# Electronic Supplementary Material (ESI) for Dalton Transactions
# This journal is © The Royal Society of Chemistry 2013

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#                                CCDC 
# 
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# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
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#  fide research purposes only. It may contain copyright material
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data_1

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C38 H76 Dy4 N4 O26'
_chemical_formula_weight         1655.03

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Orthorhombic
_symmetry_space_group_name_H-M   Pbca

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z-1/2'
'-x-1/2, y-1/2, z'

_cell_length_a                   14.093(3)
_cell_length_b                   18.890(4)
_cell_length_c                   19.669(4)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     5236.2(19)
_cell_formula_units_Z            4
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    15765
_cell_measurement_theta_min      1.0779
_cell_measurement_theta_max      27.4808

_exptl_crystal_description       block
_exptl_crystal_colour            Colorless
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.16
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.099
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3216
_exptl_absorpt_coefficient_mu    5.730
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5382
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area dtetector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean '15x15 microns'
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            29077
_diffrn_reflns_av_R_equivalents  0.0550
_diffrn_reflns_av_sigmaI/netI    0.0318
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_theta_min         2.39
_diffrn_reflns_theta_max         25.03
_reflns_number_total             4598
_reflns_number_gt                4463
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'SMART (Bruker, 2000)'
_computing_cell_refinement       SMART
_computing_data_reduction        'SAINT (Bruker, 2000)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'SHELXL-97 (Sheldrick, 1997)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'

_refine_special_details          
; 
 Refinement of F^2^ against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F^2^, conventional R-factors R are based 
 on F, with F set to zero for negative F^2^. The threshold expression of 
 F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F^2^ are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0183P)^2^+28.9720P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         4598
_refine_ls_number_parameters     334
_refine_ls_number_restraints     28
_refine_ls_R_factor_all          0.0363
_refine_ls_R_factor_gt           0.0343
_refine_ls_wR_factor_ref         0.0726
_refine_ls_wR_factor_gt          0.0716
_refine_ls_goodness_of_fit_ref   1.188
_refine_ls_restrained_S_all      1.185
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 1.005661(18) 0.065494(13) 0.440233(13) 0.01333(8) Uani 1 1 d . . .
Dy2 Dy 0.827932(19) 0.071311(13) 0.590126(13) 0.01562(8) Uani 1 1 d . . .
O1 O 1.0948(3) 0.16853(19) 0.4686(2) 0.0186(8) Uani 1 1 d . . .
H1B H 1.0802 0.2058 0.4905 0.028 Uiso 1 1 d R . .
O2 O 1.1414(3) 0.0421(2) 0.3812(2) 0.0185(8) Uani 1 1 d . . .
O3 O 1.1364(3) 0.2756(2) 0.2789(2) 0.0268(10) Uani 1 1 d . . .
H3A H 1.1535 0.3085 0.3031 0.040 Uiso 1 1 calc R . .
O4 O 0.8772(3) 0.01184(19) 0.49299(18) 0.0146(8) Uani 1 1 d . . .
O5 O 1.0080(3) -0.06768(18) 0.43126(19) 0.0148(8) Uani 1 1 d . . .
O6 O 0.7054(3) -0.0247(2) 0.3213(2) 0.0267(10) Uani 1 1 d . . .
H6C H 0.6763 -0.0377 0.2874 0.040 Uiso 1 1 calc R . .
O7 O 0.8942(3) 0.1585(2) 0.4357(2) 0.0263(10) Uani 1 1 d . . .
O8 O 0.7763(3) 0.1534(2) 0.5109(2) 0.0301(10) Uani 1 1 d . . .
O9 O 0.6826(3) 0.1077(2) 0.6459(2) 0.0278(10) Uani 1 1 d . . .
O10 O 0.6708(3) 0.0217(2) 0.5720(2) 0.0299(10) Uani 1 1 d . . .
O11 O 0.8765(3) 0.1832(2) 0.6430(2) 0.0215(9) Uani 1 1 d . . .
O12 O 0.8742(3) 0.0890(2) 0.7083(2) 0.0206(9) Uani 1 1 d . . .
O13 O 0.4941(4) -0.2470(2) 0.5579(2) 0.0359(12) Uani 1 1 d D . .
H13D H 0.5307 -0.2668 0.5975 0.043 Uiso 1 1 d R A .
N1 N 1.0409(3) 0.1474(2) 0.3334(2) 0.0188(10) Uani 1 1 d . . .
