# Electronic Supplementary Material (ESI) for Chemical Communications
# This journal is © The Royal Society of Chemistry 2012


data_global
_journal_name_full               Chem.Commun.
_journal_coden_cambridge         0182
_journal_year                    ?
_journal_volume                  ?
_journal_page_first              ?
_publ_contact_author_email       schelter@sas.upenn.edu
_publ_contact_author_name        'Ursula J.William'
loop_
_publ_author_name
'Ursula J.Williams'
'Brian D. Mahoney'
'Patrick T.DeGregorio'
'Patrick Carroll'
'Eiko Nakamaru-Ogiso'
'James M.Kikkawa'

data_UP431
_database_code_depnum_ccdc_archive 'CCDC 868275'
#TrackingRef '- 431.cif'

_audit_creation_method           SHELXL-97

_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C60 H78 Dy K N8 O8'
_chemical_formula_weight         1240.90

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 21/m '
_symmetry_Int_Tables_number      11

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
'-x, -y, -z'
'x, -y-1/2, z'

_cell_length_a                   11.5601(9)
_cell_length_b                   17.6684(14)
_cell_length_c                   14.8072(12)
_cell_angle_alpha                90.00
_cell_angle_beta                 105.726(4)
_cell_angle_gamma                90.00
_cell_volume                     2911.1(4)
_cell_formula_units_Z            2
_cell_measurement_temperature    143(1)
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.03

_exptl_crystal_density_diffrn    1.416
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1286
_exptl_absorpt_coefficient_mu    1.416
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 2007)'
_exptl_absorpt_correction_T_min  0.6436
_exptl_absorpt_correction_T_max  0.7456
_diffrn_ambient_temperature      143(1)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device       'CCD Area Detector'
_diffrn_measurement_device_type  'Bruker APEXII'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_reflns_number            63950
_diffrn_reflns_av_R_equivalents  0.0321
_diffrn_reflns_av_sigmaI/netI    0.0177
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         1.83
_diffrn_reflns_theta_max         27.64
_reflns_number_total             6921
_reflns_number_gt                6400
_reflns_threshold_expression     >2sigma(I)
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0238P)^2^+1.1251P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         6921
_refine_ls_number_parameters     470
_refine_ls_number_restraints     36
_refine_ls_R_factor_all          0.0214
_refine_ls_R_factor_gt           0.0175
_refine_ls_wR_factor_ref         0.0442
_refine_ls_wR_factor_gt          0.0427
_refine_ls_goodness_of_fit_ref   1.031
_refine_ls_restrained_S_all      1.030
_refine_ls_shift/su_max          0.008
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.632356(8) 0.2500 0.289914(6) 0.01390(3) Uani 1 2 d S . .
N1 N 0.59521(10) 0.16864(6) 0.15098(8) 0.0170(2) Uani 1 1 d . . .
N2 N 0.45444(10) 0.16855(7) 0.26382(8) 0.0178(2) Uani 1 1 d . . .
N3 N 0.81734(11) 0.17565(7) 0.31001(8) 0.0211(2) Uani 1 1 d . . .
N4 N 0.66057(11) 0.17545(7) 0.43315(8) 0.0212(3) Uani 1 1 d . . .
C1 C 0.57955(13) 0.09781(8) 0.18991(10) 0.0203(3) Uani 1 1 d . . .
C2 C 0.64276(15) 0.03190(9) 0.18169(13) 0.0296(3) Uani 1 1 d . . .
H2 H 0.6947 0.0320 0.1434 0.039 Uiso 1 1 calc R . .
C3 C 0.62977(16) -0.03331(9) 0.22910(15) 0.0389(4) Uani 1 1 d . . .
H3 H 0.6706 -0.0771 0.2212 0.052 Uiso 1 1 calc R . .
C4 C 0.55549(16) -0.03352(9) 0.28875(15) 0.0389(4) Uani 1 1 d . . .
H4 H 0.5470 -0.0774 0.3211 0.052 Uiso 1 1 calc R . .
C5 C 0.49424(14) 0.03137(9) 0.30003(13) 0.0304(4) Uani 1 1 d . . .
H5 H 0.4462 0.0309 0.3413 0.040 Uiso 1 1 calc R . .
C6 C 0.50295(13) 0.09787(8) 0.25066(10) 0.0207(3) Uani 1 1 d . . .
C7 C 0.34251(13) 0.17842(9) 0.26879(10) 0.0212(3) Uani 1 1 d . . .
C8 C 0.29361(18) 0.2500 0.27621(15) 0.0223(4) Uani 1 2 d S . .
H8 H 0.2184 0.2500 0.2876 0.030 Uiso 1 2 calc SR . .
C9 C 0.59560(13) 0.17827(8) 0.06279(10) 0.0212(3) Uani 1 1 d . . .
C10 C 0.6019(2) 0.2500 0.02394(14) 0.0244(4) Uani 1 2 d S . .
H10 H 0.6116 0.2500 -0.0364 0.032 Uiso 1 2 calc SR . .
C11 C 0.25504(15) 0.11312(10) 0.25802(15) 0.0375(4) Uani 1 1 d . . .
H11a H 0.2760 0.0746 0.2195 0.056 Uiso 1 1 calc R . .
H11b H 0.1751 0.1308 0.2290 0.056 Uiso 1 1 calc R . .
H11c H 0.2585 0.0925 0.3187 0.056 Uiso 1 1 calc R . .
C12 C 0.57923(18) 0.11258(10) -0.00594(12) 0.0362(4) Uani 1 1 d . . .
H12a H 0.6560 0.0902 -0.0025 0.054 Uiso 1 1 calc R . .
H12b H 0.5441 0.1308 -0.0685 0.054 Uiso 1 1 calc R . .
H12c H 0.5273 0.0754 0.0097 0.054 Uiso 1 1 calc R . .
C13 C 0.86452(14) 0.11717(10) 0.36222(11) 0.0293(3) Uani 1 1 d . . .
C14 C 0.81356(16) 0.08521(10) 0.42926(12) 0.0331(4) Uani 1 1 d . . .
H14 H 0.8460 0.0390 0.4537 0.044 Uiso 1 1 calc R . .
C15 C 0.72091(15) 0.11276(10) 0.46471(11) 0.0282(3) Uani 1 1 d . . .
C16 C 0.57557(13) 0.20949(9) 0.47271(10) 0.0227(3) Uani 1 1 d . . .
C17 C 0.48424(15) 0.17175(10) 0.50027(11) 0.0302(4) Uani 1 1 d . . .
H17 H 0.4821 0.1191 0.4989 0.040 Uiso 1 1 calc R . .
C18 C 0.39706(16) 0.21087(11) 0.52946(12) 0.0352(4) Uani 1 1 d . . .
H18 H 0.3385 0.1845 0.5491 0.047 Uiso 1 1 calc R . .
C19 C 0.86941(12) 0.20994(9) 0.24440(10) 0.0222(3) Uani 1 1 d . . .
C20 C 0.90651(14) 0.17156(10) 0.17437(11) 0.0290(3) Uani 1 1 d . . .
H20 H 0.9048 0.1189 0.1729 0.039 Uiso 1 1 calc R . .
C21 C 0.94573(15) 0.21090(11) 0.10716(12) 0.0340(4) Uani 1 1 d . . .
H21 H 0.9721 0.1846 0.0620 0.045 Uiso 1 1 calc R . .
C22 C 0.98419(19) 0.08333(14) 0.35831(16) 0.0548(6) Uani 1 1 d . . .
H22a H 0.9710 0.0480 0.3072 0.082 Uiso 1 1 calc R . .
H22b H 1.0204 0.0576 0.4162 0.082 Uiso 1 1 calc R . .
H22c H 1.0366 0.1230 0.3491 0.082 Uiso 1 1 calc R . .
C23 C 0.7008(2) 0.06791(12) 0.54685(13) 0.0451(5) Uani 1 1 d . . .
H23a H 0.6795 0.1019 0.5903 0.068 Uiso 1 1 calc R . .
H23b H 0.7731 0.0414 0.5778 0.068 Uiso 1 1 calc R . .
H23c H 0.6370 0.0321 0.5242 0.068 Uiso 1 1 calc R . .
K1 K 0.98949(6) 0.73285(3) 0.14525(4) 0.02543(19) Uani 0.50 1 d P . .
O1 O 0.8057(2) 0.70837(14) 0.24746(16) 0.0353(5) Uani 0.50 1 d P . .
O2 O 1.0561(2) 0.69606(15) 0.33227(17) 0.0377(6) Uani 0.50 1 d P . .
C24 C 0.8496(3) 0.6780(2) 0.3393(2) 0.0372(8) Uani 0.50 1 d P . .
H24a H 0.7946 0.6398 0.3501 0.049 Uiso 0.50 1 calc PR . .
H24b H 0.8560 0.7177 0.3856 0.049 Uiso 0.50 1 calc PR . .
C25 C 0.9708(4) 0.6435(2) 0.3480(3) 0.0400(9) Uani 0.50 1 d P . .
H25a H 1.0008 0.6222 0.4104 0.053 Uiso 0.50 1 calc PR . .
H25b H 0.9622 0.6024 0.3032 0.053 Uiso 0.50 1 calc PR . .
C26 C 0.6957(3) 0.7500 0.2372(2) 0.0419(6) Uani 1 2 d S . .
H26a H 0.6355 0.7170 0.2492 0.063 Uiso 0.50 1 calc PR . .
H26b H 0.6685 0.7695 0.1745 0.063 Uiso 0.50 1 calc PR . .
H26c H 0.7097 0.7912 0.2811 0.063 Uiso 0.50 1 calc PR . .
C27 C 1.0913(3) 0.7500 0.40406(19) 0.0418(6) Uani 1 2 d S . .
H27a H 1.0269 0.7852 0.4001 0.063 Uiso 0.50 1 calc PR . .
H27b H 1.1608 0.7766 0.3973 0.063 Uiso 0.50 1 calc PR . .
H27c H 1.1102 0.7250 0.4639 0.063 Uiso 0.50 1 calc PR . .
O3 O 1.2261(3) 0.67124(16) 0.1755(2) 0.0372(6) Uani 0.50 1 d PU . .
C28 C 1.2252(9) 0.5911(7) 0.1927(9) 0.052(3) Uani 0.50 1 d PU . .
H28a H 1.2000 0.5815 0.2490 0.069 Uiso 0.50 1 calc PR . .
H28b H 1.3051 0.5703 0.2013 0.069 Uiso 0.50 1 calc PR . .
C29 C 1.1403(4) 0.5556(2) 0.1107(3) 0.0545(12) Uani 0.50 1 d PU . .
H29a H 1.1589 0.5714 0.0535 0.073 Uiso 0.50 1 calc PR . .
H29b H 1.1475 0.5009 0.1153 0.073 Uiso 0.50 1 calc PR . .
O4 O 1.0210(4) 0.57768(18) 0.1081(2) 0.0405(8) Uani 0.50 1 d PU . .
C30 C 0.9344(4) 0.5416(2) 0.0344(3) 0.0472(10) Uani 0.50 1 d PU . .
H30a H 0.9329 0.4878 0.0467 0.063 Uiso 0.50 1 calc PR . .
H30b H 0.9546 0.5487 -0.0244 0.063 Uiso 0.50 1 calc PR . .
C31 C 0.8143(5) 0.5755(3) 0.0284(4) 0.0511(13) Uani 0.50 1 d PU . .
H31a H 0.7527 0.5498 -0.0193 0.068 Uiso 0.50 1 calc PR . .
H31b H 0.7953 0.5702 0.0880 0.068 Uiso 0.50 1 calc PR . .
O5 O 0.8184(3) 0.65226(19) 0.00554(19) 0.0367(6) Uani 0.50 1 d PU . .
C32 C 0.7026(4) 0.6865(3) -0.0144(3) 0.0482(11) Uani 0.50 1 d PU . .
H32a H 0.6713 0.6828 0.0400 0.064 Uiso 0.50 1 calc PR . .
H32b H 0.6476 0.6604 -0.0662 0.064 Uiso 0.50 1 calc PR . .
C33 C 0.7127(4) 0.7683(3) -0.0393(3) 0.0443(18) Uani 0.50 1 d PU . .
H33a H 0.7531 0.7724 -0.0886 0.059 Uiso 0.50 1 calc PR . .
H33b H 0.6333 0.7904 -0.0618 0.059 Uiso 0.50 1 calc PR . .
O6 O 0.7792(2) 0.80700(17) 0.04202(18) 0.0384(6) Uani 0.50 1 d PU . .
C34 C 0.7872(5) 0.8850(4) 0.0245(5) 0.0534(15) Uani 0.50 1 d PU . .
H34a H 0.7080 0.9078 0.0114 0.071 Uiso 0.50 1 calc PR . .
H34b H 0.8173 0.8921 -0.0300 0.071 Uiso 0.50 1 calc PR . .
C35 C 0.8686(4) 0.9223(2) 0.1067(3) 0.0475(10) Uani 0.50 1 d PU . .
H35a H 0.8663 0.9768 0.0980 0.063 Uiso 0.50 1 calc PR . .
H35b H 0.8439 0.9109 0.1628 0.063 Uiso 0.50 1 calc PR . .
O7 O 0.9865(3) 0.89493(18) 0.1162(3) 0.0339(7) Uani 0.50 1 d PU . .
C36 C 1.0735(4) 0.93039(19) 0.1901(3) 0.0392(8) Uani 0.50 1 d PU . .
H36a H 1.0565 0.9202 0.2496 0.052 Uiso 0.50 1 calc PR . .
H36b H 1.0720 0.9847 0.1806 0.052 Uiso 0.50 1 calc PR . .
C37 C 1.1938(8) 0.8994(6) 0.1908(7) 0.0380(16) Uani 0.50 1 d PU . .
H37a H 1.2060 0.9033 0.1287 0.051 Uiso 0.50 1 calc PR . .
H37b H 1.2566 0.9280 0.2341 0.051 Uiso 0.50 1 calc PR . .
O8 O 1.1987(2) 0.82354(15) 0.2185(2) 0.0301(5) Uani 0.50 1 d PU . .
C38 C 1.3086(13) 0.7875(8) 0.2235(10) 0.049(3) Uani 0.50 1 d PU . .
H38a H 1.3714 0.8134 0.2701 0.065 Uiso 0.50 1 calc PR . .
H38b H 1.3263 0.7932 0.1635 0.065 Uiso 0.50 1 calc PR . .
C39 C 1.3137(15) 0.7069(7) 0.2472(9) 0.045(3) Uani 0.50 1 d PU . .
H39a H 1.3927 0.6866 0.2506 0.060 Uiso 0.50 1 calc PR . .
H39b H 1.2970 0.6993 0.3073 0.060 Uiso 0.50 1 calc PR . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Dy1 0.01327(5) 0.01531(5) 0.01353(5) 0.000 0.00433(3) 0.000
N1 0.0171(6) 0.0150(5) 0.0200(6) -0.0012(4) 0.0070(5) -0.0002(4)
N2 0.0169(6) 0.0184(6) 0.0188(6) 0.0029(4) 0.0058(5) -0.0008(4)
N3 0.0174(6) 0.0264(6) 0.0204(6) 0.0023(5) 0.0069(5) 0.0039(5)
N4 0.0199(6) 0.0276(7) 0.0165(6) 0.0031(5) 0.0056(5) 0.0015(5)
C1 0.0182(7) 0.0148(6) 0.0261(7) -0.0014(5) 0.0031(6) -0.0015(5)
C2 0.0261(8) 0.0193(7) 0.0443(10) -0.0032(7) 0.0110(7) 0.0021(6)
C3 0.0313(9) 0.0157(8) 0.0678(13) 0.0020(8) 0.0099(9) 0.0033(7)
C4 0.0298(9) 0.0187(8) 0.0657(13) 0.0166(8) 0.0083(9) -0.0020(7)
C5 0.0221(8) 0.0259(8) 0.0433(9) 0.0130(7) 0.0091(7) -0.0021(6)
C6 0.0159(7) 0.0177(7) 0.0271(7) 0.0034(6) 0.0033(6) -0.0019(5)
C7 0.0153(7) 0.0264(7) 0.0218(7) 0.0051(6) 0.0048(5) -0.0030(6)
C8 0.0142(9) 0.0308(11) 0.0238(10) 0.000 0.0086(8) 0.000
C9 0.0197(7) 0.0245(7) 0.0203(7) -0.0065(6) 0.0071(6) 0.0003(6)
C10 0.0283(11) 0.0319(12) 0.0156(9) 0.000 0.0104(8) 0.000
C11 0.0189(8) 0.0301(9) 0.0640(12) 0.0118(8) 0.0123(8) -0.0042(7)
C12 0.0487(11) 0.0335(9) 0.0270(8) -0.0133(7) 0.0112(8) -0.0001(8)
C13 0.0240(8) 0.0360(9) 0.0282(8) 0.0055(7) 0.0075(6) 0.0127(7)
C14 0.0345(9) 0.0346(9) 0.0307(8) 0.0144(7) 0.0096(7) 0.0154(7)
C15 0.0311(8) 0.0334(9) 0.0197(7) 0.0105(6) 0.0063(6) 0.0044(7)
C16 0.0229(7) 0.0321(8) 0.0130(6) 0.0029(6) 0.0049(6) 0.0019(6)
C17 0.0326(9) 0.0371(9) 0.0240(7) 0.0057(7) 0.0132(7) -0.0018(7)
C18 0.0309(9) 0.0524(11) 0.0284(8) 0.0037(8) 0.0182(7) -0.0042(8)
C19 0.0134(7) 0.0320(8) 0.0216(7) 0.0020(6) 0.0054(5) 0.0029(6)
C20 0.0243(8) 0.0341(9) 0.0315(8) -0.0001(7) 0.0124(7) 0.0065(7)
C21 0.0289(9) 0.0471(10) 0.0315(9) -0.0037(8) 0.0174(7) 0.0048(8)
C22 0.0441(12) 0.0731(15) 0.0540(13) 0.0298(11) 0.0249(10) 0.0392(11)
C23 0.0543(12) 0.0522(12) 0.0337(10) 0.0260(9) 0.0205(9) 0.0204(10)
K1 0.0260(3) 0.0223(6) 0.0255(3) 0.0001(2) 0.0028(2) -0.0004(2)
O1 0.0362(13) 0.0427(14) 0.0289(12) 0.0047(10) 0.0119(10) 0.0005(11)
O2 0.0363(14) 0.0462(15) 0.0295(12) -0.0027(11) 0.0070(11) -0.0105(11)
C24 0.042(2) 0.044(2) 0.0277(17) -0.0011(15) 0.0123(15) -0.0141(17)
C25 0.047(2) 0.036(2) 0.0322(18) 0.0050(15) 0.0025(16) -0.0100(17)
C26 0.0505(17) 0.0357(14) 0.0460(16) 0.000 0.0241(13) 0.000
C27 0.0389(15) 0.0469(16) 0.0344(14) 0.000 0.0010(11) 0.000
O3 0.0387(16) 0.0344(15) 0.0333(15) -0.0011(12) 0.0011(13) 0.0108(12)
C28 0.060(5) 0.023(3) 0.054(4) -0.003(2) -0.015(4) 0.021(3)
C29 0.073(3) 0.031(2) 0.047(2) -0.0076(17) -0.006(2) 0.025(2)
O4 0.063(2) 0.0254(18) 0.0287(15) -0.0056(13) 0.0043(15) -0.0022(15)
C30 0.076(3) 0.0258(18) 0.039(2) -0.0086(15) 0.015(2) -0.0182(18)
C31 0.063(3) 0.052(3) 0.042(3) -0.013(2) 0.021(2) -0.038(3)
O5 0.0306(15) 0.0474(18) 0.0311(13) -0.0033(13) 0.0066(11) -0.0175(13)
C32 0.0232(19) 0.089(4) 0.033(2) -0.015(2) 0.0084(17) -0.016(2)
C33 0.0227(15) 0.081(6) 0.0256(16) 0.005(2) -0.0002(12) 0.010(2)
O6 0.0279(13) 0.0555(16) 0.0297(13) 0.0162(12) 0.0040(11) 0.0040(12)
C34 0.032(2) 0.057(4) 0.072(4) 0.038(3) 0.015(2) 0.022(3)
C35 0.050(2) 0.032(2) 0.070(3) 0.0105(19) 0.034(2) 0.0145(17)
O7 0.0395(18) 0.0255(18) 0.0397(16) 0.0001(14) 0.0159(13) 0.0077(13)
C36 0.065(2) 0.0201(16) 0.0353(19) -0.0025(14) 0.0179(18) -0.0012(16)
C37 0.051(4) 0.033(4) 0.029(3) -0.004(2) 0.008(3) -0.025(3)
O8 0.0297(14) 0.0279(13) 0.0343(15) -0.0023(11) 0.0118(12) -0.0068(10)
C38 0.020(4) 0.059(3) 0.066(8) -0.022(4) 0.009(5) -0.008(2)
C39 0.032(3) 0.043(3) 0.047(5) 0.001(4) -0.013(3) 0.010(3)

