# Electronic Supplementary Material (ESI) for Chemical Communications.
# This journal is © The Royal Society of Chemistry 2014

#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
#  on your local computer system.
# 
#  For further information on the CCDC, data deposition and
#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
#
data_shelxl

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C32 H35 Dy N4 O14 Zn'
_chemical_formula_weight         927.51

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.132(5)
_cell_length_b                   12.522(6)
_cell_length_c                   13.219(6)
_cell_angle_alpha                105.8880(10)
_cell_angle_beta                 91.753(5)
_cell_angle_gamma                94.464(6)
_cell_volume                     1764.3(14)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    3658
_cell_measurement_theta_min      3.1
_cell_measurement_theta_max      29.2

_exptl_crystal_description       Prism
_exptl_crystal_colour            'Pale Yellow'
_exptl_crystal_size_max          0.41
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.07
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.746
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             926
_exptl_absorpt_coefficient_mu    2.855
_exptl_absorpt_correction_type   Numerical
_exptl_absorpt_correction_T_min  0.3873
_exptl_absorpt_correction_T_max  0.8252
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71075
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  
;
Rigaku Saturn724+ (4x4 bin mode)
;
_diffrn_measurement_method       'profile data from ω-scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            29756
_diffrn_reflns_av_R_equivalents  0.0361
_diffrn_reflns_av_sigmaI/netI    0.0340
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         3.08
_diffrn_reflns_theta_max         29.17
_reflns_number_total             9054
_reflns_number_gt                8566
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       
;
CrystalClear-SM Expert 2.1 b24 (Rigaku, 2012)
;
_computing_cell_refinement       
;
CrystalClear-SM Expert 2.1 b24 (Rigaku, 2012)
;
_computing_data_reduction        
;
CrystalClear-SM Expert 2.1 b24 (Rigaku, 2012)
;
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0397P)²+5.3666P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         9054
_refine_ls_number_parameters     471
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0378
_refine_ls_R_factor_gt           0.0355
_refine_ls_wR_factor_ref         0.0908
_refine_ls_wR_factor_gt          0.0892
_refine_ls_goodness_of_fit_ref   1.056
_refine_ls_restrained_S_all      1.056
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Zn2 Zn 0.49521(3) 0.19007(3) 0.29115(3) 0.01618(8) Uani 1 1 d . . .
Dy1 Dy 0.282025(13) 0.304222(13) 0.170282(11) 0.01723(6) Uani 1 1 d . . .
O1S O 0.8511(3) 0.3574(3) 0.1638(2) 0.0465(9) Uani 1 1 d . . .
O2S O 0.9306(4) 0.2760(3) -0.1910(3) 0.0584(10) Uani 1 1 d . . .
O11 O 0.4549(2) 0.2135(2) 0.15002(18) 0.0188(5) Uani 1 1 d . . .
O12 O 0.3995(2) 0.3085(2) 0.00757(18) 0.0201(5) Uani 1 1 d . . .
O31 O 0.3987(2) 0.3328(2) 0.32317(18) 0.0186(4) Uani 1 1 d . . .
O32 O 0.1922(2) 0.4157(2) 0.3319(2) 0.0226(5) Uani 1 1 d . . .
O51 O 0.2111(2) 0.1609(2) 0.2395(2) 0.0230(5) Uani 1 1 d . . .
O52 O 0.3544(2) 0.1021(2) 0.32849(18) 0.0193(5) Uani 1 1 d . . .
O61 O 0.2141(2) 0.4707(2) 0.1284(2) 0.0265(5) Uani 1 1 d . . .
O62 O 0.3916(2) 0.4955(2) 0.2071(2) 0.0295(6) Uani 1 1 d . . .
O63 O 0.2965(3) 0.6404(3) 0.2060(3) 0.0432(8) Uani 1 1 d . . .
O71 O 0.1942(2) 0.1608(2) 0.0186(2) 0.0260(5) Uani 1 1 d . . .
O72 O 0.0722(2) 0.2717(2) 0.1153(2) 0.0250(5) Uani 1 1 d . . .
O73 O -0.0197(4) 0.1258(5) -0.0302(4) 0.0828(15) Uani 1 1 d . . .
N11 N 0.6069(2) 0.0673(2) 0.2183(2) 0.0168(5) Uani 1 1 d . . .
N31 N 0.5951(2) 0.2728(2) 0.4288(2) 0.0180(5) Uani 1 1 d . . .
N61 N 0.3018(3) 0.5382(3) 0.1805(3) 0.0272(6) Uani 1 1 d . . .
N71 N 0.0880(3) 0.1885(3) 0.0379(3) 0.0357(8) Uani 1 1 d . . .
C1S C 0.7853(4) 0.3743(3) 0.0792(3) 0.0291(8) Uani 1 1 d . . .
H1S1 H 0.7085 0.4029 0.1030 0.044 Uiso 1 1 calc R . .
H1S2 H 0.7695 0.3034 0.0242 0.044 Uiso 1 1 calc R . .
H1S3 H 0.8315 0.4283 0.0508 0.044 Uiso 1 1 calc R . .
C2S C 1.0281(5) 0.3578(5) -0.1474(5) 0.0573(14) Uani 1 1 d . . .
H2S1 H 0.9965 0.4253 -0.1039 0.086 Uiso 1 1 calc R . .
H2S2 H 1.0724 0.3758 -0.2044 0.086 Uiso 1 1 calc R . .
H2S3 H 1.0825 0.3287 -0.1037 0.086 Uiso 1 1 calc R . .
C11 C 0.6007(3) 0.1063(3) 0.0457(2) 0.0166(6) Uani 1 1 d . . .
C12 C 0.6550(3) 0.0776(3) -0.0528(2) 0.0186(6) Uani 1 1 d . . .
H12A H 0.7126 0.0239 -0.0655 0.022 Uiso 1 1 calc R . .
C13 C 0.6250(3) 0.1271(3) -0.1299(3) 0.0208(6) Uani 1 1 d . . .
H13A H 0.6631 0.1081 -0.1950 0.025 Uiso 1 1 calc R . .
C14 C 0.5393(3) 0.2051(3) -0.1136(3) 0.0205(6) Uani 1 1 d . . .
H14A H 0.5188 0.2389 -0.1672 0.025 Uiso 1 1 calc R . .
C15 C 0.4851(3) 0.2320(3) -0.0192(2) 0.0176(6) Uani 1 1 d . . .
C16 C 0.5136(3) 0.1831(3) 0.0623(2) 0.0155(6) Uani 1 1 d . . .
C17 C 0.6358(3) 0.0486(3) 0.1212(3) 0.0171(6) Uani 1 1 d . . .
H17A H 0.6861 -0.0100 0.0968 0.021 Uiso 1 1 calc R . .
C18 C 0.6535(3) -0.0027(3) 0.2772(3) 0.0179(6) Uani 1 1 d . . .
C19 C 0.5811(3) -0.0332(3) 0.3506(3) 0.0210(6) Uani 1 1 d . . .
H19A H 0.5041 -0.0058 0.3626 0.025 Uiso 1 1 calc R . .
C20 C 0.6222(3) -0.1042(3) 0.4062(3) 0.0248(7) Uani 1 1 d . . .
H20A H 0.5722 -0.1262 0.4553 0.030 Uiso 1 1 calc R . .
C21 C 0.7347(3) -0.1429(3) 0.3907(3) 0.0273(8) Uani 1 1 d . . .
H21A H 0.7617 -0.1920 0.4283 0.033 Uiso 1 1 calc R . .
C22 C 0.8084(3) -0.1098(3) 0.3199(3) 0.0274(8) Uani 1 1 d . . .
H22A H 0.8863 -0.1356 0.3098 0.033 Uiso 1 1 calc R . .
C23 C 0.7688(3) -0.0390(3) 0.2635(3) 0.0227(7) Uani 1 1 d . . .
H23A H 0.8201 -0.0156 0.2160 0.027 Uiso 1 1 calc R . .
C24 C 0.3618(4) 0.3556(4) -0.0745(3) 0.0315(9) Uani 1 1 d . . .
H24A H 0.4226 0.3465 -0.1276 0.047 Uiso 1 1 calc R . .
H24B H 0.3527 0.4351 -0.0445 0.047 Uiso 1 1 calc R . .
H24C H 0.2844 0.3173 -0.1075 0.047 Uiso 1 1 calc R . .
C31 C 0.4276(3) 0.3750(3) 0.5107(3) 0.0195(6) Uani 1 1 d . . .
C32 C 0.3817(3) 0.4247(3) 0.6100(3) 0.0237(7) Uani 1 1 d . . .
H32A H 0.4283 0.4290 0.6727 0.028 Uiso 1 1 calc R . .
C33 C 0.2710(4) 0.4666(3) 0.6169(3) 0.0275(7) Uani 1 1 d . . .
H33A H 0.2400 0.4970 0.6839 0.033 Uiso 1 1 calc R . .
C34 C 0.2040(3) 0.4643(3) 0.5253(3) 0.0256(7) Uani 1 1 d . . .
H34A H 0.1274 0.4932 0.5300 0.031 Uiso 1 1 calc R . .
C35 C 0.2487(3) 0.4202(3) 0.4285(3) 0.0206(6) Uani 1 1 d . . .
C36 C 0.3612(3) 0.3729(3) 0.4179(3) 0.0179(6) Uani 1 1 d . . .
C37 C 0.5473(3) 0.3364(3) 0.5087(3) 0.0201(6) Uani 1 1 d . . .
H37A H 0.5955 0.3603 0.5727 0.024 Uiso 1 1 calc R . .
C38 C 0.7179(3) 0.2508(3) 0.4430(3) 0.0203(6) Uani 1 1 d . . .
C39 C 0.7949(3) 0.2551(3) 0.3628(3) 0.0213(6) Uani 1 1 d . . .
H39A H 0.7653 0.2709 0.3008 0.026 Uiso 1 1 calc R . .
C40 C 0.9164(3) 0.2360(3) 0.3742(3) 0.0290(8) Uani 1 1 d . . .
H40A H 0.9692 0.2376 0.3194 0.035 Uiso 1 1 calc R . .
C41 C 0.9587(4) 0.2150(3) 0.4650(4) 0.0324(9) Uani 1 1 d . . .
H41A H 1.0416 0.2043 0.4736 0.039 Uiso 1 1 calc R . .
C42 C 0.8820(4) 0.2092(3) 0.5442(3) 0.0321(8) Uani 1 1 d . . .
H42A H 0.9126 0.1940 0.6062 0.039 Uiso 1 1 calc R . .
C43 C 0.7597(3) 0.2255(3) 0.5337(3) 0.0260(7) Uani 1 1 d . . .
H43A H 0.7065 0.2195 0.5871 0.031 Uiso 1 1 calc R . .
C44 C 0.0848(3) 0.4739(3) 0.3354(3) 0.0264(7) Uani 1 1 d . . .
H44A H 0.0698 0.5110 0.4089 0.040 Uiso 1 1 calc R . .
H44B H 0.0157 0.4206 0.3036 0.040 Uiso 1 1 calc R . .
H44C H 0.0959 0.5298 0.2963 0.040 Uiso 1 1 calc R . .
C51 C 0.2468(3) 0.1011(3) 0.2952(2) 0.0184(6) Uani 1 1 d . . .
C52 C 0.1549(3) 0.0188(3) 0.3216(3) 0.0234(7) Uani 1 1 d . . .
H52A H 0.0752 0.0259 0.2919 0.035 Uiso 1 1 calc R . .
H52B H 0.1525 0.0343 0.3983 0.035 Uiso 1 1 calc R . .
H52C H 0.1776 -0.0571 0.2918 0.035 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Zn2 O52 1.998(2) . ?
Zn2 O11 2.009(2) . ?
Zn2 N31 2.070(3) . ?
Zn2 N11 2.096(3) . ?
Zn2 O31 2.107(2) . ?
Zn2 Dy1 3.4314(10) . ?
Dy1 O31 2.296(2) . ?
Dy1 O11 2.297(2) . ?
Dy1 O51 2.325(3) . ?
Dy1 O72 2.395(3) . ?
Dy1 O71 2.416(3) . ?
Dy1 O61 2.465(3) . ?
Dy1 O32 2.496(3) . ?
Dy1 O62 2.517(3) . ?
Dy1 O12 2.562(2) . ?
Dy1 N71 2.779(4) . ?
Dy1 N61 2.887(3) . ?
O1S C1S 1.391(5) . ?
O2S C2S 1.423(7) . ?
O11 C16 1.327(4) . ?
O12 C15 1.389(4) . ?
O12 C24 1.436(4) . ?
O31 C36 1.310(4) . ?
O32 C35 1.391(4) . ?
O32 C44 1.444(4) . ?
O51 C51 1.261(4) . ?
O52 C51 1.262(4) . ?
O61 N61 1.286(4) . ?
O62 N61 1.253(4) . ?
O63 N61 1.237(5) . ?
O71 N71 1.272(4) . ?
O72 N71 1.273(5) . ?
O73 N71 1.504(6) . ?
N11 C17 1.296(4) . ?
N11 C18 1.437(4) . ?
N31 C37 1.293(5) . ?
N31 C38 1.433(4) . ?
C1S H1S1 0.9800 . ?
C1S H1S2 0.9800 . ?
C1S H1S3 0.9800 . ?
C2S H2S1 0.9800 . ?
C2S H2S2 0.9800 . ?
C2S H2S3 0.9800 . ?
C11 C16 1.398(4) . ?
C11 C12 1.419(4) . ?
C11 C17 1.444(4) . ?
C12 C13 1.376(4) . ?
C12 H12A 0.9500 . ?
C13 C14 1.397(5) . ?
C13 H13A 0.9500 . ?
C14 C15 1.372(5) . ?
C14 H14A 0.9500 . ?
C15 C16 1.417(4) . ?
C17 H17A 0.9500 . ?
C18 C19 1.393(5) . ?
C18 C23 1.395(5) . ?
C19 C20 1.393(4) . ?
C19 H19A 0.9500 . ?
C20 C21 1.379(5) . ?
C20 H20A 0.9500 . ?
C21 C22 1.388(6) . ?
C21 H21A 0.9500 . ?
C22 C23 1.391(5) . ?
C22 H22A 0.9500 . ?
C23 H23A 0.9500 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C31 C36 1.405(4) . ?
C31 C32 1.420(5) . ?
C31 C37 1.451(5) . ?
C32 C33 1.373(5) . ?
C32 H32A 0.9500 . ?
C33 C34 1.394(5) . ?
C33 H33A 0.9500 . ?
C34 C35 1.373(5) . ?
C34 H34A 0.9500 . ?
C35 C36 1.421(5) . ?
C37 H37A 0.9500 . ?
C38 C39 1.393(5) . ?
C38 C43 1.397(5) . ?
C39 C40 1.402(5) . ?
C39 H39A 0.9500 . ?
C40 C41 1.375(6) . ?
C40 H40A 0.9500 . ?
C41 C42 1.384(7) . ?
C41 H41A 0.9500 . ?
C42 C43 1.401(5) . ?
C42 H42A 0.9500 . ?
C43 H43A 0.9500 . ?
C44 H44A 0.9800 . ?
C44 H44B 0.9800 . ?
C44 H44C 0.9800 . ?
