# Electronic Supplementary Material for Chemical Communications
# This journal is (c) The Royal Society of Chemistry 2006

data_global

_journal_coden_Cambridge         182

_publ_requested_journal          'Chemical Communications'

loop_
_publ_author_name
'Bruno Linclau'
'Nadia Azzi'
'Ed Griffen'
'Mark E. Light'

_publ_contact_author_name        'Bruno Linclau'
_publ_contact_author_address     
;
School of Chemistry
University of Southampton
Highfield
SO17 1BJ
UNITED KINGDOM
;

_publ_contact_author_email       BRUNO.LINCLAU@SOTON.AC.UK

_publ_section_title              
;
An enantioselective desymmetrisation approach to
C9-substituted trans-hydrindene rings based on a diastereotopic
group-selective intramolecular Diels-Alder reaction.
;

# Attachment '04sot0856r.cif'

data_04sot0856r
_database_code_depnum_ccdc_archive 'CCDC 609533'

_chemical_compound_source        'N Azzi'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C17 H21 N O3'
_chemical_formula_weight         287.35

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   Pc
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x, -y, z+1/2'

_cell_length_a                   5.0398(17)
_cell_length_b                   10.910(4)
_cell_length_c                   27.268(7)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.36(2)
_cell_angle_gamma                90.00
_cell_volume                     1499.3(8)
_cell_formula_units_Z            4
_cell_measurement_temperature    120(2)
_cell_measurement_reflns_used    3522
_cell_measurement_theta_min      2.91
_cell_measurement_theta_max      27.48

_exptl_crystal_description       Rod
_exptl_crystal_colour            Colourless
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.03
_exptl_crystal_size_min          0.02
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.273
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             616
_exptl_absorpt_coefficient_mu    0.087
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.9771
_exptl_absorpt_correction_T_max  0.9983
_exptl_absorpt_process_details   
;
SADABS V2.10 (Sheldrick, G.M., 2003)
;

_exptl_special_details           
;
SADABS was used to perform the Absorption correction
Parameter refinement on 11729 reflections reduced R(int) from 0.2695 to 0.0628
Ratio of minimum to maximum apparent transmission: 0.629022
The given Tmin and Tmax were generated using the SHELX SIZE command
;

