# Supplementary Material (ESI) for Dalton Transactions # This journal is (c) The Royal Society of Chemistry 2009 data_global _journal_coden_Cambridge 222 _journal_volume ? _journal_page_first ? _journal_year ? loop_ _publ_author_name 'Ekkehardt Hahn' 'Christian Radloff' 'Jan Weigand' _publ_contact_author_name 'Ekkehardt Hahn' _publ_contact_author_email FEHAHN@UNI-MUENSTER.DE _publ_section_title ; A tetranuclear molecular rectangle from four gold(I) atoms linked by dicarbene and diphosphine ligands ; # Attachment '[1]xCHCl3.cif' data_1 _database_code_depnum_ccdc_archive 'CCDC 743965' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety 'C24 H38 Au2 Cl2 N4, C H Cl3' _chemical_formula_sum 'C25 H39 Au2 Cl5 N4' _chemical_formula_weight 966.79 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting monoclinic _symmetry_space_group_name_H-M 'P 21/n' _symmetry_space_group_name_Hall '-P 2yn' loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y-1/2, z-1/2' _cell_length_a 13.8358(12) _cell_length_b 14.9350(13) _cell_length_c 16.0256(14) _cell_angle_alpha 90.00 _cell_angle_beta 104.0690(10) _cell_angle_gamma 90.00 _cell_volume 3212.2(5) _cell_formula_units_Z 4 _cell_measurement_temperature 153(2) _cell_measurement_reflns_used 900 _cell_measurement_theta_min 1 _cell_measurement_theta_max 22.5 _exptl_crystal_description block _exptl_crystal_colour colourless _exptl_crystal_size_max 0.13 _exptl_crystal_size_mid 0.10 _exptl_crystal_size_min 0.09 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.999 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 1840 _exptl_absorpt_coefficient_mu 9.561 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_correction_T_min 0.3695 _exptl_absorpt_correction_T_max 0.4799 _exptl_absorpt_process_details ; Corrections were done with the SADABS program, utilizing the none merged raw data obtained from the integration process. Integration and final cell refinement were done with SAINT. SADABS reports ratio of Tmin/Tmax = 0.564011 ; _exptl_special_details ; ? ; _diffrn_ambient_temperature 153(1) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'rotating anode' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'CCD area detector' _diffrn_measurement_method 'Omega and Phi scans' _diffrn_detector_area_resol_mean 80 _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 36327 _diffrn_reflns_av_R_equivalents 0.0387 _diffrn_reflns_av_sigmaI/netI 0.0344 _diffrn_reflns_limit_h_min -19 _diffrn_reflns_limit_h_max 19 _diffrn_reflns_limit_k_min -20 _diffrn_reflns_limit_k_max 20 _diffrn_reflns_limit_l_min -22 _diffrn_reflns_limit_l_max 22 _diffrn_reflns_theta_min 1.75 _diffrn_reflns_theta_max 29.57 _reflns_number_total 9013 _reflns_number_gt 6660 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'APEX2(Bruker AXS, 2007)' _computing_cell_refinement 'APEX2(Bruker AXS, 2007)' _computing_data_reduction 'SAINT,SADABS (Bruker AXS, 2007 )' _computing_structure_solution ; SHELXS-97 , G. M. Sheldrick, Acta Cryst. (2008) A64, 112-122 ; _computing_structure_refinement ; SHELXL-97, G. M. Sheldrick, Acta Cryst. (2008) A64, 112-122 ; _computing_molecular_graphics ; ORTEP3,L.J. Farrugia, J. Appl. Cryst. (1997) 30, 565 ; _computing_publication_material ? _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0488P)^2^+17.8641P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment noref _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 9013 _refine_ls_number_parameters 329 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.0563 _refine_ls_R_factor_gt 0.0385 _refine_ls_wR_factor_ref 0.1080 _refine_ls_wR_factor_gt 0.0996 _refine_ls_goodness_of_fit_ref 1.031 _refine_ls_restrained_S_all 1.031 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Au1 Au 0.710177(17) 0.365345(15) 0.109212(14) 0.02494(7) Uani 1 1 d . . . Au2 Au 0.249532(17) 0.635495(16) -0.459570(14) 0.02576(7) Uani 1 1 d . . . Cl1 Cl 0.14106(11) 0.69182(9) -0.58153(9) 0.0257(3) Uani 1 1 d . . . Cl2 Cl 0.81383(11) 0.30644(9) 0.23266(9) 0.0249(3) Uani 1 1 d . . . N2 N 0.6256(4) 0.5022(3) -0.0253(3) 0.0220(9) Uani 1 1 d . . . N3 N 0.3409(4) 0.4985(3) -0.3283(3) 0.0248(10) Uani 1 1 d . . . N4 N 0.4127(4) 0.6284(3) -0.2970(3) 0.0239(10) Uani 1 1 d . . . N1 N 0.5517(4) 0.3731(3) -0.0552(3) 0.0221(9) Uani 1 1 d . . . C8 C 0.3406(4) 0.5846(4) -0.3563(4) 0.0256(12) Uani 1 1 d . . . C5 C 0.4585(4) 0.5715(4) -0.2305(4) 0.0229(11) Uani 1 1 d . . . C1 C 0.6231(4) 0.4167(4) 0.0034(4) 0.0239(11) Uani 1 1 d . . . C7 C 0.4351(4) 0.4126(4) -0.1975(4) 0.0233(11) Uani 1 1 d . . . H7 H 0.4040 0.3559 -0.2109 0.028 Uiso 1 1 calc R . . C3 C 0.5563(4) 0.5127(4) -0.1039(4) 0.0214(11) Uani 1 1 d . . . C4 C 0.5330(4) 0.5874(4) -0.1569(4) 0.0231(11) Uani 1 1 d . . . H4 H 0.5650 0.6437 -0.1440 0.028 Uiso 1 1 calc R . . C2 C 0.5089(4) 0.4290(4) -0.1232(4) 0.0213(11) Uani 1 1 d . . . C6 C 0.4113(4) 0.4873(4) -0.2504(4) 0.0230(11) Uani 1 1 d . . . C21 C 0.4394(5) 0.7232(4) -0.2992(4) 0.0310(13) Uani 1 1 d . . . H21A H 0.4471 0.7490 -0.2411 0.037 Uiso 1 1 calc R . . H21B H 0.3843 0.7553 -0.3389 0.037 Uiso 1 1 calc R . . C9 C 0.5278(5) 0.2776(4) -0.0510(4) 0.0261(12) Uani 1 1 d . . . H9A H 0.4585 0.2669 -0.0841 0.031 Uiso 1 1 calc R . . H9B H 0.5326 0.2606 0.0096 0.031 Uiso 1 1 calc R . . C13 C 0.6939(4) 0.5721(4) 0.0154(4) 0.0262(12) Uani 1 1 d . . . H13A H 0.7206 0.5571 0.0769 0.031 Uiso 1 1 calc R . . H13B H 0.6571 0.6293 0.0124 0.031 Uiso 1 1 calc R . . C17 C 0.2706(5) 0.4293(4) -0.3710(4) 0.0298(13) Uani 1 1 d . . . H17A H 0.2985 0.3694 -0.3527 0.036 Uiso 1 1 calc R . . H17B H 0.2616 0.4339 -0.4341 0.036 Uiso 1 1 calc R . . C10 C 0.5995(5) 0.2193(4) -0.0876(5) 0.0352(15) Uani 1 1 d . . . H10A H 0.6008 0.2417 -0.1455 0.042 Uiso 1 1 calc R . . H10B H 0.6676 0.2252 -0.0502 0.042 Uiso 1 1 calc R . . C18 C 0.1702(5) 0.4388(5) -0.3496(4) 0.0382(16) Uani 1 1 d . . . H18A H 0.1413 0.4977 -0.3705 0.046 Uiso 1 1 calc R . . H18B H 0.1249 0.3919 -0.3806 0.046 Uiso 1 1 calc R . . C11 C 0.5705(6) 0.1219(5) -0.0942(5) 0.0429(18) Uani 1 1 d . . . H11A H 0.5028 0.1158 -0.1324 0.051 Uiso 1 1 calc R . . H11B H 0.5682 0.0996 -0.0365 0.051 Uiso 1 1 calc R . . C20 C 0.0746(6) 0.4498(5) -0.2341(5) 0.0426(17) Uani 1 1 d . . . H20A H 0.0576 0.5132 -0.2440 0.064 Uiso 1 1 calc R . . H20B H 0.0788 0.4349 -0.1738 0.064 Uiso 1 1 calc R . . H20C H 0.0230 0.4129 -0.2713 0.064 Uiso 1 1 calc R . . C19 C 0.1753(5) 0.4314(5) -0.2547(4) 0.0352(15) Uani 1 1 d . . . H19A H 0.2251 0.4745 -0.2229 0.042 Uiso 1 1 calc R . . H19B H 0.1979 0.3704 -0.2348 0.042 Uiso 1 1 calc R . . C22 C 0.5344(5) 0.7383(5) -0.3277(5) 0.0385(16) Uani 1 1 d . . . H22A H 0.5570 0.8006 -0.3138 0.046 Uiso 1 1 calc R . . H22B H 0.5866 0.6979 -0.2946 0.046 Uiso 1 1 calc R . . C23 C 0.5241(6) 0.7225(6) -0.4217(5) 0.0473(19) Uani 1 1 d . . . H23A H 0.4718 0.7628 -0.4550 0.057 Uiso 1 1 calc R . . H23B H 0.5020 0.6601 -0.4357 0.057 Uiso 1 1 calc R . . Cl5 Cl 0.5735(2) 0.4654(2) 0.6017(2) 0.0817(8) Uani 1 1 d . . . Cl4 Cl 0.7067(2) 0.4124(3) 0.76121(19) 0.0976(11) Uani 1 1 d . . . Cl3 Cl 0.5649(3) 0.2872(2) 0.66425(19) 0.0979(11) Uani 1 1 d . . . C12 C 0.6421(7) 0.0648(5) -0.1289(6) 0.057(2) Uani 1 1 d . . . H12A H 0.6359 0.0794 -0.1896 0.085 Uiso 1 1 calc R . . H12B H 0.6263 0.0014 -0.1236 0.085 Uiso 1 1 calc R . . H12C H 0.7104 0.0766 -0.0960 0.085 Uiso 1 1 calc R . . C24 C 0.6206(7) 0.7385(8) -0.4495(7) 0.068(3) Uani 1 1 d . . . H24A H 0.6460 0.7985 -0.4316 0.102 Uiso 1 1 calc R . . H24B H 0.6077 0.7335 -0.5122 0.102 Uiso 1 1 calc R . . H24C H 0.6702 0.6937 -0.4226 0.102 Uiso 1 1 calc R . . C25 C 0.6452(8) 0.3772(8) 0.6582(6) 0.071(3) Uani 1 1 d . . . H25 H 0.6954 0.3576 0.6264 0.085 Uiso 1 1 calc R . . C14 C 0.7805(7) 0.5842(7) -0.0270(8) 0.075(3) Uani 1 1 d . . . H14A H 0.7533 0.6098 -0.0849 0.089 Uiso 1 1 calc R . . H14B H 0.8261 0.6295 0.0066 0.089 Uiso 1 1 calc R . . C15 C 0.8375(8) 0.5094(8) -0.0364(8) 0.075(3) Uani 1 1 d . . . H15A H 0.7937 0.4599 -0.0640 0.090 Uiso 1 1 calc R . . H15B H 0.8765 0.4888 0.0206 0.090 Uiso 1 1 calc R . . C16 C 0.9122(7) 0.5388(10) -0.0961(7) 0.095(5) Uani 1 1 d . . . H16A H 0.8756 0.5755 -0.1442 0.143 Uiso 1 1 calc R . . H16B H 0.9379 0.4851 -0.1184 0.143 Uiso 1 1 calc R . . H16C H 0.9678 0.5735 -0.0615 0.143 Uiso 1 1 calc R . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Au1 0.02667(12) 0.02262(12) 0.02353(12) 0.00043(8) 0.00225(9) 0.00217(9) Au2 0.02878(13) 0.02487(12) 0.02315(12) 0.00281(8) 0.00536(9) 0.00276(9) Cl1 0.0311(7) 0.0214(6) 0.0217(6) 0.0047(5) 0.0005(5) 0.0092(5) Cl2 0.0305(7) 0.0164(6) 0.0206(6) 0.0048(5) -0.0077(5) 0.0052(5) N2 0.023(2) 0.021(2) 0.022(2) -0.0015(18) 0.0047(19) 0.0008(18) N3 0.031(3) 0.021(2) 0.022(2) -0.0027(19) 0.005(2) -0.002(2) N4 0.026(2) 0.019(2) 0.025(2) 0.0023(19) 0.004(2) 0.0047(19) N1 0.025(2) 0.019(2) 0.023(2) 0.0029(18) 0.0065(19) -0.0028(18) C8 0.026(3) 0.027(3) 0.025(3) 0.001(2) 0.009(2) 0.000(2) C5 0.026(3) 0.018(3) 0.026(3) -0.001(2) 0.009(2) 0.001(2) C1 0.023(3) 0.026(3) 0.024(3) 0.000(2) 0.007(2) 0.004(2) C7 0.026(3) 0.020(3) 0.024(3) -0.003(2) 0.007(2) -0.002(2) C3 0.019(3) 0.021(3) 0.024(3) -0.003(2) 0.006(2) 0.001(2) C4 0.026(3) 0.020(3) 0.025(3) 0.000(2) 0.007(2) -0.002(2) C2 0.021(3) 0.019(3) 0.023(3) 0.002(2) 0.004(2) 0.002(2) C6 0.024(3) 0.022(3) 0.023(3) 0.000(2) 0.005(2) 0.000(2) C21 0.036(3) 0.020(3) 0.036(3) 0.002(3) 0.007(3) 0.004(2) C9 0.027(3) 0.021(3) 0.029(3) 0.003(2) 0.005(2) -0.006(2) C13 0.025(3) 0.024(3) 0.027(3) 0.000(2) 0.001(2) -0.001(2) C17 0.036(3) 0.027(3) 0.025(3) -0.004(2) 0.005(3) -0.002(3) C10 0.042(4) 0.027(3) 0.037(4) -0.001(3) 0.011(3) 0.001(3) C18 0.033(4) 0.039(4) 0.035(4) 0.003(3) -0.006(3) -0.011(3) C11 0.050(4) 0.026(3) 0.043(4) 0.002(3) -0.007(3) 0.003(3) C20 0.038(4) 0.038(4) 0.056(5) 0.000(3) 0.018(3) 0.002(3) C19 0.033(3) 0.033(3) 0.037(4) 0.002(3) 0.004(3) -0.003(3) C22 0.037(4) 0.034(4) 0.044(4) 0.005(3) 0.009(3) -0.003(3) C23 0.038(4) 0.058(5) 0.049(5) 0.002(4) 0.017(4) -0.001(4) Cl5 0.0854(19) 0.086(2) 0.0796(18) 0.0100(15) 0.0315(15) 0.0221(16) Cl4 0.0721(18) 0.163(3) 0.0581(15) -0.0214(19) 0.0160(13) -0.021(2) Cl3 0.157(3) 0.079(2) 0.0544(15) -0.0105(14) 0.0203(18) -0.013(2) C12 0.070(6) 0.034(4) 0.056(5) -0.011(4) -0.005(4) 0.014(4) C24 0.058(6) 0.082(7) 0.071(7) 0.000(5) 0.030(5) -0.006(5) C25 0.080(7) 0.100(9) 0.039(5) -0.003(5) 0.026(5) 0.024(6) C14 0.047(5) 0.062(6) 0.128(9) -0.054(6) 0.047(6) -0.026(4) C15 0.063(6) 0.077(8) 0.086(8) -0.009(6) 0.021(6) 0.000(6) C16 0.044(5) 0.177(14) 0.077(7) -0.053(8) 0.037(5) -0.024(7) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Au1 C1 1.980(6) . ? Au1 Cl2 2.3163(12) . ? Au2 C8 1.972(6) . ? Au2 Cl1 2.3138(13) . ? N2 C1 1.360(7) . ? N2 C3 1.394(7) . ? N2 C13 1.453(7) . ? N3 C8 1.361(8) . ? N3 C6 1.395(7) . ? N3 C17 1.469(8) . ? N4 C8 1.366(8) . ? N4 C5 1.390(7) . ? N4 C21 1.465(8) . ? N1 C1 1.353(7) . ? N1 C2 1.386(7) . ? N1 C9 