# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_naka095
_database_code_depnum_ccdc_archive 'CCDC 1055408'
_audit_update_record             
;
2015-03-23 deposited with the CCDC.
2015-05-12 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 'C90 H111 B Cl F15 Ge P4 Pt2'  
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C72 H110 Cl Ge P4 Pt2, C18 H B F15'
_chemical_formula_sum            'C90 H111 B Cl F15 Ge P4 Pt2'
_chemical_formula_weight         2110.70

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_Int_Tables_number      2

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   13.4568(16)
_cell_length_b                   18.179(2)
_cell_length_c                   18.421(2)
_cell_angle_alpha                92.6870(10)
_cell_angle_beta                 105.9720(10)
_cell_angle_gamma                96.8460(10)
_cell_volume                     4286.5(9)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       prism
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.09
_exptl_crystal_size_mid          0.09
_exptl_crystal_size_min          0.08
_exptl_crystal_density_meas      'not measured'
_exptl_crystal_density_diffrn    1.635
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2112
_exptl_absorpt_coefficient_mu    3.788
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.7268
_exptl_absorpt_correction_T_max  0.7515
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1997)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'Bruker TXS fine-focus rotating anode'
_diffrn_radiation_monochromator  'Bruker Helios multilayered confocal mirror'
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean 8.333
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            22264
_diffrn_reflns_av_R_equivalents  0.0716
_diffrn_reflns_av_sigmaI/netI    0.0591
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         1.13
_diffrn_reflns_theta_max         26.00
_reflns_number_total             16406
_reflns_number_gt                14001
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEX-II'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    
'Yadokari-XG 2009 (Wakita, Nemoto et al., 2009)'
_computing_publication_material  
'Yadokari-XG 2009 (Wakita, Nemoto et al., 2009)'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0608P)²+0.0150P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         16406
_refine_ls_number_parameters     1035
_refine_ls_number_restraints     2
_refine_ls_R_factor_all          0.0441
_refine_ls_R_factor_gt           0.0383
_refine_ls_wR_factor_ref         0.1019
_refine_ls_wR_factor_gt          0.0996
_refine_ls_goodness_of_fit_ref   1.018
_refine_ls_restrained_S_all      1.018
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt2 Pt 0.194441(13) 0.326085(9) 0.243934(10) 0.01229(6) Uani 1 1 d D . .
Pt1 Pt 0.222687(13) 0.171404(9) 0.273949(10) 0.01228(6) Uani 1 1 d D . .
Ge1 Ge 0.32601(4) 0.25749(3) 0.21638(3) 0.01307(11) Uani 1 1 d . . .
Cl1 Cl 0.48273(11) 0.29936(8) 0.29188(8) 0.0329(3) Uani 1 1 d . . .
P2 P 0.12781(10) 0.11135(6) 0.34785(7) 0.0149(2) Uani 1 1 d . . .
P4 P 0.05227(9) 0.37319(6) 0.26637(7) 0.0144(2) Uani 1 1 d . . .
P1 P 0.28508(9) 0.06305(6) 0.26063(7) 0.0141(2) Uani 1 1 d . . .
P3 P 0.23655(9) 0.43633(6) 0.20038(7) 0.0156(3) Uani 1 1 d . . .
F3 F -0.2912(3) 0.3350(3) 0.3666(2) 0.0612(12) Uani 1 1 d . . .
F5 F -0.2857(3) 0.34441(17) 0.62111(18) 0.0332(8) Uani 1 1 d . . .
F4 F -0.3551(3) 0.3892(2) 0.4842(2) 0.0486(10) Uani 1 1 d . . .
C75 C -0.1991(5) 0.2528(4) 0.4463(3) 0.0376(15) Uani 1 1 d . . .
F9 F 0.1425(3) 0.44140(17) 0.72833(19) 0.0332(8) Uani 1 1 d . . .
C14 C 0.4034(4) 0.3013(3) 0.0785(3) 0.0185(10) Uani 1 1 d . . .
F10 F -0.0583(2) 0.38281(16) 0.67519(19) 0.0331(8) Uani 1 1 d . . .
C85 C -0.2157(4) 0.2355(3) 0.7209(3) 0.0257(12) Uani 1 1 d . . .
C69 C 0.0480(4) 0.3560(3) 0.4912(3) 0.0272(12) Uani 1 1 d . . .
H102 H 0.0526 0.3120 0.5211 0.033 Uiso 1 1 calc R . .
H103 H -0.0204 0.3729 0.4873 0.033 Uiso 1 1 calc R . .
F6 F 0.0354(3) 0.14341(17) 0.7263(2) 0.0353(8) Uani 1 1 d . . .
C61 C -0.0779(4) 0.3176(3) 0.2244(3) 0.0187(10) Uani 1 1 d . . .
H88 H -0.0800 0.2724 0.2532 0.022 Uiso 1 1 calc R . .
C34 C 0.4637(4) 0.1234(3) 0.3793(3) 0.0227(11) Uani 1 1 d . . .
H38 H 0.4270 0.1167 0.4188 0.027 Uiso 1 1 calc R . .
H39 H 0.4500 0.1713 0.3577 0.027 Uiso 1 1 calc R . .
F8 F 0.2910(2) 0.3524(2) 0.78058(19) 0.0391(8) Uani 1 1 d . . .
F2 F -0.1711(3) 0.2233(2) 0.3867(2) 0.0526(11) Uani 1 1 d . . .
F1 F -0.1044(3) 0.17421(19) 0.5231(2) 0.0412(9) Uani 1 1 d . . .
C35 C -0.0160(4) 0.0927(3) 0.3070(3) 0.0185(10) Uani 1 1 d . . .
H40 H -0.0403 0.1422 0.2977 0.022 Uiso 1 1 calc R . .
C50 C 0.2572(5) 0.4954(4) 0.0617(4) 0.0428(16) Uani 1 1 d . . .
H67 H 0.3323 0.5105 0.0876 0.051 Uiso 1 1 calc R . .
H68 H 0.2198 0.5377 0.0689 0.051 Uiso 1 1 calc R . .
C32 C 0.6068(4) 0.0521(3) 0.4458(3) 0.0296(13) Uani 1 1 d . . .
H34 H 0.6835 0.0535 0.4626 0.036 Uiso 1 1 calc R . .
H35 H 0.5805 0.0453 0.4905 0.036 Uiso 1 1 calc R . .
F7 F 0.2352(3) 0.2032(2) 0.7774(2) 0.0382(8) Uani 1 1 d . . .
C49 C 0.2177(4) 0.4304(3) 0.0968(3) 0.0236(11) Uani 1 1 d . . .
H66 H 0.2585 0.3903 0.0872 0.028 Uiso 1 1 calc R . .
C67 C 0.0543(4) 0.4005(3) 0.3649(3) 0.0170(10) Uani 1 1 d . . .
H99 H -0.0110 0.4224 0.3629 0.020 Uiso 1 1 calc R . .
C27 C 0.3177(4) -0.0687(3) 0.0763(3) 0.0274(12) Uani 1 1 d . . .
H25 H 0.3620 -0.0310 0.0576 0.033 Uiso 1 1 calc R . .
H26 H 0.3452 -0.1167 0.0741 0.033 Uiso 1 1 calc R . .
C28 C 0.3234(4) -0.0454(3) 0.1585(3) 0.0231(11) Uani 1 1 d . . .
H27 H 0.3972 -0.0372 0.1895 0.028 Uiso 1 1 calc R . .
H28 H 0.2860 -0.0857 0.1791 0.028 Uiso 1 1 calc R . .
