# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_database_code_depnum_ccdc_archive 'CCDC 1052824'
_audit_update_record             
;
2015-03-09 deposited with the CCDC.
2015-03-10 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014
_chemical_name_systematic        
;
Tetrakis triphenylphosphane silver(I) perrhenate(VII)
;
_chemical_name_common            
'Tetrakis triphenylphosphane silver(I) perrhenate(VII)'
_chemical_melting_point          'not measured'
_chemical_formula_moiety         'C72 H60 Ag O4 P4 Re'
_chemical_formula_sum            'C72 H60 Ag O4 P4 Re'
_chemical_formula_weight         1407.15

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Re Re -1.0185 7.2310 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      trigonal
_space_group_IT_number           146
_space_group_name_H-M_alt        'R 3 :H'
_space_group_name_Hall           'R 3'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'

_cell_length_a                   14.21920(13)
_cell_length_b                   14.21920(13)
_cell_length_c                   51.1145(9)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_volume                     8950.0(2)
_cell_formula_units_Z            6
_cell_measurement_temperature    123(2)
_cell_measurement_reflns_used    61383
_cell_measurement_theta_min      2.8598
_cell_measurement_theta_max      39.3341

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      'not measured'
_exptl_crystal_density_method    'not measured'
_exptl_crystal_density_diffrn    1.566
_exptl_crystal_F_000             4236
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.27
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.17
_exptl_absorpt_coefficient_mu    2.514
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_T_min  0.89770
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.33.34d (release 27-02-2009 CrysAlis171 .NET)
(compiled Feb 27 2009,15:38:38)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_diffrn_ambient_temperature      123(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Goniometer KM4/Xcalibur, detector: Sapphire3'
_diffrn_measurement_method       ' phi- and omega-rotation '
_diffrn_detector_area_resol_mean 16.0238
_diffrn_reflns_number            204674
_diffrn_reflns_av_unetI/netI     0.0635
_diffrn_reflns_av_R_equivalents  0.0588
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_l_min       -89
_diffrn_reflns_limit_l_max       90
_diffrn_reflns_theta_min         2.865
_diffrn_reflns_theta_max         39.381
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.975
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.975
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.975
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             22832
_reflns_number_gt                12209
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         1.000
_reflns_Friedel_fraction_max     0.975
_reflns_Friedel_fraction_full    0.998

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
 Refined as a 2-component inversion twin.
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0729P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_abs_structure_details 
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.515(10)
_chemical_absolute_configuration ?
_refine_ls_number_reflns         22832
_refine_ls_number_parameters     496
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0954
_refine_ls_R_factor_gt           0.0506
_refine_ls_wR_factor_ref         0.1408
_refine_ls_wR_factor_gt          0.1280
_refine_ls_goodness_of_fit_ref   0.922
_refine_ls_restrained_S_all      0.922
_refine_ls_shift/su_max          0.010
_refine_ls_shift/su_mean         0.002

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.1285(8) 0.0978(8) 0.49051(14) 0.0292(18) Uani 1 1 d . . . . .
C2 C 0.2232(9) 0.1067(8) 0.48121(16) 0.040(2) Uani 1 1 d . . . . .
H2 H 0.2210 0.0627 0.4675 0.049 Uiso 1 1 calc R U . . .
C3 C 0.3202(8) 0.1795(8) 0.4920(2) 0.040(2) Uani 1 1 d . . . . .
H3 H 0.3844 0.1899 0.4846 0.048 Uiso 1 1 calc R U . . .
C4 C 0.3235(10) 0.2374(9) 0.5136(2) 0.042(2) Uani 1 1 d . . . . .
H4 H 0.3892 0.2818 0.5220 0.051 Uiso 1 1 calc R U . . .
C5 C 0.2316(10) 0.2299(9) 0.5228(2) 0.050(3) Uani 1 1 d . . . . .
H5 H 0.2358 0.2725 0.5370 0.061 Uiso 1 1 calc R U . . .
C6 C 0.1331(8) 0.1630(8) 0.51217(14) 0.035(2) Uani 1 1 d . . . . .
H6 H 0.0706 0.1598 0.5188 0.042 Uiso 1 1 calc R U . . .
C7 C 0.1821(7) 0.3157(7) 0.41847(15) 0.0268(16) Uani 1 1 d . . . . .
C8 C 0.2131(8) 0.3068(8) 0.44313(18) 0.038(2) Uani 1 1 d . . . . .
H8 H 0.1749 0.2420 0.4523 0.046 Uiso 1 1 calc R U . . .
C9 C 0.3062(8) 0.3991(8) 0.45496(19) 0.040(2) Uani 1 1 d . . . . .
H9 H 0.3295 0.3952 0.4717 0.048 Uiso 1 1 calc R U . . .
C10 C 0.3590(8) 0.4931(8) 0.4402(2) 0.040(2) Uani 1 1 d . . . . .
H10 H 0.4164 0.5546 0.4478 0.048 Uiso 1 1 calc R U . . .
C11 C 0.3299(8) 0.4997(8) 0.41456(18) 0.040(2) Uani 1 1 d . . . . .
H11 H 0.3698 0.5617 0.4045 0.048 Uiso 1 1 calc R U . . .
C12 C 0.2391(8) 0.4097(8) 0.40481(18) 0.040(2) Uani 1 1 d . . . . .
H12 H 0.2156 0.4136 0.3881 0.048 Uiso 1 1 calc R U . . .
