# Electronic Supplementary Material (ESI) for Dalton Transactions
# This journal is © The Royal Society of Chemistry 2013

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#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
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#  data retrieval see:
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#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
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data_c2m

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C4 Cl2 K O24 Ru2 Zn2'
_chemical_formula_sum            'C4 Cl2 K O24 Ru2 Zn2'
_chemical_formula_weight         874.92

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   'C 2/m'
_symmetry_space_group_name_Hall  '-C 2y'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'

_cell_length_a                   15.771(2)
_cell_length_b                   15.374(2)
_cell_length_c                   10.6099(17)
_cell_angle_alpha                90.00
_cell_angle_beta                 104.882(2)
_cell_angle_gamma                90.00
_cell_volume                     2486.3(7)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       block
_exptl_crystal_colour            brown
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.18
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.337
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1668
_exptl_absorpt_coefficient_mu    3.577
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.3674
_exptl_absorpt_correction_T_max  0.5653
_exptl_absorpt_process_details   sadab

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'APEX II CCD'
_diffrn_measurement_method       '\w-\p scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            6760
_diffrn_reflns_av_R_equivalents  0.0254
_diffrn_reflns_av_sigmaI/netI    0.0325
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_l_min       -9
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_theta_min         1.88
_diffrn_reflns_theta_max         25.98
_reflns_number_total             2521
_reflns_number_gt                2182
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'


_refine_special_details          
; 
 Refinement of F^2^ against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F^2^, conventional R-factors R are based 
 on F, with F set to zero for negative F^2^. The threshold expression of 
 F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F^2^ are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0726P)^2^+7.7865P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   .
_refine_ls_hydrogen_treatment    .
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         2521
_refine_ls_number_parameters     169
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0391
_refine_ls_R_factor_gt           0.0308
_refine_ls_wR_factor_ref         0.1135
_refine_ls_wR_factor_gt          0.0951
_refine_ls_goodness_of_fit_ref   1.077
_refine_ls_restrained_S_all      1.077
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.51044(3) 0.5000 0.89829(5) 0.01278(17) Uani 1 2 d S . .
Ru2 Ru 0.95383(3) 0.5000 0.89844(5) 0.01249(17) Uani 1 2 d S . .
Zn1 Zn 0.7500 0.7500 1.0000 0.0156(2) Uani 1 2 d S . .
Zn2 Zn 0.2500 0.2500 0.5000 0.0228(2) Uani 1 2 d S . .
K2 K 0.34087(13) 0.5000 0.5540(2) 0.0398(5) Uani 1 2 d S . .
Cl2 Cl 0.54474(14) 0.5000 0.67648(19) 0.0302(5) Uani 1 2 d S . .
Cl1 Cl 0.84355(14) 0.5000 0.6713(2) 0.0330(5) Uani 1 2 d S . .
O1 O 0.6029(2) 0.5938(2) 0.9561(3) 0.0215(8) Uani 1 1 d . . .
O4 O 0.8828(2) 0.5940(2) 0.9555(3) 0.0201(8) Uani 1 1 d . . .
O3 O 0.4165(2) 0.4080(2) 0.8408(3) 0.0210(8) Uani 1 1 d . . .
O6 O 1.0263(2) 0.4055(2) 0.8436(4) 0.0198(8) Uani 1 1 d . . .
O5 O 0.8667(2) 0.6909(2) 1.1042(4) 0.0234(8) Uani 1 1 d . . .
O2 O 0.6844(2) 0.6768(2) 1.1129(4) 0.0240(8) Uani 1 1 d . . .
C2 C 0.9073(3) 0.6271(3) 1.0715(5) 0.0173(10) Uani 1 1 d . . .
C1 C 0.6242(3) 0.6221(3) 1.0763(5) 0.0179(10) Uani 1 1 d . . .
O8 O 0.1629(3) 0.1712(3) 0.5754(4) 0.0308(9) Uani 1 1 d . . .
O9 O 0.2589(3) 0.1472(3) 0.3735(4) 0.0287(9) Uani 1 1 d . . .
O10 O 0.3553(3) 0.2011(3) 0.6386(4) 0.0346(10) Uani 1 1 d . . .
O11 O 0.4840(3) 0.2821(3) 0.3129(5) 0.0406(11) Uani 1 1 d . . .
O12 O 0.5731(3) 0.9093(3) 0.6057(4) 0.0395(11) Uani 1 1 d . . .
