# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2e
_database_code_depnum_ccdc_archive 'CCDC 1957894'
loop_
_audit_author_name
_audit_author_address
'Sebastian Koniarz'
;University of Wroclaw
Poland
;
_audit_update_record             
;
2019-10-07 deposited with the CCDC.	2020-03-17 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C54 H47 N5 O8, C6 H14'
_chemical_formula_sum            'C60 H61 N5 O8'
_chemical_formula_weight         980.13

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   8.9154(12)
_cell_length_b                   9.9908(11)
_cell_length_c                   14.3287(18)
_cell_angle_alpha                98.926(10)
_cell_angle_beta                 91.790(11)
_cell_angle_gamma                92.209(10)
_cell_volume                     1259.0(3)
_cell_formula_units_Z            1
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    1664
_cell_measurement_theta_min      3.1110
_cell_measurement_theta_max      75.9140

_exptl_crystal_description       plate
_exptl_crystal_colour            brown
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.293
_exptl_crystal_F_000             520
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.49
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.09
_exptl_absorpt_coefficient_mu    0.693
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   none
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     1.54184
_diffrn_radiation_type           CuK\a
_diffrn_source                   'Enhance (Cu) X-ray Source'
_diffrn_measurement_device_type  'Xcalibur, Onyx'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean 8.1956
_diffrn_reflns_number            6859
_diffrn_reflns_av_unetI/netI     0.1242
_diffrn_reflns_av_R_equivalents  0.0948
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_theta_min         4.484
_diffrn_reflns_theta_max         62.496
_diffrn_reflns_theta_full        62.496
_diffrn_measured_fraction_theta_max 0.981
_diffrn_measured_fraction_theta_full 0.981
_diffrn_reflns_Laue_measured_fraction_max 0.981
_diffrn_reflns_Laue_measured_fraction_full 0.981
_diffrn_reflns_point_group_measured_fraction_max 0.981
_diffrn_reflns_point_group_measured_fraction_full 0.981
_reflns_number_total             3952
_reflns_number_gt                2398
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1508P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         3952
_refine_ls_number_parameters     347
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1271
_refine_ls_R_factor_gt           0.0985
_refine_ls_wR_factor_ref         0.2931
_refine_ls_wR_factor_gt          0.2519
_refine_ls_goodness_of_fit_ref   0.999
_refine_ls_restrained_S_all      0.999
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
O103 O 0.7954(4) 0.5282(3) 0.9727(2) 0.0473(8) Uani 1 1 d . . . . .
O105 O 0.4772(4) 0.1284(3) 0.9492(2) 0.0456(8) Uani 1 1 d . . . . .
O53 O 0.8321(4) 0.6273(3) 0.2133(2) 0.0468(8) Uani 1 1 d . . . . .
O55 O 0.3737(4) 0.3794(3) 0.2421(3) 0.0470(8) Uani 1 1 d . . . . .
N22 N 0.8674(4) 0.1745(4) 0.5377(3) 0.0418(9) Uani 1 1 d . . . . .
C1 C 1.0811(5) -0.0390(4) 0.2900(3) 0.0418(11) Uani 1 1 d . . . . .
C3 C 0.9414(5) 0.1126(4) 0.2275(4) 0.0416(10) Uani 1 1 d . . . . .
H3A H 0.892882 0.159821 0.185190 0.050 Uiso 0.5 1 calc R U P A 2
N2 N 1.0341(5) 0.0072(4) 0.2044(3) 0.0467(11) Uani 0.5 1 d . . P B 1
N33 N 0.9343(11) 0.0584(10) 0.0694(7) 0.067(3) Uani 0.5 1 d . . P B 1
C32 C 1.0307(12) -0.0244(10) 0.1085(8) 0.054(3) Uani 0.5 1 d . . P B 1
H32A H 1.085183 -0.091742 0.074386 0.065 Uiso 0.5 1 calc R U P B 1
C33 C 0.8811(12) 0.1401(9) 0.1448(7) 0.052(2) Uani 0.5 1 d . . P B 1
H33A H 0.812118 0.206498 0.140337 0.078 Uiso 0.5 1 calc R U P B 1
C12 C 1.0341(5) 0.0072(4) 0.2044(3) 0.0467(11) Uani 0.5 1 d . . P B 2
H22A H 1.061716 -0.028102 0.143787 0.056 Uiso 0.5 1 calc R U P B 2
C4 C 0.9324(5) 0.1371(4) 0.3278(4) 0.0420(11) Uani 1 1 d . . . . .
C5 C 0.8464(5) 0.2394(4) 0.3776(3) 0.0417(10) Uani 1 1 d . . . . .
C6 C 0.8219(5) 0.2563(4) 0.4740(4) 0.0450(11) Uani 1 1 d . . . . .
C7 C 0.7375(5) 0.3596(4) 0.5271(4) 0.0476(12) Uani 1 1 d . . . . .
H7A H 0.694191 0.431440 0.503616 0.057 Uiso 1 1 calc R U . . .
