# Electronic Supplementary Material (ESI) for Dalton Transactions
# This journal is © The Royal Society of Chemistry 2013

#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
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#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
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#  data retrieval see:
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data_mo_sk264_0m

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
  ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C12 H36 Al3 Dy'
_chemical_formula_weight         423.85

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Al Al 0.0645 0.0514 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   P21/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   7.3556(10)
_cell_length_b                   17.681(2)
_cell_length_c                   32.162(4)
_cell_angle_alpha                90.00
_cell_angle_beta                 92.518(4)
_cell_angle_gamma                90.00
_cell_volume                     4178.7(9)
_cell_formula_units_Z            8
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9913
_cell_measurement_theta_min      4.607
_cell_measurement_theta_max      56.58

_exptl_crystal_description       block
_exptl_crystal_colour            colourless
_exptl_crystal_size_max          0.342
_exptl_crystal_size_mid          0.288
_exptl_crystal_size_min          0.18
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.347
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1704
_exptl_absorpt_coefficient_mu    3.685
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.92784
_exptl_absorpt_correction_T_max  0.95008
_exptl_absorpt_process_details   sadabs

_exptl_special_details           
;
  ?
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'Imus-focus sealed tube'
_diffrn_radiation_monochromator  multilayer
_diffrn_measurement_device_type  'APEX II DUO'
_diffrn_measurement_method       omega/phi
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            40025
_diffrn_reflns_av_R_equivalents  0.0301
_diffrn_reflns_av_sigmaI/netI    0.0294
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_l_min       -42
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_theta_min         1.27
_diffrn_reflns_theta_max         28.31
_reflns_number_total             10367
_reflns_number_gt                9589
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       COSMO
_computing_cell_refinement       SAINT
_computing_data_reduction        SAINT
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
  Refinement of F^2^ against ALL reflections.  The weighted R-factor wR and
  goodness of fit S are based on F^2^, conventional R-factors R are based
  on F, with F set to zero for negative F^2^. The threshold expression of
  F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
  not relevant to the choice of reflections for refinement.  R-factors based
  on F^2^ are statistically about twice as large as those based on F, and R-
  factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0169P)^2^+7.2515P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         10367
_refine_ls_number_parameters     313
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0292
_refine_ls_R_factor_gt           0.0258
_refine_ls_wR_factor_ref         0.0566
_refine_ls_wR_factor_gt          0.0554
_refine_ls_goodness_of_fit_ref   1.082
_refine_ls_restrained_S_all      1.082
_refine_ls_shift/su_max          0.008
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.454570(17) 0.098107(6) 0.650519(4) 0.01326(4) Uani 1 1 d . . .
Dy2 Dy 0.107422(17) -0.366023(7) 0.596457(4) 0.01497(4) Uani 1 1 d . . .
Al1 Al 0.69095(12) 0.23923(5) 0.66858(3) 0.01904(17) Uani 1 1 d . . .
Al2 Al 0.39748(13) -0.01091(5) 0.72313(3) 0.02059(18) Uani 1 1 d . . .
Al3 Al 0.26759(13) 0.07276(5) 0.56356(3) 0.02141(18) Uani 1 1 d . . .
Al5 Al -0.10153(13) -0.24308(5) 0.64210(3) 0.02313(19) Uani 1 1 d . . .
Al6 Al 0.28841(14) -0.32414(6) 0.51529(3) 0.0283(2) Uani 1 1 d . . .
Al4 Al 0.11380(13) -0.52798(5) 0.63141(3) 0.01961(18) Uani 1 1 d . . .
C1 C 0.4689(4) 0.20714(15) 0.70196(9) 0.0214(6) Uani 1 1 d . . .
H1A H 0.4578 0.2410 0.7258 0.032 Uiso 1 1 calc R . .
H1B H 0.4859 0.1551 0.7119 0.032 Uiso 1 1 calc R . .
H1C H 0.3581 0.2101 0.6840 0.032 Uiso 1 1 calc R . .
C2 C 0.7327(4) 0.15856(16) 0.62239(9) 0.0213(6) Uani 1 1 d . . .
H2A H 0.6213 0.1530 0.6048 0.032 Uiso 1 1 calc R . .
H2B H 0.7639 0.1099 0.6354 0.032 Uiso 1 1 calc R . .