_diffrn_ambient_temperature      120(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'Bruker Nonius FR591 Rotating Anode'
_diffrn_radiation_monochromator  '10cm confocal mirrors'
_diffrn_measurement_device_type  'Bruker-Nonius CCD camera on \k-goniostat'
_diffrn_measurement_method       '\f & \w scans to fill the asymmetric unit'
_diffrn_detector_area_resol_mean 9.091
_diffrn_standards_number         0
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            18459
_diffrn_reflns_av_R_equivalents  0.0879
_diffrn_reflns_av_sigmaI/netI    0.0748
_diffrn_reflns_limit_h_min       -6
_diffrn_reflns_limit_h_max       6
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -35
_diffrn_reflns_limit_l_max       35
_diffrn_reflns_theta_min         2.92
_diffrn_reflns_theta_max         27.58
_reflns_number_total             3464
_reflns_number_gt                2688
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'COLLECT (Hooft, R.W.W., 1998)'
_computing_cell_refinement       
'DENZO (Otwinowski & Minor, 1997) & COLLECT (Hooft, R.W.W., 1998)'
_computing_data_reduction        
'DENZO (Otwinowski & Minor, 1997) & COLLECT (Hooft, R.W.W., 1998)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'CAMERON (Watkin, et al., 1993)'
_computing_publication_material  'WINGX (Farrugia, 1998)'
_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0486P)^2^+0.0331P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         3464
_refine_ls_number_parameters     379
_refine_ls_number_restraints     2
_refine_ls_R_factor_all          0.0924
_refine_ls_R_factor_gt           0.0654
_refine_ls_wR_factor_ref         0.1197
_refine_ls_wR_factor_gt          0.1119
_refine_ls_goodness_of_fit_ref   1.183
_refine_ls_restrained_S_all      1.183
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
N1 N 0.3697(6) 0.5074(3) 0.07550(11) 0.0235(7) Uani 1 1 d . . .
O1 O 0.1117(5) 0.4100(3) 0.01531(10) 0.0323(7) Uani 1 1 d . . .
O2 O 0.0622(5) 0.6086(2) 0.03286(10) 0.0270(6) Uani 1 1 d . . .
O3 O 0.7101(6) 0.4434(3) 0.12148(12) 0.0414(8) Uani 1 1 d . . .
C1 C 0.1756(7) 0.4981(4) 0.03963(13) 0.0231(8) Uani 1 1 d . . .
C2 C 0.1750(8) 0.6973(3) 0.06671(15) 0.0289(9) Uani 1 1 d . . .
H2A H 0.0484 0.7166 0.0932 0.035 Uiso 1 1 calc R . .
H2B H 0.2216 0.7741 0.0494 0.035 Uiso 1 1 calc R . .
C3 C 0.4219(7) 0.6354(3) 0.08726(14) 0.0230(8) Uani 1 1 d . . .
H3A H 0.5845 0.6654 0.0710 0.028 Uiso 1 1 calc R . .
H3B H 0.4386 0.6482 0.1231 0.028 Uiso 1 1 calc R . .
