# Supplementary Material (ESI) for Chemical Communications
# This journal is (c) The Royal Society of Chemistry 2009

data_global
_journal_name_full               Chem.Commun.

_journal_coden_Cambridge         0182

_publ_contact_author_name        'Matthias Driess'
_publ_contact_author_email       MATTHIAS.DRIESS@TU-BERLIN.DE

_publ_section_title              
;
An unsymmetric N-donor stabilised digermylene with a
Ge(I)-Ge(I) bond and synthesis of a germylene-stannylene with a
Ge(I)-Sn(I) bond
;
loop_
_publ_author_name
'Matthias Driess'
'Shigeyoshi Inoue'
'Wenyuan Wang.'
'Shenglai Yao.'

# Attachment 'Compound4_Revised.CIF'

data_CCDC716013
_database_code_depnum_ccdc_archive 'CCDC 716013'

_audit_creation_method           
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.31.8 (release 12-01-2007 CrysAlis171 .NET)
(compiled Jan 12 2007,17:49:11)
;
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C46 H65 Ge2 N3'
_chemical_formula_weight         805.19

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   C2/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   44.536(2)
_cell_length_b                   9.8204(5)
_cell_length_c                   21.8135(10)
_cell_angle_alpha                90.00
_cell_angle_beta                 116.030(4)
_cell_angle_gamma                90.00
_cell_volume                     8572.7(7)
_cell_formula_units_Z            8
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    3839
_cell_measurement_theta_min      3.0030
_cell_measurement_theta_max      28.9953