H2C H 0.8324 0.1750 0.6053 0.032 Uiso 1 1 calc R . .
C3 C 0.9112(4) 0.23604(18) 0.70571(10) 0.0270(7) Uani 1 1 d . . .
H3A H 1.0180 0.2482 0.6898 0.041 Uiso 1 1 calc R . .
H3B H 0.9251 0.1853 0.7177 0.041 Uiso 1 1 calc R . .
H3C H 0.9000 0.2731 0.7281 0.041 Uiso 1 1 calc R . .
C4 C 0.6247(5) 0.33596(18) 0.64158(12) 0.0351(8) Uani 1 1 d . . .
H4A H 0.6105 0.3749 0.6629 0.053 Uiso 1 1 calc R . .
H4B H 0.5099 0.3300 0.6253 0.053 Uiso 1 1 calc R . .
H4C H 0.7209 0.3511 0.6231 0.053 Uiso 1 1 calc R . .
C5 C 0.6482(4) 0.01682(16) 0.69938(9) 0.0212(6) Uani 1 1 d . . .
H5A H 0.7459 -0.0080 0.7160 0.032 Uiso 1 1 calc R . .
H5B H 0.6654 0.0718 0.7005 0.032 Uiso 1 1 calc R . .
H5C H 0.6513 -0.0002 0.6704 0.032 Uiso 1 1 calc R . .
C6 C 0.1904(4) 0.04157(15) 0.68720(9) 0.0188(6) Uani 1 1 d . . .
H6A H 0.2032 0.0289 0.6578 0.028 Uiso 1 1 calc R . .
H6B H 0.1990 0.0965 0.6908 0.028 Uiso 1 1 calc R . .
H6C H 0.0720 0.0240 0.6961 0.028 Uiso 1 1 calc R . .
C7 C 0.3707(6) -0.12086(18) 0.71691(13) 0.0430(9) Uani 1 1 d . . .
H7A H 0.4765 -0.1462 0.7302 0.064 Uiso 1 1 calc R . .
H7B H 0.3623 -0.1339 0.6873 0.064 Uiso 1 1 calc R . .
H7C H 0.2599 -0.1374 0.7301 0.064 Uiso 1 1 calc R . .
C8 C 0.3897(5) 0.0334(2) 0.77903(10) 0.0367(8) Uani 1 1 d . . .
H8A H 0.4141 -0.0060 0.8000 0.055 Uiso 1 1 calc R . .
H8B H 0.2690 0.0552 0.7828 0.055 Uiso 1 1 calc R . .
H8C H 0.4821 0.0732 0.7822 0.055 Uiso 1 1 calc R . .
C9 C 0.4457(4) -0.00340(16) 0.59459(9) 0.0231(6) Uani 1 1 d . . .
H9A H 0.3960 -0.0178 0.6212 0.035 Uiso 1 1 calc R . .
H9B H 0.5646 0.0207 0.5996 0.035 Uiso 1 1 calc R . .
H9C H 0.4595 -0.0486 0.5774 0.035 Uiso 1 1 calc R . .
C10 C 0.2465(4) 0.16977(16) 0.60049(9) 0.0219(6) Uani 1 1 d . . .
H10A H 0.1670 0.2067 0.5860 0.033 Uiso 1 1 calc R . .
H10B H 0.3675 0.1919 0.6056 0.033 Uiso 1 1 calc R . .
H10C H 0.1951 0.1561 0.6271 0.033 Uiso 1 1 calc R . .
C11 C 0.0264(5) 0.02506(18) 0.55941(10) 0.0293(7) Uani 1 1 d . . .
H11A H -0.0605 0.0596 0.5453 0.044 Uiso 1 1 calc R . .
H11B H -0.0139 0.0138 0.5874 0.044 Uiso 1 1 calc R . .
H11C H 0.0332 -0.0220 0.5434 0.044 Uiso 1 1 calc R . .
C12 C 0.3818(6) 0.1047(2) 0.51225(10) 0.0380(8) Uani 1 1 d . . .
H12A H 0.3630 0.0657 0.4909 0.057 Uiso 1 1 calc R . .
H12B H 0.5125 0.1122 0.5180 0.057 Uiso 1 1 calc R . .