C51 C52 1.511(5) . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O52 Zn2 O11 107.83(10) . . ?
O52 Zn2 N31 108.09(10) . . ?
O11 Zn2 N31 138.35(11) . . ?
O52 Zn2 N11 103.22(11) . . ?
O11 Zn2 N11 89.22(10) . . ?
N31 Zn2 N11 102.35(11) . . ?
O52 Zn2 O31 90.39(10) . . ?
O11 Zn2 O31 74.58(9) . . ?
N31 Zn2 O31 84.80(10) . . ?
N11 Zn2 O31 161.53(10) . . ?
O52 Zn2 Dy1 84.89(7) . . ?
O11 Zn2 Dy1 40.17(6) . . ?
N31 Zn2 Dy1 124.95(8) . . ?
N11 Zn2 Dy1 127.06(8) . . ?
O31 Zn2 Dy1 40.82(6) . . ?
O31 Dy1 O11 65.81(8) . . ?
O31 Dy1 O51 75.89(9) . . ?
O11 Dy1 O51 83.90(9) . . ?
O31 Dy1 O72 137.79(9) . . ?
O11 Dy1 O72 140.05(9) . . ?
O51 Dy1 O72 75.95(9) . . ?
O31 Dy1 O71 142.93(9) . . ?
O11 Dy1 O71 87.59(9) . . ?
O51 Dy1 O71 76.02(10) . . ?
O72 Dy1 O71 54.40(9) . . ?
O31 Dy1 O61 117.07(9) . . ?
O11 Dy1 O61 135.66(8) . . ?
O51 Dy1 O61 140.40(9) . . ?
O72 Dy1 O61 70.50(9) . . ?
O71 Dy1 O61 99.98(10) . . ?
O31 Dy1 O32 65.23(8) . . ?
O11 Dy1 O32 130.84(8) . . ?
O51 Dy1 O32 80.41(9) . . ?
O72 Dy1 O32 79.55(9) . . ?
O71 Dy1 O32 131.91(9) . . ?
O61 Dy1 O32 73.46(9) . . ?
O31 Dy1 O62 73.09(9) . . ?
O11 Dy1 O62 94.45(10) . . ?
O51 Dy1 O62 146.56(9) . . ?
O72 Dy1 O62 121.07(9) . . ?
O71 Dy1 O62 137.38(9) . . ?
O61 Dy1 O62 51.48(9) . . ?
O32 Dy1 O62 75.56(9) . . ?
O31 Dy1 O12 115.00(8) . . ?
O11 Dy1 O12 63.65(7) . . ?
O51 Dy1 O12 133.11(9) . . ?
O72 Dy1 O12 107.21(9) . . ?
O71 Dy1 O12 70.04(9) . . ?
O61 Dy1 O12 77.99(8) . . ?
O32 Dy1 O12 146.43(8) . . ?
O62 Dy1 O12 72.94(9) . . ?
O31 Dy1 N71 149.18(10) . . ?
O11 Dy1 N71 113.86(11) . . ?
O51 Dy1 N71 73.50(10) . . ?
O72 Dy1 N71 27.21(10) . . ?
O71 Dy1 N71 27.20(10) . . ?
O61 Dy1 N71 85.41(10) . . ?
O32 Dy1 N71 105.70(10) . . ?
O62 Dy1 N71 135.39(10) . . ?
O12 Dy1 N71 89.03(10) . . ?
O31 Dy1 N61 93.01(9) . . ?
O11 Dy1 N61 117.98(9) . . ?
O51 Dy1 N61 149.27(9) . . ?
O72 Dy1 N61 95.43(9) . . ?
O71 Dy1 N61 123.05(9) . . ?
O61 Dy1 N61 26.34(9) . . ?
O32 Dy1 N61 68.96(9) . . ?
O62 Dy1 N61 25.67(9) . . ?
O12 Dy1 N61 77.60(8) . . ?
N71 Dy1 N61 111.68(10) . . ?
O31 Dy1 Zn2 36.86(6) . . ?
O11 Dy1 Zn2 34.34(6) . . ?
O51 Dy1 Zn2 63.87(6) . . ?
O72 Dy1 Zn2 139.47(7) . . ?
O71 Dy1 Zn2 107.84(7) . . ?
O61 Dy1 Zn2 148.08(6) . . ?
O32 Dy1 Zn2 98.08(6) . . ?
O62 Dy1 Zn2 96.73(7) . . ?
O12 Dy1 Zn2 96.85(6) . . ?
N71 Dy1 Zn2 126.28(8) . . ?
N61 Dy1 Zn2 121.77(7) . . ?
C16 O11 Zn2 128.29(19) . . ?
C16 O11 Dy1 126.22(18) . . ?
Zn2 O11 Dy1 105.49(10) . . ?
C15 O12 C24 115.4(3) . . ?
C15 O12 Dy1 116.17(18) . . ?
C24 O12 Dy1 125.6(2) . . ?
C36 O31 Zn2 119.3(2) . . ?
C36 O31 Dy1 124.6(2) . . ?
Zn2 O31 Dy1 102.32(10) . . ?
C35 O32 C44 116.4(3) . . ?
C35 O32 Dy1 117.25(19) . . ?
C44 O32 Dy1 126.3(2) . . ?
C51 O51 Dy1 140.7(2) . . ?
C51 O52 Zn2 124.7(2) . . ?
N61 O61 Dy1 95.4(2) . . ?
N61 O62 Dy1 93.9(2) . . ?
N71 O71 Dy1 92.5(2) . . ?
N71 O72 Dy1 93.4(2) . . ?
C17 N11 C18 116.8(3) . . ?
C17 N11 Zn2 123.9(2) . . ?
C18 N11 Zn2 119.3(2) . . ?
C37 N31 C38 117.2(3) . . ?
C37 N31 Zn2 122.2(2) . . ?
C38 N31 Zn2 120.2(2) . . ?
O63 N61 O62 121.5(4) . . ?
O63 N61 O61 121.6(3) . . ?
O62 N61 O61 116.9(3) . . ?
O63 N61 Dy1 165.2(3) . . ?
O62 N61 Dy1 60.44(18) . . ?
O61 N61 Dy1 58.24(16) . . ?
O71 N71 O72 119.6(3) . . ?
O71 N71 O73 121.2(4) . . ?
O72 N71 O73 119.2(4) . . ?
O71 N71 Dy1 60.31(19) . . ?
O72 N71 Dy1 59.36(18) . . ?
O73 N71 Dy1 177.8(3) . . ?
O1S C1S H1S1 109.5 . . ?
O1S C1S H1S2 109.5 . . ?
H1S1 C1S H1S2 109.5 . . ?
O1S C1S H1S3 109.5 . . ?
H1S1 C1S H1S3 109.5 . . ?
H1S2 C1S H1S3 109.5 . . ?
O2S C2S H2S1 109.5 . . ?
O2S C2S H2S2 109.5 . . ?
H2S1 C2S H2S2 109.5 . . ?
O2S C2S H2S3 109.5 . . ?
H2S1 C2S H2S3 109.5 . . ?
H2S2 C2S H2S3 109.5 . . ?
C16 C11 C12 119.2(3) . . ?
C16 C11 C17 124.0(3) . . ?
C12 C11 C17 116.7(3) . . ?
C13 C12 C11 120.5(3) . . ?
C13 C12 H12A 119.8 . . ?
C11 C12 H12A 119.8 . . ?
C12 C13 C14 120.8(3) . . ?
C12 C13 H13A 119.6 . . ?
C14 C13 H13A 119.6 . . ?
C15 C14 C13 119.1(3) . . ?
C15 C14 H14A 120.4 . . ?
C13 C14 H14A 120.4 . . ?
C14 C15 O12 125.0(3) . . ?
C14 C15 C16 121.8(3) . . ?
O12 C15 C16 113.1(3) . . ?
O11 C16 C11 124.2(3) . . ?
O11 C16 C15 117.2(3) . . ?
C11 C16 C15 118.6(3) . . ?
N11 C17 C11 127.8(3) . . ?
N11 C17 H17A 116.1 . . ?
C11 C17 H17A 116.1 . . ?
C19 C18 C23 119.9(3) . . ?
C19 C18 N11 118.3(3) . . ?
C23 C18 N11 121.8(3) . . ?
C20 C19 C18 119.6(3) . . ?
C20 C19 H19A 120.2 . . ?
C18 C19 H19A 120.2 . . ?
C21 C20 C19 120.6(3) . . ?
C21 C20 H20A 119.7 . . ?
C19 C20 H20A 119.7 . . ?
C20 C21 C22 119.7(3) . . ?
C20 C21 H21A 120.2 . . ?
C22 C21 H21A 120.2 . . ?
C21 C22 C23 120.5(3) . . ?
C21 C22 H22A 119.8 . . ?
C23 C22 H22A 119.8 . . ?
C22 C23 C18 119.6(3) . . ?
C22 C23 H23A 120.2 . . ?
C18 C23 H23A 120.2 . . ?
O12 C24 H24A 109.5 . . ?
O12 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
O12 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C36 C31 C32 119.6(3) . . ?
C36 C31 C37 121.9(3) . . ?
C32 C31 C37 118.2(3) . . ?
C33 C32 C31 120.9(3) . . ?
C33 C32 H32A 119.5 . . ?
C31 C32 H32A 119.5 . . ?
C32 C33 C34 119.9(3) . . ?
C32 C33 H33A 120.1 . . ?
C34 C33 H33A 120.1 . . ?
C35 C34 C33 120.1(3) . . ?
C35 C34 H34A 119.9 . . ?
C33 C34 H34A 119.9 . . ?
C34 C35 O32 125.5(3) . . ?
C34 C35 C36 121.8(3) . . ?
O32 C35 C36 112.7(3) . . ?
O31 C36 C31 123.7(3) . . ?
O31 C36 C35 118.6(3) . . ?
C31 C36 C35 117.6(3) . . ?
N31 C37 C31 126.7(3) . . ?
N31 C37 H37A 116.6 . . ?
C31 C37 H37A 116.6 . . ?
C39 C38 C43 120.8(3) . . ?
C39 C38 N31 117.7(3) . . ?
C43 C38 N31 121.5(3) . . ?
C38 C39 C40 119.6(3) . . ?
C38 C39 H39A 120.2 . . ?
C40 C39 H39A 120.2 . . ?
C41 C40 C39 119.7(4) . . ?
C41 C40 H40A 120.1 . . ?
C39 C40 H40A 120.1 . . ?
C40 C41 C42 120.8(4) . . ?
C40 C41 H41A 119.6 . . ?
C42 C41 H41A 119.6 . . ?
C41 C42 C43 120.6(4) . . ?
C41 C42 H42A 119.7 . . ?
C43 C42 H42A 119.7 . . ?
C38 C43 C42 118.5(4) . . ?
C38 C43 H43A 120.8 . . ?
C42 C43 H43A 120.8 . . ?
O32 C44 H44A 109.5 . . ?
O32 C44 H44B 109.5 . . ?
H44A C44 H44B 109.5 . . ?
O32 C44 H44C 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
O51 C51 O52 125.1(3) . . ?
O51 C51 C52 117.9(3) . . ?
O52 C51 C52 116.9(3) . . ?
C51 C52 H52A 109.5 . . ?
C51 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
C51 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O52 Zn2 Dy1 O31 96.54(12) . . . . ?
O11 Zn2 Dy1 O31 -137.82(15) . . . . ?
N31 Zn2 Dy1 O31 -11.99(13) . . . . ?
N11 Zn2 Dy1 O31 -160.73(14) . . . . ?
O52 Zn2 Dy1 O11 -125.63(13) . . . . ?
N31 Zn2 Dy1 O11 125.83(15) . . . . ?
N11 Zn2 Dy1 O11 -22.90(15) . . . . ?
O31 Zn2 Dy1 O11 137.82(15) . . . . ?
O52 Zn2 Dy1 O51 -5.08(10) . . . . ?
O11 Zn2 Dy1 O51 120.55(14) . . . . ?
N31 Zn2 Dy1 O51 -113.62(12) . . . . ?
N11 Zn2 Dy1 O51 97.65(12) . . . . ?
O31 Zn2 Dy1 O51 -101.62(12) . . . . ?
O52 Zn2 Dy1 O72 -13.33(12) . . . . ?
O11 Zn2 Dy1 O72 112.30(15) . . . . ?
N31 Zn2 Dy1 O72 -121.87(14) . . . . ?
N11 Zn2 Dy1 O72 89.39(14) . . . . ?
O31 Zn2 Dy1 O72 -109.88(14) . . . . ?
O52 Zn2 Dy1 O71 -68.95(10) . . . . ?
O11 Zn2 Dy1 O71 56.68(13) . . . . ?
N31 Zn2 Dy1 O71 -177.49(11) . . . . ?
N11 Zn2 Dy1 O71 33.78(12) . . . . ?
O31 Zn2 Dy1 O71 -165.49(12) . . . . ?
O52 Zn2 Dy1 O61 141.61(14) . . . . ?
O11 Zn2 Dy1 O61 -92.76(16) . . . . ?
N31 Zn2 Dy1 O61 33.07(15) . . . . ?
N11 Zn2 Dy1 O61 -115.66(15) . . . . ?
O31 Zn2 Dy1 O61 45.07(15) . . . . ?
O52 Zn2 Dy1 O32 70.03(10) . . . . ?
O11 Zn2 Dy1 O32 -164.34(13) . . . . ?
N31 Zn2 Dy1 O32 -38.51(11) . . . . ?
N11 Zn2 Dy1 O32 172.75(11) . . . . ?
O31 Zn2 Dy1 O32 -26.52(11) . . . . ?
O52 Zn2 Dy1 O62 146.33(10) . . . . ?
O11 Zn2 Dy1 O62 -88.04(13) . . . . ?
N31 Zn2 Dy1 O62 37.79(11) . . . . ?
N11 Zn2 Dy1 O62 -110.95(12) . . . . ?
O31 Zn2 Dy1 O62 49.78(12) . . . . ?
O52 Zn2 Dy1 O12 -140.13(9) . . . . ?
O11 Zn2 Dy1 O12 -14.50(13) . . . . ?
N31 Zn2 Dy1 O12 111.33(11) . . . . ?
N11 Zn2 Dy1 O12 -37.40(11) . . . . ?
O31 Zn2 Dy1 O12 123.32(11) . . . . ?
O52 Zn2 Dy1 N71 -46.28(12) . . . . ?
O11 Zn2 Dy1 N71 79.35(15) . . . . ?
N31 Zn2 Dy1 N71 -154.82(13) . . . . ?
N11 Zn2 Dy1 N71 56.44(14) . . . . ?
O31 Zn2 Dy1 N71 -142.83(14) . . . . ?
O52 Zn2 Dy1 N61 140.24(10) . . . . ?
O11 Zn2 Dy1 N61 -94.13(14) . . . . ?
N31 Zn2 Dy1 N61 31.70(12) . . . . ?
N11 Zn2 Dy1 N61 -117.03(12) . . . . ?
O31 Zn2 Dy1 N61 43.70(12) . . . . ?
O52 Zn2 O11 C16 -121.3(3) . . . . ?
N31 Zn2 O11 C16 90.2(3) . . . . ?
N11 Zn2 O11 C16 -17.6(3) . . . . ?
