# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_database_code_depnum_ccdc_archive 'CCDC 1958763'
loop_
_audit_author_name
_audit_author_address
'Chao Chen'
;Huzhou University
China
;
_audit_update_record             
;
2019-10-11 deposited with the CCDC.	2020-01-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C164 H192 Ag12 F72 N64 P12'
_chemical_formula_weight         6093.90

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   C2/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   41.409(4)
_cell_length_b                   18.5246(18)
_cell_length_c                   37.892(4)
_cell_angle_alpha                90.00
_cell_angle_beta                 122.160(2)
_cell_angle_gamma                90.00
_cell_volume                     24607(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    21625
_cell_measurement_theta_min      1.27
_cell_measurement_theta_max      25.01

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.15
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.645
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             12064
_exptl_absorpt_coefficient_mu    1.122
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.738
_exptl_absorpt_correction_T_max  0.773
_exptl_absorpt_process_details   sadabs

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            61593
_diffrn_reflns_av_R_equivalents  0.0401
_diffrn_reflns_av_sigmaI/netI    0.0527
_diffrn_reflns_limit_h_min       -49
_diffrn_reflns_limit_h_max       33
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_l_min       -39
_diffrn_reflns_limit_l_max       45
_diffrn_reflns_theta_min         1.27
_diffrn_reflns_theta_max         25.01
_reflns_number_total             21625
_reflns_number_gt                15081
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.1114P)²+419.7131P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         21625
_refine_ls_number_parameters     1479
_refine_ls_number_restraints     104
_refine_ls_R_factor_all          0.1165
_refine_ls_R_factor_gt           0.0851
_refine_ls_wR_factor_ref         0.2415
_refine_ls_wR_factor_gt          0.2198
_refine_ls_goodness_of_fit_ref   1.096
_refine_ls_restrained_S_all      1.107
_refine_ls_shift/su_max          0.036
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.20256(2) 0.19092(4) 0.59738(2) 0.03460(18) Uani 1 1 d . . .
Ag2 Ag 0.047500(19) 0.18875(4) 0.44486(2) 0.03465(18) Uani 1 1 d . . .
Ag3 Ag 0.17109(2) -0.12511(4) 0.51568(2) 0.0437(2) Uani 1 1 d . . .
Ag4 Ag 0.02849(2) 0.32936(4) 0.40616(2) 0.0453(2) Uani 1 1 d . . .
Ag5 Ag 0.20264(3) 0.22973(5) 0.67281(3) 0.0607(3) Uani 1 1 d . . .
Ag6 Ag 0.13952(2) -0.05544(5) 0.43578(3) 0.0578(3) Uani 1 1 d . . .
C1 C 0.1015(3) -0.0167(5) 0.5218(3) 0.035(2) Uani 1 1 d . . .
C2 C 0.1376(3) -0.0177(5) 0.5583(3) 0.032(2) Uani 1 1 d . . .
H2 H 0.1538 -0.0572 0.5653 0.039 Uiso 1 1 calc R . .
C3 C 0.1482(3) 0.0421(5) 0.5834(3) 0.0308(19) Uani 1 1 d . . .
C4 C 0.1248(3) 0.0994(5) 0.5761(3) 0.0315(19) Uani 1 1 d . . .
H4 H 0.1327 0.1377 0.5947 0.038 Uiso 1 1 calc R . .
C5 C 0.0881(3) 0.0986(5) 0.5391(3) 0.035(2) Uani 1 1 d . . .
C6 C 0.0772(3) 0.0397(5) 0.5128(3) 0.037(2) Uani 1 1 d . . .
H6 H 0.0530 0.0385 0.4887 0.045 Uiso 1 1 calc R . .
C7 C 0.1116(3) -0.1204(5) 0.4877(3) 0.034(2) Uani 1 1 d . . .
C8 C 0.0513(3) -0.1005(5) 0.4700(3) 0.041(2) Uani 1 1 d . . .
H8 H 0.0305 -0.0804 0.4695 0.049 Uiso 1 1 calc R . .
C9 C 0.0506(3) -0.1561(5) 0.4479(3) 0.039(2) Uani 1 1 d . . .
H9 H 0.0290 -0.1817 0.4284 0.047 Uiso 1 1 calc R . .
C10 C 0.0985(3) -0.2260(6) 0.4410(4) 0.060(3) Uani 1 1 d . . .
H10A H 0.0839 -0.2690 0.4379 0.072 Uiso 1 1 calc R . .
H10B H 0.1253 -0.2373 0.4597 0.072 Uiso 1 1 calc R . .
C11 C 0.0918(3) -0.2057(7) 0.4002(4) 0.071(4) Uani 1 1 d DU . .
C12 C 0.0664(4) -0.2332(10) 0.3604(4) 0.105(5) Uani 1 1 d DU . .
H12 H 0.0528 -0.2759 0.3550 0.126 Uiso 1 1 calc R . .
C13 C 0.0642(6) -0.1874(12) 0.3299(7) 0.191(10) Uani 1 1 d DU . .
C14 C 0.0378(8) -0.1761(19) 0.2832(7) 0.217(12) Uani 1 1 d DU . .
H14A H 0.0275 -0.1280 0.2779 0.326 Uiso 1 1 calc R . .
H14B H 0.0173 -0.2104 0.2723 0.326 Uiso 0.50 1 calc PR . .
H14C H 0.0518 -0.1826 0.2698 0.326 Uiso 1 1 calc R . .
C15 C 0.0952(10) -0.0752(14) 0.3342(11) 0.230(13) Uani 1 1 d DU . .
H15A H 0.0933 -0.0873 0.3084 0.345 Uiso 1 1 calc R . .
H15B H 0.1192 -0.0516 0.3524 0.345 Uiso 1 1 calc R . .
H15C H 0.0747 -0.0434 0.3286 0.345 Uiso 1 1 calc R . .
C16 C 0.0453(2) 0.1959(5) 0.4979(3) 0.0306(19) Uani 1 1 d . . .
C17 C 0.0537(3) 0.1764(5) 0.5616(3) 0.044(2) Uani 1 1 d . . .
H17 H 0.0626 0.1559 0.5876 0.052 Uiso 1 1 calc R . .
C18 C 0.0299(3) 0.2305(5) 0.5446(3) 0.042(2) Uani 1 1 d . . .
H18 H 0.0190 0.2567 0.5567 0.050 Uiso 1 1 calc R . .
C19 C 0.0008(3) 0.2995(5) 0.4772(3) 0.040(2) Uani 1 1 d . . .
H19A H -0.0200 0.3103 0.4812 0.048 Uiso 1 1 calc R . .
H19B H -0.0102 0.2838 0.4486 0.048 Uiso 1 1 calc R . .
C20 C 0.0245(2) 0.3679(5) 0.4849(3) 0.0323(19) Uani 1 1 d . . .
C21 C 0.0319(3) 0.4225(5) 0.5131(3) 0.039(2) Uani 1 1 d . . .
H21 H 0.0229 0.4259 0.5309 0.047 Uiso 1 1 calc R . .
C22 C 0.0546(3) 0.4698(5) 0.5096(3) 0.042(2) Uani 1 1 d . . .
C23 C 0.0708(3) 0.5410(6) 0.5295(4) 0.055(3) Uani 1 1 d . . .
H23A H 0.0602 0.5553 0.5456 0.083 Uiso 1 1 calc R . .
H23B H 0.0646 0.5764 0.5083 0.083 Uiso 1 1 calc R . .
H23C H 0.0980 0.5371 0.5475 0.083 Uiso 1 1 calc R . .
C24 C 0.0842(3) 0.4703(6) 0.4659(3) 0.049(3) Uani 1 1 d . . .
H24A H 0.1080 0.4447 0.4795 0.073 Uiso 1 1 calc R . .
H24B H 0.0889 0.5207 0.4725 0.073 Uiso 1 1 calc R . .
H24C H 0.0716 0.4640 0.4363 0.073 Uiso 1 1 calc R . .
C25 C 0.2107(2) 0.0987(5) 0.6322(3) 0.0308(19) Uani 1 1 d . . .
C26 C 0.2034(3) -0.0161(5) 0.6464(3) 0.037(2) Uani 1 1 d . . .
H26 H 0.1924 -0.0610 0.6443 0.044 Uiso 1 1 calc R . .
C27 C 0.2390(3) 0.0041(5) 0.6754(3) 0.042(2) Uani 1 1 d . . .
H27 H 0.2573 -0.0239 0.6974 0.051 Uiso 1 1 calc R . .
C28 C 0.2772(3) 0.1176(6) 0.6917(3) 0.040(2) Uani 1 1 d . . .
H28A H 0.2762 0.1593 0.6756 0.049 Uiso 1 1 calc R . .
H28B H 0.2998 0.0899 0.6989 0.049 Uiso 1 1 calc R . .
C29 C 0.2795(3) 0.1418(5) 0.7303(3) 0.038(2) Uani 1 1 d . . .
C30 C 0.3026(3) 0.1177(6) 0.7715(3) 0.048(2) Uani 1 1 d . . .
H30 H 0.3219 0.0833 0.7814 0.057 Uiso 1 1 calc R . .
C31 C 0.2914(3) 0.1540(6) 0.7943(3) 0.047(2) Uani 1 1 d . . .
C32 C 0.3047(4) 0.1509(8) 0.8400(4) 0.069(4) Uani 1 1 d . . .
H32A H 0.3125 0.1981 0.8520 0.104 Uiso 1 1 calc R . .
H32B H 0.3259 0.1181 0.8542 0.104 Uiso 1 1 calc R . .
H32C H 0.2842 0.1343 0.8428 0.104 Uiso 1 1 calc R . .
C33 C 0.2436(5) 0.2535(9) 0.7776(4) 0.096(6) Uani 1 1 d . . .
H33A H 0.2357 0.2931 0.7584 0.144 Uiso 1 1 calc R . .
H33B H 0.2602 0.2708 0.8055 0.144 Uiso 1 1 calc R . .
H33C H 0.2216 0.2312 0.7752 0.144 Uiso 1 1 calc R . .
C34 C 0.1314(3) 0.2355(5) 0.4564(3) 0.037(2) Uani 1 1 d . . .
H34 H 0.1153 0.2743 0.4517 0.044 Uiso 1 1 calc R . .
C35 C 0.1203(3) 0.1810(5) 0.4284(3) 0.037(2) Uani 1 1 d . . .
C36 C 0.1437(3) 0.1228(5) 0.4340(3) 0.036(2) Uani 1 1 d . . .
H36 H 0.1358 0.0865 0.4141 0.043 Uiso 1 1 calc R . .
C37 C 0.1795(2) 0.1208(5) 0.4706(3) 0.0306(19) Uani 1 1 d . . .
C38 C 0.1913(3) 0.1750(5) 0.5004(3) 0.036(2) Uani 1 1 d . . .
H38 H 0.2149 0.1731 0.5252 0.043 Uiso 1 1 calc R . .
C39 C 0.1666(3) 0.2315(5) 0.4917(3) 0.033(2) Uani 1 1 d . . .
C40 C 0.1937(3) -0.0066(5) 0.4673(3) 0.038(2) Uani 1 1 d . . .
C41 C 0.2435(3) 0.0697(6) 0.4966(3) 0.045(2) Uani 1 1 d . . .
H41 H 0.2577 0.1119 0.5068 0.053 Uiso 1 1 calc R . .
C42 C 0.2569(3) 0.0045(5) 0.4977(3) 0.045(2) Uani 1 1 d . . .
H42 H 0.2824 -0.0076 0.5086 0.054 Uiso 1 1 calc R . .
C43 C 0.2308(3) -0.1205(5) 0.4779(3) 0.048(3) Uani 1 1 d . . .
H43A H 0.2470 -0.1301 0.4671 0.058 Uiso 1 1 calc R . .
H43B H 0.2060 -0.1420 0.4589 0.058 Uiso 1 1 calc R . .
C44 C 0.2476(3) -0.1545(5) 0.5193(3) 0.038(2) Uani 1 1 d . . .
C45 C 0.2839(3) -0.1835(5) 0.5442(3) 0.039(2) Uani 1 1 d . . .
H45 H 0.3028 -0.1870 0.5381 0.047 Uiso 1 1 calc R . .
C46 C 0.2858(3) -0.2060(5) 0.5797(3) 0.045(2) Uani 1 1 d . . .
C47 C 0.3164(4) -0.2399(7) 0.6180(4) 0.065(3) Uani 1 1 d . . .
H47A H 0.3253 -0.2068 0.6409 0.097 Uiso 1 1 calc R . .
H47B H 0.3371 -0.2524 0.6147 0.097 Uiso 1 1 calc R . .
H47C H 0.3068 -0.2827 0.6236 0.097 Uiso 1 1 calc R . .
C48 C 0.2397(4) -0.2031(7) 0.6042(4) 0.066(4) Uani 1 1 d . . .
H48A H 0.2300 -0.1590 0.6084 0.099 Uiso 1 1 calc R . .
H48B H 0.2610 -0.2195 0.6304 0.099 Uiso 1 1 calc R . .
H48C H 0.2200 -0.2392 0.5930 0.099 Uiso 1 1 calc R . .
C49 C 0.1939(3) 0.2833(5) 0.5625(3) 0.038(2) Uani 1 1 d . . .
C50 C 0.1773(3) 0.3627(5) 0.5097(4) 0.041(2) Uani 1 1 d . . .
H50 H 0.1687 0.3808 0.4833 0.049 Uiso 1 1 calc R . .
C51 C 0.1909(3) 0.3998(5) 0.5451(4) 0.048(3) Uani 1 1 d . . .
H51 H 0.1931 0.4498 0.5478 0.058 Uiso 1 1 calc R . .
C52 C 0.2156(3) 0.3716(6) 0.6204(3) 0.052(3) Uani 1 1 d . . .
H52A H 0.2302 0.4160 0.6270 0.063 Uiso 1 1 calc R . .
H52B H 0.2328 0.3340 0.6384 0.063 Uiso 1 1 calc R . .
C53 C 0.1844(3) 0.3816(5) 0.6291(3) 0.041(2) Uani 1 1 d . . .
C54 C 0.1637(3) 0.4441(6) 0.6227(4) 0.052(3) Uani 1 1 d . . .
H54 H 0.1663 0.4883 0.6129 0.062 Uiso 1 1 calc R . .
C55 C 0.1384(3) 0.4259(6) 0.6342(3) 0.045(2) Uani 1 1 d . . .
C56 C 0.1095(3) 0.4703(6) 0.6363(4) 0.060(3) Uani 1 1 d . . .
H56A H 0.0846 0.4500 0.6182 0.090 Uiso 1 1 calc R . .
H56B H 0.1100 0.5188 0.6276 0.090 Uiso 1 1 calc R . .
H56C H 0.1152 0.4708 0.6644 0.090 Uiso 1 1 calc R . .
C57 C 0.1237(3) 0.3109(7) 0.6576(4) 0.060(3) Uani 1 1 d . . .
H57A H 0.1063 0.3398 0.6611 0.090 Uiso 1 1 calc R . .
H57B H 0.1413 0.2873 0.6834 0.090 Uiso 1 1 calc R . .
H57C H 0.1096 0.2754 0.6363 0.090 Uiso 1 1 calc R . .
C58 C 0.0505(3) 0.1862(5) 0.3919(3) 0.036(2) Uani 1 1 d . . .
C59 C 0.0744(3) 0.1702(6) 0.3512(3) 0.048(3) Uani 1 1 d . . .
H59 H 0.0918 0.1649 0.3429 0.058 Uiso 1 1 calc R . .
C60 C 0.0365(3) 0.1682(6) 0.3265(3) 0.051(3) Uani 1 1 d . . .
H60 H 0.0223 0.1613 0.2978 0.061 Uiso 1 1 calc R . .
C61 C -0.0184(3) 0.1785(6) 0.3369(3) 0.045(2) Uani 1 1 d . . .
H61A H -0.0214 0.1645 0.3596 0.054 Uiso 1 1 calc R . .
H61B H -0.0313 0.1428 0.3150 0.054 Uiso 1 1 calc R . .
C62 C -0.0367(2) 0.2496(5) 0.3207(3) 0.035(2) Uani 1 1 d . . .
C63 C -0.0696(3) 0.2659(6) 0.2824(3) 0.049(3) Uani 1 1 d . . .
H63 H -0.0837 0.2346 0.2601 0.059 Uiso 1 1 calc R . .
C64 C -0.0768(3) 0.3383(6) 0.2843(3) 0.047(3) Uani 1 1 d . . .
C65 C -0.1090(3) 0.3855(8) 0.2531(4) 0.066(4) Uani 1 1 d . . .
H65A H -0.1224 0.4048 0.2652 0.099 Uiso 1 1 calc R . .
H65B H -0.1263 0.3575 0.2289 0.099 Uiso 1 1 calc R . .
H65C H -0.0989 0.4245 0.2451 0.099 Uiso 1 1 calc R . .
C66 C -0.0434(4) 0.4337(7) 0.3400(4) 0.073(4) Uani 1 1 d . . .
H66A H -0.0233 0.4574 0.3389 0.110 Uiso 1 1 calc R . .
H66B H -0.0364 0.4297 0.3684 0.110 Uiso 1 1 calc R . .
H66C H -0.0664 0.4614 0.3245 0.110 Uiso 1 1 calc R . .
C67 C 0.0424(4) -0.0131(6) 0.3839(5) 0.071(4) Uani 1 1 d . . .
C68 C 0.0029(4) -0.0268(10) 0.3547(6) 0.111(7) Uani 1 1 d . . .
H68A H -0.0005 -0.0450 0.3292 0.167 Uiso 1 1 calc R . .
H68B H -0.0113 0.0172 0.3491 0.167 Uiso 1 1 calc R . .
H68C H -0.0062 -0.0619 0.3661 0.167 Uiso 1 1 calc R . .
C69 C 0.1503(4) 0.0928(8) 0.6834(4) 0.066(3) Uani 1 1 d . . .
C70 C 0.1305(5) 0.0321(10) 0.6835(8) 0.161(11) Uani 1 1 d . . .
H70A H 0.1118 0.0462 0.6898 0.242 Uiso 1 1 calc R . .
H70B H 0.1481 -0.0014 0.7042 0.242 Uiso 1 1 calc R . .
H70C H 0.1180 0.0095 0.6566 0.242 Uiso 1 1 calc R . .
C71 C 0.0751(4) 0.3614(7) 0.3561(4) 0.069(4) Uani 1 1 d . . .
C72 C 0.0875(7) 0.3687(12) 0.3263(7) 0.147(10) Uani 1 1 d . . .
H72A H 0.0660 0.3621 0.2985 0.221 Uiso 1 1 calc R . .
H72B H 0.1064 0.3328 0.3322 0.221 Uiso 1 1 calc R . .
H72C H 0.0981 0.4159 0.3289 0.221 Uiso 1 1 calc R . .
C73 C 0.8907(5) 0.2819(12) 0.3471(6) 0.094(6) Uani 1 1 d . . .
C74 C 0.8719(5) 0.2171(9) 0.3209(6) 0.090(5) Uani 1 1 d . . .
H74A H 0.8906 0.1800 0.3281 0.135 Uiso 1 1 calc R . .
H74B H 0.8604 0.2295 0.2920 0.135 Uiso 1 1 calc R . .
H74C H 0.8527 0.2000 0.3257 0.135 Uiso 1 1 calc R . .
C75 C 0.2497(4) 0.9993(6) 0.5851(4) 0.055(3) Uani 1 1 d . . .
C76 C 0.2918(4) 1.0000(8) 0.6117(4) 0.076(4) Uani 1 1 d . . .
H76A H 0.2999 0.9697 0.6355 0.114 Uiso 1 1 calc R . .
H76B H 0.3005 1.0484 0.6207 0.114 Uiso 1 1 calc R . .
H76C H 0.3023 0.9823 0.5960 0.114 Uiso 1 1 calc R . .
C77 C 0.1320(4) 0.7935(6) 0.5836(5) 0.065(3) Uani 1 1 d . . .
C78 C 0.0973(3) 0.7609(6) 0.5538(4) 0.059(3) Uani 1 1 d . . .
H78A H 0.0921 0.7213 0.5664 0.089 Uiso 1 1 calc R . .
H78B H 0.0990 0.7433 0.5310 0.089 Uiso 1 1 calc R . .
H78C H 0.0771 0.7957 0.5436 0.089 Uiso 1 1 calc R . .
C79 C 0.0632(5) 0.2008(10) 0.6761(5) 0.082(5) Uani 1 1 d . . .
C80 C 0.0639(6) 0.2499(14) 0.7047(5) 0.135(9) Uani 1 1 d . . .
H80A H 0.0622 0.2982 0.6947 0.203 Uiso 1 1 calc R . .
H80B H 0.0873 0.2444 0.7312 0.203 Uiso 1 1 calc R . .
H80C H 0.0427 0.2407 0.7077 0.203 Uiso 1 1 calc R . .
C81 C 0.1294(6) 0.5300(11) 0.4091(6) 0.104(6) Uani 1 1 d D . .
C82 C 0.1092(11) 0.5945(19) 0.3859(13) 0.28(3) Uani 1 1 d D . .
H82A H 0.1264 0.6255 0.3833 0.420 Uiso 1 1 calc R . .
H82B H 0.0995 0.6196 0.4005 0.420 Uiso 1 1 calc R . .
H82C H 0.0884 0.5811 0.3587 0.420 Uiso 1 1 calc R . .
F1 F 0.04224(18) 0.1587(3) 0.0865(2) 0.0577(16) Uani 1 1 d . . .
F2 F 0.06368(16) 0.0697(3) 0.13406(19) 0.0540(15) Uani 1 1 d . . .
F3 F 0.0486(2) -0.0123(3) 0.0840(2) 0.0690(19) Uani 1 1 d . . .
F4 F 0.0265(2) 0.0767(4) 0.0360(2) 0.080(2) Uani 1 1 d . . .
F5 F 0.08691(19) 0.0812(4) 0.0926(3) 0.075(2) Uani 1 1 d . . .
F6 F 0.00406(15) 0.0652(3) 0.07767(19) 0.0512(15) Uani 1 1 d . . .
F7 F 0.1803(2) 0.6945(4) 0.5151(3) 0.077(2) Uani 1 1 d . . .
F8 F 0.1696(2) 0.6790(5) 0.5661(2) 0.082(2) Uani 1 1 d . . .
F9 F 0.1646(3) 0.5612(4) 0.5559(3) 0.099(3) Uani 1 1 d . . .
F10 F 0.1756(3) 0.5758(5) 0.5049(3) 0.112(3) Uani 1 1 d . . .
F11 F 0.2156(2) 0.6185(7) 0.5663(3) 0.126(4) Uani 1 1 d . . .
F12 F 0.12797(19) 0.6345(4) 0.5034(2) 0.0678(18) Uani 1 1 d . . .
F13 F 0.1599(3) 0.7830(11) 0.8721(4) 0.233(10) Uani 1 1 d . . .
F14 F 0.2187(3) 0.7787(8) 0.9285(3) 0.158(6) Uani 1 1 d . . .
F15 F 0.2266(2) 0.6681(6) 0.9076(3) 0.102(3) Uani 1 1 d . . .
F16 F 0.1707(2) 0.6791(6) 0.8494(3) 0.107(3) Uani 1 1 d . . .
F17 F 0.2133(3) 0.7699(6) 0.8664(3) 0.115(3) Uani 1 1 d . . .
F18 F 0.1772(3) 0.6896(8) 0.9103(4) 0.145(5) Uani 1 1 d . . .
F19 F 0.9934(2) 0.2945(4) 0.6147(3) 0.085(2) Uani 1 1 d . . .
F20 F 0.9527(3) 0.3887(5) 0.5909(4) 0.115(3) Uani 1 1 d . . .
F21 F 0.9954(2) 0.4537(4) 0.5846(3) 0.081(2) Uani 1 1 d . . .
F22 F 1.0328(2) 0.3572(5) 0.6042(3) 0.101(3) Uani 1 1 d . . .
F23 F 1.0176(4) 0.4013(5) 0.6466(3) 0.159(6) Uani 1 1 d . . .
F24 F 0.9724(2) 0.3460(5) 0.5538(3) 0.096(3) Uani 1 1 d . . .
F25 F 0.1788(3) 0.5953(8) 0.2457(3) 0.141(4) Uani 1 1 d . . .
F26 F 0.1976(3) 0.6197(6) 0.3124(3) 0.122(4) Uani 1 1 d . . .