H1 H 1.0131 0.1800 0.3386 0.023 Uiso 1 1 d R . .
N2 N 0.8870(3) 0.0241(2) 0.3538(2) 0.0153(10) Uani 1 1 d . . .
H2 H 0.8446 0.0488 0.3520 0.018 Uiso 1 1 d R . .
C1 C 1.1408(4) 0.1667(3) 0.3488(3) 0.0166(11) Uani 1 1 d . . .
C2 C 1.1419(5) 0.2082(3) 0.4149(3) 0.0211(13) Uani 1 1 d . . .
H2A H 1.2070 0.2179 0.4280 0.025 Uiso 1 1 calc R . .
H2B H 1.1099 0.2532 0.4083 0.025 Uiso 1 1 calc R . .
C3 C 1.1972(4) 0.0968(3) 0.3537(3) 0.0203(12) Uani 1 1 d . . .
H3B H 1.2187 0.0831 0.3087 0.024 Uiso 1 1 calc R . .
H3C H 1.2527 0.1039 0.3821 0.024 Uiso 1 1 calc R . .
C4 C 1.1888(4) 0.2142(3) 0.2956(3) 0.0222(13) Uani 1 1 d . . .
H4A H 1.2505 0.2285 0.3127 0.027 Uiso 1 1 calc R . .
H4B H 1.1990 0.1869 0.2546 0.027 Uiso 1 1 calc R . .
C5 C 1.0277(4) 0.1234(3) 0.2628(3) 0.0233(13) Uani 1 1 d . . .
H5A H 1.0756 0.0882 0.2522 0.028 Uiso 1 1 calc R . .
H5B H 1.0370 0.1632 0.2324 0.028 Uiso 1 1 calc R . .
C6 C 0.9306(4) 0.0919(3) 0.2500(3) 0.0215(13) Uani 1 1 d . . .
H6A H 0.9208 0.0887 0.2013 0.026 Uiso 1 1 calc R . .
H6B H 0.8831 0.1241 0.2680 0.026 Uiso 1 1 calc R . .
C7 C 0.9145(4) 0.0191(3) 0.2810(3) 0.0203(12) Uani 1 1 d . . .
H7A H 0.8648 -0.0052 0.2560 0.024 Uiso 1 1 calc R . .
H7B H 0.9722 -0.0087 0.2770 0.024 Uiso 1 1 calc R . .
C8 C 0.8510(4) -0.0434(3) 0.3829(3) 0.0179(12) Uani 1 1 d . . .
C9 C 0.8094(4) -0.0237(3) 0.4521(3) 0.0178(12) Uani 1 1 d . . .
H9A H 0.7545 0.0066 0.4457 0.021 Uiso 1 1 calc R . .
H9B H 0.7885 -0.0663 0.4752 0.021 Uiso 1 1 calc R . .
C10 C 0.9329(4) -0.0947(3) 0.3895(3) 0.0169(12) Uani 1 1 d . . .
H10A H 0.9098 -0.1386 0.4090 0.020 Uiso 1 1 calc R . .
H10B H 0.9577 -0.1051 0.3447 0.020 Uiso 1 1 calc R . .
C11 C 0.7719(4) -0.0769(3) 0.3398(3) 0.0190(12) Uani 1 1 d . . .
H11A H 0.7990 -0.0980 0.2992 0.023 Uiso 1 1 calc R . .
H11B H 0.7406 -0.1140 0.3656 0.023 Uiso 1 1 calc R . .
C12 C 0.8127(4) 0.1749(3) 0.4566(3) 0.0239(13) Uani 1 1 d . . .
C13 C 0.7547(6) 0.2258(5) 0.4152(4) 0.055(2) Uani 1 1 d . . .
H13A H 0.6947 0.2336 0.4371 0.082 Uiso 1 1 calc R . .
H13B H 0.7443 0.2065 0.3707 0.082 Uiso 1 1 calc R . .
H13C H 0.7880 0.2700 0.4113 0.082 Uiso 1 1 calc R . .
C14 C 0.6319(5) 0.0650(3) 0.6117(3) 0.0247(14) Uani 1 1 d . . .
C15 C 0.5265(5) 0.0660(4) 0.6200(4) 0.0381(17) Uani 1 1 d . . .
H15A H 0.5072 0.0261 0.6468 0.046 Uiso 1 1 d R . .
