# Electronic Supplementary Material (ESI) for Dalton Transactions # This journal is © The Royal Society of Chemistry 2011 data_global _journal_coden_Cambridge 222 loop_ _publ_author_name 'Bauer, Richard' 'Gloaguen, Yann' 'Lutz, Martin' 'de Bruin, Bas' 'Reek, J.' 'van der Vlugt, Jarl Ivar' _publ_contact_author_name 'van der Vlugt, Jarl Ivar' _publ_contact_author_email j.i.vandervlugt@uva.nl _publ_section_title ; Pincer Ligands with an All-Phosphorus Donor Set: Subtle Differences between Group 9 and 10 Metals ; # Attachment '- deposit.cif' data_l0057a _database_code_depnum_ccdc_archive 'CCDC 815799' #TrackingRef '- deposit.cif' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety 'C46 H44 Cl N3 P3 Rh, 1.5(C7 H8)' _chemical_formula_sum 'C56.50 H56 Cl N3 P3 Rh' _chemical_formula_weight 1008.31 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting triclinic _symmetry_space_group_name_H-M 'P -1' _symmetry_space_group_name_Hall '-P 1' loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' _cell_length_a 11.4830(6) _cell_length_b 12.4619(4) _cell_length_c 18.6500(6) _cell_angle_alpha 90.887(2) _cell_angle_beta 99.603(2) _cell_angle_gamma 109.560(2) _cell_volume 2472.24(17) _cell_formula_units_Z 2 _cell_measurement_temperature 150(2) _cell_measurement_reflns_used 40186 _cell_measurement_theta_min 1.74 _cell_measurement_theta_max 27.50 _exptl_crystal_description 'irregular block' _exptl_crystal_colour orange _exptl_crystal_size_max 0.33 _exptl_crystal_size_mid 0.27 _exptl_crystal_size_min 0.21 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.355 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 1046 _exptl_absorpt_coefficient_mu 0.537 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_correction_T_min 0.69 _exptl_absorpt_correction_T_max 0.71 _exptl_absorpt_process_details TWINABS-2008/4 _exptl_special_details ; ? ; _diffrn_ambient_temperature 150(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'rotating anode' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'Nonius KappaCCD' _diffrn_measurement_method '\f and \w scans' _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 47552 _diffrn_reflns_av_R_equivalents 0.0201 _diffrn_reflns_av_sigmaI/netI 0.0159 _diffrn_reflns_limit_h_min -14 _diffrn_reflns_limit_h_max 14 _diffrn_reflns_limit_k_min -16 _diffrn_reflns_limit_k_max 16 _diffrn_reflns_limit_l_min -24 _diffrn_reflns_limit_l_max 24 _diffrn_reflns_theta_min 1.74 _diffrn_reflns_theta_max 27.68 _reflns_number_total 11346 _reflns_number_gt 10282 _reflns_threshold_expression I>2\s(I) _computing_data_collection 'Nonius COLLECT' _computing_cell_refinement Peakref _computing_data_reduction 'Eval15, Twinabs' _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics ? _computing_publication_material ? _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0281P)^2^+1.5018P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 11346 _refine_ls_number_parameters 681 _refine_ls_number_restraints 420 _refine_ls_R_factor_all 0.0298 _refine_ls_R_factor_gt 0.0255 _refine_ls_wR_factor_ref 0.0647 _refine_ls_wR_factor_gt 0.0624 _refine_ls_goodness_of_fit_ref 1.044 _refine_ls_restrained_S_all 1.134 _refine_ls_shift/su_max 0.003 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Rh1 Rh 0.315669(11) 0.593394(10) 0.216601(7) 0.01606(4) Uani 1 1 d . . . Cl1 Cl 0.25074(4) 0.74710(4) 0.17129(2) 0.02794(10) Uani 1 1 d . . . P1 P 0.38032(4) 0.45619(3) 0.25189(2) 0.01487(8) Uani 1 1 d . . . P2 P 0.51475(4) 0.70480(3) 0.26638(2) 0.01768(9) Uani 1 1 d . . . P3 P 0.12015(4) 0.47484(3) 0.22069(2) 0.01691(8) Uani 1 1 d . . . N1 N 0.46424(13) 0.39837(12) 0.20839(8) 0.0191(3) Uani 1 1 d . . . N2 N 0.25688(13) 0.33416(11) 0.26018(8) 0.0180(3) Uani 1 1 d . . . N3 N 0.48171(13) 0.50482(11) 0.33441(7) 0.0176(3) Uani 1 1 d . . . C1 C 0.40471(18) 0.34705(17) 0.13380(10) 0.0275(4) Uani 1 1 d . . . H1A H 0.3136 0.3087 0.1324 0.033 Uiso 1 1 calc R . . H1B H 0.4398 0.2877 0.1222 0.033 Uiso 1 1 calc R . . C2 C 0.4221(3) 0.4313(2) 0.07529(12) 0.0477(6) Uani 1 1 d . . . H2A H 0.3880 0.4907 0.0862 0.072 Uiso 1 1 calc R . . H2B H 0.3778 0.3912 0.0278 0.072 Uiso 1 1 calc R . . H2C H 0.5119 0.4665 0.0741 0.072 Uiso 1 1 calc R . . C3 C 0.60346(16) 0.43843(16) 0.22280(10) 0.0246(4) Uani 1 1 d . . . H3A H 0.6355 