C13 C -0.0449(7) 0.2340(7) 0.41538(16) 0.0332(18) Uani 1 1 d . . . . .
C14 C -0.0206(7) 0.3329(7) 0.42663(15) 0.0271(17) Uani 1 1 d . . . . .
H14 H 0.0512 0.3884 0.4281 0.033 Uiso 1 1 calc R U . . .
C15 C -0.1032(8) 0.3479(8) 0.43551(19) 0.040(2) Uani 1 1 d . . . . .
H15 H -0.0860 0.4116 0.4444 0.048 Uiso 1 1 calc R U . . .
C16 C -0.2128(9) 0.2703(10) 0.4316(2) 0.045(3) Uani 1 1 d . . . . .
H16 H -0.2674 0.2845 0.4365 0.054 Uiso 1 1 calc R U . . .
C17 C -0.2373(7) 0.1754(8) 0.4205(2) 0.048(3) Uani 1 1 d . . . . .
H17 H -0.3099 0.1227 0.4184 0.057 Uiso 1 1 calc R U . . .
C18 C -0.1561(6) 0.1530(7) 0.41193(18) 0.0312(18) Uani 1 1 d . . . . .
H18 H -0.1747 0.0867 0.4042 0.037 Uiso 1 1 calc R U . . .
C19 C 0.0741(7) 0.2195(7) 0.37096(14) 0.0271(17) Uani 1 1 d . . . . .
C20 C 0.0447(10) 0.2859(10) 0.35847(17) 0.054(3) Uani 1 1 d . . . . .
H20 H 0.0102 0.3167 0.3676 0.064 Uiso 1 1 calc R U . . .
C21 C 0.0666(13) 0.3063(14) 0.3326(3) 0.088(5) Uani 1 1 d . . . . .
H21 H 0.0538 0.3571 0.3243 0.105 Uiso 1 1 calc R U . . .
C22 C 0.1102(10) 0.2488(12) 0.31775(17) 0.063(3) Uani 1 1 d . . . . .
H22 H 0.1218 0.2595 0.2998 0.075 Uiso 1 1 calc R U . . .
C23 C 0.1320(8) 0.1834(10) 0.32986(18) 0.050(3) Uani 1 1 d . . . . .
H23 H 0.1589 0.1459 0.3204 0.060 Uiso 1 1 calc R U . . .
C24 C 0.1167(7) 0.1663(8) 0.35696(15) 0.0314(18) Uani 1 1 d . . . . .
H24 H 0.1349 0.1197 0.3654 0.038 Uiso 1 1 calc R U . . .
C25 C 0.4300(7) 0.6386(7) 0.52780(14) 0.0248(16) Uani 1 1 d . . . . .
C26 C 0.4409(7) 0.5513(7) 0.53752(14) 0.0291(17) Uani 1 1 d . . . . .
H26 H 0.4015 0.5133 0.5522 0.035 Uiso 1 1 calc R U . . .
C27 C 0.5106(9) 0.5214(8) 0.52532(18) 0.040(2) Uani 1 1 d . . . . .
H27 H 0.5126 0.4601 0.5309 0.048 Uiso 1 1 calc R U . . .
C28 C 0.5765(10) 0.5844(10) 0.5049(2) 0.047(3) Uani 1 1 d . . . . .
H28 H 0.6270 0.5684 0.4977 0.057 Uiso 1 1 calc R U . . .
C29 C 0.5678(9) 0.6714(9) 0.49498(18) 0.045(3) Uani 1 1 d . . . . .
H29 H 0.6095 0.7120 0.4808 0.054 Uiso 1 1 calc R U . . .
C30 C 0.4926(8) 0.6954(9) 0.50735(17) 0.041(2) Uani 1 1 d . . . . .
H30 H 0.4864 0.7534 0.5010 0.049 Uiso 1 1 calc R U . . .
C31 C 0.1534(7) 0.3533(6) 0.59937(15) 0.0231(15) Uani 1 1 d . . . . .
C32 C 0.1173(7) 0.3543(7) 0.57354(14) 0.0277(16) Uani 1 1 d . . . . .
H32 H 0.1548 0.4169 0.5635 0.033 Uiso 1 1 calc R U . . .
C33 C 0.0323(8) 0.2692(8) 0.56340(18) 0.040(2) Uani 1 1 d . . . . .
H33 H 0.0128 0.2737 0.5463 0.048 Uiso 1 1 calc R U . . .
C34 C -0.0288(8) 0.1745(9) 0.5768(2) 0.044(2) Uani 1 1 d . . . . .
H34 H -0.0901 0.1169 0.5693 0.053 Uiso 1 1 calc R U . . .
C35 C 0.0030(9) 0.1674(8) 0.6013(2) 0.047(3) Uani 1 1 d . . . . .
H35 H -0.0347 0.1016 0.6101 0.056 Uiso 1 1 calc R U . . .
C36 C 0.0917(7) 0.2567(6) 0.61421(16) 0.034(2) Uani 1 1 d . . . . .
H36 H 0.1086 0.2519 0.6316 0.041 Uiso 1 1 calc R U . . .
C37 C 0.2674(7) 0.4538(7) 0.64675(15) 0.0272(16) Uani 1 1 d . . . . .
C38 C 0.2220(8) 0.5039(8) 0.66105(17) 0.036(2) Uani 1 1 d . . . . .
H38 H 0.2055 0.5516 0.6525 0.043 Uiso 1 1 calc R U . . .
C39 C 0.2007(9) 0.4859(9) 0.68717(19) 0.046(2) Uani 1 1 d . . . . .