F27 F 0.1377(3) 0.6153(8) 0.2941(3) 0.146(5) Uani 1 1 d . . .
F28 F 0.1178(2) 0.5855(5) 0.2299(2) 0.085(2) Uani 1 1 d . . .
F29 F 0.1653(3) 0.5223(5) 0.2820(3) 0.125(4) Uani 1 1 d . . .
F30 F 0.1535(4) 0.6844(6) 0.2594(4) 0.155(5) Uani 1 1 d . . .
F31 F 0.0985(5) 0.0436(18) 0.2900(9) 0.349(15) Uani 1 1 d DU . .
F32 F 0.0397(7) 0.0092(14) 0.2887(7) 0.138(8) Uani 0.50 1 d PDU . .
F33 F 0.0095(5) 0.0269(14) 0.2206(6) 0.266(10) Uani 1 1 d DU . .
F34 F 0.0689(7) 0.0401(15) 0.2264(7) 0.278(10) Uani 1 1 d DU . .
F35 F 0.0530(7) -0.0621(7) 0.2500(7) 0.247(9) Uani 1 1 d DU . .
F36 F 0.0498(5) 0.1085(6) 0.2583(4) 0.162(5) Uani 1 1 d DU . .
N1 N 0.0888(2) -0.0775(4) 0.4942(2) 0.0342(17) Uani 1 1 d . . .
N2 N 0.0879(2) -0.1693(4) 0.4592(3) 0.0403(19) Uani 1 1 d . . .
N3 N 0.1070(4) -0.1453(7) 0.3954(4) 0.088(4) Uani 1 1 d DU . .
N4 N 0.0930(6) -0.1410(13) 0.3540(4) 0.178(8) Uani 1 1 d DU . .
N5 N 0.0630(2) 0.1557(4) 0.5330(2) 0.0324(17) Uani 1 1 d . . .
N6 N 0.0239(2) 0.2414(4) 0.5053(3) 0.0383(18) Uani 1 1 d . . .
N7 N 0.0411(2) 0.3787(4) 0.4644(2) 0.0359(18) Uani 1 1 d . . .
N8 N 0.0601(2) 0.4422(4) 0.4799(2) 0.0398(19) Uani 1 1 d . . .
N9 N 0.1863(2) 0.0418(4) 0.6203(2) 0.0326(16) Uani 1 1 d . . .
N10 N 0.2433(2) 0.0733(4) 0.6666(2) 0.0361(17) Uani 1 1 d . . .
N11 N 0.2640(3) 0.2005(5) 0.7678(3) 0.048(2) Uani 1 1 d . . .
N12 N 0.2565(3) 0.1926(5) 0.7286(3) 0.049(2) Uani 1 1 d . . .
N13 N 0.2046(2) 0.0634(4) 0.4776(3) 0.0367(18) Uani 1 1 d . . .
N14 N 0.2263(2) -0.0421(4) 0.4795(2) 0.0351(17) Uani 1 1 d . . .
N15 N 0.2521(2) -0.1903(4) 0.5751(2) 0.0415(19) Uani 1 1 d . . .
N16 N 0.2284(2) -0.1587(5) 0.5380(3) 0.044(2) Uani 1 1 d . . .
N17 N 0.1790(2) 0.2899(4) 0.5215(2) 0.0380(18) Uani 1 1 d . . .
N18 N 0.2009(3) 0.3521(5) 0.5764(3) 0.048(2) Uani 1 1 d . . .
N19 N 0.1733(2) 0.3293(4) 0.6419(3) 0.043(2) Uani 1 1 d . . .
N20 N 0.1447(2) 0.3573(4) 0.6452(2) 0.0398(18) Uani 1 1 d . . .
N21 N 0.0830(2) 0.1815(4) 0.3913(2) 0.0371(18) Uani 1 1 d . . .
N22 N 0.0222(2) 0.1785(4) 0.3516(2) 0.0390(18) Uani 1 1 d . . .
N23 N -0.0246(2) 0.3085(5) 0.3448(3) 0.046(2) Uani 1 1 d . . .
N24 N -0.0495(2) 0.3619(5) 0.3218(3) 0.046(2) Uani 1 1 d . . .
N25 N 0.0742(3) -0.0030(7) 0.4069(5) 0.097(5) Uani 1 1 d . . .
N26 N 0.1652(4) 0.1403(7) 0.6815(3) 0.068(3) Uani 1 1 d . . .
N27 N 0.0665(3) 0.3571(5) 0.3792(3) 0.052(2) Uani 1 1 d . . .
N28 N 0.9059(5) 0.3302(8) 0.3708(6) 0.109(5) Uani 1 1 d . . .
N29 N 0.2183(3) 0.9968(7) 0.5651(4) 0.075(3) Uani 1 1 d . . .
N30 N 0.1607(4) 0.8220(6) 0.6090(4) 0.074(3) Uani 1 1 d . . .
N31 N 0.0620(5) 0.1644(8) 0.6529(5) 0.113(5) Uani 1 1 d . . .
N32 N 0.1446(5) 0.4776(9) 0.4248(5) 0.105(5) Uani 1 1 d . . .
P1 P 0.04575(8) 0.07287(15) 0.08503(9) 0.0449(6) Uani 1 1 d . . .
P2 P 0.17214(8) 0.62769(16) 0.53521(9) 0.0486(7) Uani 1 1 d . . .
P3 P 0.19397(12) 0.7306(4) 0.88863(14) 0.112(2) Uani 1 1 d . . .
P4 P 0.99442(8) 0.37460(16) 0.60165(10) 0.0537(7) Uani 1 1 d . . .
P5 P 0.15794(10) 0.6037(2) 0.27103(12) 0.0787(12) Uani 1 1 d . . .
P6 P 0.0540(4) 0.0231(5) 0.2576(4) 0.222(4) Uani 1 1 d DU . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C25 2.073(9) . ?
Ag1 C49 2.074(10) . ?
Ag1 Ag5 2.9452(11) . ?
Ag2 C16 2.063(8) . ?
Ag2 C58 2.074(9) . ?
Ag2 Ag4 2.8856(11) . ?
Ag3 C7 2.103(9) . ?
Ag3 N16 2.143(9) . ?
Ag3 Ag6 2.8858(12) . ?
Ag4 N7 2.179(8) . ?
Ag4 N23 2.225(8) . ?
Ag4 N27 2.347(9) . ?
Ag5 N19 2.176(9) . ?
Ag5 N12 2.213(9) . ?
Ag5 N26 2.408(13) . ?
Ag6 C40 2.102(10) . ?
Ag6 N3 2.175(11) . ?
Ag6 N25 2.511(11) . ?
C1 C6 1.361(14) . ?
C1 C2 1.396(13) . ?
C1 N1 1.433(11) . ?
C2 C3 1.372(12) . ?
C3 C4 1.360(13) . ?
C3 N9 1.447(11) . ?
C4 C5 1.417(13) . ?
C5 C6 1.381(13) . ?
C5 N5 1.413(12) . ?
C7 N2 1.350(11) . ?
C7 N1 1.352(11) . ?
C8 C9 1.317(13) . ?
C8 N1 1.386(11) . ?
C9 N2 1.389(12) . ?
C10 N2 1.446(13) . ?
C10 C11 1.469(17) . ?
C11 N3 1.343(9) . ?
C11 C12 1.395(9) . ?
C12 C13 1.398(10) . ?
C13 N4 1.354(10) . ?
C13 C14 1.521(10) . ?
C15 N4 1.462(10) . ?
C16 N5 1.350(12) . ?
C16 N6 1.358(11) . ?
C17 C18 1.311(15) . ?
C17 N5 1.383(11) . ?
C18 N6 1.389(13) . ?
C19 N6 1.455(13) . ?
C19 C20 1.535(12) . ?
C20 N7 1.297(11) . ?
C20 C21 1.383(13) . ?
C21 C22 1.342(13) . ?
C22 N8 1.360(12) . ?
C22 C23 1.490(14) . ?
C24 N8 1.455(12) . ?
C25 N9 1.362(11) . ?
C25 N10 1.366(12) . ?
C26 C27 1.341(14) . ?
C26 N9 1.373(12) . ?
C27 N10 1.359(12) . ?
C28 N10 1.458(12) . ?
C28 C29 1.483(13) . ?
C29 N12 1.315(12) . ?
C29 C30 1.403(14) . ?
C30 C31 1.354(15) . ?
C31 N11 1.352(14) . ?
C31 C32 1.515(15) . ?
C33 N11 1.462(14) . ?
C34 C39 1.357(13) . ?
C34 C35 1.357(13) . ?
C35 C36 1.388(13) . ?
C35 N21 1.430(12) . ?
C36 C37 1.391(13) . ?
C37 C38 1.391(13) . ?
C37 N13 1.408(11) . ?
C38 C39 1.375(13) . ?
C39 N17 1.445(12) . ?
C40 N14 1.344(12) . ?
C40 N13 1.362(12) . ?
C41 C42 1.322(14) . ?
C41 N13 1.375(12) . ?
C42 N14 1.379(13) . ?
C43 N14 1.469(12) . ?
C43 C44 1.478(15) . ?
C44 N16 1.321(12) . ?
C44 C45 1.387(14) . ?
C45 C46 1.368(14) . ?
C46 N15 1.345(13) . ?
C46 C47 1.465(15) . ?
C48 N15 1.463(13) . ?
C49 N17 1.339(12) . ?
C49 N18 1.349(12) . ?
C50 C51 1.335(15) . ?
C50 N17 1.410(12) . ?
C51 N18 1.355(14) . ?
C52 N18 1.484(13) . ?
C52 C53 1.508(14) . ?
C53 N19 1.275(13) . ?
C53 C54 1.383(14) . ?
C54 C55 1.368(15) . ?
C55 N20 1.321(13) . ?
C55 C56 1.491(14) . ?
C57 N20 1.466(13) . ?
C58 N22 1.349(12) . ?
C58 N21 1.364(12) . ?
C59 C60 1.336(15) . ?
C59 N21 1.380(13) . ?
C60 N22 1.374(13) . ?
C61 N22 1.462(12) . ?
C61 C62 1.480(14) . ?
C62 N23 1.335(12) . ?
C62 C63 1.396(14) . ?
C63 C64 1.385(16) . ?
C64 N24 1.334(13) . ?
C64 C65 1.505(15) . ?
C66 N24 1.457(14) . ?
C67 N25 1.142(17) . ?
C67 C68 1.430(19) . ?
C69 N26 1.100(16) . ?
C69 C70 1.39(2) . ?
C71 N27 1.105(14) . ?
C71 C72 1.475(19) . ?
C73 N28 1.18(2) . ?
C73 C74 1.49(3) . ?
C75 N29 1.106(15) . ?
C75 C76 1.476(18) . ?
C77 N30 1.181(17) . ?
C77 C78 1.408(18) . ?
C79 N31 1.088(19) . ?
C79 C80 1.40(3) . ?
C81 N32 1.14(2) . ?
C81 C82 1.454(18) . ?
F1 P1 1.600(6) . ?
F2 P1 1.593(7) . ?
F3 P1 1.585(7) . ?
F4 P1 1.587(8) . ?
F5 P1 1.579(6) . ?
F6 P1 1.602(6) . ?
F7 P2 1.582(7) . ?
F8 P2 1.555(7) . ?
F9 P2 1.577(8) . ?
F10 P2 1.562(8) . ?
F11 P2 1.548(8) . ?
F12 P2 1.571(7) . ?
F13 P3 1.544(13) . ?
F14 P3 1.574(11) . ?
F15 P3 1.627(10) . ?
F16 P3 1.589(10) . ?
F17 P3 1.612(12) . ?
F18 P3 1.529(15) . ?
F19 P4 1.573(8) . ?
F20 P4 1.573(9) . ?
F21 P4 1.611(8) . ?
F22 P4 1.572(8) . ?
F23 P4 1.526(9) . ?
F24 P4 1.625(9) . ?
F25 P5 1.605(11) . ?
F26 P5 1.583(9) . ?
F27 P5 1.517(11) . ?
F28 P5 1.597(8) . ?
F29 P5 1.551(10) . ?
F30 P5 1.542(12) . ?
F31 P6 1.625(10) . ?
F32 P6 1.596(10) . ?
F33 P6 1.618(10) . ?
F34 P6 1.631(10) . ?
F35 P6 1.601(9) . ?
F36 P6 1.593(9) . ?
N3 N4 1.354(9) . ?
N7 N8 1.362(10) . ?
N11 N12 1.356(11) . ?
N15 N16 1.345(12) . ?
N19 N20 1.357(11) . ?
N23 N24 1.357(12) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C25 Ag1 C49 179.5(3) . . ?
C25 Ag1 Ag5 70.6(2) . . ?
C49 Ag1 Ag5 109.1(3) . . ?
C16 Ag2 C58 177.6(3) . . ?
C16 Ag2 Ag4 107.2(2) . . ?
C58 Ag2 Ag4 70.7(3) . . ?
C7 Ag3 N16 164.8(3) . . ?
C7 Ag3 Ag6 72.4(2) . . ?
N16 Ag3 Ag6 109.4(2) . . ?
N7 Ag4 N23 134.6(3) . . ?
N7 Ag4 N27 119.6(3) . . ?
N23 Ag4 N27 95.8(3) . . ?
N7 Ag4 Ag2 90.6(2) . . ?
N23 Ag4 Ag2 103.0(2) . . ?
N27 Ag4 Ag2 110.8(2) . . ?
N19 Ag5 N12 140.2(3) . . ?
N19 Ag5 N26 116.2(3) . . ?
N12 Ag5 N26 92.9(4) . . ?
N19 Ag5 Ag1 88.4(2) . . ?
N12 Ag5 Ag1 109.3(2) . . ?
N26 Ag5 Ag1 107.3(2) . . ?
C40 Ag6 N3 143.3(4) . . ?
C40 Ag6 N25 131.0(4) . . ?
N3 Ag6 N25 82.6(5) . . ?
C40 Ag6 Ag3 81.2(3) . . ?
N3 Ag6 Ag3 99.3(3) . . ?
N25 Ag6 Ag3 114.3(3) . . ?
C6 C1 C2 121.2(8) . . ?
C6 C1 N1 119.0(8) . . ?
C2 C1 N1 119.7(8) . . ?
C3 C2 C1 117.0(9) . . ?
C4 C3 C2 123.9(9) . . ?
C4 C3 N9 119.5(8) . . ?
C2 C3 N9 116.6(8) . . ?
C3 C4 C5 117.8(8) . . ?
C6 C5 N5 122.9(8) . . ?
C6 C5 C4 119.3(9) . . ?
N5 C5 C4 117.5(7) . . ?
C1 C6 C5 120.7(9) . . ?
N2 C7 N1 105.1(7) . . ?
N2 C7 Ag3 122.2(6) . . ?
N1 C7 Ag3 132.5(6) . . ?
C9 C8 N1 107.4(8) . . ?
C8 C9 N2 107.3(8) . . ?
N2 C10 C11 112.6(10) . . ?
N3 C11 C12 107.3(12) . . ?
N3 C11 C10 121.0(10) . . ?
C12 C11 C10 130.9(12) . . ?
C11 C12 C13 110.6(15) . . ?
N4 C13 C12 100.4(18) . . ?
N4 C13 C14 122(2) . . ?
C12 C13 C14 137(2) . . ?
N5 C16 N6 102.2(7) . . ?
N5 C16 Ag2 129.9(6) . . ?
N6 C16 Ag2 127.9(7) . . ?
C18 C17 N5 106.2(9) . . ?
C17 C18 N6 107.2(8) . . ?
N6 C19 C20 111.6(7) . . ?
N7 C20 C21 112.3(8) . . ?
N7 C20 C19 120.3(8) . . ?
C21 C20 C19 127.3(8) . . ?
C22 C21 C20 106.2(9) . . ?
C21 C22 N8 105.6(9) . . ?
C21 C22 C23 132.6(10) . . ?
N8 C22 C23 121.7(9) . . ?
N9 C25 N10 103.4(7) . . ?
N9 C25 Ag1 125.9(7) . . ?
N10 C25 Ag1 129.4(6) . . ?
C27 C26 N9 107.0(8) . . ?
C26 C27 N10 107.0(9) . . ?
N10 C28 C29 110.3(8) . . ?
N12 C29 C30 109.2(9) . . ?
N12 C29 C28 120.2(9) . . ?
C30 C29 C28 130.6(9) . . ?
C31 C30 C29 106.8(9) . . ?
N11 C31 C30 106.4(9) . . ?
N11 C31 C32 121.5(10) . . ?
C30 C31 C32 132.1(11) . . ?
C39 C34 C35 118.0(9) . . ?
C34 C35 C36 122.7(9) . . ?
C34 C35 N21 120.1(8) . . ?
C36 C35 N21 117.2(9) . . ?
C37 C36 C35 117.5(9) . . ?
C36 C37 C38 121.1(8) . . ?
C36 C37 N13 119.7(8) . . ?
C38 C37 N13 119.2(8) . . ?
C39 C38 C37 117.4(9) . . ?
C34 C39 C38 123.3(9) . . ?
C34 C39 N17 118.5(8) . . ?
C38 C39 N17 118.2(8) . . ?
N14 C40 N13 104.4(8) . . ?
N14 C40 Ag6 123.9(7) . . ?
N13 C40 Ag6 131.6(7) . . ?
C42 C41 N13 107.3(9) . . ?
C41 C42 N14 107.2(9) . . ?
N14 C43 C44 112.0(8) . . ?
N16 C44 C45 110.8(9) . . ?
N16 C44 C43 121.1(9) . . ?
C45 C44 C43 128.1(9) . . ?
C46 C45 C44 105.3(9) . . ?
N15 C46 C45 107.0(9) . . ?
N15 C46 C47 120.8(9) . . ?
C45 C46 C47 132.3(10) . . ?
N17 C49 N18 103.7(8) . . ?
N17 C49 Ag1 129.2(7) . . ?
N18 C49 Ag1 127.1(7) . . ?
C51 C50 N17 104.7(9) . . ?
C50 C51 N18 108.1(9) . . ?
N18 C52 C53 112.9(9) . . ?
N19 C53 C54 112.8(9) . . ?
N19 C53 C52 121.0(9) . . ?
C54 C53 C52 126.1(10) . . ?
C55 C54 C53 104.3(9) . . ?
N20 C55 C54 106.4(9) . . ?
N20 C55 C56 122.9(10) . . ?
C54 C55 C56 130.7(10) . . ?
N22 C58 N21 104.1(7) . . ?
N22 C58 Ag2 129.4(7) . . ?
N21 C58 Ag2 125.9(7) . . ?
C60 C59 N21 107.0(9) . . ?
C59 C60 N22 106.9(9) . . ?
N22 C61 C62 113.0(8) . . ?
N23 C62 C63 109.7(9) . . ?
N23 C62 C61 121.4(8) . . ?
C63 C62 C61 128.6(9) . . ?
C64 C63 C62 105.8(9) . . ?
N24 C64 C63 106.8(9) . . ?
N24 C64 C65 122.8(11) . . ?
C63 C64 C65 130.3(10) . . ?
N25 C67 C68 178.9(19) . . ?
N26 C69 C70 177.0(18) . . ?
N27 C71 C72 178.1(19) . . ?
N28 C73 C74 174.0(17) . . ?
N29 C75 C76 178.1(14) . . ?
N30 C77 C78 178.2(15) . . ?
N31 C79 C80 178(2) . . ?
N32 C81 C82 176(3) . . ?
C7 N1 C8 110.1(7) . . ?
C7 N1 C1 125.2(7) . . ?
C8 N1 C1 124.7(8) . . ?
C7 N2 C9 110.1(7) . . ?
C7 N2 C10 126.4(8) . . ?
C9 N2 C10 123.4(8) . . ?
C11 N3 N4 105.2(13) . . ?
C11 N3 Ag6 134.6(8) . . ?
N4 N3 Ag6 119.5(12) . . ?
C13 N4 N3 115.2(17) . . ?
C13 N4 C15 117(2) . . ?
N3 N4 C15 123(2) . . ?
C16 N5 C17 112.8(8) . . ?
C16 N5 C5 122.7(7) . . ?
C17 N5 C5 124.5(8) . . ?
C16 N6 C18 111.6(8) . . ?
C16 N6 C19 123.7(8) . . ?
C18 N6 C19 124.4(8) . . ?
C20 N7 N8 104.0(7) . . ?
C20 N7 Ag4 128.6(6) . . ?
N8 N7 Ag4 124.9(6) . . ?
C22 N8 N7 111.7(7) . . ?
C22 N8 C24 128.1(8) . . ?
N7 N8 C24 120.1(7) . . ?
C25 N9 C26 111.0(7) . . ?
C25 N9 C3 123.6(7) . . ?
C26 N9 C3 125.3(7) . . ?
C27 N10 C25 111.6(8) . . ?
C27 N10 C28 125.2(8) . . ?
C25 N10 C28 123.1(8) . . ?
C31 N11 N12 110.8(8) . . ?
C31 N11 C33 127.6(9) . . ?
N12 N11 C33 121.6(9) . . ?
C29 N12 N11 106.7(8) . . ?
C29 N12 Ag5 127.2(7) . . ?
N11 N12 Ag5 122.6(6) . . ?
C40 N13 C41 110.4(8) . . ?
C40 N13 C37 124.5(8) . . ?
C41 N13 C37 125.1(8) . . ?
C40 N14 C42 110.8(8) . . ?
C40 N14 C43 126.5(8) . . ?
C42 N14 C43 122.5(8) . . ?
C46 N15 N16 111.1(8) . . ?
C46 N15 C48 128.6(10) . . ?
N16 N15 C48 120.3(9) . . ?
C44 N16 N15 105.8(8) . . ?
C44 N16 Ag3 128.9(7) . . ?
N15 N16 Ag3 125.3(6) . . ?
C49 N17 C50 111.6(8) . . ?
C49 N17 C39 126.3(8) . . ?
C50 N17 C39 122.1(8) . . ?
C49 N18 C51 112.0(9) . . ?
C49 N18 C52 122.8(9) . . ?
C51 N18 C52 125.1(9) . . ?
C53 N19 N20 104.6(8) . . ?
C53 N19 Ag5 129.7(7) . . ?
N20 N19 Ag5 122.7(6) . . ?
C55 N20 N19 111.9(8) . . ?
C55 N20 C57 127.9(9) . . ?
N19 N20 C57 120.0(8) . . ?
C58 N21 C59 110.5(8) . . ?
C58 N21 C35 122.9(7) . . ?
C59 N21 C35 126.3(8) . . ?
C58 N22 C60 111.4(8) . . ?
C58 N22 C61 124.1(8) . . ?
C60 N22 C61 124.4(9) . . ?
C62 N23 N24 106.1(8) . . ?
C62 N23 Ag4 131.2(7) . . ?
N24 N23 Ag4 122.2(6) . . ?
C64 N24 N23 111.5(9) . . ?
C64 N24 C66 129.6(10) . . ?
N23 N24 C66 118.8(8) . . ?
C67 N25 Ag6 143.5(13) . . ?
C69 N26 Ag5 170.0(12) . . ?
C71 N27 Ag4 158.6(11) . . ?
F5 P1 F3 90.8(4) . . ?
F5 P1 F4 91.6(5) . . ?
F3 P1 F4 90.8(4) . . ?
F5 P1 F2 90.3(4) . . ?
F3 P1 F2 89.8(4) . . ?
F4 P1 F2 178.0(4) . . ?
F5 P1 F1 90.4(4) . . ?
F3 P1 F1 178.6(4) . . ?
F4 P1 F1 89.9(4) . . ?
F2 P1 F1 89.4(4) . . ?
F5 P1 F6 179.4(5) . . ?
F3 P1 F6 89.7(4) . . ?
F4 P1 F6 88.7(4) . . ?
F2 P1 F6 89.4(3) . . ?
F1 P1 F6 89.1(3) . . ?
F11 P2 F8 90.7(6) . . ?
F11 P2 F10 88.1(6) . . ?
F8 P2 F10 178.8(6) . . ?
F11 P2 F12 178.2(6) . . ?
F8 P2 F12 90.7(4) . . ?
F10 P2 F12 90.5(5) . . ?
F11 P2 F9 89.6(6) . . ?
F8 P2 F9 89.5(5) . . ?
F10 P2 F9 90.3(5) . . ?
F12 P2 F9 89.3(5) . . ?
F11 P2 F7 89.6(5) . . ?
F8 P2 F7 90.1(5) . . ?
F10 P2 F7 90.0(5) . . ?
F12 P2 F7 91.5(4) . . ?
F9 P2 F7 179.1(7) . . ?
F18 P3 F13 87.3(10) . . ?
F18 P3 F14 90.9(8) . . ?
F13 P3 F14 91.2(7) . . ?
F18 P3 F16 89.0(7) . . ?
F13 P3 F16 91.7(6) . . ?
F14 P3 F16 177.1(6) . . ?
F18 P3 F17 176.7(7) . . ?
F13 P3 F17 95.9(10) . . ?
F14 P3 F17 89.7(8) . . ?
F16 P3 F17 90.3(6) . . ?
F18 P3 F15 85.3(7) . . ?
F13 P3 F15 172.4(11) . . ?
F14 P3 F15 90.9(6) . . ?
F16 P3 F15 86.2(5) . . ?
F17 P3 F15 91.4(5) . . ?
F23 P4 F22 89.0(7) . . ?
F23 P4 F20 100.9(8) . . ?
F22 P4 F20 170.0(6) . . ?
F23 P4 F19 93.5(5) . . ?
F22 P4 F19 89.0(5) . . ?
F20 P4 F19 91.6(5) . . ?
F23 P4 F21 91.0(5) . . ?
F22 P4 F21 88.4(5) . . ?
F20 P4 F21 90.2(5) . . ?
F19 P4 F21 174.8(5) . . ?
F23 P4 F24 176.1(7) . . ?
F22 P4 F24 87.1(5) . . ?
F20 P4 F24 82.9(6) . . ?
F19 P4 F24 87.2(5) . . ?
F21 P4 F24 88.2(5) . . ?
F27 P5 F30 90.6(8) . . ?
F27 P5 F29 94.1(8) . . ?
F30 P5 F29 175.0(8) . . ?
F27 P5 F26 90.2(6) . . ?
F30 P5 F26 90.3(7) . . ?
F29 P5 F26 87.9(6) . . ?
F27 P5 F28 89.0(5) . . ?
F30 P5 F28 91.3(6) . . ?
F29 P5 F28 90.6(5) . . ?
F26 P5 F28 178.3(7) . . ?
F27 P5 F25 177.3(9) . . ?
F30 P5 F25 86.8(8) . . ?
F29 P5 F25 88.5(7) . . ?
F26 P5 F25 90.3(6) . . ?
F28 P5 F25 90.6(5) . . ?
F36 P6 F35 171.7(14) . . ?
F36 P6 F32 93.5(13) . . ?
F35 P6 F32 89.5(14) . . ?
F36 P6 F33 83.6(12) . . ?
F35 P6 F33 88.8(13) . . ?
F32 P6 F33 87.0(14) . . ?
F36 P6 F31 81.0(14) . . ?
F35 P6 F31 106.0(16) . . ?
F32 P6 F31 101.3(18) . . ?
F33 P6 F31 162.9(17) . . ?
F36 P6 F34 84.7(12) . . ?
F35 P6 F34 92.4(15) . . ?
F32 P6 F34 178.0(16) . . ?
F33 P6 F34 93.5(15) . . ?
F31 P6 F34 77.7(16) . . ?

