# Electronic Supplementary Material (ESI) for Dalton Transactions
# This journal is © The Royal Society of Chemistry 2013

#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
#  on your local computer system.
# 
#  For further information on the CCDC, data deposition and
#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
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data_Compound1
#TrackingRef '2CIFs.cif'


_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C25 H48 N12 O P4 Rh, Cl'
_chemical_formula_sum            'C25 H48 Cl N12 O P4 Rh'
_chemical_formula_weight         794.99

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 21/m'
_symmetry_space_group_name_Hall  '-P 2yb'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
'-x, -y, -z'
'x, -y-1/2, z'

_cell_length_a                   9.931(5)
_cell_length_b                   14.531(7)
_cell_length_c                   10.807(5)
_cell_angle_alpha                90.00
_cell_angle_beta                 97.59(2)
_cell_angle_gamma                90.00
_cell_volume                     1545.9(12)
_cell_formula_units_Z            2
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    752
_cell_measurement_theta_min      2.50
_cell_measurement_theta_max      21.64

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.08
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.708
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             824
_exptl_absorpt_coefficient_mu    0.892
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.9005
_exptl_absorpt_correction_T_max  0.9321
_exptl_absorpt_process_details   sadabs

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            9018
_diffrn_reflns_av_R_equivalents  0.2330
_diffrn_reflns_av_sigmaI/netI    0.3022
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_theta_min         2.97
_diffrn_reflns_theta_max         25.34
_reflns_number_total             2823
_reflns_number_gt                1296
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.1177P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         2823
_refine_ls_number_parameters     214
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1969
_refine_ls_R_factor_gt           0.0734
_refine_ls_wR_factor_ref         0.2629
_refine_ls_wR_factor_gt          0.1724
_refine_ls_goodness_of_fit_ref   0.948
_refine_ls_restrained_S_all      0.948
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.182(2) 0.2500 0.108(2) 0.028(5) Uani 1 2 d S . .
C11 C 0.1624(14) 0.0448(8) 0.1140(14) 0.022(3) Uani 1 1 d . . .
H11A H 0.0851 0.0815 0.0730 0.026 Uiso 1 1 calc R . .
H11B H 0.2377 0.0503 0.0629 0.026 Uiso 1 1 calc R . .
C12 C 0.0735(13) 0.0554(7) 0.3532(12) 0.013(3) Uani 1 1 d . . .
H12A H 0.0971 0.0642 0.4443 0.016 Uiso 1 1 calc R . .
H12B H -0.0073 0.0936 0.3250 0.016 Uiso 1 1 calc R . .
C13 C 0.3398(13) -0.0006(8) 0.3263(14) 0.019(3) Uani 1 1 d . . .
H13A H 0.4190 0.0026 0.2796 0.022 Uiso 1 1 calc R . .
H13B H 0.3730 0.0081 0.4160 0.022 Uiso 1 1 calc R . .
C14 C 0.2326(14) -0.1105(8) 0.1775(14) 0.025(4) Uani 1 1 d . . .
H14A H 0.2036 -0.1755 0.1682 0.030 Uiso 1 1 calc R . .
H14B H 0.3121 -0.1027 0.1320 0.030 Uiso 1 1 calc R . .
C15 C 0.0059(13) -0.0621(8) 0.1950(12) 0.018(3) Uani 1 1 d . . .
H15A H -0.0683 -0.0200 0.1612 0.021 Uiso 1 1 calc R . .
H15B H -0.0296 -0.1257 0.1851 0.021 Uiso 1 1 calc R . .
C16 C 0.1570(13) -0.1007(9) 0.3762(13) 0.019(3) Uani 1 1 d . . .
H16A H 0.1277 -0.1658 0.3748 0.023 Uiso 1 1 calc R . .
H16B H 0.1857 -0.0835 0.4644 0.023 Uiso 1 1 calc R . .
C21 C 0.3955(14) 0.1544(8) 0.5767(12) 0.017(3) Uani 1 1 d . . .
H21A H 0.3458 0.0962 0.5557 0.020 Uiso 1 1 calc R . .
H21B H 0.4848 0.1495 0.5459 0.020 Uiso 1 1 calc R . .
C22 C 0.1559(18) 0.2500 0.587(2) 0.021(5) Uani 1 2 d S . .
H22A H 0.0990 0.3051 0.5656 0.025 Uiso 0.50 1 calc PR . .
H22B H 0.0990 0.1949 0.5656 0.025 Uiso 0.50 1 calc PR . .
C24 C 0.2888(13) 0.1670(9) 0.7662(13) 0.019(3) Uani 1 1 d . . .
H24A H 0.3077 0.1664 0.8584 0.023 Uiso 1 1 calc R . .
H24B H 0.2366 0.1107 0.7397 0.023 Uiso 1 1 calc R . .
C25 C 0.4955(18) 0.2500 0.7517(19) 0.021(5) Uani 1 2 d S . .
H25A H 0.5803 0.2500 0.7129 0.026 Uiso 1 2 calc SR . .