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 N4 2.4423(12) 4_565 ?
Dy1 N4 2.4423(12) . ?
Dy1 N1 2.4503(11) . ?
Dy1 N1 2.4503(11) 4_565 ?
Dy1 N2 2.4534(12) . ?
Dy1 N2 2.4534(12) 4_565 ?
Dy1 N3 2.4581(12) 4_565 ?
Dy1 N3 2.4581(12) . ?
N1 C9 1.3182(18) . ?
N1 C1 1.4097(18) . ?
N2 C7 1.3273(18) . ?
N2 C6 1.4041(18) . ?
N3 C13 1.317(2) . ?
N3 C19 1.4107(19) . ?
N4 C15 1.325(2) . ?
N4 C16 1.4079(19) . ?
C1 C2 1.398(2) . ?
C1 C6 1.423(2) . ?
C2 C3 1.379(2) . ?
C3 C4 1.389(3) . ?
C4 C5 1.381(2) . ?
C5 C6 1.402(2) . ?
C7 C8 1.4017(17) . ?
C7 C11 1.514(2) . ?
C8 C7 1.4017(17) 4_565 ?
C9 C10 1.4018(17) . ?
C9 C12 1.521(2) . ?
C10 C9 1.4018(17) 4_565 ?
C13 C14 1.403(2) . ?
C13 C22 1.523(2) . ?
C14 C15 1.402(2) . ?
C15 C23 1.521(2) . ?
C16 C17 1.400(2) . ?
C16 C16 1.432(3) 4_565 ?
C17 C18 1.384(2) . ?
C18 C18 1.383(4) 4_565 ?
C19 C20 1.400(2) . ?
C19 C19 1.415(3) 4_565 ?
C20 C21 1.387(2) . ?
C21 C21 1.382(4) 4_565 ?
K1 K1 0.6062(11) 4_575 ?
K1 O7 2.297(3) 4_575 ?
K1 O8 2.568(3) 4_575 ?
K1 O6 2.594(3) 4_575 ?
K1 O2 2.744(3) . ?
K1 O6 2.819(3) . ?
K1 O5 2.829(3) . ?
K1 O4 2.839(3) . ?
K1 O8 2.859(3) . ?
K1 O3 2.864(3) . ?
K1 O7 2.895(3) . ?
K1 O2 2.947(3) 4_575 ?
O1 C24 1.421(4) . ?
O1 C26 1.442(3) . ?
O1 O1 1.471(5) 4_575 ?
O1 K1 3.102(2) 4_575 ?
O2 C27 1.403(3) . ?
O2 C25 1.419(4) . ?
O2 K1 2.947(3) 4_575 ?
C24 C25 1.501(6) . ?
O3 O8 0.789(3) 4_575 ?
O3 C38 1.257(15) 4_575 ?
O3 C37 1.339(13) 4_575 ?
O3 C39 1.403(14) . ?
O3 C28 1.439(12) . ?
O3 K1 3.145(3) 4_575 ?
C28 C29 1.479(12) . ?
C29 O4 1.423(6) . ?
O4 O7 0.659(3) 4_575 ?
O4 C36 1.210(5) 4_575 ?
O4 C30 1.416(5) . ?
O4 C35 1.757(6) 4_575 ?
O4 K1 3.428(3) 4_575 ?
C30 C31 1.492(8) . ?
C31 O5 1.402(6) . ?
O5 C34 0.835(7) 4_575 ?
O5 O6 1.071(4) 4_575 ?
O5 C32 1.425(6) . ?
O5 C33 1.861(6) 4_575 ?
O5 K1 3.177(3) 4_575 ?
C32 C33 1.504(8) . ?
C33 O6 1.417(5) . ?
O6 C32 1.046(5) 4_575 ?
O6 O5 1.071(4) 4_575 ?
O6 C34 1.411(6) . ?
O6 C33 1.819(5) 4_575 ?
O6 K1 2.594(3) 4_575 ?
C34 C35 1.477(8) . ?
C35 O7 1.416(5) . ?
O7 O4 0.659(3) 4_575 ?
O7 C36 1.417(5) . ?
O7 C30 1.640(5) 4_575 ?
O7 K1 2.297(3) 4_575 ?
C36 C37 1.493(12) . ?
C37 O8 1.398(12) . ?
O8 O3 0.789(3) 4_575 ?
O8 C39 1.390(16) 4_575 ?
O8 C38 1.405(14) . ?
O8 C28 1.605(11) 4_575 ?
O8 K1 2.568(3) 4_575 ?
C38 C39 1.464(8) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N4 Dy1 N4 65.27(6) 4_565 . ?
N4 Dy1 N1 175.76(4) 4_565 . ?
N4 Dy1 N1 111.37(4) . . ?
N4 Dy1 N1 111.37(4) 4_565 4_565 ?
N4 Dy1 N1 175.76(4) . 4_565 ?
N1 Dy1 N1 71.84(5) . 4_565 ?
N4 Dy1 N2 111.22(4) 4_565 . ?
N4 Dy1 N2 74.30(4) . . ?
N1 Dy1 N2 64.85(4) . . ?
N1 Dy1 N2 105.26(4) 4_565 . ?
N4 Dy1 N2 74.30(4) 4_565 4_565 ?
N4 Dy1 N2 111.22(4) . 4_565 ?
N1 Dy1 N2 105.26(4) . 4_565 ?
N1 Dy1 N2 64.85(4) 4_565 4_565 ?
N2 Dy1 N2 71.82(6) . 4_565 ?
N4 Dy1 N3 72.52(4) 4_565 4_565 ?
N4 Dy1 N3 106.02(4) . 4_565 ?
N1 Dy1 N3 111.34(4) . 4_565 ?
N1 Dy1 N3 74.74(4) 4_565 4_565 ?
N2 Dy1 N3 175.68(4) . 4_565 ?
N2 Dy1 N3 111.73(4) 4_565 4_565 ?
N4 Dy1 N3 106.02(4) 4_565 . ?
N4 Dy1 N3 72.52(4) . . ?
N1 Dy1 N3 74.74(4) . . ?
N1 Dy1 N3 111.34(4) 4_565 . ?
N2 Dy1 N3 111.73(4) . . ?
N2 Dy1 N3 175.68(4) 4_565 . ?
N3 Dy1 N3 64.61(6) 4_565 . ?
C9 N1 C1 123.70(12) . . ?
C9 N1 Dy1 135.17(10) . . ?
C1 N1 Dy1 100.97(8) . . ?
C7 N2 C6 123.81(12) . . ?
C7 N2 Dy1 134.63(10) . . ?
C6 N2 Dy1 101.21(8) . . ?
C13 N3 C19 123.72(13) . . ?
C13 N3 Dy1 134.32(10) . . ?
C19 N3 Dy1 101.93(9) . . ?
C15 N4 C16 124.79(13) . . ?
C15 N4 Dy1 133.70(10) . . ?
C16 N4 Dy1 100.77(8) . . ?
C2 C1 N1 125.17(14) . . ?
C2 C1 C6 119.03(14) . . ?
N1 C1 C6 115.39(12) . . ?
C3 C2 C1 121.36(16) . . ?
C2 C3 C4 119.85(16) . . ?
C5 C4 C3 120.02(15) . . ?
C4 C5 C6 121.41(16) . . ?
C5 C6 N2 125.83(14) . . ?
C5 C6 C1 118.30(14) . . ?
N2 C6 C1 115.38(12) . . ?
N2 C7 C8 122.87(14) . . ?
N2 C7 C11 121.84(14) . . ?
C8 C7 C11 115.08(14) . . ?
C7 C8 C7 128.92(19) 4_565 . ?
N1 C9 C10 122.53(14) . . ?
N1 C9 C12 122.07(14) . . ?
C10 C9 C12 115.23(14) . . ?
C9 C10 C9 129.41(19) 4_565 . ?
N3 C13 C14 123.01(14) . . ?
N3 C13 C22 121.45(15) . . ?
C14 C13 C22 115.40(15) . . ?
C15 C14 C13 129.43(15) . . ?
N4 C15 C14 122.75(14) . . ?
N4 C15 C23 122.50(15) . . ?
C14 C15 C23 114.62(14) . . ?
C17 C16 N4 125.76(15) . . ?
C17 C16 C16 118.45(10) . 4_565 ?
N4 C16 C16 115.29(8) . 4_565 ?
C18 C17 C16 121.58(16) . . ?
C18 C18 C17 119.95(11) 4_565 . ?
C20 C19 N3 125.14(15) . . ?
C20 C19 C19 118.97(10) . 4_565 ?
N3 C19 C19 115.43(8) . 4_565 ?
C21 C20 C19 120.93(16) . . ?
C21 C21 C20 120.08(10) 4_565 . ?
K1 K1 O7 169.40(9) 4_575 4_575 ?
K1 K1 O8 112.82(6) 4_575 4_575 ?
O7 K1 O8 70.28(11) 4_575 4_575 ?
K1 K1 O6 105.75(7) 4_575 4_575 ?
O7 K1 O6 70.03(11) 4_575 4_575 ?
O8 K1 O6 140.22(9) 4_575 4_575 ?
K1 K1 O2 103.70(6) 4_575 . ?
O7 K1 O2 86.69(11) 4_575 . ?
O8 K1 O2 60.50(9) 4_575 . ?
O6 K1 O2 119.49(8) 4_575 . ?
K1 K1 O6 62.31(6) 4_575 . ?
O7 K1 O6 112.83(11) 4_575 . ?
O8 K1 O6 169.77(9) 4_575 . ?
O6 K1 O6 43.44(13) 4_575 . ?
O2 K1 O6 128.47(8) . . ?
K1 K1 O5 120.22(7) 4_575 . ?
O7 K1 O5 52.84(11) 4_575 . ?
O8 K1 O5 120.35(9) 4_575 . ?
O6 K1 O5 22.25(8) 4_575 . ?
O2 K1 O5 124.63(8) . . ?
O6 K1 O5 60.53(9) . . ?
K1 K1 O4 164.93(8) 4_575 . ?
O7 K1 O4 8.41(13) 4_575 . ?
O8 K1 O4 63.35(10) 4_575 . ?
O6 K1 O4 76.87(10) 4_575 . ?
O2 K1 O4 87.20(9) . . ?
O6 K1 O4 118.74(10) . . ?
O5 K1 O4 58.22(10) . . ?
K1 K1 O8 55.91(6) 4_575 . ?
O7 K1 O8 126.19(10) 4_575 . ?
O8 K1 O8 56.92(11) 4_575 . ?
