# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2014

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_c:\x-seed\ru2dy2~1\p21n
_database_code_depnum_ccdc_archive 'CCDC 1032631'
_audit_update_record             
;
2014-11-04 deposited with the CCDC.
2014-12-18 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            '[RuIII2DyIII2(OMe)2(O2CPh)4(mdea)2(NO3)2]'
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C40 H48 Dy2 N4 O20 Ru2'
_chemical_formula_weight         1431.96

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   P21/n

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   8.0960(16)
_cell_length_b                   17.161(3)
_cell_length_c                   17.146(3)
_cell_angle_alpha                90.00
_cell_angle_beta                 92.44(3)
_cell_angle_gamma                90.00
_cell_volume                     2380.0(8)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    44448
_cell_measurement_theta_min      2.37
_cell_measurement_theta_max      31.49

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.05
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.998
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1392
_exptl_absorpt_coefficient_mu    3.807
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.563
_exptl_absorpt_correction_T_max  0.873
_exptl_absorpt_process_details   SADABS

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71079
_diffrn_radiation_type           synchrotron
_diffrn_radiation_source         '3BM1 dipole'
_diffrn_radiation_monochromator  'double crystal'
_diffrn_measurement_device_type  synchrotron
_diffrn_measurement_method       'scans in phi'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            44448
_diffrn_reflns_av_R_equivalents  0.0742
_diffrn_reflns_av_sigmaI/netI    0.0425
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_theta_min         2.37
_diffrn_reflns_theta_max         31.49
_reflns_number_total             6208
_reflns_number_gt                5858
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Blu-Ice (McPhillips et al, 2002)'
_computing_cell_refinement       'XDS (Kabsch, 1993)'
_computing_data_reduction        'XDS (Kabsch, 1993)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    X-SEED
_computing_publication_material  'XCIF V6.12 (BrukerAXS, 2001).'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
The crystal was run on the Australian synchrotron in which we were 
restricted to only one 360 degree phi scan.
The asymmetric unit contains half of the cluster, which lies upon
an inversion centre.
All non H-atoms are refined anisotropically 
and all H-atoms are placed in calculated positions. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0381P)²+6.5369P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         6208
_refine_ls_number_parameters     309
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0381
_refine_ls_R_factor_gt           0.0363
_refine_ls_wR_factor_ref         0.0944
_refine_ls_wR_factor_gt          0.0931
_refine_ls_goodness_of_fit_ref   1.055
_refine_ls_restrained_S_all      1.055
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.50359(2) 0.425516(9) 0.589027(9) 0.02978(7) Uani 1 1 d . . .
Ru1 Ru 0.50688(4) 0.614024(17) 0.597836(16) 0.02844(8) Uani 1 1 d . . .
O2 O 0.6864(4) 0.67436(17) 0.44220(16) 0.0370(6) Uani 1 1 d . . .
O1 O 0.6364(3) 0.53323(15) 0.52957(15) 0.0287(5) Uani 1 1 d . . .
O5 O 0.3638(4) 0.52935(16) 0.63449(16) 0.0338(6) Uani 1 1 d . . .
O6 O 0.6612(3) 0.59910(15) 0.69475(15) 0.0322(5) Uani 1 1 d . . .
O4 O 0.3606(3) 0.63766(16) 0.50524(16) 0.0328(5) Uani 1 1 d . . .
O3 O 0.6578(4) 0.70439(15) 0.56847(16) 0.0338(5) Uani 1 1 d . . .
O9 O 0.6100(4) 0.31118(16) 0.65847(16) 0.0400(6) Uani 1 1 d . . .
O7 O 0.6996(4) 0.46981(16) 0.68411(17) 0.0364(6) Uani 1 1 d . . .
O8 O 0.4133(4) 0.37521(18) 0.71348(18) 0.0434(7) Uani 1 1 d . . .