_exptl_crystal_description       red
_exptl_crystal_colour            prism
_exptl_crystal_size_max          0.38
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.248
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3408
_exptl_absorpt_coefficient_mu    1.436
_exptl_absorpt_correction_T_min  0.74676
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
(compiled May 8 2007,13:10:02)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Oxford Diffraction Xcalibur S Sapphire'
_diffrn_measurement_method       \w
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            20162
_diffrn_reflns_av_R_equivalents  0.0954
_diffrn_reflns_av_sigmaI/netI    0.1885
_diffrn_reflns_limit_h_min       -49
_diffrn_reflns_limit_h_max       52
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_theta_min         3.05
_diffrn_reflns_theta_max         25.00
_reflns_number_total             7493
_reflns_number_gt                3708
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       
;
CrysAlis CCD, Oxford Diffraction Ltd.,
Version 1.171.31.8 (release 12-01-2007 CrysAlis171 .NET)
(compiled Jan 12 2007,17:49:11)
;
_computing_cell_refinement       
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.31.8 (release 12-01-2007 CrysAlis171 .NET)
(compiled Jan 12 2007,17:49:11)
;
_computing_data_reduction        
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.31.8 (release 12-01-2007 CrysAlis171 .NET)
(compiled Jan 12 2007,17:49:11)
;
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0261P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         7493
_refine_ls_number_parameters     476
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1461
_refine_ls_R_factor_gt           0.0559
_refine_ls_wR_factor_ref         0.0965
_refine_ls_wR_factor_gt          0.0777
_refine_ls_goodness_of_fit_ref   0.917
_refine_ls_restrained_S_all      0.917
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.125811(13) 0.88502(6) 0.48734(3) 0.02159(16) Uani 1 1 d . . .
N1 N 0.16230(9) 0.9714(4) 0.57042(19) 0.0173(10) Uani 1 1 d . . .
C1 C 0.18005(13) 1.1995(5) 0.6239(3) 0.0394(17) Uani 1 1 d . . .
H1A H 0.1996 1.1865 0.6151 0.059 Uiso 1 1 calc R . .
H1B H 0.1867 1.1903 0.6729 0.059 Uiso 1 1 calc R . .
H1C H 0.1707 1.2904 0.6087 0.059 Uiso 1 1 calc R . .
Ge2 Ge 0.137242(14) 0.63017(6) 0.50531(3) 0.02485(17) Uani 1 1 d . . .
N2 N 0.09391(9) 0.9141(4) 0.53038(18) 0.0171(10) Uani 1 1 d . . .
C2 C 0.15393(12) 1.0929(5) 0.5854(2) 0.0199(13) Uani 1 1 d . . .
N3 N 0.13153(9) 0.5793(4) 0.41436(19) 0.0189(10) Uani 1 1 d . . .
C3 C 0.12084(11) 1.1280(6) 0.5695(2) 0.0229(12) Uani 1 1 d . . .
H3 H 0.1161 1.2224 0.5696 0.027 Uiso 1 1 calc R . .
C4 C 0.09404(12) 1.0385(5) 0.5536(2) 0.0183(13) Uani 1 1 d . . .
C5 C 0.06469(12) 1.0897(5) 0.5642(2) 0.0263(14) Uani 1 1 d . . .
H5A H 0.0451 1.0973 0.5200 0.039 Uiso 1 1 calc R . .
H5B H 0.0700 1.1793 0.5862 0.039 Uiso 1 1 calc R . .
H5C H 0.0600 1.0258 0.5934 0.039 Uiso 1 1 calc R . .
C6 C 0.19709(12) 0.9317(5) 0.6040(3) 0.0261(14) Uani 1 1 d . . .
C7 C 0.21655(13) 0.9389(5) 0.5685(3) 0.0269(14) Uani 1 1 d . . .
C8 C 0.25065(13) 0.9109(5) 0.6037(3) 0.0318(15) Uani 1 1 d . . .
H8 H 0.2644 0.9165 0.5805 0.038 Uiso 1 1 calc R . .
C9 C 0.26461(13) 0.8751(6) 0.6717(3) 0.0383(15) Uani 1 1 d . . .
H9 H 0.2878 0.8547 0.6949 0.046 Uiso 1 1 calc R . .
C10 C 0.24504(13) 0.8689(6) 0.7059(3) 0.0346(15) Uani 1 1 d . . .
H10 H 0.2551 0.8472 0.7532 0.041 Uiso 1 1 calc R . .
C11 C 0.21094(12) 0.8937(6) 0.6729(2) 0.0252(13) Uani 1 1 d . . .
C12 C 0.19018(13) 0.8741(7) 0.7121(3) 0.0389(15) Uani 1 1 d . . .
H12 H 0.1671 0.9078 0.6826 0.047 Uiso 1 1 calc R . .
C13 C 0.18757(18) 0.7250(7) 0.7278(4) 0.073(2) Uani 1 1 d . . .
H13A H 0.2099 0.6898 0.7575 0.110 Uiso 1 1 calc R . .
H13B H 0.1781 0.6729 0.6852 0.110 Uiso 1 1 calc R . .
H13C H 0.1731 0.7162 0.7509 0.110 Uiso 1 1 calc R . .
C14 C 0.20328(16) 0.9515(7) 0.7787(3) 0.074(2) Uani 1 1 d . . .
H14A H 0.2235 0.9068 0.8123 0.111 Uiso 1 1 calc R . .
H14B H 0.1862 0.9527 0.7957 0.111 Uiso 1 1 calc R . .
H14C H 0.2086 1.0451 0.7714 0.111 Uiso 1 1 calc R . .
C15 C 0.20215(13) 0.9780(6) 0.4930(3) 0.0344(16) Uani 1 1 d . . .
H15 H 0.1773 0.9804 0.4747 0.041 Uiso 1 1 calc R . .
C16 C 0.21377(16) 1.1215(6) 0.4845(3) 0.0602(19) Uani 1 1 d . . .
H16A H 0.2075 1.1870 0.5108 0.090 Uiso 1 1 calc R . .
H16B H 0.2031 1.1470 0.4362 0.090 Uiso 1 1 calc R . .
H16C H 0.2381 1.1218 0.5012 0.090 Uiso 1 1 calc R . .
C17 C 0.21069(13) 0.8744(6) 0.4518(2) 0.0448(16) Uani 1 1 d . . .
H17A H 0.2348 0.8763 0.4655 0.067 Uiso 1 1 calc R . .
H17B H 0.1986 0.8965 0.4032 0.067 Uiso 1 1 calc R . .
H17C H 0.2042 0.7834 0.4600 0.067 Uiso 1 1 calc R . .
C18 C 0.06510(12) 0.8268(5) 0.5154(2) 0.0185(13) Uani 1 1 d . . .
C19 C 0.06657(14) 0.7282(5) 0.5630(3) 0.0241(14) Uani 1 1 d . . .
C20 C 0.03761(13) 0.6555(5) 0.5500(3) 0.0273(14) Uani 1 1 d . . .
H20 H 0.0379 0.5907 0.5826 0.033 Uiso 1 1 calc R . .
C21 C 0.00864(14) 0.6743(5) 0.4916(3) 0.0318(15) Uani 1 1 d . . .
H21 H -0.0108 0.6234 0.4841 0.038 Uiso 1 1 calc R . .
C22 C 0.00800(13) 0.7673(5) 0.4441(3) 0.0258(14) Uani 1 1 d . . .
H22 H -0.0118 0.7777 0.4028 0.031 Uiso 1 1 calc R . .
C23 C 0.03574(12) 0.8465(5) 0.4549(2) 0.0163(12) Uani 1 1 d . . .
C24 C 0.09752(15) 0.7035(6) 0.6278(3) 0.0336(16) Uani 1 1 d . . .
H24 H 0.1167 0.7433 0.6217 0.040 Uiso 1 1 calc R . .
C25 C 0.10518(14) 0.5526(6) 0.6443(3) 0.0425(17) Uani 1 1 d . . .
H25A H 0.0880 0.5121 0.6552 0.064 Uiso 1 1 calc R . .
H25B H 0.1271 0.5430 0.6836 0.064 Uiso 1 1 calc R . .
H25C H 0.1054 0.5059 0.6049 0.064 Uiso 1 1 calc R . .
C26 C 0.09583(17) 0.7770(6) 0.6880(3) 0.074(2) Uani 1 1 d . . .
H26A H 0.0936 0.8752 0.6791 0.111 Uiso 1 1 calc R . .
H26B H 0.1163 0.7590 0.7296 0.111 Uiso 1 1 calc R . .
H26C H 0.0765 0.7440 0.6939 0.111 Uiso 1 1 calc R . .
C27 C 0.03348(12) 0.9455(5) 0.3995(2) 0.0217(13) Uani 1 1 d . . .
H27 H 0.0533 1.0071 0.4198 0.026 Uiso 1 1 calc R . .
C28 C 0.03557(12) 0.8702(6) 0.3405(2) 0.0351(15) Uani 1 1 d . . .
H28A H 0.0560 0.8156 0.3577 0.053 Uiso 1 1 calc R . .
H28B H 0.0359 0.9363 0.3071 0.053 Uiso 1 1 calc R . .
H28C H 0.0161 0.8104 0.3186 0.053 Uiso 1 1 calc R . .
C29 C 0.00219(12) 1.0357(5) 0.3734(3) 0.0332(15) Uani 1 1 d . . .
H29A H -0.0177 0.9794 0.3489 0.050 Uiso 1 1 calc R . .
H29B H 0.0036 1.1050 0.3425 0.050 Uiso 1 1 calc R . .
H29C H 0.0006 1.0802 0.4121 0.050 Uiso 1 1 calc R . .
C30 C 0.21006(13) 0.5587(6) 0.6049(2) 0.0421(17) Uani 1 1 d . . .