O6 K1 O8 159.58(9) 4_575 . ?
O2 K1 O8 76.87(8) . . ?
O6 K1 O8 117.50(8) . . ?
O5 K1 O8 155.72(9) . . ?
O4 K1 O8 118.35(10) . . ?
K1 K1 O3 112.34(6) 4_575 . ?
O7 K1 O3 67.74(10) 4_575 . ?
O8 K1 O3 15.51(7) 4_575 . ?
O6 K1 O3 133.77(9) 4_575 . ?
O2 K1 O3 75.97(9) . . ?
O6 K1 O3 155.22(9) . . ?
O5 K1 O3 111.83(9) . . ?
O4 K1 O3 59.73(10) . . ?
O8 K1 O3 58.65(7) . . ?
K1 K1 O7 8.39(7) 4_575 . ?
O7 K1 O7 161.01(16) 4_575 . ?
O8 K1 O7 114.75(9) 4_575 . ?
O6 K1 O7 102.08(10) 4_575 . ?
O2 K1 O7 111.92(9) . . ?
O6 K1 O7 59.05(9) . . ?
O5 K1 O7 114.29(10) . . ?
O4 K1 O7 157.44(8) . . ?
O8 K1 O7 58.45(9) . . ?
O3 K1 O7 111.83(9) . . ?
K1 K1 O2 64.77(5) 4_575 4_575 ?
O7 K1 O2 125.59(11) 4_575 4_575 ?
O8 K1 O2 78.02(8) 4_575 4_575 ?
O6 K1 O2 129.34(8) 4_575 4_575 ?
O2 K1 O2 38.93(11) . 4_575 ?
O6 K1 O2 106.18(8) . 4_575 ?
O5 K1 O2 148.72(8) . 4_575 ?
O4 K1 O2 125.39(9) . 4_575 ?
O8 K1 O2 54.97(8) . 4_575 ?
O3 K1 O2 91.15(8) . 4_575 ?
O7 K1 O2 73.00(9) . 4_575 ?
C24 O1 C26 111.7(2) . . ?
C24 O1 O1 112.20(19) . 4_575 ?
C26 O1 O1 59.32(12) . 4_575 ?
C24 O1 K1 115.2(2) . . ?
C26 O1 K1 127.44(16) . . ?
O1 O1 K1 81.58(5) 4_575 . ?
C24 O1 K1 118.6(2) . 4_575 ?
C26 O1 K1 118.64(15) . 4_575 ?
O1 O1 K1 70.44(5) 4_575 4_575 ?
K1 O1 K1 11.14(2) . 4_575 ?
C27 O2 C25 113.1(3) . . ?
C27 O2 K1 123.24(17) . . ?
C25 O2 K1 107.7(2) . . ?
C27 O2 K1 111.76(16) . 4_575 ?
C25 O2 K1 114.7(2) . 4_575 ?
K1 O2 K1 11.53(2) . 4_575 ?
O1 C24 C25 108.6(3) . . ?
O2 C25 C24 113.2(3) . . ?
O2 C25 K1 49.26(15) . . ?
C24 C25 K1 90.9(2) . . ?
O8 O3 C38 83.4(7) 4_575 4_575 ?
O8 O3 C37 77.4(5) 4_575 4_575 ?
C38 O3 C37 130.4(8) 4_575 4_575 ?
O8 O3 C39 72.7(7) 4_575 . ?
C38 O3 C39 13.9(11) 4_575 . ?
C37 O3 C39 117.9(7) 4_575 . ?
O8 O3 C28 87.0(6) 4_575 . ?
C38 O3 C28 120.7(8) 4_575 . ?
C37 O3 C28 15.8(6) 4_575 . ?
C39 O3 C28 110.3(7) . . ?
O8 O3 K1 60.5(3) 4_575 . ?
C38 O3 K1 114.5(7) 4_575 . ?
C37 O3 K1 94.7(4) 4_575 . ?
C39 O3 K1 114.2(6) . . ?
C28 O3 K1 110.4(4) . . ?
O8 O3 K1 61.9(3) 4_575 4_575 ?
C38 O3 K1 105.4(7) 4_575 4_575 ?
C37 O3 K1 104.8(4) 4_575 4_575 ?
C39 O3 K1 106.7(6) . 4_575 ?
C28 O3 K1 120.5(4) . 4_575 ?
K1 O3 K1 10.27(2) . 4_575 ?
O3 C28 C29 107.9(7) . . ?
O4 C29 C28 109.1(5) . . ?
O7 O4 C36 93.9(6) 4_575 4_575 ?
O7 O4 C30 97.6(6) 4_575 . ?
C36 O4 C30 141.0(4) 4_575 . ?
O7 O4 C29 145.8(7) 4_575 . ?
C36 O4 C29 73.9(3) 4_575 . ?
C30 O4 C29 112.0(3) . . ?
O7 O4 C35 49.2(5) 4_575 4_575 ?
C36 O4 C35 103.9(4) 4_575 4_575 ?
C30 O4 C35 59.6(3) . 4_575 ?
C29 O4 C35 164.0(3) . 4_575 ?
O7 O4 K1 30.6(5) 4_575 . ?
C36 O4 K1 88.6(2) 4_575 . ?
C30 O4 K1 118.8(3) . . ?
C29 O4 K1 115.7(3) . . ?
C35 O4 K1 79.69(18) 4_575 . ?
O7 O4 K1 32.6(5) 4_575 4_575 ?
C36 O4 K1 90.0(2) 4_575 4_575 ?
C30 O4 K1 118.6(3) . 4_575 ?
C29 O4 K1 114.1(3) . 4_575 ?
C35 O4 K1 81.48(18) 4_575 4_575 ?
K1 O4 K1 2.634(15) . 4_575 ?
O4 C30 C31 108.5(3) . . ?
O5 C31 C30 108.1(4) . . ?
C34 O5 O6 94.6(5) 4_575 4_575 ?
C34 O5 C31 27.1(5) 4_575 . ?
O6 O5 C31 118.8(4) 4_575 . ?
C34 O5 C32 86.4(5) 4_575 . ?
O6 O5 C32 47.0(2) 4_575 . ?
C31 O5 C32 111.7(4) . . ?
C34 O5 C33 114.4(5) 4_575 4_575 ?
O6 O5 C33 49.2(2) 4_575 4_575 ?
C31 O5 C33 138.9(4) . 4_575 ?
C32 O5 C33 28.0(2) . 4_575 ?
C34 O5 K1 115.5(5) 4_575 . ?
O6 O5 K1 66.4(2) 4_575 . ?
C31 O5 K1 111.9(3) . . ?
C32 O5 K1 111.7(3) . . ?
C33 O5 K1 98.20(19) 4_575 . ?
C34 O5 K1 122.3(5) 4_575 4_575 ?
O6 O5 K1 61.1(2) 4_575 4_575 ?
C31 O5 K1 121.1(3) . 4_575 ?
C32 O5 K1 104.3(3) . 4_575 ?
C33 O5 K1 89.03(18) 4_575 4_575 ?
K1 O5 K1 9.49(2) . 4_575 ?
O5 C32 C33 109.1(3) . . ?
O6 C33 C32 108.4(3) . . ?
C32 O6 O5 84.6(4) 4_575 4_575 ?
C32 O6 C34 80.2(4) 4_575 . ?
O5 O6 C34 36.2(3) 4_575 . ?
C32 O6 C33 39.4(3) 4_575 . ?
O5 O6 C33 95.8(3) 4_575 . ?
C34 O6 C33 111.3(4) . . ?
C32 O6 C33 55.8(4) 4_575 4_575 ?
O5 O6 C33 108.5(3) 4_575 4_575 ?
C34 O6 C33 129.0(4) . 4_575 ?
C33 O6 C33 18.1(3) . 4_575 ?
C32 O6 K1 162.9(4) 4_575 4_575 ?
O5 O6 K1 91.3(2) 4_575 4_575 ?
C34 O6 K1 106.0(3) . 4_575 ?
C33 O6 K1 125.2(3) . 4_575 ?
C33 O6 K1 110.62(18) 4_575 4_575 ?
C32 O6 K1 154.6(4) 4_575 . ?
O5 O6 K1 99.5(2) 4_575 . ?
C34 O6 K1 117.7(3) . . ?
C33 O6 K1 115.2(3) . . ?
C33 O6 K1 99.60(18) 4_575 . ?
K1 O6 K1 11.94(2) 4_575 . ?
O6 C34 C35 110.1(4) . . ?
O7 C35 C34 108.0(4) . . ?
O4 O7 C35 110.2(6) 4_575 . ?
O4 O7 C36 58.5(5) 4_575 . ?
C35 O7 C36 112.8(3) . . ?
O4 O7 C30 58.9(5) 4_575 4_575 ?
C35 O7 C30 62.8(3) . 4_575 ?
C36 O7 C30 108.1(3) . 4_575 ?
O4 O7 K1 141.0(6) 4_575 4_575 ?
C35 O7 K1 108.7(2) . 4_575 ?
C36 O7 K1 108.6(2) . 4_575 ?
C30 O7 K1 142.6(3) 4_575 4_575 ?
O4 O7 K1 140.4(6) 4_575 . ?
C35 O7 K1 109.0(2) . . ?
C36 O7 K1 110.2(2) . . ?
C30 O7 K1 140.6(2) 4_575 . ?
K1 O7 K1 2.207(19) 4_575 . ?
O7 C36 C37 107.9(4) . . ?
O8 C37 C36 108.5(5) . . ?
O3 O8 C39 74.5(7) 4_575 4_575 ?
O3 O8 C37 69.2(5) 4_575 . ?
C39 O8 C37 114.9(7) 4_575 . ?
O3 O8 C38 62.7(6) 4_575 . ?
C39 O8 C38 14.5(10) 4_575 . ?
C37 O8 C38 114.5(7) . . ?
O3 O8 C28 63.5(6) 4_575 4_575 ?
C39 O8 C28 102.0(7) 4_575 4_575 ?
C37 O8 C28 12.8(7) . 4_575 ?
C38 O8 C28 102.1(7) . 4_575 ?
O3 O8 K1 104.0(3) 4_575 4_575 ?
C39 O8 K1 133.8(6) 4_575 4_575 ?
C37 O8 K1 106.8(4) . 4_575 ?
C38 O8 K1 125.5(6) . 4_575 ?
C28 O8 K1 118.8(4) 4_575 4_575 ?
O3 O8 K1 104.0(3) 4_575 . ?
C39 O8 K1 122.7(6) 4_575 . ?
C37 O8 K1 117.6(4) . . ?
C38 O8 K1 115.2(6) . . ?
C28 O8 K1 129.2(4) 4_575 . ?
K1 O8 K1 11.27(2) 4_575 . ?
O8 C38 C39 115.5(16) . . ?
O3 C39 C38 106.4(14) . . ?

