# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_DyGa4
_database_code_depnum_ccdc_archive 'CCDC 1891863'
loop_
_audit_author_name
_audit_author_address
'Feng SHAO'
;Xiamen University
China
;
_audit_update_record             
;
2019-01-18 deposited with the CCDC.	2019-05-06 downloaded from the CCDC.
;
_audit_creation_date             2019-01-15
_audit_creation_method           
;
Olex2 1.2
(compiled May 18 2018 14:05:52 for OlexSys, GUI svn.r5506)
;
_chemical_formula_moiety         'C86 H59.4 Dy Ga4 N11 O21, 2(C5 H6 N)'
_chemical_formula_sum            'C96 H71.396 Dy Ga4 N13 O21'
_chemical_formula_weight         2184.50
loop_
_atom_type_symbol
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_Cromer_Mann_a1
_atom_type_scat_Cromer_Mann_a2
_atom_type_scat_Cromer_Mann_a3
_atom_type_scat_Cromer_Mann_a4
_atom_type_scat_Cromer_Mann_b1
_atom_type_scat_Cromer_Mann_b2
_atom_type_scat_Cromer_Mann_b3
_atom_type_scat_Cromer_Mann_b4
_atom_type_scat_Cromer_Mann_c
_atom_type_scat_source
_atom_type_scat_dispersion_source
C 0.01920 0.00962 2.31000 1.02000 1.58860 0.86500 20.84390 10.20750 0.56870
51.65120 0.215599998832
'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Henke, Gullikson and Davis, At. Data and Nucl. Data Tables, 1993, 54, 2'
H 0.00000 0.00000 0.49300 0.32291 0.14019 0.04081 10.51090 26.12570 3.14236
57.79970 0.0030380000826
'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Henke, Gullikson and Davis, At. Data and Nucl. Data Tables, 1993, 54, 2'
O 0.05239 0.03376 3.04850 2.28680 1.54630 0.86700 13.27710 5.70110 0.32390
32.90890 0.250800013542
'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Henke, Gullikson and Davis, At. Data and Nucl. Data Tables, 1993, 54, 2'
N 0.03256 0.01839 12.21260 3.13220 2.01250 1.16630 0.00570 9.89330 28.99750
0.58260 -11.5290002823
'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Henke, Gullikson and Davis, At. Data and Nucl. Data Tables, 1993, 54, 2'
Ga -1.28491 0.80318 15.23540 6.70060 4.35910 2.96230 3.06690 0.24120 10.78050
61.41350 1.71889996529
'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Henke, Gullikson and Davis, At. Data and Nucl. Data Tables, 1993, 54, 2'
Dy -9.83679 9.93930 26.50700 17.63830 14.55960 2.96577 2.18020 0.20217 12.18990
111.87400 4.29727983475
'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Henke, Gullikson and Davis, At. Data and Nucl. Data Tables, 1993, 54, 2'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 x,y,z
2 -x,-y,-z

_symmetry_Int_Tables_number      2
_cell_length_a                   17.1258(3)
_cell_length_b                   17.3229(3)
_cell_length_c                   18.9600(13)
_cell_angle_alpha                103.853(7)
_cell_angle_beta                 107.388(8)
_cell_angle_gamma                94.941(7)
_cell_volume                     5135.6(5)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    55401
_cell_measurement_theta_min      2.50
_cell_measurement_theta_max      68.30
_cell_measurement_temperature    85
_exptl_absorpt_coefficient_mu    5.599
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            gold
_exptl_crystal_density_diffrn    1.4125
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    "'not measured'"
_exptl_crystal_description       prism
_exptl_crystal_F_000             2169.2012
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.16
_diffrn_reflns_av_R_equivalents  0.0763
_diffrn_reflns_av_unetI/netI     0.0676
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            79507
_diffrn_reflns_theta_full        68.2325
_diffrn_reflns_theta_max         68.23
_diffrn_reflns_theta_min         2.54
_diffrn_measured_fraction_theta_full 0.9785
_diffrn_measured_fraction_theta_max 0.9785
_diffrn_ambient_temperature      85
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54178
_reflns_Friedel_coverage         0.0
_reflns_limit_h_max              19
_reflns_limit_h_min              -20
_reflns_limit_k_max              20
_reflns_limit_k_min              -20
_reflns_limit_l_max              22
_reflns_limit_l_min              0
_reflns_number_gt                17779
_reflns_number_total             18399
_reflns_threshold_expression     I>=2u(I)
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'olex2.refine (Bourhis et al., 2015)'
_refine_diff_density_max         3.4802
_refine_diff_density_min         -2.0649
_refine_diff_density_rms         0.2627
_refine_ls_d_res_high            0.8301
_refine_ls_d_res_low             17.3756
_refine_ls_goodness_of_fit_ref   0.9828
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_constraints    144
_refine_ls_number_parameters     1219
_refine_ls_number_reflns         18399
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0805
_refine_ls_R_factor_gt           0.0793
_refine_ls_restrained_S_all      0.9828
_refine_ls_shift/su_max          0.0033
_refine_ls_shift/su_mean         0.0001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1790P)²+21.0113P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2383
_refine_ls_wR_factor_ref         0.2402
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All N(H) groups
 At 1.5 times of:
  All O(H) groups
2. Restrained distances
 H3-H95
 2.1 with sigma of 0.01
3.a Aromatic/amide H refined with riding coordinates:
 N6(H6), N1(H1), C26(H26), C33(H33), C75(H75), C53(H53), C29(H29), C83(H83),
 C22(H22), C59(H59), C84(H84), C30(H30), C11(H11), C37(H37), C71(H71), C15(H15),
  C86(H86), C17(H17), C31(H31), C52(H52), C9(H9), C44(H44), C18(H18a), C20(H20),
  C68(H68), C48(H48), C64(H64), C50(H50), C70(H70), C74(H74), C76(H76),
 C66(H66), C19(H19), C61(H61), C6(H6a), C7(H7), C4(H4), C62(H62), C28(H28),
 C85(H85), C82(H82), C72(H72), C81(H81), C55(H55), C73(H73), C8(H8), C79(H79),
 C63(H63), C78(H78), C80(H80), C51(H51), C69(H69), C77(H77), C87(H87), C90(H90),
  C95(H95), C91(H91), C40(H40), C42(H42), N12(H12), C89(H89), C39(H39),
 C88(H88), C41(H41), N13(H13), C92(H92), C96(H96), C94(H94), C93(H93), C67(H67)
3.b Idealised tetrahedral OH refined as rotating group:
 O18(H18), O3(H3)
;
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_refinement_flags_posn
Dy1 Dy 0.10959(2) 0.21333(2) 0.87501(2) 0.02735(14) Uani 1.000000 .
Ga1 Ga 0.05449(5) 0.12676(5) 0.67824(4) 0.02886(19) Uani 1.000000 .
Ga3 Ga 0.26054(5) 0.25122(5) 1.05302(4) 0.02838(19) Uani 1.000000 .
Ga4 Ga 0.30247(5) 0.30470(5) 0.83579(4) 0.02886(19) Uani 1.000000 .
Ga2 Ga 0.17406(5) 0.00026(4) 0.86769(4) 0.02853(19) Uani 1.000000 .