O31 Zn2 O11 C16 153.4(3) . . . . ?
Dy1 Zn2 O11 C16 -179.5(3) . . . . ?
O52 Zn2 O11 Dy1 58.26(13) . . . . ?
N31 Zn2 O11 Dy1 -90.24(16) . . . . ?
N11 Zn2 O11 Dy1 161.90(11) . . . . ?
O31 Zn2 O11 Dy1 -27.08(10) . . . . ?
O31 Dy1 O11 C16 -154.2(3) . . . . ?
O51 Dy1 O11 C16 128.5(3) . . . . ?
O72 Dy1 O11 C16 69.0(3) . . . . ?
O71 Dy1 O11 C16 52.3(3) . . . . ?
O61 Dy1 O11 C16 -49.5(3) . . . . ?
O32 Dy1 O11 C16 -159.8(2) . . . . ?
O62 Dy1 O11 C16 -85.0(3) . . . . ?
O12 Dy1 O11 C16 -16.6(2) . . . . ?
N71 Dy1 O11 C16 59.6(3) . . . . ?
N61 Dy1 O11 C16 -74.2(3) . . . . ?
Zn2 Dy1 O11 C16 179.6(3) . . . . ?
O31 Dy1 O11 Zn2 26.20(10) . . . . ?
O51 Dy1 O11 Zn2 -51.04(11) . . . . ?
O72 Dy1 O11 Zn2 -110.53(14) . . . . ?
O71 Dy1 O11 Zn2 -127.23(12) . . . . ?
O61 Dy1 O11 Zn2 130.93(11) . . . . ?
O32 Dy1 O11 Zn2 20.68(16) . . . . ?
O62 Dy1 O11 Zn2 95.42(11) . . . . ?
O12 Dy1 O11 Zn2 163.89(14) . . . . ?
N71 Dy1 O11 Zn2 -119.97(12) . . . . ?
N61 Dy1 O11 Zn2 106.21(11) . . . . ?
O31 Dy1 O12 C15 58.3(2) . . . . ?
O11 Dy1 O12 C15 15.6(2) . . . . ?
O51 Dy1 O12 C15 -35.6(3) . . . . ?
O72 Dy1 O12 C15 -122.3(2) . . . . ?
O71 Dy1 O12 C15 -81.8(2) . . . . ?
O61 Dy1 O12 C15 172.8(2) . . . . ?
O32 Dy1 O12 C15 140.6(2) . . . . ?
O62 Dy1 O12 C15 119.7(2) . . . . ?
N71 Dy1 O12 C15 -101.7(2) . . . . ?
N61 Dy1 O12 C15 145.8(2) . . . . ?
Zn2 Dy1 O12 C15 24.7(2) . . . . ?
O31 Dy1 O12 C24 -142.0(3) . . . . ?
O11 Dy1 O12 C24 175.4(3) . . . . ?
O51 Dy1 O12 C24 124.1(3) . . . . ?
O72 Dy1 O12 C24 37.4(3) . . . . ?
O71 Dy1 O12 C24 77.9(3) . . . . ?
O61 Dy1 O12 C24 -27.5(3) . . . . ?
O32 Dy1 O12 C24 -59.7(3) . . . . ?
O62 Dy1 O12 C24 -80.6(3) . . . . ?
N71 Dy1 O12 C24 58.0(3) . . . . ?
N61 Dy1 O12 C24 -54.5(3) . . . . ?
Zn2 Dy1 O12 C24 -175.6(3) . . . . ?
O52 Zn2 O31 C36 60.3(2) . . . . ?
O11 Zn2 O31 C36 168.7(2) . . . . ?
N31 Zn2 O31 C36 -47.8(2) . . . . ?
N11 Zn2 O31 C36 -161.7(3) . . . . ?
Dy1 Zn2 O31 C36 142.0(3) . . . . ?
O52 Zn2 O31 Dy1 -81.71(10) . . . . ?
O11 Zn2 O31 Dy1 26.69(9) . . . . ?
N31 Zn2 O31 Dy1 170.15(11) . . . . ?
N11 Zn2 O31 Dy1 56.2(3) . . . . ?
O11 Dy1 O31 C36 -163.9(3) . . . . ?
O51 Dy1 O31 C36 -74.3(2) . . . . ?
O72 Dy1 O31 C36 -24.8(3) . . . . ?
O71 Dy1 O31 C36 -116.1(2) . . . . ?
O61 Dy1 O31 C36 65.5(3) . . . . ?
O32 Dy1 O31 C36 11.5(2) . . . . ?
O62 Dy1 O31 C36 93.0(3) . . . . ?
O12 Dy1 O31 C36 154.4(2) . . . . ?
N71 Dy1 O31 C36 -67.5(3) . . . . ?
N61 Dy1 O31 C36 76.6(2) . . . . ?
Zn2 Dy1 O31 C36 -139.4(3) . . . . ?
O11 Dy1 O31 Zn2 -24.54(9) . . . . ?
O51 Dy1 O31 Zn2 65.06(10) . . . . ?
O72 Dy1 O31 Zn2 114.55(12) . . . . ?
O71 Dy1 O31 Zn2 23.30(18) . . . . ?
O61 Dy1 O31 Zn2 -155.15(9) . . . . ?
O32 Dy1 O31 Zn2 150.87(12) . . . . ?
O62 Dy1 O31 Zn2 -127.57(12) . . . . ?
O12 Dy1 O31 Zn2 -66.26(11) . . . . ?
N71 Dy1 O31 Zn2 71.9(2) . . . . ?
N61 Dy1 O31 Zn2 -143.97(10) . . . . ?
O31 Dy1 O32 C35 -10.4(2) . . . . ?
O11 Dy1 O32 C35 -4.8(3) . . . . ?
O51 Dy1 O32 C35 68.4(2) . . . . ?
O72 Dy1 O32 C35 145.8(2) . . . . ?
O71 Dy1 O32 C35 129.7(2) . . . . ?
O61 Dy1 O32 C35 -141.7(2) . . . . ?
O62 Dy1 O32 C35 -88.1(2) . . . . ?
O12 Dy1 O32 C35 -108.8(2) . . . . ?
N71 Dy1 O32 C35 138.1(2) . . . . ?
N61 Dy1 O32 C35 -114.2(2) . . . . ?
Zn2 Dy1 O32 C35 6.8(2) . . . . ?
O31 Dy1 O32 C44 171.5(3) . . . . ?
O11 Dy1 O32 C44 177.0(2) . . . . ?
O51 Dy1 O32 C44 -109.8(3) . . . . ?
O72 Dy1 O32 C44 -32.4(3) . . . . ?
O71 Dy1 O32 C44 -48.5(3) . . . . ?
O61 Dy1 O32 C44 40.2(3) . . . . ?
O62 Dy1 O32 C44 93.7(3) . . . . ?
O12 Dy1 O32 C44 73.0(3) . . . . ?
N71 Dy1 O32 C44 -40.0(3) . . . . ?
N61 Dy1 O32 C44 67.6(3) . . . . ?
Zn2 Dy1 O32 C44 -171.4(3) . . . . ?
O31 Dy1 O51 C51 -29.8(4) . . . . ?
O11 Dy1 O51 C51 36.7(4) . . . . ?
O72 Dy1 O51 C51 -178.0(4) . . . . ?
O71 Dy1 O51 C51 125.7(4) . . . . ?
O61 Dy1 O51 C51 -145.4(3) . . . . ?
O32 Dy1 O51 C51 -96.5(4) . . . . ?
O62 Dy1 O51 C51 -52.1(4) . . . . ?
O12 Dy1 O51 C51 81.4(4) . . . . ?
N71 Dy1 O51 C51 153.8(4) . . . . ?
N61 Dy1 O51 C51 -101.3(4) . . . . ?
Zn2 Dy1 O51 C51 7.5(3) . . . . ?
O11 Zn2 O52 C51 -26.3(3) . . . . ?
N31 Zn2 O52 C51 132.3(3) . . . . ?
N11 Zn2 O52 C51 -119.8(3) . . . . ?
O31 Zn2 O52 C51 47.6(3) . . . . ?
Dy1 Zn2 O52 C51 7.1(3) . . . . ?
O31 Dy1 O61 N61 25.9(2) . . . . ?
O11 Dy1 O61 N61 -56.4(2) . . . . ?
O51 Dy1 O61 N61 126.7(2) . . . . ?
O72 Dy1 O61 N61 160.4(2) . . . . ?
O71 Dy1 O61 N61 -153.19(19) . . . . ?
O32 Dy1 O61 N61 75.9(2) . . . . ?
O62 Dy1 O61 N61 -8.62(18) . . . . ?
O12 Dy1 O61 N61 -86.3(2) . . . . ?
N71 Dy1 O61 N61 -176.3(2) . . . . ?
Zn2 Dy1 O61 N61 -2.6(3) . . . . ?
O31 Dy1 O62 N61 -139.4(2) . . . . ?
O11 Dy1 O62 N61 157.6(2) . . . . ?
O51 Dy1 O62 N61 -116.7(2) . . . . ?
O72 Dy1 O62 N61 -3.3(2) . . . . ?
O71 Dy1 O62 N61 66.3(2) . . . . ?
O61 Dy1 O62 N61 8.83(19) . . . . ?
O32 Dy1 O62 N61 -71.3(2) . . . . ?
O12 Dy1 O62 N61 96.9(2) . . . . ?
N71 Dy1 O62 N61 26.5(3) . . . . ?
Zn2 Dy1 O62 N61 -167.99(19) . . . . ?
O31 Dy1 O71 N71 122.8(2) . . . . ?
O11 Dy1 O71 N71 165.4(2) . . . . ?
O51 Dy1 O71 N71 81.0(2) . . . . ?
O72 Dy1 O71 N71 -1.5(2) . . . . ?
O61 Dy1 O71 N71 -58.6(2) . . . . ?
O32 Dy1 O71 N71 18.0(3) . . . . ?
O62 Dy1 O71 N71 -100.7(2) . . . . ?
O12 Dy1 O71 N71 -131.9(2) . . . . ?
N61 Dy1 O71 N71 -72.5(2) . . . . ?
Zn2 Dy1 O71 N71 137.2(2) . . . . ?
O31 Dy1 O72 N71 -130.6(2) . . . . ?
O11 Dy1 O72 N71 -19.1(3) . . . . ?
O51 Dy1 O72 N71 -81.2(2) . . . . ?
O71 Dy1 O72 N71 1.5(2) . . . . ?
O61 Dy1 O72 N71 120.2(2) . . . . ?
O32 Dy1 O72 N71 -163.8(2) . . . . ?
O62 Dy1 O72 N71 130.2(2) . . . . ?
O12 Dy1 O72 N71 50.1(2) . . . . ?
N61 Dy1 O72 N71 128.8(2) . . . . ?
Zn2 Dy1 O72 N71 -73.5(2) . . . . ?
O52 Zn2 N11 C17 117.7(3) . . . . ?
O11 Zn2 N11 C17 9.6(3) . . . . ?
N31 Zn2 N11 C17 -130.1(3) . . . . ?
O31 Zn2 N11 C17 -18.8(5) . . . . ?
Dy1 Zn2 N11 C17 24.1(3) . . . . ?
O52 Zn2 N11 C18 -61.1(2) . . . . ?
O11 Zn2 N11 C18 -169.2(2) . . . . ?
N31 Zn2 N11 C18 51.1(2) . . . . ?
O31 Zn2 N11 C18 162.4(3) . . . . ?
Dy1 Zn2 N11 C18 -154.70(19) . . . . ?
O52 Zn2 N31 C37 -53.8(3) . . . . ?
O11 Zn2 N31 C37 94.6(3) . . . . ?
N11 Zn2 N31 C37 -162.4(3) . . . . ?
O31 Zn2 N31 C37 34.9(3) . . . . ?
Dy1 Zn2 N31 C37 42.7(3) . . . . ?
O52 Zn2 N31 C38 118.8(2) . . . . ?
O11 Zn2 N31 C38 -92.7(3) . . . . ?
N11 Zn2 N31 C38 10.3(2) . . . . ?
O31 Zn2 N31 C38 -152.5(2) . . . . ?
Dy1 Zn2 N31 C38 -144.6(2) . . . . ?
Dy1 O62 N61 O63 162.9(3) . . . . ?
Dy1 O62 N61 O61 -15.0(3) . . . . ?
Dy1 O61 N61 O63 -162.6(3) . . . . ?
Dy1 O61 N61 O62 15.3(3) . . . . ?
O31 Dy1 N61 O63 -63.2(11) . . . . ?
O11 Dy1 N61 O63 -127.3(11) . . . . ?
O51 Dy1 N61 O63 3.9(12) . . . . ?
O72 Dy1 N61 O63 75.4(11) . . . . ?
O71 Dy1 N61 O63 125.9(11) . . . . ?
O61 Dy1 N61 O63 93.9(11) . . . . ?
O32 Dy1 N61 O63 -1.2(11) . . . . ?
O62 Dy1 N61 O63 -101.8(12) . . . . ?
O12 Dy1 N61 O63 -178.1(11) . . . . ?
N71 Dy1 N61 O63 97.9(11) . . . . ?
Zn2 Dy1 N61 O63 -87.7(11) . . . . ?
O31 Dy1 N61 O62 38.6(2) . . . . ?
O11 Dy1 N61 O62 -25.5(2) . . . . ?
O51 Dy1 N61 O62 105.7(2) . . . . ?
O72 Dy1 N61 O62 177.2(2) . . . . ?
O71 Dy1 N61 O62 -132.3(2) . . . . ?
O61 Dy1 N61 O62 -164.3(3) . . . . ?
O32 Dy1 N61 O62 100.6(2) . . . . ?
O12 Dy1 N61 O62 -76.4(2) . . . . ?
N71 Dy1 N61 O62 -160.3(2) . . . . ?
Zn2 Dy1 N61 O62 14.1(2) . . . . ?
O31 Dy1 N61 O61 -157.12(19) . . . . ?
O11 Dy1 N61 O61 138.78(19) . . . . ?
O51 Dy1 N61 O61 -90.0(2) . . . . ?
O72 Dy1 N61 O61 -18.5(2) . . . . ?
O71 Dy1 N61 O61 32.0(2) . . . . ?
O32 Dy1 N61 O61 -95.1(2) . . . . ?
O62 Dy1 N61 O61 164.3(3) . . . . ?
O12 Dy1 N61 O61 87.9(2) . . . . ?
N71 Dy1 N61 O61 4.0(2) . . . . ?
Zn2 Dy1 N61 O61 178.36(17) . . . . ?
Dy1 O71 N71 O72 2.7(3) . . . . ?
Dy1 O71 N71 O73 -178.2(4) . . . . ?
Dy1 O72 N71 O71 -2.7(4) . . . . ?
Dy1 O72 N71 O73 178.2(4) . . . . ?
O31 Dy1 N71 O71 -98.4(3) . . . . ?
O11 Dy1 N71 O71 -16.0(2) . . . . ?
O51 Dy1 N71 O71 -91.4(2) . . . . ?
O72 Dy1 N71 O71 177.3(4) . . . . ?
O61 Dy1 N71 O71 122.5(2) . . . . ?
O32 Dy1 N71 O71 -166.2(2) . . . . ?
