# Electronic Supplementary Material (ESI) for Dalton Transactions
# This journal is © The Royal Society of Chemistry 2012


data_global
_journal_name_full               'Dalton Trans.'
_journal_coden_cambridge         0222
_journal_year                    ?
_journal_volume                  ?
_journal_page_first              ?
_publ_contact_author_name        'Laguna, Antonio'
_publ_contact_author_email       alaguna@unizar.es
loop_
_publ_author_name
A.Laguna
O.Crespo
J.Camara
I.Koshevoy

data_c219s
_database_code_depnum_ccdc_archive 'CCDC 881805'
#TrackingRef '- c219s3.cif'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C48 H28 Au2 F10 P2'
_chemical_formula_weight         1250.58

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   P2(1)/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   10.766(2)
_cell_length_b                   22.498(4)
_cell_length_c                   8.4312(17)
_cell_angle_alpha                90.00
_cell_angle_beta                 94.22(3)
_cell_angle_gamma                90.00
_cell_volume                     2036.6(7)
_cell_formula_units_Z            2
_cell_measurement_temperature    130(2)
_cell_measurement_reflns_used    41533
_cell_measurement_theta_min      4.1799
_cell_measurement_theta_max      28.7748

_exptl_crystal_description       prism
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.21
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.039
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1188
_exptl_absorpt_coefficient_mu    7.356
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.1569
_exptl_absorpt_correction_T_max  0.3072
_exptl_absorpt_process_details   SADABS

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      130(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Xcalibur Oxford Diffraction'
_diffrn_measurement_method       '\w rotations'
_diffrn_detector_area_resol_mean 16.06
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            47659
_diffrn_reflns_av_R_equivalents  0.0262
_diffrn_reflns_av_sigmaI/netI    0.0110
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_theta_min         4.19
_diffrn_reflns_theta_max         26.00
_reflns_number_total             3994
_reflns_number_gt                3960
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Crysalis CCD'
_computing_cell_refinement       'Crysalis RED'
_computing_data_reduction        'Crysalis RED'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    XP
_computing_publication_material  XCIF

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0135P)^2^+3.5007P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         3994
_refine_ls_number_parameters     280
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0192
_refine_ls_R_factor_gt           0.0189
_refine_ls_wR_factor_ref         0.0461
_refine_ls_wR_factor_gt          0.0460
_refine_ls_goodness_of_fit_ref   1.350
_refine_ls_restrained_S_all      1.350
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.747309(11) 0.055270(5) 0.729921(13) 0.02001(5) Uani 1 1 d . . .
P1 P 0.66536(8) 0.11572(3) 0.53315(9) 0.01913(16) Uani 1 1 d . . .
F1 F 0.7716(2) -0.08570(10) 0.7504(2) 0.0369(5) Uani 1 1 d . . .
F2 F 0.8429(2) -0.15954(9) 0.9882(3) 0.0455(6) Uani 1 1 d . . .
F3 F 0.9290(2) -0.11545(10) 1.2779(3) 0.0395(5) Uani 1 1 d . . .
F4 F 0.9356(2) 0.00360(10) 1.3269(2) 0.0352(5) Uani 1 1 d . . .
F5 F 0.8633(2) 0.07888(9) 1.0890(2) 0.0323(5) Uani 1 1 d . . .
C1 C 0.8133(3) -0.00038(14) 0.9110(3) 0.0197(6) Uani 1 1 d . . .
C2 C 0.8106(3) -0.06104(15) 0.8929(4) 0.0256(7) Uani 1 1 d . . .
C3 C 0.8470(3) -0.10025(15) 1.0131(4) 0.0285(7) Uani 1 1 d . . .
C4 C 0.8900(3) -0.07823(16) 1.1599(4) 0.0277(7) Uani 1 1 d . . .
C5 C 0.8936(3) -0.01791(16) 1.1839(4) 0.0252(7) Uani 1 1 d . . .
C6 C 0.8552(3) 0.01979(14) 1.0594(4) 0.0226(6) Uani 1 1 d . . .
C11 C 0.7720(3) 0.17296(14) 0.4724(4) 0.0235(7) Uani 1 1 d . . .
C12 C 0.8786(3) 0.15268(17) 0.4040(4) 0.0325(8) Uani 1 1 d . . .
H12 H 0.8931 0.1112 0.3947 0.039 Uiso 1 1 calc R . .
C13 C 0.9633(4) 0.1931(2) 0.3494(5) 0.0421(10) Uani 1 1 d . . .
H13 H 1.0345 0.1793 0.3004 0.051 Uiso 1 1 calc R . .
C14 C 0.9437(4) 0.2529(2) 0.3665(5) 0.0431(10) Uani 1 1 d . . .
H14 H 1.0012 0.2804 0.3277 0.052 Uiso 1 1 calc R . .
C15 C 0.8421(4) 0.27366(18) 0.4389(5) 0.0416(10) Uani 1 1 d . . .
H15 H 0.8313 0.3152 0.4534 0.050 Uiso 1 1 calc R . .
C16 C 0.7540(3) 0.23337(16) 0.4915(4) 0.0312(8) Uani 1 1 d . . .
H16 H 0.6868 0.2487 0.5428 0.037 Uiso 1 1 d R . .
C21 C 0.5269(3) 0.15319(13) 0.5945(4) 0.0220(6) Uani 1 1 d . . .
C22 C 0.4105(3) 0.14706(16) 0.5135(4) 0.0295(7) Uani 1 1 d . . .
H22 H 0.4014 0.1241 0.4188 0.035 Uiso 1 1 calc R . .
C23 C 0.3072(4) 0.17453(19) 0.5711(5) 0.0410(9) Uani 1 1 d . . .
H23 H 0.2275 0.1699 0.5162 0.049 Uiso 1 1 calc R . .
C24 C 0.3200(4) 0.20856(19) 0.7081(5) 0.0427(9) Uani 1 1 d . . .
H24 H 0.2496 0.2282 0.7453 0.051 Uiso 1 1 calc R . .
C25 C 0.4348(4) 0.21397(18) 0.7905(5) 0.0417(9) Uani 1 1 d . . .
H25 H 0.4432 0.2366 0.8858 0.050 Uiso 1 1 calc R . .
C26 C 0.5377(4) 0.18640(16) 0.7344(4) 0.0318(8) Uani 1 1 d . . .
H26 H 0.6166 0.1901 0.7919 0.038 Uiso 1 1 calc R . .
C31 C 0.6149(3) 0.07711(14) 0.3506(3) 0.0200(6) Uani 1 1 d . . .
C32 C 0.6094(3) 0.01550(14) 0.3483(4) 0.0208(6) Uani 1 1 d . . .
H32 H 0.6364 -0.0063 0.4409 0.025 Uiso 1 1 calc R . .
C33 C 0.5646(3) -0.01459(14) 0.2115(4) 0.0213(6) Uani 1 1 d . . .
H33 H 0.5614 -0.0568 0.2121 0.026 Uiso 1 1 calc R . .
C34 C 0.5242(3) 0.01630(13) 0.0731(3) 0.0169(6) Uani 1 1 d . . .
C35 C 0.5327(4) 0.07792(15) 0.0765(4) 0.0293(8) Uani 1 1 d . . .
H35 H 0.5071 0.0999 -0.0165 0.035 Uiso 1 1 calc R . .
C36 C 0.5776(4) 0.10812(15) 0.2119(4) 0.0298(8) Uani 1 1 d . . .
H36 H 0.5830 0.1503 0.2104 0.036 Uiso 1 1 calc R . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Au1 0.02159(7) 0.02121(7) 0.01661(7) 0.00195(4) -0.00270(4) 0.00032(5)
P1 0.0242(4) 0.0168(4) 0.0155(3) -0.0001(3) -0.0042(3) -0.0025(3)
F1 0.0460(13) 0.0319(12) 0.0306(11) -0.0051(9) -0.0131(9) 0.0010(9)
F2 0.0637(16) 0.0220(11) 0.0483(13) 0.0036(9) -0.0115(11) 0.0040(10)
F3 0.0467(13) 0.0372(12) 0.0330(11) 0.0158(9) -0.0075(9) 0.0068(10)
F4 0.0431(12) 0.0418(12) 0.0192(10) -0.0006(8) -0.0079(8) 0.0044(10)
F5 0.0428(12) 0.0264(10) 0.0267(10) -0.0018(8) -0.0040(9) 0.0018(9)
C1 0.0156(14) 0.0246(16) 0.0188(14) 0.0048(12) 0.0010(11) 0.0003(12)
C2 0.0216(16) 0.0304(18) 0.0241(16) 0.0000(13) -0.0043(12) 0.0013(13)
C3 0.0294(18) 0.0214(16) 0.0340(18) 0.0032(14) -0.0014(14) 0.0017(14)
C4 0.0260(17) 0.0312(18) 0.0256(16) 0.0109(14) -0.0008(13) 0.0057(14)
C5 0.0204(16) 0.0354(19) 0.0194(15) 0.0015(13) -0.0009(12) 0.0016(13)
C6 0.0203(16) 0.0253(17) 0.0223(15) 0.0026(12) 0.0027(12) 0.0013(13)
C11 0.0269(17) 0.0251(16) 0.0170(14) 0.0016(12) -0.0077(12) -0.0059(13)
C12 0.0335(19) 0.035(2) 0.0286(17) -0.0018(14) -0.0008(14) -0.0072(15)
C13 0.033(2) 0.057(3) 0.035(2) 0.0003(18) -0.0008(16) -0.0116(19)
C14 0.042(2) 0.050(2) 0.036(2) 0.0101(18) -0.0087(17) -0.0241(19)
C15 0.052(3) 0.0276(19) 0.042(2) 0.0083(16) -0.0165(18) -0.0138(18)
C16 0.035(2) 0.0238(17) 0.0334(18) 0.0033(14) -0.0086(15) -0.0042(14)
C21 0.0267(17) 0.0146(14) 0.0244(15) 0.0026(12) -0.0005(12) -0.0008(12)
C22 0.0280(18) 0.0327(19) 0.0270(17) 0.0040(14) -0.0029(13) -0.0052(14)
C23 0.0257(19) 0.052(2) 0.045(2) 0.0125(19) -0.0017(16) -0.0001(17)
C24 0.037(2) 0.039(2) 0.053(2) 0.0038(18) 0.0144(18) 0.0074(18)
C25 0.047(2) 0.034(2) 0.045(2) -0.0135(17) 0.0068(18) 0.0054(18)
C26 0.0314(19) 0.0301(18) 0.0333(18) -0.0086(15) -0.0022(14) 0.0006(15)
C31 0.0226(16) 0.0199(15) 0.0170(14) -0.0016(11) -0.0017(11) -0.0030(12)
C32 0.0255(16) 0.0193(15) 0.0170(14) 0.0016(11) -0.0024(11) -0.0015(12)
C33 0.0250(16) 0.0177(15) 0.0205(15) 0.0007(11) -0.0019(12) -0.0010(12)
C34 0.0183(14) 0.0163(14) 0.0162(14) -0.0011(11) 0.0013(11) -0.0033(11)
C35 0.049(2) 0.0207(16) 0.0171(15) 0.0033(12) -0.0071(14) -0.0035(15)
C36 0.049(2) 0.0159(15) 0.0227(16) -0.0002(12) -0.0064(15) -0.0029(14)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C1 2.060(3) . ?
Au1 P1 2.2727(9) . ?
P1 C31 1.816(3) . ?
P1 C21 1.820(3) . ?
P1 C11 1.823(3) . ?
F1 C2 1.362(4) . ?
F2 C3 1.350(4) . ?
F3 C4 1.344(4) . ?
F4 C5 1.346(4) . ?
F5 C6 1.354(4) . ?
C1 C2 1.373(5) . ?
C1 C6 1.376(4) . ?
C2 C3 1.378(5) . ?
C3 C4 1.381(5) . ?
C4 C5 1.372(5) . ?
C5 C6 1.389(4) . ?
C11 C16 1.384(5) . ?
C11 C12 1.398(5) . ?
C12 C13 1.390(5) . ?
C12 H12 0.9500 . ?
C13 C14 1.372(6) . ?
C13 H13 0.9500 . ?
C14 C15 1.372(6) . ?
C14 H14 0.9500 . ?
C15 C16 1.407(5) . ?
C15 H15 0.9500 . ?
C16 H16 0.9360 . ?
C21 C22 1.390(5) . ?
C21 C26 1.394(5) . ?
C22 C23 1.391(5) . ?
C22 H22 0.9500 . ?
C23 C24 1.384(6) . ?
C23 H23 0.9500 . ?
C24 C25 1.378(6) . ?
C24 H24 0.9500 . ?
C25 C26 1.383(5) . ?
C25 H25 0.9500 . ?
C26 H26 0.9500 . ?
C31 C32 1.387(4) . ?
C31 C36 1.394(4) . ?
C32 C33 1.393(4) . ?
C32 H32 0.9500 . ?
C33 C34 1.399(4) . ?
C33 H33 0.9500 . ?
C34 C35 1.390(4) . ?
C34 C34 1.495(5) 3_655 ?
C35 C36 1.385(5) . ?
C35 H35 0.9500 . ?
C36 H36 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Au1 P1 177.33(8) . . ?
C31 P1 C21 105.20(15) . . ?
C31 P1 C11 104.79(14) . . ?
C21 P1 C11 107.35(15) . . ?
C31 P1 Au1 114.11(11) . . ?
C21 P1 Au1 110.59(10) . . ?
C11 P1 Au1 114.14(10) . . ?
C2 C1 C6 115.5(3) . . ?
C2 C1 Au1 121.3(2) . . ?
C6 C1 Au1 123.1(2) . . ?
F1 C2 C1 120.3(3) . . ?
F1 C2 C3 116.1(3) . . ?
C1 C2 C3 123.5(3) . . ?
F2 C3 C2 120.9(3) . . ?
F2 C3 C4 119.9(3) . . ?
C2 C3 C4 119.2(3) . . ?
F3 C4 C5 120.2(3) . . ?
F3 C4 C3 120.4(3) . . ?
C5 C4 C3 119.4(3) . . ?
F4 C5 C4 119.4(3) . . ?
F4 C5 C6 121.3(3) . . ?
C4 C5 C6 119.3(3) . . ?
F5 C6 C1 120.3(3) . . ?
F5 C6 C5 116.6(3) . . ?
C1 C6 C5 123.1(3) . . ?
C16 C11 C12 119.6(3) . . ?
C16 C11 P1 124.4(3) . . ?
C12 C11 P1 116.0(3) . . ?
C13 C12 C11 120.1(4) . . ?
C13 C12 H12 120.0 . . ?
C11 C12 H12 120.0 . . ?
C14 C13 C12 119.8(4) . . ?
C14 C13 H13 120.1 . . ?
C12 C13 H13 120.1 . . ?
C13 C14 C15 120.9(4) . . ?
C13 C14 H14 119.5 . . ?
C15 C14 H14 119.5 . . ?
C14 C15 C16 119.9(4) . . ?
C14 C15 H15 120.0 . . ?
C16 C15 H15 120.0 . . ?
C11 C16 C15 119.5(4) . . ?
C11 C16 H16 122.4 . . ?
C15 C16 H16 118.0 . . ?
C22 C21 C26 119.0(3) . . ?
C22 C21 P1 122.9(3) . . ?
C26 C21 P1 118.0(3) . . ?
C21 C22 C23 120.0(3) . . ?
C21 C22 H22 120.0 . . ?
C23 C22 H22 120.0 . . ?
C24 C23 C22 120.3(4) . . ?
C24 C23 H23 119.9 . . ?
C22 C23 H23 119.9 . . ?
C25 C24 C23 120.0(4) . . ?
C25 C24 H24 120.0 . . ?
C23 C24 H24 120.0 . . ?
C24 C25 C26 119.9(4) . . ?
C24 C25 H25 120.0 . . ?
C26 C25 H25 120.0 . . ?
C25 C26 C21 120.7(3) . . ?
C25 C26 H26 119.6 . . ?
C21 C26 H26 119.6 . . ?
C32 C31 C36 118.6(3) . . ?
C32 C31 P1 119.9(2) . . ?
C36 C31 P1 121.4(2) . . ?
C31 C32 C33 120.6(3) . . ?
C31 C32 H32 119.7 . . ?
C33 C32 H32 119.7 . . ?
C32 C33 C34 121.1(3) . . ?
C32 C33 H33 119.4 . . ?
C34 C33 H33 119.4 . . ?
C35 C34 C33 117.6(3) . . ?
C35 C34 C34 121.6(3) . 3_655 ?
C33 C34 C34 120.8(3) . 3_655 ?
C36 C35 C34 121.6(3) . . ?
C36 C35 H35 119.2 . . ?
C34 C35 H35 119.2 . . ?
C35 C36 C31 120.5(3) . . ?
C35 C36 H36 119.8 . . ?
C31 C36 H36 119.8 . . ?

