# Electronic Supplementary Material (ESI) for Chemical Communications
# This journal is © The Royal Society of Chemistry 2012


data_global

_journal_coden_Cambridge         182
_journal_volume                  ?
_journal_page_first              ?
_journal_year                    ?

loop_
_publ_author_name
'Hu, Wenping'
'Lv, Aifeng'
'Li, Yan'
'Yue, Wan'
'Jiang, Lang'
'Dong, Huanli'
'Zhao, Guangyao'
'Meng, Qing'
'Jiang, Wei'
'He, Yudong'
'Li, Zhibo'
'Wang, Zhaohui'

_publ_contact_author_name        'Dr Wenping Hu'
_publ_contact_author_email       huwp@iccas.ac.cn

_publ_section_title              
;
High performance n-type single crystalline
transistors of naphthalene bis(dicarboximide)
and their anisotropic transport in crystals

;

# Attachment '- a.cif'

data_a
_database_code_depnum_ccdc_archive 'CCDC 870196'
#TrackingRef '- a.cif'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C22 H8 F14 N2 O4'
_chemical_formula_sum            'C22 H8 F14 N2 O4'
_chemical_formula_weight         630.30

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   P2/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'

_cell_length_a                   17.379(4)
_cell_length_b                   7.7605(16)
_cell_length_c                   16.708(3)
_cell_angle_alpha                90.00
_cell_angle_beta                 101.77(3)
_cell_angle_gamma                90.00
_cell_volume                     2206.0(8)
_cell_formula_units_Z            4
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    6024
_cell_measurement_theta_min      2.3943
_cell_measurement_theta_max      27.4675

_exptl_crystal_description       plate
_exptl_crystal_colour            Colorless
_exptl_crystal_size_max          0.27
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.05
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.898
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1248
_exptl_absorpt_coefficient_mu    0.208
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.6947
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_process_details   'CrystalClear (Rigaku Inc., 2008)'

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'Rotating Anode'
_diffrn_radiation_monochromator  Confocal
_diffrn_measurement_device_type  'MM007HF + CCD (Saturn724+)'
_diffrn_measurement_method       '\w scans at fixed \c = 45\%'
_diffrn_detector_area_resol_mean 28.5714
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            15198
_diffrn_reflns_av_R_equivalents  0.0633
_diffrn_reflns_av_sigmaI/netI    0.0753
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_theta_min         2.39
_diffrn_reflns_theta_max         27.51
_reflns_number_total             5038
_reflns_number_gt                3814
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'CrystalClear (Rigaku Inc., 2008)'
_computing_cell_refinement       'CrystalClear (Rigaku Inc., 2008)'
_computing_data_reduction        'CrystalClear (Rigaku Inc., 2008)'
_computing_structure_solution    'SHELX-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELX-97 (Sheldrick, 2008)'
_computing_molecular_graphics    
;
Mercury: visualization and analysis of crystal structures, C. F. Macrae,
P. R. Edgington, P. McCabe, E. Pidcock, G. P. Shields, R. Taylor,
M. Towler and J. van de Streek, J. Appl. Cryst., 39, 453-457, 2006.
;
_computing_publication_material  'SHELX-97 (Sheldrick, 2008)'