_diffrn_measured_fraction_theta_max 0.990
_diffrn_reflns_theta_full        27.64
_diffrn_measured_fraction_theta_full 0.990
_refine_diff_density_max         0.467
_refine_diff_density_min         -0.286
_refine_diff_density_rms         0.053

# Attachment '- 452.cif'

data_UP452
_database_code_depnum_ccdc_archive 'CCDC 868276'
#TrackingRef '- 452.cif'

_audit_creation_method           SHELXL-97

_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C52 H64 Dy K N8 O4'
_chemical_formula_weight         1066.71

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 2/c '
_symmetry_Int_Tables_number      13

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'

_cell_length_a                   23.030(4)
_cell_length_b                   11.422(2)
_cell_length_c                   44.360(9)
_cell_angle_alpha                90.00
_cell_angle_beta                 91.414(6)
_cell_angle_gamma                90.00
_cell_volume                     11665(4)
_cell_formula_units_Z            8
_cell_measurement_temperature    143(1)
_exptl_crystal_size_max          0.38
_exptl_crystal_size_mid          0.38
_exptl_crystal_size_min          0.18

_exptl_crystal_density_diffrn    1.215
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             4392
_exptl_absorpt_coefficient_mu    1.397
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 2007)'
_exptl_absorpt_correction_T_min  0.6552
_exptl_absorpt_correction_T_max  0.7456
_diffrn_ambient_temperature      143(1)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device       'CCD Area Detector'
_diffrn_measurement_device_type  'Bruker APEXII'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_reflns_number            95368
_diffrn_reflns_av_R_equivalents  0.0284
_diffrn_reflns_av_sigmaI/netI    0.0274
_diffrn_reflns_limit_h_min       -30
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -57
_diffrn_reflns_limit_l_max       57
_diffrn_reflns_theta_min         1.77
_diffrn_reflns_theta_max         27.64
_refine_special_details          
;
The data were corrected for the presence of disordered solvent using the
program SQUEEZE.
;
_reflns_number_total             26911
_reflns_number_gt                22813
_reflns_threshold_expression     >2sigma(I)
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0001P)^2^+114.8309P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_number_reflns         26911
_refine_ls_number_parameters     1214
_refine_ls_number_restraints     18
_refine_ls_R_factor_all          0.0746
_refine_ls_R_factor_gt           0.0662
_refine_ls_wR_factor_ref         0.1404
_refine_ls_wR_factor_gt          0.1378
_refine_ls_goodness_of_fit_ref   1.207
_refine_ls_restrained_S_all      1.209
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.805603(11) 0.58732(2) 0.627722(6) 0.01680(6) Uani 1 1 d . . .
N1 N 0.87088(18) 0.6087(4) 0.67345(11) 0.0184(9) Uani 1 1 d . . .
N2 N 0.8894(2) 0.4507(4) 0.63097(11) 0.0190(9) Uani 1 1 d . . .
N3 N 0.8706(2) 0.6261(4) 0.58504(11) 0.0226(10) Uani 1 1 d . . .
N4 N 0.8507(2) 0.7825(4) 0.62692(12) 0.0213(10) Uani 1 1 d U . .
N5 N 0.7453(2) 0.5531(4) 0.58247(11) 0.0222(10) Uani 1 1 d . . .
N6 N 0.7636(2) 0.3929(4) 0.62448(11) 0.0217(10) Uani 1 1 d . . .
N7 N 0.74332(19) 0.5667(4) 0.67117(11) 0.0190(9) Uani 1 1 d . . .
N8 N 0.72419(19) 0.7251(4) 0.62880(11) 0.0206(10) Uani 1 1 d . . .
C1 C 0.8730(2) 0.4917(5) 0.68358(12) 0.0186(11) Uani 1 1 d . . .
C2 C 0.8596(2) 0.4535(6) 0.71248(14) 0.0265(13) Uani 1 1 d . . .
H2 H 0.8519 0.5082 0.7274 0.035 Uiso 1 1 calc R . .
C3 C 0.8577(3) 0.3341(6) 0.71933(15) 0.0305(14) Uani 1 1 d . . .
H3 H 0.8503 0.3100 0.7389 0.041 Uiso 1 1 calc R . .
C4 C 0.8669(3) 0.2508(6) 0.69686(15) 0.0324(14) Uani 1 1 d . . .
H4 H 0.8655 0.1714 0.7014 0.043 Uiso 1 1 calc R . .
C5 C 0.8782(3) 0.2873(5) 0.66785(15) 0.0277(13) Uani 1 1 d . . .
H5 H 0.8831 0.2314 0.6529 0.037 Uiso 1 1 calc R . .
C6 C 0.8823(2) 0.4065(5) 0.66033(13) 0.0202(11) Uani 1 1 d . . .
C7 C 0.9246(2) 0.4057(5) 0.61066(14) 0.0243(12) Uani 1 1 d . . .
C8 C 0.9321(3) 0.4579(6) 0.58215(14) 0.0277(13) Uani 1 1 d . . .
H8 H 0.9565 0.4174 0.5694 0.037 Uiso 1 1 calc R . .
C9 C 0.9084(3) 0.5615(5) 0.57009(14) 0.0262(12) Uani 1 1 d . . .
C10 C 0.8475(3) 0.7319(6) 0.57433(15) 0.0282(13) Uani 1 1 d . . .
C11 C 0.8280(3) 0.7565(7) 0.54465(17) 0.0399(17) Uani 1 1 d . . .
H11 H 0.8338 0.7012 0.5296 0.053 Uiso 1 1 calc R . .
C12 C 0.8011(4) 0.8590(7) 0.5373(2) 0.054(2) Uani 1 1 d . . .
H12 H 0.7904 0.8744 0.5174 0.071 Uiso 1 1 calc R . .
C13 C 0.7897(3) 0.9395(7) 0.5592(2) 0.055(2) Uani 1 1 d . . .
H13 H 0.7707 1.0087 0.5539 0.073 Uiso 1 1 calc R . .
C14 C 0.8059(3) 0.9200(6) 0.5897(2) 0.0418(18) Uani 1 1 d . . .
H14 H 0.7968 0.9743 0.6044 0.056 Uiso 1 1 calc R . .
C15 C 0.8356(3) 0.8183(5) 0.59711(15) 0.0266(13) Uani 1 1 d . . .
C16 C 0.8711(2) 0.8535(5) 0.64840(16) 0.0261(13) Uani 1 1 d . . .
C17 C 0.8884(2) 0.8143(5) 0.67755(15) 0.0268(13) Uani 1 1 d . . .
H17 H 0.9009 0.8724 0.6909 0.036 Uiso 1 1 calc R . .
C18 C 0.8892(3) 0.6997(5) 0.68915(13) 0.0230(12) Uani 1 1 d . . .
C19 C 0.9626(3) 0.3002(6) 0.61690(17) 0.0352(15) Uani 1 1 d . . .
H19a H 0.9704 0.2940 0.6382 0.053 Uiso 1 1 calc R . .
H19b H 0.9985 0.3088 0.6066 0.053 Uiso 1 1 calc R . .
H19c H 0.9430 0.2308 0.6099 0.053 Uiso 1 1 calc R . .
C20 C 0.9325(4) 0.5976(7) 0.53969(16) 0.0439(18) Uani 1 1 d . . .
H20a H 0.9064 0.5727 0.5238 0.066 Uiso 1 1 calc R . .
H20b H 0.9698 0.5617 0.5372 0.066 Uiso 1 1 calc R . .
H20c H 0.9366 0.6812 0.5390 0.066 Uiso 1 1 calc R . .
C21 C 0.8816(3) 0.9824(6) 0.64311(18) 0.0365(16) Uani 1 1 d . . .
H21a H 0.8925 0.9945 0.6226 0.055 Uiso 1 1 calc R . .
H21b H 0.9122 1.0093 0.6565 0.055 Uiso 1 1 calc R . .
H21c H 0.8467 1.0253 0.6469 0.055 Uiso 1 1 calc R . .
C22 C 0.9170(3) 0.6887(6) 0.72072(15) 0.0330(14) Uani 1 1 d . . .
H22a H 0.8872 0.6784 0.7352 0.050 Uiso 1 1 calc R . .
H22b H 0.9387 0.7585 0.7254 0.050 Uiso 1 1 calc R . .
H22c H 0.9426 0.6224 0.7213 0.050 Uiso 1 1 calc R . .
C23 C 0.7683(3) 0.4463(5) 0.57209(14) 0.0236(12) Uani 1 1 d . . .
C24 C 0.7886(3) 0.4249(6) 0.54293(15) 0.0314(14) Uani 1 1 d . . .
H24 H 0.7830 0.4814 0.5280 0.042 Uiso 1 1 calc R . .
C25 C 0.8165(3) 0.3220(6) 0.53590(16) 0.0378(16) Uani 1 1 d . . .
H25 H 0.8288 0.3088 0.5164 0.050 Uiso 1 1 calc R . .
C26 C 0.8262(3) 0.2376(6) 0.55833(18) 0.0374(16) Uani 1 1 d . . .
H26 H 0.8455 0.1686 0.5538 0.050 Uiso 1 1 calc R . .
C27 C 0.8073(3) 0.2563(5) 0.58719(16) 0.0288(13) Uani 1 1 d . . .
H27 H 0.8140 0.1993 0.6018 0.038 Uiso 1 1 calc R . .
C28 C 0.7781(2) 0.3594(5) 0.59490(14) 0.0223(12) Uani 1 1 d . . .
C29 C 0.7376(2) 0.3240(5) 0.64393(15) 0.0237(12) Uani 1 1 d . . .
C30 C 0.7217(2) 0.3608(5) 0.67269(14) 0.0228(12) Uani 1 1 d U . .
H30 H 0.7096 0.3017 0.6855 0.030 Uiso 1 1 calc R . .
C31 C 0.7216(2) 0.4748(6) 0.68496(13) 0.0231(12) Uani 1 1 d . . .
C32 C 0.7388(2) 0.6810(5) 0.68106(14) 0.0245(12) Uani 1 1 d . . .
C33 C 0.7498(3) 0.7196(6) 0.71141(15) 0.0289(13) Uani 1 1 d . . .
H33 H 0.7576 0.6646 0.7264 0.038 Uiso 1 1 calc R . .
C34 C 0.7490(3) 0.8384(7) 0.71890(17) 0.0395(17) Uani 1 1 d . . .
H34 H 0.7545 0.8620 0.7388 0.053 Uiso 1 1 calc R . .
C35 C 0.7400(3) 0.9205(6) 0.69634(19) 0.0387(17) Uani 1 1 d . . .
H35 H 0.7404 0.9998 0.7011 0.052 Uiso 1 1 calc R . .
C36 C 0.7304(3) 0.8861(6) 0.66680(17) 0.0331(15) Uani 1 1 d . . .
H36 H 0.7249 0.9426 0.6519 0.044 Uiso 1 1 calc R . .
C37 C 0.7287(2) 0.7679(5) 0.65889(15) 0.0236(12) Uani 1 1 d . . .
C38 C 0.6860(3) 0.7629(5) 0.60840(16) 0.0274(13) Uani 1 1 d . . .
C39 C 0.6794(3) 0.7155(6) 0.57955(16) 0.0317(14) Uani 1 1 d . . .
H39 H 0.6546 0.7564 0.5664 0.042 Uiso 1 1 calc R . .
C40 C 0.7051(2) 0.6139(6) 0.56744(14) 0.0268(13) Uani 1 1 d . . .
C41 C 0.7207(3) 0.1975(5) 0.63607(17) 0.0330(15) Uani 1 1 d . . .
H41a H 0.7146 0.1904 0.6147 0.050 Uiso 1 1 calc R . .
H41b H 0.6856 0.1773 0.6461 0.050 Uiso 1 1 calc R . .
H41c H 0.7513 0.1455 0.6426 0.050 Uiso 1 1 calc R . .
C42 C 0.6898(3) 0.4868(6) 0.71447(14) 0.0326(14) Uani 1 1 d . . .
H42a H 0.7165 0.4729 0.7311 0.049 Uiso 1 1 calc R . .
H42b H 0.6588 0.4308 0.7150 0.049 Uiso 1 1 calc R . .
H42c H 0.6742 0.5645 0.7160 0.049 Uiso 1 1 calc R . .
C43 C 0.6435(3) 0.8612(6) 0.61533(18) 0.0374(16) Uani 1 1 d . . .
H43a H 0.6348 0.8596 0.6364 0.056 Uiso 1 1 calc R . .
H43b H 0.6084 0.8506 0.6035 0.056 Uiso 1 1 calc R . .
H43c H 0.6607 0.9352 0.6104 0.056 Uiso 1 1 calc R . .
C44 C 0.6810(3) 0.5770(7) 0.53668(16) 0.0386(16) Uani 1 1 d . . .
H44a H 0.7046 0.6096 0.5212 0.058 Uiso 1 1 calc R . .
H44b H 0.6419 0.6050 0.5341 0.058 Uiso 1 1 calc R . .
H44c H 0.6814 0.4932 0.5352 0.058 Uiso 1 1 calc R . .
C45 C 1.0469(4) 0.9214(7) 0.6527(2) 0.051(2) Uani 1 1 d . . .
H45a H 1.0802 0.9645 0.6607 0.068 Uiso 1 1 calc R . .
H45b H 1.0125 0.9505 0.6625 0.068 Uiso 1 1 calc R . .
C46 C 1.0410(4) 0.9406(8) 0.6194(2) 0.059(3) Uani 1 1 d . . .