0.4986 0.2636 0.030 Uiso 1 1 calc R . . H3B H 0.6342 0.4731 0.1791 0.030 Uiso 1 1 calc R . . C4 C 0.6559(2) 0.3442(2) 0.24163(18) 0.0523(7) Uani 1 1 d . . . H4A H 0.6289 0.3116 0.2861 0.079 Uiso 1 1 calc R . . H4B H 0.7480 0.3754 0.2497 0.079 Uiso 1 1 calc R . . H4C H 0.6250 0.2845 0.2014 0.079 Uiso 1 1 calc R . . C5 C 0.13202(15) 0.33721(14) 0.24245(9) 0.0191(3) Uani 1 1 d . . . C6 C 0.04651(16) 0.22932(15) 0.23713(10) 0.0232(4) Uani 1 1 d . . . C7 C 0.11655(16) 0.15252(15) 0.24975(10) 0.0235(4) Uani 1 1 d . . . C8 C 0.07686(18) 0.03255(15) 0.24617(12) 0.0310(4) Uani 1 1 d . . . H8 H -0.0099 -0.0119 0.2395 0.037 Uiso 1 1 calc R . . C9 C 0.16676(19) -0.01927(16) 0.25257(12) 0.0329(4) Uani 1 1 d . . . H9 H 0.1415 -0.1002 0.2500 0.039 Uiso 1 1 calc R . . C10 C 0.29469(18) 0.04600(16) 0.26283(11) 0.0293(4) Uani 1 1 d . . . H10 H 0.3546 0.0082 0.2661 0.035 Uiso 1 1 calc R . . C11 C 0.33663(17) 0.16482(15) 0.26830(10) 0.0238(4) Uani 1 1 d . . . H11 H 0.4238 0.2084 0.2762 0.029 Uiso 1 1 calc R . . C12 C 0.24575(16) 0.21801(14) 0.26181(9) 0.0196(3) Uani 1 1 d . . . C13 C -0.09443(17) 0.19079(17) 0.21740(13) 0.0334(4) Uani 1 1 d . . . H13A H -0.1209 0.2576 0.2107 0.050 Uiso 1 1 calc R . . H13B H -0.1314 0.1484 0.2567 0.050 Uiso 1 1 calc R . . H13C H -0.1229 0.1412 0.1720 0.050 Uiso 1 1 calc R . . C14 C 0.55690(15) 0.62309(14) 0.33992(9) 0.0189(3) Uani 1 1 d . . . C15 C 0.64684(16) 0.64869(15) 0.40198(9) 0.0212(3) Uani 1 1 d . . . C16 C 0.63093(16) 0.54427(15) 0.43744(9) 0.0201(3) Uani 1 1 d . . . C17 C 0.69385(17) 0.52002(16) 0.50335(10) 0.0254(4) Uani 1 1 d . . . H17 H 0.7618 0.5784 0.5327 0.030 Uiso 1 1 calc R . . C18 C 0.65494(19) 0.41007(17) 0.52450(10) 0.0284(4) Uani 1 1 d . . . H18 H 0.6979 0.3920 0.5681 0.034 Uiso 1 1 calc R . . C19 C 0.55242(19) 0.32449(16) 0.48220(10) 0.0272(4) Uani 1 1 d . . . H19 H 0.5266 0.2497 0.4984 0.033 Uiso 1 1 calc R . . C20 C 0.48753(17) 0.34567(15) 0.41737(9) 0.0227(3) Uani 1 1 d . . . H20 H 0.4176 0.2873 0.3895 0.027 Uiso 1 1 calc R . . C21 C 0.52934(15) 0.45660(14) 0.39470(9) 0.0184(3) Uani 1 1 d . . . C22 C 0.74151(18) 0.76262(16) 0.43144(11) 0.0302(4) Uani 1 1 d . . . H22A H 0.7346 0.8201 0.3973 0.045 Uiso 1 1 calc R . . H22B H 0.8262 0.7583 0.4375 0.045 Uiso 1 1 calc R . . H22C H 0.7257 0.7840 0.4787 0.045 Uiso 1 1 calc R . . C23 C -0.00646(15) 0.44334(14) 0.14125(9) 0.0203(3) Uani 1 1 d . . . C24 C -0.09809(17) 0.49434(17) 0.13534(10) 0.0278(4) Uani 1 1 d . . . H24 H -0.1013 0.5407 0.1754 0.033 Uiso 1 1 calc R . . C25 C -0.18542(19) 0.4778(2) 0.07080(11) 0.0359(5) Uani 1 1 d . . . H25 H -0.2474 0.5133 0.0670 0.043 Uiso 1 1 calc R . . C26 C -0.18220(19) 0.40967(19) 0.01214(11) 0.0343(4) Uani 1 1 d . . . H26 H -0.2426 0.3976 -0.0314 0.041 Uiso 1 1 calc R . . C27 C -0.0906(2) 0.35925(17) 0.01732(11) 0.0325(4) Uani 1 1 d . . . H27 H -0.0881 0.3126 -0.0228 0.039 Uiso 1 1 calc R . . C28 C -0.00241(18) 0.37681(16) 0.08108(10) 0.0277(4) Uani 1 1 d . . . H28 H 0.0613 0.3434 0.0839 0.033 Uiso 1 1 calc R . . C29 C 0.05719(16) 0.51921(16) 0.29560(9) 0.0221(3) Uani 1 1 d . . . C30 C 0.0718(2) 0.63467(18) 0.30627(11) 0.0322(4) Uani 1 1 d . . . H30 H 0.1143 0.6881 0.2753 0.039 Uiso 1 1 calc R . . C31 C 0.0242(2) 0.6714(2) 0.36219(12) 0.0429(5) Uani 1 1 d . . . H31 H 0.0334 0.7497 0.3689 0.051 Uiso 1 1 calc R . . C32 C -0.0363(2) 0.5944(2) 0.40794(13) 0.0461(6) Uani 1 1 d . . . H32 H -0.0689 0.6199 0.4459 0.055 Uiso 1 1 calc R . . C33 C -0.0495(2) 0.4808(2) 0.39866(12) 0.0441(5) Uani 1 1 d . . . H33 H -0.0906 0.4282 0.4305 0.053 Uiso 1 1 calc R . . C34 C -0.00270(19) 0.44273(18) 0.34263(11) 0.0324(4) Uani 1 1 d . . . H34 H -0.0117 0.3643 0.3366 0.039 Uiso 1 1 calc R . . C35 C 0.63854(16) 0.73890(14) 0.21165(10) 0.0224(3) Uani 1 1 d . . . C36 C 0.6062(2) 0.77021(18) 0.14151(11) 0.0331(4) Uani 1 1 d . . . H36 H 0.5237 0.7713 0.1250 0.040 Uiso 1 1 calc R . . C37 C 0.6943(2) 0.7998(2) 0.09569(13) 0.0457(6) Uani 1 1 d . . . H37 H 0.6727 0.8236 0.0487 0.055 Uiso 1 1 calc R . . C38 C 0.8132(2) 0.79470(19) 0.11840(13) 0.0425(5) Uani 1 1 d . . . H38 H 0.8728 0.8140 0.0868 0.051 Uiso 1 1 calc R . . C39 C 0.84501(19) 0.76152(17) 0.18710(13) 0.0352(5) Uani 1 1 d . . . H39 H 0.9263 0.7569 0.2023 0.042 Uiso 1 1 calc R . . C40 C 0.75875(17) 0.73476(15) 0.23440(11) 