Supplementary Material (ESI) for Chemical Communications
This journal is (c) The Royal Society of Chemistry 2003 

data_global
_journal_name_full               Chem.Commun.

_journal_coden_Cambridge         0182

loop_
_publ_author_name
'Yoshihiko Yamamoto'
'Takayasu Arakawa'
'Koichi Hata'
'Kenji Itoh'

_publ_contact_author_name        'Dr Yoshihiko Yamamoto'
_publ_contact_author_address     
;
Department of Applied Chemistry
Graduate School of Engineering, Nagoya University
Chikusa
Nagoya
464-8603
JAPAN
;

_publ_contact_author_email       YAMAMOTO@APCHEM.NAGOYA-U.AC.JP

_publ_section_title              
;
Ru(II)-catalyzed [2 + 2 + 2] cycloaddition of
1,2-bis(propiolyl)benzenes with monoalkynes leading to substituted
anthraquinones
;

data_yyar41
_database_code_CSD               203734

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C35 H30 Cl4 O2 Ru'
_chemical_formula_weight         725.46

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   P2(1)/n

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   11.6335(6)
_cell_length_b                   18.8471(10)
_cell_length_c                   15.0128(8)
_cell_angle_alpha                90.00
_cell_angle_beta                 111.8490(10)
_cell_angle_gamma                90.00
_cell_volume                     3055.2(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       ?
_exptl_crystal_colour            black
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.3
_exptl_crystal_size_min          0.7
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.577
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1472
_exptl_absorpt_coefficient_mu    0.895
_exptl_absorpt_correction_type   SADABS
_exptl_absorpt_correction_T_min  0.774897
_exptl_absorpt_correction_T_max  1.000000
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
? 
;