_diffrn_measured_fraction_theta_max 0.995
_diffrn_reflns_theta_full        26.00
_diffrn_measured_fraction_theta_full 0.995
_refine_diff_density_max         0.945
_refine_diff_density_min         -0.397
_refine_diff_density_rms         0.081

# Attachment '- c220s3.cif'

data_c220s
_database_code_depnum_ccdc_archive 'CCDC 881806'
#TrackingRef '- c220s3.cif'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C94 H52 Au4 Cl4 F20 P4'
_chemical_formula_weight         2614.90

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.807(3)
_cell_length_b                   15.453(3)
_cell_length_c                   22.463(5)
_cell_angle_alpha                99.99(3)
_cell_angle_beta                 91.71(3)
_cell_angle_gamma                90.68(3)
_cell_volume                     4375.6(15)
_cell_formula_units_Z            2
_cell_measurement_temperature    130(2)
_cell_measurement_reflns_used    26544
_cell_measurement_theta_min      4.0829
_cell_measurement_theta_max      28.8983

_exptl_crystal_description       tablet
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.06
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.985
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2480
_exptl_absorpt_coefficient_mu    6.970
_exptl_absorpt_correction_type   Multi-scans
_exptl_absorpt_correction_T_min  0.3362
_exptl_absorpt_correction_T_max  0.6798
_exptl_absorpt_process_details   SADABS

_exptl_special_details           
;
A system of restraints to light-atom displacement-factor components was used.
The largest residual electron density in this complex is near the gold atoms.
This make that the structure should be interpreted with caution,
but we are confident that its main features are correct.
;

_diffrn_ambient_temperature      130(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Xcalibur Oxford Diffraction'
_diffrn_measurement_method       '\w rotations'
_diffrn_detector_area_resol_mean 16.06
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            106839
_diffrn_reflns_av_R_equivalents  0.0804
_diffrn_reflns_av_sigmaI/netI    0.0543
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_theta_min         4.12
_diffrn_reflns_theta_max         25.50
_reflns_number_total             16190
_reflns_number_gt                13257
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Crysalis CCD'
_computing_cell_refinement       'Crysalis RED'
_computing_data_reduction        'Crysalis RED'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    XP
_computing_publication_material  XCIF

