . . . .
O1 O 0.7929(3) 0.5065(2) 0.9305(14) 0.022(3) Uani 1 1 d . . . . .
O2 O 0.8104(4) 0.5404(2) 1.0416(15) 0.033(4) Uani 1 1 d . . . . .
O3 O 0.6698(3) 0.5131(2) 0.7092(16) 0.034(4) Uani 1 1 d . . . . .
O4 O 0.7082(3) 0.4897(2) 0.8148(15) 0.031(4) Uani 1 1 d . . . . .
C1S C 0.6756(8) 0.6297(8) 0.380(4) 0.115(15) Uani 1 1 d D . . . .
H1SA H 0.657566 0.618465 0.344365 0.138 Uiso 1 1 calc R . . . .
H1SB H 0.676428 0.644954 0.323529 0.138 Uiso 1 1 calc R . . . .
C2S C 0.6674(11) 0.6365(9) 0.513(5) 0.15(2) Uani 1 1 d D . . . .
H2SA H 0.661764 0.621390 0.564733 0.231 Uiso 1 1 calc GR . . . .
H2SB H 0.647560 0.647875 0.512962 0.231 Uiso 1 1 calc GR . . . .
H2SC H 0.687196 0.644957 0.554291 0.231 Uiso 1 1 calc GR . . . .
S1 S 0.7378(3) 0.6767(2) 0.864(2) 0.136(5) Uani 1 1 d D . . . .
O1A O 0.7373(16) 0.6773(8) 0.714(3) 0.25(3) Uani 1 1 d D . . . .
O2A O 0.7629(11) 0.6604(6) 0.929(7) 0.29(4) Uani 1 1 d D . . . .
O3A O 0.7347(13) 0.7011(7) 0.930(6) 0.28(3) Uani 1 1 d D . . . .
C1A C 0.7027(11) 0.6597(7) 0.908(6) 0.101(15) Uani 1 1 d . . . . .
F1 F 0.6977(14) 0.6574(7) 1.038(4) 0.24(2) Uani 1 1 d . . . . .
F2 F 0.6726(9) 0.6715(6) 0.870(4) 0.189(13) Uani 1 1 d . . . . .
F3 F 0.7009(6) 0.6377(5) 0.858(3) 0.136(9) Uani 1 1 d . . . . .
H1S H 0.730(2) 0.626(2) 0.420(14) 0.00(4) Uiso 1 1 d D . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Ag2 3.276(2) 10_664 ?
Ag1 Ag4 2.934(2) . ?
Ag1 Ag6 3.056(3) 10_665 ?
Ag1 Ag7 2.880(2) 10_665 ?
Ag1 C1 2.38(2) . ?
Ag1 C13 2.31(2) 10_665 ?
Ag1 N1 2.338(15) . ?
Ag1 O1 2.464(12) . ?
Ag2 Ag3 3.235(2) . ?
Ag2 Ag4 3.011(2) 10_665 ?
Ag2 Ag5 3.044(3) 1_556 ?
Ag2 Ag7 2.908(2) 1_556 ?
Ag2 C1 2.29(2) 10_665 ?
Ag2 C19 2.270(18) 1_556 ?
Ag2 O2 2.343(13) . ?
Ag3 Ag4 3.083(2) 10_665 ?
Ag3 Ag4 3.040(2) . ?
Ag3 Ag6 3.174(2) . ?
Ag3 C1 2.33(2) 10_665 ?
Ag3 C2 2.63(2) 10_665 ?
Ag3 C7 2.26(2) . ?
Ag3 C8 2.71(2) . ?
Ag3 O1 2.445(12) . ?
Ag3 O4 2.436(12) . ?
Ag4 Ag5 2.941(2) . ?
Ag4 Ag6 2.996(2) . ?
Ag4 C1 2.157(16) . ?
Ag4 C7 2.090(18) . ?
Ag5 Ag6 3.350(2) . ?
Ag5 Ag7 2.937(2) . ?
Ag5 C7 2.41(2) . ?
Ag5 C19 2.294(19) . ?
Ag5 N2 2.316(18) 10_664 ?
Ag5 O4 2.498(12) 10_664 ?
Ag6 Ag7 2.865(2) . ?
Ag6 C7 2.36(2) . ?
Ag6 C13 2.29(2) . ?
Ag6 O3 2.331(13) . ?
Ag7 C13 2.11(2) . ?
Ag7 C19 2.093(18) . ?
Ag7 O1S 2.484(16) . ?
C1 C2 1.20(3) . ?
C2 C3 1.47(3) . ?
C3 C4 1.54(3) . ?
C3 C5 1.50(4) . ?
C3 C6 1.56(3) . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 C8 1.21(3) . ?
C8 C9 1.53(3) . ?
C9 C10 1.53(3) . ?
C9 C11 1.45(3) . ?
C9 C12 1.54(3) . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 C14 1.19(3) . ?
C14 C15 1.51(3) . ?
C15 C16 1.50(3) . ?
C15 C17 1.41(4) . ?
C15 C18 1.49(3) . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 C20 1.21(3) . ?
C20 C21 1.52(3) . ?
C21 C22 1.49(4) . ?
C21 C23 1.51(4) . ?
C21 C24 1.54(4) . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
N1 C1C 1.33(3) . ?
N1 C5C 1.34(3) . ?
N2 C8C 1.40(2) . ?
N2 C12C 1.31(3) . ?
C1C H1C 0.9500 . ?
C1C C2C 1.34(3) . ?
C2C H2C 0.9500 . ?
C2C C3C 1.33(3) . ?
C3C H3C 0.9500 . ?
C3C C4C 1.42(3) . ?
C4C H4CA 0.9500 . ?
C4C C5C 1.40(3) . ?
C5C C6C 1.48(3) . ?
C6C O1 1.27(2) . ?
C6C O2 1.23(2) . ?
C7C C8C 1.52(3) . ?
C7C O3 1.25(2) . ?
C7C O4 1.22(2) . ?
C8C C9C 1.41(3) . ?
C9C H9C 0.9500 . ?
C9C C10C 1.37(3) . ?
C10C H10D 0.9500 . ?
C10C C11C 1.37(4) . ?
C11C H11D 0.9500 . ?
C11C C12C 1.36(3) . ?
C12C H12D 0.9500 . ?
O1S C1S 1.35(2) . ?
O1S H1S 1.09(3) . ?
C1S H1SA 0.9900 . ?
C1S H1SB 0.9900 . ?
C1S C2S 1.41(3) . ?
C2S H2SA 0.9800 . ?
C2S H2SB 0.9800 . ?
C2S H2SC 0.9800 . ?
S1 O1A 1.50(3) . ?
S1 O2A 1.45(3) . ?
S1 O3A 1.46(3) . ?
S1 C1A 1.69(4) . ?
C1A F1 1.31(5) . ?
C1A F2 1.38(5) . ?
C1A F3 1.28(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag4 Ag1 Ag2 57.68(5) . 10_664 ?
Ag4 Ag1 Ag6 117.68(7) . 10_665 ?
Ag6 Ag1 Ag2 93.01(6) 10_665 10_664 ?
Ag7 Ag1 Ag2 55.93(5) 10_665 10_664 ?
Ag7 Ag1 Ag4 112.66(7) 10_665 . ?
Ag7 Ag1 Ag6 57.61(5) 10_665 10_665 ?
C1 Ag1 Ag2 44.3(5) . 10_664 ?
C1 Ag1 Ag4 46.5(4) . . ?
C1 Ag1 Ag6 137.3(5) . 10_665 ?
C1 Ag1 Ag7 89.7(4) . 10_665 ?
C1 Ag1 O1 117.8(5) . . ?
C13 Ag1 Ag2 102.3(5) 10_665 10_664 ?
C13 Ag1 Ag4 157.5(5) 10_665 . ?
C13 Ag1 Ag6 48.0(6) 10_665 10_665 ?
C13 Ag1 Ag7 46.4(5) 10_665 10_665 ?
C13 Ag1 C1 127.8(7) 10_665 . ?
C13 Ag1 N1 111.1(7) 10_665 . ?
C13 Ag1 O1 103.0(6) 10_665 . ?
N1 Ag1 Ag2 146.0(4) . 10_664 ?
N1 Ag1 Ag4 88.3(4) . . ?
N1 Ag1 Ag6 104.2(4) . 10_665 ?
N1 Ag1 Ag7 156.6(4) . 10_665 ?
N1 Ag1 C1 113.0(6) . . ?
N1 Ag1 O1 68.9(5) . . ?
O1 Ag1 Ag2 97.8(3) . 10_664 ?
O1 Ag1 Ag4 72.5(3) . . ?
O1 Ag1 Ag6 57.5(3) . 10_665 ?
O1 Ag1 Ag7 106.3(3) . 10_665 ?
Ag3 Ag2 Ag1 91.90(5) . 10_665 ?
Ag4 Ag2 Ag1 55.44(5) 10_665 10_665 ?
Ag4 Ag2 Ag3 59.04(5) 10_665 . ?
Ag4 Ag2 Ag5 109.31(7) 10_665 1_556 ?
Ag5 Ag2 Ag1 88.08(6) 1_556 10_665 ?
Ag5 Ag2 Ag3 164.77(7) 1_556 . ?
Ag7 Ag2 Ag1 55.13(5) 1_556 10_665 ?
Ag7 Ag2 Ag3 131.91(7) 1_556 . ?
Ag7 Ag2 Ag4 109.68(7) 1_556 10_665 ?
Ag7 Ag2 Ag5 59.09(6) 1_556 1_556 ?
C1 Ag2 Ag1 46.5(5) 10_665 10_665 ?
C1 Ag2 Ag3 46.1(5) 10_665 . ?
C1 Ag2 Ag4 45.6(4) 10_665 10_665 ?
C1 Ag2 Ag5 134.3(5) 10_665 1_556 ?
C1 Ag2 Ag7 90.8(5) 10_665 1_556 ?
C1 Ag2 O2 116.0(6) 10_665 . ?
C19 Ag2 Ag1 100.5(5) 1_556 10_665 ?
C19 Ag2 Ag3 145.9(5) 1_556 . ?
C19 Ag2 Ag4 151.0(5) 1_556 10_665 ?
C19 Ag2 Ag5 48.5(5) 1_556 1_556 ?
C19 Ag2 Ag7 45.7(5) 1_556 1_556 ?
C19 Ag2 C1 131.5(6) 1_556 10_665 ?
C19 Ag2 O2 105.3(6) 1_556 . ?
O2 Ag2 Ag1 153.2(3) . 10_665 ?
O2 Ag2 Ag3 70.8(4) . . ?
O2 Ag2 Ag4 97.7(3) . 10_665 ?
O2 Ag2 Ag5 103.3(4) . 1_556 ?
O2 Ag2 Ag7 150.9(4) . 1_556 ?
Ag4 Ag3 Ag2 140.92(6) . . ?
Ag4 Ag3 Ag2 56.86(5) 10_665 . ?
Ag4 Ag3 Ag4 119.25(5) . 10_665 ?
Ag4 Ag3 Ag6 57.60(5) . . ?
Ag4 Ag3 Ag6 139.99(6) 10_665 . ?
Ag6 Ag3 Ag2 153.70(6) . . ?
C1 Ag3 Ag2 45.0(5) 10_665 . ?
C1 Ag3 Ag4 161.3(4) 10_665 . ?
C1 Ag3 Ag4 44.3(4) 10_665 10_665 ?
C1 Ag3 Ag6 126.1(5) 10_665 . ?
C1 Ag3 C2 27.0(6) 10_665 10_665 ?
C1 Ag3 C8 130.0(6) 10_665 . ?
C1 Ag3 O1 104.0(6) 10_665 . ?
C1 Ag3 O4 91.6(6) 10_665 . ?
C2 Ag3 Ag2 61.8(5) 10_665 . ?
C2 Ag3 Ag4 69.6(4) 10_665 10_665 ?
C2 Ag3 Ag4 157.3(5) 10_665 . ?
C2 Ag3 Ag6 101.5(4) 10_665 . ?
C2 Ag3 C8 111.6(6) 10_665 . ?
C7 Ag3 Ag2 126.2(5) . . ?
C7 Ag3 Ag4 43.4(5) . . ?
C7 Ag3 Ag4 159.5(5) . 10_665 ?
C7 Ag3 Ag6 47.9(5) . . ?
C7 Ag3 C1 154.7(6) . 10_665 ?
C7 Ag3 C2 130.8(6) . 10_665 ?
C7 Ag3 C8 26.3(6) . . ?
C7 Ag3 O1 91.8(6) . . ?
C7 Ag3 O4 106.8(6) . . ?
C8 Ag3 Ag2 103.2(5) . . ?
C8 Ag3 Ag4 157.9(5) . 10_665 ?
C8 Ag3 Ag4 68.7(4) . . ?
C8 Ag3 Ag6 62.2(5) . . ?
O1 Ag3 Ag2 72.5(3) . . ?
O1 Ag3 Ag4 69.2(3) . 10_665 ?
O1 Ag3 Ag4 70.8(3) . . ?
O1 Ag3 Ag6 128.3(3) . . ?
O1 Ag3 C2 130.0(5) . 10_665 ?
O1 Ag3 C8 96.9(6) . . ?
O4 Ag3 Ag2 125.1(3) . . ?
O4 Ag3 Ag4 68.6(3) . 10_665 ?
O4 Ag3 Ag4 71.4(4) . . ?
O4 Ag3 Ag6 73.8(3) . . ?
O4 Ag3 C2 95.4(6) . 10_665 ?
O4 Ag3 C8 131.5(6) . . ?
O4 Ag3 O1 94.9(4) . . ?
Ag1 Ag4 Ag2 66.87(5) . 10_664 ?
Ag1 Ag4 Ag3 90.26(7) . . ?
Ag1 Ag4 Ag3 102.07(6) . 10_664 ?
Ag1 Ag4 Ag5 133.09(7) . . ?
Ag1 Ag4 Ag6 150.95(8) . . ?
Ag2 Ag4 Ag3 94.27(6) 10_664 . ?
Ag2 Ag4 Ag3 64.10(5) 10_664 10_664 ?
Ag3 Ag4 Ag3 147.12(5) . 10_664 ?
Ag5 Ag4 Ag2 153.24(8) . 10_664 ?
Ag5 Ag4 Ag3 91.49(7) . 10_664 ?
Ag5 Ag4 Ag3 102.17(6) . . ?
Ag5 Ag4 Ag6 68.69(5) . . ?
Ag6 Ag4 Ag2 101.13(6) . 10_664 ?
Ag6 Ag4 Ag3 63.46(5) . . ?
Ag6 Ag4 Ag3 95.17(6) . 10_664 ?
C1 Ag4 Ag1 53.1(6) . . ?
C1 Ag4 Ag2 49.2(5) . 10_664 ?
C1 Ag4 Ag3 49.0(6) . 10_664 ?
C1 Ag4 Ag3 134.0(6) . . ?
C1 Ag4 Ag5 122.8(6) . . ?
C1 Ag4 Ag6 138.8(5) . . ?
C7 Ag4 Ag1 120.0(6) . . ?
C7 Ag4 Ag2 138.8(5) . 10_664 ?
C7 Ag4 Ag3 137.0(6) . 10_664 ?
C7 Ag4 Ag3 48.1(6) . . ?
C7 Ag4 Ag5 54.1(6) . . ?
C7 Ag4 Ag6 51.6(5) . . ?
C7 Ag4 C1 169.4(7) . . ?
Ag2 Ag5 Ag6 91.79(6) 1_554 . ?
Ag4 Ag5 Ag2 114.87(7) . 1_554 ?
Ag4 Ag5 Ag6 56.44(5) . . ?
Ag7 Ag5 Ag2 58.14(6) . 1_554 ?
Ag7 Ag5 Ag4 109.00(6) . . ?
Ag7 Ag5 Ag6 53.73(5) . . ?
C7 Ag5 Ag2 136.4(5) . 1_554 ?
C7 Ag5 Ag4 44.6(4) . . ?
C7 Ag5 Ag6 44.7(5) . . ?
C7 Ag5 Ag7 89.6(5) . . ?
C7 Ag5 O4 114.3(5) . 10_664 ?
C19 Ag5 Ag2 47.8(5) . 1_554 ?
C19 Ag5 Ag4 152.3(4) . . ?
C19 Ag5 Ag6 98.8(5) . . ?
C19 Ag5 Ag7 45.1(5) . . ?
C19 Ag5 C7 127.8(6) . . ?
C19 Ag5 N2 113.7(6) . 10_664 ?
C19 Ag5 O4 103.8(6) . 10_664 ?
N2 Ag5 Ag2 104.8(4) 10_664 1_554 ?
N2 Ag5 Ag4 90.4(4) 10_664 . ?
N2 Ag5 Ag6 146.8(4) 10_664 . ?
N2 Ag5 Ag7 158.0(5) 10_664 . ?
N2 Ag5 C7 111.9(7) 10_664 . ?
N2 Ag5 O4 70.4(5) 10_664 10_664 ?
O4 Ag5 Ag2 57.5(4) 10_664 1_554 ?
O4 Ag5 Ag4 70.4(3) 10_664 . ?
O4 Ag5 Ag6 96.3(3) 10_664 . ?
O4 Ag5 Ag7 105.7(3) 10_664 . ?
Ag1 Ag6 Ag3 162.92(6) 10_664 . ?
Ag1 Ag6 Ag5 86.55(6) 10_664 . ?
Ag3 Ag6 Ag5 90.97(6) . . ?
Ag4 Ag6 Ag1 106.59(7) . 10_664 ?
Ag4 Ag6 Ag3 58.94(5) . . ?
Ag4 Ag6 Ag5 54.87(5) . . ?
Ag7 Ag6 Ag1 58.11(5) . 10_664 ?
Ag7 Ag6 Ag3 132.52(7) . . ?
Ag7 Ag6 Ag4 109.45(7) . . ?
Ag7 Ag6 Ag5 55.76(5) . . ?
C7 Ag6 Ag1 131.7(5) . 10_664 ?
C7 Ag6 Ag3 45.4(5) . . ?
C7 Ag6 Ag4 44.0(4) . . ?
C7 Ag6 Ag5 46.0(5) . . ?
C7 Ag6 Ag7 92.4(5) . . ?
C13 Ag6 Ag1 48.7(6) . 10_664 ?
C13 Ag6 Ag3 147.9(6) . . ?
C13 Ag6 Ag4 150.4(6) . . ?
C13 Ag6 Ag5 102.0(6) . . ?
C13 Ag6 Ag7 46.7(6) . . ?
C13 Ag6 C7 135.2(7) . . ?
C13 Ag6 O3 103.7(7) . . ?
O3 Ag6 Ag1 105.9(4) . 10_664 ?
O3 Ag6 Ag3 70.2(4) . . ?
O3 Ag6 Ag4 98.8(3) . . ?
O3 Ag6 Ag5 153.5(3) . . ?
O3 Ag6 Ag7 150.4(4) . . ?
O3 Ag6 C7 114.7(6) . . ?
Ag1 Ag7 Ag2 68.94(6) 10_664 1_554 ?
Ag1 Ag7 Ag5 98.17(6) 10_664 . ?
Ag2 Ag7 Ag5 62.77(6) 1_554 . ?
Ag6 Ag7 Ag1 64.28(6) . 10_664 ?
Ag6 Ag7 Ag2 105.54(6) . 1_554 ?
Ag6 Ag7 Ag5 70.51(6) . . ?
C13 Ag7 Ag1 52.4(6) . 10_664 ?
C13 Ag7 Ag2 121.4(6) . 1_554 ?
C13 Ag7 Ag5 122.0(6) . . ?
C13 Ag7 Ag6 52.1(6) . . ?
C13 Ag7 O1S 97.1(7) . . ?
C19 Ag7 Ag1 119.4(5) . 10_664 ?
C19 Ag7 Ag2 50.9(5) . 1_554 ?
C19 Ag7 Ag5 51.0(5) . . ?
C19 Ag7 Ag6 121.5(5) . . ?
C19 Ag7 C13 170.3(7) . . ?
C19 Ag7 O1S 92.5(7) . . ?
O1S Ag7 Ag1 134.3(5) . 10_664 ?
O1S Ag7 Ag2 126.7(7) . 1_554 ?
O1S Ag7 Ag5 127.5(4) . . ?
O1S Ag7 Ag6 127.6(7) . . ?
Ag2 C1 Ag1 89.2(7) 10_664 . ?
Ag2 C1 Ag3 88.9(7) 10_664 10_664 ?
Ag3 C1 Ag1 167.1(8) 10_664 . ?
Ag4 C1 Ag1 80.5(6) . . ?
Ag4 C1 Ag2 85.2(7) . 10_664 ?
Ag4 C1 Ag3 86.7(6) . 10_664 ?
C2 C1 Ag1 101.5(15) . . ?
C2 C1 Ag2 119.3(15) . 10_664 ?
C2 C1 Ag3 90.5(16) . 10_664 ?
C2 C1 Ag4 155.3(17) . . ?
C1 C2 Ag3 62.5(13) . 10_664 ?
C1 C2 C3 172(2) . . ?
C3 C2 Ag3 125.3(15) . 10_664 ?
C2 C3 C4 110(2) . . ?
C2 C3 C5 111(2) . . ?
C2 C3 C6 106.7(17) . . ?
C4 C3 C6 107.9(19) . . ?
C5 C3 C4 114(2) . . ?
C5 C3 C6 108(2) . . ?
C3 C4 H4A 109.5 . . ?
C3 C4 H4B 109.5 . . ?
C3 C4 H4C 109.5 . . ?
H4A C4 H4B 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
C3 C5 H5A 109.5 . . ?
C3 C5 H5B 109.5 . . ?
C3 C5 H5C 109.5 . . ?
H5A C5 H5B 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C3 C6 H6A 109.5 . . ?
C3 C6 H6B 109.5 . . ?
C3 C6 H6C 109.5 . . ?
H6A C6 H6B 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
Ag3 C7 Ag5 169.3(9) . . ?
Ag3 C7 Ag6 86.7(6) . . ?
Ag4 C7 Ag3 88.5(7) . . ?
Ag4 C7 Ag5 81.3(7) . . ?
Ag4 C7 Ag6 84.5(6) . . ?
Ag6 C7 Ag5 89.3(7) . . ?
C8 C7 Ag3 97.7(16) . . ?
C8 C7 Ag4 160.3(18) . . ?
C8 C7 Ag5 93.0(15) . . ?
C8 C7 Ag6 114.4(16) . . ?
C7 C8 Ag3 56.0(13) . . ?
C7 C8 C9 173(2) . . ?
C9 C8 Ag3 120.8(14) . . ?
C8 C9 C12 103.2(18) . . ?
C10 C9 C8 106.7(17) . . ?
C10 C9 C12 111.1(19) . . ?
C11 C9 C8 114.6(18) . . ?
C11 C9 C10 110(2) . . ?
C11 C9 C12 111.2(17) . . ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C9 C11 H11A 109.5 . . ?
C9 C11 H11B 109.5 . . ?
C9 C11 H11C 109.5 . . ?
H11A C11 H11B 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C9 C12 H12A 109.5 . . ?
C9 C12 H12B 109.5 . . ?
C9 C12 H12C 109.5 . . ?
H12A C12 H12B 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
Ag6 C13 Ag1 83.3(6) . 10_664 ?
Ag7 C13 Ag1 81.2(8) . 10_664 ?
Ag7 C13 Ag6 81.2(7) . . ?
C14 C13 Ag1 111.6(16) . 10_664 ?
C14 C13 Ag6 122.2(18) . . ?
C14 C13 Ag7 153.5(16) . . ?
C13 C14 C15 177(2) . . ?
C16 C15 C14 110.7(17) . . ?
C17 C15 C14 111(2) . . ?
C17 C15 C16 111(2) . . ?
C17 C15 C18 99(3) . . ?
C18 C15 C14 112.6(19) . . ?
C18 C15 C16 112(3) . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16B 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C15 C17 H17A 109.5 . . ?
C15 C17 H17B 109.5 . . ?
C15 C17 H17C 109.5 . . ?
H17A C17 H17B 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C15 C18 H18A 109.5 . . ?
C15 C18 H18B 109.5 . . ?
C15 C18 H18C 109.5 . . ?
H18A C18 H18B 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
Ag2 C19 Ag5 83.6(6) 1_554 . ?
Ag7 C19 Ag2 83.5(6) . 1_554 ?
Ag7 C19 Ag5 83.9(6) . . ?
C20 C19 Ag2 122.2(17) . 1_554 ?
C20 C19 Ag5 111.3(16) . . ?
C20 C19 Ag7 150.4(16) . . ?
C19 C20 C21 178(2) . . ?
C20 C21 C24 106(2) . . ?
C22 C21 C20 108(2) . . ?
C22 C21 C23 118(2) . . ?
C22 C21 C24 109(3) . . ?
C23 C21 C20 107(2) . . ?
C23 C21 C24 108(3) . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22B 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C21 C23 H23A 109.5 . . ?
C21 C23 H23B 109.5 . . ?
C21 C23 H23C 109.5 . . ?
H23A C23 H23B 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C21 C24 H24A 109.5 . . ?
C21 C24 H24B 109.5 . . ?
C21 C24 H24C 109.5 . . ?
H24A C24 H24B 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C1C N1 Ag1 125.9(15) . . ?
C1C N1 C5C 116.3(18) . . ?
C5C N1 Ag1 115.9(13) . . ?
C8C N2 Ag5 114.0(12) . 10_665 ?
C12C N2 Ag5 127.0(15) . 10_665 ?
C12C N2 C8C 116.9(19) . . ?
N1 C1C H1C 116.1 . . ?
N1 C1C C2C 128(2) . . ?
C2C C1C H1C 116.1 . . ?
C1C C2C H2C 121.1 . . ?
C3C C2C C1C 118(2) . . ?
C3C C2C H2C 121.1 . . ?
C2C C3C H3C 121.0 . . ?
C2C C3C C4C 118(2) . . ?
C4C C3C H3C 121.0 . . ?
C3C C4C H4CA 119.9 . . ?
C5C C4C C3C 120(2) . . ?
C5C C4C H4CA 119.9 . . ?
N1 C5C C4C 120(2) . . ?
N1 C5C C6C 118.3(16) . . ?
C4C C5C C6C 121.6(19) . . ?
O1 C6C C5C 118.0(16) . . ?
O2 C6C C5C 116.5(16) . . ?
O2 C6C O1 125.4(19) . . ?
O3 C7C C8C 113.6(15) . . ?
O4 C7C C8C 118.4(17) . . ?
O4 C7C O3 127.5(17) . . ?
N2 C8C C7C 118.6(16) . . ?
N2 C8C C9C 120.8(19) . . ?
C9C C8C C7C 120.5(18) . . ?
C8C C9C H9C 120.7 . . ?
C10C C9C C8C 119(2) . . ?
C10C C9C H9C 120.7 . . ?
C9C C10C H10D 120.7 . . ?
C11C C10C C9C 119(2) . . ?
C11C C10C H10D 120.7 . . ?
C10C C11C H11D 119.7 . . ?
C12C C11C C10C 121(2) . . ?
C12C C11C H11D 119.7 . . ?
N2 C12C C11C 124(2) . . ?
N2 C12C H12D 117.9 . . ?
C11C C12C H12D 117.9 . . ?
Ag7 O1S H1S 101(7) . . ?
C1S O1S Ag7 131(2) . . ?
C1S O1S H1S 123(8) . . ?
Ag3 O1 Ag1 119.2(5) . . ?
C6C O1 Ag1 115.4(11) . . ?
C6C O1 Ag3 108.1(11) . . ?
C6C O2 Ag2 124.5(12) . . ?
C7C O3 Ag6 122.6(12) . . ?
Ag3 O4 Ag5 122.0(5) . 10_665 ?
C7C O4 Ag3 109.6(11) . . ?
C7C O4 Ag5 115.3(12) . 10_665 ?
O1S C1S H1SA 109.6 . . ?
O1S C1S H1SB 109.6 . . ?
O1S C1S C2S 110(3) . . ?
H1SA C1S H1SB 108.1 . . ?
C2S C1S H1SA 109.6 . . ?
C2S C1S H1SB 109.6 . . ?
C1S C2S H2SA 109.5 . . ?
C1S C2S H2SB 109.5 . . ?
C1S C2S H2SC 109.5 . . ?
H2SA C2S H2SB 109.5 . . ?
H2SA C2S H2SC 109.5 . . ?
H2SB C2S H2SC 109.5 . . ?
O1A S1 C1A 105(3) . . ?
O2A S1 O1A 118(4) . . ?
O2A S1 O3A 113(3) . . ?
O2A S1 C1A 96(3) . . ?
O3A S1 O1A 115(3) . . ?
O3A S1 C1A 107(3) . . ?
F1 C1A S1 115(4) . . ?
F1 C1A F2 101(4) . . ?
F2 C1A S1 112(3) . . ?
F3 C1A S1 115(3) . . ?
F3 C1A F1 107(4) . . ?
F3 C1A F2 105(4) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_ag_ag_200_0m_a
_database_code_depnum_ccdc_archive 'CCDC 1902310'
loop_
_audit_author_name
_audit_author_address
'Andreas Orthaber'
;Uppsala University
Sweden
;
_audit_update_record             
;
2019-03-11 deposited with the CCDC.	2019-10-14 downloaded from the CCDC.
;
# start Validation Reply Form
_vrf_RINTA01_ag_ag_200_0m_a      
;
PROBLEM: The value of Rint is greater than 0.18
RESPONSE: low diffraction quality of crystals precluded better data.
;
_vrf_PLAT020_ag_ag_200_0m_a      
;
PROBLEM: The Value of Rint is Greater Than 0.12 .........      0.204 Report
RESPONSE: low diffraction quality of crystals precluded better data.
;
_vrf_PLAT213_ag_ag_200_0m_a      
;
PROBLEM: Atom O4S             has ADP max/min Ratio .....        4.6 prolat
RESPONSE: badly define solvent atom
;
_vrf_PLAT342_ag_ag_200_0m_a      
;
PROBLEM: Low Bond Precision on  C-C Bonds ...............    0.04234 Ang.
RESPONSE: low diffraction quality of crystals precluded better data.
;
_vrf_PLAT987_ag_ag_200_0m_a      
;
PROBLEM: The Flack x is >> 0 -  Do a BASF/TWIN Refinement     Please Check
RESPONSE: twin refinement has not led to a better structure solution.
;
# Added during the CSD deposition process: Monday 11 March 2019 09:19 AM
# end Validation Reply Form

_audit_creation_date             2019-03-06
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C62 H68 Ag10 N3 O12 S6, 3(Cl O4)'
_chemical_formula_sum            'C62 H68 Ag10 Cl3 N3 O24 S6'
_chemical_formula_weight         2616.60
_chemical_absolute_configuration ?
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           19
_space_group_name_H-M_alt        'P 21 21 21'
_space_group_name_Hall           'P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'

_cell_length_a                   16.489(3)
_cell_length_b                   18.767(4)
_cell_length_c                   25.470(5)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     7882(3)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    7834
_cell_measurement_temperature    123(2)
_cell_measurement_theta_max      20.88
_cell_measurement_theta_min      2.17
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    2.762
_exptl_absorpt_correction_T_max  0.7454
_exptl_absorpt_correction_T_min  0.4902
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    2.205
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       rod
_exptl_crystal_F_000             5080
_exptl_crystal_size_max          0.38
_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.05
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.2043
_diffrn_reflns_av_unetI/netI     0.1225
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            96189
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.000
_diffrn_reflns_theta_max         25.000
_diffrn_reflns_theta_min         1.348
_diffrn_ambient_temperature      123.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.829
_reflns_Friedel_fraction_full    1.000
_reflns_Friedel_fraction_max     1.000
_reflns_number_gt                9661
_reflns_number_total             13905
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         2.527
_refine_diff_density_min         -1.958
_refine_diff_density_rms         0.275
_refine_ls_abs_structure_details 
;
 Flack x determined using 3301 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.10(3)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.082
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     987
_refine_ls_number_reflns         13905
_refine_ls_number_restraints     111
_refine_ls_R_factor_all          0.1226
_refine_ls_R_factor_gt           0.0730
_refine_ls_restrained_S_all      1.079
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0784P)²+85.9333P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1636
_refine_ls_wR_factor_ref         0.1893
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All C(H,H,H,H,H,H) groups
2. Restrained distances
 S2S-C3S = S2S-C4S
 1.78 with sigma of 0.02
 S2S-C3S \\sim S2S-C4S
 with sigma of 0.02
3. Uiso/Uaniso restraints and constraints
Uanis(C1) \\sim Ueq, Uanis(C2) \\sim Ueq, Uanis(C9) \\sim Ueq, Uanis(C11) \\sim
Ueq, Uanis(C12) \\sim Ueq, Uanis(C13) \\sim Ueq, Uanis(C18) \\sim Ueq,
Uanis(C20) \\sim Ueq, Uanis(C39) \\sim Ueq, Uanis(C40) \\sim Ueq, Uanis(C46)
\\sim Ueq, Uanis(C49) \\sim Ueq: with sigma of 0.005 and sigma for terminal
atoms of 0.01
Uanis(C25) \\sim Ueq, Uanis(C26) \\sim Ueq, Uanis(C33) \\sim Ueq, Uanis(C34)
\\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.01
Uanis(C3S) \\sim Ueq, Uanis(C4S) \\sim Ueq: with sigma of 0.005 and sigma for
terminal atoms of 0.01
Uanis(C3S) = Uanis(C4S)
4. Others
 Sof(H3SD)=Sof(H3SE)=Sof(H3SF)=Sof(H4SD)=Sof(H4SE)=Sof(H4SF)=Sof(S2T)=1-FVAR(1)
 Sof(H3SA)=Sof(H3SB)=Sof(H3SC)=Sof(H4SA)=Sof(H4SB)=Sof(H4SC)=Sof(S2S)=FVAR(1)
5.a Me refined with riding coordinates:
 C3S(H3SA,H3SB,H3SC), C3S(H3SD,H3SE,H3SF), C4S(H4SA,H4SB,H4SC), C4S(H4SD,H4SE,
 H4SF)
5.b Aromatic/amide H refined with riding coordinates:
 C4(H4), C5(H5), C6(H6), C7(H7), C8(H8), C12(H12), C13(H13), C14(H14),
 C15(H15), C16(H16), C20(H20), C21(H21), C22(H22), C23(H23), C24(H24), C28(H28),
  C29(H29), C30(H30), C31(H31), C32(H32), C35(H35), C36(H36), C37(H37),
 C38(H38), C41(H41), C42(H42), C43(H43), C44(H44), C47(H47), C48(H48), C49(H49),
  C50(H50)
5.c Idealised Me refined as rotating group:
 C1S(H1SA,H1SB,H1SC), C2S(H2SA,H2SB,H2SC), C5S(H5SA,H5SB,H5SC), C6S(H6SA,H6SB,
 H6SC), C7S(H7SA,H7SB,H7SC), C8S(H8SA,H8SB,H8SC), C9S(H9SA,H9SB,H9SC),
 C10S(H10A,H10B,H10C), C11S(H11A,H11B,H11C), C12S(H12A,H12B,H12C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.39268(15) 0.46019(11) 0.14256(9) 0.0310(5) Uani 1 1 d . . . . .
Ag2 Ag 0.33433(13) 0.56548(11) 0.24773(9) 0.0263(5) Uani 1 1 d . . . . .
Ag3 Ag 0.52414(14) 0.33540(11) 0.17004(8) 0.0282(5) Uani 1 1 d . . . . .
Ag4 Ag 0.53126(14) 0.53385(11) 0.18611(8) 0.0270(5) Uani 1 1 d . . . . .
Ag5 Ag 0.39063(13) 0.41780(11) 0.25325(8) 0.0247(5) Uani 1 1 d . . . . .
Ag6 Ag 0.61436(14) 0.76668(11) 0.23679(8) 0.0276(5) Uani 1 1 d . . . . .
Ag7 Ag 0.52585(14) 0.16539(11) 0.26940(8) 0.0258(5) Uani 1 1 d . . . . .
Ag8 Ag 0.58109(14) 0.31136(11) 0.30224(8) 0.0273(5) Uani 1 1 d . . . . .
Ag9 Ag 0.43548(14) 0.37102(11) 0.35889(8) 0.0267(5) Uani 1 1 d . . . . .
Ag10 Ag 0.52004(14) 0.50028(11) 0.32556(8) 0.0261(5) Uani 1 1 d . . . . .
C1 C 0.3905(16) 0.3490(13) 0.1866(9) 0.017(5) Uani 1 1 d . U . . .
C2 C 0.3819(14) 0.3086(12) 0.1497(9) 0.012(5) Uani 1 1 d . U . . .
C3 C 0.360(2) 0.2622(18) 0.1078(11) 0.036(8) Uani 1 1 d . . . . .
C4 C 0.283(3) 0.2248(18) 0.1092(11) 0.048(10) Uani 1 1 d . . . . .
H4 H 0.2454 0.2310 0.1369 0.057 Uiso 1 1 calc R . . . .
C5 C 0.269(2) 0.1798(15) 0.0677(12) 0.043(9) Uani 1 1 d . . . . .
H5 H 0.2192 0.1543 0.0673 0.051 Uiso 1 1 calc R . . . .
C6 C 0.321(2) 0.1696(19) 0.0277(15) 0.055(11) Uani 1 1 d . . . . .
H6 H 0.3056 0.1384 0.0000 0.066 Uiso 1 1 calc R . . . .
C7 C 0.396(3) 0.204(3) 0.0259(18) 0.11(2) Uani 1 1 d . . . . .
H7 H 0.4335 0.1927 -0.0012 0.127 Uiso 1 1 calc R . . . .
C8 C 0.416(3) 0.256(2) 0.0646(15) 0.074(14) Uani 1 1 d . . . . .
H8 H 0.4641 0.2838 0.0623 0.089 Uiso 1 1 calc R . . . .
C9 C 0.4822(18) 0.2570(14) 0.3320(10) 0.025(6) Uani 1 1 d . U . . .
C10 C 0.4332(15) 0.2157(13) 0.3538(9) 0.016(6) Uani 1 1 d . . . . .
C11 C 0.3829(15) 0.1699(13) 0.3841(9) 0.015(5) Uani 1 1 d . U . . .
C12 C 0.3150(16) 0.1366(13) 0.3600(10) 0.020(6) Uani 1 1 d . U . . .
H12 H 0.3031 0.1429 0.3237 0.024 Uiso 1 1 calc R . . . .
C13 C 0.2654(17) 0.0932(15) 0.3931(11) 0.026(7) Uani 1 1 d . U . . .