O20 O 0.1779(3) 0.1144(3) 0.9192(3) 0.0306(9) Uani 1.000000 .
O19 O -0.0069(3) 0.1294(3) 0.8816(3) 0.0389(11) Uani 1.000000 .
O4 O 0.2751(3) 0.2893(3) 0.7262(3) 0.0351(10) Uani 1.000000 .
O17 O 0.1374(3) 0.2579(3) 1.0163(2) 0.0293(9) Uani 1.000000 .
O5 O 0.2018(3) 0.2275(3) 0.8027(2) 0.0295(9) Uani 1.000000 .
O1 O 0.0949(3) 0.3418(3) 0.8600(3) 0.0351(10) Uani 1.000000 .
O7 O 0.3744(3) 0.2591(3) 1.0495(2) 0.0312(9) Uani 1.000000 .
O13 O -0.0160(3) 0.2559(3) 0.9066(3) 0.0410(11) Uani 1.000000 .
O18 O 0.0552(3) 0.4630(3) 1.0243(3) 0.0346(10) Uani 1.000000 .
H18 H 0.033(3) 0.433(4) 1.0422(12) 0.0519(15) Uiso 1.000000 GR
O8 O 0.2434(3) 0.2805(3) 0.9546(2) 0.0286(9) Uani 1.000000 .
O9 O 0.4145(3) 0.3079(3) 0.8500(3) 0.0379(11) Uani 1.000000 .
O2 O 0.0179(3) 0.2103(3) 0.7495(3) 0.0303(9) Uani 1.000000 .
O6 O 0.0324(3) 0.1643(3) 0.5904(3) 0.0353(10) Uani 1.000000 .
O12 O 0.1767(3) -0.1050(3) 0.8131(3) 0.0355(10) Uani 1.000000 .
O11 O 0.0804(3) 0.0946(2) 0.7742(2) 0.0277(9) Uani 1.000000 .
O16 O 0.2675(3) 0.3656(3) 1.1051(3) 0.0333(10) Uani 1.000000 .
O10 O 0.0981(3) 0.0276(3) 0.6458(3) 0.0321(9) Uani 1.000000 .
O15 O 0.2838(3) 0.2257(3) 1.1469(3) 0.0352(10) Uani 1.000000 .
O14 O 0.2299(3) -0.0008(3) 0.9732(3) 0.0339(10) Uani 1.000000 .
N7 N -0.0668(4) 0.0619(3) 0.6349(3) 0.0330(12) Uani 1.000000 .
N3 N 0.3159(3) 0.2850(3) 0.9356(3) 0.0307(11) Uani 1.000000 .
N2 N 0.1649(3) 0.2035(3) 0.7220(3) 0.0297(11) Uani 1.000000 .
N8 N 0.0593(4) -0.0403(3) 0.8790(3) 0.0325(11) Uani 1.000000 .
N10 N 0.2824(3) 0.4193(3) 0.8613(3) 0.0333(12) Uani 1.000000 .
N5 N 0.2237(3) 0.1333(3) 0.9971(3) 0.0299(11) Uani 1.000000 .
C13 C 0.1734(4) 0.2239(4) 0.6039(4) 0.0336(14) Uani 1.000000 .
N9 N 0.3002(4) 0.0318(3) 0.8639(3) 0.0355(12) Uani 1.000000 .
C27 C 0.6133(4) 0.2576(4) 0.9479(4) 0.0331(14) Uani 1.000000 .
N11 N -0.0477(4) 0.1845(4) 0.9013(3) 0.0395(13) Uani 1.000000 .
N6 N 0.1320(4) 0.3393(3) 1.0352(3) 0.0308(11) Uani 1.000000 .
H6 H 0.0857(4) 0.3555(3) 1.0181(3) 0.0370(14) Uiso 1.000000 R
N1 N 0.0192(4) 0.2860(3) 0.7363(3) 0.0328(12) Uani 1.000000 .
H1 H -0.0050(4) 0.2911(3) 0.6913(3) 0.0393(14) Uiso 1.000000 R
O3 O 0.0438(6) 0.3790(4) 0.6496(4) 0.068(2) Uani 1.000000 .
H3 H -0.0042(8) 0.3546(8) 0.6310(10) 0.102(3) Uiso 0.4(3) DGR
C26 C 0.5491(4) 0.2822(4) 0.8959(4) 0.0317(13) Uani 1.000000 .
H26 H 0.5585(4) 0.2949(4) 0.8538(4) 0.0380(16) Uiso 1.000000 R
O21 O -0.1108(4) 0.1692(4) 0.9145(4) 0.0591(16) Uani 1.000000 .
C33 C 0.5213(4) 0.2461(4) 1.0218(4) 0.0312(13) Uani 1.000000 .
H33 H 0.5118(4) 0.2348(4) 1.0644(4) 0.0375(16) Uiso 1.000000 R
C10 C 0.0552(4) 0.5724(4) 0.8350(4) 0.0337(14) Uani 1.000000 .
C58 C 0.1210(4) 0.5105(4) 1.0798(4) 0.0324(13) Uani 1.000000 .
C32 C 0.5980(4) 0.2371(4) 1.0115(4) 0.0330(14) Uani 1.000000 .
C34 C 0.1242(4) -0.0053(4) 0.7011(4) 0.0293(13) Uani 1.000000 .
N4 N 0.1204(3) 0.0273(3) 0.7705(3) 0.0294(11) Uani 1.000000 .
C56 C 0.2003(4) 0.3916(4) 1.0806(4) 0.0309(13) Uani 1.000000 .
C12 C 0.2065(4) 0.2397(4) 0.6878(4) 0.0299(13) Uani 1.000000 .
C5 C 0.0525(5) 0.5867(4) 0.7634(4) 0.0384(15) Uani 1.000000 .
C25 C 0.4734(4) 0.2880(4) 0.9053(4) 0.0314(13) Uani 1.000000 .
C24 C 0.4597(4) 0.2708(4) 0.9716(4) 0.0306(13) Uani 1.000000 .
C75 C -0.0888(5) -0.0758(5) 0.8270(5) 0.0450(17) Uani 1.000000 .
H75 H -0.1375(5) -0.0767(5) 0.7881(5) 0.054(2) Uiso 1.000000 R
C53 C 0.3660(5) -0.0557(5) 1.2257(4) 0.0414(16) Uani 1.000000 .
H53 H 0.3555(5) -0.1050(5) 1.1887(4) 0.0497(19) Uiso 1.000000 R
C29 C 0.7493(5) 0.2207(5) 0.9863(5) 0.0432(17) Uani 1.000000 .
H29 H 0.7998(5) 0.2152(5) 0.9782(5) 0.052(2) Uiso 1.000000 R
C83 C 0.2642(5) 0.5344(4) 0.9490(5) 0.0424(16) Uani 1.000000 .
H83 H 0.2590(5) 0.5578(4) 0.9966(5) 0.051(2) Uiso 1.000000 R
C46 C 0.2899(4) 0.0821(4) 1.1029(4) 0.0297(13) Uani 1.000000 .
C22 C 0.2264(5) 0.2460(4) 0.5676(4) 0.0362(14) Uani 1.000000 .