H12C H 0.3268 0.1523 0.5024 0.057 Uiso 1 1 calc R . .
C13 C 0.3423(4) -0.46333(16) 0.61803(9) 0.0222(6) Uani 1 1 d . . .
H13A H 0.4531 -0.4917 0.6259 0.033 Uiso 1 1 calc R . .
H13B H 0.3407 -0.4159 0.6337 0.033 Uiso 1 1 calc R . .
H13C H 0.3403 -0.4522 0.5882 0.033 Uiso 1 1 calc R . .
C14 C -0.1194(4) -0.46593(15) 0.61477(9) 0.0203(6) Uani 1 1 d . . .
H14A H -0.1189 -0.4531 0.5851 0.030 Uiso 1 1 calc R . .
H14B H -0.1212 -0.4194 0.6313 0.030 Uiso 1 1 calc R . .
H14C H -0.2276 -0.4962 0.6201 0.030 Uiso 1 1 calc R . .
C15 C 0.1143(5) -0.61647(18) 0.59458(11) 0.0314(7) Uani 1 1 d . . .
H15A H 0.1829 -0.6576 0.6084 0.047 Uiso 1 1 calc R . .
H15B H 0.1715 -0.6031 0.5686 0.047 Uiso 1 1 calc R . .
H15C H -0.0112 -0.6329 0.5884 0.047 Uiso 1 1 calc R . .
C16 C 0.1174(5) -0.54362(18) 0.69223(10) 0.0304(7) Uani 1 1 d . . .
H16A H 0.0075 -0.5710 0.6996 0.046 Uiso 1 1 calc R . .
H16B H 0.1214 -0.4945 0.7063 0.046 Uiso 1 1 calc R . .
H16C H 0.2252 -0.5732 0.7009 0.046 Uiso 1 1 calc R . .
C17 C -0.1442(4) -0.27258(16) 0.57938(10) 0.0234(6) Uani 1 1 d . . .
H17A H -0.1827 -0.3256 0.5773 0.035 Uiso 1 1 calc R . .
H17B H -0.0309 -0.2659 0.5649 0.035 Uiso 1 1 calc R . .
H17C H -0.2390 -0.2401 0.5666 0.035 Uiso 1 1 calc R . .
C18 C 0.1122(4) -0.30776(16) 0.66819(9) 0.0229(6) Uani 1 1 d . . .
H18A H 0.1374 -0.2921 0.6971 0.034 Uiso 1 1 calc R . .
H18B H 0.2213 -0.3002 0.6522 0.034 Uiso 1 1 calc R . .
H18C H 0.0783 -0.3614 0.6675 0.034 Uiso 1 1 calc R . .
C19 C -0.3220(5) -0.2720(2) 0.67022(11) 0.0346(8) Uani 1 1 d . . .
H19A H -0.2991 -0.2690 0.7004 0.052 Uiso 1 1 calc R . .
H19B H -0.3557 -0.3240 0.6625 0.052 Uiso 1 1 calc R . .
H19C H -0.4214 -0.2377 0.6618 0.052 Uiso 1 1 calc R . .
C20 C -0.0322(6) -0.13587(18) 0.64248(14) 0.0425(9) Uani 1 1 d . . .
H20A H -0.1270 -0.1063 0.6276 0.064 Uiso 1 1 calc R . .
H20B H 0.0833 -0.1298 0.6288 0.064 Uiso 1 1 calc R . .
H20C H -0.0182 -0.1180 0.6713 0.064 Uiso 1 1 calc R . .
C21 C 0.3432(4) -0.27267(17) 0.57280(9) 0.0233(6) Uani 1 1 d . . .
H21A H 0.4294 -0.2311 0.5695 0.035 Uiso 1 1 calc R . .
H21B H 0.3959 -0.3099 0.5924 0.035 Uiso 1 1 calc R . .
H21C H 0.2299 -0.2528 0.5835 0.035 Uiso 1 1 calc R . .
C22 C 0.0997(4) -0.41100(16) 0.52168(9) 0.0230(6) Uani 1 1 d . . .
H22A H -0.0141 -0.3899 0.5314 0.034 Uiso 1 1 calc R . .
H22B H 0.1482 -0.4481 0.5419 0.034 Uiso 1 1 calc R . .