_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            23271
_diffrn_reflns_av_R_equivalents  0.0236
_diffrn_reflns_av_sigmaI/netI    0.0227
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         1.82
_diffrn_reflns_theta_max         29.14
_reflns_number_total             8153
_reflns_number_gt                7157
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
Refinement of F^2^ against ALL reflections.  The weighted R-factor wR and 
goodness of fit S are based on F^2^, conventional R-factors R are based 
on F, with F set to zero for negative F^2^. The threshold expression of 
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is 
not relevant to the choice of reflections for refinement.  R-factors based 
on F^2^ are statistically about twice as large as those based on F, and R- 
factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0675P)^2^+1.9448P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         8153
_refine_ls_number_parameters     384
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0427
_refine_ls_R_factor_gt           0.0380
_refine_ls_wR_factor_ref         0.1097
_refine_ls_wR_factor_gt          0.1066
_refine_ls_goodness_of_fit_ref   1.063
_refine_ls_restrained_S_all      1.063
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.120565(15) 0.189715(9) 0.466798(11) 0.02043(7) Uani 1 1 d . . .
C1 C 0.26713(19) 0.25095(12) 0.48566(15) 0.0224(4) Uani 1 1 d . . .
C2 C 0.2775(2) 0.31437(11) 0.53605(15) 0.0220(4) Uani 1 1 d . . .
C3 C 0.17766(19) 0.32559(11) 0.56825(15) 0.0217(4) Uani 1 1 d . . .
C4 C 0.08777(19) 0.27213(11) 0.53886(14) 0.0221(4) Uani 1 1 d . . .
C5 C 0.3813(2) 0.36531(12) 0.56003(16) 0.0253(4) Uani 1 1 d . . .
C6 C 0.3638(2) 0.43473(12) 0.60104(15) 0.0236(4) Uani 1 1 d . . .
C7 C 0.4421(2) 0.49124(13) 0.60246(17) 0.0293(5) Uani 1 1 d . . .
H7 H 0.5050 0.4850 0.5790 0.035 Uiso 1 1 calc R . .
C8 C 0.4263(2) 0.55648(13) 0.63867(19) 0.0340(5) Uani 1 1 d . . .
H8 H 0.4760 0.5946 0.6366 0.041 Uiso 1 1 calc R . .
C9 C 0.3368(2) 0.56520(13) 0.6781(2) 0.0349(5) Uani 1 1 d . . .
H9 H 0.3278 0.6089 0.7036 0.042 Uiso 1 1 calc R . .
C10 C 0.2602(2) 0.50884(13) 0.67958(17) 0.0299(5) Uani 1 1 d . . .
H10 H 0.2019 0.5145 0.7077 0.036 Uiso 1 1 calc R . .
C11 C 0.27123(19) 0.44365(12) 0.63868(15) 0.0235(4) Uani 1 1 d . . .
C12 C 0.1827(2) 0.38468(12) 0.63508(15) 0.0235(4) Uani 1 1 d . . .
C13 C 0.3606(2) 0.22582(13) 0.44772(16) 0.0263(4) Uani 1 1 d . . .
C14 C 0.4176(2) 0.16045(14) 0.47870(18) 0.0317(5) Uani 1 1 d . . .
H14 H 0.3996 0.1349 0.5249 0.038 Uiso 1 1 calc R . .
C15 C 0.5013(3) 0.13312(17) 0.4410(2) 0.0440(7) Uani 1 1 d . . .
H15 H 0.5406 0.0901 0.4632 0.053 Uiso 1 1 calc R . .
C16 C 0.5259(3) 0.1700(2) 0.3704(2) 0.0478(8) Uani 1 1 d . . .
H16 H 0.5790 0.1508 0.3433 0.057 Uiso 1 1 calc R . .
C17 C 0.4717(3) 0.23533(18) 0.3403(2) 0.0422(7) Uani 1 1 d . . .