O7 O 0.7239(2) 0.6553(2) 0.8457(3) 0.0197(8) Uani 1 1 d . . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Ru1 0.0114(3) 0.0145(3) 0.0127(3) 0.000 0.0037(2) 0.000
Ru2 0.0107(3) 0.0123(3) 0.0141(3) 0.000 0.0024(2) 0.000
Zn1 0.0156(4) 0.0146(4) 0.0166(4) -0.0001(3) 0.0041(3) 0.0002(3)
Zn2 0.0228(5) 0.0231(5) 0.0213(5) 0.0008(3) 0.0036(4) -0.0011(4)
K2 0.0321(11) 0.0345(10) 0.0483(13) 0.000 0.0022(9) 0.000
Cl2 0.0336(11) 0.0410(11) 0.0197(9) 0.000 0.0134(8) 0.000
Cl1 0.0359(11) 0.0244(10) 0.0282(10) 0.000 -0.0109(9) 0.000
O1 0.0231(19) 0.0259(19) 0.0159(18) -0.0053(15) 0.0059(15) -0.0093(15)
O4 0.0185(18) 0.0209(18) 0.0189(19) -0.0049(14) 0.0014(15) 0.0055(14)
O3 0.024(2) 0.0264(19) 0.0141(18) -0.0025(15) 0.0078(15) -0.0085(15)
O6 0.0201(19) 0.0202(18) 0.0186(18) -0.0022(15) 0.0042(15) 0.0067(14)
O5 0.0220(19) 0.0204(18) 0.026(2) -0.0059(15) 0.0018(16) 0.0095(15)
O2 0.027(2) 0.0245(19) 0.0213(19) -0.0019(15) 0.0067(16) -0.0151(16)
C2 0.014(2) 0.018(2) 0.022(3) 0.001(2) 0.007(2) -0.0006(19)
C1 0.015(2) 0.020(2) 0.018(2) 0.001(2) 0.002(2) 0.001(2)
O8 0.031(2) 0.033(2) 0.031(2) 0.0044(18) 0.0125(18) -0.0035(18)
O9 0.032(2) 0.029(2) 0.023(2) -0.0037(17) 0.0041(17) 0.0003(18)
O10 0.031(2) 0.030(2) 0.037(2) 0.0062(19) -0.0016(19) 0.0025(18)
O11 0.040(3) 0.033(2) 0.044(3) 0.002(2) 0.003(2) 0.0034(19)
O12 0.037(3) 0.051(3) 0.032(2) 0.004(2) 0.012(2) 0.010(2)
O7 0.0187(18) 0.0202(18) 0.0202(18) -0.0031(15) 0.0052(14) 0.0003(14)

_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru1 O3 2.025(3) . ?
Ru1 O3 2.025(3) 6_565 ?
Ru1 O1 2.031(4) . ?
Ru1 O1 2.031(3) 6_565 ?
Ru1 Ru1 2.2652(11) 5_667 ?
Ru1 Cl2 2.547(2) . ?
Ru1 K2 3.934(2) . ?
Ru2 O4 2.015(3) 6_565 ?
Ru2 O4 2.015(3) . ?
Ru2 O6 2.024(3) 6_565 ?
Ru2 O6 2.024(3) . ?
Ru2 Ru2 2.2701(11) 5_767 ?
Ru2 Cl1 2.585(2) . ?
Zn1 O5 2.095(4) . ?
Zn1 O5 2.095(4) 7_667 ?
Zn1 O2 2.100(4) . ?
Zn1 O2 2.100(4) 7_667 ?
Zn1 O7 2.150(3) 7_667 ?
Zn1 O7 2.150(3) . ?
Zn2 O10 2.057(4) . ?
Zn2 O10 2.057(4) 7_556 ?
Zn2 O9 2.101(4) 7_556 ?
Zn2 O9 2.101(4) . ?
Zn2 O8 2.134(4) . ?
Zn2 O8 2.134(4) 7_556 ?
Zn2 K2 4.0907(9) . ?
Zn2 K2 4.0907(9) 7_556 ?
K2 O8 2.963(4) 7_556 ?
K2 O8 2.963(4) 4_556 ?
K2 O9 2.968(4) 7_556 ?
K2 O9 2.968(4) 4_556 ?
K2 Cl2 3.143(3) . ?
K2 Cl1 3.256(3) 5_666 ?
K2 O3 3.289(4) 6_565 ?
K2 O3 3.289(4) . ?
K2 Cl2 3.391(3) 5_666 ?
K2 Zn2 4.0907(9) 4_556 ?
Cl2 K2 3.391(3) 5_666 ?
Cl1 K2 3.256(3) 5_666 ?
O1 C1 1.307(6) . ?
O4 C2 1.295(6) . ?
O3 C1 1.301(6) 5_667 ?
O6 C2 1.295(6) 5_767 ?
O5 C2 1.268(6) . ?
O2 C1 1.252(6) . ?
C2 O6 1.295(6) 5_767 ?
C1 O3 1.301(6) 5_667 ?
O8 K2 2.963(4) 7_556 ?
O9 K2 2.968(4) 7_556 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Ru1 O3 88.6(2) . 6_565 ?
O3 Ru1 O1 178.99(15) . . ?