1.468(7) . ? C5 C4 1.385(8) . ? C5 C6 1.417(8) . ? C7 C2 1.389(8) . ? C7 C6 1.392(8) . ? C7 H7 0.9500 . ? C3 C4 1.391(8) . ? C3 C2 1.412(8) . ? C4 H4 0.9500 . ? C21 C22 1.510(10) . ? C21 H21A 0.9900 . ? C21 H21B 0.9900 . ? C9 C10 1.539(9) . ? C9 H9A 0.9900 . ? C9 H9B 0.9900 . ? C13 C14 1.525(10) . ? C13 H13A 0.9900 . ? C13 H13B 0.9900 . ? C17 C18 1.516(10) . ? C17 H17A 0.9900 . ? C17 H17B 0.9900 . ? C10 C11 1.506(9) . ? C10 H10A 0.9900 . ? C10 H10B 0.9900 . ? C18 C19 1.508(10) . ? C18 H18A 0.9900 . ? C18 H18B 0.9900 . ? C11 C12 1.512(12) . ? C11 H11A 0.9900 . ? C11 H11B 0.9900 . ? C20 C19 1.533(10) . ? C20 H20A 0.9800 . ? C20 H20B 0.9800 . ? C20 H20C 0.9800 . ? C19 H19A 0.9900 . ? C19 H19B 0.9900 . ? C22 C23 1.497(11) . ? C22 H22A 0.9900 . ? C22 H22B 0.9900 . ? C23 C24 1.526(11) . ? C23 H23A 0.9900 . ? C23 H23B 0.9900 . ? Cl5 C25 1.762(11) . ? Cl4 C25 1.744(10) . ? Cl3 C25 1.761(12) . ? C12 H12A 0.9800 . ? C12 H12B 0.9800 . ? C12 H12C 0.9800 . ? C24 H24A 0.9800 . ? C24 H24B 0.9800 . ? C24 H24C 0.9800 . ? C25 H25 1.0000 . ? C14 C15 1.396(14) . ? C14 H14A 0.9900 . ? C14 H14B 0.9900 . ? C15 C16 1.629(14) . ? C15 H15A 0.9900 . ? C15 H15B 0.9900 . ? C16 H16A 0.9800 . ? C16 H16B 0.9800 . ? C16 H16C 0.9800 . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C1 Au1 Cl2 179.22(18) . . ? C8 Au2 Cl1 178.62(19) . . ? C1 N2 C3 110.1(5) . . ? C1 N2 C13 126.2(5) . . ? C3 N2 C13 123.6(5) . . ? C8 N3 C6 110.7(5) . . ? C8 N3 C17 124.2(5) . . ? C6 N3 C17 124.9(5) . . ? C8 N4 C5 111.1(5) . . ? C8 N4 C21 126.3(5) . . ? C5 N4 C21 122.6(5) . . ? C1 N1 C2 110.9(5) . . ? C1 N1 C9 124.7(5) . . ? C2 N1 C9 124.3(5) . . ? N3 C8 N4 106.3(5) . . ? N3 C8 Au2 126.2(4) . . ? N4 C8 Au2 127.5(4) . . ? C4 C5 N4 130.9(5) . . ? C4 C5 C6 123.3(5) . . ? N4 C5 C6 105.8(5) . . ? N1 C1 N2 106.9(5) . . ? N1 C1 Au1 126.7(4) . . ? N2 C1 Au1 126.4(4) . . ? C2 C7 C6 113.4(5) . . ? C2 C7 H7 123.3 . . ? C6 C7 H7 123.3 . . ? C4 C3 N2 130.5(5) . . ? C4 C3 C2 123.3(5) . . ? N2 C3 C2 106.1(5) . . ? C5 C4 C3 113.4(5) . . ? C5 C4 H4 123.3 . . ? C3 C4 H4 123.3 . . ? N1 C2 C7 130.7(5) . . ? N1 C2 C3 105.9(5) . . ? C7 C2 C3 123.3(5) . . ? C7 C6 N3 130.7(5) . . ? C7 C6 C5 123.2(5) . . ? N3 C6 C5 106.1(5) . . ? N4 C21 C22 113.3(5) . . ? N4 C21 H21A 108.9 . . ? C22 C21 H21A 108.9 . . ? N4 C21 H21B 108.9 . . ? C22 C21 H21B 108.9 . . ? H21A C21 H21B 107.7 . . ? N1 C9 C10 111.0(5) . . ? N1 C9 H9A 109.4 . . ? C10 C9 H9A 109.4 . . ? N1 C9 H9B 109.4 . . ? C10 C9 H9B 109.4 . . ? H9A C9 H9B 108.0 . . ? N2 C13 C14 112.4(5) . . ? N2 C13 H13A 109.1 . . ? C14 C13 H13A 109.1 . . ? N2 C13 H13B 109.1 . . ? C14 C13 H13B 109.1 . . ? H13A C13 H13B 107.9 . . ? N3 C17 C18 111.6(5) . . ? N3 C17 H17A 109.3 . . ? C18 C17 H17A 109.3 . . ? N3 C17 H17B 109.3 . . ? C18 C17 H17B 109.3 . . ? H17A C17 H17B 108.0 . . ? C11 C10 C9 112.8(6) . . ? C11 C10 H10A 109.0 . . ? C9 C10 H10A 109.0 . . ? C11 C10 H10B 109.0 . . ? C9 C10 H10B 109.0 . . ? H10A C10 H10B 107.8 . . ? C19 C18 C17 113.6(5) . . ? C19 C18 H18A 108.8 . . ? C17 C18 H18A 108.8 . . ? C19 C18 H18B 108.8 . . ? C17 C18 H18B 108.8 . . ? H18A C18 H18B 107.7 . . ? C10 C11 C12 112.5(7) . . ? C10 C11 H11A 109.1 . . ? C12 C11 H11A 109.1 . . ? C10 C11 H11B 109.1 . . ? C12 C11 H11B 109.1 . . ? H11A C11 H11B 107.8 . . ? C19 C20 H20A 109.5 . . ? C19 C20 H20B 109.5 . . ? H20A C20 H20B 109.5 . . ? C19 C20 H20C 109.5 . . ? H20A C20 H20C 109.5 . . ? H20B C20 H20C 109.5 . . ? C18 C19 C20 112.4(6) . . ? C18 C19 H19A 109.1 . . ? C20 C19 H19A 109.1 . . ? C18 C19 H19B 109.1 . . ? C20 C19 H19B 109.1 . . ? H19A C19 H19B 107.8 . . ? C23 C22 C21 113.8(6) . . ? C23 C22 H22A 108.8 . . ? C21 C22 H22A 108.8 . . ? C23 C22 H22B 108.8 . . ? C21 C22 H22B 108.8 . . ? H22A C22 H22B 107.7 . . ? C22 C23 C24 113.1(7) . . ? C22 C23 H23A 109.0 . . ? C24 C23 H23A 109.0 . . ? C22 C23 H23B 109.0 . . ? C24 C23 H23B 109.0 . . ? H23A C23 H23B 107.8 . . ? C11 C12 H12A 109.5 . . ? C11 C12 H12B 109.5 . . ? H12A C12 H12B 109.5 . . ? C11 C12 H12C 109.5 . . ? H12A C12 H12C 109.5 . . ? H12B C12 H12C 109.5 . . ? C23 C24 H24A 109.5 . . ? C23 C24 H24B 109.5 . . ? H24A C24 H24B 109.5 . . ? C23 C24 H24C 109.5 . . ? H24A C24 H24C 109.5 . . ? H24B C24 H24C 109.5 . . ? Cl4 C25 Cl3 110.3(5) . . ? Cl4 C25 Cl5 110.2(6) . . ? Cl3 C25 Cl5 108.4(6) . . ? Cl4 C25 H25 109.3 . . ? Cl3 C25 H25 109.3 . . ? Cl5 C25 H25 109.3 . . ? C15 C14 C13 118.6(9) . . ? C15 C14 H14A 107.7 . . ? C13 C14 H14A 107.7 . . ? C15 C14 H14B 107.7 . . ? C13 C14 H14B 107.7 . . ? H14A C14 H14B 107.1 . . ? C14 C15 C16 107.7(10) . . ? C14 C15 H15A 110.2 . . ? C16 C15 H15A 110.2 . . ? C14 C15 H15B 110.2 . . ? C16 C15 H15B 110.2 . . ? H15A C15 H15B 108.5 . . ? C15 C16 H16A 109.5 . . ? C15 C16 H16B 109.5 . . ? H16A C16 H16B 109.5 . . ? C15 C16 H16C 109.5 . . ? H16A C16 H16C 109.5 . . ? H16B C16 H16C 109.5 . . ? _diffrn_measured_fraction_theta_max 1.000 _diffrn_reflns_theta_full 25.00 _diffrn_measured_fraction_theta_full 1.000 _refine_diff_density_max 3.584 _refine_diff_density_min -1.477 _refine_diff_density_rms 0.189 # Attachment '[2]_BF4_4.cif' data_2 _database_code_depnum_ccdc_archive 'CCDC 743966' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety 'C100 H124 Au4 N8 P4, 4(B F4)' _chemical_formula_sum 'C100 H124 Au4 B4 F16 N8 P4' _chemical_formula_weight 2697.06 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting triclinic _symmetry_space_group_name_H-M 'P -1' _symmetry_space_group_name_Hall '-P 1' loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' _cell_length_a 11.9916(6) _cell_length_b 12.7206(6) _cell_length_c 19.6897(9) _cell_angle_alpha 96.2600(7) _cell_angle_beta 94.4715(8) _cell_angle_gamma 117.7115(7) _cell_volume 2614.7(2) _cell_formula_units_Z 1 _cell_measurement_temperature 153(2) _cell_measurement_reflns_used 900 _cell_measurement_theta_min 1 _cell_measurement_theta_max 22.5 _exptl_crystal_description plate _exptl_crystal_colour colourless _exptl_crystal_size_max 0.25 _exptl_crystal_size_mid 0.08 _exptl_crystal_size_min 0.01 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.713 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 1320 _exptl_absorpt_coefficient_mu 5.732 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_correction_T_min 0.3283 _exptl_absorpt_correction_T_max 0.9449 _exptl_absorpt_process_details ; Corrections were done with the SADABS program, utilizing the none merged raw data obtained from the integration process. Integration and final cell refinement were done with SAINT. SADABS reports ratio of Tmin/Tmax = 0.272964 ; _exptl_special_details ; ? ; _diffrn_ambient_temperature 153(1) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'rotating anode' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'CCD area detector' _diffrn_measurement_method 'Omega and Phi scans' _diffrn_detector_area_resol_mean 80 _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 29898 _diffrn_reflns_av_R_equivalents 0.0298 _diffrn_reflns_av_sigmaI/netI 0.0462 _diffrn_reflns_limit_h_min -16 _diffrn_reflns_limit_h_max 16 _diffrn_reflns_limit_k_min -17 _diffrn_reflns_limit_k_max 17 _diffrn_reflns_limit_l_min -26 _diffrn_reflns_limit_l_max 27 _diffrn_reflns_theta_min 1.05 _diffrn_reflns_theta_max 29.57 _reflns_number_total 14572 _reflns_number_gt 11690 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'APEX2(Bruker AXS, 2007)' _computing_cell_refinement 'APEX2(Bruker AXS, 2007)' _computing_data_reduction 'SAINT,SADABS (Bruker AXS, 2007 )' _computing_structure_solution ; SHELXS-97 , G. M. Sheldrick, Acta Cryst. (2008) A64, 112-122 ; _computing_structure_refinement ; SHELXL-97, G. M. Sheldrick, Acta Cryst. (2008) A64, 112-122 ; _computing_molecular_graphics ; ORTEP3,L.J. Farrugia, J. Appl. Cryst. (1997) 30, 565 ; _computing_publication_material ? _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0352P)^2^+0.0122P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment noref _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 14572 _refine_ls_number_parameters 673 _refine_ls_number_restraints 6 _refine_ls_R_factor_all 0.0435 _refine_ls_R_factor_gt 0.0305 _refine_ls_wR_factor_ref 0.0754 _refine_ls_wR_factor_gt 0.0709 _refine_ls_goodness_of_fit_ref 1.039 _refine_ls_restrained_S_all 1.040 _refine_ls_shift/su_max 0.002 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group C1 C 0.7357(3) 0.0678(3) 0.35901(18) 0.0222(7) Uani 1 1 d . . . C2 C 0.7285(3) 0.0750(3) 0.47320(18) 0.0206(7) Uani 1 1 d . . . C3 C 0.7486(3) 0.1102(3) 0.54410(18) 0.0219(7) Uani 1 1 d . . . H3 H 0.8141 0.1865 0.5670 0.026 Uiso 1 1 calc R . . C4 C 0.3358(3) -0.0240(3) 0.42132(17) 0.0206(7) Uani 1 1 d . . . C5 C 0.5655(3) -0.0886(3) 0.54423(17) 0.0195(7) Uani 1 1 d . . . C6 C 0.5452(3) -0.1245(3) 0.47304(18) 0.0207(7) Uani 1 1 d . . . H6 H 0.4793 -0.2005 0.4500 0.025 Uiso 1 1 calc R . . C7 C 0.6310(3) -0.0382(3) 0.43911(17) 0.0204(7) Uani 1 1 d . . . C8 C 0.4500(3) 0.0765(3) 0.34260(17) 0.0213(7) Uani 1 1 d . . . C9 C 0.5578(3) -0.1416(3) 0.31405(18) 0.0241(7) Uani 1 1 d . . . H9A H 0.5452 -0.1113 0.2714 0.029 Uiso 1 1 calc R . . H9B H 0.4733 -0.1883 0.3283 0.029 Uiso 1 1 calc R . . C10 C 0.6147(4) -0.2228(3) 0.2989(2) 0.0342(9) Uani 1 1 d . . . H10A H 0.6236 -0.2559 0.3410 0.041 Uiso 1 1 calc R . . H10B H 0.7009 -0.1751 0.2868 0.041 Uiso 1 1 calc R . . C11 C 0.5350(4) -0.3264(4) 0.2400(3) 0.0460(12) Uani 1 1 d . . . H11A H 0.5224 -0.2938 0.1984 0.055 Uiso 1 1 calc R . . H11B H 0.4503 -0.3771 0.2530 0.055 Uiso 1 1 calc R . . C12 C 0.5993(6) -0.4040(5) 0.2233(4) 0.078(2) Uani 1 1 d . . . H12A H 0.6827 -0.3542 0.2098 0.117 Uiso 1 1 calc R . . H12B H 0.5459 -0.4696 0.1853 0.117 Uiso 1 1 calc R . . H12C H 0.6105 -0.4376 0.2642 0.117 Uiso 1 1 calc R . . C13 C 0.9039(3) 0.2558(3) 0.4346(2) 0.0276(8) Uani 1 1 d D . . H13A H 0.8816 0.3133 0.4599 0.033 Uiso 1 1 calc R A 1 H13B H 0.9257 0.2816 0.3896 0.033 Uiso 1 1 calc R A 1 C14A C 1.0202(5) 0.2635(6) 0.4750(3) 0.0281(15) Uani 0.634(9) 1 d PD B 1 H14A H 1.0018 0.2450 0.5218 0.034 Uiso 0.634(9) 1 calc PR B 1 H14B H 1.0911 0.3467 0.4804 0.034 Uiso 0.634(9) 1 calc PR B 1 C15A C 1.0609(8) 0.1775(9) 0.4405(5) 0.060(3) Uani 0.634(9) 1 d PD B 1 H15A H 1.0816 0.1979 0.3944 0.072 Uiso 0.634(9) 1 calc PR B 1 H15B H 0.9885 0.0948 0.4335 0.072 Uiso 0.634(9) 1 calc PR B 1 C16A C 1.1746(16) 0.180(2) 0.4809(7) 0.069(5) Uani 0.634(9) 1 d PD B 1 H16A H 1.2405 0.2632 0.4966 0.104 Uiso 0.634(9) 1 calc PR B 1 H16B H 1.2084 0.1376 0.4512 0.104 Uiso 0.634(9) 1 calc PR B 1 H16C H 1.1485 0.1392 0.5209 0.104 Uiso 0.634(9) 1 calc PR B 1 C14B C 1.0223(9) 0.2392(12) 0.4357(6) 0.039(3) Uani 0.366(9) 1 d PD B 2 H14C H 1.0122 0.1863 0.3923 0.047 Uiso 0.366(9) 1 calc PR B 2 H14D H 1.0961 0.3187 0.4349 0.047 Uiso 0.366(9) 1 calc PR B 2 C15B C 1.0550(11) 0.1883(13) 0.4945(7) 0.051(4) Uani 0.366(9) 1 d PD B 2 H15C H 0.9874 0.1036 0.4900 0.061 Uiso 0.366(9) 1 calc PR B 2 H15D H 1.0484 0.2320 0.5375 0.061 Uiso 