H17 H 0.4894 0.2603 0.2935 0.051 Uiso 1 1 calc R . .
C18 C 0.3906(2) 0.26404(15) 0.37940(18) 0.0330(5) Uani 1 1 d . . .
H18 H 0.3563 0.3087 0.3601 0.040 Uiso 1 1 calc R . .
C19 C -0.0285(2) 0.27218(13) 0.55692(15) 0.0257(4) Uani 1 1 d . . .
C20 C -0.1068(2) 0.33190(16) 0.53811(17) 0.0316(5) Uani 1 1 d . . .
H20 H -0.0823 0.3742 0.5185 0.038 Uiso 1 1 calc R . .
C21 C -0.2204(2) 0.32818(18) 0.5487(2) 0.0402(6) Uani 1 1 d . . .
H21 H -0.2714 0.3679 0.5358 0.048 Uiso 1 1 calc R . .
C22 C -0.2582(2) 0.26606(18) 0.5782(2) 0.0440(7) Uani 1 1 d . . .
H22 H -0.3350 0.2636 0.5839 0.053 Uiso 1 1 calc R . .
C23 C -0.1809(3) 0.20728(18) 0.5994(2) 0.0422(6) Uani 1 1 d . . .
H23 H -0.2053 0.1657 0.6208 0.051 Uiso 1 1 calc R . .
C24 C -0.0670(2) 0.21011(15) 0.58885(18) 0.0321(5) Uani 1 1 d . . .
H24 H -0.0160 0.1704 0.6032 0.039 Uiso 1 1 calc R . .
C25 C 0.0327(2) 0.21550(12) 0.30990(15) 0.0259(4) Uani 1 1 d . . .
C26 C -0.0662(2) 0.20414(13) 0.34314(16) 0.0271(4) Uani 1 1 d . . .
C27 C -0.0639(2) 0.13101(13) 0.37084(15) 0.0267(4) Uani 1 1 d . . .
C28 C 0.0381(2) 0.09838(12) 0.35765(16) 0.0255(4) Uani 1 1 d . . .
C29 C 0.0965(2) 0.14923(12) 0.31694(15) 0.0246(4) Uani 1 1 d . . .
C30 C 0.0507(3) 0.28099(14) 0.26018(19) 0.0389(6) Uani 1 1 d . . .
H30A H -0.0035 0.2795 0.1939 0.058 Uiso 1 1 calc R . .
H30B H 0.1351 0.2833 0.2646 0.058 Uiso 1 1 calc R . .
H30C H 0.0321 0.3221 0.2902 0.058 Uiso 1 1 calc R . .
C31 C -0.1685(3) 0.25566(16) 0.33075(19) 0.0405(6) Uani 1 1 d . . .
H31A H -0.1347 0.3025 0.3470 0.061 Uiso 1 1 calc R . .
H31B H -0.2112 0.2426 0.3721 0.061 Uiso 1 1 calc R . .
H31C H -0.2255 0.2550 0.2652 0.061 Uiso 1 1 calc R . .
C32 C -0.1559(2) 0.09475(16) 0.40283(19) 0.0381(6) Uani 1 1 d . . .
H32A H -0.2177 0.0721 0.3489 0.057 Uiso 1 1 calc R . .
H32B H -0.1947 0.1291 0.4298 0.057 Uiso 1 1 calc R . .
H32C H -0.1145 0.0597 0.4504 0.057 Uiso 1 1 calc R . .
C33 C 0.0768(3) 0.02180(13) 0.3766(2) 0.0392(6) Uani 1 1 d . . .
H33A H 0.0141 -0.0043 0.3900 0.059 Uiso 1 1 calc R . .
H33B H 0.1536 0.0189 0.4308 0.059 Uiso 1 1 calc R . .
H33C H 0.0873 0.0020 0.3212 0.059 Uiso 1 1 calc R . .
C34 C 0.1881(2) 0.13077(15) 0.27312(18) 0.0345(5) Uani 1 1 d . . .
H34A H 0.2457 0.0965 0.3127 0.052 Uiso 1 1 calc R . .
H34B H 0.2321 0.1727 0.2680 0.052 Uiso 1 1 calc R . .
H34C H 0.1457 0.1112 0.2104 0.052 Uiso 1 1 calc R . .
C35 C 0.0981(3) 0.49900(17) 0.3047(3) 0.0553(9) Uani 1 1 d . A 1
H35 H 0.1031 0.5509 0.3055 0.066 Uiso 1 1 calc R A 1
Cl1 Cl 0.20545(6) 0.11449(3) 0.59804(4) 0.03355(13) Uani 1 1 d . . .
Cl2 Cl -0.02401(7) 0.47196(4) 0.19950(5) 0.04654(17) Uani 1 1 d . A 1
Cl3 Cl 0.07040(11) 0.47047(6) 0.40629(7) 0.0763(3) Uani 1 1 d . A 1
Cl4 Cl 0.23974(9) 0.46410(7) 0.30882(14) 0.1110(6) Uani 1 1 d . A 1
O1 O 0.47761(16) 0.35385(11) 0.54710(15) 0.0394(4) Uani 1 1 d . . .
O2 O 0.12025(16) 0.38727(9) 0.68455(12) 0.0310(4) Uani 1 1 d . . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Ru1 0.02017(10) 0.02182(10) 0.01748(10) 0.00032(5) 0.00490(7) 0.00005(6)