H15B H 0.4973 0.0637 0.5760 0.046 Uiso 1 1 d R . .
H15C H 0.5079 0.1089 0.6425 0.046 Uiso 1 1 d R . .
C16 C 0.8843(4) 0.1551(3) 0.7010(3) 0.0178(12) Uani 1 1 d . . .
C17 C 0.9073(5) 0.2005(3) 0.7609(3) 0.0281(14) Uani 1 1 d . . .
H17A H 0.9749 0.2031 0.7664 0.042 Uiso 1 1 calc R . .
H17B H 0.8795 0.1805 0.8010 0.042 Uiso 1 1 calc R . .
H17C H 0.8824 0.2472 0.7537 0.042 Uiso 1 1 calc R . .
C19 C 0.5450(9) -0.1829(5) 0.5436(10) 0.047(4) Uani 0.634(12) 1 d PDU A 1
H19A H 0.5685 -0.1838 0.4973 0.057 Uiso 0.634(12) 1 calc PR A 1
H19B H 0.5988 -0.1787 0.5741 0.057 Uiso 0.634(12) 1 calc PR A 1
C18 C 0.4797(10) -0.1213(6) 0.5530(7) 0.059(3) Uani 0.634(12) 1 d PDU A 1
H18A H 0.4231 -0.1285 0.5267 0.089 Uiso 0.634(12) 1 calc PR A 1
H18B H 0.5107 -0.0788 0.5382 0.089 Uiso 0.634(12) 1 calc PR A 1
H18C H 0.4633 -0.1170 0.6002 0.089 Uiso 0.634(12) 1 calc PR A 1
C18' C 0.5954(16) -0.1563(13) 0.5162(12) 0.059(3) Uani 0.366(12) 1 d PDU A 2
H18D H 0.5915 -0.1762 0.4714 0.089 Uiso 0.366(12) 1 calc PR A 2
H18E H 0.6484 -0.1767 0.5399 0.089 Uiso 0.366(12) 1 calc PR A 2
H18F H 0.6039 -0.1060 0.5129 0.089 Uiso 0.366(12) 1 calc PR A 2
C19' C 0.5058(19) -0.1719(9) 0.5543(18) 0.047(4) Uani 0.366(12) 1 d PDU A 2
H19C H 0.5093 -0.1521 0.5997 0.057 Uiso 0.366(12) 1 calc PR A 2
H19D H 0.4520 -0.1508 0.5311 0.057 Uiso 0.366(12) 1 calc PR A 2

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Dy1 0.01391(14) 0.01312(14) 0.01297(15) -0.00075(10) 0.00099(9) -0.00084(10)
Dy2 0.01707(15) 0.01545(14) 0.01435(15) -0.00071(10) 0.00247(10) 0.00154(10)
O1 0.024(2) 0.0127(18) 0.020(2) -0.0026(16) 0.0006(16) -0.0057(16)
O2 0.018(2) 0.0159(19) 0.022(2) 0.0029(16) 0.0066(16) 0.0024(16)
O3 0.039(3) 0.015(2) 0.027(2) 0.0021(17) -0.0093(19) -0.0042(19)
O4 0.0125(19) 0.0173(19) 0.0138(19) -0.0039(15) -0.0010(14) -0.0039(15)
O5 0.014(2) 0.0141(19) 0.016(2) -0.0003(15) 0.0009(15) -0.0016(15)
O6 0.023(2) 0.028(2) 0.029(2) -0.0078(19) -0.0098(18) 0.0035(19)
O7 0.023(2) 0.021(2) 0.035(3) -0.0007(19) 0.0043(19) 0.0037(18)
O8 0.038(3) 0.030(2) 0.022(2) 0.0090(19) 0.0048(19) 0.014(2)
O9 0.020(2) 0.032(2) 0.031(3) -0.010(2) 0.0075(18) 0.0019(19)
O10 0.024(2) 0.029(2) 0.037(3) -0.008(2) 0.0016(19) 0.000(2)
O11 0.024(2) 0.017(2) 0.023(2) 0.0008(17) 0.0026(17) 0.0001(17)
O12 0.022(2) 0.021(2) 0.018(2) -0.0006(17) 0.0024(16) 0.0012(17)