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0709P)^2^+129.5874P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         16190
_refine_ls_number_parameters     1135
_refine_ls_number_restraints     208
_refine_ls_R_factor_all          0.0975
_refine_ls_R_factor_gt           0.0801
_refine_ls_wR_factor_ref         0.1975
_refine_ls_wR_factor_gt          0.1898
_refine_ls_goodness_of_fit_ref   1.180
_refine_ls_restrained_S_all      1.173
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au -0.07779(5) 0.14536(4) 0.23540(2) 0.02520(15) Uani 1 1 d . . .
Au2 Au 0.60739(4) 0.83747(4) 0.32100(3) 0.02599(15) Uani 1 1 d . . .
Au3 Au -0.06894(4) 0.33685(4) 0.31040(3) 0.02446(15) Uani 1 1 d . . .
Au4 Au 0.61286(5) 0.64854(4) 0.23372(3) 0.02626(15) Uani 1 1 d . . .
P1 P 0.0027(3) 0.1878(2) 0.15537(17) 0.0253(8) Uani 1 1 d . . .
P2 P 0.4620(3) 0.8113(2) 0.37147(17) 0.0235(8) Uani 1 1 d . . .
P3 P 0.0765(3) 0.3107(2) 0.36473(16) 0.0219(8) Uani 1 1 d . . .
P4 P 0.5172(3) 0.6935(3) 0.15725(18) 0.0303(9) Uani 1 1 d . . .
C1 C -0.1541(11) 0.1006(9) 0.3032(6) 0.021(3) Uani 1 1 d U . .
C2 C -0.2609(11) 0.1047(9) 0.3073(6) 0.022(3) Uani 1 1 d U . .
C3 C -0.3159(12) 0.0792(11) 0.3530(7) 0.032(3) Uani 1 1 d U . .
C4 C -0.2614(13) 0.0482(11) 0.3983(7) 0.035(3) Uani 1 1 d U . .
C5 C -0.1553(13) 0.0396(10) 0.3973(7) 0.029(3) Uani 1 1 d U . .
C6 C -0.1035(12) 0.0651(9) 0.3488(6) 0.025(3) Uani 1 1 d U . .
F1 F -0.3190(7) 0.1363(6) 0.2644(4) 0.038(2) Uani 1 1 d . . .
F2 F -0.4200(7) 0.0858(7) 0.3550(5) 0.044(2) Uani 1 1 d . . .
F3 F -0.3126(8) 0.0208(7) 0.4440(4) 0.047(3) Uani 1 1 d . . .
F4 F -0.0999(9) 0.0056(7) 0.4392(5) 0.052(3) Uani 1 1 d . . .
F5 F 0.0013(7) 0.0588(7) 0.3495(5) 0.046(3) Uani 1 1 d . . .
C11 C -0.0861(12) 0.2203(10) 0.1000(7) 0.028(3) Uani 1 1 d U . .
C12 C -0.0521(15) 0.2610(12) 0.0539(8) 0.040(4) Uani 1 1 d U . .
H12 H 0.0206 0.2710 0.0506 0.048 Uiso 1 1 calc R . .
C13 C -0.1207(15) 0.2874(12) 0.0128(8) 0.043(4) Uani 1 1 d U . .
H13 H -0.0944 0.3154 -0.0183 0.052 Uiso 1 1 calc R . .
C14 C -0.2236(16) 0.2745(14) 0.0156(8) 0.051(4) Uani 1 1 d U . .
H14 H -0.2697 0.2937 -0.0132 0.061 Uiso 1 1 calc R . .
C15 C -0.2647(14) 0.2320(13) 0.0619(9) 0.047(4) Uani 1 1 d U . .
H15 H -0.3376 0.2217 0.0643 0.057 Uiso 1 1 calc R . .
C16 C -0.1931(14) 0.2061(12) 0.1034(8) 0.040(4) Uani 1 1 d U . .
H16 H -0.2182 0.1781 0.1348 0.048 Uiso 1 1 calc R . .
C21 C 0.0881(13) 0.1065(10) 0.1142(6) 0.029(3) Uani 1 1 d U . .
C22 C 0.0426(17) 0.0290(11) 0.0847(8) 0.044(4) Uani 1 1 d U . .
H22 H -0.0310 0.0209 0.0853 0.053 Uiso 1 1 calc R . .
C23 C 0.104(2) -0.0379(13) 0.0540(9) 0.061(5) Uani 1 1 d U . .
H23 H 0.0725 -0.0907 0.0324 0.074 Uiso 1 1 calc R . .
C24 C 0.212(2) -0.0242(15) 0.0560(9) 0.065(5) Uani 1 1 d U . .
H24 H 0.2557 -0.0692 0.0364 0.078 Uiso 1 1 calc R . .
C25 C 0.2568(18) 0.0514(14) 0.0852(10) 0.059(5) Uani 1 1 d U . .
H25 H 0.3303 0.0596 0.0847 0.071 Uiso 1 1 calc R . .
C26 C 0.1963(15) 0.1177(12) 0.1163(8) 0.044(4) Uani 1 1 d U . .
H26 H 0.2282 0.1697 0.1385 0.052 Uiso 1 1 calc R . .
C27 C 0.0838(11) 0.2809(10) 0.1773(7) 0.025(3) Uani 1 1 d U . .
C28 C 0.1317(11) 0.3473(10) 0.1958(6) 0.024(3) Uani 1 1 d U . .
C31 C 0.1854(11) 0.4295(9) 0.2206(6) 0.022(3) Uani 1 1 d U . .
C32 C 0.1292(12) 0.4979(10) 0.2540(7) 0.030(3) Uani 1 1 d U . .
H32 H 0.0561 0.4917 0.2587 0.036 Uiso 1 1 calc R . .
C33 C 0.1812(12) 0.5738(9) 0.2798(7) 0.028(3) Uani 1 1 d U . .
H33 H 0.1443 0.6204 0.3028 0.033 Uiso 1 1 calc R . .
C34 C 0.2864(11) 0.5829(9) 0.2724(6) 0.022(3) Uani 1 1 d U . .
C35 C 0.3412(12) 0.5170(11) 0.2376(7) 0.031(3) Uani 1 1 d U . .
H35 H 0.4136 0.5247 0.2317 0.037 Uiso 1 1 calc R . .
C36 C 0.2908(12) 0.4412(10) 0.2118(7) 0.031(3) Uani 1 1 d U . .
H36 H 0.3281 0.3961 0.1876 0.037 Uiso 1 1 calc R . .
C37 C 0.3394(12) 0.6626(9) 0.3016(6) 0.024(3) Uani 1 1 d U . .
C38 C 0.3849(12) 0.7256(10) 0.3285(7) 0.026(3) Uani 1 1 d U . .
C41 C 0.4809(12) 0.7706(9) 0.4428(7) 0.026(3) Uani 1 1 d U . .
C42 C 0.4065(14) 0.7812(11) 0.4863(8) 0.037(3) Uani 1 1 d U . .
H42 H 0.3463 0.8147 0.4810 0.044 Uiso 1 1 calc R . .
C43 C 0.4180(15) 0.7437(11) 0.5375(8) 0.042(4) Uani 1 1 d U . .
H43 H 0.3666 0.7526 0.5675 0.050 Uiso 1 1 calc R . .
C44 C 0.5034(16) 0.6937(12) 0.5453(8) 0.044(4) Uani 1 1 d U . .
H44 H 0.5098 0.6663 0.5799 0.053 Uiso 1 1 calc R . .
C45 C 0.5795(14) 0.6832(11) 0.5031(9) 0.041(4) Uani 1 1 d U . .
H45 H 0.6396 0.6498 0.5088 0.050 Uiso 1 1 calc R . .
C46 C 0.5681(14) 0.7209(11) 0.4530(8) 0.038(3) Uani 1 1 d U . .
H46 H 0.6211 0.7132 0.4240 0.045 Uiso 1 1 calc R . .
C51 C 0.3722(12) 0.9004(9) 0.3889(6) 0.025(3) Uani 1 1 d U . .
C52 C 0.4129(13) 0.9818(10) 0.4201(7) 0.030(3) Uani 1 1 d U . .
H52 H 0.4857 0.9898 0.4292 0.036 Uiso 1 1 calc R . .
C53 C 0.3432(15) 1.0505(11) 0.4373(8) 0.041(4) Uani 1 1 d U . .
H53 H 0.3692 1.1055 0.4586 0.049 Uiso 1 1 calc R . .
C54 C 0.2420(15) 1.0398(11) 0.4244(8) 0.044(4) Uani 1 1 d U . .
H54 H 0.1969 1.0879 0.4352 0.052 Uiso 1 1 calc R . .
C55 C 0.2004(15) 0.9598(13) 0.3955(9) 0.046(4) Uani 1 1 d U . .
H55 H 0.1271 0.9517 0.3887 0.055 Uiso 1 1 calc R . .
C56 C 0.2679(13) 0.8918(10) 0.3767(7) 0.031(3) Uani 1 1 d U . .
H56 H 0.2404 0.8379 0.3548 0.037 Uiso 1 1 calc R . .
C61 C 0.7336(12) 0.8631(10) 0.2727(7) 0.026(3) Uani 1 1 d U . .
C62 C 0.8358(13) 0.8472(12) 0.2919(9) 0.039(4) Uani 1 1 d U . .
C63 C 0.9228(12) 0.8568(11) 0.2595(7) 0.031(3) Uani 1 1 d U . .
C64 C 0.9105(12) 0.8888(10) 0.2070(7) 0.032(3) Uani 1 1 d U . .
C65 C 0.8142(13) 0.9107(11) 0.1869(8) 0.034(3) Uani 1 1 d U . .
C66 C 0.7291(12) 0.8974(10) 0.2195(7) 0.029(3) Uani 1 1 d U . .
F6 F 0.8537(8) 0.8143(7) 0.3433(4) 0.042(2) Uani 1 1 d . . .
F7 F 1.0199(8) 0.8372(8) 0.2776(5) 0.053(3) Uani 1 1 d . . .
F8 F 0.9942(7) 0.8997(7) 0.1730(4) 0.042(2) Uani 1 1 d . . .
F9 F 0.8006(8) 0.9438(7) 0.1358(5) 0.046(3) Uani 1 1 d . . .
F10 F 0.6352(7) 0.9207(7) 0.2006(5) 0.046(3) Uani 1 1 d . . .
C71 C -0.2062(12) 0.3624(10) 0.2650(6) 0.025(3) Uani 1 1 d U . .
C72 C -0.3003(12) 0.3405(9) 0.2864(7) 0.026(3) Uani 1 1 d U . .
C73 C -0.3954(12) 0.3515(11) 0.2552(8) 0.033(3) Uani 1 1 d U . .
C74 C -0.3884(12) 0.3848(11) 0.2010(7) 0.033(3) Uani 1 1 d U . .
C75 C -0.2940(12) 0.4081(10) 0.1801(8) 0.032(3) Uani 1 1 d U . .
C76 C -0.2043(11) 0.3968(9) 0.2126(7) 0.024(3) Uani 1 1 d U . .
F11 F -0.3084(8) 0.3084(7) 0.3367(4) 0.043(2) Uani 1 1 d . . .
F12 F -0.4867(8) 0.3320(7) 0.2764(5) 0.045(2) Uani 1 1 d . . .
F13 F -0.4800(7) 0.3949(7) 0.1693(5) 0.046(3) Uani 1 1 d . . .
F14 F -0.2934(8) 0.4434(8) 0.1291(5) 0.052(3) Uani 1 1 d . . .
F15 F -0.1151(7) 0.4209(7) 0.1902(5) 0.044(2) Uani 1 1 d . . .
C77 C 0.1496(11) 0.2242(9) 0.3269(6) 0.022(3) Uani 1 1 d U . .
C78 C 0.1936(11) 0.1615(9) 0.3027(7) 0.026(3) Uani 1 1 d U . .
C81 C 0.0447(12) 0.2763(10) 0.4354(7) 0.026(3) Uani 1 1 d U . .
C82 C -0.0561(13) 0.2617(11) 0.4488(8) 0.036(4) Uani 1 1 d U . .
H82 H -0.1112 0.2713 0.4216 0.044 Uiso 1 1 calc R . .
C83 C -0.0791(15) 0.2323(12) 0.5030(9) 0.045(4) Uani 1 1 d U . .
H83 H -0.1496 0.2225 0.5124 0.054 Uiso 1 1 calc R . .
C84 C 0.0006(15) 0.2181(13) 0.5421(8) 0.045(4) Uani 1 1 d U . .
H84 H -0.0149 0.1987 0.5788 0.054 Uiso 1 1 calc R . .
C85 C 0.1027(15) 0.2316(12) 0.5283(8) 0.040(4) Uani 1 1 d U . .
H85 H 0.1575 0.2210 0.5554 0.048 Uiso 1 1 calc R . .
C86 C 0.1260(13) 0.2606(11) 0.4754(7) 0.036(3) Uani 1 1 d U . .
H86 H 0.1967 0.2700 0.4661 0.043 Uiso 1 1 calc R . .
C91 C 0.1724(12) 0.3998(9) 0.3859(6) 0.023(3) Uani 1 1 d U . .
C92 C 0.1421(14) 0.4758(11) 0.4227(7) 0.034(3) Uani 1 1 d U . .
H92 H 0.0721 0.4819 0.4354 0.041 Uiso 1 1 calc R . .
C93 C 0.2150(16) 0.5432(11) 0.4409(8) 0.041(4) Uani 1 1 d U . .
H93 H 0.1950 0.5946 0.4674 0.049 Uiso 1 1 calc R . .
C94 C 0.3169(16) 0.5365(12) 0.4209(10) 0.049(4) Uani 1 1 d U . .
H94 H 0.3655 0.5836 0.4331 0.059 Uiso 1 1 calc R . .
C95 C 0.3471(13) 0.4614(12) 0.3832(9) 0.044(4) Uani 1 1 d U . .
H95 H 0.4165 0.4560 0.3694 0.053 Uiso 1 1 calc R . .
C96 C 0.2726(13) 0.3923(11) 0.3657(8) 0.036(3) Uani 1 1 d U . .
H96 H 0.2922 0.3403 0.3396 0.043 Uiso 1 1 calc R . .
C101 C 0.7002(12) 0.6011(10) 0.3007(7) 0.027(3) Uani 1 1 d U . .
C102 C 0.8092(11) 0.6098(9) 0.3062(6) 0.023(3) Uani 1 1 d U . .
C103 C 0.8663(12) 0.5808(11) 0.3507(7) 0.031(3) Uani 1 1 d U . .
C104 C 0.8133(14) 0.5387(11) 0.3937(8) 0.038(3) Uani 1 1 d U . .
C105 C 0.7097(13) 0.5276(10) 0.3877(7) 0.033(3) Uani 1 1 d U . .
C106 C 0.6538(12) 0.5591(10) 0.3409(7) 0.029(3) Uani 1 1 d U . .
F16 F 0.8619(8) 0.6472(6) 0.2643(4) 0.038(2) Uani 1 1 d . . .
F17 F 0.9694(7) 0.5914(7) 0.3542(4) 0.044(3) Uani 1 1 d . . .
F18 F 0.8704(8) 0.5094(8) 0.4349(4) 0.049(3) Uani 1 1 d . . .
F19 F 0.6599(9) 0.4866(7) 0.4272(5) 0.052(3) Uani 1 1 d . . .
F20 F 0.5488(7) 0.5455(7) 0.3385(5) 0.043(2) Uani 1 1 d . . .
C107 C 0.4402(11) 0.7843(10) 0.1804(7) 0.028(3) Uani 1 1 d U . .
C108 C 0.3950(12) 0.8469(10) 0.1986(7) 0.030(3) Uani 1 1 d U . .
C111 C 0.3419(12) 0.9283(9) 0.2245(6) 0.024(3) Uani 1 1 d U . .
C112 C 0.4007(12) 0.9981(10) 0.2570(7) 0.030(3) Uani 1 1 d U . .
H112 H 0.4742 0.9928 0.2616 0.036 Uiso 1 1 calc R . .
C113 C 0.3540(12) 1.0745(10) 0.2824(8) 0.034(3) Uani 1 1 d U . .
H113 H 0.3946 1.1217 0.3048 0.041 Uiso 1 1 calc R . .
C114 C 0.2458(11) 1.0823(9) 0.2750(6) 0.021(3) Uani 1 1 d U . .