H46a H 1.0355 1.0234 0.6154 0.079 Uiso 1 1 calc R . .
H46b H 1.0763 0.9159 0.6098 0.079 Uiso 1 1 calc R . .
C47 C 1.0628(4) 0.7824(8) 0.6903(2) 0.054(2) Uani 1 1 d . . .
H47a H 1.1019 0.8034 0.6960 0.081 Uiso 1 1 calc R . .
H47b H 1.0566 0.7011 0.6945 0.081 Uiso 1 1 calc R . .
H47c H 1.0361 0.8290 0.7014 0.081 Uiso 1 1 calc R . .
C48 C 0.9788(4) 0.9084(8) 0.5788(2) 0.061(3) Uani 1 1 d . . .
H48a H 0.9785 0.9923 0.5773 0.091 Uiso 1 1 calc R . .
H48b H 0.9408 0.8787 0.5736 0.091 Uiso 1 1 calc R . .
H48c H 1.0065 0.8770 0.5652 0.091 Uiso 1 1 calc R . .
K1 K 0.96880(5) 0.65604(11) 0.63245(3) 0.0256(3) Uani 1 1 d . . .
O1 O 1.0538(2) 0.8028(5) 0.65903(14) 0.0491(14) Uani 1 1 d . . .
O2 O 0.9933(2) 0.8769(5) 0.60703(14) 0.0462(13) Uani 1 1 d . . .
C49 C 1.0893(3) 0.4478(8) 0.6525(2) 0.051(2) Uani 1 1 d . . .
H49a H 1.0781 0.3774 0.6416 0.068 Uiso 1 1 calc R . .
H49b H 1.1210 0.4281 0.6664 0.068 Uiso 1 1 calc R . .
C50 C 1.1090(3) 0.5371(7) 0.63092(19) 0.0437(19) Uani 1 1 d . . .
H50a H 1.1178 0.6091 0.6417 0.058 Uiso 1 1 calc R . .
H50b H 1.1443 0.5103 0.6216 0.058 Uiso 1 1 calc R . .
O3 O 1.0408(2) 0.4893(5) 0.66919(14) 0.0484(14) Uani 1 1 d . . .
O4 O 1.0659(2) 0.5594(6) 0.60809(13) 0.0531(15) Uani 1 1 d U . .
C51 C 1.0277(4) 0.4166(9) 0.6939(2) 0.058(2) Uani 1 1 d . . .
H51a H 1.0197 0.3387 0.6868 0.087 Uiso 1 1 calc R . .
H51b H 0.9942 0.4467 0.7038 0.087 Uiso 1 1 calc R . .
H51c H 1.0602 0.4150 0.7079 0.087 Uiso 1 1 calc R . .
C52 C 1.0873(4) 0.6342(11) 0.5865(3) 0.079(3) Uani 1 1 d . . .
H52a H 1.0944 0.7097 0.5954 0.118 Uiso 1 1 calc R . .
H52b H 1.0593 0.6416 0.5702 0.118 Uiso 1 1 calc R . .
H52c H 1.1229 0.6031 0.5790 0.118 Uiso 1 1 calc R . .
Dy1' Dy 0.693485(11) 0.55265(2) 0.372729(6) 0.01641(6) Uani 1 1 d . . .
N1' N 0.62833(19) 0.5727(4) 0.32750(10) 0.0166(9) Uani 1 1 d . . .
N2' N 0.60964(19) 0.4175(4) 0.36996(11) 0.0176(9) Uani 1 1 d . . .
N3' N 0.6282(2) 0.5941(4) 0.41519(11) 0.0202(9) Uani 1 1 d . . .
N4' N 0.6486(2) 0.7487(4) 0.37275(11) 0.0216(10) Uani 1 1 d . . .
N5' N 0.7539(2) 0.5201(4) 0.41816(11) 0.0212(10) Uani 1 1 d . . .
N6' N 0.7351(2) 0.3578(4) 0.37695(11) 0.0205(10) Uani 1 1 d . . .
N7' N 0.75562(18) 0.5279(4) 0.32950(11) 0.0190(9) Uani 1 1 d . . .
N8' N 0.7748(2) 0.6894(4) 0.37086(12) 0.0233(10) Uani 1 1 d . . .
C1' C 0.6265(2) 0.4548(5) 0.31770(13) 0.0201(11) Uani 1 1 d . . .
C2' C 0.6396(3) 0.4155(5) 0.28857(13) 0.0227(12) Uani 1 1 d . . .
H2' H 0.6469 0.4700 0.2736 0.030 Uiso 1 1 calc R . .
C3' C 0.6418(3) 0.2976(6) 0.28186(15) 0.0324(14) Uani 1 1 d . . .
H3' H 0.6500 0.2730 0.2624 0.043 Uiso 1 1 calc R . .
C4' C 0.6316(3) 0.2161(5) 0.30430(16) 0.0318(14) Uani 1 1 d . . .
H4' H 0.6322 0.1366 0.2998 0.042 Uiso 1 1 calc R . .
C5' C 0.6206(3) 0.2529(5) 0.33341(15) 0.0262(12) Uani 1 1 d . . .
H5' H 0.6162 0.1973 0.3485 0.035 Uiso 1 1 calc R . .
C6' C 0.6162(2) 0.3702(5) 0.34053(13) 0.0190(11) Uani 1 1 d . . .
C7' C 0.5742(2) 0.3738(5) 0.39030(13) 0.0203(11) Uani 1 1 d . . .
C8' C 0.5664(2) 0.4266(5) 0.41880(14) 0.0243(12) Uani 1 1 d . . .
H8' H 0.5422 0.3862 0.4317 0.032 Uiso 1 1 calc R . .
C9' C 0.5898(2) 0.5309(5) 0.43036(13) 0.0237(12) Uani 1 1 d . . .
C10' C 0.6531(2) 0.6998(5) 0.42552(15) 0.0250(12) Uani 1 1 d . . .
C11' C 0.6724(3) 0.7205(6) 0.45510(15) 0.0333(15) Uani 1 1 d . . .
H11' H 0.6661 0.6644 0.4699 0.044 Uiso 1 1 calc R . .
C12' C 0.7010(3) 0.8241(7) 0.46281(18) 0.0419(18) Uani 1 1 d . . .
H12' H 0.7124 0.8387 0.4827 0.056 Uiso 1 1 calc R . .
C13' C 0.7124(3) 0.9050(7) 0.44048(19) 0.0420(18) Uani 1 1 d . . .
H13' H 0.7322 0.9736 0.4454 0.056 Uiso 1 1 calc R . .
C14' C 0.6950(3) 0.8849(5) 0.41120(17) 0.0297(14) Uani 1 1 d . . .
H14' H 0.7038 0.9400 0.3966 0.040 Uiso 1 1 calc R . .
C15' C 0.6641(2) 0.7836(5) 0.40257(14) 0.0231(12) Uani 1 1 d . . .
C16' C 0.6275(2) 0.8192(5) 0.35151(15) 0.0229(12) Uani 1 1 d . . .
C17' C 0.6101(2) 0.7782(5) 0.32267(14) 0.0220(12) Uani 1 1 d . . .
H17' H 0.5971 0.8357 0.3093 0.029 Uiso 1 1 calc R . .
C18' C 0.6095(2) 0.6631(5) 0.31112(13) 0.0199(11) Uani 1 1 d . . .
C19' C 0.5360(3) 0.2666(6) 0.38418(16) 0.0313(14) Uani 1 1 d . . .
H19a' H 0.5008 0.2737 0.3951 0.047 Uiso 1 1 calc R . .
H19b' H 0.5564 0.1973 0.3906 0.047 Uiso 1 1 calc R . .
H19c' H 0.5269 0.2616 0.3630 0.047 Uiso 1 1 calc R . .
C20' C 0.5667(3) 0.5672(7) 0.46090(16) 0.0377(16) Uani 1 1 d . . .
H20a' H 0.5922 0.5385 0.4767 0.057 Uiso 1 1 calc R . .
H20b' H 0.5286 0.5348 0.4633 0.057 Uiso 1 1 calc R . .
H20c' H 0.5647 0.6510 0.4620 0.057 Uiso 1 1 calc R . .
C21' C 0.6185(3) 0.9485(5) 0.35684(17) 0.0326(15) Uani 1 1 d . . .
H21a' H 0.6108 0.9617 0.3777 0.049 Uiso 1 1 calc R . .
H21b' H 0.5861 0.9755 0.3447 0.049 Uiso 1 1 calc R . .
H21c' H 0.6528 0.9906 0.3515 0.049 Uiso 1 1 calc R . .
C22' C 0.5833(3) 0.6517(6) 0.27925(15) 0.0341(15) Uani 1 1 d . . .
H22a' H 0.6138 0.6526 0.2649 0.051 Uiso 1 1 calc R . .
H22b' H 0.5573 0.7159 0.2753 0.051 Uiso 1 1 calc R . .
H22c' H 0.5622 0.5793 0.2775 0.051 Uiso 1 1 calc R . .
C23' C 0.7305(3) 0.4139(6) 0.42903(14) 0.0268(13) Uani 1 1 d . . .
C24' C 0.7101(3) 0.3950(6) 0.45830(15) 0.0336(15) Uani 1 1 d . . .
H24' H 0.7158 0.4525 0.4729 0.045 Uiso 1 1 calc R . .
C25' C 0.6818(3) 0.2924(7) 0.46572(18) 0.0434(19) Uani 1 1 d . . .
H25' H 0.6693 0.2804 0.4853 0.058 Uiso 1 1 calc R . .
C26' C 0.6724(3) 0.2088(7) 0.44401(18) 0.0405(18) Uani 1 1 d . . .
H26' H 0.6534 0.1399 0.4490 0.054 Uiso 1 1 calc R . .
C27' C 0.6908(3) 0.2252(6) 0.41473(16) 0.0306(14) Uani 1 1 d . . .
H27' H 0.6831 0.1679 0.4003 0.041 Uiso 1 1 calc R . .
C28' C 0.7206(2) 0.3261(5) 0.40669(14) 0.0235(12) Uani 1 1 d . . .
C29' C 0.7610(2) 0.2871(5) 0.35770(14) 0.0241(12) Uani 1 1 d . . .
C30' C 0.7763(2) 0.3229(6) 0.32844(14) 0.0246(12) Uani 1 1 d . . .
H30' H 0.7871 0.2629 0.3156 0.033 Uiso 1 1 calc R . .
C31' C 0.7775(2) 0.4353(5) 0.31605(13) 0.0220(11) Uani 1 1 d . . .
C32' C 0.7595(2) 0.6436(5) 0.31787(14) 0.0240(12) Uani 1 1 d . . .
C33' C 0.7494(3) 0.6784(6) 0.28865(15) 0.0308(14) Uani 1 1 d . . .
H33' H 0.7423 0.6222 0.2739 0.041 Uiso 1 1 calc R . .
C34' C 0.7498(3) 0.7971(6) 0.28060(17) 0.0367(16) Uani 1 1 d . . .
H34' H 0.7436 0.8189 0.2606 0.049 Uiso 1 1 calc R . .
C35' C 0.7591(3) 0.8812(7) 0.30231(19) 0.0417(18) Uani 1 1 d . . .
H35' H 0.7593 0.9599 0.2969 0.055 Uiso 1 1 calc R . .
C36' C 0.7684(3) 0.8493(5) 0.33238(17) 0.0335(15) Uani 1 1 d . . .
H36' H 0.7736 0.9072 0.3469 0.045 Uiso 1 1 calc R . .
C37' C 0.7699(2) 0.7302(5) 0.34108(14) 0.0236(12) Uani 1 1 d . . .
C38' C 0.8134(3) 0.7288(5) 0.39112(16) 0.0283(13) Uani 1 1 d . . .
C39' C 0.8196(2) 0.6801(6) 0.42039(15) 0.0302(14) Uani 1 1 d . . .
H39' H 0.8445 0.7205 0.4335 0.040 Uiso 1 1 calc R . .
C40' C 0.7937(3) 0.5801(6) 0.43257(14) 0.0284(13) Uani 1 1 d . . .
C41' C 0.7792(3) 0.1640(6) 0.36661(18) 0.0357(16) Uani 1 1 d . . .
H41a' H 0.7853 0.1603 0.3881 0.054 Uiso 1 1 calc R . .
H41b' H 0.8145 0.1442 0.3568 0.054 Uiso 1 1 calc R . .
H41c' H 0.7492 0.1098 0.3606 0.054 Uiso 1 1 calc R . .
C42' C 0.8099(3) 0.4429(7) 0.28611(15) 0.0351(15) Uani 1 1 d . . .
H42a' H 0.7823 0.4485 0.2696 0.053 Uiso 1 1 calc R . .
H42b' H 0.8333 0.3741 0.2837 0.053 Uiso 1 1 calc R . .
H42c' H 0.8344 0.5109 0.2864 0.053 Uiso 1 1 calc R . .
C43' C 0.8561(3) 0.8263(7) 0.38382(19) 0.0413(17) Uani 1 1 d . . .
H43a' H 0.8697 0.8158 0.3637 0.062 Uiso 1 1 calc R . .
H43b' H 0.8885 0.8237 0.3979 0.062 Uiso 1 1 calc R . .
H43c' H 0.8370 0.9007 0.3853 0.062 Uiso 1 1 calc R . .
C44' C 0.8184(3) 0.5433(8) 0.46363(16) 0.0445(18) Uani 1 1 d . . .
H44a' H 0.7932 0.5704 0.4791 0.067 Uiso 1 1 calc R . .
H44b' H 0.8563 0.5769 0.4667 0.067 Uiso 1 1 calc R . .
H44c' H 0.8212 0.4595 0.4645 0.067 Uiso 1 1 calc R . .
C45' C 0.4539(3) 0.8899(7) 0.3485(2) 0.052(2) Uani 1 1 d . . .
H45a' H 0.4214 0.9342 0.3401 0.070 Uiso 1 1 calc R . .
H45b' H 0.4890 0.9177 0.3392 0.070 Uiso 1 1 calc R . .
C46' C 0.4582(3) 0.9083(7) 0.3812(2) 0.054(2) Uani 1 1 d . . .
H46a' H 0.4632 0.9911 0.3855 0.071 Uiso 1 1 calc R . .
H46b' H 0.4227 0.8824 0.3904 0.071 Uiso 1 1 calc R . .
C47' C 0.4375(4) 0.7465(8) 0.3105(2) 0.058(2) Uani 1 1 d . . .
H47a' H 0.4009 0.7789 0.3038 0.086 Uiso 1 1 calc R . .
H47b' H 0.4376 0.6637 0.3068 0.086 Uiso 1 1 calc R . .
H47c' H 0.4683 0.7826 0.2996 0.086 Uiso 1 1 calc R . .
C48' C 0.5173(4) 0.8765(10) 0.4247(2) 0.066(3) Uani 1 1 d . . .
H48a' H 0.5302 0.9563 0.4257 0.099 Uiso 1 1 calc R . .
H48b' H 0.5468 0.8262 0.4332 0.099 Uiso 1 1 calc R . .
H48c' H 0.4823 0.8680 0.4358 0.099 Uiso 1 1 calc R . .
K1' K 0.53113(5) 0.62306(11) 0.36766(3) 0.0244(3) Uani 1 1 d . . .
O1' O 0.4459(2) 0.7679(4) 0.34192(14) 0.0439(13) Uani 1 1 d . . .
O2' O 0.5061(2) 0.8447(4) 0.39355(13) 0.0421(12) Uani 1 1 d . . .
C49' C 0.4121(3) 0.4062(6) 0.34527(19) 0.0400(17) Uani 1 1 d . . .
H49a' H 0.4241 0.3373 0.3565 0.053 Uiso 1 1 calc R . .
H49b' H 0.3812 0.3833 0.3312 0.053 Uiso 1 1 calc R . .