C18 C 0.4527(4) 0.3325(3) -0.0350(3) 0.0252(12) Uani 1 1 d . . .
H12 H 0.4516 0.3199 -0.0859 0.030 Uiso 1 1 calc R . .
C9 C 0.4917(4) 0.1524(2) 0.1701(3) 0.0168(10) Uani 1 1 d . . .
H5 H 0.4944 0.1680 0.2206 0.020 Uiso 1 1 calc R . .
C11 C 0.5559(4) 0.0803(3) 0.0832(3) 0.0241(11) Uani 1 1 d . . .
H7 H 0.6000 0.0460 0.0743 0.029 Uiso 1 1 calc R . .
C26 C 0.2068(4) -0.0767(3) 0.0257(3) 0.0270(12) Uani 1 1 d . . .
H23 H 0.1644 -0.1184 0.0407 0.032 Uiso 1 1 calc R . .
H24 H 0.2063 -0.0886 -0.0274 0.032 Uiso 1 1 calc R . .
C16 C 0.5071(4) 0.4181(3) 0.0764(3) 0.0269(12) Uani 1 1 d . . .
H10 H 0.5440 0.4643 0.1014 0.032 Uiso 1 1 calc R . .
C8 C 0.4218(4) 0.1790(3) 0.1092(3) 0.0163(10) Uani 1 1 d . . .
C21 C 0.2031(4) -0.0093(3) 0.2929(3) 0.0180(10) Uani 1 1 d . . .
H14 H 0.1387 -0.0263 0.2515 0.022 Uiso 1 1 calc R . .
H15 H 0.2412 -0.0524 0.3056 0.022 Uiso 1 1 calc R . .
C80 C 0.0573(4) 0.2178(3) 0.7247(3) 0.0255(12) Uani 1 1 d . . .
C19 C 0.4039(4) 0.2823(3) 0.0037(3) 0.0196(10) Uani 1 1 d . . .
C29 C 0.4219(4) 0.0602(3) 0.3170(3) 0.0169(10) Uani 1 1 d . . .
H29 H 0.4652 0.0674 0.2811 0.020 Uiso 1 1 calc R . .
C13 C 0.4243(4) 0.1578(3) 0.0351(3) 0.0182(10) Uani 1 1 d . . .
C36 C -0.0429(4) 0.0491(3) 0.2288(3) 0.0264(12) Uani 1 1 d . . .
H41 H -0.0087 0.0775 0.1957 0.032 Uiso 1 1 calc R . .
H42 H -0.0154 0.0009 0.2347 0.032 Uiso 1 1 calc R . .
C43 C 0.1640(4) 0.1485(3) 0.5833(3) 0.0294(12) Uani 1 1 d . . .
H54 H 0.1132 0.1843 0.5793 0.035 Uiso 1 1 calc R . .
H55 H 0.1552 0.1148 0.6224 0.035 Uiso 1 1 calc R . .
C74 C -0.1661(4) 0.2283(3) 0.5171(3) 0.0302(13) Uani 1 1 d . . .
C52 C 0.1261(5) 0.4501(3) -0.0649(3) 0.0339(14) Uani 1 1 d . . .
H71 H 0.0830 0.4898 -0.0613 0.041 Uiso 1 1 calc R . .
H72 H 0.1186 0.4372 -0.1192 0.041 Uiso 1 1 calc R . .
C12 C 0.4885(4) 0.1087(3) 0.0224(3) 0.0234(11) Uani 1 1 d . . .
H8 H 0.4872 0.0938 -0.0280 0.028 Uiso 1 1 calc R . .
C23 C 0.2746(4) 0.0263(2) 0.1636(3) 0.0163(10) Uani 1 1 d . . .
H18 H 0.3152 0.0650 0.1423 0.020 Uiso 1 1 calc R . .
C10 C 0.5580(4) 0.1026(3) 0.1564(3) 0.0227(11) Uani 1 1 d . . .
H6 H 0.6047 0.0841 0.1978 0.027 Uiso 1 1 calc R . .
C70 C 0.1357(5) 0.4182(3) 0.5322(3) 0.0296(13) Uani 1 1 d . . .
H104 H 0.1243 0.4352 0.5807 0.036 Uiso 1 1 calc R . .
H105 H 0.2035 0.3986 0.5438 0.036 Uiso 1 1 calc R . .
C33 C 0.5811(4) 0.1254(3) 0.4150(3) 0.0260(12) Uani 1 1 d . . .
H36 H 0.6182 0.1368 0.3765 0.031 Uiso 1 1 calc R . .
H37 H 0.6058 0.1655 0.4566 0.031 Uiso 1 1 calc R . .
C17 C 0.5026(4) 0.4002(3) 0.0013(3) 0.0282(12) Uani 1 1 d . . .
H11 H 0.5342 0.4351 -0.0253 0.034 Uiso 1 1 calc R . .
C72 C 0.1480(4) 0.4601(3) 0.4052(3) 0.0232(11) Uani 1 1 d . . .
H108 H 0.2142 0.4397 0.4100 0.028 Uiso 1 1 calc R . .
H109 H 0.1478 0.5038 0.3751 0.028 Uiso 1 1 calc R . .
C71 C 0.1392(5) 0.4835(3) 0.4838(3) 0.0299(13) Uani 1 1 d . . .
H106 H 0.1996 0.5210 0.5100 0.036 Uiso 1 1 calc R . .
H107 H 0.0751 0.5070 0.4782 0.036 Uiso 1 1 calc R . .
C24 C 0.1618(4) 0.0171(3) 0.1119(3) 0.0245(11) Uani 1 1 d . . .
H19 H 0.1179 -0.0210 0.1304 0.029 Uiso 1 1 calc R . .
H20 H 0.1333 0.0647 0.1135 0.029 Uiso 1 1 calc R . .
C37 C -0.1603(4) 0.0349(3) 0.1914(3) 0.0292(12) Uani 1 1 d . . .
H43 H -0.1869 0.0829 0.1806 0.035 Uiso 1 1 calc R . .
H44 H -0.1747 0.0047 0.1426 0.035 Uiso 1 1 calc R . .
C41 C 0.1545(4) 0.1551(3) 0.4455(3) 0.0176(10) Uani 1 1 d . . .
H51 H 0.1049 0.1923 0.4437 0.021 Uiso 1 1 calc R . .
C76 C -0.2614(5) 0.3085(4) 0.4346(3) 0.0378(15) Uani 1 1 d . . .
C1 C 0.3499(4) 0.2374(3) 0.1139(3) 0.0161(10) Uani 1 1 d . . .
C78 C -0.2560(4) 0.3104(3) 0.5647(3) 0.0281(12) Uani 1 1 d . . .
C45 C 0.2925(4) 0.2409(3) 0.5474(3) 0.0309(13) Uani 1 1 d . . .
H58 H 0.3665 0.2638 0.5622 0.037 Uiso 1 1 calc R . .
H59 H 0.2488 0.2814 0.5447 0.037 Uiso 1 1 calc R . .
C46 C 0.2662(4) 0.1985(3) 0.4696(3) 0.0254(12) Uani 1 1 d . . .
H60 H 0.3170 0.1632 0.4704 0.031 Uiso 1 1 calc R . .
H61 H 0.2729 0.2341 0.4316 0.031 Uiso 1 1 calc R . .
C55 C 0.3672(4) 0.4857(3) 0.2489(3) 0.0222(11) Uani 1 1 d . . .
H77 H 0.4177 0.4629 0.2270 0.027 Uiso 1 1 calc R . .