H22C H 0.0764 -0.4358 0.4947 0.034 Uiso 1 1 calc R . .
C23 C 0.5146(6) -0.3727(3) 0.49851(13) 0.0531(12) Uani 1 1 d . . .
H23A H 0.4909 -0.4007 0.4725 0.080 Uiso 1 1 calc R . .
H23B H 0.5583 -0.4077 0.5204 0.080 Uiso 1 1 calc R . .
H23C H 0.6071 -0.3339 0.4943 0.080 Uiso 1 1 calc R . .
C24 C 0.1662(6) -0.2472(2) 0.47981(11) 0.0488(11) Uani 1 1 d . . .
H24A H 0.2232 -0.1978 0.4851 0.073 Uiso 1 1 calc R . .
H24B H 0.0372 -0.2446 0.4861 0.073 Uiso 1 1 calc R . .
H24C H 0.1772 -0.2608 0.4505 0.073 Uiso 1 1 calc R . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Dy1 0.01471(6) 0.01326(6) 0.01192(6) -0.00025(4) 0.00171(5) 0.00083(4)
Dy2 0.01403(7) 0.01709(6) 0.01374(6) 0.00204(4) -0.00016(5) -0.00200(4)
Al1 0.0154(4) 0.0169(4) 0.0250(5) 0.0006(3) 0.0027(4) -0.0019(3)
Al2 0.0251(5) 0.0197(4) 0.0172(4) 0.0044(3) 0.0039(4) 0.0005(3)
Al3 0.0241(5) 0.0251(4) 0.0149(4) -0.0015(3) -0.0005(4) -0.0006(4)
Al5 0.0223(5) 0.0179(4) 0.0293(5) -0.0041(3) 0.0020(4) -0.0018(3)
Al6 0.0268(5) 0.0426(5) 0.0155(4) 0.0046(4) 0.0004(4) -0.0126(4)
Al4 0.0239(5) 0.0176(4) 0.0171(4) 0.0023(3) -0.0016(4) 0.0000(3)
C1 0.0221(15) 0.0190(13) 0.0233(15) -0.0089(11) 0.0048(12) -0.0013(11)
C2 0.0186(14) 0.0266(14) 0.0192(14) 0.0023(11) 0.0062(12) -0.0027(11)
C3 0.0198(15) 0.0287(15) 0.0325(18) -0.0073(13) -0.0002(13) 0.0020(12)
C4 0.036(2) 0.0215(15) 0.048(2) 0.0090(14) -0.0004(17) -0.0014(14)
C5 0.0217(15) 0.0263(14) 0.0156(14) 0.0026(11) 0.0012(11) 0.0065(11)
C6 0.0159(14) 0.0169(12) 0.0242(15) -0.0018(11) 0.0063(11) -0.0024(10)
C7 0.049(2) 0.0233(16) 0.057(3) 0.0124(16) 0.005(2) 0.0018(15)
C8 0.037(2) 0.055(2) 0.0185(16) 0.0026(15) 0.0045(14) 0.0011(17)
C9 0.0290(17) 0.0216(13) 0.0188(14) -0.0064(11) 0.0040(12) 0.0028(12)
C10 0.0234(15) 0.0203(13) 0.0216(15) 0.0011(11) -0.0048(12) 0.0027(11)
C11 0.0289(18) 0.0335(16) 0.0251(16) -0.0045(13) -0.0035(14) -0.0039(13)
C12 0.047(2) 0.048(2) 0.0200(17) 0.0038(15) 0.0044(15) -0.0013(17)
C13 0.0188(15) 0.0267(14) 0.0211(15) 0.0021(11) -0.0004(12) 0.0031(11)
C14 0.0202(15) 0.0174(12) 0.0235(15) 0.0023(11) 0.0031(12) -0.0037(11)
C15 0.0341(19) 0.0248(15) 0.0352(19) -0.0049(13) -0.0001(15) 0.0038(13)
C16 0.0350(19) 0.0320(16) 0.0239(16) 0.0070(13) -0.0023(14) -0.0053(14)
C17 0.0168(14) 0.0221(14) 0.0312(17) 0.0053(12) -0.0003(12) 0.0009(11)
C18 0.0273(16) 0.0239(14) 0.0174(14) -0.0019(11) -0.0004(12) -0.0036(12)
C19 0.0274(18) 0.0413(19) 0.036(2) -0.0078(15) 0.0094(15) -0.0017(14)
C20 0.045(2) 0.0217(16) 0.061(3) -0.0066(16) 0.001(2) -0.0040(15)
C21 0.0180(15) 0.0288(15) 0.0231(15) 0.0044(12) 0.0005(12) -0.0085(12)
C22 0.0269(16) 0.0267(14) 0.0150(14) -0.0015(11) -0.0018(12) -0.0013(12)
C23 0.040(2) 0.084(3) 0.036(2) -0.018(2) 0.0189(19) -0.016(2)
C24 0.066(3) 0.051(2) 0.0283(19) 0.0208(17) -0.0162(19) -0.029(2)

_geom_special_details            
;
  All esds (except the esd in the dihedral angle between two l.s. planes)
  are estimated using the full covariance matrix.  The cell esds are taken
  into account individually in the estimation of esds in distances, angles
  and torsion angles; correlations between esds in cell parameters are only
  used when they are defined by crystal symmetry.  An approximate (isotropic)
  treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 C2 2.512(3) . ?