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        25.01
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         2.002
_refine_diff_density_min         -1.659
_refine_diff_density_rms         0.182

# SQUEEZE RESULTS (APPEND TO CIF)
# Note: Data are Listed for all Voids in the P1 Unit Cell
# i.e. Centre of Gravity, Solvent Accessible Volume,
# Recovered number of Electrons in the Void and
# Details about the Squeezed Material
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.111 0.689 0.047 21 1 ' '
2 0.611 0.189 0.047 21 1 ' '
3 0.500 0.355 0.250 955 281 ' '
4 1.000 -0.145 0.250 955 281 ' '
5 0.389 0.189 0.453 21 2 ' '
6 0.889 0.689 0.453 21 2 ' '
7 0.111 0.310 0.547 21 2 ' '
8 0.611 0.810 0.547 21 2 ' '
9 0.500 0.645 0.750 955 285 ' '
10 1.000 0.145 0.750 955 285 ' '
11 0.389 0.810 0.953 21 2 ' '
12 0.889 0.310 0.953 21 2 ' '
_platon_squeeze_details          
;
;

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_3
_database_code_depnum_ccdc_archive 'CCDC 1958764'
loop_
_audit_author_name
_audit_author_address
'Chao Chen'
;Huzhou University
China
;
_audit_update_record             
;
2019-10-11 deposited with the CCDC.	2020-01-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C53 H67 Ag3 F18 N17 O P3'
_chemical_formula_weight         1731.73

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   c2/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   18.8950(9)
_cell_length_b                   23.5495(9)
_cell_length_c                   15.6257(7)
_cell_angle_alpha                90.00
_cell_angle_beta                 93.532(5)
_cell_angle_gamma                90.00
_cell_volume                     6939.7(5)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    4308
_cell_measurement_theta_min      2.2345
_cell_measurement_theta_max      24.5678

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.19
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.657
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3467
_exptl_absorpt_coefficient_mu    1.028
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.8131
_exptl_absorpt_correction_T_max  0.8287
_exptl_absorpt_process_details   sadabs