H30A H 0.2267 0.4927 0.6055 0.063 Uiso 1 1 calc R . .
H30B H 0.2014 0.5298 0.6371 0.063 Uiso 1 1 calc R . .
H30C H 0.2205 0.6485 0.6182 0.063 Uiso 1 1 calc R . .
C31 C 0.18173(12) 0.5662(5) 0.5341(2) 0.0226(13) Uani 1 1 d . . .
C32 C 0.18487(13) 0.5012(5) 0.4813(3) 0.0237(14) Uani 1 1 d . . .
H32 H 0.2049 0.4549 0.4884 0.028 Uiso 1 1 calc R . .
C33 C 0.15769(13) 0.5057(5) 0.4173(3) 0.0226(14) Uani 1 1 d . . .
C34 C 0.15643(12) 0.4245(5) 0.3577(2) 0.0326(15) Uani 1 1 d . . .
H34A H 0.1468 0.3346 0.3575 0.049 Uiso 1 1 calc R . .
H34B H 0.1791 0.4138 0.3618 0.049 Uiso 1 1 calc R . .
H34C H 0.1426 0.4723 0.3152 0.049 Uiso 1 1 calc R . .
C35 C 0.10086(12) 0.5856(5) 0.3516(2) 0.0195(13) Uani 1 1 d . . .
C36 C 0.07598(13) 0.4886(5) 0.3419(3) 0.0225(14) Uani 1 1 d . . .
C37 C 0.04654(13) 0.4934(6) 0.2806(3) 0.0299(15) Uani 1 1 d . . .
H37 H 0.0292 0.4294 0.2728 0.036 Uiso 1 1 calc R . .
C38 C 0.04240(13) 0.5893(6) 0.2317(3) 0.0313(15) Uani 1 1 d . . .
H38 H 0.0223 0.5916 0.1906 0.038 Uiso 1 1 calc R . .
C39 C 0.06727(13) 0.6820(5) 0.2419(3) 0.0258(14) Uani 1 1 d . . .
H39 H 0.0641 0.7469 0.2073 0.031 Uiso 1 1 calc R . .
C40 C 0.09698(13) 0.6833(5) 0.3017(3) 0.0219(13) Uani 1 1 d . . .
C41 C 0.12436(13) 0.7860(5) 0.3112(3) 0.0265(15) Uani 1 1 d . . .
H41 H 0.1424 0.7764 0.3588 0.032 Uiso 1 1 calc R . .
C42 C 0.13950(15) 0.7559(7) 0.2620(3) 0.0529(19) Uani 1 1 d . . .
H42A H 0.1481 0.6626 0.2691 0.079 Uiso 1 1 calc R . .
H42B H 0.1578 0.8198 0.2703 0.079 Uiso 1 1 calc R . .
H42C H 0.1223 0.7660 0.2149 0.079 Uiso 1 1 calc R . .
C43 C 0.11156(14) 0.9309(5) 0.3021(3) 0.0349(16) Uani 1 1 d . . .
H43A H 0.0946 0.9440 0.2550 0.052 Uiso 1 1 calc R . .
H43B H 0.1302 0.9941 0.3120 0.052 Uiso 1 1 calc R . .
H43C H 0.1016 0.9484 0.3335 0.052 Uiso 1 1 calc R . .
C44 C 0.07991(13) 0.3736(6) 0.3926(3) 0.0322(14) Uani 1 1 d . . .
H44 H 0.1026 0.3830 0.4317 0.039 Uiso 1 1 calc R . .
C45 C 0.07846(16) 0.2358(6) 0.3605(3) 0.0502(19) Uani 1 1 d . . .
H45A H 0.0558 0.2193 0.3251 0.075 Uiso 1 1 calc R . .
H45B H 0.0846 0.1650 0.3955 0.075 Uiso 1 1 calc R . .
H45C H 0.0941 0.2340 0.3400 0.075 Uiso 1 1 calc R . .
C46 C 0.05410(13) 0.3893(6) 0.4214(3) 0.0433(16) Uani 1 1 d . . .
H46A H 0.0557 0.4810 0.4403 0.065 Uiso 1 1 calc R . .
H46B H 0.0586 0.3218 0.4575 0.065 Uiso 1 1 calc R . .
H46C H 0.0316 0.3750 0.3848 0.065 Uiso 1 1 calc R . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Ge1 0.0212(3) 0.0232(4) 0.0212(3) -0.0020(3) 0.0100(3) 0.0003(3)
N1 0.022(3) 0.011(2) 0.019(2) -0.004(2) 0.009(2) 0.003(2)
C1 0.029(4) 0.028(4) 0.050(4) -0.018(3) 0.007(3) -0.004(3)
Ge2 0.0309(3) 0.0232(4) 0.0219(3) 0.0004(3) 0.0129(3) 0.0021(3)
N2 0.014(2) 0.020(3) 0.013(2) 0.002(2) 0.0027(19) -0.003(2)
C2 0.020(3) 0.018(3) 0.022(3) 0.003(3) 0.010(2) -0.006(3)
N3 0.016(2) 0.018(3) 0.022(2) 0.007(2) 0.007(2) 0.001(2)
C3 0.022(3) 0.016(3) 0.029(3) -0.007(3) 0.010(3) 0.001(3)
C4 0.019(3) 0.016(3) 0.024(3) -0.001(3) 0.013(3) -0.001(3)
C5 0.029(3) 0.024(4) 0.032(3) -0.011(3) 0.018(3) -0.004(3)
C6 0.014(3) 0.022(3) 0.033(3) -0.013(3) 0.002(3) -0.005(3)
C7 0.026(3) 0.021(3) 0.038(4) -0.002(3) 0.018(3) -0.001(3)
C8 0.025(3) 0.031(4) 0.045(4) 0.006(3) 0.020(3) 0.006(3)
C9 0.023(3) 0.034(4) 0.044(4) -0.003(4) 0.002(3) 0.007(3)
C10 0.029(3) 0.039(4) 0.030(3) -0.015(3) 0.007(3) -0.007(3)
C11 0.022(3) 0.024(4) 0.024(3) -0.014(3) 0.006(3) -0.001(3)
C12 0.033(3) 0.057(4) 0.024(3) 0.006(4) 0.010(3) 0.003(4)
C13 0.096(6) 0.073(6) 0.086(6) 0.010(5) 0.073(5) 0.004(5)
C14 0.057(5) 0.119(7) 0.048(5) -0.034(5) 0.023(4) 0.006(5)
C15 0.022(3) 0.040(4) 0.046(4) 0.014(3) 0.021(3) 0.005(3)
C16 0.091(5) 0.033(4) 0.067(4) 0.024(4) 0.045(4) 0.027(5)
C17 0.051(4) 0.050(4) 0.035(3) 0.005(4) 0.021(3) 0.003(4)
C18 0.018(3) 0.020(3) 0.023(3) 0.003(3) 0.015(3) 0.002(3)
C19 0.032(4) 0.019(4) 0.028(4) -0.003(3) 0.019(3) -0.004(3)
C20 0.045(4) 0.014(4) 0.029(3) 0.002(3) 0.022(3) 0.001(3)
C21 0.033(4) 0.021(4) 0.049(4) -0.006(3) 0.026(3) -0.009(3)
C22 0.015(3) 0.028(4) 0.035(4) -0.007(3) 0.012(3) -0.004(3)
C23 0.023(3) 0.007(3) 0.028(3) -0.005(2) 0.019(3) 0.000(2)
C24 0.045(4) 0.034(4) 0.028(4) 0.003(3) 0.023(3) -0.007(3)
C25 0.051(4) 0.040(4) 0.039(4) 0.020(3) 0.022(3) 0.007(4)
C26 0.109(7) 0.053(5) 0.031(4) -0.011(4) 0.005(4) 0.027(5)
C27 0.019(3) 0.021(3) 0.027(3) -0.005(3) 0.011(3) -0.001(3)
C28 0.031(3) 0.047(4) 0.029(3) 0.002(3) 0.015(3) 0.007(4)
C29 0.033(3) 0.030(4) 0.037(4) 0.009(3) 0.016(3) 0.002(3)
C30 0.043(4) 0.043(4) 0.027(3) 0.000(3) 0.003(3) 0.006(3)
C31 0.024(3) 0.012(3) 0.025(3) -0.004(3) 0.005(3) 0.000(3)
C32 0.026(3) 0.019(3) 0.029(3) -0.001(3) 0.015(3) 0.007(3)
C33 0.025(3) 0.023(4) 0.025(3) 0.002(3) 0.015(3) 0.002(3)
C34 0.033(3) 0.040(4) 0.027(3) -0.010(3) 0.015(3) 0.009(3)
C35 0.022(3) 0.018(3) 0.021(3) 0.007(3) 0.012(3) 0.004(3)
C36 0.030(3) 0.014(3) 0.023(3) 0.001(3) 0.011(3) 0.002(3)
C37 0.023(3) 0.031(4) 0.036(4) -0.001(3) 0.013(3) -0.007(3)
C38 0.022(3) 0.036(4) 0.031(3) 0.001(3) 0.008(3) 0.003(3)
C39 0.031(3) 0.024(3) 0.022(3) -0.001(3) 0.011(3) 0.008(3)
C40 0.023(3) 0.024(3) 0.025(3) -0.005(3) 0.017(3) 0.002(3)
C41 0.024(4) 0.030(4) 0.024(3) 0.002(3) 0.009(3) 0.005(3)
C42 0.052(5) 0.054(4) 0.075(5) -0.011(4) 0.049(4) -0.015(4)
C43 0.050(4) 0.021(4) 0.043(4) 0.004(3) 0.028(3) -0.003(3)
C44 0.038(3) 0.023(3) 0.032(3) 0.006(3) 0.012(3) -0.005(3)
C45 0.060(5) 0.037(4) 0.056(5) 0.009(4) 0.028(4) -0.004(4)
C46 0.053(4) 0.044(4) 0.049(4) 0.008(4) 0.037(3) 0.000(4)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ge1 N1 2.015(4) . ?
Ge1 N2 2.038(4) . ?
Ge1 Ge2 2.5498(8) . ?
N1 C2 1.333(6) . ?
N1 C6 1.447(6) . ?
C1 C2 1.515(6) . ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
Ge2 C31 1.903(5) . ?
Ge2 N3 1.951(4) . ?
N2 C4 1.322(6) . ?
N2 C18 1.456(6) . ?
C2 C3 1.401(6) . ?
N3 C33 1.348(6) . ?
N3 C35 1.450(6) . ?
C3 C4 1.398(6) . ?
C3 H3 0.9500 . ?
C4 C5 1.510(6) . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C6 C7 1.395(6) . ?
C6 C11 1.401(7) . ?
C7 C8 1.396(7) . ?
C7 C15 1.531(7) . ?
C8 C9 1.379(6) . ?
C8 H8 0.9500 . ?
C9 C10 1.376(6) . ?
C9 H9 0.9500 . ?
C10 C11 1.387(6) . ?
C10 H10 0.9500 . ?
C11 C12 1.522(7) . ?
C12 C14 1.512(7) . ?
C12 C13 1.520(8) . ?
C12 H12 1.0000 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 C17 1.513(7) . ?
C15 C16 1.540(7) . ?
C15 H15 1.0000 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 C19 1.400(6) . ?
C18 C23 1.405(6) . ?
C19 C20 1.390(7) . ?
C19 C24 1.499(7) . ?
C20 C21 1.371(7) . ?
