data_global
_journal_name_full               'Dalton Trans.'
_journal_coden_cambridge         0222
_journal_year                    ?
_journal_volume                  ?
_journal_page_first              ?
_publ_contact_author_name        'Serena Fantasia'
_publ_contact_author_email       sfantasia@ICIQ.ES
loop_
_publ_author_name
'Serena Fantasia'
'Jeffrey L. Petersen'
'Heiko Jacobsen'
'Luigi Cavallo'
'Steven P. Nolan'

data_sere62c_0m
_database_code_depnum_ccdc_archive 'CCDC 630114'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C33 H51 Cl11 N4 Pt'
_chemical_formula_weight         1088.82

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   P2(1)

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'

_cell_length_a                   9.6623(8)
_cell_length_b                   24.792(2)
_cell_length_c                   9.7344(8)
_cell_angle_alpha                90.00
_cell_angle_beta                 109.9250(10)
_cell_angle_gamma                90.00
_cell_volume                     2192.3(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9984
_cell_measurement_theta_min      5.38
_cell_measurement_theta_max      36.67

_exptl_crystal_description       Block
_exptl_crystal_colour            translucent
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      0
_exptl_crystal_density_diffrn    1.649
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1084
_exptl_absorpt_coefficient_mu    3.900
_exptl_absorpt_correction_type   none
_exptl_absorpt_correction_T_min  0.3045
_exptl_absorpt_correction_T_max  0.6964
_exptl_absorpt_process_details   ?

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            31846
_diffrn_reflns_av_R_equivalents  0.0211
_diffrn_reflns_av_sigmaI/netI    0.0528
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -30
_diffrn_reflns_limit_k_max       41
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_theta_min         5.38
_diffrn_reflns_theta_max         36.83
_reflns_number_total             16621
_reflns_number_gt                16371
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0117P)^2^+0.7043P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.027(3)
_refine_ls_number_reflns         16621
_refine_ls_number_parameters     442
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0233
_refine_ls_R_factor_gt           0.0228
_refine_ls_wR_factor_ref         0.0708
_refine_ls_wR_factor_gt          0.0704
_refine_ls_goodness_of_fit_ref   1.223
_refine_ls_restrained_S_all      1.223
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.830344(7) 0.412150(6) 0.635584(7) 0.00869(2) Uani 1 1 d . . .
Cl1 Cl 0.89279(7) 0.39571(3) 0.88890(6) 0.01638(10) Uani 1 1 d . . .
C1 C 0.6331(3) 0.38246(10) 0.6104(2) 0.0098(3) Uani 1 1 d . . .
N1 N 0.5048(2) 0.40855(13) 0.5922(2) 0.0125(4) Uani 1 1 d . . .
N2 N 0.6010(2) 0.32929(9) 0.6167(2) 0.0126(3) Uani 1 1 d . . .
C2 C 0.3942(3) 0.37293(12) 0.5878(3) 0.0188(5) Uani 1 1 d . . .
H2 H 0.2955 0.3818 0.5772 0.023 Uiso 1 1 calc R . .
N3 N 0.7540(2) 0.47962(9) 0.3638(2) 0.0122(3) Uani 1 1 d . . .
C3 C 0.4528(3) 0.32299(12) 0.6015(3) 0.0185(5) Uani 1 1 d . . .
H3 H 0.4029 0.2899 0.6008 0.022 Uiso 1 1 calc R . .
C4 C 0.4925(3) 0.46763(10) 0.6099(3) 0.0127(4) Uani 1 1 d . . .
H4 H 0.5761 0.4855 0.5893 0.015 Uiso 1 1 calc R . .
N4 N 0.7814(3) 0.39596(10) 0.3143(2) 0.0129(3) Uani 1 1 d . . .
C5 C 0.3488(3) 0.48969(11) 0.5026(3) 0.0148(4) Uani 1 1 d . . .
H5A H 0.2650 0.4693 0.5134 0.018 Uiso 1 1 calc R . .