C4 C 0.5217(7) 0.4141(4) 0.09641(14) 0.0290(10) Uani 1 1 d . . .
C5 C 0.4399(8) 0.2822(3) 0.08846(15) 0.0293(9) Uani 1 1 d . . .
H5 H 0.2582 0.2812 0.0735 0.035 Uiso 1 1 calc R . .
C6 C 0.6314(8) 0.2189(4) 0.05307(16) 0.0346(10) Uani 1 1 d . . .
H6A H 0.5916 0.2465 0.0192 0.042 Uiso 1 1 calc R . .
H6B H 0.8151 0.2444 0.0611 0.042 Uiso 1 1 calc R . .
C7 C 0.6151(8) 0.0818(4) 0.05495(16) 0.0337(10) Uani 1 1 d . . .
H7 H 0.7081 0.0367 0.0307 0.040 Uiso 1 1 calc R . .
C8 C 0.4796(8) 0.0188(4) 0.08820(15) 0.0308(10) Uani 1 1 d . . .
H8 H 0.4820 -0.0683 0.0875 0.037 Uiso 1 1 calc R . .
C9 C 0.3244(7) 0.0839(3) 0.12645(14) 0.0247(9) Uani 1 1 d . . .
H9 H 0.1397 0.0938 0.1134 0.030 Uiso 1 1 calc R . .
C10 C 0.3022(8) 0.0289(4) 0.17773(15) 0.0282(9) Uani 1 1 d . . .
H10 H 0.4840 0.0076 0.1899 0.034 Uiso 1 1 calc R . .
C11 C 0.1952(9) 0.1394(4) 0.20809(16) 0.0360(10) Uani 1 1 d . . .
H11A H 0.0013 0.1318 0.2128 0.043 Uiso 1 1 calc R . .
H11B H 0.2825 0.1424 0.2407 0.043 Uiso 1 1 calc R . .
C12 C 0.2602(9) 0.2570(4) 0.17825(17) 0.0348(10) Uani 1 1 d . . .
H12A H 0.0959 0.2958 0.1656 0.042 Uiso 1 1 calc R . .
H12B H 0.3576 0.3171 0.1987 0.042 Uiso 1 1 calc R . .
C13 C 0.4323(8) 0.2117(3) 0.13628(14) 0.0268(9) Uani 1 1 d . . .
H13 H 0.6184 0.2033 0.1488 0.032 Uiso 1 1 calc R . .
C14 C 0.1330(8) -0.0824(4) 0.17988(14) 0.0291(9) Uani 1 1 d . . .
H14 H -0.0452 -0.0733 0.1689 0.035 Uiso 1 1 calc R . .
C15 C 0.2029(8) -0.1936(4) 0.19543(14) 0.0265(9) Uani 1 1 d . . .
H15 H 0.3770 -0.2029 0.2085 0.032 Uiso 1 1 calc R . .
C16 C 0.0358(8) -0.3015(4) 0.19413(15) 0.0294(9) Uani 1 1 d . . .
H16 H -0.1447 -0.2903 0.1849 0.035 Uiso 1 1 calc R . .
C17 C 0.1126(9) -0.4134(4) 0.20465(15) 0.0371(11) Uani 1 1 d . . .
H17A H 0.2914 -0.4286 0.2141 0.045 Uiso 1 1 calc R . .
H17B H -0.0106 -0.4792 0.2028 0.045 Uiso 1 1 calc R . .
N2 N 0.8624(6) 1.2974(3) 0.42884(11) 0.0240(7) Uani 1 1 d . . .
O4 O 0.6124(6) 1.2009(3) 0.48917(10) 0.0332(7) Uani 1 1 d . . .
O5 O 0.5587(5) 1.3987(2) 0.47133(9) 0.0269(6) Uani 1 1 d . . .
O6 O 1.1992(6) 1.2327(3) 0.38278(12) 0.0418(8) Uani 1 1 d . . .
C18 C 0.6721(7) 1.2886(4) 0.46503(14) 0.0251(9) Uani 1 1 d . . .
C19 C 0.6658(8) 1.4865(4) 0.43739(15) 0.0299(9) Uani 1 1 d . . .
H19A H 0.7112 1.5640 0.4544 0.036 Uiso 1 1 calc R . .
H19B H 0.5366 1.5044 0.4108 0.036 Uiso 1 1 calc R . .
C20 C 0.9121(7) 1.4264(3) 0.41698(14) 0.0240(8) Uani 1 1 d . . .
H20A H 0.9265 1.4393 0.3812 0.029 Uiso 1 1 calc R . .
H20B H 1.0749 1.4571 0.4334 0.029 Uiso 1 1 calc R . .
C21 C 1.0123(8) 1.2042(4) 0.40813(15) 0.0286(9) Uani 1 1 d . . .