O10 O 0.5230(6) 0.2740(2) 0.7713(2) 0.0663(12) Uani 1 1 d . . .
C2 C 0.7170(5) 0.7154(2) 0.5015(2) 0.0323(7) Uani 1 1 d . . .
N2 N 0.5156(5) 0.3186(2) 0.71600(19) 0.0424(8) Uani 1 1 d . . .
C15 C 0.8447(5) 0.5379(2) 0.7855(2) 0.0320(7) Uani 1 1 d . . .
N1 N 0.3469(5) 0.6854(2) 0.6560(2) 0.0381(7) Uani 1 1 d . . .
C16 C 0.8896(5) 0.6097(2) 0.8179(2) 0.0349(8) Uani 1 1 d . . .
H16 H 0.8427 0.6564 0.7969 0.042 Uiso 1 1 calc R . .
C14 C 0.7270(5) 0.5342(2) 0.7164(2) 0.0308(7) Uani 1 1 d . . .
C4 C 0.9053(5) 0.7963(3) 0.4241(3) 0.0438(10) Uani 1 1 d . . .
H4 H 0.8782 0.7642 0.3802 0.053 Uiso 1 1 calc R . .
C3 C 0.8325(5) 0.7827(2) 0.4944(3) 0.0365(8) Uani 1 1 d . . .
C8 C 0.8697(6) 0.8303(2) 0.5583(3) 0.0446(10) Uani 1 1 d . . .
H8 H 0.8186 0.8213 0.6063 0.053 Uiso 1 1 calc R . .
C20 C 0.9154(6) 0.4700(3) 0.8159(3) 0.0460(10) Uani 1 1 d . . .
H20 H 0.8865 0.4210 0.7935 0.055 Uiso 1 1 calc R . .
C17 C 1.0023(6) 0.6132(3) 0.8809(3) 0.0422(9) Uani 1 1 d . . .
H17 H 1.0328 0.6622 0.9030 0.051 Uiso 1 1 calc R . .
C5 C 1.0182(6) 0.8569(3) 0.4176(4) 0.0539(13) Uani 1 1 d . . .
H5 H 1.0679 0.8665 0.3693 0.065 Uiso 1 1 calc R . .
C19 C 1.0285(8) 0.4741(3) 0.8791(3) 0.0580(14) Uani 1 1 d . . .
H19 H 1.0770 0.4278 0.9000 0.070 Uiso 1 1 calc R . .
C13 C 0.4266(8) 0.7510(3) 0.6976(4) 0.0593(13) Uani 1 1 d . . .
H13A H 0.4815 0.7844 0.6602 0.089 Uiso 1 1 calc R . .
H13B H 0.5087 0.7311 0.7363 0.089 Uiso 1 1 calc R . .
H13C H 0.3430 0.7812 0.7240 0.089 Uiso 1 1 calc R . .
C6 C 1.0569(6) 0.9022(3) 0.4805(4) 0.0607(16) Uani 1 1 d . . .
H6 H 1.1366 0.9424 0.4760 0.073 Uiso 1 1 calc R . .
C7 C 0.9822(7) 0.8914(3) 0.5520(4) 0.0597(14) Uani 1 1 d . . .
H7 H 1.0076 0.9247 0.5950 0.072 Uiso 1 1 calc R . .
C12 C 0.2407(8) 0.5530(3) 0.6857(4) 0.0606(14) Uani 1 1 d . . .
H12A H 0.2404 0.5171 0.7309 0.073 Uiso 1 1 calc R . .
H12B H 0.1309 0.5501 0.6582 0.073 Uiso 1 1 calc R . .
C18 C 1.0702(7) 0.5453(3) 0.9115(3) 0.0508(11) Uani 1 1 d . . .
H18 H 1.1462 0.5478 0.9552 0.061 Uiso 1 1 calc R . .
C1 C 0.8123(6) 0.5328(3) 0.5307(3) 0.0491(10) Uani 1 1 d . . .