C8 C 0.7318(5) 0.3347(4) 0.6169(3) 0.0431(11) Uani 1 1 d . . . . .
H8A H 0.682310 0.386072 0.665290 0.052 Uiso 1 1 calc R U . . .
C9 C 0.8132(5) 0.2175(4) 0.6260(3) 0.0435(11) Uani 1 1 d . . . . .
C10 C 0.8334(5) 0.1549(4) 0.7059(3) 0.0422(11) Uani 1 1 d . . . . .
C101 C 0.7639(5) 0.2176(4) 0.7946(3) 0.0421(10) Uani 1 1 d . . . . .
C102 C 0.8164(5) 0.3474(4) 0.8399(4) 0.0438(11) Uani 1 1 d . . . . .
H10G H 0.892260 0.395164 0.814285 0.053 Uiso 1 1 calc R U . . .
C103 C 0.7526(5) 0.4018(4) 0.9232(3) 0.0425(10) Uani 1 1 d . . . . .
C104 C 0.6406(5) 0.3319(4) 0.9642(3) 0.0417(10) Uani 1 1 d . . . . .
H10H H 0.601398 0.369105 1.021401 0.050 Uiso 1 1 calc R U . . .
C105 C 0.5888(5) 0.2050(4) 0.9178(4) 0.0431(10) Uani 1 1 d . . . . .
C106 C 0.6495(5) 0.1484(4) 0.8335(3) 0.0433(11) Uani 1 1 d . . . . .
H10I H 0.613397 0.063871 0.802921 0.052 Uiso 1 1 calc R U . . .
C107 C 0.9056(6) 0.6066(4) 0.9320(4) 0.0488(12) Uani 1 1 d . . . . .
H10A H 0.925800 0.691615 0.972623 0.073 Uiso 1 1 calc R U . . .
H10B H 0.996362 0.557958 0.924700 0.073 Uiso 1 1 calc R U . . .
H10C H 0.868737 0.622838 0.871260 0.073 Uiso 1 1 calc R U . . .
C108 C 0.4206(6) 0.1737(5) 1.0401(4) 0.0503(12) Uani 1 1 d . . . . .
H10D H 0.343004 0.110723 1.053312 0.075 Uiso 1 1 calc R U . . .
H10E H 0.500574 0.179227 1.087182 0.075 Uiso 1 1 calc R U . . .
H10F H 0.380169 0.261513 1.041042 0.075 Uiso 1 1 calc R U . . .
C21 C 1.0181(5) 0.0435(4) 0.3647(3) 0.0445(10) Uani 0.5 1 d . . P B .
H21A H 1.031333 0.036898 0.428418 0.053 Uiso 0.5 1 calc R U P . .
N23 N 1.0181(5) 0.0435(4) 0.3647(3) 0.0445(10) Uani 0.5 1 d . . P B .
C40 C 0.7202(7) 0.7585(6) 0.4427(5) 0.0698(16) Uani 1 1 d . . . . .
H40A H 0.774556 0.724623 0.387826 0.105 Uiso 1 1 calc R U . . .
H40B H 0.789557 0.785180 0.495552 0.105 Uiso 1 1 calc R U . . .
H40C H 0.651314 0.688668 0.456702 0.105 Uiso 1 1 calc R U . . .
C41 C 0.6339(7) 0.8797(5) 0.4240(4) 0.0604(14) Uani 1 1 d . . . . .
H41A H 0.565737 0.852452 0.369638 0.072 Uiso 1 1 calc R U . . .
H41B H 0.703953 0.948945 0.408480 0.072 Uiso 1 1 calc R U . . .
C42 C 0.5440(6) 0.9400(5) 0.5080(4) 0.0586(14) Uani 1 1 d . . . . .
H42A H 0.475013 0.870053 0.523590 0.070 Uiso 1 1 calc R U . . .
H42B H 0.612689 0.967075 0.562031 0.070 Uiso 1 1 calc R U . . .
C51 C 0.7630(5) 0.3301(4) 0.3229(3) 0.0420(10) Uani 1 1 d . . . . .
C52 C 0.8368(5) 0.4364(4) 0.2894(3) 0.0434(11) Uani 1 1 d . . . . .
H52A H 0.940290 0.450708 0.298551 0.052 Uiso 1 1 calc R U . . .
C53 C 0.7522(5) 0.5227(4) 0.2409(3) 0.0418(10) Uani 1 1 d . . . . .
C54 C 0.5988(5) 0.5006(4) 0.2248(3) 0.0411(10) Uani 1 1 d . . . . .
H54A H 0.543870 0.556169 0.191557 0.049 Uiso 1 1 calc R U . . .
C55 C 0.5283(5) 0.3914(4) 0.2603(3) 0.0413(10) Uani 1 1 d . . . . .
C56 C 0.6083(5) 0.3069(4) 0.3068(3) 0.0426(11) Uani 1 1 d . . . . .