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  bruker-CCD
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            13612
_diffrn_reflns_av_R_equivalents  0.0409
_diffrn_reflns_av_sigmaI/netI    0.0592
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_theta_min         3.13
_diffrn_reflns_theta_max         25.01
_reflns_number_total             6096
_reflns_number_gt                4308
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0717P)²+29.9166P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         6096
_refine_ls_number_parameters     494
_refine_ls_number_restraints     49
_refine_ls_R_factor_all          0.0821
_refine_ls_R_factor_gt           0.0503
_refine_ls_wR_factor_ref         0.1491
_refine_ls_wR_factor_gt          0.1216
_refine_ls_goodness_of_fit_ref   1.018
_refine_ls_restrained_S_all      1.015
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
O1 O -0.0058(9) 0.0198(7) -0.0317(11) 0.225(7) Uani 0.50 1 d P . 1
Ag1 Ag 0.03608(2) 0.309440(18) 0.17539(3) 0.03680(17) Uani 1 1 d . . .
Ag2 Ag 0.0000 0.20767(3) 0.2500 0.0383(2) Uani 1 2 d S . .
N1 N -0.0820(3) 0.1477(2) 0.1638(4) 0.0506(14) Uani 1 1 d . . .
N2 N 0.0230(3) 0.1996(2) 0.0571(3) 0.0418(12) Uani 1 1 d . . .
N3 N 0.1268(3) 0.2070(2) 0.1212(3) 0.0384(12) Uani 1 1 d . . .
N4 N 0.1559(3) 0.3272(2) 0.1522(3) 0.0452(13) Uani 1 1 d . A .
N5 N 0.1917(3) 0.3765(2) 0.1446(3) 0.0457(13) Uani 1 1 d . . .
N6 N -0.0456(2) 0.41999(19) 0.2056(3) 0.0378(11) Uani 1 1 d . . .
N7 N -0.0133(13) 0.3598(11) 0.0563(10) 0.028(5) Uani 0.50 1 d PD A 1
N7A N -0.0251(15) 0.3495(11) 0.0425(12) 0.044(7) Uani 0.50 1 d PD A 2
N8 N -0.0030(14) 0.3536(12) -0.0286(12) 0.042(6) Uani 0.50 1 d PD A 1
N9 N 0.2004(4) 0.2803(3) 0.4010(4) 0.0740(19) Uani 1 1 d . . .
C1 C -0.1202(4) 0.1079(3) 0.2000(5) 0.0554(18) Uani 1 1 d . A .
H1A H -0.1136 0.1028 0.2590 0.067 Uiso 1 1 calc R . .
C2 C -0.1692(5) 0.0736(3) 0.1554(6) 0.079(3) Uani 1 1 d . . .
H2A H -0.1952 0.0468 0.1837 0.095 Uiso 1 1 calc R A .
C3 C -0.1782(5) 0.0802(4) 0.0684(6) 0.081(3) Uani 1 1 d . A .
H3A H -0.2096 0.0573 0.0359 0.098 Uiso 1 1 calc R . .
C4 C -0.1395(4) 0.1218(3) 0.0301(5) 0.068(2) Uani 1 1 d . . .
H4A H -0.1451 0.1271 -0.0289 0.082 Uiso 1 1 calc R A .
C5 C -0.0928(4) 0.1555(3) 0.0779(4) 0.0486(16) Uani 1 1 d . A .
C6 C -0.0535(4) 0.2023(3) 0.0393(4) 0.0490(16) Uani 1 1 d . A .
H6A H -0.0636 0.2017 -0.0223 0.059 Uiso 1 1 calc R . .
H6B H -0.0706 0.2381 0.0606 0.059 Uiso 1 1 calc R . .
C7 C 0.0699(4) 0.1731(3) 0.0054(4) 0.0538(17) Uani 1 1 d . A .
H7A H 0.0586 0.1552 -0.0466 0.065 Uiso 1 1 calc R . .
C8 C 0.1344(4) 0.1782(3) 0.0444(4) 0.0496(16) Uani 1 1 d . A .
H8A H 0.1766 0.1650 0.0240 0.059 Uiso 1 1 calc R . .
C9 C 0.0590(3) 0.2199(2) 0.1275(4) 0.0418(15) Uani 1 1 d . A .
C10 C 0.1847(3) 0.2267(3) 0.1794(4) 0.0458(15) Uani 1 1 d . A .
H10A H 0.2255 0.2024 0.1735 0.055 Uiso 1 1 calc R . .
H10B H 0.1707 0.2232 0.2379 0.055 Uiso 1 1 calc R . .
C11 C 0.2055(3) 0.2866(3) 0.1638(4) 0.0406(14) Uani 1 1 d . . .
C12 C 0.2729(4) 0.3106(3) 0.1632(4) 0.0486(16) Uani 1 1 d . A .
H12A H 0.3161 0.2917 0.1702 0.058 Uiso 1 1 calc R . .
C13 C 0.2626(4) 0.3676(3) 0.1503(4) 0.0501(16) Uani 1 1 d . A .
C14 C 0.3135(4) 0.4155(3) 0.1435(6) 0.077(2) Uani 1 1 d . . .
H14A H 0.2877 0.4503 0.1343 0.115 Uiso 1 1 calc R A .
H14B H 0.3426 0.4088 0.0963 0.115 Uiso 1 1 calc R . .
H14C H 0.3430 0.4182 0.1956 0.115 Uiso 1 1 calc R . .
C15 C 0.1538(4) 0.4288(3) 0.1251(5) 0.0583(19) Uani 1 1 d . A .
H15A H 0.1870 0.4594 0.1219 0.087 Uiso 1 1 calc R . .
H15B H 0.1220 0.4365 0.1694 0.087 Uiso 1 1 calc R . .
H15C H 0.1271 0.4250 0.0711 0.087 Uiso 1 1 calc R . .
C16 C -0.0283(3) 0.4761(3) 0.2213(4) 0.0452(16) Uani 1 1 d . . .
H16 H -0.0511 0.5078 0.1971 0.054 Uiso 1 1 calc R . .
C17 C 0.0000 0.3856(4) 0.2500 0.0367(19) Uani 1 2 d S . .
C18 C -0.1013(3) 0.4005(3) 0.1427(4) 0.0449(15) Uani 1 1 d U A .
H18A H -0.1216 0.3652 0.1620 0.054 Uiso 0.50 1 calc PR B 1
H18B H -0.1389 0.4286 0.1368 0.054 Uiso 0.50 1 calc PR B 1
H18C H -0.1398 0.4278 0.1406 0.054 Uiso 0.50 1 d PR B 2
H18D H -0.1198 0.3645 0.1618 0.054 Uiso 0.50 1 d PR B 2
C19 C -0.0717(17) 0.3920(15) 0.0628(12) 0.040(6) Uani 0.50 1 d PDU A 1
C19A C -0.0761(17) 0.3897(14) 0.0498(11) 0.042(7) Uani 0.50 1 d PDU A 2
C20 C -0.0956(12) 0.4089(11) -0.0176(15) 0.065(10) Uani 0.50 1 d PD A 1
H20A H -0.1343 0.4324 -0.0310 0.078 Uiso 0.50 1 calc PR A 1
C20A C -0.1035(11) 0.4185(11) -0.0217(11) 0.037(6) Uani 0.50 1 d PD A 2
H20B H -0.1395 0.4450 -0.0165 0.044 Uiso 0.50 1 calc PR A 2
C21 C -0.0526(10) 0.3852(6) -0.0747(9) 0.057(5) Uani 0.50 1 d PD A 1
C21A C -0.0777(7) 0.4082(6) -0.1006(8) 0.055(4) Uani 0.50 1 d PD A 2
H21A H -0.0966 0.4270 -0.1491 0.066 Uiso 0.50 1 calc PR A 2
C22 C -0.0502(9) 0.3870(7) -0.1691(10) 0.069(5) Uani 0.50 1 d PD A 1
H22A H -0.0871 0.4114 -0.1927 0.104 Uiso 0.50 1 calc PR A 1
H22B H -0.0568 0.3494 -0.1920 0.104 Uiso 0.50 1 calc PR A 1
H22C H -0.0050 0.4014 -0.1839 0.104 Uiso 0.50 1 calc PR A 1
C22A C -0.0233(8) 0.3695(7) -0.1072(10) 0.058(5) Uani 0.50 1 d PD A 2
H22D H -0.0053 0.3622 -0.1601 0.069 Uiso 0.50 1 calc PR A 2
C23 C 0.0560(9) 0.3219(7) -0.0539(10) 0.057(4) Uani 0.50 1 d PD A 1
H23A H 0.0786 0.3034 -0.0047 0.086 Uiso 0.50 1 calc PR A 1
H23B H 0.0892 0.3469 -0.0788 0.086 Uiso 0.50 1 calc PR A 1
H23C H 0.0402 0.2938 -0.0954 0.086 Uiso 0.50 1 calc PR A 1
C23A C 0.0042(18) 0.3417(16) -0.0350(14) 0.058(9) Uani 0.50 1 d PD A 2
H23D H 0.0429 0.3176 -0.0387 0.070 Uiso 0.50 1 calc PR A 2
C24 C 0.2476(4) 0.2520(3) 0.3908(4) 0.0584(18) Uani 1 1 d . . .
C25 C 0.3071(4) 0.2150(4) 0.3768(5) 0.072(2) Uani 1 1 d . . .
H25A H 0.3272 0.2016 0.4311 0.108 Uiso 1 1 calc R . .
H25B H 0.3423 0.2356 0.3479 0.108 Uiso 1 1 calc R . .
H25C H 0.2911 0.1832 0.3423 0.108 Uiso 1 1 calc R . .
C26 C -0.0377(12) -0.0100(9) -0.1003(17) 0.212(9) Uani 1 1 d . . .
H26A H -0.0067 -0.0401 -0.1178 0.254 Uiso 1 1 calc R . 1
H26B H -0.0818 -0.0269 -0.0841 0.254 Uiso 1 1 calc R . 1
C27 C -0.050(2) 0.0274(15) -0.1652(19) 0.39(2) Uani 1 1 d . . .
H27A H -0.0716 0.0079 -0.2143 0.591 Uiso 1 1 calc R C 1
H27B H -0.0067 0.0445 -0.1797 0.591 Uiso 1 1 calc R C 1
H27C H -0.0822 0.0564 -0.1476 0.591 Uiso 1 1 calc R C 1
P1 P 0.28858(10) 0.06345(8) 0.13042(12) 0.0549(5) Uani 1 1 d . . .
P2 P 0.5000 0.29446(14) 0.2500 0.0635(8) Uani 1 2 d S . .
F1 F 0.2750(4) 0.0153(3) 0.0638(4) 0.121(2) Uani 1 1 d . . .
F2 F 0.3013(5) 0.1126(2) 0.1964(4) 0.138(3) Uani 1 1 d . . .
F3 F 0.2829(3) 0.1104(2) 0.0566(3) 0.0827(14) Uani 1 1 d . . .
F4 F 0.2084(3) 0.0688(3) 0.1441(4) 0.120(2) Uani 1 1 d . . .
F5 F 0.2979(3) 0.0182(2) 0.2052(3) 0.0853(15) Uani 1 1 d . . .
F6 F 0.3691(3) 0.0581(3) 0.1141(4) 0.123(2) Uani 1 1 d . . .
F7 F 0.5482(3) 0.3396(3) 0.2950(4) 0.125(2) Uani 1 1 d . . .
F8 F 0.4546(4) 0.2950(5) 0.3270(4) 0.201(5) Uani 1 1 d . . .
F9 F 0.4485(4) 0.2490(3) 0.2091(6) 0.188(4) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
O1 O1 1.37(3) 5 ?
O1 C26 1.39(2) . ?
O1 C26 2.18(3) 5 ?
O1 C27 2.21(3) . ?
Ag1 C17 2.267(7) . ?
Ag1 C9 2.287(6) . ?
Ag1 N7 2.350(15) . ?
Ag1 N4 2.353(5) . ?
Ag1 N7A 2.498(17) . ?
Ag1 Ag2 2.7687(7) . ?
Ag1 Ag1 2.7728(9) 2 ?
Ag2 C9 2.291(7) 2 ?
Ag2 C9 2.291(7) . ?
Ag2 N1 2.440(5) . ?
Ag2 N1 2.440(5) 2 ?
Ag2 Ag1 2.7687(7) 2 ?
N1 C1 1.329(8) . ?
N1 C5 1.358(8) . ?
N2 C9 1.346(8) . ?
N2 C7 1.382(8) . ?
N2 C6 1.457(8) . ?
N3 C9 1.326(8) . ?
N3 C8 1.393(8) . ?
N3 C10 1.456(8) . ?
N4 C11 1.344(8) . ?
N4 N5 1.353(7) . ?
N5 C13 1.353(8) . ?
N5 C15 1.447(8) . ?
N6 C17 1.344(7) . ?
N6 C16 1.379(7) . ?
N6 C18 1.470(7) . ?
N7 C19 1.349(9) . ?
N7 N8 1.361(9) . ?
N7A C19A 1.363(9) . ?
N7A C23A 1.374(9) . ?
N8 C21 1.366(9) . ?
N8 C23 1.42(2) . ?
N9 C24 1.133(9) . ?
C1 C2 1.384(10) . ?
C1 H1A 0.9300 . ?
C2 C3 1.367(12) . ?
C2 H2A 0.9300 . ?
C3 C4 1.381(12) . ?
C3 H3A 0.9300 . ?
C4 C5 1.372(9) . ?
C4 H4A 0.9300 . ?
C5 C6 1.479(9) . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 C8 1.334(9) . ?
C7 H7A 0.9300 . ?
C8 H8A 0.9300 . ?
C10 C11 1.488(9) . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C11 C12 1.394(9) . ?
C12 C13 1.370(9) . ?
C12 H12A 0.9300 . ?
C13 C14 1.489(10) . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C14 H14C 0.9600 . ?
C15 H15A 0.9600 . ?
C15 H15B 0.9600 . ?
C15 H15C 0.9600 . ?
C16 C16 1.353(12) 2 ?
C16 H16 0.9300 . ?
C17 N6 1.344(7) 2 ?
C17 Ag1 2.267(7) 2 ?
C18 C19 1.412(18) . ?
C18 C19A 1.575(17) . ?
C18 H18A 0.9700 . ?
C18 H18B 0.9700 . ?
C18 H18C 0.9699 . ?
C18 H18D 0.9700 . ?
C19 C20 1.368(9) . ?
C19A C20A 1.379(9) . ?
C20 C21 1.363(9) . ?
C20 H20A 0.9300 . ?
C20A C21A 1.376(9) . ?
C20A H20B 0.9300 . ?
C21 C22 1.48(2) . ?
C21A C22A 1.381(9) . ?
C21A H21A 0.9300 . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?
C22A C23A 1.378(9) . ?
C22A H22D 0.9300 . ?
C23 H23A 0.9600 . ?
C23 H23B 0.9600 . ?
C23 H23C 0.9600 . ?
C23A H23D 0.9300 . ?
C24 C25 1.448(11) . ?
C25 H25A 0.9600 . ?
C25 H25B 0.9600 . ?
C25 H25C 0.9600 . ?
C26 C27 1.35(3) . ?
C26 O1 2.18(3) 5 ?
C26 H26A 0.9700 . ?
C26 H26B 0.9700 . ?
C27 H27A 0.9600 . ?
C27 H27B 0.9600 . ?
C27 H27C 0.9600 . ?
P1 F4 1.548(5) . ?
P1 F1 1.551(5) . ?
P1 F2 1.559(6) . ?
P1 F6 1.563(5) . ?
P1 F5 1.583(5) . ?
P1 F3 1.597(5) . ?
P2 F8 1.520(7) 2_655 ?
P2 F8 1.520(7) . ?
P2 F7 1.541(6) . ?
P2 F7 1.541(6) 2_655 ?
P2 F9 1.558(7) . ?
P2 F9 1.558(7) 2_655 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 O1 C26 105(2) 5 . ?
O1 O1 C26 37.9(13) 5 5 ?
C26 O1 C26 142.7(14) . 5 ?
O1 O1 C27 141(2) 5 . ?
C26 O1 C27 35.8(12) . . ?
C26 O1 C27 178.6(14) 5 . ?
C17 Ag1 C9 165.1(2) . . ?
C17 Ag1 N7 83.8(6) . . ?
C9 Ag1 N7 106.2(6) . . ?
C17 Ag1 N4 105.14(16) . . ?
C9 Ag1 N4 84.9(2) . . ?
N7 Ag1 N4 97.3(6) . . ?
C17 Ag1 N7A 89.5(6) . . ?
C9 Ag1 N7A 99.4(6) . . ?
N7 Ag1 N7A 8.4(12) . . ?
N4 Ag1 N7A 101.9(7) . . ?
C17 Ag1 Ag2 112.24(14) . . ?
C9 Ag1 Ag2 52.86(15) . . ?
N7 Ag1 Ag2 132.4(6) . . ?
N4 Ag1 Ag2 118.88(13) . . ?
N7A Ag1 Ag2 124.3(6) . . ?
C17 Ag1 Ag1 52.29(14) . 2 ?
C9 Ag1 Ag1 112.81(15) . 2 ?
N7 Ag1 Ag1 118.3(6) . 2 ?
N4 Ag1 Ag1 131.08(13) . 2 ?
N7A Ag1 Ag1 118.2(7) . 2 ?
Ag2 Ag1 Ag1 59.951(11) . 2 ?
C9 Ag2 C9 165.5(3) 2 . ?
C9 Ag2 N1 102.04(19) 2 . ?
C9 Ag2 N1 86.4(2) . . ?
C9 Ag2 N1 86.4(2) 2 2 ?
C9 Ag2 N1 102.04(19) . 2 ?
N1 Ag2 N1 109.2(3) . 2 ?
C9 Ag2 Ag1 52.71(14) 2 2 ?
C9 Ag2 Ag1 112.81(14) . 2 ?
N1 Ag2 Ag1 124.69(13) . 2 ?
N1 Ag2 Ag1 115.69(13) 2 2 ?
C9 Ag2 Ag1 112.81(14) 2 . ?
C9 Ag2 Ag1 52.71(14) . . ?
N1 Ag2 Ag1 115.69(13) . . ?
N1 Ag2 Ag1 124.69(13) 2 . ?
Ag1 Ag2 Ag1 60.10(2) 2 . ?
C1 N1 C5 117.6(6) . . ?
C1 N1 Ag2 121.1(5) . . ?
C5 N1 Ag2 121.2(4) . . ?
C9 N2 C7 109.2(5) . . ?
C9 N2 C6 125.8(6) . . ?
C7 N2 C6 124.9(5) . . ?
C9 N3 C8 109.2(5) . . ?
C9 N3 C10 124.9(5) . . ?
C8 N3 C10 125.4(5) . . ?
C11 N4 N5 106.0(5) . . ?
C11 N4 Ag1 121.5(4) . . ?
N5 N4 Ag1 131.1(4) . . ?
N4 N5 C13 111.1(5) . . ?
N4 N5 C15 120.3(5) . . ?
C13 N5 C15 128.4(6) . . ?
C17 N6 C16 110.4(5) . . ?
C17 N6 C18 124.5(5) . . ?
C16 N6 C18 124.8(5) . . ?
C19 N7 N8 107.5(9) . . ?
C19 N7 Ag1 120.7(14) . . ?
N8 N7 Ag1 130.2(15) . . ?
C19A N7A C23A 119.5(11) . . ?
C19A N7A Ag1 119.1(14) . . ?
C23A N7A Ag1 119.4(14) . . ?
N7 N8 C21 108.8(9) . . ?
N7 N8 C23 119.3(17) . . ?
C21 N8 C23 131.7(17) . . ?
N1 C1 C2 124.1(7) . . ?
N1 C1 H1A 117.9 . . ?
C2 C1 H1A 117.9 . . ?
C3 C2 C1 118.2(8) . . ?
C3 C2 H2A 120.9 . . ?
C1 C2 H2A 120.9 . . ?
C2 C3 C4 118.3(8) . . ?
C2 C3 H3A 120.8 . . ?
C4 C3 H3A 120.8 . . ?
C5 C4 C3 120.9(8) . . ?
C5 C4 H4A 119.5 . . ?
C3 C4 H4A 119.5 . . ?
N1 C5 C4 120.8(7) . . ?
N1 C5 C6 117.2(6) . . ?
C4 C5 C6 122.0(6) . . ?
N2 C6 C5 114.0(5) . . ?
N2 C6 H6A 108.7 . . ?
C5 C6 H6A 108.7 . . ?
N2 C6 H6B 108.7 . . ?
C5 C6 H6B 108.7 . . ?
H6A C6 H6B 107.6 . . ?
C8 C7 N2 107.1(6) . . ?
C8 C7 H7A 126.5 . . ?
N2 C7 H7A 126.5 . . ?
C7 C8 N3 107.2(6) . . ?
C7 C8 H8A 126.4 . . ?
N3 C8 H8A 126.4 . . ?
N3 C9 N2 107.3(6) . . ?
N3 C9 Ag1 116.1(4) . . ?
N2 C9 Ag1 120.0(4) . . ?
N3 C9 Ag2 123.7(4) . . ?
N2 C9 Ag2 113.1(4) . . ?
Ag1 C9 Ag2 74.4(2) . . ?
N3 C10 C11 113.3(5) . . ?
N3 C10 H10A 108.9 . . ?
C11 C10 H10A 108.9 . . ?
N3 C10 H10B 108.9 . . ?
C11 C10 H10B 108.9 . . ?
H10A C10 H10B 107.7 . . ?
N4 C11 C12 109.9(5) . . ?
N4 C11 C10 120.5(5) . . ?
C12 C11 C10 129.5(6) . . ?
C13 C12 C11 106.1(6) . . ?
C13 C12 H12A 127.0 . . ?
C11 C12 H12A 127.0 . . ?
N5 C13 C12 107.0(6) . . ?
N5 C13 C14 121.2(6) . . ?
C12 C13 C14 131.8(7) . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
N5 C15 H15A 109.5 . . ?
N5 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
N5 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C16 C16 N6 106.7(3) 2 . ?
C16 C16 H16 126.7 2 . ?
N6 C16 H16 126.7 . . ?
N6 C17 N6 105.9(7) 2 . ?
N6 C17 Ag1 114.5(3) 2 2 ?
N6 C17 Ag1 122.6(3) . 2 ?
N6 C17 Ag1 122.6(3) 2 . ?
N6 C17 Ag1 114.5(3) . . ?
Ag1 C17 Ag1 75.4(3) 2 . ?
C19 C18 N6 109.2(15) . . ?
C19 C18 C19A 6(3) . . ?
N6 C18 C19A 115.0(14) . . ?
C19 C18 H18A 109.8 . . ?
N6 C18 H18A 109.8 . . ?
C19A C18 H18A 107.2 . . ?
C19 C18 H18B 109.8 . . ?
N6 C18 H18B 109.8 . . ?
C19A C18 H18B 106.4 . . ?
H18A C18 H18B 108.3 . . ?
C19 C18 H18C 113.6 . . ?
N6 C18 H18C 108.6 . . ?
C19A C18 H18C 110.1 . . ?
H18A C18 H18C 105.6 . . ?
H18B C18 H18C 3.9 . . ?
C19 C18 H18D 108.6 . . ?
N6 C18 H18D 108.9 . . ?
C19A C18 H18D 106.2 . . ?
H18A C18 H18D 2.2 . . ?
H18B C18 H18D 110.4 . . ?
H18C C18 H18D 107.8 . . ?
N7 C19 C20 108.6(9) . . ?
N7 C19 C18 121.1(19) . . ?
C20 C19 C18 130(2) . . ?
N7A C19A C20A 120.4(11) . . ?
N7A C19A C18 116.4(17) . . ?
C20A C19A C18 123.2(17) . . ?
C21 C20 C19 107.8(9) . . ?
C21 C20 H20A 126.1 . . ?
C19 C20 H20A 126.1 . . ?
C21A C20A C19A 120.2(11) . . ?
C21A C20A H20B 119.9 . . ?
C19A C20A H20B 119.9 . . ?
C20 C21 N8 107.2(9) . . ?
C20 C21 C22 134.2(17) . . ?
N8 C21 C22 118.6(17) . . ?
C20A C21A C22A 119.3(11) . . ?
C20A C21A H21A 120.4 . . ?
C22A C21A H21A 120.4 . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C23A C22A C21A 119.8(11) . . ?
C23A C22A H22D 120.1 . . ?
C21A C22A H22D 120.1 . . ?
N8 C23 H23A 109.5 . . ?
N8 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
N8 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
N7A C23A C22A 120.4(12) . . ?
N7A C23A H23D 119.8 . . ?
C22A C23A H23D 119.8 . . ?
N9 C24 C25 178.9(9) . . ?
C24 C25 H25A 109.5 . . ?
C24 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C24 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C27 C26 O1 107(2) . . ?
C27 C26 O1 145(2) . 5 ?
O1 C26 O1 37.3(14) . 5 ?
C27 C26 H26A 110.2 . . ?
O1 C26 H26A 110.2 . . ?
O1 C26 H26A 89.5 5 . ?
C27 C26 H26B 110.2 . . ?
O1 C26 H26B 110.2 . . ?
O1 C26 H26B 89.5 5 . ?
H26A C26 H26B 108.5 . . ?
C26 C27 O1 36.8(13) . . ?
C26 C27 H27A 109.5 . . ?
O1 C27 H27A 146.3 . . ?
C26 C27 H27B 109.5 . . ?
O1 C27 H27B 88.4 . . ?
H27A C27 H27B 109.5 . . ?
C26 C27 H27C 109.5 . . ?
O1 C27 H27C 89.8 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
F4 P1 F1 91.7(4) . . ?
F4 P1 F2 87.8(4) . . ?
F1 P1 F2 178.9(4) . . ?
F4 P1 F6 178.6(4) . . ?
F1 P1 F6 87.4(4) . . ?
F2 P1 F6 93.1(4) . . ?
F4 P1 F5 91.0(3) . . ?
F1 P1 F5 90.5(3) . . ?
F2 P1 F5 90.4(3) . . ?
F6 P1 F5 90.1(3) . . ?
F4 P1 F3 91.2(3) . . ?
F1 P1 F3 91.2(3) . . ?
F2 P1 F3 87.9(3) . . ?
F6 P1 F3 87.8(3) . . ?
F5 P1 F3 177.2(3) . . ?
F8 P2 F8 179.0(9) 2_655 . ?
F8 P2 F7 90.5(5) 2_655 . ?
F8 P2 F7 88.8(4) . . ?
F8 P2 F7 88.8(4) 2_655 2_655 ?
F8 P2 F7 90.5(5) . 2_655 ?
F7 P2 F7 92.8(5) . 2_655 ?
F8 P2 F9 92.9(6) 2_655 . ?
F8 P2 F9 87.8(5) . . ?
F7 P2 F9 176.6(5) . . ?
F7 P2 F9 87.1(4) 2_655 . ?
F8 P2 F9 87.8(5) 2_655 2_655 ?
F8 P2 F9 92.9(6) . 2_655 ?
F7 P2 F9 87.1(4) . 2_655 ?
F7 P2 F9 176.6(5) 2_655 2_655 ?
F9 P2 F9 93.1(6) . 2_655 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C17 Ag1 Ag2 C9 -0.10(16) . . . 2 ?
C9 Ag1 Ag2 C9 -179.98(2) . . . 2 ?
N7 Ag1 Ag2 C9 -102.4(8) . . . 2 ?
N4 Ag1 Ag2 C9 123.1(2) . . . 2 ?
N7A Ag1 Ag2 C9 -105.6(8) . . . 2 ?
Ag1 Ag1 Ag2 C9 -0.10(16) 2 . . 2 ?
C17 Ag1 Ag2 C9 179.88(18) . . . . ?
N7 Ag1 Ag2 C9 77.5(8) . . . . ?
N4 Ag1 Ag2 C9 -56.9(2) . . . . ?
N7A Ag1 Ag2 C9 74.4(8) . . . . ?
Ag1 Ag1 Ag2 C9 179.88(18) 2 . . . ?
C17 Ag1 Ag2 N1 116.87(15) . . . . ?
C9 Ag1 Ag2 N1 -63.0(2) . . . . ?
N7 Ag1 Ag2 N1 14.5(8) . . . . ?
N4 Ag1 Ag2 N1 -119.9(2) . . . . ?
N7A Ag1 Ag2 N1 11.4(8) . . . . ?
Ag1 Ag1 Ag2 N1 116.87(15) 2 . . . ?
C17 Ag1 Ag2 N1 -102.13(16) . . . 2 ?
C9 Ag1 Ag2 N1 78.0(2) . . . 2 ?
N7 Ag1 Ag2 N1 155.5(8) . . . 2 ?
N4 Ag1 Ag2 N1 21.1(2) . . . 2 ?
N7A Ag1 Ag2 N1 152.4(8) . . . 2 ?
Ag1 Ag1 Ag2 N1 -102.13(16) 2 . . 2 ?
C17 Ag1 Ag2 Ag1 0.0 . . . 2 ?
C9 Ag1 Ag2 Ag1 -179.88(18) . . . 2 ?
N7 Ag1 Ag2 Ag1 -102.3(8) . . . 2 ?
N4 Ag1 Ag2 Ag1 123.22(15) . . . 2 ?
N7A Ag1 Ag2 Ag1 -105.5(8) . . . 2 ?
C9 Ag2 N1 C1 -35.9(5) 2 . . . ?
C9 Ag2 N1 C1 156.0(5) . . . . ?
N1 Ag2 N1 C1 54.5(5) 2 . . . ?
Ag1 Ag2 N1 C1 -88.6(5) 2 . . . ?
Ag1 Ag2 N1 C1 -158.7(5) . . . . ?
C9 Ag2 N1 C5 140.9(5) 2 . . . ?
C9 Ag2 N1 C5 -27.2(5) . . . . ?
N1 Ag2 N1 C5 -128.7(5) 2 . . . ?
Ag1 Ag2 N1 C5 88.2(5) 2 . . . ?
Ag1 Ag2 N1 C5 18.0(5) . . . . ?
C17 Ag1 N4 C11 135.6(5) . . . . ?
C9 Ag1 N4 C11 -33.2(5) . . . . ?
N7 Ag1 N4 C11 -139.0(8) . . . . ?
N7A Ag1 N4 C11 -131.7(8) . . . . ?
Ag2 Ag1 N4 C11 8.9(5) . . . . ?
Ag1 Ag1 N4 C11 82.8(5) 2 . . . ?
C17 Ag1 N4 N5 -28.8(5) . . . . ?
C9 Ag1 N4 N5 162.5(5) . . . . ?
N7 Ag1 N4 N5 56.7(8) . . . . ?
N7A Ag1 N4 N5 63.9(8) . . . . ?
Ag2 Ag1 N4 N5 -155.4(5) . . . . ?
Ag1 Ag1 N4 N5 -81.5(5) 2 . . . ?
C11 N4 N5 C13 0.6(7) . . . . ?
Ag1 N4 N5 C13 166.7(4) . . . . ?
C11 N4 N5 C15 175.4(6) . . . . ?
Ag1 N4 N5 C15 -18.4(8) . . . . ?
C17 Ag1 N7 C19 -35(2) . . . . ?
C9 Ag1 N7 C19 134(2) . . . . ?
N4 Ag1 N7 C19 -139(2) . . . . ?
N7A Ag1 N7 C19 98(9) . . . . ?
Ag2 Ag1 N7 C19 80(2) . . . . ?
Ag1 Ag1 N7 C19 6(2) 2 . . . ?
C17 Ag1 N7 N8 162(2) . . . . ?
C9 Ag1 N7 N8 -30(2) . . . . ?
N4 Ag1 N7 N8 57(2) . . . . ?
N7A Ag1 N7 N8 -66(8) . . . . ?
Ag2 Ag1 N7 N8 -84(2) . . . . ?
Ag1 Ag1 N7 N8 -158(2) 2 . . . ?
C17 Ag1 N7A C19A -19(2) . . . . ?
C9 Ag1 N7A C19A 149(2) . . . . ?
N7 Ag1 N7A C19A -66(8) . . . . ?
N4 Ag1 N7A C19A -124(2) . . . . ?
Ag2 Ag1 N7A C19A 98(2) . . . . ?
Ag1 Ag1 N7A C19A 27(2) 2 . . . ?
C17 Ag1 N7A C23A 145(3) . . . . ?
C9 Ag1 N7A C23A -47(3) . . . . ?
N7 Ag1 N7A C23A 98(9) . . . . ?
N4 Ag1 N7A C23A 40(3) . . . . ?
Ag2 Ag1 N7A C23A -98(3) . . . . ?
Ag1 Ag1 N7A C23A -169(2) 2 . . . ?
C19 N7 N8 C21 4(3) . . . . ?
Ag1 N7 N8 C21 169.0(19) . . . . ?
C19 N7 N8 C23 179(3) . . . . ?
Ag1 N7 N8 C23 -16(4) . . . . ?
C5 N1 C1 C2 1.1(11) . . . . ?
Ag2 N1 C1 C2 178.0(6) . . . . ?
N1 C1 C2 C3 1.1(13) . . . . ?
C1 C2 C3 C4 -1.8(13) . . . . ?
C2 C3 C4 C5 0.3(13) . . . . ?
C1 N1 C5 C4 -2.7(10) . . . . ?
Ag2 N1 C5 C4 -179.5(5) . . . . ?
C1 N1 C5 C6 176.1(6) . . . . ?
Ag2 N1 C5 C6 -0.7(8) . . . . ?
C3 C4 C5 N1 2.0(12) . . . . ?
C3 C4 C5 C6 -176.7(7) . . . . ?
C9 N2 C6 C5 -84.8(7) . . . . ?
C7 N2 C6 C5 91.9(7) . . . . ?
N1 C5 C6 N2 54.9(8) . . . . ?
C4 C5 C6 N2 -126.3(7) . . . . ?
C9 N2 C7 C8 -0.8(7) . . . . ?
C6 N2 C7 C8 -178.1(6) . . . . ?
N2 C7 C8 N3 1.2(7) . . . . ?
C9 N3 C8 C7 -1.2(7) . . . . ?
C10 N3 C8 C7 -173.3(6) . . . . ?
C8 N3 C9 N2 0.7(6) . . . . ?
C10 N3 C9 N2 172.8(5) . . . . ?
C8 N3 C9 Ag1 -136.6(4) . . . . ?
C10 N3 C9 Ag1 35.4(7) . . . . ?
C8 N3 C9 Ag2 135.2(5) . . . . ?
C10 N3 C9 Ag2 -52.7(7) . . . . ?
C7 N2 C9 N3 0.1(6) . . . . ?
C6 N2 C9 N3 177.3(5) . . . . ?
C7 N2 C9 Ag1 135.4(5) . . . . ?
C6 N2 C9 Ag1 -47.3(7) . . . . ?
C7 N2 C9 Ag2 -139.8(4) . . . . ?
C6 N2 C9 Ag2 37.4(7) . . . . ?
C17 Ag1 C9 N3 -120.8(6) . . . . ?
N7 Ag1 C9 N3 108.4(8) . . . . ?
N4 Ag1 C9 N3 12.2(4) . . . . ?
N7A Ag1 C9 N3 113.4(8) . . . . ?
Ag2 Ag1 C9 N3 -120.3(5) . . . . ?
Ag1 Ag1 C9 N3 -120.4(4) 2 . . . ?
C17 Ag1 C9 N2 107.5(6) . . . . ?
N7 Ag1 C9 N2 -23.3(8) . . . . ?
N4 Ag1 C9 N2 -119.5(5) . . . . ?
N7A Ag1 C9 N2 -18.2(9) . . . . ?
Ag2 Ag1 C9 N2 108.0(5) . . . . ?
Ag1 Ag1 C9 N2 107.9(5) 2 . . . ?
C17 Ag1 C9 Ag2 -0.4(7) . . . . ?
N7 Ag1 C9 Ag2 -131.3(7) . . . . ?
N4 Ag1 C9 Ag2 132.57(17) . . . . ?
N7A Ag1 C9 Ag2 -126.2(7) . . . . ?
Ag1 Ag1 C9 Ag2 -0.11(17) 2 . . . ?
C9 Ag2 C9 N3 111.3(5) 2 . . . ?
N1 Ag2 C9 N3 -122.3(5) . . . . ?
N1 Ag2 C9 N3 -13.4(5) 2 . . . ?
Ag1 Ag2 C9 N3 111.4(5) 2 . . . ?
Ag1 Ag2 C9 N3 111.3(5) . . . . ?
C9 Ag2 C9 N2 -116.3(4) 2 . . . ?
N1 Ag2 C9 N2 10.0(4) . . . . ?
N1 Ag2 C9 N2 118.9(4) 2 . . . ?
Ag1 Ag2 C9 N2 -116.3(4) 2 . . . ?
Ag1 Ag2 C9 N2 -116.4(4) . . . . ?
N1 Ag2 C9 Ag1 126.42(17) . . . . ?
N1 Ag2 C9 Ag1 -124.68(16) 2 . . . ?
Ag1 Ag2 C9 Ag1 0.11(17) 2 . . . ?
C9 N3 C10 C11 -77.2(7) . . . . ?
C8 N3 C10 C11 93.6(7) . . . . ?
N5 N4 C11 C12 -0.1(7) . . . . ?
Ag1 N4 C11 C12 -167.8(4) . . . . ?
N5 N4 C11 C10 176.6(5) . . . . ?
Ag1 N4 C11 C10 8.9(8) . . . . ?
N3 C10 C11 N4 46.1(8) . . . . ?
N3 C10 C11 C12 -137.9(7) . . . . ?
N4 C11 C12 C13 -0.4(8) . . . . ?
C10 C11 C12 C13 -176.7(6) . . . . ?
N4 N5 C13 C12 -0.8(8) . . . . ?
C15 N5 C13 C12 -175.2(6) . . . . ?
N4 N5 C13 C14 179.8(6) . . . . ?
C15 N5 C13 C14 5.4(11) . . . . ?
C11 C12 C13 N5 0.7(8) . . . . ?
C11 C12 C13 C14 -180.0(8) . . . . ?
C17 N6 C16 C16 -1.7(9) . . . 2 ?
C18 N6 C16 C16 -175.8(6) . . . 2 ?
C16 N6 C17 N6 0.7(3) . . . 2 ?
C18 N6 C17 N6 174.8(6) . . . 2 ?
C16 N6 C17 Ag1 134.6(5) . . . 2 ?
C18 N6 C17 Ag1 -51.3(6) . . . 2 ?
C16 N6 C17 Ag1 -137.5(4) . . . . ?
C18 N6 C17 Ag1 36.6(6) . . . . ?
C9 Ag1 C17 N6 110.4(7) . . . 2 ?
N7 Ag1 C17 N6 -116.5(8) . . . 2 ?
N4 Ag1 C17 N6 -20.6(5) . . . 2 ?
N7A Ag1 C17 N6 -122.7(8) . . . 2 ?
Ag2 Ag1 C17 N6 110.1(4) . . . 2 ?
Ag1 Ag1 C17 N6 110.1(4) 2 . . 2 ?
C9 Ag1 C17 N6 -119.2(7) . . . . ?
N7 Ag1 C17 N6 13.9(7) . . . . ?
N4 Ag1 C17 N6 109.8(4) . . . . ?
N7A Ag1 C17 N6 7.7(8) . . . . ?
Ag2 Ag1 C17 N6 -119.5(4) . . . . ?
Ag1 Ag1 C17 N6 -119.5(4) 2 . . . ?
C9 Ag1 C17 Ag1 0.4(6) . . . 2 ?
N7 Ag1 C17 Ag1 133.4(6) . . . 2 ?
N4 Ag1 C17 Ag1 -130.64(14) . . . 2 ?
N7A Ag1 C17 Ag1 127.2(7) . . . 2 ?
Ag2 Ag1 C17 Ag1 0.0 . . . 2 ?
C17 N6 C18 C19 -83.2(15) . . . . ?
C16 N6 C18 C19 90.1(15) . . . . ?
C17 N6 C18 C19A -83.7(14) . . . . ?
C16 N6 C18 C19A 89.6(14) . . . . ?
N8 N7 C19 C20 -4(3) . . . . ?
Ag1 N7 C19 C20 -170.4(15) . . . . ?
N8 N7 C19 C18 172(3) . . . . ?
Ag1 N7 C19 C18 5(4) . . . . ?
N6 C18 C19 N7 52(3) . . . . ?
C19A C18 C19 N7 -133(26) . . . . ?
N6 C18 C19 C20 -133(2) . . . . ?
C19A C18 C19 C20 42(22) . . . . ?
C23A N7A C19A C20A 7(4) . . . . ?
Ag1 N7A C19A C20A 170.5(16) . . . . ?
C23A N7A C19A C18 -174(3) . . . . ?
Ag1 N7A C19A C18 -10(3) . . . . ?
C19 C18 C19A N7A 56(23) . . . . ?
N6 C18 C19A N7A 61(3) . . . . ?
C19 C18 C19A C20A -125(25) . . . . ?
N6 C18 C19A C20A -119.6(17) . . . . ?
N7 C19 C20 C21 1.9(16) . . . . ?
C18 C19 C20 C21 -173(3) . . . . ?
N7A C19A C20A C21A -2(2) . . . . ?
C18 C19A C20A C21A 178(3) . . . . ?
C19 C20 C21 N8 0.4(15) . . . . ?
C19 C20 C21 C22 -179.8(18) . . . . ?
N7 N8 C21 C20 -3(3) . . . . ?
C23 N8 C21 C20 -177(3) . . . . ?
N7 N8 C21 C22 177.6(18) . . . . ?
C23 N8 C21 C22 3(4) . . . . ?
C19A C20A C21A C22A -1.2(17) . . . . ?
C20A C21A C22A C23A 0(3) . . . . ?
C19A N7A C23A C22A -8(5) . . . . ?
Ag1 N7A C23A C22A -171(3) . . . . ?
C21A C22A C23A N7A 4(5) . . . . ?
O1 O1 C26 C27 180(3) 5 . . . ?
C26 O1 C26 C27 180(3) 5 . . . ?
C26 O1 C26 O1 0.000(2) 5 . . 5 ?
C27 O1 C26 O1 180(3) . . . 5 ?
O1 C26 C27 O1 0(3) 5 . . . ?
O1 O1 C27 C26 0(4) 5 . . . ?
C26 O1 C27 C26 0(67) 5 . . . ?

