# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelx
_database_code_depnum_ccdc_archive 'CCDC 1979249'
loop_
_audit_author_name
_audit_author_address
'Armando di Biase'
;Universita degli Studi di Milano, Dipartimento di Chimica
Italy
;
_audit_update_record             
;
2020-01-21 deposited with the CCDC.	2020-05-04 downloaded from the CCDC.
;
# start Validation Reply Form
_vrf_PLAT971_shelx               
;
PROBLEM: Check Calcd Resid. Dens.  0.92A   From Pt2             3.25 eA-3
RESPONSE: Critical absorption correction
;
_vrf_PLAT971_shelx_2             
;
PROBLEM: Check Calcd Resid. Dens.  0.92A   From Pt2             3.10 eA-3
RESPONSE: Critical absorption correction
;
_vrf_PLAT971_shelx_3             
;
PROBLEM: Check Calcd Resid. Dens.  0.93A   From Pt1             3.00 eA-3
RESPONSE: Critical absorption correction
;
# Added during the CSD deposition process: Tuesday 21 January 2020 03:31 PM
# end Validation Reply Form


_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         '(Pt 2+), (C32 H26 N6 S 2-), 0.5(C H2 Cl2)'
_chemical_formula_sum            'C32.50 H27 Cl N6 Pt S'
_chemical_formula_weight         764.20

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   20.869(2)
_cell_length_b                   9.2720(1)
_cell_length_c                   29.834(3)
_cell_angle_alpha                90
_cell_angle_beta                 92.711(2)
_cell_angle_gamma                90
_cell_volume                     5766(2)
_cell_formula_units_Z            8
_cell_measurement_temperature    200(2)
_cell_measurement_reflns_used    9926
_cell_measurement_theta_min      2.30
_cell_measurement_theta_max      25.26

_exptl_crystal_description       plate
_exptl_crystal_colour            red
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.761
_exptl_crystal_F_000             3000
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.06
_exptl_crystal_size_min          0.01
_exptl_absorpt_coefficient_mu    5.066
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.699
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_process_details   SADABS
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      200(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'sealed X-ray tube'
_diffrn_measurement_device_type  'Bruker APEX II CCD diffractometer'
_diffrn_measurement_method       'omega scan'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            39824
_diffrn_reflns_av_unetI/netI     0.0581
_diffrn_reflns_av_R_equivalents  0.0882
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_l_min       -35
_diffrn_reflns_limit_l_max       35
_diffrn_reflns_theta_min         1.165
_diffrn_reflns_theta_max         25.290
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             10463
_reflns_number_gt                8347
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        'Bruker AXS SAINT software'
_computing_structure_solution    SIR-92
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0433P)²+75.6900P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         10463
_refine_ls_number_parameters     748
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0848
_refine_ls_R_factor_gt           0.0618
_refine_ls_wR_factor_ref         0.1348
_refine_ls_wR_factor_gt          0.1264
_refine_ls_goodness_of_fit_ref   1.119
_refine_ls_restrained_S_all      1.119
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.003

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.9899(4) 0.9009(10) 0.1177(3) 0.026(2) Uani 1 1 d . . . . .
C2 C 1.0329(5) 0.9863(10) 0.0961(3) 0.027(2) Uani 1 1 d . . . . .
C3 C 1.0026(5) 1.0728(11) 0.0604(3) 0.030(2) Uani 1 1 d . . . . .
C4 C 1.0321(5) 1.1706(11) 0.0328(3) 0.034(3) Uani 1 1 d . . . . .
H4 H 1.076274 1.184124 0.035845 0.041 Uiso 1 1 calc R U . . .
C5 C 0.9972(6) 1.2472(12) 0.0012(4) 0.042(3) Uani 1 1 d . . . . .
H5 H 1.017330 1.311731 -0.017432 0.050 Uiso 1 1 calc R U . . .
C6 C 0.9319(6) 1.2280(12) -0.0029(4) 0.041(3) Uani 1 1 d . . . . .
H6 H 0.907242 1.279161 -0.024280 0.049 Uiso 1 1 calc R U . . .
C7 C 0.9040(6) 1.1334(12) 0.0247(3) 0.036(3) Uani 1 1 d . . . . .
H7 H 0.859618 1.123967 0.022618 0.044 Uiso 1 1 calc R U . . .
C8 C 1.0083(5) 0.8066(11) 0.1526(3) 0.028(2) Uani 1 1 d . . . . .
C9 C 1.0728(5) 0.8081(11) 0.1677(4) 0.034(2) Uani 1 1 d . . . . .
H9 H 1.086148 0.750058 0.191806 0.040 Uiso 1 1 calc R U . . .
C10 C 1.1178(5) 0.8962(11) 0.1471(3) 0.033(2) Uani 1 1 d . . . . .
C11 C 1.0972(5) 0.9838(12) 0.1115(3) 0.032(2) Uani 1 1 d . . . . .
H11 H 1.126737 1.041982 0.097637 0.039 Uiso 1 1 calc R U . . .
C12 C 0.9540(5) 0.7236(10) 0.1693(3) 0.026(2) Uani 1 1 d . . . . .
C13 C 0.9585(5) 0.6263(11) 0.2036(4) 0.035(2) Uani 1 1 d . . . . .
H13 H 0.997342 0.610980 0.219405 0.043 Uiso 1 1 calc R U . . .
C14 C 0.9038(5) 0.5503(11) 0.2144(4) 0.037(3) Uani 1 1 d . . . . .
H14 H 0.905822 0.482101 0.237310 0.045 Uiso 1 1 calc R U . . .
C15 C 0.8477(5) 0.5766(11) 0.1913(4) 0.036(3) Uani 1 1 d . . . . .
H15 H 0.810799 0.526821 0.198321 0.043 Uiso 1 1 calc R U . . .
C16 C 0.8453(5) 0.6791(10) 0.1568(3) 0.031(2) Uani 1 1 d . . . . .
H16 H 0.806614 0.696850 0.140949 0.037 Uiso 1 1 calc R U . . .