C50' C 0.3900(3) 0.4938(7) 0.36609(19) 0.0451(19) Uani 1 1 d . . .
H50a' H 0.3803 0.5650 0.3551 0.060 Uiso 1 1 calc R . .
H50b' H 0.3550 0.4648 0.3752 0.060 Uiso 1 1 calc R . .
O3' O 0.4597(2) 0.4490(5) 0.32890(14) 0.0464(13) Uani 1 1 d . . .
O4' O 0.4313(2) 0.5177(4) 0.38818(13) 0.0447(13) Uani 1 1 d . . .
C51' C 0.4138(4) 0.5948(9) 0.4116(2) 0.062(3) Uani 1 1 d . . .
H51a' H 0.4035 0.6695 0.4031 0.093 Uiso 1 1 calc R . .
H51b' H 0.4453 0.6046 0.4260 0.093 Uiso 1 1 calc R . .
H51c' H 0.3809 0.5623 0.4215 0.093 Uiso 1 1 calc R . .
C52' C 0.4736(3) 0.3746(8) 0.3048(2) 0.055(2) Uani 1 1 d . . .
H52a' H 0.4781 0.2959 0.3121 0.082 Uiso 1 1 calc R . .
H52b' H 0.5092 0.4001 0.2961 0.082 Uiso 1 1 calc R . .
H52c' H 0.4429 0.3771 0.2897 0.082 Uiso 1 1 calc R . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Dy1 0.01385(11) 0.01294(12) 0.02358(13) 0.00143(10) -0.00001(9) -0.00027(9)
N1 0.009(2) 0.018(2) 0.028(2) -0.0009(19) 0.0013(17) -0.0011(16)
N2 0.021(2) 0.008(2) 0.028(2) -0.0025(17) 0.0029(19) 0.0025(17)
N3 0.023(2) 0.017(2) 0.028(3) 0.0022(19) -0.0011(19) -0.0023(19)
N4 0.018(2) 0.011(2) 0.035(2) 0.0028(18) 0.0010(18) -0.0009(16)
N5 0.023(2) 0.015(2) 0.028(3) 0.0023(19) -0.0011(19) -0.0017(18)
N6 0.017(2) 0.020(2) 0.028(3) 0.0028(19) -0.0013(19) 0.0042(18)
N7 0.016(2) 0.017(2) 0.024(2) 0.0015(18) 0.0002(18) -0.0004(17)
N8 0.013(2) 0.017(2) 0.032(3) 0.0032(19) 0.0001(18) 0.0029(17)
C1 0.014(2) 0.020(3) 0.022(3) 0.001(2) -0.005(2) -0.002(2)
C2 0.019(3) 0.035(4) 0.025(3) 0.001(2) -0.001(2) 0.003(2)
C3 0.035(3) 0.028(3) 0.029(3) 0.013(3) -0.002(3) 0.001(3)
C4 0.035(4) 0.024(3) 0.037(4) 0.013(3) -0.004(3) 0.004(3)
C5 0.029(3) 0.017(3) 0.037(3) 0.005(2) 0.002(3) 0.005(2)
C6 0.012(2) 0.022(3) 0.027(3) -0.002(2) 0.001(2) 0.003(2)
C7 0.019(3) 0.023(3) 0.030(3) -0.009(2) -0.001(2) 0.003(2)
C8 0.023(3) 0.032(3) 0.028(3) -0.008(3) 0.005(2) 0.002(2)
C9 0.027(3) 0.026(3) 0.026(3) -0.004(2) 0.003(2) -0.006(2)
C10 0.027(3) 0.026(3) 0.032(3) 0.007(3) -0.004(2) -0.009(2)
C11 0.045(4) 0.036(4) 0.039(4) 0.018(3) -0.012(3) -0.016(3)
C12 0.054(5) 0.045(5) 0.061(5) 0.033(4) -0.029(4) -0.022(4)
C13 0.041(4) 0.033(4) 0.088(7) 0.029(4) -0.031(4) -0.012(3)
C14 0.031(4) 0.024(4) 0.070(5) 0.014(3) -0.010(3) -0.006(3)
C15 0.020(3) 0.014(3) 0.046(4) 0.007(2) -0.001(3) -0.009(2)
C16 0.014(3) 0.016(3) 0.049(4) -0.002(3) 0.009(2) 0.003(2)
C17 0.018(3) 0.023(3) 0.040(4) -0.013(3) 0.004(2) -0.001(2)
C18 0.023(3) 0.021(3) 0.026(3) -0.004(2) 0.005(2) 0.001(2)
C19 0.029(3) 0.029(4) 0.048(4) -0.010(3) 0.004(3) 0.010(3)
C20 0.048(4) 0.053(5) 0.030(4) 0.002(3) 0.010(3) -0.008(4)
C21 0.026(3) 0.021(3) 0.062(5) -0.006(3) -0.002(3) 0.001(3)
C22 0.033(3) 0.037(4) 0.029(3) -0.006(3) -0.002(3) -0.009(3)
C23 0.022(3) 0.019(3) 0.030(3) -0.001(2) 0.000(2) -0.005(2)
C24 0.036(4) 0.026(3) 0.031(3) -0.002(3) 0.000(3) -0.007(3)
C25 0.047(4) 0.032(4) 0.035(4) -0.012(3) 0.008(3) -0.008(3)
C26 0.035(4) 0.020(3) 0.057(5) -0.012(3) 0.012(3) -0.003(3)
C27 0.027(3) 0.015(3) 0.044(4) -0.002(3) 0.002(3) -0.004(2)
C28 0.020(3) 0.012(3) 0.035(3) -0.001(2) -0.003(2) -0.004(2)
C29 0.013(2) 0.012(3) 0.047(4) 0.006(2) 0.000(2) -0.0025(19)
C30 0.024(2) 0.012(2) 0.033(3) 0.008(2) -0.001(2) -0.0024(19)
C31 0.010(2) 0.034(3) 0.025(3) 0.006(2) -0.001(2) 0.001(2)
C32 0.007(2) 0.029(3) 0.037(3) -0.004(3) 0.001(2) 0.000(2)
C33 0.027(3) 0.026(3) 0.034(3) -0.007(3) 0.005(3) -0.002(2)
C34 0.030(3) 0.047(4) 0.041(4) -0.020(3) 0.007(3) -0.002(3)
C35 0.031(3) 0.021(3) 0.065(5) -0.011(3) 0.008(3) -0.001(3)
C36 0.021(3) 0.029(4) 0.049(4) -0.003(3) 0.004(3) 0.001(2)
C37 0.015(3) 0.014(3) 0.043(4) -0.003(2) 0.007(2) 0.002(2)
C38 0.018(3) 0.018(3) 0.046(4) 0.012(3) -0.001(2) 0.003(2)
C39 0.028(3) 0.024(3) 0.042(4) 0.013(3) -0.003(3) 0.003(3)
C40 0.016(3) 0.035(4) 0.029(3) 0.007(3) -0.006(2) -0.004(2)
C41 0.039(4) 0.013(3) 0.048(4) 0.000(3) 0.002(3) -0.006(3)
C42 0.033(3) 0.037(4) 0.027(3) 0.005(3) 0.005(3) -0.007(3)
C43 0.031(3) 0.020(3) 0.061(5) 0.006(3) -0.003(3) 0.014(3)
C44 0.040(4) 0.038(4) 0.036(4) 0.002(3) -0.019(3) 0.003(3)
C45 0.040(4) 0.037(4) 0.076(6) -0.011(4) -0.001(4) -0.011(3)
C46 0.043(5) 0.035(5) 0.100(8) 0.000(5) 0.006(5) -0.019(4)
C47 0.046(5) 0.048(5) 0.068(6) -0.007(4) -0.007(4) -0.001(4)
C48 0.043(5) 0.043(5) 0.095(7) 0.024(5) -0.024(5) -0.022(4)
K1 0.0192(6) 0.0216(6) 0.0361(7) -0.0027(5) 0.0025(5) -0.0022(5)
O1 0.042(3) 0.039(3) 0.066(4) -0.021(3) -0.007(3) 0.000(2)
O2 0.035(3) 0.039(3) 0.064(4) 0.004(3) 0.008(3) -0.014(2)
C49 0.025(4) 0.054(5) 0.072(6) -0.020(4) -0.007(4) 0.011(3)
C50 0.015(3) 0.052(5) 0.064(5) -0.011(4) -0.006(3) 0.013(3)
O3 0.024(2) 0.046(3) 0.075(4) -0.007(3) 0.004(2) 0.010(2)
O4 0.028(2) 0.083(3) 0.047(3) -0.001(3) -0.018(2) 0.023(2)
C51 0.034(4) 0.074(7) 0.066(6) -0.010(5) -0.005(4) 0.008(4)
C52 0.051(6) 0.112(10) 0.073(7) -0.011(7) 0.006(5) 0.027(6)
Dy1' 0.01397(11) 0.01298(12) 0.02228(13) -0.00107(10) 0.00050(9) 0.00085(9)
N1' 0.015(2) 0.016(2) 0.019(2) 0.0006(17) 0.0001(17) -0.0016(17)
N2' 0.016(2) 0.012(2) 0.025(2) 0.0008(17) 0.0002(18) -0.0012(16)
N3' 0.017(2) 0.020(2) 0.023(2) -0.0024(19) 0.0021(18) 0.0037(18)
N4' 0.023(2) 0.011(2) 0.031(3) -0.0008(19) 0.001(2) -0.0011(18)
N5' 0.017(2) 0.021(2) 0.026(2) -0.0035(19) -0.0021(18) 0.0057(18)
N6' 0.024(2) 0.010(2) 0.027(2) 0.0002(18) 0.0005(19) 0.0058(18)
N7' 0.011(2) 0.023(2) 0.023(2) -0.0005(19) 0.0004(17) -0.0011(17)
N8' 0.021(2) 0.015(2) 0.033(3) -0.005(2) 0.000(2) -0.0028(18)
C1' 0.012(2) 0.021(3) 0.027(3) 0.000(2) 0.002(2) 0.000(2)
C2' 0.027(3) 0.017(3) 0.024(3) -0.002(2) 0.000(2) -0.004(2)
C3' 0.029(3) 0.037(4) 0.032(3) -0.011(3) 0.001(3) 0.002(3)
C4' 0.036(3) 0.015(3) 0.045(4) -0.010(3) -0.005(3) -0.001(2)
C5' 0.022(3) 0.022(3) 0.034(3) 0.000(2) -0.005(2) 0.002(2)
C6' 0.018(3) 0.015(3) 0.024(3) -0.002(2) -0.003(2) -0.001(2)
C7' 0.017(3) 0.011(3) 0.032(3) 0.005(2) -0.003(2) 0.000(2)
C8' 0.021(3) 0.025(3) 0.028(3) 0.013(2) 0.006(2) 0.000(2)
C9' 0.019(3) 0.027(3) 0.025(3) 0.000(2) 0.002(2) 0.009(2)
C10' 0.017(3) 0.022(3) 0.037(3) -0.010(2) 0.001(2) 0.004(2)
C11' 0.033(3) 0.036(4) 0.031(3) -0.006(3) -0.004(3) 0.007(3)
C12' 0.037(4) 0.044(4) 0.044(4) -0.025(3) -0.011(3) 0.011(3)
C13' 0.031(4) 0.032(4) 0.063(5) -0.023(4) -0.006(3) -0.002(3)
C14' 0.019(3) 0.017(3) 0.053(4) -0.009(3) -0.001(3) -0.001(2)
C15' 0.017(3) 0.016(3) 0.036(3) -0.008(2) -0.002(2) 0.002(2)
C16' 0.019(3) 0.009(3) 0.041(3) 0.003(2) 0.000(2) 0.000(2)
C17' 0.018(3) 0.013(3) 0.035(3) 0.008(2) 0.002(2) 0.002(2)
C18' 0.010(2) 0.023(3) 0.027(3) 0.007(2) 0.000(2) 0.000(2)
C19' 0.031(3) 0.025(3) 0.038(4) 0.005(3) -0.001(3) -0.013(3)
C20' 0.041(4) 0.041(4) 0.032(4) -0.005(3) 0.013(3) 0.001(3)
C21' 0.030(3) 0.011(3) 0.056(4) 0.001(3) 0.000(3) 0.004(2)
C22' 0.036(4) 0.032(4) 0.033(4) 0.006(3) -0.006(3) 0.006(3)
C23' 0.020(3) 0.030(3) 0.030(3) 0.005(3) -0.002(2) 0.007(2)
C24' 0.038(4) 0.033(4) 0.030(3) 0.007(3) 0.002(3) 0.010(3)
C25' 0.042(4) 0.049(5) 0.040(4) 0.020(3) 0.013(3) 0.015(3)
C26' 0.037(4) 0.032(4) 0.054(5) 0.021(3) 0.011(3) 0.010(3)
C27' 0.025(3) 0.022(3) 0.045(4) 0.002(3) 0.001(3) 0.006(2)
C28' 0.019(3) 0.018(3) 0.033(3) 0.005(2) 0.000(2) 0.008(2)
C29' 0.017(3) 0.023(3) 0.032(3) -0.004(2) -0.004(2) -0.003(2)
C30' 0.011(2) 0.033(3) 0.030(3) -0.014(3) -0.001(2) -0.001(2)
C31' 0.019(3) 0.019(3) 0.028(3) -0.006(2) -0.004(2) 0.002(2)
C32' 0.021(3) 0.024(3) 0.028(3) 0.002(2) 0.008(2) -0.004(2)
C33' 0.018(3) 0.042(4) 0.033(3) 0.003(3) 0.001(2) -0.001(3)
C34' 0.030(3) 0.036(4) 0.045(4) 0.020(3) 0.006(3) 0.004(3)
C35' 0.039(4) 0.030(4) 0.057(5) 0.016(3) 0.013(3) -0.002(3)
C36' 0.033(3) 0.012(3) 0.055(4) 0.003(3) 0.006(3) -0.002(2)
C37' 0.011(2) 0.027(3) 0.033(3) -0.002(2) 0.000(2) -0.004(2)
C38' 0.022(3) 0.016(3) 0.047(4) -0.013(3) 0.002(3) -0.001(2)
C39' 0.014(3) 0.035(4) 0.040(4) -0.016(3) -0.013(2) -0.001(2)
C40' 0.033(3) 0.024(3) 0.028(3) -0.009(2) -0.001(3) 0.005(3)
C41' 0.029(3) 0.018(3) 0.060(5) -0.002(3) 0.011(3) 0.008(3)
C42' 0.030(3) 0.047(4) 0.028(3) -0.004(3) 0.005(3) 0.011(3)
C43' 0.026(3) 0.038(4) 0.059(5) -0.007(3) -0.001(3) -0.010(3)
C44' 0.041(4) 0.060(5) 0.032(4) -0.007(3) -0.010(3) 0.005(4)
C45' 0.029(4) 0.028(4) 0.100(7) 0.016(4) -0.003(4) 0.005(3)
C46' 0.036(4) 0.036(4) 0.090(7) 0.001(4) 0.009(4) 0.018(3)
C47' 0.042(5) 0.056(6) 0.074(6) 0.031(5) -0.005(4) 0.007(4)
C48' 0.053(5) 0.086(7) 0.060(6) -0.011(5) 0.031(5) 0.020(5)
K1' 0.0181(6) 0.0214(6) 0.0339(7) 0.0026(5) 0.0026(5) 0.0028(5)
O1' 0.033(3) 0.030(3) 0.068(4) 0.010(2) -0.004(2) 0.002(2)
O2' 0.025(2) 0.037(3) 0.064(4) -0.001(2) 0.006(2) 0.011(2)
C49' 0.022(3) 0.032(4) 0.066(5) 0.010(3) -0.005(3) -0.005(3)
C50' 0.025(3) 0.050(5) 0.060(5) 0.014(4) -0.002(3) -0.004(3)
O3' 0.031(3) 0.041(3) 0.067(4) 0.001(3) 0.006(2) -0.007(2)
O4' 0.037(3) 0.033(3) 0.065(4) 0.005(2) 0.019(3) -0.002(2)
C51' 0.052(5) 0.065(6) 0.070(6) -0.001(5) 0.012(5) -0.020(5)
C52' 0.032(4) 0.066(6) 0.066(6) -0.009(5) -0.007(4) -0.005(4)