H1A H 0.8495 0.5448 0.4783 0.074 Uiso 1 1 calc R . .
H1B H 0.8531 0.4812 0.5467 0.074 Uiso 1 1 calc R . .
H1C H 0.8554 0.5721 0.5677 0.074 Uiso 1 1 calc R . .
C9 C 0.2702(8) 0.7062(3) 0.5174(3) 0.0589(14) Uani 1 1 d . . .
H9A H 0.1704 0.7064 0.4820 0.071 Uiso 1 1 calc R . .
H9B H 0.3386 0.7518 0.5041 0.071 Uiso 1 1 calc R . .
C11 C 0.2701(8) 0.6334(3) 0.7140(4) 0.0601(14) Uani 1 1 d . . .
H11A H 0.3429 0.6315 0.7618 0.072 Uiso 1 1 calc R . .
H11B H 0.1633 0.6563 0.7283 0.072 Uiso 1 1 calc R . .
C10 C 0.2213(10) 0.7136(5) 0.5962(3) 0.086(3) Uani 1 1 d . . .
H10A H 0.1175 0.6840 0.6021 0.104 Uiso 1 1 calc R . .
H10B H 0.1974 0.7691 0.6067 0.104 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O5 2.267(3) . ?
Dy1 O4 2.269(3) 3_666 ?
Dy1 O2 2.350(3) 3_666 ?
Dy1 O7 2.353(3) . ?
Dy1 O1 2.389(3) . ?
Dy1 O1 2.392(3) 3_666 ?
Dy1 O9 2.434(3) . ?
Dy1 O8 2.443(3) . ?
Dy1 N2 2.845(3) . ?
Dy1 Ru1 3.2386(7) . ?
Dy1 Ru1 3.2726(7) 3_666 ?
Dy1 Dy1 3.9804(6) 3_666 ?
Ru1 O5 1.977(3) . ?
Ru1 O4 1.982(3) . ?
Ru1 O3 2.050(3) . ?
Ru1 O6 2.052(3) . ?
Ru1 N1 2.069(3) . ?
Ru1 O1 2.120(3) . ?
Ru1 Dy1 3.2725(7) 3_666 ?
O2 C2 1.254(5) . ?
O2 Dy1 2.350(3) 3_666 ?
O1 C1 1.424(6) . ?
O1 Dy1 2.392(3) 3_666 ?
O5 C12 1.416(6) . ?
O6 C14 1.283(5) . ?
O4 C9 1.406(5) . ?
O4 Dy1 2.269(3) 3_666 ?
O3 C2 1.277(5) . ?
O9 N2 1.280(5) . ?
O7 C14 1.252(5) . ?
O8 N2 1.276(5) . ?
O10 N2 1.219(4) . ?
C2 C3 1.495(5) . ?
C15 C20 1.389(6) . ?
C15 C16 1.394(5) . ?
C15 C14 1.489(5) . ?
N1 C13 1.467(7) . ?
N1 C11 1.491(6) . ?
N1 C10 1.494(6) . ?
C16 C17 1.384(6) . ?
C16 H16 0.9500 . ?
C4 C3 1.384(6) . ?
C4 C5 1.393(6) . ?
C4 H4 0.9500 . ?
C3 C8 1.390(6) . ?
C8 C7 1.395(7) . ?
C8 H8 0.9500 . ?
C20 C19 1.391(6) . ?
C20 H20 0.9500 . ?
C17 C18 1.382(7) . ?
C17 H17 0.9500 . ?
C5 C6 1.355(9) . ?
C5 H5 0.9500 . ?
C19 C18 1.378(7) . ?
C19 H19 0.9500 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C6 C7 1.402(10) . ?
C6 H6 0.9500 . ?
C7 H7 0.9500 . ?
C12 C11 1.478(8) . ?
C12 H12A 0.9900 . ?
C12 H12B 0.9900 . ?