C17 C 1.1855(5) 0.8984(11) 0.1659(3) 0.031(2) Uani 1 1 d . . . . .
C18 C 1.2247(6) 0.7767(13) 0.1634(4) 0.048(3) Uani 1 1 d . . . . .
C19 C 1.2861(6) 0.7817(13) 0.1832(5) 0.050(3) Uani 1 1 d . . . . .
H19 H 1.311994 0.700474 0.181367 0.060 Uiso 1 1 calc R U . . .
C20 C 1.3103(5) 0.8984(14) 0.2051(4) 0.046(3) Uani 1 1 d . . . . .
C21 C 1.2704(5) 1.0185(13) 0.2072(4) 0.041(3) Uani 1 1 d . . . . .
H21 H 1.285628 1.100075 0.222392 0.049 Uiso 1 1 calc R U . . .
C22 C 1.2096(5) 1.0212(12) 0.1878(4) 0.035(3) Uani 1 1 d . . . . .
C23 C 1.1708(6) 1.1564(14) 0.1899(5) 0.057(4) Uani 1 1 d . . . . .
H23A H 1.189427 1.219102 0.212496 0.068 Uiso 1 1 calc R U . . .
H23B H 1.127676 1.132674 0.197112 0.068 Uiso 1 1 calc R U . . .
H23C H 1.170190 1.204037 0.161278 0.068 Uiso 1 1 calc R U . . .
C24 C 1.2017(7) 0.6436(15) 0.1395(6) 0.077(5) Uani 1 1 d . . . . .
H24A H 1.199296 0.661012 0.107747 0.092 Uiso 1 1 calc R U . . .
H24B H 1.159976 0.618300 0.149227 0.092 Uiso 1 1 calc R U . . .
H24C H 1.231061 0.565941 0.146154 0.092 Uiso 1 1 calc R U . . .
C25 C 1.3778(6) 0.9070(15) 0.2250(5) 0.060(4) Uani 1 1 d . . . . .
H25A H 1.393625 0.811464 0.231076 0.072 Uiso 1 1 calc R U . . .
H25B H 1.378135 0.961227 0.252419 0.072 Uiso 1 1 calc R U . . .
H25C H 1.404652 0.953861 0.204177 0.072 Uiso 1 1 calc R U . . .
C26 C 0.7977(5) 0.7896(12) 0.0203(3) 0.036(3) Uani 1 1 d . . . . .
C27 C 0.7079(6) 0.8983(13) -0.0301(4) 0.044(3) Uani 1 1 d . . . . .
C28 C 0.6614(6) 0.9289(15) 0.0001(5) 0.057(4) Uani 1 1 d . . . . .
H28 H 0.664317 0.889716 0.028791 0.068 Uiso 1 1 calc R U . . .
C29 C 0.6114(7) 1.0169(17) -0.0125(5) 0.068(4) Uani 1 1 d . . . . .
H29 H 0.579853 1.037722 0.007480 0.082 Uiso 1 1 calc R U . . .
C30 C 0.6078(9) 1.0755(18) -0.0556(6) 0.079(5) Uani 1 1 d . . . . .
H30 H 0.573912 1.135879 -0.064373 0.095 Uiso 1 1 calc R U . . .
C31 C 0.6535(9) 1.0446(19) -0.0847(5) 0.078(5) Uani 1 1 d . . . . .
H31 H 0.650937 1.082685 -0.113527 0.093 Uiso 1 1 calc R U . . .
C32 C 0.7042(8) 0.9562(16) -0.0713(4) 0.064(4) Uani 1 1 d . . . . .
H32 H 0.736095 0.936650 -0.091160 0.076 Uiso 1 1 calc R U . . .
C33 C 0.8326(4) 1.2183(9) 0.1414(3) 0.0191(19) Uani 1 1 d . . . . .
C34 C 0.7698(5) 1.1705(10) 0.1447(3) 0.027(2) Uani 1 1 d . . . . .
C35 C 0.7640(5) 1.0525(10) 0.1775(3) 0.027(2) Uani 1 1 d . . . . .
C36 C 0.7085(5) 0.9767(11) 0.1853(4) 0.036(3) Uani 1 1 d . . . . .
H36 H 0.670822 0.996683 0.168486 0.043 Uiso 1 1 calc R U . . .
C37 C 0.7091(6) 0.8718(12) 0.2179(4) 0.045(3) Uani 1 1 d . . . . .
H37 H 0.672446 0.818391 0.223138 0.054 Uiso 1 1 calc R U . . .
C38 C 0.7655(6) 0.8484(11) 0.2426(4) 0.038(3) Uani 1 1 d . . . . .
H38 H 0.766818 0.779731 0.265339 0.045 Uiso 1 1 calc R U . . .
C39 C 0.8195(6) 0.9246(11) 0.2341(3) 0.036(3) Uani 1 1 d . . . . .
H39 H 0.857038 0.908249 0.251442 0.043 Uiso 1 1 calc R U . . .
C40 C 0.8492(5) 1.3291(9) 0.1133(3) 0.021(2) Uani 1 1 d . . . . .
C41 C 0.9171(5) 1.3629(10) 0.1157(3) 0.026(2) Uani 1 1 d . . . . .
C42 C 0.9493(5) 1.4625(11) 0.0918(3) 0.034(2) Uani 1 1 d . . . . .
H42 H 0.926654 1.519001 0.070774 0.040 Uiso 1 1 calc R U . . .
C43 C 1.0151(5) 1.4817(12) 0.0982(4) 0.037(3) Uani 1 1 d . . . . .
H43 H 1.036691 1.549192 0.081443 0.045 Uiso 1 1 calc R U . . .
C44 C 1.0473(5) 1.3979(12) 0.1299(4) 0.042(3) Uani 1 1 d . . . . .
H44 H 1.091504 1.407002 0.134709 0.050 Uiso 1 1 calc R U . . .
C45 C 1.0138(5) 1.3007(12) 0.1546(4) 0.037(3) Uani 1 1 d . . . . .