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0414P)^2^+2.1057P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         5038
_refine_ls_number_parameters     379
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1153
_refine_ls_R_factor_gt           0.0833
_refine_ls_wR_factor_ref         0.1603
_refine_ls_wR_factor_gt          0.1476
_refine_ls_goodness_of_fit_ref   1.169
_refine_ls_restrained_S_all      1.169
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
F1 F 0.49286(15) 0.9521(3) 0.34922(16) 0.0636(7) Uani 1 1 d . . .
F2 F 0.38476(17) 0.9121(4) 0.26291(16) 0.0778(9) Uani 1 1 d . . .
F3 F 0.41273(19) 0.7558(3) 0.3698(2) 0.0894(11) Uani 1 1 d . . .
F4 F 0.38286(13) 1.1972(3) 0.35422(13) 0.0478(6) Uani 1 1 d . . .
F5 F 0.41883(13) 1.0500(3) 0.46591(12) 0.0543(6) Uani 1 1 d . . .
F6 F 0.25134(12) 0.9737(2) 0.31549(11) 0.0381(5) Uani 1 1 d . . .
F7 F 0.28844(13) 0.8655(2) 0.43720(12) 0.0386(5) Uani 1 1 d . . .
F8 F 0.47549(16) 0.4409(4) 0.08354(18) 0.0762(9) Uani 1 1 d . . .
F9 F 0.39936(15) 0.6473(3) 0.10142(15) 0.0565(7) Uani 1 1 d . . .
F10 F 0.35948(17) 0.4620(4) 0.00866(15) 0.0708(8) Uani 1 1 d . . .
F11 F 0.41429(13) 0.4089(3) 0.21952(13) 0.0568(7) Uani 1 1 d . . .
F12 F 0.38167(14) 0.2066(3) 0.12783(16) 0.0583(7) Uani 1 1 d . . .
F13 F 0.23908(12) 0.3440(2) 0.07779(11) 0.0382(5) Uani 1 1 d . . .
F14 F 0.26915(12) 0.2841(2) 0.20744(12) 0.0380(5) Uani 1 1 d . . .
O1 O 0.24286(14) 1.0531(3) 0.57943(13) 0.0300(5) Uani 1 1 d . . .
O2 O 0.11602(14) 1.2066(3) 0.32416(13) 0.0339(6) Uani 1 1 d . . .
O3 O 0.24310(14) 0.5562(3) 0.32799(13) 0.0332(6) Uani 1 1 d . . .
O4 O 0.12484(14) 0.6085(3) 0.05936(13) 0.0313(5) Uani 1 1 d . . .
N1 N 0.18037(16) 1.1112(3) 0.44863(15) 0.0251(6) Uani 1 1 d . . .
N2 N 0.18449(16) 0.5842(3) 0.19352(15) 0.0270(6) Uani 1 1 d . . .
C1 C 0.4181(3) 0.9109(5) 0.3418(3) 0.0479(10) Uani 1 1 d . . .
C2 C 0.3778(2) 1.0420(4) 0.3887(2) 0.0330(8) Uani 1 1 d . . .
C3 C 0.2917(2) 1.0103(4) 0.39230(18) 0.0271(7) Uani 1 1 d . . .
C4 C 0.25523(19) 1.1609(4) 0.42858(19) 0.0280(7) Uani 1 1 d . . .
H4B H 0.2916 1.2010 0.4787 0.034 Uiso 1 1 calc R . .
H4A H 0.2467 1.2573 0.3890 0.034 Uiso 1 1 calc R . .
C5 C 0.1123(2) 1.1435(4) 0.39019(18) 0.0262(7) Uani 1 1 d . . .
C6 C 0.03652(19) 1.0959(4) 0.41234(18) 0.0257(7) Uani 1 1 d . . .