H25B H 0.5208 0.2500 0.8434 0.026 Uiso 1 2 calc SR . .
C31 C 0.5422(17) 0.2500 0.0948(18) 0.020(4) Uani 1 2 d S . .
H31A H 0.4988 0.1951 0.0526 0.024 Uiso 0.50 1 calc PR . .
H31B H 0.4988 0.3049 0.0526 0.024 Uiso 0.50 1 calc PR . .
C32 C 0.6246(13) 0.1540(9) 0.3130(14) 0.023(3) Uani 1 1 d . . .
H32A H 0.6330 0.1529 0.4053 0.028 Uiso 1 1 calc R . .
H32B H 0.5849 0.0947 0.2815 0.028 Uiso 1 1 calc R . .
C34 C 0.7577(14) 0.1689(9) 0.1375(13) 0.025(3) Uani 1 1 d . . .
H34A H 0.8516 0.1657 0.1163 0.030 Uiso 1 1 calc R . .
H34B H 0.7088 0.1137 0.1015 0.030 Uiso 1 1 calc R . .
C35 C 0.8276(19) 0.2500 0.3271(19) 0.021(5) Uani 1 2 d S . .
H35A H 0.9246 0.2500 0.3145 0.025 Uiso 1 2 calc SR . .
H35B H 0.8237 0.2500 0.4181 0.025 Uiso 1 2 calc SR . .
N11 N 0.1213(11) -0.0519(7) 0.1172(11) 0.021(3) Uani 1 1 d . . .
N12 N 0.0403(11) -0.0435(7) 0.3269(11) 0.018(3) Uani 1 1 d . . .
N13 N 0.2751(11) -0.0928(7) 0.3075(11) 0.021(3) Uani 1 1 d . . .
N21 N 0.4177(11) 0.1652(7) 0.7144(11) 0.022(3) Uani 1 1 d . . .
N22 N 0.2040(15) 0.2500 0.7254(16) 0.021(4) Uani 1 2 d S . .
N31 N 0.6923(14) 0.2500 0.0778(14) 0.012(3) Uiso 1 2 d S . .
N32 N 0.7638(11) 0.1649(7) 0.2732(11) 0.018(3) Uani 1 1 d . . .
O1 O 0.1257(17) 0.2500 0.0152(16) 0.045(5) Uani 1 2 d S . .
P1 P 0.2183(3) 0.0935(2) 0.2722(3) 0.0160(9) Uani 1 1 d . . .
P2 P 0.2994(5) 0.2500 0.4951(5) 0.0157(11) Uani 1 2 d S . .
P3 P 0.5088(5) 0.2500 0.2525(5) 0.0179(12) Uani 1 2 d S . .
Rh1 Rh 0.27195(15) 0.2500 0.27671(15) 0.0135(5) Uani 1 2 d S . .
Cl1 Cl 0.5000 0.0000 0.0000 0.0375(15) Uani 1 2 d S . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
C1 0.060(16) 0.006(9) 0.014(14) 0.000 -0.010(11) 0.000
C11 0.021(8) 0.006(6) 0.034(10) -0.006(6) -0.011(6) -0.004(5)
C12 0.025(8) 0.010(6) 0.004(8) -0.003(5) 0.002(6) 0.003(5)
C13 0.016(7) 0.021(7) 0.019(9) 0.004(6) 0.001(6) -0.005(5)
C14 0.031(9) 0.010(6) 0.033(10) 0.000(6) 0.005(7) 0.004(6)
C15 0.027(8) 0.018(7) 0.008(9) -0.004(5) 0.002(6) -0.003(6)
C16 0.020(8) 0.022(7) 0.014(9) 0.007(6) 0.000(6) -0.003(6)
C21 0.025(8) 0.019(7) 0.007(9) -0.003(5) 0.004(6) 0.002(6)
C22 0.009(10) 0.015(9) 0.038(15) 0.000 0.005(9) 0.000
C24 0.017(8) 0.031(7) 0.010(9) 0.006(6) 0.007(6) -0.004(6)
C25 0.016(11) 0.029(11) 0.018(14) 0.000 0.001(9) 0.000
C31 0.007(10) 0.041(12) 0.010(12) 0.000 -0.004(8) 0.000
C32 0.027(9) 0.021(7) 0.024(10) 0.002(6) 0.009(7) -0.005(6)
C34 0.022(9) 0.040(8) 0.013(9) -0.009(7) 0.004(7) 0.009(6)
C35 0.021(11) 0.027(10) 0.012(13) 0.000 -0.005(9) 0.000
N11 0.019(7) 0.019(6) 0.025(8) 0.004(5) 0.001(5) -0.008(5)
N12 0.019(6) 0.015(5) 0.019(8) 0.000(5) 0.001(5) -0.003(4)
N13 0.025(7) 0.019(6) 0.018(8) -0.003(5) -0.003(5) 0.000(5)
N21 0.021(7) 0.026(6) 0.018(8) 0.004(5) 0.000(5) 0.000(5)
N22 0.020(10) 0.023(8) 0.018(11) 0.000 -0.004(7) 0.000
N32 0.018(6) 0.022(6) 0.015(7) 0.002(5) 0.002(5) 0.000(5)
O1 0.077(13) 0.027(8) 0.021(11) 0.000 -0.030(9) 0.000
P1 0.0139(18) 0.0105(16) 0.022(2) -0.0009(14) -0.0015(15) -0.0001(13)
P2 0.018(3) 0.015(2) 0.013(3) 0.000 -0.002(2) 0.000
P3 0.013(3) 0.017(2) 0.023(4) 0.000 0.001(2) 0.000
Rh1 0.0160(9) 0.0135(7) 0.0106(10) 0.000 0.0001(6) 0.000
Cl1 0.041(4) 0.034(3) 0.040(4) -0.002(2) 0.015(3) -0.010(2)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 O1 1.08(2) . ?
C1 Rh1 1.92(2) . ?
C11 N11 1.465(15) . ?
C11 P1 1.866(14) . ?
C11 H11A 0.9900 . ?
C11 H11B 0.9900 . ?
C12 N12 1.493(14) . ?
C12 P1 1.864(13) . ?
C12 H12A 0.9900 . ?
C12 H12B 0.9900 . ?
C13 N13 1.488(15) . ?
C13 P1 1.866(13) . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C14 N13 1.436(18) . ?
C14 N11 1.476(16) . ?
C14 H14A 0.9900 . ?
C14 H14B 0.9900 . ?
C15 N12 1.447(17) . ?
C15 N11 1.516(16) . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?
C16 N12 1.468(16) . ?
C16 N13 1.473(16) . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C21 N21 1.483(17) . ?
C21 P2 1.843(13) . ?
C21 H21A 0.9900 . ?
C21 H21B 0.9900 . ?
C22 N22 1.51(3) . ?
C22 P2 1.843(18) . ?
C22 H22A 0.9900 . ?
C22 H22B 0.9900 . ?
C24 N21 1.464(16) . ?
C24 N22 1.504(15) . ?
C24 H24A 0.9900 . ?
C24 H24B 0.9900 . ?
C25 N21 1.482(14) . ?
C25 N21 1.482(14) 4_565 ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?