C22 C 0.1739(4) 0.0200(2) 0.3627(3) 0.0170(10) Uani 1 1 d . . .
H16 H 0.2355 0.0248 0.4077 0.020 Uiso 1 1 calc R . .
H17 H 0.1182 -0.0158 0.3722 0.020 Uiso 1 1 calc R . .
C54 C 0.1031(5) 0.3999(4) 0.0550(3) 0.0372(14) Uani 1 1 d . . .
H75 H 0.0818 0.3543 0.0775 0.045 Uiso 1 1 calc R . .
H76 H 0.0576 0.4372 0.0615 0.045 Uiso 1 1 calc R . .
C44 C 0.2745(4) 0.1906(3) 0.6072(3) 0.0297(13) Uani 1 1 d . . .
H56 H 0.2858 0.2208 0.6556 0.036 Uiso 1 1 calc R . .
H57 H 0.3254 0.1546 0.6154 0.036 Uiso 1 1 calc R . .
C56 C 0.3972(5) 0.4731(3) 0.3348(4) 0.0387(15) Uani 1 1 d . . .
H78 H 0.3516 0.4978 0.3593 0.046 Uiso 1 1 calc R . .
H79 H 0.3860 0.4192 0.3410 0.046 Uiso 1 1 calc R . .
C77 C -0.2922(5) 0.3363(3) 0.4939(3) 0.0336(13) Uani 1 1 d . . .
C82 C 0.1905(4) 0.3225(3) 0.7537(3) 0.0291(13) Uani 1 1 d . . .
C73 C -0.1916(4) 0.2563(3) 0.5799(3) 0.0247(11) Uani 1 1 d . . .
C68 C 0.0553(4) 0.3340(3) 0.4117(3) 0.0246(11) Uani 1 1 d . . .
H100 H 0.1204 0.3121 0.4159 0.030 Uiso 1 1 calc R . .
H101 H -0.0043 0.2957 0.3858 0.030 Uiso 1 1 calc R . .
C38 C -0.2167(4) -0.0054(3) 0.2420(3) 0.0295(13) Uani 1 1 d . . .
H45 H -0.2928 -0.0132 0.2171 0.035 Uiso 1 1 calc R . .
H46 H -0.1933 -0.0547 0.2505 0.035 Uiso 1 1 calc R . .
C81 C 0.1605(4) 0.2476(3) 0.7513(3) 0.0289(12) Uani 1 1 d . . .
C51 C 0.2426(6) 0.4782(4) -0.0228(4) 0.0465(17) Uani 1 1 d . . .
H69 H 0.2861 0.4398 -0.0299 0.056 Uiso 1 1 calc R . .
H70 H 0.2658 0.5237 -0.0446 0.056 Uiso 1 1 calc R . .
C79 C -0.0221(4) 0.2596(3) 0.6963(3) 0.0236(11) Uani 1 1 d . . .
C25 C 0.1584(4) -0.0061(3) 0.0307(3) 0.0297(13) Uani 1 1 d . . .
H21 H 0.0849 -0.0142 -0.0011 0.036 Uiso 1 1 calc R . .
H22 H 0.1963 0.0344 0.0107 0.036 Uiso 1 1 calc R . .
C39 C -0.1941(4) 0.0398(3) 0.3172(3) 0.0301(13) Uani 1 1 d . . .
H47 H -0.2290 0.0122 0.3505 0.036 Uiso 1 1 calc R . .
H48 H -0.2231 0.0872 0.3088 0.036 Uiso 1 1 calc R . .
C15 C 0.4581(4) 0.3690(3) 0.1151(3) 0.0208(11) Uani 1 1 d . . .
H9 H 0.4618 0.3815 0.1665 0.025 Uiso 1 1 calc R . .
C53 C 0.0887(6) 0.3819(4) -0.0297(4) 0.0491(17) Uani 1 1 d . . .
H73 H 0.1287 0.3411 -0.0366 0.059 Uiso 1 1 calc R . .
H74 H 0.0141 0.3650 -0.0557 0.059 Uiso 1 1 calc R . .
C42 C 0.1422(5) 0.1033(3) 0.5071(3) 0.0287(12) Uani 1 1 d . . .
H52 H 0.0704 0.0762 0.4928 0.034 Uiso 1 1 calc R . .
H53 H 0.1915 0.0663 0.5114 0.034 Uiso 1 1 calc R . .
C31 C 0.5600(4) -0.0133(3) 0.3880(4) 0.0352(14) Uani 1 1 d . . .
H32 H 0.5708 -0.0599 0.4130 0.042 Uiso 1 1 calc R . .
H33 H 0.5969 -0.0119 0.3483 0.042 Uiso 1 1 calc R . .
C84 C 0.0130(4) 0.3352(3) 0.6992(3) 0.0234(11) Uani 1 1 d . . .
C40 C -0.0763(4) 0.0564(3) 0.3569(3) 0.0263(12) Uani 1 1 d . . .
H49 H -0.0647 0.0896 0.4035 0.032 Uiso 1 1 calc R . .
H50 H -0.0494 0.0094 0.3721 0.032 Uiso 1 1 calc R . .
C30 C 0.4427(4) -0.0141(3) 0.3504(3) 0.0218(11) Uani 1 1 d . . .
H30 H 0.4175 -0.0550 0.3097 0.026 Uiso 1 1 calc R . .
H31 H 0.4039 -0.0230 0.3884 0.026 Uiso 1 1 calc R . .
C83 C 0.1150(4) 0.3675(3) 0.7263(3) 0.0251(12) Uani 1 1 d . . .
C48 C 0.0416(4) 0.4604(2) 0.2191(3) 0.0168(10) Uani 1 1 d . . .
H64 H -0.0031 0.4491 0.1663 0.020 Uiso 1 1 calc R . .
H65 H 0.0073 0.4938 0.2456 0.020 Uiso 1 1 calc R . .
C58 C 0.5330(5) 0.5862(4) 0.3601(5) 0.068(3) Uani 1 1 d . . .
H82 H 0.4963 0.6158 0.3882 0.081 Uiso 1 1 calc R . .
H83 H 0.6088 0.6029 0.3809 0.081 Uiso 1 1 calc R . .
C47 C 0.1480(4) 0.5005(3) 0.2185(3) 0.0196(10) Uani 1 1 d . . .
H62 H 0.1812 0.5293 0.2680 0.024 Uiso 1 1 calc R . .
H63 H 0.1376 0.5361 0.1789 0.024 Uiso 1 1 calc R . .
B1 B -0.1452(5) 0.2238(3) 0.6620(4) 0.0234(13) Uani 1 1 d . . .
H110 H -0.142(4) 0.164(3) 0.649(3) 0.011(12) Uiso 1 1 d . . .
C57 C 0.5104(5) 0.5040(4) 0.3734(5) 0.061(2) Uani 1 1 d . . .
H80 H 0.5563 0.4751 0.3533 0.073 Uiso 1 1 calc R . .
H81 H 0.5260 0.4987 0.4285 0.073 Uiso 1 1 calc R . .
C60 C 0.3845(4) 0.5697(3) 0.2413(3) 0.0295(13) Uani 1 1 d . . .
H86 H 0.3400 0.5950 0.2662 0.035 Uiso 1 1 calc R . .
H87 H 0.3645 0.5792 0.1870 0.035 Uiso 1 1 calc R . .
C59 C 0.4998(5) 0.6011(3) 0.2780(5) 0.052(2) Uani 1 1 d . . .
H84 H 0.5439 0.5779 0.2509 0.062 Uiso 1 1 calc R . .