O3 Ru1 O1 90.46(16) 6_565 . ?
O3 Ru1 O1 90.46(16) . 6_565 ?
O3 Ru1 O1 178.99(15) 6_565 6_565 ?
O1 Ru1 O1 90.5(2) . 6_565 ?
O3 Ru1 Ru1 90.76(10) . 5_667 ?
O3 Ru1 Ru1 90.76(10) 6_565 5_667 ?
O1 Ru1 Ru1 88.91(10) . 5_667 ?
O1 Ru1 Ru1 88.91(10) 6_565 5_667 ?
O3 Ru1 Cl2 91.94(10) . . ?
O3 Ru1 Cl2 91.94(10) 6_565 . ?
O1 Ru1 Cl2 88.43(11) . . ?
O1 Ru1 Cl2 88.43(11) 6_565 . ?
Ru1 Ru1 Cl2 176.22(6) 5_667 . ?
O3 Ru1 K2 56.64(10) . . ?
O3 Ru1 K2 56.64(10) 6_565 . ?
O1 Ru1 K2 123.01(11) . . ?
O1 Ru1 K2 123.01(11) 6_565 . ?
Ru1 Ru1 K2 130.86(5) 5_667 . ?
Cl2 Ru1 K2 52.92(6) . . ?
O4 Ru2 O4 91.7(2) 6_565 . ?
O4 Ru2 O6 179.22(15) 6_565 6_565 ?
O4 Ru2 O6 88.26(15) . 6_565 ?
O4 Ru2 O6 88.26(15) 6_565 . ?
O4 Ru2 O6 179.22(15) . . ?
O6 Ru2 O6 91.8(2) 6_565 . ?
O4 Ru2 Ru2 89.17(10) 6_565 5_767 ?
O4 Ru2 Ru2 89.17(10) . 5_767 ?
O6 Ru2 Ru2 90.06(11) 6_565 5_767 ?
O6 Ru2 Ru2 90.06(11) . 5_767 ?
O4 Ru2 Cl1 89.27(11) 6_565 . ?
O4 Ru2 Cl1 89.27(11) . . ?
O6 Ru2 Cl1 91.51(11) 6_565 . ?
O6 Ru2 Cl1 91.51(11) . . ?
Ru2 Ru2 Cl1 177.75(7) 5_767 . ?
O5 Zn1 O5 180.000(1) . 7_667 ?
O5 Zn1 O2 87.80(16) . . ?
O5 Zn1 O2 92.20(16) 7_667 . ?
O5 Zn1 O2 92.20(16) . 7_667 ?
O5 Zn1 O2 87.80(16) 7_667 7_667 ?
O2 Zn1 O2 180.000(1) . 7_667 ?
O5 Zn1 O7 85.46(14) . 7_667 ?
O5 Zn1 O7 94.54(14) 7_667 7_667 ?
O2 Zn1 O7 87.39(14) . 7_667 ?
O2 Zn1 O7 92.61(14) 7_667 7_667 ?
O5 Zn1 O7 94.54(14) . . ?
O5 Zn1 O7 85.46(14) 7_667 . ?
O2 Zn1 O7 92.61(14) . . ?
O2 Zn1 O7 87.39(14) 7_667 . ?
O7 Zn1 O7 180.000(1) 7_667 . ?
O10 Zn2 O10 180.000(1) . 7_556 ?
O10 Zn2 O9 89.57(16) . 7_556 ?
O10 Zn2 O9 90.43(16) 7_556 7_556 ?
O10 Zn2 O9 90.43(16) . . ?
O10 Zn2 O9 89.57(16) 7_556 . ?
O9 Zn2 O9 180.0 7_556 . ?
O10 Zn2 O8 90.22(17) . . ?
O10 Zn2 O8 89.78(17) 7_556 . ?
O9 Zn2 O8 91.86(16) 7_556 . ?
O9 Zn2 O8 88.14(16) . . ?
O10 Zn2 O8 89.78(17) . 7_556 ?
O10 Zn2 O8 90.22(17) 7_556 7_556 ?
O9 Zn2 O8 88.14(16) 7_556 7_556 ?
O9 Zn2 O8 91.86(16) . 7_556 ?
O8 Zn2 O8 180.00(18) . 7_556 ?
O10 Zn2 K2 93.09(12) . . ?
O10 Zn2 K2 86.91(12) 7_556 . ?
O9 Zn2 K2 44.13(12) 7_556 . ?
O9 Zn2 K2 135.87(12) . . ?
O8 Zn2 K2 135.77(12) . . ?
O8 Zn2 K2 44.23(12) 7_556 . ?
O10 Zn2 K2 86.91(12) . 7_556 ?
O10 Zn2 K2 93.09(12) 7_556 7_556 ?
O9 Zn2 K2 135.87(12) 7_556 7_556 ?
