Negishi coupling


Definition: A carbon-carbon coupling reaction between an organohalide or organotriflate and an organozinc compound. The reaction is catalysed by palladium or nickel.

ID: RXNO:0000088

Synonyms:

More about the RSC Name Reaction Ontology (RXNO)


Articles referencing this term

Oligoarenes as molecular backbones of catalysts: synthesis and applications
Kei Manabe and Shunpei Ishikawa, Chem. Commun., 2008 , 3829
DOI: 10.1039/b807779g

Long-distance ferromagnetic coupling through spin polarization in a linear heterotrinuclear iron(iii)–copper(ii)–iron(iii) complex derived from 5-ferrocenyl-2-aminotropone
Yoshihiro Miyake, Sayaka Watanabe, Satoshi Aono, Tohru Nishinaga, Akira Miyazaki, Toshiaki Enoki, Hitoshi Miyasaka, Hiroyuki Otani and Masahiko Iyoda, Chem. Commun., 2008 , 6167
DOI: 10.1039/b813944j

Iron-catalysed Negishi coupling of benzyl halides and phosphates
Robin B. Bedford, Michael Huwe and Mark C. Wilkinson, Chem. Commun., 2009 , 600
DOI: 10.1039/b818961g

Efficient and convenient preparation of 3-aryl-2,2-dimethylpropanoates via Negishi coupling
Young-Shin Kwak, Aaron D. Kanter, Bing Wang and Yugang Liu, Chem. Commun., 2009 , 2145
DOI: 10.1039/b902779c

A divergent synthesis of oligoarylalkanethiols with Lewis-basic N-donor termini
Björn Schüpbach and Andreas Terfort, Org. Biomol. Chem., 2010 , 8 , 3552
DOI: 10.1039/c003795h

Synthesis and biological activity of new pyridone diaryl ether non-nucleoside inhibitors of HIV-1 reverse transcriptase
Joshua J. Kennedy-Smith, Nidhi Arora, J. Roland Billedeau, Jennifer Fretland, Julie Q. Hang, Gabrielle M. Heilek, Seth F. Harris, Donald Hirschfeld, Hassan Javanbakht, Yu Li, Weiling Liang, Ralf Roetz, Mark Smith, Guoping Su, Judy M. Suh, Armando G. Villaseñor, Jeffrey Wu, Dennis Yasuda, Klaus Klumpp and Zachary K. Sweeney, Med. Chem. Commun., 2010 , 1 , 79
DOI: 10.1039/c0md00009d

Synthetic studies on the mycolactone core
Kwang-Seuk Ko, Matthew D. Alexander, Shaun D. Fontaine, James E. Biggs-Houck, James J. La Clair and Michael D. Burkart, Org. Biomol. Chem., 2010 , 8 , 5159
DOI: 10.1039/c0ob00540a