H5B H 0.3479 0.4844 0.4015 0.018 Uiso 1 1 calc R . .
C6 C 0.3294(3) 0.54995(12) 0.5284(3) 0.0168(4) Uani 1 1 d . . .
H6A H 0.4061 0.5709 0.5056 0.020 Uiso 1 1 calc R . .
H6B H 0.2321 0.5622 0.4619 0.020 Uiso 1 1 calc R . .
C7 C 0.3409(3) 0.56064(12) 0.6873(3) 0.0196(5) Uani 1 1 d . . .
H7A H 0.3321 0.5998 0.7022 0.023 Uiso 1 1 calc R . .
H7B H 0.2596 0.5421 0.7082 0.023 Uiso 1 1 calc R . .
Cl8 Cl 1.07309(6) 0.44323(3) 0.67645(6) 0.01441(9) Uani 1 1 d . . .
C8 C 0.4894(4) 0.54004(12) 0.7915(3) 0.0201(5) Uani 1 1 d . . .
H8A H 0.5703 0.5601 0.7738 0.024 Uiso 1 1 calc R . .
H8B H 0.4957 0.5467 0.8938 0.024 Uiso 1 1 calc R . .
C9 C 0.5072(3) 0.47967(12) 0.7693(3) 0.0182(5) Uani 1 1 d . . .
H9A H 0.4311 0.4594 0.7948 0.022 Uiso 1 1 calc R . .
H9B H 0.6049 0.4676 0.8351 0.022 Uiso 1 1 calc R . .
C10 C 0.7063(3) 0.28431(10) 0.6514(3) 0.0127(4) Uani 1 1 d . . .
H10 H 0.8038 0.2986 0.6539 0.015 Uiso 1 1 calc R . .
C11 C 0.7252(3) 0.26088(11) 0.8033(3) 0.0164(4) Uani 1 1 d . . .
H11A H 0.7601 0.2895 0.8780 0.020 Uiso 1 1 calc R . .
H11B H 0.6289 0.2478 0.8049 0.020 Uiso 1 1 calc R . .
C12 C 0.8356(4) 0.21432(12) 0.8401(3) 0.0197(5) Uani 1 1 d . . .
H12A H 0.8410 0.1984 0.9351 0.024 Uiso 1 1 calc R . .
H12B H 0.9344 0.2284 0.8501 0.024 Uiso 1 1 calc R . .
C13 C 0.7931(4) 0.17038(12) 0.7228(3) 0.0193(5) Uani 1 1 d . . .
H13A H 0.7006 0.1529 0.7214 0.023 Uiso 1 1 calc R . .
H13B H 0.8712 0.1425 0.7464 0.023 Uiso 1 1 calc R . .
C14 C 0.7723(3) 0.19436(11) 0.5722(3) 0.0179(5) Uani 1 1 d . . .
H14A H 0.8679 0.2082 0.5705 0.021 Uiso 1 1 calc R . .
H14B H 0.7389 0.1657 0.4972 0.021 Uiso 1 1 calc R . .
C15 C 0.6597(3) 0.24018(11) 0.5352(3) 0.0147(4) Uani 1 1 d . . .
H15A H 0.6509 0.2556 0.4387 0.018 Uiso 1 1 calc R . .
H15B H 0.5622 0.2259 0.5292 0.018 Uiso 1 1 calc R . .
C16 C 0.7832(3) 0.42967(10) 0.4250(2) 0.0108(3) Uani 1 1 d . . .
C17 C 0.7351(3) 0.47669(12) 0.2156(3) 0.0168(4) Uani 1 1 d . . .
H17 H 0.7132 0.5059 0.1484 0.020 Uiso 1 1 calc R . .
C18 C 0.7537(3) 0.42480(11) 0.1854(3) 0.0180(5) Uani 1 1 d . . .
H18 H 0.7489 0.4106 0.0933 0.022 Uiso 1 1 calc R . .