0.366(9) 1 calc PR B 2 C16B C 1.181(2) 0.188(3) 0.5056(14) 0.055(6) Uani 0.366(9) 1 d PD B 2 H16D H 1.1740 0.1159 0.4781 0.082 Uiso 0.366(9) 1 calc PR B 2 H16E H 1.2030 0.1885 0.5546 0.082 Uiso 0.366(9) 1 calc PR B 2 H16F H 1.2469 0.2600 0.4914 0.082 Uiso 0.366(9) 1 calc PR B 2 C17 C 0.2562(3) -0.1193(3) 0.29510(18) 0.0238(7) Uani 1 1 d . . . H17A H 0.1987 -0.1908 0.3144 0.029 Uiso 1 1 calc R . . H17B H 0.3020 -0.1442 0.2627 0.029 Uiso 1 1 calc R . . C18 C 0.1771(4) -0.0732(4) 0.2557(2) 0.0393(10) Uani 1 1 d . . . H18A H 0.2349 -0.0086 0.2319 0.047 Uiso 1 1 calc R . . H18B H 0.1149 -0.1399 0.2196 0.047 Uiso 1 1 calc R . . C19 C 0.1057(5) -0.0254(6) 0.2966(3) 0.0680(18) Uani 1 1 d . . . H19A H 0.1655 0.0352 0.3361 0.082 Uiso 1 1 calc R . . H19B H 0.0744 0.0165 0.2671 0.082 Uiso 1 1 calc R . . C20 C -0.0035(6) -0.1169(7) 0.3235(3) 0.080(2) Uani 1 1 d . . . H20A H -0.0666 -0.1742 0.2848 0.120 Uiso 1 1 calc R . . H20B H -0.0423 -0.0775 0.3511 0.120 Uiso 1 1 calc R . . H20C H 0.0258 -0.1598 0.3524 0.120 Uiso 1 1 calc R . . C21 C 0.6054(3) 0.2716(3) 0.41825(19) 0.0260(8) Uani 1 1 d . . . H21A H 0.6558 0.2858 0.3795 0.031 Uiso 1 1 calc R . . H21B H 0.6625 0.2843 0.4609 0.031 Uiso 1 1 calc R . . C22 C 0.5547(4) 0.3616(4) 0.4260(2) 0.0435(11) Uani 1 1 d . . . H22A H 0.5076 0.3482 0.4661 0.052 Uiso 1 1 calc R . . H22B H 0.6284 0.4436 0.4370 0.052 Uiso 1 1 calc R . . C23 C 0.4704(6) 0.3578(5) 0.3658(3) 0.0592(14) Uani 1 1 d . . . H23A H 0.3953 0.2767 0.3549 0.071 Uiso 1 1 calc R . . H23B H 0.5166 0.3714 0.3254 0.071 Uiso 1 1 calc R . . C24 C 0.4250(7) 0.4516(6) 0.3778(4) 0.085(2) Uani 1 1 d . . . H24A H 0.3796 0.4391 0.4179 0.127 Uiso 1 1 calc R . . H24B H 0.3676 0.4433 0.3368 0.127 Uiso 1 1 calc R . . H24C H 0.4986 0.5325 0.3862 0.127 Uiso 1 1 calc R . . C25 C 0.6677(3) 0.0456(3) 0.09225(18) 0.0199(7) Uani 1 1 d . . . H25A H 0.6837 0.0180 0.0468 0.024 Uiso 1 1 calc R . . H25B H 0.6058 -0.0269 0.1091 0.024 Uiso 1 1 calc R . . C26 C 0.6040(3) 0.1235(3) 0.08037(17) 0.0207(7) Uani 1 1 d . . . H26A H 0.5205 0.0707 0.0514 0.025 Uiso 1 1 calc R . . H26B H 0.6563 0.1837 0.0525 0.025 Uiso 1 1 calc R . . C27 C 0.9259(3) 0.2530(3) 0.12860(18) 0.0198(7) Uani 1 1 d . . . C28 C 0.9239(3) 0.2701(3) 0.05982(19) 0.0251(7) Uani 1 1 d . . . H28 H 0.8625 0.2080 0.0249 0.030 Uiso 1 1 calc R . . C29 C 1.0121(4) 0.3784(3) 0.0425(2) 0.0324(9) Uani 1 1 d . . . H29 H 1.0103 0.3908 -0.0042 0.039 Uiso 1 1 calc R . . C30 C 1.1022(4) 0.4677(3) 0.0934(2) 0.0378(10) Uani 1 1 d . . . H30 H 1.1634 0.5410 0.0814 0.045 Uiso 1 1 calc R . . C31 C 1.1046(4) 0.4517(3) 0.1614(2) 0.0348(10) Uani 1 1 d . . . H31 H 1.1667 0.5139 0.1961 0.042 Uiso 1 1 calc R . . C32 C 1.0161(3) 0.3445(3) 0.1793(2) 0.0272(8) Uani 1 1 d . . . H32 H 1.0172 0.3338 0.2263 0.033 Uiso 1 1 calc R . . C33 C 0.8810(3) 0.0103(3) 0.12872(18) 0.0225(7) Uani 1 1 d . . . C34 C 0.9958(4) 0.0497(4) 0.1026(2) 0.0370(10) Uani 1 1 d . . . H34 H 1.0418 0.1308 0.0954 0.044 Uiso 1 1 calc R . . C35 C 1.0434(4) -0.0299(4) 0.0870(2) 0.0425(11) Uani 1 1 d . . . H35 H 1.1218 -0.0027 0.0691 0.051 Uiso 1 1 calc R . . C36 C 0.9788(4) -0.1458(4) 0.0970(2) 0.0350(9) Uani 1 1 d . . . H36 H 1.0118 -0.1996 0.0863 0.042 Uiso 1 1 calc R . . C37 C 0.8654(4) -0.1851(4) 0.1227(3) 0.0474(12) Uani 1 1 d . . . H37 H 0.8200 -0.2665 0.1294 0.057 Uiso 1 1 calc R . . C38 C 0.8165(4) -0.1078(4) 0.1388(3) 0.0435(11) Uani 1 1 d . . . H38 H 0.7383 -0.1361 0.1569 0.052 Uiso 1 1 calc R . . C39 C 0.7182(3) 0.3506(3) 0.17784(18) 0.0201(7) Uani 1 1 d . . . C40 C 0.7720(4) 0.4228(3) 0.1286(2) 0.0289(8) Uani 1 1 d . . . H40 H 0.7367 0.3956 0.0811 0.035 Uiso 1 1 calc R . . C41 C 0.8778(4) 0.5349(3) 0.1499(2) 0.0372(10) Uani 1 1 d . . . H41 H 0.9155 0.5842 0.1165 0.045 Uiso 1 1 calc R . . C42 C 0.9286(4) 0.5757(4) 0.2178(3) 0.0417(11) Uani 1 1 d . . . H42 H 1.0006 0.6531 0.2312 0.050 Uiso 1 1 calc R . . C43 C 0.8760(4) 0.5048(4) 0.2674(2) 0.0401(10) Uani 1 1 d . . . H43 H 0.9115 0.5332 0.3148 0.048 Uiso 1 1 calc R . . C44 C 0.7711(3) 0.3925(3) 0.2470(2) 0.0279(8) Uani 1 1 d . . . H44 H 0.7347 0.3433 0.2806 0.033 Uiso 1 1 calc R . . C45 C 0.4629(3) 0.2459(3) 0.1139(2) 0.0277(8) Uani 1 1 d . . . C46 C 0.4630(4) 0.2689(5) 0.0463(2) 0.0453(12) Uani 1 1 d . . . H46 H 0.5167 0.2543 0.0180 0.054 Uiso 1 1 calc R . . C47 C 0.3853(5) 0.3127(6) 0.0201(3) 0.0666(17) Uani 1 1 d . . . H47 H 0.3863 0.3291 -0.0259 0.080 Uiso 1 1 calc R . . C48 C 0.3064(5) 0.3326(6) 0.0607(3) 0.0630(16) Uani 1 1 d . . . H48 H 0.2532 0.3626 0.0426 0.076 Uiso 1 1 calc R . . C49 C 0.3038(4) 0.3097(5) 0.1265(3) 0.0523(13) Uani 1 1 d . . . H49 H 0.2485 0.3232 0.1540 0.063 Uiso 1 1 calc R . . C50 C 0.3828(4) 0.2661(4) 0.1539(2) 0.0378(10) Uani 1 1 d . . . H50 H 0.3812 0.2505 0.2000 0.045 Uiso 1 1 calc R . . B1 B 0.3116(4) 0.8173(4) 0.1054(2) 0.0270(9) Uani 1 1 d . . . B2 B 0.1836(5) 0.5709(4) 0.3849(3) 0.0401(12) Uani 1 1 d . . . N1 N 0.6388(3) -0.0381(3) 0.36909(15) 0.0209(6) Uani 1 1 d . . . N2 N 0.7910(3) 0.1356(3) 0.42155(14) 0.0206(6) Uani 1 1 d . B . N4 N 0.3496(3) -0.0257(3) 0.35196(15) 0.0220(6) Uani 1 1 d . . . N4A N 0.5016(3) 0.1469(2) 0.40518(14) 0.0202(6) Uani 1 1 d . . . F1 F 0.3268(2) 0.7398(2) 0.05513(12) 0.0399(6) Uani 1 1 d . . . F2 F 0.1963(2) 0.7546(2) 0.12860(13) 0.0394(6) Uani 1 1 d . . . F3 F 0.4109(2) 0.8607(2) 0.15962(13) 0.0447(6) Uani 1 1 d . . . F4 F 0.3141(2) 0.9126(2) 0.07660(13) 0.0427(6) Uani 1 1 d . . . F5A F 0.2932(7) 0.6542(6) 0.3708(5) 0.082(3) Uani 0.634(9) 1 d P B 1 F6A F 0.0985(15) 0.6083(16) 0.4013(9) 0.084(5) Uani 0.634(9) 1 d P B 1 F7A F 0.2553(15) 0.5745(12) 0.4398(7) 0.161(7) Uani 0.634(9) 1 d P B 1 F5B F 0.2400(16) 0.6377(11) 0.3321(7) 0.084(4) Uani 0.366(9) 1 d P B 2 F6B F 0.109(2) 0.626(2) 0.3802(15) 0.089(10) Uani 0.366(9) 1 d P B 2 F7B F 0.1898(15) 0.5531(14) 0.4520(7) 0.081(6) Uani 0.366(9) 1 d P B 2 F8 F 0.1252(3) 0.4595(2) 0.34582(15) 0.0554(8) Uani 1 1 d . B . P1A P 0.81690(8) 0.11183(8) 0.15179(5) 0.01866(17) Uani 1 1 d . . . P2A P 0.57572(8) 0.20501(8) 0.15359(5) 0.01914(17) Uani 1 1 d . . . Au1 Au 0.778444(12) 0.104464(12) 0.263429(6) 0.02081(4) Uani 1 1 d . . . Au2 Au 0.511936(12) 0.123923(11) 0.251021(7) 0.02134(4) Uani 1 1 d . . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 C1 0.0229(17) 0.0299(18) 0.0169(16) 0.0083(14) 0.0058(13) 0.0138(15) C2 0.0201(16) 0.0218(16) 0.0190(17) 0.0087(13) 0.0043(13) 0.0078(13) C3 0.0207(16) 0.0234(17) 0.0193(17) 0.0055(13) 0.0033(13) 0.0082(14) C4 0.0220(16) 0.0241(17) 0.0151(16) 0.0065(13) 0.0060(13) 0.0094(14) C5 0.0209(16) 0.0216(16) 0.0176(16) 0.0068(13) 0.0065(13) 0.0101(13) C6 0.0199(16) 0.0214(16) 0.0200(17) 0.0035(13) 0.0038(13) 0.0091(13) C7 0.0206(16) 0.0273(17) 0.0166(16) 0.0073(13) 0.0054(13) 0.0129(14) C8 0.0239(17) 0.0236(17) 0.0171(16) 0.0058(13) 0.0066(13) 0.0109(14) C9 0.0280(18) 0.0251(18) 0.0178(17) 0.0045(14) 0.0045(14) 0.0111(15) C10 0.034(2) 0.0256(19) 0.041(2) 0.0023(17) 0.0076(18) 0.0126(17) C11 0.045(3) 0.028(2) 0.056(3) -0.008(2) 0.009(2) 0.012(2) C12 0.079(4) 0.036(3) 0.113(6) -0.010(3) 0.038(4) 0.023(3) C13 0.0247(18) 0.0253(18) 0.029(2) 0.0111(15) 0.0088(15) 0.0069(15) C14A 0.023(3) 0.038(4) 0.017(3) 0.006(3) 0.005(2) 0.009(3) C15A 0.051(5) 0.090(7) 0.049(6) -0.010(5) -0.005(4) 0.047(5) C16A 0.057(7) 0.116(12) 0.056(10) 0.004(10) -0.002(6) 0.061(8) C14B 0.038(7) 0.037(7) 0.034(8) 0.013(6) 0.004(6) 0.009(5) C15B 0.028(6) 0.055(9) 0.069(11) 0.021(8) 0.006(6) 0.017(6) C16B 0.036(9) 0.063(12) 0.059(17) 0.002(13) -0.004(9) 0.022(9) C17 0.0265(18) 0.0213(17) 0.0197(17) 0.0029(13) 0.0059(14) 0.0080(14) C18 0.030(2) 0.037(2) 0.043(3) -0.0017(19) -0.0054(18) 0.0128(18) C19 0.058(3) 0.084(4) 0.065(4) -0.027(3) -0.010(3) 0.047(3) C20 0.061(4) 0.110(6) 0.067(4) -0.005(4) 0.023(3) 0.041(4) C21 0.0242(17) 0.0217(17) 0.0251(19) 0.0054(14) 0.0064(14) 0.0046(14) C22 0.049(3) 0.026(2) 0.047(3) 0.0081(19) 0.007(2) 0.011(2) C23 0.077(4) 0.050(3) 0.060(4) 0.016(3) 0.011(3) 0.037(3) C24 0.127(6) 0.083(5) 0.087(5) 0.024(4) 0.022(4) 0.082(5) C25 0.0194(15) 0.0179(15) 0.0213(17) 0.0033(13) 0.0072(13) 0.0075(13) C26 0.0196(16) 0.0254(17) 0.0164(16) 0.0041(13) 0.0043(13) 0.0096(14) C27 0.0204(16) 0.0206(16) 0.0220(17) 0.0059(13) 0.0085(13) 0.0115(13) C28 0.0276(18) 0.0274(18) 0.0267(19) 0.0103(15) 0.0124(15) 0.0159(15) C29 0.042(2) 0.030(2) 0.037(2) 0.0179(17) 0.0266(18) 0.0202(18) C30 0.037(2) 0.0207(18) 0.059(3) 0.0122(19) 0.027(2) 0.0119(17) C31 0.0221(18) 0.0199(18) 0.058(3) -0.0001(18) 0.0080(18) 0.0078(15) C32 0.0238(18) 0.0259(18) 0.032(2) 0.0026(15) 0.0066(15) 0.0119(15) C33 0.0258(17) 0.0230(17) 0.0224(18) 0.0062(14) 0.0056(14) 0.0139(14) C34 0.036(2) 0.036(2) 0.051(3) 0.017(2) 0.021(2) 0.0225(19) C35 0.049(3) 0.052(3) 0.046(3) 0.014(2) 0.021(2) 0.037(2) C36 0.050(3) 0.039(2) 0.030(2) 0.0011(17) 0.0024(18) 0.034(2) C37 0.051(3) 0.027(2) 0.072(4) 0.013(2) 0.015(2) 0.023(2) C38 0.039(2) 0.026(2) 0.073(3) 0.018(2) 0.024(2) 0.0180(19) C39 0.0195(16) 0.0196(16) 0.0237(18) 0.0039(13) 0.0080(13) 0.0107(13) C40 0.035(2) 0.0270(19) 0.032(2) 0.0115(16) 0.0140(16) 0.0179(17) C41 0.042(2) 0.0229(19) 0.051(3) 0.0134(18) 0.024(2) 0.0150(18) C42 0.028(2) 0.023(2) 0.064(3) -0.001(2) 0.013(2) 0.0050(17) C43 0.034(2) 0.037(2) 0.038(2) -0.0117(19) 0.0017(18) 0.0110(19) C44 0.0274(19) 0.0273(19) 0.026(2) -0.0001(15) 0.0031(15) 0.0114(16) C45 0.0205(17) 0.032(2) 0.030(2) 0.0018(16) 0.0038(15) 0.0128(15) C46 0.048(3) 0.079(4) 0.030(2) 0.014(2) 0.006(2) 0.046(3) C47 0.073(4) 0.113(5) 0.049(3) 0.018(3) 0.004(3) 0.073(4) C48 0.054(3) 0.091(4) 0.067(4) 0.007(3) -0.007(3) 0.057(3) C49 0.032(2) 0.055(3) 0.074(4) -0.002(3) 0.005(2) 0.028(2) C50 0.0251(19) 0.043(2) 0.046(3) 0.006(2) 0.0091(18) 0.0162(18) B1 0.028(2) 0.026(2) 0.025(2) 0.0086(17) 0.0064(17) 0.0101(17) B2 0.036(3) 0.030(2) 0.046(3) 0.004(2) -0.003(2) 0.011(2) N1 0.0230(14) 0.0220(14) 0.0170(14) 0.0063(11) 0.0057(11) 0.0091(12) N2 0.0206(14) 0.0244(14) 0.0154(14) 0.0083(11) 0.0077(11) 0.0079(12) N4 0.0242(15) 0.0218(14) 0.0176(15) 0.0056(11) 0.0074(12) 0.0078(12) N4A 0.0215(14) 0.0210(14) 0.0165(14) 0.0059(11) 0.0072(11) 0.0077(12) F1 0.0507(15) 0.0412(14) 0.0299(13) 0.0052(11) 0.0160(11) 0.0224(12) F2 0.0350(13) 0.0304(12) 0.0489(16) 0.0081(11) 0.0200(11) 0.0100(10) F3 0.0399(14) 0.0531(16) 0.0295(14) 0.0070(12) -0.0014(11) 0.0136(12) F4 0.0535(15) 0.0310(13) 0.0431(15) 0.0166(11) 0.0085(12) 0.0174(12) F5A 0.055(4) 0.053(4) 0.110(7) 0.011(5) 0.028(4) 0.001(3) F6A 0.046(5) 0.077(8) 0.103(9) -0.041(6) 0.011(6) 0.020(4) F7A 0.222(14) 0.122(10) 0.128(11) -0.080(7) -0.140(10) 0.119(10) F5B 0.114(12) 0.046(6) 0.073(9) 0.033(6) 0.033(7) 0.014(7) F6B 0.071(15) 0.039(7) 0.14(2) -0.034(10) -0.065(13) 0.032(9) F7B 0.114(12) 0.042(5) 0.025(5) 0.014(4) -0.011(7) -0.013(7) F8 0.0587(17) 0.0412(15) 0.0484(18) -0.0116(13) -0.0048(14) 0.0151(14) P1A 0.0206(4) 0.0196(4) 0.0173(4) 0.0060(3) 0.0067(3) 0.0097(3) P2A 0.0183(4) 0.0215(4) 