O13 0.049(3) 0.020(2) 0.039(3) 0.001(2) -0.013(2) -0.005(2)
N1 0.018(3) 0.018(2) 0.020(3) -0.002(2) 0.0003(19) 0.001(2)
N2 0.014(2) 0.014(2) 0.018(2) -0.0012(19) -0.0008(18) 0.0001(19)
C1 0.016(3) 0.015(3) 0.019(3) 0.004(2) 0.001(2) -0.005(2)
C2 0.036(4) 0.015(3) 0.013(3) -0.002(2) -0.001(2) -0.009(3)
C3 0.018(3) 0.018(3) 0.025(3) 0.001(2) 0.003(2) -0.006(2)
C4 0.021(3) 0.022(3) 0.024(3) 0.005(3) 0.002(2) -0.006(3)
C5 0.028(3) 0.020(3) 0.022(3) -0.001(2) 0.003(2) -0.007(3)
C6 0.027(3) 0.022(3) 0.015(3) 0.006(2) -0.006(2) -0.006(3)
C7 0.027(3) 0.017(3) 0.017(3) -0.001(2) -0.001(2) -0.003(2)
C8 0.018(3) 0.017(3) 0.019(3) -0.004(2) -0.005(2) -0.004(2)
C9 0.015(3) 0.020(3) 0.019(3) -0.005(2) 0.001(2) 0.000(2)
C10 0.020(3) 0.016(3) 0.015(3) 0.000(2) -0.004(2) -0.005(2)
C11 0.016(3) 0.025(3) 0.016(3) -0.003(2) -0.001(2) -0.002(2)
C12 0.026(3) 0.023(3) 0.023(3) 0.000(3) 0.002(3) 0.007(3)
C13 0.042(5) 0.076(6) 0.046(5) 0.037(4) 0.018(4) 0.034(4)
C14 0.025(3) 0.024(3) 0.024(3) 0.008(3) 0.004(3) 0.008(3)
C15 0.024(4) 0.045(4) 0.045(4) -0.002(3) 0.001(3) 0.005(3)
C16 0.009(3) 0.021(3) 0.023(3) -0.003(2) 0.004(2) 0.000(2)
C17 0.029(3) 0.031(3) 0.024(3) -0.005(3) -0.004(3) 0.008(3)
C19 0.055(10) 0.038(6) 0.049(7) 0.008(5) -0.007(8) -0.012(6)
C18 0.086(8) 0.037(6) 0.054(7) -0.001(5) -0.012(6) 0.006(6)
C18' 0.086(8) 0.037(6) 0.054(7) -0.001(5) -0.012(6) 0.006(6)
C19' 0.055(10) 0.038(6) 0.049(7) 0.008(5) -0.007(8) -0.012(6)

_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O2 2.281(4) . ?
Dy1 O4 2.320(4) . ?
Dy1 O7 2.358(4) . ?
Dy1 O1 2.382(4) . ?
Dy1 N2 2.510(4) . ?
Dy1 O5 2.522(4) . ?
Dy1 O5 2.535(4) 5_756 ?
Dy1 O4 2.566(4) 5_756 ?
Dy1 N1 2.657(5) . ?
Dy1 Dy1 3.4170(7) 5_756 ?
Dy1 Dy2 3.5405(6) 5_756 ?
Dy1 Dy2 3.8701(7) . ?
Dy2 O2 2.258(4) 5_756 ?
Dy2 O8 2.316(4) . ?
Dy2 O4 2.323(4) . ?
Dy2 O5 2.351(4) 5_756 ?
Dy2 O9 2.423(4) . ?
Dy2 O10 2.431(4) . ?
Dy2 O12 2.437(4) . ?
Dy2 O11 2.454(4) . ?
Dy2 C14 2.797(6) . ?
Dy2 C16 2.809(6) . ?
Dy2 Dy1 3.5405(6) 5_756 ?
O1 C2 1.456(7) . ?
O1 H1B 0.8501 . ?
O2 C3 1.405(7) . ?
O2 Dy2 2.258(4) 5_756 ?
O3 C4 1.413(7) . ?
O3 H3A 0.8200 . ?
O4 C9 1.418(6) . ?
O4 Dy1 2.566(4) 5_756 ?
O5 C10 1.433(6) . ?
O5 Dy2 2.351(4) 5_756 ?
O5 Dy1 2.535(4) 5_756 ?
O6 C11 1.408(7) . ?
O6 H6C 0.8200 . ?
O7 C12 1.258(7) . ?
O8 C12 1.253(7) . ?
O9 C14 1.269(8) . ?
O10 C14 1.257(7) . ?
O11 C16 1.263(7) . ?