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 N6 2.425(5) . ?
Dy1 N7 2.442(5) . ?
Dy1 N5 2.444(5) . ?
Dy1 N8 2.449(4) . ?
Dy1 N4 2.461(5) . ?
Dy1 N3 2.482(5) . ?
Dy1 N2 2.484(4) . ?
Dy1 N1 2.507(5) . ?
Dy1 K1 3.8402(14) . ?
N1 C18 1.314(7) . ?
N1 C1 1.411(7) . ?
N1 K1 2.981(5) . ?
N2 C7 1.329(7) . ?
N2 C6 1.410(7) . ?
N2 K1 2.973(5) . ?
N3 C9 1.330(8) . ?
N3 C10 1.399(8) . ?
N3 K1 3.069(5) . ?
N4 C16 1.328(8) . ?
N4 C15 1.419(8) . ?
N4 K1 3.084(5) . ?
N5 C40 1.324(7) . ?
N5 C23 1.412(8) . ?
N6 C29 1.321(7) . ?
N6 C28 1.414(8) . ?
N7 C31 1.320(7) . ?
N7 C32 1.382(8) . ?
N8 C38 1.318(8) . ?
N8 C37 1.423(8) . ?
C1 C2 1.395(8) . ?
C1 C6 1.437(8) . ?
C2 C3 1.398(9) . ?
C3 C4 1.397(10) . ?
C4 C5 1.383(9) . ?
C5 C6 1.406(8) . ?
C7 C8 1.413(9) . ?
C7 C19 1.511(8) . ?
C7 K1 3.178(6) . ?
C8 C9 1.404(9) . ?
C8 K1 3.275(6) . ?
C9 C20 1.529(9) . ?
C9 K1 3.251(6) . ?
C10 C11 1.408(9) . ?
C10 C15 1.444(9) . ?
C11 C12 1.361(11) . ?
C12 C13 1.368(14) . ?
C13 C14 1.410(12) . ?
C14 C15 1.385(9) . ?
C16 C17 1.416(9) . ?
C16 C21 1.511(9) . ?
C16 K1 3.275(6) . ?
C17 C18 1.407(9) . ?
C17 K1 3.299(6) . ?
C18 C22 1.531(9) . ?
C18 K1 3.188(6) . ?
C23 C24 1.407(9) . ?
C23 C28 1.431(8) . ?
C24 C25 1.379(10) . ?
C25 C26 1.400(11) . ?
C26 C27 1.379(10) . ?
C27 C28 1.403(8) . ?
C29 C30 1.400(9) . ?
C29 C41 1.535(8) . ?
C30 C31 1.412(9) . ?
C31 C42 1.521(8) . ?
C32 C37 1.413(9) . ?
C32 C33 1.433(9) . ?
C33 C34 1.397(10) . ?
C34 C35 1.383(11) . ?
C35 C36 1.381(10) . ?
C36 C37 1.395(9) . ?
C38 C39 1.395(10) . ?
C38 C43 1.526(8) . ?
C39 C40 1.414(9) . ?
C40 C44 1.519(9) . ?
C45 O1 1.392(10) . ?
C45 C46 1.498(13) . ?
C46 O2 1.417(9) . ?
C47 O1 1.415(11) . ?
C48 O2 1.339(10) . ?
K1 O4 2.739(6) . ?
K1 O1 2.814(5) . ?
K1 O2 2.826(5) . ?
K1 O3 2.983(6) . ?
C49 O3 1.435(9) . ?
C49 C50 1.477(12) . ?
C50 O4 1.424(8) . ?
O3 C51 1.414(11) . ?
O4 C52 1.382(13) . ?
Dy1' N6' 2.428(4) . ?
Dy1' N7' 2.437(5) . ?
Dy1' N8' 2.441(5) . ?
Dy1' N5' 2.448(5) . ?
Dy1' N4' 2.466(5) . ?
Dy1' N2' 2.473(4) . ?
Dy1' N3' 2.485(5) . ?
Dy1' N1' 2.486(5) . ?
Dy1' K1' 3.8258(14) . ?
N1' C18' 1.330(7) . ?
N1' C1' 1.414(7) . ?
N1' K1' 2.952(5) . ?
N2' C7' 1.329(7) . ?
N2' C6' 1.424(7) . ?
N2' K1' 2.963(5) . ?
N3' C9' 1.335(7) . ?
N3' C10' 1.409(8) . ?
N3' K1' 3.052(5) . ?
N4' C16' 1.323(7) . ?
N4' C15' 1.419(8) . ?
N4' K1' 3.065(5) . ?
N5' C40' 1.300(8) . ?
N5' C23' 1.418(8) . ?
N6' C29' 1.328(7) . ?
N6' C28' 1.415(8) . ?
N7' C31' 1.320(7) . ?
N7' C32' 1.423(8) . ?
N8' C38' 1.327(8) . ?
N8' C37' 1.403(8) . ?
C1' C2' 1.408(8) . ?
C1' C6' 1.424(8) . ?
C2' C3' 1.380(9) . ?
C3' C4' 1.386(10) . ?
C4' C5' 1.387(9) . ?
C5' C6' 1.380(8) . ?
C7' C8' 1.416(9) . ?
C7' C19' 1.528(8) . ?
C7' K1' 3.170(5) . ?
C8' C9' 1.401(9) . ?
C8' K1' 3.279(6) . ?
C9' C20' 1.525(8) . ?
C9' K1' 3.238(6) . ?
C10' C11' 1.395(9) . ?
C10' C15' 1.424(9) . ?
C11' C12' 1.393(10) . ?
C12' C13' 1.384(12) . ?
C13' C14' 1.370(10) . ?
C14' C15' 1.405(8) . ?
C16' C17' 1.411(9) . ?
C16' C21' 1.511(8) . ?
C16' K1' 3.246(6) . ?
C17' C18' 1.411(8) . ?
C17' K1' 3.258(6) . ?
C18' C22' 1.529(8) . ?
C18' K1' 3.159(6) . ?
C23' C24' 1.408(9) . ?
C23' C28' 1.424(9) . ?
C24' C25' 1.384(10) . ?
C25' C26' 1.370(12) . ?
C26' C27' 1.389(10) . ?
C27' C28' 1.393(9) . ?
C29' C30' 1.414(9) . ?
C29' C41' 1.516(9) . ?
C30' C31' 1.397(9) . ?
C31' C42' 1.542(8) . ?
C32' C33' 1.370(9) . ?
C32' C37' 1.443(8) . ?
C33' C34' 1.402(10) . ?
C34' C35' 1.374(11) . ?
C35' C36' 1.394(11) . ?
C36' C37' 1.414(9) . ?
C38' C39' 1.416(10) . ?
C38' C43' 1.527(9) . ?
C39' C40' 1.402(10) . ?
C40' C44' 1.537(9) . ?
C45' O1' 1.435(9) . ?
C45' C46' 1.468(13) . ?
C46' O2' 1.419(9) . ?
C47' O1' 1.425(11) . ?
C48' O2' 1.444(11) . ?
K1' O4' 2.769(5) . ?
K1' O1' 2.789(5) . ?
K1' O2' 2.845(5) . ?
K1' O3' 3.078(6) . ?
C49' O3' 1.417(8) . ?
C49' C50' 1.461(11) . ?
C50' O4' 1.376(9) . ?
O3' C52' 1.410(10) . ?
O4' C51' 1.426(11) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N6 Dy1 N7 73.57(16) . . ?
N6 Dy1 N5 65.60(16) . . ?
N7 Dy1 N5 107.43(16) . . ?
N6 Dy1 N8 106.55(16) . . ?
N7 Dy1 N8 65.28(16) . . ?
N5 Dy1 N8 72.47(16) . . ?
N6 Dy1 N4 175.50(17) . . ?
N7 Dy1 N4 110.82(16) . . ?
N5 Dy1 N4 111.39(16) . . ?
N8 Dy1 N4 75.04(15) . . ?
N6 Dy1 N3 111.43(16) . . ?
N7 Dy1 N3 174.99(16) . . ?
N5 Dy1 N3 75.14(16) . . ?
N8 Dy1 N3 112.13(16) . . ?
N4 Dy1 N3 64.17(16) . . ?
N6 Dy1 N2 74.74(15) . . ?
N7 Dy1 N2 111.37(15) . . ?
N5 Dy1 N2 111.87(16) . . ?
N8 Dy1 N2 175.45(16) . . ?
N4 Dy1 N2 104.01(15) . . ?
N3 Dy1 N2 70.96(16) . . ?
N6 Dy1 N1 111.59(16) . . ?
N7 Dy1 N1 73.92(15) . . ?
N5 Dy1 N1 175.94(16) . . ?
N8 Dy1 N1 111.45(16) . . ?
N4 Dy1 N1 71.23(16) . . ?
N3 Dy1 N1 103.81(15) . . ?
N2 Dy1 N1 64.18(15) . . ?
N6 Dy1 K1 125.39(11) . . ?
N7 Dy1 K1 124.73(11) . . ?
N5 Dy1 K1 127.83(12) . . ?
N8 Dy1 K1 128.04(11) . . ?
N4 Dy1 K1 53.30(11) . . ?
N3 Dy1 K1 52.94(12) . . ?
N2 Dy1 K1 50.73(11) . . ?
N1 Dy1 K1 50.89(10) . . ?
C18 N1 C1 124.9(5) . . ?
C18 N1 Dy1 133.1(4) . . ?
C1 N1 Dy1 100.4(3) . . ?
C18 N1 K1 86.7(3) . . ?
C1 N1 K1 110.2(3) . . ?
Dy1 N1 K1 88.38(14) . . ?
C7 N2 C6 125.1(5) . . ?
C7 N2 Dy1 133.5(4) . . ?
C6 N2 Dy1 99.8(3) . . ?
C7 N2 K1 86.3(3) . . ?
C6 N2 K1 110.3(3) . . ?
Dy1 N2 K1 88.97(13) . . ?
C9 N3 C10 123.9(5) . . ?
C9 N3 Dy1 134.0(4) . . ?
C10 N3 Dy1 100.4(4) . . ?
C9 N3 K1 85.6(4) . . ?
C10 N3 K1 113.9(4) . . ?
Dy1 N3 K1 86.86(15) . . ?
C16 N4 C15 124.6(5) . . ?
C16 N4 Dy1 133.2(4) . . ?
C15 N4 Dy1 100.4(3) . . ?
C16 N4 K1 86.2(3) . . ?
C15 N4 K1 113.9(4) . . ?
Dy1 N4 K1 86.92(14) . . ?
C40 N5 C23 123.5(5) . . ?
C40 N5 Dy1 134.9(4) . . ?
C23 N5 Dy1 101.3(3) . . ?
C29 N6 C28 124.5(5) . . ?
C29 N6 Dy1 133.8(4) . . ?
C28 N6 Dy1 101.5(3) . . ?
C31 N7 C32 124.8(5) . . ?
C31 N7 Dy1 132.8(4) . . ?
C32 N7 Dy1 102.1(3) . . ?
C38 N8 C37 124.3(5) . . ?
C38 N8 Dy1 134.0(4) . . ?
C37 N8 Dy1 101.6(3) . . ?
C2 C1 N1 125.6(5) . . ?
C2 C1 C6 119.2(5) . . ?
N1 C1 C6 114.6(5) . . ?
C1 C2 C3 120.9(6) . . ?
C4 C3 C2 120.2(6) . . ?
C5 C4 C3 119.6(6) . . ?
C4 C5 C6 121.9(6) . . ?
C5 C6 N2 125.1(5) . . ?
C5 C6 C1 118.2(5) . . ?
N2 C6 C1 116.4(5) . . ?
N2 C7 C8 122.3(5) . . ?
N2 C7 C19 122.9(6) . . ?
C8 C7 C19 114.6(5) . . ?
N2 C7 K1 69.0(3) . . ?
C8 C7 K1 81.2(4) . . ?
C19 C7 K1 118.8(4) . . ?
C9 C8 C7 129.9(6) . . ?
C9 C8 K1 76.6(4) . . ?
C7 C8 K1 73.5(3) . . ?
N3 C9 C8 122.1(6) . . ?
N3 C9 C20 123.1(6) . . ?
C8 C9 C20 114.6(6) . . ?
N3 C9 K1 70.3(3) . . ?
C8 C9 K1 78.5(4) . . ?
C20 C9 K1 120.2(4) . . ?
N3 C10 C11 126.8(6) . . ?
N3 C10 C15 115.5(5) . . ?
C11 C10 C15 117.2(6) . . ?
C12 C11 C10 121.9(8) . . ?
C11 C12 C13 120.2(8) . . ?
C12 C13 C14 121.5(7) . . ?
C15 C14 C13 118.6(8) . . ?
C14 C15 N4 124.9(7) . . ?
C14 C15 C10 120.5(7) . . ?
N4 C15 C10 114.1(5) . . ?
N4 C16 C17 123.3(5) . . ?
N4 C16 C21 122.5(6) . . ?
C17 C16 C21 114.1(6) . . ?
N4 C16 K1 70.0(3) . . ?
C17 C16 K1 78.5(3) . . ?
C21 C16 K1 121.6(4) . . ?
C18 C17 C16 129.0(6) . . ?
C18 C17 K1 73.1(3) . . ?
C16 C17 K1 76.6(3) . . ?
N1 C18 C17 122.7(6) . . ?
N1 C18 C22 122.8(6) . . ?
C17 C18 C22 114.3(5) . . ?
N1 C18 K1 69.0(3) . . ?
C17 C18 K1 81.9(3) . . ?
C22 C18 K1 118.2(4) . . ?
C24 C23 N5 125.9(6) . . ?
C24 C23 C28 118.6(6) . . ?
N5 C23 C28 115.0(5) . . ?
C25 C24 C23 121.5(6) . . ?
C24 C25 C26 119.6(6) . . ?
C27 C26 C25 120.3(6) . . ?
C26 C27 C28 121.4(6) . . ?
C27 C28 N6 125.4(6) . . ?
C27 C28 C23 118.5(6) . . ?
N6 C28 C23 115.6(5) . . ?
N6 C29 C30 123.3(5) . . ?
N6 C29 C41 121.9(6) . . ?
C30 C29 C41 114.8(5) . . ?
C29 C30 C31 129.1(5) . . ?
N7 C31 C30 123.4(5) . . ?
N7 C31 C42 121.5(6) . . ?
C30 C31 C42 114.9(5) . . ?
N7 C32 C37 117.1(5) . . ?
N7 C32 C33 125.2(6) . . ?
C37 C32 C33 117.4(6) . . ?
C34 C33 C32 121.3(7) . . ?
C35 C34 C33 119.3(7) . . ?
C36 C35 C34 120.7(6) . . ?
C35 C36 C37 121.1(7) . . ?
C36 C37 C32 120.1(6) . . ?
C36 C37 N8 124.7(6) . . ?
C32 C37 N8 114.7(5) . . ?
N8 C38 C39 124.0(6) . . ?
N8 C38 C43 121.5(6) . . ?
C39 C38 C43 114.5(6) . . ?
C38 C39 C40 129.0(6) . . ?
N5 C40 C39 122.2(6) . . ?
N5 C40 C44 122.8(6) . . ?
C39 C40 C44 115.0(6) . . ?
O1 C45 C46 110.3(7) . . ?
O2 C46 C45 111.0(7) . . ?
O4 K1 O1 80.76(18) . . ?
O4 K1 O2 91.70(19) . . ?
O1 K1 O2 59.47(18) . . ?
O4 K1 N2 100.40(17) . . ?
O1 K1 N2 154.17(17) . . ?
O2 K1 N2 145.48(16) . . ?
O4 K1 N1 143.57(18) . . ?
O1 K1 N1 112.41(16) . . ?
O2 K1 N1 124.51(15) . . ?
N2 K1 N1 52.89(13) . . ?
O4 K1 O3 60.66(17) . . ?
O1 K1 O3 77.27(17) . . ?
O2 K1 O3 132.39(16) . . ?
N2 K1 O3 80.90(15) . . ?
N1 K1 O3 88.28(14) . . ?
O4 K1 N3 106.22(15) . . ?
O1 K1 N3 147.86(17) . . ?
O2 K1 N3 88.67(15) . . ?
N2 K1 N3 56.97(13) . . ?
N1 K1 N3 80.92(13) . . ?
O3 K1 N3 133.92(15) . . ?
O4 K1 N4 152.13(16) . . ?
O1 K1 N4 110.92(15) . . ?
O2 K1 N4 74.57(14) . . ?
N2 K1 N4 80.07(13) . . ?
N1 K1 N4 56.96(13) . . ?
O3 K1 N4 145.08(15) . . ?
N3 K1 N4 50.53(13) . . ?
O4 K1 C7 77.06(18) . . ?