C20 H20 0.9500 . ?
C21 C22 1.373(7) . ?
C21 H21 0.9500 . ?
C22 C23 1.390(6) . ?
C22 H22 0.9500 . ?
C23 C27 1.520(6) . ?
C24 C25 1.527(7) . ?
C24 C26 1.529(7) . ?
C24 H24 1.0000 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C27 C28 1.523(6) . ?
C27 C29 1.534(6) . ?
C27 H27 1.0000 . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C30 C31 1.508(6) . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
C31 C32 1.377(6) . ?
C32 C33 1.391(7) . ?
C32 H32 0.9500 . ?
C33 C34 1.504(6) . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C35 C40 1.404(6) . ?
C35 C36 1.405(6) . ?
C36 C37 1.404(7) . ?
C36 C44 1.536(7) . ?
C37 C38 1.374(6) . ?
C37 H37 0.9500 . ?
C38 C39 1.374(6) . ?
C38 H38 0.9500 . ?
C39 C40 1.392(7) . ?
C39 H39 0.9500 . ?
C40 C41 1.525(7) . ?
C41 C43 1.513(7) . ?
C41 C42 1.526(6) . ?
C41 H41 1.0000 . ?
C42 H42A 0.9800 . ?
C42 H42B 0.9800 . ?
C42 H42C 0.9800 . ?
C43 H43A 0.9800 . ?
C43 H43B 0.9800 . ?
C43 H43C 0.9800 . ?
C44 C45 1.512(7) . ?
C44 C46 1.541(6) . ?
C44 H44 1.0000 . ?
C45 H45A 0.9800 . ?
C45 H45B 0.9800 . ?
C45 H45C 0.9800 . ?
C46 H46A 0.9800 . ?
C46 H46B 0.9800 . ?
C46 H46C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ge1 N2 88.67(15) . . ?
N1 Ge1 Ge2 104.30(11) . . ?
N2 Ge1 Ge2 101.49(12) . . ?
C2 N1 C6 118.0(4) . . ?
C2 N1 Ge1 113.3(3) . . ?
C6 N1 Ge1 127.2(3) . . ?
C2 C1 H1A 109.5 . . ?
C2 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
C2 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
C31 Ge2 N3 84.47(19) . . ?
C31 Ge2 Ge1 118.90(15) . . ?
N3 Ge2 Ge1 99.62(12) . . ?
C4 N2 C18 119.1(4) . . ?
C4 N2 Ge1 114.8(3) . . ?
C18 N2 Ge1 122.5(3) . . ?
N1 C2 C3 122.5(5) . . ?
N1 C2 C1 121.7(4) . . ?
C3 C2 C1 115.8(5) . . ?
C33 N3 C35 120.3(4) . . ?
C33 N3 Ge2 111.4(3) . . ?
C35 N3 Ge2 126.7(3) . . ?
C4 C3 C2 126.7(5) . . ?
C4 C3 H3 116.7 . . ?
C2 C3 H3 116.7 . . ?
N2 C4 C3 122.4(5) . . ?
N2 C4 C5 120.5(5) . . ?
C3 C4 C5 117.1(4) . . ?
C4 C5 H5A 109.5 . . ?
C4 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C4 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C7 C6 C11 121.4(5) . . ?
C7 C6 N1 119.5(5) . . ?
C11 C6 N1 119.0(5) . . ?
C6 C7 C8 118.5(5) . . ?
C6 C7 C15 122.8(5) . . ?
C8 C7 C15 118.8(5) . . ?
C9 C8 C7 120.6(5) . . ?
C9 C8 H8 119.7 . . ?
C7 C8 H8 119.7 . . ?
C10 C9 C8 120.1(5) . . ?
C10 C9 H9 119.9 . . ?
C8 C9 H9 119.9 . . ?
C9 C10 C11 121.3(5) . . ?
C9 C10 H10 119.3 . . ?
C11 C10 H10 119.3 . . ?
C10 C11 C6 118.0(5) . . ?
C10 C11 C12 118.9(5) . . ?
C6 C11 C12 123.1(5) . . ?
C14 C12 C13 107.6(5) . . ?
C14 C12 C11 113.8(5) . . ?
C13 C12 C11 112.0(5) . . ?
C14 C12 H12 107.8 . . ?
C13 C12 H12 107.8 . . ?
C11 C12 H12 107.8 . . ?
C12 C13 H13A 109.5 . . ?
C12 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C12 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C12 C14 H14A 109.5 . . ?
C12 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C12 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C17 C15 C7 112.0(5) . . ?
C17 C15 C16 111.0(5) . . ?
C7 C15 C16 110.8(5) . . ?
C17 C15 H15 107.6 . . ?
C7 C15 H15 107.6 . . ?
C16 C15 H15 107.6 . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C15 C17 H17A 109.5 . . ?
C15 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C15 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C19 C18 C23 120.9(5) . . ?
C19 C18 N2 119.4(5) . . ?
C23 C18 N2 119.6(4) . . ?
C20 C19 C18 117.8(5) . . ?
C20 C19 C24 119.8(5) . . ?
C18 C19 C24 122.4(5) . . ?
C21 C20 C19 122.1(5) . . ?
C21 C20 H20 118.9 . . ?
C19 C20 H20 118.9 . . ?
C20 C21 C22 119.4(5) . . ?
C20 C21 H21 120.3 . . ?
C22 C21 H21 120.3 . . ?
C21 C22 C23 121.4(5) . . ?
C21 C22 H22 119.3 . . ?
C23 C22 H22 119.3 . . ?
C22 C23 C18 118.3(5) . . ?
C22 C23 C27 118.6(5) . . ?
C18 C23 C27 123.0(4) . . ?
C19 C24 C25 113.5(5) . . ?
C19 C24 C26 111.2(5) . . ?
C25 C24 C26 110.2(5) . . ?
C19 C24 H24 107.2 . . ?
C25 C24 H24 107.2 . . ?
C26 C24 H24 107.2 . . ?
C24 C25 H25A 109.5 . . ?
C24 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C24 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C24 C26 H26A 109.5 . . ?
C24 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C24 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C23 C27 C28 110.8(4) . . ?
C23 C27 C29 113.4(4) . . ?
C28 C27 C29 110.4(4) . . ?
C23 C27 H27 107.3 . . ?
C28 C27 H27 107.3 . . ?
C29 C27 H27 107.3 . . ?
C27 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C27 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C27 C29 H29A 109.5 . . ?
C27 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C27 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C31 C30 H30A 109.5 . . ?
C31 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C31 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C32 C31 C30 119.2(5) . . ?
C32 C31 Ge2 110.5(4) . . ?
C30 C31 Ge2 129.5(4) . . ?
C31 C32 C33 117.5(5) . . ?
C31 C32 H32 121.2 . . ?
C33 C32 H32 121.2 . . ?
N3 C33 C32 114.7(5) . . ?
N3 C33 C34 122.7(5) . . ?
C32 C33 C34 122.4(5) . . ?
C33 C34 H34A 109.5 . . ?
C33 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
C33 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
C40 C35 C36 121.7(5) . . ?
C40 C35 N3 120.4(4) . . ?
C36 C35 N3 117.8(4) . . ?
C37 C36 C35 117.7(5) . . ?
C37 C36 C44 118.3(5) . . ?
C35 C36 C44 123.8(5) . . ?
C38 C37 C36 121.0(5) . . ?
C38 C37 H37 119.5 . . ?
C36 C37 H37 119.5 . . ?
C37 C38 C39 120.3(5) . . ?
C37 C38 H38 119.9 . . ?
C39 C38 H38 119.9 . . ?
C38 C39 C40 121.7(5) . . ?
C38 C39 H39 119.2 . . ?
C40 C39 H39 119.2 . . ?
C39 C40 C35 117.6(5) . . ?
C39 C40 C41 120.5(5) . . ?
C35 C40 C41 121.9(5) . . ?
C43 C41 C40 111.8(4) . . ?
C43 C41 C42 110.3(5) . . ?
C40 C41 C42 110.5(4) . . ?
C43 C41 H41 108.0 . . ?
C40 C41 H41 108.0 . . ?
C42 C41 H41 108.0 . . ?
C41 C42 H42A 109.5 . . ?
C41 C42 H42B 109.5 . . ?
H42A C42 H42B 109.5 . . ?
C41 C42 H42C 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
C41 C43 H43A 109.5 . . ?
C41 C43 H43B 109.5 . . ?
H43A C43 H43B 109.5 . . ?
C41 C43 H43C 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
C45 C44 C36 110.9(4) . . ?
C45 C44 C46 113.0(5) . . ?
C36 C44 C46 110.5(5) . . ?
C45 C44 H44 107.4 . . ?
C36 C44 H44 107.4 . . ?
C46 C44 H44 107.4 . . ?
C44 C45 H45A 109.5 . . ?
C44 C45 H45B 109.5 . . ?
H45A C45 H45B 109.5 . . ?
C44 C45 H45C 109.5 . . ?
H45A C45 H45C 109.5 . . ?
H45B C45 H45C 109.5 . . ?
C44 C46 H46A 109.5 . . ?
C44 C46 H46B 109.5 . . ?
H46A C46 H46B 109.5 . . ?
C44 C46 H46C 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?