C18 H18 0.9500 . ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
C9 C10 1.431(8) . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C11 H11A 0.9900 . ?
C11 H11B 0.9900 . ?
C10 H10A 0.9900 . ?
C10 H10B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O5 Dy1 O4 152.22(9) . 3_666 ?
O5 Dy1 O2 108.68(11) . 3_666 ?
O4 Dy1 O2 79.72(10) 3_666 3_666 ?
O5 Dy1 O7 80.77(11) . . ?
O4 Dy1 O7 108.36(11) 3_666 . ?
O2 Dy1 O7 144.04(10) 3_666 . ?
O5 Dy1 O1 77.22(10) . . ?
O4 Dy1 O1 79.93(10) 3_666 . ?
O2 Dy1 O1 140.31(9) 3_666 . ?
O7 Dy1 O1 75.11(9) . . ?
O5 Dy1 O1 80.47(9) . 3_666 ?
O4 Dy1 O1 76.25(9) 3_666 3_666 ?
O2 Dy1 O1 74.95(9) 3_666 3_666 ?
O7 Dy1 O1 140.76(9) . 3_666 ?
O1 Dy1 O1 67.28(10) . 3_666 ?
O5 Dy1 O9 129.57(10) . . ?
O4 Dy1 O9 77.94(10) 3_666 . ?
O2 Dy1 O9 74.81(10) 3_666 . ?
O7 Dy1 O9 72.97(10) . . ?
O1 Dy1 O9 132.56(10) . . ?
O1 Dy1 O9 143.07(9) 3_666 . ?
O5 Dy1 O8 78.75(11) . . ?
O4 Dy1 O8 128.73(11) 3_666 . ?
O2 Dy1 O8 73.97(10) 3_666 . ?
O7 Dy1 O8 74.16(11) . . ?
O1 Dy1 O8 143.45(10) . . ?
O1 Dy1 O8 134.30(11) 3_666 . ?
O9 Dy1 O8 53.17(11) . . ?
O5 Dy1 N2 104.18(11) . . ?
O4 Dy1 N2 103.61(11) 3_666 . ?
O2 Dy1 N2 72.83(10) 3_666 . ?
O7 Dy1 N2 71.22(10) . . ?
O1 Dy1 N2 145.50(10) . . ?
O1 Dy1 N2 147.20(10) 3_666 . ?
O9 Dy1 N2 26.62(11) . . ?
O8 Dy1 N2 26.55(12) . . ?
O5 Dy1 Ru1 37.06(7) . . ?
O4 Dy1 Ru1 120.48(7) 3_666 . ?
O2 Dy1 Ru1 138.02(8) 3_666 . ?
O7 Dy1 Ru1 68.96(7) . . ?
O1 Dy1 Ru1 40.88(7) . . ?
O1 Dy1 Ru1 75.33(6) 3_666 . ?
O9 Dy1 Ru1 141.31(7) . . ?
O8 Dy1 Ru1 108.33(8) . . ?
N2 Dy1 Ru1 127.47(7) . . ?
O5 Dy1 Ru1 120.48(7) . 3_666 ?
O4 Dy1 Ru1 36.55(7) 3_666 3_666 ?
O2 Dy1 Ru1 68.67(7) 3_666 3_666 ?
O7 Dy1 Ru1 137.22(8) . 3_666 ?
O1 Dy1 Ru1 74.69(6) . 3_666 ?
O1 Dy1 Ru1 40.33(7) 3_666 3_666 ?
O9 Dy1 Ru1 107.80(7) . 3_666 ?
O8 Dy1 Ru1 141.79(8) . 3_666 ?
N2 Dy1 Ru1 127.88(7) . 3_666 ?
Ru1 Dy1 Ru1 104.631(8) . 3_666 ?
O5 Dy1 Dy1 76.57(7) . 3_666 ?
O4 Dy1 Dy1 75.65(7) 3_666 3_666 ?