C19 C 0.7659(3) 0.53090(10) 0.4426(3) 0.0125(4) Uani 1 1 d . . .
H19 H 0.7681 0.5228 0.5439 0.015 Uiso 1 1 calc R . .
C20 C 0.6333(3) 0.56702(11) 0.3692(3) 0.0163(4) Uani 1 1 d . . .
H20A H 0.5419 0.5483 0.3661 0.020 Uiso 1 1 calc R . .
H20B H 0.6272 0.5748 0.2675 0.020 Uiso 1 1 calc R . .
C21 C 0.6482(3) 0.62021(12) 0.4547(4) 0.0214(5) Uani 1 1 d . . .
H21A H 0.5630 0.6437 0.4046 0.026 Uiso 1 1 calc R . .
H21B H 0.6464 0.6124 0.5538 0.026 Uiso 1 1 calc R . .
C22 C 0.7892(4) 0.64989(12) 0.4675(4) 0.0234(6) Uani 1 1 d . . .
H22A H 0.7976 0.6827 0.5279 0.028 Uiso 1 1 calc R . .
H22B H 0.7872 0.6612 0.3693 0.028 Uiso 1 1 calc R . .
C23 C 0.9231(4) 0.61266(13) 0.5384(4) 0.0226(5) Uani 1 1 d . . .
H23A H 1.0143 0.6316 0.5412 0.027 Uiso 1 1 calc R . .
H23B H 0.9305 0.6046 0.6403 0.027 Uiso 1 1 calc R . .
C24 C 0.9096(3) 0.55975(12) 0.4535(3) 0.0184(5) Uani 1 1 d . . .
H24A H 0.9944 0.5361 0.5037 0.022 Uiso 1 1 calc R . .
H24B H 0.9110 0.5674 0.3541 0.022 Uiso 1 1 calc R . .
C25 C 0.8370(3) 0.34010(10) 0.3334(3) 0.0133(4) Uani 1 1 d . . .
H25 H 0.8319 0.3259 0.4278 0.016 Uiso 1 1 calc R . .
C26 C 0.7430(3) 0.30355(12) 0.2089(3) 0.0161(4) Uani 1 1 d . . .
H26A H 0.6416 0.3017 0.2116 0.019 Uiso 1 1 calc R . .
H26B H 0.7379 0.3194 0.1139 0.019 Uiso 1 1 calc R . .
C27 C 0.8068(3) 0.24670(12) 0.2216(3) 0.0189(5) Uani 1 1 d . . .
H27A H 0.7481 0.2252 0.1358 0.023 Uiso 1 1 calc R . .
H27B H 0.7995 0.2291 0.3102 0.023 Uiso 1 1 calc R . .
C28 C 0.9677(4) 0.24726(13) 0.2300(3) 0.0201(5) Uani 1 1 d . . .
H28A H 0.9742 0.2612 0.1371 0.024 Uiso 1 1 calc R . .
H28B H 1.0070 0.2100 0.2441 0.024 Uiso 1 1 calc R . .
C29 C 1.0602(4) 0.28292(13) 0.3571(3) 0.0218(5) Uani 1 1 d . . .
H29A H 1.0611 0.2671 0.4508 0.026 Uiso 1 1 calc R . .
H29B H 1.1630 0.2842 0.3582 0.026 Uiso 1 1 calc R . .
C30 C 0.9976(3) 0.34038(12) 0.3426(3) 0.0173(4) Uani 1 1 d . . .
H30A H 1.0563 0.3621 0.4279 0.021 Uiso 1 1 calc R . .
H30B H 1.0056 0.3574 0.2536 0.021 Uiso 1 1 calc R . .
Cl1S Cl 0.05345(10) 0.51143(4) 0.14661(10) 0.03173(18) Uani 1 1 d . . .
C1S C 0.1339(4) 0.51178(16) 0.0086(4) 0.0259(6) Uani 1 1 d . . .