Dy1 C10 2.514(3) . ?
Dy1 C6 2.523(3) . ?
Dy1 C5 2.523(3) . ?
Dy1 C1 2.540(3) . ?
Dy1 C9 2.540(3) . ?
Dy1 Al2 3.0712(9) . ?
Dy1 Al1 3.0818(9) . ?
Dy1 Al3 3.0946(9) . ?
Dy2 C13 2.514(3) . ?
Dy2 C14 2.517(3) . ?
Dy2 C17 2.523(3) . ?
Dy2 C18 2.526(3) . ?
Dy2 C22 2.531(3) . ?
Dy2 C21 2.535(3) . ?
Dy2 Al5 3.0725(9) . ?
Dy2 Al6 3.0727(10) . ?
Dy2 Al4 3.0757(9) . ?
Al1 C4 1.970(3) . ?
Al1 C3 1.971(3) . ?
Al1 C1 2.073(3) . ?
Al1 C2 2.092(3) . ?
Al2 C7 1.963(3) . ?
Al2 C8 1.964(3) . ?
Al2 C5 2.086(3) . ?
Al2 C6 2.088(3) . ?
Al3 C11 1.963(3) . ?
Al3 C12 1.967(4) . ?
Al3 C10 2.096(3) . ?
Al3 C9 2.100(3) . ?
Al5 C19 1.959(3) . ?
Al5 C20 1.963(3) . ?
Al5 C18 2.090(3) . ?
Al5 C17 2.094(3) . ?
Al6 C24 1.968(4) . ?
Al6 C23 1.969(4) . ?
Al6 C21 2.085(3) . ?
Al6 C22 2.086(3) . ?
Al4 C15 1.962(3) . ?
Al4 C16 1.975(3) . ?
Al4 C14 2.086(3) . ?
Al4 C13 2.093(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Al2 Dy1 Al1 117.36(3) . . ?
Al2 Dy1 Al3 121.75(3) . . ?
Al1 Dy1 Al3 120.81(2) . . ?
Al5 Dy2 Al6 118.68(3) . . ?
Al5 Dy2 Al4 118.94(3) . . ?
Al6 Dy2 Al4 122.32(3) . . ?
C2 Dy1 C10 92.15(10) . . ?
C2 Dy1 C6 173.23(10) . . ?
C10 Dy1 C6 92.25(10) . . ?
C2 Dy1 C5 91.16(10) . . ?
C10 Dy1 C5 175.38(10) . . ?
C6 Dy1 C5 84.75(9) . . ?
C2 Dy1 C1 84.28(9) . . ?
C10 Dy1 C1 92.36(10) . . ?
C6 Dy1 C1 90.40(9) . . ?
C5 Dy1 C1 91.18(10) . . ?
C2 Dy1 C9 92.39(10) . . ?
C10 Dy1 C9 84.65(9) . . ?
C6 Dy1 C9 93.14(10) . . ?
C5 Dy1 C9 91.99(10) . . ?
C1 Dy1 C9 175.45(10) . . ?
C4 Al1 C3 118.21(15) . . ?
C4 Al1 C1 106.32(14) . . ?