_diffrn_measured_fraction_theta_max 0.992
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.992
_refine_diff_density_max         0.590
_refine_diff_density_min         -0.578
_refine_diff_density_rms         0.089

data_CCDC716014
_database_code_depnum_ccdc_archive 'CCDC 716014'

_audit_creation_method           
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.31.8 (release 12-01-2007 CrysAlis171 .NET)
(compiled Jan 12 2007,17:49:11)
;
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C46 H65 Ge N3 Sn'
_chemical_formula_weight         851.29

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   8.67780(10)
_cell_length_b                   12.0514(4)
_cell_length_c                   21.0797(6)
_cell_angle_alpha                96.333(2)
_cell_angle_beta                 97.393(2)
_cell_angle_gamma                99.141(2)
_cell_volume                     2139.08(10)
_cell_formula_units_Z            2
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    10926
_cell_measurement_theta_min      2.9450
_cell_measurement_theta_max      32.3712

_exptl_crystal_description       ?
_exptl_crystal_colour            ?
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.12
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.322
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             888
_exptl_absorpt_coefficient_mu    1.320
_exptl_absorpt_correction_T_min  0.99037
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.24 (release 21-04-2008 CrysAlis171 .NET)
(compiled Apr 21 2008,18:23:10)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Oxford Diffraction Xcalibur S Sapphire'
_diffrn_measurement_method       \w
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            16936
_diffrn_reflns_av_R_equivalents  0.0251
_diffrn_reflns_av_sigmaI/netI    0.0411
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_theta_min         2.95
_diffrn_reflns_theta_max         25.00
_reflns_number_total             7496
_reflns_number_gt                6141
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       
;
CrysAlis CCD, Oxford Diffraction Ltd.,
Version 1.171.31.8 (release 12-01-2007 CrysAlis171 .NET)
(compiled Jan 12 2007,17:49:11)
;
_computing_cell_refinement       
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.31.8 (release 12-01-2007 CrysAlis171 .NET)
(compiled Jan 12 2007,17:49:11)
;
_computing_data_reduction        
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.31.8 (release 12-01-2007 CrysAlis171 .NET)
(compiled Jan 12 2007,17:49:11)
;
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0430P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         7496
_refine_ls_number_parameters     494
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0438
_refine_ls_R_factor_gt           0.0310
_refine_ls_wR_factor_ref         0.0734
_refine_ls_wR_factor_gt          0.0707
_refine_ls_goodness_of_fit_ref   1.003
_refine_ls_restrained_S_all      1.003
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Sn1 Sn 0.58170(2) 0.270643(18) 0.268905(10) 0.01899(7) Uani 0.95 1 d P A 1
Ge1 Ge 0.31965(3) 0.36813(3) 0.252977(15) 0.02325(9) Uani 0.95 1 d P A 1
N1 N 0.5301(2) 0.1515(2) 0.34050(10) 0.0198(5) Uani 1 1 d . . .
C1 C 0.6425(3) -0.0009(3) 0.38758(14) 0.0270(7) Uani 1 1 d . . .
H1A H 0.6912 0.0553 0.4248 0.041 Uiso 1 1 calc R A .
H1B H 0.7185 -0.0489 0.3761 0.041 Uiso 1 1 calc R . .
H1C H 0.5493 -0.0481 0.3985 0.041 Uiso 1 1 calc R . .
N2 N 0.4821(2) 0.1166(2) 0.19791(11) 0.0188(5) Uani 1 1 d . . .
C2 C 0.5936(3) 0.0592(2) 0.33097(13) 0.0197(6) Uani 1 1 d . A .
N3 N 0.4099(2) 0.5250(2) 0.24463(11) 0.0206(5) Uani 1 1 d . . .
C3 C 0.6172(3) 0.0099(2) 0.27014(13) 0.0205(6) Uani 1 1 d . . .
H3 H 0.6904 -0.0409 0.2706 0.025 Uiso 1 1 calc R A .
C4 C 0.5463(3) 0.0261(2) 0.20835(13) 0.0189(6) Uani 1 1 d . A .
C5 C 0.5461(3) -0.0652(3) 0.15367(14) 0.0247(6) Uani 1 1 d . . .
H5A H 0.4371 -0.0981 0.1348 0.037 Uiso 1 1 calc R A .
H5B H 0.5994 -0.1246 0.1699 0.037 Uiso 1 1 calc R . .
H5C H 0.6019 -0.0326 0.1206 0.037 Uiso 1 1 calc R . .
C6 C 0.4823(3) 0.1829(2) 0.40251(13) 0.0215(6) Uani 1 1 d . A .
C7 C 0.5720(3) 0.2738(3) 0.44505(13) 0.0239(6) Uani 1 1 d . . .
C8 C 0.5182(3) 0.3079(3) 0.50236(14) 0.0295(7) Uani 1 1 d . A .
H8 H 0.5771 0.3712 0.5309 0.035 Uiso 1 1 calc R . .
C9 C 0.3802(3) 0.2508(3) 0.51818(14) 0.0314(7) Uani 1 1 d . . .
H9 H 0.3443 0.2749 0.5573 0.038 Uiso 1 1 calc R A .
C10 C 0.2955(3) 0.1589(3) 0.47703(14) 0.0297(7) Uani 1 1 d . A .
H10 H 0.2025 0.1187 0.4889 0.036 Uiso 1 1 calc R . .
C11 C 0.3417(3) 0.1230(3) 0.41853(14) 0.0248(6) Uani 1 1 d . . .
C12 C 0.2388(3) 0.0217(3) 0.37508(15) 0.0331(8) Uani 1 1 d . A .
H12 H 0.2934 0.0029 0.3373 0.040 Uiso 1 1 calc R . .
C13 C 0.0795(4) 0.0515(4) 0.34970(18) 0.0519(10) Uani 1 1 d . . .
H13A H 0.0259 0.0732 0.3861 0.078 Uiso 1 1 calc R A .
H13B H 0.0143 -0.0145 0.3222 0.078 Uiso 1 1 calc R . .
H13C H 0.0962 0.1149 0.3245 0.078 Uiso 1 1 calc R . .
C14 C 0.2123(4) -0.0834(3) 0.40985(18) 0.0471(9) Uani 1 1 d . . .