H1S H 0.0711 0.4901 -0.0764 0.031 Uiso 1 1 calc R . .
Cl5S Cl 0.14481(16) 0.57920(5) -0.04975(13) 0.0438(3) Uani 1 1 d . . .
Cl6S Cl 0.31146(12) 0.48345(6) 0.07423(11) 0.0409(2) Uani 1 1 d . . .
Cl2S Cl 0.41776(10) 0.35737(5) 0.95036(10) 0.03266(18) Uani 1 1 d . . .
C2S C 0.2337(4) 0.34138(15) 0.9200(4) 0.0253(6) Uani 1 1 d . . .
H2S H 0.1738 0.3751 0.8938 0.030 Uiso 1 1 calc R . .
Cl3S Cl 0.21598(14) 0.31441(5) 1.08110(12) 0.0411(2) Uani 1 1 d . . .
Cl4S Cl 0.16707(11) 0.29470(4) 0.77398(11) 0.03205(17) Uani 1 1 d . . .
C3S C 0.3339(6) 0.18018(18) 0.0237(4) 0.0390(10) Uani 1 1 d . . .
H3S H 0.2904 0.2155 -0.0196 0.047 Uiso 1 1 calc R . .
Cl7S Cl 0.47642(17) 0.16343(7) -0.04480(13) 0.0533(4) Uani 1 1 d . . .
Cl8S Cl 0.19378(13) 0.13066(6) -0.02782(14) 0.0461(3) Uani 1 1 d . . .
Cl9S Cl 0.40628(17) 0.18738(5) 0.21485(10) 0.0454(3) Uani 1 1 d . . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Pt1 0.00799(3) 0.00904(3) 0.00913(3) -0.00075(3) 0.00303(2) -0.00079(3)
Cl1 0.0154(3) 0.0233(3) 0.01001(19) -0.00045(17) 0.00384(18) -0.00256(19)
C1 0.0128(9) 0.0080(8) 0.0099(7) -0.0006(6) 0.0057(7) -0.0009(6)
N1 0.0097(7) 0.0088(11) 0.0192(7) 0.0001(7) 0.0054(6) -0.0011(7)
N2 0.0110(8) 0.0108(8) 0.0170(8) -0.0009(6) 0.0061(7) -0.0019(6)
C2 0.0124(10) 0.0138(11) 0.0303(13) -0.0007(9) 0.0075(9) -0.0024(8)
N3 0.0142(9) 0.0113(8) 0.0108(7) 0.0013(6) 0.0040(6) 0.0003(6)
C3 0.0118(10) 0.0134(11) 0.0323(13) -0.0005(9) 0.0100(10) -0.0037(8)
C4 0.0120(9) 0.0102(9) 0.0170(9) 0.0009(7) 0.0064(8) 0.0000(7)
N4 0.0150(9) 0.0122(8) 0.0116(7) 0.0005(6) 0.0048(7) 0.0014(7)
C5 0.0134(10) 0.0152(11) 0.0158(9) 0.0010(8) 0.0050(8) 0.0025(8)
C6 0.0150(11) 0.0161(11) 0.0208(10) 0.0040(8) 0.0079(9) 0.0034(8)
C7 0.0224(13) 0.0149(11) 0.0233(12) -0.0007(9) 0.0103(10) 0.0025(9)
Cl8 0.0094(2) 0.0184(3) 0.0150(2) -0.00045(18) 0.00359(17) -0.00335(17)
C8 0.0267(14) 0.0140(11) 0.0186(10) -0.0018(8) 0.0065(10) 0.0013(9)
C9 0.0225(12) 0.0125(10) 0.0175(10) 0.0005(8) 0.0040(9) 0.0018(8)
C10 0.0153(10) 0.0092(9) 0.0143(9) -0.0008(7) 0.0058(8) -0.0009(7)
C11 0.0251(13) 0.0124(10) 0.0131(9) -0.0006(7) 0.0083(9) -0.0007(8)