H13 H 0.2208 0.0687 0.3779 0.031 Uiso 1 1 calc R . . . .
C14 C 0.2784(19) 0.0857(17) 0.4430(11) 0.036(8) Uani 1 1 d . . . . .
H14 H 0.2419 0.0584 0.4636 0.043 Uiso 1 1 calc R . . . .
C15 C 0.3443(18) 0.1166(15) 0.4659(11) 0.029(7) Uani 1 1 d . . . . .
H15 H 0.3554 0.1077 0.5019 0.035 Uiso 1 1 calc R . . . .
C16 C 0.3973(18) 0.1626(15) 0.4362(11) 0.028(7) Uani 1 1 d . . . . .
H16 H 0.4410 0.1869 0.4526 0.033 Uiso 1 1 calc R . . . .
C17 C 0.3888(17) 0.4853(13) 0.3192(10) 0.024(6) Uani 1 1 d . . . . .
C18 C 0.3716(16) 0.5293(14) 0.3513(10) 0.019(6) Uani 1 1 d . U . . .
C19 C 0.3488(19) 0.5825(14) 0.3914(10) 0.028(7) Uani 1 1 d . . . . .
C20 C 0.269(2) 0.5876(18) 0.4054(12) 0.041(8) Uani 1 1 d . U . . .
H20 H 0.2304 0.5560 0.3904 0.049 Uiso 1 1 calc R . . . .
C21 C 0.243(2) 0.641(2) 0.4428(12) 0.050(10) Uani 1 1 d . . . . .
H21 H 0.1877 0.6453 0.4527 0.060 Uiso 1 1 calc R . . . .
C22 C 0.303(2) 0.6848(18) 0.4638(14) 0.047(9) Uani 1 1 d . . . . .
H22 H 0.2885 0.7192 0.4894 0.056 Uiso 1 1 calc R . . . .
C23 C 0.380(3) 0.680(2) 0.4489(12) 0.054(10) Uani 1 1 d . . . . .
H23 H 0.4176 0.7121 0.4648 0.065 Uiso 1 1 calc R . . . .
C24 C 0.411(2) 0.6321(18) 0.4118(13) 0.049(9) Uani 1 1 d . . . . .
H24 H 0.4660 0.6314 0.4009 0.059 Uiso 1 1 calc R . . . .
C25 C 0.4147(18) 0.5769(15) 0.1698(11) 0.031(7) Uani 1 1 d . U . . .
C26 C 0.3612(16) 0.6091(14) 0.1502(10) 0.023(6) Uani 1 1 d . U . . .
C27 C 0.3037(18) 0.6544(15) 0.1253(11) 0.028(7) Uani 1 1 d . . . . .
C28 C 0.2198(17) 0.6407(14) 0.1296(10) 0.023(6) Uani 1 1 d . . . . .
H28 H 0.2020 0.6006 0.1493 0.028 Uiso 1 1 calc R . . . .
C29 C 0.1634(18) 0.6836(14) 0.1061(10) 0.027(7) Uani 1 1 d . . . . .
H29 H 0.1072 0.6743 0.1106 0.032 Uiso 1 1 calc R . . . .
C30 C 0.1892(18) 0.7423(15) 0.0750(11) 0.028(7) Uani 1 1 d . . . . .
H30 H 0.1508 0.7709 0.0569 0.033 Uiso 1 1 calc R . . . .
C31 C 0.271(2) 0.7569(16) 0.0716(12) 0.035(8) Uani 1 1 d . . . . .
H31 H 0.2896 0.7981 0.0534 0.042 Uiso 1 1 calc R . . . .
C32 C 0.3258(18) 0.7123(14) 0.0943(12) 0.029(7) Uani 1 1 d . . . . .
H32 H 0.3819 0.7211 0.0888 0.035 Uiso 1 1 calc R . . . .
C33 C 0.6629(18) 0.2197(15) 0.1963(11) 0.026(7) Uani 1 1 d . U . . .
C34 C 0.7040(17) 0.2777(14) 0.1626(10) 0.023(6) Uani 1 1 d . U . . .
C35 C 0.7838(17) 0.2744(13) 0.1519(9) 0.020(6) Uani 1 1 d . . . . .
H35 H 0.8145 0.2345 0.1633 0.024 Uiso 1 1 calc R . . . .
C36 C 0.8227(18) 0.3302(15) 0.1234(12) 0.033(8) Uani 1 1 d . . . . .
H36 H 0.8791 0.3295 0.1161 0.040 Uiso 1 1 calc R . . . .
C37 C 0.7731(19) 0.3855(19) 0.1071(11) 0.037(8) Uani 1 1 d . . . . .
H37 H 0.7955 0.4249 0.0887 0.044 Uiso 1 1 calc R . . . .
C38 C 0.6911(19) 0.3830(16) 0.1177(10) 0.031(7) Uani 1 1 d . . . . .
H38 H 0.6586 0.4209 0.1047 0.038 Uiso 1 1 calc R . . . .
C39 C 0.6434(15) 0.4408(13) 0.2342(10) 0.017(6) Uani 1 1 d . U . . .
C40 C 0.7179(14) 0.4046(12) 0.2509(9) 0.013(5) Uani 1 1 d . U . . .
C41 C 0.7917(19) 0.4294(17) 0.2385(10) 0.034(7) Uani 1 1 d . . . . .
H41 H 0.7971 0.4706 0.2171 0.041 Uiso 1 1 calc R . . . .
C42 C 0.8617(16) 0.3938(14) 0.2575(11) 0.025(6) Uani 1 1 d . . . . .
H42 H 0.9147 0.4106 0.2498 0.030 Uiso 1 1 calc R . . . .
C43 C 0.8494(17) 0.3332(14) 0.2880(11) 0.026(7) Uani 1 1 d . . . . .
H43 H 0.8947 0.3071 0.3007 0.032 Uiso 1 1 calc R . . . .
C44 C 0.7700(16) 0.3104(13) 0.3001(9) 0.016(6) Uani 1 1 d . . . . .
H44 H 0.7638 0.2691 0.3213 0.019 Uiso 1 1 calc R . . . .
C45 C 0.6415(17) 0.6205(13) 0.2918(9) 0.015(6) Uani 1 1 d . . . . .
C46 C 0.6912(16) 0.5660(13) 0.3237(10) 0.019(6) Uani 1 1 d . U . . .
C47 C 0.7736(17) 0.5743(14) 0.3280(11) 0.028(7) Uani 1 1 d . . . . .
H47 H 0.8007 0.6134 0.3120 0.033 Uiso 1 1 calc R . . . .
C48 C 0.8170(17) 0.5223(14) 0.3575(11) 0.026(7) Uani 1 1 d . . . . .
H48 H 0.8742 0.5258 0.3615 0.031 Uiso 1 1 calc R . . . .
C49 C 0.7751(18) 0.4667(16) 0.3803(11) 0.028(7) Uani 1 1 d . U . . .
H49 H 0.8019 0.4312 0.4005 0.034 Uiso 1 1 calc R . . . .
C50 C 0.6922(17) 0.4653(15) 0.3724(10) 0.025(7) Uani 1 1 d . . . . .
H50 H 0.6628 0.4278 0.3887 0.030 Uiso 1 1 calc R . . . .
C1S C 0.138(2) 0.451(2) 0.0504(13) 0.051(10) Uani 1 1 d . . . . .
H1SA H 0.1307 0.4991 0.0647 0.077 Uiso 1 1 calc GR . . . .
H1SB H 0.0877 0.4237 0.0556 0.077 Uiso 1 1 calc GR . . . .
H1SC H 0.1497 0.4541 0.0128 0.077 Uiso 1 1 calc GR . . . .
C2S C 0.181(2) 0.4114(19) 0.1480(12) 0.050(9) Uani 1 1 d . . . . .
H2SA H 0.2199 0.3898 0.1721 0.074 Uiso 1 1 calc GR . . . .
H2SB H 0.1293 0.3850 0.1498 0.074 Uiso 1 1 calc GR . . . .
H2SC H 0.1713 0.4611 0.1581 0.074 Uiso 1 1 calc GR . . . .
C3S C 0.428(2) 0.449(3) -0.0103(18) 0.104(12) Uani 1 1 d D U . . .
H3SA H 0.4276 0.4754 -0.0433 0.156 Uiso 0.68(2) 1 calc R . P A 1
H3SB H 0.4357 0.3978 -0.0179 0.156 Uiso 0.68(2) 1 calc R . P A 1
H3SC H 0.3762 0.4554 0.0079 0.156 Uiso 0.68(2) 1 calc R . P A 1
H3SD H 0.4237 0.4220 -0.0433 0.156 Uiso 0.32(2) 1 calc R . P A 2
H3SE H 0.3741 0.4531 0.0056 0.156 Uiso 0.32(2) 1 calc R . P A 2
H3SF H 0.4501 0.4960 -0.0173 0.156 Uiso 0.32(2) 1 calc R . P A 2
C4S C 0.591(2) 0.438(3) -0.0023(19) 0.104(12) Uani 1 1 d D U . . .
H4SA H 0.6007 0.4618 -0.0361 0.156 Uiso 0.68(2) 1 calc R . P A 1
H4SB H 0.6397 0.4428 0.0197 0.156 Uiso 0.68(2) 1 calc R . P A 1
H4SC H 0.5794 0.3877 -0.0082 0.156 Uiso 0.68(2) 1 calc R . P A 1
H4SD H 0.5930 0.4262 -0.0397 0.156 Uiso 0.32(2) 1 calc R . P A 2
H4SE H 0.5979 0.4898 0.0020 0.156 Uiso 0.32(2) 1 calc R . P A 2
H4SF H 0.6350 0.4134 0.0161 0.156 Uiso 0.32(2) 1 calc R . P A 2
C5S C 0.0513(17) 0.5300(16) 0.2948(13) 0.036(8) Uani 1 1 d . . . . .
H5SA H 0.0236 0.5275 0.2608 0.053 Uiso 1 1 calc GR . . . .
H5SB H 0.0160 0.5535 0.3205 0.053 Uiso 1 1 calc GR . . . .
H5SC H 0.0641 0.4817 0.3069 0.053 Uiso 1 1 calc GR . . . .
C6S C 0.0999(18) 0.6505(16) 0.2494(11) 0.033(7) Uani 1 1 d . . . . .
H6SA H 0.1430 0.6842 0.2402 0.049 Uiso 1 1 calc GR . . . .
H6SB H 0.0579 0.6752 0.2697 0.049 Uiso 1 1 calc GR . . . .
H6SC H 0.0759 0.6310 0.2172 0.049 Uiso 1 1 calc GR . . . .
C7S C 0.226(2) 0.4054(19) 0.4854(12) 0.046(9) Uani 1 1 d . . . . .
H7SA H 0.2591 0.3793 0.5111 0.069 Uiso 1 1 calc GR . . . .
H7SB H 0.1692 0.3922 0.4895 0.069 Uiso 1 1 calc GR . . . .
H7SC H 0.2326 0.4567 0.4911 0.069 Uiso 1 1 calc GR . . . .
C8S C 0.228(2) 0.2947(17) 0.4214(11) 0.046(10) Uani 1 1 d . . . . .
H8SA H 0.2302 0.2772 0.3851 0.069 Uiso 1 1 calc GR . . . .
H8SB H 0.1729 0.2904 0.4349 0.069 Uiso 1 1 calc GR . . . .
H8SC H 0.2651 0.2663 0.4432 0.069 Uiso 1 1 calc GR . . . .
C9S C 0.495(2) 0.3506(18) 0.5169(12) 0.048(10) Uani 1 1 d . . . . .
H9SA H 0.4397 0.3642 0.5080 0.072 Uiso 1 1 calc GR . . . .
H9SB H 0.5070 0.3647 0.5532 0.072 Uiso 1 1 calc GR . . . .
H9SC H 0.5015 0.2989 0.5134 0.072 Uiso 1 1 calc GR . . . .
C10S C 0.515(2) 0.4788(15) 0.4723(11) 0.037(8) Uani 1 1 d . . . . .
H10A H 0.5397 0.5090 0.4454 0.055 Uiso 1 1 calc GR . . . .
H10B H 0.5200 0.5017 0.5067 0.055 Uiso 1 1 calc GR . . . .
H10C H 0.4572 0.4720 0.4641 0.055 Uiso 1 1 calc GR . . . .
C11S C 0.8686(18) 0.7115(15) 0.2191(12) 0.031(7) Uani 1 1 d . . . . .
H11A H 0.8316 0.6713 0.2134 0.047 Uiso 1 1 calc GR . . . .
H11B H 0.9114 0.6973 0.2437 0.047 Uiso 1 1 calc GR . . . .
H11C H 0.8931 0.7255 0.1856 0.047 Uiso 1 1 calc GR . . . .
C12S C 0.887(2) 0.8574(17) 0.2349(12) 0.050(10) Uani 1 1 d . . . . .
H12A H 0.9024 0.8586 0.1977 0.076 Uiso 1 1 calc GR . . . .
H12B H 0.9356 0.8488 0.2563 0.076 Uiso 1 1 calc GR . . . .
H12C H 0.8629 0.9031 0.2448 0.076 Uiso 1 1 calc GR . . . .
Cl1 Cl 0.0281(5) 0.2169(4) 0.1163(4) 0.046(2) Uani 1 1 d . . . . .
Cl2 Cl 0.0110(5) 0.3621(4) 0.4129(3) 0.0342(18) Uani 1 1 d . . . . .
Cl3 Cl 0.9626(5) 0.5172(4) 0.1438(3) 0.0330(17) Uani 1 1 d . . . . .
N1 N 0.6528(14) 0.3309(12) 0.1452(9) 0.029(6) Uani 1 1 d . . . . .
N2 N 0.7032(14) 0.3435(11) 0.2834(8) 0.022(5) Uani 1 1 d . . . . .
N3 N 0.6501(13) 0.5116(13) 0.3440(9) 0.025(6) Uani 1 1 d . . . . .
O1 O 0.5900(13) 0.2259(10) 0.2027(8) 0.036(5) Uani 1 1 d . . . . .
O2 O 0.7075(12) 0.1744(10) 0.2153(7) 0.028(5) Uani 1 1 d . . . . .
O3 O 0.5732(13) 0.4188(9) 0.2446(6) 0.027(5) Uani 1 1 d . . . . .
O4 O 0.6523(10) 0.4956(10) 0.2050(7) 0.022(4) Uani 1 1 d . . . . .
O5 O 0.5681(14) 0.6106(11) 0.2884(7) 0.033(5) Uani 1 1 d . . . . .
O6 O 0.6829(12) 0.6692(9) 0.2720(7) 0.028(5) Uani 1 1 d . . . . .
O1C O -0.0520(17) 0.1874(17) 0.1090(13) 0.090(10) Uani 1 1 d . . . . .
O2C O 0.049(3) 0.247(3) 0.0713(15) 0.17(2) Uani 1 1 d . . . . .
O3C O 0.0816(18) 0.1640(18) 0.1339(14) 0.103(12) Uani 1 1 d . . . . .
O4C O 0.0180(19) 0.2637(18) 0.1604(13) 0.094(11) Uani 1 1 d . . . . .
O5C O -0.0627(15) 0.4021(15) 0.4124(10) 0.066(8) Uani 1 1 d . . . . .
O6C O 0.0280(14) 0.3369(12) 0.4649(8) 0.044(6) Uani 1 1 d . . . . .
O7C O 0.0785(14) 0.4067(12) 0.3963(8) 0.044(6) Uani 1 1 d . . . . .
O8C O 0.0027(15) 0.3036(13) 0.3777(9) 0.057(7) Uani 1 1 d . . . . .
O9C O 0.9110(14) 0.5492(11) 0.1827(9) 0.048(6) Uani 1 1 d . . . . .
O10C O 0.9222(15) 0.5134(13) 0.0957(8) 0.053(7) Uani 1 1 d . . . . .
O11C O 0.9842(14) 0.4471(12) 0.1609(10) 0.057(7) Uani 1 1 d . . . . .
O12C O 1.0336(12) 0.5591(12) 0.1358(9) 0.047(6) Uani 1 1 d . . . . .
O1S O 0.2896(12) 0.4630(11) 0.0814(8) 0.035(5) Uani 1 1 d . . . . .
O2S O 0.5042(12) 0.4340(14) 0.0810(8) 0.049(7) Uani 1 1 d . . . . .
O3S O 0.1937(12) 0.5369(11) 0.2497(8) 0.035(5) Uani 1 1 d . . . . .
O4S O 0.3502(11) 0.3824(14) 0.4294(8) 0.044(6) Uani 1 1 d . . . . .
O5S O 0.5496(11) 0.3642(11) 0.4186(8) 0.030(5) Uani 1 1 d . . . . .
O6S O 0.7471(12) 0.8001(10) 0.2081(8) 0.036(5) Uani 1 1 d . . . . .
S1S S 0.2190(5) 0.4081(4) 0.0831(3) 0.0350(19) Uani 1 1 d . . . . .
S2S S 0.5076(8) 0.4790(6) 0.0297(5) 0.039(4) Uani 0.68(2) 1 d D . P A 1
S3S S 0.1417(4) 0.5791(4) 0.2880(3) 0.0278(17) Uani 1 1 d . . . . .
S4S S 0.2582(5) 0.3841(4) 0.4229(3) 0.0334(18) Uani 1 1 d . . . . .
S5S S 0.5644(5) 0.3944(4) 0.4736(3) 0.0285(17) Uani 1 1 d . . . . .
S6S S 0.8133(5) 0.7852(4) 0.2459(3) 0.0332(18) Uani 1 1 d . . . . .
S2T S 0.485(2) 0.4085(15) 0.0276(10) 0.047(10) Uani 0.32(2) 1 d . . P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Ag3 3.267(3) . ?
Ag1 Ag4 2.892(3) . ?
Ag1 Ag5 2.930(3) . ?
Ag1 C1 2.37(2) . ?
Ag1 C25 2.33(3) . ?
Ag1 O1S 2.31(2) . ?
Ag1 O2S 2.466(19) . ?
Ag2 Ag5 2.926(3) . ?
Ag2 Ag7 3.004(3) 3_655 ?
Ag2 C17 2.53(2) . ?
Ag2 C25 2.40(3) . ?
Ag2 C26 2.65(3) . ?
Ag2 O2 2.354(18) 3_655 ?
Ag2 O3S 2.38(2) . ?
Ag3 C1 2.26(3) . ?
Ag3 C2 2.45(2) . ?
Ag3 N1 2.22(2) . ?
Ag3 O1 2.469(18) . ?
Ag3 O3 2.591(17) . ?
Ag4 Ag7 2.875(3) 3_655 ?
Ag4 C25 2.13(3) . ?
Ag4 O4 2.175(17) . ?
Ag5 Ag6 2.849(3) 3_645 ?
Ag5 Ag9 2.925(3) . ?
Ag5 Ag10 3.216(3) . ?
Ag5 C1 2.13(2) . ?
Ag5 C17 2.10(3) . ?
Ag6 Ag5 2.849(3) 3_655 ?
Ag6 Ag7 2.997(3) 3_655 ?
Ag6 Ag9 3.232(3) 3_655 ?
Ag6 C1 2.49(2) 3_655 ?
Ag6 C9 2.38(3) 3_655 ?
Ag6 C10 2.62(2) 3_655 ?
Ag6 O6 2.330(17) . ?
Ag6 O6S 2.39(2) . ?
Ag7 Ag2 3.004(3) 3_645 ?
Ag7 Ag4 2.875(3) 3_645 ?
Ag7 Ag6 2.997(3) 3_645 ?
Ag7 Ag8 3.006(3) . ?
Ag7 C9 2.45(3) . ?
Ag7 C25 2.47(3) 3_645 ?
Ag7 O1 2.302(19) . ?
Ag7 O5 2.371(19) 3_645 ?
Ag8 Ag9 3.017(3) . ?
Ag8 C9 2.07(3) . ?
Ag8 N2 2.16(2) . ?
Ag8 O3 2.497(17) . ?
Ag9 Ag6 3.232(3) 3_645 ?
Ag9 Ag10 2.924(3) . ?
Ag9 C9 2.38(3) . ?
Ag9 C17 2.49(2) . ?
Ag9 O4S 2.29(2) . ?
Ag9 O5S 2.423(19) . ?
Ag10 C17 2.19(3) . ?
Ag10 C18 2.59(3) . ?
Ag10 N3 2.20(2) . ?
Ag10 O5 2.41(2) . ?
C1 Ag6 2.49(2) 3_645 ?
C1 C2 1.22(3) . ?
C2 C3 1.42(4) . ?
C3 C4 1.45(5) . ?
C3 C8 1.45(5) . ?
C4 H4 0.9500 . ?
C4 C5 1.37(4) . ?
C5 H5 0.9500 . ?
C5 C6 1.34(5) . ?
C6 H6 0.9500 . ?
C6 C7 1.40(7) . ?
C7 H7 0.9500 . ?
C7 C8 1.42(5) . ?
C8 H8 0.9500 . ?
C9 Ag6 2.38(3) 3_645 ?
C9 C10 1.25(4) . ?
C10 Ag6 2.62(2) 3_645 ?
C10 C11 1.42(3) . ?
C11 C12 1.42(3) . ?
C11 C16 1.36(4) . ?
C12 H12 0.9500 . ?
C12 C13 1.43(4) . ?
C13 H13 0.9500 . ?
C13 C14 1.29(4) . ?
C14 H14 0.9500 . ?
C14 C15 1.36(4) . ?
C15 H15 0.9500 . ?
C15 C16 1.44(4) . ?
C16 H16 0.9500 . ?
C17 C18 1.20(4) . ?
C18 C19 1.48(4) . ?
C19 C20 1.37(4) . ?
C19 C24 1.48(5) . ?
C20 H20 0.9500 . ?
C20 C21 1.44(5) . ?
C21 H21 0.9500 . ?
C21 C22 1.40(5) . ?
C22 H22 0.9500 . ?
C22 C23 1.33(5) . ?
C23 H23 0.9500 . ?
C23 C24 1.40(5) . ?
C24 H24 0.9500 . ?
C25 Ag7 2.47(3) 3_655 ?
C25 C26 1.18(4) . ?
C26 C27 1.42(4) . ?
C27 C28 1.41(4) . ?
C27 C32 1.39(4) . ?
C28 H28 0.9500 . ?
C28 C29 1.37(4) . ?
C29 H29 0.9500 . ?
C29 C30 1.42(4) . ?
C30 H30 0.9500 . ?
C30 C31 1.38(4) . ?
C31 H31 0.9500 . ?
C31 C32 1.36(4) . ?
C32 H32 0.9500 . ?
C33 C34 1.54(4) . ?
C33 O1 1.22(3) . ?
C33 O2 1.22(3) . ?
C34 C35 1.34(4) . ?
C34 N1 1.38(3) . ?
C35 H35 0.9500 . ?
C35 C36 1.43(4) . ?
C36 H36 0.9500 . ?
C36 C37 1.38(4) . ?
C37 H37 0.9500 . ?
C37 C38 1.38(4) . ?
C38 H38 0.9500 . ?
C38 N1 1.36(4) . ?
C39 C40 1.47(3) . ?
C39 O3 1.26(3) . ?
C39 O4 1.28(3) . ?
C40 C41 1.34(4) . ?
C40 N2 1.44(3) . ?
C41 H41 0.9500 . ?
C41 C42 1.42(4) . ?
C42 H42 0.9500 . ?
C42 C43 1.39(4) . ?
C43 H43 0.9500 . ?
C43 C44 1.41(4) . ?
C44 H44 0.9500 . ?
C44 N2 1.33(3) . ?
C45 C46 1.54(3) . ?
C45 O5 1.23(3) . ?
C45 O6 1.25(3) . ?
C46 C47 1.37(4) . ?
C46 N3 1.33(3) . ?
C47 H47 0.9500 . ?
C47 C48 1.43(4) . ?
C48 H48 0.9500 . ?
C48 C49 1.38(4) . ?
C49 H49 0.9500 . ?
C49 C50 1.38(4) . ?
C50 H50 0.9500 . ?
C50 N3 1.33(3) . ?
C1S H1SA 0.9800 . ?
C1S H1SB 0.9800 . ?
C1S H1SC 0.9800 . ?
C1S S1S 1.77(3) . ?
C2S H2SA 0.9800 . ?
C2S H2SB 0.9800 . ?
C2S H2SC 0.9800 . ?
C2S S1S 1.77(3) . ?
C3S H3SA 0.9800 . ?
C3S H3SB 0.9800 . ?
C3S H3SC 0.9800 . ?
C3S H3SD 0.9800 . ?
C3S H3SE 0.9800 . ?
C3S H3SF 0.9800 . ?
C3S S2S 1.76(2) . ?
C3S S2T 1.54(5) . ?
C4S H4SA 0.9800 . ?
C4S H4SB 0.9800 . ?
C4S H4SC 0.9800 . ?
C4S H4SD 0.9800 . ?
C4S H4SE 0.9800 . ?
C4S H4SF 0.9800 . ?
C4S S2S 1.77(2) . ?
C4S S2T 2.00(5) . ?
C5S H5SA 0.9800 . ?
C5S H5SB 0.9800 . ?
C5S H5SC 0.9800 . ?
C5S S3S 1.76(3) . ?
C6S H6SA 0.9800 . ?
C6S H6SB 0.9800 . ?
C6S H6SC 0.9800 . ?
C6S S3S 1.80(3) . ?
C7S H7SA 0.9800 . ?
C7S H7SB 0.9800 . ?
C7S H7SC 0.9800 . ?
C7S S4S 1.72(3) . ?
C8S H8SA 0.9800 . ?
C8S H8SB 0.9800 . ?
C8S H8SC 0.9800 . ?
C8S S4S 1.75(3) . ?
C9S H9SA 0.9800 . ?
C9S H9SB 0.9800 . ?
C9S H9SC 0.9800 . ?
C9S S5S 1.79(3) . ?
C10S H10A 0.9800 . ?
C10S H10B 0.9800 . ?
C10S H10C 0.9800 . ?
C10S S5S 1.78(3) . ?
C11S H11A 0.9800 . ?
C11S H11B 0.9800 . ?
C11S H11C 0.9800 . ?
C11S S6S 1.79(3) . ?
C12S H12A 0.9800 . ?
C12S H12B 0.9800 . ?
C12S H12C 0.9800 . ?
C12S S6S 1.84(3) . ?
Cl1 O1C 1.44(3) . ?
Cl1 O2C 1.32(3) . ?
Cl1 O3C 1.40(3) . ?
Cl1 O4C 1.44(3) . ?
Cl2 O5C 1.43(2) . ?
Cl2 O6C 1.43(2) . ?
Cl2 O7C 1.46(2) . ?
Cl2 O8C 1.42(2) . ?
Cl3 O9C 1.44(2) . ?
Cl3 O10C 1.40(2) . ?
Cl3 O11C 1.43(2) . ?
Cl3 O12C 1.43(2) . ?
O2 Ag2 2.354(18) 3_645 ?
O5 Ag7 2.371(19) 3_655 ?
O1S S1S 1.56(2) . ?
O2S S2S 1.56(2) . ?
O2S S2T 1.48(4) . ?
O3S S3S 1.52(2) . ?
O4S S4S 1.53(2) . ?
O5S S5S 1.53(2) . ?
O6S S6S 1.48(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag4 Ag1 Ag3 74.70(8) . . ?
Ag4 Ag1 Ag5 76.69(8) . . ?
Ag5 Ag1 Ag3 66.85(7) . . ?
C1 Ag1 Ag3 43.7(6) . . ?
C1 Ag1 Ag4 104.5(6) . . ?
C1 Ag1 Ag5 45.9(6) . . ?
C1 Ag1 O2S 97.9(9) . . ?
C25 Ag1 Ag3 120.5(8) . . ?
C25 Ag1 Ag4 46.5(7) . . ?
C25 Ag1 Ag5 88.3(7) . . ?
C25 Ag1 C1 133.7(9) . . ?
C25 Ag1 O2S 105.1(9) . . ?
O1S Ag1 Ag3 130.5(5) . . ?
O1S Ag1 Ag4 146.2(5) . . ?
O1S Ag1 Ag5 130.4(5) . . ?
O1S Ag1 C1 109.2(8) . . ?
O1S Ag1 C25 107.2(9) . . ?
O1S Ag1 O2S 97.2(7) . . ?
O2S Ag1 Ag3 59.9(5) . . ?
O2S Ag1 Ag4 75.5(6) . . ?
O2S Ag1 Ag5 124.5(5) . . ?
Ag5 Ag2 Ag7 110.78(9) . 3_655 ?
C17 Ag2 Ag5 44.7(6) . . ?
C17 Ag2 Ag7 101.8(7) . 3_655 ?
C17 Ag2 C26 143.1(8) . . ?
C25 Ag2 Ag5 87.1(7) . . ?
C25 Ag2 Ag7 53.1(7) . 3_655 ?
C25 Ag2 C17 117.0(9) . . ?
C25 Ag2 C26 26.4(9) . . ?
C26 Ag2 Ag5 106.5(6) . . ?
C26 Ag2 Ag7 62.8(6) . 3_655 ?
O2 Ag2 Ag5 153.7(5) 3_655 . ?
O2 Ag2 Ag7 75.0(5) 3_655 3_655 ?
O2 Ag2 C17 109.4(8) 3_655 . ?
O2 Ag2 C25 114.6(8) 3_655 . ?
O2 Ag2 C26 99.0(7) 3_655 . ?
O2 Ag2 O3S 84.4(7) 3_655 . ?
O3S Ag2 Ag5 95.4(5) . . ?
O3S Ag2 Ag7 153.1(5) . 3_655 ?
O3S Ag2 C17 101.3(8) . . ?
O3S Ag2 C25 125.2(9) . . ?
O3S Ag2 C26 104.6(8) . . ?
C1 Ag3 Ag1 46.5(6) . . ?
C1 Ag3 C2 29.5(8) . . ?
C1 Ag3 O1 117.4(8) . . ?
C1 Ag3 O3 95.7(8) . . ?
C2 Ag3 Ag1 57.8(6) . . ?
C2 Ag3 O1 108.7(8) . . ?
C2 Ag3 O3 125.2(7) . . ?
N1 Ag3 Ag1 127.0(6) . . ?
N1 Ag3 C1 172.8(8) . . ?
N1 Ag3 C2 147.9(8) . . ?
N1 Ag3 O1 69.1(7) . . ?
N1 Ag3 O3 86.2(8) . . ?
O1 Ag3 Ag1 163.9(5) . . ?
O1 Ag3 O3 96.8(7) . . ?
O3 Ag3 Ag1 86.1(4) . . ?
Ag7 Ag4 Ag1 107.63(10) 3_655 . ?
C25 Ag4 Ag1 52.6(8) . . ?
C25 Ag4 Ag7 57.0(8) . 3_655 ?
C25 Ag4 O4 176.7(9) . . ?
O4 Ag4 Ag1 130.7(5) . . ?
O4 Ag4 Ag7 119.8(5) . 3_655 ?
Ag1 Ag5 Ag10 114.38(9) . . ?
Ag2 Ag5 Ag1 72.56(8) . . ?
Ag2 Ag5 Ag10 77.41(7) . . ?
Ag6 Ag5 Ag1 110.88(9) 3_645 . ?
Ag6 Ag5 Ag2 159.74(11) 3_645 . ?
Ag6 Ag5 Ag9 68.07(7) 3_645 . ?
Ag6 Ag5 Ag10 116.58(9) 3_645 . ?
Ag9 Ag5 Ag1 164.53(11) . . ?
Ag9 Ag5 Ag2 114.12(9) . . ?
Ag9 Ag5 Ag10 56.63(7) . . ?
C1 Ag5 Ag1 53.0(6) . . ?
C1 Ag5 Ag2 122.3(6) . . ?
C1 Ag5 Ag6 57.9(6) . 3_645 ?
C1 Ag5 Ag9 123.4(6) . . ?
C1 Ag5 Ag10 138.4(7) . . ?
C17 Ag5 Ag1 127.2(6) . . ?
C17 Ag5 Ag2 57.6(6) . . ?
C17 Ag5 Ag6 121.9(6) . 3_645 ?
C17 Ag5 Ag9 56.6(6) . . ?
C17 Ag5 Ag10 42.5(8) . . ?
C17 Ag5 C1 179.1(11) . . ?
Ag5 Ag6 Ag7 127.87(11) 3_655 3_655 ?
Ag5 Ag6 Ag9 57.09(7) 3_655 3_655 ?
Ag7 Ag6 Ag9 98.54(8) 3_655 3_655 ?
C1 Ag6 Ag5 46.5(6) 3_655 3_655 ?
C1 Ag6 Ag7 114.2(6) 3_655 3_655 ?
C1 Ag6 Ag9 101.9(6) 3_655 3_655 ?
C1 Ag6 C10 155.2(8) 3_655 3_655 ?
C9 Ag6 Ag5 97.1(6) 3_655 3_655 ?
C9 Ag6 Ag7 52.8(6) 3_655 3_655 ?
C9 Ag6 Ag9 47.1(6) 3_655 3_655 ?
C9 Ag6 C1 127.2(9) 3_655 3_655 ?
C9 Ag6 C10 28.5(9) 3_655 3_655 ?
C9 Ag6 O6S 114.1(8) 3_655 . ?
C10 Ag6 Ag5 115.7(6) 3_655 3_655 ?
C10 Ag6 Ag7 59.4(5) 3_655 3_655 ?
C10 Ag6 Ag9 58.7(5) 3_655 3_655 ?
O6 Ag6 Ag5 139.6(5) . 3_655 ?
O6 Ag6 Ag7 84.1(5) . 3_655 ?
O6 Ag6 Ag9 152.8(5) . 3_655 ?
O6 Ag6 C1 101.6(7) . 3_655 ?
O6 Ag6 C9 123.3(8) . 3_655 ?
O6 Ag6 C10 101.4(7) . 3_655 ?
O6 Ag6 O6S 83.1(7) . . ?
O6S Ag6 Ag5 78.0(5) . 3_655 ?
O6S Ag6 Ag7 148.9(5) . 3_655 ?
O6S Ag6 Ag9 81.0(5) . 3_655 ?
O6S Ag6 C1 96.1(8) . 3_655 ?
O6S Ag6 C10 95.8(7) . 3_655 ?
Ag2 Ag7 Ag8 112.13(9) 3_645 . ?
Ag4 Ag7 Ag2 76.86(8) 3_645 3_645 ?
Ag4 Ag7 Ag6 108.22(10) 3_645 3_645 ?
Ag4 Ag7 Ag8 140.55(9) 3_645 . ?
Ag6 Ag7 Ag2 168.63(10) 3_645 3_645 ?
Ag6 Ag7 Ag8 70.75(8) 3_645 . ?
C9 Ag7 Ag2 139.2(7) . 3_645 ?
C9 Ag7 Ag4 104.4(7) . 3_645 ?
C9 Ag7 Ag6 50.5(7) . 3_645 ?
C9 Ag7 Ag8 43.0(7) . . ?
C9 Ag7 C25 100.3(9) . 3_645 ?
C25 Ag7 Ag2 50.8(7) 3_645 3_645 ?
C25 Ag7 Ag4 46.1(7) 3_645 3_645 ?
C25 Ag7 Ag6 139.9(7) 3_645 3_645 ?
C25 Ag7 Ag8 108.5(7) 3_645 . ?
O1 Ag7 Ag2 81.2(5) . 3_645 ?
O1 Ag7 Ag4 149.9(5) . 3_645 ?
O1 Ag7 Ag6 90.2(5) . 3_645 ?
O1 Ag7 Ag8 67.5(5) . . ?
O1 Ag7 C9 105.6(8) . . ?
O1 Ag7 C25 127.7(8) . 3_645 ?
O1 Ag7 O5 93.2(8) . 3_645 ?
O5 Ag7 Ag2 98.1(5) 3_645 3_645 ?
O5 Ag7 Ag4 70.0(5) 3_645 3_645 ?
O5 Ag7 Ag6 74.8(5) 3_645 3_645 ?
O5 Ag7 Ag8 140.0(5) 3_645 . ?
O5 Ag7 C9 121.1(9) 3_645 . ?
O5 Ag7 C25 110.9(9) 3_645 3_645 ?
Ag7 Ag8 Ag9 103.31(9) . . ?
C9 Ag8 Ag7 54.1(7) . . ?
C9 Ag8 Ag9 51.7(7) . . ?
C9 Ag8 N2 162.9(9) . . ?
C9 Ag8 O3 125.0(9) . . ?
N2 Ag8 Ag7 118.4(6) . . ?
N2 Ag8 Ag9 138.3(6) . . ?
N2 Ag8 O3 72.1(7) . . ?
O3 Ag8 Ag7 123.8(4) . . ?
O3 Ag8 Ag9 86.6(5) . . ?
Ag5 Ag9 Ag6 54.84(7) . 3_645 ?
Ag5 Ag9 Ag8 82.68(8) . . ?
Ag8 Ag9 Ag6 67.47(7) . 3_645 ?
Ag10 Ag9 Ag5 66.71(7) . . ?
Ag10 Ag9 Ag6 113.89(9) . 3_645 ?
Ag10 Ag9 Ag8 77.85(8) . . ?
C9 Ag9 Ag5 95.0(7) . . ?
C9 Ag9 Ag6 47.1(7) . 3_645 ?
C9 Ag9 Ag8 43.1(7) . . ?
C9 Ag9 Ag10 120.6(7) . . ?
C9 Ag9 C17 139.4(9) . . ?
C9 Ag9 O5S 83.1(8) . . ?
C17 Ag9 Ag5 44.8(6) . . ?
C17 Ag9 Ag6 97.9(7) . 3_645 ?
C17 Ag9 Ag8 111.8(6) . . ?
C17 Ag9 Ag10 46.8(7) . . ?
O4S Ag9 Ag5 122.6(5) . . ?
O4S Ag9 Ag6 119.4(6) . 3_645 ?
O4S Ag9 Ag8 153.9(5) . . ?
O4S Ag9 Ag10 116.3(7) . . ?
O4S Ag9 C9 120.6(9) . . ?
O4S Ag9 C17 92.8(9) . . ?
O4S Ag9 O5S 89.4(6) . . ?
O5S Ag9 Ag5 142.1(5) . . ?
O5S Ag9 Ag6 129.7(5) . 3_645 ?
O5S Ag9 Ag8 70.3(4) . . ?
O5S Ag9 Ag10 81.7(5) . . ?
O5S Ag9 C17 122.7(8) . . ?
Ag9 Ag10 Ag5 56.67(7) . . ?
C17 Ag10 Ag5 40.5(7) . . ?
C17 Ag10 Ag9 56.2(6) . . ?
C17 Ag10 C18 27.3(9) . . ?