H85 H 0.5100 0.6554 0.2736 0.062 Uiso 1 1 calc R . .
F15 F -0.3685(3) 0.18106(18) 0.62634(19) 0.0375(8) Uani 1 1 d . . .
C2 C 0.2439(4) 0.2111(3) 0.0557(3) 0.0186(10) Uani 1 1 d . . .
C20 C 0.3601(4) 0.2018(3) -0.0240(3) 0.0209(11) Uani 1 1 d . . .
H13 H 0.3635 0.1883 -0.0765 0.025 Uiso 1 1 calc R . .
C7 C 0.2494(4) 0.1912(3) -0.0169(3) 0.0202(10) Uani 1 1 d . . .
C63 C -0.1978(4) 0.2435(3) 0.1061(3) 0.0286(12) Uani 1 1 d . . .
H91 H -0.2057 0.2314 0.0517 0.034 Uiso 1 1 calc R . .
H92 H -0.2006 0.1962 0.1305 0.034 Uiso 1 1 calc R . .
C3 C 0.1464(4) 0.2070(3) 0.0686(3) 0.0246(11) Uani 1 1 d . . .
H1 H 0.1411 0.2201 0.1178 0.030 Uiso 1 1 calc R . .
C90 C -0.3223(4) 0.2107(3) 0.6990(3) 0.0288(13) Uani 1 1 d . . .
C5 C 0.0626(4) 0.1635(3) -0.0621(3) 0.0296(13) Uani 1 1 d . . .
H3 H 0.0006 0.1475 -0.1018 0.036 Uiso 1 1 calc R . .
C4 C 0.0566(4) 0.1835(3) 0.0095(3) 0.0309(13) Uani 1 1 d . . .
H2 H -0.0098 0.1813 0.0186 0.037 Uiso 1 1 calc R . .
C66 C -0.1695(4) 0.3578(3) 0.2314(3) 0.0253(12) Uani 1 1 d . . .
H97 H -0.1617 0.3713 0.2856 0.030 Uiso 1 1 calc R . .
H98 H -0.1681 0.4043 0.2055 0.030 Uiso 1 1 calc R . .
C6 C 0.1590(4) 0.1666(3) -0.0765(3) 0.0255(12) Uani 1 1 d . . .
H4 H 0.1638 0.1524 -0.1256 0.031 Uiso 1 1 calc R . .
C65 C -0.2741(4) 0.3089(3) 0.1964(3) 0.0320(13) Uani 1 1 d . . .
H95 H -0.2783 0.2649 0.2256 0.038 Uiso 1 1 calc R . .
H96 H -0.3315 0.3372 0.1995 0.038 Uiso 1 1 calc R . .
C64 C -0.2877(4) 0.2834(3) 0.1141(3) 0.0276(12) Uani 1 1 d . . .
H93 H -0.2913 0.3271 0.0837 0.033 Uiso 1 1 calc R . .
H94 H -0.3542 0.2496 0.0941 0.033 Uiso 1 1 calc R . .
C62 C -0.0919(4) 0.2903(3) 0.1422(3) 0.0245(11) Uani 1 1 d . . .
H89 H -0.0359 0.2603 0.1400 0.029 Uiso 1 1 calc R . .
H90 H -0.0848 0.3338 0.1126 0.029 Uiso 1 1 calc R . .
F11 F -0.0768(3) 0.2925(2) 0.8262(2) 0.0485(10) Uani 1 1 d . . .
F14 F -0.4899(3) 0.1900(2) 0.7183(2) 0.0503(10) Uani 1 1 d . . .
F13 F -0.4075(3) 0.2490(2) 0.8643(2) 0.0519(10) Uani 1 1 d . . .
F12 F -0.1995(3) 0.3003(2) 0.9157(2) 0.0566(11) Uani 1 1 d . . .
C86 C -0.1797(4) 0.2651(3) 0.7951(3) 0.0313(13) Uani 1 1 d . . .
C88 C -0.3466(5) 0.2447(3) 0.8179(4) 0.0380(15) Uani 1 1 d . . .
C89 C -0.3864(5) 0.2155(3) 0.7445(4) 0.0326(13) Uani 1 1 d . . .
C87 C -0.2413(5) 0.2704(3) 0.8434(3) 0.0373(15) Uani 1 1 d . . .
H111 H 0.171(6) 0.2527(16) 0.306(3) 0.11(3) Uiso 1 1 d D . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt2 P3 2.2608(12) . ?
Pt2 P4 2.3145(12) . ?
Pt2 Ge1 2.4308(5) . ?
Pt2 Pt1 2.9397(4) . ?
Pt2 H111 1.851(10) . ?
Pt1 P1 2.2599(12) . ?
Pt1 P2 2.3321(12) . ?
Pt1 Ge1 2.4403(5) . ?
Pt1 H111 1.847(10) . ?
Ge1 C1 2.025(5) . ?
Ge1 Cl1 2.2057(15) . ?
P2 C22 1.847(5) . ?
P2 C35 1.856(5) . ?
P2 C41 1.855(5) . ?
P4 C48 1.845(5) . ?
P4 C67 1.851(5) . ?
P4 C61 1.857(5) . ?
P1 C23 1.840(5) . ?
P1 C21 1.841(5) . ?
P1 C29 1.857(5) . ?
P3 C55 1.838(5) . ?
P3 C47 1.845(5) . ?
P3 C49 1.850(5) . ?
F3 C76 1.339(7) . ?
F5 C78 1.359(6) . ?
F4 C77 1.342(7) . ?
C75 F2 1.363(7) . ?
C75 C74 1.370(8) . ?
C75 C76 1.377(9) . ?
F9 C83 1.346(6) . ?
C14 C15 1.395(7) . ?
C14 C19 1.407(7) . ?
C14 C1 1.556(7) . ?
F10 C84 1.365(6) . ?
C85 C86 1.378(8) . ?
C85 C90 1.390(8) . ?
C85 B1 1.647(8) . ?
C69 C68 1.532(7) . ?
C69 C70 1.533(7) . ?
C69 H102 0.9900 . ?
C69 H103 0.9900 . ?
F6 C80 1.353(6) . ?
C61 C62 1.525(7) . ?
C61 C66 1.537(7) . ?
C61 H88 1.0000 . ?
C34 C29 1.523(7) . ?
C34 C33 1.530(7) . ?
C34 H38 0.9900 . ?
C34 H39 0.9900 . ?
F8 C82 1.342(6) . ?
F1 C74 1.350(7) . ?
C35 C40 1.509(7) . ?
C35 C36 1.540(7) . ?
C35 H40 1.0000 . ?
C50 C49 1.485(8) . ?
C50 C51 1.526(9) . ?
C50 H67 0.9900 . ?
C50 H68 0.9900 . ?
C32 C31 1.508(8) . ?
C32 C33 1.513(7) . ?
C32 H34 0.9900 . ?
C32 H35 0.9900 . ?
F7 C81 1.362(6) . ?
C49 C54 1.544(8) . ?
C49 H66 1.0000 . ?
C67 C68 1.517(7) . ?
C67 C72 1.549(7) . ?
C67 H99 1.0000 . ?
C27 C26 1.512(7) . ?
C27 C28 1.532(7) . ?
C27 H25 0.9900 . ?
C27 H26 0.9900 . ?
C28 C23 1.538(6) . ?
C28 H27 0.9900 . ?
C28 H28 0.9900 . ?
C18 C17 1.376(8) . ?
C18 C19 1.396(7) . ?
C18 H12 0.9500 . ?
