# Electronic Supplementary Material (ESI) for Chemical Communications.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_p-1_a
_database_code_depnum_ccdc_archive 'CCDC 1040519'

_audit_update_record             
;
2014-12-20 deposited with the CCDC.
2015-02-26 downloaded from the CCDC.
;
#============================================================================== 
# YH9-63-1
#==============================================================================
_audit_creation_date             'December 19 2013'
_audit_creation_method           SHELXL-97

#==============================================================================

#  CHEMICAL DATA

#==============================================================================

_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C29 H46 O5 Si'
_chemical_formula_sum            'C29 H46 O5 Si'
_chemical_formula_weight         502.75
_chemical_formula_structural     ?
_chemical_formula_analytical     ?
_chemical_absolute_configuration .

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'


#==============================================================================

#   CRYSTAL DATA

#==============================================================================

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1  '
_symmetry_space_group_name_Hall  '-P 1 '
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.3975(6)
_cell_length_b                   11.1440(6)
_cell_length_c                   13.6268(8)
_cell_angle_alpha                113.7770(6)
_cell_angle_beta                 91.5850(6)
_cell_angle_gamma                102.5500(6)
_cell_volume                     1398.60(14)
_cell_formula_units_Z            2
_cell_measurement_temperature    90
_cell_measurement_reflns_used    7066
_cell_measurement_theta_min      2.44
_cell_measurement_theta_max      27.61
_exptl_crystal_description       prism
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.14
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.194
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             548
_exptl_absorpt_coefficient_mu    0.119
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_correction_T_min  0.9765
_exptl_absorpt_correction_T_max  0.9835
_exptl_absorpt_process_details   
;
Crystal Faces plugin in Bruker APEX2 software
;
_exptl_special_details           ?