C12 0.0281(14) 0.0145(11) 0.0146(10) 0.0002(8) 0.0047(9) 0.0003(9)
C13 0.0267(14) 0.0117(10) 0.0168(10) 0.0012(8) 0.0038(9) 0.0007(9)
C14 0.0248(13) 0.0125(10) 0.0170(10) -0.0035(8) 0.0079(9) 0.0007(9)
C15 0.0185(11) 0.0111(10) 0.0138(9) -0.0016(7) 0.0046(8) -0.0007(8)
C16 0.0091(8) 0.0113(8) 0.0126(8) 0.0005(7) 0.0046(7) 0.0000(7)
C17 0.0221(12) 0.0148(11) 0.0148(9) 0.0033(8) 0.0083(9) 0.0031(8)
C18 0.0235(12) 0.0184(13) 0.0128(8) 0.0016(7) 0.0072(8) 0.0023(8)
C19 0.0117(9) 0.0101(9) 0.0168(9) 0.0012(7) 0.0063(8) -0.0006(7)
C20 0.0132(10) 0.0131(10) 0.0217(11) -0.0007(8) 0.0046(8) 0.0010(8)
C21 0.0188(12) 0.0140(11) 0.0302(13) -0.0046(10) 0.0067(10) 0.0016(9)
C22 0.0258(14) 0.0107(11) 0.0312(14) 0.0003(10) 0.0065(12) -0.0031(9)
C23 0.0187(12) 0.0175(12) 0.0286(13) -0.0009(10) 0.0040(10) -0.0073(9)
C24 0.0128(11) 0.0173(12) 0.0243(11) 0.0034(9) 0.0055(9) -0.0020(8)
C25 0.0177(11) 0.0102(9) 0.0125(8) -0.0011(7) 0.0057(8) 0.0016(7)
C26 0.0140(10) 0.0185(12) 0.0146(9) -0.0037(8) 0.0034(8) -0.0016(8)
C27 0.0228(13) 0.0171(12) 0.0173(10) -0.0039(8) 0.0074(9) -0.0021(9)
C28 0.0236(13) 0.0175(12) 0.0187(10) -0.0055(9) 0.0064(9) 0.0012(9)
C29 0.0217(13) 0.0193(13) 0.0205(11) -0.0029(9) 0.0020(10) 0.0066(10)
C30 0.0144(11) 0.0160(11) 0.0187(10) -0.0050(8) 0.0019(8) 0.0020(8)
Cl1S 0.0291(4) 0.0421(5) 0.0294(4) -0.0060(3) 0.0169(3) -0.0045(3)
C1S 0.0237(15) 0.0339(18) 0.0203(12) -0.0062(11) 0.0077(11) -0.0020(12)
Cl5S 0.0690(8) 0.0326(5) 0.0409(5) -0.0018(4) 0.0333(5) -0.0002(5)
Cl6S 0.0285(4) 0.0638(8) 0.0311(4) -0.0057(4) 0.0110(3) 0.0080(4)
Cl2S 0.0210(4) 0.0410(5) 0.0316(4) 0.0058(3) 0.0033(3) -0.0020(3)
C2S 0.0248(15) 0.0238(15) 0.0266(13) 0.0072(11) 0.0077(11) 0.0043(11)
Cl3S 0.0541(6) 0.0405(6) 0.0385(5) 0.0164(4) 0.0284(5) 0.0131(5)
Cl4S 0.0330(4) 0.0282(4) 0.0337(4) 0.0006(3) 0.0099(3) -0.0038(3)
C3S 0.053(3) 0.0263(18) 0.0250(15) 0.0006(13) -0.0028(16) 0.0036(16)
Cl7S 0.0611(8) 0.0618(8) 0.0363(5) -0.0129(5) 0.0157(5) -0.0345(7)
Cl8S 0.0284(5) 0.0549(7) 0.0465(6) -0.0041(5) 0.0018(4) -0.0033(4)
Cl9S 0.0686(8) 0.0332(5) 0.0229(4) -0.0018(3) 0.0005(4) 0.0067(5)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C1 1.979(2) . ?