O12 C16 1.264(7) . ?
O13 C19' 1.430(16) . ?
O13 C19 1.435(11) . ?
O13 H13D 1.0064 . ?
N1 C5 1.473(7) . ?
N1 C1 1.485(7) . ?
N1 H1 0.7380 . ?
N2 C7 1.485(7) . ?
N2 C8 1.487(7) . ?
N2 H2 0.7596 . ?
C1 C2 1.518(8) . ?
C1 C4 1.536(7) . ?
C1 C3 1.545(8) . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C3 H3B 0.9700 . ?
C3 H3C 0.9700 . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
C5 C6 1.513(8) . ?
C5 H5A 0.9700 . ?
C5 H5B 0.9700 . ?
C6 C7 1.522(8) . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C8 C10 1.513(8) . ?
C8 C9 1.528(8) . ?
C8 C11 1.538(7) . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C12 C13 1.503(9) . ?
C13 H13A 0.9600 . ?
C13 H13B 0.9600 . ?
C13 H13C 0.9600 . ?
C14 C15 1.494(9) . ?
C15 H15A 0.9601 . ?
C15 H15B 0.9599 . ?
C15 H15C 0.9600 . ?
C16 C17 1.493(8) . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C19 C18 1.496(9) . ?
C19 H19A 0.9700 . ?
C19 H19B 0.9700 . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C18' C19' 1.499(9) . ?
C18' H18D 0.9600 . ?
C18' H18E 0.9600 . ?
C18' H18F 0.9600 . ?
C19' H19C 0.9700 . ?
C19' H19D 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Dy1 O4 142.92(13) . . ?
O2 Dy1 O7 133.13(14) . . ?
O4 Dy1 O7 79.77(14) . . ?
O2 Dy1 O1 80.50(14) . . ?
O4 Dy1 O1 131.57(13) . . ?
O7 Dy1 O1 75.61(14) . . ?
O2 Dy1 N2 98.85(15) . . ?
O4 Dy1 N2 69.34(14) . . ?
O7 Dy1 N2 76.27(15) . . ?
O1 Dy1 N2 139.83(14) . . ?
O2 Dy1 O5 76.15(13) . . ?
O4 Dy1 O5 66.77(12) . . ?
O7 Dy1 O5 138.50(13) . . ?
O1 Dy1 O5 145.53(13) . . ?
N2 Dy1 O5 69.54(13) . . ?
O2 Dy1 O5 125.03(13) . 5_756 ?
O4 Dy1 O5 60.13(12) . 5_756 ?
O7 Dy1 O5 88.56(13) . 5_756 ?
O1 Dy1 O5 78.07(12) . 5_756 ?
N2 Dy1 O5 129.06(13) . 5_756 ?
O5 Dy1 O5 94.99(11) . 5_756 ?
O2 Dy1 O4 67.09(13) . 5_756 ?
O4 Dy1 O4 91.40(12) . 5_756 ?
O7 Dy1 O4 150.69(13) . 5_756 ?
O1 Dy1 O4 90.36(12) . 5_756 ?
N2 Dy1 O4 126.73(13) . 5_756 ?
O5 Dy1 O4 57.29(11) . 5_756 ?
O5 Dy1 O4 63.11(11) 5_756 5_756 ?
O2 Dy1 N1 63.45(14) . . ?
O4 Dy1 N1 138.97(14) . . ?
O7 Dy1 N1 70.19(15) . . ?
O1 Dy1 N1 67.09(14) . . ?
N2 Dy1 N1 76.71(14) . . ?
O5 Dy1 N1 121.54(13) . . ?
O5 Dy1 N1 142.51(13) 5_756 . ?
O4 Dy1 N1 128.03(13) 5_756 . ?
O2 Dy1 Dy1 104.44(10) . 5_756 ?
O4 Dy1 Dy1 48.65(9) . 5_756 ?
O7 Dy1 Dy1 122.29(10) . 5_756 ?
O1 Dy1 Dy1 117.08(9) . 5_756 ?
N2 Dy1 Dy1 102.10(10) . 5_756 ?
O5 Dy1 Dy1 47.66(9) . 5_756 ?
O5 Dy1 Dy1 47.33(8) 5_756 5_756 ?
O4 Dy1 Dy1 42.74(8) 5_756 5_756 ?
N1 Dy1 Dy1 167.10(10) . 5_756 ?
O2 Dy1 Dy2 38.50(9) . 5_756 ?