O62 Dy1 N71 O71 108.7(2) . . . . ?
O12 Dy1 N71 O71 44.4(2) . . . . ?
N61 Dy1 N71 O71 120.7(2) . . . . ?
Zn2 Dy1 N71 O71 -53.4(2) . . . . ?
O31 Dy1 N71 O72 84.3(3) . . . . ?
O11 Dy1 N71 O72 166.69(19) . . . . ?
O51 Dy1 N71 O72 91.3(2) . . . . ?
O71 Dy1 N71 O72 -177.3(4) . . . . ?
O61 Dy1 N71 O72 -54.8(2) . . . . ?
O32 Dy1 N71 O72 16.6(2) . . . . ?
O62 Dy1 N71 O72 -68.6(3) . . . . ?
O12 Dy1 N71 O72 -132.8(2) . . . . ?
N61 Dy1 N71 O72 -56.6(2) . . . . ?
Zn2 Dy1 N71 O72 129.37(18) . . . . ?
O31 Dy1 N71 O73 37(8) . . . . ?
O11 Dy1 N71 O73 120(8) . . . . ?
O51 Dy1 N71 O73 44(8) . . . . ?
O72 Dy1 N71 O73 -47(8) . . . . ?
O71 Dy1 N71 O73 136(8) . . . . ?
O61 Dy1 N71 O73 -102(8) . . . . ?
O32 Dy1 N71 O73 -30(8) . . . . ?
O62 Dy1 N71 O73 -116(8) . . . . ?
O12 Dy1 N71 O73 -180(100) . . . . ?
N61 Dy1 N71 O73 -104(8) . . . . ?
Zn2 Dy1 N71 O73 82(8) . . . . ?
C16 C11 C12 C13 1.8(5) . . . . ?
C17 C11 C12 C13 178.8(3) . . . . ?
C11 C12 C13 C14 -1.0(5) . . . . ?
C12 C13 C14 C15 0.1(5) . . . . ?
C13 C14 C15 O12 179.4(3) . . . . ?
C13 C14 C15 C16 0.0(5) . . . . ?
C24 O12 C15 C14 4.2(5) . . . . ?
Dy1 O12 C15 C14 166.0(3) . . . . ?
C24 O12 C15 C16 -176.4(3) . . . . ?
Dy1 O12 C15 C16 -14.6(3) . . . . ?
Zn2 O11 C16 C11 15.1(5) . . . . ?
Dy1 O11 C16 C11 -164.3(2) . . . . ?
Zn2 O11 C16 C15 -165.1(2) . . . . ?
Dy1 O11 C16 C15 15.5(4) . . . . ?
C12 C11 C16 O11 178.1(3) . . . . ?
C17 C11 C16 O11 1.4(5) . . . . ?
C12 C11 C16 C15 -1.7(5) . . . . ?
C17 C11 C16 C15 -178.5(3) . . . . ?
C14 C15 C16 O11 -179.0(3) . . . . ?
O12 C15 C16 O11 1.5(4) . . . . ?
C14 C15 C16 C11 0.8(5) . . . . ?
O12 C15 C16 C11 -178.7(3) . . . . ?
C18 N11 C17 C11 179.7(3) . . . . ?
Zn2 N11 C17 C11 0.9(5) . . . . ?
C16 C11 C17 N11 -9.7(5) . . . . ?
C12 C11 C17 N11 173.4(3) . . . . ?
C17 N11 C18 C19 -144.0(3) . . . . ?
Zn2 N11 C18 C19 34.9(4) . . . . ?
C17 N11 C18 C23 36.8(5) . . . . ?
Zn2 N11 C18 C23 -144.3(3) . . . . ?
C23 C18 C19 C20 -3.1(5) . . . . ?
N11 C18 C19 C20 177.8(3) . . . . ?
C18 C19 C20 C21 1.2(5) . . . . ?
C19 C20 C21 C22 0.8(6) . . . . ?
C20 C21 C22 C23 -0.8(6) . . . . ?
C21 C22 C23 C18 -1.1(6) . . . . ?
C19 C18 C23 C22 3.0(5) . . . . ?
N11 C18 C23 C22 -177.9(3) . . . . ?
C36 C31 C32 C33 2.8(5) . . . . ?
C37 C31 C32 C33 177.5(3) . . . . ?
C31 C32 C33 C34 -2.4(6) . . . . ?
C32 C33 C34 C35 0.0(6) . . . . ?
C33 C34 C35 O32 -178.3(3) . . . . ?
C33 C34 C35 C36 1.9(6) . . . . ?
C44 O32 C35 C34 7.6(5) . . . . ?
Dy1 O32 C35 C34 -170.8(3) . . . . ?
C44 O32 C35 C36 -172.6(3) . . . . ?
Dy1 O32 C35 C36 9.0(4) . . . . ?
Zn2 O31 C36 C31 37.3(4) . . . . ?
Dy1 O31 C36 C31 170.5(2) . . . . ?
Zn2 O31 C36 C35 -144.6(2) . . . . ?
Dy1 O31 C36 C35 -11.4(4) . . . . ?
C32 C31 C36 O31 177.3(3) . . . . ?
C37 C31 C36 O31 2.7(5) . . . . ?
C32 C31 C36 C35 -0.9(5) . . . . ?
C37 C31 C36 C35 -175.4(3) . . . . ?
C34 C35 C36 O31 -179.7(3) . . . . ?
O32 C35 C36 O31 0.5(4) . . . . ?
C34 C35 C36 C31 -1.5(5) . . . . ?
O32 C35 C36 C31 178.7(3) . . . . ?
C38 N31 C37 C31 176.2(3) . . . . ?
Zn2 N31 C37 C31 -11.0(5) . . . . ?
C36 C31 C37 N31 -18.3(5) . . . . ?
C32 C31 C37 N31 167.1(3) . . . . ?
C37 N31 C38 C39 -136.5(3) . . . . ?
Zn2 N31 C38 C39 50.5(4) . . . . ?
C37 N31 C38 C43 43.6(5) . . . . ?
Zn2 N31 C38 C43 -129.4(3) . . . . ?
C43 C38 C39 C40 -1.3(5) . . . . ?
N31 C38 C39 C40 178.9(3) . . . . ?
C38 C39 C40 C41 -1.0(5) . . . . ?
C39 C40 C41 C42 1.9(6) . . . . ?
C40 C41 C42 C43 -0.5(6) . . . . ?
C39 C38 C43 C42 2.6(5) . . . . ?
N31 C38 C43 C42 -177.5(3) . . . . ?
C41 C42 C43 C38 -1.7(6) . . . . ?
Dy1 O51 C51 O52 -5.1(6) . . . . ?
Dy1 O51 C51 C52 177.1(3) . . . . ?
Zn2 O52 C51 O51 -5.0(5) . . . . ?
Zn2 O52 C51 C52 172.8(2) . . . . ?

_diffrn_measured_fraction_theta_max 0.950
_diffrn_reflns_theta_full        29.17
_diffrn_measured_fraction_theta_full 0.950
_refine_diff_density_max         1.262
_refine_diff_density_min         -1.825
_refine_diff_density_rms         0.129
_database_code_depnum_ccdc_archive 'CCDC 990256'
#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
#  on your local computer system.
# 
#  For further information on the CCDC, data deposition and
#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
#
data_shelxl

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C28 H26 Dy N5 O13'
_chemical_formula_weight         803.04

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Orthorhombic
_symmetry_space_group_name_H-M   Aba2

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, z'
'x+1/2, -y+1/2, z'
'-x, -y, z'
'x, y+1/2, z+1/2'
'-x+1/2, y+1, z+1/2'
'x+1/2, -y+1, z+1/2'
'-x, -y+1/2, z+1/2'

_cell_length_a                   17.654(3)
_cell_length_b                   54.092(9)
_cell_length_c                   9.5502(16)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     9120(3)
_cell_formula_units_Z            12
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      3.01
_cell_measurement_theta_max      29.17

_exptl_crystal_description       Block
_exptl_crystal_colour            'Orange red'
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.755
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             4788
_exptl_absorpt_coefficient_mu    2.534
_exptl_absorpt_correction_type   Numerical
_exptl_absorpt_correction_T_min  0.6312
_exptl_absorpt_correction_T_max  0.6312
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71075
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  
;
Rigaku Saturn724+ (4x4 bin mode)
;
_diffrn_measurement_method       'profile data from ω-scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            33334
_diffrn_reflns_av_R_equivalents  0.0510
_diffrn_reflns_av_sigmaI/netI    0.0633
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_k_min       -74
_diffrn_reflns_limit_k_max       74
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_theta_min         3.01
_diffrn_reflns_theta_max         29.17
_reflns_number_total             11627
_reflns_number_gt                9529
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       
;
CrystalClear-SM Expert 2.1 b24 (Rigaku, 2012)
;
_computing_cell_refinement       
;
CrystalClear-SM Expert 2.1 b24 (Rigaku, 2012)
;
_computing_data_reduction        
;
CrystalClear-SM Expert 2.1 b24 (Rigaku, 2012)
;
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0342P)²+19.6649P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   -0.008(11)
_refine_ls_number_reflns         11627
_refine_ls_number_parameters     632
_refine_ls_number_restraints     25
_refine_ls_R_factor_all          0.0628
_refine_ls_R_factor_gt           0.0494
_refine_ls_wR_factor_ref         0.1015
_refine_ls_wR_factor_gt          0.0941
_refine_ls_goodness_of_fit_ref   1.067
_refine_ls_restrained_S_all      1.067
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.503158(12) -0.166199(6) 0.63036(3) 0.01758(8) Uani 1 1 d . . .
Dy2 Dy 0.5000 0.0000 0.43114(5) 0.01227(10) Uani 1 2 d S . .
O11 O 0.6265(2) -0.16465(7) 0.6974(4) 0.0180(9) Uani 1 1 d . . .
O12 O 0.6002(2) -0.19826(7) 0.5084(5) 0.0206(9) Uani 1 1 d . . .
O31 O 0.3834(2) -0.16780(7) 0.7267(5) 0.0175(9) Uani 1 1 d . . .
O32 O 0.3970(2) -0.13373(7) 0.5369(4) 0.0188(9) Uani 1 1 d . . .
O41 O 0.5421(2) -0.12187(8) 0.6269(6) 0.0303(10) Uani 1 1 d . . .
O42 O 0.5049(2) -0.13639(9) 0.8256(7) 0.0296(11) Uani 1 1 d . . .
O43 O 0.5383(3) -0.09737(9) 0.8079(6) 0.0416(14) Uani 1 1 d . . .
O51 O 0.4547(3) -0.17747(9) 0.3969(5) 0.0327(12) Uani 1 1 d U . .
O52 O 0.5464(3) -0.15168(9) 0.4006(5) 0.0335(11) Uani 1 1 d U . .
O53 O 0.5007(2) -0.16550(15) 0.2014(6) 0.054(2) Uani 1 1 d U . .
O61 O 0.4533(3) -0.20935(10) 0.6166(8) 0.0610(19) Uani 1 1 d . . .
O62 O 0.5095(3) -0.19764(14) 0.8124(8) 0.056(2) Uani 1 1 d . . .
O63 O 0.4653(5) -0.23516(12) 0.7911(10) 0.114(4) Uani 1 1 d . . .
O112 O 0.4739(2) 0.02648(7) 0.6465(5) 0.0195(9) Uani 1 1 d . . .
O141 O 0.5597(2) -0.03777(7) 0.3387(5) 0.0244(10) Uani 1 1 d . . .
O142 O 0.4436(2) -0.04264(7) 0.4029(5) 0.0229(10) Uani 1 1 d . . .
O143 O 0.4996(3) -0.07190(11) 0.2875(6) 0.046(2) Uani 1 1 d . . .
O151 O 0.4456(2) -0.00887(8) 0.1941(5) 0.0230(10) Uani 1 1 d . . .
O153 O 0.5000 0.0000 -0.0030(7) 0.040(2) Uani 1 2 d S . .
C11 C 0.7615(3) -0.16840(10) 0.6735(7) 0.0186(13) Uani 1 1 d . . .
C12 C 0.6861(3) -0.17493(9) 0.6386(6) 0.0118(10) Uani 1 1 d . . .
C13 C 0.6760(3) -0.19313(10) 0.5346(7) 0.0154(12) Uani 1 1 d . . .
C14 C 0.7360(3) -0.20392(11) 0.4687(7) 0.0190(13) Uani 1 1 d . . .
H14A H 0.7274 -0.2160 0.3982 0.023 Uiso 1 1 calc R . .
C15 C 0.8118(3) -0.19722(11) 0.5051(7) 0.0222(14) Uani 1 1 d . . .
H15A H 0.8538 -0.2048 0.4602 0.027 Uiso 1 1 calc R . .
C16 C 0.8227(3) -0.17965(10) 0.6058(7) 0.0192(14) Uani 1 1 d . . .
H16A H 0.8728 -0.1750 0.6303 0.023 Uiso 1 1 calc R . .
C17 C 0.7755(3) -0.15025(11) 0.7797(6) 0.0173(14) Uani 1 1 d . . .
H17A H 0.8264 -0.1458 0.8001 0.021 Uiso 1 1 calc R . .
C18 C 0.7254(3) -0.12116(10) 0.9555(6) 0.0171(12) Uani 1 1 d . . .
C19 C 0.6581(4) -0.11487(12) 1.0203(8) 0.0289(15) Uani 1 1 d . . .
H19A H 0.6122 -0.1229 0.9952 0.035 Uiso 1 1 calc R . .
C20 C 0.6585(4) -0.09647(12) 1.1235(8) 0.0336(16) Uani 1 1 d . . .
H20A H 0.6126 -0.0917 1.1680 0.040 Uiso 1 1 calc R . .
C21 C 0.7261(4) -0.08524(11) 1.1605(8) 0.0336(17) Uani 1 1 d . . .
H21A H 0.7265 -0.0726 1.2296 0.040 Uiso 1 1 calc R . .
C22 C 0.7934(4) -0.09237(11) 1.0968(7) 0.0268(15) Uani 1 1 d . . .
H22A H 0.8396 -0.0848 1.1244 0.032 Uiso 1 1 calc R . .
C23 C 0.7940(4) -0.11038(11) 0.9932(7) 0.0239(14) Uani 1 1 d . . .
H23A H 0.8399 -0.1152 0.9493 0.029 Uiso 1 1 calc R . .
C24 C 0.5844(3) -0.21802(11) 0.4098(7) 0.0228(14) Uani 1 1 d . . .
H24A H 0.6318 -0.2263 0.3843 0.034 Uiso 1 1 calc R . .
H24B H 0.5608 -0.2111 0.3256 0.034 Uiso 1 1 calc R . .
H24C H 0.5499 -0.2300 0.4530 0.034 Uiso 1 1 calc R . .
C31 C 0.2484(3) -0.16631(10) 0.7266(7) 0.0191(13) Uani 1 1 d . . .
C32 C 0.3204(3) -0.15858(10) 0.6780(6) 0.0162(12) Uani 1 1 d . . .
C33 C 0.3240(3) -0.14003(9) 0.5741(6) 0.0128(11) Uani 1 1 d . . .
C34 C 0.2596(3) -0.12991(10) 0.5200(6) 0.0166(12) Uani 1 1 d . . .