H14A H 0.3142 -0.0983 0.4296 0.071 Uiso 1 1 calc R A .
H14B H 0.1589 -0.1490 0.3787 0.071 Uiso 1 1 calc R . .
H14C H 0.1466 -0.0702 0.4435 0.071 Uiso 1 1 calc R . .
C15 C 0.7309(3) 0.3369(3) 0.43301(15) 0.0304(7) Uani 1 1 d . A .
H15 H 0.7534 0.3014 0.3908 0.037 Uiso 1 1 calc R . .
C16 C 0.7266(4) 0.4617(3) 0.42808(17) 0.0438(9) Uani 1 1 d . . .
H16A H 0.6385 0.4679 0.3953 0.066 Uiso 1 1 calc R A .
H16B H 0.8259 0.4975 0.4158 0.066 Uiso 1 1 calc R . .
H16C H 0.7125 0.4999 0.4699 0.066 Uiso 1 1 calc R . .
C17 C 0.8629(3) 0.3234(3) 0.48545(16) 0.0391(8) Uani 1 1 d . . .
H17A H 0.8433 0.3573 0.5275 0.059 Uiso 1 1 calc R A .
H17B H 0.9643 0.3617 0.4762 0.059 Uiso 1 1 calc R . .
H17C H 0.8658 0.2427 0.4864 0.059 Uiso 1 1 calc R . .
C18 C 0.3946(3) 0.1218(2) 0.13558(13) 0.0198(6) Uani 1 1 d . A .
C19 C 0.2295(3) 0.0885(2) 0.12617(13) 0.0221(6) Uani 1 1 d . . .
C20 C 0.1468(3) 0.0917(3) 0.06579(14) 0.0261(7) Uani 1 1 d . A .
H20 H 0.0357 0.0672 0.0583 0.031 Uiso 1 1 calc R . .
C21 C 0.2213(3) 0.1294(3) 0.01662(14) 0.0280(7) Uani 1 1 d . . .
H21 H 0.1622 0.1303 -0.0245 0.034 Uiso 1 1 calc R A .
C22 C 0.3830(3) 0.1661(3) 0.02710(14) 0.0251(6) Uani 1 1 d . A .
H22 H 0.4340 0.1941 -0.0067 0.030 Uiso 1 1 calc R . .
C23 C 0.4718(3) 0.1628(2) 0.08633(14) 0.0217(6) Uani 1 1 d . . .
C24 C 0.6499(3) 0.2086(2) 0.09603(14) 0.0249(6) Uani 1 1 d . A .
H24 H 0.6996 0.1818 0.1357 0.030 Uiso 1 1 calc R . .
C25 C 0.6794(4) 0.3378(3) 0.10654(16) 0.0337(7) Uani 1 1 d . . .
H25A H 0.6364 0.3659 0.0673 0.051 Uiso 1 1 calc R A .
H25B H 0.7932 0.3664 0.1166 0.051 Uiso 1 1 calc R . .
H25C H 0.6275 0.3643 0.1425 0.051 Uiso 1 1 calc R . .
C26 C 0.7287(4) 0.1669(3) 0.03922(16) 0.0355(8) Uani 1 1 d . . .
H26A H 0.6852 0.1955 0.0002 0.053 Uiso 1 1 calc R A .
H26B H 0.7086 0.0838 0.0323 0.053 Uiso 1 1 calc R . .
H26C H 0.8427 0.1948 0.0488 0.053 Uiso 1 1 calc R . .
C27 C 0.1426(3) 0.0498(3) 0.18047(15) 0.0295(7) Uani 1 1 d . A .
H27 H 0.2105 0.0831 0.2223 0.035 Uiso 1 1 calc R B 2
C28 C -0.0143(3) 0.0924(3) 0.17963(17) 0.0416(9) Uani 1 1 d . . .
H28A H -0.0873 0.0547 0.1412 0.062 Uiso 1 1 calc R A .
H28B H 0.0036 0.1745 0.1788 0.062 Uiso 1 1 calc R . .
H28C H -0.0597 0.0752 0.2184 0.062 Uiso 1 1 calc R . .
C29 C 0.1175(4) -0.0779(3) 0.17754(19) 0.0465(9) Uani 1 1 d . . .
H29A H 0.0572 -0.1008 0.2116 0.070 Uiso 1 1 calc R A .
H29B H 0.2200 -0.1026 0.1838 0.070 Uiso 1 1 calc R . .
H29C H 0.0589 -0.1129 0.1354 0.070 Uiso 1 1 calc R . .
C30 C 0.1703(4) 0.3767(3) 0.37755(17) 0.0451(9) Uani 1 1 d . A .
H30A H 0.1317 0.4333 0.4055 0.068 Uiso 1 1 calc R . .
H30B H 0.2391 0.3370 0.4040 0.068 Uiso 1 1 calc R . .
H30C H 0.0805 0.3220 0.3535 0.068 Uiso 1 1 calc R . .
C31 C 0.2613(3) 0.4345(3) 0.33118(15) 0.0287(7) Uani 1 1 d . . .
C32 C 0.2858(3) 0.5510(3) 0.33426(14) 0.0276(7) Uani 1 1 d . A .
H32 H 0.2516 0.5968 0.3674 0.033 Uiso 1 1 calc R . .
C33 C 0.3629(3) 0.5996(3) 0.28686(14) 0.0241(6) Uani 1 1 d . A .
C34 C 0.3728(4) 0.7216(3) 0.27892(17) 0.0384(8) Uani 1 1 d . . .
H34A H 0.4678 0.7473 0.2602 0.058 Uiso 1 1 calc R A .
H34B H 0.3777 0.7663 0.3211 0.058 Uiso 1 1 calc R . .
H34C H 0.2793 0.7316 0.2502 0.058 Uiso 1 1 calc R . .
C35 C 0.4894(3) 0.5632(2) 0.19304(14) 0.0230(6) Uani 1 1 d . A .
C36 C 0.4008(3) 0.5639(3) 0.13249(14) 0.0263(7) Uani 1 1 d . . .
C37 C 0.4819(4) 0.6009(3) 0.08387(15) 0.0338(8) Uani 1 1 d . A .
H37 H 0.4250 0.6000 0.0421 0.041 Uiso 1 1 calc R . .
C38 C 0.6428(4) 0.6388(3) 0.09460(16) 0.0354(8) Uani 1 1 d . . .
H38 H 0.6952 0.6653 0.0608 0.042 Uiso 1 1 calc R A .
C39 C 0.7277(4) 0.6381(3) 0.15486(16) 0.0330(8) Uani 1 1 d . A .
H39 H 0.8384 0.6645 0.1620 0.040 Uiso 1 1 calc R . .
C40 C 0.6542(3) 0.5996(2) 0.20521(14) 0.0250(7) Uani 1 1 d . . .
C41 C 0.7508(3) 0.5967(3) 0.26988(15) 0.0312(7) Uani 1 1 d . A .
H41 H 0.6830 0.5488 0.2950 0.037 Uiso 1 1 calc R . .
C42 C 0.7985(5) 0.7139(3) 0.30820(18) 0.0517(10) Uani 1 1 d . . .
H42A H 0.8588 0.7644 0.2832 0.078 Uiso 1 1 calc R A .
H42B H 0.8639 0.7093 0.3490 0.078 Uiso 1 1 calc R . .
H42C H 0.7038 0.7438 0.3171 0.078 Uiso 1 1 calc R . .
C43 C 0.8973(4) 0.5435(3) 0.26329(18) 0.0482(10) Uani 1 1 d . . .
H43A H 0.8657 0.4672 0.2391 0.072 Uiso 1 1 calc R A .
H43B H 0.9520 0.5386 0.3063 0.072 Uiso 1 1 calc R . .
H43C H 0.9681 0.5904 0.2403 0.072 Uiso 1 1 calc R . .
C44 C 0.2226(3) 0.5248(3) 0.11899(15) 0.0308(7) Uani 1 1 d . A .
H44 H 0.1846 0.5153 0.1612 0.037 Uiso 1 1 calc R . .
C45 C 0.1804(4) 0.4111(3) 0.07697(19) 0.0518(10) Uani 1 1 d . . .
H45A H 0.2157 0.4182 0.0350 0.078 Uiso 1 1 calc R A .
H45B H 0.0658 0.3860 0.0706 0.078 Uiso 1 1 calc R . .
H45C H 0.2325 0.3555 0.0980 0.078 Uiso 1 1 calc R . .
C46 C 0.1376(4) 0.6125(4) 0.0882(2) 0.0526(10) Uani 1 1 d . . .
H46A H 0.1658 0.6187 0.0451 0.079 Uiso 1 1 calc R A .
H46B H 0.1694 0.6863 0.1151 0.079 Uiso 1 1 calc R . .
H46C H 0.0232 0.5883 0.0849 0.079 Uiso 1 1 calc R . .
Sn1A Sn 0.3282(8) 0.2030(7) 0.2707(3) 0.0768(19) Uani 0.05 1 d P A 2
Ge1A Ge 0.4843(16) 0.4243(12) 0.3017(7) 0.100(4) Uani 0.05 1 d P A 2