C115 C 0.1864(12) 1.0148(10) 0.2416(7) 0.030(3) Uani 1 1 d U . .
H115 H 0.1133 1.0212 0.2359 0.036 Uiso 1 1 calc R . .
C116 C 0.2356(12) 0.9353(9) 0.2156(7) 0.028(3) Uani 1 1 d U . .
H116 H 0.1958 0.8881 0.1927 0.033 Uiso 1 1 calc R . .
C121 C 0.6044(14) 0.7280(11) 0.0991(7) 0.035(3) Uani 1 1 d U . .
C122 C 0.7061(15) 0.7135(13) 0.1023(8) 0.045(4) Uani 1 1 d U . .
H122 H 0.7348 0.6852 0.1332 0.054 Uiso 1 1 calc R . .
C123 C 0.7711(17) 0.7407(15) 0.0592(10) 0.060(5) Uani 1 1 d U . .
H123 H 0.8445 0.7333 0.0616 0.072 Uiso 1 1 calc R . .
C124 C 0.7277(17) 0.7772(12) 0.0147(10) 0.053(5) Uani 1 1 d U . .
H124 H 0.7710 0.7942 -0.0151 0.064 Uiso 1 1 calc R . .
C125 C 0.6208(18) 0.7907(12) 0.0112(9) 0.052(4) Uani 1 1 d U . .
H125 H 0.5920 0.8169 -0.0207 0.062 Uiso 1 1 calc R . .
C126 C 0.5553(16) 0.7660(14) 0.0545(8) 0.049(4) Uani 1 1 d U . .
H126 H 0.4820 0.7747 0.0533 0.058 Uiso 1 1 calc R . .
C131 C 0.4280(13) 0.6102(10) 0.1156(7) 0.029(3) Uani 1 1 d U . .
C132 C 0.4699(16) 0.5329(11) 0.0860(8) 0.042(4) Uani 1 1 d U . .
H132 H 0.5432 0.5241 0.0870 0.050 Uiso 1 1 calc R . .
C133 C 0.4024(17) 0.4686(12) 0.0549(9) 0.048(4) Uani 1 1 d U . .
H133 H 0.4308 0.4155 0.0344 0.057 Uiso 1 1 calc R . .
C134 C 0.2952(18) 0.4788(12) 0.0527(9) 0.053(5) Uani 1 1 d U . .
H134 H 0.2504 0.4339 0.0311 0.063 Uiso 1 1 calc R . .
C135 C 0.2557(17) 0.5557(13) 0.0824(10) 0.058(5) Uani 1 1 d U . .
H135 H 0.1825 0.5645 0.0812 0.069 Uiso 1 1 calc R . .
C136 C 0.3213(14) 0.6211(12) 0.1143(8) 0.040(4) Uani 1 1 d U . .
H136 H 0.2924 0.6736 0.1353 0.048 Uiso 1 1 calc R . .
Cl1 Cl 0.4978(6) 0.1766(4) 0.1531(3) 0.0834(19) Uani 1 1 d . . .
Cl2 Cl 0.5645(6) 0.0291(5) 0.0662(3) 0.086(2) Uani 1 1 d . . .
C140 C 0.551(2) 0.0750(15) 0.1393(10) 0.065(6) Uani 1 1 d . . .
H14A H 0.6205 0.0784 0.1598 0.078 Uiso 1 1 calc R . .
H14B H 0.5067 0.0349 0.1582 0.078 Uiso 1 1 calc R . .
Cl3 Cl 0.9424(6) 0.5352(4) 0.0663(3) 0.0757(17) Uani 1 1 d . . .
Cl4 Cl 1.0213(6) 0.6851(4) 0.1507(3) 0.0729(17) Uani 1 1 d . . .
C141 C 0.962(2) 0.5806(15) 0.1390(10) 0.069(7) Uani 1 1 d . . .
H14C H 1.0069 0.5412 0.1588 0.083 Uiso 1 1 calc R . .
H14D H 0.8944 0.5847 0.1590 0.083 Uiso 1 1 calc R . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Au1 0.0328(3) 0.0195(3) 0.0229(3) 0.0020(2) 0.0060(2) -0.0040(2)
Au2 0.0276(3) 0.0209(3) 0.0288(3) 0.0017(2) 0.0068(2) -0.0038(2)
Au3 0.0254(3) 0.0199(3) 0.0271(3) 0.0014(2) -0.0010(2) 0.0046(2)
Au4 0.0321(3) 0.0203(3) 0.0256(3) 0.0019(2) -0.0013(2) 0.0058(2)
P1 0.037(2) 0.0187(19) 0.0200(18) 0.0014(15) 0.0061(15) -0.0061(16)
P2 0.0281(19) 0.0187(18) 0.0227(19) 0.0007(15) 0.0031(15) -0.0046(15)
P3 0.0258(19) 0.0174(18) 0.0222(18) 0.0020(14) 0.0008(14) 0.0050(14)
P4 0.039(2) 0.024(2) 0.024(2) -0.0053(16) 0.0033(17) 0.0086(17)
C1 0.025(4) 0.017(4) 0.018(4) -0.003(4) 0.004(4) 0.002(4)
C2 0.028(6) 0.015(7) 0.021(6) 0.003(5) -0.007(5) 0.000(5)
C3 0.023(7) 0.034(9) 0.038(8) 0.004(7) 0.006(5) -0.006(6)
C4 0.043(7) 0.034(9) 0.031(8) 0.008(7) 0.015(6) 0.000(7)
C5 0.040(7) 0.023(8) 0.024(7) 0.002(6) 0.001(6) -0.001(6)
C6 0.030(7) 0.021(7) 0.023(7) 0.002(5) 0.004(5) 0.007(6)
F1 0.028(5) 0.044(6) 0.043(6) 0.011(4) -0.009(4) -0.001(4)
F2 0.032(5) 0.054(7) 0.047(6) 0.009(5) 0.001(4) -0.007(5)
F3 0.051(6) 0.059(7) 0.034(5) 0.018(5) 0.009(5) -0.009(5)
F4 0.060(7) 0.052(7) 0.054(7) 0.035(6) -0.004(5) 0.010(5)
F5 0.030(5) 0.058(7) 0.055(6) 0.025(5) 0.006(4) 0.013(5)
C11 0.035(5) 0.022(5) 0.027(5) 0.007(4) 0.000(4) 0.002(4)
C12 0.045(8) 0.039(10) 0.042(10) 0.023(8) 0.001(7) -0.006(8)
C13 0.059(9) 0.037(10) 0.038(9) 0.020(7) -0.001(7) 0.000(8)
C14 0.057(8) 0.059(13) 0.035(9) 0.011(8) -0.017(8) -0.002(9)
C15 0.033(8) 0.055(12) 0.054(11) 0.010(8) -0.006(7) -0.002(8)
C16 0.041(7) 0.042(10) 0.041(9) 0.016(8) 0.000(7) -0.002(8)
C21 0.052(7) 0.021(7) 0.016(7) 0.008(5) 0.012(6) 0.005(6)
C22 0.066(10) 0.031(8) 0.035(9) 0.006(7) -0.006(8) 0.004(7)
C23 0.108(12) 0.027(9) 0.046(11) -0.006(8) 0.010(11) 0.004(9)
C24 0.106(12) 0.053(10) 0.036(11) -0.003(8) 0.040(11) 0.025(10)
C25 0.062(10) 0.049(11) 0.072(14) 0.017(9) 0.040(10) 0.011(7)
C26 0.058(8) 0.029(8) 0.048(11) 0.014(7) 0.023(8) 0.001(7)
C27 0.029(8) 0.021(7) 0.026(8) 0.005(6) 0.001(6) -0.006(5)
C28 0.028(7) 0.024(6) 0.019(7) 0.003(5) 0.002(6) -0.002(5)
C31 0.028(6) 0.016(6) 0.024(7) 0.006(5) -0.007(5) 0.001(5)
C32 0.026(7) 0.028(7) 0.033(8) -0.003(6) -0.002(6) -0.001(5)
C33 0.034(6) 0.011(6) 0.037(8) 0.000(5) 0.005(6) 0.006(5)
C34 0.028(6) 0.019(6) 0.021(7) 0.011(5) -0.002(5) 0.001(5)
C35 0.021(6) 0.036(8) 0.031(8) -0.004(6) 0.000(6) -0.003(5)
C36 0.032(6) 0.021(7) 0.041(9) 0.005(6) 0.004(6) 0.001(5)
C37 0.039(8) 0.013(6) 0.025(7) 0.013(5) -0.001(6) 0.002(5)
C38 0.031(8) 0.022(7) 0.025(8) 0.006(6) 0.006(6) -0.002(6)
C41 0.033(7) 0.013(7) 0.032(7) 0.005(6) -0.003(5) -0.008(5)
C42 0.039(8) 0.028(9) 0.043(9) 0.007(7) 0.001(6) 0.009(7)
C43 0.061(10) 0.031(9) 0.037(8) 0.013(7) 0.012(8) 0.007(7)
C44 0.062(11) 0.038(10) 0.035(9) 0.015(8) -0.006(7) 0.001(8)
C45 0.041(9) 0.029(9) 0.055(10) 0.010(7) -0.011(7) 0.004(7)
C46 0.044(9) 0.032(9) 0.036(8) -0.001(7) 0.005(7) 0.006(7)
C51 0.041(7) 0.019(6) 0.018(7) 0.007(5) 0.004(6) -0.001(6)
C52 0.039(7) 0.025(7) 0.027(8) 0.003(6) -0.001(6) -0.002(5)
C53 0.063(8) 0.021(7) 0.038(9) 0.000(7) 0.018(8) -0.001(6)
C54 0.059(8) 0.023(7) 0.055(11) 0.020(7) 0.005(8) 0.026(7)
C55 0.044(9) 0.047(9) 0.050(11) 0.016(8) -0.005(8) 0.010(6)
C56 0.045(7) 0.026(7) 0.020(7) -0.002(6) 0.003(6) -0.008(6)
C61 0.029(6) 0.023(8) 0.028(7) 0.008(6) 0.011(6) 0.001(6)
C62 0.029(7) 0.035(9) 0.056(10) 0.016(8) -0.004(6) -0.004(7)
C63 0.022(6) 0.031(9) 0.036(8) 0.000(6) -0.007(6) 0.002(6)
C64 0.032(6) 0.025(8) 0.034(7) -0.009(6) 0.001(6) -0.007(6)
C65 0.036(7) 0.030(9) 0.039(9) 0.017(7) 0.000(6) -0.013(7)
C66 0.029(7) 0.032(9) 0.022(7) -0.003(6) 0.000(5) -0.003(6)
F6 0.058(6) 0.053(6) 0.016(4) 0.011(4) -0.003(4) 0.002(5)
F7 0.030(5) 0.084(9) 0.047(6) 0.017(6) -0.002(4) -0.001(5)
F8 0.033(5) 0.049(6) 0.044(6) 0.006(5) 0.013(4) -0.008(4)
F9 0.040(6) 0.060(7) 0.045(6) 0.028(5) -0.001(4) -0.006(5)
F10 0.027(5) 0.049(6) 0.068(7) 0.029(5) 0.004(5) 0.007(4)
C71 0.033(6) 0.025(8) 0.016(6) -0.001(5) 0.001(5) -0.003(6)
C72 0.032(7) 0.006(6) 0.041(8) 0.003(6) 0.007(5) 0.007(5)
C73 0.030(7) 0.029(8) 0.040(8) 0.001(6) 0.011(6) 0.012(6)
C74 0.024(6) 0.040(10) 0.033(8) -0.002(6) -0.009(6) 0.002(7)
C75 0.026(7) 0.027(8) 0.047(9) 0.016(7) -0.002(6) 0.010(6)
C76 0.023(4) 0.020(5) 0.030(5) 0.009(4) -0.001(4) 0.004(4)
F11 0.044(6) 0.043(6) 0.041(6) 0.003(5) 0.006(4) 0.006(5)
F12 0.036(5) 0.043(6) 0.058(7) 0.010(5) 0.010(5) 0.002(5)
F13 0.028(5) 0.053(7) 0.061(7) 0.020(5) -0.005(5) 0.013(5)
F14 0.047(6) 0.058(7) 0.055(7) 0.020(6) -0.005(5) 0.013(5)
F15 0.029(5) 0.052(6) 0.054(6) 0.019(5) -0.001(4) -0.007(4)
C77 0.030(8) 0.015(6) 0.021(7) -0.001(5) -0.002(6) 0.002(5)
C78 0.024(7) 0.017(7) 0.037(9) 0.003(6) 0.001(6) 0.001(5)
C81 0.036(7) 0.020(7) 0.023(7) 0.003(6) 0.004(5) -0.001(6)
C82 0.031(7) 0.041(10) 0.035(8) 0.001(7) 0.005(6) -0.006(7)
C83 0.039(8) 0.043(11) 0.057(10) 0.018(9) 0.016(7) 0.001(8)
C84 0.053(9) 0.051(11) 0.027(8) -0.003(7) 0.010(6) -0.004(9)
C85 0.050(7) 0.040(10) 0.034(8) 0.018(7) -0.006(7) 0.009(8)
C86 0.037(7) 0.040(10) 0.032(8) 0.010(7) 0.000(6) -0.002(7)
C91 0.035(7) 0.015(6) 0.020(7) 0.006(5) -0.003(6) -0.001(5)
C92 0.048(8) 0.030(8) 0.024(8) 0.001(6) 0.002(7) 0.002(6)
C93 0.072(10) 0.018(7) 0.031(9) 0.005(6) -0.007(7) -0.008(7)
C94 0.054(8) 0.025(8) 0.072(13) 0.020(7) -0.026(8) -0.012(7)
C95 0.026(7) 0.036(8) 0.075(13) 0.027(8) -0.009(7) -0.002(6)
C96 0.032(7) 0.028(8) 0.050(10) 0.016(7) 0.001(7) 0.001(6)
C101 0.026(4) 0.023(5) 0.033(5) 0.007(4) 0.000(4) 0.004(4)
C102 0.033(6) 0.016(7) 0.017(6) -0.008(5) 0.007(5) 0.003(5)
C103 0.027(7) 0.030(9) 0.032(8) -0.008(6) -0.003(5) 0.008(6)
C104 0.044(7) 0.031(9) 0.037(9) 0.002(6) -0.002(6) 0.019(7)
C105 0.045(7) 0.018(8) 0.039(8) 0.010(6) 0.006(7) 0.006(7)
C106 0.032(7) 0.016(7) 0.039(8) 0.006(6) 0.002(6) 0.000(6)
F16 0.044(6) 0.037(5) 0.034(5) 0.007(4) 0.010(4) 0.000(4)
F17 0.022(5) 0.065(7) 0.043(6) 0.005(5) -0.002(4) 0.005(5)
F18 0.050(6) 0.064(7) 0.036(6) 0.021(5) -0.006(5) 0.000(5)
F19 0.061(7) 0.054(7) 0.049(6) 0.029(5) 0.011(5) -0.007(5)
F20 0.029(5) 0.046(6) 0.055(6) 0.013(5) -0.002(4) -0.003(4)
C107 0.024(8) 0.030(8) 0.030(8) 0.006(6) -0.008(6) 0.010(6)
C108 0.037(8) 0.022(7) 0.027(8) -0.002(6) -0.004(6) 0.004(6)
C111 0.032(6) 0.017(6) 0.025(7) 0.004(5) 0.008(6) 0.004(5)
C112 0.027(7) 0.026(7) 0.032(8) -0.003(6) -0.004(6) 0.006(5)
C113 0.028(6) 0.023(7) 0.048(10) -0.002(6) 0.008(7) 0.002(6)
C114 0.029(6) 0.014(6) 0.018(7) -0.003(5) 0.001(5) 0.005(5)
C115 0.030(7) 0.023(7) 0.032(8) -0.010(6) 0.004(6) 0.002(5)
C116 0.035(6) 0.009(6) 0.036(8) -0.002(6) 0.002(6) -0.002(5)
C121 0.047(7) 0.027(8) 0.033(8) 0.010(6) 0.003(7) 0.004(7)
C122 0.051(8) 0.056(12) 0.029(8) 0.007(7) 0.001(7) 0.018(9)
C123 0.053(10) 0.057(13) 0.073(14) 0.020(10) 0.020(9) 0.018(10)
C124 0.070(9) 0.034(10) 0.062(12) 0.021(9) 0.023(9) -0.004(9)
C125 0.078(10) 0.034(10) 0.048(10) 0.021(8) 0.011(9) 0.011(10)
C126 0.051(9) 0.055(12) 0.042(10) 0.017(8) -0.003(7) 0.009(9)
C131 0.041(7) 0.025(7) 0.021(7) 0.004(6) -0.004(6) 0.002(6)
C132 0.058(9) 0.031(8) 0.034(9) 0.000(7) 0.000(7) 0.005(6)
C133 0.073(10) 0.022(8) 0.047(11) 0.005(7) -0.002(9) -0.002(7)