H56A H 0.559691 0.233790 0.327900 0.051 Uiso 1 1 calc R U . . .
C57 C 0.7511(5) 0.7246(4) 0.1709(3) 0.0439(11) Uani 1 1 d . . . . .
H57A H 0.820303 0.792709 0.154809 0.066 Uiso 1 1 calc R U . . .
H57B H 0.697612 0.680058 0.114794 0.066 Uiso 1 1 calc R U . . .
H57C H 0.681127 0.766461 0.214756 0.066 Uiso 1 1 calc R U . . .
C58 C 0.2935(6) 0.2858(5) 0.2902(4) 0.0589(14) Uani 1 1 d . . . . .
H58A H 0.188405 0.284761 0.273112 0.088 Uiso 1 1 calc R U . . .
H58B H 0.330219 0.196660 0.272563 0.088 Uiso 1 1 calc R U . . .
H58C H 0.307851 0.312977 0.357233 0.088 Uiso 1 1 calc R U . . .
H22 H 0.926(8) 0.114(7) 0.524(5) 0.08(2) Uiso 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
O103 C103 1.382(5) . ?
O103 C107 1.427(5) . ?
O105 C105 1.362(5) . ?
O105 C108 1.424(6) . ?
O53 C53 1.358(5) . ?
O53 C57 1.430(5) . ?
O55 C55 1.392(6) . ?
O55 C58 1.428(5) . ?
N22 C6 1.378(6) . ?
N22 C9 1.380(6) . ?
C1 C21 1.393(6) . ?
C1 C10 1.418(6) 2_756 ?
C1 C12 1.432(7) . ?
C1 N2 1.432(7) . ?
C3 C33 1.356(12) . ?
C3 C12 1.370(6) . ?
C3 N2 1.370(6) . ?
C3 C4 1.426(7) . ?
N2 C32 1.361(12) . ?
N33 C33 1.359(14) . ?
N33 C32 1.381(15) . ?
C4 C21 1.386(6) . ?
C4 C5 1.417(6) . ?
C5 C6 1.391(7) . ?
C5 C51 1.491(7) . ?
C6 C7 1.436(7) . ?
C7 C8 1.351(7) . ?
C8 C9 1.422(7) . ?
C9 C10 1.398(7) . ?
C10 C101 1.491(6) . ?
C101 C106 1.389(6) . ?
C101 C102 1.413(6) . ?
C102 C103 1.381(7) . ?
C103 C104 1.393(6) . ?
C104 C105 1.391(7) . ?
C105 C106 1.387(7) . ?
C40 C41 1.514(9) . ?
C41 C42 1.525(7) . ?
C42 C42 1.500(11) 2_676 ?
C51 C52 1.385(6) . ?
C51 C56 1.396(7) . ?
C52 C53 1.414(7) . ?
C53 C54 1.383(7) . ?
C54 C55 1.408(6) . ?
C55 C56 1.362(7) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C103 O103 C107 117.3(4) . . ?
C105 O105 C108 118.2(4) . . ?
C53 O53 C57 117.9(4) . . ?
C55 O55 C58 115.8(4) . . ?
C6 N22 C9 111.0(4) . . ?
C21 C1 C10 127.7(5) . 2_756 ?
C21 C1 C12 107.5(4) . . ?
C10 C1 C12 124.6(4) 2_756 . ?
C21 C1 N2 107.5(4) . . ?
C10 C1 N2 124.6(4) 2_756 . ?
C33 C3 N2 106.5(6) . . ?
C33 C3 C4 144.9(6) . . ?
C12 C3 C4 107.9(4) . . ?
N2 C3 C4 107.9(4) . . ?
C32 N2 C3 107.7(6) . . ?
C32 N2 C1 143.5(6) . . ?
C3 N2 C1 108.1(4) . . ?
C33 N33 C32 104.6(9) . . ?
N2 C32 N33 109.8(9) . . ?
C3 C33 N33 111.5(9) . . ?
C3 C12 C1 108.1(4) . . ?
C21 C4 C5 128.0(4) . . ?
C21 C4 C3 108.1(4) . . ?
C5 C4 C3 123.9(4) . . ?
C6 C5 C4 125.3(4) . . ?
C6 C5 C51 115.7(4) . . ?
C4 C5 C51 118.8(4) . . ?
N22 C6 C5 127.4(4) . . ?
N22 C6 C7 105.6(4) . . ?
C5 C6 C7 126.9(4) . . ?
C8 C7 C6 108.3(4) . . ?
C7 C8 C9 109.4(4) . . ?
N22 C9 C10 126.1(4) . . ?
N22 C9 C8 105.6(4) . . ?
C10 C9 C8 128.3(5) . . ?
C9 C10 C1 125.1(4) . 2_756 ?
C9 C10 C101 117.4(4) . . ?
C1 C10 C101 117.5(4) 2_756 . ?
C106 C101 C102 119.9(4) . . ?
C106 C101 C10 120.4(4) . . ?
C102 C101 C10 119.6(4) . . ?