H39 H 0.1707 0.5206 0.6965 0.055 Uiso 1 1 calc R U . . .
C40 C 0.2270(8) 0.4091(11) 0.69989(17) 0.061(3) Uani 1 1 d . . . . .
H40 H 0.2127 0.3943 0.7176 0.073 Uiso 1 1 calc R U . . .
C41 C 0.2694(9) 0.3621(10) 0.68693(12) 0.053(3) Uani 1 1 d . . . . .
H41 H 0.2858 0.3145 0.6956 0.064 Uiso 1 1 calc R U . . .
C42 C 0.2915(8) 0.3807(8) 0.66028(16) 0.042(2) Uani 1 1 d . . . . .
H42 H 0.3219 0.3454 0.6513 0.050 Uiso 1 1 calc R U . . .
C43 C 0.3805(5) 0.4345(6) 0.60276(11) 0.0179(12) Uani 1 1 d . . . . .
C44 C 0.4872(8) 0.5093(7) 0.60703(17) 0.036(2) Uani 1 1 d . . . . .
H44 H 0.5042 0.5733 0.6158 0.043 Uiso 1 1 calc R U . . .
C45 C 0.5682(7) 0.4935(7) 0.59902(15) 0.036(2) Uani 1 1 d . . . . .
H45 H 0.6400 0.5468 0.6019 0.043 Uiso 1 1 calc R U . . .
C46 C 0.5448(7) 0.3965(8) 0.58626(16) 0.033(2) Uani 1 1 d . . . . .
H46 H 0.6010 0.3870 0.5801 0.040 Uiso 1 1 calc R U . . .
C47 C 0.4398(8) 0.3167(8) 0.58298(17) 0.035(2) Uani 1 1 d . . . . .
H47 H 0.4237 0.2502 0.5758 0.042 Uiso 1 1 calc R U . . .
C48 C 0.3553(7) 0.3363(8) 0.59073(15) 0.0295(17) Uani 1 1 d . . . . .
H48 H 0.2831 0.2839 0.5878 0.035 Uiso 1 1 calc R U . . .
O1 O 0.4316(7) 0.6455(7) 0.35936(19) 0.134(3) Uani 1 1 d . . . . .
O2 O 0.3333 0.6667 0.3137(2) 0.201(10) Uani 1 3 d S T P . .
O3A O 0.5432(4) 0.2569(5) 0.53043(11) 0.0754(15) Uani 1 1 d . . . . .
O4A O 0.6667 0.3333 0.4906(8) 0.38(3) Uiso 1 3 d S . P . .
P1 P 0.0000 0.0000 0.47485(7) 0.0289(9) Uani 1 3 d S T P . .
P2 P 0.05700(18) 0.19700(17) 0.40654(4) 0.0223(4) Uani 1 1 d . . . . .
P3 P 0.3333 0.6667 0.54344(6) 0.0214(7) Uani 1 3 d S T P . .
P4 P 0.27718(18) 0.46932(17) 0.61169(4) 0.0211(4) Uani 1 1 d . . . . .
Ag1 Ag 0.0000 0.0000 0.42352(2) 0.0218(2) Uani 1 3 d S T P . .
Ag2 Ag 0.3333 0.6667 0.59474(2) 0.01836(18) Uani 1 3 d S T P . .
Re1 Re 0.3333 0.6667 0.34260(3) 0.06506(12) Uani 1 3 d S T P . .
Re2A Re 0.6667 0.3333 0.50602(5) 0.0633(5) Uani 0.746(6) 3 d S T P . .
Re2B Re 0.6667 0.3333 0.51722(4) 0.0203(6) Uiso 0.254(6) 3 d S . P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.372(13) . ?
C1 C6 1.425(11) . ?
C1 P1 1.836(9) . ?
C2 C3 1.360(13) . ?
C3 C4 1.366(14) . ?
C4 C5 1.340(16) . ?
C5 C6 1.352(14) . ?
C7 C12 1.359(13) . ?
C7 C8 1.362(12) . ?
C7 P2 1.839(9) . ?
C8 C9 1.450(12) . ?
C9 C10 1.384(14) . ?
C10 C11 1.392(14) . ?
C11 C12 1.379(13) . ?
C13 C14 1.393(12) . ?
C13 C18 1.427(11) . ?
C13 P2 1.828(9) . ?
C14 C15 1.373(12) . ?
C15 C16 1.403(15) . ?
C16 C17 1.339(14) . ?
C17 C18 1.413(11) . ?
C19 C20 1.367(13) . ?
C19 C24 1.382(12) . ?
C19 P2 1.842(8) . ?
C20 C21 1.354(15) . ?
C21 C22 1.464(18) . ?
C22 C23 1.278(16) . ?
C23 C24 1.404(12) . ?
C25 C30 1.349(11) . ?
C25 C26 1.416(11) . ?
C25 P3 1.799(9) . ?
C26 C27 1.404(12) . ?
C27 C28 1.390(14) . ?
C28 C29 1.398(14) . ?
C29 C30 1.423(12) . ?
C31 C32 1.419(11) . ?
C31 C36 1.424(9) . ?
C31 P4 1.820(9) . ?
C32 C33 1.316(13) . ?
C33 C34 1.365(14) . ?
C34 C35 1.353(15) . ?
C35 C36 1.427(13) . ?
C37 C38 1.384(12) . ?
C37 C42 1.425(11) . ?
C37 P4 1.803(8) . ?