H45 H 1.036268 1.246723 0.176396 0.044 Uiso 1 1 calc R U . . .
C46 C 0.8015(5) 1.3967(12) 0.0876(4) 0.038(3) Uani 1 1 d . . . . .
H46 H 0.811819 1.471360 0.068351 0.046 Uiso 1 1 calc R U . . .
C47 C 0.7383(4) 1.3535(12) 0.0903(3) 0.031(2) Uani 1 1 d . . . . .
C48 C 0.7223(5) 1.2395(11) 0.1182(3) 0.032(2) Uani 1 1 d . . . . .
H48 H 0.679810 1.209575 0.119154 0.039 Uiso 1 1 calc R U . . .
C49 C 0.6864(5) 1.4345(13) 0.0649(4) 0.042(3) Uani 1 1 d . . . . .
C50 C 0.6792(6) 1.4194(14) 0.0184(4) 0.046(3) Uani 1 1 d . . . . .
C51 C 0.6315(6) 1.4941(16) -0.0047(5) 0.057(4) Uani 1 1 d . . . . .
H51 H 0.626424 1.482908 -0.035646 0.068 Uiso 1 1 calc R U . . .
C52 C 0.5904(6) 1.5862(15) 0.0170(6) 0.063(4) Uani 1 1 d . . . . .
C53 C 0.5994(6) 1.6023(15) 0.0627(5) 0.061(4) Uani 1 1 d . . . . .
H53 H 0.572926 1.665427 0.077505 0.073 Uiso 1 1 calc R U . . .
C54 C 0.6461(5) 1.5282(13) 0.0874(4) 0.044(3) Uani 1 1 d . . . . .
C55 C 0.6528(8) 1.5503(17) 0.1382(5) 0.070(4) Uani 1 1 d . . . . .
H55A H 0.623083 1.622862 0.146969 0.084 Uiso 1 1 calc R U . . .
H55B H 0.695772 1.580529 0.146451 0.084 Uiso 1 1 calc R U . . .
H55C H 0.643821 1.461294 0.153118 0.084 Uiso 1 1 calc R U . . .
C56 C 0.7226(7) 1.3233(15) -0.0067(4) 0.057(4) Uani 1 1 d . . . . .
H56A H 0.705129 1.309747 -0.036763 0.068 Uiso 1 1 calc R U . . .
H56B H 0.726326 1.231606 0.008120 0.068 Uiso 1 1 calc R U . . .
H56C H 0.764260 1.366946 -0.007638 0.068 Uiso 1 1 calc R U . . .
C57 C 0.5383(8) 1.6653(19) -0.0090(7) 0.096(6) Uani 1 1 d . . . . .
H57A H 0.515330 1.725445 0.010918 0.115 Uiso 1 1 calc R U . . .
H57B H 0.509267 1.597124 -0.023234 0.115 Uiso 1 1 calc R U . . .
H57C H 0.556860 1.724137 -0.031514 0.115 Uiso 1 1 calc R U . . .
C58 C 0.9824(5) 1.1429(11) 0.2788(4) 0.032(2) Uani 1 1 d . . . . .
C59 C 1.0724(6) 1.0212(12) 0.3250(4) 0.043(3) Uani 1 1 d . . . . .
C60 C 1.1091(6) 0.9732(13) 0.2902(4) 0.048(3) Uani 1 1 d . . . . .
H60 H 1.099933 1.003520 0.260868 0.057 Uiso 1 1 calc R U . . .
C61 C 1.1603(7) 0.8777(15) 0.3002(5) 0.060(4) Uani 1 1 d . . . . .
H61 H 1.185491 0.843841 0.277590 0.072 Uiso 1 1 calc R U . . .
C62 C 1.1724(7) 0.8355(17) 0.3440(5) 0.068(4) Uani 1 1 d . . . . .
H62 H 1.206265 0.773276 0.351107 0.082 Uiso 1 1 calc R U . . .
C63 C 1.1350(7) 0.8845(16) 0.3768(4) 0.065(4) Uani 1 1 d . . . . .
H63 H 1.142105 0.852442 0.406173 0.078 Uiso 1 1 calc R U . . .
C64 C 1.0869(7) 0.9809(14) 0.3666(4) 0.059(4) Uani 1 1 d . . . . .
H64 H 1.063758 1.019191 0.389734 0.071 Uiso 1 1 calc R U . . .
C65 C 0.4990(8) 0.8676(17) 0.8636(5) 0.077(5) Uani 1 1 d . . . . .
H65A H 0.508098 0.966970 0.855944 0.092 Uiso 1 1 calc R U . . .
H65B H 0.539277 0.821707 0.872915 0.092 Uiso 1 1 calc R U . . .
N1 N 0.9376(4) 1.0516(8) 0.0553(3) 0.0287(19) Uani 1 1 d . . . . .
N2 N 0.8975(4) 0.7513(9) 0.1464(3) 0.0284(19) Uani 1 1 d . . . . .
N3 N 0.8396(4) 0.6858(11) 0.0137(3) 0.043(2) Uani 1 1 d . . . . .
N4 N 0.8264(6) 0.6357(13) -0.0280(4) 0.061(3) Uani 1 1 d . . . . .
N5 N 0.7788(6) 0.7033(13) -0.0482(3) 0.061(3) Uani 1 1 d . . . . .
N6 N 0.7589(5) 0.8024(10) -0.0175(3) 0.041(2) Uani 1 1 d . . . . .
N7 N 0.9508(4) 1.2800(8) 0.1487(3) 0.0284(19) Uani 1 1 d . . . . .
N8 N 0.8193(4) 1.0215(9) 0.2015(3) 0.031(2) Uani 1 1 d . . . . .
N9 N 0.9472(5) 1.2622(10) 0.2855(3) 0.043(2) Uani 1 1 d . . . . .
N10 N 0.9665(5) 1.3087(11) 0.3271(4) 0.051(3) Uani 1 1 d . . . . .
N11 N 1.0112(5) 1.2294(11) 0.3455(3) 0.052(3) Uani 1 1 d . . . . .