0.0174(4) 0.0046(3) 0.0059(3) 0.0085(3) Au1 0.02381(7) 0.02447(7) 0.01616(7) 0.00765(5) 0.00727(5) 0.01163(6) Au2 0.02324(7) 0.02062(7) 0.01771(7) 0.00497(5) 0.00897(5) 0.00719(5) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag C1 N2 1.345(4) . ? C1 N1 1.358(4) . ? C1 Au1 2.035(3) . ? C2 C3 1.385(5) . ? C2 N2 1.394(4) . ? C2 C7 1.411(5) . ? C3 C4 1.388(5) 2_656 ? C3 H3 0.9500 . ? C4 N4 1.388(4) . ? C4 C3 1.388(5) 2_656 ? C4 C5 1.414(5) 2_656 ? C5 N4A 1.386(4) 2_656 ? C5 C6 1.392(5) . ? C5 C4 1.414(5) 2_656 ? C6 C7 1.388(5) . ? C6 H6 0.9500 . ? C7 N1 1.389(4) . ? C8 N4 1.343(4) . ? C8 N4A 1.352(4) . ? C8 Au2 2.049(3) . ? C9 N1 1.478(4) . ? C9 C10 1.498(5) . ? C9 H9A 0.9900 . ? C9 H9B 0.9900 . ? C10 C11 1.521(5) . ? C10 H10A 0.9900 . ? C10 H10B 0.9900 . ? C11 C12 1.534(7) . ? C11 H11A 0.9900 . ? C11 H11B 0.9900 . ? C12 H12A 0.9800 . ? C12 H12B 0.9800 . ? C12 H12C 0.9800 . ? C13 N2 1.474(4) . ? C13 C14A 1.507(5) . ? C13 C14B 1.528(6) . ? C13 H13A 0.9900 . ? C13 H13B 0.9900 . ? C14A C15A 1.511(6) . ? C14A H14A 0.9900 . ? C14A H14B 0.9900 . ? C15A C16A 1.512(6) . ? C15A H15A 0.9900 . ? C15A H15B 0.9900 . ? C16A H16A 0.9800 . ? C16A H16B 0.9800 . ? C16A H16C 0.9800 . ? C14B C15B 1.499(7) . ? C14B H14C 0.9900 . ? C14B H14D 0.9900 . ? C15B C16B 1.506(7) . ? C15B H15C 0.9900 . ? C15B H15D 0.9900 . ? C16B H16D 0.9800 . ? C16B H16E 0.9800 . ? C16B H16F 0.9800 . ? C17 N4 1.483(4) . ? C17 C18 1.532(5) . ? C17 H17A 0.9900 . ? C17 H17B 0.9900 . ? C18 C19 1.496(6) . ? C18 H18A 0.9900 . ? C18 H18B 0.9900 . ? C19 C20 1.474(8) . ? C19 H19A 0.9900 . ? C19 H19B 0.9900 . ? C20 H20A 0.9800 . ? C20 H20B 0.9800 . ? C20 H20C 0.9800 . ? C21 N4A 1.469(4) . ? C21 C22 1.524(6) . ? C21 H21A 0.9900 . ? C21 H21B 0.9900 . ? C22 C23 1.478(7) . ? C22 H22A 0.9900 . ? C22 H22B 0.9900 . ? C23 C24 1.529(7) . ? C23 H23A 0.9900 . ? C23 H23B 0.9900 . ? C24 H24A 0.9800 . ? C24 H24B 0.9800 . ? C24 H24C 0.9800 . ? C25 C26 1.532(5) . ? C25 P1A 1.828(3) . ? C25 H25A 0.9900 . ? C25 H25B 0.9900 . ? C26 P2A 1.829(3) . ? C26 H26A 0.9900 . ? C26 H26B 0.9900 . ? C27 C32 1.389(5) . ? C27 C28 1.395(5) . ? C27 P1A 1.798(3) . ? C28 C29 1.392(5) . ? C28 H28 0.9500 . ? C29 C30 1.380(6) . ? C29 H29 0.9500 . ? C30 C31 1.376(6) . ? C30 H30 0.9500 . ? C31 C32 1.387(5) . ? C31 H31 0.9500 . ? C32 H32 0.9500 . ? C33 C38 1.380(5) . ? C33 C34 1.392(5) . ? C33 P1A 1.820(3) . ? C34 C35 1.394(5) . ? C34 H34 0.9500 . ? C35 C36 1.356(6) . ? C35 H35 0.9500 . ? C36 C37 1.372(6) . ? C36 H36 0.9500 . ? C37 C38 1.382(6) . ? C37 H37 0.9500 . ? C38 H38 0.9500 . ? C39 C44 1.390(5) . ? C39 C40 1.394(5) . ? C39 P2A 1.820(3) . ? C40 C41 1.387(5) . ? C40 H40 0.9500 . ? C41 C42 1.362(6) . ? C41 H41 0.9500 . ? C42 C43 1.388(6) . ? C42 H42 0.9500 . ? C43 C44 1.382(5) . ? C43 H43 0.9500 . ? C44 H44 0.9500 . ? C45 C50 1.383(5) . ? C45 C46 1.394(6) . ? C45 P2A 1.814(4) . ? C46 C47 1.385(6) . ? C46 H46 0.9500 . ? C47 C48 1.377(7) . ? C47 H47 0.9500 . ? C48 C49 1.357(8) . ? C48 H48 0.9500 . ? C49 C50 1.403(6) . ? C49 H49 0.9500 . ? C50 H50 0.9500 . ? B1 F2 1.382(5) . ? B1 F4 1.383(5) . ? B1 F3 1.387(5) . ? B1 F1 1.402(5) . ? B2 F7A 1.309(11) . ? B2 F5A 1.324(8) . ? B2 F6A 1.357(14) . ? B2 F8 1.358(6) . ? B2 F7B 1.366(13) . ? B2 F6B 1.37(2) . ? B2 F5B 1.425(13) . ? N4A C5 1.386(4) 2_656 ? F5A F7A 1.75(2) . ? P1A Au1 2.2838(9) . ? P2A Au2 2.2926(9) . ? Au1 Au2 3.3108(2) . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag N2 C1 N1 107.3(3) . . ? N2 C1 Au1 130.1(3) . . ? N1 C1 Au1 122.6(3) . . ? C3 C2 N2 131.0(3) . . ? C3 C2 C7 123.1(3) . . ? N2 C2 C7 105.9(3) . . ? C2 C3 C4 113.9(3) . 2_656 ? C2 C3 H3 123.0 . . ? C4 C3 H3 123.0 2_656 . ? N4 C4 C3 131.6(3) . 2_656 ? N4 C4 C5 105.6(3) . 2_656 ? C3 C4 C5 122.8(3) 2_656 2_656 ? N4A C5 C6 130.4(3) 2_656 . ? N4A C5 C4 106.2(3) 2_656 2_656 ? C6 C5 C4 123.4(3) . 2_656 ? C7 C6 C5 113.2(3) . . ? C7 C6 H6 123.4 . . ? C5 C6 H6 123.4 . . ? C6 C7 N1 130.4(3) . . ? C6 C7 C2 123.5(3) . . ? N1 C7 C2 106.0(3) . . ? N4 C8 N4A 107.4(3) . . ? N4 C8 Au2 127.4(3) . . ? N4A C8 Au2 125.1(2) . . ? N1 C9 C10 112.4(3) . . ? N1 C9 H9A 109.1 . . ? C10 C9 H9A 109.1 . . ? N1 C9 H9B 109.1 . . ? C10 C9 H9B 109.1 . . ? H9A C9 H9B 107.9 . . ? C9 C10 C11 112.8(3) . . ? C9 C10 H10A 109.0 . . ? C11 C10 H10A 109.0 . . ? C9 C10 H10B 109.0 . . ? C11 C10 H10B 109.0 . . ? H10A C10 H10B 107.8 . . ? C10 C11 C12 111.4(4) . . ? C10 C11 H11A 109.3 . . ? C12 C11 H11A 109.3 . . ? C10 C11 H11B 109.3 . . ? C12 C11 H11B 109.3 . . ? H11A C11 H11B 108.0 . . ? C11 C12 H12A 109.5 . . ? C11 C12 H12B 109.5 . . ? H12A C12 H12B 109.5 . . ? C11 C12 H12C 109.5 . . ? H12A C12 H12C 109.5 . . ? H12B C12 H12C 109.5 . . ? N2 C13 C14A 115.1(4) . . ? N2 C13 C14B 108.1(6) . . ? C14A C13 C14B 30.9(5) . . ? N2 C13 H13A 108.5 . . ? C14A C13 H13A 108.5 . . ? C14B C13 H13A 135.5 . . ? N2 C13 H13B 108.5 . . ? C14A C13 H13B 108.5 . . ? C14B C13 H13B 83.7 . . ? H13A C13 H13B 107.5 . . ? C13 C14A C15A 112.3(5) . . ? C13 C14A H14A 109.1 . . ? C15A C14A H14A 109.1 . . ? C13 C14A H14B 109.1 . . ? C15A C14A H14B 109.1 . . ? H14A C14A H14B 107.9 . . ? C14A C15A C16A 113.8(9) . . ? C14A C15A H15A 108.8 . . ? C16A C15A H15A 108.8 . . ? C14A C15A H15B 108.8 . . ? C16A C15A H15B 108.8 . . ? H15A C15A H15B 107.7 . . ? C15B C14B C13 118.3(8) . . ? C15B C14B H14C 107.7 . . ? C13 C14B H14C 107.7 . . ? C15B C14B H14D 107.7 . . ? C13 C14B H14D 107.7 . . ? H14C C14B H14D 107.1 . . ? C14B C15B C16B 121.3(15) . . ? C14B C15B H15C 