H22 H 0.2816(5) 0.2677(4) 0.5968(4) 0.0434(17) Uiso 1.000000 R
C59 C 0.1210(4) 0.5902(4) 1.1150(4) 0.0361(14) Uani 1.000000 .
H59 H 0.0729(4) 0.6118(4) 1.0998(4) 0.0433(17) Uiso 1.000000 R
C57 C 0.1959(4) 0.4776(4) 1.1047(4) 0.0337(14) Uani 1.000000 .
C54 C 0.3463(4) 0.0146(4) 1.2026(4) 0.0361(14) Uani 1.000000 .
C49 C 0.3611(5) 0.0884(4) 1.2600(4) 0.0371(15) Uani 1.000000 .
C84 C 0.2632(5) 0.5794(5) 0.8969(5) 0.0440(17) Uani 1.000000 .
H84 H 0.2572(5) 0.6334(5) 0.9089(5) 0.053(2) Uiso 1.000000 R
C35 C 0.1565(4) -0.0815(4) 0.6870(4) 0.0340(14) Uani 1.000000 .
C30 C 0.7343(5) 0.2000(5) 1.0496(5) 0.0427(17) Uani 1.000000 .
H30 H 0.7743(5) 0.1801(5) 1.0824(5) 0.051(2) Uiso 1.000000 R
C11 C 0.0586(4) 0.4936(4) 0.8423(4) 0.0332(14) Uani 1.000000 .
H11 H 0.0630(4) 0.4842(4) 0.8895(4) 0.0398(16) Uiso 1.000000 R
C21 C 0.2004(5) 0.2370(5) 0.4877(4) 0.0425(17) Uani 1.000000 .
C45 C 0.2468(4) 0.0711(4) 1.0210(4) 0.0316(13) Uani 1.000000 .
C37 C 0.1973(6) -0.2037(5) 0.7170(5) 0.0495(19) Uani 1.000000 .
H37 H 0.2149(6) -0.2330(5) 0.7523(5) 0.059(2) Uiso 1.000000 R
C2 C 0.0555(5) 0.4303(4) 0.7816(4) 0.0366(15) Uani 1.000000 .
C71 C -0.0983(4) 0.0196(4) 0.5606(4) 0.0354(14) Uani 1.000000 .
H71 H -0.0665(4) 0.0215(4) 0.5287(4) 0.0424(17) Uiso 1.000000 R
C16 C 0.1147(5) 0.2085(4) 0.4453(4) 0.0402(16) Uani 1.000000 .
C15 C 0.0611(5) 0.1846(4) 0.4829(4) 0.0382(15) Uani 1.000000 .
H15 H 0.0056(5) 0.1645(4) 0.4541(4) 0.0458(18) Uiso 1.000000 R
C60 C 0.1910(5) 0.6394(4) 1.1729(4) 0.0397(15) Uani 1.000000 .
C1 C 0.0584(4) 0.3489(4) 0.7942(4) 0.0296(13) Uani 1.000000 .
C86 C 0.2818(5) 0.4630(5) 0.8115(4) 0.0430(17) Uani 1.000000 .
H86 H 0.2887(5) 0.4390(5) 0.7648(4) 0.052(2) Uiso 1.000000 R
C17 C 0.0858(6) 0.2040(5) 0.3652(5) 0.0503(19) Uani 1.000000 .
H17 H 0.0299(6) 0.1863(5) 0.3364(5) 0.060(2) Uiso 1.000000 R
C14 C 0.0870(5) 0.1896(4) 0.5597(4) 0.0341(14) Uani 1.000000 .
C31 C 0.6611(4) 0.2095(4) 1.0623(4) 0.0355(14) Uani 1.000000 .
H31 H 0.6523(4) 0.1977(4) 1.1050(4) 0.0426(17) Uiso 1.000000 R
C52 C 0.4005(5) -0.0510(5) 1.3021(5) 0.0471(18) Uani 1.000000 .
H52 H 0.4139(5) -0.0972(5) 1.3163(5) 0.057(2) Uiso 1.000000 R
C36 C 0.1777(4) -0.1286(4) 0.7418(4) 0.0353(14) Uani 1.000000 .
C9 C 0.0548(5) 0.6373(4) 0.8965(4) 0.0369(15) Uani 1.000000 .
H9 H 0.0565(5) 0.6283(4) 0.9433(4) 0.0443(17) Uiso 1.000000 R
C44 C 0.1568(5) -0.1126(5) 0.6133(5) 0.0466(18) Uani 1.000000 .
H44 H 0.1468(5) -0.0803(5) 0.5799(5) 0.056(2) Uiso 1.000000 R
C18 C 0.1408(7) 0.2260(6) 0.3312(5) 0.056(2) Uani 1.000000 .
H18a H 0.1214(7) 0.2242(6) 0.2794(5) 0.067(3) Uiso 1.000000 R
C20 C 0.2554(6) 0.2587(6) 0.4508(5) 0.0500(19) Uani 1.000000 .
H20 H 0.3112(6) 0.2779(6) 0.4791(5) 0.060(2) Uiso 1.000000 R
C68 C -0.1918(5) 0.0134(5) 0.6535(5) 0.0464(17) Uani 1.000000 .
H68 H -0.2230(5) 0.0127(5) 0.6860(5) 0.056(2) Uiso 1.000000 R
C48 C 0.3405(5) 0.1583(5) 1.2374(4) 0.0383(15) Uani 1.000000 .
H48 H 0.3512(5) 0.2071(5) 1.2751(4) 0.0460(18) Uiso 1.000000 R
C64 C 0.3386(5) 0.6581(5) 1.2512(5) 0.052(2) Uani 1.000000 .
H64 H 0.3886(5) 0.6389(5) 1.2637(5) 0.063(2) Uiso 1.000000 R
C50 C 0.3958(5) 0.0909(5) 1.3393(5) 0.0481(19) Uani 1.000000 .
H50 H 0.4047(5) 0.1391(5) 1.3774(5) 0.058(2) Uiso 1.000000 R
C70 C -0.1758(5) -0.0264(5) 0.5303(5) 0.0480(18) Uani 1.000000 .
H70 H -0.1964(5) -0.0549(5) 0.4784(5) 0.058(2) Uiso 1.000000 R
C74 C -0.0921(5) -0.1050(5) 0.8869(5) 0.0444(17) Uani 1.000000 .
H74 H -0.1423(5) -0.1271(5) 0.8896(5) 0.053(2) Uiso 1.000000 R
C3 C 0.0491(6) 0.4443(4) 0.7089(5) 0.0470(19) Uani 1.000000 .
C65 C 0.2669(5) 0.6081(4) 1.1926(4) 0.0401(16) Uani 1.000000 .
C76 C -0.0130(4) -0.0450(4) 0.8241(4) 0.0355(14) Uani 1.000000 .
H76 H -0.0121(4) -0.0266(4) 0.7821(4) 0.0426(17) Uiso 1.000000 R
C66 C 0.2666(4) 0.5268(4) 1.1576(4) 0.0365(14) Uani 1.000000 .
H66 H 0.3154(4) 0.5057(4) 1.1706(4) 0.0439(17) Uiso 1.000000 R
C19 C 0.2276(6) 0.2518(6) 0.3734(5) 0.056(2) Uani 1.000000 .