C17 Ag10 N3 171.8(9) . . ?
C17 Ag10 O5 114.0(8) . . ?
C18 Ag10 Ag5 67.6(6) . . ?
C18 Ag10 Ag9 69.5(6) . . ?
N3 Ag10 Ag5 144.4(6) . . ?
N3 Ag10 Ag9 118.8(6) . . ?
N3 Ag10 C18 147.6(8) . . ?
N3 Ag10 O5 71.4(8) . . ?
O5 Ag10 Ag5 114.0(4) . . ?
O5 Ag10 Ag9 169.5(5) . . ?
O5 Ag10 C18 103.3(8) . . ?
Ag1 C1 Ag6 156.7(11) . 3_645 ?
Ag3 C1 Ag1 89.8(9) . . ?
Ag3 C1 Ag6 96.2(9) . 3_645 ?
Ag5 C1 Ag1 81.0(8) . . ?
Ag5 C1 Ag3 102.5(10) . . ?
Ag5 C1 Ag6 75.7(7) . 3_645 ?
C2 C1 Ag1 100.6(17) . . ?
C2 C1 Ag3 84.2(17) . . ?
C2 C1 Ag5 173(2) . . ?
C2 C1 Ag6 102.4(18) . 3_645 ?
C1 C2 Ag3 66.3(16) . . ?
C1 C2 C3 172(3) . . ?
C3 C2 Ag3 121.7(19) . . ?
C2 C3 C4 120(3) . . ?
C2 C3 C8 117(3) . . ?
C8 C3 C4 123(3) . . ?
C3 C4 H4 122.2 . . ?
C5 C4 C3 116(3) . . ?
C5 C4 H4 122.2 . . ?
C4 C5 H5 117.9 . . ?
C6 C5 C4 124(4) . . ?
C6 C5 H5 117.9 . . ?
C5 C6 H6 119.2 . . ?
C5 C6 C7 122(3) . . ?
C7 C6 H6 119.2 . . ?
C6 C7 H7 120.0 . . ?
C6 C7 C8 120(4) . . ?
C8 C7 H7 120.0 . . ?
C3 C8 H8 122.1 . . ?
C7 C8 C3 116(4) . . ?
C7 C8 H8 122.1 . . ?
Ag6 C9 Ag7 76.7(8) 3_645 . ?
Ag6 C9 Ag9 85.7(9) 3_645 . ?
Ag8 C9 Ag6 102.7(11) . 3_645 ?
Ag8 C9 Ag7 82.9(10) . . ?
Ag8 C9 Ag9 85.2(9) . . ?
Ag9 C9 Ag7 156.0(13) . . ?
C10 C9 Ag6 86.7(19) . 3_645 ?
C10 C9 Ag7 92.6(17) . . ?
C10 C9 Ag8 168(2) . . ?
C10 C9 Ag9 102.7(19) . . ?
C9 C10 Ag6 64.9(16) . 3_645 ?
C9 C10 C11 173(3) . . ?
C11 C10 Ag6 121.6(17) . 3_645 ?
C12 C11 C10 119(2) . . ?
C16 C11 C10 119(2) . . ?
C16 C11 C12 121(2) . . ?
C11 C12 H12 121.8 . . ?
C11 C12 C13 116(2) . . ?
C13 C12 H12 121.8 . . ?
C12 C13 H13 118.4 . . ?
C14 C13 C12 123(3) . . ?
C14 C13 H13 118.4 . . ?
C13 C14 H14 119.8 . . ?
C13 C14 C15 120(3) . . ?
C15 C14 H14 119.8 . . ?
C14 C15 H15 119.6 . . ?
C14 C15 C16 121(3) . . ?
C16 C15 H15 119.6 . . ?
C11 C16 C15 118(3) . . ?
C11 C16 H16 121.1 . . ?
C15 C16 H16 121.1 . . ?
Ag5 C17 Ag2 77.8(8) . . ?
Ag5 C17 Ag9 78.5(8) . . ?
Ag5 C17 Ag10 97.0(11) . . ?
Ag9 C17 Ag2 156.1(13) . . ?
Ag10 C17 Ag2 109.1(10) . . ?
Ag10 C17 Ag9 77.0(8) . . ?
C18 C17 Ag2 89.8(17) . . ?
C18 C17 Ag5 165(2) . . ?
C18 C17 Ag9 113.0(19) . . ?
C18 C17 Ag10 95(2) . . ?
C17 C18 Ag10 57.2(18) . . ?
C17 C18 C19 179(3) . . ?
C19 C18 Ag10 123.8(19) . . ?
C20 C19 C18 118(3) . . ?
C20 C19 C24 122(3) . . ?
C24 C19 C18 120(3) . . ?
C19 C20 H20 119.8 . . ?
C19 C20 C21 120(3) . . ?
C21 C20 H20 119.8 . . ?
C20 C21 H21 121.6 . . ?
C22 C21 C20 117(3) . . ?
C22 C21 H21 121.6 . . ?
C21 C22 H22 119.0 . . ?
C23 C22 C21 122(3) . . ?
C23 C22 H22 119.0 . . ?
C22 C23 H23 117.3 . . ?
C22 C23 C24 125(4) . . ?
C24 C23 H23 117.3 . . ?
C19 C24 H24 123.4 . . ?
C23 C24 C19 113(3) . . ?
C23 C24 H24 123.4 . . ?
Ag1 C25 Ag2 94.4(10) . . ?
Ag1 C25 Ag7 151.7(14) . 3_655 ?
Ag2 C25 Ag7 76.1(8) . 3_655 ?
Ag4 C25 Ag1 80.9(10) . . ?
Ag4 C25 Ag2 107.7(12) . . ?
Ag4 C25 Ag7 76.9(9) . 3_655 ?
C26 C25 Ag1 104(2) . . ?
C26 C25 Ag2 89(2) . . ?
C26 C25 Ag4 162(3) . . ?
C26 C25 Ag7 103(2) . 3_655 ?
C25 C26 Ag2 64.6(18) . . ?
C25 C26 C27 173(3) . . ?
C27 C26 Ag2 119.4(19) . . ?
C28 C27 C26 121(3) . . ?
C32 C27 C26 123(3) . . ?
C32 C27 C28 116(3) . . ?
C27 C28 H28 119.2 . . ?
C29 C28 C27 122(3) . . ?
C29 C28 H28 119.2 . . ?
C28 C29 H29 120.1 . . ?
C28 C29 C30 120(3) . . ?
C30 C29 H29 120.1 . . ?
C29 C30 H30 120.6 . . ?
C31 C30 C29 119(3) . . ?
C31 C30 H30 120.6 . . ?
C30 C31 H31 120.0 . . ?
C32 C31 C30 120(3) . . ?
C32 C31 H31 120.0 . . ?
C27 C32 H32 118.3 . . ?
C31 C32 C27 123(3) . . ?
C31 C32 H32 118.3 . . ?
O1 C33 C34 116(2) . . ?
O1 C33 O2 127(3) . . ?
O2 C33 C34 116(3) . . ?
C35 C34 C33 121(2) . . ?
C35 C34 N1 124(2) . . ?
N1 C34 C33 115(2) . . ?
C34 C35 H35 119.7 . . ?
C34 C35 C36 121(2) . . ?
C36 C35 H35 119.7 . . ?
C35 C36 H36 122.0 . . ?
C37 C36 C35 116(3) . . ?
C37 C36 H36 122.0 . . ?
C36 C37 H37 120.2 . . ?
C38 C37 C36 120(3) . . ?
C38 C37 H37 120.2 . . ?
C37 C38 H38 117.2 . . ?
N1 C38 C37 126(3) . . ?
N1 C38 H38 117.2 . . ?
O3 C39 C40 124(2) . . ?
O3 C39 O4 120(2) . . ?
O4 C39 C40 117(2) . . ?
C41 C40 C39 122(2) . . ?
C41 C40 N2 125(2) . . ?
N2 C40 C39 113(2) . . ?
C40 C41 H41 120.2 . . ?
C40 C41 C42 120(3) . . ?
C42 C41 H41 120.2 . . ?
C41 C42 H42 121.4 . . ?
C43 C42 C41 117(3) . . ?
C43 C42 H42 121.4 . . ?
C42 C43 H43 119.8 . . ?
C42 C43 C44 120(2) . . ?
C44 C43 H43 119.8 . . ?
C43 C44 H44 118.2 . . ?
N2 C44 C43 124(2) . . ?
N2 C44 H44 118.2 . . ?
O5 C45 C46 118(2) . . ?
O5 C45 O6 128(2) . . ?
O6 C45 C46 114(2) . . ?
C47 C46 C45 120(2) . . ?
N3 C46 C45 116(2) . . ?
N3 C46 C47 124(2) . . ?
C46 C47 H47 121.3 . . ?
C46 C47 C48 117(2) . . ?
C48 C47 H47 121.3 . . ?
C47 C48 H48 120.4 . . ?
C49 C48 C47 119(3) . . ?
C49 C48 H48 120.4 . . ?
C48 C49 H49 121.7 . . ?
C48 C49 C50 117(3) . . ?
C50 C49 H49 121.7 . . ?
C49 C50 H50 117.1 . . ?
N3 C50 C49 126(3) . . ?
N3 C50 H50 117.1 . . ?
H1SA C1S H1SB 109.5 . . ?
H1SA C1S H1SC 109.5 . . ?
H1SB C1S H1SC 109.5 . . ?
S1S C1S H1SA 109.5 . . ?
S1S C1S H1SB 109.5 . . ?
S1S C1S H1SC 109.5 . . ?
H2SA C2S H2SB 109.5 . . ?
H2SA C2S H2SC 109.5 . . ?
H2SB C2S H2SC 109.5 . . ?
S1S C2S H2SA 109.5 . . ?
S1S C2S H2SB 109.5 . . ?
S1S C2S H2SC 109.5 . . ?
H3SA C3S H3SB 109.5 . . ?
H3SA C3S H3SC 109.5 . . ?
H3SB C3S H3SC 109.5 . . ?
H3SD C3S H3SE 109.5 . . ?
H3SD C3S H3SF 109.5 . . ?
H3SE C3S H3SF 109.5 . . ?
S2S C3S H3SA 109.5 . . ?
S2S C3S H3SB 109.5 . . ?
S2S C3S H3SC 109.5 . . ?
S2T C3S H3SD 109.5 . . ?
S2T C3S H3SE 109.5 . . ?
S2T C3S H3SF 109.5 . . ?
H4SA C4S H4SB 109.5 . . ?
H4SA C4S H4SC 109.5 . . ?
H4SB C4S H4SC 109.5 . . ?
H4SD C4S H4SE 109.5 . . ?
H4SD C4S H4SF 109.5 . . ?
H4SE C4S H4SF 109.5 . . ?
S2S C4S H4SA 109.5 . . ?
S2S C4S H4SB 109.5 . . ?
S2S C4S H4SC 109.5 . . ?
S2T C4S H4SD 109.5 . . ?
S2T C4S H4SE 109.5 . . ?
S2T C4S H4SF 109.5 . . ?
H5SA C5S H5SB 109.5 . . ?
H5SA C5S H5SC 109.5 . . ?
H5SB C5S H5SC 109.5 . . ?
S3S C5S H5SA 109.5 . . ?
S3S C5S H5SB 109.5 . . ?
S3S C5S H5SC 109.5 . . ?
H6SA C6S H6SB 109.5 . . ?
H6SA C6S H6SC 109.5 . . ?
H6SB C6S H6SC 109.5 . . ?
S3S C6S H6SA 109.5 . . ?
S3S C6S H6SB 109.5 . . ?
S3S C6S H6SC 109.5 . . ?
H7SA C7S H7SB 109.5 . . ?
H7SA C7S H7SC 109.5 . . ?
H7SB C7S H7SC 109.5 . . ?
S4S C7S H7SA 109.5 . . ?
S4S C7S H7SB 109.5 . . ?
S4S C7S H7SC 109.5 . . ?
H8SA C8S H8SB 109.5 . . ?
H8SA C8S H8SC 109.5 . . ?
H8SB C8S H8SC 109.5 . . ?
S4S C8S H8SA 109.5 . . ?
S4S C8S H8SB 109.5 . . ?
S4S C8S H8SC 109.5 . . ?
H9SA C9S H9SB 109.5 . . ?
H9SA C9S H9SC 109.5 . . ?
H9SB C9S H9SC 109.5 . . ?
S5S C9S H9SA 109.5 . . ?
S5S C9S H9SB 109.5 . . ?
S5S C9S H9SC 109.5 . . ?
H10A C10S H10B 109.5 . . ?
H10A C10S H10C 109.5 . . ?
H10B C10S H10C 109.5 . . ?
S5S C10S H10A 109.5 . . ?
S5S C10S H10B 109.5 . . ?
S5S C10S H10C 109.5 . . ?
H11A C11S H11B 109.5 . . ?
H11A C11S H11C 109.5 . . ?
H11B C11S H11C 109.5 . . ?
S6S C11S H11A 109.5 . . ?
S6S C11S H11B 109.5 . . ?
S6S C11S H11C 109.5 . . ?
H12A C12S H12B 109.5 . . ?
H12A C12S H12C 109.5 . . ?
H12B C12S H12C 109.5 . . ?
S6S C12S H12A 109.5 . . ?
S6S C12S H12B 109.5 . . ?
S6S C12S H12C 109.5 . . ?
O2C Cl1 O1C 107(2) . . ?
O2C Cl1 O3C 114(3) . . ?
O2C Cl1 O4C 117(3) . . ?
O3C Cl1 O1C 110(2) . . ?
O3C Cl1 O4C 105(2) . . ?
O4C Cl1 O1C 103.3(19) . . ?
O5C Cl2 O6C 110.3(14) . . ?
O5C Cl2 O7C 110.2(16) . . ?
O6C Cl2 O7C 108.0(13) . . ?
O8C Cl2 O5C 108.5(17) . . ?
O8C Cl2 O6C 110.2(15) . . ?
O8C Cl2 O7C 109.6(14) . . ?
O10C Cl3 O9C 110.1(15) . . ?
O10C Cl3 O11C 109.8(15) . . ?
O10C Cl3 O12C 107.1(14) . . ?
O11C Cl3 O9C 108.7(14) . . ?
O12C Cl3 O9C 110.8(14) . . ?
O12C Cl3 O11C 110.3(15) . . ?
C34 N1 Ag3 121.4(18) . . ?
C38 N1 Ag3 124(2) . . ?
C38 N1 C34 114(2) . . ?
C40 N2 Ag8 120.6(16) . . ?
C44 N2 Ag8 124.8(18) . . ?
C44 N2 C40 115(2) . . ?
C46 N3 Ag10 119.1(18) . . ?
C50 N3 Ag10 124.2(19) . . ?
C50 N3 C46 117(2) . . ?
Ag7 O1 Ag3 117.2(8) . . ?
C33 O1 Ag3 118.0(18) . . ?
C33 O1 Ag7 120.3(18) . . ?
C33 O2 Ag2 125.8(19) . 3_645 ?
Ag8 O3 Ag3 87.7(5) . . ?
C39 O3 Ag3 109.3(15) . . ?
C39 O3 Ag8 110.0(16) . . ?
C39 O4 Ag4 106.9(15) . . ?
Ag7 O5 Ag10 113.7(9) 3_655 . ?
C45 O5 Ag7 128.5(17) . 3_655 ?
C45 O5 Ag10 115.2(17) . . ?
C45 O6 Ag6 117.8(17) . . ?
S1S O1S Ag1 121.2(11) . . ?
S2S O2S Ag1 116.9(12) . . ?
S2T O2S Ag1 119.1(16) . . ?
S3S O3S Ag2 116.4(11) . . ?
S4S O4S Ag9 121.8(12) . . ?
S5S O5S Ag9 132.7(11) . . ?
S6S O6S Ag6 115.2(12) . . ?
C1S S1S C2S 98.8(17) . . ?
O1S S1S C1S 104.6(16) . . ?
O1S S1S C2S 105.7(15) . . ?
C3S S2S C4S 100(2) . . ?
O2S S2S C3S 106(2) . . ?
O2S S2S C4S 100(2) . . ?
C5S S3S C6S 96.8(14) . . ?
O3S S3S C5S 105.5(14) . . ?
O3S S3S C6S 104.7(12) . . ?
C7S S4S C8S 99.0(16) . . ?
O4S S4S C7S 102.0(15) . . ?
O4S S4S C8S 105.2(16) . . ?
C10S S5S C9S 97.3(16) . . ?
O5S S5S C9S 107.1(14) . . ?
O5S S5S C10S 103.9(12) . . ?
C11S S6S C12S 100.0(16) . . ?
O6S S6S C11S 105.9(13) . . ?
O6S S6S C12S 104.5(14) . . ?
C3S S2T C4S 99(3) . . ?
O2S S2T C3S 123(3) . . ?
O2S S2T C4S 94(2) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_AG_AG221
_database_code_depnum_ccdc_archive 'CCDC 1902311'
loop_
_audit_author_name
_audit_author_address
'Andreas Orthaber'
;Uppsala University
Sweden
;
_audit_update_record             
;
2019-10-10 deposited with the CCDC.	2019-10-14 downloaded from the CCDC.
;
# start Validation Reply Form
_vrf_PLAT973_AG_AG221            
;
PROBLEM: Check Calcd Positive Resid. Density on       Ag1       2.39 eA-3  
RESPONSE: Sligt disorder around the silver centers leads to
slightly higher peaks and holes around the silver
centers
;
_vrf_PLAT260_AG_AG221            
;
PROBLEM: Large Average Ueq of Residue Including       Cl1      0.302 Check 
RESPONSE: The perchlorate is poorly ordered (nearby the masked void) 
and certain resatraints had to be aplied for a reasonable solution.
;
_vrf_PLAT342_AG_AG221            
;
PROBLEM: Low Bond Precision on  C-C Bonds ...............      0.037 Ang.  
RESPONSE: Due to the low data quality no higher bond precision could be achieved
;
_vrf_PLAT364_AG_AG221            
;
PROBLEM: Short  C(sp3)-C(sp)  Bond  C41      - C42      .       1.22 Ang.  
RESPONSE: C41 is actually the alkynide carbon atom thus C41-C42 is 
a triple bond
;
_vrf_PLAT919_AG_AG221            
;
PROBLEM: Reflection # Likely Affected by the Beamstop ...          1 Check 
RESPONSE: omitting this reflection had barely any effect on the solution.
;
_vrf_PLAT975_AG_AG221            
;
PROBLEM: Check Calcd Resid. Dens.  1.00A   From O1C             1.72 eA-3  
RESPONSE: The perchlorate is poorly ordered (nearby the masked void) 
and certain resatraints had to be aplied for a reasonable solution.
;
# end Validation Reply Form
_audit_creation_date             2019-10-10
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C74 H86 Ag15 N4 O8, Cl O4'
_chemical_formula_sum            'C74 H86 Ag15 Cl N4 O12'
_chemical_formula_weight         2876.96
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   13.969(3)
_cell_length_b                   15.629(3)
_cell_length_c                   20.922(4)
_cell_angle_alpha                74.668(2)
_cell_angle_beta                 77.661(2)
_cell_angle_gamma                84.863(2)
_cell_volume                     4300.9(15)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    48854
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      25.0
_cell_measurement_theta_min      1.0
_shelx_estimated_absorpt_T_max   0.796
_shelx_estimated_absorpt_T_min   0.705
_exptl_absorpt_coefficient_mu    3.416
_exptl_absorpt_correction_T_max  0.7454
_exptl_absorpt_correction_T_min  0.5159
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    2.222
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             2752
_exptl_crystal_size_max          0.11
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.07
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0610
_diffrn_reflns_av_unetI/netI     0.0643
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            48950
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        25.026
_diffrn_reflns_theta_max         25.026
_diffrn_reflns_theta_min         1.030
_diffrn_ambient_temperature      150.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker Apex-II'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                9556
_reflns_number_total             15192
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         2.617
_refine_diff_density_min         -2.341
_refine_diff_density_rms         0.396
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.026
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     973
_refine_ls_number_reflns         15192
_refine_ls_number_restraints     173
_refine_ls_R_factor_all          0.1275
_refine_ls_R_factor_gt           0.0770
_refine_ls_restrained_S_all      1.024
_refine_ls_shift/su_max          0.066
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1338P)²+74.6510P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2092
_refine_ls_wR_factor_ref         0.2591
_refine_special_details          
;  
Solvent Masking as implemented in Olex2 was usted to treat diffuse 
scattering contributions from disordered solvent molecules.
A cavity of 254 Å^3 containing approx. 124 electrons was identified and tentativley assigned to four DCM molecules each.
_olex2_refinement_description

1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 C13-C14 = C13-C15
 1.55 with sigma of 0.02
 C38-C39 = C38-C40
 1.55 with sigma of 0.02
 C18-C19 = C18-C20
 1.55 with sigma of 0.02
 C13-C14 ∼ C13-C15
 with sigma of 0.02
 C38-C39 ∼ C38-C40
 with sigma of 0.02
 C18-C19 ∼ C18-C20
 with sigma of 0.02
 Cl1-O1C ∼ Cl1-O2C ∼ Cl1-O3C ∼ Cl1-O4C
 with sigma of 0.02
3. Uiso/Uaniso restraints and constraints
Uanis(C3) ∼ Ueq, Uanis(C4) ∼ Ueq, Uanis(C5) ∼ Ueq, Uanis(C9) ∼
Ueq, Uanis(C10) ∼ Ueq, Uanis(C13) ∼ Ueq, Uanis(C14) ∼ Ueq,
Uanis(C15) ∼ Ueq, Uanis(C18) ∼ Ueq, Uanis(C19) ∼ Ueq, Uanis(C44)
∼ Ueq, Uanis(C45) ∼ Ueq, Uanis(C29) ∼ Ueq, Uanis(C33) ∼ Ueq,
Uanis(C38) ∼ Ueq, Uanis(C42) ∼ Ueq, Uanis(C49) ∼ Ueq: with sigma of
0.005 and sigma for terminal atoms of 0.01
Uanis(O2C) ∼ Ueq, Uanis(O4C) ∼ Ueq, Uanis(O1C) ∼ Ueq: with sigma of
0.005 and sigma for terminal atoms of 0.01
Uanis(C43) ∼ Ueq, Uanis(C43) ∼ Ueq, Uanis(O3C) ∼ Ueq: with sigma of
0.005 and sigma for terminal atoms of 0.01
4. Rigid body (RIGU) restrains
 O3C, Cl1, O1C, O4C, O2C
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
5.a Ternary CH refined with riding coordinates:
 C3(H3), C8(H8), C13(H13), C18(H18), C23(H23), C28(H28), C33(H33), C38(H38),
 C48(H48), C43(H43)
5.b Me refined with riding coordinates:
 C44(H44A,H44B,H44C), C45(H45A,H45B,H45C)
5.c Aromatic/amide H refined with riding coordinates:
 C3A(H3A), C4A(H4AA), C5A(H5AA), C6A(H6A), C9A(H9AA), C10A(H10D), C11A(H11A),
 C12A(H12A), C15A(H15D), C16A(H16A), C17A(H17A), C18A(H18A), C21A(H21A),
 C22A(H22A), C23A(H23A), C24A(H24D)
5.d Idealised Me refined as rotating group:
 C4(H4A,H4B,H4C), C5(H5A,H5B,H5C), C9(H9A,H9B,H9C), C10(H10A,H10B,H10C),
 C14(H14A,H14B,H14C), C15(H15A,H15B,H15C), C19(H19A,H19B,H19C), C20(H20A,H20B,
 H20C), C24(H24A,H24B,H24C), C25(H25A,H25B,H25C), C29(H29A,H29B,H29C), C30(H30A,
 H30B,H30C), C34(H34A,H34B,H34C), C35(H35A,H35B,H35C), C39(H39A,H39B,H39C),
 C40(H40A,H40B,H40C), C49(H49A,H49B,H49C), C50(H50A,H50B,H50C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.97463(8) 0.48226(8) 0.42407(6) 0.0455(3) Uani 1 1 d . . . . .
Ag2 Ag 0.83103(10) 0.56457(10) 0.52025(7) 0.0586(4) Uani 1 1 d . . . . .
Ag3 Ag 0.82242(9) 0.43642(10) 0.64633(6) 0.0544(4) Uani 1 1 d . . . . .
Ag4 Ag 0.88338(9) 0.59100(9) 0.68145(6) 0.0518(3) Uani 1 1 d . . . . .
Ag5 Ag 0.66396(9) 0.56703(9) 0.94832(7) 0.0538(3) Uani 1 1 d . . . . .
Ag6 Ag 0.48189(14) 0.67415(12) 0.99495(9) 0.0846(5) Uani 1 1 d . . . . .
Ag7 Ag 0.52581(8) 0.47542(8) 1.08169(6) 0.0437(3) Uani 1 1 d . . . . .
Ag8 Ag 0.25663(12) 0.73829(12) 1.02417(8) 0.0773(5) Uani 1 1 d . . . . .
Ag9 Ag 0.42700(12) 0.72741(13) 1.12298(8) 0.0780(5) Uani 1 1 d . . . . .
Ag10 Ag 0.32411(9) 0.57309(9) 1.11672(6) 0.0501(3) Uani 1 1 d . . . . .
Ag11 Ag 0.38541(8) 0.41719(9) 1.21501(6) 0.0483(3) Uani 1 1 d . . . . .
Ag12 Ag 0.24052(8) 0.66408(9) 1.21862(6) 0.0475(3) Uani 1 1 d . . . . .
Ag13 Ag 0.04289(11) 0.70766(13) 1.29687(9) 0.0766(5) Uani 1 1 d . . . . .
Ag14 Ag 0.20912(15) 0.74098(14) 1.37945(10) 0.0917(6) Uani 1 1 d . . . . .
Ag15 Ag 0.01332(16) 0.67011(13) 1.44350(9) 0.0936(6) Uani 1 1 d . . . . .
C1 C 0.8880(11) 0.5976(12) 0.4010(8) 0.050(4) Uani 1 1 d . . . . .
C2 C 0.8365(16) 0.6605(16) 0.3795(11) 0.077(6) Uani 1 1 d . . . . .
C3 C 0.775(2) 0.7410(19) 0.3510(14) 0.102(8) Uani 1 1 d . U . . .
H3 H 0.809820 0.794053 0.351825 0.122 Uiso 1 1 calc R . . . .
C4 C 0.773(2) 0.749(2) 0.2815(14) 0.114(9) Uani 1 1 d . U . . .
H4A H 0.839521 0.744735 0.255879 0.171 Uiso 1 1 calc GR . . . .
H4B H 0.742338 0.806860 0.262796 0.171 Uiso 1 1 calc GR . . . .
H4C H 0.734045 0.701581 0.278442 0.171 Uiso 1 1 calc GR . . . .
C5 C 0.687(2) 0.741(2) 0.3949(16) 0.130(11) Uani 1 1 d . U . . .
H5A H 0.697165 0.749539 0.437509 0.196 Uiso 1 1 calc GR . . . .
H5B H 0.656400 0.683541 0.403499 0.196 Uiso 1 1 calc GR . . . .
H5C H 0.643780 0.788638 0.374844 0.196 Uiso 1 1 calc GR . . . .
C6 C 1.0459(12) 0.3556(13) 0.4421(8) 0.048(4) Uani 1 1 d . . . . .
C7 C 1.0746(15) 0.2817(15) 0.4479(10) 0.067(5) Uani 1 1 d . . . . .
C8 C 1.112(2) 0.1862(13) 0.4633(13) 0.087(7) Uani 1 1 d . . . . .
H8 H 1.142276 0.174263 0.504344 0.104 Uiso 1 1 calc R . . . .
C9 C 1.1882(18) 0.1698(18) 0.4065(14) 0.097(7) Uani 1 1 d . U . . .
H9A H 1.215843 0.109199 0.419050 0.146 Uiso 1 1 calc GR . . . .
H9B H 1.240337 0.212252 0.395880 0.146 Uiso 1 1 calc GR . . . .
H9C H 1.158776 0.176911 0.366776 0.146 Uiso 1 1 calc GR . . . .
C10 C 1.028(2) 0.1244(19) 0.4782(14) 0.108(8) Uani 1 1 d . U . . .
H10A H 1.053722 0.062842 0.484929 0.162 Uiso 1 1 calc GR . . . .
H10B H 0.994131 0.139176 0.440071 0.162 Uiso 1 1 calc GR . . . .
H10C H 0.982166 0.131155 0.519214 0.162 Uiso 1 1 calc GR . . . .
C11 C 0.7737(14) 0.4152(13) 0.5644(9) 0.060(5) Uani 1 1 d . . . . .
C12 C 0.7359(15) 0.3984(16) 0.5245(11) 0.079(6) Uani 1 1 d . . . . .
C13 C 0.686(2) 0.374(2) 0.4763(15) 0.127(10) Uani 1 1 d D U . . .
H13 H 0.655738 0.318854 0.506778 0.152 Uiso 1 1 calc R . . . .
C14 C 0.7535(19) 0.3336(19) 0.4247(13) 0.103(8) Uani 1 1 d D U . . .
H14A H 0.811938 0.369058 0.405188 0.155 Uiso 1 1 calc GR . . . .
H14B H 0.719041 0.332256 0.388785 0.155 Uiso 1 1 calc GR . . . .
H14C H 0.772972 0.272913 0.446580 0.155 Uiso 1 1 calc GR . . . .
C15 C 0.594(3) 0.431(3) 0.470(2) 0.186(17) Uani 1 1 d D U . . .
H15A H 0.562063 0.414466 0.437455 0.279 Uiso 1 1 calc GR . . . .
H15B H 0.610589 0.493491 0.453411 0.279 Uiso 1 1 calc GR . . . .
H15C H 0.549676 0.421036 0.513858 0.279 Uiso 1 1 calc GR . . . .
C16 C 0.8918(10) 0.4303(12) 0.7273(9) 0.050(4) Uani 1 1 d . . . . .
C17 C 0.9495(10) 0.4385(12) 0.7620(8) 0.050(4) Uani 1 1 d . . . . .
C18 C 1.0185(15) 0.4500(19) 0.8017(11) 0.100(8) Uani 1 1 d D U . . .
H18 H 1.045097 0.387722 0.805160 0.120 Uiso 1 1 calc R . . . .
C19 C 0.982(2) 0.431(2) 0.8768(12) 0.137(11) Uani 1 1 d D U . . .
H19A H 0.945222 0.482545 0.888293 0.206 Uiso 1 1 calc GR . . . .
H19B H 1.038294 0.416958 0.899538 0.206 Uiso 1 1 calc GR . . . .
H19C H 0.939698 0.379625 0.891481 0.206 Uiso 1 1 calc GR . . . .
C20 C 1.1157(13) 0.4869(16) 0.7620(11) 0.079(6) Uani 1 1 d D . . . .
H20A H 1.144336 0.451754 0.729669 0.119 Uiso 1 1 calc GR . . . .
H20B H 1.160069 0.484250 0.792982 0.119 Uiso 1 1 calc GR . . . .
H20C H 1.105809 0.548749 0.737444 0.119 Uiso 1 1 calc GR . . . .
C21 C 0.6014(11) 0.5910(12) 1.0588(8) 0.049(4) Uani 1 1 d . . . . .
C22 C 0.6549(13) 0.6486(15) 1.0553(11) 0.070(5) Uani 1 1 d . . . . .
C23 C 0.7233(16) 0.7162(17) 1.0538(13) 0.090(8) Uani 1 1 d . . . . .
H23 H 0.705960 0.769811 1.019392 0.108 Uiso 1 1 calc R . . . .
C24 C 0.8225(17) 0.695(2) 1.0283(16) 0.124(12) Uani 1 1 d . . . . .
H24A H 0.833479 0.707174 0.978949 0.187 Uiso 1 1 calc GR . . . .
H24B H 0.837222 0.632449 1.047544 0.187 Uiso 1 1 calc GR . . . .
H24C H 0.865305 0.731951 1.040756 0.187 Uiso 1 1 calc GR . . . .
C25 C 0.7053(17) 0.7460(16) 1.1196(12) 0.090(7) Uani 1 1 d . . . . .
H25A H 0.730111 0.699718 1.154488 0.135 Uiso 1 1 calc GR . . . .
H25B H 0.634803 0.756336 1.134540 0.135 Uiso 1 1 calc GR . . . .
H25C H 0.739438 0.801043 1.111835 0.135 Uiso 1 1 calc GR . . . .
C26 C 0.4622(10) 0.3530(12) 1.1150(7) 0.042(4) Uani 1 1 d . . . . .
C27 C 0.4410(13) 0.2766(13) 1.1407(9) 0.057(4) Uani 1 1 d . . . . .
C28 C 0.414(2) 0.1785(15) 1.1681(12) 0.087(7) Uani 1 1 d . . . . .
H28 H 0.475480 0.141930 1.172825 0.104 Uiso 1 1 calc R . . . .
C29 C 0.365(2) 0.147(2) 1.1234(16) 0.119(10) Uani 1 1 d . U . . .
H29A H 0.311396 0.188288 1.111259 0.179 Uiso 1 1 calc GR . . . .
H29B H 0.339577 0.087987 1.146661 0.179 Uiso 1 1 calc GR . . . .
H29C H 0.412954 0.143017 1.082249 0.179 Uiso 1 1 calc GR . . . .
C30 C 0.350(2) 0.1644(18) 1.2358(13) 0.101(8) Uani 1 1 d . . . . .
H30A H 0.282383 0.184570 1.231027 0.151 Uiso 1 1 calc GR . . . .
H30B H 0.373258 0.198093 1.262314 0.151 Uiso 1 1 calc GR . . . .
H30C H 0.350501 0.101044 1.258858 0.151 Uiso 1 1 calc GR . . . .
C31 C 0.2678(11) 0.5811(12) 1.0305(9) 0.052(4) Uani 1 1 d . . . . .
C32 C 0.2304(14) 0.5959(15) 0.9813(10) 0.069(5) Uani 1 1 d . . . . .
C33 C 0.1828(19) 0.6002(19) 0.9256(13) 0.099(8) Uani 1 1 d . U . . .
H33 H 0.193169 0.537875 0.920871 0.119 Uiso 1 1 calc R . . . .
C34 C 0.0792(17) 0.608(3) 0.9407(13) 0.130(13) Uani 1 1 d . . . . .
H34A H 0.053327 0.609766 0.900390 0.195 Uiso 1 1 calc GR . . . .
H34B H 0.059343 0.663588 0.954637 0.195 Uiso 1 1 calc GR . . . .
H34C H 0.053207 0.557762 0.977365 0.195 Uiso 1 1 calc GR . . . .
C35 C 0.2383(19) 0.650(2) 0.8607(11) 0.109(9) Uani 1 1 d . . . . .
H35A H 0.248731 0.709556 0.863370 0.164 Uiso 1 1 calc GR . . . .
H35B H 0.201447 0.653056 0.825110 0.164 Uiso 1 1 calc GR . . . .
H35C H 0.301817 0.618933 0.850288 0.164 Uiso 1 1 calc GR . . . .
C36 C 0.3873(12) 0.5781(12) 1.1981(9) 0.052(4) Uani 1 1 d . . . . .
C37 C 0.4453(11) 0.5708(12) 1.2366(10) 0.057(5) Uani 1 1 d . . . . .
C38 C 0.5055(16) 0.5496(18) 1.2859(14) 0.106(8) Uani 1 1 d D U . . .
H38 H 0.475278 0.494045 1.316588 0.127 Uiso 1 1 calc R . . . .
C39 C 0.489(2) 0.609(2) 1.3328(16) 0.154(16) Uani 1 1 d D . . . .
H39A H 0.419342 0.610970 1.353562 0.232 Uiso 1 1 calc GR . . . .
H39B H 0.509637 0.668829 1.307518 0.232 Uiso 1 1 calc GR . . . .
H39C H 0.527569 0.585915 1.368187 0.232 Uiso 1 1 calc GR . . . .
C40 C 0.6065(12) 0.5155(14) 1.2613(11) 0.072(6) Uani 1 1 d D . . . .
H40A H 0.603453 0.477968 1.231005 0.108 Uiso 1 1 calc GR . . . .
H40B H 0.633922 0.480575 1.299965 0.108 Uiso 1 1 calc GR . . . .
H40C H 0.648399 0.565657 1.236777 0.108 Uiso 1 1 calc GR . . . .
C41 C 0.4110(14) 0.7924(12) 1.0187(10) 0.064(5) Uani 1 1 d . . . . .
C42 C 0.374(2) 0.8669(19) 1.0021(14) 0.100(8) Uani 1 1 d . U . . .
C46 C 0.0521(18) 0.7950(13) 1.3667(11) 0.076(6) Uani 1 1 d . . . . .
C47 C 0.0585(19) 0.8682(14) 1.3321(12) 0.082(7) Uani 1 1 d . . . . .
C48 C 0.058(3) 0.9649(15) 1.2911(14) 0.108(9) Uani 1 1 d . . . . .
H48 H -0.010446 0.987735 1.287696 0.130 Uiso 1 1 calc R . . . .
C49 C 0.121(3) 0.970(3) 1.2205(19) 0.157(14) Uani 1 1 d . U . . .
H49A H 0.083994 0.949159 1.193031 0.236 Uiso 1 1 calc GR . . . .
H49B H 0.180630 0.931747 1.224821 0.236 Uiso 1 1 calc GR . . . .
H49C H 0.139915 1.031114 1.198584 0.236 Uiso 1 1 calc GR . . . .
C50 C 0.102(3) 1.0146(19) 1.3260(17) 0.133(12) Uani 1 1 d . . . . .
H50A H 0.081892 0.990796 1.374980 0.199 Uiso 1 1 calc GR . . . .
H50B H 0.080817 1.077233 1.313612 0.199 Uiso 1 1 calc GR . . . .
H50C H 0.173759 1.009476 1.313210 0.199 Uiso 1 1 calc GR . . . .
C1A C 0.8228(12) 0.6503(11) 0.8237(8) 0.048(4) Uani 1 1 d . . . . .
C2A C 0.9129(11) 0.7031(12) 0.7855(9) 0.052(4) Uani 1 1 d . . . . .
C3A C 1.0347(13) 0.7358(13) 0.6914(9) 0.061(5) Uani 1 1 d . . . . .
H3A H 1.063925 0.728654 0.647716 0.073 Uiso 1 1 calc R . . . .
C4A C 1.0787(14) 0.7901(15) 0.7166(11) 0.072(6) Uani 1 1 d . . . . .
H4AA H 1.136265 0.820382 0.691447 0.086 Uiso 1 1 calc R . . . .
C5A C 1.0363(16) 0.7992(15) 0.7801(12) 0.081(6) Uani 1 1 d . . . . .