#==============================================================================

#   EXPERIMENTAL DATA

#==============================================================================

_diffrn_ambient_temperature      90
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'Bruker TXS fine-focus rotating anode'
_diffrn_radiation_monochromator  'Bruker Helios multilayer confocal mirror'
_diffrn_measurement_device_type  'Bruker APEXII CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean 8.333
_diffrn_reflns_number            13770
_diffrn_reflns_av_R_equivalents  0.0199
_diffrn_reflns_av_sigmaI/netI    0.0219
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_theta_min         2.06
_diffrn_reflns_theta_max         25.03
_reflns_number_total             4936
_reflns_number_gt                4480
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'APEX2 (Bruker AXS, 2006)'
_computing_cell_refinement       'APEX2 (Bruker AXS, 2006)'
_computing_data_reduction        'SAINT (Bruker AXS, 2004)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'XSHEL (Bruker AXS,2002)'
_computing_publication_material  'XCIF (Bruker AXS, 2001)'
_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0371P)²+0.7570P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         4936
_refine_ls_number_parameters     381
_refine_ls_number_restraints     200
_refine_ls_R_factor_all          0.0369
_refine_ls_R_factor_gt           0.0332
_refine_ls_wR_factor_ref         0.0850
_refine_ls_wR_factor_gt          0.0820
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_restrained_S_all      1.008
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.13952(12) 0.70765(13) 0.68331(10) 0.0124(3) Uani 1 1 d U . .
C2 C 0.09305(12) 0.82969(13) 0.76363(10) 0.0126(3) Uani 1 1 d U . .
H2 H 0.1367 0.8516 0.8372 0.015 Uiso 1 1 calc R . .
C3 C 0.12384(13) 0.96384(13) 0.74889(11) 0.0163(3) Uani 1 1 d U . .
H3 H 0.1348 0.9438 0.6716 0.020 Uiso 1 1 calc R . .
C4 C -0.00217(14) 1.01853(14) 0.77760(12) 0.0197(3) Uani 1 1 d U . .
H4A H 0.0230 1.1160 0.8272 0.024 Uiso 1 1 calc R . .
H4B H -0.0556 1.0062 0.7114 0.024 Uiso 1 1 calc R . .
C5 C -0.08075(14) 0.93541(13) 0.83254(11) 0.0171(3) Uani 1 1 d U . .
H5A H -0.0453 0.9708 0.9098 0.021 Uiso 1 1 calc R . .
H5B H -0.1763 0.9338 0.8264 0.021 Uiso 1 1 calc R . .
C6 C -0.05770(13) 0.79582(13) 0.76733(10) 0.0130(3) Uani 1 1 d U . .
H6 H -0.1030 0.7616 0.6920 0.016 Uiso 1 1 calc R . .