H34A H 0.2630 -0.1174 0.4506 0.020 Uiso 1 1 calc R . .
C35 C 0.1876(3) -0.13802(11) 0.5668(7) 0.0219(14) Uani 1 1 d . . .
H35A H 0.1429 -0.1312 0.5271 0.026 Uiso 1 1 calc R . .
C36 C 0.1824(3) -0.15528(11) 0.6668(6) 0.0172(13) Uani 1 1 d . . .
H36A H 0.1338 -0.1603 0.6987 0.021 Uiso 1 1 calc R . .
C37 C 0.2413(3) -0.18387(10) 0.8357(7) 0.0166(12) Uani 1 1 d . . .
H37A H 0.1922 -0.1887 0.8657 0.020 Uiso 1 1 calc R . .
C38 C 0.3015(3) -0.21135(10) 1.0062(7) 0.0203(13) Uani 1 1 d . . .
C39 C 0.3723(3) -0.21574(11) 1.0671(7) 0.0232(14) Uani 1 1 d . . .
H39A H 0.4161 -0.2074 1.0337 0.028 Uiso 1 1 calc R . .
C40 C 0.3780(4) -0.23245(11) 1.1770(7) 0.0268(15) Uani 1 1 d . . .
H40A H 0.4256 -0.2353 1.2204 0.032 Uiso 1 1 calc R . .
C41 C 0.3148(4) -0.24497(12) 1.2235(8) 0.0346(17) Uani 1 1 d . . .
H41A H 0.3191 -0.2565 1.2981 0.041 Uiso 1 1 calc R . .
C42 C 0.2451(4) -0.24080(12) 1.1620(8) 0.0349(18) Uani 1 1 d . . .
H42A H 0.2019 -0.2497 1.1929 0.042 Uiso 1 1 calc R . .
C43 C 0.2381(4) -0.22338(12) 1.0539(7) 0.0255(15) Uani 1 1 d . . .
H43A H 0.1900 -0.2199 1.0141 0.031 Uiso 1 1 calc R . .
C44 C 0.4063(3) -0.11355(10) 0.4397(7) 0.0234(13) Uani 1 1 d . . .
H44A H 0.3575 -0.1052 0.4259 0.035 Uiso 1 1 calc R . .
H44B H 0.4246 -0.1199 0.3498 0.035 Uiso 1 1 calc R . .
H44C H 0.4431 -0.1017 0.4773 0.035 Uiso 1 1 calc R . .
C111 C 0.2797(3) 0.00599(9) 0.6764(6) 0.0128(11) Uani 1 1 d . . .
C112 C 0.3547(3) 0.00919(9) 0.6281(7) 0.0128(10) Uani 1 1 d . . .
C113 C 0.4016(3) 0.02575(10) 0.7025(6) 0.0146(12) Uani 1 1 d . . .
C114 C 0.3760(4) 0.03894(10) 0.8151(7) 0.0197(13) Uani 1 1 d . . .
H11A H 0.4089 0.0500 0.8631 0.024 Uiso 1 1 calc R . .
C115 C 0.3000(3) 0.03597(10) 0.8593(6) 0.0201(13) Uani 1 1 d . . .
H11B H 0.2820 0.0452 0.9373 0.024 Uiso 1 1 calc R . .
C116 C 0.2519(4) 0.02008(11) 0.7918(6) 0.0182(14) Uani 1 1 d . . .
H11C H 0.2008 0.0185 0.8214 0.022 Uiso 1 1 calc R . .
C117 C 0.2313(3) -0.01233(9) 0.6166(6) 0.0139(11) Uani 1 1 d . . .
H11D H 0.1803 -0.0134 0.6472 0.017 Uiso 1 1 calc R . .
C118 C 0.2168(3) -0.04817(10) 0.4600(7) 0.0151(12) Uani 1 1 d . . .
C119 C 0.2522(3) -0.05973(10) 0.3480(6) 0.0189(13) Uani 1 1 d . . .
H11E H 0.2998 -0.0539 0.3154 0.023 Uiso 1 1 calc R . .
C120 C 0.2179(4) -0.07971(11) 0.2841(6) 0.0194(14) Uani 1 1 d . . .
H12A H 0.2420 -0.0879 0.2081 0.023 Uiso 1 1 calc R . .
C121 C 0.1475(3) -0.08782(10) 0.3321(7) 0.0199(13) Uani 1 1 d . . .
H12B H 0.1229 -0.1012 0.2866 0.024 Uiso 1 1 calc R . .
C122 C 0.1138(3) -0.07664(11) 0.4441(7) 0.0223(14) Uani 1 1 d . . .
H12C H 0.0667 -0.0827 0.4778 0.027 Uiso 1 1 calc R . .
C123 C 0.1478(3) -0.05640(11) 0.5097(7) 0.0174(12) Uani 1 1 d . . .
H12D H 0.1239 -0.0485 0.5867 0.021 Uiso 1 1 calc R . .
C124 C 0.5275(3) 0.04156(11) 0.7248(8) 0.0241(14) Uani 1 1 d . . .
H12E H 0.5014 0.0496 0.8030 0.036 Uiso 1 1 calc R . .
H12F H 0.5492 0.0542 0.6629 0.036 Uiso 1 1 calc R . .
H12G H 0.5682 0.0310 0.7613 0.036 Uiso 1 1 calc R . .
N11 N 0.7209(2) -0.13959(8) 0.8495(5) 0.0160(10) Uani 1 1 d . . .
H11F H 0.6748 -0.1445 0.8279 0.019 Uiso 1 1 calc R . .
N31 N 0.3006(3) -0.19366(8) 0.8964(5) 0.0162(10) Uani 1 1 d . . .
H31A H 0.3450 -0.1887 0.8656 0.019 Uiso 1 1 calc R . .
N41 N 0.5278(3) -0.11802(10) 0.7551(7) 0.0271(13) Uani 1 1 d . . .
N51 N 0.5003(3) -0.16556(13) 0.3291(9) 0.0299(14) Uani 1 1 d U . .
N61 N 0.4782(5) -0.21461(13) 0.7395(13) 0.058(2) Uani 1 1 d . . .
N111 N 0.2555(2) -0.02755(9) 0.5211(5) 0.0144(10) Uani 1 1 d . . .
H11G H 0.3017 -0.0248 0.4900 0.017 Uiso 1 1 calc R . .
N141 N 0.4994(3) -0.05155(10) 0.3430(7) 0.0273(13) Uani 1 1 d . . .
N151 N 0.5000 0.0000 0.1312(9) 0.0056(12) Uani 1 2 d S . .
O111 O 0.3813(2) -0.00320(6) 0.5212(4) 0.0123(8) Uiso 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O11 2.272(4) . ?
Dy1 O31 2.308(4) . ?
Dy1 O62 2.434(6) . ?
Dy1 O52 2.453(5) . ?
Dy1 O42 2.465(6) . ?
Dy1 O51 2.465(5) . ?
Dy1 O41 2.495(4) . ?
Dy1 O61 2.498(5) . ?
Dy1 O12 2.702(4) . ?
Dy1 O32 2.719(4) . ?
Dy1 N61 2.853(7) . ?
Dy1 N51 2.878(9) . ?
Dy2 O111 2.271(4) 4_655 ?
Dy2 O111 2.271(4) . ?
Dy2 O141 2.463(4) . ?
Dy2 O141 2.463(4) 4_655 ?
Dy2 O151 2.505(4) . ?
Dy2 O151 2.505(4) 4_655 ?
Dy2 O142 2.527(4) . ?
Dy2 O142 2.527(4) 4_655 ?
Dy2 O112 2.548(4) . ?
Dy2 O112 2.548(4) 4_655 ?
Dy2 N151 2.865(9) . ?
Dy2 N141 2.913(6) 4_655 ?
O11 C12 1.316(6) . ?
O12 C13 1.388(6) . ?
O12 C24 1.451(7) . ?
O31 C32 1.305(6) . ?
O32 C33 1.380(6) . ?
O32 C44 1.442(7) . ?
O41 N41 1.268(8) . ?
O42 N41 1.266(8) . ?
O43 N41 1.239(7) . ?
O51 N51 1.218(8) . ?
O52 N51 1.300(8) . ?
O53 N51 1.219(10) . ?
O61 N61 1.284(12) . ?
O62 N61 1.278(12) . ?
O63 N61 1.237(9) . ?
O112 C113 1.385(6) . ?
O112 C124 1.457(7) . ?
O141 N141 1.301(6) . ?
O142 N141 1.238(6) . ?
O143 N141 1.221(8) . ?
O151 N151 1.230(6) . ?
O153 N151 1.281(11) . ?
C11 C16 1.398(8) . ?
C11 C12 1.416(7) . ?
C11 C17 1.433(8) . ?
C12 C13 1.410(8) . ?
C13 C14 1.363(8) . ?
C14 C15 1.429(8) . ?
C14 H14A 0.9500 . ?
C15 C16 1.366(9) . ?
C15 H15A 0.9500 . ?
C16 H16A 0.9500 . ?
C17 N11 1.306(7) . ?
C17 H17A 0.9500 . ?
C18 C19 1.383(9) . ?
C18 C23 1.391(8) . ?
C18 N11 1.423(7) . ?
C19 C20 1.401(9) . ?
C19 H19A 0.9500 . ?
C20 C21 1.385(9) . ?
C20 H20A 0.9500 . ?
C21 C22 1.390(9) . ?
C21 H21A 0.9500 . ?
C22 C23 1.389(8) . ?
C22 H22A 0.9500 . ?
C23 H23A 0.9500 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C31 C37 1.415(8) . ?
C31 C32 1.416(7) . ?
C31 C36 1.427(8) . ?
C32 C33 1.413(8) . ?
C33 C34 1.364(7) . ?
C34 C35 1.417(8) . ?
C34 H34A 0.9500 . ?
C35 C36 1.339(8) . ?
C35 H35A 0.9500 . ?
C36 H36A 0.9500 . ?
C37 N31 1.308(7) . ?
C37 H37A 0.9500 . ?
C38 C43 1.372(8) . ?
C38 C39 1.399(8) . ?
C38 N31 1.420(7) . ?
C39 C40 1.389(8) . ?
C39 H39A 0.9500 . ?
C40 C41 1.379(9) . ?
C40 H40A 0.9500 . ?
C41 C42 1.381(10) . ?
C41 H41A 0.9500 . ?
C42 C43 1.403(9) . ?
C42 H42A 0.9500 . ?
C43 H43A 0.9500 . ?
C44 H44A 0.9800 . ?
C44 H44B 0.9800 . ?
C44 H44C 0.9800 . ?
C111 C112 1.412(7) . ?
C111 C116 1.426(8) . ?
C111 C117 1.427(7) . ?
C112 O111 1.309(7) . ?
C112 C113 1.412(7) . ?
C113 C114 1.367(8) . ?
C114 C115 1.416(8) . ?
C114 H11A 0.9500 . ?
C115 C116 1.370(8) . ?
C115 H11B 0.9500 . ?
C116 H11C 0.9500 . ?
C117 N111 1.300(7) . ?
C117 H11D 0.9500 . ?
C118 C123 1.381(7) . ?
C118 C119 1.388(8) . ?
C118 N111 1.433(7) . ?
C119 C120 1.381(8) . ?
C119 H11E 0.9500 . ?
C120 C121 1.395(8) . ?
C120 H12A 0.9500 . ?
C121 C122 1.366(9) . ?
C121 H12B 0.9500 . ?
C122 C123 1.397(8) . ?
C122 H12C 0.9500 . ?
C123 H12D 0.9500 . ?
C124 H12E 0.9800 . ?
C124 H12F 0.9800 . ?
C124 H12G 0.9800 . ?
N11 H11F 0.8800 . ?
N31 H31A 0.8800 . ?
N111 H11G 0.8800 . ?
N151 O151 1.230(6) 4_655 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O11 Dy1 O31 140.12(16) . . ?
O11 Dy1 O62 77.30(17) . . ?
O31 Dy1 O62 74.42(15) . . ?
O11 Dy1 O52 86.67(15) . . ?
O31 Dy1 O52 130.85(15) . . ?
O62 Dy1 O52 148.0(2) . . ?
O11 Dy1 O42 75.58(14) . . ?
O31 Dy1 O42 74.58(15) . . ?
O62 Dy1 O42 85.2(2) . . ?
O52 Dy1 O42 117.60(18) . . ?
O11 Dy1 O51 126.65(15) . . ?
O31 Dy1 O51 91.91(16) . . ?
O62 Dy1 O51 119.3(2) . . ?
O52 Dy1 O51 51.53(18) . . ?
O42 Dy1 O51 148.23(16) . . ?
O11 Dy1 O41 72.78(14) . . ?
O31 Dy1 O41 107.10(14) . . ?
O62 Dy1 O41 131.9(2) . . ?
O52 Dy1 O41 66.08(18) . . ?
O42 Dy1 O41 51.53(18) . . ?
O51 Dy1 O41 108.75(18) . . ?
O11 Dy1 O61 112.77(19) . . ?
O31 Dy1 O61 70.31(16) . . ?
O62 Dy1 O61 53.2(3) . . ?
O52 Dy1 O61 111.2(2) . . ?
O42 Dy1 O61 130.9(2) . . ?
O51 Dy1 O61 66.4(2) . . ?
O41 Dy1 O61 174.0(2) . . ?
O11 Dy1 O12 62.43(13) . . ?
O31 Dy1 O12 136.80(13) . . ?
O62 Dy1 O12 80.2(2) . . ?
O52 Dy1 O12 67.81(15) . . ?
O42 Dy1 O12 137.57(13) . . ?
O51 Dy1 O12 70.82(14) . . ?
O41 Dy1 O12 115.86(14) . . ?
O61 Dy1 O12 66.49(15) . . ?
O11 Dy1 O32 136.84(13) . . ?
O31 Dy1 O32 61.56(12) . . ?
O62 Dy1 O32 135.86(15) . . ?
O52 Dy1 O32 73.37(14) . . ?
O42 Dy1 O32 80.46(15) . . ?
O51 Dy1 O32 67.88(14) . . ?
O41 Dy1 O32 64.20(13) . . ?
O61 Dy1 O32 110.10(19) . . ?
O12 Dy1 O32 135.24(14) . . ?
O11 Dy1 N61 94.5(2) . . ?
O31 Dy1 N61 71.24(17) . . ?
O62 Dy1 N61 26.5(3) . . ?
O52 Dy1 N61 132.0(2) . . ?
O42 Dy1 N61 109.0(3) . . ?
O51 Dy1 N61 92.9(3) . . ?
O41 Dy1 N61 158.4(3) . . ?
O61 Dy1 N61 26.7(3) . . ?
O12 Dy1 N61 70.50(17) . . ?
O32 Dy1 N61 127.3(2) . . ?
O11 Dy1 N51 107.34(15) . . ?
O31 Dy1 N51 112.54(15) . . ?
O62 Dy1 N51 136.3(3) . . ?
O52 Dy1 N51 26.74(16) . . ?
O42 Dy1 N51 138.5(2) . . ?
O51 Dy1 N51 24.85(16) . . ?
O41 Dy1 N51 88.8(2) . . ?
O61 Dy1 N51 87.3(2) . . ?
O12 Dy1 N51 65.65(15) . . ?