N12 N 1.0216(4) 1.1232(9) 0.3153(3) 0.035(2) Uani 1 1 d . . . . .
S1 S 0.79086(13) 0.8976(3) 0.06730(9) 0.0372(6) Uani 1 1 d . . . . .
S2 S 0.97871(14) 1.0349(3) 0.23230(9) 0.0373(7) Uani 1 1 d . . . . .
Cl1 Cl 0.4483(3) 0.8641(14) 0.90734(19) 0.220(6) Uani 1 1 d . . . . .
Cl2 Cl 0.4663(4) 0.7807(7) 0.8174(2) 0.138(2) Uani 1 1 d . . . . .
Pt1 Pt 0.90146(2) 0.90096(4) 0.09663(2) 0.02577(12) Uani 1 1 d . . . . .
Pt2 Pt 0.89716(2) 1.13726(4) 0.18208(2) 0.02634(12) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.380(13) . ?
C1 C8 1.400(14) . ?
C1 Pt1 1.921(10) . ?
C2 C11 1.397(14) . ?
C2 C3 1.454(14) . ?
C3 N1 1.372(13) . ?
C3 C4 1.389(14) . ?
C4 C5 1.363(15) . ?
C4 H4 0.9300 . ?
C5 C6 1.374(16) . ?
C5 H5 0.9300 . ?
C6 C7 1.354(15) . ?
C6 H6 0.9300 . ?
C7 N1 1.356(13) . ?
C7 H7 0.9300 . ?
C8 C9 1.399(14) . ?
C8 C12 1.476(14) . ?
C9 C10 1.409(14) . ?
C9 H9 0.9300 . ?
C10 C11 1.389(14) . ?
C10 C17 1.495(14) . ?
C11 H11 0.9300 . ?
C12 N2 1.359(13) . ?
C12 C13 1.365(14) . ?
C13 C14 1.392(15) . ?
C13 H13 0.9300 . ?
C14 C15 1.353(15) . ?
C14 H14 0.9300 . ?
C15 C16 1.400(15) . ?
C15 H15 0.9300 . ?
C16 N2 1.327(12) . ?
C16 H16 0.9300 . ?
C17 C22 1.395(15) . ?
C17 C18 1.399(15) . ?
C18 C19 1.387(17) . ?
C18 C24 1.493(18) . ?
C19 C20 1.349(17) . ?
C19 H19 0.9300 . ?
C20 C21 1.394(16) . ?
C20 C25 1.504(17) . ?
C21 C22 1.368(15) . ?
C21 H21 0.9300 . ?
C22 C23 1.496(16) . ?
C23 H23A 0.9600 . ?
C23 H23B 0.9600 . ?
C23 H23C 0.9600 . ?
C24 H24A 0.9600 . ?
C24 H24B 0.9600 . ?
C24 H24C 0.9600 . ?
C25 H25A 0.9600 . ?
C25 H25B 0.9600 . ?
C25 H25C 0.9600 . ?
C26 N3 1.322(14) . ?
C26 N6 1.362(14) . ?
C26 S1 1.735(11) . ?
C27 C32 1.341(17) . ?
C27 C28 1.382(18) . ?
C27 N6 1.425(16) . ?
C28 C29 1.364(19) . ?
C28 H28 0.9300 . ?
C29 C30 1.39(2) . ?
C29 H29 0.9300 . ?
C30 C31 1.35(2) . ?
C30 H30 0.9300 . ?
C31 C32 1.38(2) . ?
C31 H31 0.9300 . ?
C32 H32 0.9300 . ?
C33 C40 1.382(12) . ?
C33 C34 1.392(13) . ?
C33 Pt2 1.923(9) . ?
C34 C48 1.393(14) . ?
C34 C35 1.476(14) . ?
C35 N8 1.360(13) . ?
C35 C36 1.385(14) . ?
C36 C37 1.376(16) . ?
C36 H36 0.9300 . ?
C37 C38 1.376(17) . ?
C37 H37 0.9300 . ?
C38 C39 1.365(15) . ?
C38 H38 0.9300 . ?
C39 N8 1.323(13) . ?
C39 H39 0.9300 . ?
C40 C46 1.378(15) . ?
C40 C41 1.449(13) . ?
C41 C42 1.363(14) . ?
C41 N7 1.410(13) . ?
C42 C43 1.388(15) . ?
C42 H42 0.9300 . ?
C43 C44 1.377(15) . ?
C43 H43 0.9300 . ?
C44 C45 1.375(15) . ?
C44 H44 0.9300 . ?
C45 N7 1.333(13) . ?
C45 H45 0.9300 . ?
C46 C47 1.385(14) . ?
C46 H46 0.9300 . ?
C47 C48 1.397(14) . ?
C47 C49 1.495(15) . ?
C48 H48 0.9300 . ?
C49 C50 1.394(16) . ?
C49 C54 1.402(16) . ?
C50 C51 1.373(17) . ?
C50 C56 1.498(18) . ?
C51 C52 1.39(2) . ?
C51 H51 0.9300 . ?
C52 C53 1.38(2) . ?
C52 C57 1.499(19) . ?
C53 C54 1.377(18) . ?
C53 H53 0.9300 . ?
C54 C55 1.530(18) . ?
C55 H55A 0.9600 . ?
C55 H55B 0.9600 . ?
C55 H55C 0.9600 . ?
C56 H56A 0.9600 . ?
C56 H56B 0.9600 . ?
C56 H56C 0.9600 . ?
C57 H57A 0.9600 . ?
C57 H57B 0.9600 . ?
C57 H57C 0.9600 . ?
C58 N12 1.344(13) . ?
C58 N9 1.347(13) . ?
C58 S2 1.709(11) . ?
C59 C64 1.318(16) . ?
C59 C60 1.393(17) . ?
C59 N12 1.439(14) . ?
C60 C61 1.408(17) . ?
C60 H60 0.9300 . ?
C61 C62 1.374(19) . ?
C61 H61 0.9300 . ?
C62 C63 1.359(19) . ?
C62 H62 0.9300 . ?
C63 C64 1.368(18) . ?