C7 C 0.03626(18) 1.0236(4) 0.49020(17) 0.0239(7) Uani 1 1 d . . .
C8 C 0.1065(2) 0.9991(4) 0.54858(18) 0.0251(7) Uani 1 1 d . . .
C9 C 0.1821(2) 1.0547(4) 0.52930(18) 0.0259(7) Uani 1 1 d . . .
C10 C 0.1043(2) 0.9285(4) 0.62362(18) 0.0287(7) Uani 1 1 d . . .
H10 H 0.1517 0.9129 0.6628 0.034 Uiso 1 1 calc R . .
C11 C 0.0326(2) 0.8795(4) 0.64266(18) 0.0284(7) Uani 1 1 d . . .
H11 H 0.0319 0.8287 0.6942 0.034 Uiso 1 1 calc R . .
C12 C 0.4021(3) 0.4817(5) 0.0835(3) 0.0461(10) Uani 1 1 d . . .
C13 C 0.3704(2) 0.3724(4) 0.1456(2) 0.0369(8) Uani 1 1 d . . .
C14 C 0.2839(2) 0.3976(4) 0.15045(19) 0.0289(7) Uani 1 1 d . . .
C15 C 0.2617(2) 0.5777(4) 0.17128(19) 0.0295(7) Uani 1 1 d . . .
H15B H 0.3019 0.6219 0.2174 0.035 Uiso 1 1 calc R . .
H15A H 0.2614 0.6539 0.1237 0.035 Uiso 1 1 calc R . .
C16 C 0.1180(2) 0.6003(4) 0.13054(18) 0.0260(7) Uani 1 1 d . . .
C17 C 0.0409(2) 0.6067(4) 0.15485(17) 0.0243(7) Uani 1 1 d . . .
C18 C 0.03691(19) 0.6051(4) 0.23910(18) 0.0250(7) Uani 1 1 d . . .
C19 C 0.1061(2) 0.5998(4) 0.30093(18) 0.0266(7) Uani 1 1 d . . .
C20 C 0.1832(2) 0.5783(4) 0.27821(18) 0.0274(7) Uani 1 1 d . . .
C21 C 0.1007(2) 0.6054(4) 0.38220(18) 0.0290(7) Uani 1 1 d . . .
H21 H 0.1471 0.6053 0.4236 0.035 Uiso 1 1 calc R . .
C22 C 0.0272(2) 0.6111(4) 0.40383(18) 0.0280(7) Uani 1 1 d . . .
H22 H 0.0242 0.6181 0.4599 0.034 Uiso 1 1 calc R . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
F1 0.0335(16) 0.0809(18) 0.0820(18) -0.0085(14) 0.0251(13) -0.0004(13)
F2 0.060(2) 0.119(2) 0.0582(16) -0.0350(16) 0.0229(14) -0.0062(17)
F3 0.085(2) 0.0457(15) 0.159(3) 0.0102(16) 0.076(2) 0.0182(14)
F4 0.0402(15) 0.0421(12) 0.0627(14) 0.0094(10) 0.0138(11) -0.0086(10)
F5 0.0287(14) 0.0923(18) 0.0362(12) -0.0024(11) -0.0068(9) 0.0036(12)
F6 0.0320(13) 0.0447(11) 0.0342(11) -0.0083(9) -0.0011(9) -0.0022(9)
F7 0.0448(14) 0.0284(10) 0.0462(11) 0.0060(8) 0.0175(10) 0.0026(9)
F8 0.0460(19) 0.0783(18) 0.116(2) 0.0269(16) 0.0442(17) 0.0153(14)
F9 0.0516(17) 0.0414(13) 0.0827(17) 0.0027(11) 0.0279(13) -0.0087(11)
F10 0.086(2) 0.0847(19) 0.0444(14) 0.0010(13) 0.0191(14) -0.0171(16)
F11 0.0283(14) 0.0850(18) 0.0513(14) 0.0175(12) -0.0055(11) -0.0010(12)
F12 0.0471(17) 0.0355(12) 0.0974(19) 0.0118(12) 0.0270(14) 0.0158(11)
F13 0.0343(13) 0.0383(11) 0.0378(11) -0.0084(8) -0.0027(9) 0.0028(9)