C31 N31 1.53(2) . ?
C31 P3 1.78(2) . ?
C31 H31A 0.9900 . ?
C31 H31B 0.9900 . ?
C32 N32 1.509(16) . ?
C32 P3 1.870(13) . ?
C32 H32A 0.9900 . ?
C32 H32B 0.9900 . ?
C34 N31 1.455(16) . ?
C34 N32 1.462(18) . ?
C34 H34A 0.9900 . ?
C34 H34B 0.9900 . ?
C35 N32 1.474(14) . ?
C35 N32 1.474(14) 4_565 ?
C35 H35A 0.9900 . ?
C35 H35B 0.9900 . ?
N22 C24 1.504(15) 4_565 ?
N31 C34 1.455(16) 4_565 ?
P1 Rh1 2.334(3) . ?
P2 C21 1.843(13) 4_565 ?
P2 Rh1 2.339(5) . ?
P3 C32 1.870(14) 4_565 ?
P3 Rh1 2.401(5) . ?
Rh1 P1 2.334(3) 4_565 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 C1 Rh1 177(2) . . ?
N11 C11 P1 113.1(9) . . ?
N11 C11 H11A 108.9 . . ?
P1 C11 H11A 108.9 . . ?
N11 C11 H11B 108.9 . . ?
P1 C11 H11B 108.9 . . ?
H11A C11 H11B 107.8 . . ?
N12 C12 P1 111.2(8) . . ?
N12 C12 H12A 109.4 . . ?
P1 C12 H12A 109.4 . . ?
N12 C12 H12B 109.4 . . ?
P1 C12 H12B 109.4 . . ?
H12A C12 H12B 108.0 . . ?
N13 C13 P1 111.6(9) . . ?
N13 C13 H13A 109.3 . . ?
P1 C13 H13A 109.3 . . ?
N13 C13 H13B 109.3 . . ?
P1 C13 H13B 109.3 . . ?
H13A C13 H13B 108.0 . . ?
N13 C14 N11 115.8(11) . . ?
N13 C14 H14A 108.3 . . ?
N11 C14 H14A 108.3 . . ?
N13 C14 H14B 108.3 . . ?
N11 C14 H14B 108.3 . . ?
H14A C14 H14B 107.4 . . ?
N12 C15 N11 115.6(11) . . ?
N12 C15 H15A 108.4 . . ?
N11 C15 H15A 108.4 . . ?
N12 C15 H15B 108.4 . . ?
N11 C15 H15B 108.4 . . ?
H15A C15 H15B 107.5 . . ?
N12 C16 N13 114.6(10) . . ?
N12 C16 H16A 108.6 . . ?
N13 C16 H16A 108.6 . . ?
N12 C16 H16B 108.6 . . ?
N13 C16 H16B 108.6 . . ?
H16A C16 H16B 107.6 . . ?
N21 C21 P2 113.5(8) . . ?
N21 C21 H21A 108.9 . . ?
P2 C21 H21A 108.9 . . ?
N21 C21 H21B 108.9 . . ?
P2 C21 H21B 108.9 . . ?
H21A C21 H21B 107.7 . . ?
N22 C22 P2 111.6(12) . . ?
N22 C22 H22A 109.3 . . ?
P2 C22 H22A 109.3 . . ?
N22 C22 H22B 109.3 . . ?
P2 C22 H22B 109.3 . . ?
H22A C22 H22B 108.0 . . ?
N21 C24 N22 112.7(11) . . ?
N21 C24 H24A 109.0 . . ?
N22 C24 H24A 109.0 . . ?
N21 C24 H24B 109.0 . . ?
N22 C24 H24B 109.0 . . ?
H24A C24 H24B 107.8 . . ?
N21 C25 N21 112.6(15) . 4_565 ?
N21 C25 H25A 109.1 . . ?
N21 C25 H25A 109.1 4_565 . ?
N21 C25 H25B 109.1 . . ?
N21 C25 H25B 109.1 4_565 . ?
H25A C25 H25B 107.8 . . ?
N31 C31 P3 115.1(12) . . ?
N31 C31 H31A 108.5 . . ?
P3 C31 H31A 108.5 . . ?
N31 C31 H31B 108.5 . . ?
P3 C31 H31B 108.5 . . ?
H31A C31 H31B 107.5 . . ?
N32 C32 P3 111.5(9) . . ?
N32 C32 H32A 109.3 . . ?
P3 C32 H32A 109.3 . . ?
N32 C32 H32B 109.3 . . ?
P3 C32 H32B 109.3 . . ?
H32A C32 H32B 108.0 . . ?
N31 C34 N32 115.7(11) . . ?
N31 C34 H34A 108.4 . . ?
N32 C34 H34A 108.4 . . ?
N31 C34 H34B 108.4 . . ?
N32 C34 H34B 108.4 . . ?
H34A C34 H34B 107.4 . . ?
N32 C35 N32 114.1(15) . 4_565 ?
N32 C35 H35A 108.7 . . ?
N32 C35 H35A 108.7 4_565 . ?
N32 C35 H35B 108.7 . . ?
N32 C35 H35B 108.7 4_565 . ?
H35A C35 H35B 107.6 . . ?
C11 N11 C14 111.6(10) . . ?
C11 N11 C15 109.9(10) . . ?
C14 N11 C15 106.0(10) . . ?
C15 N12 C16 108.9(10) . . ?
C15 N12 C12 112.6(10) . . ?
C16 N12 C12 109.4(10) . . ?
C14 N13 C16 109.2(11) . . ?
C14 N13 C13 111.1(10) . . ?
C16 N13 C13 111.1(10) . . ?
C24 N21 C25 109.4(11) . . ?
C24 N21 C21 111.3(10) . . ?
C25 N21 C21 111.4(11) . . ?
C24 N22 C24 106.7(14) . 4_565 ?
C24 N22 C22 112.5(10) . . ?
C24 N22 C22 112.5(10) 4_565 . ?
C34 N31 C34 108.2(15) 4_565 . ?
C34 N31 C31 109.4(10) 4_565 . ?
C34 N31 C31 109.4(10) . . ?
C34 N32 C35 108.7(12) . . ?
C34 N32 C32 111.9(11) . . ?
C35 N32 C32 109.7(12) . . ?
C12 P1 C11 99.4(6) . . ?
C12 P1 C13 98.2(6) . . ?
C11 P1 C13 96.3(6) . . ?
C12 P1 Rh1 117.9(4) . . ?
C11 P1 Rh1 115.4(4) . . ?
C13 P1 Rh1 124.8(4) . . ?
C22 P2 C21 97.5(6) . . ?
C22 P2 C21 97.5(6) . 4_565 ?
C21 P2 C21 97.9(8) . 4_565 ?
C22 P2 Rh1 123.3(7) . . ?
C21 P2 Rh1 117.8(4) . . ?
C21 P2 Rh1 117.8(4) 4_565 . ?
C31 P3 C32 98.7(6) . 4_565 ?
C31 P3 C32 98.7(6) . . ?
C32 P3 C32 96.4(9) 4_565 . ?
C31 P3 Rh1 114.5(6) . . ?
C32 P3 Rh1 121.9(4) 4_565 . ?
C32 P3 Rh1 121.9(4) . . ?
C1 Rh1 P1 84.47(18) . . ?
C1 Rh1 P1 84.47(18) . 4_565 ?
P1 Rh1 P1 153.80(18) . 4_565 ?
C1 Rh1 P2 159.1(7) . . ?
P1 Rh1 P2 90.97(10) . . ?
P1 Rh1 P2 90.97(10) 4_565 . ?
C1 Rh1 P3 103.7(7) . . ?
P1 Rh1 P3 102.83(9) . . ?
P1 Rh1 P3 102.83(9) 4_565 . ?
P2 Rh1 P3 97.18(18) . . ?