C63 H63 0.9300 . ?
C64 H64 0.9300 . ?
C65 Cl2 1.713(17) . ?
C65 Cl1 1.719(17) . ?
C65 H65A 0.9700 . ?
C65 H65B 0.9700 . ?
N1 Pt1 2.032(8) . ?
N2 Pt1 2.036(8) . ?
N3 N4 1.345(14) . ?
N4 N5 1.298(16) . ?
N5 N6 1.375(14) . ?
N7 Pt2 2.024(8) . ?
N8 Pt2 2.054(9) . ?
N9 N10 1.356(13) . ?
N10 N11 1.289(14) . ?
N11 N12 1.359(12) . ?
S1 Pt1 2.430(3) . ?
S2 Pt2 2.408(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 C8 122.9(9) . . ?
C2 C1 Pt1 118.9(8) . . ?
C8 C1 Pt1 118.0(7) . . ?
C1 C2 C11 118.2(9) . . ?
C1 C2 C3 112.8(9) . . ?
C11 C2 C3 128.9(9) . . ?
N1 C3 C4 119.5(10) . . ?
N1 C3 C2 113.3(9) . . ?
C4 C3 C2 127.3(10) . . ?
C5 C4 C3 120.8(11) . . ?
C5 C4 H4 119.6 . . ?
C3 C4 H4 119.6 . . ?
C4 C5 C6 119.3(10) . . ?
C4 C5 H5 120.3 . . ?
C6 C5 H5 120.3 . . ?
C7 C6 C5 118.9(10) . . ?
C7 C6 H6 120.6 . . ?
C5 C6 H6 120.6 . . ?
C6 C7 N1 123.3(11) . . ?
C6 C7 H7 118.4 . . ?
N1 C7 H7 118.3 . . ?
C9 C8 C1 117.4(9) . . ?
C9 C8 C12 129.7(9) . . ?
C1 C8 C12 112.8(9) . . ?
C8 C9 C10 121.1(10) . . ?
C8 C9 H9 119.5 . . ?
C10 C9 H9 119.5 . . ?
C11 C10 C9 119.0(10) . . ?
C11 C10 C17 122.2(9) . . ?
C9 C10 C17 118.7(9) . . ?
C10 C11 C2 121.3(9) . . ?
C10 C11 H11 119.4 . . ?
C2 C11 H11 119.4 . . ?
N2 C12 C13 122.0(9) . . ?
N2 C12 C8 113.2(8) . . ?
C13 C12 C8 124.8(9) . . ?
C12 C13 C14 118.7(10) . . ?
C12 C13 H13 120.6 . . ?
C14 C13 H13 120.6 . . ?
C15 C14 C13 119.3(10) . . ?
C15 C14 H14 120.4 . . ?
C13 C14 H14 120.3 . . ?
C14 C15 C16 119.8(10) . . ?
C14 C15 H15 120.1 . . ?
C16 C15 H15 120.1 . . ?
N2 C16 C15 120.8(10) . . ?
N2 C16 H16 119.6 . . ?
C15 C16 H16 119.6 . . ?
C22 C17 C18 119.0(10) . . ?
C22 C17 C10 120.1(9) . . ?
C18 C17 C10 120.9(10) . . ?
C19 C18 C17 118.8(11) . . ?
C19 C18 C24 120.1(11) . . ?
C17 C18 C24 121.1(11) . . ?
C20 C19 C18 123.4(11) . . ?
C20 C19 H19 118.3 . . ?
C18 C19 H19 118.3 . . ?
C19 C20 C21 116.9(11) . . ?
C19 C20 C25 123.7(12) . . ?
C21 C20 C25 119.4(12) . . ?
C22 C21 C20 122.6(12) . . ?
C22 C21 H21 118.7 . . ?
C20 C21 H21 118.7 . . ?
C21 C22 C17 119.3(10) . . ?
C21 C22 C23 119.5(11) . . ?
C17 C22 C23 121.2(10) . . ?
C22 C23 H23A 109.5 . . ?
C22 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C22 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C18 C24 H24A 109.5 . . ?
C18 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C18 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C20 C25 H25A 109.5 . . ?
C20 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C20 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
N3 C26 N6 108.1(10) . . ?
N3 C26 S1 128.5(9) . . ?
N6 C26 S1 123.4(9) . . ?
C32 C27 C28 120.2(14) . . ?
C32 C27 N6 120.1(13) . . ?
C28 C27 N6 119.7(11) . . ?
C29 C28 C27 119.6(13) . . ?
C29 C28 H28 120.2 . . ?
C27 C28 H28 120.2 . . ?
C28 C29 C30 119.6(15) . . ?
C28 C29 H29 120.2 . . ?
C30 C29 H29 120.2 . . ?
C31 C30 C29 120.0(16) . . ?
C31 C30 H30 120.0 . . ?
C29 C30 H30 120.0 . . ?
C30 C31 C32 119.7(15) . . ?
C30 C31 H31 120.1 . . ?
C32 C31 H31 120.1 . . ?
C27 C32 C31 120.8(16) . . ?
C27 C32 H32 119.6 . . ?
C31 C32 H32 119.6 . . ?
C40 C33 C34 123.0(9) . . ?
C40 C33 Pt2 119.0(7) . . ?
C34 C33 Pt2 117.7(7) . . ?
C33 C34 C48 117.4(9) . . ?
C33 C34 C35 112.9(9) . . ?
C48 C34 C35 129.6(9) . . ?
N8 C35 C36 120.0(9) . . ?
N8 C35 C34 114.4(9) . . ?
C36 C35 C34 125.6(10) . . ?
C37 C36 C35 119.9(11) . . ?
C37 C36 H36 120.1 . . ?
C35 C36 H36 120.1 . . ?
C36 C37 C38 118.0(10) . . ?
C36 C37 H37 121.0 . . ?
C38 C37 H37 121.0 . . ?
C39 C38 C37 120.8(11) . . ?
C39 C38 H38 119.6 . . ?
C37 C38 H38 119.6 . . ?