O2 Dy1 Dy1 107.80(7) 3_666 3_666 ?
O7 Dy1 Dy1 108.14(7) . 3_666 ?
O1 Dy1 Dy1 33.67(6) . 3_666 ?
O1 Dy1 Dy1 33.61(6) 3_666 3_666 ?
O9 Dy1 Dy1 152.42(8) . 3_666 ?
O8 Dy1 Dy1 154.41(8) . 3_666 ?
N2 Dy1 Dy1 178.86(9) . 3_666 ?
Ru1 Dy1 Dy1 52.703(10) . 3_666 ?
Ru1 Dy1 Dy1 51.928(13) 3_666 3_666 ?
O5 Ru1 O4 93.84(12) . . ?
O5 Ru1 O3 175.66(11) . . ?
O4 Ru1 O3 89.45(11) . . ?
O5 Ru1 O6 89.74(11) . . ?
O4 Ru1 O6 175.35(11) . . ?
O3 Ru1 O6 86.83(11) . . ?
O5 Ru1 N1 83.95(14) . . ?
O4 Ru1 N1 84.26(13) . . ?
O3 Ru1 N1 93.57(13) . . ?
O6 Ru1 N1 93.18(13) . . ?
O5 Ru1 O1 90.29(12) . . ?
O4 Ru1 O1 89.10(11) . . ?
O3 Ru1 O1 92.59(11) . . ?
O6 Ru1 O1 93.85(11) . . ?
N1 Ru1 O1 170.88(13) . . ?
O5 Ru1 Dy1 43.70(9) . . ?
O4 Ru1 Dy1 99.42(8) . . ?
O3 Ru1 Dy1 138.41(8) . . ?
O6 Ru1 Dy1 85.22(7) . . ?
N1 Ru1 Dy1 127.56(11) . . ?
O1 Ru1 Dy1 47.50(7) . . ?
O5 Ru1 Dy1 99.66(9) . 3_666 ?
O4 Ru1 Dy1 42.98(8) . 3_666 ?
O3 Ru1 Dy1 84.68(8) . 3_666 ?
O6 Ru1 Dy1 139.16(8) . 3_666 ?
N1 Ru1 Dy1 127.15(10) . 3_666 ?
O1 Ru1 Dy1 46.90(7) . 3_666 ?
Dy1 Ru1 Dy1 75.369(8) . 3_666 ?
C2 O2 Dy1 134.4(3) . 3_666 ?
C1 O1 Ru1 121.0(3) . . ?
C1 O1 Dy1 117.3(3) . . ?
Ru1 O1 Dy1 91.62(10) . . ?
C1 O1 Dy1 116.7(3) . 3_666 ?
Ru1 O1 Dy1 92.77(10) . 3_666 ?
Dy1 O1 Dy1 112.72(10) . 3_666 ?
C12 O5 Ru1 115.1(3) . . ?
C12 O5 Dy1 144.5(3) . . ?
Ru1 O5 Dy1 99.24(12) . . ?
C14 O6 Ru1 125.0(2) . . ?
C9 O4 Ru1 110.5(3) . . ?
C9 O4 Dy1 140.9(3) . 3_666 ?
Ru1 O4 Dy1 100.47(11) . 3_666 ?
C2 O3 Ru1 125.7(2) . . ?
N2 O9 Dy1 94.9(2) . . ?
C14 O7 Dy1 133.9(2) . . ?
N2 O8 Dy1 94.6(2) . . ?
O2 C2 O3 125.3(3) . . ?
O2 C2 C3 118.1(4) . . ?
O3 C2 C3 116.7(3) . . ?
O10 N2 O8 121.0(4) . . ?
O10 N2 O9 121.7(4) . . ?
O8 N2 O9 117.3(3) . . ?
O10 N2 Dy1 178.6(3) . . ?
O8 N2 Dy1 58.85(19) . . ?