_diffrn_measured_fraction_theta_max 0.996
_diffrn_reflns_theta_full        25.01
_diffrn_measured_fraction_theta_full 0.996
_refine_diff_density_max         1.091
_refine_diff_density_min         -0.514
_refine_diff_density_rms         0.113
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1958765'
loop_
_audit_author_name
_audit_author_address
'Chao Chen'
;Huzhou University
China
;
_audit_update_record             
;
2019-10-11 deposited with the CCDC.	2020-01-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C60 H72 Ag4 F30 N20 P4'
_chemical_formula_weight         2198.73

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 2/c'
_space_group_name_Hall           '-C 2yc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   25.685(15)
_cell_length_b                   21.237(13)
_cell_length_c                   19.52(2)
_cell_angle_alpha                90
_cell_angle_beta                 124.195(7)
_cell_angle_gamma                90
_cell_volume                     8806(12)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    7747
_cell_measurement_theta_min      1.44
_cell_measurement_theta_max      25.01

_exptl_crystal_description       block
_exptl_crystal_colour            clorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.658
_exptl_crystal_F_000             4360
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.33
_exptl_crystal_size_mid          0.31
_exptl_crystal_size_min          0.25
_exptl_absorpt_coefficient_mu    1.061
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.712
_exptl_absorpt_correction_T_max  0.767
_exptl_absorpt_process_details   sadabs