N8 C39 C38 120.9(11) . . ?
N8 C39 H39 119.6 . . ?
C38 C39 H39 119.6 . . ?
C46 C40 C33 118.7(9) . . ?
C46 C40 C41 127.5(9) . . ?
C33 C40 C41 113.8(8) . . ?
C42 C41 N7 119.6(9) . . ?
C42 C41 C40 128.7(9) . . ?
N7 C41 C40 111.8(8) . . ?
C41 C42 C43 121.6(10) . . ?
C41 C42 H42 119.2 . . ?
C43 C42 H42 119.2 . . ?
C44 C43 C42 118.0(10) . . ?
C44 C43 H43 121.0 . . ?
C42 C43 H43 121.0 . . ?
C45 C44 C43 119.6(10) . . ?
C45 C44 H44 120.2 . . ?
C43 C44 H44 120.2 . . ?
N7 C45 C44 123.3(10) . . ?
N7 C45 H45 118.4 . . ?
C44 C45 H45 118.4 . . ?
C40 C46 C47 120.1(11) . . ?
C40 C46 H46 120.0 . . ?
C47 C46 H46 120.0 . . ?
C46 C47 C48 120.7(10) . . ?
C46 C47 C49 119.7(10) . . ?
C48 C47 C49 119.6(9) . . ?
C34 C48 C47 120.1(10) . . ?
C34 C48 H48 120.0 . . ?
C47 C48 H48 119.9 . . ?
C50 C49 C54 120.0(11) . . ?
C50 C49 C47 119.6(11) . . ?
C54 C49 C47 120.4(10) . . ?
C51 C50 C49 119.4(13) . . ?
C51 C50 C56 119.4(12) . . ?
C49 C50 C56 121.3(11) . . ?
C50 C51 C52 121.6(13) . . ?
C50 C51 H51 119.2 . . ?
C52 C51 H51 119.2 . . ?
C53 C52 C51 118.1(12) . . ?
C53 C52 C57 121.5(16) . . ?
C51 C52 C57 120.4(16) . . ?
C52 C53 C54 122.4(14) . . ?
C52 C53 H53 118.8 . . ?
C54 C53 H53 118.8 . . ?
C53 C54 C49 118.6(12) . . ?
C53 C54 C55 119.5(12) . . ?
C49 C54 C55 121.9(11) . . ?
C54 C55 H55A 109.5 . . ?
C54 C55 H55B 109.5 . . ?
H55A C55 H55B 109.5 . . ?
C54 C55 H55C 109.5 . . ?
H55A C55 H55C 109.5 . . ?
H55B C55 H55C 109.5 . . ?
C50 C56 H56A 109.5 . . ?
C50 C56 H56B 109.5 . . ?
H56A C56 H56B 109.5 . . ?
C50 C56 H56C 109.5 . . ?
H56A C56 H56C 109.5 . . ?
H56B C56 H56C 109.5 . . ?
C52 C57 H57A 109.5 . . ?
C52 C57 H57B 109.5 . . ?
H57A C57 H57B 109.5 . . ?
C52 C57 H57C 109.5 . . ?
H57A C57 H57C 109.5 . . ?
H57B C57 H57C 109.5 . . ?
N12 C58 N9 107.8(9) . . ?
N12 C58 S2 125.5(8) . . ?
N9 C58 S2 126.7(8) . . ?
C64 C59 C60 120.1(12) . . ?
C64 C59 N12 120.7(11) . . ?
C60 C59 N12 119.0(10) . . ?
C59 C60 C61 118.7(12) . . ?
C59 C60 H60 120.6 . . ?
C61 C60 H60 120.6 . . ?
C62 C61 C60 118.9(13) . . ?
C62 C61 H61 120.5 . . ?
C60 C61 H61 120.5 . . ?
C63 C62 C61 120.3(13) . . ?
C63 C62 H62 119.9 . . ?
C61 C62 H62 119.9 . . ?
C62 C63 C64 119.9(13) . . ?
C62 C63 H63 120.1 . . ?
C64 C63 H63 120.1 . . ?
C59 C64 C63 121.9(13) . . ?
C59 C64 H64 119.1 . . ?
C63 C64 H64 119.1 . . ?
Cl2 C65 Cl1 111.4(10) . . ?
Cl2 C65 H65A 109.3 . . ?
Cl1 C65 H65A 109.3 . . ?
Cl2 C65 H65B 109.3 . . ?
Cl1 C65 H65B 109.3 . . ?
H65A C65 H65B 108.0 . . ?
C7 N1 C3 118.1(9) . . ?
C7 N1 Pt1 126.7(8) . . ?
C3 N1 Pt1 115.2(7) . . ?
C16 N2 C12 119.3(8) . . ?
C16 N2 Pt1 125.2(7) . . ?
C12 N2 Pt1 115.5(6) . . ?
C26 N3 N4 106.3(10) . . ?
N5 N4 N3 112.4(11) . . ?
N4 N5 N6 105.2(9) . . ?
C26 N6 N5 107.9(10) . . ?
C26 N6 C27 132.9(10) . . ?
N5 N6 C27 119.1(10) . . ?
C45 N7 C41 117.9(9) . . ?
C45 N7 Pt2 126.5(7) . . ?
C41 N7 Pt2 115.6(6) . . ?
C39 N8 C35 120.3(9) . . ?
C39 N8 Pt2 125.9(8) . . ?
C35 N8 Pt2 113.8(6) . . ?
C58 N9 N10 104.9(9) . . ?
N11 N10 N9 112.6(9) . . ?
N10 N11 N12 105.5(9) . . ?
C58 N12 N11 109.1(9) . . ?
C58 N12 C59 131.8(9) . . ?
N11 N12 C59 118.8(9) . . ?
C26 S1 Pt1 100.7(4) . . ?
C58 S2 Pt2 106.1(4) . . ?
C1 Pt1 N1 79.6(4) . . ?
C1 Pt1 N2 80.4(4) . . ?
N1 Pt1 N2 160.0(3) . . ?
C1 Pt1 S1 177.8(3) . . ?