H5AA H 1.064953 0.836223 0.799838 0.098 Uiso 1 1 calc R . . . .
C6A C 0.9530(13) 0.7555(14) 0.8153(10) 0.065(5) Uani 1 1 d . . . . .
H6A H 0.923679 0.761332 0.859350 0.078 Uiso 1 1 calc R . . . .
C7A C 0.3324(12) 0.3615(13) 1.3823(9) 0.055(4) Uani 1 1 d . . . . .
C8A C 0.4238(12) 0.3046(13) 1.3637(9) 0.056(4) Uani 1 1 d . . . . .
C9A C 0.5435(14) 0.2699(15) 1.2788(10) 0.070(6) Uani 1 1 d . . . . .
H9AA H 0.571010 0.278753 1.231982 0.084 Uiso 1 1 calc R . . . .
C10A C 0.5886(14) 0.2081(16) 1.3242(11) 0.075(6) Uani 1 1 d . . . . .
H10D H 0.644084 0.173135 1.309700 0.090 Uiso 1 1 calc R . . . .
C11A C 0.5501(18) 0.1997(18) 1.3902(12) 0.093(7) Uani 1 1 d . . . . .
H11A H 0.582159 0.161569 1.423325 0.112 Uiso 1 1 calc R . . . .
C12A C 0.4632(13) 0.2464(14) 1.4108(10) 0.064(5) Uani 1 1 d . . . . .
H12A H 0.433350 0.236710 1.457323 0.077 Uiso 1 1 calc R . . . .
C13A C 0.0809(14) 0.7861(14) 1.1391(10) 0.065(5) Uani 1 1 d . . . . .
C14A C 0.0473(13) 0.8288(12) 1.0725(11) 0.061(5) Uani 1 1 d . . . . .
C15A C 0.080(2) 0.8568(16) 0.9540(12) 0.095(8) Uani 1 1 d . . . . .
H15D H 0.120181 0.848376 0.913274 0.115 Uiso 1 1 calc R . . . .
C16A C -0.010(2) 0.9076(18) 0.9527(16) 0.105(9) Uani 1 1 d . . . . .
H16A H -0.027676 0.937927 0.910975 0.126 Uiso 1 1 calc R . . . .
C17A C -0.068(2) 0.9119(17) 1.0109(18) 0.104(9) Uani 1 1 d . . . . .
H17A H -0.130616 0.941465 1.010542 0.125 Uiso 1 1 calc R . . . .
C18A C -0.0401(16) 0.8742(14) 1.0724(14) 0.083(7) Uani 1 1 d . . . . .
H18A H -0.081352 0.880056 1.113562 0.100 Uiso 1 1 calc R . . . .
C19A C 0.3830(15) 0.8019(13) 1.2475(11) 0.064(5) Uani 1 1 d . . . . .
C20A C 0.4020(19) 0.8498(15) 1.2996(12) 0.084(7) Uani 1 1 d . . . . .
C21A C 0.349(3) 0.8837(19) 1.4045(17) 0.127(12) Uani 1 1 d . . . . .
H21A H 0.305705 0.874329 1.447282 0.153 Uiso 1 1 calc R . . . .
C22A C 0.424(3) 0.941(2) 1.388(2) 0.144(15) Uani 1 1 d . . . . .
H22A H 0.429976 0.975380 1.418187 0.173 Uiso 1 1 calc R . . . .
C23A C 0.486(3) 0.948(2) 1.332(2) 0.136(13) Uani 1 1 d . . . . .
H23A H 0.540946 0.983928 1.322887 0.163 Uiso 1 1 calc R . . . .
C24A C 0.4768(17) 0.9052(14) 1.2854(13) 0.086(7) Uani 1 1 d . . . . .
H24D H 0.521912 0.914151 1.243466 0.103 Uiso 1 1 calc R . . . .
N1 N 0.9502(10) 0.6901(10) 0.7248(7) 0.054(3) Uani 1 1 d . . . . .
N2 N 0.4633(9) 0.3182(10) 1.2968(6) 0.050(3) Uani 1 1 d . . . . .
N3 N 0.1069(14) 0.8200(11) 1.0155(9) 0.075(5) Uani 1 1 d . . . . .
N4 N 0.3375(18) 0.8394(14) 1.3571(10) 0.098(7) Uani 1 1 d . . . . .
O1 O 0.7828(8) 0.6074(9) 0.7923(6) 0.057(3) Uani 1 1 d . . . . .
O2 O 0.7930(8) 0.6509(8) 0.8847(6) 0.057(3) Uani 1 1 d . . . . .
O3 O 0.2925(7) 0.4071(9) 1.3347(6) 0.056(3) Uani 1 1 d . . . . .
O4 O 0.3045(9) 0.3540(9) 1.4433(6) 0.061(3) Uani 1 1 d . . . . .
O5 O 0.1678(9) 0.7574(9) 1.1358(6) 0.066(3) Uani 1 1 d . . . . .
O6 O 0.0180(10) 0.7855(10) 1.1901(7) 0.080(4) Uani 1 1 d . . . . .
O7 O 0.4472(11) 0.8057(10) 1.1963(7) 0.079(4) Uani 1 1 d . . . . .
O8 O 0.3003(9) 0.7635(9) 1.2627(7) 0.065(3) Uani 1 1 d . . . . .
C44 C 0.290(3) 0.982(3) 1.055(2) 0.195(19) Uani 1 1 d . U . . .
H44A H 0.234309 0.945030 1.079654 0.293 Uiso 1 1 calc R . . . .
H44B H 0.344342 0.966196 1.079532 0.293 Uiso 1 1 calc R . . . .
H44C H 0.270977 1.044574 1.050814 0.293 Uiso 1 1 calc R . . . .
C43 C 0.328(4) 0.963(3) 0.975(3) 0.186(17) Uani 1 1 d . U . . .
H43 H 0.272875 0.963096 0.951286 0.223 Uiso 1 1 calc R . . . .
C45 C 0.415(4) 1.015(3) 0.929(3) 0.22(2) Uani 1 1 d . U . . .
H45A H 0.392686 1.076232 0.910063 0.327 Uiso 1 1 calc R . . . .
H45B H 0.464356 1.016525 0.955859 0.327 Uiso 1 1 calc R . . . .
H45C H 0.443244 0.986919 0.892707 0.327 Uiso 1 1 calc R . . . .
Cl1 Cl 0.2453(8) 0.9689(9) 0.7849(6) 0.166(4) Uani 1 1 d D U . . .
O1C O 0.270(4) 0.986(4) 0.7035(15) 0.342(17) Uani 1 1 d D U . . .
O2C O 0.284(4) 0.875(3) 0.824(3) 0.331(17) Uani 1 1 d D U . . .
O3C O 0.269(4) 1.033(3) 0.828(3) 0.347(17) Uani 1 1 d D U . . .
O4C O 0.130(2) 0.995(4) 0.798(3) 0.324(16) Uani 1 1 d D U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Ag2 2.9848(17) . ?
Ag1 Ag2 3.1317(19) 2_766 ?
Ag1 Ag3 3.1135(17) 2_766 ?
Ag1 Ag4 3.0295(16) 2_766 ?
Ag1 Ag15 3.176(2) 1_654 ?
Ag1 Ag15 3.165(2) 2_667 ?
Ag1 C1 2.084(18) . ?
Ag1 C6 2.113(19) . ?
Ag2 Ag3 2.846(2) . ?
Ag2 Ag15 3.064(2) 1_654 ?
Ag2 C1 2.381(16) . ?
Ag2 C6 2.571(16) 2_766 ?
Ag2 C11 2.412(19) . ?
Ag2 O4 2.291(12) 2_667 ?
Ag3 Ag4 2.9456(19) . ?
Ag3 Ag12 2.8393(18) 2_667 ?
Ag3 Ag13 2.967(2) 2_667 ?
Ag3 Ag14 3.047(2) 2_667 ?
Ag3 Ag15 3.271(2) 2_667 ?
Ag3 C11 2.086(17) . ?
Ag3 C16 2.101(17) . ?
Ag4 C6 2.505(16) 2_766 ?
Ag4 C16 2.441(18) . ?
Ag4 N1 2.335(14) . ?
Ag4 O1 2.505(10) . ?
Ag4 O3 2.547(10) 2_667 ?
Ag5 Ag6 3.044(2) . ?
Ag5 Ag7 3.1050(17) . ?
Ag5 Ag7 3.0180(17) 2_667 ?
Ag5 Ag10 2.8440(18) 2_667 ?
Ag5 C21 2.405(15) . ?
Ag5 C26 2.480(16) 2_667 ?
Ag5 C31 2.390(18) 2_667 ?
Ag5 O2 2.284(11) . ?
Ag6 Ag7 3.186(2) 2_667 ?
Ag6 Ag7 3.236(2) . ?
Ag6 Ag8 3.197(2) . ?
Ag6 Ag9 2.940(2) . ?
Ag6 Ag10 3.153(2) . ?
Ag6 C21 2.431(17) . ?
Ag6 C26 2.402(13) 2_667 ?
Ag6 C41 2.143(17) . ?
Ag7 Ag10 3.1216(17) . ?
Ag7 Ag11 3.0156(16) . ?
Ag7 C21 2.067(17) . ?
Ag7 C26 2.067(17) . ?
Ag8 Ag10 3.001(2) . ?
Ag8 C31 2.418(18) . ?
Ag8 C32 2.69(2) . ?
Ag8 C41 2.36(2) . ?
Ag8 C42 2.59(3) . ?
Ag8 N3 2.366(18) . ?
Ag8 O5 2.480(12) . ?
Ag9 Ag10 2.961(2) . ?
Ag9 Ag12 2.9927(19) . ?
Ag9 C36 2.479(19) . ?
Ag9 C41 2.20(2) . ?
Ag9 O7 2.273(14) . ?
Ag10 Ag11 2.9373(19) . ?
Ag10 Ag12 2.8589(17) . ?
Ag10 C31 2.088(17) . ?
Ag10 C36 2.100(17) . ?
Ag11 C26 2.549(13) . ?
Ag11 C36 2.447(17) . ?
Ag11 N2 2.366(14) . ?
Ag11 O1 2.457(10) 2_667 ?
Ag11 O3 2.533(11) . ?
Ag12 Ag13 3.0145(19) . ?
Ag12 C16 2.363(15) 2_667 ?
Ag12 C36 2.373(16) . ?
Ag12 O5 2.304(13) . ?
Ag12 O8 2.298(11) . ?
Ag13 Ag14 3.325(3) . ?
Ag13 Ag15 2.911(3) . ?
Ag13 C16 2.402(17) 2_667 ?
Ag13 C46 2.28(2) . ?
Ag13 O6 2.326(15) . ?
Ag14 Ag15 2.949(3) . ?
Ag14 C11 2.43(2) 2_667 ?
Ag14 C46 2.32(2) . ?
Ag14 N4 2.357(19) . ?
Ag14 O8 2.451(13) . ?
Ag15 C1 2.587(17) 1_456 ?
Ag15 C6 2.297(16) 2_667 ?
Ag15 C7 2.60(2) 2_667 ?
Ag15 C46 2.20(2) . ?
C1 C2 1.21(3) . ?
C2 C3 1.51(4) . ?
C3 H3 1.0000 . ?
C3 C4 1.43(4) . ?
C3 C5 1.37(4) . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C6 C7 1.17(3) . ?
C7 C8 1.51(3) . ?
C8 H8 1.0000 . ?
C8 C9 1.47(3) . ?
C8 C10 1.52(3) . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 C12 1.17(2) . ?
C12 C13 1.48(3) . ?
C13 H13 1.0000 . ?
C13 C14 1.508(15) . ?
C13 C15 1.505(15) . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 C17 1.23(2) . ?
C17 C18 1.45(3) . ?
C18 H18 1.0000 . ?
C18 C19 1.501(15) . ?
C18 C20 1.506(14) . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 C22 1.20(2) . ?
C22 C23 1.48(3) . ?
C23 H23 1.0000 . ?
C23 C24 1.42(3) . ?
C23 C25 1.53(3) . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C26 C27 1.21(2) . ?
C27 C28 1.54(3) . ?
C28 H28 1.0000 . ?
C28 C29 1.47(3) . ?
C28 C30 1.48(3) . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
C31 C32 1.21(2) . ?
C32 C33 1.44(3) . ?
C33 H33 1.0000 . ?
C33 C34 1.42(3) . ?
C33 C35 1.46(3) . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C35 H35A 0.9800 . ?
C35 H35B 0.9800 . ?
C35 H35C 0.9800 . ?
C36 C37 1.24(2) . ?
C37 C38 1.42(3) . ?
C38 H38 1.0000 . ?
C38 C39 1.490(15) . ?
C38 C40 1.497(14) . ?
C39 H39A 0.9800 . ?
C39 H39B 0.9800 . ?
C39 H39C 0.9800 . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?
C41 C42 1.22(3) . ?
C42 C43 1.60(5) . ?
C46 C47 1.18(3) . ?
C47 C48 1.53(3) . ?
C48 H48 1.0000 . ?
C48 C49 1.54(4) . ?
C48 C50 1.45(4) . ?
C49 H49A 0.9800 . ?
C49 H49B 0.9800 . ?
C49 H49C 0.9800 . ?
C50 H50A 0.9800 . ?
C50 H50B 0.9800 . ?
C50 H50C 0.9800 . ?
C1A C2A 1.52(2) . ?
C1A O1 1.283(18) . ?
C1A O2 1.257(18) . ?
C2A C6A 1.37(2) . ?
C2A N1 1.33(2) . ?
C3A H3A 0.9500 . ?
C3A C4A 1.36(3) . ?
C3A N1 1.39(2) . ?
C4A H4AA 0.9500 . ?
C4A C5A 1.37(3) . ?
C5A H5AA 0.9500 . ?
C5A C6A 1.37(3) . ?
C6A H6A 0.9500 . ?
C7A C8A 1.53(2) . ?
C7A O3 1.27(2) . ?
C7A O4 1.23(2) . ?
C8A C12A 1.33(3) . ?
C8A N2 1.36(2) . ?
C9A H9AA 0.9500 . ?
C9A C10A 1.38(3) . ?
C9A N2 1.34(2) . ?
C10A H10D 0.9500 . ?
C10A C11A 1.35(3) . ?
C11A H11A 0.9500 . ?
C11A C12A 1.41(3) . ?
C12A H12A 0.9500 . ?
C13A C14A 1.53(3) . ?
C13A O5 1.25(2) . ?
C13A O6 1.23(2) . ?
C14A C18A 1.36(3) . ?
C14A N3 1.33(3) . ?
C15A H15D 0.9500 . ?
C15A C16A 1.42(4) . ?
C15A N3 1.38(3) . ?
C16A H16A 0.9500 . ?
C16A C17A 1.33(4) . ?
C17A H17A 0.9500 . ?
C17A C18A 1.39(4) . ?
C18A H18A 0.9500 . ?
C19A C20A 1.55(3) . ?
C19A O7 1.23(2) . ?
C19A O8 1.29(2) . ?
C20A C24A 1.35(3) . ?
C20A N4 1.32(3) . ?
C21A H21A 0.9500 . ?
C21A C22A 1.36(4) . ?
C21A N4 1.39(3) . ?
C22A H22A 0.9500 . ?
C22A C23A 1.30(5) . ?
C23A H23A 0.9500 . ?
C23A C24A 1.34(4) . ?
C24A H24D 0.9500 . ?
C44 H44A 0.9800 . ?
C44 H44B 0.9800 . ?
C44 H44C 0.9800 . ?
C44 C43 1.74(6) . ?
C43 H43 1.0000 . ?
C43 C45 1.52(6) . ?
C45 H45A 0.9800 . ?
C45 H45B 0.9800 . ?
C45 H45C 0.9800 . ?
Cl1 O1C 1.62(3) . ?
Cl1 O2C 1.60(3) . ?
Cl1 O3C 1.61(3) . ?
Cl1 O4C 1.61(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag2 Ag1 Ag2 108.23(5) . 2_766 ?
Ag2 Ag1 Ag3 121.77(5) . 2_766 ?
Ag2 Ag1 Ag4 176.03(6) . 2_766 ?
Ag2 Ag1 Ag15 59.55(5) . 1_654 ?
Ag2 Ag1 Ag15 58.24(5) 2_766 2_667 ?
Ag2 Ag1 Ag15 80.36(6) 2_766 1_654 ?
Ag2 Ag1 Ag15 82.82(5) . 2_667 ?
Ag3 Ag1 Ag2 54.22(4) 2_766 2_766 ?
Ag3 Ag1 Ag15 62.66(5) 2_766 1_654 ?
Ag3 Ag1 Ag15 112.26(6) 2_766 2_667 ?
Ag4 Ag1 Ag2 74.53(4) 2_766 2_766 ?
Ag4 Ag1 Ag3 57.29(4) 2_766 2_766 ?
Ag4 Ag1 Ag15 118.84(5) 2_766 1_654 ?
Ag4 Ag1 Ag15 101.13(6) 2_766 2_667 ?
Ag15 Ag1 Ag15 111.09(5) 2_667 1_654 ?
C1 Ag1 Ag2 52.5(4) . . ?
C1 Ag1 Ag2 134.6(5) . 2_766 ?
C1 Ag1 Ag3 97.8(5) . 2_766 ?
C1 Ag1 Ag4 123.6(4) . 2_766 ?
C1 Ag1 Ag15 54.2(5) . 1_654 ?
C1 Ag1 Ag15 134.9(4) . 2_667 ?
C1 Ag1 C6 170.8(6) . . ?
C6 Ag1 Ag2 129.0(4) . . ?
C6 Ag1 Ag2 54.6(4) . 2_766 ?
C6 Ag1 Ag3 88.5(4) . 2_766 ?
C6 Ag1 Ag4 54.9(4) . 2_766 ?
C6 Ag1 Ag15 135.0(4) . 1_654 ?
C6 Ag1 Ag15 46.5(4) . 2_667 ?
Ag1 Ag2 Ag1 71.77(5) . 2_766 ?
Ag1 Ag2 Ag15 63.32(5) . 1_654 ?
Ag3 Ag2 Ag1 103.40(6) . . ?
Ag3 Ag2 Ag1 62.57(4) . 2_766 ?
Ag3 Ag2 Ag15 123.74(7) . 1_654 ?
Ag15 Ag2 Ag1 61.42(6) 1_654 2_766 ?
C1 Ag2 Ag1 43.9(4) . . ?
C1 Ag2 Ag1 102.8(4) . 2_766 ?
C1 Ag2 Ag3 146.7(4) . . ?
C1 Ag2 Ag15 55.0(4) . 1_654 ?
C1 Ag2 C6 102.1(5) . 2_766 ?
C1 Ag2 C11 111.4(6) . . ?
C6 Ag2 Ag1 97.8(4) 2_766 . ?
C6 Ag2 Ag1 42.1(4) 2_766 2_766 ?
C6 Ag2 Ag3 86.5(4) 2_766 . ?
C6 Ag2 Ag15 47.1(4) 2_766 1_654 ?
C11 Ag2 Ag1 83.0(5) . . ?
C11 Ag2 Ag1 93.5(4) . 2_766 ?
C11 Ag2 Ag3 45.8(4) . . ?
C11 Ag2 Ag15 142.3(5) . 1_654 ?
C11 Ag2 C6 130.0(6) . 2_766 ?
O4 Ag2 Ag1 129.2(3) 2_667 2_766 ?
O4 Ag2 Ag1 157.5(3) 2_667 . ?
O4 Ag2 Ag3 95.2(3) 2_667 . ?
O4 Ag2 Ag15 116.0(3) 2_667 1_654 ?
O4 Ag2 C1 115.5(5) 2_667 . ?
O4 Ag2 C6 95.9(5) 2_667 2_766 ?
O4 Ag2 C11 101.6(6) 2_667 . ?
Ag1 Ag3 Ag15 59.60(5) 2_766 2_667 ?
Ag2 Ag3 Ag1 63.22(4) . 2_766 ?
Ag2 Ag3 Ag4 80.21(5) . . ?
Ag2 Ag3 Ag13 134.66(6) . 2_667 ?
Ag2 Ag3 Ag14 106.14(6) . 2_667 ?
Ag2 Ag3 Ag15 83.11(6) . 2_667 ?
Ag4 Ag3 Ag1 59.92(4) . 2_766 ?
Ag4 Ag3 Ag13 102.53(6) . 2_667 ?
Ag4 Ag3 Ag14 169.59(7) . 2_667 ?
Ag4 Ag3 Ag15 118.42(6) . 2_667 ?
Ag12 Ag3 Ag1 129.30(5) 2_667 2_766 ?
Ag12 Ag3 Ag2 162.82(7) 2_667 . ?
Ag12 Ag3 Ag4 96.19(5) 2_667 . ?
Ag12 Ag3 Ag13 62.50(5) 2_667 2_667 ?
Ag12 Ag3 Ag14 80.11(6) 2_667 2_667 ?
Ag12 Ag3 Ag15 113.00(6) 2_667 2_667 ?
Ag13 Ag3 Ag1 78.96(5) 2_667 2_766 ?
Ag13 Ag3 Ag14 67.11(6) 2_667 2_667 ?
Ag13 Ag3 Ag15 55.38(6) 2_667 2_667 ?
Ag14 Ag3 Ag1 115.08(6) 2_667 2_766 ?
Ag14 Ag3 Ag15 55.51(5) 2_667 2_667 ?
C11 Ag3 Ag1 101.1(5) . 2_766 ?
C11 Ag3 Ag2 56.0(5) . . ?
C11 Ag3 Ag4 135.6(5) . . ?
C11 Ag3 Ag12 123.0(5) . 2_667 ?
C11 Ag3 Ag13 113.2(6) . 2_667 ?
C11 Ag3 Ag14 52.5(5) . 2_667 ?
C11 Ag3 Ag15 67.6(5) . 2_667 ?
C11 Ag3 C16 166.4(7) . . ?
C16 Ag3 Ag1 76.3(4) . 2_766 ?
C16 Ag3 Ag2 130.8(5) . . ?
C16 Ag3 Ag4 54.8(5) . . ?
C16 Ag3 Ag12 54.7(4) . 2_667 ?
C16 Ag3 Ag13 53.3(5) . 2_667 ?
C16 Ag3 Ag14 116.1(5) . 2_667 ?
C16 Ag3 Ag15 100.3(4) . 2_667 ?
Ag3 Ag4 Ag1 62.79(4) . 2_766 ?
C6 Ag4 Ag1 43.6(4) 2_766 2_766 ?
C6 Ag4 Ag3 85.6(4) 2_766 . ?
C6 Ag4 O1 154.2(5) 2_766 . ?
C6 Ag4 O3 94.7(5) 2_766 2_667 ?
C16 Ag4 Ag1 73.8(4) . 2_766 ?
C16 Ag4 Ag3 44.7(4) . . ?
C16 Ag4 C6 115.2(6) . 2_766 ?
C16 Ag4 O1 89.7(5) . . ?
C16 Ag4 O3 93.8(4) . 2_667 ?
N1 Ag4 Ag1 114.9(3) . 2_766 ?
N1 Ag4 Ag3 167.4(4) . . ?
N1 Ag4 C6 100.9(5) . 2_766 ?
N1 Ag4 C16 122.9(5) . . ?
N1 Ag4 O1 67.8(4) . . ?
N1 Ag4 O3 126.8(5) . 2_667 ?
O1 Ag4 Ag1 162.0(3) . 2_766 ?
O1 Ag4 Ag3 110.4(3) . . ?
O1 Ag4 O3 76.4(4) . 2_667 ?
O3 Ag4 Ag1 111.3(3) 2_667 2_766 ?
O3 Ag4 Ag3 62.6(3) 2_667 . ?
Ag6 Ag5 Ag7 63.49(5) . . ?
Ag7 Ag5 Ag6 63.40(5) 2_667 . ?
Ag7 Ag5 Ag7 70.06(5) 2_667 . ?
Ag10 Ag5 Ag6 127.64(6) 2_667 . ?
Ag10 Ag5 Ag7 64.27(4) 2_667 2_667 ?
Ag10 Ag5 Ag7 96.93(5) 2_667 . ?
C21 Ag5 Ag6 51.4(4) . . ?
C21 Ag5 Ag7 98.6(4) . 2_667 ?
C21 Ag5 Ag7 41.7(4) . . ?
C21 Ag5 Ag10 137.8(4) . 2_667 ?
C21 Ag5 C26 101.6(5) . 2_667 ?
C26 Ag5 Ag6 50.3(3) 2_667 . ?
C26 Ag5 Ag7 98.6(3) 2_667 . ?
C26 Ag5 Ag7 42.8(4) 2_667 2_667 ?
C26 Ag5 Ag10 90.7(3) 2_667 2_667 ?
C31 Ag5 Ag6 140.9(4) 2_667 . ?
C31 Ag5 Ag7 78.3(4) 2_667 . ?
C31 Ag5 Ag7 96.8(4) 2_667 2_667 ?
C31 Ag5 Ag10 46.0(4) 2_667 2_667 ?
C31 Ag5 C21 104.5(6) 2_667 . ?
C31 Ag5 C26 134.7(5) 2_667 2_667 ?
O2 Ag5 Ag6 114.4(3) . . ?
O2 Ag5 Ag7 155.1(3) . . ?
O2 Ag5 Ag7 133.0(3) . 2_667 ?
O2 Ag5 Ag10 102.1(3) . 2_667 ?
O2 Ag5 C21 115.9(5) . . ?
O2 Ag5 C26 97.0(5) . 2_667 ?
O2 Ag5 C31 103.8(5) . 2_667 ?
Ag5 Ag6 Ag7 57.90(4) . 2_667 ?
Ag5 Ag6 Ag7 59.17(5) . . ?
Ag5 Ag6 Ag8 159.60(8) . . ?
Ag5 Ag6 Ag10 116.97(7) . . ?
Ag7 Ag6 Ag7 66.38(5) 2_667 . ?
Ag7 Ag6 Ag8 101.76(7) 2_667 . ?
Ag8 Ag6 Ag7 113.75(6) . . ?
Ag9 Ag6 Ag5 127.42(9) . . ?
Ag9 Ag6 Ag7 146.54(7) . 2_667 ?
Ag9 Ag6 Ag7 88.09(7) . . ?
Ag9 Ag6 Ag8 67.97(5) . . ?
Ag9 Ag6 Ag10 58.04(5) . . ?
Ag10 Ag6 Ag7 58.49(4) . . ?
Ag10 Ag6 Ag7 89.36(6) . 2_667 ?
Ag10 Ag6 Ag8 56.41(5) . . ?
C21 Ag6 Ag5 50.6(4) . . ?
C21 Ag6 Ag7 93.7(4) . 2_667 ?
C21 Ag6 Ag7 39.7(4) . . ?
C21 Ag6 Ag8 137.9(4) . . ?
C21 Ag6 Ag9 77.6(4) . . ?
C21 Ag6 Ag10 85.2(4) . . ?
C26 Ag6 Ag5 52.6(4) 2_667 . ?
C26 Ag6 Ag7 96.9(4) 2_667 . ?
C26 Ag6 Ag7 40.4(4) 2_667 2_667 ?
C26 Ag6 Ag8 114.0(4) 2_667 . ?
C26 Ag6 Ag9 173.0(4) 2_667 . ?
C26 Ag6 Ag10 128.9(4) 2_667 . ?
C26 Ag6 C21 103.2(5) 2_667 . ?
C41 Ag6 Ag5 151.8(6) . . ?
C41 Ag6 Ag7 144.9(6) . 2_667 ?
C41 Ag6 Ag7 135.1(5) . . ?
C41 Ag6 Ag8 47.5(6) . . ?
C41 Ag6 Ag9 48.2(5) . . ?
C41 Ag6 Ag10 85.2(5) . . ?
C41 Ag6 C21 120.3(7) . . ?
C41 Ag6 C26 127.6(7) . 2_667 ?
Ag5 Ag7 Ag5 109.94(5) 2_667 . ?
Ag5 Ag7 Ag6 57.33(4) . . ?
Ag5 Ag7 Ag6 58.69(5) 2_667 2_667 ?
Ag5 Ag7 Ag6 84.61(6) 2_667 . ?
Ag5 Ag7 Ag6 84.07(5) . 2_667 ?
Ag5 Ag7 Ag10 55.16(4) 2_667 . ?
Ag5 Ag7 Ag10 116.08(5) . . ?
Ag6 Ag7 Ag6 113.62(5) 2_667 . ?
Ag10 Ag7 Ag6 59.42(4) . . ?
Ag10 Ag7 Ag6 113.83(5) . 2_667 ?
Ag11 Ag7 Ag5 72.55(4) . 2_667 ?
Ag11 Ag7 Ag5 170.41(6) . . ?
Ag11 Ag7 Ag6 114.58(5) . . ?
Ag11 Ag7 Ag6 104.74(5) . 2_667 ?
Ag11 Ag7 Ag10 57.16(4) . . ?
C21 Ag7 Ag5 50.7(4) . . ?
C21 Ag7 Ag5 133.3(5) . 2_667 ?
C21 Ag7 Ag6 134.6(4) . 2_667 ?
C21 Ag7 Ag6 48.7(5) . . ?
C21 Ag7 Ag10 92.4(4) . . ?
C21 Ag7 Ag11 120.6(4) . . ?
C26 Ag7 Ag5 54.6(4) . 2_667 ?
C26 Ag7 Ag5 132.7(4) . . ?
C26 Ag7 Ag6 139.2(4) . . ?
C26 Ag7 Ag6 48.9(4) . 2_667 ?
C26 Ag7 Ag10 91.7(4) . . ?
C26 Ag7 Ag11 56.6(4) . . ?
C26 Ag7 C21 171.8(6) . . ?
Ag10 Ag8 Ag6 61.06(5) . . ?
C31 Ag8 Ag6 70.4(4) . . ?
C31 Ag8 Ag10 43.7(4) . . ?
C31 Ag8 C32 26.8(6) . . ?
C31 Ag8 C42 138.2(7) . . ?
C31 Ag8 O5 107.5(5) . . ?
C32 Ag8 Ag6 82.8(4) . . ?
C32 Ag8 Ag10 70.5(5) . . ?
C41 Ag8 Ag6 42.1(4) . . ?
C41 Ag8 Ag10 85.3(5) . . ?
C41 Ag8 C31 111.2(6) . . ?
C41 Ag8 C32 124.3(6) . . ?
C41 Ag8 C42 28.0(7) . . ?
C41 Ag8 N3 128.0(6) . . ?
C41 Ag8 O5 100.9(5) . . ?
C42 Ag8 Ag6 67.8(6) . . ?
C42 Ag8 Ag10 111.2(7) . . ?
C42 Ag8 C32 142.5(7) . . ?
N3 Ag8 Ag6 162.4(4) . . ?
N3 Ag8 Ag10 136.5(4) . . ?
N3 Ag8 C31 120.6(6) . . ?
N3 Ag8 C32 102.0(6) . . ?
N3 Ag8 C42 100.2(8) . . ?
N3 Ag8 O5 68.7(5) . . ?
O5 Ag8 Ag6 123.5(3) . . ?
O5 Ag8 Ag10 79.1(3) . . ?
O5 Ag8 C32 121.2(5) . . ?
O5 Ag8 C42 94.9(7) . . ?
Ag6 Ag9 Ag10 64.58(6) . . ?
Ag6 Ag9 Ag12 119.46(7) . . ?
Ag10 Ag9 Ag12 57.39(4) . . ?
C36 Ag9 Ag6 97.3(4) . . ?
C36 Ag9 Ag10 44.3(4) . . ?
C36 Ag9 Ag12 50.4(4) . . ?
C41 Ag9 Ag6 46.6(4) . . ?
C41 Ag9 Ag10 89.1(5) . . ?
C41 Ag9 Ag12 115.0(5) . . ?
C41 Ag9 C36 133.1(7) . . ?
C41 Ag9 O7 122.2(6) . . ?
O7 Ag9 Ag6 153.1(3) . . ?
O7 Ag9 Ag10 141.6(4) . . ?
O7 Ag9 Ag12 87.3(3) . . ?
O7 Ag9 C36 102.8(5) . . ?
Ag5 Ag10 Ag6 89.10(5) 2_667 . ?
Ag5 Ag10 Ag7 60.57(4) 2_667 . ?
Ag5 Ag10 Ag8 107.43(6) 2_667 . ?
Ag5 Ag10 Ag9 144.12(6) 2_667 . ?
Ag5 Ag10 Ag11 76.25(5) 2_667 . ?
Ag5 Ag10 Ag12 153.72(6) 2_667 . ?
Ag7 Ag10 Ag6 62.09(5) . . ?
Ag8 Ag10 Ag6 62.54(6) . . ?
Ag8 Ag10 Ag7 123.24(6) . . ?
Ag9 Ag10 Ag6 57.38(5) . . ?
Ag9 Ag10 Ag7 89.89(6) . . ?
Ag9 Ag10 Ag8 70.40(6) . . ?
Ag11 Ag10 Ag6 119.48(6) . . ?
Ag11 Ag10 Ag7 59.61(4) . . ?
Ag11 Ag10 Ag8 176.06(6) . . ?
Ag11 Ag10 Ag9 107.55(6) . . ?
Ag12 Ag10 Ag6 116.85(6) . . ?
Ag12 Ag10 Ag7 133.78(5) . . ?
Ag12 Ag10 Ag8 83.06(6) . . ?
Ag12 Ag10 Ag9 61.86(5) . . ?
Ag12 Ag10 Ag11 93.01(5) . . ?
C31 Ag10 Ag5 55.4(5) . 2_667 ?
C31 Ag10 Ag6 74.9(5) . . ?
C31 Ag10 Ag7 100.7(5) . . ?
C31 Ag10 Ag8 53.1(5) . . ?
C31 Ag10 Ag9 118.4(5) . . ?
C31 Ag10 Ag11 130.1(5) . . ?
C31 Ag10 Ag12 124.5(5) . . ?
C31 Ag10 C36 173.9(7) . . ?
C36 Ag10 Ag5 128.6(5) . 2_667 ?
C36 Ag10 Ag6 100.0(5) . . ?
C36 Ag10 Ag7 79.4(4) . . ?
C36 Ag10 Ag8 121.8(5) . . ?
C36 Ag10 Ag9 55.6(5) . . ?
C36 Ag10 Ag11 55.1(5) . . ?
C36 Ag10 Ag12 54.6(4) . . ?
Ag10 Ag11 Ag7 63.24(4) . . ?
C26 Ag11 Ag7 42.6(4) . . ?
C26 Ag11 Ag10 87.3(4) . . ?
C36 Ag11 Ag7 76.9(4) . . ?
C36 Ag11 Ag10 44.8(4) . . ?
C36 Ag11 C26 117.8(6) . . ?
C36 Ag11 O1 103.4(5) . 2_667 ?
C36 Ag11 O3 88.3(5) . . ?
N2 Ag11 Ag7 111.4(3) . . ?
N2 Ag11 Ag10 164.9(3) . . ?
N2 Ag11 C26 97.6(5) . . ?
N2 Ag11 C36 121.4(5) . . ?
N2 Ag11 O1 120.4(5) . 2_667 ?
N2 Ag11 O3 67.5(4) . . ?
O1 Ag11 Ag7 115.7(3) 2_667 . ?
O1 Ag11 Ag10 73.3(3) 2_667 . ?
O1 Ag11 C26 93.4(4) 2_667 . ?
O1 Ag11 O3 77.5(3) 2_667 . ?
O3 Ag11 Ag7 162.0(3) . . ?
O3 Ag11 Ag10 112.8(3) . . ?
O3 Ag11 C26 153.8(5) . . ?
Ag3 Ag12 Ag9 139.11(6) 2_667 . ?
Ag3 Ag12 Ag10 119.04(6) 2_667 . ?
Ag3 Ag12 Ag13 60.83(5) 2_667 . ?
Ag9 Ag12 Ag13 148.83(7) . . ?
Ag10 Ag12 Ag9 60.75(5) . . ?
Ag10 Ag12 Ag13 139.91(6) . . ?
C16 Ag12 Ag3 46.5(4) 2_667 2_667 ?
C16 Ag12 Ag9 157.8(4) 2_667 . ?
C16 Ag12 Ag10 97.3(4) 2_667 . ?
C16 Ag12 Ag13 51.3(4) 2_667 . ?
C16 Ag12 C36 109.9(6) 2_667 . ?
C36 Ag12 Ag3 95.1(4) . 2_667 ?
C36 Ag12 Ag9 53.5(5) . . ?
C36 Ag12 Ag10 46.2(4) . . ?
C36 Ag12 Ag13 155.5(4) . . ?
O5 Ag12 Ag3 136.5(3) . 2_667 ?
O5 Ag12 Ag9 83.7(3) . . ?
O5 Ag12 Ag10 85.0(3) . . ?
O5 Ag12 Ag13 77.3(3) . . ?
O5 Ag12 C16 98.4(5) . 2_667 ?
O5 Ag12 C36 124.9(5) . . ?
O8 Ag12 Ag3 87.4(4) . 2_667 ?
O8 Ag12 Ag9 74.1(3) . . ?
O8 Ag12 Ag10 133.4(3) . . ?
O8 Ag12 Ag13 85.7(3) . . ?
O8 Ag12 C16 126.3(5) . 2_667 ?
O8 Ag12 C36 98.0(5) . . ?
O8 Ag12 O5 101.7(5) . . ?
Ag3 Ag13 Ag12 56.67(5) 2_667 . ?
Ag3 Ag13 Ag14 57.59(5) 2_667 . ?
Ag12 Ag13 Ag14 73.27(5) . . ?
Ag15 Ag13 Ag3 67.60(6) . 2_667 ?
Ag15 Ag13 Ag12 118.79(8) . . ?
Ag15 Ag13 Ag14 55.96(6) . . ?
C16 Ag13 Ag3 44.5(4) 2_667 2_667 ?
C16 Ag13 Ag12 50.2(4) 2_667 . ?
C16 Ag13 Ag14 99.0(4) 2_667 . ?
C16 Ag13 Ag15 103.7(4) 2_667 . ?
C46 Ag13 Ag3 96.1(6) . 2_667 ?
C46 Ag13 Ag12 113.0(6) . . ?
C46 Ag13 Ag14 44.3(6) . . ?
C46 Ag13 Ag15 48.3(5) . . ?
C46 Ag13 C16 140.6(7) . 2_667 ?
C46 Ag13 O6 114.3(7) . . ?
O6 Ag13 Ag3 137.0(3) . 2_667 ?
O6 Ag13 Ag12 82.9(3) . . ?
O6 Ag13 Ag14 128.2(4) . . ?
