# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2014


data_tm184re

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C30 H30 N P Pt'
_chemical_formula_sum            'C30 H30 N P Pt'
_chemical_formula_weight         630.61

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1
_symmetry_space_group_name_Hall  -P1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.7744(13)
_cell_length_b                   11.3517(15)
_cell_length_c                   12.6780(16)
_cell_angle_alpha                72.898(3)
_cell_angle_beta                 67.960(3)
_cell_angle_gamma                82.749(3)
_cell_volume                     1246.0(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    27034
_cell_measurement_theta_min      1.80
_cell_measurement_theta_max      28.34

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.09
_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.06
_exptl_crystal_density_meas      'not measured'
_exptl_crystal_density_diffrn    1.681
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             620
_exptl_absorpt_coefficient_mu    5.713
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.6776
_exptl_absorpt_correction_T_max  0.7980
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1997)'

_exptl_special_details           
; 
Half sphere of data collected using SAINT strategy (Bruker, 2006).
 Crystal to detector distance = 50mm; combination of φ and ω scans of
 0.5°, 10s per °, 2 iterations.
;

_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker Kappa Duo Apex II Diffractometer'
_diffrn_measurement_method       '0.5° φ scans and ω scans'
_diffrn_standards_number         n/a
_diffrn_standards_interval_count n/a
_diffrn_standards_interval_time  n/a
_diffrn_standards_decay_%        0
_diffrn_reflns_number            27034
_diffrn_reflns_av_R_equivalents  0.0549
_diffrn_reflns_av_sigmaI/netI    0.0469
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_theta_min         1.80
_diffrn_reflns_theta_max         28.34
_reflns_number_total             6180
_reflns_number_gt                5358
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'SAINT program (Bruker, 2006)'
_computing_cell_refinement       'DENZO-SMN (Otwinowski & Minor, 1997)'
_computing_data_reduction        'DENZO-SMN (Otwinowski & Minor, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'X-Seed (Barbour, 2001)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 2001)'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0334P)²+2.2008P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       none
_refine_ls_number_reflns         6180
_refine_ls_number_parameters     298
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0448
_refine_ls_R_factor_gt           0.0350
_refine_ls_wR_factor_ref         0.0786
_refine_ls_wR_factor_gt          0.0746
_refine_ls_goodness_of_fit_ref   1.043
_refine_ls_restrained_S_all      1.043
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.09650(2) 0.141262(16) 0.216148(16) 0.02454(6) Uani 1 1 d . . .
P1 P 0.07811(13) 0.27864(11) 0.31716(11) 0.0241(2) Uani 1 1 d . . .
N1 N 0.3283(5) 0.1623(4) 0.1485(4) 0.0294(9) Uani 1 1 d . . .
C1 C 0.1136(7) 0.0016(4) 0.1282(5) 0.0431(15) Uani 1 1 d . . .
H1A H 0.1353 0.0385 0.0427 0.052 Uiso 1 1 calc R . .
H1B H 0.1922 -0.0596 0.1391 0.052 Uiso 1 1 calc R . .
C2 C -0.0433(6) -0.0601(5) 0.1898(5) 0.0384(12) Uani 1 1 d . . .
H2A H -0.0569 -0.1062 0.1393 0.046 Uiso 1 1 calc R . .
H2B H -0.0496 -0.1191 0.2665 0.046 Uiso 1 1 calc R . .
C3 C -0.1635(6) 0.0377(5) 0.2095(5) 0.0402(13) Uani 1 1 d . . .
H3A H -0.2611 -0.0009 0.2555 0.048 Uiso 1 1 calc R . .
H3B H -0.1658 0.0917 0.1329 0.048 Uiso 1 1 calc R . .
C4 C -0.1263(6) 0.1124(5) 0.2780(5) 0.0397(13) Uani 1 1 d . . .
H4A H -0.1596 0.0676 0.3628 0.048 Uiso 1 1 calc R . .