C134 0.078(9) 0.029(8) 0.050(11) 0.011(7) -0.028(10) -0.002(8)
C135 0.059(10) 0.035(9) 0.077(15) 0.007(9) -0.031(10) -0.001(7)
C136 0.045(8) 0.033(8) 0.041(10) 0.003(7) -0.016(7) 0.007(7)
Cl1 0.110(5) 0.060(4) 0.075(4) 0.003(3) -0.003(4) -0.015(4)
Cl2 0.108(5) 0.070(4) 0.074(4) -0.001(3) 0.000(4) 0.011(4)
C140 0.081(16) 0.055(14) 0.052(13) -0.006(10) -0.016(11) 0.004(12)
Cl3 0.098(5) 0.065(4) 0.061(4) 0.002(3) 0.006(3) -0.007(3)
Cl4 0.113(5) 0.049(3) 0.055(3) 0.002(3) 0.014(3) 0.012(3)
C141 0.094(18) 0.056(14) 0.060(14) 0.016(11) 0.019(13) 0.003(13)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C1 2.048(14) . ?
Au1 P1 2.287(4) . ?
Au1 Au3 3.1399(12) . ?
Au2 C61 2.046(14) . ?
Au2 P2 2.277(4) . ?
Au2 Au4 3.2249(13) . ?
Au3 C71 2.082(15) . ?
Au3 P3 2.275(4) . ?
Au4 C101 2.087(15) . ?
Au4 P4 2.289(4) . ?
P1 C27 1.755(14) . ?
P1 C11 1.799(16) . ?
P1 C21 1.823(15) . ?
P2 C38 1.768(15) . ?
P2 C51 1.803(15) . ?
P2 C41 1.830(15) . ?
P3 C77 1.752(14) . ?
P3 C81 1.815(15) . ?
P3 C91 1.824(15) . ?
P4 C107 1.739(15) . ?
P4 C131 1.823(16) . ?
P4 C121 1.884(17) . ?
C1 C2 1.37(2) . ?
C1 C6 1.39(2) . ?
C2 F1 1.360(16) . ?
C2 C3 1.37(2) . ?
C3 F2 1.339(18) . ?
C3 C4 1.37(2) . ?
C4 F3 1.360(18) . ?
C4 C5 1.37(2) . ?
C5 F4 1.345(18) . ?
C5 C6 1.40(2) . ?
C6 F5 1.346(17) . ?
C11 C12 1.38(2) . ?
C11 C16 1.39(2) . ?
C12 C13 1.37(2) . ?
C13 C14 1.34(3) . ?
C14 C15 1.43(3) . ?
C15 C16 1.40(3) . ?
C21 C22 1.38(2) . ?
C21 C26 1.39(2) . ?
C22 C23 1.40(3) . ?
C23 C24 1.41(3) . ?
C24 C25 1.35(3) . ?
C25 C26 1.39(3) . ?
C27 C28 1.19(2) . ?
C28 C31 1.45(2) . ?
C31 C36 1.38(2) . ?
C31 C32 1.41(2) . ?
C32 C33 1.37(2) . ?
C33 C34 1.37(2) . ?
C34 C35 1.38(2) . ?
C34 C37 1.44(2) . ?
C35 C36 1.36(2) . ?
C37 C38 1.19(2) . ?
C41 C42 1.38(2) . ?
C41 C46 1.40(2) . ?
C42 C43 1.38(2) . ?
C43 C44 1.37(3) . ?
C44 C45 1.37(3) . ?
C45 C46 1.36(2) . ?
C51 C56 1.36(2) . ?
C51 C52 1.42(2) . ?
C52 C53 1.41(2) . ?
C53 C54 1.32(3) . ?
C54 C55 1.39(3) . ?
C55 C56 1.38(2) . ?
C61 C66 1.39(2) . ?
C61 C62 1.40(2) . ?
C62 F6 1.35(2) . ?
C62 C63 1.37(2) . ?
C63 F7 1.352(18) . ?
C63 C64 1.36(2) . ?
C64 F8 1.361(18) . ?
C64 C65 1.37(2) . ?
C65 F9 1.344(18) . ?
C65 C66 1.36(2) . ?
C66 F10 1.338(18) . ?
C71 C72 1.37(2) . ?
C71 C76 1.37(2) . ?
C72 F11 1.317(18) . ?
C72 C73 1.41(2) . ?
C73 F12 1.327(18) . ?
C73 C74 1.41(2) . ?
C74 C75 1.38(2) . ?
C74 F13 1.378(18) . ?
C75 F14 1.351(19) . ?
C75 C76 1.37(2) . ?
C76 F15 1.336(17) . ?
C77 C78 1.18(2) . ?
C78 C114 1.454(19) 1_545 ?
C81 C82 1.36(2) . ?
C81 C86 1.41(2) . ?
C82 C83 1.41(2) . ?
C83 C84 1.37(3) . ?
C84 C85 1.37(3) . ?
C85 C86 1.38(2) . ?
C91 C96 1.37(2) . ?
C91 C92 1.38(2) . ?
C92 C93 1.39(2) . ?
C93 C94 1.39(3) . ?
C94 C95 1.38(3) . ?
C95 C96 1.42(2) . ?
C101 C106 1.35(2) . ?
C101 C102 1.40(2) . ?
C102 C103 1.36(2) . ?
C102 F16 1.375(17) . ?
C103 F17 1.326(18) . ?
C103 C104 1.44(2) . ?
C104 F18 1.308(19) . ?
C104 C105 1.34(2) . ?
C105 F19 1.348(18) . ?
C105 C106 1.41(2) . ?
C106 F20 1.356(18) . ?
C107 C108 1.15(2) . ?
C108 C111 1.47(2) . ?
C111 C116 1.38(2) . ?
C111 C112 1.39(2) . ?
C112 C113 1.37(2) . ?
C113 C114 1.40(2) . ?
C114 C115 1.38(2) . ?
C114 C78 1.454(19) 1_565 ?
C115 C116 1.43(2) . ?
C121 C122 1.33(2) . ?
C121 C126 1.39(2) . ?
C122 C123 1.41(3) . ?
C123 C124 1.34(3) . ?
C124 C125 1.39(3) . ?
C125 C126 1.40(3) . ?
C131 C136 1.38(2) . ?
C131 C132 1.38(2) . ?
C132 C133 1.39(3) . ?
C133 C134 1.38(3) . ?
C134 C135 1.37(3) . ?
C135 C136 1.39(3) . ?
Cl1 C140 1.70(2) . ?
Cl2 C140 1.69(2) . ?
Cl3 C141 1.67(2) . ?
Cl4 C141 1.75(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Au1 P1 176.3(4) . . ?
C1 Au1 Au3 90.8(4) . . ?
P1 Au1 Au3 92.58(10) . . ?
C61 Au2 P2 177.3(4) . . ?
C61 Au2 Au4 82.8(4) . . ?
P2 Au2 Au4 97.12(10) . . ?
C71 Au3 P3 176.9(4) . . ?
C71 Au3 Au1 88.4(4) . . ?
P3 Au3 Au1 93.21(10) . . ?
C101 Au4 P4 177.0(4) . . ?
C101 Au4 Au2 89.0(4) . . ?
P4 Au4 Au2 93.95(10) . . ?
C27 P1 C11 103.4(7) . . ?
C27 P1 C21 104.1(7) . . ?
C11 P1 C21 106.5(7) . . ?
C27 P1 Au1 112.5(5) . . ?
C11 P1 Au1 114.0(5) . . ?
C21 P1 Au1 115.2(5) . . ?
C38 P2 C51 104.0(7) . . ?
C38 P2 C41 101.4(7) . . ?
C51 P2 C41 104.4(7) . . ?
C38 P2 Au2 110.6(5) . . ?
C51 P2 Au2 117.1(5) . . ?
C41 P2 Au2 117.5(5) . . ?
C77 P3 C81 104.3(7) . . ?
C77 P3 C91 103.8(7) . . ?
C81 P3 C91 104.9(7) . . ?
C77 P3 Au3 112.3(5) . . ?
C81 P3 Au3 112.1(5) . . ?
C91 P3 Au3 118.1(5) . . ?
C107 P4 C131 105.1(7) . . ?
C107 P4 C121 104.7(8) . . ?
C131 P4 C121 105.8(7) . . ?
C107 P4 Au4 114.4(5) . . ?
C131 P4 Au4 114.6(5) . . ?
C121 P4 Au4 111.4(6) . . ?
C2 C1 C6 114.8(13) . . ?
C2 C1 Au1 121.7(10) . . ?
C6 C1 Au1 123.5(10) . . ?
F1 C2 C3 115.7(13) . . ?
F1 C2 C1 120.0(12) . . ?
C3 C2 C1 124.3(13) . . ?
F2 C3 C4 119.9(14) . . ?
F2 C3 C2 121.7(15) . . ?
C4 C3 C2 118.4(14) . . ?
F3 C4 C5 118.0(15) . . ?
F3 C4 C3 120.5(15) . . ?
C5 C4 C3 121.4(14) . . ?
F4 C5 C4 123.1(14) . . ?
F4 C5 C6 119.2(14) . . ?
C4 C5 C6 117.7(14) . . ?
F5 C6 C1 119.8(13) . . ?
F5 C6 C5 116.8(13) . . ?
C1 C6 C5 123.3(14) . . ?
C12 C11 C16 117.7(15) . . ?
C12 C11 P1 122.2(13) . . ?
C16 C11 P1 120.1(12) . . ?
C13 C12 C11 121.7(17) . . ?
C14 C13 C12 121.3(17) . . ?
C13 C14 C15 120.2(17) . . ?
C16 C15 C14 117.3(17) . . ?
C11 C16 C15 121.8(16) . . ?
C22 C21 C26 120.4(16) . . ?
C22 C21 P1 117.4(14) . . ?
C26 C21 P1 122.0(12) . . ?
C21 C22 C23 121(2) . . ?
C22 C23 C24 117.7(19) . . ?
C25 C24 C23 121.4(19) . . ?
C24 C25 C26 121(2) . . ?
C21 C26 C25 118.8(18) . . ?
C28 C27 P1 173.8(14) . . ?
C27 C28 C31 176.9(16) . . ?
C36 C31 C32 119.7(13) . . ?
C36 C31 C28 121.0(13) . . ?
C32 C31 C28 119.3(13) . . ?
C33 C32 C31 119.0(14) . . ?
C34 C33 C32 120.2(14) . . ?
C33 C34 C35 120.8(13) . . ?
C33 C34 C37 118.8(13) . . ?
C35 C34 C37 120.4(13) . . ?
C36 C35 C34 119.7(14) . . ?
C35 C36 C31 120.4(14) . . ?
C38 C37 C34 175.9(15) . . ?
C37 C38 P2 173.7(14) . . ?
C42 C41 C46 117.1(15) . . ?
C42 C41 P2 121.7(12) . . ?
C46 C41 P2 120.9(12) . . ?
C41 C42 C43 120.9(16) . . ?
C44 C43 C42 120.2(17) . . ?
C43 C44 C45 120.0(17) . . ?
C46 C45 C44 119.4(17) . . ?
C45 C46 C41 122.2(16) . . ?
C56 C51 C52 118.9(14) . . ?
C56 C51 P2 123.4(12) . . ?
C52 C51 P2 117.6(12) . . ?
C53 C52 C51 118.5(15) . . ?
C54 C53 C52 120.9(16) . . ?
C53 C54 C55 121.4(16) . . ?
C56 C55 C54 118.6(17) . . ?
C51 C56 C55 121.6(15) . . ?
C66 C61 C62 113.3(14) . . ?
C66 C61 Au2 125.3(11) . . ?
C62 C61 Au2 121.3(12) . . ?
F6 C62 C63 115.0(14) . . ?
F6 C62 C61 120.7(15) . . ?
C63 C62 C61 124.2(16) . . ?
F7 C63 C64 118.7(14) . . ?
F7 C63 C62 123.2(15) . . ?
C64 C63 C62 118.2(15) . . ?
F8 C64 C63 120.7(15) . . ?
F8 C64 C65 118.1(15) . . ?
C63 C64 C65 121.2(15) . . ?
F9 C65 C66 119.0(15) . . ?
F9 C65 C64 122.1(15) . . ?
C66 C65 C64 118.8(15) . . ?
F10 C66 C65 118.8(14) . . ?
F10 C66 C61 117.1(13) . . ?
C65 C66 C61 124.1(15) . . ?
C72 C71 C76 119.4(14) . . ?
C72 C71 Au3 119.1(11) . . ?
C76 C71 Au3 121.4(11) . . ?
F11 C72 C71 122.8(14) . . ?
F11 C72 C73 115.8(14) . . ?
C71 C72 C73 121.3(15) . . ?
F12 C73 C74 121.8(15) . . ?
F12 C73 C72 121.5(15) . . ?
C74 C73 C72 116.7(14) . . ?
C75 C74 F13 120.4(15) . . ?
C75 C74 C73 121.8(14) . . ?
F13 C74 C73 117.8(14) . . ?
F14 C75 C76 122.4(14) . . ?
F14 C75 C74 118.7(14) . . ?
C76 C75 C74 118.9(15) . . ?
F15 C76 C75 116.1(13) . . ?
F15 C76 C71 122.1(13) . . ?
C75 C76 C71 121.8(14) . . ?
C78 C77 P3 175.0(14) . . ?
C77 C78 C114 177.3(17) . 1_545 ?
C82 C81 C86 119.7(15) . . ?
C82 C81 P3 121.0(13) . . ?
C86 C81 P3 119.3(12) . . ?
C81 C82 C83 120.2(17) . . ?
C84 C83 C82 119.8(17) . . ?
C83 C84 C85 120.2(17) . . ?
C84 C85 C86 120.4(17) . . ?
C85 C86 C81 119.7(16) . . ?
C96 C91 C92 120.3(15) . . ?
C96 C91 P3 121.1(12) . . ?
C92 C91 P3 118.6(12) . . ?
C91 C92 C93 119.3(16) . . ?
C92 C93 C94 121.1(17) . . ?
C95 C94 C93 119.9(16) . . ?
C94 C95 C96 118.7(17) . . ?
C91 C96 C95 120.7(16) . . ?
C106 C101 C102 116.3(14) . . ?
C106 C101 Au4 121.2(11) . . ?
C102 C101 Au4 122.5(11) . . ?
C103 C102 F16 118.0(13) . . ?
C103 C102 C101 122.8(14) . . ?
F16 C102 C101 119.1(13) . . ?
F17 C103 C102 120.5(15) . . ?
F17 C103 C104 120.5(14) . . ?
C102 C103 C104 119.0(14) . . ?
F18 C104 C105 123.7(17) . . ?
F18 C104 C103 117.7(15) . . ?
C105 C104 C103 118.6(15) . . ?
C104 C105 F19 118.8(15) . . ?
C104 C105 C106 120.3(15) . . ?
F19 C105 C106 120.9(15) . . ?
C101 C106 F20 120.8(14) . . ?
C101 C106 C105 123.0(15) . . ?
F20 C106 C105 116.3(14) . . ?
C108 C107 P4 175.0(15) . . ?
C107 C108 C111 176.8(17) . . ?
C116 C111 C112 120.7(13) . . ?
C116 C111 C108 120.1(13) . . ?
C112 C111 C108 119.2(14) . . ?
C113 C112 C111 120.9(15) . . ?
C112 C113 C114 119.3(14) . . ?
C115 C114 C113 120.8(13) . . ?
C115 C114 C78 118.6(13) . 1_565 ?
C113 C114 C78 120.6(13) . 1_565 ?
C114 C115 C116 119.5(14) . . ?
C111 C116 C115 118.8(13) . . ?
C122 C121 C126 124.4(17) . . ?
C122 C121 P4 119.4(13) . . ?
C126 C121 P4 116.2(14) . . ?
C121 C122 C123 119.1(18) . . ?
C124 C123 C122 119(2) . . ?
C123 C124 C125 121.4(18) . . ?
C124 C125 C126 120.4(18) . . ?
C121 C126 C125 115.6(18) . . ?
C136 C131 C132 119.8(16) . . ?
C136 C131 P4 122.1(12) . . ?
C132 C131 P4 118.1(13) . . ?
C131 C132 C133 118.4(18) . . ?
C134 C133 C132 122.5(18) . . ?
C135 C134 C133 117.9(18) . . ?
C134 C135 C136 121(2) . . ?
C131 C136 C135 120.3(17) . . ?
Cl2 C140 Cl1 117.0(14) . . ?
Cl3 C141 Cl4 114.6(13) . . ?