F14 0.0360(13) 0.0325(10) 0.0450(11) 0.0088(9) 0.0069(9) -0.0007(9)
O1 0.0230(14) 0.0353(12) 0.0287(12) 0.0014(9) -0.0021(10) -0.0003(10)
O2 0.0356(16) 0.0384(13) 0.0266(11) 0.0056(10) 0.0041(10) -0.0007(11)
O3 0.0252(14) 0.0415(13) 0.0289(12) -0.0009(10) -0.0037(10) -0.0004(11)
O4 0.0322(15) 0.0354(12) 0.0260(11) 0.0024(9) 0.0050(10) 0.0000(10)
N1 0.0219(16) 0.0279(13) 0.0248(13) -0.0012(10) 0.0029(11) -0.0014(11)
N2 0.0236(17) 0.0290(13) 0.0275(13) 0.0011(11) 0.0029(11) -0.0016(11)
C1 0.032(3) 0.059(3) 0.057(3) -0.002(2) 0.0191(19) -0.001(2)
C2 0.027(2) 0.0394(18) 0.0306(17) 0.0053(14) 0.0011(14) -0.0010(15)
C3 0.0243(19) 0.0295(16) 0.0255(15) 0.0037(12) 0.0004(13) -0.0025(14)
C4 0.0226(19) 0.0292(16) 0.0305(16) -0.0007(13) 0.0014(13) -0.0036(13)
C5 0.027(2) 0.0250(15) 0.0249(15) -0.0031(12) 0.0006(13) 0.0004(13)
C6 0.024(2) 0.0281(16) 0.0244(15) -0.0008(12) 0.0028(13) 0.0021(13)
C7 0.0221(18) 0.0234(15) 0.0241(15) -0.0037(11) 0.0001(12) 0.0046(13)
C8 0.0244(19) 0.0244(15) 0.0244(15) -0.0024(12) 0.0000(13) 0.0021(13)
C9 0.024(2) 0.0240(15) 0.0275(16) -0.0047(12) 0.0004(14) 0.0019(13)
C10 0.027(2) 0.0332(17) 0.0229(15) -0.0001(13) -0.0017(13) 0.0045(14)
C11 0.027(2) 0.0359(17) 0.0217(15) 0.0064(13) 0.0038(13) 0.0050(15)
C12 0.039(3) 0.046(2) 0.055(2) 0.0004(18) 0.014(2) 0.0023(19)
C13 0.025(2) 0.0384(19) 0.046(2) 0.0047(16) 0.0026(16) 0.0041(16)
C14 0.027(2) 0.0281(16) 0.0288(16) 0.0026(13) -0.0017(14) -0.0026(14)
C15 0.023(2) 0.0316(17) 0.0326(17) 0.0066(13) 0.0033(14) -0.0038(14)
C16 0.029(2) 0.0202(14) 0.0272(16) 0.0003(12) 0.0020(13) 0.0001(13)
C17 0.0255(19) 0.0214(14) 0.0237(15) 0.0001(11) -0.0003(13) 0.0002(13)
C18 0.028(2) 0.0189(14) 0.0267(15) 0.0007(12) 0.0022(13) 0.0017(12)
C19 0.028(2) 0.0220(15) 0.0273(16) 0.0019(12) -0.0007(13) -0.0002(13)
C20 0.030(2) 0.0223(15) 0.0274(16) -0.0025(12) 0.0003(14) -0.0023(13)
C21 0.025(2) 0.0320(17) 0.0259(16) -0.0009(13) -0.0037(13) -0.0007(14)
C22 0.029(2) 0.0319(16) 0.0224(15) -0.0015(12) 0.0030(13) 0.0002(14)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
F1 C1 1.319(5) . ?
F2 C1 1.327(5) . ?
F3 C1 1.302(5) . ?
F4 C2 1.346(4) . ?
F5 C2 1.342(4) . ?
F6 C3 1.361(4) . ?
F7 C3 1.359(3) . ?
F8 C12 1.314(5) . ?
F9 C12 1.323(4) . ?
F10 C12 1.326(5) . ?
F11 C13 1.343(4) . ?
F12 C13 1.343(4) . ?
F13 C14 1.366(4) . ?