O4 Dy1 Dy2 105.87(9) . 5_756 ?
O7 Dy1 Dy2 168.12(11) . 5_756 ?
O1 Dy1 Dy2 106.66(10) . 5_756 ?
N2 Dy1 Dy2 95.72(10) . 5_756 ?
O5 Dy1 Dy2 41.54(8) . 5_756 ?
O5 Dy1 Dy2 103.31(8) 5_756 5_756 ?
O4 Dy1 Dy2 40.94(8) 5_756 5_756 ?
N1 Dy1 Dy2 99.65(10) . 5_756 ?
Dy1 Dy1 Dy2 67.568(14) 5_756 5_756 ?
O2 Dy1 Dy2 159.40(10) . . ?
O4 Dy1 Dy2 33.55(9) . . ?
O7 Dy1 Dy2 64.94(10) . . ?
O1 Dy1 Dy2 98.03(9) . . ?
N2 Dy1 Dy2 95.39(10) . . ?
O5 Dy1 Dy2 95.16(8) . . ?
O5 Dy1 Dy2 36.00(8) 5_756 . ?
O4 Dy1 Dy2 92.44(8) 5_756 . ?
N1 Dy1 Dy2 135.01(10) . . ?
Dy1 Dy1 Dy2 57.736(12) 5_756 . ?
Dy2 Dy1 Dy2 125.303(10) 5_756 . ?
O2 Dy2 O8 149.71(15) 5_756 . ?
O2 Dy2 O4 71.88(13) 5_756 . ?
O8 Dy2 O4 82.19(14) . . ?
O2 Dy2 O5 80.15(13) 5_756 5_756 ?
O8 Dy2 O5 102.03(14) . 5_756 ?
O4 Dy2 O5 62.92(13) . 5_756 ?
O2 Dy2 O9 108.53(14) 5_756 . ?
O8 Dy2 O9 81.31(15) . . ?
O4 Dy2 O9 139.64(14) . . ?
O5 Dy2 O9 157.04(14) 5_756 . ?
O2 Dy2 O10 81.07(15) 5_756 . ?
O8 Dy2 O10 82.69(16) . . ?
O4 Dy2 O10 88.01(14) . . ?
O5 Dy2 O10 149.14(13) 5_756 . ?
O9 Dy2 O10 53.51(14) . . ?
O2 Dy2 O12 80.87(14) 5_756 . ?
O8 Dy2 O12 129.36(14) . . ?
O4 Dy2 O12 140.44(13) . . ?
O5 Dy2 O12 84.92(13) 5_756 . ?
O9 Dy2 O12 75.87(14) . . ?
O10 Dy2 O12 115.89(14) . . ?
O2 Dy2 O11 131.21(14) 5_756 . ?
O8 Dy2 O11 78.25(15) . . ?
O4 Dy2 O11 133.00(13) . . ?
O5 Dy2 O11 80.00(13) 5_756 . ?
O9 Dy2 O11 78.47(14) . . ?
O10 Dy2 O11 130.44(14) . . ?
O12 Dy2 O11 53.32(13) . . ?
O2 Dy2 C14 96.34(15) 5_756 . ?
O8 Dy2 C14 79.64(17) . . ?
O4 Dy2 C14 113.54(16) . . ?
O5 Dy2 C14 175.59(16) 5_756 . ?
O9 Dy2 C14 26.93(16) . . ?
O10 Dy2 C14 26.65(16) . . ?
O12 Dy2 C14 97.20(16) . . ?
O11 Dy2 C14 104.37(16) . . ?
O2 Dy2 C16 106.68(16) 5_756 . ?
O8 Dy2 C16 103.56(16) . . ?
O4 Dy2 C16 145.75(14) . . ?
O5 Dy2 C16 82.95(14) 5_756 . ?
O9 Dy2 C16 74.22(15) . . ?
O10 Dy2 C16 126.05(15) . . ?
O12 Dy2 C16 26.69(15) . . ?
O11 Dy2 C16 26.70(15) . . ?
C14 Dy2 C16 100.68(17) . . ?
O2 Dy2 Dy1 38.97(9) 5_756 5_756 ?
O8 Dy2 Dy1 125.68(11) . 5_756 ?
O4 Dy2 Dy1 46.38(9) . 5_756 ?
O5 Dy2 Dy1 45.34(9) 5_756 5_756 ?
O9 Dy2 Dy1 147.49(11) . 5_756 ?