O9 Zn2 K2 44.13(12) . 7_556 ?
O8 Zn2 K2 44.23(12) . 7_556 ?
O8 Zn2 K2 135.77(12) 7_556 7_556 ?
K2 Zn2 K2 180.0 . 7_556 ?
O8 K2 O8 125.41(17) 7_556 4_556 ?
O8 K2 O9 59.56(11) 7_556 7_556 ?
O8 K2 O9 148.07(13) 4_556 7_556 ?
O8 K2 O9 148.07(13) 7_556 4_556 ?
O8 K2 O9 59.56(11) 4_556 4_556 ?
O9 K2 O9 99.39(17) 7_556 4_556 ?
O8 K2 Cl2 95.07(9) 7_556 . ?
O8 K2 Cl2 95.07(9) 4_556 . ?
O9 K2 Cl2 116.54(9) 7_556 . ?
O9 K2 Cl2 116.54(9) 4_556 . ?
O8 K2 Cl1 75.63(9) 7_556 5_666 ?
O8 K2 Cl1 75.63(9) 4_556 5_666 ?
O9 K2 Cl1 75.95(9) 7_556 5_666 ?
O9 K2 Cl1 75.95(9) 4_556 5_666 ?
Cl2 K2 Cl1 158.36(10) . 5_666 ?
O8 K2 O3 140.37(11) 7_556 6_565 ?
O8 K2 O3 90.33(10) 4_556 6_565 ?
O9 K2 O3 100.30(12) 7_556 6_565 ?
O9 K2 O3 61.50(10) 4_556 6_565 ?
Cl2 K2 O3 61.83(8) . 6_565 ?
Cl1 K2 O3 136.27(9) 5_666 6_565 ?
O8 K2 O3 90.33(10) 7_556 . ?
O8 K2 O3 140.37(11) 4_556 . ?
O9 K2 O3 61.50(10) 7_556 . ?
O9 K2 O3 100.30(12) 4_556 . ?
Cl2 K2 O3 61.83(8) . . ?
Cl1 K2 O3 136.27(9) 5_666 . ?
O3 K2 O3 50.95(13) 6_565 . ?
O8 K2 Cl2 67.48(9) 7_556 5_666 ?
O8 K2 Cl2 67.48(9) 4_556 5_666 ?
O9 K2 Cl2 127.03(9) 7_556 5_666 ?
O9 K2 Cl2 127.03(9) 4_556 5_666 ?
Cl2 K2 Cl2 67.73(7) . 5_666 ?
Cl1 K2 Cl2 90.63(8) 5_666 5_666 ?
O3 K2 Cl2 122.23(9) 6_565 5_666 ?
O3 K2 Cl2 122.23(9) . 5_666 ?
O8 K2 Ru1 110.99(9) 7_556 . ?
O8 K2 Ru1 110.99(9) 4_556 . ?
O9 K2 Ru1 92.21(9) 7_556 . ?
O9 K2 Ru1 92.21(9) 4_556 . ?
Cl2 K2 Ru1 40.27(4) . . ?
Cl1 K2 Ru1 161.38(8) 5_666 . ?
O3 K2 Ru1 30.96(6) 6_565 . ?
O3 K2 Ru1 30.96(6) . . ?
Cl2 K2 Ru1 107.99(7) 5_666 . ?
O8 K2 Zn2 30.17(8) 7_556 . ?
O8 K2 Zn2 143.65(11) 4_556 . ?
O9 K2 Zn2 29.53(8) 7_556 . ?
O9 K2 Zn2 124.26(10) 4_556 . ?
Cl2 K2 Zn2 110.02(3) . . ?
Cl1 K2 Zn2 71.48(3) 5_666 . ?
O3 K2 Zn2 124.37(8) 6_565 . ?
O3 K2 Zn2 75.90(6) . . ?
Cl2 K2 Zn2 97.53(4) 5_666 . ?
Ru1 K2 Zn2 105.08(3) . . ?
O8 K2 Zn2 143.65(11) 7_556 4_556 ?
O8 K2 Zn2 30.17(8) 4_556 4_556 ?
O9 K2 Zn2 124.26(10) 7_556 4_556 ?
O9 K2 Zn2 29.53(8) 4_556 4_556 ?
Cl2 K2 Zn2 110.02(3) . 4_556 ?
Cl1 K2 Zn2 71.48(3) 5_666 4_556 ?
O3 K2 Zn2 75.90(6) 6_565 4_556 ?
O3 K2 Zn2 124.37(8) . 4_556 ?
Cl2 K2 Zn2 97.53(4) 5_666 4_556 ?
Ru1 K2 Zn2 105.08(3) . 4_556 ?
Zn2 K2 Zn2 139.97(5) . 4_556 ?
Ru1 Cl2 K2 86.82(7) . . ?