O6 Ag13 Ag15 155.2(3) . . ?
O6 Ag13 C16 99.6(5) . 2_667 ?
Ag3 Ag14 Ag13 55.30(5) 2_667 . ?
Ag15 Ag14 Ag3 66.10(6) . 2_667 ?
Ag15 Ag14 Ag13 54.90(6) . . ?
C11 Ag14 Ag3 43.0(4) 2_667 2_667 ?
C11 Ag14 Ag13 93.8(4) 2_667 . ?
C11 Ag14 Ag15 70.7(4) 2_667 . ?
C11 Ag14 O8 107.7(6) 2_667 . ?
C46 Ag14 Ag3 93.0(5) . 2_667 ?
C46 Ag14 Ag13 43.2(5) . . ?
C46 Ag14 Ag15 47.5(5) . . ?
C46 Ag14 C11 116.7(7) . 2_667 ?
C46 Ag14 N4 120.4(8) . . ?
C46 Ag14 O8 103.4(6) . . ?
N4 Ag14 Ag3 138.1(6) . 2_667 ?
N4 Ag14 Ag13 135.9(5) . . ?
N4 Ag14 Ag15 155.4(6) . . ?
N4 Ag14 C11 121.9(7) . 2_667 ?
N4 Ag14 O8 68.7(6) . . ?
O8 Ag14 Ag3 80.2(3) . 2_667 ?
O8 Ag14 Ag13 76.8(3) . . ?
O8 Ag14 Ag15 130.8(3) . . ?
Ag1 Ag15 Ag1 68.91(5) 2_667 1_456 ?
Ag1 Ag15 Ag3 90.64(7) 2_667 2_667 ?
Ag1 Ag15 Ag3 57.74(4) 1_456 2_667 ?
Ag2 Ag15 Ag1 60.34(5) 1_456 2_667 ?
Ag2 Ag15 Ag1 57.12(5) 1_456 1_456 ?
Ag2 Ag15 Ag3 114.47(7) 1_456 2_667 ?
Ag13 Ag15 Ag1 78.77(6) . 1_456 ?
Ag13 Ag15 Ag1 143.55(8) . 2_667 ?
Ag13 Ag15 Ag2 114.81(8) . 1_456 ?
Ag13 Ag15 Ag3 57.01(5) . 2_667 ?
Ag13 Ag15 Ag14 69.13(6) . . ?
Ag14 Ag15 Ag1 116.10(7) . 1_456 ?
Ag14 Ag15 Ag1 110.25(9) . 2_667 ?
Ag14 Ag15 Ag2 169.31(10) . 1_456 ?
Ag14 Ag15 Ag3 58.39(5) . 2_667 ?
C1 Ag15 Ag1 40.8(4) 1_456 1_456 ?
C1 Ag15 Ag1 97.3(4) 1_456 2_667 ?
C1 Ag15 Ag2 49.0(4) 1_456 1_456 ?
C1 Ag15 Ag3 84.6(3) 1_456 2_667 ?
C1 Ag15 Ag13 66.1(4) 1_456 . ?
C1 Ag15 Ag14 132.8(3) 1_456 . ?
C1 Ag15 C7 109.0(5) 1_456 2_667 ?
C6 Ag15 Ag1 41.9(5) 2_667 2_667 ?
C6 Ag15 Ag1 98.9(5) 2_667 1_456 ?
C6 Ag15 Ag2 55.1(4) 2_667 1_456 ?
C6 Ag15 Ag3 132.1(5) 2_667 2_667 ?
C6 Ag15 Ag13 167.4(4) 2_667 . ?
C6 Ag15 Ag14 122.3(4) 2_667 . ?
C6 Ag15 C1 104.0(5) 2_667 1_456 ?
C6 Ag15 C7 26.7(6) 2_667 2_667 ?
C7 Ag15 Ag1 68.3(5) 2_667 2_667 ?
C7 Ag15 Ag1 120.4(4) 2_667 1_456 ?
C7 Ag15 Ag2 66.2(4) 2_667 1_456 ?
C7 Ag15 Ag3 155.8(5) 2_667 2_667 ?
C7 Ag15 Ag13 146.5(6) 2_667 . ?
C7 Ag15 Ag14 116.5(4) 2_667 . ?
C46 Ag15 Ag1 156.6(6) . 2_667 ?
C46 Ag15 Ag1 129.4(5) . 1_456 ?
C46 Ag15 Ag2 139.3(7) . 1_456 ?
C46 Ag15 Ag3 89.5(5) . 2_667 ?
C46 Ag15 Ag13 50.6(5) . . ?
C46 Ag15 Ag14 51.1(6) . . ?
C46 Ag15 C1 106.0(8) . 1_456 ?
C46 Ag15 C6 130.3(7) . 2_667 ?
C46 Ag15 C7 105.0(7) . 2_667 ?
Ag1 C1 Ag2 83.6(6) . . ?
Ag1 C1 Ag15 84.9(6) . 1_654 ?
Ag2 C1 Ag15 76.0(5) . 1_654 ?
C2 C1 Ag1 170.5(16) . . ?
C2 C1 Ag2 103.9(13) . . ?
C2 C1 Ag15 102.4(15) . 1_654 ?
C1 C2 C3 178(2) . . ?
C2 C3 H3 106.3 . . ?
C4 C3 C2 112(2) . . ?
C4 C3 H3 106.3 . . ?
C5 C3 C2 108(3) . . ?
C5 C3 H3 106.3 . . ?
C5 C3 C4 117(3) . . ?
C3 C4 H4A 109.5 . . ?
C3 C4 H4B 109.5 . . ?
C3 C4 H4C 109.5 . . ?
H4A C4 H4B 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
C3 C5 H5A 109.5 . . ?
C3 C5 H5B 109.5 . . ?
C3 C5 H5C 109.5 . . ?
H5A C5 H5B 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
Ag1 C6 Ag2 83.3(6) . 2_766 ?
Ag1 C6 Ag4 81.5(6) . 2_766 ?
Ag1 C6 Ag15 91.6(6) . 2_667 ?
Ag4 C6 Ag2 94.6(5) 2_766 2_766 ?
Ag15 C6 Ag2 77.8(5) 2_667 2_766 ?
Ag15 C6 Ag4 170.4(9) 2_667 2_766 ?
C7 C6 Ag1 169.7(16) . . ?
C7 C6 Ag2 106.9(14) . 2_766 ?
C7 C6 Ag4 96.5(13) . 2_766 ?
C7 C6 Ag15 91.5(14) . 2_667 ?
C6 C7 Ag15 61.8(12) . 2_667 ?
C6 C7 C8 174(2) . . ?
C8 C7 Ag15 112.4(14) . 2_667 ?
C7 C8 H8 108.6 . . ?
C7 C8 C10 110(2) . . ?
C9 C8 C7 111(2) . . ?
C9 C8 H8 108.6 . . ?
C9 C8 C10 110(2) . . ?
C10 C8 H8 108.6 . . ?
C8 C9 H9A 109.5 . . ?
C8 C9 H9B 109.5 . . ?
C8 C9 H9C 109.5 . . ?
H9A C9 H9B 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C8 C10 H10A 109.5 . . ?
C8 C10 H10B 109.5 . . ?
C8 C10 H10C 109.5 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
Ag2 C11 Ag14 153.5(8) . 2_667 ?
Ag3 C11 Ag2 78.1(5) . . ?
Ag3 C11 Ag14 84.5(7) . 2_667 ?
C12 C11 Ag2 108.3(17) . . ?
C12 C11 Ag3 171.1(18) . . ?
C12 C11 Ag14 91.5(16) . 2_667 ?
C11 C12 C13 178(3) . . ?
C12 C13 H13 98.3 . . ?
C12 C13 C14 114(2) . . ?
C12 C13 C15 110(3) . . ?
C14 C13 H13 98.3 . . ?
C15 C13 H13 98.3 . . ?
C15 C13 C14 129(3) . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14B 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15B 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
Ag3 C16 Ag4 80.5(6) . . ?
Ag3 C16 Ag12 78.8(5) . 2_667 ?
Ag3 C16 Ag13 82.2(6) . 2_667 ?
Ag12 C16 Ag4 127.3(7) 2_667 . ?
Ag12 C16 Ag13 78.5(5) 2_667 2_667 ?
Ag13 C16 Ag4 144.5(7) 2_667 . ?
C17 C16 Ag3 164.1(14) . . ?
C17 C16 Ag4 90.5(12) . . ?
C17 C16 Ag12 117.0(13) . 2_667 ?
C17 C16 Ag13 98.3(13) . 2_667 ?
C16 C17 C18 179(2) . . ?
C17 C18 H18 91.4 . . ?
C17 C18 C19 116.4(19) . . ?
C17 C18 C20 115.8(17) . . ?
C19 C18 H18 91.4 . . ?
C19 C18 C20 128(2) . . ?
C20 C18 H18 91.4 . . ?
C18 C19 H19A 109.5 . . ?
C18 C19 H19B 109.5 . . ?
C18 C19 H19C 109.5 . . ?
H19A C19 H19B 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C18 C20 H20A 109.5 . . ?
C18 C20 H20B 109.5 . . ?
C18 C20 H20C 109.5 . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
Ag5 C21 Ag6 78.0(5) . . ?
Ag7 C21 Ag5 87.6(6) . . ?
Ag7 C21 Ag6 91.6(6) . . ?
C22 C21 Ag5 97.9(13) . . ?
C22 C21 Ag6 101.0(15) . . ?
C22 C21 Ag7 167.0(17) . . ?
C21 C22 C23 177(3) . . ?
C22 C23 H23 104.5 . . ?
C22 C23 C25 113.1(18) . . ?
C24 C23 C22 114(2) . . ?
C24 C23 H23 104.5 . . ?
C24 C23 C25 115(2) . . ?
C25 C23 H23 104.5 . . ?
C23 C24 H24A 109.5 . . ?
C23 C24 H24B 109.5 . . ?
C23 C24 H24C 109.5 . . ?
H24A C24 H24B 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C23 C25 H25A 109.5 . . ?
C23 C25 H25B 109.5 . . ?
C23 C25 H25C 109.5 . . ?
H25A C25 H25B 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
Ag5 C26 Ag11 90.4(5) 2_667 . ?
Ag6 C26 Ag5 77.1(4) 2_667 2_667 ?
Ag6 C26 Ag11 165.8(8) 2_667 . ?
Ag7 C26 Ag5 82.6(6) . 2_667 ?
Ag7 C26 Ag6 90.6(6) . 2_667 ?
Ag7 C26 Ag11 80.9(5) . . ?
C27 C26 Ag5 110.5(12) . 2_667 ?
C27 C26 Ag6 92.6(11) . 2_667 ?
C27 C26 Ag7 166.9(14) . . ?
C27 C26 Ag11 98.3(12) . . ?
C26 C27 C28 175.8(19) . . ?
C27 C28 H28 108.0 . . ?
C29 C28 C27 113(2) . . ?
C29 C28 H28 108.0 . . ?
C29 C28 C30 109(2) . . ?
C30 C28 C27 110(2) . . ?
C30 C28 H28 108.0 . . ?
C28 C29 H29A 109.5 . . ?
C28 C29 H29B 109.5 . . ?
C28 C29 H29C 109.5 . . ?
H29A C29 H29B 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C28 C30 H30A 109.5 . . ?
C28 C30 H30B 109.5 . . ?
C28 C30 H30C 109.5 . . ?
H30A C30 H30B 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
Ag5 C31 Ag8 157.2(8) 2_667 . ?
Ag10 C31 Ag5 78.5(6) . 2_667 ?
Ag10 C31 Ag8 83.2(6) . . ?
C32 C31 Ag5 109.4(15) . 2_667 ?
C32 C31 Ag8 89.3(14) . . ?
C32 C31 Ag10 172.0(17) . . ?
C31 C32 Ag8 64.0(12) . . ?
C31 C32 C33 172(2) . . ?
C33 C32 Ag8 123.7(18) . . ?
C32 C33 H33 101.5 . . ?
C32 C33 C35 113(2) . . ?
C34 C33 C32 115(2) . . ?
C34 C33 H33 101.5 . . ?
C34 C33 C35 121(2) . . ?
C35 C33 H33 101.5 . . ?
C33 C34 H34A 109.5 . . ?
C33 C34 H34B 109.5 . . ?
C33 C34 H34C 109.5 . . ?
H34A C34 H34B 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
C33 C35 H35A 109.5 . . ?
C33 C35 H35B 109.5 . . ?
C33 C35 H35C 109.5 . . ?
H35A C35 H35B 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
Ag10 C36 Ag9 80.1(6) . . ?
Ag10 C36 Ag11 80.1(6) . . ?
Ag10 C36 Ag12 79.2(5) . . ?
Ag11 C36 Ag9 150.1(7) . . ?
Ag12 C36 Ag9 76.1(5) . . ?
Ag12 C36 Ag11 121.5(7) . . ?
C37 C36 Ag9 100.4(14) . . ?
C37 C36 Ag10 163.1(13) . . ?
C37 C36 Ag11 92.3(13) . . ?
C37 C36 Ag12 117.5(12) . . ?
C36 C37 C38 171(2) . . ?
C37 C38 H38 101.0 . . ?
C37 C38 C39 114.6(19) . . ?
C37 C38 C40 114.1(18) . . ?
C39 C38 H38 101.0 . . ?
C39 C38 C40 121(2) . . ?
C40 C38 H38 101.0 . . ?
C38 C39 H39A 109.5 . . ?
C38 C39 H39B 109.5 . . ?
C38 C39 H39C 109.5 . . ?
H39A C39 H39B 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
C38 C40 H40A 109.5 . . ?
C38 C40 H40B 109.5 . . ?
C38 C40 H40C 109.5 . . ?
H40A C40 H40B 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
Ag6 C41 Ag8 90.4(7) . . ?
Ag6 C41 Ag9 85.2(7) . . ?
Ag9 C41 Ag8 97.9(7) . . ?
C42 C41 Ag6 151.5(19) . . ?
C42 C41 Ag8 86.9(17) . . ?
C42 C41 Ag9 123.3(18) . . ?
C41 C42 Ag8 65.0(16) . . ?
C41 C42 C43 176(3) . . ?
C43 C42 Ag8 114(2) . . ?
Ag13 C46 Ag14 92.6(7) . . ?
Ag15 C46 Ag13 81.1(6) . . ?
Ag15 C46 Ag14 81.3(8) . . ?
C47 C46 Ag13 105.7(17) . . ?
C47 C46 Ag14 108(2) . . ?
C47 C46 Ag15 168(2) . . ?
C46 C47 C48 175(3) . . ?
C47 C48 H48 110.8 . . ?
C47 C48 C49 108(2) . . ?
C49 C48 H48 110.8 . . ?
C50 C48 C47 106(2) . . ?
C50 C48 H48 110.8 . . ?
C50 C48 C49 110(3) . . ?
C48 C49 H49A 109.5 . . ?
C48 C49 H49B 109.5 . . ?
C48 C49 H49C 109.5 . . ?
H49A C49 H49B 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
C48 C50 H50A 109.5 . . ?
C48 C50 H50B 109.5 . . ?
C48 C50 H50C 109.5 . . ?
H50A C50 H50B 109.5 . . ?
H50A C50 H50C 109.5 . . ?
H50B C50 H50C 109.5 . . ?
O1 C1A C2A 118.6(14) . . ?
O2 C1A C2A 117.1(14) . . ?
O2 C1A O1 124.3(15) . . ?
C6A C2A C1A 120.4(16) . . ?
N1 C2A C1A 114.9(14) . . ?
N1 C2A C6A 124.6(16) . . ?
C4A C3A H3A 117.5 . . ?
C4A C3A N1 124.9(17) . . ?
N1 C3A H3A 117.5 . . ?
C3A C4A H4AA 121.5 . . ?
C3A C4A C5A 116.9(18) . . ?
C5A C4A H4AA 121.5 . . ?
C4A C5A H5AA 119.7 . . ?
C6A C5A C4A 121(2) . . ?
C6A C5A H5AA 119.7 . . ?
C2A C6A C5A 118.5(19) . . ?
C2A C6A H6A 120.8 . . ?
C5A C6A H6A 120.7 . . ?
O3 C7A C8A 117.6(15) . . ?
O4 C7A C8A 114.5(16) . . ?
O4 C7A O3 127.8(16) . . ?
C12A C8A C7A 121.5(17) . . ?
C12A C8A N2 122.2(16) . . ?
N2 C8A C7A 116.3(16) . . ?
C10A C9A H9AA 118.1 . . ?
N2 C9A H9AA 118.1 . . ?
N2 C9A C10A 123.7(17) . . ?
C9A C10A H10D 121.7 . . ?
C11A C10A C9A 116.6(19) . . ?
C11A C10A H10D 121.7 . . ?
C10A C11A H11A 119.5 . . ?
C10A C11A C12A 121(2) . . ?
C12A C11A H11A 119.5 . . ?
C8A C12A C11A 118.4(19) . . ?
C8A C12A H12A 120.8 . . ?
C11A C12A H12A 120.8 . . ?
O5 C13A C14A 117.5(18) . . ?
O6 C13A C14A 114.8(17) . . ?
O6 C13A O5 127.7(19) . . ?
C18A C14A C13A 120(2) . . ?
N3 C14A C13A 117.6(17) . . ?
N3 C14A C18A 122(2) . . ?
C16A C15A H15D 120.6 . . ?
N3 C15A H15D 120.6 . . ?
N3 C15A C16A 119(3) . . ?
C15A C16A H16A 120.6 . . ?
C17A C16A C15A 119(2) . . ?
C17A C16A H16A 120.6 . . ?
C16A C17A H17A 119.2 . . ?
C16A C17A C18A 122(3) . . ?
C18A C17A H17A 119.2 . . ?
C14A C18A C17A 119(3) . . ?
C14A C18A H18A 120.6 . . ?
C17A C18A H18A 120.6 . . ?
O7 C19A C20A 117.1(18) . . ?
O7 C19A O8 127.4(17) . . ?
O8 C19A C20A 115.5(18) . . ?
C24A C20A C19A 122(2) . . ?
N4 C20A C19A 117.2(19) . . ?
N4 C20A C24A 121(2) . . ?
C22A C21A H21A 120.7 . . ?
C22A C21A N4 119(3) . . ?
N4 C21A H21A 120.7 . . ?
C21A C22A H22A 120.2 . . ?
C23A C22A C21A 120(3) . . ?
C23A C22A H22A 120.2 . . ?
C22A C23A H23A 118.7 . . ?
C22A C23A C24A 123(3) . . ?
C24A C23A H23A 118.7 . . ?
C20A C24A H24D 120.6 . . ?
C23A C24A C20A 119(3) . . ?
C23A C24A H24D 120.6 . . ?
C2A N1 Ag4 122.1(11) . . ?
C2A N1 C3A 114.5(15) . . ?
C3A N1 Ag4 123.2(11) . . ?
C8A N2 Ag11 120.6(11) . . ?
C9A N2 Ag11 121.4(12) . . ?
C9A N2 C8A 117.8(16) . . ?
C14A N3 Ag8 117.9(13) . . ?
C14A N3 C15A 120(2) . . ?
C15A N3 Ag8 122.1(17) . . ?
C20A N4 Ag14 119.1(14) . . ?
C20A N4 C21A 119(2) . . ?
C21A N4 Ag14 121(2) . . ?
Ag11 O1 Ag4 103.9(4) 2_667 . ?
C1A O1 Ag4 115.2(9) . . ?
C1A O1 Ag11 136.1(10) . 2_667 ?
C1A O2 Ag5 120.0(10) . . ?
Ag11 O3 Ag4 100.6(4) . 2_667 ?
C7A O3 Ag4 129.7(10) . 2_667 ?
C7A O3 Ag11 117.2(10) . . ?
C7A O4 Ag2 119.0(11) . 2_667 ?
Ag12 O5 Ag8 108.6(5) . . ?
C13A O5 Ag8 116.4(12) . . ?
C13A O5 Ag12 129.3(12) . . ?
C13A O6 Ag13 121.6(13) . . ?
C19A O7 Ag9 117.9(12) . . ?
Ag12 O8 Ag14 105.9(5) . . ?
C19A O8 Ag12 132.4(12) . . ?
C19A O8 Ag14 117.4(11) . . ?
H44A C44 H44B 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
C43 C44 H44A 109.5 . . ?
C43 C44 H44B 109.5 . . ?
C43 C44 H44C 109.5 . . ?
C42 C43 C44 94(3) . . ?
C42 C43 H43 113.5 . . ?
C44 C43 H43 113.5 . . ?
C45 C43 C42 104(4) . . ?
C45 C43 C44 116(4) . . ?
C45 C43 H43 113.5 . . ?
C43 C45 H45A 109.5 . . ?
C43 C45 H45B 109.5 . . ?
C43 C45 H45C 109.5 . . ?
H45A C45 H45B 109.5 . . ?
H45A C45 H45C 109.5 . . ?
H45B C45 H45C 109.5 . . ?
O2C Cl1 O1C 114(3) . . ?
O2C Cl1 O3C 101(3) . . ?
O2C Cl1 O4C 120(3) . . ?
O3C Cl1 O1C 127(3) . . ?
O3C Cl1 O4C 93(3) . . ?
O4C Cl1 O1C 101(3) . . ?

_smtbx_masks_special_details     ?
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 -0.500 0.000 0.500 254.0 124.6 ?
2 0.173 0.144 0.093 7.1 0.0 ?
3 0.250 0.653 0.718 11.0 5.5 ?
4 0.275 0.460 0.645 9.5 5.4 ?
5 0.725 0.540 0.355 9.5 5.4 ?
6 0.750 0.347 0.282 11.0 5.7 ?
7 0.827 0.856 0.907 7.1 0.0 ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_ag_ag_498_0m_a
_database_code_depnum_ccdc_archive 'CCDC 1953779'
loop_
_audit_author_name
_audit_author_address
'Andreas Orthaber'
;Uppsala University
Sweden
;
_audit_update_record             
;
2019-10-10 deposited with the CCDC.	2019-10-14 downloaded from the CCDC.
;
_audit_creation_date             2019-10-06
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         '0.5(C76 H68 Ag18 F12 N8 O28 S4)'
_chemical_formula_sum            'C38 H34 Ag9 F6 N4 O14 S2'
_chemical_formula_weight         1919.64
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   22.973(8)
_cell_length_b                   19.990(9)
_cell_length_c                   15.639(5)
_cell_angle_alpha                90
_cell_angle_beta                 129.995(10)
_cell_angle_gamma                90
_cell_volume                     5502(4)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    3092
_cell_measurement_temperature    150
_cell_measurement_theta_max      21.90
_cell_measurement_theta_min      2.32
_shelx_estimated_absorpt_T_max   0.827
_shelx_estimated_absorpt_T_min   0.384
_exptl_absorpt_coefficient_mu    3.286
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.6271
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2014/5 (Bruker,2014/5) was used for absorption correction.
wR2(int) was 0.1584 before and 0.0716 after correction.
The Ratio of minimum to maximum transmission is 0.8410.
The λ/2 correction factor is 0.00150.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'metallic light colourless'
_exptl_crystal_colour_lustre     metallic
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    2.317
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       needle
_exptl_crystal_F_000             3644
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.06
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1260
_diffrn_reflns_av_unetI/netI     0.0901
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.982
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_h_min       -30
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            52482
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.982
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.576
_diffrn_reflns_theta_min         1.542
_diffrn_ambient_temperature      150.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4397
_reflns_number_total             6900
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'Bruker APEX2'
_computing_data_collection       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'XT (Sheldrick, 2015)'
_refine_diff_density_max         0.816
_refine_diff_density_min         -1.310
_refine_diff_density_rms         0.211
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.030
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     333
_refine_ls_number_reflns         6900
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0884
_refine_ls_R_factor_gt           0.0462
_refine_ls_restrained_S_all      1.030
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0338P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0916
_refine_ls_wR_factor_ref         0.1043
_refine_special_details          
;
Solvent Masking as implemented in Olex2 was usted to treat diffuse 
scattering contributions from disordered solvent molecules.
2 cavities containing approx 193 electrons were identified and tentativley 
assigned to four DCM molecules each.
;
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C00V(H00V), C00W(H00W), C00X(H00X), C00Z(H00Z), C010(H010), C011(H011),
 C012(H012), C015(H015)
2.b Idealised Me refined as rotating group:
 C00Q(H00A,H00B,H00C), C00Y(H00D,H00E,H00F), C014(H01A,H01B,H01C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag01 Ag 0.47138(3) 0.48763(2) 0.35672(4) 0.02240(12) Uani 1 1 d . . . . .
Ag02 Ag 0.500000 0.59524(3) 0.250000 0.02220(17) Uani 1 2 d S T P . .
Ag03 Ag 0.60800(3) 0.48270(2) 0.37556(4) 0.02867(14) Uani 1 1 d . . . . .
Ag04 Ag 0.66809(3) 0.47748(3) 0.68500(5) 0.03318(15) Uani 1 1 d . . . . .
Ag05 Ag 0.57079(3) 0.35625(2) 0.64634(5) 0.03233(15) Uani 1 1 d . . . . .
S006 S 0.77562(10) 0.41448(9) 0.62319(15) 0.0326(4) Uani 1 1 d . . . . .
O5 O 0.5280(3) 0.3985(2) 0.4568(4) 0.0259(10) Uani 1 1 d . . . . .
O4 O 0.7361(3) 0.4031(2) 0.6665(4) 0.0393(13) Uani 1 1 d . . . . .
O6 O 0.5809(3) 0.3764(2) 0.3793(4) 0.0344(12) Uani 1 1 d . . . . .
O3 O 0.7412(3) 0.4646(2) 0.5382(4) 0.0378(13) Uani 1 1 d . . . . .
O2 O 0.5664(3) 0.6355(2) 0.4335(4) 0.0295(11) Uani 1 1 d . . . . .
F00D F 0.9077(3) 0.4685(3) 0.7127(4) 0.0670(15) Uani 1 1 d . . . . .
O1 O 0.6028(3) 0.5353(2) 0.5141(4) 0.0283(11) Uani 1 1 d . . . . .
C1 C 0.3892(4) 0.5564(3) 0.2323(5) 0.0198(14) Uani 1 1 d . . . . .
C2 C 0.6397(4) 0.6318(3) 0.6295(5) 0.0257(15) Uani 1 1 d . . . . .
F00H F 0.9041(3) 0.4136(3) 0.8280(4) 0.0733(17) Uani 1 1 d . . . . .
N1 N 0.5760(3) 0.2744(3) 0.5564(5) 0.0318(14) Uani 1 1 d . . . . .
O00K O 0.7987(3) 0.3553(2) 0.6024(4) 0.0435(14) Uani 1 1 d . . . . .
N00L N 0.6784(3) 0.5925(3) 0.7181(5) 0.0325(14) Uani 1 1 d . . . . .
F00M F 0.8519(3) 0.5100(3) 0.7693(4) 0.0705(16) Uani 1 1 d . . . . .
C00N C 0.6007(4) 0.5984(3) 0.5176(6) 0.0289(16) Uani 1 1 d . . . . .
C00O C 0.3297(4) 0.5876(3) 0.1714(5) 0.0257(15) Uani 1 1 d . . . . .
C00P C 0.5596(4) 0.3602(3) 0.4317(5) 0.0247(15) Uani 1 1 d . . . . .
C00Q C 0.1906(4) 0.5764(4) 0.0462(6) 0.047(2) Uani 1 1 d . . . . .
H00A H 0.194147 0.535431 0.015404 0.071 Uiso 1 1 calc GR . . . .
H00B H 0.142305 0.598897 -0.011480 0.071 Uiso 1 1 calc GR . . . .
H00C H 0.193207 0.565109 0.109549 0.071 Uiso 1 1 calc GR . . . .
C00S C 0.5721(4) 0.2880(3) 0.4690(6) 0.0278(16) Uani 1 1 d . . . . .
C00T C 0.2564(4) 0.6230(4) 0.0854(6) 0.0365(19) Uani 1 1 d . . . . .
C00V C 0.7094(4) 0.6213(4) 0.8166(6) 0.042(2) Uani 1 1 d . . . . .
H00V H 0.736425 0.593699 0.881071 0.050 Uiso 1 1 calc R . . . .
C00W C 0.6644(5) 0.7273(4) 0.7361(7) 0.046(2) Uani 1 1 d . . . . .
H00W H 0.659174 0.773766 0.742198 0.055 Uiso 1 1 calc R . . . .
C00X C 0.5784(4) 0.2392(3) 0.4141(6) 0.0342(17) Uani 1 1 d . . . . .
H00X H 0.577982 0.250625 0.354712 0.041 Uiso 1 1 calc R . . . .
C00Y C 0.2542(5) 0.6391(4) -0.0132(6) 0.045(2) Uani 1 1 d . . . . .
H00D H 0.299114 0.665299 0.013681 0.067 Uiso 1 1 calc GR . . . .
H00E H 0.208214 0.664818 -0.069546 0.067 Uiso 1 1 calc GR . . . .
H00F H 0.253711 0.597248 -0.046346 0.067 Uiso 1 1 calc GR . . . .
C00Z C 0.5843(5) 0.2103(3) 0.5873(7) 0.040(2) Uani 1 1 d . . . . .
H00Z H 0.587123 0.199913 0.649133 0.048 Uiso 1 1 calc R . . . .
C010 C 0.6317(4) 0.6993(3) 0.6335(6) 0.0339(18) Uani 1 1 d . . . . .
H010 H 0.604565 0.725893 0.567918 0.041 Uiso 1 1 calc R . . . .
C011 C 0.7045(5) 0.6873(4) 0.8291(7) 0.046(2) Uani 1 1 d . . . . .
H011 H 0.728240 0.705642 0.900787 0.055 Uiso 1 1 calc R . . . .
C012 C 0.5855(4) 0.1733(3) 0.4455(7) 0.040(2) Uani 1 1 d . . . . .
H012 H 0.587859 0.138541 0.406476 0.048 Uiso 1 1 calc R . . . .
C013 C 0.8653(5) 0.4540(5) 0.7394(7) 0.050(2) Uani 1 1 d . . . . .
C014 C 0.2518(5) 0.6879(4) 0.1321(7) 0.054(3) Uani 1 1 d . . . . .
H01A H 0.256778 0.677951 0.197891 0.082 Uiso 1 1 calc GR . . . .
H01B H 0.202661 0.709452 0.075096 0.082 Uiso 1 1 calc GR . . . .
H01C H 0.292860 0.717918 0.153137 0.082 Uiso 1 1 calc GR . . . .
C015 C 0.5889(5) 0.1593(3) 0.5339(7) 0.047(2) Uani 1 1 d . . . . .
H015 H 0.594430 0.114447 0.558172 0.057 Uiso 1 1 calc R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag01 Ag02 3.0424(10) . ?
Ag01 Ag03 2.8312(13) 2_655 ?
Ag01 Ag03 2.9596(13) . ?
Ag01 Ag04 2.9138(13) 5_666 ?
Ag01 Ag05 3.2590(15) 5_666 ?
Ag01 O5 2.167(4) . ?
Ag01 O1 2.555(5) . ?
Ag01 C1 2.126(6) . ?
Ag02 Ag03 2.9682(11) 2_655 ?
Ag02 Ag03 2.9682(11) . ?
Ag02 Ag05 3.0988(9) 5_666 ?
Ag02 Ag05 3.0988(9) 6_565 ?
Ag02 O2 2.362(4) . ?
Ag02 O2 2.362(4) 2_655 ?
Ag02 C1 2.501(6) . ?
Ag02 C1 2.501(6) 2_655 ?
Ag03 O6 2.225(5) . ?
Ag03 O3 2.441(5) . ?
Ag03 O1 2.479(4) . ?
Ag03 C1 2.271(6) 2_655 ?
Ag04 Ag05 3.0819(13) . ?
Ag04 O4 2.306(5) . ?
Ag04 O1 2.362(4) . ?
Ag04 C1 2.460(6) 5_666 ?
Ag04 N00L 2.336(6) . ?
Ag04 C00O 2.568(7) 5_666 ?
Ag05 O5 2.593(4) . ?
Ag05 O2 2.543(5) 5_666 ?
Ag05 C1 2.292(6) 5_666 ?
Ag05 N1 2.211(5) . ?
Ag05 C00O 2.496(7) 5_666 ?
S006 O4 1.457(5) . ?
S006 O3 1.430(5) . ?
S006 O00K 1.418(5) . ?
S006 C013 1.832(9) . ?
O5 C00P 1.278(8) . ?
O6 C00P 1.239(8) . ?
O2 C00N 1.253(8) . ?
F00D C013 1.316(10) . ?
O1 C00N 1.264(8) . ?
C1 C00O 1.221(8) . ?
C2 N00L 1.320(8) . ?
C2 C00N 1.516(9) . ?
C2 C010 1.368(9) . ?
F00H C013 1.333(9) . ?
N1 C00S 1.337(8) . ?
N1 C00Z 1.339(8) . ?
N00L C00V 1.342(9) . ?
F00M C013 1.324(10) . ?
C00O C00T 1.494(9) . ?
C00P C00S 1.513(9) . ?
C00Q C00T 1.529(11) . ?
C00S C00X 1.369(9) . ?
C00T C00Y 1.543(10) . ?
C00T C014 1.525(10) . ?
C00V C011 1.349(11) . ?
C00W C010 1.379(9) . ?
C00W C011 1.372(11) . ?
C00X C012 1.378(9) . ?
C00Z C015 1.364(9) . ?
C012 C015 1.363(10) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag02 Ag01 Ag05 58.79(3) . 5_666 ?
Ag03 Ag01 Ag02 59.258(19) . . ?
Ag03 Ag01 Ag02 60.58(2) 2_655 . ?
Ag03 Ag01 Ag03 83.91(3) 2_655 . ?
Ag03 Ag01 Ag04 90.70(3) 2_655 5_666 ?
Ag03 Ag01 Ag05 108.64(2) . 5_666 ?
Ag03 Ag01 Ag05 94.258(19) 2_655 5_666 ?
Ag04 Ag01 Ag02 107.59(3) 5_666 . ?
Ag04 Ag01 Ag03 166.75(2) 5_666 . ?
Ag04 Ag01 Ag05 59.589(18) 5_666 5_666 ?
O5 Ag01 Ag02 137.43(12) . . ?
O5 Ag01 Ag03 119.38(12) . 2_655 ?
O5 Ag01 Ag03 78.18(12) . . ?
O5 Ag01 Ag04 114.92(12) . 5_666 ?
O5 Ag01 Ag05 146.35(12) . 5_666 ?
O5 Ag01 O1 79.76(16) . . ?
O1 Ag01 Ag02 74.12(10) . . ?
O1 Ag01 Ag03 52.82(11) . . ?
O1 Ag01 Ag03 129.54(10) . 2_655 ?
O1 Ag01 Ag04 125.09(11) . 5_666 ?
O1 Ag01 Ag05 79.22(10) . 5_666 ?
C1 Ag01 Ag02 54.45(17) . . ?
C1 Ag01 Ag03 52.21(15) . 2_655 ?
C1 Ag01 Ag03 111.95(17) . . ?
C1 Ag01 Ag04 55.83(17) . 5_666 ?
C1 Ag01 Ag05 44.48(16) . 5_666 ?
C1 Ag01 O5 163.8(2) . . ?
C1 Ag01 O1 116.4(2) . . ?
Ag01 Ag02 Ag01 90.01(4) . 2_655 ?
Ag01 Ag02 Ag05 64.10(3) . 5_666 ?
Ag01 Ag02 Ag05 151.57(2) . 6_565 ?
Ag01 Ag02 Ag05 151.57(2) 2_655 5_666 ?
Ag01 Ag02 Ag05 64.09(3) 2_655 6_565 ?
Ag03 Ag02 Ag01 56.19(3) . 2_655 ?
Ag03 Ag02 Ag01 56.19(3) 2_655 . ?
Ag03 Ag02 Ag01 58.98(3) 2_655 2_655 ?
Ag03 Ag02 Ag01 58.98(3) . . ?
Ag03 Ag02 Ag03 81.43(4) . 2_655 ?
Ag03 Ag02 Ag05 112.81(3) 2_655 6_565 ?
Ag03 Ag02 Ag05 94.97(3) . 6_565 ?
Ag03 Ag02 Ag05 112.81(3) . 5_666 ?
Ag03 Ag02 Ag05 94.97(3) 2_655 5_666 ?
Ag05 Ag02 Ag05 143.53(3) 5_666 6_565 ?
O2 Ag02 Ag01 135.11(12) . 2_655 ?
O2 Ag02 Ag01 76.90(11) . . ?
O2 Ag02 Ag01 135.12(12) 2_655 . ?
O2 Ag02 Ag01 76.90(11) 2_655 2_655 ?
O2 Ag02 Ag03 80.91(12) . . ?
O2 Ag02 Ag03 80.91(12) 2_655 2_655 ?
O2 Ag02 Ag03 132.42(11) . 2_655 ?
O2 Ag02 Ag03 132.42(11) 2_655 . ?
O2 Ag02 Ag05 53.46(12) . 5_666 ?
O2 Ag02 Ag05 53.45(12) 2_655 6_565 ?
O2 Ag02 Ag05 112.47(11) 2_655 5_666 ?
O2 Ag02 Ag05 112.47(11) . 6_565 ?
O2 Ag02 O2 140.2(2) . 2_655 ?
O2 Ag02 C1 98.87(19) . 2_655 ?
O2 Ag02 C1 93.29(18) . . ?
O2 Ag02 C1 93.29(18) 2_655 2_655 ?
O2 Ag02 C1 98.87(19) 2_655 . ?
C1 Ag02 Ag01 106.45(13) . 2_655 ?
C1 Ag02 Ag01 106.45(13) 2_655 . ?
C1 Ag02 Ag01 43.76(14) . . ?
C1 Ag02 Ag01 43.75(14) 2_655 2_655 ?
C1 Ag02 Ag03 48.15(13) 2_655 . ?
C1 Ag02 Ag03 48.15(13) . 2_655 ?
C1 Ag02 Ag03 101.33(14) . . ?
C1 Ag02 Ag03 101.33(14) 2_655 2_655 ?
C1 Ag02 Ag05 151.45(14) 2_655 5_666 ?
C1 Ag02 Ag05 46.84(13) . 5_666 ?
C1 Ag02 Ag05 46.84(13) 2_655 6_565 ?
C1 Ag02 Ag05 151.45(14) . 6_565 ?
C1 Ag02 C1 143.8(3) 2_655 . ?
Ag01 Ag03 Ag01 95.96(3) 2_655 . ?
Ag01 Ag03 Ag02 63.232(18) 2_655 . ?