O10 Dy2 Dy1 107.29(10) . 5_756 ?
O12 Dy2 Dy1 94.81(9) . 5_756 ?
O11 Dy2 Dy1 121.03(9) . 5_756 ?
C14 Dy2 Dy1 130.43(13) . 5_756 ?
C16 Dy2 Dy1 110.79(11) . 5_756 ?
O2 Dy2 Dy1 92.26(10) 5_756 . ?
O8 Dy2 Dy1 73.13(11) . . ?
O4 Dy2 Dy1 33.50(9) . . ?
O5 Dy2 Dy1 39.32(9) 5_756 . ?
O9 Dy2 Dy1 154.15(11) . . ?
O10 Dy2 Dy1 117.83(11) . . ?
O12 Dy2 Dy1 123.87(9) . . ?
O11 Dy2 Dy1 99.59(9) . . ?
C14 Dy2 Dy1 138.89(13) . . ?
C16 Dy2 Dy1 115.12(11) . . ?
Dy1 Dy2 Dy1 54.697(10) 5_756 . ?
C2 O1 Dy1 119.4(3) . . ?
C2 O1 H1B 92.9 . . ?
Dy1 O1 H1B 131.9 . . ?
C3 O2 Dy2 133.3(3) . 5_756 ?
C3 O2 Dy1 121.5(3) . . ?
Dy2 O2 Dy1 102.53(15) 5_756 . ?
C4 O3 H3A 109.5 . . ?
C9 O4 Dy1 118.6(3) . . ?
C9 O4 Dy2 119.6(3) . . ?
Dy1 O4 Dy2 112.95(14) . . ?
C9 O4 Dy1 117.0(3) . 5_756 ?
Dy1 O4 Dy1 88.60(12) . 5_756 ?
Dy2 O4 Dy1 92.68(12) . 5_756 ?
C10 O5 Dy2 127.9(3) . 5_756 ?
C10 O5 Dy1 112.7(3) . . ?
Dy2 O5 Dy1 93.11(12) 5_756 . ?
C10 O5 Dy1 121.4(3) . 5_756 ?
Dy2 O5 Dy1 104.68(14) 5_756 5_756 ?
Dy1 O5 Dy1 85.01(11) . 5_756 ?
C11 O6 H6C 109.5 . . ?
C12 O7 Dy1 141.2(4) . . ?
C12 O8 Dy2 131.5(4) . . ?
C14 O9 Dy2 93.2(4) . . ?
C14 O10 Dy2 93.2(4) . . ?
C16 O11 Dy2 92.5(3) . . ?
C16 O12 Dy2 93.3(3) . . ?
C19' O13 C19 25.3(10) . . ?
C19' O13 H13D 110.4 . . ?
C19 O13 H13D 102.1 . . ?
C5 N1 C1 112.9(4) . . ?
C5 N1 Dy1 122.9(3) . . ?
C1 N1 Dy1 99.1(3) . . ?
C5 N1 H1 108.8 . . ?
C1 N1 H1 105.7 . . ?
Dy1 N1 H1 106.0 . . ?
C7 N2 C8 113.9(4) . . ?
C7 N2 Dy1 119.9(3) . . ?
C8 N2 Dy1 103.5(3) . . ?
C7 N2 H2 101.6 . . ?
C8 N2 H2 106.0 . . ?
Dy1 N2 H2 111.4 . . ?
N1 C1 C2 108.1(5) . . ?
N1 C1 C4 115.0(5) . . ?
C2 C1 C4 106.0(4) . . ?
N1 C1 C3 106.9(4) . . ?
C2 C1 C3 112.6(5) . . ?
C4 C1 C3 108.4(5) . . ?
O1 C2 C1 110.5(4) . . ?
O1 C2 H2A 109.6 . . ?
C1 C2 H2A 109.6 . . ?
O1 C2 H2B 109.6 . . ?
C1 C2 H2B 109.6 . . ?
H2A C2 H2B 108.1 . . ?
O2 C3 C1 111.4(4) . . ?
O2 C3 H3B 109.4 . . ?
C1 C3 H3B 109.4 . . ?
O2 C3 H3C 109.4 . . ?
C1 C3 H3C 109.4 . . ?
H3B C3 H3C 108.0 . . ?
O3 C4 C1 114.1(5) . . ?
O3 C4 H4A 108.7 . . ?
C1 C4 H4A 108.7 . . ?
O3 C4 H4B 108.7 . . ?