C22 C 0.9320(8) 1.0725(3) 0.41637(15) 0.0272(9) Uani 1 1 d . . .
H22 H 0.7525 1.0713 0.4318 0.033 Uiso 1 1 calc R . .
C23 C 1.1296(8) 1.0090(4) 0.45130(16) 0.0339(10) Uani 1 1 d . . .
H23A H 1.3121 1.0341 0.4426 0.041 Uiso 1 1 calc R . .
H23B H 1.0954 1.0366 0.4853 0.041 Uiso 1 1 calc R . .
C24 C 1.1103(8) 0.8713(4) 0.44926(15) 0.0322(10) Uani 1 1 d . . .
H24 H 1.2056 0.8256 0.4732 0.039 Uiso 1 1 calc R . .
C25 C 0.9706(7) 0.8102(4) 0.41657(15) 0.0286(9) Uani 1 1 d . . .
H25 H 0.9715 0.7232 0.4174 0.034 Uiso 1 1 calc R . .
C26 C 0.8108(7) 0.8742(3) 0.37822(14) 0.0231(8) Uani 1 1 d . . .
H26 H 0.6281 0.8845 0.3917 0.028 Uiso 1 1 calc R . .
C27 C 0.7796(8) 0.8201(4) 0.32725(14) 0.0275(9) Uani 1 1 d . . .
H27 H 0.9596 0.7987 0.3146 0.033 Uiso 1 1 calc R . .
C28 C 0.6705(8) 0.9303(4) 0.29731(15) 0.0307(10) Uani 1 1 d . . .
H28A H 0.4760 0.9230 0.2930 0.037 Uiso 1 1 calc R . .
H28B H 0.7536 0.9331 0.2645 0.037 Uiso 1 1 calc R . .
C29 C 0.7395(8) 1.0481(4) 0.32676(15) 0.0305(10) Uani 1 1 d . . .
H29A H 0.8345 1.1080 0.3060 0.037 Uiso 1 1 calc R . .
H29B H 0.5771 1.0871 0.3398 0.037 Uiso 1 1 calc R . .
C30 C 0.9183(7) 1.0018(3) 0.36857(15) 0.0265(9) Uani 1 1 d . . .
H30 H 1.1027 0.9935 0.3557 0.032 Uiso 1 1 calc R . .
C31 C 0.6092(8) 0.7084(4) 0.32510(15) 0.0291(9) Uani 1 1 d . . .
H31 H 0.4313 0.7171 0.3358 0.035 Uiso 1 1 calc R . .
C32 C 0.6816(8) 0.5985(4) 0.30972(14) 0.0281(9) Uani 1 1 d . . .
H32 H 0.8570 0.5901 0.2976 0.034 Uiso 1 1 calc R . .
C33 C 0.5166(9) 0.4898(4) 0.30978(15) 0.0363(10) Uani 1 1 d . . .
H33 H 0.3392 0.4989 0.3208 0.044 Uiso 1 1 calc R . .
C34 C 0.5917(10) 0.3788(4) 0.29585(17) 0.0460(13) Uani 1 1 d . . .
H34A H 0.7674 0.3656 0.2846 0.055 Uiso 1 1 calc R . .
H34B H 0.4698 0.3125 0.2971 0.055 Uiso 1 1 calc R . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
N1 0.0245(16) 0.0220(17) 0.0239(16) 0.0030(14) -0.0046(13) -0.0009(14)
O1 0.0399(17) 0.0266(16) 0.0303(16) 0.0026(13) -0.0109(13) -0.0080(13)
O2 0.0253(14) 0.0262(15) 0.0294(15) 0.0010(12) -0.0017(11) -0.0003(12)
O3 0.0376(17) 0.0312(16) 0.0551(19) 0.0093(15) -0.0228(15) -0.0090(13)
C1 0.022(2) 0.027(2) 0.021(2) 0.0059(17) 0.0010(15) -0.0046(17)
C2 0.030(2) 0.029(2) 0.028(2) 0.0006(18) -0.0017(17) -0.0005(18)
C3 0.026(2) 0.021(2) 0.022(2) -0.0025(16) 0.0021(16) -0.0046(16)
C4 0.027(2) 0.032(2) 0.027(2) 0.0071(19) -0.0058(18) -0.0045(18)
C5 0.023(2) 0.029(2) 0.036(2) 0.0033(19) -0.0056(17) -0.0031(18)
C6 0.035(2) 0.037(2) 0.032(2) 0.006(2) -0.0015(18) -0.0111(19)