F14 C14 1.359(3) . ?
O1 C9 1.207(4) . ?
O2 C5 1.221(3) . ?
O3 C20 1.205(4) . ?
O4 C16 1.221(3) . ?
N1 C5 1.394(4) . ?
N1 C9 1.412(4) . ?
N1 C4 1.460(4) . ?
N2 C16 1.401(4) . ?
N2 C20 1.421(4) . ?
N2 C15 1.465(4) . ?
C1 C2 1.536(5) . ?
C2 C3 1.530(5) . ?
C3 C4 1.514(4) . ?
C4 H4B 0.9900 . ?
C4 H4A 0.9900 . ?
C5 C6 1.486(4) . ?
C6 C11 1.369(4) 3_576 ?
C6 C7 1.418(4) . ?
C7 C8 1.412(4) . ?
C7 C7 1.414(6) 3_576 ?
C8 C10 1.376(4) . ?
C8 C9 1.479(5) . ?
C10 C11 1.399(5) . ?
C10 H10 0.9500 . ?
C11 C6 1.369(4) 3_576 ?
C11 H11 0.9500 . ?
C12 C13 1.527(5) . ?
C13 C14 1.536(5) . ?
C14 C15 1.509(4) . ?
C15 H15B 0.9900 . ?
C15 H15A 0.9900 . ?
C16 C17 1.478(5) . ?
C17 C22 1.375(4) 2 ?
C17 C18 1.423(4) . ?
C18 C18 1.403(6) 2 ?
C18 C19 1.417(4) . ?
C19 C21 1.381(4) . ?
C19 C20 1.475(5) . ?
C21 C22 1.397(4) . ?
C21 H21 0.9500 . ?
C22 C17 1.375(4) 2 ?
C22 H22 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C5 N1 C9 125.1(3) . . ?
C5 N1 C4 117.4(2) . . ?
C9 N1 C4 117.0(3) . . ?
C16 N2 C20 124.9(3) . . ?
C16 N2 C15 118.1(3) . . ?
C20 N2 C15 116.9(3) . . ?
F3 C1 F1 109.4(4) . . ?
F3 C1 F2 108.3(4) . . ?
F1 C1 F2 108.3(3) . . ?
F3 C1 C2 110.8(3) . . ?
F1 C1 C2 109.5(3) . . ?
F2 C1 C2 110.5(3) . . ?
F5 C2 F4 107.6(3) . . ?
F5 C2 C3 107.5(3) . . ?
F4 C2 C3 108.1(3) . . ?
F5 C2 C1 108.3(3) . . ?
F4 C2 C1 107.4(3) . . ?
C3 C2 C1 117.7(3) . . ?
F7 C3 F6 106.0(2) . . ?
F7 C3 C4 110.4(2) . . ?
F6 C3 C4 111.2(3) . . ?
F7 C3 C2 107.9(3) . . ?
F6 C3 C2 108.5(3) . . ?
C4 C3 C2 112.6(3) . . ?
N1 C4 C3 110.7(2) . . ?
N1 C4 H4B 109.5 . . ?
C3 C4 H4B 109.5 . . ?
N1 C4 H4A 109.5 . . ?
C3 C4 H4A 109.5 . . ?
H4B C4 H4A 108.1 . . ?
O2 C5 N1 120.8(3) . . ?
O2 C5 C6 122.5(3) . . ?
N1 C5 C6 116.7(3) . . ?
C11 C6 C7 120.3(3) 3_576 . ?
C11 C6 C5 120.0(3) 3_576 . ?
C7 C6 C5 119.7(3) . . ?
C8 C7 C7 119.4(3) . 3_576 ?
C8 C7 C6 121.6(3) . . ?
C7 C7 C6 119.0(3) 3_576 . ?
C10 C8 C7 120.1(3) . . ?
C10 C8 C9 120.4(3) . . ?
C7 C8 C9 119.4(3) . . ?
O1 C9 N1 120.7(3) . . ?
O1 C9 C8 122.4(3) . . ?
N1 C9 C8 116.9(3) . . ?
C8 C10 C11 120.5(3) . . ?
C8 C10 H10 119.7 . . ?
C11 C10 H10 119.7 . . ?
C6 C11 C10 120.6(3) 3_576 . ?
C6 C11 H11 119.7 3_576 . ?
C10 C11 H11 119.7 . . ?
F8 C12 F9 108.3(3) . . ?
F8 C12 F10 109.2(3) . . ?
F9 C12 F10 106.6(3) . . ?
F8 C12 C13 110.5(3) . . ?
F9 C12 C13 110.6(3) . . ?
F10 C12 C13 111.5(3) . . ?