_diffrn_measured_fraction_theta_max 0.959
_diffrn_reflns_theta_full        25.34
_diffrn_measured_fraction_theta_full 0.959
_refine_diff_density_max         2.415
_refine_diff_density_min         -3.157
_refine_diff_density_rms         0.324
_database_code_depnum_ccdc_archive 'CCDC 896276'
#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
#  on your local computer system.
# 
#  For further information on the CCDC, data deposition and
#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
#
data_Compound2
#TrackingRef '2CIFs.cif'


_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C24 H48 Cl3 N12 P4 Rh'
_chemical_formula_sum            'C24 H48 Cl3 N12 P4 Rh'
_chemical_formula_weight         837.88

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   C2/c
_symmetry_space_group_name_Hall  -C2yc

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   27.2415(10)
_cell_length_b                   11.3351(5)
_cell_length_c                   25.7238(11)
_cell_angle_alpha                90.00
_cell_angle_beta                 108.5830(10)
_cell_angle_gamma                90.00
_cell_volume                     7529.0(5)
_cell_formula_units_Z            8
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    6354
_cell_measurement_theta_min      2.23
_cell_measurement_theta_max      26.74

_exptl_crystal_description       prism
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.06
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.478
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3456
_exptl_absorpt_coefficient_mu    0.872
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.8877
_exptl_absorpt_correction_T_max  0.9495
_exptl_absorpt_process_details   sadabs

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71069
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            30989
_diffrn_reflns_av_R_equivalents  0.0540
_diffrn_reflns_av_sigmaI/netI    0.0609
_diffrn_reflns_limit_h_min       -34
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_theta_min         1.67
_diffrn_reflns_theta_max         27.13
_reflns_number_total             8182
_reflns_number_gt                5810
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0472P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    none
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         8182
_refine_ls_number_parameters     397
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0636
_refine_ls_R_factor_gt           0.0390
_refine_ls_wR_factor_ref         0.0951
_refine_ls_wR_factor_gt          0.0885
_refine_ls_goodness_of_fit_ref   0.965
_refine_ls_restrained_S_all      0.965
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
1 0.500 -0.090 0.250 344.0 52.2
2 0.500 0.089 0.750 344.0 51.9
3 0.000 0.410 0.250 344.0 52.2
4 0.000 0.589 0.750 344.0 51.9
_platon_squeeze_details          
;
;