N1 Pt1 S1 99.4(2) . . ?
N2 Pt1 S1 100.5(2) . . ?
C33 Pt2 N7 79.7(4) . . ?
C33 Pt2 N8 80.9(4) . . ?
N7 Pt2 N8 160.6(3) . . ?
C33 Pt2 S2 179.3(3) . . ?
N7 Pt2 S2 99.9(2) . . ?
N8 Pt2 S2 99.4(2) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C8 C1 C2 C11 -3.5(14) . . . . ?
Pt1 C1 C2 C11 -179.3(7) . . . . ?
C8 C1 C2 C3 178.8(9) . . . . ?
Pt1 C1 C2 C3 3.0(11) . . . . ?
C1 C2 C3 N1 -0.2(12) . . . . ?
C11 C2 C3 N1 -177.6(10) . . . . ?
C1 C2 C3 C4 179.2(10) . . . . ?
C11 C2 C3 C4 1.8(17) . . . . ?
N1 C3 C4 C5 0.9(16) . . . . ?
C2 C3 C4 C5 -178.4(10) . . . . ?
C3 C4 C5 C6 0.7(17) . . . . ?
C4 C5 C6 C7 0.1(17) . . . . ?
C5 C6 C7 N1 -2.7(17) . . . . ?
C2 C1 C8 C9 4.4(14) . . . . ?
Pt1 C1 C8 C9 -179.7(7) . . . . ?
C2 C1 C8 C12 -178.1(9) . . . . ?
Pt1 C1 C8 C12 -2.3(11) . . . . ?
C1 C8 C9 C10 -3.0(15) . . . . ?
C12 C8 C9 C10 -179.9(10) . . . . ?
C8 C9 C10 C11 0.8(15) . . . . ?
C8 C9 C10 C17 177.3(9) . . . . ?
C9 C10 C11 C2 0.2(15) . . . . ?
C17 C10 C11 C2 -176.2(9) . . . . ?
C1 C2 C11 C10 1.1(15) . . . . ?
C3 C2 C11 C10 178.4(10) . . . . ?
C9 C8 C12 N2 179.3(10) . . . . ?
C1 C8 C12 N2 2.2(12) . . . . ?
C9 C8 C12 C13 -1.8(17) . . . . ?
C1 C8 C12 C13 -178.8(9) . . . . ?
N2 C12 C13 C14 1.9(15) . . . . ?
C8 C12 C13 C14 -176.9(9) . . . . ?
C12 C13 C14 C15 -1.2(16) . . . . ?
C13 C14 C15 C16 0.3(16) . . . . ?
C14 C15 C16 N2 -0.1(15) . . . . ?
C11 C10 C17 C22 66.2(14) . . . . ?
C9 C10 C17 C22 -110.1(12) . . . . ?
C11 C10 C17 C18 -116.0(12) . . . . ?
C9 C10 C17 C18 67.6(14) . . . . ?
C22 C17 C18 C19 0.7(17) . . . . ?
C10 C17 C18 C19 -177.0(11) . . . . ?
C22 C17 C18 C24 -178.6(12) . . . . ?
C10 C17 C18 C24 3.6(18) . . . . ?
C17 C18 C19 C20 0(2) . . . . ?
C24 C18 C19 C20 179.5(14) . . . . ?
C18 C19 C20 C21 0(2) . . . . ?
C18 C19 C20 C25 -177.3(12) . . . . ?
C19 C20 C21 C22 -0.8(18) . . . . ?
C25 C20 C21 C22 176.5(11) . . . . ?
C20 C21 C22 C17 1.7(17) . . . . ?
C20 C21 C22 C23 -177.4(11) . . . . ?
C18 C17 C22 C21 -1.6(16) . . . . ?
C10 C17 C22 C21 176.2(10) . . . . ?
C18 C17 C22 C23 177.5(11) . . . . ?
C10 C17 C22 C23 -4.8(16) . . . . ?
C32 C27 C28 C29 0.8(19) . . . . ?
N6 C27 C28 C29 -177.8(12) . . . . ?
C27 C28 C29 C30 0(2) . . . . ?
C28 C29 C30 C31 0(2) . . . . ?
C29 C30 C31 C32 -1(2) . . . . ?
C28 C27 C32 C31 -1(2) . . . . ?
N6 C27 C32 C31 177.3(12) . . . . ?
C30 C31 C32 C27 1(2) . . . . ?
C40 C33 C34 C48 -0.2(14) . . . . ?
Pt2 C33 C34 C48 173.9(7) . . . . ?
C40 C33 C34 C35 -179.1(8) . . . . ?
Pt2 C33 C34 C35 -5.1(10) . . . . ?
C33 C34 C35 N8 6.2(11) . . . . ?
C48 C34 C35 N8 -172.6(9) . . . . ?
C33 C34 C35 C36 -174.8(9) . . . . ?
C48 C34 C35 C36 6.4(16) . . . . ?
N8 C35 C36 C37 1.1(14) . . . . ?
C34 C35 C36 C37 -177.9(9) . . . . ?
C35 C36 C37 C38 1.5(15) . . . . ?
C36 C37 C38 C39 -1.6(15) . . . . ?
C37 C38 C39 N8 -1.0(16) . . . . ?
C34 C33 C40 C46 0.6(13) . . . . ?
Pt2 C33 C40 C46 -173.4(7) . . . . ?
C34 C33 C40 C41 179.0(8) . . . . ?
Pt2 C33 C40 C41 5.0(10) . . . . ?
C46 C40 C41 C42 -3.7(16) . . . . ?
C33 C40 C41 C42 178.1(10) . . . . ?
C46 C40 C41 N7 174.5(9) . . . . ?
C33 C40 C41 N7 -3.7(11) . . . . ?
N7 C41 C42 C43 2.0(15) . . . . ?
C40 C41 C42 C43 -179.9(10) . . . . ?
C41 C42 C43 C44 -0.8(16) . . . . ?
C42 C43 C44 C45 -1.0(17) . . . . ?
C43 C44 C45 N7 1.6(17) . . . . ?