F11 C13 F12 108.9(3) . . ?
F11 C13 C12 107.0(3) . . ?
F12 C13 C12 107.1(3) . . ?
F11 C13 C14 107.6(3) . . ?
F12 C13 C14 108.8(3) . . ?
C12 C13 C14 117.3(3) . . ?
F14 C14 F13 105.7(2) . . ?
F14 C14 C15 110.2(3) . . ?
F13 C14 C15 111.2(3) . . ?
F14 C14 C13 106.4(3) . . ?
F13 C14 C13 107.5(3) . . ?
C15 C14 C13 115.4(3) . . ?
N2 C15 C14 112.3(3) . . ?
N2 C15 H15B 109.1 . . ?
C14 C15 H15B 109.1 . . ?
N2 C15 H15A 109.1 . . ?
C14 C15 H15A 109.1 . . ?
H15B C15 H15A 107.9 . . ?
O4 C16 N2 120.4(3) . . ?
O4 C16 C17 122.7(3) . . ?
N2 C16 C17 116.9(3) . . ?
C22 C17 C18 119.8(3) 2 . ?
C22 C17 C16 120.1(3) 2 . ?
C18 C17 C16 120.1(3) . . ?
C18 C18 C19 119.7(3) 2 . ?
C18 C18 C17 119.2(4) 2 . ?
C19 C18 C17 121.1(3) . . ?
C21 C19 C18 119.9(3) . . ?
C21 C19 C20 120.3(3) . . ?
C18 C19 C20 119.7(3) . . ?
O3 C20 N2 120.4(3) . . ?
O3 C20 C19 122.7(3) . . ?
N2 C20 C19 116.9(3) . . ?
C19 C21 C22 120.3(3) . . ?
C19 C21 H21 119.8 . . ?
C22 C21 H21 119.8 . . ?
C17 C22 C21 120.9(3) 2 . ?
C17 C22 H22 119.5 2 . ?
C21 C22 H22 119.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
F3 C1 C2 F5 66.7(4) . . . . ?
F1 C1 C2 F5 -54.0(4) . . . . ?
F2 C1 C2 F5 -173.2(3) . . . . ?
F3 C1 C2 F4 -177.5(3) . . . . ?
F1 C1 C2 F4 61.8(4) . . . . ?
F2 C1 C2 F4 -57.4(4) . . . . ?
F3 C1 C2 C3 -55.4(5) . . . . ?
F1 C1 C2 C3 -176.1(3) . . . . ?
F2 C1 C2 C3 64.7(4) . . . . ?
F5 C2 C3 F7 -55.7(3) . . . . ?
F4 C2 C3 F7 -171.6(2) . . . . ?
C1 C2 C3 F7 66.7(4) . . . . ?
F5 C2 C3 F6 -170.2(2) . . . . ?
F4 C2 C3 F6 74.0(3) . . . . ?
C1 C2 C3 F6 -47.7(4) . . . . ?
F5 C2 C3 C4 66.4(3) . . . . ?
F4 C2 C3 C4 -49.5(3) . . . . ?
C1 C2 C3 C4 -171.2(3) . . . . ?
C5 N1 C4 C3 -94.2(3) . . . . ?
C9 N1 C4 C3 93.6(3) . . . . ?
F7 C3 C4 N1 -46.0(3) . . . . ?
F6 C3 C4 N1 71.4(3) . . . . ?
C2 C3 C4 N1 -166.7(3) . . . . ?
C9 N1 C5 O2 173.5(3) . . . . ?
C4 N1 C5 O2 2.0(4) . . . . ?
C9 N1 C5 C6 -7.1(4) . . . . ?
C4 N1 C5 C6 -178.6(2) . . . . ?
O2 C5 C6 C11 0.8(5) . . . 3_576 ?
N1 C5 C6 C11 -178.6(3) . . . 3_576 ?
O2 C5 C6 C7 -179.8(3) . . . . ?
N1 C5 C6 C7 0.8(4) . . . . ?
C11 C6 C7 C8 -179.1(3) 3_576 . . . ?
C5 C6 C7 C8 1.5(4) . . . . ?
C11 C6 C7 C7 0.5(5) 3_576 . . 3_576 ?
C5 C6 C7 C7 -178.9(3) . . . 3_576 ?
C7 C7 C8 C10 0.5(5) 3_576 . . . ?
C6 C7 C8 C10 -180.0(3) . . . . ?
C7 C7 C8 C9 -177.6(3) 3_576 . . . ?
C6 C7 C8 C9 1.9(4) . . . . ?