C7 0.033(2) 0.034(2) 0.034(2) -0.008(2) 0.0051(19) -0.0017(19)
C8 0.031(2) 0.026(2) 0.035(2) -0.0021(19) -0.0018(19) -0.0025(18)
C9 0.025(2) 0.021(2) 0.029(2) 0.0019(17) -0.0032(17) 0.0010(16)
C10 0.028(2) 0.023(2) 0.033(2) 0.0027(18) -0.0022(17) 0.0009(16)
C11 0.046(3) 0.030(2) 0.032(2) -0.0046(19) 0.003(2) -0.004(2)
C12 0.044(3) 0.026(2) 0.035(2) -0.0017(19) -0.0029(19) 0.001(2)
C13 0.028(2) 0.021(2) 0.031(2) 0.0019(17) -0.0068(17) -0.0006(16)
C14 0.024(2) 0.035(3) 0.028(2) 0.0024(19) 0.0003(17) -0.0033(18)
C15 0.030(2) 0.023(2) 0.027(2) -0.0026(17) 0.0027(17) 0.0020(17)
C16 0.036(2) 0.025(2) 0.028(2) -0.0002(18) 0.0057(17) -0.0021(18)
C17 0.049(3) 0.031(3) 0.032(2) 0.003(2) 0.006(2) -0.002(2)
N2 0.0222(17) 0.0278(18) 0.0221(17) -0.0018(14) 0.0051(13) -0.0064(14)
O4 0.0399(16) 0.0281(16) 0.0318(16) -0.0022(13) 0.0117(13) -0.0057(13)
O5 0.0257(15) 0.0274(15) 0.0276(15) -0.0008(12) 0.0035(11) 0.0009(12)
O6 0.0372(17) 0.0305(17) 0.058(2) -0.0046(16) 0.0245(15) -0.0059(14)
C18 0.027(2) 0.028(2) 0.021(2) -0.0048(18) 0.0022(16) -0.0045(18)
C19 0.032(2) 0.029(2) 0.029(2) 0.0037(19) 0.0052(17) 0.0012(18)
C20 0.0229(19) 0.029(2) 0.0202(19) 0.0004(17) -0.0020(15) -0.0056(17)
C21 0.029(2) 0.029(2) 0.027(2) -0.0063(18) 0.0044(18) -0.0033(18)
C22 0.024(2) 0.028(2) 0.030(2) -0.0058(18) 0.0077(16) -0.0017(17)
C23 0.030(2) 0.039(3) 0.033(2) -0.006(2) 0.0003(18) -0.0079(19)
C24 0.030(2) 0.032(2) 0.034(2) 0.006(2) -0.0048(18) 0.0000(19)
C25 0.029(2) 0.025(2) 0.032(2) 0.0028(18) 0.0004(17) -0.0015(17)
C26 0.021(2) 0.025(2) 0.023(2) -0.0012(17) 0.0042(15) -0.0005(16)
C27 0.030(2) 0.024(2) 0.029(2) -0.0026(17) 0.0028(17) 0.0011(17)
C28 0.038(2) 0.026(2) 0.028(2) -0.0006(18) -0.0026(18) 0.0011(19)
C29 0.030(2) 0.025(2) 0.036(2) 0.0014(19) 0.0049(18) -0.0013(17)
C30 0.024(2) 0.024(2) 0.031(2) -0.0028(17) 0.0055(17) 0.0011(16)
C31 0.033(2) 0.027(2) 0.027(2) -0.0028(18) -0.0035(17) 0.0013(18)
C32 0.032(2) 0.029(2) 0.024(2) -0.0004(18) 0.0011(17) -0.0039(18)
C33 0.047(3) 0.034(3) 0.028(2) 0.001(2) -0.008(2) -0.006(2)
C34 0.072(4) 0.026(3) 0.040(3) -0.003(2) -0.011(3) -0.009(2)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
N1 C1 1.383(5) . ?
N1 C4 1.394(5) . ?
N1 C3 1.457(4) . ?
O1 C1 1.211(4) . ?
O2 C1 1.346(4) . ?
O2 C2 1.451(5) . ?
O3 C4 1.210(4) . ?
C2 C3 1.520(5) . ?
C4 C5 1.512(5) . ?
C5 C13 1.515(5) . ?
C5 C6 1.534(6) . ?
C6 C7 1.499(6) . ?
C7 C8 1.330(6) . ?
C8 C9 1.488(6) . ?
C9 C13 1.519(5) . ?
C9 C10 1.527(6) . ?
C10 C14 1.485(6) . ?
C10 C11 1.561(6) . ?