Ru1 Cl2 K2 160.91(9) . 5_666 ?
K2 Cl2 K2 112.27(7) . 5_666 ?
Ru2 Cl1 K2 160.87(11) . 5_666 ?
C1 O1 Ru1 121.0(3) . . ?
C2 O4 Ru2 120.9(3) . . ?
C1 O3 Ru1 119.6(3) 5_667 . ?
C1 O3 K2 130.8(3) 5_667 . ?
Ru1 O3 K2 92.40(12) . . ?
C2 O6 Ru2 119.6(3) 5_767 . ?
C2 O5 Zn1 128.9(3) . . ?
C1 O2 Zn1 128.9(3) . . ?
O5 C2 O6 118.9(5) . 5_767 ?
O5 C2 O4 121.1(5) . . ?
O6 C2 O4 120.0(4) 5_767 . ?
O2 C1 O3 119.7(5) . 5_667 ?
O2 C1 O1 120.7(5) . . ?
O3 C1 O1 119.6(4) 5_667 . ?
Zn2 O8 K2 105.60(16) . 7_556 ?
Zn2 O9 K2 106.34(16) . 7_556 ?

_diffrn_measured_fraction_theta_max 0.994
_diffrn_reflns_theta_full        25.98
_diffrn_measured_fraction_theta_full 0.994
_refine_diff_density_max         0.917
_refine_diff_density_min         -0.833
_refine_diff_density_rms         0.246
_database_code_depnum_ccdc_archive 'CCDC 945135'
#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
#  on your local computer system.
# 
#  For further information on the CCDC, data deposition and
#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
#
data_c2m

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C4 Cl2 K O24 Ru2 Mn2'
_chemical_formula_sum            'C4 Cl2 K Mn2 O24 Ru2'
_chemical_formula_weight         854.06

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   'C 2/m'
_symmetry_space_group_name_Hall  '-C 2y'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'

_cell_length_a                   15.943(3)
_cell_length_b                   15.564(3)
_cell_length_c                   10.689(2)
_cell_angle_alpha                90.00
_cell_angle_beta                 104.867(3)
_cell_angle_gamma                90.00
_cell_volume                     2563.6(9)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       block
_exptl_crystal_colour            brown
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.13
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.213
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1628
_exptl_absorpt_coefficient_mu    2.583
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.6536
_exptl_absorpt_correction_T_max  0.7301
_exptl_absorpt_process_details   sadab

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'APEX II CCD'
_diffrn_measurement_method       '\w-\p scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            6334
_diffrn_reflns_av_R_equivalents  0.0292
_diffrn_reflns_av_sigmaI/netI    0.0342
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_limit_l_max       5
_diffrn_reflns_theta_min         1.86
_diffrn_reflns_theta_max         25.05
_reflns_number_total             2307
_reflns_number_gt                2080
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F^2^ against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F^2^, conventional R-factors R are based 
 on F, with F set to zero for negative F^2^. The threshold expression of 
 F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F^2^ are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.1177P)^2^+12.8106P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   .
_refine_ls_hydrogen_treatment    .
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         2307
_refine_ls_number_parameters     169
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0587
_refine_ls_R_factor_gt           0.0549
_refine_ls_wR_factor_ref         0.1618
_refine_ls_wR_factor_gt          0.1565
_refine_ls_goodness_of_fit_ref   1.112
_refine_ls_restrained_S_all      1.112
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.01108(4) 1.0000 0.39939(6) 0.0098(3) Uani 1 2 d S . .
Ru2 Ru 0.45341(4) 1.0000 0.39981(6) 0.0098(3) Uani 1 2 d S . .
Mn1 Mn 0.2500 1.2500 0.5000 0.0136(3) Uani 1 2 d S . .
Mn2 Mn -0.2500 0.7500 0.0000 0.0204(4) Uani 1 2 d S . .
K1 K -0.15725(16) 1.0000 0.0546(3) 0.0372(6) Uani 1 2 d S . .
Cl1 Cl 0.04530(16) 1.0000 0.1790(2) 0.0265(5) Uani 1 2 d S . .
Cl2 Cl 0.34117(17) 1.0000 0.1764(2) 0.0309(6) Uani 1 2 d S . .
C1 C 0.1223(4) 1.1202(4) 0.5783(6) 0.0146(12) Uani 1 1 d . . .
C2 C 0.4095(4) 1.1257(3) 0.5739(6) 0.0137(12) Uani 1 1 d . . .
O1 O 0.1021(3) 1.0925(3) 0.4584(4) 0.0203(10) Uani 1 1 d . . .
O2 O -0.0817(3) 0.9091(3) 0.3415(4) 0.0187(9) Uani 1 1 d . . .
O3 O 0.1832(3) 1.1741(3) 0.6146(4) 0.0233(10) Uani 1 1 d . . .