C103 C102 C101 118.5(4) . . ?
C102 C103 O103 123.0(4) . . ?
C102 C103 C104 122.1(4) . . ?
O103 C103 C104 114.9(4) . . ?
C105 C104 C103 118.5(4) . . ?
O105 C105 C106 115.2(4) . . ?
O105 C105 C104 124.1(4) . . ?
C106 C105 C104 120.7(4) . . ?
C105 C106 C101 120.3(4) . . ?
C4 C21 C1 108.4(4) . . ?
C40 C41 C42 112.9(5) . . ?
C42 C42 C41 114.6(6) 2_676 . ?
C52 C51 C56 120.3(4) . . ?
C52 C51 C5 120.8(4) . . ?
C56 C51 C5 118.9(4) . . ?
C51 C52 C53 118.8(4) . . ?
O53 C53 C54 123.6(4) . . ?
O53 C53 C52 115.2(4) . . ?
C54 C53 C52 121.1(4) . . ?
C53 C54 C55 118.1(4) . . ?
C56 C55 O55 124.9(4) . . ?
C56 C55 C54 121.5(4) . . ?
O55 C55 C54 113.6(4) . . ?
C55 C56 C51 120.1(4) . . ?

_refine_diff_density_max         0.394
_refine_diff_density_min         -0.420
_refine_diff_density_rms         0.088



_exptl_crystal_recrystallization_method 'Re-crystallisation from solvent'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_SK17_5a
_database_code_depnum_ccdc_archive 'CCDC 1977696'
loop_
_audit_author_name
_audit_author_address
'Sebastian Koniarz'
;University of Wroclaw
Poland
;
_audit_update_record             
;
2020-02-07 deposited with the CCDC.	2020-03-17 downloaded from the CCDC.
;
# start Validation Reply Form
_vrf_PLAT973_SK17_5a             
;
PROBLEM: Check Calcd Positive Resid. Density on       Ag1       1.94 eA-3
RESPONSE: Probably twinned crystal or disordered structure
;
# Added during the CSD deposition process: Friday 07 February 2020 06:43 PM
# end Validation Reply Form


_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         '2(C47 H30 Ag Au Cl N5), 3(C H2 Cl2) '
_chemical_formula_sum            'C48.50 H33 Ag Au Cl4 N5'
_chemical_formula_weight         1132.43

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -4.4197 7.2980 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.9193(5)
_cell_length_b                   13.7034(8)
_cell_length_c                   15.7321(8)
_cell_angle_alpha                75.013(5)
_cell_angle_beta                 84.724(4)
_cell_angle_gamma                78.550(4)
_cell_volume                     2022.72(19)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    7411
_cell_measurement_theta_min      5.2050
_cell_measurement_theta_max      68.0300

_exptl_crystal_description       needle
_exptl_crystal_colour            purple
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.859
_exptl_crystal_F_000             1106
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.335
_exptl_crystal_size_mid          0.034
_exptl_crystal_size_min          0.031
_exptl_absorpt_coefficient_mu    13.379
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_correction_T_min  0.212
_exptl_absorpt_correction_T_max  0.736
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.40.53 (Rigaku Oxford Diffraction, 2019)
Analytical numeric absorption correction using a multifaceted crystal
			model based on expressions derived by R.C. Clark & J.S. Reid.
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     1.54184
_diffrn_radiation_type           CuK\a
_diffrn_source                   'Enhance Ultra (Cu) X-ray Source'
_diffrn_measurement_device_type  'Xcalibur, Ruby, Gemini ultra'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean 10.3456
_diffrn_reflns_number            13937
_diffrn_reflns_av_unetI/netI     0.0804
_diffrn_reflns_av_R_equivalents  0.0689
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_theta_min         3.891
_diffrn_reflns_theta_max         62.494
_diffrn_reflns_theta_full        62.494
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measured_fraction_theta_full 0.990
_diffrn_reflns_Laue_measured_fraction_max 0.990
_diffrn_reflns_Laue_measured_fraction_full 0.990
_diffrn_reflns_point_group_measured_fraction_max 0.990
_diffrn_reflns_point_group_measured_fraction_full 0.990
_reflns_number_total             6395
_reflns_number_gt                5470
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0695P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         6395
_refine_ls_number_parameters     552
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0574
_refine_ls_R_factor_gt           0.0449
_refine_ls_wR_factor_ref         0.1180
_refine_ls_wR_factor_gt          0.1083
_refine_ls_goodness_of_fit_ref   1.017
_refine_ls_restrained_S_all      1.017
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 1.07493(2) 0.35078(2) 0.32934(2) 0.02296(12) Uani 1 1 d . . . . .