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            21666
_diffrn_reflns_av_unetI/netI     0.0390
_diffrn_reflns_av_R_equivalents  0.0332
_diffrn_reflns_limit_h_min       -30
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_theta_min         1.439
_diffrn_reflns_theta_max         25.009
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measured_fraction_theta_full 0.973
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_Laue_measured_fraction_full 0.973
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_point_group_measured_fraction_full 0.973
_reflns_number_total             7747
_reflns_number_gt                6187
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1297P)²+112.6896P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         7747
_refine_ls_number_parameters     543
_refine_ls_number_restraints     510
_refine_ls_R_factor_all          0.0910
_refine_ls_R_factor_gt           0.0746
_refine_ls_wR_factor_ref         0.2318
_refine_ls_wR_factor_gt          0.2073
_refine_ls_goodness_of_fit_ref   1.044
_refine_ls_restrained_S_all      1.051
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.12148(2) 0.33438(2) 0.21626(3) 0.0344(2) Uani 1 1 d . . . . .
Ag2 Ag 0.23976(4) 0.26338(4) 0.23060(4) 0.0686(3) Uani 1 1 d . . . . .
N1 N 0.1325(3) 0.4440(3) 0.3302(3) 0.0356(12) Uani 1 1 d . . . . .
N7 N 0.2075(3) 0.2333(3) 0.1080(4) 0.0441(15) Uani 1 1 d . . . . .
N3 N 0.2716(3) 0.2734(3) 0.3578(4) 0.0479(16) Uani 1 1 d . . . . .
C2 C 0.0253(3) 0.4480(3) 0.2026(4) 0.0353(14) Uani 1 1 d . U . . .
H2 H 0.0424 0.4501 0.1713 0.042 Uiso 1 1 calc R U . . .
C1 C -0.0395(3) 0.4467(3) 0.1635(4) 0.0357(14) Uani 1 1 d . U . . .
H1 H -0.0659 0.4461 0.1060 0.043 Uiso 1 1 calc R U . . .
C15 C 0.0156(4) 0.2170(3) 0.1914(5) 0.0438(16) Uani 1 1 d . U . . .
C7 C 0.2777(4) 0.3894(4) 0.3641(5) 0.0443(16) Uani 1 1 d . U . . .
H7A H 0.3149 0.4158 0.3943 0.053 Uiso 1 1 calc R U . . .
H7B H 0.2664 0.3850 0.3079 0.053 Uiso 1 1 calc R U . . .
C3 C 0.0651(3) 0.4462(3) 0.2894(4) 0.0337(14) Uani 1 1 d . U . . .
C20 C 0.1005(4) 0.2817(4) 0.0301(5) 0.0493(17) Uani 1 1 d . U . . .
H20A H 0.1183 0.3200 0.0621 0.059 Uiso 1 1 calc R U . . .
H20B H 0.0700 0.2935 -0.0272 0.059 Uiso 1 1 calc R U . . .
N5 N 0.0314(3) 0.2180(3) 0.1321(4) 0.0454(15) Uani 1 1 d . . . . .
C8 C 0.2923(3) 0.3253(4) 0.4045(5) 0.0435(16) Uani 1 1 d . U . . .
N2 N 0.2252(3) 0.4203(3) 0.3626(4) 0.0383(13) Uani 1 1 d . . . . .
N4 N 0.2884(3) 0.2244(3) 0.4120(4) 0.0523(17) Uani 1 1 d . . . . .
N6 N 0.0685(3) 0.2460(3) 0.0614(4) 0.0451(15) Uani 1 1 d . . . . .
C21 C 0.1525(4) 0.2430(4) 0.0357(5) 0.0447(16) Uani 1 1 d . U . . .
C4 C 0.1632(3) 0.4068(3) 0.3068(4) 0.0347(14) Uani 1 1 d . U . . .
C22 C 0.1521(5) 0.2131(4) -0.0292(6) 0.0532(19) Uani 1 1 d . U . . .
H22 H 0.1196 0.2130 -0.0852 0.064 Uiso 1 1 calc R U . . .
N8 N 0.2427(3) 0.1967(3) 0.0904(5) 0.0515(17) Uani 1 1 d . . . . .
C9 C 0.3225(4) 0.3102(4) 0.4868(5) 0.0520(18) Uani 1 1 d . U . . .
H9 H 0.3414 0.3380 0.5312 0.062 Uiso 1 1 calc R U . . .
C5 C 0.1754(4) 0.4789(4) 0.4013(5) 0.0471(17) Uani 1 1 d . U . . .
H5 H 0.1658 0.5069 0.4292 0.057 Uiso 1 1 calc R U . . .
C19 C 0.0713(3) 0.2610(3) 0.1309(5) 0.0385(15) Uani 1 1 d . U . . .
C18 C 0.0281(5) 0.1954(5) 0.0206(6) 0.066(2) Uani 1 1 d . U . . .
H18 H 0.0188 0.1773 -0.0284 0.079 Uiso 1 1 calc R U . . .
C24 C 0.2368(6) 0.1439(5) -0.0286(7) 0.072(3) Uani 1 1 d . U . . .
H24A H 0.2817 0.1483 0.0036 0.108 Uiso 1 1 calc R U . . .
H24B H 0.2195 0.1572 -0.0845 0.108 Uiso 1 1 calc R U . . .
H24C H 0.2260 0.1007 -0.0286 0.108 Uiso 1 1 calc R U . . .
C6 C 0.2339(4) 0.4637(4) 0.4213(5) 0.0499(18) Uani 1 1 d . U . . .
H6 H 0.2720 0.4794 0.4655 0.060 Uiso 1 1 calc R U . . .
C12 C 0.2740(6) 0.1595(5) 0.3811(7) 0.070(3) Uani 1 1 d . U . . .
H12A H 0.2967 0.1308 0.4277 0.084 Uiso 1 1 calc R U . . .
H12B H 0.2888 0.1526 0.3456 0.084 Uiso 1 1 calc R U . . .
C10 C 0.3193(4) 0.2453(5) 0.4908(5) 0.0542(19) Uani 1 1 d . U . . .
C23 C 0.2103(4) 0.1840(4) 0.0082(6) 0.0533(18) Uani 1 1 d . U . . .
C17 C 0.0051(5) 0.1776(4) 0.0631(6) 0.062(2) Uani 1 1 d . U . . .
H17 H -0.0229 0.1447 0.0501 0.075 Uiso 1 1 calc R U . . .
C25 C 0.3051(5) 0.1758(5) 0.1558(8) 0.075(3) Uani 1 1 d . U . . .
H25A H 0.3265 0.2093 0.1960 0.090 Uiso 1 1 calc R U . . .
H25B H 0.3292 0.1666 0.1326 0.090 Uiso 1 1 calc R U . . .
C14 C 0.0065(3) 0.2733(3) 0.2187(5) 0.0357(14) Uani 1 1 d . U . . .
H14 H 0.0089 0.3111 0.1967 0.043 Uiso 1 1 calc R U . . .
C26 C 0.3027(7) 0.1177(6) 0.1987(9) 0.097(4) Uani 1 1 d . U . . .
H26A H 0.2783 0.1265 0.2209 0.145 Uiso 1 1 calc R U . . .
H26B H 0.3447 0.1060 0.2428 0.145 Uiso 1 1 calc R U . . .
H26C H 0.2836 0.0838 0.1596 0.145 Uiso 1 1 calc R U . . .
C13 C 0.2037(8) 0.1440(6) 0.3325(10) 0.114(5) Uani 1 1 d . U . . .
H13A H 0.1894 0.1473 0.3685 0.171 Uiso 1 1 calc R U . . .
H13B H 0.1969 0.1019 0.3112 0.171 Uiso 1 1 calc R U . . .
H13C H 0.1807 0.1730 0.2874 0.171 Uiso 1 1 calc R U . . .
C11 C 0.3424(5) 0.2021(6) 0.5626(6) 0.073(3) Uani 1 1 d . U . . .
H11A H 0.3076 0.1789 0.5554 0.109 Uiso 1 1 calc R U . . .
H11B H 0.3619 0.2263 0.6127 0.109 Uiso 1 1 calc R U . . .
H11C H 0.3725 0.1734 0.5658 0.109 Uiso 1 1 calc R U . . .
C16 C 0.0084(5) 0.1604(4) 0.2225(6) 0.057(2) Uani 1 1 d . U . . .
H16 H 0.0151 0.1223 0.2052 0.069 Uiso 1 1 calc R U . . .
P1 P 0.32452(10) 0.03371(10) 0.89383(13) 0.0463(5) Uani 1 1 d . . . . .
F1 F 0.3559(3) 0.0692(3) 0.9809(3) 0.0668(14) Uani 1 1 d . . . . .
F3 F 0.3851(3) 0.0522(3) 0.8930(4) 0.0762(16) Uani 1 1 d . . . . .
F2 F 0.2646(3) 0.0163(3) 0.8967(4) 0.0737(16) Uani 1 1 d . . . . .
F4 F 0.2918(3) 0.0987(3) 0.8473(4) 0.0731(15) Uani 1 1 d . . . . .
F6 F 0.3587(3) -0.0296(3) 0.9434(4) 0.0794(17) Uani 1 1 d . . . . .
F5 F 0.2935(4) -0.0010(3) 0.8076(4) 0.093(2) Uani 1 1 d . . . . .
P3 P 0.5000 0.1684(4) 0.2500 0.118(2) Uani 1 2 d DS TU P . .
F13 F 0.4621(9) 0.2184(9) 0.265(2) 0.44(2) Uani 1 1 d D . . . .
F15 F 0.4438(7) 0.1597(14) 0.1581(6) 0.324(15) Uani 1 1 d D U . . .
F14 F 0.4655(9) 0.1132(9) 0.2656(17) 0.320(13) Uani 1 1 d D . . . .
P2 P 0.4247(3) 0.5119(3) 0.5713(6) 0.118(3) Uani 0.5 1 d D U P . .
F10 F 0.3689(7) 0.5317(8) 0.4869(18) 0.342(17) Uani 1 1 d . . . . .
F8 F 0.4891(6) 0.4848(7) 0.6454(10) 0.294(10) Uani 1 1 d D U . . .
F12 F 0.3867(11) 0.4736(13) 0.5996(16) 0.332(12) Uani 1 1 d D U . . .
F7 F 0.4605(9) 0.5569(9) 0.5459(13) 0.351(13) Uani 1 1 d D U . . .
F9 F 0.4205(12) 0.4591(9) 0.5114(12) 0.397(15) Uani 1 1 d D U . . .
C27 C 0.4580(8) 0.8736(9) 0.9679(11) 0.113(5) Uani 1 1 d . U . . .
C28 C 0.4739(7) 0.9170(8) 0.9302(10) 0.107(4) Uani 1 1 d . U . . .
H28A H 0.4424 0.9494 0.9051 0.161 Uiso 1 1 calc R U . . .
H28B H 0.4765 0.8965 0.8884 0.161 Uiso 1 1 calc R U . . .
H28C H 0.5139 0.9355 0.9708 0.161 Uiso 1 1 calc R U . . .
N9 N 0.4451(9) 0.8392(10) 1.0001(16) 0.195(10) Uani 1 1 d . . . . .
F11 F 0.4201(18) 0.5673(12) 0.622(2) 0.47(2) Uani 1 1 d D U . . .
N10 N 0.3590(10) 0.3293(10) 0.2743(13) 0.175(8) Uani 1 1 d D . . . .
C29 C 0.389(2) 0.3745(14) 0.279(4) 0.38(3) Uani 1 1 d D U . . .
C30 C 0.392(2) 0.4409(14) 0.286(3) 0.40(3) Uani 1 1 d D U . . .
H30A H 0.4113 0.4577 0.2597 0.605 Uiso 1 1 calc R U . . .
H30B H 0.4171 0.4524 0.3439 0.605 Uiso 1 1 calc R U . . .
H30C H 0.3506 0.4578 0.2604 0.605 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C19 2.110(7) . ?
Ag1 C4 2.124(7) . ?
Ag1 Ag2 3.2598(19) . ?
Ag2 N7 2.143(7) . ?
Ag2 N3 2.144(7) . ?
N1 C4 1.363(9) . ?
N1 C5 1.404(9) . ?
N1 C3 1.443(9) . ?
N7 C21 1.337(11) . ?
N7 N8 1.376(9) . ?
N3 C8 1.336(11) . ?
N3 N4 1.369(9) . ?
C2 C1 1.389(10) . ?
C2 C3 1.404(10) . ?
C1 C3 1.398(10) 2 ?
C15 C14 1.382(10) . ?
C15 C16 1.404(12) . ?
C15 N5 1.426(10) . ?
C7 N2 1.483(9) . ?
C7 C8 1.510(11) . ?
C3 C1 1.398(10) 2 ?
C20 N6 1.480(10) . ?
C20 C21 1.517(11) . ?
N5 C19 1.382(9) . ?
N5 C17 1.408(11) . ?
C8 C9 1.372(11) . ?
N2 C4 1.363(9) . ?
N2 C6 1.389(10) . ?
N4 C10 1.350(12) . ?
N4 C12 1.466(12) . ?
N6 C19 1.357(10) . ?
N6 C18 1.393(11) . ?
C21 C22 1.411(11) . ?
C22 C23 1.389(13) . ?
N8 C23 1.355(12) . ?
N8 C25 1.448(13) . ?
C9 C10 1.385(13) . ?
C5 C6 1.361(12) . ?
C18 C17 1.313(14) . ?
C24 C23 1.500(11) . ?
C12 C13 1.530(19) . ?
C10 C11 1.490(12) . ?
C25 C26 1.510(17) . ?
C14 C14 1.436(14) 2 ?
C16 C16 1.364(18) 2 ?
P1 F5 1.582(6) . ?
P1 F6 1.600(6) . ?
P1 F1 1.603(6) . ?
P1 F4 1.606(5) . ?
P1 F2 1.613(6) . ?
P1 F3 1.614(6) . ?
P3 F15 1.558(9) . ?
P3 F15 1.558(9) 2_655 ?
P3 F13 1.576(9) 2_655 ?
P3 F13 1.576(9) . ?
P3 F14 1.598(9) . ?
P3 F14 1.598(9) 2_655 ?
P2 F10 1.51(2) . ?
P2 F8 1.572(9) . ?
P2 F9 1.580(10) . ?
P2 F11 1.584(10) . ?
P2 F7 1.588(9) . ?
P2 F12 1.588(10) . ?
C27 N9 1.13(2) . ?
C27 C28 1.38(2) . ?
N10 C29 1.201(10) . ?
C29 C30 1.416(10) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C19 Ag1 C4 172.2(2) . . ?
C19 Ag1 Ag2 81.53(19) . . ?
C4 Ag1 Ag2 104.71(19) . . ?
N7 Ag2 N3 168.3(3) . . ?
N7 Ag2 Ag1 106.55(18) . . ?
N3 Ag2 Ag1 77.50(17) . . ?
C4 N1 C5 110.8(6) . . ?
C4 N1 C3 125.1(6) . . ?
C5 N1 C3 124.1(6) . . ?
C21 N7 N8 106.1(6) . . ?
C21 N7 Ag2 130.5(5) . . ?
N8 N7 Ag2 123.5(5) . . ?
C8 N3 N4 105.6(6) . . ?
C8 N3 Ag2 128.2(5) . . ?
N4 N3 Ag2 124.6(5) . . ?
C1 C2 C3 119.7(6) . . ?
C2 C1 C3 120.1(6) . 2 ?
C14 C15 C16 118.8(7) . . ?
C14 C15 N5 119.2(7) . . ?
C16 C15 N5 122.0(7) . . ?
N2 C7 C8 111.5(6) . . ?
C1 C3 C2 120.1(6) 2 . ?
C1 C3 N1 119.9(6) 2 . ?
C2 C3 N1 120.0(6) . . ?
N6 C20 C21 111.3(7) . . ?
C19 N5 C17 110.4(6) . . ?
C19 N5 C15 125.1(6) . . ?
C17 N5 C15 124.4(6) . . ?
N3 C8 C9 110.5(7) . . ?
N3 C8 C7 120.0(7) . . ?
C9 C8 C7 129.3(8) . . ?
C4 N2 C6 111.8(6) . . ?
C4 N2 C7 124.4(6) . . ?
C6 N2 C7 123.7(6) . . ?
C10 N4 N3 111.0(7) . . ?
C10 N4 C12 129.0(8) . . ?
N3 N4 C12 120.0(7) . . ?
C19 N6 C18 110.8(7) . . ?
C19 N6 C20 124.4(6) . . ?
C18 N6 C20 124.7(7) . . ?
N7 C21 C22 110.4(7) . . ?
N7 C21 C20 121.6(7) . . ?
C22 C21 C20 128.0(8) . . ?
N1 C4 N2 104.4(6) . . ?
N1 C4 Ag1 125.6(5) . . ?
N2 C4 Ag1 129.3(5) . . ?
C23 C22 C21 105.4(8) . . ?
C23 N8 N7 110.8(7) . . ?
C23 N8 C25 128.4(8) . . ?
N7 N8 C25 120.8(8) . . ?
C8 C9 C10 106.7(8) . . ?
C6 C5 N1 106.6(7) . . ?
N6 C19 N5 103.8(6) . . ?
N6 C19 Ag1 128.9(5) . . ?
N5 C19 Ag1 127.3(5) . . ?
C17 C18 N6 108.5(8) . . ?
C5 C6 N2 106.3(7) . . ?
N4 C12 C13 113.2(9) . . ?
N4 C10 C9 106.1(7) . . ?
N4 C10 C11 122.5(9) . . ?
C9 C10 C11 131.4(9) . . ?
N8 C23 C22 107.3(7) . . ?
N8 C23 C24 122.6(9) . . ?
C22 C23 C24 130.2(9) . . ?
C18 C17 N5 106.5(8) . . ?
N8 C25 C26 111.6(9) . . ?
C15 C14 C14 119.9(4) . 2 ?
C16 C16 C15 121.2(5) 2 . ?
F5 P1 F6 91.7(4) . . ?
F5 P1 F1 179.6(4) . . ?
F6 P1 F1 88.6(4) . . ?
F5 P1 F4 90.4(4) . . ?
F6 P1 F4 177.9(4) . . ?
F1 P1 F4 89.3(3) . . ?
F5 P1 F2 90.6(4) . . ?
F6 P1 F2 89.8(3) . . ?
F1 P1 F2 89.6(3) . . ?
F4 P1 F2 90.6(3) . . ?
F5 P1 F3 90.9(4) . . ?
F6 P1 F3 90.3(3) . . ?
F1 P1 F3 89.0(3) . . ?
F4 P1 F3 89.2(3) . . ?
F2 P1 F3 178.5(4) . . ?
F15 P3 F15 166(2) . 2_655 ?
F15 P3 F13 97.7(15) . 2_655 ?
F15 P3 F13 91.4(13) 2_655 2_655 ?
F15 P3 F13 91.4(13) . . ?
F15 P3 F13 97.7(15) 2_655 . ?
F13 P3 F13 95.2(19) 2_655 . ?
F15 P3 F14 83.0(12) . . ?
F15 P3 F14 87.0(14) 2_655 . ?
F13 P3 F14 175.1(16) 2_655 . ?
F13 P3 F14 89.6(6) . . ?
F15 P3 F14 87.0(14) . 2_655 ?
F15 P3 F14 83.0(12) 2_655 2_655 ?
F13 P3 F14 89.6(6) 2_655 2_655 ?
F13 P3 F14 175.1(16) . 2_655 ?
F14 P3 F14 85.6(18) . 2_655 ?
F10 P2 F8 165.0(15) . . ?
F10 P2 F9 76.2(13) . . ?
F8 P2 F9 91.1(7) . . ?
F10 P2 F11 96.8(17) . . ?
F8 P2 F11 96.0(17) . . ?
F9 P2 F11 172.8(18) . . ?
F10 P2 F7 81.5(12) . . ?
F8 P2 F7 90.7(6) . . ?
F9 P2 F7 90.3(7) . . ?
F11 P2 F7 90.5(7) . . ?
F10 P2 F12 97.5(13) . . ?
F8 P2 F12 91.6(12) . . ?
F9 P2 F12 95.5(14) . . ?
F11 P2 F12 83.5(15) . . ?
F7 P2 F12 173.8(14) . . ?
N9 C27 C28 178(2) . . ?
N10 C29 C30 143(2) . . ?

_refine_diff_density_max         4.563
_refine_diff_density_min         -1.932
_refine_diff_density_rms         0.170

_shelxl_version_number           2014-3

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_4S
_database_code_depnum_ccdc_archive 'CCDC 1958766'
loop_
_audit_author_name
_audit_author_address
'Chao Chen'
;Huzhou University
China
;
_audit_update_record             
;
2019-10-11 deposited with the CCDC.	2020-01-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C75 H75 Ag6 F36 N21 O3 P6'
_chemical_formula_weight         2835.60

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           4
_space_group_name_H-M_alt        'P 21'
_space_group_name_Hall           'P 2yb'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'

_cell_length_a                   13.876(8)
_cell_length_b                   25.304(14)
_cell_length_c                   15.283(8)
_cell_angle_alpha                90
_cell_angle_beta                 105.803(10)
_cell_angle_gamma                90
_cell_volume                     5163(5)
_cell_formula_units_Z            2
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    15592
_cell_measurement_theta_min      1.38
_cell_measurement_theta_max      25.01

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.824
_exptl_crystal_F_000             2784
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.22
_exptl_absorpt_coefficient_mu    1.328
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.715
_exptl_absorpt_correction_T_max  0.767
_exptl_absorpt_process_details   sadabs
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            26058
_diffrn_reflns_av_unetI/netI     0.0881
_diffrn_reflns_av_R_equivalents  0.0515
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -30
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_theta_min         1.385
_diffrn_reflns_theta_max         25.009
_diffrn_reflns_theta_full        25.009
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             15592
_reflns_number_gt                12294
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.952
_reflns_Friedel_fraction_max     0.999
_reflns_Friedel_fraction_full    0.999