C1 0.0206(9) 0.0268(10) 0.0192(9) 0.0002(8) 0.0068(7) 0.0014(8)
C2 0.0190(9) 0.0270(10) 0.0192(9) -0.0006(7) 0.0064(8) 0.0011(7)
C3 0.0203(9) 0.0250(9) 0.0193(9) -0.0001(8) 0.0069(8) 0.0014(7)
C4 0.0206(9) 0.0264(10) 0.0184(9) -0.0011(7) 0.0064(7) 0.0007(8)
C5 0.0204(10) 0.0305(11) 0.0243(10) -0.0038(8) 0.0073(8) -0.0011(8)
C6 0.0209(9) 0.0277(10) 0.0200(9) -0.0006(8) 0.0049(8) -0.0008(8)
C7 0.0264(11) 0.0324(11) 0.0283(11) -0.0001(9) 0.0092(9) -0.0039(9)
C8 0.0326(12) 0.0281(11) 0.0389(13) 0.0008(10) 0.0105(10) -0.0052(9)
C9 0.0365(13) 0.0247(11) 0.0412(14) -0.0037(10) 0.0117(11) 0.0009(9)
C10 0.0291(11) 0.0290(11) 0.0327(12) -0.0039(9) 0.0128(9) 0.0018(9)
C11 0.0208(9) 0.0260(10) 0.0214(9) -0.0007(8) 0.0050(8) 0.0004(8)
C12 0.0210(9) 0.0273(10) 0.0209(9) -0.0012(8) 0.0063(8) 0.0010(8)
C13 0.0215(10) 0.0327(11) 0.0241(10) -0.0083(9) 0.0078(8) -0.0022(8)
C14 0.0241(11) 0.0364(13) 0.0324(12) -0.0066(10) 0.0079(9) 0.0024(9)
C15 0.0301(13) 0.0475(16) 0.0506(16) -0.0164(13) 0.0105(12) 0.0079(11)
C16 0.0257(12) 0.072(2) 0.0476(16) -0.0280(15) 0.0163(12) -0.0027(13)
C17 0.0305(12) 0.0682(19) 0.0319(13) -0.0105(12) 0.0162(11) -0.0097(12)
C18 0.0275(11) 0.0435(14) 0.0288(11) -0.0049(10) 0.0115(9) -0.0066(10)
C19 0.0213(10) 0.0345(12) 0.0213(10) -0.0064(8) 0.0079(8) -0.0026(8)
C20 0.0251(11) 0.0410(13) 0.0274(11) -0.0063(9) 0.0084(9) 0.0018(9)
C21 0.0251(12) 0.0588(17) 0.0345(13) -0.0129(12) 0.0088(10) 0.0065(11)
C22 0.0258(12) 0.072(2) 0.0383(14) -0.0179(14) 0.0166(11) -0.0080(12)
C23 0.0373(14) 0.0547(16) 0.0423(15) -0.0109(13) 0.0238(12) -0.0167(12)
C24 0.0301(12) 0.0397(13) 0.0301(12) -0.0066(10) 0.0153(10) -0.0058(10)
C25 0.0286(11) 0.0259(10) 0.0182(9) 0.0012(8) 0.0029(8) -0.0016(8)
C26 0.0248(10) 0.0315(11) 0.0193(10) -0.0024(8) 0.0016(8) 0.0026(8)
C27 0.0233(10) 0.0331(11) 0.0190(9) -0.0002(8) 0.0023(8) -0.0037(8)
C28 0.0272(10) 0.0233(10) 0.0210(9) -0.0019(8) 0.0031(8) -0.0014(8)
C29 0.0240(10) 0.0280(10) 0.0186(9) -0.0038(8) 0.0042(8) -0.0024(8)
C30 0.0492(15) 0.0305(12) 0.0314(12) 0.0083(10) 0.0086(11) -0.0056(11)
C31 0.0340(13) 0.0480(15) 0.0291(12) -0.0047(11) -0.0002(10) 0.0161(11)
C32 0.0316(12) 0.0503(15) 0.0307(12) 0.0009(11) 0.0094(10) -0.0098(11)
C33 0.0497(16) 0.0235(11) 0.0366(13) 0.0012(10) 0.0069(12) 0.0015(10)
C34 0.0296(12) 0.0460(14) 0.0270(11) -0.0104(10) 0.0096(10) -0.0019(10)
C35 0.0360(14) 0.0328(14) 0.079(2) 0.0067(15) 0.0000(15) -0.0049(11)
Cl1 0.0351(3) 0.0350(3) 0.0251(3) 0.0087(2) 0.0048(2) 0.0036(2)
Cl2 0.0517(4) 0.0449(4) 0.0392(3) -0.0022(3) 0.0126(3) 0.0005(3)
Cl3 0.0884(7) 0.0750(6) 0.0430(4) 0.0072(4) -0.0014(4) 0.0263(5)
Cl4 0.0392(5) 0.0875(8) 0.2053(17) 0.0555(10) 0.0443(7) 0.0039(5)
O1 0.0235(8) 0.0462(11) 0.0529(11) -0.0197(9) 0.0194(8) -0.0076(7)
O2 0.0291(8) 0.0381(9) 0.0296(8) -0.0082(7) 0.0152(7) -0.0051(7)