H4B H -0.1796 0.1929 0.2698 0.048 Uiso 1 1 calc R . .
C5 C 0.4085(6) 0.1577(5) 0.0243(5) 0.0357(12) Uani 1 1 d . . .
H5A H 0.3715 0.0888 0.0100 0.043 Uiso 1 1 calc R . .
H5B H 0.5151 0.1429 0.0103 0.043 Uiso 1 1 calc R . .
C6 C 0.3867(5) 0.2767(5) -0.0594(4) 0.0300(10) Uani 1 1 d . . .
C7 C 0.2839(6) 0.2893(5) -0.1126(5) 0.0365(12) Uani 1 1 d . . .
H7 H 0.2242 0.2212 -0.0949 0.044 Uiso 1 1 calc R . .
C8 C 0.2655(6) 0.3981(5) -0.1908(5) 0.0402(13) Uani 1 1 d . . .
H8 H 0.1927 0.4047 -0.2252 0.048 Uiso 1 1 calc R . .
C9 C 0.3521(7) 0.4967(6) -0.2190(5) 0.0472(15) Uani 1 1 d . . .
H9 H 0.3407 0.5712 -0.2739 0.057 Uiso 1 1 calc R . .
C10 C 0.4567(7) 0.4873(6) -0.1669(5) 0.0465(14) Uani 1 1 d . . .
H10 H 0.5169 0.5555 -0.1858 0.056 Uiso 1 1 calc R . .
C11 C 0.4729(6) 0.3772(6) -0.0866(5) 0.0403(13) Uani 1 1 d . . .
H11 H 0.5436 0.3709 -0.0503 0.048 Uiso 1 1 calc R . .
C12 C 0.4082(5) 0.1788(5) 0.2030(5) 0.0335(11) Uani 1 1 d . . .
H12 H 0.5118 0.1776 0.1615 0.040 Uiso 1 1 calc R . .
C13 C 0.3618(5) 0.1993(4) 0.3207(5) 0.0298(10) Uani 1 1 d . . .
C14 C 0.4706(6) 0.1763(5) 0.3712(5) 0.0414(13) Uani 1 1 d . . .
H14 H 0.5647 0.1458 0.3302 0.050 Uiso 1 1 calc R . .
C15 C 0.4450(7) 0.1967(6) 0.4783(6) 0.0470(15) Uani 1 1 d . . .
H15 H 0.5199 0.1780 0.5117 0.056 Uiso 1 1 calc R . .
C16 C 0.3111(7) 0.2440(6) 0.5374(5) 0.0423(13) Uani 1 1 d . . .
H16 H 0.2940 0.2597 0.6110 0.051 Uiso 1 1 calc R . .
C17 C 0.1999(6) 0.2690(5) 0.4889(5) 0.0342(11) Uani 1 1 d . . .
H17 H 0.1075 0.3019 0.5300 0.041 Uiso 1 1 calc R . .
C18 C 0.2227(5) 0.2464(4) 0.3814(4) 0.0267(10) Uani 1 1 d . . .
C19 C 0.1064(5) 0.4392(4) 0.2323(4) 0.0252(9) Uani 1 1 d . . .
C20 C 0.1104(5) 0.4718(5) 0.1167(4) 0.0314(11) Uani 1 1 d . . .
H20 H 0.1005 0.4100 0.0833 0.038 Uiso 1 1 calc R . .
C21 C 0.1287(6) 0.5936(5) 0.0495(5) 0.0356(12) Uani 1 1 d . . .
H21 H 0.1324 0.6146 -0.0298 0.043 Uiso 1 1 calc R . .
C22 C 0.1413(6) 0.6835(5) 0.0971(5) 0.0350(11) Uani 1 1 d . . .
H22 H 0.1516 0.7670 0.0513 0.042 Uiso 1 1 calc R . .
C23 C 0.1392(6) 0.6532(5) 0.2122(5) 0.0381(12) Uani 1 1 d . . .
H23 H 0.1486 0.7159 0.2448 0.046 Uiso 1 1 calc R . .