0.0274(4) Uani 1 1 d . . . H40 H 0.7820 0.7138 0.2820 0.033 Uiso 1 1 calc R . . C41 C 0.53415(16) 0.84234(14) 0.31218(9) 0.0212(3) Uani 1 1 d . . . C42 C 0.45415(19) 0.84294(16) 0.36073(10) 0.0277(4) Uani 1 1 d . . . H42 H 0.3906 0.7740 0.3677 0.033 Uiso 1 1 calc R . . C43 C 0.4673(2) 0.94440(19) 0.39906(11) 0.0373(5) Uani 1 1 d . . . H43 H 0.4146 0.9442 0.4333 0.045 Uiso 1 1 calc R . . C44 C 0.5573(2) 1.04569(18) 0.38726(13) 0.0409(5) Uani 1 1 d . . . H44 H 0.5668 1.1147 0.4138 0.049 Uiso 1 1 calc R . . C45 C 0.6328(2) 1.04623(17) 0.33717(14) 0.0404(5) Uani 1 1 d . . . H45 H 0.6922 1.1162 0.3279 0.048 Uiso 1 1 calc R . . C46 C 0.62257(19) 0.94470(16) 0.29992(12) 0.0316(4) Uani 1 1 d . . . H46 H 0.6762 0.9455 0.2661 0.038 Uiso 1 1 calc R . . C101 C 0.4968(4) 0.0034(4) -0.0375(3) 0.0490(12) Uani 0.50 1 d PDU . . C102 C 0.5859(4) 0.1070(4) -0.0092(3) 0.0385(14) Uani 0.50 1 d PDU . . H102 H 0.6321 0.1564 -0.0407 0.046 Uiso 0.50 1 calc PR . . C103 C 0.6086(4) 0.1395(4) 0.0642(2) 0.0454(11) Uani 0.50 1 d PDU . . H103 H 0.6704 0.2111 0.0825 0.055 Uiso 0.50 1 calc PR . . C104 C 0.5433(7) 0.0702(6) 0.1114(4) 0.065(3) Uani 0.50 1 d PDU . . H104 H 0.5593 0.0933 0.1619 0.078 Uiso 0.50 1 calc PR . . C105 C 0.4537(6) -0.0340(5) 0.0837(4) 0.085(3) Uani 0.50 1 d PDU . . H105 H 0.4075 -0.0833 0.1152 0.102 Uiso 0.50 1 calc PR . . C106 C 0.4318(6) -0.0662(5) 0.0102(4) 0.062(3) Uani 0.50 1 d PDU . . H106 H 0.3704 -0.1380 -0.0081 0.075 Uiso 0.50 1 calc PR . . C107 C 0.4734(8) -0.0308(8) -0.1163(5) 0.076(3) Uani 0.50 1 d PDU . . H10A H 0.4083 -0.1065 -0.1267 0.114 Uiso 0.50 1 calc PR . . H10B H 0.5511 -0.0334 -0.1302 0.114 Uiso 0.50 1 calc PR . . H10C H 0.4453 0.0248 -0.1442 0.114 Uiso 0.50 1 calc PR . . C201 C 0.9165(4) -0.0081(3) -0.0303(2) 0.0329(9) Uani 0.50 1 d PD . . C202 C 0.9660(6) 0.0759(4) 0.0256(3) 0.0409(16) Uani 0.50 1 d PD . . H202 H 0.9188 0.1218 0.0365 0.049 Uiso 0.50 1 calc PR . . C203 C 1.0831(6) 0.0942(5) 0.0661(3) 0.0586(18) Uani 0.50 1 d PD . . H203 H 1.1167 0.1526 0.1048 0.070 Uiso 0.50 1 calc PR . . C204 C 1.1517(6) 0.0283(5) 0.0508(3) 0.066(2) Uani 0.50 1 d PD . . H204 H 1.2329 0.0414 0.0789 0.080 Uiso 0.50 1 calc PR . . C205 C 1.1036(6) -0.0563(5) -0.0047(3) 0.0531(16) Uani 0.50 1 d PD . . H205 H 1.1507 -0.1026 -0.0151 0.064 Uiso 0.50 1 calc PR . . C206 C 0.9860(6) -0.0735(5) -0.0454(3) 0.0341(14) Uani 0.50 1 d PD . . H206 H 0.9528 -0.1314 -0.0844 0.041 Uiso 0.50 1 calc PR . . C207 C 0.7899(5) -0.0264(5) -0.0736(3) 0.0500(13) Uani 0.50 1 d PD . . H20A H 0.7692 -0.0883 -0.1117 0.075 Uiso 0.50 1 calc PR . . H20B H 0.7891 0.0439 -0.0962 0.075 Uiso 0.50 1 calc PR . . H20C H 0.7275 -0.0470 -0.0415 0.075 Uiso 0.50 1 calc PR . . C301 C 0.0040(8) 0.0356(6) 0.4660(4) 0.101(4) Uani 0.50 1 d PDU . . C302 C 0.0914(7) -0.0123(8) 0.4528(5) 0.106(4) Uani 0.50 1 d PDU . . H302 H 0.1318 0.0072 0.4120 0.127 Uiso 0.50 1 calc PR . . C303 C 0.1198(8) -0.0886(7) 0.4994(6) 0.112(3) Uani 0.50 1 d PDU . . H303 H 0.1795 -0.1237 0.4930 0.134 Uiso 0.50 1 calc PR . . C304 C 0.0555(9) -0.1088(7) 0.5543(6) 0.136(5) Uani 0.50 1 d PDU . . H304 H 0.0708 -0.1623 0.5871 0.163 Uiso 0.50 1 calc PR . . C305 C -0.0312(10) -0.0596(8) 0.5683(4) 0.116(4) Uani 0.50 1 d PDU . . H305 H -0.0697 -0.0782 0.6099 0.139 Uiso 0.50 1 calc PR . . C306 C -0.0618(8) 0.0159(7) 0.5224(5) 0.091(3) Uani 0.50 1 d PDU . . H306 H -0.1218 0.0507 0.5289 0.110 Uiso 0.50 1 calc PR . . C307 C -0.0203(12) 0.1166(8) 0.4149(6) 0.131(5) Uani 0.50 1 d PDU . . H30A H 0.0304 0.1230 0.3768 0.196 Uiso 0.50 1 calc PR . . H30B H 0.0019 0.1915 0.4411 0.196 Uiso 0.50 1 calc PR . . H30C H -0.1096 0.0896 0.3926 0.196 Uiso 0.50 1 calc PR . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Rh1 0.01606(7) 0.01356(6) 0.01837(7) 0.00178(4) 0.00159(5) 0.00554(5) Cl1 0.0343(2) 0.0213(2) 0.0299(2) 0.00470(17) -0.00080(18) 0.01475(18) P1 0.01376(18) 0.01324(18) 0.01729(19) 0.00073(14) 0.00169(14) 0.00478(15) P2 0.01752(19) 0.01415(19) 0.0197(2) 0.00190(15) 0.00213(15) 0.00386(15) P3 0.01517(19) 0.01602(19) 0.0203(2) 0.00087(15) 0.00243(15) 0.00670(15) N1 0.0175(7) 0.0205(7) 0.0204(7) -0.0008(5) 0.0029(5) 0.0084(6) N2 0.0156(6) 0.0144(6) 0.0244(7) 0.0018(5) 0.0028(5) 0.0060(5) N3 0.0192(7) 0.0149(6) 0.0181(7) 0.0017(5) 0.0018(5) 0.0057(5) C1 0.0303(9) 0.0312(10) 0.0225(9) -0.0047(7) 0.0024(7) 0.0141(8) C2 0.0626(16) 0.0569(15) 0.0236(10) 0.0068(10) 0.0025(10) 0.0229(13) C3 0.0179(8) 0.0270(9) 0.0307(9) 0.0002(7) 0.0068(7) 0.0087(7) C4 0.0263(11) 0.0424(13) 0.094(2) 0.0099(13) 0.0090(12) 0.0198(10) C5 0.0162(7) 0.0182(8) 0.0236(8) 0.0020(6) 0.0042(6) 0.0064(6) C6 0.0177(8) 0.0193(8) 0.0319(9) 0.0036(7) 0.0052(7) 0.0049(7) C7 0.0213(8) 0.0171(8) 0.0306(9) 0.0021(7) 0.0043(7) 0.0050(7) C8 0.0261(9) 0.0168(8) 0.0456(12) 0.0026(8) 0.0046(8) 0.0023(7) C9 0.0355(11) 0.0145(8) 0.0461(12) 0.0017(8) 0.0030(9) 0.0073(8) C10 0.0311(10) 0.0206(9) 0.0382(11) 0.0017(8) 0.0019(8) 0.0134(8) C11 0.0220(8) 0.0190(8) 0.0296(9) 0.0013(7) 0.0004(7) 0.0081(7) C12 0.0215(8) 0.0144(7) 0.0220(8) 0.0014(6) 0.0023(6) 0.0056(6) C13 0.0171(8) 0.0259(9) 0.0544(13) 0.0056(9) 0.0062(8) 0.0039(7) C14 0.0189(8) 0.0156(7) 0.0215(8) 0.0014(6) 0.0038(6) 0.0051(6) C15 0.0198(8) 0.0206(8) 0.0216(8) -0.0001(6) 0.0012(6) 0.0062(7) C16 0.0202(8) 0.0224(8) 0.0186(8) -0.0002(6) 0.0022(6) 0.0091(7) C17 0.0255(9) 0.0295(9) 0.0201(8) -0.0003(7) -0.0005(7) 0.0105(7) C18 0.0343(10) 0.0348(10) 0.0201(9) 0.0055(7) 0.0012(7) 0.0187(8) C19 0.0382(10) 0.0243(9) 0.0235(9) 0.0067(7) 0.0066(8) 0.0155(8) C20 0.0282(9) 0.0198(8) 0.0209(8) 0.0013(6) 0.0039(7) 0.0096(7) C21 0.0209(8) 0.0208(8) 0.0162(7) 0.0016(6) 0.0039(6) 0.0106(6) C22 0.0281(9) 0.0244(9) 0.0306(10) -0.0021(8) -0.0046(8) 0.0044(8) C23 0.0174(8) 0.0198(8) 0.0224(8) 0.0032(6) 0.0026(6) 0.0052(6) C24 0.0238(9) 0.0359(10) 0.0268(9) 0.0011(8) 0.0026(7) 0.0151(8) C25 0.0261(10) 0.0519(13) 0.0333(11) 0.0071(9) 0.0005(8) 0.0204(9) C26 0.0286(10) 0.0409(11) 0.0258(10) 0.0050(8) -0.0045(8) 0.0064(9) C27 0.0368(11) 0.0305(10) 0.0249(10) -0.0025(8) 0.0005(8) 0.0073(8) C28 0.0284(9) 0.0275(9) 0.0281(9) -0.0012(7) 0.0023(7) 0.0122(8) C29 0.0194(8) 0.0287(9) 0.0207(8) 0.0000(7) 0.0017(6) 0.0125(7) C30 0.0402(11) 0.0317(10) 0.0319(10) 0.0006(8) 0.0095(8) 0.0203(9) C31 0.0570(14) 0.0470(13) 0.0368(12) -0.0044(10) 0.0113(10) 0.0328(12) C32 0.0528(14) 0.0666(16) 0.0336(12) -0.0022(11) 0.0163(10) 0.0360(13) C33 0.0472(13) 0.0593(15) 0.0332(12) 0.0093(10) 0.0206(10) 0.0212(12) C34 0.0340(10) 0.0353(11) 0.0315(10) 0.0039(8) 0.0114(8) 0.0138(9) C35 0.0234(8) 0.0161(8) 0.0259(9) 0.0009(6) 0.0065(7) 0.0036(6) C36 0.0318(10) 0.0389(11) 0.0291(10) 0.0074(8) 0.0081(8) 0.0112(9) C37 0.0517(14) 0.0543(15) 0.0316(11) 0.0110(10) 0.0186(10) 0.0133(12) C38 0.0429(12) 0.0372(12) 0.0476(13) 0.0020(10) 0.0283(11) 0.0045(10) C39 0.0254(9) 0.0238(9) 0.0548(13) -0.0015(9) 0.0155(9) 0.0029(8) C40 0.0232(9) 0.0213(9) 0.0352(10) 0.0018(7) 0.0057(7) 0.0040(7) C41 0.0242(8) 0.0174(8) 0.0214(8) 0.0010(6) -0.0005(6) 0.0086(7) C42 0.0363(10) 0.0252(9) 0.0245(9) 0.0061(7) 0.0065(8) 0.0135(8) C43 0.0542(13) 0.0390(12) 0.0281(10) 0.0023(9) 0.0101(9) 0.0271(10) C44 0.0555(14) 0.0280(10) 0.0398(12) -0.0094(9) -0.0020(10) 0.0208(10) C45 0.0406(12) 0.0196(9) 0.0554(14) -0.0038(9) 0.0055(10) 0.0048(9) C46 0.0305(10) 0.0186(9) 0.0430(12) -0.0014(8) 0.0082(8) 0.0043(7) C101 0.036(3) 0.034(3) 0.075(3) 0.002(3) -0.004(3) 0.016(2) C102 0.032(3) 0.027(4) 0.055(3) 0.015(2) 0.009(2) 0.008(3) C103 0.052(3) 0.037(2) 0.046(3) 0.012(2) 0.012(2) 0.012(2) C104 0.105(6) 0.043(5) 0.054(4) 0.012(3) 0.031(4) 0.026(4) C105 0.094(5) 0.054(4) 0.137(7) 0.047(5) 0.080(6) 0.033(4) C106 0.041(3) 0.024(4) 0.121(7) 0.013(4) 0.024(4) 0.007(3) C107 0.074(5) 0.055(6) 0.092(6) -0.009(5) -0.020(5) 0.030(4) C201 0.040(3) 0.030(2) 0.028(2) 0.0079(18) 0.007(2) 0.010(2) C202 0.045(4) 0.039(3) 0.036(4) -0.004(3) 0.007(4) 0.012(4) C203 0.060(4) 0.062(4) 0.035(3) -0.015(3) 0.003(3) -0.001(3) C204 0.043(4) 0.093(6) 0.045(4) 0.021(4) -0.014(3) 0.009(4) C205 0.048(4) 0.052(4) 0.063(4) 0.009(3) 0.005(3) 0.025(3) C206 0.039(4) 0.027(2) 0.032(3) -0.005(2) -0.002(3) 0.011(3) C207 0.051(3) 0.051(3) 0.047(3) 0.011(3) 0.011(3) 0.014(3) C301 0.114(7) 0.051(4) 0.070(5) 0.018(4) -0.043(5) -0.031(4) C302 0.085(6) 0.100(7) 0.092(7) -0.043(6) -0.001(5) -0.012(5) C303 0.094(6) 0.094(6) 0.112(6) -0.045(5) -0.044(5) 0.018(5) C304 0.122(8) 0.107(7) 0.098(7) -0.019(6) -0.077(6) -0.019(6) C305 0.118(7) 0.114(8) 0.053(5) -0.015(5) -0.019(5) -0.024(6) C306 0.080(6) 0.059(5) 0.094(7) -0.027(5) -0.008(5) -0.018(4) C307 0.130(8) 0.127(8) 