O9 N2 Dy1 58.45(19) . . ?
C20 C15 C16 119.7(4) . . ?
C20 C15 C14 120.1(4) . . ?
C16 C15 C14 120.1(4) . . ?
C13 N1 C11 108.8(4) . . ?
C13 N1 C10 110.9(5) . . ?
C11 N1 C10 111.1(5) . . ?
C13 N1 Ru1 114.6(3) . . ?
C11 N1 Ru1 104.8(3) . . ?
C10 N1 Ru1 106.5(3) . . ?
C17 C16 C15 120.1(4) . . ?
C17 C16 H16 120.0 . . ?
C15 C16 H16 120.0 . . ?
O7 C14 O6 125.1(3) . . ?
O7 C14 C15 119.0(3) . . ?
O6 C14 C15 115.9(3) . . ?
C3 C4 C5 120.0(5) . . ?
C3 C4 H4 120.0 . . ?
C5 C4 H4 120.0 . . ?
C4 C3 C8 120.2(4) . . ?
C4 C3 C2 119.5(4) . . ?
C8 C3 C2 120.3(4) . . ?
C3 C8 C7 120.0(5) . . ?
C3 C8 H8 120.0 . . ?
C7 C8 H8 120.0 . . ?
C15 C20 C19 119.8(4) . . ?
C15 C20 H20 120.1 . . ?
C19 C20 H20 120.1 . . ?
C18 C17 C16 119.9(4) . . ?
C18 C17 H17 120.1 . . ?
C16 C17 H17 120.1 . . ?
C6 C5 C4 119.7(5) . . ?
C6 C5 H5 120.1 . . ?
C4 C5 H5 120.1 . . ?
C18 C19 C20 120.0(5) . . ?
C18 C19 H19 120.0 . . ?
C20 C19 H19 120.0 . . ?
N1 C13 H13A 109.5 . . ?
N1 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
N1 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C5 C6 C7 121.7(5) . . ?
C5 C6 H6 119.2 . . ?
C7 C6 H6 119.2 . . ?
C8 C7 C6 118.4(5) . . ?
C8 C7 H7 120.8 . . ?
C6 C7 H7 120.8 . . ?
O5 C12 C11 111.3(4) . . ?
O5 C12 H12A 109.4 . . ?
C11 C12 H12A 109.4 . . ?
O5 C12 H12B 109.4 . . ?
C11 C12 H12B 109.4 . . ?
H12A C12 H12B 108.0 . . ?
C19 C18 C17 120.5(4) . . ?
C19 C18 H18 119.8 . . ?
C17 C18 H18 119.8 . . ?
O1 C1 H1A 109.5 . . ?
O1 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
O1 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
O4 C9 C10 112.4(4) . . ?
O4 C9 H9A 109.1 . . ?
C10 C9 H9A 109.1 . . ?
O4 C9 H9B 109.1 . . ?
C10 C9 H9B 109.1 . . ?
H9A C9 H9B 107.9 . . ?
C12 C11 N1 113.9(4) . . ?
C12 C11 H11A 108.8 . . ?
N1 C11 H11A 108.8 . . ?
C12 C11 H11B 108.8 . . ?
N1 C11 H11B 108.8 . . ?
H11A C11 H11B 107.7 . . ?
C9 C10 N1 114.3(5) . . ?
C9 C10 H10A 108.7 . . ?
N1 C10 H10A 108.7 . . ?
C9 C10 H10B 108.7 . . ?
N1 C10 H10B 108.7 . . ?
H10A C10 H10B 107.6 . . ?

_diffrn_measured_fraction_theta_max 0.784
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.953
_refine_diff_density_max         1.294
_refine_diff_density_min         -1.295
_refine_diff_density_rms         0.150
_exptl_crystal_recrystallization_method 
'layering of diethylether on to methanol solution'
_exptl_crystal_preparation       'Magnetic properties'