C38 C39 1.365(12) . ?
C39 C40 1.471(16) . ?
C40 C41 1.285(15) . ?
C41 C42 1.393(10) . ?
C43 C44 1.367(12) . ?
C43 C48 1.398(11) . ?
C43 P4 1.827(6) . ?
C44 C45 1.344(12) . ?
C45 C46 1.406(12) . ?
C46 C47 1.360(14) . ?
C47 C48 1.420(12) . ?
O1 Re1 1.788(8) . ?
O2 Re1 1.478(12) . ?
O3A Re2B 1.677(5) . ?
O3A Re2A 1.978(5) . ?
O4A Re2A 0.79(4) . ?
O4A Re2B 1.36(4) . ?
P1 C1 1.836(9) 3 ?
P1 C1 1.836(9) 2 ?
P1 Ag1 2.624(4) . ?
P2 Ag1 2.643(2) . ?
P3 C25 1.799(9) 3_565 ?
P3 C25 1.799(9) 2_665 ?
P3 Ag2 2.622(3) . ?
P4 Ag2 2.650(2) . ?
Ag1 P2 2.643(2) 2 ?
Ag1 P2 2.643(2) 3 ?
Ag2 P4 2.650(2) 3_565 ?
Ag2 P4 2.650(2) 2_665 ?
Re1 O1 1.788(8) 3_565 ?
Re1 O1 1.788(8) 2_665 ?
Re2A Re2B 0.572(2) . ?
Re2A O3A 1.978(5) 2_655 ?
Re2A O3A 1.978(5) 3_665 ?
Re2B O3A 1.677(5) 2_655 ?
Re2B O3A 1.677(5) 3_665 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 C6 119.1(9) . . ?
C2 C1 P1 118.5(7) . . ?
C6 C1 P1 122.4(7) . . ?
C3 C2 C1 120.3(9) . . ?
C2 C3 C4 120.2(10) . . ?
C5 C4 C3 119.7(10) . . ?
C4 C5 C6 122.8(10) . . ?
C5 C6 C1 117.6(9) . . ?
C12 C7 C8 120.4(9) . . ?
C12 C7 P2 124.0(7) . . ?
C8 C7 P2 115.5(7) . . ?
C7 C8 C9 119.6(9) . . ?
C10 C9 C8 117.1(9) . . ?
C9 C10 C11 122.8(9) . . ?
C12 C11 C10 116.8(9) . . ?
C7 C12 C11 123.2(9) . . ?
C14 C13 C18 118.8(8) . . ?
C14 C13 P2 124.1(7) . . ?
C18 C13 P2 117.0(6) . . ?
C15 C14 C13 119.6(9) . . ?
C14 C15 C16 122.1(9) . . ?
C17 C16 C15 118.7(9) . . ?
C16 C17 C18 121.9(9) . . ?
C17 C18 C13 118.7(8) . . ?
C20 C19 C24 120.3(7) . . ?
C20 C19 P2 121.5(7) . . ?
C24 C19 P2 118.2(7) . . ?
C21 C20 C19 119.2(11) . . ?
C20 C21 C22 120.2(12) . . ?
C23 C22 C21 118.7(9) . . ?
C22 C23 C24 122.0(10) . . ?
C19 C24 C23 119.3(9) . . ?
C30 C25 C26 117.9(8) . . ?
C30 C25 P3 124.1(7) . . ?
C26 C25 P3 118.0(5) . . ?
C27 C26 C25 120.8(7) . . ?
C28 C27 C26 119.3(9) . . ?
C27 C28 C29 120.9(10) . . ?
C28 C29 C30 117.5(9) . . ?
C25 C30 C29 123.4(9) . . ?
C32 C31 C36 117.0(8) . . ?
C32 C31 P4 120.2(6) . . ?
C36 C31 P4 122.7(6) . . ?
C33 C32 C31 121.8(8) . . ?
C32 C33 C34 123.2(9) . . ?
C35 C34 C33 117.8(9) . . ?
C34 C35 C36 122.8(9) . . ?
C31 C36 C35 117.1(8) . . ?
C38 C37 C42 117.5(8) . . ?
C38 C37 P4 119.3(7) . . ?
C42 C37 P4 122.7(7) . . ?
C39 C38 C37 122.5(10) . . ?
C38 C39 C40 117.1(10) . . ?
C41 C40 C39 121.2(8) . . ?
C40 C41 C42 121.7(9) . . ?
C41 C42 C37 119.9(9) . . ?
C44 C43 C48 118.6(7) . . ?
C44 C43 P4 118.6(6) . . ?
C48 C43 P4 122.7(6) . . ?
C45 C44 C43 122.1(8) . . ?
C44 C45 C46 120.2(9) . . ?
C47 C46 C45 119.9(8) . . ?
C46 C47 C48 119.1(9) . . ?
C43 C48 C47 119.9(8) . . ?
Re2B O3A Re2A 15.36(9) . . ?
Re2A O4A Re2B 0.000(1) . . ?
C1 P1 C1 102.4(3) . 3 ?
C1 P1 C1 102.4(3) . 2 ?
C1 P1 C1 102.4(3) 3 2 ?
C1 P1 Ag1 115.8(3) . . ?
C1 P1 Ag1 115.8(3) 3 . ?
C1 P1 Ag1 115.8(3) 2 . ?
C13 P2 C7 101.3(4) . . ?
C13 P2 C19 104.4(4) . . ?
C7 P2 C19 100.7(4) . . ?