Ag01 Ag03 Ag02 61.76(2) . . ?
O6 Ag03 Ag01 74.79(13) . . ?
O6 Ag03 Ag01 96.12(12) . 2_655 ?
O6 Ag03 Ag02 127.73(13) . . ?
O6 Ag03 O3 90.91(17) . . ?
O6 Ag03 O1 102.16(16) . . ?
O6 Ag03 C1 141.33(19) . 2_655 ?
O3 Ag03 Ag01 133.19(12) . 2_655 ?
O3 Ag03 Ag01 130.36(12) . . ?
O3 Ag03 Ag02 139.16(12) . . ?
O3 Ag03 O1 83.37(16) . . ?
O1 Ag03 Ag01 55.18(11) . . ?
O1 Ag03 Ag01 138.87(11) . 2_655 ?
O1 Ag03 Ag02 76.54(11) . . ?
C1 Ag03 Ag01 47.70(16) 2_655 2_655 ?
C1 Ag03 Ag01 116.04(16) 2_655 . ?
C1 Ag03 Ag02 55.10(16) 2_655 . ?
C1 Ag03 O3 104.8(2) 2_655 . ?
C1 Ag03 O1 114.46(19) 2_655 . ?
Ag01 Ag04 Ag05 65.78(3) 5_666 . ?
O4 Ag04 Ag01 149.61(14) . 5_666 ?
O4 Ag04 Ag05 86.17(13) . . ?
O4 Ag04 O1 99.34(17) . . ?
O4 Ag04 C1 121.56(18) . 5_666 ?
O4 Ag04 N00L 133.01(19) . . ?
O4 Ag04 C00O 98.58(18) . 5_666 ?
O1 Ag04 Ag01 79.76(12) . 5_666 ?
O1 Ag04 Ag05 108.05(11) . . ?
O1 Ag04 C1 124.37(19) . 5_666 ?
O1 Ag04 C00O 151.52(19) . 5_666 ?
C1 Ag04 Ag01 45.64(15) 5_666 5_666 ?
C1 Ag04 Ag05 47.24(13) 5_666 . ?
C1 Ag04 C00O 28.00(19) 5_666 5_666 ?
N00L Ag04 Ag01 75.77(15) . 5_666 ?
N00L Ag04 Ag05 140.82(15) . . ?
N00L Ag04 O1 70.67(17) . . ?
N00L Ag04 C1 99.60(19) . 5_666 ?
N00L Ag04 C00O 111.29(19) . 5_666 ?
C00O Ag04 Ag01 73.61(15) 5_666 5_666 ?
C00O Ag04 Ag05 51.46(15) 5_666 . ?
Ag02 Ag05 Ag01 57.114(17) 5_666 5_666 ?
Ag04 Ag05 Ag01 54.63(3) . 5_666 ?
Ag04 Ag05 Ag02 102.10(3) . 5_666 ?
O5 Ag05 Ag01 77.31(9) . 5_666 ?
O5 Ag05 Ag02 123.72(10) . 5_666 ?
O5 Ag05 Ag04 70.27(10) . . ?
O2 Ag05 Ag01 70.59(10) 5_666 5_666 ?
O2 Ag05 Ag02 48.29(10) 5_666 5_666 ?
O2 Ag05 Ag04 124.02(10) 5_666 . ?
O2 Ag05 O5 88.73(14) 5_666 . ?
C1 Ag05 Ag01 40.53(16) 5_666 5_666 ?
C1 Ag05 Ag02 52.73(16) 5_666 5_666 ?
C1 Ag05 Ag04 51.99(16) 5_666 . ?
C1 Ag05 O5 110.74(18) 5_666 . ?
C1 Ag05 O2 93.90(19) 5_666 5_666 ?
C1 Ag05 C00O 29.1(2) 5_666 5_666 ?
N1 Ag05 Ag01 146.77(14) . 5_666 ?
N1 Ag05 Ag02 145.70(15) . 5_666 ?
N1 Ag05 Ag04 112.17(15) . . ?
N1 Ag05 O5 69.48(17) . . ?
N1 Ag05 O2 107.04(19) . 5_666 ?
N1 Ag05 C1 159.0(2) . 5_666 ?
N1 Ag05 C00O 132.4(2) . 5_666 ?
C00O Ag05 Ag01 68.40(14) 5_666 5_666 ?
C00O Ag05 Ag02 70.44(15) 5_666 5_666 ?
C00O Ag05 Ag04 53.58(15) 5_666 . ?
C00O Ag05 O5 123.73(18) 5_666 . ?
C00O Ag05 O2 117.89(18) 5_666 5_666 ?
O4 S006 C013 104.2(4) . . ?
O3 S006 O4 113.8(3) . . ?
O3 S006 C013 102.6(4) . . ?
O00K S006 O4 114.4(3) . . ?
O00K S006 O3 115.9(3) . . ?
O00K S006 C013 103.9(4) . . ?
Ag01 O5 Ag05 134.77(19) . . ?
C00P O5 Ag01 117.8(4) . . ?
C00P O5 Ag05 106.4(4) . . ?
S006 O4 Ag04 129.2(3) . . ?
C00P O6 Ag03 120.3(4) . . ?
S006 O3 Ag03 130.2(3) . . ?
Ag02 O2 Ag05 78.26(14) . 5_666 ?
C00N O2 Ag02 123.6(4) . . ?
C00N O2 Ag05 107.4(4) . 5_666 ?
Ag03 O1 Ag01 72.00(12) . . ?
Ag04 O1 Ag01 113.91(17) . . ?
Ag04 O1 Ag03 115.40(18) . . ?
C00N O1 Ag01 111.1(4) . . ?
C00N O1 Ag03 119.0(4) . . ?
C00N O1 Ag04 117.0(4) . . ?
Ag01 C1 Ag02 81.8(2) . . ?
Ag01 C1 Ag03 80.1(2) . 2_655 ?
Ag01 C1 Ag04 78.53(19) . 5_666 ?
Ag01 C1 Ag05 95.0(2) . 5_666 ?
Ag03 C1 Ag02 76.76(18) 2_655 . ?
Ag03 C1 Ag04 119.5(2) 2_655 5_666 ?
Ag03 C1 Ag05 157.1(3) 2_655 5_666 ?
Ag04 C1 Ag02 151.4(3) 5_666 . ?
Ag05 C1 Ag02 80.43(19) 5_666 . ?
Ag05 C1 Ag04 80.77(18) 5_666 5_666 ?
C00O C1 Ag01 159.2(6) . . ?
C00O C1 Ag02 118.5(5) . . ?
C00O C1 Ag03 107.7(5) . 2_655 ?
C00O C1 Ag04 80.9(4) . 5_666 ?
C00O C1 Ag05 84.7(4) . 5_666 ?
N00L C2 C00N 116.7(6) . . ?
N00L C2 C010 123.9(6) . . ?
C010 C2 C00N 119.4(6) . . ?
C00S N1 Ag05 120.3(4) . . ?
C00S N1 C00Z 117.6(6) . . ?
C00Z N1 Ag05 122.1(5) . . ?
C2 N00L Ag04 116.7(4) . . ?
C2 N00L C00V 116.9(6) . . ?
C00V N00L Ag04 125.4(5) . . ?
O2 C00N O1 124.1(6) . . ?
O2 C00N C2 117.2(6) . . ?
O1 C00N C2 118.6(6) . . ?
Ag05 C00O Ag04 74.95(18) 5_666 5_666 ?
C1 C00O Ag04 71.1(4) . 5_666 ?
C1 C00O Ag05 66.1(4) . 5_666 ?
C1 C00O C00T 173.0(7) . . ?
C00T C00O Ag04 113.8(5) . 5_666 ?
C00T C00O Ag05 119.4(4) . 5_666 ?
O5 C00P C00S 117.3(6) . . ?
O6 C00P O5 126.1(6) . . ?
O6 C00P C00S 116.6(6) . . ?
N1 C00S C00P 117.3(6) . . ?
N1 C00S C00X 122.1(6) . . ?
C00X C00S C00P 120.5(6) . . ?
C00O C00T C00Q 109.0(6) . . ?
C00O C00T C00Y 107.0(6) . . ?
C00O C00T C014 110.9(6) . . ?
C00Q C00T C00Y 109.7(6) . . ?
C014 C00T C00Q 110.7(7) . . ?
C014 C00T C00Y 109.5(6) . . ?
N00L C00V C011 123.6(7) . . ?
C011 C00W C010 119.3(7) . . ?
C00S C00X C012 119.5(7) . . ?
N1 C00Z C015 122.9(7) . . ?
C2 C010 C00W 117.7(7) . . ?
C00V C011 C00W 118.5(7) . . ?
C015 C012 C00X 118.4(7) . . ?
F00D C013 S006 111.7(6) . . ?
F00D C013 F00H 109.1(7) . . ?
F00D C013 F00M 108.3(8) . . ?
F00H C013 S006 110.2(7) . . ?
F00M C013 S006 110.2(6) . . ?
F00M C013 F00H 107.3(7) . . ?
C012 C015 C00Z 119.4(7) . . ?

_smtbx_masks_special_details     ?
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 0.000 0.500 -0.092 385.2 193.9 4(CH2Cl2)
2 0.500 0.000 -0.056 385.2 193.9 4(CH2Cl2)

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_ag_ag_501_0m_a
_database_code_depnum_ccdc_archive 'CCDC 1953781'
loop_
_audit_author_name
_audit_author_address
'Andreas Orthaber'
;Uppsala University
Sweden
;
_audit_update_record             
;
2019-10-10 deposited with the CCDC.	2019-10-14 downloaded from the CCDC.
;
# start Validation Reply Form
_vrf_PLAT972_ag_ag_501_0m_a      
;
PROBLEM: Check Calcd Resid. Dens.  1.11A   From Ag5            -3.59 eA-3  
RESPONSE: The disorder of the central silver in one of the two clusters 
led to additional disorder whic hwe were unable to modell satisfactorily
;
_vrf_PLAT342_ag_ag_501_0m_a      
;
PROBLEM: Low Bond Precision on  C-C Bonds ...............    0.02649 Ang.  
RESPONSE: Due to low data quality unaccounted disorder no better 
CC bond precisision could be obtained
;
_vrf_PLAT364_ag_ag_501_0m_a      
;
PROBLEM: Short  C(sp3)-C(sp)  Bond  C1       - C2       .       1.20 Ang.  
RESPONSE: C1 is erronously assigned to a sp3 hybridisation. it is an 
acetylide carbon
;
_vrf_PLAT934_ag_ag_501_0m_a      
;
PROBLEM: Number of (Iobs-Icalc)/Sigma(W) > 10 Outliers ..          7 Check 
RESPONSE: The measured crystal presumably contained another domain 
which we count not completely eliminate
;
_vrf_PLAT971_ag_ag_501_0m_a      
;
PROBLEM: Check Calcd Resid. Dens.  1.06A   From Ag12            3.45 eA-3  
RESPONSE: The disorder of the central silver in one of the two clusters 
led to additional disorder whic hwe were unable to modell satisfactorily
;
# end Validation Reply Form
_audit_creation_date             2019-08-15
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         '2(C58 H96 Ag6.5 N2 O4 Si4), Cl O4'
_chemical_formula_sum            'C116 H192 Ag13 Cl N4 O12 Si8'
_chemical_formula_weight         3497.20
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   16.217(4)
_cell_length_b                   16.611(4)
_cell_length_c                   29.328(6)
_cell_angle_alpha                91.328(7)
_cell_angle_beta                 94.827(7)
_cell_angle_gamma                117.772(7)
_cell_volume                     6948(3)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9656
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      26.95
_cell_measurement_theta_min      2.52
_shelx_estimated_absorpt_T_max   0.893
_shelx_estimated_absorpt_T_min   0.723
_exptl_absorpt_coefficient_mu    1.927
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.6559
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.672
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       plate
_exptl_crystal_F_000             3504
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.06
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0691
_diffrn_reflns_av_unetI/netI     0.0337
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_number            285113
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        24.999
_diffrn_reflns_theta_max         24.999
_diffrn_reflns_theta_min         0.698
_diffrn_ambient_temperature      150.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                19963
_reflns_number_total             24428
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'Bruker APEX2'
_computing_data_collection       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'XT (Sheldrick, 2015)'
_refine_diff_density_max         3.482
_refine_diff_density_min         -3.609
_refine_diff_density_rms         0.256
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.133
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1445
_refine_ls_number_reflns         24428
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1048
_refine_ls_R_factor_gt           0.0864
_refine_ls_restrained_S_all      1.133
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0835P)²+238.8645P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2332
_refine_ls_wR_factor_ref         0.2530
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Others
 Fixed Sof: Ag4(0.5)
3.a Ternary CH refined with riding coordinates:
 C3(H3), C6(H6), C9(H9), C17(H17), C20(H20), C25(H25), C28(H28), C31(H31),
 C36(H36), C39(H39), C42(H42), C61(H61), C64(H64), C67(H67), C72(H72), C75(H75),
  C78(H78), C83(H83), C86(H86), C89(H89), C106(H106), C110(H110), C113(H113),
 C116(H116)
3.b Aromatic/amide H refined with riding coordinates:
 C47(H47), C50(H50), C51(H51), C54(H54), C57(H57), C58(H58), C94(H94),
 C97(H97), C98(H98), C101(H101), C104(H104), C105(H105)
3.c Idealised Me refined as rotating group:
 C4(H4A,H4B,H4C), C7(H7A,H7B,H7C), C8(H8A,H8B,H8C), C10(H10A,H10B,H10C),
 C11(H11A,H11B,H11C), C15(H15A,H15B,H15C), C16(H16A,H16B,H16C), C18(H18A,H18B,
 H18C), C19(H19A,H19B,H19C), C21(H21A,H21B,H21C), C22(H22A,H22B,H22C), C26(H26A,
 H26B,H26C), C27(H27A,H27B,H27C), C29(H29A,H29B,H29C), C30(H30A,H30B,H30C),
 C32(H32A,H32B,H32C), C33(H33A,H33B,H33C), C37(H37A,H37B,H37C), C38(H38A,H38B,
 H38C), C40(H40A,H40B,H40C), C41(H41A,H41B,H41C), C43(H43A,H43B,H43C), C44(H44A,
 H44B,H44C), C49(H49A,H49B,H49C), C56(H56A,H56B,H56C), C62(H62A,H62B,H62C),
 C63(H63A,H63B,H63C), C65(H65A,H65B,H65C), C66(H66A,H66B,H66C), C68(H68A,H68B,
 H68C), C69(H69A,H69B,H69C), C73(H73A,H73B,H73C), C74(H74A,H74B,H74C), C76(H76A,
 H76B,H76C), C77(H77A,H77B,H77C), C79(H79A,H79B,H79C), C80(H80A,H80B,H80C),
 C84(H84A,H84B,H84C), C85(H85A,H85B,H85C), C87(H87A,H87B,H87C), C88(H88A,H88B,
 H88C), C90(H90A,H90B,H90C), C91(H91A,H91B,H91C), C96(H96A,H96B,H96C),
 C103(H10G,H10H,H10I), C107(H10D,H10E,H10F), C111(H11D,H11E,H11F), C112(H11G,
 H11H,H11I), C114(H11J,H11K,H11L), C115(H11M,H11N,H11O), C117(H11P,H11Q,H11R),
 C118(H11S,H11T,H11U)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.99935(9) 0.89320(8) -0.14590(4) 0.0419(3) Uani 1 1 d . . . . .
Ag2 Ag 0.88922(7) 1.00476(6) -0.12806(3) 0.0308(2) Uani 1 1 d . . . . .
Ag3 Ag 0.84954(13) 0.85648(14) -0.06392(5) 0.0769(6) Uani 1 1 d . . . . .
Ag4 Ag 1.00536(18) 1.02983(16) 0.00386(8) 0.0406(6) Uani 0.5 1 d . . . . .
Ag6 Ag 0.87917(9) 0.95651(8) 0.07270(4) 0.0437(3) Uani 1 1 d . . . . .
Ag5 Ag 0.92647(11) 1.11585(12) -0.04021(4) 0.0817(6) Uani 1 1 d . . . . .
Ag7 Ag 0.91604(8) 0.81321(8) 0.11885(4) 0.0396(3) Uani 1 1 d . . . . .
Ag8 Ag 0.39483(8) 0.86969(8) 0.35829(4) 0.0374(3) Uani 1 1 d . . . . .
Ag9 Ag 0.500000 1.000000 0.500000 0.0415(4) Uani 1 2 d S T P . .
Ag10 Ag 0.30052(8) 0.89731(7) 0.52402(3) 0.0354(3) Uani 1 1 d . . . . .
Ag11 Ag 0.40083(7) 0.86214(7) 0.62520(3) 0.0322(2) Uani 1 1 d . . . . .
Ag12 Ag 0.38196(6) 1.02693(6) 0.61180(3) 0.0243(2) Uani 1 1 d . . . . .
Ag13 Ag 0.58666(7) 0.96605(7) 0.58316(3) 0.0306(2) Uani 1 1 d . . . . .
Ag14 Ag 0.51149(8) 1.17223(8) 0.54577(4) 0.0387(3) Uani 1 1 d . . . . .
C1 C 0.8442(10) 0.8663(9) -0.1420(4) 0.032(3) Uani 1 1 d . . . . .
C2 C 0.8104(10) 0.7863(10) -0.1527(5) 0.035(3) Uani 1 1 d . . . . .
C3 C 0.7728(14) 0.6562(13) -0.2344(6) 0.070(6) Uani 1 1 d . . . . .
H3 H 0.733904 0.591367 -0.246808 0.084 Uiso 1 1 calc R . . . .
C4 C 0.8777(15) 0.676(2) -0.2315(9) 0.117(13) Uani 1 1 d . . . . .
H4A H 0.883958 0.635584 -0.253977 0.176 Uiso 1 1 calc GR . . . .
H4B H 0.897683 0.666625 -0.200622 0.176 Uiso 1 1 calc GR . . . .
H4C H 0.917014 0.739937 -0.238209 0.176 Uiso 1 1 calc GR . . . .
C6 C 0.6141(12) 0.6399(13) -0.1802(8) 0.065(6) Uani 1 1 d . . . . .
H6 H 0.611389 0.686913 -0.200086 0.078 Uiso 1 1 calc R . . . .
C7 C 0.580(2) 0.652(3) -0.1373(13) 0.19(2) Uani 1 1 d . . . . .
H7A H 0.520988 0.654617 -0.144099 0.279 Uiso 1 1 calc GR . . . .
H7B H 0.626464 0.708120 -0.120157 0.279 Uiso 1 1 calc GR . . . .
H7C H 0.568327 0.599709 -0.118769 0.279 Uiso 1 1 calc GR . . . .
C8 C 0.5463(15) 0.5480(16) -0.2054(10) 0.097(9) Uani 1 1 d . . . . .
H8A H 0.530943 0.499697 -0.184041 0.146 Uiso 1 1 calc GR . . . .
H8B H 0.575559 0.535865 -0.230751 0.146 Uiso 1 1 calc GR . . . .
H8C H 0.488800 0.549328 -0.217529 0.146 Uiso 1 1 calc GR . . . .
C9 C 0.7575(17) 0.5886(12) -0.1316(9) 0.080(7) Uani 1 1 d . . . . .
H9 H 0.715147 0.582651 -0.107516 0.096 Uiso 1 1 calc R . . . .
C10 C 0.8496(17) 0.6210(13) -0.1072(7) 0.079(7) Uani 1 1 d . . . . .
H10A H 0.844950 0.587075 -0.079814 0.118 Uiso 1 1 calc GR . . . .
H10B H 0.875915 0.686103 -0.098073 0.118 Uiso 1 1 calc GR . . . .
H10C H 0.890417 0.611867 -0.127204 0.118 Uiso 1 1 calc GR . . . .
C11 C 0.719(2) 0.4895(15) -0.1549(12) 0.146(17) Uani 1 1 d . . . . .
H11A H 0.763369 0.488929 -0.175447 0.219 Uiso 1 1 calc GR . . . .
H11B H 0.658216 0.471257 -0.172510 0.219 Uiso 1 1 calc GR . . . .
H11C H 0.711581 0.446708 -0.131161 0.219 Uiso 1 1 calc GR . . . .
C12 C 0.9210(10) 1.1404(10) -0.1163(5) 0.033(3) Uani 1 1 d . . . . .
C13 C 0.9353(10) 1.2185(9) -0.1121(5) 0.033(3) Uani 1 1 d . . . . .
C15 C 1.0319(13) 1.5047(10) -0.0635(5) 0.049(4) Uani 1 1 d . . . . .
H15A H 0.972854 1.488133 -0.050376 0.074 Uiso 1 1 calc GR . . . .
H15B H 1.031288 1.532303 -0.092594 0.074 Uiso 1 1 calc GR . . . .
H15C H 1.084394 1.548489 -0.042065 0.074 Uiso 1 1 calc GR . . . .
C16 C 1.0532(13) 1.3819(12) -0.0269(5) 0.050(4) Uani 1 1 d . . . . .
H16A H 1.108350 1.428436 -0.007828 0.075 Uiso 1 1 calc GR . . . .
H16B H 1.060958 1.327383 -0.031981 0.075 Uiso 1 1 calc GR . . . .
H16C H 0.997117 1.366005 -0.011222 0.075 Uiso 1 1 calc GR . . . .
C17 C 0.8268(12) 1.3241(10) -0.1020(5) 0.045(4) Uani 1 1 d . . . . .
H17 H 0.830604 1.385494 -0.105290 0.054 Uiso 1 1 calc R . . . .
C18 C 0.7484(13) 1.2580(13) -0.1379(7) 0.064(5) Uani 1 1 d . . . . .
H18A H 0.740570 1.196264 -0.134962 0.096 Uiso 1 1 calc GR . . . .
H18B H 0.764848 1.276898 -0.168658 0.096 Uiso 1 1 calc GR . . . .
H18C H 0.689711 1.258679 -0.132919 0.096 Uiso 1 1 calc GR . . . .
C19 C 0.8049(14) 1.2994(14) -0.0533(6) 0.060(5) Uani 1 1 d . . . . .
H19A H 0.745858 1.299190 -0.048101 0.090 Uiso 1 1 calc GR . . . .
H19B H 0.855626 1.344436 -0.031507 0.090 Uiso 1 1 calc GR . . . .
H19C H 0.799050 1.238766 -0.048865 0.090 Uiso 1 1 calc GR . . . .
C20 C 0.9660(12) 1.3658(10) -0.1752(5) 0.042(4) Uani 1 1 d . . . . .
H20 H 0.917145 1.313097 -0.195519 0.050 Uiso 1 1 calc R . . . .
C21 C 1.0597(13) 1.3760(13) -0.1860(5) 0.055(5) Uani 1 1 d . . . . .
H21A H 1.068152 1.390646 -0.218012 0.083 Uiso 1 1 calc GR . . . .
H21B H 1.061806 1.318710 -0.181304 0.083 Uiso 1 1 calc GR . . . .
H21C H 1.109929 1.425165 -0.165733 0.083 Uiso 1 1 calc GR . . . .
C22 C 0.9547(18) 1.4504(14) -0.1879(7) 0.071(6) Uani 1 1 d . . . . .
H22A H 0.999396 1.503464 -0.167755 0.107 Uiso 1 1 calc GR . . . .
H22B H 0.890685 1.438813 -0.184115 0.107 Uiso 1 1 calc GR . . . .
H22C H 0.966747 1.462347 -0.219866 0.107 Uiso 1 1 calc GR . . . .
C23 C 0.8594(11) 0.9692(11) -0.0058(4) 0.039(3) Uani 1 1 d . . . . .
C24 C 0.7811(12) 0.9470(11) 0.0053(5) 0.046(4) Uani 1 1 d . . . . .
C25 C 0.6111(14) 0.9353(14) -0.0440(6) 0.059(5) Uani 1 1 d . . . . .
H25 H 0.546808 0.926952 -0.040601 0.071 Uiso 1 1 calc R . . . .
C26 C 0.6676(17) 1.0337(16) -0.0611(8) 0.093(8) Uani 1 1 d . . . . .
H26A H 0.684027 1.079389 -0.035603 0.139 Uiso 1 1 calc GR . . . .
H26B H 0.628910 1.043138 -0.085754 0.139 Uiso 1 1 calc GR . . . .
H26C H 0.724973 1.039643 -0.072755 0.139 Uiso 1 1 calc GR . . . .
C27 C 0.597(2) 0.853(2) -0.0755(9) 0.116(11) Uani 1 1 d . . . . .
H27A H 0.609638 0.871798 -0.106649 0.174 Uiso 1 1 calc GR . . . .
H27B H 0.532729 0.804014 -0.075954 0.174 Uiso 1 1 calc GR . . . .
H27C H 0.640815 0.830621 -0.063757 0.174 Uiso 1 1 calc GR . . . .
C28 C 0.5927(11) 0.8058(10) 0.0357(6) 0.049(4) Uani 1 1 d . . . . .
H28 H 0.586552 0.761401 0.010325 0.059 Uiso 1 1 calc R . . . .
C29 C 0.4915(14) 0.7878(15) 0.0425(10) 0.084(7) Uani 1 1 d . . . . .
H29A H 0.451510 0.722360 0.044889 0.126 Uiso 1 1 calc GR . . . .
H29B H 0.466376 0.807994 0.016170 0.126 Uiso 1 1 calc GR . . . .
H29C H 0.492884 0.821567 0.070595 0.126 Uiso 1 1 calc GR . . . .
C30 C 0.6361(13) 0.7846(12) 0.0774(8) 0.066(5) Uani 1 1 d . . . . .
H30A H 0.633775 0.819303 0.104330 0.098 Uiso 1 1 calc GR . . . .
H30B H 0.701505 0.801276 0.073738 0.098 Uiso 1 1 calc GR . . . .
H30C H 0.601541 0.719156 0.081701 0.098 Uiso 1 1 calc GR . . . .
C31 C 0.6763(15) 1.0206(14) 0.0582(6) 0.062(5) Uani 1 1 d . . . . .
H31 H 0.729817 1.077064 0.048860 0.074 Uiso 1 1 calc R . . . .
C32 C 0.5980(17) 1.0391(19) 0.0556(8) 0.085(7) Uani 1 1 d . . . . .
H32A H 0.543853 0.987360 0.066104 0.127 Uiso 1 1 calc GR . . . .
H32B H 0.582573 1.048331 0.023736 0.127 Uiso 1 1 calc GR . . . .
H32C H 0.614181 1.094203 0.075047 0.127 Uiso 1 1 calc GR . . . .
C33 C 0.7057(14) 1.0108(14) 0.1077(7) 0.068(5) Uani 1 1 d . . . . .
H33A H 0.734034 1.070384 0.124974 0.101 Uiso 1 1 calc GR . . . .
H33B H 0.751417 0.987685 0.108213 0.101 Uiso 1 1 calc GR . . . .
H33C H 0.650528 0.967978 0.121845 0.101 Uiso 1 1 calc GR . . . .
C34 C 0.9009(11) 0.9440(9) 0.1427(4) 0.037(3) Uani 1 1 d . . . . .
C35 C 0.8938(9) 0.9230(9) 0.1826(4) 0.031(3) Uani 1 1 d . . . . .
C36 C 0.9929(10) 0.9286(11) 0.2752(5) 0.043(4) Uani 1 1 d . . . . .
H36 H 0.983774 0.921342 0.308399 0.051 Uiso 1 1 calc R . . . .
C37 C 1.0614(12) 1.0275(12) 0.2703(6) 0.053(4) Uani 1 1 d . . . . .
H37A H 1.122795 1.041637 0.286084 0.079 Uiso 1 1 calc GR . . . .
H37B H 1.038609 1.066796 0.283950 0.079 Uiso 1 1 calc GR . . . .
H37C H 1.067170 1.038128 0.237718 0.079 Uiso 1 1 calc GR . . . .
C38 C 1.0317(13) 0.8635(14) 0.2600(6) 0.058(5) Uani 1 1 d . . . . .
H38A H 1.048991 0.874731 0.228668 0.087 Uiso 1 1 calc GR . . . .
H38B H 0.983503 0.800078 0.260993 0.087 Uiso 1 1 calc GR . . . .
H38C H 1.087124 0.874819 0.280812 0.087 Uiso 1 1 calc GR . . . .
C39 C 0.8174(12) 0.9626(11) 0.2667(5) 0.044(4) Uani 1 1 d . . . . .
H39 H 0.748588 0.924373 0.257785 0.053 Uiso 1 1 calc R . . . .
C40 C 0.8426(12) 1.0516(11) 0.2461(5) 0.046(4) Uani 1 1 d . . . . .
H40A H 0.816087 1.084607 0.262543 0.068 Uiso 1 1 calc GR . . . .
H40B H 0.817357 1.040312 0.213735 0.068 Uiso 1 1 calc GR . . . .
H40C H 0.911006 1.088204 0.248621 0.068 Uiso 1 1 calc GR . . . .
C41 C 0.8294(16) 0.9707(13) 0.3197(6) 0.063(5) Uani 1 1 d . . . . .
H41A H 0.896243 1.002563 0.330760 0.095 Uiso 1 1 calc GR . . . .
H41B H 0.800589 0.909623 0.331068 0.095 Uiso 1 1 calc GR . . . .
H41C H 0.798818 1.005135 0.330759 0.095 Uiso 1 1 calc GR . . . .
C42 C 0.7950(11) 0.7674(10) 0.2418(5) 0.040(3) Uani 1 1 d . . . . .
H42 H 0.830179 0.736909 0.229844 0.048 Uiso 1 1 calc R . . . .
C43 C 0.7713(13) 0.7343(11) 0.2889(6) 0.054(4) Uani 1 1 d . . . . .
H43A H 0.739984 0.765406 0.302779 0.081 Uiso 1 1 calc GR . . . .
H43B H 0.829056 0.747613 0.308344 0.081 Uiso 1 1 calc GR . . . .
H43C H 0.729596 0.668316 0.286254 0.081 Uiso 1 1 calc GR . . . .
C44 C 0.7056(11) 0.7373(12) 0.2080(6) 0.056(5) Uani 1 1 d . . . . .
H44A H 0.669271 0.670565 0.205705 0.084 Uiso 1 1 calc GR . . . .
H44B H 0.723319 0.758551 0.177715 0.084 Uiso 1 1 calc GR . . . .
H44C H 0.667441 0.763573 0.219217 0.084 Uiso 1 1 calc GR . . . .
C45 C 0.8143(11) 0.7400(11) 0.0159(5) 0.040(3) Uani 1 1 d . . . . .
C46 C 0.7617(11) 0.6657(10) 0.0460(5) 0.042(4) Uani 1 1 d . . . . .
C47 C 0.6895(14) 0.5859(12) 0.0253(6) 0.063(5) Uani 1 1 d . . . . .
H47 H 0.675030 0.579738 -0.007028 0.076 Uiso 1 1 calc R . . . .
C48 C 0.6377(15) 0.5143(14) 0.0514(8) 0.075(6) Uani 1 1 d . . . . .
C49 C 0.559(2) 0.4258(18) 0.0310(10) 0.129(13) Uani 1 1 d . . . . .
H49A H 0.504156 0.433793 0.021887 0.194 Uiso 1 1 calc GR . . . .
H49B H 0.543869 0.379945 0.053724 0.194 Uiso 1 1 calc GR . . . .
H49C H 0.578286 0.405517 0.004027 0.194 Uiso 1 1 calc GR . . . .
C50 C 0.6649(13) 0.5275(12) 0.0984(7) 0.062(5) Uani 1 1 d . . . . .
H50 H 0.631719 0.480467 0.117768 0.075 Uiso 1 1 calc R . . . .
C51 C 0.7388(12) 0.6075(10) 0.1170(6) 0.047(4) Uani 1 1 d . . . . .
H51 H 0.756441 0.614653 0.149148 0.056 Uiso 1 1 calc R . . . .
C52 C 0.9369(10) 1.1800(10) 0.0580(5) 0.035(3) Uani 1 1 d . . . . .
C53 C 0.9067(11) 1.2157(8) 0.0976(5) 0.036(3) Uani 1 1 d . . . . .
C54 C 0.8538(13) 1.2610(12) 0.0882(7) 0.057(5) Uani 1 1 d . . . . .
H54 H 0.840007 1.271355 0.057465 0.069 Uiso 1 1 calc R . . . .
C55 C 0.8214(14) 1.2907(11) 0.1238(8) 0.063(6) Uani 1 1 d . . . . .
C56 C 0.761(2) 1.3374(16) 0.1143(10) 0.097(9) Uani 1 1 d . . . . .
H56A H 0.792640 1.388088 0.094952 0.146 Uiso 1 1 calc GR . . . .
H56B H 0.752116 1.360875 0.143352 0.146 Uiso 1 1 calc GR . . . .
H56C H 0.700363 1.293493 0.098458 0.146 Uiso 1 1 calc GR . . . .
C57 C 0.8454(13) 1.2777(11) 0.1673(8) 0.062(5) Uani 1 1 d . . . . .
H57 H 0.826970 1.299893 0.192567 0.075 Uiso 1 1 calc R . . . .
C58 C 0.8974(13) 1.2311(11) 0.1743(6) 0.050(4) Uani 1 1 d . . . . .
H58 H 0.912403 1.220941 0.204908 0.060 Uiso 1 1 calc R . . . .
C59 C 0.6047(8) 0.9597(9) 0.5061(4) 0.022(2) Uani 1 1 d . . . . .
C60 C 0.6568(9) 0.9278(8) 0.5212(4) 0.026(3) Uani 1 1 d . . . . .
C61 C 0.6779(13) 0.7799(12) 0.5698(7) 0.058(5) Uani 1 1 d . . . . .
H61 H 0.622877 0.737992 0.547808 0.070 Uiso 1 1 calc R . . . .
C62 C 0.738(2) 0.729(2) 0.5785(12) 0.130(14) Uani 1 1 d . . . . .
H62A H 0.794317 0.767040 0.599651 0.196 Uiso 1 1 calc GR . . . .
H62B H 0.757312 0.716661 0.549368 0.196 Uiso 1 1 calc GR . . . .
H62C H 0.701042 0.670998 0.591984 0.196 Uiso 1 1 calc GR . . . .
C63 C 0.6389(14) 0.7877(14) 0.6113(7) 0.067(5) Uani 1 1 d . . . . .
H63A H 0.615386 0.729932 0.626087 0.100 Uiso 1 1 calc GR . . . .
H63B H 0.587239 0.801802 0.603629 0.100 Uiso 1 1 calc GR . . . .
H63C H 0.687629 0.836631 0.632285 0.100 Uiso 1 1 calc GR . . . .
C64 C 0.7773(10) 0.8549(9) 0.4832(5) 0.033(3) Uani 1 1 d . . . . .
H64 H 0.822920 0.831767 0.492115 0.040 Uiso 1 1 calc R . . . .
C65 C 0.8285(17) 0.9385(14) 0.4560(7) 0.070(6) Uani 1 1 d . . . . .
H65A H 0.853579 0.921747 0.430237 0.105 Uiso 1 1 calc GR . . . .
H65B H 0.880163 0.986815 0.476060 0.105 Uiso 1 1 calc GR . . . .
H65C H 0.784686 0.960301 0.444317 0.105 Uiso 1 1 calc GR . . . .
C66 C 0.6954(15) 0.7786(13) 0.4547(7) 0.065(5) Uani 1 1 d . . . . .
H66A H 0.642349 0.791812 0.451962 0.097 Uiso 1 1 calc GR . . . .
H66B H 0.677471 0.721291 0.469480 0.097 Uiso 1 1 calc GR . . . .
H66C H 0.713071 0.772965 0.424111 0.097 Uiso 1 1 calc GR . . . .
C67 C 0.8437(13) 0.9817(13) 0.5724(6) 0.052(4) Uani 1 1 d . . . . .
H67 H 0.864471 1.032613 0.551409 0.062 Uiso 1 1 calc R . . . .
C68 C 0.9281(16) 0.969(2) 0.5832(11) 0.118(13) Uani 1 1 d . . . . .
H68A H 0.977225 1.023080 0.601178 0.177 Uiso 1 1 calc GR . . . .
H68B H 0.951037 0.960179 0.554597 0.177 Uiso 1 1 calc GR . . . .
H68C H 0.911641 0.915279 0.600943 0.177 Uiso 1 1 calc GR . . . .
C69 C 0.8234(12) 1.0205(10) 0.6149(5) 0.045(4) Uani 1 1 d . . . . .
H69A H 0.813218 0.978804 0.639458 0.068 Uiso 1 1 calc GR . . . .
H69B H 0.767127 1.027603 0.607790 0.068 Uiso 1 1 calc GR . . . .
H69C H 0.876792 1.080019 0.624987 0.068 Uiso 1 1 calc GR . . . .
C70 C 0.5554(9) 0.9754(10) 0.6503(5) 0.032(3) Uani 1 1 d . . . . .
C71 C 0.5388(9) 0.9693(9) 0.6901(4) 0.029(3) Uani 1 1 d . . . . .
C72 C 0.6449(12) 0.9740(13) 0.7796(5) 0.054(4) Uani 1 1 d . . . . .
H72 H 0.642487 0.972511 0.813531 0.065 Uiso 1 1 calc R . . . .
C73 C 0.6578(16) 0.8893(15) 0.7623(8) 0.074(6) Uani 1 1 d . . . . .
H73A H 0.660124 0.888998 0.728998 0.111 Uiso 1 1 calc GR . . . .
H73B H 0.604998 0.832503 0.769786 0.111 Uiso 1 1 calc GR . . . .
H73C H 0.716410 0.894253 0.777440 0.111 Uiso 1 1 calc GR . . . .
C74 C 0.7250(12) 1.0621(15) 0.7705(6) 0.064(5) Uani 1 1 d . . . . .
H74A H 0.779876 1.074082 0.791874 0.097 Uiso 1 1 calc GR . . . .
H74B H 0.708492 1.111346 0.774703 0.097 Uiso 1 1 calc GR . . . .
H74C H 0.739439 1.059011 0.738934 0.097 Uiso 1 1 calc GR . . . .
C75 C 0.4318(11) 0.8437(10) 0.7609(5) 0.041(4) Uani 1 1 d . . . . .
H75 H 0.446057 0.799660 0.743777 0.049 Uiso 1 1 calc R . . . .
C76 C 0.4293(15) 0.8187(14) 0.8108(6) 0.071(6) Uani 1 1 d . . . . .
H76A H 0.412252 0.857868 0.828966 0.107 Uiso 1 1 calc GR . . . .
H76B H 0.491232 0.827476 0.823076 0.107 Uiso 1 1 calc GR . . . .