C33 C40 C46 C47 0.2(14) . . . . ?
C41 C40 C46 C47 -177.9(9) . . . . ?
C40 C46 C47 C48 -1.4(15) . . . . ?
C40 C46 C47 C49 175.4(9) . . . . ?
C33 C34 C48 C47 -1.0(14) . . . . ?
C35 C34 C48 C47 177.7(9) . . . . ?
C46 C47 C48 C34 1.8(15) . . . . ?
C49 C47 C48 C34 -175.0(9) . . . . ?
C46 C47 C49 C50 73.3(14) . . . . ?
C48 C47 C49 C50 -109.8(12) . . . . ?
C46 C47 C49 C54 -104.9(13) . . . . ?
C48 C47 C49 C54 72.0(14) . . . . ?
C54 C49 C50 C51 -1.7(18) . . . . ?
C47 C49 C50 C51 -180.0(11) . . . . ?
C54 C49 C50 C56 178.3(11) . . . . ?
C47 C49 C50 C56 0.0(17) . . . . ?
C49 C50 C51 C52 0.8(19) . . . . ?
C56 C50 C51 C52 -179.2(12) . . . . ?
C50 C51 C52 C53 1(2) . . . . ?
C50 C51 C52 C57 -179.4(13) . . . . ?
C51 C52 C53 C54 -2(2) . . . . ?
C57 C52 C53 C54 178.6(13) . . . . ?
C52 C53 C54 C49 1(2) . . . . ?
C52 C53 C54 C55 -179.3(13) . . . . ?
C50 C49 C54 C53 0.9(18) . . . . ?
C47 C49 C54 C53 179.2(11) . . . . ?
C50 C49 C54 C55 -179.0(12) . . . . ?
C47 C49 C54 C55 -0.7(18) . . . . ?
C64 C59 C60 C61 2(2) . . . . ?
N12 C59 C60 C61 177.5(11) . . . . ?
C59 C60 C61 C62 0(2) . . . . ?
C60 C61 C62 C63 1(2) . . . . ?
C61 C62 C63 C64 -3(3) . . . . ?
C60 C59 C64 C63 -4(2) . . . . ?
N12 C59 C64 C63 -179.8(13) . . . . ?
C62 C63 C64 C59 5(2) . . . . ?
C6 C7 N1 C3 4.3(15) . . . . ?
C6 C7 N1 Pt1 -177.4(8) . . . . ?
C4 C3 N1 C7 -3.3(14) . . . . ?
C2 C3 N1 C7 176.1(8) . . . . ?
C4 C3 N1 Pt1 178.2(7) . . . . ?
C2 C3 N1 Pt1 -2.4(10) . . . . ?
C15 C16 N2 C12 0.8(14) . . . . ?
C15 C16 N2 Pt1 179.1(7) . . . . ?
C13 C12 N2 C16 -1.8(14) . . . . ?
C8 C12 N2 C16 177.2(8) . . . . ?
C13 C12 N2 Pt1 179.7(8) . . . . ?
C8 C12 N2 Pt1 -1.3(10) . . . . ?
N6 C26 N3 N4 0.1(11) . . . . ?
S1 C26 N3 N4 -178.9(8) . . . . ?
C26 N3 N4 N5 0.6(14) . . . . ?
N3 N4 N5 N6 -1.0(14) . . . . ?
N3 C26 N6 N5 -0.7(11) . . . . ?
S1 C26 N6 N5 178.4(8) . . . . ?
N3 C26 N6 C27 -177.1(11) . . . . ?
S1 C26 N6 C27 2.0(16) . . . . ?
N4 N5 N6 C26 1.0(12) . . . . ?
N4 N5 N6 C27 178.0(10) . . . . ?
C32 C27 N6 C26 136.4(13) . . . . ?
C28 C27 N6 C26 -45.0(17) . . . . ?
C32 C27 N6 N5 -39.7(15) . . . . ?
C28 C27 N6 N5 138.9(11) . . . . ?
C44 C45 N7 C41 -0.3(15) . . . . ?
C44 C45 N7 Pt2 178.6(8) . . . . ?
C42 C41 N7 C45 -1.5(14) . . . . ?
C40 C41 N7 C45 -179.8(8) . . . . ?
C42 C41 N7 Pt2 179.5(7) . . . . ?
C40 C41 N7 Pt2 1.1(10) . . . . ?
C38 C39 N8 C35 3.6(14) . . . . ?
C38 C39 N8 Pt2 -176.5(7) . . . . ?
C36 C35 N8 C39 -3.7(13) . . . . ?
C34 C35 N8 C39 175.4(8) . . . . ?
C36 C35 N8 Pt2 176.4(7) . . . . ?
C34 C35 N8 Pt2 -4.5(10) . . . . ?
N12 C58 N9 N10 -1.1(12) . . . . ?
S2 C58 N9 N10 179.2(8) . . . . ?
C58 N9 N10 N11 1.5(13) . . . . ?
N9 N10 N11 N12 -1.2(14) . . . . ?
N9 C58 N12 N11 0.4(12) . . . . ?
S2 C58 N12 N11 -179.9(8) . . . . ?
N9 C58 N12 C59 -174.4(11) . . . . ?
S2 C58 N12 C59 5.3(17) . . . . ?
N10 N11 N12 C58 0.5(13) . . . . ?
N10 N11 N12 C59 176.1(10) . . . . ?
C64 C59 N12 C58 -152.0(13) . . . . ?
C60 C59 N12 C58 32.5(18) . . . . ?
C64 C59 N12 N11 33.6(17) . . . . ?
C60 C59 N12 N11 -141.9(11) . . . . ?
N3 C26 S1 Pt1 28.5(10) . . . . ?
N6 C26 S1 Pt1 -150.3(8) . . . . ?
N12 C58 S2 Pt2 179.5(8) . . . . ?
N9 C58 S2 Pt2 -0.9(10) . . . . ?

_refine_diff_density_max         3.194
_refine_diff_density_min         -2.383
_refine_diff_density_rms         0.178