C9 C8 1.399(7) . ?
C9 C10 1.404(7) . ?
C9 H5 0.9500 . ?
C11 C10 1.381(7) . ?
C11 C12 1.395(7) . ?
C11 H7 0.9500 . ?
C26 C25 1.517(7) . ?
C26 H23 0.9900 . ?
C26 H24 0.9900 . ?
C16 C15 1.384(7) . ?
C16 C17 1.390(8) . ?
C16 H10 0.9500 . ?
C8 C13 1.411(7) . ?
C8 C1 1.532(6) . ?
C21 C22 1.534(6) . ?
C21 H14 0.9900 . ?
C21 H15 0.9900 . ?
C80 C81 1.373(8) . ?
C80 C79 1.385(7) . ?
C19 C20 1.519(7) . ?
C29 C30 1.533(6) . ?
C29 H29 1.0000 . ?
C13 C12 1.370(7) . ?
C13 C20 1.517(7) . ?
C36 C37 1.524(7) . ?
C36 H41 0.9900 . ?
C36 H42 0.9900 . ?
C43 C44 1.524(8) . ?
C43 C42 1.530(7) . ?
C43 H54 0.9900 . ?
C43 H55 0.9900 . ?
C74 C73 1.387(8) . ?
C52 C53 1.522(9) . ?
C52 C51 1.557(9) . ?
C52 H71 0.9900 . ?
C52 H72 0.9900 . ?
C12 H8 0.9500 . ?
C23 C24 1.538(7) . ?
C23 H18 1.0000 . ?
C10 H6 0.9500 . ?
C70 C71 1.522(8) . ?
C70 H104 0.9900 . ?
C70 H105 0.9900 . ?
C33 H36 0.9900 . ?
C33 H37 0.9900 . ?
C17 H11 0.9500 . ?
C72 C71 1.530(7) . ?
C72 H108 0.9900 . ?
C72 H109 0.9900 . ?
C71 H106 0.9900 . ?
C71 H107 0.9900 . ?
C24 C25 1.520(7) . ?
C24 H19 0.9900 . ?
C24 H20 0.9900 . ?
C37 C38 1.519(8) . ?
C37 H43 0.9900 . ?
C37 H44 0.9900 . ?
C41 C42 1.538(7) . ?
C41 C46 1.548(7) . ?
C41 H51 1.0000 . ?
C76 C77 1.367(9) . ?
C1 C2 1.536(6) . ?
C78 C73 1.376(8) . ?
C78 C77 1.387(8) . ?
C45 C44 1.515(8) . ?
C45 C46 1.525(7) . ?
C45 H58 0.9900 . ?
C45 H59 0.9900 . ?
C46 H60 0.9900 . ?
C46 H61 0.9900 . ?
C55 C60 1.536(7) . ?
C55 C56 1.557(8) . ?
C55 H77 1.0000 . ?
C22 H16 0.9900 . ?
C22 H17 0.9900 . ?
C54 C53 1.534(8) . ?
C54 H75 0.9900 . ?
C54 H76 0.9900 . ?
C44 H56 0.9900 . ?
C44 H57 0.9900 . ?
C56 C57 1.517(8) . ?
C56 H78 0.9900 . ?
C56 H79 0.9900 . ?
C82 C81 1.368(8) . ?
C82 C83 1.382(8) . ?
C73 B1 1.635(8) . ?
C68 H100 0.9900 . ?
C68 H101 0.9900 . ?
C38 C39 1.513(8) . ?
C38 H45 0.9900 . ?
C38 H46 0.9900 . ?
C51 H69 0.9900 . ?
C51 H70 0.9900 . ?
C79 C84 1.393(7) . ?
C79 B1 1.642(8) . ?
C25 H21 0.9900 . ?
C25 H22 0.9900 . ?
C39 C40 1.538(7) . ?
C39 H47 0.9900 . ?
C39 H48 0.9900 . ?
C15 H9 0.9500 . ?
C53 H73 0.9900 . ?
C53 H74 0.9900 . ?
C42 H52 0.9900 . ?
C42 H53 0.9900 . ?
C31 C30 1.537(7) . ?
C31 H32 0.9900 . ?
C31 H33 0.9900 . ?
C84 C83 1.372(8) . ?
C40 H49 0.9900 . ?
C40 H50 0.9900 . ?
C30 H30 0.9900 . ?
C30 H31 0.9900 . ?
C48 C47 1.532(7) . ?
C48 H64 0.9900 . ?
C48 H65 0.9900 . ?
C58 C59 1.502(11) . ?
C58 C57 1.534(10) . ?
C58 H82 0.9900 . ?
C58 H83 0.9900 . ?
C47 H62 0.9900 . ?
C47 H63 0.9900 . ?
B1 H110 1.11(5) . ?
C57 H80 0.9900 . ?
C57 H81 0.9900 . ?
C60 C59 1.538(8) . ?
C60 H86 0.9900 . ?
C60 H87 0.9900 . ?
C59 H84 0.9900 . ?
C59 H85 0.9900 . ?
F15 C90 1.364(7) . ?
C2 C3 1.391(7) . ?
C2 C7 1.393(7) . ?
C20 C7 1.521(7) . ?
C20 H13 1.0000 . ?
C7 C6 1.405(7) . ?
C63 C64 1.519(8) . ?
C63 C62 1.528(7) . ?
C63 H91 0.9900 . ?
C63 H92 0.9900 . ?
C3 C4 1.393(7) . ?
C3 H1 0.9500 . ?
C90 C89 1.366(8) . ?
C5 C4 1.379(8) . ?
C5 C6 1.389(8) . ?
C5 H3 0.9500 . ?
C4 H2 0.9500 . ?
C66 C65 1.529(7) . ?
C66 H97 0.9900 . ?
C66 H98 0.9900 . ?
C6 H4 0.9500 . ?
C65 C64 1.519(8) . ?
C65 H95 0.9900 . ?
C65 H96 0.9900 . ?
C64 H93 0.9900 . ?
C64 H94 0.9900 . ?
C62 H89 0.9900 . ?
C62 H90 0.9900 . ?
F11 C86 1.365(7) . ?
F14 C89 1.358(7) . ?
F13 C88 1.342(7) . ?
F12 C87 1.354(7) . ?
C86 C87 1.380(9) . ?
C88 C89 1.365(9) . ?
C88 C87 1.378(9) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P3 Pt2 P4 87.74(4) . . ?
P3 Pt2 Ge1 100.02(3) . . ?
P4 Pt2 Ge1 170.82(3) . . ?
P3 Pt2 Pt1 153.05(3) . . ?
P4 Pt2 Pt1 119.07(3) . . ?
Ge1 Pt2 Pt1 53.026(12) . . ?
P3 Pt2 H111 163.4(18) . . ?
P4 Pt2 H111 86.1(13) . . ?
Ge1 Pt2 H111 87.7(10) . . ?
Pt1 Pt2 H111 37.3(3) . . ?
P1 Pt1 P2 87.10(4) . . ?
P1 Pt1 Ge1 102.84(3) . . ?
P2 Pt1 Ge1 167.48(3) . . ?
P1 Pt1 Pt2 154.76(3) . . ?
P2 Pt1 Pt2 118.00(3) . . ?
Ge1 Pt1 Pt2 52.732(13) . . ?
P1 Pt1 H111 167.0(9) . . ?
P2 Pt1 H111 81.7(7) . . ?
Ge1 Pt1 H111 87.5(10) . . ?
Pt2 Pt1 H111 37.4(3) . . ?
C1 Ge1 Cl1 104.24(14) . . ?