H76C H 0.382794 0.754751 0.812270 0.107 Uiso 1 1 calc GR . . . .
C77 C 0.3354(11) 0.8262(10) 0.7402(5) 0.048(4) Uani 1 1 d . . . . .
H77A H 0.292070 0.760667 0.738785 0.072 Uiso 1 1 calc GR . . . .
H77B H 0.339355 0.847534 0.709213 0.072 Uiso 1 1 calc GR . . . .
H77C H 0.312498 0.859065 0.759350 0.072 Uiso 1 1 calc GR . . . .
C78 C 0.5133(12) 1.0597(10) 0.7736(5) 0.048(4) Uani 1 1 d . . . . .
H78 H 0.571951 1.114869 0.767561 0.058 Uiso 1 1 calc R . . . .
C79 C 0.4340(14) 1.0711(12) 0.7485(7) 0.058(5) Uani 1 1 d . . . . .
H79A H 0.375435 1.013786 0.747560 0.087 Uiso 1 1 calc GR . . . .
H79B H 0.448141 1.087075 0.717089 0.087 Uiso 1 1 calc GR . . . .
H79C H 0.427235 1.119713 0.764537 0.087 Uiso 1 1 calc GR . . . .
C80 C 0.5105(16) 1.0661(14) 0.8250(6) 0.067(5) Uani 1 1 d . . . . .
H80A H 0.518717 1.126438 0.834762 0.100 Uiso 1 1 calc GR . . . .
H80B H 0.561060 1.056960 0.840642 0.100 Uiso 1 1 calc GR . . . .
H80C H 0.449966 1.019023 0.832918 0.100 Uiso 1 1 calc GR . . . .
C81 C 0.4810(9) 1.1627(9) 0.6217(4) 0.029(3) Uani 1 1 d . . . . .
C82 C 0.5395(9) 1.2440(8) 0.6277(5) 0.029(3) Uani 1 1 d . . . . .
C83 C 0.7283(9) 1.4124(9) 0.6359(5) 0.036(3) Uani 1 1 d . . . . .
H83 H 0.751703 1.374099 0.652799 0.043 Uiso 1 1 calc R . . . .
C84 C 0.7473(11) 1.4059(11) 0.5871(5) 0.043(4) Uani 1 1 d . . . . .
H84A H 0.730465 1.446072 0.569125 0.065 Uiso 1 1 calc GR . . . .
H84B H 0.709849 1.342809 0.574136 0.065 Uiso 1 1 calc GR . . . .
H84C H 0.814025 1.424502 0.586156 0.065 Uiso 1 1 calc GR . . . .
C85 C 0.7893(13) 1.5111(12) 0.6581(8) 0.078(7) Uani 1 1 d . . . . .
H85A H 0.855044 1.524269 0.662744 0.117 Uiso 1 1 calc GR . . . .
H85B H 0.767920 1.516674 0.687718 0.117 Uiso 1 1 calc GR . . . .
H85C H 0.783297 1.554516 0.637773 0.117 Uiso 1 1 calc GR . . . .
C86 C 0.5369(11) 1.4241(9) 0.6198(6) 0.042(4) Uani 1 1 d . . . . .
H86 H 0.469004 1.381814 0.621504 0.051 Uiso 1 1 calc R . . . .
C87 C 0.5480(14) 1.4374(11) 0.5687(6) 0.057(5) Uani 1 1 d . . . . .
H87A H 0.508022 1.463083 0.556188 0.086 Uiso 1 1 calc GR . . . .
H87B H 0.529379 1.378471 0.552315 0.086 Uiso 1 1 calc GR . . . .
H87C H 0.613548 1.479280 0.564989 0.086 Uiso 1 1 calc GR . . . .
C88 C 0.5576(15) 1.5142(11) 0.6459(7) 0.060(5) Uani 1 1 d . . . . .
H88A H 0.623936 1.558196 0.645836 0.091 Uiso 1 1 calc GR . . . .
H88B H 0.543035 1.502728 0.677663 0.091 Uiso 1 1 calc GR . . . .
H88C H 0.518790 1.538995 0.630972 0.091 Uiso 1 1 calc GR . . . .
C89 C 0.5952(10) 1.3677(9) 0.7114(5) 0.038(3) Uani 1 1 d . . . . .
H89 H 0.625432 1.433233 0.723046 0.045 Uiso 1 1 calc R . . . .
C90 C 0.4923(11) 1.3254(10) 0.7218(6) 0.047(4) Uani 1 1 d . . . . .
H90A H 0.459189 1.261302 0.710085 0.071 Uiso 1 1 calc GR . . . .
H90B H 0.462250 1.358693 0.706921 0.071 Uiso 1 1 calc GR . . . .
H90C H 0.490156 1.329450 0.755034 0.071 Uiso 1 1 calc GR . . . .
C91 C 0.6496(14) 1.3252(12) 0.7370(5) 0.055(5) Uani 1 1 d . . . . .
H91A H 0.639851 1.324217 0.769548 0.083 Uiso 1 1 calc GR . . . .
H91B H 0.716500 1.361386 0.733780 0.083 Uiso 1 1 calc GR . . . .
H91C H 0.627240 1.262709 0.724068 0.083 Uiso 1 1 calc GR . . . .
C92 C 0.2435(11) 0.8117(9) 0.4317(5) 0.035(3) Uani 1 1 d . . . . .
C93 C 0.1887(9) 0.7687(8) 0.3852(4) 0.026(3) Uani 1 1 d . . . . .
C94 C 0.0912(11) 0.7166(10) 0.3827(5) 0.042(4) Uani 1 1 d . . . . .
H94 H 0.060413 0.707920 0.409694 0.050 Uiso 1 1 calc R . . . .
C95 C 0.0396(11) 0.6773(10) 0.3404(5) 0.041(3) Uani 1 1 d . . . . .
C96 C -0.0644(12) 0.6187(13) 0.3363(7) 0.064(5) Uani 1 1 d . . . . .
H96A H -0.083867 0.598167 0.366533 0.096 Uiso 1 1 calc GR . . . .
H96B H -0.082142 0.565520 0.315015 0.096 Uiso 1 1 calc GR . . . .
H96C H -0.095320 0.653799 0.324794 0.096 Uiso 1 1 calc GR . . . .
C97 C 0.0885(12) 0.6923(12) 0.3022(5) 0.047(4) Uani 1 1 d . . . . .
H97 H 0.056219 0.665223 0.272927 0.056 Uiso 1 1 calc R . . . .
C98 C 0.1826(10) 0.7457(10) 0.3070(5) 0.040(3) Uani 1 1 d . . . . .
H98 H 0.214345 0.757619 0.280257 0.048 Uiso 1 1 calc R . . . .
C99 C 0.5871(9) 1.2533(9) 0.4607(5) 0.031(3) Uani 1 1 d . . . . .
C100 C 0.6185(9) 1.3195(9) 0.4234(4) 0.030(3) Uani 1 1 d . . . . .
C101 C 0.6393(10) 1.4073(9) 0.4322(5) 0.034(3) Uani 1 1 d . . . . .
H101 H 0.632417 1.426980 0.461638 0.041 Uiso 1 1 calc R . . . .
C102 C 0.6708(11) 1.4698(9) 0.3984(5) 0.037(3) Uani 1 1 d . . . . .
C103 C 0.7006(13) 1.5702(10) 0.4082(6) 0.052(4) Uani 1 1 d . . . . .
H10G H 0.672328 1.577918 0.435135 0.078 Uiso 1 1 calc GR . . . .
H10H H 0.679604 1.593216 0.381647 0.078 Uiso 1 1 calc GR . . . .
H10I H 0.769005 1.604185 0.414230 0.078 Uiso 1 1 calc GR . . . .
C104 C 0.6787(11) 1.4376(9) 0.3565(5) 0.041(4) Uani 1 1 d . . . . .
H104 H 0.701732 1.477784 0.332808 0.049 Uiso 1 1 calc R . . . .
C105 C 0.6528(11) 1.3453(9) 0.3490(5) 0.037(3) Uani 1 1 d . . . . .
H105 H 0.654503 1.322629 0.319243 0.044 Uiso 1 1 calc R . . . .
C106 C 1.0430(12) 1.4183(10) -0.0720(5) 0.040(3) Uani 1 1 d . . . . .
H106 H 1.102537 1.436984 -0.086278 0.048 Uiso 1 1 calc R . . . .
C107 C 0.752(2) 0.7114(17) -0.2657(8) 0.117(12) Uani 1 1 d . . . . .
H10D H 0.796996 0.775881 -0.257922 0.176 Uiso 1 1 calc GR . . . .
H10E H 0.688507 0.701813 -0.263408 0.176 Uiso 1 1 calc GR . . . .
H10F H 0.757697 0.694305 -0.297079 0.176 Uiso 1 1 calc GR . . . .
C108 C 0.2759(9) 0.8934(8) 0.6015(4) 0.025(3) Uani 1 1 d . . . . .
C109 C 0.2066(9) 0.8205(9) 0.5890(4) 0.028(3) Uani 1 1 d . . . . .
C110 C 0.0194(10) 0.7162(10) 0.5290(5) 0.038(3) Uani 1 1 d . . . . .
H110 H 0.042160 0.701005 0.501079 0.045 Uiso 1 1 calc R . . . .
C111 C -0.0837(11) 0.6430(12) 0.5287(6) 0.051(4) Uani 1 1 d . . . . .
H11D H -0.111832 0.658916 0.553378 0.077 Uiso 1 1 calc GR . . . .
H11E H -0.086592 0.583584 0.533380 0.077 Uiso 1 1 calc GR . . . .
H11F H -0.118331 0.640032 0.499104 0.077 Uiso 1 1 calc GR . . . .
C112 C 0.0276(13) 0.8121(11) 0.5233(7) 0.056(5) Uani 1 1 d . . . . .
H11G H -0.010999 0.810430 0.495388 0.084 Uiso 1 1 calc GR . . . .
H11H H 0.093187 0.856216 0.521034 0.084 Uiso 1 1 calc GR . . . .
H11I H 0.005847 0.830324 0.549936 0.084 Uiso 1 1 calc GR . . . .
C113 C 0.1317(9) 0.6203(9) 0.5673(5) 0.035(3) Uani 1 1 d . . . . .
H113 H 0.183122 0.629735 0.591599 0.042 Uiso 1 1 calc R . . . .
C114 C 0.0504(12) 0.5227(10) 0.5711(7) 0.053(4) Uani 1 1 d . . . . .
H11J H -0.005133 0.514053 0.551161 0.080 Uiso 1 1 calc GR . . . .
H11K H 0.035582 0.514968 0.602916 0.080 Uiso 1 1 calc GR . . . .
H11L H 0.069531 0.477452 0.561541 0.080 Uiso 1 1 calc GR . . . .
C115 C 0.1712(10) 0.6274(9) 0.5214(5) 0.039(3) Uani 1 1 d . . . . .
H11M H 0.197648 0.585318 0.519121 0.058 Uiso 1 1 calc GR . . . .
H11N H 0.220327 0.689961 0.519071 0.058 Uiso 1 1 calc GR . . . .
H11O H 0.120878 0.611516 0.496434 0.058 Uiso 1 1 calc GR . . . .
C116 C 0.0399(11) 0.6937(11) 0.6340(5) 0.050(4) Uani 1 1 d . . . . .
H116 H -0.019027 0.634246 0.628893 0.060 Uiso 1 1 calc R . . . .
C117 C 0.0103(15) 0.7660(15) 0.6451(7) 0.075(6) Uani 1 1 d . . . . .
H11P H -0.004654 0.762780 0.676905 0.113 Uiso 1 1 calc GR . . . .
H11Q H -0.045064 0.755210 0.624398 0.113 Uiso 1 1 calc GR . . . .
H11R H 0.061693 0.826592 0.641126 0.113 Uiso 1 1 calc GR . . . .
C118 C 0.1011(15) 0.6827(16) 0.6735(6) 0.080(7) Uani 1 1 d . . . . .
H11S H 0.149977 0.742949 0.686074 0.120 Uiso 1 1 calc GR . . . .
H11T H 0.130321 0.647199 0.662167 0.120 Uiso 1 1 calc GR . . . .
H11U H 0.062152 0.650788 0.697653 0.120 Uiso 1 1 calc GR . . . .
Cl1C Cl 0.7162(4) 0.4488(3) 0.23204(14) 0.0590(12) Uani 1 1 d . . . . .
N1 N 0.7876(8) 0.6766(8) 0.0908(4) 0.035(3) Uani 1 1 d . . . . .
N2 N 0.9280(9) 1.1995(8) 0.1400(4) 0.042(3) Uani 1 1 d . . . . .
N3 N 0.2335(8) 0.7827(8) 0.3476(4) 0.034(3) Uani 1 1 d . . . . .
N4 N 0.6255(7) 1.2875(7) 0.3823(4) 0.028(2) Uani 1 1 d . . . . .
O5 O 0.8895(7) 0.8083(7) 0.0333(3) 0.043(2) Uani 1 1 d . . . . .
O6 O 0.7789(9) 0.7333(8) -0.0244(4) 0.058(3) Uani 1 1 d . . . . .
O7 O 0.9088(9) 1.1922(9) 0.0185(4) 0.054(3) Uani 1 1 d . . . . .
O8 O 0.9877(7) 1.1431(7) 0.0657(3) 0.037(2) Uani 1 1 d . . . . .
O9 O 0.3311(7) 0.8464(6) 0.4344(3) 0.038(2) Uani 1 1 d . . . . .
O10 O 0.1974(7) 0.8142(7) 0.4619(3) 0.043(3) Uani 1 1 d . . . . .
O11 O 0.5637(8) 1.2796(7) 0.4949(3) 0.043(2) Uani 1 1 d . . . . .
O12 O 0.5876(6) 1.1787(6) 0.4549(3) 0.030(2) Uani 1 1 d . . . . .
O1C O 0.7839(15) 0.4238(16) 0.2467(9) 0.133(8) Uani 1 1 d . . . . .
O2C O 0.6285(11) 0.3870(10) 0.2465(5) 0.082(4) Uani 1 1 d . . . . .
O3C O 0.7447(14) 0.5364(10) 0.2506(8) 0.111(7) Uani 1 1 d . . . . .
O4C O 0.7042(18) 0.4474(14) 0.1849(6) 0.138(9) Uani 1 1 d . . . . .
Si1 Si 0.7395(3) 0.6636(2) -0.17489(13) 0.0335(8) Uani 1 1 d . . . . .
Si2 Si 0.9436(3) 1.3348(2) -0.11427(13) 0.0325(8) Uani 1 1 d . . . . .
Si3 Si 0.6598(3) 0.9243(3) 0.01443(15) 0.0428(10) Uani 1 1 d . . . . .
Si4 Si 0.8744(3) 0.8944(3) 0.24264(12) 0.0294(8) Uani 1 1 d . . . . .
Si5 Si 0.7427(3) 0.8858(3) 0.53856(13) 0.0298(8) Uani 1 1 d . . . . .
Si6 Si 0.5283(3) 0.9597(3) 0.75247(12) 0.0309(8) Uani 1 1 d . . . . .
Si7 Si 0.6028(3) 1.3665(2) 0.64760(13) 0.0298(8) Uani 1 1 d . . . . .
Si8 Si 0.0966(2) 0.7115(2) 0.57952(12) 0.0274(7) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Ag2 3.1771(16) . ?
Ag1 Ag6 3.0297(17) 2_775 ?
Ag1 C1 2.355(15) . ?
Ag1 C34 2.414(14) 2_775 ?
Ag1 N2 2.335(13) 2_775 ?
Ag1 O8 2.457(9) 2_775 ?
Ag2 Ag3 2.9934(18) . ?
Ag2 Ag5 2.9811(18) . ?
Ag2 Ag7 3.1795(16) 2_775 ?
Ag2 C1 2.081(13) . ?
Ag2 C12 2.076(14) . ?
Ag3 Ag4 2.686(3) 2_775 ?
Ag3 Ag4 3.277(3) . ?
Ag3 C1 2.297(13) . ?
Ag3 C23 2.443(15) . ?
Ag3 O6 2.235(12) . ?
Ag4 Ag4 0.941(5) 2_775 ?
Ag4 Ag6 2.989(3) 2_775 ?
Ag4 Ag6 2.870(3) . ?
Ag4 Ag5 3.260(3) 2_775 ?
Ag4 Ag5 2.619(3) . ?
Ag4 C23 2.181(16) 2_775 ?
Ag4 C23 2.085(16) . ?
Ag6 Ag7 3.0322(17) . ?
Ag6 C23 2.325(13) . ?
Ag6 C24 2.384(16) . ?
Ag6 C34 2.084(13) . ?
Ag5 C12 2.279(14) . ?
Ag5 C23 2.443(15) . ?
Ag5 O7 2.231(12) . ?
Ag7 C12 2.392(14) 2_775 ?
Ag7 C34 2.392(14) . ?
Ag7 N1 2.321(11) . ?
Ag7 O5 2.504(10) . ?
Ag8 Ag12 3.2287(16) 2_676 ?
Ag8 Ag13 3.0687(15) 2_676 ?
Ag8 Ag14 3.3267(17) 2_676 ?
Ag8 C70 2.337(14) 2_676 ?
Ag8 C81 2.348(13) 2_676 ?
Ag8 C82 2.590(13) 2_676 ?
Ag8 N3 2.314(12) . ?
Ag8 O9 2.501(10) . ?
Ag9 Ag10 3.0279(13) . ?
Ag9 Ag10 3.0278(13) 2_676 ?
Ag9 Ag13 2.9099(11) 2_676 ?
Ag9 Ag13 2.9099(11) . ?
Ag9 Ag14 3.0505(13) 2_676 ?
Ag9 Ag14 3.0505(13) . ?
Ag9 C59 2.092(11) 2_676 ?
Ag9 C59 2.092(11) . ?
Ag10 Ag12 3.0870(14) . ?
Ag10 C59 2.389(13) 2_676 ?
Ag10 C108 2.336(12) . ?
Ag10 C109 2.524(13) . ?
Ag10 O10 2.290(10) . ?
Ag11 Ag12 2.9243(15) . ?
Ag11 Ag13 3.0755(15) . ?
Ag11 C70 2.366(14) . ?
Ag11 C71 2.684(13) . ?
Ag11 C108 2.371(13) . ?
Ag11 N4 2.319(11) 2_676 ?
Ag11 O12 2.477(9) 2_676 ?
Ag12 Ag14 3.1881(15) . ?
Ag12 C81 2.065(13) . ?
Ag12 C108 2.072(12) . ?
Ag13 C59 2.309(10) . ?
Ag13 C60 2.442(11) . ?
Ag13 C70 2.094(13) . ?
Ag14 C59 2.487(12) 2_676 ?
Ag14 C81 2.316(13) . ?
Ag14 C82 2.564(13) . ?
Ag14 O11 2.247(10) . ?
C1 C2 1.200(19) . ?
C2 Si1 1.878(15) . ?
C3 H3 1.0000 . ?
C3 C4 1.57(3) . ?
C3 C107 1.44(3) . ?
C3 Si1 1.886(17) . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C6 H6 1.0000 . ?
C6 C7 1.47(3) . ?
C6 C8 1.53(3) . ?
C6 Si1 1.874(18) . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 H9 1.0000 . ?
C9 C10 1.44(3) . ?
C9 C11 1.58(3) . ?
C9 Si1 1.90(2) . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 C13 1.209(19) . ?
C13 Si2 1.875(14) . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C15 C106 1.55(2) . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C16 C106 1.50(2) . ?
C17 H17 1.0000 . ?
C17 C18 1.53(2) . ?
C17 C19 1.52(2) . ?
C17 Si2 1.886(17) . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20 1.0000 . ?
C20 C21 1.51(2) . ?
C20 C22 1.55(2) . ?
C20 Si2 1.888(15) . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 C24 1.22(2) . ?
C24 Si3 1.868(18) . ?
C25 H25 1.0000 . ?
C25 C26 1.58(3) . ?
C25 C27 1.55(3) . ?
C25 Si3 1.873(17) . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C28 H28 1.0000 . ?
C28 C29 1.56(3) . ?
C28 C30 1.49(3) . ?
C28 Si3 1.904(16) . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
C31 H31 1.0000 . ?
C31 C32 1.44(3) . ?
C31 C33 1.53(3) . ?
C31 Si3 1.929(19) . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C33 H33A 0.9800 . ?
C33 H33B 0.9800 . ?
C33 H33C 0.9800 . ?
C34 C35 1.230(19) . ?
C35 Si4 1.848(14) . ?
C36 H36 1.0000 . ?
C36 C37 1.51(2) . ?
C36 C38 1.56(2) . ?
C36 Si4 1.890(15) . ?
C37 H37A 0.9800 . ?
C37 H37B 0.9800 . ?
C37 H37C 0.9800 . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
C39 H39 1.0000 . ?
C39 C40 1.50(2) . ?
C39 C41 1.54(2) . ?
C39 Si4 1.920(15) . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?
C41 H41A 0.9800 . ?
C41 H41B 0.9800 . ?
C41 H41C 0.9800 . ?
C42 H42 1.0000 . ?
C42 C43 1.51(2) . ?
C42 C44 1.55(2) . ?
C42 Si4 1.890(15) . ?
C43 H43A 0.9800 . ?
C43 H43B 0.9800 . ?
C43 H43C 0.9800 . ?
C44 H44A 0.9800 . ?
C44 H44B 0.9800 . ?
C44 H44C 0.9800 . ?
C45 C46 1.49(2) . ?
C45 O5 1.269(18) . ?
C45 O6 1.248(18) . ?
C46 C47 1.38(2) . ?
C46 N1 1.326(19) . ?
C47 H47 0.9500 . ?
C47 C48 1.39(3) . ?
C48 C49 1.49(3) . ?
C48 C50 1.39(3) . ?
C49 H49A 0.9800 . ?
C49 H49B 0.9800 . ?
C49 H49C 0.9800 . ?
C50 H50 0.9500 . ?
C50 C51 1.37(2) . ?
C51 H51 0.9500 . ?
C51 N1 1.354(18) . ?
C52 C53 1.507(19) . ?
C52 O7 1.263(18) . ?
C52 O8 1.246(17) . ?
C53 C54 1.40(2) . ?
C53 N2 1.33(2) . ?
C54 H54 0.9500 . ?
C54 C55 1.39(2) . ?
C55 C56 1.52(3) . ?
C55 C57 1.35(3) . ?
C56 H56A 0.9800 . ?
C56 H56B 0.9800 . ?
C56 H56C 0.9800 . ?
C57 H57 0.9500 . ?
C57 C58 1.39(3) . ?
C58 H58 0.9500 . ?
C58 N2 1.356(19) . ?
C59 C60 1.246(17) . ?
C60 Si5 1.868(13) . ?
C61 H61 1.0000 . ?
C61 C62 1.58(3) . ?
C61 C63 1.45(3) . ?
C61 Si5 1.885(16) . ?
C62 H62A 0.9800 . ?
C62 H62B 0.9800 . ?
C62 H62C 0.9800 . ?
C63 H63A 0.9800 . ?
C63 H63B 0.9800 . ?
C63 H63C 0.9800 . ?
C64 H64 1.0000 . ?
C64 C65 1.53(2) . ?
C64 C66 1.51(2) . ?
C64 Si5 1.896(14) . ?
C65 H65A 0.9800 . ?
C65 H65B 0.9800 . ?
C65 H65C 0.9800 . ?
C66 H66A 0.9800 . ?
C66 H66B 0.9800 . ?
C66 H66C 0.9800 . ?
C67 H67 1.0000 . ?
C67 C68 1.49(3) . ?
C67 C69 1.52(2) . ?
C67 Si5 1.851(18) . ?
C68 H68A 0.9800 . ?
C68 H68B 0.9800 . ?
C68 H68C 0.9800 . ?
C69 H69A 0.9800 . ?
C69 H69B 0.9800 . ?
C69 H69C 0.9800 . ?
C70 C71 1.215(18) . ?
C71 Si6 1.856(13) . ?
C72 H72 1.0000 . ?
C72 C73 1.60(3) . ?
C72 C74 1.48(3) . ?
C72 Si6 1.893(16) . ?
C73 H73A 0.9800 . ?
C73 H73B 0.9800 . ?
C73 H73C 0.9800 . ?
C74 H74A 0.9800 . ?
C74 H74B 0.9800 . ?
C74 H74C 0.9800 . ?
C75 H75 1.0000 . ?
C75 C76 1.53(2) . ?
C75 C77 1.52(2) . ?
C75 Si6 1.869(14) . ?
C76 H76A 0.9800 . ?
C76 H76B 0.9800 . ?
C76 H76C 0.9800 . ?
C77 H77A 0.9800 . ?
C77 H77B 0.9800 . ?
C77 H77C 0.9800 . ?
C78 H78 1.0000 . ?
C78 C79 1.52(3) . ?
C78 C80 1.51(2) . ?
C78 Si6 1.885(17) . ?
C79 H79A 0.9800 . ?
C79 H79B 0.9800 . ?
C79 H79C 0.9800 . ?
C80 H80A 0.9800 . ?
C80 H80B 0.9800 . ?
C80 H80C 0.9800 . ?
C81 C82 1.234(18) . ?
C82 Si7 1.852(12) . ?
C83 H83 1.0000 . ?
C83 C84 1.50(2) . ?
C83 C85 1.56(2) . ?
C83 Si7 1.877(13) . ?
C84 H84A 0.9800 . ?
C84 H84B 0.9800 . ?
C84 H84C 0.9800 . ?
C85 H85A 0.9800 . ?
C85 H85B 0.9800 . ?
C85 H85C 0.9800 . ?
C86 H86 1.0000 . ?
C86 C87 1.53(2) . ?
C86 C88 1.54(2) . ?
C86 Si7 1.889(17) . ?
C87 H87A 0.9800 . ?
C87 H87B 0.9800 . ?
C87 H87C 0.9800 . ?
C88 H88A 0.9800 . ?
C88 H88B 0.9800 . ?
C88 H88C 0.9800 . ?
C89 H89 1.0000 . ?
C89 C90 1.54(2) . ?
C89 C91 1.53(2) . ?
C89 Si7 1.886(14) . ?
C90 H90A 0.9800 . ?
C90 H90B 0.9800 . ?
C90 H90C 0.9800 . ?
C91 H91A 0.9800 . ?
C91 H91B 0.9800 . ?
C91 H91C 0.9800 . ?
C92 C93 1.523(19) . ?
C92 O9 1.255(17) . ?
C92 O10 1.218(17) . ?
C93 C94 1.40(2) . ?
C93 N3 1.334(17) . ?
C94 H94 0.9500 . ?
C94 C95 1.39(2) . ?
C95 C96 1.50(2) . ?
C95 C97 1.39(2) . ?
C96 H96A 0.9800 . ?
C96 H96B 0.9800 . ?
C96 H96C 0.9800 . ?
C97 H97 0.9500 . ?
C97 C98 1.35(2) . ?
C98 H98 0.9500 . ?
C98 N3 1.343(18) . ?
C99 C100 1.516(19) . ?
C99 O11 1.241(17) . ?
C99 O12 1.250(16) . ?
C100 C101 1.348(19) . ?
C100 N4 1.339(17) . ?
C101 H101 0.9500 . ?
C101 C102 1.399(19) . ?
C102 C103 1.517(19) . ?
C102 C104 1.37(2) . ?
C103 H10G 0.9800 . ?
C103 H10H 0.9800 . ?
C103 H10I 0.9800 . ?
C104 H104 0.9500 . ?
C104 C105 1.39(2) . ?
C105 H105 0.9500 . ?
C105 N4 1.339(17) . ?
C106 H106 1.0000 . ?
C106 Si2 1.887(16) . ?
C107 H10D 0.9800 . ?
C107 H10E 0.9800 . ?
C107 H10F 0.9800 . ?
C108 C109 1.227(18) . ?
C109 Si8 1.849(13) . ?
C110 H110 1.0000 . ?
C110 C111 1.54(2) . ?
C110 C112 1.55(2) . ?
C110 Si8 1.885(15) . ?
C111 H11D 0.9800 . ?
C111 H11E 0.9800 . ?
C111 H11F 0.9800 . ?
C112 H11G 0.9800 . ?
C112 H11H 0.9800 . ?
C112 H11I 0.9800 . ?
C113 H113 1.0000 . ?
C113 C114 1.556(19) . ?
C113 C115 1.52(2) . ?
C113 Si8 1.887(14) . ?
C114 H11J 0.9800 . ?
C114 H11K 0.9800 . ?
C114 H11L 0.9800 . ?
C115 H11M 0.9800 . ?
C115 H11N 0.9800 . ?
C115 H11O 0.9800 . ?
C116 H116 1.0000 . ?
C116 C117 1.52(3) . ?
C116 C118 1.53(3) . ?
C116 Si8 1.872(15) . ?
C117 H11P 0.9800 . ?
C117 H11Q 0.9800 . ?
C117 H11R 0.9800 . ?
C118 H11S 0.9800 . ?
C118 H11T 0.9800 . ?
C118 H11U 0.9800 . ?
Cl1C O1C 1.384(18) . ?
Cl1C O2C 1.421(15) . ?
Cl1C O3C 1.386(15) . ?
Cl1C O4C 1.379(17) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag6 Ag1 Ag2 73.58(4) 2_775 . ?
C1 Ag1 Ag2 40.9(3) . . ?
C1 Ag1 Ag6 106.6(3) . 2_775 ?
C1 Ag1 C34 108.1(5) . 2_775 ?
C1 Ag1 O8 91.3(4) . 2_775 ?
C34 Ag1 Ag2 67.5(4) 2_775 . ?
C34 Ag1 Ag6 43.2(3) 2_775 2_775 ?
C34 Ag1 O8 103.1(4) 2_775 2_775 ?
N2 Ag1 Ag2 165.3(3) 2_775 . ?
N2 Ag1 Ag6 100.4(3) 2_775 2_775 ?
N2 Ag1 C1 133.5(4) 2_775 . ?
N2 Ag1 C34 117.5(5) 2_775 2_775 ?
N2 Ag1 O8 70.5(4) 2_775 2_775 ?
O8 Ag1 Ag2 95.1(2) 2_775 . ?
O8 Ag1 Ag6 59.9(2) 2_775 2_775 ?
Ag1 Ag2 Ag7 88.56(5) . 2_775 ?
Ag3 Ag2 Ag1 67.34(4) . . ?
Ag3 Ag2 Ag7 121.99(6) . 2_775 ?
Ag5 Ag2 Ag1 121.37(6) . . ?
Ag5 Ag2 Ag3 81.82(6) . . ?
Ag5 Ag2 Ag7 66.85(4) . 2_775 ?
C1 Ag2 Ag1 47.8(4) . . ?
C1 Ag2 Ag3 50.0(3) . . ?
C1 Ag2 Ag5 131.7(3) . . ?
C1 Ag2 Ag7 136.3(4) . 2_775 ?
C12 Ag2 Ag1 137.3(4) . . ?
C12 Ag2 Ag3 131.3(4) . . ?
C12 Ag2 Ag5 49.7(4) . . ?
C12 Ag2 Ag7 48.8(4) . 2_775 ?
C12 Ag2 C1 174.5(6) . . ?
Ag2 Ag3 Ag4 81.09(7) . . ?
Ag4 Ag3 Ag2 91.11(8) 2_775 . ?
Ag4 Ag3 Ag4 14.18(9) 2_775 . ?
C1 Ag3 Ag2 43.9(3) . . ?
C1 Ag3 Ag4 124.2(4) . 2_775 ?
C1 Ag3 Ag4 119.7(3) . . ?
C1 Ag3 C23 127.5(5) . . ?
C23 Ag3 Ag2 84.7(3) . . ?
C23 Ag3 Ag4 50.1(4) . 2_775 ?
C23 Ag3 Ag4 39.5(4) . . ?
O6 Ag3 Ag2 164.0(3) . . ?
O6 Ag3 Ag4 102.4(3) . 2_775 ?
O6 Ag3 Ag4 110.6(3) . . ?
O6 Ag3 C1 128.8(4) . . ?
O6 Ag3 C23 97.4(4) . . ?
Ag3 Ag4 Ag3 165.81(9) 2_775 . ?
Ag3 Ag4 Ag6 95.44(9) 2_775 2_775 ?
Ag3 Ag4 Ag6 94.15(8) 2_775 . ?
Ag3 Ag4 Ag5 81.68(8) 2_775 2_775 ?
Ag4 Ag4 Ag3 121.4(3) 2_775 2_775 ?
Ag4 Ag4 Ag3 44.4(3) 2_775 . ?
Ag4 Ag4 Ag6 73.6(3) 2_775 2_775 ?
Ag4 Ag4 Ag6 88.0(3) 2_775 . ?
Ag4 Ag4 Ag5 40.7(3) 2_775 2_775 ?
Ag4 Ag4 Ag5 125.8(3) 2_775 . ?
Ag4 Ag4 C23 71.6(5) 2_775 2_775 ?
Ag4 Ag4 C23 83.0(5) 2_775 . ?
Ag6 Ag4 Ag3 86.03(7) . . ?
Ag6 Ag4 Ag3 80.87(6) 2_775 . ?
Ag6 Ag4 Ag6 161.66(9) . 2_775 ?
Ag6 Ag4 Ag5 83.93(7) 2_775 2_775 ?
Ag6 Ag4 Ag5 82.04(7) . 2_775 ?
Ag5 Ag4 Ag3 84.31(7) 2_775 . ?
Ag5 Ag4 Ag3 82.33(8) . . ?
Ag5 Ag4 Ag3 111.57(10) . 2_775 ?
Ag5 Ag4 Ag6 91.74(8) . 2_775 ?
Ag5 Ag4 Ag6 99.22(9) . . ?
Ag5 Ag4 Ag5 166.45(9) . 2_775 ?
C23 Ag4 Ag3 140.5(4) . 2_775 ?
C23 Ag4 Ag3 109.2(4) 2_775 . ?
C23 Ag4 Ag3 48.1(4) . . ?
C23 Ag4 Ag3 59.2(4) 2_775 2_775 ?
C23 Ag4 Ag6 53.1(4) . . ?
C23 Ag4 Ag6 124.0(4) 2_775 . ?
C23 Ag4 Ag6 50.5(3) 2_775 2_775 ?
C23 Ag4 Ag6 122.5(4) . 2_775 ?
C23 Ag4 Ag5 61.3(4) . . ?
C23 Ag4 Ag5 48.5(4) 2_775 2_775 ?
C23 Ag4 Ag5 110.5(4) . 2_775 ?
C23 Ag4 Ag5 135.3(4) 2_775 . ?
C23 Ag4 C23 154.6(2) . 2_775 ?
Ag1 Ag6 Ag7 94.13(5) 2_775 . ?
Ag4 Ag6 Ag1 94.88(6) . 2_775 ?
Ag4 Ag6 Ag1 108.00(7) 2_775 2_775 ?
Ag4 Ag6 Ag4 18.34(9) . 2_775 ?
Ag4 Ag6 Ag7 108.48(7) . . ?
Ag4 Ag6 Ag7 94.28(6) 2_775 . ?
C23 Ag6 Ag1 127.7(4) . 2_775 ?
C23 Ag6 Ag4 46.4(4) . 2_775 ?
C23 Ag6 Ag4 45.9(4) . . ?
C23 Ag6 Ag7 126.6(4) . . ?
C23 Ag6 C24 30.0(5) . . ?
C24 Ag6 Ag1 134.2(4) . 2_775 ?
C24 Ag6 Ag4 75.8(4) . 2_775 ?
C24 Ag6 Ag4 75.5(4) . . ?
C24 Ag6 Ag7 131.5(4) . . ?
C34 Ag6 Ag1 52.5(4) . 2_775 ?
C34 Ag6 Ag4 131.5(4) . 2_775 ?
C34 Ag6 Ag4 132.5(4) . . ?
C34 Ag6 Ag7 51.8(4) . . ?
C34 Ag6 C23 177.9(6) . . ?
C34 Ag6 C24 151.8(6) . . ?
Ag2 Ag5 Ag4 81.03(7) . 2_775 ?
Ag4 Ag5 Ag2 93.34(8) . . ?
Ag4 Ag5 Ag4 13.55(9) . 2_775 ?
C12 Ag5 Ag2 44.0(4) . . ?
C12 Ag5 Ag4 128.5(4) . . ?
C12 Ag5 Ag4 119.8(4) . 2_775 ?
C12 Ag5 C23 127.3(5) . . ?
C23 Ag5 Ag2 84.9(3) . . ?
C23 Ag5 Ag4 48.5(4) . . ?
C23 Ag5 Ag4 42.0(4) . 2_775 ?
O7 Ag5 Ag2 161.8(3) . . ?
O7 Ag5 Ag4 110.9(3) . 2_775 ?
O7 Ag5 Ag4 100.2(3) . . ?
O7 Ag5 C12 128.8(5) . . ?
O7 Ag5 C23 95.0(5) . . ?
Ag6 Ag7 Ag2 73.51(4) . 2_775 ?
C12 Ag7 Ag2 40.8(3) 2_775 2_775 ?
C12 Ag7 Ag6 106.3(3) 2_775 . ?
C12 Ag7 C34 108.1(5) 2_775 . ?
C12 Ag7 O5 91.5(4) 2_775 . ?
C34 Ag7 Ag2 67.7(4) . 2_775 ?
C34 Ag7 Ag6 43.2(3) . . ?
C34 Ag7 O5 102.5(4) . . ?
N1 Ag7 Ag2 162.8(3) . 2_775 ?
N1 Ag7 Ag6 103.7(3) . . ?
N1 Ag7 C12 128.7(5) . 2_775 ?
N1 Ag7 C34 122.2(5) . . ?
N1 Ag7 O5 69.7(4) . . ?
O5 Ag7 Ag2 95.1(2) . 2_775 ?
O5 Ag7 Ag6 59.3(2) . . ?
Ag12 Ag8 Ag14 58.18(3) 2_676 2_676 ?
Ag13 Ag8 Ag12 79.73(4) 2_676 2_676 ?
Ag13 Ag8 Ag14 83.75(4) 2_676 2_676 ?
C70 Ag8 Ag12 73.8(3) 2_676 2_676 ?
C70 Ag8 Ag13 43.0(3) 2_676 2_676 ?
C70 Ag8 Ag14 114.0(3) 2_676 2_676 ?
C70 Ag8 C81 113.1(5) 2_676 2_676 ?
C70 Ag8 C82 141.1(4) 2_676 2_676 ?
C70 Ag8 O9 103.0(4) 2_676 . ?
C81 Ag8 Ag12 39.7(3) 2_676 2_676 ?
C81 Ag8 Ag13 111.7(3) 2_676 2_676 ?