Ag1 Ag 0.64269(4) 0.06222(3) 0.59594(2) 0.01627(13) Uani 1 1 d . . . A 1
Cl1 Cl 1.18204(15) 0.48624(12) 0.32351(10) 0.0294(3) Uani 1 1 d . . . B 1
Cl41 Cl 1.1518(2) 0.46433(18) 0.07658(13) 0.0536(5) Uani 1 1 d . . . C 1
Cl42 Cl 1.0262(2) 0.68012(17) 0.04940(12) 0.0474(4) Uani 1 1 d . . . C 1
N2 N 0.9003(5) 0.1804(4) 0.3808(3) 0.0192(10) Uani 1 1 d . . . A 1
N22 N 0.6443(5) -0.0793(4) 0.5748(3) 0.0212(10) Uani 1 1 d . . . A 1
N23 N 0.5405(5) 0.0202(4) 0.7159(3) 0.0225(10) Uani 1 1 d . . . A 1
N24 N 0.6436(5) 0.2025(4) 0.6157(3) 0.0207(10) Uani 1 1 d . . . A 1
N32 N 1.0562(5) 0.1604(4) 0.2812(3) 0.0247(11) Uani 1 1 d . . . A 1
C1 C 0.7994(6) 0.1945(5) 0.4512(4) 0.0210(12) Uani 1 1 d . . . A 1
C3 C 0.9044(6) 0.0831(5) 0.3681(4) 0.0201(12) Uani 1 1 d . . . A 1
C4 C 0.8109(6) 0.0317(5) 0.4321(4) 0.0204(12) Uani 1 1 d . . . A 1
C5 C 0.7845(6) -0.0659(5) 0.4371(4) 0.0198(12) Uani 1 1 d . . . A 1
C6 C 0.6983(6) -0.1140(4) 0.5027(4) 0.0189(12) Uani 1 1 d . . . A 1
C7 C 0.6556(6) -0.2092(5) 0.5058(4) 0.0227(12) Uani 1 1 d . . . A 1
H7A H 0.678656 -0.248504 0.464671 0.027 Uiso 1 1 calc R U . A 1
C8 C 0.5742(6) -0.2309(5) 0.5811(4) 0.0202(12) Uani 1 1 d . . . A 1
H8A H 0.530085 -0.287151 0.599876 0.024 Uiso 1 1 calc R U . A 1
C9 C 0.5694(6) -0.1507(5) 0.6258(4) 0.0196(12) Uani 1 1 d . . . A 1
C10 C 0.5075(6) -0.1521(5) 0.7089(4) 0.0206(12) Uani 1 1 d . . . A 1
C11 C 0.5050(6) -0.0745(5) 0.7534(4) 0.0197(12) Uani 1 1 d . . . A 1
C12 C 0.4701(6) -0.0820(5) 0.8452(4) 0.0227(12) Uani 1 1 d . . . A 1
H12A H 0.443857 -0.138290 0.885733 0.027 Uiso 1 1 calc R U . A 1
C13 C 0.4823(6) 0.0080(5) 0.8621(4) 0.0241(13) Uani 1 1 d . . . A 1
H13A H 0.466375 0.024472 0.916314 0.029 Uiso 1 1 calc R U . A 1
C14 C 0.5241(6) 0.0731(5) 0.7812(4) 0.0218(13) Uani 1 1 d . . . A 1
C15 C 0.5386(6) 0.1753(5) 0.7683(4) 0.0218(12) Uani 1 1 d . . . A 1
C16 C 0.5822(6) 0.2356(5) 0.6879(4) 0.0216(12) Uani 1 1 d . . . A 1
C17 C 0.5683(6) 0.3452(5) 0.6688(4) 0.0222(12) Uani 1 1 d . . . A 1
H17A H 0.531817 0.386380 0.706954 0.027 Uiso 1 1 calc R U . A 1
C18 C 0.6173(6) 0.3778(5) 0.5858(4) 0.0253(13) Uani 1 1 d . . . A 1
H18A H 0.616531 0.445796 0.555200 0.030 Uiso 1 1 calc R U . A 1
C19 C 0.6714(6) 0.2882(5) 0.5530(4) 0.0195(12) Uani 1 1 d . . . A 1
C20 C 0.7530(6) 0.2885(5) 0.4746(4) 0.0207(12) Uani 1 1 d . . . A 1
C21 C 0.7530(6) 0.1009(5) 0.4832(4) 0.0198(12) Uani 1 1 d . . . A 1
C31 C 1.0025(6) 0.0723(5) 0.3026(4) 0.0232(13) Uani 1 1 d . . . A 1
H31A H 1.027473 0.016342 0.277608 0.028 Uiso 1 1 calc R U . A 1
C33 C 0.9964(6) 0.2269(5) 0.3301(4) 0.0211(12) Uani 1 1 d . . . A 1
C34 C 1.1588(6) 0.1804(5) 0.2085(4) 0.0267(14) Uani 1 1 d . . . A 1
H34A H 1.215227 0.116549 0.202966 0.040 Uiso 1 1 calc R U . A 1
H34B H 1.215573 0.224087 0.220378 0.040 Uiso 1 1 calc R U . A 1
H34C H 1.112818 0.213491 0.154701 0.040 Uiso 1 1 calc R U . A 1
C40 C 1.0238(8) 0.5539(7) 0.1156(5) 0.0447(19) Uani 1 1 d . . . C 1
H40A H 1.040029 0.550973 0.176125 0.054 Uiso 1 1 calc R U . C 1
H40B H 0.934053 0.536449 0.114152 0.054 Uiso 1 1 calc R U . C 1
C51 C 0.8537(6) -0.1200(5) 0.3688(4) 0.0202(12) Uani 1 1 d . . . A 1
C52 C 0.8155(6) -0.0858(5) 0.2814(4) 0.0231(13) Uani 1 1 d . . . A 1
H52A H 0.740616 -0.032969 0.265867 0.028 Uiso 1 1 calc R U . A 1