Pt1 C16 1.991(2) . ?
Pt1 Cl1 2.3657(6) . ?
Pt1 Cl8 2.3701(6) . ?
C1 N1 1.356(3) . ?
C1 N2 1.360(3) . ?
N1 C2 1.375(4) . ?
N1 C4 1.484(4) . ?
N2 C3 1.398(3) . ?
N2 C10 1.469(4) . ?
C2 C3 1.349(4) . ?
N3 C16 1.361(3) . ?
N3 C17 1.393(3) . ?
N3 C19 1.469(3) . ?
C4 C5 1.526(4) . ?
C4 C9 1.539(4) . ?
N4 C16 1.359(3) . ?
N4 C18 1.389(3) . ?
N4 C25 1.474(4) . ?
C5 C6 1.537(4) . ?
C6 C7 1.535(4) . ?
C7 C8 1.535(4) . ?
C8 C9 1.530(4) . ?
C10 C15 1.528(4) . ?
C10 C11 1.540(3) . ?
C11 C12 1.529(4) . ?
C12 C13 1.530(4) . ?
C13 C14 1.531(4) . ?
C14 C15 1.529(4) . ?
C17 C18 1.345(4) . ?
C19 C20 1.526(4) . ?
C19 C24 1.533(4) . ?
C20 C21 1.539(4) . ?
C21 C22 1.516(5) . ?
C22 C23 1.548(5) . ?
C23 C24 1.532(5) . ?
C25 C30 1.524(4) . ?
C25 C26 1.538(4) . ?
C26 C27 1.526(4) . ?
C27 C28 1.529(4) . ?
C28 C29 1.536(4) . ?
C29 C30 1.535(4) . ?
Cl1S C1S 1.766(3) . ?
C1S Cl6S 1.760(4) . ?
C1S Cl5S 1.780(4) . ?
Cl2S C2S 1.746(4) . ?
C2S Cl3S 1.766(3) . ?
C2S Cl4S 1.775(4) . ?
C3S Cl9S 1.759(4) . ?
C3S Cl8S 1.769(5) . ?
C3S Cl7S 1.771(6) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Pt1 C16 94.66(9) . . ?
C1 Pt1 Cl1 87.57(6) . . ?
C16 Pt1 Cl1 177.01(8) . . ?
C1 Pt1 Cl8 176.35(7) . . ?
C16 Pt1 Cl8 88.16(7) . . ?
Cl1 Pt1 Cl8 89.70(2) . . ?
N1 C1 N2 104.8(2) . . ?
N1 C1 Pt1 129.6(2) . . ?
N2 C1 Pt1 125.42(18) . . ?
C1 N1 C2 111.3(3) . . ?
C1 N1 C4 124.1(2) . . ?
C2 N1 C4 123.1(2) . . ?
C1 N2 C3 110.1(2) . . ?
C1 N2 C10 126.6(2) . . ?
C3 N2 C10 122.9(2) . . ?
C3 C2 N1 106.9(2) . . ?
C16 N3 C17 109.9(2) . . ?
C16 N3 C19 126.3(2) . . ?
C17 N3 C19 123.0(2) . . ?
C2 C3 N2 106.8(2) . . ?
N1 C4 C5 111.4(2) . . ?
N1 C4 C9 108.9(2) . . ?
C5 C4 C9 111.7(2) . . ?
C16 N4 C18 110.3(2) . . ?
C16 N4 C25 124.9(2) . . ?
C18 N4 C25 123.2(2) . . ?
C4 C5 C6 111.7(2) . . ?
C7 C6 C5 111.2(2) . . ?
C8 C7 C6 109.8(2) . . ?
C9 C8 C7 110.9(2) . . ?
C8 C9 C4 110.9(2) . . ?
N2 C10 C15 111.5(2) . . ?
N2 C10 C11 110.7(2) . . ?