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          
;
 Refined as a 2-component perfect inversion twin.
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0965P)²+8.2221P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_abs_structure_details 
;
 Refined as a perfect inversion twin.
;
_refine_ls_abs_structure_Flack   0.5
_chemical_absolute_configuration ?
_refine_ls_number_reflns         15592
_refine_ls_number_parameters     1330
_refine_ls_number_restraints     1500
_refine_ls_R_factor_all          0.0853
_refine_ls_R_factor_gt           0.0620
_refine_ls_wR_factor_ref         0.1738
_refine_ls_wR_factor_gt          0.1506
_refine_ls_goodness_of_fit_ref   1.033
_refine_ls_restrained_S_all      1.011
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.79274(9) 0.57397(5) 0.75349(8) 0.0354(3) Uani 1 1 d . . . . .
Ag2 Ag 0.96346(11) 0.64600(6) 0.78805(9) 0.0482(4) Uani 1 1 d D . . . .
Ag3 Ag 0.67407(8) 0.37752(5) 0.58559(8) 0.0354(3) Uani 1 1 d . . . . .
Ag4 Ag 0.49857(12) 0.31848(6) 0.49121(12) 0.0568(4) Uani 1 1 d D . . . .
Ag5 Ag 0.78609(8) 0.39352(5) 0.96842(8) 0.0341(3) Uani 1 1 d . . . . .
Ag6 Ag 0.70540(11) 0.37810(6) 1.12253(10) 0.0513(4) Uani 1 1 d D . . . .
C1 C 0.6433(18) 0.2856(9) 1.2210(15) 0.070(4) Uani 1 1 d . U . . .
H1 H 0.6503 0.3122 1.2643 0.084 Uiso 1 1 calc R U . . .
C2 C 0.6077(19) 0.2374(9) 1.2386(15) 0.075(4) Uani 1 1 d D U . . .
H2 H 0.5895 0.2312 1.2919 0.090 Uiso 1 1 calc R U . . .
C3 C 0.5999(19) 0.1990(9) 1.1750(15) 0.076(4) Uani 1 1 d D U . . .
H3 H 0.5729 0.1666 1.1843 0.091 Uiso 1 1 calc R U . . .
C4 C 0.6307(18) 0.2063(9) 1.0960(15) 0.070(3) Uani 1 1 d . U . . .
H4 H 0.6281 0.1789 1.0549 0.084 Uiso 1 1 calc R U . . .
C5 C 0.6643(16) 0.2548(8) 1.0818(14) 0.057(3) Uani 1 1 d . U . . .
C6 C 0.6953(16) 0.2665(8) 0.9972(13) 0.056(3) Uani 1 1 d . U . . .
H6A H 0.7623 0.2814 1.0140 0.068 Uiso 1 1 calc R U . . .
H6B H 0.6974 0.2338 0.9648 0.068 Uiso 1 1 calc R U . . .
C7 C 0.6530(13) 0.3509(7) 0.9194(11) 0.042(3) Uani 1 1 d . U . . .
C8 C 0.5317(15) 0.2912(8) 0.8898(13) 0.052(3) Uani 1 1 d . U . . .
H8 H 0.4982 0.2595 0.8914 0.063 Uiso 1 1 calc R U . . .
C9 C 0.4955(14) 0.3336(7) 0.8410(13) 0.049(3) Uani 1 1 d . U . . .
H9 H 0.4319 0.3369 0.8009 0.059 Uiso 1 1 calc R U . . .
C10 C 0.5651(12) 0.4191(7) 0.8163(11) 0.037(2) Uani 1 1 d . U . . .
C11 C 0.5390(12) 0.4202(7) 0.7213(11) 0.038(2) Uani 1 1 d . U . . .
H11 H 0.5186 0.3894 0.6883 0.045 Uiso 1 1 calc R U . . .
C12 C 0.5435(12) 0.4673(7) 0.6763(11) 0.037(2) Uani 1 1 d . U . . .
C13 C 0.5759(12) 0.5123(7) 0.7240(11) 0.037(2) Uani 1 1 d . U . . .
H13 H 0.5801 0.5434 0.6930 0.045 Uiso 1 1 calc R U . . .
C14 C 0.6028(12) 0.5124(7) 0.8187(11) 0.035(2) Uani 1 1 d . U . . .
C15 C 0.5949(12) 0.4655(7) 0.8633(11) 0.035(2) Uani 1 1 d . U . . .
H15 H 0.6100 0.4654 0.9265 0.042 Uiso 1 1 calc R U . . .
C16 C 0.5623(12) 0.4331(7) 0.5317(11) 0.040(3) Uani 1 1 d . U . . .
C17 C 0.4639(13) 0.5054(7) 0.5257(11) 0.042(3) Uani 1 1 d . U . . .
H17 H 0.4315 0.5337 0.5442 0.050 Uiso 1 1 calc R U . . .
C18 C 0.4615(14) 0.4929(8) 0.4393(12) 0.047(3) Uani 1 1 d . U . . .
H18 H 0.4262 0.5101 0.3865 0.056 Uiso 1 1 calc R U . . .
C19 C 0.5384(15) 0.4219(9) 0.3663(13) 0.054(3) Uani 1 1 d . U . . .
H19A H 0.5934 0.3970 0.3849 0.065 Uiso 1 1 calc R U . . .
H19B H 0.5560 0.4477 0.3263 0.065 Uiso 1 1 calc R U . . .
C20 C 0.4478(15) 0.3938(10) 0.3169(14) 0.060(3) Uani 1 1 d . U . . .
C21 C 0.3802(16) 0.4157(9) 0.2399(14) 0.064(3) Uani 1 1 d . U . . .
H21 H 0.3932 0.4480 0.2163 0.077 Uiso 1 1 calc R U . . .
C22 C 0.2938(16) 0.3876(10) 0.2004(15) 0.074(4) Uani 1 1 d . U . . .
H22 H 0.2451 0.4014 0.1513 0.089 Uiso 1 1 calc R U . . .
C23 C 0.2819(18) 0.3387(11) 0.2356(15) 0.077(4) Uani 1 1 d . U . . .
H23 H 0.2265 0.3183 0.2072 0.092 Uiso 1 1 calc R U . . .
C24 C 0.3476(17) 0.3200(10) 0.3092(15) 0.074(4) Uani 1 1 d . U . . .
H24 H 0.3368 0.2872 0.3322 0.088 Uiso 1 1 calc R U . . .
C25 C 0.7121(12) 0.5875(7) 0.8498(11) 0.037(3) Uani 1 1 d . U . . .
C26 C 0.6059(12) 0.5799(7) 0.9352(11) 0.039(2) Uani 1 1 d . U . . .
H26 H 0.5564 0.5664 0.9594 0.047 Uiso 1 1 calc R U . . .
C27 C 0.6592(13) 0.6248(7) 0.9604(12) 0.042(3) Uani 1 1 d . U . . .
H27 H 0.6531 0.6485 1.0051 0.050 Uiso 1 1 calc R U . . .
C28 C 0.7994(12) 0.6683(7) 0.9149(11) 0.040(3) Uani 1 1 d . U . . .
H28A H 0.7793 0.6996 0.9420 0.048 Uiso 1 1 calc R U . . .
H28B H 0.8043 0.6777 0.8548 0.048 Uiso 1 1 calc R U . . .
C29 C 0.9012(12) 0.6507(7) 0.9722(11) 0.038(3) Uani 1 1 d . U . . .
C30 C 0.9178(13) 0.6493(8) 1.0685(12) 0.046(3) Uani 1 1 d . U . . .
H30 H 0.8681 0.6592 1.0955 0.055 Uiso 1 1 calc R U . . .
C31 C 1.0114(13) 0.6327(8) 1.1202(12) 0.048(3) Uani 1 1 d . U . . .
H31 H 1.0241 0.6323 1.1832 0.057 Uiso 1 1 calc R U . . .
C32 C 1.0841(14) 0.6173(7) 1.0835(12) 0.045(3) Uani 1 1 d . U . . .
H32 H 1.1467 0.6067 1.1192 0.054 Uiso 1 1 calc R U . . .
C33 C 1.0597(13) 0.6180(7) 0.9846(12) 0.044(3) Uani 1 1 d . U . . .
H33 H 1.1076 0.6071 0.9561 0.052 Uiso 1 1 calc R U . . .
C34 C 0.4690(15) 0.2475(8) 0.6429(13) 0.052(3) Uani 1 1 d . U . . .
H34 H 0.4128 0.2691 0.6329 0.063 Uiso 1 1 calc R U . . .
C35 C 0.4772(16) 0.2056(8) 0.7004(14) 0.059(3) Uani 1 1 d . U . . .
H35 H 0.4266 0.1986 0.7281 0.070 Uiso 1 1 calc R U . . .
C36 C 0.5613(15) 0.1732(9) 0.7176(14) 0.058(3) Uani 1 1 d . U . . .
H36 H 0.5693 0.1448 0.7575 0.070 Uiso 1 1 calc R U . . .
C37 C 0.6321(14) 0.1853(8) 0.6729(13) 0.052(3) Uani 1 1 d . U . . .
H37 H 0.6892 0.1644 0.6825 0.062 Uiso 1 1 calc R U . . .
C38 C 0.6208(14) 0.2271(8) 0.6147(13) 0.049(3) Uani 1 1 d . U . . .
C39 C 0.7003(13) 0.2406(8) 0.5684(13) 0.047(3) Uani 1 1 d . U . . .
H39A H 0.7266 0.2084 0.5494 0.056 Uiso 1 1 calc R U . . .
H39B H 0.6712 0.2616 0.5146 0.056 Uiso 1 1 calc R U . . .
C40 C 0.7828(12) 0.3222(7) 0.6440(11) 0.036(3) Uani 1 1 d . U . . .
C41 C 0.8651(12) 0.2445(7) 0.6884(12) 0.042(3) Uani 1 1 d . U . . .
H41 H 0.8785 0.2085 0.6928 0.051 Uiso 1 1 calc R U . . .
C42 C 0.9185(12) 0.2827(7) 0.7346(11) 0.039(3) Uani 1 1 d . U . . .
H42 H 0.9804 0.2788 0.7771 0.047 Uiso 1 1 calc R U . . .
C43 C 0.9031(10) 0.3805(7) 0.7454(10) 0.032(2) Uani 1 1 d . U . . .
C44 C 0.9333(10) 0.3892(7) 0.8393(10) 0.034(2) Uani 1 1 d . U . . .
H44 H 0.9357 0.3614 0.8798 0.040 Uiso 1 1 calc R U . . .
C45 C 0.9590(11) 0.4392(6) 0.8704(10) 0.032(2) Uani 1 1 d . U . . .
C46 C 0.9614(12) 0.4801(7) 0.8103(11) 0.036(2) Uani 1 1 d . U . . .
H46 H 0.9830 0.5137 0.8319 0.043 Uiso 1 1 calc R U . . .
C47 C 0.9315(12) 0.4701(7) 0.7185(11) 0.034(2) Uani 1 1 d . U . . .
C48 C 0.9013(12) 0.4207(7) 0.6824(11) 0.034(2) Uani 1 1 d . U . . .
H48 H 0.8810 0.4146 0.6200 0.041 Uiso 1 1 calc R U . . .
C49 C 1.0639(12) 0.4767(7) 1.0168(11) 0.039(3) Uani 1 1 d . U . . .
H49 H 1.1160 0.4911 0.9971 0.046 Uiso 1 1 calc R U . . .
C50 C 1.0531(13) 0.4776(7) 1.1038(12) 0.041(3) Uani 1 1 d . U . . .
H50 H 1.0976 0.4920 1.1552 0.049 Uiso 1 1 calc R U . . .
C51 C 0.9169(12) 0.4360(7) 1.0171(10) 0.033(3) Uani 1 1 d . U . . .
C52 C 0.9216(13) 0.4457(7) 1.1805(12) 0.042(3) Uani 1 1 d . U . . .
H52A H 0.8998 0.4094 1.1818 0.050 Uiso 1 1 calc R U . . .
H52B H 0.9736 0.4523 1.2363 0.050 Uiso 1 1 calc R U . . .
C53 C 0.8373(13) 0.4810(7) 1.1762(12) 0.043(3) Uani 1 1 d . U . . .
C54 C 0.8536(14) 0.5333(7) 1.2051(12) 0.049(3) Uani 1 1 d . U . . .
H54 H 0.9179 0.5475 1.2211 0.058 Uiso 1 1 calc R U . . .
C55 C 0.7697(14) 0.5647(8) 1.2094(13) 0.052(3) Uani 1 1 d . U . . .
H55 H 0.7783 0.5981 1.2356 0.063 Uiso 1 1 calc R U . . .
C56 C 0.6797(14) 0.5448(8) 1.1753(13) 0.050(3) Uani 1 1 d . U . . .
H56 H 0.6240 0.5660 1.1717 0.060 Uiso 1 1 calc R U . . .
C57 C 0.6657(14) 0.4939(8) 1.1451(12) 0.046(3) Uani 1 1 d . U . . .
H57 H 0.6006 0.4812 1.1229 0.056 Uiso 1 1 calc R U . . .
C58 C 0.8743(13) 0.5587(7) 0.6614(11) 0.043(3) Uani 1 1 d . U . . .
C59 C 0.9610(14) 0.5128(8) 0.5801(12) 0.048(3) Uani 1 1 d . U . . .
H59 H 0.9961 0.4855 0.5621 0.058 Uiso 1 1 calc R U . . .
C60 C 0.9366(14) 0.5595(8) 0.5381(13) 0.050(3) Uani 1 1 d . U . . .
H60 H 0.9522 0.5716 0.4862 0.061 Uiso 1 1 calc R U . . .
C61 C 0.8452(15) 0.6407(8) 0.5645(13) 0.052(3) Uani 1 1 d . U . . .
H61A H 0.8049 0.6419 0.5017 0.063 Uiso 1 1 calc R U . . .
H61B H 0.8037 0.6516 0.6031 0.063 Uiso 1 1 calc R U . . .
C62 C 0.9315(16) 0.6765(8) 0.5773(14) 0.054(3) Uani 1 1 d . U . . .
C63 C 0.9582(16) 0.6986(9) 0.5074(15) 0.060(3) Uani 1 1 d . U . . .
H63 H 0.9218 0.6915 0.4479 0.072 Uiso 1 1 calc R U . . .
C64 C 1.0396(17) 0.7320(9) 0.5242(15) 0.065(4) Uani 1 1 d . U . . .
H64 H 1.0583 0.7469 0.4756 0.078 Uiso 1 1 calc R U . . .
C65 C 1.0955(18) 0.7442(9) 0.6148(15) 0.064(4) Uani 1 1 d . U . . .
H65 H 1.1514 0.7661 0.6276 0.077 Uiso 1 1 calc R U . . .
C66 C 1.0608(17) 0.7208(9) 0.6825(16) 0.064(3) Uani 1 1 d . U . . .
H66 H 1.0936 0.7284 0.7428 0.076 Uiso 1 1 calc R U . . .
C67 C 1.170(2) 0.5762(15) 0.762(2) 0.105(5) Uani 1 1 d . U . . .
H67 H 1.1825 0.6120 0.7561 0.126 Uiso 1 1 calc R U . . .
C68 C 1.244(3) 0.5038(14) 0.777(3) 0.150(9) Uani 1 1 d D U . . .
H68A H 1.2869 0.5053 0.8380 0.225 Uiso 1 1 calc R U . . .
H68B H 1.2708 0.4790 0.7422 0.225 Uiso 1 1 calc R U . . .
H68C H 1.1783 0.4926 0.7782 0.225 Uiso 1 1 calc R U . . .
C69 C 1.311(2) 0.5608(18) 0.681(3) 0.149(8) Uani 1 1 d D U . . .
H69A H 1.3091 0.5953 0.6541 0.224 Uiso 1 1 calc R U . . .
H69B H 1.2959 0.5346 0.6337 0.224 Uiso 1 1 calc R U . . .
H69C H 1.3772 0.5545 0.7201 0.224 Uiso 1 1 calc R U . . .
C70 C 0.2901(18) 0.3841(12) 0.4836(16) 0.079(5) Uani 1 1 d . U . . .
H70 H 0.3032 0.4179 0.4658 0.094 Uiso 1 1 calc R U . . .
C71 C 0.193(2) 0.3070(10) 0.460(2) 0.117(8) Uani 1 1 d D U . . .
H71A H 0.2570 0.2908 0.4870 0.176 Uiso 1 1 calc R U . . .
H71B H 0.1628 0.2903 0.4025 0.176 Uiso 1 1 calc R U . . .
H71C H 0.1507 0.3032 0.4993 0.176 Uiso 1 1 calc R U . . .
C72 C 0.137(2) 0.3959(13) 0.3757(19) 0.111(7) Uani 1 1 d D U . . .
H72A H 0.1128 0.4242 0.4054 0.166 Uiso 1 1 calc R U . . .
H72B H 0.0824 0.3745 0.3428 0.166 Uiso 1 1 calc R U . . .
H72C H 0.1716 0.4103 0.3342 0.166 Uiso 1 1 calc R U . . .
C73 C 0.429(2) 0.3939(11) 1.0236(17) 0.080(5) Uani 1 1 d . U . . .
H73 H 0.4129 0.4273 0.9988 0.096 Uiso 1 1 calc R U . . .
C74 C 0.370(2) 0.3045(10) 1.031(2) 0.106(7) Uani 1 1 d D U . . .
H74A H 0.4096 0.2878 0.9966 0.159 Uiso 1 1 calc R U . . .
H74B H 0.3056 0.2876 1.0186 0.159 Uiso 1 1 calc R U . . .
H74C H 0.4033 0.3013 1.0950 0.159 Uiso 1 1 calc R U . . .
C75 C 0.2572(19) 0.3744(15) 0.949(2) 0.110(8) Uani 1 1 d D U . . .
H75A H 0.2551 0.4111 0.9326 0.166 Uiso 1 1 calc R U . . .
H75B H 0.2083 0.3676 0.9815 0.166 Uiso 1 1 calc R U . . .
H75C H 0.2427 0.3531 0.8949 0.166 Uiso 1 1 calc R U . . .
F1 F 0.7585(13) 0.7097(10) 0.3195(14) 0.138(7) Uani 1 1 d . U . . .
F2 F 0.7031(12) 0.7757(7) 0.2259(14) 0.120(6) Uani 1 1 d . . . . .
F3 F 0.7262(13) 0.6980(7) 0.1702(12) 0.117(6) Uani 1 1 d . . . . .
F4 F 0.8830(10) 0.6968(6) 0.2595(10) 0.088(4) Uani 1 1 d . . . . .
F5 F 0.8620(14) 0.7723(8) 0.3136(15) 0.139(8) Uani 1 1 d . . . . .
F6 F 0.8320(11) 0.7641(8) 0.1664(12) 0.116(6) Uani 1 1 d . . . . .
F7 F 0.7886(9) 0.4293(5) 0.4683(7) 0.059(3) Uani 1 1 d . . . . .
F8 F 0.9192(9) 0.3773(7) 0.4807(8) 0.086(4) Uani 1 1 d . . . . .
F9 F 0.8904(10) 0.4448(6) 0.3803(9) 0.081(4) Uani 1 1 d . . . . .
F10 F 0.7377(9) 0.4128(6) 0.3163(7) 0.076(4) Uani 1 1 d . . . . .
F11 F 0.7649(10) 0.3465(5) 0.4151(9) 0.073(4) Uani 1 1 d . . . . .
F12 F 0.8733(10) 0.3610(5) 0.3294(9) 0.077(4) Uani 1 1 d . . . . .
F13 F 0.9169(11) 0.3190(5) 0.1296(10) 0.083(4) Uani 1 1 d . . . . .
F14 F 1.0627(12) 0.2770(7) 0.1949(12) 0.121(7) Uani 1 1 d . . . . .
F15 F 1.0573(10) 0.3445(5) 0.0924(13) 0.104(6) Uani 1 1 d . . . . .
F16 F 0.9339(10) 0.3026(5) -0.0074(9) 0.076(4) Uani 1 1 d . . . . .
F17 F 0.9391(9) 0.2364(4) 0.0924(9) 0.070(3) Uani 1 1 d . . . . .
F18 F 1.0831(13) 0.2631(6) 0.0556(17) 0.134(8) Uani 1 1 d . . . . .
F19 F 0.3840(11) 0.1942(8) 0.4518(14) 0.133(8) Uani 1 1 d . . . . .
F20 F 0.4947(14) 0.2177(7) 0.3866(13) 0.126(7) Uani 1 1 d . . . . .
F21 F 0.5213(16) 0.1468(8) 0.4668(19) 0.197(14) Uani 1 1 d . . . . .
F22 F 0.3779(11) 0.1132(5) 0.3915(9) 0.084(4) Uani 1 1 d . . . . .
F23 F 0.3457(19) 0.1836(7) 0.3074(13) 0.150(9) Uani 1 1 d . . . . .
F24 F 0.4783(15) 0.1410(7) 0.3123(15) 0.138(8) Uani 1 1 d . . . . .
F25 F 0.424(2) 0.5352(15) 0.1514(19) 0.228(16) Uani 1 1 d . . . . .
F26 F 0.4268(14) 0.5258(9) 0.018(2) 0.167(11) Uani 1 1 d . . . . .
F27 F 0.2861(14) 0.5166(10) 0.0428(19) 0.170(10) Uani 1 1 d . . . . .
F28 F 0.3170(16) 0.5858(18) 0.124(3) 0.32(3) Uani 1 1 d . . . . .
F29 F 0.4532(12) 0.6039(7) 0.0768(15) 0.124(7) Uani 1 1 d . . . . .
F30 F 0.311(2) 0.5888(12) -0.022(2) 0.26(2) Uani 1 1 d . . . . .
F31 F 0.192(3) 0.6142(11) 0.4535(19) 0.25(2) Uani 1 1 d . . . . .
F32 F 0.2619(16) 0.5553(16) 0.401(3) 0.266(19) Uani 1 1 d . . . . .
F33 F 0.150(3) 0.5311(11) 0.4627(14) 0.231(17) Uani 1 1 d . . . . .
F34 F 0.0488(17) 0.5907(15) 0.371(2) 0.210(14) Uani 1 1 d . . . . .
F35 F 0.1678(14) 0.6094(8) 0.3124(13) 0.130(7) Uani 1 1 d . . . . .
F36 F 0.1127(17) 0.5303(8) 0.3121(13) 0.143(8) Uani 1 1 d . . . . .