C24 C 0.1233(6) 0.5317(5) 0.2794(5) 0.0318(11) Uani 1 1 d . . .
H24 H 0.1238 0.5109 0.3575 0.038 Uiso 1 1 calc R . .
C25 C -0.0898(5) 0.2800(5) 0.4446(4) 0.0278(10) Uani 1 1 d . . .
C26 C -0.1842(5) 0.3821(5) 0.4548(4) 0.0314(11) Uani 1 1 d . . .
H26 H -0.1582 0.4577 0.3950 0.038 Uiso 1 1 calc R . .
C27 C -0.3143(6) 0.3758(6) 0.5498(5) 0.0386(12) Uani 1 1 d . . .
H27 H -0.3776 0.4462 0.5550 0.046 Uiso 1 1 calc R . .
C28 C -0.3525(6) 0.2665(6) 0.6374(5) 0.0389(13) Uani 1 1 d . . .
H28 H -0.4419 0.2620 0.7033 0.047 Uiso 1 1 calc R . .
C29 C -0.2611(6) 0.1643(5) 0.6295(5) 0.0380(12) Uani 1 1 d . . .
H29 H -0.2875 0.0894 0.6901 0.046 Uiso 1 1 calc R . .
C30 C -0.1307(6) 0.1702(5) 0.5335(5) 0.0356(12) Uani 1 1 d . . .
H30 H -0.0688 0.0990 0.5282 0.043 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C4 2.052(5) . ?
Pt1 N1 2.118(4) . ?
Pt1 C1 2.148(5) . ?
Pt1 P1 2.2440(12) . ?
P1 C19 1.818(5) . ?
P1 C25 1.822(5) . ?
P1 C18 1.831(5) . ?
N1 C12 1.281(6) . ?
N1 C5 1.487(6) . ?
C1 C2 1.582(8) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
C2 C3 1.513(8) . ?
C2 H2A 0.9900 . ?
C2 H2B 0.9900 . ?
C3 C4 1.534(7) . ?
C3 H3A 0.9900 . ?
C3 H3B 0.9900 . ?
C4 H4A 0.9900 . ?
C4 H4B 0.9900 . ?
C5 C6 1.500(7) . ?
C5 H5A 0.9900 . ?
C5 H5B 0.9900 . ?
C6 C7 1.379(7) . ?
C6 C11 1.386(7) . ?
C7 C8 1.377(8) . ?
C7 H7 0.9500 . ?
C8 C9 1.369(8) . ?
C8 H8 0.9500 . ?
C9 C10 1.390(9) . ?
C9 H9 0.9500 . ?
C10 C11 1.395(8) . ?
C10 H10 0.9500 . ?
C11 H11 0.9500 . ?
C12 C13 1.469(7) . ?
C12 H12 0.9500 . ?
C13 C14 1.397(7) . ?
C13 C18 1.414(7) . ?
C14 C15 1.369(8) . ?
C14 H14 0.9500 . ?
C15 C16 1.374(9) . ?
C15 H15 0.9500 . ?
C16 C17 1.400(7) . ?
C16 H16 0.9500 . ?
C17 C18 1.392(7) . ?
C17 H17 0.9500 . ?
C19 C20 1.389(7) . ?
C19 C24 1.405(6) . ?
C20 C21 1.388(7) . ?
C20 H20 0.9500 . ?
C21 C22 1.368(7) . ?
C21 H21 0.9500 . ?
C22 C23 1.391(7) . ?
C22 H22 0.9500 . ?
C23 C24 1.384(7) . ?
C23 H23 0.9500 . ?
C24 H24 0.9500 . ?
C25 C26 1.393(7) . ?
C25 C30 1.395(7) . ?
C26 C27 1.377(7) . ?
C26 H26 0.9500 . ?
C27 C28 1.381(8) . ?
C27 H27 0.9500 . ?
C28 C29 1.376(8) . ?
C28 H28 0.9500 . ?