O1 K1 C7 151.40(16) . . ?
O2 K1 C7 138.36(17) . . ?
N2 K1 C7 24.66(13) . . ?
N1 K1 C7 77.33(14) . . ?
O3 K1 C7 76.22(16) . . ?
N3 K1 C7 57.72(14) . . ?
N4 K1 C7 97.00(14) . . ?
O4 K1 C18 149.90(17) . . ?
O1 K1 C18 89.08(17) . . ?
O2 K1 C18 107.43(16) . . ?
N2 K1 C18 77.03(14) . . ?
N1 K1 C18 24.30(14) . . ?
O3 K1 C18 89.53(16) . . ?
N3 K1 C18 97.45(15) . . ?
N4 K1 C18 57.75(15) . . ?
C7 K1 C18 101.20(16) . . ?
O4 K1 C9 82.35(16) . . ?
O1 K1 C9 146.46(18) . . ?
O2 K1 C9 92.43(17) . . ?
N2 K1 C9 57.92(14) . . ?
N1 K1 C9 98.30(14) . . ?
O3 K1 C9 118.26(17) . . ?
N3 K1 C9 24.07(14) . . ?
N4 K1 C9 74.32(15) . . ?
C7 K1 C9 46.75(16) . . ?
C18 K1 C9 118.73(16) . . ?
O4 K1 C8 69.64(17) . . ?
O1 K1 C8 149.60(16) . . ?
O2 K1 C8 113.31(17) . . ?
N2 K1 C8 44.88(14) . . ?
N1 K1 C8 95.96(14) . . ?
O3 K1 C8 93.54(17) . . ?
N3 K1 C8 44.16(15) . . ?
N4 K1 C8 93.29(15) . . ?
C7 K1 C8 25.23(16) . . ?
C18 K1 C8 120.11(16) . . ?
C9 K1 C8 24.84(16) . . ?
C45 O1 C47 111.7(6) . . ?
C45 O1 K1 114.9(5) . . ?
C47 O1 K1 113.4(5) . . ?
C48 O2 C46 113.4(6) . . ?
C48 O2 K1 124.5(5) . . ?
C46 O2 K1 117.6(5) . . ?
O3 C49 C50 111.2(7) . . ?
O4 C50 C49 111.3(6) . . ?
O4 C50 K1 47.0(3) . . ?
C49 C50 K1 87.5(4) . . ?
C51 O3 C49 113.0(6) . . ?
C51 O3 K1 132.2(4) . . ?
C49 O3 K1 111.0(5) . . ?
C52 O4 C50 110.4(7) . . ?
C52 O4 K1 109.4(5) . . ?
C50 O4 K1 110.7(4) . . ?
N6' Dy1' N7' 73.51(16) . . ?
N6' Dy1' N8' 106.73(16) . . ?
N7' Dy1' N8' 65.29(16) . . ?
N6' Dy1' N5' 65.33(16) . . ?
N7' Dy1' N5' 107.31(15) . . ?
N8' Dy1' N5' 72.82(17) . . ?
N6' Dy1' N4' 175.27(16) . . ?
N7' Dy1' N4' 111.10(16) . . ?
N8' Dy1' N4' 74.99(16) . . ?
N5' Dy1' N4' 111.53(16) . . ?
N6' Dy1' N2' 74.80(15) . . ?
N7' Dy1' N2' 111.19(15) . . ?
N8' Dy1' N2' 175.07(16) . . ?
N5' Dy1' N2' 111.91(16) . . ?
N4' Dy1' N2' 103.87(15) . . ?
N6' Dy1' N3' 111.17(16) . . ?
N7' Dy1' N3' 175.31(16) . . ?
N8' Dy1' N3' 112.51(16) . . ?
N5' Dy1' N3' 75.35(15) . . ?
N4' Dy1' N3' 64.21(16) . . ?
N2' Dy1' N3' 70.73(15) . . ?
N6' Dy1' N1' 112.06(16) . . ?
N7' Dy1' N1' 74.34(15) . . ?
N8' Dy1' N1' 111.21(16) . . ?
N5' Dy1' N1' 175.90(16) . . ?
N4' Dy1' N1' 70.86(16) . . ?
N2' Dy1' N1' 64.04(15) . . ?
N3' Dy1' N1' 103.27(15) . . ?
N6' Dy1' K1' 125.47(12) . . ?
N7' Dy1' K1' 124.76(11) . . ?
N8' Dy1' K1' 127.78(12) . . ?
N5' Dy1' K1' 127.92(11) . . ?
N4' Dy1' K1' 53.13(11) . . ?
N2' Dy1' K1' 50.76(11) . . ?
N3' Dy1' K1' 52.80(11) . . ?
N1' Dy1' K1' 50.49(10) . . ?
C18' N1' C1' 124.4(5) . . ?
C18' N1' Dy1' 134.0(4) . . ?
C1' N1' Dy1' 100.0(3) . . ?
C18' N1' K1' 86.3(3) . . ?
C1' N1' K1' 110.7(3) . . ?
Dy1' N1' K1' 88.99(14) . . ?
C7' N2' C6' 124.1(5) . . ?
C7' N2' Dy1' 133.8(4) . . ?
C6' N2' Dy1' 100.5(3) . . ?
C7' N2' K1' 86.4(3) . . ?
C6' N2' K1' 110.3(3) . . ?
Dy1' N2' K1' 88.98(14) . . ?
C9' N3' C10' 124.7(5) . . ?
C9' N3' Dy1' 134.4(4) . . ?
C10' N3' Dy1' 99.2(3) . . ?
C9' N3' K1' 85.7(3) . . ?
C10' N3' K1' 114.7(4) . . ?
Dy1' N3' K1' 86.77(14) . . ?
C16' N4' C15' 125.0(5) . . ?
C16' N4' Dy1' 134.3(4) . . ?
C15' N4' Dy1' 99.1(3) . . ?
C16' N4' K1' 85.7(3) . . ?
C15' N4' K1' 113.7(3) . . ?
Dy1' N4' K1' 86.80(13) . . ?
C40' N5' C23' 123.6(5) . . ?
C40' N5' Dy1' 134.8(4) . . ?
C23' N5' Dy1' 101.4(3) . . ?
C29' N6' C28' 124.3(5) . . ?
C29' N6' Dy1' 133.7(4) . . ?
C28' N6' Dy1' 101.8(3) . . ?
C31' N7' C32' 123.6(5) . . ?
C31' N7' Dy1' 133.3(4) . . ?
C32' N7' Dy1' 102.7(3) . . ?
C38' N8' C37' 124.1(5) . . ?
C38' N8' Dy1' 134.1(4) . . ?
C37' N8' Dy1' 101.6(3) . . ?
C2' C1' N1' 125.5(5) . . ?
C2' C1' C6' 118.6(5) . . ?
N1' C1' C6' 115.6(5) . . ?
C3' C2' C1' 121.3(6) . . ?
C2' C3' C4' 119.5(6) . . ?
C3' C4' C5' 120.2(6) . . ?
C6' C5' C4' 121.6(6) . . ?
C5' C6' C1' 118.8(5) . . ?
C5' C6' N2' 126.0(5) . . ?
C1' C6' N2' 114.7(5) . . ?
N2' C7' C8' 122.7(5) . . ?
N2' C7' C19' 122.7(5) . . ?
C8' C7' C19' 114.5(5) . . ?
N2' C7' K1' 68.9(3) . . ?
C8' C7' K1' 81.6(3) . . ?
C19' C7' K1' 119.3(4) . . ?
C9' C8' C7' 129.2(5) . . ?
C9' C8' K1' 76.0(3) . . ?
C7' C8' K1' 73.1(3) . . ?
N3' C9' C8' 122.0(5) . . ?
N3' C9' C20' 123.4(6) . . ?
C8' C9' C20' 114.6(5) . . ?
N3' C9' K1' 70.0(3) . . ?
C8' C9' K1' 79.2(3) . . ?
C20' C9' K1' 121.8(4) . . ?
C11' C10' N3' 124.7(6) . . ?
C11' C10' C15' 120.0(6) . . ?
N3' C10' C15' 114.9(5) . . ?
C12' C11' C10' 120.8(7) . . ?
C13' C12' C11' 119.2(7) . . ?
C14' C13' C12' 120.7(7) . . ?
C13' C14' C15' 122.1(7) . . ?
C14' C15' N4' 126.8(6) . . ?
C14' C15' C10' 117.1(6) . . ?
N4' C15' C10' 115.6(5) . . ?
N4' C16' C17' 122.4(5) . . ?
N4' C16' C21' 122.2(6) . . ?
C17' C16' C21' 115.4(5) . . ?
N4' C16' K1' 70.3(3) . . ?
C17' C16' K1' 77.9(3) . . ?
C21' C16' K1' 122.9(4) . . ?
C16' C17' C18' 129.7(5) . . ?
C16' C17' K1' 77.0(3) . . ?
C18' C17' K1' 73.4(3) . . ?
N1' C18' C17' 121.7(5) . . ?
N1' C18' C22' 123.7(5) . . ?
C17' C18' C22' 114.6(5) . . ?
N1' C18' K1' 68.8(3) . . ?
C17' C18' K1' 81.3(3) . . ?
C22' C18' K1' 120.1(4) . . ?
C24' C23' N5' 125.6(6) . . ?
C24' C23' C28' 118.9(6) . . ?
N5' C23' C28' 114.9(5) . . ?
C25' C24' C23' 121.2(7) . . ?
C26' C25' C24' 119.4(7) . . ?
C25' C26' C27' 121.1(7) . . ?
C26' C27' C28' 121.0(7) . . ?
C27' C28' N6' 125.4(6) . . ?
C27' C28' C23' 118.4(6) . . ?
N6' C28' C23' 115.6(5) . . ?
N6' C29' C30' 122.7(6) . . ?
N6' C29' C41' 121.5(6) . . ?
C30' C29' C41' 115.7(6) . . ?
C31' C30' C29' 129.4(5) . . ?
N7' C31' C30' 123.1(5) . . ?
N7' C31' C42' 122.8(6) . . ?
C30' C31' C42' 113.9(5) . . ?
C33' C32' N7' 127.0(6) . . ?
C33' C32' C37' 119.8(6) . . ?
N7' C32' C37' 112.9(5) . . ?
C32' C33' C34' 121.3(7) . . ?
C35' C34' C33' 120.0(7) . . ?
C34' C35' C36' 120.3(7) . . ?
C35' C36' C37' 121.0(7) . . ?
N8' C37' C36' 125.3(6) . . ?
N8' C37' C32' 116.9(5) . . ?
C36' C37' C32' 117.5(6) . . ?
N8' C38' C39' 122.6(6) . . ?
N8' C38' C43' 121.9(6) . . ?
C39' C38' C43' 115.5(6) . . ?
C40' C39' C38' 129.7(5) . . ?
N5' C40' C39' 122.8(6) . . ?
N5' C40' C44' 122.5(6) . . ?
C39' C40' C44' 114.6(6) . . ?
O1' C45' C46' 110.2(7) . . ?
O2' C46' C45' 110.0(6) . . ?
O4' K1' O1' 79.09(16) . . ?
O4' K1' O2' 94.34(15) . . ?
O1' K1' O2' 59.34(16) . . ?
O4' K1' N1' 139.64(15) . . ?
O1' K1' N1' 113.88(16) . . ?
O2' K1' N1' 125.55(14) . . ?
O4' K1' N2' 98.94(14) . . ?
O1' K1' N2' 155.00(16) . . ?
O2' K1' N2' 145.16(15) . . ?
N1' K1' N2' 52.78(13) . . ?
O4' K1' N3' 109.00(16) . . ?
O1' K1' N3' 147.43(16) . . ?
O2' K1' N3' 88.27(14) . . ?
N1' K1' N3' 80.94(13) . . ?
N2' K1' N3' 56.96(13) . . ?
O4' K1' N4' 156.58(17) . . ?
O1' K1' N4' 111.30(14) . . ?
O2' K1' N4' 74.99(14) . . ?
N1' K1' N4' 56.96(13) . . ?
N2' K1' N4' 80.32(13) . . ?
N3' K1' N4' 50.96(13) . . ?
O4' K1' O3' 57.75(16) . . ?
O1' K1' O3' 78.07(16) . . ?
O2' K1' O3' 133.58(15) . . ?
N1' K1' O3' 86.54(14) . . ?
N2' K1' O3' 79.91(14) . . ?
N3' K1' O3' 133.47(15) . . ?
N4' K1' O3' 143.31(14) . . ?
O4' K1' C18' 145.01(17) . . ?
O1' K1' C18' 89.93(16) . . ?
O2' K1' C18' 108.48(16) . . ?
N1' K1' C18' 24.85(13) . . ?
N2' K1' C18' 77.42(14) . . ?
N3' K1' C18' 98.13(14) . . ?
N4' K1' C18' 58.03(14) . . ?
O3' K1' C18' 87.59(15) . . ?
O4' K1' C7' 76.20(15) . . ?
O1' K1' C7' 150.90(15) . . ?
O2' K1' C7' 137.42(16) . . ?
N1' K1' C7' 77.29(14) . . ?
N2' K1' C7' 24.73(13) . . ?
N3' K1' C7' 57.71(14) . . ?
N4' K1' C7' 97.37(14) . . ?
O3' K1' C7' 75.86(15) . . ?
C18' K1' C7' 101.62(15) . . ?
O4' K1' C9' 84.77(17) . . ?
O1' K1' C9' 144.99(17) . . ?
O2' K1' C9' 91.55(16) . . ?
N1' K1' C9' 98.52(14) . . ?
N2' K1' C9' 58.10(14) . . ?
N3' K1' C9' 24.28(14) . . ?
N4' K1' C9' 74.92(15) . . ?
O3' K1' C9' 118.42(16) . . ?
C18' K1' C9' 119.64(14) . . ?
C7' K1' C9' 46.78(15) . . ?
O4' K1' C16' 161.87(15) . . ?
O1' K1' C16' 88.76(15) . . ?
O2' K1' C16' 67.76(15) . . ?
N1' K1' C16' 57.89(14) . . ?
N2' K1' C16' 97.72(13) . . ?
N3' K1' C16' 74.59(14) . . ?
N4' K1' C16' 23.97(14) . . ?
O3' K1' C16' 132.95(16) . . ?
C18' K1' C16' 46.98(16) . . ?
C7' K1' C16' 118.64(14) . . ?
C9' K1' C16' 98.08(16) . . ?
C47' O1' C45' 112.2(7) . . ?
C47' O1' K1' 112.1(4) . . ?
C45' O1' K1' 114.1(4) . . ?
C46' O2' C48' 111.1(6) . . ?
C46' O2' K1' 117.6(5) . . ?
C48' O2' K1' 125.2(5) . . ?
O3' C49' C50' 111.9(6) . . ?
O4' C50' C49' 110.0(6) . . ?
C52' O3' C49' 112.0(6) . . ?
C52' O3' K1' 133.3(4) . . ?
C49' O3' K1' 110.3(5) . . ?
C50' O4' C51' 116.0(6) . . ?
C50' O4' K1' 114.6(4) . . ?
C51' O4' K1' 102.9(4) . . ?

_diffrn_measured_fraction_theta_max 0.990
_diffrn_reflns_theta_full        27.64
_diffrn_measured_fraction_theta_full 0.990
_refine_diff_density_max         4.384
_refine_diff_density_min         -6.077
_refine_diff_density_rms         0.144

loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 -0.230 -0.057 0.035 189 44 ' '
2 0.230 0.443 0.465 189 45 ' '
3 0.270 0.557 -0.035 189 45 ' '
4 0.133 0.151 0.064 8 1 ' '
5 0.366 0.848 0.564 8 1 ' '
6 0.729 1.057 0.535 189 44 ' '
7 0.633 0.348 0.936 8 1 ' '
8 0.867 0.651 0.436 8 1 ' '