C53 C 0.8897(7) -0.1309(5) 0.2174(4) 0.0265(13) Uani 1 1 d . . . A 1
H53A H 0.863829 -0.108662 0.159150 0.032 Uiso 1 1 calc R U . A 1
C54 C 1.0014(7) -0.2085(5) 0.2407(5) 0.0311(15) Uani 1 1 d . . . A 1
H54A H 1.051362 -0.237564 0.197542 0.037 Uiso 1 1 calc R U . A 1
C55 C 1.0400(7) -0.2434(5) 0.3257(5) 0.0293(14) Uani 1 1 d . . . A 1
H55A H 1.115384 -0.296118 0.340373 0.035 Uiso 1 1 calc R U . A 1
C56 C 0.9666(6) -0.2001(5) 0.3904(4) 0.0257(13) Uani 1 1 d . . . A 1
H56A H 0.992477 -0.224388 0.448518 0.031 Uiso 1 1 calc R U . A 1
C101 C 0.4522(6) -0.2440(5) 0.7602(4) 0.0209(12) Uani 1 1 d . . . A 1
C102 C 0.5358(7) -0.3416(5) 0.7787(4) 0.0263(13) Uani 1 1 d . . . A 1
H10A H 0.625106 -0.350702 0.754415 0.032 Uiso 1 1 calc R U . A 1
C103 C 0.4853(7) -0.4248(5) 0.8332(4) 0.0291(14) Uani 1 1 d . . . A 1
H10B H 0.541829 -0.489148 0.845610 0.035 Uiso 1 1 calc R U . A 1
C104 C 0.3529(7) -0.4135(6) 0.8691(4) 0.0310(15) Uani 1 1 d . . . A 1
H10C H 0.320533 -0.469594 0.906069 0.037 Uiso 1 1 calc R U . A 1
C105 C 0.2688(7) -0.3184(6) 0.8500(4) 0.0307(14) Uani 1 1 d . . . A 1
H10D H 0.179213 -0.310843 0.873997 0.037 Uiso 1 1 calc R U . A 1
C106 C 0.3154(6) -0.2343(5) 0.7957(4) 0.0236(13) Uani 1 1 d . . . A 1
H10E H 0.256656 -0.170899 0.782429 0.028 Uiso 1 1 calc R U . A 1
C151 C 0.5061(7) 0.2238(5) 0.8437(4) 0.0248(13) Uani 1 1 d . . . A 1
C152 C 0.3775(7) 0.2326(5) 0.8855(4) 0.0260(13) Uani 1 1 d . . . A 1
H15A H 0.307532 0.208655 0.865976 0.031 Uiso 1 1 calc R U . A 1
C153 C 0.3518(7) 0.2778(5) 0.9576(4) 0.0312(15) Uani 1 1 d . . . A 1
H15B H 0.264987 0.283269 0.985768 0.037 Uiso 1 1 calc R U . A 1
C154 C 0.4543(8) 0.3139(5) 0.9864(4) 0.0327(15) Uani 1 1 d . . . A 1
H15C H 0.436215 0.343870 1.033966 0.039 Uiso 1 1 calc R U . A 1
C155 C 0.5849(8) 0.3062(5) 0.9454(4) 0.0323(15) Uani 1 1 d . . . A 1
H15D H 0.654349 0.330527 0.964997 0.039 Uiso 1 1 calc R U . A 1
C156 C 0.6094(7) 0.2610(5) 0.8741(4) 0.0265(13) Uani 1 1 d . . . A 1
H15E H 0.696311 0.255512 0.846094 0.032 Uiso 1 1 calc R U . A 1
C201 C 0.7780(6) 0.3894(5) 0.4207(4) 0.0232(13) Uani 1 1 d . . . A 1
C202 C 0.8346(6) 0.4548(5) 0.4561(4) 0.0236(13) Uani 1 1 d . . . A 1
H20A H 0.865451 0.432321 0.513164 0.028 Uiso 1 1 calc R U . A 1
C203 C 0.8454(6) 0.5528(5) 0.4072(4) 0.0256(13) Uani 1 1 d . . . A 1
H20B H 0.883910 0.595666 0.431234 0.031 Uiso 1 1 calc R U . A 1
C204 C 0.7992(6) 0.5866(5) 0.3230(5) 0.0274(14) Uani 1 1 d . . . A 1
H20C H 0.803665 0.653287 0.290822 0.033 Uiso 1 1 calc R U . A 1
C205 C 0.7458(6) 0.5218(5) 0.2858(4) 0.0270(14) Uani 1 1 d . . . A 1
H20D H 0.718212 0.544002 0.227966 0.032 Uiso 1 1 calc R U . A 1
C206 C 0.7339(6) 0.4249(5) 0.3345(4) 0.0230(13) Uani 1 1 d . . . A 1
H20E H 0.696007 0.382312 0.309706 0.028 Uiso 1 1 calc R U . A 1
C60 C 1.128(2) 0.9241(19) -0.0115(15) 0.077(7) Uani 0.5 1 d . . P D -1
H60A H 1.187409 0.921880 -0.063513 0.092 Uiso 0.5 1 calc R U P D -1
H60B H 1.146315 0.856856 0.029089 0.092 Uiso 0.5 1 calc R U P D -1
Cl61 Cl 0.9590(7) 0.9470(6) -0.0417(4) 0.0831(17) Uani 0.5 1 d . . P D -1
Cl62 Cl 1.1710(7) 1.0150(6) 0.0386(4) 0.0836(17) Uani 0.5 1 d . . P D -1


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C33 2.001(6) . ?