C29 C30 1.385(7) . ?
C29 H29 0.9500 . ?
C30 H30 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C4 Pt1 N1 176.77(18) . . ?
C4 Pt1 C1 84.6(2) . . ?
N1 Pt1 C1 92.2(2) . . ?
C4 Pt1 P1 94.98(15) . . ?
N1 Pt1 P1 88.18(11) . . ?
C1 Pt1 P1 176.78(14) . . ?
C19 P1 C25 104.8(2) . . ?
C19 P1 C18 103.4(2) . . ?
C25 P1 C18 102.9(2) . . ?
C19 P1 Pt1 116.59(15) . . ?
C25 P1 Pt1 117.91(16) . . ?
C18 P1 Pt1 109.41(16) . . ?
C12 N1 C5 115.8(4) . . ?
C12 N1 Pt1 127.1(3) . . ?
C5 N1 Pt1 117.1(3) . . ?
C2 C1 Pt1 104.2(4) . . ?
C2 C1 H1A 110.9 . . ?
Pt1 C1 H1A 110.9 . . ?
C2 C1 H1B 110.9 . . ?
Pt1 C1 H1B 110.9 . . ?
H1A C1 H1B 108.9 . . ?
C3 C2 C1 110.1(4) . . ?
C3 C2 H2A 109.6 . . ?
C1 C2 H2A 109.6 . . ?
C3 C2 H2B 109.6 . . ?
C1 C2 H2B 109.6 . . ?
H2A C2 H2B 108.2 . . ?
C2 C3 C4 106.4(4) . . ?
C2 C3 H3A 110.5 . . ?
C4 C3 H3A 110.5 . . ?
C2 C3 H3B 110.5 . . ?
C4 C3 H3B 110.5 . . ?
H3A C3 H3B 108.6 . . ?
C3 C4 Pt1 111.0(4) . . ?
C3 C4 H4A 109.4 . . ?
Pt1 C4 H4A 109.4 . . ?
C3 C4 H4B 109.4 . . ?
Pt1 C4 H4B 109.4 . . ?
H4A C4 H4B 108.0 . . ?
N1 C5 C6 110.3(4) . . ?
N1 C5 H5A 109.6 . . ?
C6 C5 H5A 109.6 . . ?
N1 C5 H5B 109.6 . . ?
C6 C5 H5B 109.6 . . ?
H5A C5 H5B 108.1 . . ?
C7 C6 C11 118.2(5) . . ?
C7 C6 C5 121.8(5) . . ?
C11 C6 C5 120.0(5) . . ?
C8 C7 C6 121.7(5) . . ?
C8 C7 H7 119.1 . . ?
C6 C7 H7 119.1 . . ?
C9 C8 C7 120.0(6) . . ?
C9 C8 H8 120.0 . . ?
C7 C8 H8 120.0 . . ?
C8 C9 C10 119.8(6) . . ?
C8 C9 H9 120.1 . . ?
C10 C9 H9 120.1 . . ?
C9 C10 C11 119.6(5) . . ?
C9 C10 H10 120.2 . . ?
C11 C10 H10 120.2 . . ?
C6 C11 C10 120.6(5) . . ?
C6 C11 H11 119.7 . . ?
C10 C11 H11 119.7 . . ?
N1 C12 C13 128.9(5) . . ?
N1 C12 H12 115.6 . . ?
C13 C12 H12 115.6 . . ?
C14 C13 C18 118.9(5) . . ?
C14 C13 C12 115.2(5) . . ?
C18 C13 C12 125.8(4) . . ?
C15 C14 C13 121.6(5) . . ?
C15 C14 H14 119.2 . . ?
C13 C14 H14 119.2 . . ?
C14 C15 C16 120.1(5) . . ?
C14 C15 H15 119.9 . . ?
C16 C15 H15 119.9 . . ?
C15 C16 C17 119.8(5) . . ?
C15 C16 H16 120.1 . . ?
C17 C16 H16 120.1 . . ?