C1 Ge1 Pt2 126.90(13) . . ?
Cl1 Ge1 Pt2 111.30(4) . . ?
C1 Ge1 Pt1 124.72(13) . . ?
Cl1 Ge1 Pt1 113.52(4) . . ?
Pt2 Ge1 Pt1 74.242(16) . . ?
C22 P2 C35 106.6(2) . . ?
C22 P2 C41 103.5(2) . . ?
C35 P2 C41 107.4(2) . . ?
C22 P2 Pt1 106.26(15) . . ?
C35 P2 Pt1 116.87(16) . . ?
C41 P2 Pt1 115.03(16) . . ?
C48 P4 C67 104.0(2) . . ?
C48 P4 C61 103.5(2) . . ?
C67 P4 C61 104.5(2) . . ?
C48 P4 Pt2 106.49(16) . . ?
C67 P4 Pt2 119.40(16) . . ?
C61 P4 Pt2 117.09(16) . . ?
C23 P1 C21 102.8(2) . . ?
C23 P1 C29 106.4(2) . . ?
C21 P1 C29 106.7(2) . . ?
C23 P1 Pt1 117.17(15) . . ?
C21 P1 Pt1 107.02(15) . . ?
C29 P1 Pt1 115.58(15) . . ?
C55 P3 C47 103.6(2) . . ?
C55 P3 C49 109.3(2) . . ?
C47 P3 C49 105.9(2) . . ?
C55 P3 Pt2 115.60(17) . . ?
C47 P3 Pt2 108.15(15) . . ?
C49 P3 Pt2 113.34(17) . . ?
F2 C75 C74 121.3(6) . . ?
F2 C75 C76 118.8(6) . . ?
C74 C75 C76 119.9(6) . . ?
C15 C14 C19 119.0(5) . . ?
C15 C14 C1 127.3(5) . . ?
C19 C14 C1 113.4(4) . . ?
C86 C85 C90 112.7(5) . . ?
C86 C85 B1 126.7(5) . . ?
C90 C85 B1 120.5(5) . . ?
C68 C69 C70 111.3(5) . . ?
C68 C69 H102 109.4 . . ?
C70 C69 H102 109.4 . . ?
C68 C69 H103 109.4 . . ?
C70 C69 H103 109.4 . . ?
H102 C69 H103 108.0 . . ?
C62 C61 C66 110.8(4) . . ?
C62 C61 P4 111.0(3) . . ?
C66 C61 P4 113.9(3) . . ?
C62 C61 H88 106.9 . . ?
C66 C61 H88 106.9 . . ?
P4 C61 H88 106.9 . . ?
C29 C34 C33 110.9(4) . . ?
C29 C34 H38 109.5 . . ?
C33 C34 H38 109.5 . . ?
C29 C34 H39 109.5 . . ?
C33 C34 H39 109.5 . . ?
H38 C34 H39 108.1 . . ?
C40 C35 C36 111.5(4) . . ?
C40 C35 P2 116.0(4) . . ?
C36 C35 P2 109.7(3) . . ?
C40 C35 H40 106.3 . . ?
C36 C35 H40 106.3 . . ?
P2 C35 H40 106.3 . . ?
C49 C50 C51 112.0(5) . . ?
C49 C50 H67 109.2 . . ?
C51 C50 H67 109.2 . . ?
C49 C50 H68 109.2 . . ?
C51 C50 H68 109.2 . . ?
H67 C50 H68 107.9 . . ?
C31 C32 C33 112.6(5) . . ?
C31 C32 H34 109.1 . . ?
C33 C32 H34 109.1 . . ?
C31 C32 H35 109.1 . . ?
C33 C32 H35 109.1 . . ?
H34 C32 H35 107.8 . . ?
C50 C49 C54 112.1(5) . . ?
C50 C49 P3 119.5(4) . . ?
C54 C49 P3 109.8(4) . . ?
C50 C49 H66 104.7 . . ?
C54 C49 H66 104.7 . . ?
P3 C49 H66 104.7 . . ?
C68 C67 C72 109.3(4) . . ?
C68 C67 P4 111.7(3) . . ?
C72 C67 P4 112.5(3) . . ?
C68 C67 H99 107.7 . . ?
C72 C67 H99 107.7 . . ?
P4 C67 H99 107.7 . . ?
C26 C27 C28 111.2(4) . . ?
C26 C27 H25 109.4 . . ?
C28 C27 H25 109.4 . . ?
C26 C27 H26 109.4 . . ?
C28 C27 H26 109.4 . . ?
H25 C27 H26 108.0 . . ?
C27 C28 C23 111.0(4) . . ?
C27 C28 H27 109.4 . . ?
C23 C28 H27 109.4 . . ?
C27 C28 H28 109.4 . . ?
C23 C28 H28 109.4 . . ?
H27 C28 H28 108.0 . . ?
C17 C18 C19 119.4(5) . . ?
C17 C18 H12 120.3 . . ?
C19 C18 H12 120.3 . . ?
C8 C9 C10 119.9(5) . . ?
C8 C9 H5 120.1 . . ?
C10 C9 H5 120.1 . . ?
C10 C11 C12 119.5(5) . . ?
C10 C11 H7 120.2 . . ?
C12 C11 H7 120.2 . . ?
C27 C26 C25 111.6(4) . . ?
C27 C26 H23 109.3 . . ?
C25 C26 H23 109.3 . . ?
C27 C26 H24 109.3 . . ?
C25 C26 H24 109.3 . . ?
H23 C26 H24 108.0 . . ?
C15 C16 C17 120.4(5) . . ?
C15 C16 H10 119.8 . . ?
C17 C16 H10 119.8 . . ?
C9 C8 C13 118.3(4) . . ?
C9 C8 C1 126.6(4) . . ?
C13 C8 C1 114.7(4) . . ?
C22 C21 P1 111.3(3) . . ?
C22 C21 H14 109.4 . . ?
P1 C21 H14 109.4 . . ?
C22 C21 H15 109.4 . . ?
P1 C21 H15 109.4 . . ?
H14 C21 H15 108.0 . . ?
F6 C80 C81 116.4(5) . . ?
F6 C80 C79 120.2(5) . . ?
C81 C80 C79 123.4(5) . . ?
C18 C19 C14 120.5(5) . . ?
C18 C19 C20 125.4(5) . . ?
C14 C19 C20 113.6(4) . . ?
C34 C29 C30 109.5(4) . . ?
C34 C29 P1 113.4(3) . . ?
C30 C29 P1 114.9(3) . . ?
C34 C29 H29 106.1 . . ?
C30 C29 H29 106.1 . . ?
P1 C29 H29 106.1 . . ?
C12 C13 C8 121.2(5) . . ?
C12 C13 C20 125.8(5) . . ?
C8 C13 C20 112.7(4) . . ?
C37 C36 C35 111.8(4) . . ?
C37 C36 H41 109.2 . . ?
C35 C36 H41 109.2 . . ?
C37 C36 H42 109.2 . . ?
C35 C36 H42 109.2 . . ?
H41 C36 H42 107.9 . . ?
C44 C43 C42 110.9(5) . . ?
C44 C43 H54 109.5 . . ?
C42 C43 H54 109.5 . . ?
C44 C43 H55 109.5 . . ?
C42 C43 H55 109.5 . . ?
H54 C43 H55 108.0 . . ?
F1 C74 C75 115.6(5) . . ?
F1 C74 C73 120.5(5) . . ?
C75 C74 C73 123.9(6) . . ?
C53 C52 C51 109.7(5) . . ?