O32 Dy1 N51 69.63(14) . . ?
N61 Dy1 N51 111.9(3) . . ?
O111 Dy2 O111 135.5(2) 4_655 . ?
O111 Dy2 O141 78.71(14) 4_655 . ?
O111 Dy2 O141 117.87(13) . . ?
O111 Dy2 O141 117.87(13) 4_655 4_655 ?
O111 Dy2 O141 78.72(14) . 4_655 ?
O141 Dy2 O141 138.0(2) . 4_655 ?
O111 Dy2 O151 135.26(14) 4_655 . ?
O111 Dy2 O151 88.53(14) . . ?
O141 Dy2 O151 71.40(15) . . ?
O141 Dy2 O151 70.78(15) 4_655 . ?
O111 Dy2 O151 88.53(14) 4_655 4_655 ?
O111 Dy2 O151 135.26(14) . 4_655 ?
O141 Dy2 O151 70.78(15) . 4_655 ?
O141 Dy2 O151 71.40(15) 4_655 4_655 ?
O151 Dy2 O151 50.7(2) . 4_655 ?
O111 Dy2 O142 118.27(13) 4_655 . ?
O111 Dy2 O142 66.87(12) . . ?
O141 Dy2 O142 51.20(13) . . ?
O141 Dy2 O142 123.38(14) 4_655 . ?
O151 Dy2 O142 65.02(14) . . ?
O151 Dy2 O142 103.27(14) 4_655 . ?
O111 Dy2 O142 66.87(12) 4_655 4_655 ?
O111 Dy2 O142 118.28(13) . 4_655 ?
O141 Dy2 O142 123.37(14) . 4_655 ?
O141 Dy2 O142 51.20(13) 4_655 4_655 ?
O151 Dy2 O142 103.26(15) . 4_655 ?
O151 Dy2 O142 65.02(14) 4_655 4_655 ?
O142 Dy2 O142 167.7(2) . 4_655 ?
O111 Dy2 O112 79.53(13) 4_655 . ?
O111 Dy2 O112 64.54(13) . . ?
O141 Dy2 O112 146.42(15) . . ?
O141 Dy2 O112 75.27(15) 4_655 . ?
O151 Dy2 O112 140.14(13) . . ?
O151 Dy2 O112 133.71(14) 4_655 . ?
O142 Dy2 O112 121.85(13) . . ?
O142 Dy2 O112 69.18(14) 4_655 . ?
O111 Dy2 O112 64.54(13) 4_655 4_655 ?
O111 Dy2 O112 79.53(13) . 4_655 ?
O141 Dy2 O112 75.27(15) . 4_655 ?
O141 Dy2 O112 146.42(15) 4_655 4_655 ?
O151 Dy2 O112 133.71(14) . 4_655 ?
O151 Dy2 O112 140.14(13) 4_655 4_655 ?
O142 Dy2 O112 69.17(14) . 4_655 ?
O142 Dy2 O112 121.85(13) 4_655 4_655 ?
O112 Dy2 O112 72.4(2) . 4_655 ?
O111 Dy2 N151 112.26(10) 4_655 . ?
O111 Dy2 N151 112.27(10) . . ?
O141 Dy2 N151 68.98(12) . . ?
O141 Dy2 N151 68.98(12) 4_655 . ?
O151 Dy2 N151 25.36(10) . . ?
O151 Dy2 N151 25.36(10) 4_655 . ?
O142 Dy2 N151 83.87(11) . . ?
O142 Dy2 N151 83.87(11) 4_655 . ?
O112 Dy2 N151 143.81(10) . . ?
O112 Dy2 N151 143.81(10) 4_655 . ?
O111 Dy2 N141 91.90(13) 4_655 4_655 ?
O111 Dy2 N141 100.71(14) . 4_655 ?
O141 Dy2 N141 133.54(16) . 4_655 ?
O141 Dy2 N141 26.33(13) 4_655 4_655 ?
O151 Dy2 N141 85.61(15) . 4_655 ?
O151 Dy2 N141 63.52(17) 4_655 4_655 ?
O142 Dy2 N141 147.61(15) . 4_655 ?
O142 Dy2 N141 25.03(13) 4_655 4_655 ?
O112 Dy2 N141 72.29(16) . 4_655 ?
O112 Dy2 N141 140.41(16) 4_655 4_655 ?
N151 Dy2 N141 73.20(13) . 4_655 ?
C12 O11 Dy1 129.1(4) . . ?
C13 O12 C24 116.7(4) . . ?
C13 O12 Dy1 113.9(3) . . ?
C24 O12 Dy1 129.0(3) . . ?
C32 O31 Dy1 128.6(4) . . ?
C33 O32 C44 117.3(4) . . ?
C33 O32 Dy1 113.6(3) . . ?
C44 O32 Dy1 128.5(3) . . ?
N41 O41 Dy1 95.2(4) . . ?
N41 O42 Dy1 96.6(4) . . ?
N51 O51 Dy1 96.9(4) . . ?
N51 O52 Dy1 95.2(4) . . ?
N61 O61 Dy1 92.2(5) . . ?
N61 O62 Dy1 95.3(6) . . ?
C113 O112 C124 114.6(5) . . ?
C113 O112 Dy2 117.6(3) . . ?
C124 O112 Dy2 127.7(3) . . ?
N141 O141 Dy2 96.5(3) . . ?
N141 O142 Dy2 95.2(3) . . ?
N151 O151 Dy2 93.9(4) . . ?
C16 C11 C12 120.6(5) . . ?
C16 C11 C17 119.4(5) . . ?
C12 C11 C17 120.0(5) . . ?
O11 C12 C13 119.6(5) . . ?
O11 C12 C11 123.0(5) . . ?
C13 C12 C11 117.3(5) . . ?
C14 C13 O12 125.4(5) . . ?
C14 C13 C12 121.7(5) . . ?
O12 C13 C12 112.9(5) . . ?
C13 C14 C15 120.5(6) . . ?
C13 C14 H14A 119.8 . . ?
C15 C14 H14A 119.8 . . ?
C16 C15 C14 118.6(5) . . ?
C16 C15 H15A 120.7 . . ?
C14 C15 H15A 120.7 . . ?
C15 C16 C11 121.3(5) . . ?
C15 C16 H16A 119.3 . . ?
C11 C16 H16A 119.3 . . ?
N11 C17 C11 122.4(5) . . ?
N11 C17 H17A 118.8 . . ?
C11 C17 H17A 118.8 . . ?
C19 C18 C23 121.9(6) . . ?
C19 C18 N11 116.3(5) . . ?
C23 C18 N11 121.8(5) . . ?
C18 C19 C20 119.0(6) . . ?
C18 C19 H19A 120.5 . . ?
C20 C19 H19A 120.5 . . ?
C21 C20 C19 119.7(6) . . ?
C21 C20 H20A 120.1 . . ?
C19 C20 H20A 120.1 . . ?
C20 C21 C22 120.2(6) . . ?
C20 C21 H21A 119.9 . . ?
C22 C21 H21A 119.9 . . ?
C23 C22 C21 120.9(6) . . ?
C23 C22 H22A 119.6 . . ?
C21 C22 H22A 119.6 . . ?
C22 C23 C18 118.2(6) . . ?
C22 C23 H23A 120.9 . . ?
C18 C23 H23A 120.9 . . ?
O12 C24 H24A 109.5 . . ?
O12 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
O12 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C37 C31 C32 121.2(5) . . ?
C37 C31 C36 120.2(5) . . ?
C32 C31 C36 118.5(5) . . ?
O31 C32 C33 118.9(5) . . ?
O31 C32 C31 122.4(5) . . ?
C33 C32 C31 118.7(5) . . ?
C34 C33 O32 125.6(5) . . ?
C34 C33 C32 120.9(5) . . ?
O32 C33 C32 113.5(5) . . ?
C33 C34 C35 120.2(6) . . ?
C33 C34 H34A 119.9 . . ?
C35 C34 H34A 119.9 . . ?
C36 C35 C34 120.2(5) . . ?
C36 C35 H35A 119.9 . . ?
C34 C35 H35A 119.9 . . ?
C35 C36 C31 121.4(5) . . ?
C35 C36 H36A 119.3 . . ?
C31 C36 H36A 119.3 . . ?
N31 C37 C31 121.8(5) . . ?
N31 C37 H37A 119.1 . . ?
C31 C37 H37A 119.1 . . ?
C43 C38 C39 120.7(6) . . ?
C43 C38 N31 123.7(6) . . ?
C39 C38 N31 115.6(5) . . ?
C40 C39 C38 119.3(6) . . ?
C40 C39 H39A 120.4 . . ?
C38 C39 H39A 120.4 . . ?
C41 C40 C39 120.3(6) . . ?
C41 C40 H40A 119.8 . . ?
C39 C40 H40A 119.8 . . ?
C40 C41 C42 120.2(7) . . ?
C40 C41 H41A 119.9 . . ?
C42 C41 H41A 119.9 . . ?
C41 C42 C43 120.1(6) . . ?
C41 C42 H42A 120.0 . . ?
C43 C42 H42A 120.0 . . ?
C38 C43 C42 119.4(6) . . ?
C38 C43 H43A 120.3 . . ?
C42 C43 H43A 120.3 . . ?
O32 C44 H44A 109.5 . . ?
O32 C44 H44B 109.5 . . ?
H44A C44 H44B 109.5 . . ?
O32 C44 H44C 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
C112 C111 C116 120.6(5) . . ?
C112 C111 C117 121.0(5) . . ?
C116 C111 C117 118.4(5) . . ?
O111 C112 C113 120.4(5) . . ?
O111 C112 C111 122.0(5) . . ?
C113 C112 C111 117.6(5) . . ?
C114 C113 O112 126.4(5) . . ?
C114 C113 C112 122.3(5) . . ?
O112 C113 C112 111.4(5) . . ?
C113 C114 C115 119.2(6) . . ?
C113 C114 H11A 120.4 . . ?
C115 C114 H11A 120.4 . . ?
C116 C115 C114 121.2(6) . . ?
C116 C115 H11B 119.4 . . ?
C114 C115 H11B 119.4 . . ?
C115 C116 C111 119.1(6) . . ?
C115 C116 H11C 120.4 . . ?
C111 C116 H11C 120.4 . . ?
N111 C117 C111 121.6(5) . . ?
N111 C117 H11D 119.2 . . ?
C111 C117 H11D 119.2 . . ?
C123 C118 C119 121.1(6) . . ?
C123 C118 N111 122.1(5) . . ?
C119 C118 N111 116.7(5) . . ?
C120 C119 C118 119.7(6) . . ?
C120 C119 H11E 120.1 . . ?
C118 C119 H11E 120.1 . . ?
C119 C120 C121 119.4(6) . . ?
C119 C120 H12A 120.3 . . ?
C121 C120 H12A 120.3 . . ?
C122 C121 C120 120.4(5) . . ?
C122 C121 H12B 119.8 . . ?
C120 C121 H12B 119.8 . . ?
C121 C122 C123 120.7(5) . . ?
C121 C122 H12C 119.6 . . ?
C123 C122 H12C 119.6 . . ?
C118 C123 C122 118.5(6) . . ?
C118 C123 H12D 120.7 . . ?
C122 C123 H12D 120.7 . . ?
O112 C124 H12E 109.5 . . ?
O112 C124 H12F 109.5 . . ?
H12E C124 H12F 109.5 . . ?
O112 C124 H12G 109.5 . . ?
H12E C124 H12G 109.5 . . ?
H12F C124 H12G 109.5 . . ?
C17 N11 C18 129.1(5) . . ?
C17 N11 H11F 115.4 . . ?
C18 N11 H11F 115.4 . . ?
C37 N31 C38 127.6(5) . . ?
C37 N31 H31A 116.2 . . ?
C38 N31 H31A 116.2 . . ?
O43 N41 O42 122.6(7) . . ?
O43 N41 O41 120.7(6) . . ?
O42 N41 O41 116.6(6) . . ?
O43 N41 Dy1 179.7(6) . . ?
O42 N41 Dy1 57.7(4) . . ?
O41 N41 Dy1 59.0(3) . . ?
O51 N51 O53 122.4(7) . . ?
O51 N51 O52 116.1(7) . . ?
O53 N51 O52 121.4(7) . . ?
O51 N51 Dy1 58.2(4) . . ?
O53 N51 Dy1 178.6(4) . . ?
O52 N51 Dy1 58.1(4) . . ?
O63 N61 O62 120.5(12) . . ?
O63 N61 O61 120.0(11) . . ?
O62 N61 O61 119.1(7) . . ?
O63 N61 Dy1 177.2(6) . . ?
O62 N61 Dy1 58.2(4) . . ?
O61 N61 Dy1 61.0(4) . . ?
C117 N111 C118 128.5(5) . . ?
C117 N111 H11G 115.8 . . ?
C118 N111 H11G 115.8 . . ?
O143 N141 O142 123.6(5) . . ?
O143 N141 O141 120.0(5) . . ?
O142 N141 O141 116.3(5) . . ?
O143 N141 Dy2 171.1(5) . . ?
O142 N141 Dy2 59.8(3) . . ?
O141 N141 Dy2 57.1(3) . . ?
O151 N151 O151 121.4(8) . 4_655 ?
O151 N151 O153 119.3(4) . . ?
O151 N151 O153 119.3(4) 4_655 . ?
O151 N151 Dy2 60.7(4) . . ?
O151 N151 Dy2 60.7(4) 4_655 . ?
O153 N151 Dy2 180.0 . . ?
C112 O111 Dy2 126.0(3) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O31 Dy1 O11 C12 144.1(4) . . . . ?
O62 Dy1 O11 C12 98.4(5) . . . . ?
O52 Dy1 O11 C12 -53.7(4) . . . . ?
O42 Dy1 O11 C12 -173.3(5) . . . . ?
O51 Dy1 O11 C12 -18.8(5) . . . . ?
O41 Dy1 O11 C12 -119.7(5) . . . . ?
O61 Dy1 O11 C12 58.0(5) . . . . ?
O12 Dy1 O11 C12 13.0(4) . . . . ?
O32 Dy1 O11 C12 -114.9(4) . . . . ?
N61 Dy1 O11 C12 78.2(5) . . . . ?
N51 Dy1 O11 C12 -36.5(5) . . . . ?
O11 Dy1 O12 C13 -11.5(4) . . . . ?
O31 Dy1 O12 C13 -146.7(4) . . . . ?
O62 Dy1 O12 C13 -92.2(4) . . . . ?
O52 Dy1 O12 C13 86.6(4) . . . . ?
O42 Dy1 O12 C13 -20.5(5) . . . . ?
O51 Dy1 O12 C13 141.9(4) . . . . ?
O41 Dy1 O12 C13 39.8(4) . . . . ?
O61 Dy1 O12 C13 -146.2(5) . . . . ?
O32 Dy1 O12 C13 118.4(4) . . . . ?
N61 Dy1 O12 C13 -117.7(5) . . . . ?
N51 Dy1 O12 C13 115.7(4) . . . . ?
O11 Dy1 O12 C24 175.5(5) . . . . ?
O31 Dy1 O12 C24 40.4(5) . . . . ?
O62 Dy1 O12 C24 94.8(5) . . . . ?