C13 P2 Ag1 110.9(3) . . ?
C7 P2 Ag1 120.5(3) . . ?
C19 P2 Ag1 116.9(3) . . ?
C25 P3 C25 101.7(3) . 3_565 ?
C25 P3 C25 101.7(3) . 2_665 ?
C25 P3 C25 101.7(3) 3_565 2_665 ?
C25 P3 Ag2 116.4(2) . . ?
C25 P3 Ag2 116.4(2) 3_565 . ?
C25 P3 Ag2 116.4(2) 2_665 . ?
C37 P4 C31 104.6(4) . . ?
C37 P4 C43 103.8(4) . . ?
C31 P4 C43 102.2(3) . . ?
C37 P4 Ag2 114.8(3) . . ?
C31 P4 Ag2 119.3(2) . . ?
C43 P4 Ag2 110.4(2) . . ?
P1 Ag1 P2 109.16(5) . 2 ?
P1 Ag1 P2 109.16(5) . 3 ?
P2 Ag1 P2 109.78(5) 2 3 ?
P1 Ag1 P2 109.16(5) . . ?
P2 Ag1 P2 109.78(5) 2 . ?
P2 Ag1 P2 109.78(5) 3 . ?
P3 Ag2 P4 109.08(5) . 3_565 ?
P3 Ag2 P4 109.08(5) . . ?
P4 Ag2 P4 109.86(5) 3_565 . ?
P3 Ag2 P4 109.08(5) . 2_665 ?
P4 Ag2 P4 109.86(5) 3_565 2_665 ?
P4 Ag2 P4 109.86(5) . 2_665 ?
O2 Re1 O1 118.6(3) . . ?
O2 Re1 O1 118.6(3) . 3_565 ?
O1 Re1 O1 98.9(4) . 3_565 ?
O2 Re1 O1 118.6(3) . 2_665 ?
O1 Re1 O1 98.9(4) . 2_665 ?
O1 Re1 O1 98.9(4) 3_565 2_665 ?
Re2B Re2A O4A 180.00(3) . . ?
Re2B Re2A O3A 50.91(18) . 2_655 ?
O4A Re2A O3A 129.09(18) . 2_655 ?
Re2B Re2A O3A 50.91(18) . 3_665 ?
O4A Re2A O3A 129.09(19) . 3_665 ?
O3A Re2A O3A 84.5(3) 2_655 3_665 ?
Re2B Re2A O3A 50.91(19) . . ?
O4A Re2A O3A 129.09(19) . . ?
O3A Re2A O3A 84.5(3) 2_655 . ?
O3A Re2A O3A 84.5(3) 3_665 . ?
Re2A Re2B O4A 0.000(10) . . ?
Re2A Re2B O3A 113.7(2) . . ?
O4A Re2B O3A 113.7(2) . . ?
Re2A Re2B O3A 113.7(2) . 2_655 ?
O4A Re2B O3A 113.7(2) . 2_655 ?
O3A Re2B O3A 104.9(2) . 2_655 ?
Re2A Re2B O3A 113.7(2) . 3_665 ?
O4A Re2B O3A 113.7(2) . 3_665 ?
O3A Re2B O3A 104.9(2) . 3_665 ?
O3A Re2B O3A 104.9(3) 2_655 3_665 ?

_refine_diff_density_max         4.270
_refine_diff_density_min         -3.421
_refine_diff_density_rms         0.117

_shelxl_version_number           2014-3

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_database_code_depnum_ccdc_archive 'CCDC 1052825'
_audit_update_record             
;
2015-03-09 deposited with the CCDC.
2015-03-10 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014
_chemical_name_systematic        
;
'Bis(triphenylphosphine) silver(I) perrhenate(VII)'
;
_chemical_name_common            
'Bis(triphenylphosphine) silver(I) perrhenate(VII)'
_chemical_melting_point          'not measured'
_chemical_formula_moiety         'C72 H60 Ag2 O8 P4 Re2'
_chemical_formula_sum            'C72 H60 Ag2 O8 P4 Re2'
_chemical_formula_weight         1765.22

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Re Re -1.0185 7.2310 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.1764(4)
_cell_length_b                   12.4966(3)
_cell_length_c                   13.2647(5)
_cell_angle_alpha                89.938(2)
_cell_angle_beta                 62.745(3)
_cell_angle_gamma                68.528(2)
_cell_volume                     1635.60(10)
_cell_formula_units_Z            1
_cell_measurement_temperature    123(2)
_cell_measurement_reflns_used    16988
_cell_measurement_theta_min      2.75
_cell_measurement_theta_max      39.21

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      'not measured'
_exptl_crystal_density_method    'not measured'
_exptl_crystal_density_diffrn    1.792
_exptl_crystal_F_000             860
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.3
_exptl_crystal_size_min          0.2
_exptl_absorpt_coefficient_mu    4.432
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.75231
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.33.34d (release 27-02-2009 CrysAlis171 .NET)
(compiled Feb 27 2009,15:38:38)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      123(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device       ' κ-geometry diffractometer '
_diffrn_measurement_device_type  ' Oxford-Diffraction Xcalibur3 '
_diffrn_measurement_method       ' phi- and omega-rotation '
_diffrn_detector                 ' CCD plate '
_diffrn_detector_area_resol_mean 16.0238
_diffrn_reflns_number            68987
_diffrn_reflns_av_unetI/netI     0.1383
_diffrn_reflns_av_R_equivalents  0.0620
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_theta_min         2.753
_diffrn_reflns_theta_max         39.321
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.948
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.948
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.948
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             18415
_reflns_number_gt                8110
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0364P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         18415
_refine_ls_number_parameters     416
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1117
_refine_ls_R_factor_gt           0.0403
_refine_ls_wR_factor_ref         0.0846
_refine_ls_wR_factor_gt          0.0747
_refine_ls_goodness_of_fit_ref   0.776
_refine_ls_restrained_S_all      0.776
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.5782(3) -0.4358(2) 0.1989(2) 0.0202(5) Uani 1 1 d . . . . .