O4 O 0.3835(3) 1.0931(3) 0.4581(4) 0.0191(9) Uani 1 1 d . . .
O5 O 0.5243(3) 0.9060(3) 0.3437(4) 0.0176(9) Uani 1 1 d . . .
O6 O 0.3693(3) 1.1884(3) 0.6059(4) 0.0229(10) Uani 1 1 d . . .
O7 O 0.2228(3) 1.1496(3) 0.3423(4) 0.0190(9) Uani 1 1 d . . .
O8 O -0.2602(3) 0.8566(3) 0.1297(5) 0.0314(11) Uani 1 1 d . . .
O9 O -0.3592(4) 0.8001(3) -0.1416(6) 0.0376(13) Uani 1 1 d . . .
O10 O -0.1596(4) 0.8306(3) -0.0747(5) 0.0344(12) Uani 1 1 d . . .
O11 O 0.5168(4) 0.2831(3) 0.1911(6) 0.0437(14) Uani 1 1 d . . .
O12 O 0.4282(4) 0.0902(4) 0.8926(5) 0.0398(13) Uani 1 1 d . . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Ru1 0.0095(4) 0.0117(4) 0.0088(4) 0.000 0.0032(3) 0.000
Ru2 0.0078(4) 0.0094(4) 0.0111(4) 0.000 0.0005(3) 0.000
Mn1 0.0130(7) 0.0127(6) 0.0146(7) 0.0006(5) 0.0025(5) 0.0003(5)
Mn2 0.0219(8) 0.0192(7) 0.0182(7) 0.0012(5) 0.0020(6) -0.0012(6)
K1 0.0313(13) 0.0307(12) 0.0453(14) 0.000 0.0018(11) 0.000
Cl1 0.0309(13) 0.0354(12) 0.0161(11) 0.000 0.0114(9) 0.000
Cl2 0.0352(14) 0.0232(11) 0.0238(12) 0.000 -0.0118(10) 0.000
C1 0.015(3) 0.016(3) 0.013(3) 0.000(2) 0.003(2) 0.002(2)
C2 0.011(3) 0.012(3) 0.018(3) -0.001(2) 0.004(2) 0.000(2)
O1 0.019(2) 0.028(2) 0.015(2) -0.0044(18) 0.0066(18) -0.0129(19)
O2 0.021(2) 0.021(2) 0.014(2) -0.0022(17) 0.0045(18) -0.0080(18)
O3 0.023(2) 0.028(2) 0.019(2) -0.0045(19) 0.0056(19) -0.017(2)
O4 0.015(2) 0.023(2) 0.018(2) -0.0038(17) 0.0008(18) 0.0087(17)
O5 0.018(2) 0.020(2) 0.015(2) -0.0018(17) 0.0050(18) 0.0063(18)
O6 0.020(2) 0.022(2) 0.024(2) -0.0093(18) 0.0009(19) 0.0102(19)
O7 0.019(2) 0.017(2) 0.021(2) -0.0016(17) 0.0046(19) 0.0027(17)
O8 0.033(3) 0.037(3) 0.022(2) -0.002(2) 0.003(2) 0.002(2)
O9 0.032(3) 0.032(3) 0.041(3) 0.008(2) -0.006(3) 0.002(2)
O10 0.035(3) 0.035(3) 0.036(3) 0.004(2) 0.014(2) -0.006(2)
O11 0.038(3) 0.027(3) 0.058(4) 0.001(3) -0.001(3) 0.000(2)
O12 0.037(3) 0.051(3) 0.034(3) 0.007(2) 0.014(3) 0.011(3)

_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru1 O2 2.026(4) 6_575 ?
Ru1 O2 2.026(4) . ?
Ru1 O1 2.027(4) . ?
Ru1 O1 2.027(4) 6_575 ?
Ru1 Ru1 2.2674(13) 5_576 ?
Ru1 Cl1 2.551(2) . ?
Ru1 K1 3.964(3) . ?
Ru2 O4 2.021(4) 6_575 ?
Ru2 O4 2.021(4) . ?
Ru2 O5 2.030(4) 6_575 ?
Ru2 O5 2.030(4) . ?
Ru2 Ru2 2.2720(13) 5_676 ?
Ru2 Cl2 2.591(2) . ?
Mn1 O3 2.168(4) . ?
Mn1 O3 2.168(4) 7_576 ?
Mn1 O6 2.171(4) 7_576 ?
Mn1 O6 2.171(4) . ?
Mn1 O7 2.257(4) 7_576 ?
Mn1 O7 2.257(4) . ?
Mn2 O9 2.140(5) 7_465 ?
Mn2 O9 2.140(5) . ?
Mn2 O8 2.194(5) . ?
Mn2 O8 2.194(5) 7_465 ?
Mn2 O10 2.209(5) . ?
Mn2 O10 2.209(5) 7_465 ?