0.117(8) -0.010(6) -0.003(7) 0.032(7) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Rh1 P1 2.1516(4) . ? Rh1 P3 2.2514(4) . ? Rh1 P2 2.2677(4) . ? Rh1 Cl1 2.3948(4) . ? P1 N1 1.6774(14) . ? P1 N2 1.7271(14) . ? P1 N3 1.7298(14) . ? P2 C14 1.8178(17) . ? P2 C35 1.8265(18) . ? P2 C41 1.8310(17) . ? P3 C5 1.8123(17) . ? P3 C23 1.8286(17) . ? P3 C29 1.8333(18) . ? N1 C1 1.474(2) . ? N1 C3 1.482(2) . ? N2 C12 1.411(2) . ? N2 C5 1.430(2) . ? N3 C21 1.400(2) . ? N3 C14 1.429(2) . ? C1 C2 1.517(3) . ? C1 H1A 0.9900 . ? C1 H1B 0.9900 . ? C2 H2A 0.9800 . ? C2 H2B 0.9800 . ? C2 H2C 0.9800 . ? C3 C4 1.510(3) . ? C3 H3A 0.9900 . ? C3 H3B 0.9900 . ? C4 H4A 0.9800 . ? C4 H4B 0.9800 . ? C4 H4C 0.9800 . ? C5 C6 1.364(2) . ? C6 C7 1.441(2) . ? C6 C13 1.504(2) . ? C7 C8 1.406(2) . ? C7 C12 1.411(2) . ? C8 C9 1.380(3) . ? C8 H8 0.9500 . ? C9 C10 1.399(3) . ? C9 H9 0.9500 . ? C10 C11 1.392(2) . ? C10 H10 0.9500 . ? C11 C12 1.402(2) . ? C11 H11 0.9500 . ? C13 H13A 0.9800 . ? C13 H13B 0.9800 . ? C13 H13C 0.9800 . ? C14 C15 1.370(2) . ? C15 C16 1.439(2) . ? C15 C22 1.497(2) . ? C16 C17 1.409(2) . ? C16 C21 1.414(2) . ? C17 C18 1.378(3) . ? C17 H17 0.9500 . ? C18 C19 1.403(3) . ? C18 H18 0.9500 . ? C19 C20 1.388(2) . ? C19 H19 0.9500 . ? C20 C21 1.401(2) . ? C20 H20 0.9500 . ? C22 H22A 0.9800 . ? C22 H22B 0.9800 . ? C22 H22C 0.9800 . ? C23 C24 1.391(2) . ? C23 C28 1.401(3) . ? C24 C25 1.396(3) . ? C24 H24 0.9500 . ? C25 C26 1.387(3) . ? C25 H25 0.9500 . ? C26 C27 1.386(3) . ? C26 H26 0.9500 . ? C27 C28 1.389(3) . ? C27 H27 0.9500 . ? C28 H28 0.9500 . ? C29 C34 1.392(3) . ? C29 C30 1.399(3) . ? C30 C31 1.393(3) . ? C30 H30 0.9500 . ? C31 C32 1.381(4) . ? C31 H31 0.9500 . ? C32 C33 1.378(4) . ? C32 H32 0.9500 . ? C33 C34 1.396(3) . ? C33 H33 0.9500 . ? C34 H34 0.9500 . ? C35 C40 1.393(3) . ? C35 C36 1.397(3) . ? C36 C37 1.393(3) . ? C36 H36 0.9500 . ? C37 C38 1.383(4) . ? C37 H37 0.9500 . ? C38 C39 1.381(3) . ? C38 H38 0.9500 . ? C39 C40 1.396(3) . ? C39 H39 0.9500 . ? C40 H40 0.9500 . ? C41 C46 1.389(3) . ? C41 C42 1.395(3) . ? C42 C43 1.393(3) . ? C42 H42 0.9500 . ? C43 C44 1.386(3) . ? C43 H43 0.9500 . ? C44 C45 1.375(3) . ? C44 H44 0.9500 . ? C45 C46 1.394(3) . ? C45 H45 0.9500 . ? C46 H46 0.9500 . ? C101 C102 1.380(5) . ? C101 C106 1.383(6) . ? C101 C107 1.479(8) . ? C102 C103 1.379(6) . ? C102 H102 0.9500 . ? C103 C104 1.376(6) . ? C103 H103 0.9500 . ? C104 C105 1.386(6) . ? C104 H104 0.9500 . ? C105 C106 1.379(7) . ? C105 H105 0.9500 . ? C106 H106 0.9500 . ? C107 H10A 0.9800 . ? C107 H10B 0.9800 . ? C107 H10C 0.9800 . ? C201 C202 1.370(6) . ? C201 C206 1.373(5) . ? C201 C207 1.483(7) . ? C202 C203 1.372(6) . ? C202 H202 0.9500 . ? C203 C204 1.369(6) . ? C203 H203 0.9500 . ? C204 C205 1.370(6) . ? C204 H204 0.9500 . ? C205 C206 1.380(5) . ? C205 H205 0.9500 . ? C206 H206 0.9500 . ? C207 H20A 0.9800 . ? C207 H20B 0.9800 . ? C207 H20C 0.9800 . ? C301 C306 1.373(7) . ? C301 C302 1.380(7) . ? C301 C307 1.462(9) . ? C302 C303 1.379(7) . ? C302 H302 0.9500 . ? C303 C304 1.340(7) . ? C303 H303 0.9500 . ? C304 C305 1.388(7) . ? C304 H304 0.9500 . ? C305 C306 1.374(7) . ? C305 H305 0.9500 . ? C306 H306 0.9500 . ? C307 H30A 0.9800 . ? C307 H30B 0.9800 . ? C307 H30C 0.9800 . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag P1 Rh1 P3 87.092(16) . . ? P1 Rh1 P2 83.620(16) . . ? P3 Rh1 P2 154.301(17) . . ? P1 Rh1 Cl1 176.474(17) . . ? P3 Rh1 Cl1 95.087(16) . . ? P2 Rh1 Cl1 95.501(16) . . ? N1 P1 N2 99.56(7) . . ? N1 P1 N3 100.78(7) . . ? N2 P1 N3 111.30(7) . . ? N1 P1 Rh1 126.06(5) . . ? N2 P1 Rh1 111.67(5) . . ? N3 P1 Rh1 106.76(5) . . ? C14 P2 C35 107.48(8) . . ? C14 P2 C41 104.10(8) . . ? C35 P2 C41 104.15(8) . . ? C14 P2 Rh1 102.72(5) . . ? C35 P2 Rh1 120.32(6) . . ? C41 P2 Rh1 116.66(6) . . ? C5 P3 C23 104.83(8) . . ? C5 P3 C29 105.17(8) . . ? C23 P3 C29 105.22(8) . . ? C5 P3 Rh1 107.08(5) . . ? C23 P3 Rh1 121.44(6) . . ? C29 P3 Rh1 111.82(6) . . ? C1 N1 C3 114.74(14) . . ? C1 N1 P1 115.89(11) . . ? C3 N1 P1 123.45(11) . . ? C12 N2 C5 106.77(13) . . ? C12 N2 P1 132.60(11) . . ? C5 N2 P1 118.07(11) . . ? C21 N3 C14 107.15(13) . . ? C21 N3 P1 137.00(12) . . ? C14 N3 P1 114.61(11) . . ? N1 C1 C2 114.48(17) . . ? N1 C1 H1A 108.6 . . ? C2 C1 H1A 108.6 . . ? N1 C1 H1B 108.6 . . ? C2 C1 H1B 108.6 . . ? H1A C1 H1B 