Supplementary Material (ESI) for Dalton Transactions
This journal is © The Royal Society of Chemistry 2002

Table S1: Atomic coordinates and isotropic displacement parameters Uiso (Å2) 
for KVIV/V2O3{O3P-(CH2)2-PO3} or MIL-3Kan.

Atoms		     x	 	    y	 	    z	  	  Uiso
V(1)		0.5072(5)	0.0433(5)	0.2301(4)	0.059(1)
V(2)		0.0537(7)	0.2666(4)	0.7469(5)	0.059(1)
P(1)		-0.418(1)	0.2561(7)	0.9200(7)	0.064(2)
P(2)		0.4998(9)	0.2443(7)	0.4937(7)	0.064(2)
K		0.0022(7)	-0.2097(5)	0.8861(5)	0.062(2)
O(1)		0.553(2)	0.093(1)	0.585(115)	0.049(2)
O(2)		0.569(2)	0.211(1)	0.3306(9)	0.049(2)
O(3)		0.284(1)	0.145(1)	0.2387(9)	0.049(2)
O(4)		0.133(2)	0.096(1)	0.821(1)	0.049(2)
O(5)		0.264(1)	0.271(1)	0.553(1)	0.049(2)
O(6)		0.060(2)	0.423(1)	0.831(1)	 0.049(2)
O(7)		-0.534(1)	0.149(1)	0.885(1)	0.049(2)
O(8)		-0.346(2)	0.157(1)	1.034(1)	0.049(2)
O(9)		-0.229(1)	0.272(1)	0.778(1)	0.049(2)
C(1)		0.550(2)	0.4320(9)	0.539(1)	 0.004(4)
C(2)		-0.571(1)	0.462(1)	0.982(2)	 0.004(4)