K1 O10 2.973(6) 6_575 ?
K1 O10 2.973(6) . ?
K1 O8 2.999(5) 6_575 ?
K1 O8 2.999(5) . ?
K1 Cl1 3.161(4) . ?
K1 O2 3.311(5) 6_575 ?
K1 O2 3.311(5) . ?
K1 Cl2 3.313(3) 5_575 ?
K1 Cl1 3.421(4) 5_575 ?
Cl1 K1 3.421(4) 5_575 ?
Cl2 K1 3.313(3) 5_575 ?
C1 O3 1.267(8) . ?
C1 O2 1.283(7) 5_576 ?
C1 O1 1.312(7) . ?
C2 O6 1.261(7) . ?
C2 O5 1.288(7) 5_676 ?
C2 O4 1.304(7) . ?
O2 C1 1.283(7) 5_576 ?
O5 C2 1.288(7) 5_676 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Ru1 O2 88.6(3) 6_575 . ?
O2 Ru1 O1 90.4(2) 6_575 . ?
O2 Ru1 O1 178.85(17) . . ?
O2 Ru1 O1 178.85(17) 6_575 6_575 ?
O2 Ru1 O1 90.42(19) . 6_575 ?
O1 Ru1 O1 90.5(3) . 6_575 ?
O2 Ru1 Ru1 90.61(12) 6_575 5_576 ?
O2 Ru1 Ru1 90.61(12) . 5_576 ?
O1 Ru1 Ru1 88.76(12) . 5_576 ?
O1 Ru1 Ru1 88.76(12) 6_575 5_576 ?
O2 Ru1 Cl1 91.74(13) 6_575 . ?
O2 Ru1 Cl1 91.74(13) . . ?
O1 Ru1 Cl1 88.93(13) . . ?
O1 Ru1 Cl1 88.93(12) 6_575 . ?
Ru1 Ru1 Cl1 176.73(7) 5_576 . ?
O2 Ru1 K1 56.56(12) 6_575 . ?
O2 Ru1 K1 56.56(12) . . ?
O1 Ru1 K1 123.31(13) . . ?
O1 Ru1 K1 123.31(13) 6_575 . ?
Ru1 Ru1 K1 130.47(6) 5_576 . ?
Cl1 Ru1 K1 52.80(7) . . ?
O4 Ru2 O4 91.6(3) 6_575 . ?
O4 Ru2 O5 179.25(18) 6_575 6_575 ?
O4 Ru2 O5 88.13(18) . 6_575 ?
O4 Ru2 O5 88.13(18) 6_575 . ?
O4 Ru2 O5 179.25(17) . . ?
O5 Ru2 O5 92.2(2) 6_575 . ?
O4 Ru2 Ru2 89.33(12) 6_575 5_676 ?
O4 Ru2 Ru2 89.33(12) . 5_676 ?
O5 Ru2 Ru2 89.98(13) 6_575 5_676 ?
O5 Ru2 Ru2 89.98(13) . 5_676 ?
O4 Ru2 Cl2 88.80(13) 6_575 . ?
O4 Ru2 Cl2 88.80(13) . . ?
O5 Ru2 Cl2 91.87(13) 6_575 . ?
O5 Ru2 Cl2 91.87(13) . . ?
Ru2 Ru2 Cl2 177.33(8) 5_676 . ?
O3 Mn1 O3 180.0(2) . 7_576 ?
O3 Mn1 O6 92.52(19) . 7_576 ?
O3 Mn1 O6 87.48(19) 7_576 7_576 ?
O3 Mn1 O6 87.48(19) . . ?
O3 Mn1 O6 92.52(19) 7_576 . ?
O6 Mn1 O6 180.000(1) 7_576 . ?
O3 Mn1 O7 89.03(16) . 7_576 ?
O3 Mn1 O7 90.97(16) 7_576 7_576 ?
O6 Mn1 O7 93.35(15) 7_576 7_576 ?
O6 Mn1 O7 86.65(15) . 7_576 ?
O3 Mn1 O7 90.97(16) . . ?
O3 Mn1 O7 89.03(16) 7_576 . ?
O6 Mn1 O7 86.65(15) 7_576 . ?
O6 Mn1 O7 93.35(15) . . ?
O7 Mn1 O7 180.000(1) 7_576 . ?
O9 Mn2 O9 180.000(1) 7_465 . ?
O9 Mn2 O8 90.4(2) 7_465 . ?
O9 Mn2 O8 89.6(2) . . ?
O9 Mn2 O8 89.6(2) 7_465 7_465 ?
O9 Mn2 O8 90.4(2) . 7_465 ?
O8 Mn2 O8 180.0 . 7_465 ?
O9 Mn2 O10 88.5(2) 7_465 . ?
O9 Mn2 O10 91.5(2) . . ?
O8 Mn2 O10 87.7(2) . . ?