C1 C4 H4B 108.7 . . ?
H4A C4 H4B 107.6 . . ?
N1 C5 C6 113.1(5) . . ?
N1 C5 H5A 109.0 . . ?
C6 C5 H5A 109.0 . . ?
N1 C5 H5B 109.0 . . ?
C6 C5 H5B 109.0 . . ?
H5A C5 H5B 107.8 . . ?
C5 C6 C7 115.1(5) . . ?
C5 C6 H6A 108.5 . . ?
C7 C6 H6A 108.5 . . ?
C5 C6 H6B 108.5 . . ?
C7 C6 H6B 108.5 . . ?
H6A C6 H6B 107.5 . . ?
N2 C7 C6 111.5(5) . . ?
N2 C7 H7A 109.3 . . ?
C6 C7 H7A 109.3 . . ?
N2 C7 H7B 109.3 . . ?
C6 C7 H7B 109.3 . . ?
H7A C7 H7B 108.0 . . ?
N2 C8 C10 108.8(4) . . ?
N2 C8 C9 105.4(4) . . ?
C10 C8 C9 111.8(5) . . ?
N2 C8 C11 112.9(5) . . ?
C10 C8 C11 109.7(4) . . ?
C9 C8 C11 108.3(5) . . ?
O4 C9 C8 111.2(4) . . ?
O4 C9 H9A 109.4 . . ?
C8 C9 H9A 109.4 . . ?
O4 C9 H9B 109.4 . . ?
C8 C9 H9B 109.4 . . ?
H9A C9 H9B 108.0 . . ?
O5 C10 C8 112.6(4) . . ?
O5 C10 H10A 109.1 . . ?
C8 C10 H10A 109.1 . . ?
O5 C10 H10B 109.1 . . ?
C8 C10 H10B 109.1 . . ?
H10A C10 H10B 107.8 . . ?
O6 C11 C8 109.6(5) . . ?
O6 C11 H11A 109.7 . . ?
C8 C11 H11A 109.7 . . ?
O6 C11 H11B 109.7 . . ?
C8 C11 H11B 109.7 . . ?
H11A C11 H11B 108.2 . . ?
O8 C12 O7 124.9(6) . . ?
O8 C12 C13 116.5(6) . . ?
O7 C12 C13 118.5(6) . . ?
C12 C13 H13A 109.5 . . ?
C12 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C12 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
O10 C14 O9 119.8(6) . . ?
O10 C14 C15 120.7(6) . . ?
O9 C14 C15 119.5(6) . . ?
O10 C14 Dy2 60.2(3) . . ?
O9 C14 Dy2 59.9(3) . . ?
C15 C14 Dy2 176.0(5) . . ?
C14 C15 H15A 109.4 . . ?
C14 C15 H15B 109.0 . . ?
H15A C15 H15B 109.7 . . ?
C14 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.7 . . ?
O11 C16 O12 120.5(5) . . ?
O11 C16 C17 119.3(5) . . ?
O12 C16 C17 120.2(5) . . ?
O11 C16 Dy2 60.8(3) . . ?
O12 C16 Dy2 60.0(3) . . ?
C17 C16 Dy2 176.1(4) . . ?
C16 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C16 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
O13 C19 C18 109.0(10) . . ?
O13 C19 H19A 109.9 . . ?
C18 C19 H19A 109.9 . . ?
O13 C19 H19B 109.9 . . ?
C18 C19 H19B 109.9 . . ?
H19A C19 H19B 108.3 . . ?
C19' C18' H18D 109.5 . . ?
C19' C18' H18E 109.5 . . ?
H18D C18' H18E 109.5 . . ?
C19' C18' H18F 109.5 . . ?
H18D C18' H18F 109.5 . . ?
H18E C18' H18F 109.5 . . ?
O13 C19' C18' 108.5(17) . . ?
O13 C19' H19C 110.0 . . ?
C18' C19' H19C 110.0 . . ?
O13 C19' H19D 110.0 . . ?
C18' C19' H19D 110.0 . . ?
H19C C19' H19D 108.4 . . ?

_diffrn_measured_fraction_theta_max 0.994
_diffrn_reflns_theta_full        25.03
_diffrn_measured_fraction_theta_full 0.994
_refine_diff_density_max         1.388
_refine_diff_density_min         -0.995
_refine_diff_density_rms         0.139
_database_code_depnum_ccdc_archive 'CCDC 934455'