_diffrn_measured_fraction_theta_max 0.993
_diffrn_reflns_theta_full        25.50
_diffrn_measured_fraction_theta_full 0.993
_refine_diff_density_max         6.789
_refine_diff_density_min         -3.341
_refine_diff_density_rms         0.284

# Attachment '- ol74.cif'

data_ol74
_database_code_depnum_ccdc_archive 'CCDC 881807'
#TrackingRef '- ol74.cif'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C85 H50 Au4 Cl2 F20 P4'
_chemical_formula_weight         2433.90

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.886(3)
_cell_length_b                   13.589(3)
_cell_length_c                   13.618(3)
_cell_angle_alpha                106.60(3)
_cell_angle_beta                 115.98(3)
_cell_angle_gamma                93.65(3)
_cell_volume                     2004.2(7)
_cell_formula_units_Z            1
_cell_measurement_temperature    373(2)
_cell_measurement_reflns_used    26406
_cell_measurement_theta_min      4.1661
_cell_measurement_theta_max      35.1153

_exptl_crystal_description       'irregular prism'
_exptl_crystal_colour            colourless
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.05
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.017
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1150
_exptl_absorpt_coefficient_mu    7.536
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.4650
_exptl_absorpt_correction_T_max  0.7044
_exptl_absorpt_process_details   SADABS