C2 C 0.6518(3) -0.5217(3) 0.2376(3) 0.0274(6) Uani 1 1 d . . . . .
H2 H 0.6932 -0.5022 0.2743 0.033 Uiso 1 1 calc R U . . .
C3 C 0.6642(3) -0.6357(3) 0.2224(3) 0.0320(7) Uani 1 1 d . . . . .
H3 H 0.7144 -0.6924 0.2481 0.038 Uiso 1 1 calc R U . . .
C4 C 0.6020(3) -0.6654(3) 0.1692(3) 0.0340(7) Uani 1 1 d . . . . .
H4 H 0.6096 -0.7419 0.1594 0.041 Uiso 1 1 calc R U . . .
C5 C 0.5290(4) -0.5813(3) 0.1307(3) 0.0357(8) Uani 1 1 d . . . . .
H5 H 0.4873 -0.6014 0.0947 0.043 Uiso 1 1 calc R U . . .
C6 C 0.5167(3) -0.4667(3) 0.1449(3) 0.0287(7) Uani 1 1 d . . . . .
H6 H 0.4672 -0.4106 0.1183 0.034 Uiso 1 1 calc R U . . .
C7 C 0.4165(3) -0.1931(2) 0.2130(3) 0.0221(6) Uani 1 1 d . . . . .
C8 C 0.2941(3) -0.1353(3) 0.3153(3) 0.0322(7) Uani 1 1 d . . . . .
H8 H 0.2899 -0.1432 0.3865 0.039 Uiso 1 1 calc R U . . .
C9 C 0.1789(3) -0.0659(3) 0.3102(3) 0.0444(9) Uani 1 1 d . . . . .
H9 H 0.0971 -0.0286 0.3785 0.053 Uiso 1 1 calc R U . . .
C10 C 0.1836(3) -0.0515(3) 0.2063(3) 0.0390(8) Uani 1 1 d . . . . .
H10 H 0.1054 -0.0051 0.2042 0.047 Uiso 1 1 calc R U . . .
C11 C 0.3053(4) -0.1062(3) 0.1041(3) 0.0357(8) Uani 1 1 d . . . . .
H11 H 0.3094 -0.0952 0.0333 0.043 Uiso 1 1 calc R U . . .
C12 C 0.4212(3) -0.1778(3) 0.1078(3) 0.0277(6) Uani 1 1 d . . . . .
H12 H 0.5025 -0.2156 0.0392 0.033 Uiso 1 1 calc R U . . .
C13 C 0.7093(3) -0.2820(2) 0.0965(2) 0.0209(5) Uani 1 1 d . . . . .
C14 C 0.8112(3) -0.3798(3) 0.0128(3) 0.0272(6) Uani 1 1 d . . . . .
H14 H 0.8016 -0.4503 0.0139 0.033 Uiso 1 1 calc R U . . .
C15 C 0.9285(3) -0.3738(3) -0.0734(3) 0.0339(7) Uani 1 1 d . . . . .
H15 H 0.9978 -0.4407 -0.1285 0.041 Uiso 1 1 calc R U . . .
C16 C 0.9420(3) -0.2687(3) -0.0771(3) 0.0333(7) Uani 1 1 d . . . . .
H16 H 1.0199 -0.2647 -0.1358 0.040 Uiso 1 1 calc R U . . .
C17 C 0.8412(3) -0.1697(3) 0.0053(3) 0.0304(7) Uani 1 1 d . . . . .
H17 H 0.8509 -0.0992 0.0029 0.036 Uiso 1 1 calc R U . . .
C18 C 0.7242(3) -0.1764(3) 0.0927(3) 0.0259(6) Uani 1 1 d . . . . .
H18 H 0.6557 -0.1099 0.1487 0.031 Uiso 1 1 calc R U . . .
C19 C 0.7176(3) -0.2814(2) 0.5903(2) 0.0212(6) Uani 1 1 d . . . . .
C20 C 0.7489(3) -0.3549(3) 0.6604(3) 0.0259(6) Uani 1 1 d . . . . .
H20 H 0.7866 -0.4358 0.6353 0.031 Uiso 1 1 calc R U . . .
C21 C 0.7247(3) -0.3096(3) 0.7670(3) 0.0314(7) Uani 1 1 d . . . . .
H21 H 0.7457 -0.3598 0.8135 0.038 Uiso 1 1 calc R U . . .
C22 C 0.6697(3) -0.1901(3) 0.8043(3) 0.0380(8) Uani 1 1 d . . . . .
H22 H 0.6555 -0.1595 0.8753 0.046 Uiso 1 1 calc R U . . .
C23 C 0.6356(4) -0.1155(3) 0.7365(3) 0.0411(9) Uani 1 1 d . . . . .
H23 H 0.5973 -0.0347 0.7625 0.049 Uiso 1 1 calc R U . . .
C24 C 0.6580(3) -0.1602(3) 0.6306(3) 0.0321(7) Uani 1 1 d . . . . .