H19 H 0.2646(6) 0.2637(6) 0.3486(5) 0.067(3) Uiso 1.000000 R
C61 C 0.1898(6) 0.7193(5) 1.2143(5) 0.0488(19) Uani 1.000000 .
H61 H 0.1409(6) 0.7405(5) 1.2031(5) 0.059(2) Uiso 1.000000 R
C6 C 0.0499(5) 0.6665(4) 0.7566(5) 0.0419(16) Uani 1.000000 .
H6a H 0.0489(5) 0.6770(4) 0.7105(5) 0.0503(19) Uiso 1.000000 R
C7 C 0.0489(5) 0.7271(4) 0.8157(5) 0.0434(17) Uani 1.000000 .
H7 H 0.0462(5) 0.7786(4) 0.8095(5) 0.052(2) Uiso 1.000000 R
C4 C 0.0497(6) 0.5212(5) 0.7008(5) 0.0452(18) Uani 1.000000 .
H4 H 0.0484(6) 0.5302(5) 0.6541(5) 0.054(2) Uiso 1.000000 R
C62 C 0.2595(6) 0.7648(5) 1.2702(6) 0.061(2) Uani 1.000000 .
H62 H 0.2576(6) 0.8171(5) 1.2962(6) 0.073(3) Uiso 1.000000 R
C28 C 0.6903(4) 0.2485(4) 0.9373(4) 0.0377(15) Uani 1.000000 .
H28 H 0.7010(4) 0.2617(4) 0.8960(4) 0.0452(18) Uiso 1.000000 R
C85 C 0.2714(6) 0.5420(5) 0.8275(5) 0.051(2) Uani 1.000000 .
H85 H 0.2699(6) 0.5704(5) 0.7914(5) 0.061(2) Uiso 1.000000 R
C23 C 0.3794(4) 0.2718(4) 0.9868(4) 0.0304(13) Uani 1.000000 .
C82 C 0.2728(5) 0.4555(4) 0.9288(4) 0.0378(15) Uani 1.000000 .
H82 H 0.2719(5) 0.4252(4) 0.9631(4) 0.0453(18) Uiso 1.000000 R
C72 C 0.0556(5) -0.0678(4) 0.9387(4) 0.0386(15) Uani 1.000000 .
H72 H 0.1046(5) -0.0645(4) 0.9781(4) 0.0463(19) Uiso 1.000000 R
C81 C 0.3587(5) -0.0057(5) 0.8975(5) 0.0477(18) Uani 1.000000 .
H81 H 0.3456(5) -0.0416(5) 0.9235(5) 0.057(2) Uiso 1.000000 R
C55 C 0.3107(4) 0.0132(4) 1.1254(4) 0.0338(14) Uani 1.000000 .
H55 H 0.3005(4) -0.0354(4) 1.0876(4) 0.0406(17) Uiso 1.000000 R
C73 C -0.0175(5) -0.1002(5) 0.9436(5) 0.0443(18) Uani 1.000000 .
H73 H -0.0170(5) -0.1193(5) 0.9856(5) 0.053(2) Uiso 1.000000 R
C8 C 0.0519(5) 0.7137(4) 0.8877(4) 0.0402(16) Uani 1.000000 .
H8 H 0.0520(5) 0.7563(4) 0.9284(4) 0.0483(19) Uiso 1.000000 R
C79 C 0.4594(6) 0.0601(6) 0.8564(6) 0.060(2) Uani 1.000000 .
H79 H 0.5127(6) 0.0704(6) 0.8544(6) 0.072(3) Uiso 1.000000 R
C63 C 0.3338(6) 0.7348(5) 1.2892(6) 0.063(2) Uani 1.000000 .
H63 H 0.3804(6) 0.7670(5) 1.3280(6) 0.076(3) Uiso 1.000000 R
C47 C 0.3049(4) 0.1564(4) 1.1612(4) 0.0328(13) Uani 1.000000 .
C78 C 0.3956(5) 0.0981(5) 0.8199(5) 0.051(2) Uani 1.000000 .
H78 H 0.4057(5) 0.1332(5) 0.7922(5) 0.061(2) Uiso 1.000000 R
C80 C 0.4401(6) 0.0073(6) 0.8950(6) 0.062(2) Uani 1.000000 .
H80 H 0.4802(6) -0.0195(6) 0.9191(6) 0.075(3) Uiso 1.000000 R
C51 C 0.4159(6) 0.0221(6) 1.3590(5) 0.052(2) Uani 1.000000 .
H51 H 0.4400(6) 0.0242(6) 1.4105(5) 0.062(2) Uiso 1.000000 R
C69 C -0.2233(5) -0.0303(5) 0.5768(5) 0.0445(17) Uani 1.000000 .
H69 H -0.2758(5) -0.0620(5) 0.5570(5) 0.053(2) Uiso 1.000000 R
C77 C 0.3193(5) 0.0824(4) 0.8260(5) 0.0399(16) Uani 1.000000 .
H77 H 0.2780(5) 0.1083(4) 0.8025(5) 0.0479(19) Uiso 1.000000 R
C87 C 0.1629(8) 0.4944(7) 1.2839(8) 0.075(3) Uani 1.000000 .
H87 H 0.1147(8) 0.5169(7) 1.2778(8) 0.090(4) Uiso 1.000000 R
C90 C 0.3063(7) 0.4301(9) 1.3067(7) 0.078(3) Uani 1.000000 .
H90 H 0.3550(7) 0.4086(9) 1.3152(7) 0.093(4) Uiso 1.000000 R
C43 C 0.1714(7) -0.1909(6) 0.5863(5) 0.065(3) Uani 1.000000 .
C95 C 0.1015(10) 0.4176(6) 0.5503(6) 0.072(3) Uani 1.000000 .
H95 H 0.0651(10) 0.4110(6) 0.5771(6) 0.086(4) Uiso 1.000000 DR
C91 C 0.2310(8) 0.3824(7) 1.2567(6) 0.067(3) Uani 1.000000 .
H91 H 0.2296(8) 0.3291(7) 1.2308(6) 0.081(3) Uiso 1.000000 R
C40 C 0.1934(16) -0.3502(10) 0.5356(9) 0.153(9) Uani 1.000000 .
H40 H 0.2009(16) -0.4030(10) 0.5180(9) 0.184(11) Uiso 1.000000 R
C42 C 0.1643(11) -0.2242(8) 0.5101(6) 0.105(5) Uani 1.000000 .
H42 H 0.1541(11) -0.1930(8) 0.4757(6) 0.126(7) Uiso 1.000000 R
N12 N 0.1596(7) 0.4144(7) 1.2460(6) 0.085(3) Uani 1.000000 .
H12 H 0.1129(7) 0.3851(7) 1.2160(6) 0.102(3) Uiso 1.000000 R
C89 C 0.3074(9) 0.5069(9) 1.3421(8) 0.087(4) Uani 1.000000 .
H89 H 0.3574(9) 0.5384(9) 1.3758(8) 0.105(4) Uiso 1.000000 R
C38 C 0.1915(8) -0.2374(6) 0.6396(6) 0.074(3) Uani 1.000000 .