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C11 C 0.66618(15) -0.0498(3) 0.53767(14) 0.0373(9) Uani 1 1 d . . .
H11A H 0.6305 -0.0493 0.5139 0.045 Uiso 1 1 calc R . .
H11B H 0.6857 0.0029 0.5220 0.045 Uiso 1 1 calc R . .
C12 C 0.73738(14) -0.0336(3) 0.64219(16) 0.0384(9) Uani 1 1 d . . .
H12A H 0.7597 0.0183 0.6298 0.046 Uiso 1 1 calc R . .
H12B H 0.7448 -0.0210 0.6812 0.046 Uiso 1 1 calc R . .
C13 C 0.63753(15) -0.1221(3) 0.62739(15) 0.0369(9) Uani 1 1 d . . .
H13A H 0.6405 -0.1143 0.6658 0.044 Uiso 1 1 calc R . .
H13B H 0.6010 -0.1230 0.6063 0.044 Uiso 1 1 calc R . .
C14 C 0.71690(15) -0.2381(3) 0.65087(16) 0.0438(10) Uani 1 1 d . . .
H14A H 0.7206 -0.2215 0.6889 0.053 Uiso 1 1 calc R . .
H14B H 0.7296 -0.3175 0.6492 0.053 Uiso 1 1 calc R . .
C15 C 0.65652(16) -0.2512(3) 0.56055(15) 0.0426(10) Uani 1 1 d . . .
H15A H 0.6670 -0.3310 0.5555 0.051 Uiso 1 1 calc R . .
H15B H 0.6203 -0.2428 0.5389 0.051 Uiso 1 1 calc R . .
C16 C 0.74124(15) -0.1771(3) 0.57437(17) 0.0444(10) Uani 1 1 d . . .
H16A H 0.7613 -0.1200 0.5616 0.053 Uiso 1 1 calc R . .
H16B H 0.7543 -0.2550 0.5702 0.053 Uiso 1 1 calc R . .
C21 C 0.77085(13) 0.2787(3) 0.67894(13) 0.0326(8) Uani 1 1 d . . .
H21A H 0.7628 0.3110 0.7102 0.039 Uiso 1 1 calc R . .
H21B H 0.7812 0.1971 0.6871 0.039 Uiso 1 1 calc R . .
C22 C 0.74275(13) 0.2440(3) 0.56508(14) 0.0317(8) Uani 1 1 d . . .
H22A H 0.7517 0.1609 0.5684 0.038 Uiso 1 1 calc R . .
H22B H 0.7181 0.2571 0.5289 0.038 Uiso 1 1 calc R . .
C23 C 0.70926(14) 0.4438(3) 0.60466(14) 0.0330(8) Uani 1 1 d . . .
H23A H 0.6847 0.4591 0.5686 0.040 Uiso 1 1 calc R . .
H23B H 0.6970 0.4837 0.6315 0.040 Uiso 1 1 calc R . .
C24 C 0.79962(15) 0.4689(3) 0.66031(14) 0.0411(9) Uani 1 1 d . . .
H24A H 0.8306 0.5128 0.6619 0.049 Uiso 1 1 calc R . .
H24B H 0.7872 0.4983 0.6893 0.049 Uiso 1 1 calc R . .
C25 C 0.82802(14) 0.2958(4) 0.62492(15) 0.0412(9) Uani 1 1 d . . .
H25A H 0.8603 0.3319 0.6250 0.049 Uiso 1 1 calc R . .
H25B H 0.8341 0.2118 0.6307 0.049 Uiso 1 1 calc R . .
C26 C 0.77748(15) 0.4403(3) 0.56412(15) 0.0406(9) Uani 1 1 d . . .
H26A H 0.8082 0.4821 0.5630 0.049 Uiso 1 1 calc R . .
H26B H 0.7508 0.4520 0.5291 0.049 Uiso 1 1 calc R . .
C31 C 0.60762(14) 0.2066(3) 0.47878(13) 0.0361(9) Uani 1 1 d . . .
H31A H 0.6348 0.2620 0.4789 0.043 Uiso 1 1 calc R . .
H31B H 0.6218 0.1276 0.4807 0.043 Uiso 1 1 calc R . .
C32 C 0.55688(16) 0.3800(3) 0.51772(14) 0.0423(10) Uani 1 1 d . . .
H32A H 0.5385 0.4051 0.5425 0.051 Uiso 1 1 calc R . .
H32B H 0.5837 0.4376 0.5195 0.051 Uiso 1 1 calc R . .
C33 C 0.52684(14) 0.1454(3) 0.52035(14) 0.0390(9) Uani 1 1 d . . .
H33A H 0.5355 0.0621 0.5241 0.047 Uiso 1 1 calc R . .
H33B H 0.5075 0.1635 0.5452 0.047 Uiso 1 1 calc R . .
C34 C 0.52113(16) 0.1415(3) 0.42469(15) 0.0455(10) Uani 1 1 d . . .
H34A H 0.5339 0.0611 0.4308 0.055 Uiso 1 1 calc R . .
H34B H 0.4964 0.1453 0.3880 0.055 Uiso 1 1 calc R . .
C35 C 0.47893(14) 0.2933(4) 0.45772(16) 0.0453(10) Uani 1 1 d . . .
H35A H 0.4525 0.3034 0.4223 0.054 Uiso 1 1 calc R . .
H35B H 0.4635 0.3134 0.4857 0.054 Uiso 1 1 calc R . .
C36 C 0.54572(15) 0.3413(3) 0.42115(15) 0.0413(10) Uani 1 1 d . . .
H36A H 0.5747 0.3939 0.4246 0.050 Uiso 1 1 calc R . .
H36B H 0.5213 0.3514 0.3846 0.050 Uiso 1 1 calc R . .
C41 C 0.67269(13) 0.4302(3) 0.72900(14) 0.0323(8) Uani 1 1 d . . .
H41A H 0.6926 0.3716 0.7546 0.039 Uiso 1 1 calc R . .
H41B H 0.6956 0.4674 0.7118 0.039 Uiso 1 1 calc R . .
C42 C 0.58005(16) 0.3172(3) 0.72056(15) 0.0418(9) Uani 1 1 d . . .
H42A H 0.5466 0.2873 0.6983 0.050 Uiso 1 1 calc R . .
H42B H 0.5974 0.2552 0.7457 0.050 Uiso 1 1 calc R . .
C43 C 0.58279(15) 0.4892(3) 0.64339(14) 0.0383(9) Uani 1 1 d . . .
H43A H 0.6016 0.5294 0.6224 0.046 Uiso 1 1 calc R . .
H43B H 0.5494 0.4659 0.6183 0.046 Uiso 1 1 calc R . .
C44 C 0.54517(15) 0.5148(4) 0.71597(16) 0.0458(10) Uani 1 1 d . . .
H44A H 0.5134 0.4836 0.6906 0.055 Uiso 1 1 calc R . .
H44B H 0.5358 0.5745 0.7381 0.055 Uiso 1 1 calc R . .
C45 C 0.62425(14) 0.6114(3) 0.72248(15) 0.0372(9) Uani 1 1 d . . .
H45A H 0.6175 0.6746 0.7447 0.045 Uiso 1 1 calc R . .
H45B H 0.6451 0.6436 0.7015 0.045 Uiso 1 1 calc R . .
C46 C 0.62190(15) 0.4656(3) 0.78829(14) 0.0414(9) Uani 1 1 d . . .
H46A H 0.6149 0.5242 0.8125 0.050 Uiso 1 1 calc R . .