C7 C -0.09966(12) 0.68418(13) 0.80627(10) 0.0129(3) Uani 1 1 d U . .
H7 H -0.0480 0.7135 0.8785 0.015 Uiso 1 1 calc R . .
C8 C -0.06010(12) 0.55978(13) 0.72512(10) 0.0126(3) Uani 1 1 d U . .
C9 C -0.08124(13) 0.32716(13) 0.68456(11) 0.0168(3) Uani 1 1 d U . .
H9A H -0.1595 0.2840 0.6283 0.020 Uiso 1 1 calc R . .
H9B H -0.0800 0.2680 0.7225 0.020 Uiso 1 1 calc R . .
C10 C 0.04189(13) 0.33560(13) 0.63052(10) 0.0150(3) Uani 1 1 d U . .
C11 C 0.11935(13) 0.45379(13) 0.64202(10) 0.0134(3) Uani 1 1 d U . .
H11 H 0.1928 0.4546 0.6022 0.016 Uiso 1 1 calc R . .
C12 C 0.09291(12) 0.58715(13) 0.71729(10) 0.0118(3) Uani 1 1 d U . .
C13 C 0.24821(15) 1.06741(14) 0.82211(13) 0.0253(3) Uani 1 1 d U . .
H13A H 0.2350 1.0916 0.8980 0.038 Uiso 1 1 calc R . .
H13B H 0.2642 1.1488 0.8082 0.038 Uiso 1 1 calc R . .
H13C H 0.3250 1.0281 0.8069 0.038 Uiso 1 1 calc R . .
C14 C -0.24789(13) 0.65265(14) 0.81722(12) 0.0186(3) Uani 1 1 d U . .
H14A H -0.2687 0.7328 0.8722 0.028 Uiso 1 1 calc R . .
H14B H -0.2700 0.5774 0.8387 0.028 Uiso 1 1 calc R . .
H14C H -0.2999 0.6275 0.7477 0.028 Uiso 1 1 calc R . .
C15 C 0.06855(15) 0.20152(14) 0.56167(12) 0.0217(3) Uani 1 1 d U . .
H15A H 0.1439 0.2156 0.5225 0.033 Uiso 1 1 calc R . .
H15B H -0.0103 0.1433 0.5098 0.033 Uiso 1 1 calc R . .
H15C H 0.0895 0.1581 0.6078 0.033 Uiso 1 1 calc R . .
C16 C 0.28982(13) 0.75177(13) 0.68643(11) 0.0148(3) Uani 1 1 d U . .
H16A H 0.3109 0.8251 0.6616 0.018 Uiso 1 1 calc R . .
H16B H 0.3326 0.7883 0.7619 0.018 Uiso 1 1 calc R . .
C17 C 0.48272(14) 0.68427(16) 0.62273(12) 0.0222(3) Uani 1 1 d U . .
H17A H 0.5190 0.6033 0.5972 0.027 Uiso 1 1 calc R A 1
H17B H 0.5237 0.7433 0.6982 0.027 Uiso 1 1 calc R A 1
C24 C 0.39327(14) 0.51930(16) 0.80463(12) 0.0236(3) Uani 1 1 d U . .
H24A H 0.3563 0.4438 0.7344 0.035 Uiso 1 1 calc R . .
H24B H 0.4492 0.4904 0.8455 0.035 Uiso 1 1 calc R . .
H24C H 0.4469 0.5955 0.7933 0.035 Uiso 1 1 calc R . .
C25 C 0.15747(14) 0.42706(14) 0.90475(12) 0.0196(3) Uani 1 1 d U . .
H25A H 0.0764 0.4484 0.9347 0.029 Uiso 1 1 calc R . .
H25B H 0.2110 0.4099 0.9557 0.029 Uiso 1 1 calc R . .
H25C H 0.1336 0.3463 0.8359 0.029 Uiso 1 1 calc R . .
C26 C 0.32543(13) 0.72106(13) 1.01651(11) 0.0162(3) Uani 1 1 d U . .
C27 C 0.39669(16) 0.84722(15) 1.00123(13) 0.0280(4) Uani 1 1 d U . .
H27A H 0.3333 0.8739 0.9645 0.042 Uiso 1 1 calc R . .
H27B H 0.4688 0.8267 0.9574 0.042 Uiso 1 1 calc R . .
H27C H 0.4335 0.9215 1.0720 0.042 Uiso 1 1 calc R . .
C28 C 0.21301(16) 0.75443(16) 1.08497(12) 0.0278(4) Uani 1 1 d U . .