Au1 Cl1 2.2936(16) . ?
Ag1 C21 2.002(6) . ?
Ag1 N24 2.027(5) . ?
Ag1 N22 2.048(5) . ?
Ag1 N23 2.059(5) . ?
Cl41 C40 1.767(8) . ?
Cl42 C40 1.777(9) . ?
N2 C33 1.337(8) . ?
N2 C3 1.391(8) . ?
N2 C1 1.448(8) . ?
N22 C6 1.366(8) . ?
N22 C9 1.387(8) . ?
N23 C11 1.380(8) . ?
N23 C14 1.383(8) . ?
N24 C16 1.377(8) . ?
N24 C19 1.380(8) . ?
N32 C33 1.356(8) . ?
N32 C31 1.368(9) . ?
N32 C34 1.467(8) . ?
C1 C21 1.403(9) . ?
C1 C20 1.409(9) . ?
C3 C31 1.368(9) . ?
C3 C4 1.445(9) . ?
C4 C5 1.395(9) . ?
C4 C21 1.404(9) . ?
C5 C6 1.392(9) . ?
C5 C51 1.501(8) . ?
C6 C7 1.437(9) . ?
C7 C8 1.371(9) . ?
C8 C9 1.442(9) . ?
C9 C10 1.389(9) . ?
C10 C11 1.413(9) . ?
C10 C101 1.485(9) . ?
C11 C12 1.436(8) . ?
C12 C13 1.357(9) . ?
C13 C14 1.431(9) . ?
C14 C15 1.397(9) . ?
C15 C16 1.403(9) . ?
C15 C151 1.486(9) . ?
C16 C17 1.434(9) . ?
C17 C18 1.344(9) . ?
C18 C19 1.442(9) . ?
C19 C20 1.411(9) . ?
C20 C201 1.477(9) . ?
C51 C52 1.394(9) . ?
C51 C56 1.401(9) . ?
C52 C53 1.393(9) . ?
C53 C54 1.378(10) . ?
C54 C55 1.363(10) . ?
C55 C56 1.386(9) . ?
C101 C102 1.402(9) . ?
C101 C106 1.413(9) . ?
C102 C103 1.388(10) . ?
C103 C104 1.378(10) . ?
C104 C105 1.376(11) . ?
C105 C106 1.380(10) . ?
C151 C152 1.378(10) . ?
C151 C156 1.400(10) . ?
C152 C153 1.408(10) . ?
C153 C154 1.373(11) . ?
C154 C155 1.390(11) . ?
C155 C156 1.396(9) . ?
C201 C202 1.394(9) . ?
C201 C206 1.398(9) . ?
C202 C203 1.383(10) . ?
C203 C204 1.375(10) . ?
C204 C205 1.387(10) . ?
C205 C206 1.373(10) . ?
C60 Cl61 1.73(2) . ?
C60 Cl62 1.77(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C33 Au1 Cl1 175.13(17) . . ?
C21 Ag1 N24 88.8(2) . . ?
C21 Ag1 N22 90.5(2) . . ?
N24 Ag1 N22 179.15(19) . . ?
C21 Ag1 N23 176.4(2) . . ?
N24 Ag1 N23 90.7(2) . . ?
N22 Ag1 N23 90.0(2) . . ?
C33 N2 C3 111.3(5) . . ?
C33 N2 C1 140.4(5) . . ?
C3 N2 C1 108.0(5) . . ?
C6 N22 C9 107.6(5) . . ?
C6 N22 Ag1 127.2(4) . . ?
C9 N22 Ag1 124.4(4) . . ?
C11 N23 C14 107.1(5) . . ?