C18 C17 C16 121.0(5) . . ?
C18 C17 H17 119.5 . . ?
C16 C17 H17 119.5 . . ?
C17 C18 C13 118.6(4) . . ?
C17 C18 P1 121.4(4) . . ?
C13 C18 P1 120.0(4) . . ?
C20 C19 C24 118.7(4) . . ?
C20 C19 P1 118.7(4) . . ?
C24 C19 P1 122.6(4) . . ?
C21 C20 C19 120.7(5) . . ?
C21 C20 H20 119.7 . . ?
C19 C20 H20 119.7 . . ?
C22 C21 C20 120.2(5) . . ?
C22 C21 H21 119.9 . . ?
C20 C21 H21 119.9 . . ?
C21 C22 C23 120.3(5) . . ?
C21 C22 H22 119.8 . . ?
C23 C22 H22 119.8 . . ?
C24 C23 C22 119.9(5) . . ?
C24 C23 H23 120.0 . . ?
C22 C23 H23 120.0 . . ?
C23 C24 C19 120.2(5) . . ?
C23 C24 H24 119.9 . . ?
C19 C24 H24 119.9 . . ?
C26 C25 C30 118.1(5) . . ?
C26 C25 P1 123.8(4) . . ?
C30 C25 P1 118.0(4) . . ?
C27 C26 C25 121.3(5) . . ?
C27 C26 H26 119.3 . . ?
C25 C26 H26 119.3 . . ?
C26 C27 C28 119.7(5) . . ?
C26 C27 H27 120.1 . . ?
C28 C27 H27 120.1 . . ?
C29 C28 C27 120.1(5) . . ?
C29 C28 H28 119.9 . . ?
C27 C28 H28 119.9 . . ?
C28 C29 C30 120.3(5) . . ?
C28 C29 H29 119.9 . . ?
C30 C29 H29 119.9 . . ?
C29 C30 C25 120.5(5) . . ?
C29 C30 H30 119.8 . . ?
C25 C30 H30 119.8 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C4 Pt1 P1 C19 -106.1(2) . . . . ?
N1 Pt1 P1 C19 74.5(2) . . . . ?
C1 Pt1 P1 C19 171(3) . . . . ?
C4 Pt1 P1 C25 20.0(3) . . . . ?
N1 Pt1 P1 C25 -159.4(2) . . . . ?
C1 Pt1 P1 C25 -63(3) . . . . ?
C4 Pt1 P1 C18 137.0(2) . . . . ?
N1 Pt1 P1 C18 -42.4(2) . . . . ?
C1 Pt1 P1 C18 54(3) . . . . ?
C4 Pt1 N1 C12 -132(4) . . . . ?
C1 Pt1 N1 C12 -140.6(4) . . . . ?
P1 Pt1 N1 C12 36.2(4) . . . . ?
C4 Pt1 N1 C5 48(4) . . . . ?
C1 Pt1 N1 C5 39.6(4) . . . . ?
P1 Pt1 N1 C5 -143.6(3) . . . . ?
C4 Pt1 C1 C2 -14.3(4) . . . . ?
N1 Pt1 C1 C2 165.2(3) . . . . ?
P1 Pt1 C1 C2 69(3) . . . . ?
Pt1 C1 C2 C3 41.3(5) . . . . ?
C1 C2 C3 C4 -54.1(6) . . . . ?
C2 C3 C4 Pt1 40.0(6) . . . . ?
N1 Pt1 C4 C3 -22(4) . . . . ?
C1 Pt1 C4 C3 -13.7(4) . . . . ?
P1 Pt1 C4 C3 169.5(4) . . . . ?
C12 N1 C5 C6 -103.5(5) . . . . ?
Pt1 N1 C5 C6 76.4(5) . . . . ?
N1 C5 C6 C7 -98.9(5) . . . . ?
N1 C5 C6 C11 82.2(6) . . . . ?
C11 C6 C7 C8 -0.1(7) . . . . ?