H24 H 0.6334 -0.1095 0.5859 0.038 Uiso 1 1 calc R U . . .
C25 C 0.9132(3) -0.3309(2) 0.3464(2) 0.0199(5) Uani 1 1 d . . . . .
C26 C 1.0093(3) -0.3374(3) 0.3779(3) 0.0258(6) Uani 1 1 d . . . . .
H26 H 0.9919 -0.3429 0.4532 0.031 Uiso 1 1 calc R U . . .
C27 C 1.1309(3) -0.3356(3) 0.2971(3) 0.0306(7) Uani 1 1 d . . . . .
H27 H 1.1955 -0.3414 0.3182 0.037 Uiso 1 1 calc R U . . .
C28 C 1.1575(3) -0.3254(3) 0.1854(3) 0.0314(7) Uani 1 1 d . . . . .
H28 H 1.2394 -0.3240 0.1318 0.038 Uiso 1 1 calc R U . . .
C29 C 1.0611(3) -0.3173(3) 0.1538(3) 0.0283(6) Uani 1 1 d . . . . .
H29 H 1.0782 -0.3102 0.0788 0.034 Uiso 1 1 calc R U . . .
C30 C 0.9394(3) -0.3197(3) 0.2344(2) 0.0243(6) Uani 1 1 d . . . . .
H30 H 0.8747 -0.3138 0.2132 0.029 Uiso 1 1 calc R U . . .
C31 C 0.7882(3) -0.4909(2) 0.4422(2) 0.0203(5) Uani 1 1 d . . . . .
C32 C 0.6785(3) -0.5218(3) 0.4999(3) 0.0276(6) Uani 1 1 d . . . . .
H32 H 0.5910 -0.4636 0.5420 0.033 Uiso 1 1 calc R U . . .
C33 C 0.7004(3) -0.6390(3) 0.4943(3) 0.0317(7) Uani 1 1 d . . . . .
H33 H 0.6275 -0.6593 0.5334 0.038 Uiso 1 1 calc R U . . .
C34 C 0.8307(3) -0.7264(3) 0.4306(3) 0.0289(7) Uani 1 1 d . . . . .
H34 H 0.8446 -0.8049 0.4259 0.035 Uiso 1 1 calc R U . . .
C35 C 0.9389(3) -0.6967(3) 0.3744(3) 0.0263(6) Uani 1 1 d . . . . .
H35 H 1.0263 -0.7552 0.3328 0.032 Uiso 1 1 calc R U . . .
C36 C 0.9183(3) -0.5793(2) 0.3797(2) 0.0236(6) Uani 1 1 d . . . . .
H36 H 0.9919 -0.5598 0.3413 0.028 Uiso 1 1 calc R U . . .
O1 O 0.6371(2) -0.06311(19) 0.3625(2) 0.0393(6) Uani 1 1 d . . . . .
O2 O 0.6122(2) 0.1623(2) 0.4281(2) 0.0417(6) Uani 1 1 d . . . . .
O3A O 0.8171(15) 0.0276(14) 0.2098(17) 0.056(4) Uani 0.44(5) 1 d . . P . .
O3B O 0.763(4) 0.054(2) 0.1977(11) 0.099(8) Uani 0.56(5) 1 d . . P . .
O4A O 0.8259(15) -0.0260(12) 0.4057(13) 0.049(4) Uani 0.44(5) 1 d . . P . .
O4B O 0.8607(19) -0.0344(12) 0.350(4) 0.128(8) Uani 0.56(5) 1 d . . P . .
P1 P 0.56421(7) -0.28671(6) 0.22300(6) 0.02011(14) Uani 1 1 d . . . . .
P2 P 0.75204(7) -0.33528(6) 0.44684(6) 0.01909(14) Uani 1 1 d . . . . .
Ag1 Ag 0.58457(2) -0.24099(2) 0.38762(2) 0.02062(5) Uani 1 1 d . . . . .
Re1 Re 0.72069(2) 0.02670(2) 0.34186(2) 0.03650(5) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C6 1.388(4) . ?
C1 C2 1.391(4) . ?
C1 P1 1.823(3) . ?
C2 C3 1.381(4) . ?
C3 C4 1.380(5) . ?
C4 C5 1.373(5) . ?
C5 C6 1.388(4) . ?
C7 C12 1.386(4) . ?
C7 C8 1.395(4) . ?
C7 P1 1.816(3) . ?
C8 C9 1.385(5) . ?
C9 C10 1.368(5) . ?
C10 C11 1.386(5) . ?
C11 C12 1.391(4) . ?
C13 C14 1.378(4) . ?
C13 C18 1.394(4) . ?
C13 P1 1.817(3) . ?
C14 C15 1.390(4) . ?
C15 C16 1.381(5) . ?
C16 C17 1.376(5) . ?
C17 C18 1.399(4) . ?
C19 C20 1.385(4) . ?
C19 C24 1.397(4) . ?
C19 P2 1.821(3) . ?
C20 C21 1.380(4) . ?
C21 C22 1.375(5) . ?
C22 C23 1.381(5) . ?
C23 C24 1.378(5) . ?
C25 C30 1.388(4) . ?
C25 C26 1.389(4) . ?
C25 P2 1.820(3) . ?
C26 C27 1.382(4) . ?
C27 C28 1.380(5) . ?
C28 C29 1.389(4) . ?
C29 C30 1.387(4) . ?
C31 C36 1.391(4) . ?
C31 C32 1.400(4) . ?