_geom_special_details            
; 
All esds (except the esd in the dihedral angle between two l.s. planes) 
are estimated using the full covariance matrix.  The cell esds are taken 
into account individually in the estimation of esds in distances, angles 
and torsion angles; correlations between esds in cell parameters are only 
used when they are defined by crystal symmetry.  An approximate (isotropic) 
treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru1 C1 1.990(2) . ?
Ru1 C4 2.009(2) . ?
Ru1 C25 2.244(2) . ?
Ru1 C26 2.289(2) . ?
Ru1 C29 2.292(2) . ?
Ru1 C28 2.323(2) . ?
Ru1 Cl1 2.3279(6) . ?
Ru1 C27 2.367(2) . ?
C1 C2 1.395(3) . ?
C1 C13 1.481(3) . ?
C2 C3 1.430(3) . ?
C2 C5 1.478(3) . ?
C3 C4 1.400(3) . ?
C3 C12 1.485(3) . ?
C4 C19 1.475(3) . ?
C5 O1 1.226(3) . ?
C5 C6 1.492(3) . ?
C6 C7 1.396(3) . ?
C6 C11 1.400(3) . ?
C7 C8 1.384(4) . ?
C8 C9 1.386(4) . ?
C9 C10 1.392(3) . ?
C10 C11 1.400(3) . ?
C11 C12 1.502(3) . ?
C12 O2 1.218(3) . ?
C13 C14 1.394(4) . ?
C13 C18 1.400(3) . ?
C14 C15 1.395(4) . ?
C15 C16 1.383(5) . ?
C16 C17 1.381(5) . ?
C17 C18 1.393(4) . ?
C19 C24 1.399(3) . ?
C19 C20 1.409(3) . ?
C20 C21 1.390(3) . ?
C21 C22 1.381(5) . ?
C22 C23 1.387(5) . ?
C23 C24 1.393(3) . ?
C25 C26 1.429(3) . ?
C25 C29 1.436(3) . ?
C25 C30 1.497(3) . ?
C26 C27 1.437(3) . ?
C26 C31 1.493(3) . ?
C27 C28 1.415(3) . ?
C27 C32 1.492(3) . ?
C28 C29 1.436(3) . ?
C28 C33 1.507(3) . ?
C29 C34 1.488(3) . ?
C35 Cl4 1.754(4) . ?
C35 Cl3 1.756(4) . ?
C35 Cl2 1.761(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Ru1 C4 78.42(9) . . ?
C1 Ru1 C25 93.17(8) . . ?
C4 Ru1 C25 107.10(8) . . ?
C1 Ru1 C26 123.43(9) . . ?
C4 Ru1 C26 91.82(8) . . ?
C25 Ru1 C26 36.75(8) . . ?
C1 Ru1 C29 96.78(8) . . ?
C4 Ru1 C29 143.87(8) . . ?
C25 Ru1 C29 36.90(8) . . ?
C26 Ru1 C29 60.71(8) . . ?
C1 Ru1 C28 129.57(8) . . ?
C4 Ru1 C28 147.28(8) . . ?
C25 Ru1 C28 60.86(8) . . ?
C26 Ru1 C28 59.86(8) . . ?
C29 Ru1 C28 36.24(8) . . ?
C1 Ru1 Cl1 99.30(6) . . ?
C4 Ru1 Cl1 96.94(6) . . ?
C25 Ru1 Cl1 154.72(6) . . ?
C26 Ru1 Cl1 137.27(7) . . ?
C29 Ru1 Cl1 119.11(6) . . ?
C28 Ru1 Cl1 94.56(6) . . ?
C1 Ru1 C27 153.18(8) . . ?
C4 Ru1 C27 112.22(8) . . ?
C25 Ru1 C27 60.45(8) . . ?
C26 Ru1 C27 35.91(8) . . ?
C29 Ru1 C27 59.67(8) . . ?
C28 Ru1 C27 35.10(8) . . ?
Cl1 Ru1 C27 103.49(6) . . ?