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      373(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Xcalibur Oxford Diffraction'
_diffrn_measurement_method       /w-scans
_diffrn_detector_area_resol_mean 16.06
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            56814
_diffrn_reflns_av_R_equivalents  0.0221
_diffrn_reflns_av_sigmaI/netI    0.0134
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_theta_min         4.18
_diffrn_reflns_theta_max         25.00
_reflns_number_total             6993
_reflns_number_gt                6710
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Crysalis CCD'
_computing_cell_refinement       'Crysalis CCD'
_computing_data_reduction        'Crysalis RED'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Siemens XP'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0250P)^2^+10.7136P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    riding
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         6993
_refine_ls_number_parameters     534
_refine_ls_number_restraints     255
_refine_ls_R_factor_all          0.0270
_refine_ls_R_factor_gt           0.0257
_refine_ls_wR_factor_ref         0.0613
_refine_ls_wR_factor_gt          0.0606
_refine_ls_goodness_of_fit_ref   1.069
_refine_ls_restrained_S_all      1.127
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.921045(17) 0.656001(15) 0.233487(16) 0.02213(6) Uani 1 1 d . . .
Au2 Au 0.713544(15) 0.785422(14) 0.830061(15) 0.01992(6) Uani 1 1 d . . .
C1 C 0.9047(5) 0.6139(4) 0.0691(4) 0.0231(10) Uani 1 1 d U . .
C2 C 0.9947(5) 0.6371(4) 0.0450(5) 0.0252(11) Uani 1 1 d U . .
C3 C 0.9801(5) 0.6101(4) -0.0670(5) 0.0287(11) Uani 1 1 d U . .
C4 C 0.8710(5) 0.5575(4) -0.1598(5) 0.0302(12) Uani 1 1 d U . .
C5 C 0.7778(5) 0.5301(4) -0.1410(5) 0.0297(12) Uani 1 1 d U . .
C6 C 0.7970(5) 0.5596(4) -0.0274(5) 0.0262(11) Uani 1 1 d U . .
C11 C 1.0416(4) 0.8104(4) 0.5252(5) 0.0226(10) Uani 1 1 d U . .
C12 C 1.0873(5) 0.8253(4) 0.6429(5) 0.0328(12) Uani 1 1 d U . .
H12 H 1.0633 0.7734 0.6653 0.039 Uiso 1 1 calc R . .
C13 C 1.1679(6) 0.9163(5) 0.7268(5) 0.0388(13) Uani 1 1 d U . .
H13 H 1.1990 0.9252 0.8054 0.047 Uiso 1 1 calc R . .
C14 C 1.2026(5) 0.9946(4) 0.6931(6) 0.0367(13) Uani 1 1 d U . .
H14 H 1.2567 1.0562 0.7493 0.044 Uiso 1 1 calc R . .
C15 C 1.1569(5) 0.9805(4) 0.5774(6) 0.0361(13) Uani 1 1 d U . .
H15 H 1.1799 1.0333 0.5554 0.043 Uiso 1 1 calc R . .
C16 C 1.0773(5) 0.8892(4) 0.4925(5) 0.0304(12) Uani 1 1 d U . .
H16 H 1.0476 0.8803 0.4140 0.036 Uiso 1 1 calc R . .
C21 C 0.7920(5) 0.7155(4) 0.4101(5) 0.0247(11) Uani 1 1 d U . .
C22 C 0.7880(5) 0.7852(4) 0.5051(5) 0.0317(12) Uani 1 1 d U . .
H22 H 0.8576 0.8209 0.5738 0.038 Uiso 1 1 calc R . .
C23 C 0.6792(6) 0.8013(5) 0.4966(7) 0.0454(17) Uani 1 1 d U . .
H23 H 0.6762 0.8478 0.5599 0.054 Uiso 1 1 calc R . .
C24 C 0.5771(6) 0.7491(6) 0.3958(8) 0.0520(19) Uani 1 1 d U . .
H24 H 0.5049 0.7610 0.3905 0.062 Uiso 1 1 calc R . .
C25 C 0.5799(6) 0.6784(7) 0.3013(7) 0.0547(19) Uani 1 1 d U . .
H25 H 0.5099 0.6422 0.2333 0.066 Uiso 1 1 calc R . .
C26 C 0.6879(5) 0.6620(6) 0.3085(6) 0.0414(14) Uani 1 1 d U . .
H26 H 0.6903 0.6150 0.2451 0.050 Uiso 1 1 calc R . .
C31 C 0.9683(4) 0.5860(4) 0.4650(4) 0.0179(9) Uani 1 1 d U . .
C32 C 1.0482(4) 0.5335(4) 0.4396(4) 0.0200(10) Uani 1 1 d U . .
H32 H 1.0805 0.5557 0.3983 0.024 Uiso 1 1 calc R . .
C33 C 0.9197(4) 0.5511(4) 0.5255(4) 0.0191(9) Uani 1 1 d U . .
H33 H 0.8657 0.5845 0.5424 0.023 Uiso 1 1 calc R . .
C41 C 0.8881(4) 0.8458(4) 0.9521(4) 0.0215(10) Uani 1 1 d U . .
C42 C 0.9229(4) 0.8789(4) 1.0699(4) 0.0220(10) Uani 1 1 d U . .
C43 C 1.0395(5) 0.9179(4) 1.1555(4) 0.0268(11) Uani 1 1 d U . .
C44 C 1.1267(5) 0.9233(4) 1.1232(5) 0.0318(12) Uani 1 1 d U . .
C45 C 1.0961(5) 0.8905(5) 1.0069(5) 0.0319(12) Uani 1 1 d U . .
C46 C 0.9787(5) 0.8535(4) 0.9249(4) 0.0274(11) Uani 1 1 d U . .
C51 C 0.4328(5) 0.6752(4) 0.7594(4) 0.0235(10) Uani 1 1 d U . .
C52 C 0.4878(6) 0.6402(5) 0.8525(5) 0.0399(14) Uani 1 1 d U . .
H52 H 0.5672 0.6376 0.8809 0.048 Uiso 1 1 calc R . .
C53 C 0.4249(6) 0.6092(6) 0.9032(6) 0.0501(17) Uani 1 1 d U . .
H53 H 0.4619 0.5846 0.9644 0.060 Uiso 1 1 calc R . .
C54 C 0.3078(6) 0.6147(5) 0.8629(6) 0.0444(15) Uani 1 1 d U . .
H54 H 0.2659 0.5946 0.8975 0.053 Uiso 1 1 calc R . .
C55 C 0.2529(5) 0.6500(5) 0.7721(5) 0.0361(13) Uani 1 1 d U . .
H55 H 0.1738 0.6536 0.7450 0.043 Uiso 1 1 calc R . .
C56 C 0.3150(5) 0.6805(4) 0.7198(4) 0.0274(11) Uani 1 1 d U . .
H56 H 0.2773 0.7045 0.6582 0.033 Uiso 1 1 calc R . .
C61 C 0.4449(4) 0.7863(4) 0.6069(4) 0.0204(10) Uani 1 1 d U . .
C62 C 0.4882(4) 0.8941(4) 0.6487(5) 0.0253(11) Uani 1 1 d U . .
H62 H 0.5516 0.9268 0.7232 0.030 Uiso 1 1 calc R . .
C63 C 0.4367(5) 0.9534(5) 0.5793(5) 0.0338(12) Uani 1 1 d U . .
H63 H 0.4663 1.0256 0.6073 0.041 Uiso 1 1 calc R . .
C64 C 0.3417(5) 0.9054(5) 0.4690(5) 0.0360(13) Uani 1 1 d U . .
H64 H 0.3084 0.9452 0.4224 0.043 Uiso 1 1 calc R . .
C65 C 0.2958(5) 0.7976(5) 0.4273(5) 0.0339(13) Uani 1 1 d U . .
H65 H 0.2304 0.7657 0.3539 0.041 Uiso 1 1 calc R . .
C66 C 0.3478(4) 0.7380(4) 0.4956(4) 0.0261(11) Uani 1 1 d U . .
H66 H 0.3182 0.6657 0.4673 0.031 Uiso 1 1 calc R . .
C71 C 0.5090(4) 0.5879(4) 0.5880(4) 0.0182(9) Uani 1 1 d U . .
C72 C 0.4133(4) 0.5032(4) 0.5348(4) 0.0206(10) Uani 1 1 d U . .
H72 H 0.3556 0.5053 0.5586 0.025 Uiso 1 1 calc R . .
C73 C 0.4041(4) 0.4162(4) 0.4467(4) 0.0198(9) Uani 1 1 d U . .
H73 H 0.3394 0.3599 0.4102 0.024 Uiso 1 1 calc R . .
C100 C 0.529(2) 0.0678(11) 0.9861(16) 0.106(7) Uani 0.50 1 d PDU A -1
H101 H 0.4489 0.0546 0.9754 0.127 Uiso 0.50 1 calc PR A -1
H102 H 0.5792 0.1165 1.0649 0.127 Uiso 0.50 1 calc PR A -1
Cl1 Cl 0.5778(3) -0.0539(3) 0.9705(3) 0.0584(9) Uani 0.50 1 d PDU A -1
Cl2 Cl 0.5297(4) 0.1285(3) 0.8856(4) 0.0855(14) Uani 0.50 1 d PD A -1
F1 F 1.1044(3) 0.6882(2) 0.1335(3) 0.0343(7) Uani 1 1 d . . .
F2 F 1.0699(3) 0.6355(3) -0.0863(3) 0.0395(8) Uani 1 1 d . . .
F3 F 0.8532(3) 0.5315(3) -0.2697(3) 0.0447(9) Uani 1 1 d . . .
F4 F 0.6727(3) 0.4765(3) -0.2320(3) 0.0449(9) Uani 1 1 d . . .
F5 F 0.7020(3) 0.5312(3) -0.0143(3) 0.0383(8) Uani 1 1 d . . .
F6 F 0.8413(3) 0.8722(2) 1.1063(3) 0.0310(7) Uani 1 1 d . . .
F7 F 1.0704(3) 0.9499(3) 1.2697(3) 0.0393(8) Uani 1 1 d . . .
F8 F 1.2405(3) 0.9602(3) 1.2055(3) 0.0489(10) Uani 1 1 d . . .
F9 F 1.1808(3) 0.8953(4) 0.9753(3) 0.0528(10) Uani 1 1 d . . .
F10 F 0.9528(3) 0.8218(3) 0.8108(3) 0.0400(8) Uani 1 1 d . . .
P1 P 0.93140(11) 0.69473(10) 0.41226(11) 0.0193(2) Uani 1 1 d . . .
P2 P 0.52089(10) 0.71042(9) 0.69603(10) 0.0182(2) Uani 1 1 d . . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Au1 0.02985(11) 0.02605(11) 0.02138(10) 0.01427(8) 0.01671(9) 0.01403(8)
Au2 0.01903(10) 0.01699(10) 0.01685(10) 0.00221(7) 0.00501(8) 0.00392(7)
C1 0.034(3) 0.025(3) 0.023(2) 0.015(2) 0.019(2) 0.016(2)
C2 0.034(3) 0.021(2) 0.029(3) 0.014(2) 0.019(2) 0.013(2)
C3 0.039(3) 0.029(3) 0.038(3) 0.020(2) 0.029(3) 0.019(2)
C4 0.049(3) 0.033(3) 0.025(3) 0.017(2) 0.026(3) 0.025(3)
C5 0.032(3) 0.037(3) 0.025(3) 0.016(2) 0.013(2) 0.018(2)
C6 0.029(3) 0.035(3) 0.027(3) 0.020(2) 0.017(2) 0.018(2)
C11 0.025(3) 0.019(2) 0.033(3) 0.012(2) 0.020(2) 0.010(2)
C12 0.043(3) 0.027(3) 0.031(3) 0.011(2) 0.020(3) 0.005(2)
C13 0.045(3) 0.033(3) 0.033(3) 0.009(3) 0.015(3) 0.004(3)
C14 0.032(3) 0.026(3) 0.049(4) 0.005(3) 0.021(3) 0.004(2)
C15 0.043(3) 0.027(3) 0.055(4) 0.017(3) 0.035(3) 0.007(2)
C16 0.040(3) 0.027(3) 0.041(3) 0.018(2) 0.029(3) 0.013(2)
C21 0.030(3) 0.027(3) 0.038(3) 0.024(2) 0.024(2) 0.017(2)
C22 0.041(3) 0.026(3) 0.051(3) 0.021(3) 0.036(3) 0.015(2)
C23 0.060(4) 0.039(3) 0.086(5) 0.041(4) 0.061(4) 0.032(3)
C24 0.047(4) 0.070(5) 0.098(6) 0.065(5) 0.057(4) 0.041(4)
C25 0.026(3) 0.088(6) 0.064(5) 0.049(4) 0.020(3) 0.019(3)
C26 0.031(3) 0.065(4) 0.042(3) 0.030(3) 0.021(3) 0.021(3)
C31 0.020(2) 0.018(2) 0.018(2) 0.0072(18) 0.0099(19) 0.0068(18)
C32 0.025(2) 0.023(2) 0.021(2) 0.012(2) 0.016(2) 0.007(2)
C33 0.022(2) 0.021(2) 0.023(2) 0.010(2) 0.015(2) 0.0092(19)
C41 0.024(2) 0.014(2) 0.022(2) 0.0051(19) 0.008(2) 0.0041(19)
C42 0.024(3) 0.018(2) 0.024(2) 0.008(2) 0.012(2) 0.0041(19)
C43 0.030(3) 0.026(3) 0.018(2) 0.011(2) 0.004(2) 0.003(2)
C44 0.021(3) 0.037(3) 0.030(3) 0.020(2) 0.002(2) -0.002(2)
C45 0.024(3) 0.044(3) 0.038(3) 0.025(3) 0.017(2) 0.009(2)
C46 0.029(3) 0.032(3) 0.021(2) 0.013(2) 0.010(2) 0.006(2)
C51 0.031(3) 0.022(2) 0.021(2) 0.006(2) 0.016(2) 0.009(2)
C52 0.041(3) 0.062(4) 0.038(3) 0.030(3) 0.026(3) 0.029(3)
C53 0.060(4) 0.076(5) 0.055(4) 0.048(4) 0.043(4) 0.040(4)
C54 0.052(4) 0.057(4) 0.055(4) 0.033(3) 0.042(3) 0.025(3)
C55 0.033(3) 0.041(3) 0.040(3) 0.013(3) 0.023(3) 0.008(3)
C56 0.027(3) 0.031(3) 0.022(2) 0.006(2) 0.012(2) 0.005(2)
C61 0.019(2) 0.023(2) 0.024(2) 0.009(2) 0.013(2) 0.0090(19)
C62 0.018(2) 0.025(3) 0.030(3) 0.009(2) 0.010(2) 0.005(2)
C63 0.035(3) 0.031(3) 0.050(3) 0.024(3) 0.025(3) 0.015(2)
C64 0.034(3) 0.050(4) 0.041(3) 0.030(3) 0.021(3) 0.023(3)
C65 0.025(3) 0.051(4) 0.025(3) 0.015(3) 0.010(2) 0.019(3)
C66 0.022(3) 0.030(3) 0.023(2) 0.008(2) 0.008(2) 0.008(2)
C71 0.019(2) 0.019(2) 0.016(2) 0.0062(18) 0.0081(19) 0.0034(18)
C72 0.020(2) 0.023(2) 0.020(2) 0.008(2) 0.011(2) 0.0040(19)
C73 0.019(2) 0.018(2) 0.020(2) 0.0066(19) 0.008(2) 0.0026(18)
C100 0.105(7) 0.110(7) 0.105(7) 0.036(3) 0.052(4) 0.024(3)
Cl1 0.0385(13) 0.0615(16) 0.0505(15) -0.0218(12) 0.0258(12) 0.0103(12)
Cl2 0.069(3) 0.076(3) 0.082(3) -0.006(2) 0.032(2) 0.012(2)
F1 0.0366(18) 0.0344(17) 0.0346(17) 0.0134(14) 0.0187(15) 0.0060(14)
F2 0.049(2) 0.048(2) 0.049(2) 0.0250(17) 0.0400(18) 0.0197(16)
F3 0.063(2) 0.062(2) 0.0270(17) 0.0196(16) 0.0321(17) 0.0309(19)
F4 0.0395(19) 0.066(2) 0.0257(17) 0.0182(17) 0.0105(15) 0.0144(17)
F5 0.0301(17) 0.063(2) 0.0349(18) 0.0285(17) 0.0186(15) 0.0156(16)
F6 0.0292(16) 0.0390(18) 0.0279(16) 0.0104(14) 0.0170(14) 0.0069(13)
F7 0.0418(19) 0.045(2) 0.0174(15) 0.0078(14) 0.0055(14) -0.0013(15)
F8 0.0235(17) 0.068(3) 0.039(2) 0.0272(19) -0.0018(15) -0.0095(16)
F9 0.0282(18) 0.095(3) 0.050(2) 0.040(2) 0.0226(17) 0.0129(19)
F10 0.0362(18) 0.065(2) 0.0246(16) 0.0170(16) 0.0174(15) 0.0166(17)
P1 0.0244(6) 0.0215(6) 0.0218(6) 0.0124(5) 0.0156(5) 0.0111(5)
P2 0.0185(6) 0.0170(6) 0.0165(6) 0.0035(5) 0.0074(5) 0.0040(5)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.