O52 Dy1 O12 C24 -86.3(5) . . . . ?
O42 Dy1 O12 C24 166.5(4) . . . . ?
O51 Dy1 O12 C24 -31.0(4) . . . . ?
O41 Dy1 O12 C24 -133.1(4) . . . . ?
O61 Dy1 O12 C24 40.8(5) . . . . ?
O32 Dy1 O12 C24 -54.5(5) . . . . ?
N61 Dy1 O12 C24 69.3(5) . . . . ?
N51 Dy1 O12 C24 -57.2(5) . . . . ?
O11 Dy1 O31 C32 148.0(4) . . . . ?
O62 Dy1 O31 C32 -165.7(5) . . . . ?
O52 Dy1 O31 C32 -8.3(6) . . . . ?
O42 Dy1 O31 C32 105.1(5) . . . . ?
O51 Dy1 O31 C32 -45.7(5) . . . . ?
O41 Dy1 O31 C32 64.6(5) . . . . ?
O61 Dy1 O31 C32 -109.8(5) . . . . ?
O12 Dy1 O31 C32 -109.3(5) . . . . ?
O32 Dy1 O31 C32 17.7(4) . . . . ?
N61 Dy1 O31 C32 -138.1(6) . . . . ?
N51 Dy1 O31 C32 -31.5(5) . . . . ?
O11 Dy1 O32 C33 -149.5(3) . . . . ?
O31 Dy1 O32 C33 -15.2(3) . . . . ?
O62 Dy1 O32 C33 -20.0(5) . . . . ?
O52 Dy1 O32 C33 144.5(4) . . . . ?
O42 Dy1 O32 C33 -92.8(4) . . . . ?
O51 Dy1 O32 C33 89.9(4) . . . . ?
O41 Dy1 O32 C33 -144.5(4) . . . . ?
O61 Dy1 O32 C33 37.4(4) . . . . ?
O12 Dy1 O32 C33 113.9(4) . . . . ?
N61 Dy1 O32 C33 13.9(5) . . . . ?
N51 Dy1 O32 C33 116.5(4) . . . . ?
O11 Dy1 O32 C44 40.2(5) . . . . ?
O31 Dy1 O32 C44 174.5(5) . . . . ?
O62 Dy1 O32 C44 169.8(5) . . . . ?
O52 Dy1 O32 C44 -25.8(5) . . . . ?
O42 Dy1 O32 C44 96.9(5) . . . . ?
O51 Dy1 O32 C44 -80.4(5) . . . . ?
O41 Dy1 O32 C44 45.2(5) . . . . ?
O61 Dy1 O32 C44 -132.8(5) . . . . ?
O12 Dy1 O32 C44 -56.4(5) . . . . ?
N61 Dy1 O32 C44 -156.3(5) . . . . ?
N51 Dy1 O32 C44 -53.8(5) . . . . ?
O11 Dy1 O41 N41 -86.4(4) . . . . ?
O31 Dy1 O41 N41 51.8(4) . . . . ?
O62 Dy1 O41 N41 -32.4(4) . . . . ?
O52 Dy1 O41 N41 179.6(4) . . . . ?
O42 Dy1 O41 N41 -1.3(3) . . . . ?
O51 Dy1 O41 N41 149.9(4) . . . . ?
O61 Dy1 O41 N41 115.3(19) . . . . ?
O12 Dy1 O41 N41 -132.8(3) . . . . ?
O32 Dy1 O41 N41 97.2(4) . . . . ?
N61 Dy1 O41 N41 -30.3(7) . . . . ?
N51 Dy1 O41 N41 165.1(4) . . . . ?
O11 Dy1 O42 N41 80.6(4) . . . . ?
O31 Dy1 O42 N41 -126.2(4) . . . . ?
O62 Dy1 O42 N41 158.7(4) . . . . ?
O52 Dy1 O42 N41 2.3(4) . . . . ?
O51 Dy1 O42 N41 -58.4(5) . . . . ?
O41 Dy1 O42 N41 1.3(3) . . . . ?
O61 Dy1 O42 N41 -171.6(4) . . . . ?
O12 Dy1 O42 N41 88.9(4) . . . . ?
O32 Dy1 O42 N41 -63.2(4) . . . . ?
N61 Dy1 O42 N41 170.5(4) . . . . ?
N51 Dy1 O42 N41 -19.4(4) . . . . ?
O11 Dy1 O51 N51 -43.7(4) . . . . ?
O31 Dy1 O51 N51 147.2(4) . . . . ?
O62 Dy1 O51 N51 -139.6(4) . . . . ?
O52 Dy1 O51 N51 3.2(4) . . . . ?
O42 Dy1 O51 N51 84.0(5) . . . . ?
O41 Dy1 O51 N51 38.4(4) . . . . ?
O61 Dy1 O51 N51 -145.3(4) . . . . ?
O12 Dy1 O51 N51 -73.3(4) . . . . ?
O32 Dy1 O51 N51 89.1(4) . . . . ?
N61 Dy1 O51 N51 -141.5(4) . . . . ?
O11 Dy1 O52 N51 141.1(4) . . . . ?
O31 Dy1 O52 N51 -53.9(4) . . . . ?
O62 Dy1 O52 N51 81.7(5) . . . . ?
O42 Dy1 O52 N51 -147.0(3) . . . . ?
O51 Dy1 O52 N51 -3.0(3) . . . . ?
O41 Dy1 O52 N51 -146.2(4) . . . . ?
O61 Dy1 O52 N51 28.0(4) . . . . ?
O12 Dy1 O52 N51 79.6(4) . . . . ?
O32 Dy1 O52 N51 -77.6(3) . . . . ?
N61 Dy1 O52 N51 48.0(5) . . . . ?
O11 Dy1 O61 N61 50.0(5) . . . . ?
O31 Dy1 O61 N61 -87.2(4) . . . . ?
O62 Dy1 O61 N61 -2.3(4) . . . . ?
O52 Dy1 O61 N61 145.5(4) . . . . ?
O42 Dy1 O61 N61 -40.4(5) . . . . ?
O51 Dy1 O61 N61 171.5(5) . . . . ?
O41 Dy1 O61 N61 -152.5(18) . . . . ?
O12 Dy1 O61 N61 93.1(4) . . . . ?
O32 Dy1 O61 N61 -135.2(4) . . . . ?
N51 Dy1 O61 N61 157.7(4) . . . . ?
O11 Dy1 O62 N61 -129.3(5) . . . . ?
O31 Dy1 O62 N61 79.1(4) . . . . ?
O52 Dy1 O62 N61 -67.6(5) . . . . ?
O42 Dy1 O62 N61 154.4(5) . . . . ?
O51 Dy1 O62 N61 -4.2(5) . . . . ?
O41 Dy1 O62 N61 178.3(4) . . . . ?
O61 Dy1 O62 N61 2.3(4) . . . . ?
O12 Dy1 O62 N61 -65.6(5) . . . . ?
O32 Dy1 O62 N61 83.4(6) . . . . ?
N51 Dy1 O62 N61 -27.4(5) . . . . ?
O111 Dy2 O112 C113 -155.0(4) 4_655 . . . ?
O111 Dy2 O112 C113 -2.0(3) . . . . ?
O141 Dy2 O112 C113 -104.7(4) . . . . ?
O141 Dy2 O112 C113 82.3(4) 4_655 . . . ?
O151 Dy2 O112 C113 50.1(5) . . . . ?
O151 Dy2 O112 C113 127.3(4) 4_655 . . . ?
O142 Dy2 O112 C113 -38.1(4) . . . . ?
O142 Dy2 O112 C113 135.9(4) 4_655 . . . ?
O112 Dy2 O112 C113 -88.6(4) 4_655 . . . ?
N151 Dy2 O112 C113 91.4(4) . . . . ?
N141 Dy2 O112 C113 109.6(4) 4_655 . . . ?
O111 Dy2 O112 C124 21.1(5) 4_655 . . . ?
O111 Dy2 O112 C124 174.1(5) . . . . ?
O141 Dy2 O112 C124 71.5(5) . . . . ?
O141 Dy2 O112 C124 -101.6(5) 4_655 . . . ?
O151 Dy2 O112 C124 -133.8(4) . . . . ?
O151 Dy2 O112 C124 -56.6(5) 4_655 . . . ?
O142 Dy2 O112 C124 138.0(4) . . . . ?
O142 Dy2 O112 C124 -48.0(4) 4_655 . . . ?
O112 Dy2 O112 C124 87.5(5) 4_655 . . . ?
N151 Dy2 O112 C124 -92.5(5) . . . . ?
N141 Dy2 O112 C124 -74.3(5) 4_655 . . . ?
O111 Dy2 O141 N141 146.1(4) 4_655 . . . ?
O111 Dy2 O141 N141 10.3(4) . . . . ?
O141 Dy2 O141 N141 -94.5(4) 4_655 . . . ?
O151 Dy2 O141 N141 -67.6(4) . . . . ?
O151 Dy2 O141 N141 -121.5(4) 4_655 . . . ?
O142 Dy2 O141 N141 4.8(4) . . . . ?
O142 Dy2 O141 N141 -161.5(4) 4_655 . . . ?
O112 Dy2 O141 N141 95.6(4) . . . . ?
O112 Dy2 O141 N141 79.8(4) 4_655 . . . ?
N151 Dy2 O141 N141 -94.5(4) . . . . ?
N141 Dy2 O141 N141 -132.1(4) 4_655 . . . ?
O111 Dy2 O142 N141 -49.2(4) 4_655 . . . ?
O111 Dy2 O142 N141 -179.8(4) . . . . ?
O141 Dy2 O142 N141 -5.1(4) . . . . ?
O141 Dy2 O142 N141 122.6(4) 4_655 . . . ?
O151 Dy2 O142 N141 80.5(4) . . . . ?
O151 Dy2 O142 N141 46.3(4) 4_655 . . . ?
O142 Dy2 O142 N141 62.8(4) 4_655 . . . ?
O112 Dy2 O142 N141 -144.5(4) . . . . ?
O112 Dy2 O142 N141 -92.6(4) 4_655 . . . ?
N151 Dy2 O142 N141 62.8(4) . . . . ?
N141 Dy2 O142 N141 107.4(6) 4_655 . . . ?
O111 Dy2 O151 N151 -29.3(3) 4_655 . . . ?
O111 Dy2 O151 N151 159.9(2) . . . . ?
O141 Dy2 O151 N151 -80.0(2) . . . . ?
O141 Dy2 O151 N151 81.3(2) 4_655 . . . ?
O151 Dy2 O151 N151 0.0 4_655 . . . ?
O142 Dy2 O151 N151 -135.1(3) . . . . ?
O142 Dy2 O151 N151 41.1(2) 4_655 . . . ?
O112 Dy2 O151 N151 114.4(2) . . . . ?
O112 Dy2 O151 N151 -126.2(2) 4_655 . . . ?
N141 Dy2 O151 N151 59.0(2) 4_655 . . . ?
Dy1 O11 C12 C13 -12.9(7) . . . . ?
Dy1 O11 C12 C11 166.4(4) . . . . ?
C16 C11 C12 O11 -178.9(5) . . . . ?
C17 C11 C12 O11 1.5(9) . . . . ?
C16 C11 C12 C13 0.4(8) . . . . ?
C17 C11 C12 C13 -179.2(5) . . . . ?
C24 O12 C13 C14 4.7(9) . . . . ?
Dy1 O12 C13 C14 -169.2(5) . . . . ?
C24 O12 C13 C12 -175.8(5) . . . . ?
Dy1 O12 C13 C12 10.3(6) . . . . ?
O11 C12 C13 C14 178.6(5) . . . . ?
C11 C12 C13 C14 -0.7(8) . . . . ?
O11 C12 C13 O12 -0.9(8) . . . . ?
C11 C12 C13 O12 179.8(5) . . . . ?
O12 C13 C14 C15 -179.7(6) . . . . ?
C12 C13 C14 C15 0.8(9) . . . . ?
C13 C14 C15 C16 -0.7(9) . . . . ?
C14 C15 C16 C11 0.4(9) . . . . ?
C12 C11 C16 C15 -0.3(9) . . . . ?
C17 C11 C16 C15 179.3(6) . . . . ?
C16 C11 C17 N11 -178.0(5) . . . . ?
C12 C11 C17 N11 1.5(9) . . . . ?
C23 C18 C19 C20 2.3(10) . . . . ?
N11 C18 C19 C20 -178.7(6) . . . . ?
C18 C19 C20 C21 -1.1(10) . . . . ?
C19 C20 C21 C22 -0.8(10) . . . . ?
C20 C21 C22 C23 1.5(10) . . . . ?
C21 C22 C23 C18 -0.3(9) . . . . ?
C19 C18 C23 C22 -1.6(9) . . . . ?
N11 C18 C23 C22 179.4(5) . . . . ?
Dy1 O31 C32 C33 -18.0(8) . . . . ?
Dy1 O31 C32 C31 162.7(4) . . . . ?
C37 C31 C32 O31 2.7(9) . . . . ?
C36 C31 C32 O31 -179.7(5) . . . . ?
C37 C31 C32 C33 -176.6(5) . . . . ?
C36 C31 C32 C33 1.0(8) . . . . ?
C44 O32 C33 C34 4.6(8) . . . . ?
Dy1 O32 C33 C34 -166.8(5) . . . . ?
C44 O32 C33 C32 -175.1(5) . . . . ?
Dy1 O32 C33 C32 13.4(6) . . . . ?
O31 C32 C33 C34 179.8(5) . . . . ?
C31 C32 C33 C34 -0.9(8) . . . . ?
O31 C32 C33 O32 -0.4(8) . . . . ?
C31 C32 C33 O32 178.9(5) . . . . ?
O32 C33 C34 C35 179.9(5) . . . . ?
C32 C33 C34 C35 -0.4(9) . . . . ?
C33 C34 C35 C36 1.5(9) . . . . ?
C34 C35 C36 C31 -1.3(9) . . . . ?
C37 C31 C36 C35 177.7(6) . . . . ?
C32 C31 C36 C35 0.1(8) . . . . ?
C32 C31 C37 N31 0.2(9) . . . . ?
C36 C31 C37 N31 -177.4(5) . . . . ?
C43 C38 C39 C40 -0.1(9) . . . . ?
N31 C38 C39 C40 178.8(5) . . . . ?
C38 C39 C40 C41 1.4(9) . . . . ?
C39 C40 C41 C42 -0.6(10) . . . . ?
C40 C41 C42 C43 -1.4(11) . . . . ?
C39 C38 C43 C42 -2.0(9) . . . . ?
N31 C38 C43 C42 179.2(6) . . . . ?
C41 C42 C43 C38 2.7(10) . . . . ?
C116 C111 C112 O111 -179.0(5) . . . . ?
C117 C111 C112 O111 4.6(8) . . . . ?
C116 C111 C112 C113 3.2(8) . . . . ?
C117 C111 C112 C113 -173.1(5) . . . . ?
C124 O112 C113 C114 4.9(8) . . . . ?
Dy2 O112 C113 C114 -178.4(5) . . . . ?
C124 O112 C113 C112 -175.0(5) . . . . ?
Dy2 O112 C113 C112 1.6(6) . . . . ?
O111 C112 C113 C114 -179.6(5) . . . . ?