107.0 . . ? C16B C15B H15C 107.0 . . ? C14B C15B H15D 107.0 . . ? C16B C15B H15D 107.0 . . ? H15C C15B H15D 106.7 . . ? C15B C16B H16D 109.5 . . ? C15B C16B H16E 109.5 . . ? H16D C16B H16E 109.5 . . ? C15B C16B H16F 109.5 . . ? H16D C16B H16F 109.5 . . ? H16E C16B H16F 109.5 . . ? N4 C17 C18 111.5(3) . . ? N4 C17 H17A 109.3 . . ? C18 C17 H17A 109.3 . . ? N4 C17 H17B 109.3 . . ? C18 C17 H17B 109.3 . . ? H17A C17 H17B 108.0 . . ? C19 C18 C17 117.4(4) . . ? C19 C18 H18A 107.9 . . ? C17 C18 H18A 107.9 . . ? C19 C18 H18B 107.9 . . ? C17 C18 H18B 107.9 . . ? H18A C18 H18B 107.2 . . ? C20 C19 C18 114.9(5) . . ? C20 C19 H19A 108.5 . . ? C18 C19 H19A 108.5 . . ? C20 C19 H19B 108.5 . . ? C18 C19 H19B 108.5 . . ? H19A C19 H19B 107.5 . . ? C19 C20 H20A 109.5 . . ? C19 C20 H20B 109.5 . . ? H20A C20 H20B 109.5 . . ? C19 C20 H20C 109.5 . . ? H20A C20 H20C 109.5 . . ? H20B C20 H20C 109.5 . . ? N4A C21 C22 111.6(3) . . ? N4A C21 H21A 109.3 . . ? C22 C21 H21A 109.3 . . ? N4A C21 H21B 109.3 . . ? C22 C21 H21B 109.3 . . ? H21A C21 H21B 108.0 . . ? C23 C22 C21 116.6(4) . . ? C23 C22 H22A 108.2 . . ? C21 C22 H22A 108.2 . . ? C23 C22 H22B 108.2 . . ? C21 C22 H22B 108.2 . . ? H22A C22 H22B 107.3 . . ? C22 C23 C24 113.1(5) . . ? C22 C23 H23A 109.0 . . ? C24 C23 H23A 109.0 . . ? C22 C23 H23B 109.0 . . ? C24 C23 H23B 109.0 . . ? H23A C23 H23B 107.8 . . ? C23 C24 H24A 109.5 . . ? C23 C24 H24B 109.5 . . ? H24A C24 H24B 109.5 . . ? C23 C24 H24C 109.5 . . ? H24A C24 H24C 109.5 . . ? H24B C24 H24C 109.5 . . ? C26 C25 P1A 118.5(2) . . ? C26 C25 H25A 107.7 . . ? P1A C25 H25A 107.7 . . ? C26 C25 H25B 107.7 . . ? P1A C25 H25B 107.7 . . ? H25A C25 H25B 107.1 . . ? C25 C26 P2A 120.6(2) . . ? C25 C26 H26A 107.2 . . ? P2A C26 H26A 107.2 . . ? C25 C26 H26B 107.2 . . ? P2A C26 H26B 107.2 . . ? H26A C26 H26B 106.8 . . ? C32 C27 C28 119.6(3) . . ? C32 C27 P1A 119.7(3) . . ? C28 C27 P1A 120.7(3) . . ? C29 C28 C27 119.9(4) . . ? C29 C28 H28 120.0 . . ? C27 C28 H28 120.0 . . ? C30 C29 C28 119.7(4) . . ? C30 C29 H29 120.2 . . ? C28 C29 H29 120.2 . . ? C31 C30 C29 120.7(4) . . ? C31 C30 H30 119.6 . . ? C29 C30 H30 119.6 . . ? C30 C31 C32 120.0(4) . . ? C30 C31 H31 120.0 . . ? C32 C31 H31 120.0 . . ? C31 C32 C27 120.1(4) . . ? C31 C32 H32 119.9 . . ? C27 C32 H32 119.9 . . ? C38 C33 C34 118.8(4) . . ? C38 C33 P1A 119.7(3) . . ? C34 C33 P1A 121.6(3) . . ? C33 C34 C35 120.0(4) . . ? C33 C34 H34 120.0 . . ? C35 C34 H34 120.0 . . ? C36 C35 C34 120.6(4) . . ? C36 C35 H35 119.7 . . ? C34 C35 H35 119.7 . . ? C35 C36 C37 119.7(4) . . ? C35 C36 H36 120.1 . . ? C37 C36 H36 120.1 . . ? C36 C37 C38 120.8(4) . . ? C36 C37 H37 119.6 . . ? C38 C37 H37 119.6 . . ? C33 C38 C37 120.2(4) . . ? C33 C38 H38 119.9 . . ? C37 C38 H38 119.9 . . ? C44 C39 C40 119.5(3) . . ? C44 C39 P2A 119.4(3) . . ? C40 C39 P2A 121.0(3) . . ? C41 C40 C39 118.9(4) . . ? C41 C40 H40 120.5 . . ? C39 C40 H40 120.5 . . ? C42 C41 C40 121.3(4) . . ? C42 C41 H41 119.4 . . ? C40 C41 H41 119.4 . . ? C41 C42 C43 120.4(4) . . ? C41 C42 H42 119.8 . . ? C43 C42 H42 119.8 . . ? C44 C43 C42 119.0(4) . . ? C44 C43 H43 120.5 . . ? C42 C43 H43 120.5 . . ? C43 C44 C39 120.8(4) . . ? C43 C44 H44 119.6 . . ? C39 C44 H44 119.6 . . ? C50 C45 C46 118.9(4) . . ? C50 C45 P2A 119.0(3) . . ? C46 C45 P2A 121.9(3) . . ? C47 C46 C45 120.3(4) . . ? C47 C46 H46 119.8 . . ? C45 C46 H46 119.8 . . ? C48 C47 C46 119.9(5) . . ? C48 C47 H47 120.1 . . ? C46 C47 H47 120.1 . . ? C49 C48 C47 120.8(5) . . ? C49 C48 H48 119.6 . . ? C47 C48 H48 119.6 . . ? C48 C49 C50 119.9(4) . . ? C48 C49 H49 120.0 . . ? C50 C49 H49 120.0 . . ? C45 C50 C49 120.2(5) . . ? C45 C50 H50 119.9 . . ? C49 C50 H50 119.9 . . ? F2 B1 F4 109.8(3) . . ? F2 B1 F3 110.3(3) . . ? F4 B1 F3 109.3(3) . . ? F2 B1 F1 109.1(3) . . ? F4 B1 F1 109.2(3) . . ? F3 B1 F1 109.0(3) . . ? F7A B2 F5A 83.0(10) . . ? F7A B2 F6A 112.2(11) . . ? F5A B2 F6A 116.2(9) . . ? F7A B2 F8 111.0(7) . . ? F5A B2 F8 119.5(6) . . ? F6A B2 F8 111.6(8) . . ? F7A B2 F7B 33.4(10) . . ? F5A B2 F7B 112.8(9) . . ? F6A B2 F7B 85.1(12) . . ? F8 B2 F7B 106.0(8) . . ? F7A B2 F6B 127.7(13) . . ? F5A B2 F6B 101.6(13) . . ? F6A B2 F6B 20.8(17) . . ? F8 B2 F6B 111.2(12) . . ? F7B B2 F6B 104.8(15) . . ? F7A B2 F5B 120.2(13) . . ? F5A B2 F5B 37.7(5) . . ? F6A B2 F5B 103.2(11) . . ? F8 B2 F5B 97.7(7) . . ? F7B B2 F5B 150.0(10) . . ? F6B B2 F5B 82.7(15) . . ? C1 N1 C7 110.3(3) . . ? C1 N1 C9 125.0(3) . . ? C7 N1 C9 124.6(3) . . ? C1 N2 C2 110.5(3) . . ? C1 N2 C13 125.3(3) . . ? C2 N2 C13 124.2(3) . . ? C8 N4 C4 110.7(3) . . ? C8 N4 C17 124.3(3) . . ? C4 N4 C17 124.5(3) . . ? C8 N4A C5 110.1(3) . 2_656 ? C8 N4A C21 125.9(3) . . ? C5 N4A C21 123.7(3) 2_656 . ? B2 F5A F7A 48.1(6) . . ? B2 F7A F5A 48.9(6) . . ? C27 P1A C33 105.35(15) . . ? C27 P1A C25 108.93(16) . . ? C33 P1A C25 102.62(16) . . ? C27 P1A Au1 119.28(12) . . ? C33 P1A Au1 108.49(12) . . ? C25 P1A Au1 110.74(11) . . ? C45 P2A C39 101.95(16) . . ? C45 P2A C26 102.96(17) . . ? C39 P2A C26 107.00(15) . . ? C45 P2A Au2 111.24(13) . . ? C39 P2A Au2 109.36(12) . . ? C26 P2A Au2 122.34(12) . . ? C1 Au1 P1A 170.28(10) . . ? C1 Au1 Au2 82.96(9) . . ? P1A Au1 Au2 99.93(2) . . ? C8 Au2 P2A 170.08(10) . . ? C8 Au2 Au1 101.44(9) . . ? P2A Au2 Au1 85.02(2) . . ? _diffrn_measured_fraction_theta_max 0.993 _diffrn_reflns_theta_full 25.00 _diffrn_measured_fraction_theta_full 1.000 _refine_diff_density_max 1.535 _refine_diff_density_min -2.000 _refine_diff_density_rms 0.134