H46B H 0.6410 0.4017 0.8109 0.050 Uiso 1 1 calc R . .
N11 N 0.68700(12) -0.1692(3) 0.53990(13) 0.0384(7) Uani 1 1 d . . .
N12 N 0.74918(12) -0.1558(2) 0.63280(14) 0.0424(8) Uani 1 1 d . . .
N13 N 0.66158(12) -0.2344(2) 0.61887(12) 0.0377(7) Uani 1 1 d . . .
N21 N 0.81325(11) 0.3442(3) 0.67073(12) 0.0370(7) Uani 1 1 d . . .
N22 N 0.78940(11) 0.3142(3) 0.57133(11) 0.0339(7) Uani 1 1 d . . .
N23 N 0.76001(12) 0.4914(2) 0.60727(12) 0.0359(7) Uani 1 1 d . . .
N31 N 0.56442(11) 0.2196(3) 0.42741(11) 0.0378(7) Uani 1 1 d . . .
N32 N 0.52069(12) 0.3748(3) 0.46144(12) 0.0384(8) Uani 1 1 d . . .
N33 N 0.49436(12) 0.1691(3) 0.46413(12) 0.0403(8) Uani 1 1 d . . .
N41 N 0.65393(11) 0.5186(2) 0.75887(11) 0.0330(7) Uani 1 1 d . . .
N42 N 0.57243(13) 0.4194(3) 0.75192(13) 0.0427(8) Uani 1 1 d . . .
N43 N 0.57502(12) 0.5705(3) 0.68447(12) 0.0400(8) Uani 1 1 d . . .
P1 P 0.66904(3) 0.00515(7) 0.60625(3) 0.0272(2) Uani 1 1 d . . .
P2 P 0.71235(3) 0.28425(7) 0.61802(3) 0.02407(19) Uani 1 1 d . . .
P3 P 0.58712(3) 0.23311(7) 0.53978(3) 0.02505(19) Uani 1 1 d . . .
P4 P 0.61919(3) 0.35543(8) 0.67550(3) 0.0268(2) Uani 1 1 d . . .
Cl1 Cl 0.56880(3) 0.09262(8) 0.64405(4) 0.0363(2) Uani 1 1 d . . .
Cl2 Cl 0.68972(4) 0.13519(8) 0.72064(3) 0.0369(2) Uani 1 1 d . . .
Rh1 Rh 0.641123(10) 0.19208(2) 0.627796(10) 0.02253(8) Uani 1 1 d . . .
Cl10 Cl 0.66314(5) 0.49196(10) 0.45270(5) 0.0647(3) Uani 1 1 d . . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
C11 0.047(2) 0.033(2) 0.0338(19) 0.0016(16) 0.0154(17) 0.0047(17)
C12 0.034(2) 0.0210(18) 0.050(2) -0.0011(16) -0.0022(17) -0.0021(15)
C13 0.046(2) 0.0266(19) 0.041(2) 0.0012(16) 0.0174(18) -0.0039(16)
C14 0.053(3) 0.027(2) 0.043(2) 0.0065(17) 0.004(2) 0.0047(18)
C15 0.047(2) 0.032(2) 0.046(2) -0.0098(17) 0.0101(19) -0.0025(17)
C16 0.043(2) 0.030(2) 0.066(3) -0.0001(19) 0.025(2) 0.0035(17)
C21 0.0334(19) 0.035(2) 0.0278(17) -0.0004(15) 0.0073(15) -0.0041(15)
C22 0.0306(19) 0.033(2) 0.0316(18) -0.0062(15) 0.0107(15) -0.0013(15)
C23 0.040(2) 0.0272(19) 0.0342(19) 0.0026(15) 0.0149(16) 0.0028(16)
C24 0.045(2) 0.045(2) 0.035(2) -0.0146(17) 0.0171(18) -0.0221(18)
C25 0.0254(19) 0.054(2) 0.045(2) -0.0069(19) 0.0119(17) -0.0040(17)
C26 0.040(2) 0.048(2) 0.040(2) 0.0010(18) 0.0211(18) -0.0127(18)
C31 0.033(2) 0.045(2) 0.0288(18) 0.0052(16) 0.0089(15) 0.0075(17)
C32 0.050(2) 0.033(2) 0.033(2) -0.0008(16) -0.0009(18) 0.0042(18)
C33 0.034(2) 0.045(2) 0.0305(19) 0.0066(16) -0.0012(16) -0.0123(17)
C34 0.056(3) 0.040(2) 0.031(2) -0.0036(17) -0.0004(19) -0.0083(19)
C35 0.029(2) 0.061(3) 0.040(2) 0.0088(19) 0.0035(17) 0.0045(19)
C36 0.040(2) 0.044(2) 0.0314(19) 0.0151(16) -0.0009(17) -0.0057(17)
C41 0.0293(19) 0.037(2) 0.0293(18) -0.0024(15) 0.0078(15) 0.0012(15)
C42 0.046(2) 0.046(2) 0.041(2) -0.0065(18) 0.0236(18) -0.0137(19)
C43 0.042(2) 0.040(2) 0.0292(18) -0.0038(16) 0.0065(17) 0.0117(17)
C44 0.031(2) 0.062(3) 0.048(2) -0.018(2) 0.0175(19) 0.0032(19)
C45 0.045(2) 0.030(2) 0.039(2) -0.0065(16) 0.0162(18) 0.0007(17)
C46 0.053(3) 0.046(2) 0.0267(18) -0.0061(16) 0.0154(18) -0.0012(19)
N11 0.044(2) 0.0312(17) 0.0424(18) -0.0015(14) 0.0177(15) 0.0021(14)
N12 0.0371(19) 0.0248(16) 0.055(2) -0.0003(14) 0.0001(16) 0.0047(13)
N13 0.0452(19) 0.0241(15) 0.0438(18) 0.0010(13) 0.0145(15) -0.0032(14)
N21 0.0294(17) 0.048(2) 0.0326(16) -0.0046(14) 0.0083(14) -0.0093(14)
N22 0.0303(16) 0.0443(18) 0.0298(15) -0.0109(14) 0.0136(13) -0.0070(14)
N23 0.0447(19) 0.0300(16) 0.0391(17) -0.0045(13) 0.0219(15) -0.0096(13)
N31 0.0356(18) 0.051(2) 0.0243(14) 0.0035(14) 0.0061(13) 0.0070(15)
N32 0.0342(18) 0.0365(18) 0.0369(17) 0.0045(14) 0.0007(14) 0.0064(14)
N33 0.0335(18) 0.048(2) 0.0299(16) 0.0051(14) -0.0033(14) -0.0149(14)
N41 0.0351(17) 0.0346(17) 0.0289(15) -0.0050(13) 0.0098(13) -0.0011(13)
N42 0.046(2) 0.052(2) 0.0390(17) -0.0075(16) 0.0258(15) -0.0038(16)
N43 0.0415(19) 0.0434(19) 0.0342(16) -0.0043(14) 0.0108(15) 0.0140(15)
P1 0.0292(5) 0.0223(4) 0.0274(4) 0.0026(3) 0.0051(4) -0.0014(4)
P2 0.0264(4) 0.0216(4) 0.0237(4) -0.0009(3) 0.0072(4) -0.0012(3)
P3 0.0252(5) 0.0247(4) 0.0223(4) 0.0019(3) 0.0033(4) -0.0017(3)
P4 0.0266(5) 0.0298(5) 0.0236(4) -0.0009(3) 0.0075(4) -0.0005(4)