C111 C112 C113 C114 -1.8(8) . . . . ?
O111 C112 C113 O112 0.3(7) . . . . ?
C111 C112 C113 O112 178.1(5) . . . . ?
O112 C113 C114 C115 -179.9(5) . . . . ?
C112 C113 C114 C115 0.1(9) . . . . ?
C113 C114 C115 C116 0.3(9) . . . . ?
C114 C115 C116 C111 1.1(9) . . . . ?
C112 C111 C116 C115 -2.9(8) . . . . ?
C117 C111 C116 C115 173.6(5) . . . . ?
C112 C111 C117 N111 3.7(8) . . . . ?
C116 C111 C117 N111 -172.8(5) . . . . ?
C123 C118 C119 C120 0.4(9) . . . . ?
N111 C118 C119 C120 -179.9(5) . . . . ?
C118 C119 C120 C121 0.8(9) . . . . ?
C119 C120 C121 C122 -2.1(9) . . . . ?
C120 C121 C122 C123 2.2(9) . . . . ?
C119 C118 C123 C122 -0.3(8) . . . . ?
N111 C118 C123 C122 180.0(5) . . . . ?
C121 C122 C123 C118 -1.0(9) . . . . ?
C11 C17 N11 C18 -179.0(5) . . . . ?
C19 C18 N11 C17 -174.3(6) . . . . ?
C23 C18 N11 C17 4.7(9) . . . . ?
C31 C37 N31 C38 -180.0(5) . . . . ?
C43 C38 N31 C37 8.8(10) . . . . ?
C39 C38 N31 C37 -170.1(6) . . . . ?
Dy1 O42 N41 O43 179.9(6) . . . . ?
Dy1 O42 N41 O41 -2.3(6) . . . . ?
Dy1 O41 N41 O43 -179.9(5) . . . . ?
Dy1 O41 N41 O42 2.3(6) . . . . ?
O11 Dy1 N41 O43 103(100) . . . . ?
O31 Dy1 N41 O43 -114(100) . . . . ?
O62 Dy1 N41 O43 173(100) . . . . ?
O52 Dy1 N41 O43 17(100) . . . . ?
O42 Dy1 N41 O43 -165(100) . . . . ?
O51 Dy1 N41 O43 -21(100) . . . . ?
O41 Dy1 N41 O43 17(100) . . . . ?
O61 Dy1 N41 O43 -149(100) . . . . ?
O12 Dy1 N41 O43 79(100) . . . . ?
O32 Dy1 N41 O43 -54(100) . . . . ?
N61 Dy1 N41 O43 -178(100) . . . . ?
N51 Dy1 N41 O43 1(100) . . . . ?
O11 Dy1 N41 O42 -92.0(4) . . . . ?
O31 Dy1 N41 O42 51.1(4) . . . . ?
O62 Dy1 N41 O42 -22.5(4) . . . . ?
O52 Dy1 N41 O42 -178.0(4) . . . . ?
O51 Dy1 N41 O42 144.0(3) . . . . ?
O41 Dy1 N41 O42 -177.6(6) . . . . ?
O61 Dy1 N41 O42 15.9(7) . . . . ?
O12 Dy1 N41 O42 -116.2(3) . . . . ?
O32 Dy1 N41 O42 110.5(4) . . . . ?
N61 Dy1 N41 O42 -12.6(5) . . . . ?
N51 Dy1 N41 O42 166.1(3) . . . . ?
O11 Dy1 N41 O41 85.5(4) . . . . ?
O31 Dy1 N41 O41 -131.3(4) . . . . ?
O62 Dy1 N41 O41 155.1(3) . . . . ?
O52 Dy1 N41 O41 -0.4(4) . . . . ?
O42 Dy1 N41 O41 177.6(6) . . . . ?
O51 Dy1 N41 O41 -38.4(4) . . . . ?
O61 Dy1 N41 O41 -166.5(5) . . . . ?
O12 Dy1 N41 O41 61.3(4) . . . . ?
O32 Dy1 N41 O41 -71.9(3) . . . . ?
N61 Dy1 N41 O41 165.0(4) . . . . ?
N51 Dy1 N41 O41 -16.3(4) . . . . ?
Dy1 O51 N51 O53 178.6(5) . . . . ?
Dy1 O51 N51 O52 -5.2(6) . . . . ?
Dy1 O52 N51 O51 5.2(6) . . . . ?
Dy1 O52 N51 O53 -178.5(5) . . . . ?
O11 Dy1 N51 O51 144.5(4) . . . . ?
O31 Dy1 N51 O51 -35.9(4) . . . . ?
O62 Dy1 N51 O51 54.9(4) . . . . ?
O52 Dy1 N51 O51 -174.5(6) . . . . ?
O42 Dy1 N51 O51 -127.9(4) . . . . ?
O41 Dy1 N51 O51 -143.9(4) . . . . ?
O61 Dy1 N51 O51 31.5(4) . . . . ?
O12 Dy1 N51 O51 96.8(4) . . . . ?
O32 Dy1 N51 O51 -81.1(4) . . . . ?
N61 Dy1 N51 O51 42.1(4) . . . . ?
O11 Dy1 N51 O53 26(26) . . . . ?
O31 Dy1 N51 O53 -154(100) . . . . ?
O62 Dy1 N51 O53 -63(26) . . . . ?
O52 Dy1 N51 O53 67(26) . . . . ?
O42 Dy1 N51 O53 114(26) . . . . ?
O51 Dy1 N51 O53 -118(27) . . . . ?
O41 Dy1 N51 O53 98(26) . . . . ?
O61 Dy1 N51 O53 -87(26) . . . . ?
O12 Dy1 N51 O53 -21(26) . . . . ?
O32 Dy1 N51 O53 161(100) . . . . ?
N61 Dy1 N51 O53 -76(26) . . . . ?
O11 Dy1 N51 O52 -41.0(4) . . . . ?
O31 Dy1 N51 O52 138.6(3) . . . . ?
O62 Dy1 N51 O52 -130.6(4) . . . . ?
O42 Dy1 N51 O52 46.6(4) . . . . ?
O51 Dy1 N51 O52 174.5(6) . . . . ?
O41 Dy1 N51 O52 30.5(4) . . . . ?
O61 Dy1 N51 O52 -154.0(4) . . . . ?
O12 Dy1 N51 O52 -88.7(3) . . . . ?
O32 Dy1 N51 O52 93.4(4) . . . . ?
N61 Dy1 N51 O52 -143.4(4) . . . . ?
Dy1 O62 N61 O63 -177.1(7) . . . . ?
Dy1 O62 N61 O61 -4.1(8) . . . . ?
Dy1 O61 N61 O63 177.0(7) . . . . ?
Dy1 O61 N61 O62 4.0(7) . . . . ?
O11 Dy1 N61 O63 112(21) . . . . ?
O31 Dy1 N61 O63 -30(21) . . . . ?
O62 Dy1 N61 O63 63(21) . . . . ?
O52 Dy1 N61 O63 -159(21) . . . . ?
O42 Dy1 N61 O63 35(22) . . . . ?
O51 Dy1 N61 O63 -121(21) . . . . ?
O41 Dy1 N61 O63 59(22) . . . . ?
O61 Dy1 N61 O63 -113(22) . . . . ?
O12 Dy1 N61 O63 170(22) . . . . ?
O32 Dy1 N61 O63 -57(22) . . . . ?
N51 Dy1 N61 O63 -137(21) . . . . ?
O11 Dy1 N61 O62 49.2(5) . . . . ?
O31 Dy1 N61 O62 -92.6(5) . . . . ?
O52 Dy1 N61 O62 138.8(4) . . . . ?
O42 Dy1 N61 O62 -27.1(5) . . . . ?
O51 Dy1 N61 O62 176.3(5) . . . . ?
O41 Dy1 N61 O62 -3.4(8) . . . . ?
O61 Dy1 N61 O62 -175.9(8) . . . . ?
O12 Dy1 N61 O62 107.8(5) . . . . ?
O32 Dy1 N61 O62 -119.5(5) . . . . ?
N51 Dy1 N61 O62 160.0(4) . . . . ?
O11 Dy1 N61 O61 -134.9(4) . . . . ?
O31 Dy1 N61 O61 83.3(4) . . . . ?
O62 Dy1 N61 O61 175.9(8) . . . . ?
O52 Dy1 N61 O61 -45.3(5) . . . . ?
O42 Dy1 N61 O61 148.8(4) . . . . ?
O51 Dy1 N61 O61 -7.8(4) . . . . ?
O41 Dy1 N61 O61 172.5(4) . . . . ?
O12 Dy1 N61 O61 -76.2(4) . . . . ?
O32 Dy1 N61 O61 56.4(5) . . . . ?
N51 Dy1 N61 O61 -24.1(5) . . . . ?
C111 C117 N111 C118 173.9(5) . . . . ?
C123 C118 N111 C117 -7.7(9) . . . . ?
C119 C118 N111 C117 172.6(5) . . . . ?
Dy2 O142 N141 O143 -170.3(7) . . . . ?
Dy2 O142 N141 O141 8.4(6) . . . . ?
Dy2 O141 N141 O143 170.1(6) . . . . ?
Dy2 O141 N141 O142 -8.6(6) . . . . ?
O111 Dy2 N141 O143 -108(3) 4_655 . . . ?
O111 Dy2 N141 O143 115(3) . . . . ?
O141 Dy2 N141 O143 -74(3) . . . . ?
O141 Dy2 N141 O143 39(3) 4_655 . . . ?
O151 Dy2 N141 O143 28(3) . . . . ?
O151 Dy2 N141 O143 -20(3) 4_655 . . . ?
O142 Dy2 N141 O143 115(3) . . . . ?
O142 Dy2 N141 O143 -45(3) 4_655 . . . ?
O112 Dy2 N141 O143 166(3) . . . . ?
O112 Dy2 N141 O143 -167(3) 4_655 . . . ?
N151 Dy2 N141 O143 2(3) . . . . ?
N141 Dy2 N141 O143 2(3) 4_655 . . . ?
O111 Dy2 N141 O142 137.3(4) 4_655 . . . ?
O111 Dy2 N141 O142 0.2(4) . . . . ?
O141 Dy2 N141 O142 171.0(7) . . . . ?
O141 Dy2 N141 O142 -76.0(4) 4_655 . . . ?
O151 Dy2 N141 O142 -87.2(4) . . . . ?
O151 Dy2 N141 O142 -135.1(4) 4_655 . . . ?
O142 Dy2 N141 O142 -159.4(4) 4_655 . . . ?
O112 Dy2 N141 O142 50.8(5) . . . . ?
O112 Dy2 N141 O142 78.6(4) 4_655 . . . ?
N151 Dy2 N141 O142 -112.5(4) . . . . ?
N141 Dy2 N141 O142 -112.5(4) 4_655 . . . ?
O111 Dy2 N141 O141 -33.8(4) 4_655 . . . ?
O111 Dy2 N141 O141 -170.9(4) . . . . ?
O141 Dy2 N141 O141 112.9(5) 4_655 . . . ?
O151 Dy2 N141 O141 101.7(4) . . . . ?
O151 Dy2 N141 O141 53.9(4) 4_655 . . . ?
O142 Dy2 N141 O141 -171.0(7) . . . . ?
O142 Dy2 N141 O141 29.6(6) 4_655 . . . ?
O112 Dy2 N141 O141 -120.3(4) . . . . ?
O112 Dy2 N141 O141 -92.5(4) 4_655 . . . ?
N151 Dy2 N141 O141 76.4(4) . . . . ?
N141 Dy2 N141 O141 76.4(4) 4_655 . . . ?
Dy2 O151 N151 O151 0.0 . . . 4_655 ?
Dy2 O151 N151 O153 180.0 . . . . ?
O111 Dy2 N151 O151 158.2(2) 4_655 . . . ?
O111 Dy2 N151 O151 -21.8(2) . . . . ?
O141 Dy2 N151 O151 90.7(2) . . . . ?
O141 Dy2 N151 O151 -89.3(2) 4_655 . . . ?
O151 Dy2 N151 O151 -180.0 4_655 . . . ?
O142 Dy2 N151 O151 40.1(2) . . . . ?
O142 Dy2 N151 O151 -139.9(2) 4_655 . . . ?
O112 Dy2 N151 O151 -98.7(3) . . . . ?
O112 Dy2 N151 O151 81.3(3) 4_655 . . . ?
N141 Dy2 N151 O151 -116.8(3) 4_655 . . . ?
O111 Dy2 N151 O151 -21.8(2) 4_655 . . 4_655 ?
O111 Dy2 N151 O151 158.2(2) . . . 4_655 ?
O141 Dy2 N151 O151 -89.3(2) . . . 4_655 ?
O141 Dy2 N151 O151 90.7(2) 4_655 . . 4_655 ?
O151 Dy2 N151 O151 180.0 . . . 4_655 ?
O142 Dy2 N151 O151 -139.9(2) . . . 4_655 ?
O142 Dy2 N151 O151 40.1(2) 4_655 . . 4_655 ?
O112 Dy2 N151 O151 81.3(3) . . . 4_655 ?
O112 Dy2 N151 O151 -98.7(3) 4_655 . . 4_655 ?
N141 Dy2 N151 O151 63.2(3) 4_655 . . 4_655 ?
O111 Dy2 N151 O153 5(100) 4_655 . . . ?
O111 Dy2 N151 O153 -175(100) . . . . ?
O141 Dy2 N151 O153 -63(100) . . . . ?
O141 Dy2 N151 O153 117(100) 4_655 . . . ?
O151 Dy2 N151 O153 -153(100) . . . . ?
O151 Dy2 N151 O153 27(100) 4_655 . . . ?
O142 Dy2 N151 O153 -113(100) . . . . ?
O142 Dy2 N151 O153 67(100) 4_655 . . . ?
O112 Dy2 N151 O153 108(100) . . . . ?
O112 Dy2 N151 O153 -72(100) 4_655 . . . ?
N141 Dy2 N151 O153 90(100) 4_655 . . . ?
C113 C112 O111 Dy2 -2.5(7) . . . . ?
C111 C112 O111 Dy2 179.8(4) . . . . ?
O111 Dy2 O111 C112 41.9(4) 4_655 . . . ?
O141 Dy2 O111 C112 144.7(4) . . . . ?
O141 Dy2 O111 C112 -76.6(4) 4_655 . . . ?
O151 Dy2 O111 C112 -147.2(4) . . . . ?
O151 Dy2 O111 C112 -125.0(4) 4_655 . . . ?
O142 Dy2 O111 C112 149.4(4) . . . . ?
O142 Dy2 O111 C112 -43.0(4) 4_655 . . . ?
O112 Dy2 O111 C112 2.4(4) . . . . ?
O112 Dy2 O111 C112 77.7(4) 4_655 . . . ?
N151 Dy2 O111 C112 -138.1(4) . . . . ?
N141 Dy2 O111 C112 -62.0(4) 4_655 . . . ?

_diffrn_measured_fraction_theta_max 0.992
_diffrn_reflns_theta_full        29.17
_diffrn_measured_fraction_theta_full 0.992
_refine_diff_density_max         2.071
_refine_diff_density_min         -1.099
_refine_diff_density_rms         0.131
_database_code_depnum_ccdc_archive 'CCDC 990257'