C53 C52 H71 109.7 . . ?
C51 C52 H71 109.7 . . ?
C53 C52 H72 109.7 . . ?
C51 C52 H72 109.7 . . ?
H71 C52 H72 108.2 . . ?
C13 C12 C11 120.3(5) . . ?
C13 C12 H8 119.8 . . ?
C11 C12 H8 119.8 . . ?
C28 C23 C24 110.7(4) . . ?
C28 C23 P1 114.7(3) . . ?
C24 C23 P1 112.4(3) . . ?
C28 C23 H18 106.1 . . ?
C24 C23 H18 106.1 . . ?
P1 C23 H18 106.1 . . ?
C11 C10 C9 120.7(5) . . ?
C11 C10 H6 119.7 . . ?
C9 C10 H6 119.7 . . ?
C71 C70 C69 111.0(4) . . ?
C71 C70 H104 109.4 . . ?
C69 C70 H104 109.4 . . ?
C71 C70 H105 109.4 . . ?
C69 C70 H105 109.4 . . ?
H104 C70 H105 108.0 . . ?
C32 C33 C34 111.6(4) . . ?
C32 C33 H36 109.3 . . ?
C34 C33 H36 109.3 . . ?
C32 C33 H37 109.3 . . ?
C34 C33 H37 109.3 . . ?
H36 C33 H37 108.0 . . ?
C18 C17 C16 120.6(5) . . ?
C18 C17 H11 119.7 . . ?
C16 C17 H11 119.7 . . ?
C71 C72 C67 109.0(4) . . ?
C71 C72 H108 109.9 . . ?
C67 C72 H108 109.9 . . ?
C71 C72 H109 109.9 . . ?
C67 C72 H109 109.9 . . ?
H108 C72 H109 108.3 . . ?
C70 C71 C72 112.4(4) . . ?
C70 C71 H106 109.1 . . ?
C72 C71 H106 109.1 . . ?
C70 C71 H107 109.1 . . ?
C72 C71 H107 109.1 . . ?
H106 C71 H107 107.8 . . ?
C25 C24 C23 110.6(4) . . ?
C25 C24 H19 109.5 . . ?
C23 C24 H19 109.5 . . ?
C25 C24 H20 109.5 . . ?
C23 C24 H20 109.5 . . ?
H19 C24 H20 108.1 . . ?
C38 C37 C36 111.0(4) . . ?
C38 C37 H43 109.4 . . ?
C36 C37 H43 109.4 . . ?
C38 C37 H44 109.4 . . ?
C36 C37 H44 109.4 . . ?
H43 C37 H44 108.0 . . ?
C42 C41 C46 109.0(4) . . ?
C42 C41 P2 117.0(3) . . ?
C46 C41 P2 108.6(3) . . ?
C42 C41 H51 107.3 . . ?
C46 C41 H51 107.3 . . ?
P2 C41 H51 107.3 . . ?
F3 C76 C77 120.5(6) . . ?
F3 C76 C75 120.8(6) . . ?
C77 C76 C75 118.7(6) . . ?
C8 C1 C2 107.5(4) . . ?
C8 C1 C14 98.7(4) . . ?
C2 C1 C14 105.7(4) . . ?
C8 C1 Ge1 116.0(3) . . ?
C2 C1 Ge1 108.5(3) . . ?
C14 C1 Ge1 119.4(3) . . ?
F5 C78 C73 120.6(5) . . ?
F5 C78 C77 115.1(5) . . ?
C73 C78 C77 124.3(5) . . ?
C44 C45 C46 111.8(5) . . ?
C44 C45 H58 109.3 . . ?
C46 C45 H58 109.3 . . ?
C44 C45 H59 109.3 . . ?
C46 C45 H59 109.3 . . ?
H58 C45 H59 107.9 . . ?
C45 C46 C41 112.4(4) . . ?
C45 C46 H60 109.1 . . ?
C41 C46 H60 109.1 . . ?
C45 C46 H61 109.1 . . ?
C41 C46 H61 109.1 . . ?
H60 C46 H61 107.9 . . ?
C60 C55 C56 108.1(4) . . ?
C60 C55 P3 116.6(4) . . ?
C56 C55 P3 110.5(4) . . ?
C60 C55 H77 107.0 . . ?
C56 C55 H77 107.0 . . ?
P3 C55 H77 107.0 . . ?
C21 C22 P2 110.4(3) . . ?
C21 C22 H16 109.6 . . ?
P2 C22 H16 109.6 . . ?
C21 C22 H17 109.6 . . ?
P2 C22 H17 109.6 . . ?
H16 C22 H17 108.1 . . ?
C53 C54 C49 111.1(5) . . ?
C53 C54 H75 109.4 . . ?
C49 C54 H75 109.4 . . ?
C53 C54 H76 109.4 . . ?
C49 C54 H76 109.4 . . ?
H75 C54 H76 108.0 . . ?
C45 C44 C43 111.1(4) . . ?
C45 C44 H56 109.4 . . ?
C43 C44 H56 109.4 . . ?
C45 C44 H57 109.4 . . ?
C43 C44 H57 109.4 . . ?
H56 C44 H57 108.0 . . ?
C57 C56 C55 111.1(6) . . ?
C57 C56 H78 109.4 . . ?
C55 C56 H78 109.4 . . ?
C57 C56 H79 109.4 . . ?
C55 C56 H79 109.4 . . ?
H78 C56 H79 108.0 . . ?
F4 C77 C76 120.5(5) . . ?
F4 C77 C78 120.2(5) . . ?
C76 C77 C78 119.3(6) . . ?
F8 C82 C81 121.4(5) . . ?
F8 C82 C83 120.0(5) . . ?
C81 C82 C83 118.6(5) . . ?
C78 C73 C74 113.8(5) . . ?
C78 C73 B1 126.8(5) . . ?
C74 C73 B1 119.4(5) . . ?
C67 C68 C69 111.4(4) . . ?
C67 C68 H100 109.3 . . ?
C69 C68 H100 109.3 . . ?
C67 C68 H101 109.3 . . ?
C69 C68 H101 109.3 . . ?
H100 C68 H101 108.0 . . ?
C39 C38 C37 109.9(5) . . ?
C39 C38 H45 109.7 . . ?
C37 C38 H45 109.7 . . ?
C39 C38 H46 109.7 . . ?
C37 C38 H46 109.7 . . ?
H45 C38 H46 108.2 . . ?
F7 C81 C82 118.6(5) . . ?
F7 C81 C80 120.5(5) . . ?
C82 C81 C80 120.9(5) . . ?
C50 C51 C52 110.9(5) . . ?
C50 C51 H69 109.5 . . ?
C52 C51 H69 109.5 . . ?
C50 C51 H70 109.5 . . ?
C52 C51 H70 109.5 . . ?
H69 C51 H70 108.1 . . ?
C80 C79 C84 113.2(5) . . ?
C80 C79 B1 123.6(5) . . ?
C84 C79 B1 123.3(5) . . ?
C26 C25 C24 111.7(5) . . ?
C26 C25 H21 109.3 . . ?
C24 C25 H21 109.3 . . ?
C26 C25 H22 109.3 . . ?
C24 C25 H22 109.3 . . ?
H21 C25 H22 108.0 . . ?
C38 C39 C40 111.8(4) . . ?
C38 C39 H47 109.3 . . ?
C40 C39 H47 109.3 . . ?
C38 C39 H48 109.3 . . ?
C40 C39 H48 109.3 . . ?
H47 C39 H48 107.9 . . ?
C16 C15 C14 120.0(5) . . ?