Cl1 0.0359(5) 0.0372(5) 0.0375(5) 0.0015(4) 0.0140(4) -0.0098(4)
Cl2 0.0441(5) 0.0381(5) 0.0238(4) 0.0081(4) 0.0041(4) 0.0009(4)
Rh1 0.02403(14) 0.02143(13) 0.02049(12) 0.00263(10) 0.00478(10) -0.00106(11)
Cl10 0.0526(7) 0.0630(7) 0.0718(8) 0.0156(6) 0.0105(6) -0.0148(5)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C11 N11 1.462(4) . ?
C11 P1 1.849(4) . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C12 N12 1.459(4) . ?
C12 P1 1.849(4) . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C13 N13 1.480(5) . ?
C13 P1 1.847(3) . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C14 N12 1.456(5) . ?
C14 N13 1.470(5) . ?
C14 H14A 0.9700 . ?
C14 H14B 0.9700 . ?
C15 N11 1.455(5) . ?
C15 N13 1.474(5) . ?
C15 H15A 0.9700 . ?
C15 H15B 0.9700 . ?
C16 N11 1.464(5) . ?
C16 N12 1.469(5) . ?
C16 H16A 0.9700 . ?
C16 H16B 0.9700 . ?
C21 N21 1.444(4) . ?
C21 P2 1.846(3) . ?
C21 H21A 0.9700 . ?
C21 H21B 0.9700 . ?
C22 N22 1.464(4) . ?
C22 P2 1.862(3) . ?
C22 H22A 0.9700 . ?
C22 H22B 0.9700 . ?
C23 N23 1.466(4) . ?
C23 P2 1.838(3) . ?
C23 H23A 0.9700 . ?
C23 H23B 0.9700 . ?
C24 N21 1.464(5) . ?
C24 N23 1.467(5) . ?
C24 H24A 0.9700 . ?
C24 H24B 0.9700 . ?
C25 N22 1.458(4) . ?
C25 N21 1.467(5) . ?
C25 H25A 0.9700 . ?
C25 H25B 0.9700 . ?
C26 N23 1.460(4) . ?
C26 N22 1.464(5) . ?
C26 H26A 0.9700 . ?
C26 H26B 0.9700 . ?
C31 N31 1.470(4) . ?
C31 P3 1.850(4) . ?
C31 H31A 0.9700 . ?
C31 H31B 0.9700 . ?
C32 N32 1.470(4) . ?
C32 P3 1.864(4) . ?
C32 H32A 0.9700 . ?
C32 H32B 0.9700 . ?
C33 N33 1.460(4) . ?
C33 P3 1.847(3) . ?
C33 H33A 0.9700 . ?
C33 H33B 0.9700 . ?
C34 N31 1.458(5) . ?
C34 N33 1.460(5) . ?
C34 H34A 0.9700 . ?
C34 H34B 0.9700 . ?
C35 N32 1.445(5) . ?
C35 N33 1.464(5) . ?
C35 H35A 0.9700 . ?
C35 H35B 0.9700 . ?
C36 N32 1.461(5) . ?
C36 N31 1.462(5) . ?
C36 H36A 0.9700 . ?
C36 H36B 0.9700 . ?
C41 N41 1.452(4) . ?
C41 P4 1.859(3) . ?
C41 H41A 0.9700 . ?
C41 H41B 0.9700 . ?
C42 N42 1.464(5) . ?
C42 P4 1.859(4) . ?
C42 H42A 0.9700 . ?
C42 H42B 0.9700 . ?
C43 N43 1.468(4) . ?
C43 P4 1.855(3) . ?
C43 H43A 0.9700 . ?
C43 H43B 0.9700 . ?
C44 N43 1.462(5) . ?
C44 N42 1.462(5) . ?
C44 H44A 0.9700 . ?
C44 H44B 0.9700 . ?
C45 N43 1.461(5) . ?
C45 N41 1.468(4) . ?
C45 H45A 0.9700 . ?
C45 H45B 0.9700 . ?
C46 N41 1.455(5) . ?
C46 N42 1.470(5) . ?
C46 H46A 0.9700 . ?
C46 H46B 0.9700 . ?
P1 Rh1 2.3756(9) . ?
P2 Rh1 2.2872(9) . ?
P3 Rh1 2.3204(8) . ?
P4 Rh1 2.3997(9) . ?
Cl1 Rh1 2.4192(9) . ?
Cl2 Rh1 2.4200(8) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N11 C11 P1 112.1(2) . . ?
N11 C11 H11A 109.2 . . ?
P1 C11 H11A 109.2 . . ?
N11 C11 H11B 109.2 . . ?
P1 C11 H11B 109.2 . . ?
H11A C11 H11B 107.9 . . ?
N12 C12 P1 112.5(2) . . ?
N12 C12 H12A 109.1 . . ?
P1 C12 H12A 109.1 . . ?
N12 C12 H12B 109.1 . . ?
P1 C12 H12B 109.1 . . ?
H12A C12 H12B 107.8 . . ?
N13 C13 P1 111.0(3) . . ?
N13 C13 H13A 109.4 . . ?
P1 C13 H13A 109.4 . . ?
N13 C13 H13B 109.4 . . ?
P1 C13 H13B 109.4 . . ?
H13A C13 H13B 108.0 . . ?
N12 C14 N13 114.8(3) . . ?
N12 C14 H14A 108.6 . . ?
N13 C14 H14A 108.6 . . ?
N12 C14 H14B 108.6 . . ?
N13 C14 H14B 108.6 . . ?
H14A C14 H14B 107.6 . . ?
N11 C15 N13 114.2(3) . . ?
N11 C15 H15A 108.7 . . ?
N13 C15 H15A 108.7 . . ?
N11 C15 H15B 108.7 . . ?
N13 C15 H15B 108.7 . . ?
H15A C15 H15B 107.6 . . ?
N11 C16 N12 113.6(3) . . ?
N11 C16 H16A 108.8 . . ?
N12 C16 H16A 108.8 . . ?
N11 C16 H16B 108.8 . . ?
N12 C16 H16B 108.8 . . ?
H16A C16 H16B 107.7 . . ?
N21 C21 P2 111.9(2) . . ?
N21 C21 H21A 109.2 . . ?
P2 C21 H21A 109.2 . . ?
N21 C21 H21B 109.2 . . ?
P2 C21 H21B 109.2 . . ?
H21A C21 H21B 107.9 . . ?
N22 C22 P2 111.1(2) . . ?
N22 C22 H22A 109.4 . . ?
P2 C22 H22A 109.4 . . ?
N22 C22 H22B 109.4 . . ?
P2 C22 H22B 109.4 . . ?
H22A C22 H22B 108.0 . . ?
N23 C23 P2 111.6(2) . . ?
N23 C23 H23A 109.3 . . ?
P2 C23 H23A 109.3 . . ?
N23 C23 H23B 109.3 . . ?
P2 C23 H23B 109.3 . . ?
H23A C23 H23B 108.0 . . ?
N21 C24 N23 114.0(3) . . ?
N21 C24 H24A 108.7 . . ?
N23 C24 H24A 108.7 . . ?
N21 C24 H24B 108.7 . . ?
N23 C24 H24B 108.7 . . ?
H24A C24 H24B 107.6 . . ?
N22 C25 N21 114.0(3) . . ?
N22 C25 H25A 108.8 . . ?
N21 C25 H25A 108.8 . . ?
N22 C25 H25B 108.8 . . ?
N21 C25 H25B 108.8 . . ?
H25A C25 H25B 107.7 . . ?
N23 C26 N22 113.9(3) . . ?
N23 C26 H26A 108.8 . . ?
N22 C26 H26A 108.8 . . ?