N1 N 0.6700(14) 0.2967(7) 1.1402(11) 0.060(5) Uani 1 1 d . . . . .
N2 N 0.6281(11) 0.3030(5) 0.9375(9) 0.038(3) Uani 1 1 d . . . . .
N3 N 0.5672(9) 0.3712(6) 0.8598(9) 0.041(3) Uani 1 1 d . . . . .
N4 N 0.5235(10) 0.4681(5) 0.5818(8) 0.034(3) Uani 1 1 d . . . . .
N5 N 0.5239(10) 0.4484(5) 0.4458(8) 0.033(3) Uani 1 1 d . . . . .
N6 N 0.4279(11) 0.3474(8) 0.3501(11) 0.061(5) Uani 1 1 d . . . . .
N7 N 0.6393(9) 0.5585(5) 0.8676(8) 0.031(3) Uani 1 1 d . . . . .
N8 N 0.7241(10) 0.6285(5) 0.9066(9) 0.036(3) Uani 1 1 d . . . . .
N9 N 0.9673(10) 0.6344(6) 0.9325(9) 0.038(3) Uani 1 1 d . . . . .
N10 N 0.9232(10) 0.5134(5) 0.6559(9) 0.034(3) Uani 1 1 d . . . . .
N11 N 0.8835(10) 0.5855(5) 0.5887(9) 0.036(3) Uani 1 1 d . . . . .
N12 N 0.9805(12) 0.6872(6) 0.6648(10) 0.048(4) Uani 1 1 d . . . . .
N13 N 0.9813(9) 0.4498(5) 0.9649(8) 0.031(3) Uani 1 1 d . . . . .
N14 N 0.9643(9) 0.4533(5) 1.0999(8) 0.029(3) Uani 1 1 d . . . . .
N15 N 0.7427(11) 0.4612(6) 1.1460(9) 0.040(3) Uani 1 1 d . . . . .
N16 N 0.8689(9) 0.3293(5) 0.7107(8) 0.031(3) Uani 1 1 d . . . . .
N17 N 0.7828(10) 0.2705(5) 0.6302(9) 0.034(3) Uani 1 1 d . . . . .
N18 N 0.5405(11) 0.2588(6) 0.5996(11) 0.050(4) Uani 1 1 d . . . . .
N19 N 1.2379(19) 0.5579(11) 0.7338(16) 0.104(7) Uani 1 1 d D U . . .
N20 N 0.2081(14) 0.3631(7) 0.4448(19) 0.102(9) Uani 1 1 d D . . . .
N21 N 0.3565(15) 0.3613(8) 1.0064(15) 0.084(7) Uani 1 1 d D . . . .
O1 O 1.1048(11) 0.5802(7) 0.7897(12) 0.084(5) Uani 1 1 d D . . . .
O2 O 0.3593(11) 0.3605(8) 0.5487(15) 0.109(7) Uani 1 1 d D . . . .
O3 O 0.5141(11) 0.3893(10) 1.0653(17) 0.136(10) Uani 1 1 d D . . . .
P1 P 0.7928(4) 0.7362(3) 0.2410(4) 0.0607(15) Uani 1 1 d . . . . .
P2 P 0.8303(4) 0.3948(2) 0.3978(3) 0.0477(12) Uani 1 1 d . . . . .
P3 P 0.9997(4) 0.2902(2) 0.0939(4) 0.0585(15) Uani 1 1 d . . . . .
P4 P 0.4348(5) 0.1654(3) 0.3887(5) 0.0688(18) Uani 1 1 d . . . . .
P5 P 0.3681(5) 0.5610(3) 0.0623(7) 0.095(3) Uani 1 1 d . . . . .
P6 P 0.1586(4) 0.5691(3) 0.3869(4) 0.0672(16) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C58 2.069(18) . ?
Ag1 C25 2.106(17) . ?
Ag1 Ag2 2.921(2) . ?
Ag2 N9 2.214(13) . ?
Ag2 N12 2.221(15) . ?
Ag2 O1 2.568(14) . ?
Ag3 C40 2.074(17) . ?
Ag3 C16 2.089(17) . ?
Ag3 Ag4 2.886(2) . ?
Ag4 N18 2.199(17) . ?
Ag4 N6 2.235(17) . ?
Ag4 O2 2.562(15) . ?
Ag5 C51 2.066(16) . ?
Ag5 C7 2.092(17) . ?
Ag5 Ag6 2.896(2) . ?
Ag6 N1 2.151(17) . ?
Ag6 N15 2.172(15) . ?
Ag6 O3 2.574(15) . ?
C1 C2 1.37(3) . ?
C1 N1 1.41(3) . ?
C2 C3 1.36(2) . ?
C3 C4 1.40(3) . ?
C4 C5 1.35(3) . ?
C5 N1 1.37(3) . ?
C5 C6 1.50(3) . ?
C6 N2 1.45(2) . ?
C7 N2 1.31(2) . ?
C7 N3 1.39(2) . ?
C8 C9 1.33(3) . ?
C8 N2 1.37(2) . ?
C9 N3 1.35(2) . ?
C10 N3 1.38(2) . ?
C10 C15 1.38(2) . ?
C10 C11 1.40(2) . ?
C11 C12 1.39(2) . ?
C12 C13 1.36(2) . ?
C12 N4 1.39(2) . ?
C13 C14 1.39(2) . ?
C14 C15 1.39(2) . ?
C14 N7 1.40(2) . ?
C16 N5 1.33(2) . ?
C16 N4 1.37(2) . ?
C17 C18 1.35(3) . ?
C17 N4 1.39(2) . ?
C18 N5 1.41(2) . ?
C19 N5 1.45(2) . ?
C19 C20 1.46(3) . ?
C20 N6 1.34(3) . ?
C20 C21 1.40(3) . ?
C21 C22 1.38(3) . ?
C22 C23 1.38(4) . ?
C23 C24 1.33(3) . ?
C24 N6 1.32(3) . ?
C25 N8 1.33(2) . ?
C25 N7 1.33(2) . ?
C26 C27 1.35(2) . ?
C26 N7 1.35(2) . ?
C27 N8 1.38(2) . ?
C28 N8 1.43(2) . ?
C28 C29 1.51(2) . ?
C29 N9 1.30(2) . ?
C29 C30 1.43(2) . ?
C30 C31 1.39(2) . ?
C31 C32 1.34(3) . ?
C32 C33 1.46(2) . ?
C33 N9 1.38(2) . ?
C34 C35 1.36(3) . ?
C34 N18 1.37(3) . ?
C35 C36 1.39(3) . ?
C36 C37 1.37(3) . ?
C37 C38 1.36(3) . ?
C38 N18 1.34(2) . ?
C38 C39 1.50(3) . ?
C39 N17 1.48(2) . ?
C40 N17 1.32(2) . ?
C40 N16 1.355(19) . ?
C41 C42 1.30(2) . ?
C41 N17 1.40(2) . ?
C42 N16 1.37(2) . ?
C43 C48 1.39(2) . ?
C43 C44 1.40(2) . ?
C43 N16 1.43(2) . ?
C44 C45 1.36(2) . ?
C45 C46 1.39(2) . ?
C45 N13 1.42(2) . ?
C46 C47 1.37(2) . ?
C47 C48 1.39(2) . ?
C47 N10 1.44(2) . ?
C49 C50 1.38(2) . ?
C49 N13 1.38(2) . ?
C50 N14 1.36(2) . ?
C51 N14 1.33(2) . ?
C51 N13 1.39(2) . ?
C52 C53 1.46(3) . ?
C52 N14 1.52(2) . ?
C53 N15 1.36(2) . ?
C53 C54 1.40(3) . ?
C54 C55 1.42(3) . ?
C55 C56 1.32(3) . ?
C56 C57 1.36(3) . ?
C57 N15 1.35(2) . ?
C58 N11 1.34(2) . ?
C58 N10 1.35(2) . ?
C59 C60 1.34(3) . ?
C59 N10 1.40(2) . ?
C60 N11 1.37(2) . ?
C61 C62 1.47(3) . ?
C61 N11 1.51(2) . ?
C62 C63 1.35(3) . ?
C62 N12 1.35(2) . ?
C63 C64 1.38(3) . ?
C64 C65 1.42(3) . ?
C65 C66 1.39(3) . ?
C66 N12 1.37(3) . ?
C67 O1 1.10(3) . ?
C67 N19 1.23(4) . ?
C68 N19 1.51(2) . ?
C69 N19 1.46(2) . ?
C70 N20 1.25(3) . ?
C70 O2 1.32(3) . ?
C71 N20 1.46(2) . ?
C72 N20 1.48(2) . ?
C73 O3 1.18(3) . ?
C73 N21 1.28(3) . ?
C74 N21 1.49(2) . ?
C75 N21 1.46(2) . ?
F1 P1 1.558(19) . ?
F2 P1 1.565(14) . ?
F3 P1 1.554(16) . ?
F4 P1 1.564(13) . ?
F5 P1 1.551(18) . ?
F6 P1 1.560(16) . ?
F7 P2 1.612(12) . ?
F8 P2 1.574(12) . ?
F9 P2 1.578(14) . ?
F10 P2 1.592(11) . ?
F11 P2 1.588(14) . ?
F12 P2 1.586(12) . ?
F13 P3 1.577(14) . ?
F14 P3 1.589(15) . ?
F15 P3 1.592(15) . ?
F16 P3 1.599(14) . ?
F17 P3 1.596(13) . ?
F18 P3 1.587(16) . ?
F19 P4 1.525(15) . ?
F20 P4 1.567(17) . ?
F21 P4 1.52(2) . ?
F22 P4 1.546(16) . ?
F23 P4 1.56(2) . ?
F24 P4 1.579(16) . ?
F25 P5 1.52(3) . ?
F26 P5 1.49(2) . ?
F27 P5 1.57(2) . ?
F28 P5 1.47(3) . ?
F29 P5 1.574(18) . ?
F30 P5 1.50(3) . ?
F31 P6 1.52(3) . ?
F32 P6 1.43(2) . ?
F33 P6 1.53(2) . ?
F34 P6 1.57(3) . ?
F35 P6 1.559(16) . ?
F36 P6 1.509(17) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C58 Ag1 C25 178.1(7) . . ?
C58 Ag1 Ag2 70.9(5) . . ?
C25 Ag1 Ag2 109.4(4) . . ?
N9 Ag2 N12 158.3(5) . . ?
N9 Ag2 O1 95.3(5) . . ?
N12 Ag2 O1 93.2(6) . . ?
N9 Ag2 Ag1 84.0(4) . . ?
N12 Ag2 Ag1 114.1(4) . . ?
O1 Ag2 Ag1 100.2(4) . . ?
C40 Ag3 C16 177.5(7) . . ?
C40 Ag3 Ag4 106.3(5) . . ?
C16 Ag3 Ag4 73.5(5) . . ?
N18 Ag4 N6 155.2(6) . . ?
N18 Ag4 O2 95.5(7) . . ?
N6 Ag4 O2 91.2(7) . . ?
N18 Ag4 Ag3 88.0(4) . . ?
N6 Ag4 Ag3 113.7(5) . . ?
O2 Ag4 Ag3 103.1(4) . . ?
C51 Ag5 C7 179.6(7) . . ?
C51 Ag5 Ag6 105.9(4) . . ?
C7 Ag5 Ag6 73.9(5) . . ?
N1 Ag6 N15 163.4(6) . . ?
N1 Ag6 O3 84.2(8) . . ?
N15 Ag6 O3 97.3(7) . . ?
N1 Ag6 Ag5 112.5(5) . . ?
N15 Ag6 Ag5 82.9(4) . . ?
O3 Ag6 Ag5 107.5(6) . . ?
C2 C1 N1 123(2) . . ?
C3 C2 C1 117(2) . . ?
C2 C3 C4 123(2) . . ?
C5 C4 C3 117(2) . . ?
C4 C5 N1 124(2) . . ?
C4 C5 C6 121(2) . . ?
N1 C5 C6 115.4(18) . . ?
N2 C6 C5 112.5(18) . . ?
N2 C7 N3 104.6(15) . . ?
N2 C7 Ag5 131.2(13) . . ?
N3 C7 Ag5 124.1(13) . . ?
C9 C8 N2 106.7(17) . . ?
C8 C9 N3 107.8(16) . . ?
N3 C10 C15 122.1(15) . . ?
N3 C10 C11 118.9(15) . . ?
C15 C10 C11 118.8(16) . . ?
C12 C11 C10 119.9(16) . . ?
C13 C12 C11 120.4(16) . . ?
C13 C12 N4 119.2(15) . . ?
C11 C12 N4 120.2(15) . . ?
C12 C13 C14 121.0(16) . . ?
C15 C14 C13 118.4(16) . . ?
C15 C14 N7 120.9(15) . . ?
C13 C14 N7 120.7(15) . . ?
C10 C15 C14 121.5(15) . . ?
N5 C16 N4 104.4(14) . . ?
N5 C16 Ag3 129.6(13) . . ?
N4 C16 Ag3 125.2(11) . . ?
C18 C17 N4 107.3(16) . . ?
C17 C18 N5 105.5(15) . . ?
N5 C19 C20 111.2(17) . . ?
N6 C20 C21 120(2) . . ?
N6 C20 C19 118.0(18) . . ?
C21 C20 C19 122(2) . . ?
C22 C21 C20 118(2) . . ?
C23 C22 C21 118(2) . . ?
C24 C23 C22 122(2) . . ?
N6 C24 C23 121(3) . . ?
N8 C25 N7 105.2(14) . . ?
N8 C25 Ag1 125.8(12) . . ?
N7 C25 Ag1 129.0(12) . . ?
C27 C26 N7 106.3(14) . . ?
C26 C27 N8 106.3(15) . . ?
N8 C28 C29 112.8(14) . . ?
N9 C29 C30 122.6(15) . . ?
N9 C29 C28 119.4(14) . . ?
C30 C29 C28 117.8(15) . . ?
C31 C30 C29 117.3(17) . . ?
C32 C31 C30 122.9(18) . . ?
C31 C32 C33 116.3(17) . . ?
N9 C33 C32 121.3(17) . . ?
C35 C34 N18 122(2) . . ?
C34 C35 C36 120(2) . . ?
C37 C36 C35 117(2) . . ?
C38 C37 C36 122(2) . . ?
N18 C38 C37 121(2) . . ?
N18 C38 C39 117.7(17) . . ?
C37 C38 C39 120.9(18) . . ?
N17 C39 C38 110.8(15) . . ?
N17 C40 N16 102.4(13) . . ?
N17 C40 Ag3 129.0(11) . . ?
N16 C40 Ag3 128.5(12) . . ?
C42 C41 N17 104.0(16) . . ?
C41 C42 N16 109.0(15) . . ?
C48 C43 C44 122.6(15) . . ?
C48 C43 N16 117.5(13) . . ?
C44 C43 N16 119.9(14) . . ?
C45 C44 C43 118.6(15) . . ?
C44 C45 C46 120.8(15) . . ?
C44 C45 N13 119.6(14) . . ?
C46 C45 N13 119.5(14) . . ?
C47 C46 C45 118.8(16) . . ?
C46 C47 C48 123.2(16) . . ?
C46 C47 N10 119.1(15) . . ?
C48 C47 N10 117.5(14) . . ?
C47 C48 C43 115.9(15) . . ?
C50 C49 N13 105.7(15) . . ?
N14 C50 C49 106.5(14) . . ?
N14 C51 N13 103.5(13) . . ?
N14 C51 Ag5 132.2(12) . . ?
N13 C51 Ag5 124.2(11) . . ?
C53 C52 N14 111.8(14) . . ?
N15 C53 C54 120.9(17) . . ?
N15 C53 C52 118.5(16) . . ?
C54 C53 C52 120.5(17) . . ?
C53 C54 C55 118.6(18) . . ?
C56 C55 C54 117.9(19) . . ?
C55 C56 C57 122(2) . . ?
N15 C57 C56 122.4(18) . . ?
N11 C58 N10 102.5(15) . . ?
N11 C58 Ag1 131.6(13) . . ?
N10 C58 Ag1 125.5(12) . . ?
C60 C59 N10 106.5(17) . . ?
C59 C60 N11 104.9(17) . . ?
C62 C61 N11 108.6(16) . . ?
C63 C62 N12 122(2) . . ?
C63 C62 C61 123(2) . . ?
N12 C62 C61 115.3(17) . . ?
C62 C63 C64 120(2) . . ?
C63 C64 C65 121(2) . . ?
C66 C65 C64 115(2) . . ?
N12 C66 C65 123(2) . . ?
O1 C67 N19 163(4) . . ?
N20 C70 O2 123(3) . . ?
O3 C73 N21 132(3) . . ?
C5 N1 C1 115.7(18) . . ?
C5 N1 Ag6 129.2(14) . . ?
C1 N1 Ag6 115.1(14) . . ?
C7 N2 C8 111.4(15) . . ?
C7 N2 C6 124.2(15) . . ?
C8 N2 C6 124.3(15) . . ?
C9 N3 C10 126.8(14) . . ?
C9 N3 C7 109.3(15) . . ?
C10 N3 C7 123.0(14) . . ?
C16 N4 C17 110.7(14) . . ?
C16 N4 C12 124.8(13) . . ?
C17 N4 C12 124.6(14) . . ?
C16 N5 C18 112.0(14) . . ?
C16 N5 C19 125.6(15) . . ?
C18 N5 C19 122.3(14) . . ?
C24 N6 C20 121.2(19) . . ?
C24 N6 Ag4 112.2(17) . . ?
C20 N6 Ag4 124.8(13) . . ?
C25 N7 C26 111.7(14) . . ?
C25 N7 C14 122.1(14) . . ?
C26 N7 C14 126.2(14) . . ?
C25 N8 C27 110.5(14) . . ?
C25 N8 C28 124.3(15) . . ?
C27 N8 C28 125.0(15) . . ?
C29 N9 C33 119.5(14) . . ?
C29 N9 Ag2 126.6(11) . . ?
C33 N9 Ag2 112.5(11) . . ?
C58 N10 C59 111.7(14) . . ?
C58 N10 C47 123.8(14) . . ?
C59 N10 C47 124.4(14) . . ?
C58 N11 C60 114.3(15) . . ?
C58 N11 C61 124.6(15) . . ?
C60 N11 C61 121.0(14) . . ?
C62 N12 C66 118.8(17) . . ?
C62 N12 Ag2 127.2(13) . . ?
C66 N12 Ag2 113.2(13) . . ?
C49 N13 C51 110.9(13) . . ?
C49 N13 C45 126.5(14) . . ?
C51 N13 C45 122.6(12) . . ?
C51 N14 C50 113.4(14) . . ?
C51 N14 C52 121.9(13) . . ?
C50 N14 C52 124.7(13) . . ?
C57 N15 C53 117.8(15) . . ?
C57 N15 Ag6 116.1(12) . . ?
C53 N15 Ag6 125.1(12) . . ?
C40 N16 C42 111.3(13) . . ?
C40 N16 C43 122.4(13) . . ?
C42 N16 C43 126.3(12) . . ?
C40 N17 C41 113.3(13) . . ?
C40 N17 C39 125.0(14) . . ?
C41 N17 C39 121.4(14) . . ?
C38 N18 C34 118.0(18) . . ?
C38 N18 Ag4 125.3(14) . . ?
C34 N18 Ag4 115.6(12) . . ?
C67 N19 C69 153(3) . . ?
C67 N19 C68 98(3) . . ?
C69 N19 C68 109(3) . . ?
C70 N20 C71 119(2) . . ?
C70 N20 C72 116(2) . . ?
C71 N20 C72 124(2) . . ?
C73 N21 C75 123(2) . . ?
C73 N21 C74 122(2) . . ?
C75 N21 C74 114(2) . . ?
C67 O1 Ag2 139(3) . . ?
C70 O2 Ag4 113.0(16) . . ?
C73 O3 Ag6 168(2) . . ?
F5 P1 F3 177.6(12) . . ?
F5 P1 F1 87.9(13) . . ?
F3 P1 F1 91.1(12) . . ?
F5 P1 F6 89.1(13) . . ?
F3 P1 F6 91.9(11) . . ?
F1 P1 F6 176.9(12) . . ?
F5 P1 F4 86.4(9) . . ?
F3 P1 F4 91.4(9) . . ?
F1 P1 F4 89.1(10) . . ?
F6 P1 F4 90.0(9) . . ?
F5 P1 F2 92.3(11) . . ?
F3 P1 F2 89.8(10) . . ?
F1 P1 F2 89.5(11) . . ?
F6 P1 F2 91.3(10) . . ?
F4 P1 F2 178.1(10) . . ?
F8 P2 F9 91.6(8) . . ?
F8 P2 F12 91.5(8) . . ?
F9 P2 F12 90.5(8) . . ?
F8 P2 F11 90.4(8) . . ?
F9 P2 F11 177.0(8) . . ?
F12 P2 F11 91.7(7) . . ?
F8 P2 F10 177.9(7) . . ?
F9 P2 F10 89.4(8) . . ?
F12 P2 F10 90.4(7) . . ?
F11 P2 F10 88.6(8) . . ?
F8 P2 F7 87.7(7) . . ?
F9 P2 F7 88.9(7) . . ?
F12 P2 F7 179.0(8) . . ?
F11 P2 F7 88.9(6) . . ?
F10 P2 F7 90.4(7) . . ?
F13 P3 F18 177.9(9) . . ?
F13 P3 F14 91.2(11) . . ?
F18 P3 F14 90.2(12) . . ?
F13 P3 F15 91.3(8) . . ?
F18 P3 F15 87.0(9) . . ?
F14 P3 F15 92.8(9) . . ?
F13 P3 F17 88.2(7) . . ?
F18 P3 F17 93.5(8) . . ?
F14 P3 F17 89.0(8) . . ?
F15 P3 F17 178.1(8) . . ?
F13 P3 F16 88.1(8) . . ?
F18 P3 F16 90.5(11) . . ?
F14 P3 F16 178.5(9) . . ?
F15 P3 F16 88.5(8) . . ?
F17 P3 F16 89.7(7) . . ?
F21 P4 F19 93.0(14) . . ?
F21 P4 F22 90.8(12) . . ?
F19 P4 F22 93.6(10) . . ?
F21 P4 F23 179.0(12) . . ?
F19 P4 F23 87.7(12) . . ?
F22 P4 F23 88.6(10) . . ?
F21 P4 F20 88.1(13) . . ?
F19 P4 F20 87.1(10) . . ?
F22 P4 F20 178.7(11) . . ?
F23 P4 F20 92.5(12) . . ?
F21 P4 F24 94.6(15) . . ?
F19 P4 F24 171.8(14) . . ?
F22 P4 F24 89.2(8) . . ?
F23 P4 F24 84.7(13) . . ?
F20 P4 F24 90.2(9) . . ?
F28 P5 F26 166(3) . . ?
F28 P5 F30 97(3) . . ?
F26 P5 F30 97(2) . . ?
F28 P5 F25 80(2) . . ?
F26 P5 F25 86.5(19) . . ?
F30 P5 F25 177(2) . . ?
F28 P5 F27 88.6(16) . . ?
F26 P5 F27 86.7(12) . . ?
F30 P5 F27 89.2(16) . . ?
F25 P5 F27 91.8(16) . . ?
F28 P5 F29 95.2(16) . . ?
F26 P5 F29 89.6(10) . . ?
F30 P5 F29 89.9(14) . . ?
F25 P5 F29 89.3(13) . . ?
F27 P5 F29 176.1(14) . . ?
F32 P6 F36 99(2) . . ?
F32 P6 F31 88(2) . . ?
F36 P6 F31 170.8(18) . . ?
F32 P6 F33 91(2) . . ?
F36 P6 F33 93.5(12) . . ?
F31 P6 F33 92.1(14) . . ?
F32 P6 F35 89.6(17) . . ?
F36 P6 F35 88.6(12) . . ?
F31 P6 F35 85.8(14) . . ?
F33 P6 F35 177.8(15) . . ?
F32 P6 F34 174(2) . . ?
F36 P6 F34 85.3(15) . . ?
F31 P6 F34 87(2) . . ?
F33 P6 F34 93.7(19) . . ?
F35 P6 F34 85.8(14) . . ?

_refine_diff_density_max         1.079
_refine_diff_density_min         -1.002
_refine_diff_density_rms         0.199