Anisotropic displacement parameters (SIMU) and distant restrainst in
the solvent region have been applied.

The electronic density in the solvent region has been solved as
two dichloromethane molecules. The highest electronic density peak
is near these two molecules
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C1 2.054(5) . ?
Au1 P1 2.2794(13) . ?
Au2 C41 2.051(5) . ?
Au2 P2 2.2756(17) . ?
C1 C2 1.378(7) . ?
C1 C6 1.384(8) . ?
C2 F1 1.355(6) . ?
C2 C3 1.385(7) . ?
C3 F2 1.339(6) . ?
C3 C4 1.372(8) . ?
C4 F3 1.343(6) . ?
C4 C5 1.384(8) . ?
C5 F4 1.337(7) . ?
C5 C6 1.383(7) . ?
C6 F5 1.360(6) . ?
C11 C12 1.388(8) . ?
C11 C16 1.395(7) . ?
C11 P1 1.809(5) . ?
C12 C13 1.379(8) . ?
C13 C14 1.392(8) . ?
C14 C15 1.367(9) . ?
C15 C16 1.382(8) . ?
C21 C26 1.384(9) . ?
C21 C22 1.393(8) . ?
C21 P1 1.825(5) . ?
C22 C23 1.391(8) . ?
C23 C24 1.364(11) . ?
C24 C25 1.386(11) . ?
C25 C26 1.389(9) . ?
C31 C33 1.390(6) . ?
C31 C32 1.398(7) . ?
C31 P1 1.823(5) . ?
C32 C33 1.385(7) 2_766 ?
C33 C32 1.385(7) 2_766 ?
C41 C46 1.377(7) . ?
C41 C42 1.381(7) . ?
C42 F6 1.353(6) . ?
C42 C43 1.382(7) . ?
C43 F7 1.348(6) . ?
C43 C44 1.380(8) . ?
C44 F8 1.343(6) . ?
C44 C45 1.374(8) . ?
C45 F9 1.341(6) . ?
C45 C46 1.376(8) . ?
C46 F10 1.362(6) . ?
C51 C56 1.385(7) . ?
C51 C52 1.391(7) . ?
C51 P2 1.813(5) . ?
C52 C53 1.387(8) . ?
C53 C54 1.378(9) . ?
C54 C55 1.370(9) . ?
C55 C56 1.395(8) . ?
C61 C62 1.386(7) . ?
C61 C66 1.400(7) . ?
C61 P2 1.816(5) . ?
C62 C63 1.392(7) . ?
C63 C64 1.381(9) . ?
C64 C65 1.392(9) . ?
C65 C66 1.387(8) . ?
C71 C72 1.390(7) . ?
C71 C73 1.391(7) 2_666 ?
C71 P2 1.825(5) . ?
C72 C73 1.378(7) . ?
C73 C71 1.391(7) 2_666 ?
C100 Cl2 1.793(5) . ?
C100 Cl1 1.797(5) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Au1 P1 176.87(15) . . ?
C41 Au2 P2 177.06(13) . . ?
C2 C1 C6 115.2(4) . . ?
C2 C1 Au1 124.7(4) . . ?
C6 C1 Au1 120.1(4) . . ?
F1 C2 C1 119.9(4) . . ?
F1 C2 C3 116.8(5) . . ?
C1 C2 C3 123.3(5) . . ?
F2 C3 C4 119.6(5) . . ?
F2 C3 C2 121.2(5) . . ?
C4 C3 C2 119.1(5) . . ?
F3 C4 C3 120.8(5) . . ?
F3 C4 C5 119.1(5) . . ?
C3 C4 C5 120.2(5) . . ?
F4 C5 C6 122.1(5) . . ?
F4 C5 C4 119.6(5) . . ?
C6 C5 C4 118.3(5) . . ?
F5 C6 C5 115.7(5) . . ?
F5 C6 C1 120.4(4) . . ?
C5 C6 C1 123.9(5) . . ?
C12 C11 C16 119.2(5) . . ?
C12 C11 P1 122.3(4) . . ?
C16 C11 P1 118.5(4) . . ?
C13 C12 C11 120.7(5) . . ?
C12 C13 C14 119.6(6) . . ?
C15 C14 C13 119.8(6) . . ?
C14 C15 C16 121.1(5) . . ?
C15 C16 C11 119.6(5) . . ?
C26 C21 C22 119.8(5) . . ?
C26 C21 P1 118.0(4) . . ?
C22 C21 P1 122.2(4) . . ?
C23 C22 C21 119.6(6) . . ?
C24 C23 C22 120.2(6) . . ?
C23 C24 C25 120.6(6) . . ?
C24 C25 C26 119.7(7) . . ?
C21 C26 C25 120.0(6) . . ?
C33 C31 C32 118.8(4) . . ?
C33 C31 P1 124.1(4) . . ?
C32 C31 P1 117.1(3) . . ?
C33 C32 C31 121.3(4) 2_766 . ?
C32 C33 C31 120.0(4) 2_766 . ?
C46 C41 C42 115.2(5) . . ?
C46 C41 Au2 123.8(4) . . ?
C42 C41 Au2 121.0(4) . . ?
F6 C42 C41 120.1(4) . . ?
F6 C42 C43 116.7(4) . . ?
C41 C42 C43 123.2(5) . . ?
F7 C43 C44 119.1(5) . . ?
F7 C43 C42 121.8(5) . . ?
C44 C43 C42 119.1(5) . . ?
F8 C44 C45 120.7(5) . . ?
F8 C44 C43 119.8(5) . . ?
C45 C44 C43 119.6(5) . . ?
F9 C45 C44 119.7(5) . . ?
F9 C45 C46 121.1(5) . . ?
C44 C45 C46 119.2(5) . . ?
F10 C46 C45 117.0(5) . . ?
F10 C46 C41 119.3(5) . . ?
C45 C46 C41 123.7(5) . . ?
C56 C51 C52 118.9(5) . . ?
C56 C51 P2 123.8(4) . . ?
C52 C51 P2 117.3(4) . . ?
C53 C52 C51 120.5(6) . . ?
C54 C53 C52 120.0(6) . . ?
C55 C54 C53 120.1(5) . . ?
C54 C55 C56 120.4(5) . . ?
C51 C56 C55 120.1(5) . . ?
C62 C61 C66 119.6(5) . . ?
C62 C61 P2 118.7(4) . . ?
C66 C61 P2 121.6(4) . . ?
C61 C62 C63 120.0(5) . . ?
C64 C63 C62 120.2(5) . . ?
C63 C64 C65 120.1(5) . . ?
C66 C65 C64 119.8(5) . . ?
C65 C66 C61 120.1(5) . . ?
C72 C71 C73 120.0(4) . 2_666 ?
C72 C71 P2 122.3(4) . . ?
C73 C71 P2 117.6(4) 2_666 . ?
C73 C72 C71 119.7(4) . . ?
C72 C73 C71 120.3(4) . 2_666 ?
Cl2 C100 Cl1 114.0(4) . . ?
C11 P1 C31 105.8(2) . . ?
C11 P1 C21 105.5(2) . . ?
C31 P1 C21 106.9(2) . . ?
C11 P1 Au1 115.45(16) . . ?
C31 P1 Au1 109.72(15) . . ?
C21 P1 Au1 112.92(18) . . ?
C51 P2 C61 108.4(2) . . ?
C51 P2 C71 105.6(2) . . ?
C61 P2 C71 102.7(2) . . ?
C51 P2 Au2 113.04(17) . . ?
C61 P2 Au2 115.44(17) . . ?
C71 P2 Au2 110.73(16) . . ?

_diffrn_measured_fraction_theta_max 0.992
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.992
_refine_diff_density_max         3.028
_refine_diff_density_min         -1.970
_refine_diff_density_rms         0.118