H28A H 0.2494 0.8326 1.1538 0.042 Uiso 1 1 calc R . .
H28B H 0.1706 0.6763 1.0989 0.042 Uiso 1 1 calc R . .
H28C H 0.1471 0.7757 1.0460 0.042 Uiso 1 1 calc R . .
C29 C 0.42562(15) 0.68389(16) 1.07724(13) 0.0265(3) Uani 1 1 d U . .
H29A H 0.4985 0.6631 1.0344 0.040 Uiso 1 1 calc R . .
H29B H 0.3811 0.6045 1.0889 0.040 Uiso 1 1 calc R . .
H29C H 0.4612 0.7603 1.1472 0.040 Uiso 1 1 calc R . .
O1 O 0.08377(9) 0.67012(9) 0.57416(7) 0.0142(2) Uani 1 1 d U . .
H1 H 0.0013 0.6386 0.5670 0.021 Uiso 1 1 calc R . .
O2 O -0.13386(9) 0.52351(9) 0.62335(7) 0.0146(2) Uani 1 1 d U . .
H2A H -0.1115 0.4583 0.5757 0.022 Uiso 1 1 calc R . .
O3 O -0.09637(9) 0.45506(9) 0.76050(7) 0.0148(2) Uani 1 1 d U . .
O4 O 0.34253(9) 0.64325(10) 0.62041(8) 0.0190(2) Uani 1 1 d U B .
O5 O 0.16105(8) 0.63475(9) 0.82429(7) 0.0124(2) Uani 1 1 d U . .
Si1 Si 0.25521(3) 0.57270(3) 0.88180(3) 0.01175(10) Uani 1 1 d U . .
C18 C 0.5201(13) 0.7610(10) 0.5515(7) 0.017(2) Uani 0.592(18) 1 d PDU B 1
C19 C 0.6230(10) 0.8774(8) 0.5834(7) 0.0256(13) Uani 0.592(18) 1 d PDU B 1
H19 H 0.6715 0.9149 0.6536 0.031 Uiso 0.592(18) 1 calc PR B 1
C20 C 0.6560(6) 0.9395(6) 0.5148(8) 0.0295(16) Uani 0.592(18) 1 d PDU B 1
H20 H 0.7264 1.0191 0.5377 0.035 Uiso 0.592(18) 1 calc PR B 1
C21 C 0.5860(8) 0.8852(8) 0.4129(7) 0.0299(14) Uani 0.592(18) 1 d PDU B 1
H21 H 0.6102 0.9259 0.3645 0.036 Uiso 0.592(18) 1 calc PR B 1
C22 C 0.4813(8) 0.7721(8) 0.3808(5) 0.0267(12) Uani 0.592(18) 1 d PDU B 1
H22 H 0.4325 0.7361 0.3108 0.032 Uiso 0.592(18) 1 calc PR B 1
C23 C 0.4468(9) 0.7108(7) 0.4501(5) 0.0196(13) Uani 0.592(18) 1 d PDU B 1
H23 H 0.3729 0.6344 0.4284 0.023 Uiso 0.592(18) 1 calc PR B 1
C18B C 0.5255(18) 0.7654(15) 0.5621(10) 0.016(3) Uani 0.408(18) 1 d PDU B 2
C19B C 0.6238(13) 0.8854(12) 0.6134(9) 0.0184(18) Uani 0.408(18) 1 d PDU B 2
H19B H 0.6587 0.9135 0.6865 0.022 Uiso 0.408(18) 1 calc PR B 2
C20B C 0.6714(8) 0.9645(10) 0.5597(12) 0.031(2) Uani 0.408(18) 1 d PDU B 2
H20B H 0.7375 1.0470 0.5961 0.037 Uiso 0.408(18) 1 calc PR B 2
C21B C 0.6223(11) 0.9231(12) 0.4531(11) 0.029(2) Uani 0.408(18) 1 d PDU B 2
H21B H 0.6545 0.9774 0.4160 0.035 Uiso 0.408(18) 1 calc PR B 2
C22B C 0.5268(14) 0.8032(11) 0.4002(7) 0.034(2) Uani 0.408(18) 1 d PDU B 2
H22B H 0.4925 0.7757 0.3270 0.041 Uiso 0.408(18) 1 calc PR B 2
C23B C 0.4806(14) 0.7225(10) 0.4534(9) 0.026(3) Uani 0.408(18) 1 d PDU B 2
H23B H 0.4181 0.6378 0.4155 0.032 Uiso 0.408(18) 1 calc PR B 2