C39 C 0.2031(14) -0.3174(8) 0.6125(7) 0.129(8) Uani 1.000000 .
H39 H 0.2175(14) -0.3484(8) 0.6467(7) 0.155(9) Uiso 1.000000 R
C88 C 0.2382(10) 0.5397(8) 1.3304(8) 0.087(4) Uani 1.000000 .
H88 H 0.2415(10) 0.5940(8) 1.3542(8) 0.104(4) Uiso 1.000000 R
C41 C 0.1723(17) -0.3033(11) 0.4855(8) 0.167(11) Uani 1.000000 .
H41 H 0.1633(17) -0.3261(11) 0.4335(8) 0.201(13) Uiso 1.000000 R
N13 N 0.2368(19) 0.4523(10) 0.5455(13) 0.195(11) Uani 1.000000 .
H13 H 0.2890(19) 0.4686(10) 0.5699(13) 0.235(13) Uiso 1.000000 R
C92 C 0.2081(12) 0.4384(9) 0.4688(9) 0.097(4) Uani 1.000000 .
H92 H 0.2435(12) 0.4451(9) 0.4411(9) 0.116(5) Uiso 1.000000 R
C96 C 0.1827(14) 0.4408(8) 0.5872(9) 0.102(5) Uani 1.000000 .
H96 H 0.2039(14) 0.4494(8) 0.6402(9) 0.122(6) Uiso 1.000000 R
C94 C 0.0744(10) 0.4043(7) 0.4763(7) 0.085(4) Uani 1.000000 .
H94 H 0.0176(10) 0.3872(7) 0.4514(7) 0.102(5) Uiso 1.000000 R
C93 C 0.1216(13) 0.4130(8) 0.4321(8) 0.098(5) Uani 1.000000 .
H93 H 0.0979(13) 0.4026(8) 0.3791(8) 0.117(6) Uiso 1.000000 R
C67 C -0.1121(5) 0.0586(5) 0.6808(5) 0.0412(16) Uani 1.000000 .
H67 H -0.0898(5) 0.0873(5) 0.7325(5) 0.0494(19) Uiso 1.000000 R


loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 Ga1 3.4686(9) . ?
Dy1 Ga3 3.4550(9) . ?
Dy1 O20 2.336(4) . ?
Dy1 O19 2.418(5) . ?
Dy1 O17 2.487(4) . ?
Dy1 O5 2.412(4) . ?
Dy1 O1 2.334(4) . ?
Dy1 O13 2.521(5) . ?
Dy1 O8 2.349(4) . ?
Dy1 O2 2.414(4) . ?
Dy1 O11 2.346(4) . ?
Dy1 N11 2.905(6) . ?
Dy1 C1 3.148(6) . ?
Ga1 O2 2.010(5) . ?
Ga1 O6 1.876(5) . ?
Ga1 O11 1.966(4) . ?
Ga1 O10 1.969(5) . ?
Ga1 N7 2.094(6) . ?
Ga1 N2 2.033(6) . ?
Ga3 O17 2.037(5) . ?
Ga3 O7 1.966(5) . ?
Ga3 O8 1.995(4) . ?
Ga3 O16 1.967(5) . ?
Ga3 O15 1.873(5) . ?
Ga3 N5 2.009(6) . ?
Ga4 O4 1.933(5) . ?
Ga4 O5 1.926(5) . ?
Ga4 O9 1.850(5) . ?
Ga4 N3 1.953(5) . ?
Ga4 N10 2.012(6) . ?
Ga2 O20 1.970(4) . ?
Ga2 O12 1.881(5) . ?
Ga2 O14 1.948(5) . ?
Ga2 N8 2.118(6) . ?
Ga2 N9 2.209(6) . ?
Ga2 N4 1.984(5) . ?
O20 N5 1.390(7) . ?
O19 N11 1.280(8) . ?
O4 C12 1.290(8) . ?
O17 N6 1.387(7) . ?
O5 N2 1.409(7) . ?
O1 C1 1.260(8) . ?
O7 C23 1.285(8) . ?
O13 N11 1.275(8) . ?
O18 C58 1.330(8) . ?
O8 N3 1.393(7) . ?
O9 C25 1.356(8) . ?
O2 N1 1.391(6) . ?
O6 C14 1.336(8) . ?
O12 C36 1.321(8) . ?
O11 N4 1.399(6) . ?
O16 C56 1.270(8) . ?
O10 C34 1.293(8) . ?
O15 C47 1.347(8) . ?
O14 C45 1.302(8) . ?
N7 C71 1.341(9) . ?
N7 C67 1.334(10) . ?
N3 C23 1.301(8) . ?
N2 C12 1.311(8) . ?
N8 C76 1.340(9) . ?
N8 C72 1.344(9) . ?
N10 C86 1.343(9) . ?
N10 C82 1.350(9) . ?
N5 C45 1.313(8) . ?
C13 C12 1.467(9) . ?
C13 C22 1.372(10) . ?
C13 C14 1.454(10) . ?
N9 C81 1.327(10) . ?
N9 C77 1.335(9) . ?
C27 C26 1.414(9) . ?
C27 C32 1.425(10) . ?
C27 C28 1.407(10) . ?
N11 O21 1.202(8) . ?
N6 C56 1.331(9) . ?
N1 C1 1.304(9) . ?
O3 C3 1.365(9) . ?
C26 C25 1.368(10) . ?
C33 C32 1.401(10) . ?
C33 C24 1.370(9) . ?
C10 C5 1.426(9) . ?
C10 C11 1.409(9) . ?
C10 C9 1.415(10) . ?
C58 C59 1.381(10) . ?
C58 C57 1.446(9) . ?
C32 C31 1.418(10) . ?
C34 N4 1.324(8) . ?
C34 C35 1.473(9) . ?
C56 C57 1.465(9) . ?
C5 C6 1.422(10) . ?
C5 C4 1.418(10) . ?
C25 C24 1.437(9) . ?
C24 C23 1.487(9) . ?
C75 C74 1.363(11) . ?
C75 C76 1.383(10) . ?
C53 C54 1.425(10) . ?
C53 C52 1.371(11) . ?
C29 C30 1.417(11) . ?
C29 C28 1.362(11) . ?
C83 C84 1.394(11) . ?
C83 C82 1.362(10) . ?
C46 C45 1.465(9) . ?
C46 C55 1.400(9) . ?
C46 C47 1.427(10) . ?
C22 C21 1.411(10) . ?
C59 C60 1.400(11) . ?
C57 C66 1.373(10) . ?
C54 C49 1.413(10) . ?
C54 C55 1.399(10) . ?
C49 C48 1.417(10) . ?
C49 C50 1.429(10) . ?
C84 C85 1.375(12) . ?
C35 C36 1.452(9) . ?
C35 C44 1.373(10) . ?
C30 C31 1.362(10) . ?
C11 C2 1.371(10) . ?
C21 C16 1.422(12) . ?
C21 C20 1.407(11) . ?
C37 C36 1.379(10) . ?
C37 C38 1.414(13) . ?
C2 C1 1.488(9) . ?
C2 C3 1.430(10) . ?
C71 C70 1.368(11) . ?
C16 C15 1.410(11) . ?
C16 C17 1.431(10) . ?
C15 C14 1.369(10) . ?