C31 P2 1.824(3) . ?
C32 C33 1.385(4) . ?
C33 C34 1.389(4) . ?
C34 C35 1.374(4) . ?
C35 C36 1.391(4) . ?
O1 Re1 1.718(2) . ?
O1 Ag1 2.511(2) . ?
O2 Re1 1.705(2) . ?
O2 Ag1 2.366(2) 2_656 ?
O3A O3B 0.71(3) . ?
O3A Re1 1.604(18) . ?
O3B Re1 1.806(18) . ?
O4A O4B 0.65(4) . ?
O4A Re1 1.779(10) . ?
O4B Re1 1.646(15) . ?
P1 Ag1 2.3997(8) . ?
P2 Ag1 2.4227(7) . ?
Ag1 O2 2.366(2) 2_656 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C6 C1 C2 118.6(3) . . ?
C6 C1 P1 122.6(2) . . ?
C2 C1 P1 118.7(2) . . ?
C3 C2 C1 120.9(3) . . ?
C4 C3 C2 120.0(3) . . ?
C5 C4 C3 119.7(3) . . ?
C4 C5 C6 120.8(3) . . ?
C1 C6 C5 120.0(3) . . ?
C12 C7 C8 119.2(3) . . ?
C12 C7 P1 122.4(2) . . ?
C8 C7 P1 118.4(2) . . ?
C9 C8 C7 119.7(3) . . ?
C10 C9 C8 121.0(3) . . ?
C9 C10 C11 119.9(3) . . ?
C10 C11 C12 119.7(3) . . ?
C7 C12 C11 120.5(3) . . ?
C14 C13 C18 119.2(3) . . ?
C14 C13 P1 123.2(2) . . ?
C18 C13 P1 117.2(2) . . ?
C13 C14 C15 120.4(3) . . ?
C16 C15 C14 120.0(3) . . ?
C17 C16 C15 120.5(3) . . ?
C16 C17 C18 119.3(3) . . ?
C13 C18 C17 120.5(3) . . ?
C20 C19 C24 118.7(3) . . ?
C20 C19 P2 123.2(2) . . ?
C24 C19 P2 118.1(2) . . ?
C21 C20 C19 120.9(3) . . ?
C22 C21 C20 119.9(3) . . ?
C21 C22 C23 120.0(3) . . ?
C24 C23 C22 120.4(3) . . ?
C23 C24 C19 120.1(3) . . ?
C30 C25 C26 119.3(3) . . ?
C30 C25 P2 118.1(2) . . ?
C26 C25 P2 122.6(2) . . ?
C27 C26 C25 119.9(3) . . ?
C28 C27 C26 120.9(3) . . ?
C27 C28 C29 119.5(3) . . ?
C30 C29 C28 119.8(3) . . ?
C29 C30 C25 120.6(3) . . ?
C36 C31 C32 119.0(3) . . ?
C36 C31 P2 123.0(2) . . ?
C32 C31 P2 117.9(2) . . ?
C33 C32 C31 120.0(3) . . ?
C32 C33 C34 120.4(3) . . ?
C35 C34 C33 119.9(3) . . ?
C34 C35 C36 120.2(3) . . ?
C31 C36 C35 120.4(3) . . ?
Re1 O1 Ag1 161.56(14) . . ?
Re1 O2 Ag1 136.73(12) . 2_656 ?
O3B O3A Re1 95(2) . . ?
O3A O3B Re1 62(2) . . ?
O4B O4A Re1 68(2) . . ?
O4A O4B Re1 90.9(17) . . ?
C7 P1 C13 105.75(13) . . ?
C7 P1 C1 105.62(13) . . ?
C13 P1 C1 105.06(13) . . ?
C7 P1 Ag1 119.53(10) . . ?
C13 P1 Ag1 106.54(9) . . ?
C1 P1 Ag1 113.22(10) . . ?
C25 P2 C19 105.42(13) . . ?
C25 P2 C31 105.18(12) . . ?
C19 P2 C31 104.16(13) . . ?
C25 P2 Ag1 110.55(9) . . ?
C19 P2 Ag1 119.24(9) . . ?
C31 P2 Ag1 111.20(9) . . ?
O2 Ag1 P1 119.32(7) 2_656 . ?
O2 Ag1 P2 99.40(7) 2_656 . ?
P1 Ag1 P2 133.38(3) . . ?
O2 Ag1 O1 97.67(8) 2_656 . ?
P1 Ag1 O1 105.85(6) . . ?
P2 Ag1 O1 92.55(6) . . ?
O3A Re1 O4B 86.1(11) . . ?
O3A Re1 O2 114.6(6) . . ?
O4B Re1 O2 114.7(10) . . ?
O3A Re1 O1 116.0(7) . . ?
O4B Re1 O1 112.9(6) . . ?
O2 Re1 O1 110.63(11) . . ?
O3A Re1 O4A 107.0(6) . . ?
O4B Re1 O4A 21.4(13) . . ?
O2 Re1 O4A 100.8(5) . . ?
O1 Re1 O4A 106.1(5) . . ?
O3A Re1 O3B 23.1(9) . . ?
O4B Re1 O3B 109.2(7) . . ?
O2 Re1 O3B 103.3(9) . . ?
O1 Re1 O3B 105.2(8) . . ?
O4A Re1 O3B 130.0(10) . . ?

_refine_diff_density_max         3.164
_refine_diff_density_min         -3.319
_refine_diff_density_rms         0.163

_shelxl_version_number           2014-3