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Sn1 0.02332(11) 0.01748(12) 0.01615(11) 0.00405(8) 0.00292(8) 0.00226(8)
Ge1 0.02501(17) 0.02036(18) 0.02612(19) 0.00621(14) 0.00648(14) 0.00492(14)
N1 0.0223(11) 0.0232(13) 0.0138(12) 0.0047(10) 0.0023(9) 0.0026(10)
C1 0.0345(16) 0.0282(17) 0.0205(16) 0.0093(13) 0.0030(13) 0.0085(14)
N2 0.0193(11) 0.0201(13) 0.0175(12) 0.0032(10) 0.0002(9) 0.0067(10)
C2 0.0155(13) 0.0214(16) 0.0212(15) 0.0076(12) 0.0002(11) -0.0005(11)
N3 0.0244(12) 0.0196(13) 0.0190(13) 0.0031(10) 0.0068(10) 0.0044(10)
C3 0.0207(13) 0.0193(15) 0.0231(15) 0.0069(12) 0.0028(11) 0.0057(12)
C4 0.0152(13) 0.0180(15) 0.0226(15) 0.0041(12) 0.0024(11) -0.0002(11)
C5 0.0285(15) 0.0236(16) 0.0237(16) 0.0029(13) 0.0046(12) 0.0097(13)
C6 0.0247(14) 0.0254(16) 0.0160(15) 0.0060(12) 0.0031(11) 0.0063(12)
C7 0.0283(15) 0.0243(17) 0.0201(15) 0.0046(13) 0.0035(12) 0.0063(13)
C8 0.0349(16) 0.0319(18) 0.0207(16) 0.0013(14) 0.0031(13) 0.0051(14)
C9 0.0386(17) 0.039(2) 0.0206(16) 0.0051(14) 0.0089(14) 0.0137(15)
C10 0.0272(15) 0.0355(19) 0.0288(18) 0.0117(15) 0.0085(13) 0.0044(14)
C11 0.0264(14) 0.0266(17) 0.0222(16) 0.0080(13) 0.0030(12) 0.0037(13)
C12 0.0306(16) 0.0362(19) 0.0294(18) 0.0007(15) 0.0067(14) -0.0034(14)
C13 0.0364(19) 0.066(3) 0.046(2) -0.002(2) 0.0003(17) -0.0032(19)
C14 0.052(2) 0.036(2) 0.050(2) 0.0052(18) 0.0160(18) -0.0065(17)
C15 0.0347(16) 0.0334(19) 0.0201(16) 0.0021(14) 0.0051(13) -0.0031(14)
C16 0.054(2) 0.036(2) 0.037(2) 0.0075(17) 0.0047(17) -0.0058(17)
C17 0.0283(16) 0.053(2) 0.0326(19) 0.0081(17) 0.0042(14) -0.0034(16)
C18 0.0277(14) 0.0141(14) 0.0171(15) -0.0003(11) 0.0002(11) 0.0068(12)
C19 0.0237(14) 0.0210(16) 0.0214(15) 0.0013(12) 0.0018(12) 0.0059(12)
C20 0.0223(14) 0.0251(17) 0.0292(17) 0.0010(13) -0.0012(12) 0.0053(12)
C21 0.0345(16) 0.0280(18) 0.0200(16) 0.0023(13) -0.0044(13) 0.0088(14)
C22 0.0344(16) 0.0233(16) 0.0194(16) 0.0047(13) 0.0041(13) 0.0089(13)
C23 0.0278(14) 0.0153(15) 0.0227(16) 0.0000(12) 0.0036(12) 0.0082(12)
C24 0.0274(15) 0.0243(16) 0.0239(16) 0.0052(13) 0.0031(12) 0.0071(13)
C25 0.0348(17) 0.0282(18) 0.0358(19) 0.0027(15) 0.0048(14) -0.0004(14)
C26 0.0358(17) 0.037(2) 0.0367(19) 0.0078(16) 0.0125(15) 0.0095(15)
C27 0.0220(14) 0.0379(19) 0.0272(17) 0.0070(14) -0.0005(12) 0.0030(13)
C28 0.0287(16) 0.059(3) 0.040(2) 0.0116(18) 0.0090(15) 0.0099(16)
C29 0.0431(19) 0.043(2) 0.057(2) 0.0195(19) 0.0147(18) 0.0056(17)
C30 0.053(2) 0.049(2) 0.045(2) 0.0223(18) 0.0253(18) 0.0181(18)
C31 0.0235(14) 0.038(2) 0.0286(17) 0.0112(15) 0.0075(13) 0.0109(14)
C32 0.0278(15) 0.0365(19) 0.0193(16) 0.0002(14) 0.0045(12) 0.0093(14)
C33 0.0218(14) 0.0265(17) 0.0217(16) -0.0034(13) -0.0003(12) 0.0047(12)
C34 0.0450(19) 0.0266(18) 0.046(2) -0.0002(16) 0.0195(16) 0.0067(15)
C35 0.0305(15) 0.0181(15) 0.0238(16) 0.0056(12) 0.0087(12) 0.0090(13)
C36 0.0323(15) 0.0258(17) 0.0243(16) 0.0057(13) 0.0090(13) 0.0104(13)
C37 0.0455(19) 0.037(2) 0.0246(17) 0.0110(15) 0.0112(14) 0.0162(16)
C38 0.0478(19) 0.0345(19) 0.0349(19) 0.0189(16) 0.0249(16) 0.0156(16)
C39 0.0296(16) 0.0292(18) 0.044(2) 0.0090(15) 0.0137(15) 0.0078(14)
C40 0.0261(15) 0.0212(16) 0.0301(17) 0.0057(13) 0.0081(13) 0.0066(13)
C41 0.0234(15) 0.0332(19) 0.0360(19) 0.0085(15) 0.0037(13) -0.0002(13)
C42 0.062(2) 0.044(2) 0.043(2) -0.0016(18) -0.0035(18) 0.0057(19)
C43 0.0346(18) 0.060(3) 0.051(2) 0.008(2) -0.0016(17) 0.0146(18)
C44 0.0349(16) 0.0369(19) 0.0229(17) 0.0061(14) 0.0042(13) 0.0121(15)
C45 0.044(2) 0.055(3) 0.051(2) -0.009(2) 0.0064(18) 0.0076(19)
C46 0.043(2) 0.060(3) 0.060(3) 0.017(2) 0.0012(18) 0.0229(19)
Sn1A 0.089(4) 0.082(5) 0.058(4) 0.012(4) 0.003(4) 0.017(4)
Ge1A 0.114(9) 0.098(10) 0.093(9) 0.023(8) 0.004(8) 0.036(8)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sn1 N2 2.231(2) . ?
Sn1 N1 2.233(2) . ?
Sn1 Ge1 2.7210(4) . ?
Ge1 C31 1.915(3) . ?
Ge1 N3 1.964(2) . ?
N1 C2 1.325(4) . ?
N1 C6 1.450(3) . ?
N1 Sn1A 2.346(7) . ?
C1 C2 1.513(4) . ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
N2 C4 1.327(4) . ?
N2 C18 1.444(3) . ?
N2 Sn1A 2.417(8) . ?
C2 C3 1.406(4) . ?
N3 C33 1.342(3) . ?
N3 C35 1.439(3) . ?
N3 Ge1A 1.926(14) . ?
C3 C4 1.415(4) . ?
C3 H3 0.9500 . ?
C4 C5 1.503(4) . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C6 C7 1.394(4) . ?
C6 C11 1.415(4) . ?
C7 C8 1.394(4) . ?
C7 C15 1.530(4) . ?
C8 C9 1.382(4) . ?
C8 H8 0.9500 . ?
C9 C10 1.373(4) . ?
C9 H9 0.9500 . ?
C10 C11 1.391(4) . ?
C10 H10 0.9500 . ?
C11 C12 1.524(4) . ?
C12 C13 1.528(5) . ?
C12 C14 1.534(5) . ?
C12 H12 1.0000 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 C16 1.525(5) . ?
C15 C17 1.528(4) . ?
C15 H15 1.0000 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 C23 1.399(4) . ?
C18 C19 1.407(4) . ?
C19 C20 1.386(4) . ?
C19 C27 1.525(4) . ?
C20 C21 1.372(4) . ?
C20 H20 0.9500 . ?
C21 C22 1.384(4) . ?
C21 H21 0.9500 . ?
C22 C23 1.388(4) . ?
C22 H22 0.9500 . ?
C23 C24 1.535(4) . ?
C24 C25 1.525(4) . ?
C24 C26 1.530(4) . ?
C24 H24 1.0000 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C27 C29 1.513(5) . ?
C27 C28 1.528(4) . ?
C27 Sn1A 2.668(8) . ?
C27 H27 1.0000 . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C30 C31 1.496(4) . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
C31 C32 1.380(4) . ?
C31 Ge1A 2.125(14) . ?
C32 C33 1.402(4) . ?
C32 H32 0.9500 . ?
C33 C34 1.488(4) . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C35 C36 1.404(4) . ?
C35 C40 1.409(4) . ?
C36 C37 1.390(4) . ?
C36 C44 1.523(4) . ?
C37 C38 1.380(4) . ?
C37 H37 0.9500 . ?
C38 C39 1.386(5) . ?
C38 H38 0.9500 . ?
C39 C40 1.392(4) . ?
C39 H39 0.9500 . ?
C40 C41 1.513(4) . ?
C41 C42 1.515(5) . ?
C41 C43 1.527(4) . ?
C41 H41 1.0000 . ?
C42 H42A 0.9800 . ?
C42 H42B 0.9800 . ?
C42 H42C 0.9800 . ?
C43 H43A 0.9800 . ?
C43 H43B 0.9800 . ?
C43 H43C 0.9800 . ?
C44 C45 1.512(5) . ?
C44 C46 1.535(5) . ?
C44 H44 1.0000 . ?
C45 H45A 0.9800 . ?
C45 H45B 0.9800 . ?
C45 H45C 0.9800 . ?
C46 H46A 0.9800 . ?
C46 H46B 0.9800 . ?
C46 H46C 0.9800 . ?
Sn1A Ge1A 2.759(17) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Sn1 N1 82.88(8) . . ?
N2 Sn1 Ge1 95.41(5) . . ?
N1 Sn1 Ge1 103.68(5) . . ?