C11 N23 Ag1 126.3(4) . . ?
C14 N23 Ag1 125.1(4) . . ?
C16 N24 C19 107.1(5) . . ?
C16 N24 Ag1 124.3(4) . . ?
C19 N24 Ag1 126.7(4) . . ?
C33 N32 C31 112.1(5) . . ?
C33 N32 C34 125.8(6) . . ?
C31 N32 C34 122.0(5) . . ?
C21 C1 C20 129.1(6) . . ?
C21 C1 N2 106.4(5) . . ?
C20 C1 N2 124.3(6) . . ?
C31 C3 N2 106.1(5) . . ?
C31 C3 C4 144.9(6) . . ?
N2 C3 C4 108.9(5) . . ?
C5 C4 C21 129.0(5) . . ?
C5 C4 C3 124.9(5) . . ?
C21 C4 C3 106.0(5) . . ?
C6 C5 C4 122.7(5) . . ?
C6 C5 C51 119.7(5) . . ?
C4 C5 C51 117.6(5) . . ?
N22 C6 C5 125.2(6) . . ?
N22 C6 C7 109.7(5) . . ?
C5 C6 C7 125.0(5) . . ?
C8 C7 C6 106.8(5) . . ?
C7 C8 C9 107.6(5) . . ?
N22 C9 C10 127.6(6) . . ?
N22 C9 C8 108.3(5) . . ?
C10 C9 C8 123.9(6) . . ?
C9 C10 C11 123.9(6) . . ?
C9 C10 C101 120.0(5) . . ?
C11 C10 C101 115.8(5) . . ?
N23 C11 C10 125.3(5) . . ?
N23 C11 C12 108.8(5) . . ?
C10 C11 C12 126.0(6) . . ?
C13 C12 C11 107.6(5) . . ?
C12 C13 C14 107.6(5) . . ?
N23 C14 C15 125.0(5) . . ?
N23 C14 C13 108.9(5) . . ?
C15 C14 C13 126.0(5) . . ?
C14 C15 C16 124.0(5) . . ?
C14 C15 C151 118.5(5) . . ?
C16 C15 C151 117.6(6) . . ?
N24 C16 C15 127.5(6) . . ?
N24 C16 C17 108.8(5) . . ?
C15 C16 C17 123.7(6) . . ?
C18 C17 C16 107.9(5) . . ?
C17 C18 C19 107.4(6) . . ?
N24 C19 C20 126.3(5) . . ?
N24 C19 C18 108.5(5) . . ?
C20 C19 C18 124.7(6) . . ?
C1 C20 C19 118.4(6) . . ?
C1 C20 C201 124.7(5) . . ?
C19 C20 C201 116.9(5) . . ?
C1 C21 C4 110.5(5) . . ?
C1 C21 Ag1 125.2(4) . . ?
C4 C21 Ag1 123.7(5) . . ?
N32 C31 C3 106.0(5) . . ?
N2 C33 N32 104.5(5) . . ?
N2 C33 Au1 133.5(4) . . ?
N32 C33 Au1 121.2(4) . . ?
Cl41 C40 Cl42 110.3(4) . . ?
C52 C51 C56 118.8(5) . . ?
C52 C51 C5 120.9(5) . . ?
C56 C51 C5 120.1(5) . . ?
C53 C52 C51 120.0(6) . . ?
C54 C53 C52 119.7(6) . . ?
C55 C54 C53 121.3(6) . . ?
C54 C55 C56 119.8(6) . . ?
C55 C56 C51 120.5(6) . . ?
C102 C101 C106 118.2(6) . . ?
C102 C101 C10 121.1(5) . . ?
C106 C101 C10 120.6(5) . . ?
C103 C102 C101 120.0(6) . . ?
C104 C103 C102 121.0(6) . . ?
C105 C104 C103 119.5(6) . . ?
C104 C105 C106 121.0(6) . . ?
C105 C106 C101 120.2(6) . . ?
C152 C151 C156 118.8(6) . . ?
C152 C151 C15 122.0(6) . . ?
C156 C151 C15 119.2(6) . . ?
C151 C152 C153 120.1(6) . . ?
C154 C153 C152 120.3(6) . . ?
C153 C154 C155 120.8(6) . . ?
C154 C155 C156 118.5(7) . . ?
C155 C156 C151 121.6(6) . . ?
C202 C201 C206 118.4(6) . . ?
C202 C201 C20 121.5(5) . . ?
C206 C201 C20 119.9(6) . . ?
C203 C202 C201 120.7(6) . . ?
C204 C203 C202 119.9(6) . . ?
C203 C204 C205 120.3(6) . . ?
C206 C205 C204 119.9(6) . . ?
C205 C206 C201 120.8(6) . . ?
Cl61 C60 Cl62 115.6(16) . . ?

_refine_diff_density_max         1.740
_refine_diff_density_min         -1.471
_refine_diff_density_rms         0.208


_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: Dichloromethane/ hexane'
