Meerwein-Ponndorf-Verley reduction


Definition: A reduction of an aldehyde or ketone to an alcohol involving an equilibrium between the aldehyde or ketone and a reagent alcohol present in excess, catalysed by a metal alkoxide. This reaction is the reverse of the Oppenauer oxidation (RXNO:0000047).

ID: RXNO:0000089

More about the RSC Name Reaction Ontology (RXNO)


Articles referencing this term

Synergy between Brønsted acid sites and Lewis acid sites
Selvedin Telalović, Jeck Fei Ng, Rajamanickam Maheswari, Anand Ramanathan, Gaik Khuan Chuah and Ulf Hanefeld, Chem. Commun., 2008 , 4631
DOI: 10.1039/b807953f

Transition metal borylene complexes: boron analogues of classical organometallic systems
Dragoslav Vidovic, Glesni A. Pierce and Simon Aldridge, Chem. Commun., 2009 , 1157
DOI: 10.1039/b816042b

Cyclisation of citronellal over heterogeneous inorganic fluorides—highly chemo- and diastereoselective catalysts for (±)-isopulegol
Simona M. Coman, Pratap Patil, Stefan Wuttke and Erhard Kemnitz, Chem. Commun., 2009 , 460
DOI: 10.1039/b817572a

Green alcohol couplings without transition metal catalysts: base-mediated β-alkylation of alcohols in aerobic conditions
Laura J. Allen and Robert H. Crabtree, Green Chem., 2010 , 12 , 1362
DOI: 10.1039/c0gc00079e

Asymmetric transfer hydrogenation of ketones catalyzed by rhodium complexes containing amino acid triazole ligands
Fredrik Tinnis and Hans Adolfsson, Org. Biomol. Chem., 2010 , 8 , 4536
DOI: 10.1039/c0ob00400f