C81 Ag8 Ag14 44.1(3) 2_676 2_676 ?
C81 Ag8 C82 28.4(4) 2_676 2_676 ?
C81 Ag8 O9 97.4(4) 2_676 . ?
C82 Ag8 Ag12 68.1(3) 2_676 2_676 ?
C82 Ag8 Ag13 132.1(3) 2_676 2_676 ?
C82 Ag8 Ag14 49.5(3) 2_676 2_676 ?
N3 Ag8 Ag12 170.5(3) . 2_676 ?
N3 Ag8 Ag13 100.3(3) . 2_676 ?
N3 Ag8 Ag14 112.3(3) . 2_676 ?
N3 Ag8 C70 112.8(4) . 2_676 ?
N3 Ag8 C81 134.1(4) . 2_676 ?
N3 Ag8 C82 106.0(4) . 2_676 ?
N3 Ag8 O9 70.5(4) . . ?
O9 Ag8 Ag12 101.8(2) . 2_676 ?
O9 Ag8 Ag13 60.3(2) . 2_676 ?
O9 Ag8 Ag14 53.6(2) . 2_676 ?
O9 Ag8 C82 92.1(4) . 2_676 ?
Ag10 Ag9 Ag10 180.0 2_676 . ?
Ag10 Ag9 Ag14 91.76(3) 2_676 . ?
Ag10 Ag9 Ag14 88.24(3) . . ?
Ag10 Ag9 Ag14 88.24(3) 2_676 2_676 ?
Ag10 Ag9 Ag14 91.76(3) . 2_676 ?
Ag13 Ag9 Ag10 84.05(3) . 2_676 ?
Ag13 Ag9 Ag10 95.95(3) 2_676 2_676 ?
Ag13 Ag9 Ag10 95.95(3) . . ?
Ag13 Ag9 Ag10 84.05(3) 2_676 . ?
Ag13 Ag9 Ag13 180.0 . 2_676 ?
Ag13 Ag9 Ag14 91.57(3) 2_676 2_676 ?
Ag13 Ag9 Ag14 91.57(3) . . ?
Ag13 Ag9 Ag14 88.43(3) 2_676 . ?
Ag13 Ag9 Ag14 88.43(3) . 2_676 ?
Ag14 Ag9 Ag14 180.0 . 2_676 ?
C59 Ag9 Ag10 51.8(3) . 2_676 ?
C59 Ag9 Ag10 128.2(3) 2_676 2_676 ?
C59 Ag9 Ag10 128.2(3) . . ?
C59 Ag9 Ag10 51.8(3) 2_676 . ?
C59 Ag9 Ag13 128.1(3) 2_676 . ?
C59 Ag9 Ag13 128.1(3) . 2_676 ?
C59 Ag9 Ag13 51.9(3) 2_676 2_676 ?
C59 Ag9 Ag13 51.9(3) . . ?
C59 Ag9 Ag14 126.0(3) 2_676 2_676 ?
C59 Ag9 Ag14 54.0(3) . 2_676 ?
C59 Ag9 Ag14 126.0(3) . . ?
C59 Ag9 Ag14 54.0(3) 2_676 . ?
C59 Ag9 C59 180.0 2_676 . ?
Ag9 Ag10 Ag12 82.95(3) . . ?
C59 Ag10 Ag9 43.5(3) 2_676 . ?
C59 Ag10 Ag12 78.0(3) 2_676 . ?
C59 Ag10 C109 145.1(4) 2_676 . ?
C108 Ag10 Ag9 118.0(3) . . ?
C108 Ag10 Ag12 42.1(3) . . ?
C108 Ag10 C59 119.3(4) . 2_676 ?
C108 Ag10 C109 28.9(4) . . ?
C109 Ag10 Ag9 142.0(3) . . ?
C109 Ag10 Ag12 70.8(3) . . ?
O10 Ag10 Ag9 112.2(3) . . ?
O10 Ag10 Ag12 159.2(3) . . ?
O10 Ag10 C59 102.8(4) . 2_676 ?
O10 Ag10 C108 129.0(4) . . ?
O10 Ag10 C109 101.0(4) . . ?
Ag12 Ag11 Ag13 84.57(4) . . ?
C70 Ag11 Ag12 79.7(3) . . ?
C70 Ag11 Ag13 42.8(3) . . ?
C70 Ag11 C71 26.9(4) . . ?
C70 Ag11 C108 124.2(4) . . ?
C70 Ag11 O12 102.9(4) . 2_676 ?
C71 Ag11 Ag12 83.7(3) . . ?
C71 Ag11 Ag13 69.5(3) . . ?
C108 Ag11 Ag12 44.6(3) . . ?
C108 Ag11 Ag13 118.2(3) . . ?
C108 Ag11 C71 121.6(4) . . ?
C108 Ag11 O12 91.5(4) . 2_676 ?
N4 Ag11 Ag12 161.3(3) 2_676 . ?
N4 Ag11 Ag13 102.3(3) 2_676 . ?
N4 Ag11 C70 117.2(4) 2_676 . ?
N4 Ag11 C71 115.0(4) 2_676 . ?
N4 Ag11 C108 118.4(4) 2_676 . ?
N4 Ag11 O12 69.8(3) 2_676 2_676 ?
O12 Ag11 Ag12 99.8(2) 2_676 . ?
O12 Ag11 Ag13 60.2(2) 2_676 . ?
O12 Ag11 C71 128.8(4) 2_676 . ?
Ag10 Ag12 Ag8 120.24(4) . 2_676 ?
Ag10 Ag12 Ag14 84.79(4) . . ?
Ag11 Ag12 Ag8 83.79(4) . 2_676 ?
Ag11 Ag12 Ag10 70.14(4) . . ?
Ag11 Ag12 Ag14 119.24(4) . . ?
Ag14 Ag12 Ag8 62.45(3) . 2_676 ?
C81 Ag12 Ag8 46.5(4) . 2_676 ?
C81 Ag12 Ag10 131.2(4) . . ?
C81 Ag12 Ag11 130.3(4) . . ?
C81 Ag12 Ag14 46.5(3) . . ?
C81 Ag12 C108 176.2(5) . . ?
C108 Ag12 Ag8 137.2(3) . 2_676 ?
C108 Ag12 Ag10 49.2(3) . . ?
C108 Ag12 Ag11 53.4(3) . . ?
C108 Ag12 Ag14 133.9(3) . . ?
Ag8 Ag13 Ag11 84.09(4) 2_676 . ?
Ag9 Ag13 Ag8 96.21(4) . 2_676 ?
Ag9 Ag13 Ag11 94.29(4) . . ?
C59 Ag13 Ag8 127.1(3) . 2_676 ?
C59 Ag13 Ag9 45.5(3) . . ?
C59 Ag13 Ag11 125.2(3) . . ?
C59 Ag13 C60 30.3(4) . . ?
C60 Ag13 Ag8 141.3(3) . 2_676 ?
C60 Ag13 Ag9 75.6(3) . . ?
C60 Ag13 Ag11 133.6(3) . . ?
C70 Ag13 Ag8 49.5(4) . 2_676 ?
C70 Ag13 Ag9 126.9(4) . . ?
C70 Ag13 Ag11 50.2(4) . . ?
C70 Ag13 C59 172.3(5) . . ?
C70 Ag13 C60 157.2(5) . . ?
Ag9 Ag14 Ag8 88.43(4) . 2_676 ?
Ag9 Ag14 Ag12 80.93(4) . . ?
Ag12 Ag14 Ag8 59.37(3) . 2_676 ?
C59 Ag14 Ag8 118.3(3) 2_676 2_676 ?
C59 Ag14 Ag9 42.9(3) 2_676 . ?
C59 Ag14 Ag12 74.7(3) 2_676 . ?
C59 Ag14 C82 141.8(4) 2_676 . ?
C81 Ag14 Ag8 44.9(3) . 2_676 ?
C81 Ag14 Ag9 115.1(3) . . ?
C81 Ag14 Ag12 40.3(3) . . ?
C81 Ag14 C59 114.2(4) . 2_676 ?
C81 Ag14 C82 28.7(4) . . ?
C82 Ag14 Ag8 50.1(3) . 2_676 ?
C82 Ag14 Ag9 137.1(3) . . ?
C82 Ag14 Ag12 69.0(3) . . ?
O11 Ag14 Ag8 135.0(3) . 2_676 ?
O11 Ag14 Ag9 106.5(3) . . ?
O11 Ag14 Ag12 162.7(3) . . ?
O11 Ag14 C59 99.8(4) . 2_676 ?
O11 Ag14 C81 138.0(4) . . ?
O11 Ag14 C82 111.3(4) . . ?
Ag2 C1 Ag1 91.3(5) . . ?
Ag2 C1 Ag3 86.1(5) . . ?
Ag3 C1 Ag1 94.8(5) . . ?
C2 C1 Ag1 94.1(11) . . ?
C2 C1 Ag2 173.2(13) . . ?
C2 C1 Ag3 97.6(10) . . ?
C1 C2 Si1 169.6(13) . . ?
C4 C3 H3 106.8 . . ?
C4 C3 Si1 109.9(15) . . ?
C107 C3 H3 106.8 . . ?
C107 C3 C4 113(2) . . ?
C107 C3 Si1 113.6(18) . . ?
Si1 C3 H3 106.8 . . ?
C3 C4 H4A 109.5 . . ?
C3 C4 H4B 109.5 . . ?
C3 C4 H4C 109.5 . . ?
H4A C4 H4B 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
C7 C6 H6 105.6 . . ?
C7 C6 C8 110(2) . . ?
C7 C6 Si1 115.1(19) . . ?
C8 C6 H6 105.6 . . ?
C8 C6 Si1 113.8(13) . . ?
Si1 C6 H6 105.6 . . ?
C6 C7 H7A 109.5 . . ?
C6 C7 H7B 109.5 . . ?
C6 C7 H7C 109.5 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C6 C8 H8A 109.5 . . ?
C6 C8 H8B 109.5 . . ?
C6 C8 H8C 109.5 . . ?
H8A C8 H8B 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C10 C9 H9 105.6 . . ?
C10 C9 C11 111.8(19) . . ?
C10 C9 Si1 118.2(16) . . ?
C11 C9 H9 105.6 . . ?
C11 C9 Si1 109.0(16) . . ?
Si1 C9 H9 105.6 . . ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C9 C11 H11A 109.5 . . ?
C9 C11 H11B 109.5 . . ?
C9 C11 H11C 109.5 . . ?
H11A C11 H11B 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
Ag2 C12 Ag5 86.3(5) . . ?
Ag2 C12 Ag7 90.5(5) . 2_775 ?
Ag5 C12 Ag7 93.3(5) . 2_775 ?
C13 C12 Ag2 175.5(13) . . ?
C13 C12 Ag5 97.4(10) . . ?
C13 C12 Ag7 92.0(10) . 2_775 ?
C12 C13 Si2 170.6(13) . . ?
H15A C15 H15B 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C106 C15 H15A 109.5 . . ?
C106 C15 H15B 109.5 . . ?
C106 C15 H15C 109.5 . . ?
H16A C16 H16B 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C106 C16 H16A 109.5 . . ?
C106 C16 H16B 109.5 . . ?
C106 C16 H16C 109.5 . . ?
C18 C17 H17 106.9 . . ?
C18 C17 Si2 110.8(12) . . ?
C19 C17 H17 106.9 . . ?
C19 C17 C18 112.1(15) . . ?
C19 C17 Si2 112.9(12) . . ?
Si2 C17 H17 106.9 . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
C17 C18 H18C 109.5 . . ?
H18A C18 H18B 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C17 C19 H19A 109.5 . . ?
C17 C19 H19B 109.5 . . ?
C17 C19 H19C 109.5 . . ?
H19A C19 H19B 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C21 C20 H20 106.5 . . ?
C21 C20 C22 111.3(15) . . ?
C21 C20 Si2 111.8(10) . . ?
C22 C20 H20 106.5 . . ?
C22 C20 Si2 113.7(12) . . ?
Si2 C20 H20 106.5 . . ?
C20 C21 H21A 109.5 . . ?
C20 C21 H21B 109.5 . . ?
C20 C21 H21C 109.5 . . ?
H21A C21 H21B 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C20 C22 H22A 109.5 . . ?
C20 C22 H22B 109.5 . . ?
C20 C22 H22C 109.5 . . ?
H22A C22 H22B 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
Ag4 C23 Ag3 70.8(5) 2_775 . ?
Ag4 C23 Ag3 92.4(6) . . ?
Ag4 C23 Ag4 25.4(2) . 2_775 ?
Ag4 C23 Ag6 81.0(5) . . ?
Ag4 C23 Ag6 83.1(5) 2_775 . ?
Ag4 C23 Ag5 89.5(5) 2_775 . ?
Ag4 C23 Ag5 70.2(4) . . ?
Ag6 C23 Ag3 123.7(7) . . ?
Ag6 C23 Ag5 122.7(6) . . ?
Ag5 C23 Ag3 106.4(5) . . ?
C24 C23 Ag3 109.0(12) . . ?
C24 C23 Ag4 156.3(13) . 2_775 ?
C24 C23 Ag4 155.7(12) . . ?
C24 C23 Ag6 77.7(9) . . ?
C24 C23 Ag5 112.5(12) . . ?
C23 C24 Ag6 72.3(10) . . ?
C23 C24 Si3 170.6(14) . . ?
Si3 C24 Ag6 115.6(7) . . ?
C26 C25 H25 106.0 . . ?
C26 C25 Si3 112.4(14) . . ?
C27 C25 H25 106.0 . . ?
C27 C25 C26 118(2) . . ?
C27 C25 Si3 107.7(15) . . ?
Si3 C25 H25 106.0 . . ?
C25 C26 H26A 109.5 . . ?
C25 C26 H26B 109.5 . . ?
C25 C26 H26C 109.5 . . ?
H26A C26 H26B 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C25 C27 H27A 109.5 . . ?
C25 C27 H27B 109.5 . . ?
C25 C27 H27C 109.5 . . ?
H27A C27 H27B 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C29 C28 H28 106.6 . . ?
C29 C28 Si3 108.9(12) . . ?
C30 C28 H28 106.6 . . ?
C30 C28 C29 110.4(17) . . ?
C30 C28 Si3 117.1(12) . . ?
Si3 C28 H28 106.6 . . ?
C28 C29 H29A 109.5 . . ?
C28 C29 H29B 109.5 . . ?
C28 C29 H29C 109.5 . . ?
H29A C29 H29B 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C28 C30 H30A 109.5 . . ?
C28 C30 H30B 109.5 . . ?
C28 C30 H30C 109.5 . . ?
H30A C30 H30B 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C32 C31 H31 105.4 . . ?
C32 C31 C33 110.9(17) . . ?
C32 C31 Si3 113.2(15) . . ?
C33 C31 H31 105.4 . . ?
C33 C31 Si3 115.4(13) . . ?
Si3 C31 H31 105.4 . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32B 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C31 C33 H33A 109.5 . . ?
C31 C33 H33B 109.5 . . ?
C31 C33 H33C 109.5 . . ?
H33A C33 H33B 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
Ag6 C34 Ag1 84.3(5) . 2_775 ?
Ag6 C34 Ag7 85.0(5) . . ?
Ag7 C34 Ag1 134.9(7) . 2_775 ?
C35 C34 Ag1 106.4(10) . 2_775 ?
C35 C34 Ag6 166.3(13) . . ?
C35 C34 Ag7 92.8(10) . . ?
C34 C35 Si4 174.7(13) . . ?
C37 C36 H36 107.5 . . ?
C37 C36 C38 111.7(14) . . ?
C37 C36 Si4 111.9(11) . . ?
C38 C36 H36 107.5 . . ?
C38 C36 Si4 110.4(11) . . ?
Si4 C36 H36 107.5 . . ?
C36 C37 H37A 109.5 . . ?
C36 C37 H37B 109.5 . . ?
C36 C37 H37C 109.5 . . ?
H37A C37 H37B 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
C36 C38 H38A 109.5 . . ?
C36 C38 H38B 109.5 . . ?
C36 C38 H38C 109.5 . . ?
H38A C38 H38B 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C40 C39 H39 105.3 . . ?
C40 C39 C41 113.3(14) . . ?
C40 C39 Si4 115.0(11) . . ?
C41 C39 H39 105.3 . . ?
C41 C39 Si4 111.6(11) . . ?
Si4 C39 H39 105.3 . . ?
C39 C40 H40A 109.5 . . ?
C39 C40 H40B 109.5 . . ?
C39 C40 H40C 109.5 . . ?
H40A C40 H40B 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
C39 C41 H41A 109.5 . . ?
C39 C41 H41B 109.5 . . ?
C39 C41 H41C 109.5 . . ?
H41A C41 H41B 109.5 . . ?
H41A C41 H41C 109.5 . . ?
H41B C41 H41C 109.5 . . ?
C43 C42 H42 106.8 . . ?
C43 C42 C44 111.5(13) . . ?
C43 C42 Si4 113.3(11) . . ?
C44 C42 H42 106.8 . . ?
C44 C42 Si4 111.3(11) . . ?
Si4 C42 H42 106.8 . . ?
C42 C43 H43A 109.5 . . ?
C42 C43 H43B 109.5 . . ?
C42 C43 H43C 109.5 . . ?
H43A C43 H43B 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
C42 C44 H44A 109.5 . . ?
C42 C44 H44B 109.5 . . ?
C42 C44 H44C 109.5 . . ?
H44A C44 H44B 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
O5 C45 C46 118.4(13) . . ?
O6 C45 C46 117.6(14) . . ?
O6 C45 O5 123.9(14) . . ?
C47 C46 C45 117.7(15) . . ?
N1 C46 C45 119.9(13) . . ?
N1 C46 C47 122.3(15) . . ?
C46 C47 H47 119.7 . . ?
C46 C47 C48 120.5(18) . . ?
C48 C47 H47 119.7 . . ?
C47 C48 C49 123(2) . . ?
C47 C48 C50 116.4(18) . . ?
C50 C48 C49 121(2) . . ?
C48 C49 H49A 109.5 . . ?
C48 C49 H49B 109.5 . . ?
C48 C49 H49C 109.5 . . ?
H49A C49 H49B 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
C48 C50 H50 119.7 . . ?
C51 C50 C48 120.7(17) . . ?
C51 C50 H50 119.7 . . ?
C50 C51 H51 119.2 . . ?
N1 C51 C50 121.7(16) . . ?
N1 C51 H51 119.2 . . ?
O7 C52 C53 115.6(13) . . ?
O8 C52 C53 119.6(13) . . ?
O8 C52 O7 124.8(13) . . ?
C54 C53 C52 118.8(14) . . ?
N2 C53 C52 118.8(13) . . ?
N2 C53 C54 122.4(14) . . ?
C53 C54 H54 120.0 . . ?
C55 C54 C53 120.0(18) . . ?
C55 C54 H54 120.0 . . ?
C54 C55 C56 121(2) . . ?
C57 C55 C54 118.3(18) . . ?
C57 C55 C56 120.8(18) . . ?
C55 C56 H56A 109.5 . . ?
C55 C56 H56B 109.5 . . ?
C55 C56 H56C 109.5 . . ?
H56A C56 H56B 109.5 . . ?
H56A C56 H56C 109.5 . . ?
H56B C56 H56C 109.5 . . ?
C55 C57 H57 120.6 . . ?
C55 C57 C58 118.8(16) . . ?
C58 C57 H57 120.6 . . ?
C57 C58 H58 118.1 . . ?
N2 C58 C57 123.8(17) . . ?
N2 C58 H58 118.1 . . ?
Ag9 C59 Ag10 84.7(4) . 2_676 ?
Ag9 C59 Ag13 82.6(4) . . ?
Ag9 C59 Ag14 83.1(4) . 2_676 ?
Ag10 C59 Ag14 120.4(4) 2_676 2_676 ?
Ag13 C59 Ag10 115.6(5) . 2_676 ?
Ag13 C59 Ag14 120.1(5) . 2_676 ?
C60 C59 Ag9 162.1(10) . . ?
C60 C59 Ag10 108.4(9) . 2_676 ?
C60 C59 Ag13 80.8(7) . . ?
C60 C59 Ag14 99.7(9) . 2_676 ?
C59 C60 Ag13 69.0(7) . . ?
C59 C60 Si5 173.7(11) . . ?
Si5 C60 Ag13 116.4(6) . . ?
C62 C61 H61 105.4 . . ?
C62 C61 Si5 110.9(13) . . ?
C63 C61 H61 105.4 . . ?
C63 C61 C62 110.2(18) . . ?
C63 C61 Si5 118.5(14) . . ?
Si5 C61 H61 105.4 . . ?
C61 C62 H62A 109.5 . . ?
C61 C62 H62B 109.5 . . ?
C61 C62 H62C 109.5 . . ?
H62A C62 H62B 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?
C61 C63 H63A 109.5 . . ?
C61 C63 H63B 109.5 . . ?
C61 C63 H63C 109.5 . . ?
H63A C63 H63B 109.5 . . ?
H63A C63 H63C 109.5 . . ?
H63B C63 H63C 109.5 . . ?
C65 C64 H64 106.7 . . ?
C65 C64 Si5 111.8(10) . . ?
C66 C64 H64 106.7 . . ?
C66 C64 C65 112.3(15) . . ?
C66 C64 Si5 112.2(11) . . ?
Si5 C64 H64 106.7 . . ?
C64 C65 H65A 109.5 . . ?
C64 C65 H65B 109.5 . . ?
C64 C65 H65C 109.5 . . ?
H65A C65 H65B 109.5 . . ?
H65A C65 H65C 109.5 . . ?
H65B C65 H65C 109.5 . . ?
C64 C66 H66A 109.5 . . ?
C64 C66 H66B 109.5 . . ?
C64 C66 H66C 109.5 . . ?
H66A C66 H66B 109.5 . . ?
H66A C66 H66C 109.5 . . ?
H66B C66 H66C 109.5 . . ?
C68 C67 H67 104.2 . . ?
C68 C67 C69 109.8(16) . . ?
C68 C67 Si5 115.8(14) . . ?
C69 C67 H67 104.2 . . ?
C69 C67 Si5 116.9(13) . . ?
Si5 C67 H67 104.2 . . ?
C67 C68 H68A 109.5 . . ?
C67 C68 H68B 109.5 . . ?
C67 C68 H68C 109.5 . . ?
H68A C68 H68B 109.5 . . ?
H68A C68 H68C 109.5 . . ?
H68B C68 H68C 109.5 . . ?
C67 C69 H69A 109.5 . . ?
C67 C69 H69B 109.5 . . ?
C67 C69 H69C 109.5 . . ?
H69A C69 H69B 109.5 . . ?
H69A C69 H69C 109.5 . . ?
H69B C69 H69C 109.5 . . ?
Ag8 C70 Ag11 122.1(6) 2_676 . ?
Ag13 C70 Ag8 87.5(5) . 2_676 ?
Ag13 C70 Ag11 87.0(5) . . ?
C71 C70 Ag8 101.5(10) . 2_676 ?
C71 C70 Ag11 91.3(10) . . ?
C71 C70 Ag13 170.3(12) . . ?
C70 C71 Ag11 61.8(9) . . ?
C70 C71 Si6 172.4(12) . . ?
Si6 C71 Ag11 123.3(6) . . ?
C73 C72 H72 107.8 . . ?
C73 C72 Si6 108.8(12) . . ?
C74 C72 H72 107.8 . . ?
C74 C72 C73 111.6(16) . . ?
C74 C72 Si6 112.8(13) . . ?
Si6 C72 H72 107.8 . . ?
C72 C73 H73A 109.5 . . ?
C72 C73 H73B 109.5 . . ?
C72 C73 H73C 109.5 . . ?
H73A C73 H73B 109.5 . . ?
H73A C73 H73C 109.5 . . ?
H73B C73 H73C 109.5 . . ?
C72 C74 H74A 109.5 . . ?
C72 C74 H74B 109.5 . . ?
C72 C74 H74C 109.5 . . ?
H74A C74 H74B 109.5 . . ?
H74A C74 H74C 109.5 . . ?
H74B C74 H74C 109.5 . . ?
C76 C75 H75 105.8 . . ?
C76 C75 Si6 113.6(12) . . ?
C77 C75 H75 105.8 . . ?
C77 C75 C76 110.5(14) . . ?
C77 C75 Si6 114.3(10) . . ?
Si6 C75 H75 105.8 . . ?
C75 C76 H76A 109.5 . . ?
C75 C76 H76B 109.5 . . ?
C75 C76 H76C 109.5 . . ?
H76A C76 H76B 109.5 . . ?
H76A C76 H76C 109.5 . . ?
H76B C76 H76C 109.5 . . ?
C75 C77 H77A 109.5 . . ?
C75 C77 H77B 109.5 . . ?
C75 C77 H77C 109.5 . . ?
H77A C77 H77B 109.5 . . ?
H77A C77 H77C 109.5 . . ?
H77B C77 H77C 109.5 . . ?
C79 C78 H78 105.1 . . ?
C79 C78 Si6 116.2(11) . . ?
C80 C78 H78 105.1 . . ?
C80 C78 C79 110.6(15) . . ?
C80 C78 Si6 113.6(13) . . ?
Si6 C78 H78 105.1 . . ?
C78 C79 H79A 109.5 . . ?
C78 C79 H79B 109.5 . . ?
C78 C79 H79C 109.5 . . ?
H79A C79 H79B 109.5 . . ?
H79A C79 H79C 109.5 . . ?
H79B C79 H79C 109.5 . . ?
C78 C80 H80A 109.5 . . ?
C78 C80 H80B 109.5 . . ?
C78 C80 H80C 109.5 . . ?
H80A C80 H80B 109.5 . . ?
H80A C80 H80C 109.5 . . ?
H80B C80 H80C 109.5 . . ?
Ag12 C81 Ag8 93.8(5) . 2_676 ?
Ag12 C81 Ag14 93.2(5) . . ?
Ag14 C81 Ag8 91.0(4) . 2_676 ?
C82 C81 Ag8 86.7(9) . 2_676 ?
C82 C81 Ag12 179.4(12) . . ?
C82 C81 Ag14 86.9(9) . . ?
Ag14 C82 Ag8 80.4(3) . 2_676 ?
C81 C82 Ag8 64.8(8) . 2_676 ?
C81 C82 Ag14 64.4(8) . . ?
C81 C82 Si7 163.4(11) . . ?
Si7 C82 Ag8 124.2(7) . 2_676 ?
Si7 C82 Ag14 128.2(6) . . ?
C84 C83 H83 105.4 . . ?
C84 C83 C85 110.8(13) . . ?
C84 C83 Si7 117.6(11) . . ?
C85 C83 H83 105.4 . . ?
C85 C83 Si7 111.1(10) . . ?
Si7 C83 H83 105.4 . . ?
C83 C84 H84A 109.5 . . ?
C83 C84 H84B 109.5 . . ?
C83 C84 H84C 109.5 . . ?
H84A C84 H84B 109.5 . . ?
H84A C84 H84C 109.5 . . ?
H84B C84 H84C 109.5 . . ?
C83 C85 H85A 109.5 . . ?
C83 C85 H85B 109.5 . . ?
C83 C85 H85C 109.5 . . ?
H85A C85 H85B 109.5 . . ?
H85A C85 H85C 109.5 . . ?
H85B C85 H85C 109.5 . . ?
C87 C86 H86 105.9 . . ?
C87 C86 C88 110.8(13) . . ?
C87 C86 Si7 114.2(11) . . ?
C88 C86 H86 105.9 . . ?
C88 C86 Si7 113.2(12) . . ?
Si7 C86 H86 105.9 . . ?
C86 C87 H87A 109.5 . . ?
C86 C87 H87B 109.5 . . ?
C86 C87 H87C 109.5 . . ?
H87A C87 H87B 109.5 . . ?
H87A C87 H87C 109.5 . . ?
H87B C87 H87C 109.5 . . ?
C86 C88 H88A 109.5 . . ?
C86 C88 H88B 109.5 . . ?
C86 C88 H88C 109.5 . . ?
H88A C88 H88B 109.5 . . ?
H88A C88 H88C 109.5 . . ?
H88B C88 H88C 109.5 . . ?
C90 C89 H89 106.5 . . ?
C90 C89 Si7 110.9(10) . . ?
C91 C89 H89 106.5 . . ?
C91 C89 C90 112.7(13) . . ?
C91 C89 Si7 113.1(10) . . ?
Si7 C89 H89 106.5 . . ?
C89 C90 H90A 109.5 . . ?
C89 C90 H90B 109.5 . . ?
C89 C90 H90C 109.5 . . ?
H90A C90 H90B 109.5 . . ?
H90A C90 H90C 109.5 . . ?
H90B C90 H90C 109.5 . . ?
C89 C91 H91A 109.5 . . ?
C89 C91 H91B 109.5 . . ?
C89 C91 H91C 109.5 . . ?
H91A C91 H91B 109.5 . . ?
H91A C91 H91C 109.5 . . ?
H91B C91 H91C 109.5 . . ?
O9 C92 C93 117.6(12) . . ?
O10 C92 C93 115.8(13) . . ?
O10 C92 O9 126.4(14) . . ?
C94 C93 C92 118.7(12) . . ?
N3 C93 C92 120.0(12) . . ?
N3 C93 C94 121.3(12) . . ?
C93 C94 H94 120.2 . . ?
C95 C94 C93 119.7(14) . . ?
C95 C94 H94 120.2 . . ?
C94 C95 C96 121.6(15) . . ?
C97 C95 C94 117.5(15) . . ?
C97 C95 C96 120.9(15) . . ?
C95 C96 H96A 109.5 . . ?
C95 C96 H96B 109.5 . . ?
C95 C96 H96C 109.5 . . ?
H96A C96 H96B 109.5 . . ?
H96A C96 H96C 109.5 . . ?
H96B C96 H96C 109.5 . . ?
C95 C97 H97 120.2 . . ?
C98 C97 C95 119.5(15) . . ?
C98 C97 H97 120.2 . . ?
C97 C98 H98 118.2 . . ?
N3 C98 C97 123.6(14) . . ?
N3 C98 H98 118.2 . . ?
O11 C99 C100 115.6(12) . . ?
O11 C99 O12 126.0(13) . . ?
O12 C99 C100 118.5(12) . . ?
C101 C100 C99 120.1(12) . . ?
N4 C100 C99 117.5(12) . . ?
N4 C100 C101 122.4(13) . . ?
C100 C101 H101 119.6 . . ?
C100 C101 C102 120.7(13) . . ?
C102 C101 H101 119.6 . . ?
C101 C102 C103 121.9(14) . . ?
C104 C102 C101 117.2(13) . . ?
C104 C102 C103 120.9(13) . . ?
C102 C103 H10G 109.5 . . ?
C102 C103 H10H 109.5 . . ?
C102 C103 H10I 109.5 . . ?
H10G C103 H10H 109.5 . . ?
H10G C103 H10I 109.5 . . ?
H10H C103 H10I 109.5 . . ?
C102 C104 H104 120.3 . . ?
C102 C104 C105 119.4(13) . . ?
C105 C104 H104 120.3 . . ?
C104 C105 H105 118.9 . . ?
N4 C105 C104 122.1(13) . . ?
N4 C105 H105 118.9 . . ?
C15 C106 H106 107.6 . . ?
C15 C106 Si2 109.7(11) . . ?
C16 C106 C15 109.0(12) . . ?
C16 C106 H106 107.6 . . ?
C16 C106 Si2 115.1(11) . . ?
Si2 C106 H106 107.6 . . ?
C3 C107 H10D 109.5 . . ?
C3 C107 H10E 109.5 . . ?
C3 C107 H10F 109.5 . . ?
H10D C107 H10E 109.5 . . ?
H10D C107 H10F 109.5 . . ?
H10E C107 H10F 109.5 . . ?
Ag10 C108 Ag11 94.5(4) . . ?
Ag12 C108 Ag10 88.7(4) . . ?
Ag12 C108 Ag11 82.0(4) . . ?
C109 C108 Ag10 84.0(9) . . ?
C109 C108 Ag11 107.8(9) . . ?
C109 C108 Ag12 168.2(11) . . ?
C108 C109 Ag10 67.0(8) . . ?
C108 C109 Si8 170.8(11) . . ?
Si8 C109 Ag10 122.0(6) . . ?
C111 C110 H110 106.1 . . ?
C111 C110 C112 111.3(13) . . ?
C111 C110 Si8 112.6(11) . . ?
C112 C110 H110 106.1 . . ?
C112 C110 Si8 113.9(11) . . ?
Si8 C110 H110 106.1 . . ?
C110 C111 H11D 109.5 . . ?
C110 C111 H11E 109.5 . . ?
C110 C111 H11F 109.5 . . ?
H11D C111 H11E 109.5 . . ?
H11D C111 H11F 109.5 . . ?
H11E C111 H11F 109.5 . . ?
C110 C112 H11G 109.5 . . ?
C110 C112 H11H 109.5 . . ?
C110 C112 H11I 109.5 . . ?
H11G C112 H11H 109.5 . . ?
H11G C112 H11I 109.5 . . ?
H11H C112 H11I 109.5 . . ?
C114 C113 H113 106.8 . . ?
C114 C113 Si8 112.3(10) . . ?
C115 C113 H113 106.8 . . ?
C115 C113 C114 110.6(12) . . ?
C115 C113 Si8 113.0(10) . . ?
Si8 C113 H113 106.8 . . ?
C113 C114 H11J 109.5 . . ?
C113 C114 H11K 109.5 . . ?
C113 C114 H11L 109.5 . . ?
H11J C114 H11K 109.5 . . ?
H11J C114 H11L 109.5 . . ?
H11K C114 H11L 109.5 . . ?
C113 C115 H11M 109.5 . . ?
C113 C115 H11N 109.5 . . ?
C113 C115 H11O 109.5 . . ?
H11M C115 H11N 109.5 . . ?
H11M C115 H11O 109.5 . . ?
H11N C115 H11O 109.5 . . ?
C117 C116 H116 106.4 . . ?
C117 C116 C118 113.4(16) . . ?
C117 C116 Si8 112.7(13) . . ?
C118 C116 H116 106.4 . . ?
C118 C116 Si8 110.9(12) . . ?
Si8 C116 H116 106.4 . . ?
C116 C117 H11P 109.5 . . ?
C116 C117 H11Q 109.5 . . ?
C116 C117 H11R 109.5 . . ?
H11P C117 H11Q 109.5 . . ?
H11P C117 H11R 109.5 . . ?
H11Q C117 H11R 109.5 . . ?
C116 C118 H11S 109.5 . . ?
C116 C118 H11T 109.5 . . ?
C116 C118 H11U 109.5 . . ?
H11S C118 H11T 109.5 . . ?
H11S C118 H11U 109.5 . . ?
H11T C118 H11U 109.5 . . ?
O1C Cl1C O2C 110.1(11) . . ?
O1C Cl1C O3C 108.1(15) . . ?
O3C Cl1C O2C 110.5(11) . . ?
O4C Cl1C O1C 111.6(16) . . ?
O4C Cl1C O2C 107.4(12) . . ?
O4C Cl1C O3C 109.2(13) . . ?
C46 N1 Ag7 117.4(9) . . ?
C46 N1 C51 118.4(13) . . ?
C51 N1 Ag7 124.2(10) . . ?
C53 N2 Ag1 115.8(9) . 2_775 ?
C53 N2 C58 116.5(14) . . ?
C58 N2 Ag1 127.3(12) . 2_775 ?
C93 N3 Ag8 116.5(9) . . ?
C93 N3 C98 118.4(12) . . ?
C98 N3 Ag8 125.1(10) . . ?
C100 N4 Ag11 117.9(9) . 2_676 ?
C100 N4 C105 118.1(12) . . ?
C105 N4 Ag11 123.9(9) . 2_676 ?
C45 O5 Ag7 113.7(9) . . ?
C45 O6 Ag3 115.5(11) . . ?
C52 O7 Ag5 116.2(10) . . ?
C52 O8 Ag1 113.8(8) . 2_775 ?
C92 O9 Ag8 113.8(9) . . ?
C92 O10 Ag10 107.3(10) . . ?
C99 O11 Ag14 111.9(9) . . ?
C99 O12 Ag11 114.5(8) . 2_676 ?
C2 Si1 C3 106.2(7) . . ?
C2 Si1 C9 109.1(7) . . ?
C3 Si1 C9 117.2(11) . . ?
C6 Si1 C2 105.9(7) . . ?
C6 Si1 C3 108.1(10) . . ?
C6 Si1 C9 109.7(11) . . ?
C13 Si2 C17 107.5(7) . . ?
C13 Si2 C20 104.7(6) . . ?
C13 Si2 C106 110.2(7) . . ?
C17 Si2 C20 110.4(7) . . ?
C17 Si2 C106 112.3(7) . . ?
C106 Si2 C20 111.3(7) . . ?
C24 Si3 C25 102.7(8) . . ?
C24 Si3 C28 109.7(8) . . ?
C24 Si3 C31 105.0(8) . . ?
C25 Si3 C28 113.0(9) . . ?
C25 Si3 C31 112.3(9) . . ?
C28 Si3 C31 113.2(8) . . ?
C35 Si4 C36 107.3(7) . . ?
C35 Si4 C39 107.6(7) . . ?
C35 Si4 C42 107.4(6) . . ?
C36 Si4 C39 111.0(7) . . ?
C42 Si4 C36 111.6(7) . . ?
C42 Si4 C39 111.6(7) . . ?
C60 Si5 C61 106.5(7) . . ?
C60 Si5 C64 106.0(6) . . ?
C61 Si5 C64 109.7(8) . . ?
C67 Si5 C60 106.5(7) . . ?
C67 Si5 C61 115.9(9) . . ?
C67 Si5 C64 111.5(7) . . ?
C71 Si6 C72 106.0(7) . . ?
C71 Si6 C75 108.2(7) . . ?
C71 Si6 C78 106.7(7) . . ?
C75 Si6 C72 110.7(8) . . ?
C75 Si6 C78 116.4(7) . . ?
C78 Si6 C72 108.3(8) . . ?
C82 Si7 C83 108.1(6) . . ?
C82 Si7 C86 107.9(7) . . ?
C82 Si7 C89 104.4(6) . . ?
C83 Si7 C86 116.2(7) . . ?
C83 Si7 C89 110.0(7) . . ?
C89 Si7 C86 109.5(7) . . ?
C109 Si8 C110 110.1(6) . . ?
C109 Si8 C113 106.4(6) . . ?
C109 Si8 C116 106.7(6) . . ?
C110 Si8 C113 110.1(7) . . ?
C116 Si8 C110 112.2(7) . . ?
C116 Si8 C113 111.0(8) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