C11 C12 1.555(6) . ?
C12 C13 1.523(6) . ?
C14 C15 1.331(5) . ?
C15 C16 1.448(5) . ?
C16 C17 1.312(5) . ?
N2 C18 1.384(5) . ?
N2 C21 1.389(5) . ?
N2 C20 1.466(5) . ?
O4 C18 1.200(4) . ?
O5 C18 1.342(5) . ?
O5 C19 1.440(5) . ?
O6 C21 1.212(5) . ?
C19 C20 1.513(5) . ?
C21 C22 1.511(5) . ?
C22 C30 1.516(6) . ?
C22 C23 1.538(6) . ?
C23 C24 1.506(6) . ?
C24 C25 1.314(6) . ?
C25 C26 1.489(5) . ?
C26 C27 1.517(5) . ?
C26 C30 1.518(5) . ?
C27 C31 1.492(6) . ?
C27 C28 1.552(6) . ?
C28 C29 1.553(5) . ?
C29 C30 1.534(6) . ?
C31 C32 1.322(5) . ?
C32 C33 1.448(6) . ?
C33 C34 1.325(6) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 N1 C4 128.4(3) . . ?
C1 N1 C3 110.6(3) . . ?
C4 N1 C3 120.8(3) . . ?
C1 O2 C2 110.2(3) . . ?
O1 C1 O2 121.7(3) . . ?
O1 C1 N1 129.0(4) . . ?
O2 C1 N1 109.2(3) . . ?
O2 C2 C3 104.8(3) . . ?
N1 C3 C2 101.5(3) . . ?
O3 C4 N1 117.7(4) . . ?
O3 C4 C5 123.0(4) . . ?
N1 C4 C5 119.2(3) . . ?
C4 C5 C13 111.6(3) . . ?
C4 C5 C6 110.3(3) . . ?
C13 C5 C6 109.4(3) . . ?
C7 C6 C5 113.2(3) . . ?
C8 C7 C6 124.6(4) . . ?
C7 C8 C9 120.4(4) . . ?
C8 C9 C13 111.9(3) . . ?
C8 C9 C10 119.7(3) . . ?
C13 C9 C10 103.1(3) . . ?
C14 C10 C9 113.8(3) . . ?
C14 C10 C11 114.2(3) . . ?
C9 C10 C11 102.1(3) . . ?
C12 C11 C10 106.6(3) . . ?
C13 C12 C11 104.4(3) . . ?
C5 C13 C9 109.0(3) . . ?
C5 C13 C12 120.0(3) . . ?
C9 C13 C12 103.0(3) . . ?
C15 C14 C10 127.3(4) . . ?
C14 C15 C16 125.5(4) . . ?
C17 C16 C15 125.5(4) . . ?
C18 N2 C21 128.3(3) . . ?
C18 N2 C20 110.1(3) . . ?
C21 N2 C20 121.3(3) . . ?
C18 O5 C19 110.6(3) . . ?
O4 C18 O5 122.3(4) . . ?
O4 C18 N2 128.6(4) . . ?
O5 C18 N2 109.1(3) . . ?
O5 C19 C20 105.0(3) . . ?
N2 C20 C19 101.1(3) . . ?
O6 C21 N2 118.1(4) . . ?
O6 C21 C22 122.6(4) . . ?
N2 C21 C22 119.3(3) . . ?
C21 C22 C30 111.5(3) . . ?
C21 C22 C23 110.3(3) . . ?
C30 C22 C23 109.2(3) . . ?
C24 C23 C22 112.6(3) . . ?
C25 C24 C23 124.4(4) . . ?
C24 C25 C26 121.6(4) . . ?
C25 C26 C27 120.9(3) . . ?
C25 C26 C30 111.1(3) . . ?
C27 C26 C30 103.5(3) . . ?
C31 C27 C26 114.2(3) . . ?
C31 C27 C28 114.2(3) . . ?
C26 C27 C28 102.4(3) . . ?
C27 C28 C29 106.9(3) . . ?
C30 C29 C28 103.9(3) . . ?
C22 C30 C26 109.4(3) . . ?
C22 C30 C29 119.7(3) . . ?
C26 C30 C29 102.8(3) . . ?
C32 C31 C27 126.4(4) . . ?
C31 C32 C33 125.6(4) . . ?
C34 C33 C32 125.7(5) . . ?

_diffrn_measured_fraction_theta_max 0.992
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.997
_refine_diff_density_max         0.326
_refine_diff_density_min         -0.272
_refine_diff_density_rms         0.078