107.6 . . ? C1 C2 H2A 109.5 . . ? C1 C2 H2B 109.5 . . ? H2A C2 H2B 109.5 . . ? C1 C2 H2C 109.5 . . ? H2A C2 H2C 109.5 . . ? H2B C2 H2C 109.5 . . ? N1 C3 C4 113.19(16) . . ? N1 C3 H3A 108.9 . . ? C4 C3 H3A 108.9 . . ? N1 C3 H3B 108.9 . . ? C4 C3 H3B 108.9 . . ? H3A C3 H3B 107.8 . . ? C3 C4 H4A 109.5 . . ? C3 C4 H4B 109.5 . . ? H4A C4 H4B 109.5 . . ? C3 C4 H4C 109.5 . . ? H4A C4 H4C 109.5 . . ? H4B C4 H4C 109.5 . . ? C6 C5 N2 110.14(14) . . ? C6 C5 P3 133.56(13) . . ? N2 C5 P3 115.71(11) . . ? C5 C6 C7 107.05(15) . . ? C5 C6 C13 128.95(16) . . ? C7 C6 C13 123.90(16) . . ? C8 C7 C12 120.42(16) . . ? C8 C7 C6 131.25(17) . . ? C12 C7 C6 108.12(15) . . ? C9 C8 C7 118.56(17) . . ? C9 C8 H8 120.7 . . ? C7 C8 H8 120.7 . . ? C8 C9 C10 120.80(17) . . ? C8 C9 H9 119.6 . . ? C10 C9 H9 119.6 . . ? C11 C10 C9 121.80(17) . . ? C11 C10 H10 119.1 . . ? C9 C10 H10 119.1 . . ? C10 C11 C12 117.68(17) . . ? C10 C11 H11 121.2 . . ? C12 C11 H11 121.2 . . ? C11 C12 C7 120.71(15) . . ? C11 C12 N2 131.36(15) . . ? C7 C12 N2 107.79(14) . . ? C6 C13 H13A 109.5 . . ? C6 C13 H13B 109.5 . . ? H13A C13 H13B 109.5 . . ? C6 C13 H13C 109.5 . . ? H13A C13 H13C 109.5 . . ? H13B C13 H13C 109.5 . . ? C15 C14 N3 109.94(14) . . ? C15 C14 P2 134.46(13) . . ? N3 C14 P2 115.59(12) . . ? C14 C15 C16 106.87(15) . . ? C14 C15 C22 128.31(16) . . ? C16 C15 C22 124.77(16) . . ? C17 C16 C21 119.92(16) . . ? C17 C16 C15 131.95(16) . . ? C21 C16 C15 108.10(14) . . ? C18 C17 C16 118.76(17) . . ? C18 C17 H17 120.6 . . ? C16 C17 H17 120.6 . . ? C17 C18 C19 120.64(17) . . ? C17 C18 H18 119.7 . . ? C19 C18 H18 119.7 . . ? C20 C19 C18 122.10(17) . . ? C20 C19 H19 119.0 . . ? C18 C19 H19 119.0 . . ? C19 C20 C21 117.32(17) . . ? C19 C20 H20 121.3 . . ? C21 C20 H20 121.3 . . ? N3 C21 C20 130.73(16) . . ? N3 C21 C16 107.92(14) . . ? C20 C21 C16 121.22(15) . . ? C15 C22 H22A 109.5 . . ? C15 C22 H22B 109.5 . . ? H22A C22 H22B 109.5 . . ? C15 C22 H22C 109.5 . . ? H22A C22 H22C 109.5 . . ? H22B C22 H22C 109.5 . . ? C24 C23 C28 118.86(16) . . ? C24 C23 P3 121.85(14) . . ? C28 C23 P3 118.85(13) . . ? C23 C24 C25 120.28(18) . . ? C23 C24 H24 119.9 . . ? C25 C24 H24 119.9 . . ? C26 C25 C24 120.34(19) . . ? C26 C25 H25 119.8 . . ? C24 C25 H25 119.8 . . ? C27 C26 C25 119.78(18) . . ? C27 C26 H26 120.1 . . ? C25 C26 H26 120.1 . . ? C26 C27 C28 120.08(19) . . ? C26 C27 H27 120.0 . . ? C28 C27 H27 120.0 . . ? C27 C28 C23 120.64(18) . . ? C27 C28 H28 119.7 . . ? C23 C28 H28 119.7 . . ? C34 C29 C30 119.06(17) . . ? C34 C29 P3 122.49(14) . . ? C30 C29 P3 118.44(14) . . ? C31 C30 C29 120.1(2) . . ? C31 C30 H30 120.0 . . ? C29 C30 H30 120.0 . . ? C32 C31 C30 120.3(2) . . ? C32 C31 H31 119.9 . . ? C30 C31 H31 119.9 . . ? C33 C32 C31 120.1(2) . . ? C33 C32 H32 119.9 . . ? C31 C32 H32 119.9 . . ? C32 C33 C34 120.2(2) . . ? C32 C33 H33 119.9 . . ? C34 C33 H33 119.9 . . ? C29 C34 C33 120.2(2) . . ? C29 C34 H34 119.9 . . ? C33 C34 H34 119.9 . . ? C40 C35 C36 119.24(17) . . ? C40 C35 P2 125.18(14) . . ? C36 C35 P2 115.58(14) . . ? C37 C36 C35 120.2(2) . . ? C37 C36 H36 119.9 . . ? C35 C36 H36 119.9 . . ? C38 C37 C36 120.2(2) . . ? C38 C37 H37 119.9 . . ? C36 C37 H37 119.9 . . ? C39 C38 C37 119.87(19) . . ? C39 C38 H38 120.1 . . ? C37 C38 H38 120.1 . . ? C38 C39 C40 120.5(2) . . ? C38 C39 H39 119.7 . . ? C40 C39 H39 119.7 . . ? C35 C40 C39 119.87(19) . . ? C35 C40 H40 120.1 . . ? C39 C40 H40 120.1 . . ? C46 C41 C42 119.24(17) . . ? C46 C41 P2 123.20(14) . . ? C42 C41 P2 117.55(13) . . ? C43 C42 C41 120.12(19) . . ? C43 C42 H42 119.9 . . ? C41 C42 H42 119.9 . . ? C44 C43 C42 120.0(2) . . ? C44 C43 H43 120.0 . . ? C42 C43 H43 120.0 . . ? C45 C44 C43 119.98(19) . . ? C45 C44 H44 120.0 . . ? C43 C44 H44 120.0 . . ? C44 C45 C46 120.4(2) . . ? C44 C45 H45 119.8 . . ? C46 C45 H45 119.8 . . ? C41 C46 C45 120.1(2) . . ? C41 C46 H46 119.9 . . ? C45 C46 H46 119.9 . . ? C102 C101 C106 117.8(5) . . ? C102 C101 C107 120.3(5) . . ? C106 C101 C107 121.8(6) . . ? C103 C102 C101 120.8(5) . . ? C103 C102 H102 119.6 . . ? C101 C102 H102 119.6 . . ? C104 C103 C102 121.2(5) . . ? C104 C103 H103 119.4 . . ? C102 C103 H103 119.4 . . ? C103 C104 C105 118.6(6) . . ? C103 C104 H104 120.7 . . ? C105 C104 H104 120.7 . . ? C106 C105 C104 119.9(5) . . ? C106 C105 H105 120.0 . . ? C104 C105 H105 