Additions and corrections


Interception of a Rh(I)–Rh(III) dinuclear trihydride complex revealing the dihydrogen activation by [Rh(CO)2{(R,R)-Ph–BPE}]+

Delphine Crozet, David McKay, Christian Bijani, Aitor Gual, Cyril Godard, Carmen Claver, Laurent Maron, Martine Urrutigoïty and Philippe Kalck

Dalton Trans., 2012, 41 (DOI: 10.1039/c2dt12400a). Amendment published 8th March 2012.


In the published version of the abstract of this paper there was an error in the formula of complexes 2 and 4, the corrected version of the abstract is shown below:

Reaction of [Rh(CO)2{(R,R)-Ph–BPE}][BF4] 1 under 7 bar H2 provides the dihydride [Rh(H)2(CO)2{(R,R)-Ph–BPE}][BF4] 3 which reacts with the neutral hydride [Rh(H)(CO)2{(R,R)-Ph–BPE}] 2 arising from 3 in THF. The resulting complex is the dimeric monocationic Rh(I)–Rh(III) complex [Rh2(μ-H)(μ-CO)(H)2(CO)2{(R,R)-Ph–BPE)}2][BF4] 4.


The Royal Society of Chemistry apologises for this error and any consequent inconvenience to authors and readers.


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