C5 N1 C9 O1 -169.4(3) . . . . ?
C4 N1 C9 O1 2.1(4) . . . . ?
C5 N1 C9 C8 10.4(4) . . . . ?
C4 N1 C9 C8 -178.0(2) . . . . ?
C10 C8 C9 O1 -5.7(5) . . . . ?
C7 C8 C9 O1 172.4(3) . . . . ?
C10 C8 C9 N1 174.4(3) . . . . ?
C7 C8 C9 N1 -7.4(4) . . . . ?
C7 C8 C10 C11 0.4(5) . . . . ?
C9 C8 C10 C11 178.5(3) . . . . ?
C8 C10 C11 C6 -1.3(5) . . . 3_576 ?
F8 C12 C13 F11 62.0(4) . . . . ?
F9 C12 C13 F11 -57.9(4) . . . . ?
F10 C12 C13 F11 -176.4(3) . . . . ?
F8 C12 C13 F12 -54.6(4) . . . . ?
F9 C12 C13 F12 -174.5(3) . . . . ?
F10 C12 C13 F12 67.0(4) . . . . ?
F8 C12 C13 C14 -177.1(3) . . . . ?
F9 C12 C13 C14 63.0(5) . . . . ?
F10 C12 C13 C14 -55.5(4) . . . . ?
F11 C13 C14 F14 -61.2(3) . . . . ?
F12 C13 C14 F14 56.6(3) . . . . ?
C12 C13 C14 F14 178.2(3) . . . . ?
F11 C13 C14 F13 -174.1(2) . . . . ?
F12 C13 C14 F13 -56.3(3) . . . . ?
C12 C13 C14 F13 65.4(4) . . . . ?
F11 C13 C14 C15 61.3(4) . . . . ?
F12 C13 C14 C15 179.1(3) . . . . ?
C12 C13 C14 C15 -59.3(4) . . . . ?
C16 N2 C15 C14 -85.8(3) . . . . ?
C20 N2 C15 C14 95.9(3) . . . . ?
F14 C14 C15 N2 -46.3(4) . . . . ?
F13 C14 C15 N2 70.6(3) . . . . ?
C13 C14 C15 N2 -166.7(3) . . . . ?
C20 N2 C16 O4 178.2(3) . . . . ?
C15 N2 C16 O4 0.1(4) . . . . ?
C20 N2 C16 C17 -1.8(4) . . . . ?
C15 N2 C16 C17 -179.9(3) . . . . ?
O4 C16 C17 C22 4.3(4) . . . 2 ?
N2 C16 C17 C22 -175.7(3) . . . 2 ?
O4 C16 C17 C18 -176.9(3) . . . . ?
N2 C16 C17 C18 3.1(4) . . . . ?
C22 C17 C18 C18 1.1(3) 2 . . 2 ?
C16 C17 C18 C18 -177.76(19) . . . 2 ?
C22 C17 C18 C19 179.7(3) 2 . . . ?
C16 C17 C18 C19 0.9(4) . . . . ?
C18 C18 C19 C21 -4.0(3) 2 . . . ?
C17 C18 C19 C21 177.4(3) . . . . ?
C18 C18 C19 C20 172.52(19) 2 . . . ?
C17 C18 C19 C20 -6.1(4) . . . . ?
C16 N2 C20 O3 176.6(3) . . . . ?
C15 N2 C20 O3 -5.3(4) . . . . ?
C16 N2 C20 C19 -3.2(4) . . . . ?
C15 N2 C20 C19 174.9(3) . . . . ?
C21 C19 C20 O3 3.8(5) . . . . ?
C18 C19 C20 O3 -172.6(3) . . . . ?
C21 C19 C20 N2 -176.3(3) . . . . ?
C18 C19 C20 N2 7.2(4) . . . . ?
C18 C19 C21 C22 1.9(5) . . . . ?
C20 C19 C21 C22 -174.6(3) . . . . ?
C19 C21 C22 C17 1.7(5) . . . 2 ?

_diffrn_measured_fraction_theta_max 0.996
_diffrn_reflns_theta_full        27.51
_diffrn_measured_fraction_theta_full 0.996
_refine_diff_density_max         0.423
_refine_diff_density_min         -0.357
_refine_diff_density_rms         0.071