C60 C65 1.432(11) . ?
C60 C61 1.423(10) . ?
C86 C85 1.368(11) . ?
C17 C18 1.366(13) . ?
C52 C51 1.399(12) . ?
C9 C8 1.376(10) . ?
C44 C43 1.402(12) . ?
C18 C19 1.433(14) . ?
C20 C19 1.373(12) . ?
C68 C69 1.383(12) . ?
C68 C67 1.394(11) . ?
C48 C47 1.381(10) . ?
C64 C65 1.426(11) . ?
C64 C63 1.374(12) . ?
C50 C51 1.373(12) . ?
C70 C69 1.375(12) . ?
C74 C73 1.384(12) . ?
C3 C4 1.375(10) . ?
C65 C66 1.405(10) . ?
C61 C62 1.361(12) . ?
C6 C7 1.345(11) . ?
C7 C8 1.426(11) . ?
C62 C63 1.396(13) . ?
C72 C73 1.365(11) . ?
C81 C80 1.411(12) . ?
C79 C78 1.412(14) . ?
C79 C80 1.376(15) . ?
C78 C77 1.356(11) . ?
C87 N12 1.388(16) . ?
C87 C88 1.369(19) . ?
C90 C91 1.398(17) . ?
C90 C89 1.335(19) . ?
C43 C42 1.384(14) . ?
C43 C38 1.422(14) . ?
C95 C96 1.33(2) . ?
C95 C94 1.295(15) . ?
C91 N12 1.367(15) . ?
C40 C39 1.385(18) . ?
C40 C41 1.38(2) . ?
C42 C41 1.370(18) . ?
C89 C88 1.34(2) . ?
C38 C39 1.410(13) . ?
N13 C92 1.34(2) . ?
N13 C96 1.41(3) . ?
C92 C93 1.41(2) . ?
C94 C93 1.349(19) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ga3 Dy1 Ga1 146.52(2) . . ?
O20 Dy1 Ga1 99.52(11) . . ?
O20 Dy1 Ga3 56.37(11) . . ?
O19 Dy1 Ga1 91.50(12) . . ?
O19 Dy1 Ga3 105.15(13) . . ?
O19 Dy1 O20 80.65(16) . . ?
O17 Dy1 Ga1 171.93(10) . . ?
O17 Dy1 Ga3 35.60(10) . . ?
O17 Dy1 O20 76.45(14) . . ?
O17 Dy1 O19 80.99(16) . . ?
O5 Dy1 Ga1 56.81(10) . . ?
O5 Dy1 Ga3 97.19(10) . . ?
O5 Dy1 O20 90.45(15) . . ?
O5 Dy1 O19 145.34(16) . . ?
O5 Dy1 O17 129.53(15) . . ?
O1 Dy1 Ga1 92.60(11) . . ?
O1 Dy1 Ga3 103.69(12) . . ?
O1 Dy1 O20 156.69(17) . . ?
O1 Dy1 O19 119.10(17) . . ?
O1 Dy1 O17 93.64(15) . . ?
O1 Dy1 O5 79.58(16) . . ?
O13 Dy1 Ga1 109.26(12) . . ?
O13 Dy1 Ga3 103.81(12) . . ?
O13 Dy1 O20 123.36(16) . . ?
O13 Dy1 O19 51.76(16) . . ?
O13 Dy1 O17 68.32(16) . . ?
O13 Dy1 O5 146.09(16) . . ?
O13 Dy1 O1 69.82(17) . . ?
O8 Dy1 Ga1 124.24(10) . . ?
O8 Dy1 Ga3 33.88(10) . . ?
O8 Dy1 O20 74.62(16) . . ?
O8 Dy1 O19 138.99(16) . . ?
O8 Dy1 O17 61.84(14) . . ?
O8 Dy1 O5 67.69(14) . . ?
O8 Dy1 O1 82.09(16) . . ?
O8 Dy1 O13 120.11(16) . . ?
O2 Dy1 Ga1 34.40(11) . . ?
O2 Dy1 Ga3 169.05(10) . . ?
O2 Dy1 O20 131.17(15) . . ?
O2 Dy1 O19 84.89(16) . . ?
O2 Dy1 O17 146.19(15) . . ?
O2 Dy1 O5 75.98(15) . . ?
O2 Dy1 O1 66.94(15) . . ?
O2 Dy1 O13 78.79(16) . . ?
O2 Dy1 O8 135.78(14) . . ?
O11 Dy1 Ga1 32.86(10) . . ?
O11 Dy1 Ga3 125.12(10) . . ?
O11 Dy1 O20 69.78(15) . . ?
O11 Dy1 O19 73.51(16) . . ?
O11 Dy1 O17 140.24(14) . . ?
O11 Dy1 O5 71.98(15) . . ?
O11 Dy1 O1 125.31(15) . . ?
O11 Dy1 O13 114.38(16) . . ?
O11 Dy1 O8 124.95(15) . . ?
O11 Dy1 O2 61.40(14) . . ?
N11 Dy1 Ga1 101.96(12) . . ?
N11 Dy1 Ga3 105.52(12) . . ?
N11 Dy1 O20 102.03(17) . . ?
N11 Dy1 O19 25.81(17) . . ?
N11 Dy1 O17 72.43(16) . . ?
N11 Dy1 O5 157.29(16) . . ?
N11 Dy1 O1 94.76(17) . . ?
N11 Dy1 O13 25.96(17) . . ?
N11 Dy1 O8 133.75(16) . . ?
N11 Dy1 O2 81.56(16) . . ?
N11 Dy1 O11 94.42(16) . . ?
C1 Dy1 Ga1 72.74(12) . . ?
C1 Dy1 Ga3 123.24(12) . . ?
C1 Dy1 O20 163.44(16) . . ?
C1 Dy1 O19 113.62(17) . . ?
C1 Dy1 O17 112.94(15) . . ?
C1 Dy1 O5 73.04(15) . . ?
C1 Dy1 O1 20.44(17) . . ?
C1 Dy1 O13 73.20(16) . . ?
C1 Dy1 O8 97.31(16) . . ?
C1 Dy1 O2 46.88(16) . . ?
C1 Dy1 O11 105.13(16) . . ?
C1 Dy1 N11 93.99(17) . . ?
O2 Ga1 Dy1 42.72(12) . . ?
O6 Ga1 Dy1 136.10(15) . . ?
O6 Ga1 O2 101.96(19) . . ?
O11 Ga1 Dy1 40.37(12) . . ?
O11 Ga1 O2 75.38(16) . . ?
O11 Ga1 O6 176.38(19) . . ?
O10 Ga1 Dy1 116.31(13) . . ?
O10 Ga1 O2 156.17(18) . . ?
O10 Ga1 O6 101.9(2) . . ?
O10 Ga1 O11 80.87(17) . . ?
N7 Ga1 Dy1 110.15(16) . . ?
N7 Ga1 O2 88.7(2) . . ?
N7 Ga1 O6 89.2(2) . . ?
N7 Ga1 O11 93.2(2) . . ?
N7 Ga1 O10 90.7(2) . . ?
N2 Ga1 Dy1 67.52(14) . . ?
N2 Ga1 O2 84.8(2) . . ?