N23 C26 H26B 108.8 . . ?
N22 C26 H26B 108.8 . . ?
H26A C26 H26B 107.7 . . ?
N31 C31 P3 112.0(2) . . ?
N31 C31 H31A 109.2 . . ?
P3 C31 H31A 109.2 . . ?
N31 C31 H31B 109.2 . . ?
P3 C31 H31B 109.2 . . ?
H31A C31 H31B 107.9 . . ?
N32 C32 P3 110.9(2) . . ?
N32 C32 H32A 109.5 . . ?
P3 C32 H32A 109.5 . . ?
N32 C32 H32B 109.5 . . ?
P3 C32 H32B 109.5 . . ?
H32A C32 H32B 108.0 . . ?
N33 C33 P3 112.0(2) . . ?
N33 C33 H33A 109.2 . . ?
P3 C33 H33A 109.2 . . ?
N33 C33 H33B 109.2 . . ?
P3 C33 H33B 109.2 . . ?
H33A C33 H33B 107.9 . . ?
N31 C34 N33 114.3(3) . . ?
N31 C34 H34A 108.7 . . ?
N33 C34 H34A 108.7 . . ?
N31 C34 H34B 108.7 . . ?
N33 C34 H34B 108.7 . . ?
H34A C34 H34B 107.6 . . ?
N32 C35 N33 114.6(3) . . ?
N32 C35 H35A 108.6 . . ?
N33 C35 H35A 108.6 . . ?
N32 C35 H35B 108.6 . . ?
N33 C35 H35B 108.6 . . ?
H35A C35 H35B 107.6 . . ?
N32 C36 N31 113.1(3) . . ?
N32 C36 H36A 109.0 . . ?
N31 C36 H36A 109.0 . . ?
N32 C36 H36B 109.0 . . ?
N31 C36 H36B 109.0 . . ?
H36A C36 H36B 107.8 . . ?
N41 C41 P4 112.4(2) . . ?
N41 C41 H41A 109.1 . . ?
P4 C41 H41A 109.1 . . ?
N41 C41 H41B 109.1 . . ?
P4 C41 H41B 109.1 . . ?
H41A C41 H41B 107.9 . . ?
N42 C42 P4 111.6(2) . . ?
N42 C42 H42A 109.3 . . ?
P4 C42 H42A 109.3 . . ?
N42 C42 H42B 109.3 . . ?
P4 C42 H42B 109.3 . . ?
H42A C42 H42B 108.0 . . ?
N43 C43 P4 111.8(2) . . ?
N43 C43 H43A 109.2 . . ?
P4 C43 H43A 109.2 . . ?
N43 C43 H43B 109.2 . . ?
P4 C43 H43B 109.2 . . ?
H43A C43 H43B 107.9 . . ?
N43 C44 N42 114.2(3) . . ?
N43 C44 H44A 108.7 . . ?
N42 C44 H44A 108.7 . . ?
N43 C44 H44B 108.7 . . ?
N42 C44 H44B 108.7 . . ?
H44A C44 H44B 107.6 . . ?
N43 C45 N41 113.6(3) . . ?
N43 C45 H45A 108.8 . . ?
N41 C45 H45A 108.8 . . ?
N43 C45 H45B 108.8 . . ?
N41 C45 H45B 108.8 . . ?
H45A C45 H45B 107.7 . . ?
N41 C46 N42 113.3(3) . . ?
N41 C46 H46A 108.9 . . ?
N42 C46 H46A 108.9 . . ?
N41 C46 H46B 108.9 . . ?
N42 C46 H46B 108.9 . . ?
H46A C46 H46B 107.7 . . ?
C15 N11 C11 110.3(3) . . ?
C15 N11 C16 108.8(3) . . ?
C11 N11 C16 112.6(3) . . ?
C14 N12 C12 111.6(3) . . ?
C14 N12 C16 108.3(3) . . ?
C12 N12 C16 110.9(3) . . ?
C14 N13 C15 108.2(3) . . ?
C14 N13 C13 111.4(3) . . ?
C15 N13 C13 111.1(3) . . ?
C21 N21 C24 110.8(3) . . ?
C21 N21 C25 111.2(3) . . ?
C24 N21 C25 109.4(3) . . ?
C25 N22 C22 111.4(3) . . ?
C25 N22 C26 108.9(3) . . ?
C22 N22 C26 111.5(3) . . ?
C26 N23 C23 110.5(3) . . ?
C26 N23 C24 108.4(3) . . ?
C23 N23 C24 112.4(3) . . ?
C34 N31 C36 108.6(3) . . ?
C34 N31 C31 112.7(3) . . ?
C36 N31 C31 110.2(3) . . ?
C35 N32 C36 108.8(3) . . ?
C35 N32 C32 110.9(3) . . ?
C36 N32 C32 113.0(3) . . ?
C33 N33 C34 111.7(3) . . ?
C33 N33 C35 110.5(3) . . ?
C34 N33 C35 108.5(3) . . ?
C41 N41 C46 111.1(3) . . ?
C41 N41 C45 111.9(3) . . ?
C46 N41 C45 109.2(3) . . ?
C44 N42 C42 111.7(3) . . ?
C44 N42 C46 108.5(3) . . ?
C42 N42 C46 111.7(3) . . ?
C45 N43 C44 108.7(3) . . ?
C45 N43 C43 111.7(3) . . ?
C44 N43 C43 111.2(3) . . ?
C13 P1 C12 98.94(17) . . ?
C13 P1 C11 97.80(17) . . ?
C12 P1 C11 97.28(18) . . ?
C13 P1 Rh1 114.50(12) . . ?
C12 P1 Rh1 116.21(11) . . ?
C11 P1 Rh1 127.13(12) . . ?
C23 P2 C21 99.67(16) . . ?
C23 P2 C22 96.26(16) . . ?
C21 P2 C22 98.49(16) . . ?
C23 P2 Rh1 118.70(12) . . ?
C21 P2 Rh1 115.10(11) . . ?
C22 P2 Rh1 123.99(11) . . ?
C33 P3 C31 99.55(17) . . ?
C33 P3 C32 97.47(18) . . ?
C31 P3 C32 96.34(17) . . ?
C33 P3 Rh1 112.86(11) . . ?
C31 P3 Rh1 121.75(11) . . ?
C32 P3 Rh1 123.87(11) . . ?
C43 P4 C41 97.99(16) . . ?
C43 P4 C42 97.86(19) . . ?
C41 P4 C42 96.60(17) . . ?
C43 P4 Rh1 126.00(11) . . ?
C41 P4 Rh1 117.77(11) . . ?
C42 P4 Rh1 115.11(12) . . ?
P2 Rh1 P3 95.59(3) . . ?
P2 Rh1 P1 92.06(3) . . ?
P3 Rh1 P1 95.83(3) . . ?
P2 Rh1 P4 93.55(3) . . ?
P3 Rh1 P4 99.24(3) . . ?
P1 Rh1 P4 163.31(3) . . ?
P2 Rh1 Cl1 176.45(3) . . ?
P3 Rh1 Cl1 87.94(3) . . ?
P1 Rh1 Cl1 87.91(3) . . ?
P4 Rh1 Cl1 85.53(3) . . ?
P2 Rh1 Cl2 90.79(3) . . ?
P3 Rh1 Cl2 173.55(3) . . ?
P1 Rh1 Cl2 82.96(3) . . ?
P4 Rh1 Cl2 81.25(3) . . ?
Cl1 Rh1 Cl2 85.69(3) . . ?

_diffrn_measured_fraction_theta_max 0.984
_diffrn_reflns_theta_full        27.13
_diffrn_measured_fraction_theta_full 0.984
_refine_diff_density_max         0.750
_refine_diff_density_min         -0.378
_refine_diff_density_rms         0.087


_database_code_depnum_ccdc_archive 'CCDC 896277'