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 O1 1.4382(15) . ?
C1 C16 1.5268(18) . ?
C1 C2 1.5478(17) . ?
C1 C12 1.5759(17) . ?
C2 C6 1.5377(17) . ?
C2 C3 1.5541(17) . ?
C2 H2 1.0000 . ?
C3 C13 1.5334(19) . ?
C3 C4 1.5570(19) . ?
C3 H3 1.0000 . ?
C4 C5 1.533(2) . ?
C4 H4A 0.9900 . ?
C4 H4B 0.9900 . ?
C5 C6 1.5251(18) . ?
C5 H5A 0.9900 . ?
C5 H5B 0.9900 . ?
C6 C7 1.5262(18) . ?
C6 H6 1.0000 . ?
C7 C14 1.5299(18) . ?
C7 C8 1.5332(18) . ?
C7 H7 1.0000 . ?
C8 O3 1.4174(15) . ?
C8 O2 1.4245(15) . ?
C8 C12 1.5686(17) . ?
C9 O3 1.4298(16) . ?
C9 C10 1.4986(19) . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C10 C11 1.3317(19) . ?
C10 C15 1.5012(19) . ?
C11 C12 1.5167(17) . ?
C11 H11 0.9500 . ?
C12 O5 1.4371(15) . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 O4 1.4178(16) . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C17 O4 1.4252(16) . ?
C17 C18B 1.465(6) . ?
C17 C18 1.540(5) . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C24 Si1 1.8629(14) . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 Si1 1.8641(14) . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C26 C28 1.531(2) . ?
C26 C29 1.5355(19) . ?
C26 C27 1.5365(19) . ?
C26 Si1 1.8948(14) . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
O1 H1 0.8400 . ?
O2 H2A 0.8400 . ?
O5 Si1 1.6550(9) . ?
C18 C19 1.391(3) . ?
C18 C23 1.391(4) . ?
C19 C20 1.381(4) . ?
C19 H19 0.9500 . ?
C20 C21 1.378(5) . ?
C20 H20 0.9500 . ?
C21 C22 1.378(5) . ?
C21 H21 0.9500 . ?
C22 C23 1.386(3) . ?
C22 H22 0.9500 . ?
C23 H23 0.9500 . ?
C18B C19B 1.391(3) . ?
C18B C23B 1.391(4) . ?
C19B C20B 1.381(4) . ?
C19B H19B 0.9500 . ?
C20B C21B 1.378(5) . ?
C20B H20B 0.9500 . ?
C21B C22B 1.378(5) . ?
C21B H21B 0.9500 . ?
C22B C23B 1.386(3) . ?
C22B H22B 0.9500 . ?
C23B H23B 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 C1 C16 105.96(10) . . ?
O1 C1 C2 110.82(10) . . ?
C16 C1 C2 108.17(10) . . ?
O1 C1 C12 110.65(10) . . ?
C16 C1 C12 113.99(10) . . ?
C2 C1 C12 107.26(10) . . ?
C6 C2 C1 112.47(10) . . ?
C6 C2 C3 104.81(10) . . ?
C1 C2 C3 118.81(11) . . ?
C6 C2 H2 106.7 . . ?
C1 C2 H2 106.7 . . ?
C3 C2 H2 106.7 . . ?
C13 C3 C2 112.94(11) . . ?
C13 C3 C4 110.81(11) . . ?
C2 C3 C4 104.34(10) . . ?
C13 C3 H3 109.5 . . ?
C2 C3 H3 109.5 . . ?
C4 C3 H3 109.5 . . ?
C5 C4 C3 105.58(11) . . ?
C5 C4 H4A 110.6 . . ?
C3 C4 H4A 110.6 . . ?
C5 C4 H4B 110.6 . . ?
C3 C4 H4B 110.6 . . ?
H4A C4 H4B 108.8 . . ?
C6 C5 C4 101.47(11) . . ?
C6 C5 H5A 111.5 . . ?
C4 C5 H5A 111.5 . . ?
C6 C5 H5B 111.5 . . ?
C4 C5 H5B 111.5 . . ?
H5A C5 H5B 109.3 . . ?
C5 C6 C7 119.59(11) . . ?
C5 C6 C2 101.96(10) . . ?
C7 C6 C2 111.25(10) . . ?
C5 C6 H6 107.8 . . ?
C7 C6 H6 107.8 . . ?
C2 C6 H6 107.8 . . ?
C6 C7 C14 113.02(11) . . ?
C6 C7 C8 106.40(10) . . ?
C14 C7 C8 111.69(11) . . ?
C6 C7 H7 108.5 . . ?
C14 C7 H7 108.5 . . ?
C8 C7 H7 108.5 . . ?
O3 C8 O2 110.70(10) . . ?
O3 C8 C7 107.47(10) . . ?
O2 C8 C7 106.51(10) . . ?
O3 C8 C12 108.64(10) . . ?
O2 C8 C12 110.79(10) . . ?
C7 C8 C12 112.69(10) . . ?
O3 C9 C10 114.21(11) . . ?
O3 C9 H9A 108.7 . . ?
C10 C9 H9A 108.7 . . ?
O3 C9 H9B 108.7 . . ?
C10 C9 H9B 108.7 . . ?
H9A C9 H9B 107.6 . . ?
C11 C10 C9 121.83(12) . . ?
C11 C10 C15 123.29(13) . . ?
C9 C10 C15 114.87(12) . . ?
C10 C11 C12 121.49(12) . . ?
C10 C11 H11 119.3 . . ?
C12 C11 H11 119.3 . . ?
O5 C12 C11 111.25(10) . . ?