C3 Al1 C1 108.89(14) . . ?
C4 Al1 C2 108.67(14) . . ?
C3 Al1 C2 105.57(13) . . ?
C1 Al1 C2 108.95(11) . . ?
C4 Al1 Dy1 119.57(12) . . ?
C3 Al1 Dy1 122.21(10) . . ?
C1 Al1 Dy1 54.91(8) . . ?
C2 Al1 Dy1 54.07(8) . . ?
C7 Al2 C8 118.79(17) . . ?
C7 Al2 C5 106.36(15) . . ?
C8 Al2 C5 107.66(15) . . ?
C7 Al2 C6 108.42(15) . . ?
C8 Al2 C6 106.22(14) . . ?
C5 Al2 C6 109.15(12) . . ?
C7 Al2 Dy1 124.08(13) . . ?
C8 Al2 Dy1 117.13(12) . . ?
C5 Al2 Dy1 54.64(8) . . ?
C6 Al2 Dy1 54.63(8) . . ?
C11 Al3 C12 118.96(16) . . ?
C11 Al3 C10 107.51(14) . . ?
C12 Al3 C10 106.57(15) . . ?
C11 Al3 C9 107.45(14) . . ?
C12 Al3 C9 107.60(15) . . ?
C10 Al3 C9 108.40(12) . . ?
C11 Al3 Dy1 119.21(10) . . ?
C12 Al3 Dy1 121.82(12) . . ?
C10 Al3 Dy1 53.87(8) . . ?
C9 Al3 Dy1 54.56(8) . . ?
C19 Al5 C20 118.01(17) . . ?
C19 Al5 C18 107.15(15) . . ?
C20 Al5 C18 109.58(16) . . ?
C19 Al5 C17 106.72(14) . . ?
C20 Al5 C17 105.94(16) . . ?
C18 Al5 C17 109.20(12) . . ?
C19 Al5 Dy2 118.50(11) . . ?
C20 Al5 Dy2 123.43(13) . . ?
C18 Al5 Dy2 54.65(8) . . ?
C17 Al5 Dy2 54.58(8) . . ?
C24 Al6 C23 120.9(2) . . ?
C24 Al6 C21 106.15(16) . . ?
C23 Al6 C21 107.52(16) . . ?
C24 Al6 C22 106.09(15) . . ?
C23 Al6 C22 106.25(17) . . ?
C21 Al6 C22 109.71(12) . . ?
C24 Al6 Dy2 117.08(14) . . ?
C23 Al6 Dy2 122.05(15) . . ?
C21 Al6 Dy2 54.93(8) . . ?
C22 Al6 Dy2 54.82(8) . . ?
C15 Al4 C16 119.07(15) . . ?
C15 Al4 C14 106.72(14) . . ?
C16 Al4 C14 107.64(14) . . ?
C15 Al4 C13 106.77(14) . . ?
C16 Al4 C13 107.71(14) . . ?
C14 Al4 C13 108.59(12) . . ?
C15 Al4 Dy2 121.47(11) . . ?
C16 Al4 Dy2 119.46(10) . . ?
C14 Al4 Dy2 54.37(8) . . ?
C13 Al4 Dy2 54.27(8) . . ?
Al1 C1 Dy1 83.19(9) . . ?
Al1 C2 Dy1 83.52(10) . . ?
Al2 C5 Dy1 82.98(10) . . ?
Al2 C6 Dy1 82.93(10) . . ?
Al3 C9 Dy1 83.09(9) . . ?
Al3 C10 Dy1 83.81(10) . . ?
Al4 C13 Dy2 83.22(10) . . ?
Al4 C14 Dy2 83.29(10) . . ?
Al5 C17 Dy2 82.87(10) . . ?
Al5 C18 Dy2 82.89(10) . . ?
Al6 C21 Dy2 82.76(10) . . ?
Al6 C22 Dy2 82.83(10) . . ?

_diffrn_measured_fraction_theta_max 0.996
_diffrn_reflns_theta_full        28.31
_diffrn_measured_fraction_theta_full 0.996
_refine_diff_density_max         0.602
_refine_diff_density_min         -0.730
_refine_diff_density_rms         0.106


#+++++++++++++++++++++++++++++++++

_database_code_depnum_ccdc_archive 'CCDC 954825'