C2 C1 C13 123.70(19) . . ?
C2 C1 Ru1 118.08(15) . . ?
C13 C1 Ru1 118.21(15) . . ?
C1 C2 C3 113.11(19) . . ?
C1 C2 C5 125.90(19) . . ?
C3 C2 C5 120.93(19) . . ?
C4 C3 C2 113.11(19) . . ?
C4 C3 C12 126.12(19) . . ?
C2 C3 C12 120.41(19) . . ?
C3 C4 C19 124.76(19) . . ?
C3 C4 Ru1 117.18(15) . . ?
C19 C4 Ru1 118.06(15) . . ?
O1 C5 C2 124.0(2) . . ?
O1 C5 C6 119.5(2) . . ?
C2 C5 C6 116.49(18) . . ?
C7 C6 C11 119.8(2) . . ?
C7 C6 C5 119.2(2) . . ?
C11 C6 C5 121.0(2) . . ?
C8 C7 C6 120.2(2) . . ?
C7 C8 C9 120.2(2) . . ?
C8 C9 C10 120.2(2) . . ?
C9 C10 C11 120.0(2) . . ?
C6 C11 C10 119.5(2) . . ?
C6 C11 C12 121.10(19) . . ?
C10 C11 C12 119.4(2) . . ?
O2 C12 C3 124.0(2) . . ?
O2 C12 C11 120.3(2) . . ?
C3 C12 C11 115.67(18) . . ?
C14 C13 C18 118.8(2) . . ?
C14 C13 C1 118.7(2) . . ?
C18 C13 C1 122.4(2) . . ?
C13 C14 C15 120.5(3) . . ?
C16 C15 C14 120.0(3) . . ?
C17 C16 C15 120.0(2) . . ?
C16 C17 C18 120.5(3) . . ?
C17 C18 C13 120.1(3) . . ?
C24 C19 C20 118.1(2) . . ?
C24 C19 C4 119.6(2) . . ?
C20 C19 C4 122.2(2) . . ?
C21 C20 C19 120.5(3) . . ?
C22 C21 C20 120.6(3) . . ?
C21 C22 C23 119.6(2) . . ?
C22 C23 C24 120.4(3) . . ?
C23 C24 C19 120.7(3) . . ?
C26 C25 C29 107.7(2) . . ?
C26 C25 C30 125.3(2) . . ?
C29 C25 C30 126.1(2) . . ?
C26 C25 Ru1 73.30(12) . . ?
C29 C25 Ru1 73.34(12) . . ?
C30 C25 Ru1 127.45(17) . . ?
C25 C26 C27 108.3(2) . . ?
C25 C26 C31 124.5(2) . . ?
C27 C26 C31 126.0(2) . . ?
C25 C26 Ru1 69.95(12) . . ?
C27 C26 Ru1 75.04(13) . . ?
C31 C26 Ru1 130.57(16) . . ?
C28 C27 C26 107.6(2) . . ?
C28 C27 C32 125.9(2) . . ?
C26 C27 C32 126.5(2) . . ?
C28 C27 Ru1 70.75(12) . . ?
C26 C27 Ru1 69.05(12) . . ?
C32 C27 Ru1 127.94(16) . . ?
C27 C28 C29 108.9(2) . . ?
C27 C28 C33 126.6(2) . . ?
C29 C28 C33 124.4(2) . . ?
C27 C28 Ru1 74.15(13) . . ?
C29 C28 Ru1 70.68(12) . . ?
C33 C28 Ru1 124.09(16) . . ?
C28 C29 C25 107.4(2) . . ?
C28 C29 C34 124.2(2) . . ?
C25 C29 C34 127.3(2) . . ?
C28 C29 Ru1 73.08(12) . . ?
C25 C29 Ru1 69.75(12) . . ?
C34 C29 Ru1 131.76(15) . . ?
Cl4 C35 Cl3 109.16(19) . . ?
Cl4 C35 Cl2 110.9(2) . . ?
Cl3 C35 Cl2 110.04(18) . . ?

_diffrn_measured_fraction_theta_max 0.992
_diffrn_reflns_theta_full        29.14
_diffrn_measured_fraction_theta_full 0.992
_refine_diff_density_max         1.915
_refine_diff_density_min         -1.616
_refine_diff_density_rms         0.094