O5 C12 C8 107.68(10) . . ?
C11 C12 C8 107.04(10) . . ?
O5 C12 C1 104.92(10) . . ?
C11 C12 C1 115.16(10) . . ?
C8 C12 C1 110.61(10) . . ?
C3 C13 H13A 109.5 . . ?
C3 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C3 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C7 C14 H14A 109.5 . . ?
C7 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C7 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C10 C15 H15A 109.5 . . ?
C10 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C10 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
O4 C16 C1 112.06(10) . . ?
O4 C16 H16A 109.2 . . ?
C1 C16 H16A 109.2 . . ?
O4 C16 H16B 109.2 . . ?
C1 C16 H16B 109.2 . . ?
H16A C16 H16B 107.9 . . ?
O4 C17 C18B 114.9(8) . . ?
O4 C17 C18 112.1(5) . . ?
C18B C17 C18 4.4(6) . . ?
O4 C17 H17A 109.2 . . ?
C18B C17 H17A 110.5 . . ?
C18 C17 H17A 109.2 . . ?
O4 C17 H17B 109.2 . . ?
C18B C17 H17B 104.8 . . ?
C18 C17 H17B 109.2 . . ?
H17A C17 H17B 107.9 . . ?
Si1 C24 H24A 109.5 . . ?
Si1 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
Si1 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
Si1 C25 H25A 109.5 . . ?
Si1 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
Si1 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C28 C26 C29 108.79(12) . . ?
C28 C26 C27 108.94(12) . . ?
C29 C26 C27 108.51(11) . . ?
C28 C26 Si1 109.71(9) . . ?
C29 C26 Si1 109.51(10) . . ?
C27 C26 Si1 111.32(9) . . ?
C26 C27 H27A 109.5 . . ?
C26 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
C26 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C26 C28 H28A 109.5 . . ?
C26 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C26 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C26 C29 H29A 109.5 . . ?
C26 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C26 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C1 O1 H1 109.5 . . ?
C8 O2 H2A 109.5 . . ?
C8 O3 C9 113.42(10) . . ?
C16 O4 C17 112.19(11) . . ?
C12 O5 Si1 133.83(8) . . ?
O5 Si1 C24 113.46(6) . . ?
O5 Si1 C25 112.46(6) . . ?
C24 Si1 C25 108.50(7) . . ?
O5 Si1 C26 102.75(5) . . ?
C24 Si1 C26 109.83(7) . . ?
C25 Si1 C26 109.70(6) . . ?
C19 C18 C23 118.6(3) . . ?
C19 C18 C17 123.3(5) . . ?
C23 C18 C17 118.1(4) . . ?
C20 C19 C18 121.1(3) . . ?
C20 C19 H19 119.4 . . ?
C18 C19 H19 119.4 . . ?
C21 C20 C19 119.6(3) . . ?
C21 C20 H20 120.2 . . ?
C19 C20 H20 120.2 . . ?
C22 C21 C20 120.3(3) . . ?
C22 C21 H21 119.9 . . ?
C20 C21 H21 119.9 . . ?
C21 C22 C23 120.2(3) . . ?
C21 C22 H22 119.9 . . ?
C23 C22 H22 119.9 . . ?
C22 C23 C18 120.1(3) . . ?
C22 C23 H23 119.9 . . ?
C18 C23 H23 119.9 . . ?
C19B C18B C23B 118.6(3) . . ?
C19B C18B C17 118.2(7) . . ?
C23B C18B C17 123.0(7) . . ?
C20B C19B C18B 121.1(3) . . ?
C20B C19B H19B 119.5 . . ?
C18B C19B H19B 119.5 . . ?
C21B C20B C19B 119.6(3) . . ?
C21B C20B H20B 120.2 . . ?
C19B C20B H20B 120.2 . . ?
C22B C21B C20B 120.3(3) . . ?
C22B C21B H21B 119.9 . . ?
C20B C21B H21B 119.9 . . ?
C21B C22B C23B 120.2(3) . . ?
C21B C22B H22B 119.9 . . ?
C23B C22B H22B 119.9 . . ?
C22B C23B C18B 120.1(3) . . ?
C22B C23B H23B 119.9 . . ?
C18B C23B H23B 119.9 . . ?

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        25.03
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         0.362
_refine_diff_density_min         -0.277
_refine_diff_density_rms         0.040