C15 C10 C11 110.5(2) . . ?
C12 C11 C10 110.7(2) . . ?
C11 C12 C13 112.0(2) . . ?
C12 C13 C14 110.7(2) . . ?
C15 C14 C13 111.4(2) . . ?
C10 C15 C14 110.6(2) . . ?
N4 C16 N3 105.5(2) . . ?
N4 C16 Pt1 128.25(19) . . ?
N3 C16 Pt1 126.12(18) . . ?
C18 C17 N3 107.2(2) . . ?
C17 C18 N4 107.1(2) . . ?
N3 C19 C20 111.1(2) . . ?
N3 C19 C24 110.4(2) . . ?
C20 C19 C24 110.8(2) . . ?
C19 C20 C21 109.9(2) . . ?
C22 C21 C20 112.1(3) . . ?
C21 C22 C23 109.8(2) . . ?
C24 C23 C22 111.4(3) . . ?
C23 C24 C19 110.2(2) . . ?
N4 C25 C30 108.9(2) . . ?
N4 C25 C26 111.2(2) . . ?
C30 C25 C26 111.4(2) . . ?
C27 C26 C25 111.5(2) . . ?
C26 C27 C28 111.8(2) . . ?
C27 C28 C29 110.5(2) . . ?
C30 C29 C28 110.9(2) . . ?
C25 C30 C29 111.3(3) . . ?
Cl6S C1S Cl1S 110.4(2) . . ?
Cl6S C1S Cl5S 109.5(2) . . ?
Cl1S C1S Cl5S 109.7(2) . . ?
Cl2S C2S Cl3S 109.71(19) . . ?
Cl2S C2S Cl4S 110.7(2) . . ?
Cl3S C2S Cl4S 110.2(2) . . ?
Cl9S C3S Cl8S 111.1(3) . . ?
Cl9S C3S Cl7S 110.0(3) . . ?
Cl8S C3S Cl7S 110.4(2) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C16 Pt1 C1 N1 -77.3(2) . . . . ?
Cl1 Pt1 C1 N1 100.7(2) . . . . ?
Cl8 Pt1 C1 N1 142.4(9) . . . . ?
C16 Pt1 C1 N2 106.8(2) . . . . ?
Cl1 Pt1 C1 N2 -75.22(19) . . . . ?
Cl8 Pt1 C1 N2 -33.6(12) . . . . ?
N2 C1 N1 C2 0.4(3) . . . . ?
Pt1 C1 N1 C2 -176.20(19) . . . . ?
N2 C1 N1 C4 166.9(2) . . . . ?
Pt1 C1 N1 C4 -9.7(3) . . . . ?
N1 C1 N2 C3 0.3(3) . . . . ?
Pt1 C1 N2 C3 177.03(18) . . . . ?
N1 C1 N2 C10 -172.8(2) . . . . ?
Pt1 C1 N2 C10 3.9(3) . . . . ?
C1 N1 C2 C3 -0.9(3) . . . . ?
C4 N1 C2 C3 -167.6(2) . . . . ?
N1 C2 C3 N2 1.0(3) . . . . ?
C1 N2 C3 C2 -0.8(3) . . . . ?
C10 N2 C3 C2 172.6(2) . . . . ?
C1 N1 C4 C5 145.4(2) . . . . ?
C2 N1 C4 C5 -49.6(3) . . . . ?
C1 N1 C4 C9 -90.9(3) . . . . ?
C2 N1 C4 C9 74.1(3) . . . . ?
N1 C4 C5 C6 175.4(2) . . . . ?
C9 C4 C5 C6 53.3(3) . . . . ?
C4 C5 C6 C7 -55.0(3) . . . . ?
C5 C6 C7 C8 57.1(3) . . . . ?
C6 C7 C8 C9 -58.5(3) . . . . ?
C7 C8 C9 C4 57.2(3) . . . . ?
N1 C4 C9 C8 -177.9(2) . . . . ?