120.0 . . ? C105 C106 C101 121.7(6) . . ? C105 C106 H106 119.1 . . ? C101 C106 H106 119.1 . . ? C101 C107 H10A 109.5 . . ? C101 C107 H10B 109.5 . . ? H10A C107 H10B 109.5 . . ? C101 C107 H10C 109.5 . . ? H10A C107 H10C 109.5 . . ? H10B C107 H10C 109.5 . . ? C202 C201 C206 119.0(4) . . ? C202 C201 C207 119.8(5) . . ? C206 C201 C207 121.2(5) . . ? C201 C202 C203 120.6(6) . . ? C201 C202 H202 119.7 . . ? C203 C202 H202 119.7 . . ? C204 C203 C202 120.1(6) . . ? C204 C203 H203 120.0 . . ? C202 C203 H203 120.0 . . ? C203 C204 C205 120.3(5) . . ? C203 C204 H204 119.9 . . ? C205 C204 H204 119.9 . . ? C204 C205 C206 119.2(6) . . ? C204 C205 H205 120.4 . . ? C206 C205 H205 120.4 . . ? C201 C206 C205 121.0(6) . . ? C201 C206 H206 119.5 . . ? C205 C206 H206 119.5 . . ? C201 C207 H20A 109.5 . . ? C201 C207 H20B 109.5 . . ? H20A C207 H20B 109.5 . . ? C201 C207 H20C 109.5 . . ? H20A C207 H20C 109.5 . . ? H20B C207 H20C 109.5 . . ? C306 C301 C302 126.9(7) . . ? C306 C301 C307 116.6(8) . . ? C302 C301 C307 116.5(7) . . ? C303 C302 C301 119.5(7) . . ? C303 C302 H302 120.2 . . ? C301 C302 H302 120.2 . . ? C304 C303 C302 114.0(7) . . ? C304 C303 H303 123.0 . . ? C302 C303 H303 123.0 . . ? C303 C304 C305 126.7(8) . . ? C303 C304 H304 116.7 . . ? C305 C304 H304 116.7 . . ? C306 C305 C304 120.4(8) . . ? C306 C305 H305 119.8 . . ? C304 C305 H305 119.8 . . ? C301 C306 C305 112.5(7) . . ? C301 C306 H306 123.8 . . ? C305 C306 H306 123.8 . . ? C301 C307 H30A 109.5 . . ? C301 C307 H30B 109.5 . . ? H30A C307 H30B 109.5 . . ? C301 C307 H30C 109.5 . . ? H30A C307 H30C 109.5 . . ? H30B C307 H30C 109.5 . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag P3 Rh1 P1 N1 123.27(6) . . . . ? P2 Rh1 P1 N1 -80.73(6) . . . . ? P3 Rh1 P1 N2 2.57(5) . . . . ? P2 Rh1 P1 N2 158.58(6) . . . . ? P3 Rh1 P1 N3 -119.28(5) . . . . ? P2 Rh1 P1 N3 36.72(5) . . . . ? P1 Rh1 P2 C14 -30.67(6) . . . . ? P3 Rh1 P2 C14 38.84(7) . . . . ? Cl1 Rh1 P2 C14 152.77(6) . . . . ? P1 Rh1 P2 C35 88.58(7) . . . . ? P3 Rh1 P2 C35 158.09(7) . . . . ? Cl1 Rh1 P2 C35 -87.98(7) . . . . ? P1 Rh1 P2 C41 -143.79(6) . . . . ? P3 Rh1 P2 C41 -74.28(7) . . . . ? Cl1 Rh1 P2 C41 39.64(6) . . . . ? P1 Rh1 P3 C5 -4.71(6) . . . . ? P2 Rh1 P3 C5 -73.48(7) . . . . ? Cl1 Rh1 P3 C5 172.51(6) . . . . ? P1 Rh1 P3 C23 -124.82(7) . . . . ? P2 Rh1 P3 C23 166.41(7) . . . . ? Cl1 Rh1 P3 C23 52.40(7) . . . . ? P1 Rh1 P3 C29 109.99(6) . . . . ? P2 Rh1 P3 C29 41.23(7) . . . . ? Cl1 Rh1 P3 C29 -72.78(6) . . . . ? N2 P1 N1 C1 66.05(13) . . . . ? N3 P1 N1 C1 -179.93(12) . . . . ? Rh1 P1 N1 C1 -59.81(14) . . . . ? N2 P1 N1 C3 -142.54(13) . . . . ? N3 P1 N1 C3 -28.52(15) . . . . ? Rh1 P1 N1 C3 91.60(14) . . . . ? N1 P1 N2 C12 24.97(17) . . . . ? N3 P1 N2 C12 -80.65(17) . . . . ? Rh1 P1 N2 C12 160.15(14) . . . . ? N1 P1 N2 C5 -134.22(12) . . . . ? N3 P1 N2 C5 120.16(12) . . . . ? Rh1 P1 N2 C5 0.96(14) . . . . ? N1 P1 N3 C21 -67.85(17) . . . . ? N2 P1 N3 C21 36.96(18) . . . . ? Rh1 P1 N3 C21 159.05(15) . . . . ? N1 P1 N3 C14 97.35(12) . . . . ? N2 P1 N3 C14 -157.84(11) . . . . ? Rh1 P1 N3 C14 -35.74(12) . . . . ? C3 N1 C1 C2 -70.1(2) . . . . ? P1 N1 C1 C2 83.77(19) . . . . ? C1 N1 C3 C4 -82.7(2) . . . . ? P1 N1 C3 C4 125.58(18) . . . . ? C12 N2 C5 C6 3.16(19) . . . . ? P1 N2 C5 C6 167.31(12) . . . . ? C12 N2 C5 P3 -169.30(11) . . . . ? P1 N2 C5 P3 -5.15(17) . . . . ? C23 P3 C5 C6 -33.3(2) . . . . ? C29 P3 C5 C6 77.4(2) . . . . ? Rh1 P3 C5 C6 -163.52(17) . . . . ? C23 P3 C5 N2 136.92(12) . . . . ? C29 P3 C5 N2 -112.40(13) . . . . ? Rh1 P3 C5 N2 6.70(14) . . . . ? N2 C5 C6 C7 -1.5(2) . . . . ? P3 C5 C6 C7 169.08(15) . . . . ? N2 C5 C6 C13 -177.90(19) . . . . ? P3 C5 C6 C13 -7.3(3) . . . . ? C5 C6 C7 C8 -175.4(2) . . . . ? C13 C6 C7 C8 1.2(3) . . . . ? C5 C6 C7 C12 -0.7(2) . . . . ? C13 C6 C7 C12 175.92(18) . . . . ? C12 C7 C8 C9 -1.9(3) . . . . ? C6 C7 C8 C9 172.3(2) . . . . ? C7 C8 C9 C10 0.4(3) . . . . ? C8 C9 C10 C11 1.2(3) . . . . ? C9 C10 C11 C12 -1.2(3) . . . . ? C10 C11 C12 C7 -0.3(3) . . . . ? C10 C11 C12 N2 -175.41(18) . . . . ? C8 C7 C12 C11 1.9(3) . . . . ? C6 C7 C12 C11 -173.49(16) . . . . ? C8 C7 C12 N2 178.00(17) . . . . ? C6 C7 C12 N2 2.6(2) . . . . ? C5 N2 C12 C11 172.06(18) . . . . ? P1 N2 C12 C11 11.2(3) . . . . ? C5 N2 C12 C7 -3.49(19) . . . . ? P1 N2 C12 C7 -164.38(13) . . . . ? C21 N3 C14 C15 -1.07(18) . . . . ? P1 N3 C14 C15 -170.57(12) . . . . ? C21 N3 C14 P2 179.09(11) . . . . ? P1 N3 C14 P2 9.59(16) . . . . ? C35 P2 C14 C15 71.21(19) . . . . ? C41 P2 C14 C15 -38.9(2) . . . . ? Rh1 P2 C14 C15 -160.94(17) . . . . ? C35 P2 C14 N3 -109.00(13) . . . . ? C41 P2 C14 N3 140.92(12) . . . . ? Rh1 P2 C14 N3 18.85(13) . . . . ? N3 C14 C15 C16 0.67(19) . . . . ? P2 C14 C15 C16 -179.53(14) . . . . ? N3 C14 C15 C22 -176.71(17) . . . . ? P2 C14 C15 C22 3.1(3) . . . . ? C14 C15 C16 C17 -178.14(18) . . . . ? C22 C15 C16 C17 -0.6(3) . . . . ? C14 C15 C16 C21 -0.03(19) . . . . ? C22 C15 C16 C21 177.47(17) . . . . ? C21 C16 C17 C18 0.5(3) . . . . ? C15 C16 C17 C18 178.38(18) . . . . ? C16 C17 C18 C19 -1.7(3) . . . . ? C17 C18 C19 C20 1.1(3) . . . . ? C18 C19 C20 C21 0.8(3) . . . . ? C14 N3 C21 C20 176.84(17) . . . . ? P1 N3 C21 C20 -17.2(3) . . . . ? C14 N3 C21 C16 1.03(17) . . . . ? P1 N3 C21 C16 166.96(13) . . . . ? C19 C20 C21 N3 -177.38(17) . . . . ? C19 C20 C21 C16 -2.0(2) . . . . ? C17 C16 C21 N3 177.74(15) . . . . ? C15 C16 C21 N3 -0.63(18) . . . . ? C17 C16 C21 C20 1.5(2) . . . . ? C15 C16 C21 C20 -176.92(15) . . . . ? C5 P3 C23 C24 136.62(15) . . . . ? C29 P3 C23 C24 25.97(17) . . . . ? Rh1 P3 C23 C24 -102.19(15) . . . . ? C5 P3 C23 C28 -51.15(16) . . . . ? C29 P3 C23 C28 -161.80(14) . . . . ? Rh1 P3 C23 C28 70.04(15) . . . . ? C28 C23 C24 C25 1.0(3) . . . . ? P3 C23 C24 C25 173.20(16) . . . . ? C23 C24 C25 C26 0.4(3) . . . . ? C24 C25 C26 C27 -1.0(3) . . . . ? C25 C26 C27 C28 0.1(3) . . . . ? C26 C27 C28 C23 1.4(3) . . . . ? C24 C23 C28 C27 -1.9(3) . . . . ? P3 C23 C28 C27 -174.34(15) . . . . ? C5 P3 C29 C34 -17.79(18) . . . . ? C23 P3 C29 C34 92.61(16) . . . . ? Rh1 P3 C29 C34 -133.67(15) . . . . ? C5 P3 C29 C30 161.25(15) . . . . ? C23 P3 C29 C30 -88.35(16) . . . . ? Rh1 P3 C29 C30 45.37(16) . . . . ? C34 C29 C30 C31 -1.5(3) . . . . ? P3 C29 C30 C31 179.40(17) . . . . ? C29 C30 C31 C32 0.8(3) . . . . ? C30 C31 C32 C33 0.2(4) . . . . ? C31 C32 C33 C34 -0.5(4) . . . . ? C30 C29 C34 C33 1.3(3) . . . . ? P3 C29 C34 C33 -179.71(17) . . . . ? C32 C33 C34 C29 -0.2(3) . . . . ? C14 P2 C35 C40 -18.04(18) . . . . ? C41 P2 C35 C40 92.00(16) . . . . ? Rh1 P2 C35 C40 -134.88(14) . . . . ? C14 P2 C35 C36 161.34(14) . . . . ? C41 P2 C35 C36 -88.62(15) . . . . ? Rh1 P2 C35 C36 44.50(16) . . . . ? C40 C35 C36 C37 -1.7(3) . . . . ? P2 C35 C36 C37 178.90(18) . . . . ? C35 C36 C37 C38 2.2(4) . . . . ? C36 C37 C38 C39 -0.8(4) . . . . ? C37 C38 C39 C40 -1.0(3) . . . . ? C36 C35 C40 C39 -0.2(3) . . . . ? P2 C35 C40 C39 179.20(14) . . . . ? C38 C39 C40 C35 1.5(3) . . . . ? C14 P2 C41 C46 115.72(16) . . . . ? C35 P2 C41 C46 3.23(18) . . . . ? Rh1 P2 C41 C46 -131.94(15) . . . . ? C14 P2 C41 C42 -65.27(15) . . . . ? C35 P2 C41 C42 -177.76(14) . . . . ? Rh1 P2 C41 C42 47.07(15) . . . . ? C46 C41 C42 C43 -3.2(3) . . . . ? P2 C41 C42 C43 177.79(15) . . . . ? C41 C42 C43 C44 2.1(3) . . . . ? C42 C43 C44 C45 0.6(3) . . . . ? C43 C44 C45 C46 -2.3(4) . . . . ? C42 C41 C46 C45 1.5(3) . . . . ? P2 C41 C46 C45 -179.52(16) . . . . ? C44 C45 C46 C41 1.3(3) . . . . ? C106 C101 C102 C103 -0.1(3) . . . . ? C107 C101 C102 C103 -179.9(3) . . . . ? C101 C102 C103 C104 -0.1(3) . . . . ? C102 C103 C104 C105 0.1(6) . . . . ? C103 C104 C105 C106 0.1(8) . . . . ? C104 C105 C106 C101 -0.3(8) . . . . ? C102 C101 C106 C105 0.3(6) . . . . ? C107 C101 C106 C105 -179.9(4) . . . . ? C206 C201 C202 C203 -0.2(3) . . . . ? C207 C201 C202 C203 -179.8(3) . . . . ? C201 C202 C203 C204 0.0(3) . . . . ? C202 C203 C204 C205 -0.2(6) . . . . ? C203 C204 C205 C206 0.6(7) . . . . ? C202 C201 C206 C205 0.7(6) . . . . ? C207 C201 C206 C205 -179.7(4) . . . . ? C204 C205 C206 C201 -0.9(7) . . . . ? C306 C301 C302 C303 0.0(3) . . . . ? C307 C301 C302 C303 179.4(3) . . . . ? C301 C302 C303 C304 0.4(3) . . . . ? C302 C303 C304 C305 -1.4(7) . . . . ? C303 C304 C305 C306 2.0(9) . . . . ? C302 C301 C306 C305 0.5(6) . . . . ? C307 C301 C306 C305 -178.9(4) . . . . ? C304 C305 C306 C301 -1.4(7) . . . . ? _diffrn_measured_fraction_theta_max 0.982 _diffrn_reflns_theta_full 27.68 _diffrn_measured_fraction_theta_full 0.982 _refine_diff_density_max 0.565 _refine_diff_density_min -0.428 _refine_diff_density_rms 0.055 #===END