N2 Ga1 O6 87.9(2) . . ?
N2 Ga1 O11 89.40(19) . . ?
N2 Ga1 O10 97.0(2) . . ?
N2 Ga1 N7 172.1(2) . . ?
O17 Ga3 Dy1 45.31(12) . . ?
O7 Ga3 Dy1 113.88(13) . . ?
O7 Ga3 O17 156.00(17) . . ?
O8 Ga3 Dy1 41.03(12) . . ?
O8 Ga3 O17 76.20(17) . . ?
O8 Ga3 O7 79.82(17) . . ?
O16 Ga3 Dy1 105.83(14) . . ?
O16 Ga3 O17 81.39(18) . . ?
O16 Ga3 O7 96.98(19) . . ?
O16 Ga3 O8 88.65(19) . . ?
O15 Ga3 Dy1 142.38(15) . . ?
O15 Ga3 O17 107.27(19) . . ?
O15 Ga3 O7 96.68(19) . . ?
O15 Ga3 O8 176.38(19) . . ?
O15 Ga3 O16 90.9(2) . . ?
N5 Ga3 Dy1 66.31(15) . . ?
N5 Ga3 O17 85.00(19) . . ?
N5 Ga3 O7 97.0(2) . . ?
N5 Ga3 O8 91.8(2) . . ?
N5 Ga3 O16 165.9(2) . . ?
N5 Ga3 O15 89.5(2) . . ?
O5 Ga4 O4 82.15(18) . . ?
O9 Ga4 O4 92.4(2) . . ?
O9 Ga4 O5 140.0(2) . . ?
N3 Ga4 O4 162.4(2) . . ?
N3 Ga4 O5 83.6(2) . . ?
N3 Ga4 O9 91.9(2) . . ?
N10 Ga4 O4 96.3(2) . . ?
N10 Ga4 O5 112.3(2) . . ?
N10 Ga4 O9 107.7(2) . . ?
N10 Ga4 N3 98.6(2) . . ?
O12 Ga2 O20 174.34(19) . . ?
O14 Ga2 O20 81.63(18) . . ?
O14 Ga2 O12 101.11(19) . . ?
N8 Ga2 O20 94.6(2) . . ?
N8 Ga2 O12 90.4(2) . . ?
N8 Ga2 O14 89.1(2) . . ?
N9 Ga2 O20 89.3(2) . . ?
N9 Ga2 O12 86.0(2) . . ?
N9 Ga2 O14 85.5(2) . . ?
N9 Ga2 N8 172.8(2) . . ?
N4 Ga2 O20 85.8(2) . . ?
N4 Ga2 O12 91.3(2) . . ?
N4 Ga2 O14 167.4(2) . . ?
N4 Ga2 N8 93.4(2) . . ?
N4 Ga2 N9 92.9(2) . . ?
Ga2 O20 Dy1 131.3(2) . . ?
N5 O20 Dy1 117.6(3) . . ?
N5 O20 Ga2 110.8(3) . . ?
N11 O19 Dy1 98.9(4) . . ?
C12 O4 Ga4 111.8(4) . . ?
Ga3 O17 Dy1 99.09(16) . . ?
N6 O17 Dy1 106.9(3) . . ?
N6 O17 Ga3 106.4(4) . . ?
Ga4 O5 Dy1 126.8(2) . . ?
N2 O5 Dy1 115.9(3) . . ?
N2 O5 Ga4 111.8(3) . . ?
C1 O1 Dy1 119.2(4) . . ?
C23 O7 Ga3 112.7(4) . . ?
N11 O13 Dy1 94.1(4) . . ?
Ga3 O8 Dy1 105.09(18) . . ?
N3 O8 Dy1 128.0(4) . . ?
N3 O8 Ga3 111.8(3) . . ?
C25 O9 Ga4 129.0(4) . . ?
Ga1 O2 Dy1 102.88(18) . . ?
N1 O2 Dy1 112.9(3) . . ?
N1 O2 Ga1 115.9(4) . . ?
C14 O6 Ga1 127.6(4) . . ?
C36 O12 Ga2 126.6(4) . . ?
Ga1 O11 Dy1 106.77(17) . . ?
N4 O11 Dy1 129.2(4) . . ?
N4 O11 Ga1 112.2(3) . . ?
C56 O16 Ga3 112.5(4) . . ?
C34 O10 Ga1 112.2(4) . . ?
C47 O15 Ga3 127.2(4) . . ?
C45 O14 Ga2 111.8(4) . . ?
C71 N7 Ga1 119.6(5) . . ?
C67 N7 Ga1 121.3(5) . . ?
C67 N7 C71 119.1(6) . . ?
O8 N3 Ga4 114.5(4) . . ?
C23 N3 Ga4 132.0(5) . . ?
C23 N3 O8 113.4(5) . . ?
O5 N2 Ga1 116.7(4) . . ?
C12 N2 Ga1 130.5(4) . . ?
C12 N2 O5 112.7(5) . . ?
C76 N8 Ga2 121.3(4) . . ?
C72 N8 Ga2 121.8(5) . . ?
C72 N8 C76 116.7(6) . . ?
C86 N10 Ga4 119.8(5) . . ?
C82 N10 Ga4 122.0(4) . . ?
C82 N10 C86 118.2(6) . . ?
O20 N5 Ga3 116.4(4) . . ?
C45 N5 Ga3 128.5(5) . . ?
C45 N5 O20 114.3(5) . . ?
C22 C13 C12 117.5(6) . . ?
C14 C13 C12 122.4(6) . . ?
C14 C13 C22 120.0(6) . . ?
C81 N9 Ga2 117.4(5) . . ?
C77 N9 Ga2 123.7(5) . . ?
C77 N9 C81 118.7(7) . . ?
C32 C27 C26 118.6(6) . . ?
C28 C27 C26 122.8(6) . . ?
C28 C27 C32 118.5(6) . . ?
O19 N11 Dy1 55.3(3) . . ?
O13 N11 Dy1 60.0(3) . . ?
O13 N11 O19 115.2(6) . . ?
O21 N11 Dy1 176.0(5) . . ?
O21 N11 O19 121.6(6) . . ?
O21 N11 O13 123.1(6) . . ?
C56 N6 O17 118.2(5) . . ?
C1 N1 O2 118.2(5) . . ?
C25 C26 C27 122.2(6) . . ?
C24 C33 C32 122.6(6) . . ?
C11 C10 C5 118.6(6) . . ?
C9 C10 C5 119.4(6) . . ?
C9 C10 C11 122.1(6) . . ?
C59 C58 O18 123.0(6) . . ?
C57 C58 O18 118.7(6) . . ?
C57 C58 C59 118.3(6) . . ?
C33 C32 C27 118.4(6) . . ?
C31 C32 C27 118.9(6) . . ?
C31 C32 C33 122.7(6) . . ?
N4 C34 O10 121.2(6) . . ?
C35 C34 O10 120.0(6) . . ?
C35 C34 N4 118.8(6) . . ?
O11 N4 Ga2 118.2(4) . . ?
C34 N4 Ga2 128.2(4) . . ?
C34 N4 O11 113.1(5) . . ?
N6 C56 O16 119.3(6) . . ?
C57 C56 O16 121.0(6) . . ?