C5 C4 C9 C8 -54.4(3) . . . . ?
C1 N2 C10 C15 -127.7(2) . . . . ?
C3 N2 C10 C15 60.0(3) . . . . ?
C1 N2 C10 C11 108.9(3) . . . . ?
C3 N2 C10 C11 -63.4(3) . . . . ?
N2 C10 C11 C12 -179.6(2) . . . . ?
C15 C10 C11 C12 56.4(3) . . . . ?
C10 C11 C12 C13 -55.2(3) . . . . ?
C11 C12 C13 C14 54.6(3) . . . . ?
C12 C13 C14 C15 -55.5(3) . . . . ?
N2 C10 C15 C14 178.9(2) . . . . ?
C11 C10 C15 C14 -57.5(3) . . . . ?
C13 C14 C15 C10 57.4(3) . . . . ?
C18 N4 C16 N3 1.1(3) . . . . ?
C25 N4 C16 N3 166.7(2) . . . . ?
C18 N4 C16 Pt1 -175.5(2) . . . . ?
C25 N4 C16 Pt1 -9.9(4) . . . . ?
C17 N3 C16 N4 -0.4(3) . . . . ?
C19 N3 C16 N4 -170.1(2) . . . . ?
C17 N3 C16 Pt1 176.27(19) . . . . ?
C19 N3 C16 Pt1 6.6(4) . . . . ?
C1 Pt1 C16 N4 -80.5(2) . . . . ?
Cl1 Pt1 C16 N4 141.5(12) . . . . ?
Cl8 Pt1 C16 N4 97.2(2) . . . . ?
C1 Pt1 C16 N3 103.6(2) . . . . ?
Cl1 Pt1 C16 N3 -34.4(15) . . . . ?
Cl8 Pt1 C16 N3 -78.8(2) . . . . ?
C16 N3 C17 C18 -0.4(3) . . . . ?
C19 N3 C17 C18 169.7(2) . . . . ?
N3 C17 C18 N4 1.0(3) . . . . ?
C16 N4 C18 C17 -1.3(3) . . . . ?
C25 N4 C18 C17 -167.2(2) . . . . ?
C16 N3 C19 C20 -136.1(3) . . . . ?
C17 N3 C19 C20 55.6(3) . . . . ?
C16 N3 C19 C24 100.7(3) . . . . ?
C17 N3 C19 C24 -67.7(3) . . . . ?
N3 C19 C20 C21 179.5(2) . . . . ?
C24 C19 C20 C21 -57.4(3) . . . . ?
C19 C20 C21 C22 57.4(3) . . . . ?
C20 C21 C22 C23 -56.0(4) . . . . ?
C21 C22 C23 C24 55.8(4) . . . . ?
C22 C23 C24 C19 -56.8(3) . . . . ?
N3 C19 C24 C23 -178.8(2) . . . . ?
C20 C19 C24 C23 57.7(3) . . . . ?
C16 N4 C25 C30 -92.1(3) . . . . ?
C18 N4 C25 C30 71.7(3) . . . . ?
C16 N4 C25 C26 144.8(2) . . . . ?
C18 N4 C25 C26 -51.4(3) . . . . ?
N4 C25 C26 C27 175.6(2) . . . . ?
C30 C25 C26 C27 54.0(3) . . . . ?
C25 C26 C27 C28 -54.6(3) . . . . ?
C26 C27 C28 C29 55.8(3) . . . . ?
C27 C28 C29 C30 -56.5(4) . . . . ?
N4 C25 C30 C29 -178.0(2) . . . . ?
C26 C25 C30 C29 -55.0(3) . . . . ?
C28 C29 C30 C25 56.5(3) . . . . ?

_diffrn_measured_fraction_theta_max 0.947
_diffrn_reflns_theta_full        36.83
_diffrn_measured_fraction_theta_full 0.947
_refine_diff_density_max         1.468
_refine_diff_density_min         -2.103
_refine_diff_density_rms         0.154