C5 C6 C7 C8 -179.0(5) . . . . ?
C6 C7 C8 C9 1.1(8) . . . . ?
C7 C8 C9 C10 -1.1(8) . . . . ?
C8 C9 C10 C11 0.2(9) . . . . ?
C7 C6 C11 C10 -0.8(8) . . . . ?
C5 C6 C11 C10 178.1(5) . . . . ?
C9 C10 C11 C6 0.7(8) . . . . ?
C5 N1 C12 C13 173.5(5) . . . . ?
Pt1 N1 C12 C13 -6.4(8) . . . . ?
N1 C12 C13 C14 160.9(5) . . . . ?
N1 C12 C13 C18 -23.2(9) . . . . ?
C18 C13 C14 C15 0.9(8) . . . . ?
C12 C13 C14 C15 177.1(5) . . . . ?
C13 C14 C15 C16 -1.8(9) . . . . ?
C14 C15 C16 C17 1.3(9) . . . . ?
C15 C16 C17 C18 0.1(8) . . . . ?
C16 C17 C18 C13 -1.0(7) . . . . ?
C16 C17 C18 P1 180.0(4) . . . . ?
C14 C13 C18 C17 0.5(7) . . . . ?
C12 C13 C18 C17 -175.2(5) . . . . ?
C14 C13 C18 P1 179.5(4) . . . . ?
C12 C13 C18 P1 3.8(7) . . . . ?
C19 P1 C18 C17 87.7(4) . . . . ?
C25 P1 C18 C17 -21.3(5) . . . . ?
Pt1 P1 C18 C17 -147.4(4) . . . . ?
C19 P1 C18 C13 -91.3(4) . . . . ?
C25 P1 C18 C13 159.7(4) . . . . ?
Pt1 P1 C18 C13 33.6(4) . . . . ?
C25 P1 C19 C20 -120.7(4) . . . . ?
C18 P1 C19 C20 131.8(4) . . . . ?
Pt1 P1 C19 C20 11.7(4) . . . . ?
C25 P1 C19 C24 58.8(4) . . . . ?
C18 P1 C19 C24 -48.7(5) . . . . ?
Pt1 P1 C19 C24 -168.8(4) . . . . ?
C24 C19 C20 C21 -0.9(7) . . . . ?
P1 C19 C20 C21 178.7(4) . . . . ?
C19 C20 C21 C22 -0.8(8) . . . . ?
C20 C21 C22 C23 1.4(8) . . . . ?
C21 C22 C23 C24 -0.4(8) . . . . ?
C22 C23 C24 C19 -1.3(8) . . . . ?
C20 C19 C24 C23 1.9(7) . . . . ?
P1 C19 C24 C23 -177.7(4) . . . . ?
C19 P1 C25 C26 11.3(5) . . . . ?
C18 P1 C25 C26 119.2(4) . . . . ?
Pt1 P1 C25 C26 -120.4(4) . . . . ?
C19 P1 C25 C30 -173.0(4) . . . . ?
C18 P1 C25 C30 -65.1(4) . . . . ?
Pt1 P1 C25 C30 55.4(4) . . . . ?
C30 C25 C26 C27 0.1(7) . . . . ?
P1 C25 C26 C27 175.9(4) . . . . ?
C25 C26 C27 C28 0.4(8) . . . . ?
C26 C27 C28 C29 -0.4(8) . . . . ?
C27 C28 C29 C30 -0.2(8) . . . . ?
C28 C29 C30 C25 0.7(8) . . . . ?
C26 C25 C30 C29 -0.7(7) . . . . ?
P1 C25 C30 C29 -176.7(4) . . . . ?

_diffrn_measured_fraction_theta_max 0.994
_diffrn_reflns_theta_full        28.34
_diffrn_measured_fraction_theta_full 0.994
_refine_diff_density_max         2.829
_refine_diff_density_min         -1.044
_refine_diff_density_rms         0.149
_database_code_depnum_ccdc_archive 'CCDC 973798'