C31 Ge1 N3 84.34(12) . . ?
C31 Ge1 Sn1 114.94(9) . . ?
N3 Ge1 Sn1 102.00(6) . . ?
C2 N1 C6 119.7(2) . . ?
C2 N1 Sn1 112.43(17) . . ?
C6 N1 Sn1 124.81(18) . . ?
C2 N1 Sn1A 126.1(3) . . ?
C6 N1 Sn1A 100.6(2) . . ?
Sn1 N1 Sn1A 58.17(19) . . ?
C2 C1 H1A 109.5 . . ?
C2 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
C2 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
C4 N2 C18 120.1(2) . . ?
C4 N2 Sn1 114.44(17) . . ?
C18 N2 Sn1 122.68(17) . . ?
C4 N2 Sn1A 123.7(3) . . ?
C18 N2 Sn1A 102.1(2) . . ?
Sn1 N2 Sn1A 57.11(18) . . ?
N1 C2 C3 124.1(3) . . ?
N1 C2 C1 119.8(2) . . ?
C3 C2 C1 116.1(2) . . ?
C33 N3 C35 120.4(2) . . ?
C33 N3 Ge1A 100.4(5) . . ?
C35 N3 Ge1A 124.2(4) . . ?
C33 N3 Ge1 111.51(18) . . ?
C35 N3 Ge1 126.90(18) . . ?
Ge1A N3 Ge1 50.1(4) . . ?
C2 C3 C4 128.5(2) . . ?
C2 C3 H3 115.7 . . ?
C4 C3 H3 115.7 . . ?
N2 C4 C3 122.8(2) . . ?
N2 C4 C5 120.5(2) . . ?
C3 C4 C5 116.7(2) . . ?
C4 C5 H5A 109.5 . . ?
C4 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C4 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C7 C6 C11 120.4(3) . . ?
C7 C6 N1 120.0(2) . . ?
C11 C6 N1 119.6(2) . . ?
C8 C7 C6 119.1(3) . . ?
C8 C7 C15 117.7(3) . . ?
C6 C7 C15 123.1(2) . . ?
C9 C8 C7 120.9(3) . . ?
C9 C8 H8 119.6 . . ?
C7 C8 H8 119.6 . . ?
C10 C9 C8 119.5(3) . . ?
C10 C9 H9 120.2 . . ?
C8 C9 H9 120.2 . . ?
C9 C10 C11 121.9(3) . . ?
C9 C10 H10 119.0 . . ?
C11 C10 H10 119.0 . . ?
C10 C11 C6 118.0(3) . . ?
C10 C11 C12 118.5(3) . . ?
C6 C11 C12 123.5(3) . . ?
C11 C12 C13 110.3(3) . . ?
C11 C12 C14 112.2(3) . . ?
C13 C12 C14 109.5(3) . . ?
C11 C12 H12 108.2 . . ?
C13 C12 H12 108.2 . . ?
C14 C12 H12 108.2 . . ?
C12 C13 H13A 109.5 . . ?
C12 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C12 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C12 C14 H14A 109.5 . . ?
C12 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C12 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C16 C15 C17 111.2(3) . . ?
C16 C15 C7 111.7(3) . . ?
C17 C15 C7 110.5(2) . . ?
C16 C15 H15 107.8 . . ?
C17 C15 H15 107.8 . . ?
C7 C15 H15 107.8 . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C15 C17 H17A 109.5 . . ?
C15 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C15 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C23 C18 C19 120.8(3) . . ?
C23 C18 N2 120.7(2) . . ?
C19 C18 N2 118.5(2) . . ?
C20 C19 C18 118.1(3) . . ?
C20 C19 C27 120.4(2) . . ?
C18 C19 C27 121.4(2) . . ?
C21 C20 C19 121.7(3) . . ?
C21 C20 H20 119.2 . . ?
C19 C20 H20 119.2 . . ?
C20 C21 C22 119.7(3) . . ?
C20 C21 H21 120.1 . . ?
C22 C21 H21 120.1 . . ?
C21 C22 C23 120.9(3) . . ?
C21 C22 H22 119.6 . . ?
C23 C22 H22 119.6 . . ?
C22 C23 C18 118.7(2) . . ?
C22 C23 C24 118.6(3) . . ?
C18 C23 C24 122.6(2) . . ?
C25 C24 C26 109.6(3) . . ?
C25 C24 C23 109.9(2) . . ?
C26 C24 C23 112.6(2) . . ?
C25 C24 H24 108.2 . . ?
C26 C24 H24 108.2 . . ?
C23 C24 H24 108.2 . . ?
C24 C25 H25A 109.5 . . ?
C24 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C24 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C24 C26 H26A 109.5 . . ?
C24 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C24 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C29 C27 C19 111.0(3) . . ?
C29 C27 C28 110.7(3) . . ?
C19 C27 C28 111.7(3) . . ?
C29 C27 Sn1A 127.4(3) . . ?
C19 C27 Sn1A 93.6(2) . . ?
C28 C27 Sn1A 101.0(3) . . ?
C29 C27 H27 107.7 . . ?
C19 C27 H27 107.7 . . ?
C28 C27 H27 107.7 . . ?
Sn1A C27 H27 20.3 . . ?
C27 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C27 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C27 C29 H29A 109.5 . . ?
C27 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C27 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C31 C30 H30A 109.5 . . ?
C31 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C31 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C32 C31 C30 120.6(3) . . ?
C32 C31 Ge1 110.0(2) . . ?
C30 C31 Ge1 128.2(3) . . ?
C32 C31 Ge1A 92.5(4) . . ?
C30 C31 Ge1A 133.6(4) . . ?
Ge1 C31 Ge1A 47.8(4) . . ?
C31 C32 C33 117.8(3) . . ?
C31 C32 H32 121.1 . . ?
C33 C32 H32 121.1 . . ?
N3 C33 C32 114.5(3) . . ?
N3 C33 C34 122.5(3) . . ?
C32 C33 C34 122.5(3) . . ?
C33 C34 H34A 109.5 . . ?
C33 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
C33 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
C36 C35 C40 122.0(3) . . ?
C36 C35 N3 119.3(2) . . ?
C40 C35 N3 118.7(3) . . ?
C37 C36 C35 117.5(3) . . ?
C37 C36 C44 120.1(3) . . ?
C35 C36 C44 122.4(3) . . ?
C38 C37 C36 121.8(3) . . ?
C38 C37 H37 119.1 . . ?
C36 C37 H37 119.1 . . ?
C37 C38 C39 119.7(3) . . ?
C37 C38 H38 120.2 . . ?
C39 C38 H38 120.2 . . ?
C38 C39 C40 121.4(3) . . ?
C38 C39 H39 119.3 . . ?
C40 C39 H39 119.3 . . ?
C39 C40 C35 117.5(3) . . ?
C39 C40 C41 120.2(3) . . ?
C35 C40 C41 122.3(3) . . ?
C40 C41 C42 111.6(3) . . ?
C40 C41 C43 112.4(3) . . ?
C42 C41 C43 109.7(3) . . ?
C40 C41 H41 107.6 . . ?
C42 C41 H41 107.6 . . ?
C43 C41 H41 107.6 . . ?
C41 C42 H42A 109.5 . . ?
C41 C42 H42B 109.5 . . ?
H42A C42 H42B 109.5 . . ?
C41 C42 H42C 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
C41 C43 H43A 109.5 . . ?
C41 C43 H43B 109.5 . . ?
H43A C43 H43B 109.5 . . ?
C41 C43 H43C 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
C45 C44 C36 110.8(3) . . ?
C45 C44 C46 110.5(3) . . ?
C36 C44 C46 112.0(3) . . ?
C45 C44 H44 107.8 . . ?
C36 C44 H44 107.8 . . ?
C46 C44 H44 107.8 . . ?
C44 C45 H45A 109.5 . . ?
C44 C45 H45B 109.5 . . ?
H45A C45 H45B 109.5 . . ?
C44 C45 H45C 109.5 . . ?
H45A C45 H45C 109.5 . . ?
H45B C45 H45C 109.5 . . ?
C44 C46 H46A 109.5 . . ?
C44 C46 H46B 109.5 . . ?
H46A C46 H46B 109.5 . . ?
C44 C46 H46C 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
N1 Sn1A N2 76.7(2) . . ?
N1 Sn1A C27 120.9(3) . . ?
N2 Sn1A C27 69.1(2) . . ?
N1 Sn1A Ge1A 87.5(4) . . ?
N2 Sn1A Ge1A 104.2(4) . . ?
C27 Sn1A Ge1A 146.1(4) . . ?
N3 Ge1A C31 79.9(5) . . ?
N3 Ge1A Sn1A 113.5(6) . . ?
C31 Ge1A Sn1A 77.9(5) . . ?

_diffrn_measured_fraction_theta_max 0.994
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.994
_refine_diff_density_max         1.469
_refine_diff_density_min         -0.465
_refine_diff_density_rms         0.065