O8 Mn2 O10 92.3(2) 7_465 . ?
O9 Mn2 O10 91.5(2) 7_465 7_465 ?
O9 Mn2 O10 88.5(2) . 7_465 ?
O8 Mn2 O10 92.3(2) . 7_465 ?
O8 Mn2 O10 87.7(2) 7_465 7_465 ?
O10 Mn2 O10 180.000(1) . 7_465 ?
O10 K1 O10 125.0(2) 6_575 . ?
O10 K1 O8 61.43(14) 6_575 6_575 ?
O10 K1 O8 147.36(17) . 6_575 ?
O10 K1 O8 147.36(17) 6_575 . ?
O10 K1 O8 61.43(14) . . ?
O8 K1 O8 96.2(2) 6_575 . ?
O10 K1 Cl1 94.90(12) 6_575 . ?
O10 K1 Cl1 94.90(12) . . ?
O8 K1 Cl1 117.21(12) 6_575 . ?
O8 K1 Cl1 117.21(12) . . ?
O10 K1 O2 90.55(13) 6_575 6_575 ?
O10 K1 O2 140.16(14) . 6_575 ?
O8 K1 O2 61.83(13) 6_575 6_575 ?
O8 K1 O2 99.44(14) . 6_575 ?
Cl1 K1 O2 61.36(9) . 6_575 ?
O10 K1 O2 140.16(14) 6_575 . ?
O10 K1 O2 90.55(13) . . ?
O8 K1 O2 99.44(14) 6_575 . ?
O8 K1 O2 61.83(13) . . ?
Cl1 K1 O2 61.36(9) . . ?
O2 K1 O2 50.60(15) 6_575 . ?
O10 K1 Cl2 75.55(12) 6_575 5_575 ?
O10 K1 Cl2 75.55(12) . 5_575 ?
O8 K1 Cl2 76.06(12) 6_575 5_575 ?
O8 K1 Cl2 76.06(12) . 5_575 ?
Cl1 K1 Cl2 157.94(11) . 5_575 ?
O2 K1 Cl2 137.06(11) 6_575 5_575 ?
O2 K1 Cl2 137.06(11) . 5_575 ?
O10 K1 Cl1 66.89(11) 6_575 5_575 ?
O10 K1 Cl1 66.89(11) . 5_575 ?
O8 K1 Cl1 128.25(11) 6_575 5_575 ?
O8 K1 Cl1 128.25(11) . 5_575 ?
Cl1 K1 Cl1 68.85(8) . 5_575 ?
O2 K1 Cl1 122.82(11) 6_575 5_575 ?
O2 K1 Cl1 122.82(11) . 5_575 ?
Cl2 K1 Cl1 89.09(9) 5_575 5_575 ?
O10 K1 Ru1 110.92(12) 6_575 . ?
O10 K1 Ru1 110.92(12) . . ?
O8 K1 Ru1 92.14(11) 6_575 . ?
O8 K1 Ru1 92.14(11) . . ?
Cl1 K1 Ru1 40.00(5) . . ?
O2 K1 Ru1 30.70(8) 6_575 . ?
O2 K1 Ru1 30.70(8) . . ?
Cl2 K1 Ru1 162.06(10) 5_575 . ?
Cl1 K1 Ru1 108.85(8) 5_575 . ?
Ru1 Cl1 K1 87.20(8) . . ?
Ru1 Cl1 K1 161.65(11) . 5_575 ?
K1 Cl1 K1 111.15(8) . 5_575 ?
Ru2 Cl2 K1 163.06(12) . 5_575 ?
O3 C1 O2 120.6(5) . 5_576 ?
O3 C1 O1 119.6(5) . . ?
O2 C1 O1 119.8(5) 5_576 . ?
O6 C2 O5 119.7(5) . 5_676 ?
O6 C2 O4 119.9(5) . . ?
O5 C2 O4 120.3(5) 5_676 . ?
C1 O1 Ru1 120.9(4) . . ?
C1 O2 Ru1 119.9(4) 5_576 . ?
C1 O2 K1 130.1(4) 5_576 . ?
Ru1 O2 K1 92.75(15) . . ?
C1 O3 Mn1 129.5(4) . . ?
C2 O4 Ru2 120.4(4) . . ?
C2 O5 Ru2 119.7(4) 5_676 . ?
C2 O6 Mn1 129.6(4) . . ?
Mn2 O8 K1 105.04(19) . . ?
Mn2 O10 K1 105.5(2) . . ?

_diffrn_measured_fraction_theta_max 0.973
_diffrn_reflns_theta_full        25.05
_diffrn_measured_fraction_theta_full 0.973
_refine_diff_density_max         4.691
_refine_diff_density_min         -1.303
_refine_diff_density_rms         0.268
_database_code_depnum_ccdc_archive 'CCDC 945136'