C57 C56 N6 119.6(6) . . ?
N2 C12 O4 121.5(6) . . ?
C13 C12 O4 119.6(6) . . ?
C13 C12 N2 118.9(6) . . ?
C6 C5 C10 118.4(6) . . ?
C4 C5 C10 119.4(6) . . ?
C4 C5 C6 122.1(6) . . ?
C26 C25 O9 117.6(6) . . ?
C24 C25 O9 123.5(6) . . ?
C24 C25 C26 118.9(6) . . ?
C25 C24 C33 119.2(6) . . ?
C23 C24 C33 116.6(6) . . ?
C23 C24 C25 124.1(6) . . ?
C76 C75 C74 119.9(8) . . ?
C52 C53 C54 120.3(7) . . ?
C28 C29 C30 120.3(7) . . ?
C82 C83 C84 118.8(7) . . ?
C55 C46 C45 117.1(6) . . ?
C47 C46 C45 124.2(6) . . ?
C47 C46 C55 118.5(6) . . ?
C21 C22 C13 122.3(7) . . ?
C60 C59 C58 122.1(7) . . ?
C56 C57 C58 123.6(6) . . ?
C66 C57 C58 119.9(6) . . ?
C66 C57 C56 116.4(6) . . ?
C49 C54 C53 118.6(6) . . ?
C55 C54 C53 122.6(7) . . ?
C55 C54 C49 118.7(6) . . ?
C48 C49 C54 118.8(6) . . ?
C50 C49 C54 119.6(7) . . ?
C50 C49 C48 121.5(7) . . ?
C85 C84 C83 118.3(7) . . ?
C36 C35 C34 124.5(6) . . ?
C44 C35 C34 115.5(6) . . ?
C44 C35 C36 119.6(6) . . ?
C31 C30 C29 119.9(7) . . ?
C2 C11 C10 121.8(6) . . ?
C16 C21 C22 117.6(7) . . ?
C20 C21 C22 122.0(8) . . ?
C20 C21 C16 120.3(7) . . ?
N5 C45 O14 121.0(6) . . ?
C46 C45 O14 119.4(5) . . ?
C46 C45 N5 119.6(6) . . ?
C38 C37 C36 122.0(7) . . ?
C1 C2 C11 118.1(6) . . ?
C3 C2 C11 119.4(6) . . ?
C3 C2 C1 122.5(6) . . ?
C70 C71 N7 121.8(7) . . ?
C15 C16 C21 119.4(6) . . ?
C17 C16 C21 118.7(7) . . ?
C17 C16 C15 121.9(8) . . ?
C14 C15 C16 123.0(7) . . ?
C65 C60 C59 119.0(7) . . ?
C61 C60 C59 122.7(7) . . ?
C61 C60 C65 118.3(7) . . ?
O1 C1 Dy1 40.3(3) . . ?
N1 C1 Dy1 81.4(4) . . ?
N1 C1 O1 121.3(6) . . ?
C2 C1 Dy1 160.1(5) . . ?
C2 C1 O1 120.3(6) . . ?
C2 C1 N1 118.3(6) . . ?
C85 C86 N10 121.8(7) . . ?
C18 C17 C16 119.5(9) . . ?
C13 C14 O6 123.5(6) . . ?
C15 C14 O6 119.2(7) . . ?
C15 C14 C13 117.4(6) . . ?
C30 C31 C32 121.0(7) . . ?
C51 C52 C53 121.1(7) . . ?
C35 C36 O12 124.1(6) . . ?
C37 C36 O12 118.0(6) . . ?
C37 C36 C35 117.9(7) . . ?
C8 C9 C10 120.7(7) . . ?
C43 C44 C35 122.9(7) . . ?
C19 C18 C17 121.7(7) . . ?
C19 C20 C21 120.6(8) . . ?
C67 C68 C69 118.2(8) . . ?
C47 C48 C49 122.2(7) . . ?
C63 C64 C65 119.9(8) . . ?
C51 C50 C49 119.9(8) . . ?
C69 C70 C71 119.7(8) . . ?
C73 C74 C75 117.0(7) . . ?
C2 C3 O3 117.1(6) . . ?
C4 C3 O3 122.5(7) . . ?
C4 C3 C2 120.4(7) . . ?
C64 C65 C60 119.3(7) . . ?
C66 C65 C60 118.6(7) . . ?
C66 C65 C64 121.9(7) . . ?
C75 C76 N8 123.1(7) . . ?
C65 C66 C57 121.7(7) . . ?
C20 C19 C18 119.1(8) . . ?
C62 C61 C60 120.5(8) . . ?
C7 C6 C5 121.1(7) . . ?
C8 C7 C6 121.1(7) . . ?
C3 C4 C5 120.4(7) . . ?
C63 C62 C61 121.4(8) . . ?
C29 C28 C27 121.4(7) . . ?
C86 C85 C84 120.1(7) . . ?
N3 C23 O7 121.9(6) . . ?
C24 C23 O7 119.3(6) . . ?
C24 C23 N3 118.8(6) . . ?
C83 C82 N10 122.8(7) . . ?
C73 C72 N8 122.6(7) . . ?
C80 C81 N9 121.7(8) . . ?
C54 C55 C46 122.6(7) . . ?
C72 C73 C74 120.7(7) . . ?
C7 C8 C9 119.4(7) . . ?
C80 C79 C78 117.9(8) . . ?
C62 C63 C64 120.6(8) . . ?
C46 C47 O15 123.9(6) . . ?
C48 C47 O15 116.9(6) . . ?
C48 C47 C46 119.2(6) . . ?
C77 C78 C79 118.7(8) . . ?
C79 C80 C81 119.2(9) . . ?
C50 C51 C52 120.4(7) . . ?
C70 C69 C68 119.1(7) . . ?
C78 C77 N9 123.8(8) . . ?
C88 C87 N12 118.8(12) . . ?
C89 C90 C91 119.3(12) . . ?
C42 C43 C44 122.4(9) . . ?
C38 C43 C44 117.7(8) . . ?
C38 C43 C42 119.9(9) . . ?
C94 C95 C96 118.4(13) . . ?
N12 C91 C90 119.7(11) . . ?
C41 C40 C39 119.0(11) . . ?
C41 C42 C43 119.9(13) . . ?
C91 N12 C87 119.6(12) . . ?
C88 C89 C90 121.6(14) . . ?
C43 C38 C37 119.7(8) . . ?
C39 C38 C37 121.9(10) . . ?
C39 C38 C43 118.3(10) . . ?
C38 C39 C40 120.8(12) . . ?
C89 C88 C87 121.0(13) . . ?
C42 C41 C40 122.0(12) . . ?
C96 N13 C92 121(3) . . ?
C93 C92 N13 116.9(18) . . ?
N13 C96 C95 119.9(17) . . ?
C93 C94 C95 125.5(17) . . ?
C94 C93 C92 118.0(14) . . ?
C68 C67 N7 122.1(7) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
loop_
_restr_distance_atom_site_label_1
_restr_distance_atom_site_label_2
_restr_distance_site_symmetry_2
_restr_distance_target
_restr_distance_target_weight_param
_restr_distance_diff
H3 H95 1 2.1000 0.0100 0.0002