C16 C15 H9 120.0 . . ?
C14 C15 H9 120.0 . . ?
C52 C53 C54 110.6(5) . . ?
C52 C53 H73 109.5 . . ?
C54 C53 H73 109.5 . . ?
C52 C53 H74 109.5 . . ?
C54 C53 H74 109.5 . . ?
H73 C53 H74 108.1 . . ?
C43 C42 C41 110.1(4) . . ?
C43 C42 H52 109.6 . . ?
C41 C42 H52 109.6 . . ?
C43 C42 H53 109.6 . . ?
C41 C42 H53 109.6 . . ?
H52 C42 H53 108.1 . . ?
C32 C31 C30 112.9(5) . . ?
C32 C31 H32 109.0 . . ?
C30 C31 H32 109.0 . . ?
C32 C31 H33 109.0 . . ?
C30 C31 H33 109.0 . . ?
H32 C31 H33 107.8 . . ?
F10 C84 C83 115.7(4) . . ?
F10 C84 C79 118.9(5) . . ?
C83 C84 C79 125.4(5) . . ?
C35 C40 C39 112.5(4) . . ?
C35 C40 H49 109.1 . . ?
C39 C40 H49 109.1 . . ?
C35 C40 H50 109.1 . . ?
C39 C40 H50 109.1 . . ?
H49 C40 H50 107.8 . . ?
C29 C30 C31 110.5(4) . . ?
C29 C30 H30 109.6 . . ?
C31 C30 H30 109.6 . . ?
C29 C30 H31 109.6 . . ?
C31 C30 H31 109.6 . . ?
H30 C30 H31 108.1 . . ?
F9 C83 C84 121.8(5) . . ?
F9 C83 C82 119.7(5) . . ?
C84 C83 C82 118.5(5) . . ?
C47 C48 P4 112.4(3) . . ?
C47 C48 H64 109.1 . . ?
P4 C48 H64 109.1 . . ?
C47 C48 H65 109.1 . . ?
P4 C48 H65 109.1 . . ?
H64 C48 H65 107.9 . . ?
C59 C58 C57 113.4(6) . . ?
C59 C58 H82 108.9 . . ?
C57 C58 H82 108.9 . . ?
C59 C58 H83 108.9 . . ?
C57 C58 H83 108.9 . . ?
H82 C58 H83 107.7 . . ?
C48 C47 P3 112.9(3) . . ?
C48 C47 H62 109.0 . . ?
P3 C47 H62 109.0 . . ?
C48 C47 H63 109.0 . . ?
P3 C47 H63 109.0 . . ?
H62 C47 H63 107.8 . . ?
C73 B1 C79 108.4(4) . . ?
C73 B1 C85 113.2(4) . . ?
C79 B1 C85 113.7(4) . . ?
C73 B1 H110 105(2) . . ?
C79 B1 H110 104(2) . . ?
C85 B1 H110 112(2) . . ?
C56 C57 C58 111.0(5) . . ?
C56 C57 H80 109.4 . . ?
C58 C57 H80 109.4 . . ?
C56 C57 H81 109.4 . . ?
C58 C57 H81 109.4 . . ?
H80 C57 H81 108.0 . . ?
C55 C60 C59 110.1(5) . . ?
C55 C60 H86 109.6 . . ?
C59 C60 H86 109.6 . . ?
C55 C60 H87 109.6 . . ?
C59 C60 H87 109.6 . . ?
H86 C60 H87 108.2 . . ?
C58 C59 C60 110.8(6) . . ?
C58 C59 H84 109.5 . . ?
C60 C59 H84 109.5 . . ?
C58 C59 H85 109.5 . . ?
C60 C59 H85 109.5 . . ?
H84 C59 H85 108.1 . . ?
C3 C2 C7 118.8(4) . . ?
C3 C2 C1 126.6(4) . . ?
C7 C2 C1 114.6(4) . . ?
C13 C20 C19 103.8(4) . . ?
C13 C20 C7 107.2(4) . . ?
C19 C20 C7 106.0(4) . . ?
C13 C20 H13 113.0 . . ?
C19 C20 H13 113.0 . . ?
C7 C20 H13 113.0 . . ?
C2 C7 C6 121.4(5) . . ?
C2 C7 C20 113.3(4) . . ?
C6 C7 C20 125.2(5) . . ?
C64 C63 C62 112.2(4) . . ?
C64 C63 H91 109.2 . . ?
C62 C63 H91 109.2 . . ?
C64 C63 H92 109.2 . . ?
C62 C63 H92 109.2 . . ?
H91 C63 H92 107.9 . . ?
C2 C3 C4 120.0(5) . . ?
C2 C3 H1 120.0 . . ?
C4 C3 H1 120.0 . . ?
F15 C90 C89 116.5(5) . . ?
F15 C90 C85 118.8(5) . . ?
C89 C90 C85 124.7(6) . . ?
C4 C5 C6 120.3(5) . . ?
C4 C5 H3 119.8 . . ?
C6 C5 H3 119.8 . . ?
C5 C4 C3 120.9(5) . . ?
C5 C4 H2 119.6 . . ?
C3 C4 H2 119.6 . . ?
C65 C66 C61 111.3(4) . . ?
C65 C66 H97 109.4 . . ?
C61 C66 H97 109.4 . . ?
C65 C66 H98 109.4 . . ?
C61 C66 H98 109.4 . . ?
H97 C66 H98 108.0 . . ?
C5 C6 C7 118.6(5) . . ?
C5 C6 H4 120.7 . . ?
C7 C6 H4 120.7 . . ?
C64 C65 C66 111.6(5) . . ?
C64 C65 H95 109.3 . . ?
C66 C65 H95 109.3 . . ?
C64 C65 H96 109.3 . . ?
C66 C65 H96 109.3 . . ?
H95 C65 H96 108.0 . . ?
C65 C64 C63 111.0(4) . . ?
C65 C64 H93 109.4 . . ?
C63 C64 H93 109.4 . . ?
C65 C64 H94 109.4 . . ?
C63 C64 H94 109.4 . . ?
H93 C64 H94 108.0 . . ?
C61 C62 C63 112.4(4) . . ?
C61 C62 H89 109.1 . . ?
C63 C62 H89 109.1 . . ?
C61 C62 H90 109.1 . . ?
C63 C62 H90 109.1 . . ?
H89 C62 H90 107.9 . . ?
F11 C86 C85 120.7(5) . . ?
F11 C86 C87 114.8(5) . . ?
C85 C86 C87 124.5(6) . . ?
F13 C88 C89 121.5(6) . . ?
F13 C88 C87 120.5(6) . . ?
C89 C88 C87 118.0(6) . . ?
F14 C89 C88 119.0(6) . . ?
F14 C89 C90 120.8(6) . . ?
C88 C89 C90 120.2(6) . . ?
F12 C87 C88 119.5(6) . . ?
F12 C87 C86 120.7(6) . . ?
C88 C87 C86 119.8(6) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P3 Pt2 Pt1 P1 -15.82(10) . . . . ?
P4 Pt2 Pt1 P1 157.97(8) . . . . ?
Ge1 Pt2 Pt1 P1 -16.44(7) . . . . ?
P3 Pt2 Pt1 P2 170.60(8) . . . . ?
P4 Pt2 Pt1 P2 -15.62(5) . . . . ?
Ge1 Pt2 Pt1 P2 169.98(4) . . . . ?
P3 Pt2 Pt1 Ge1 0.62(7) . . . . ?
P4 Pt2 Pt1 Ge1 174.40(4) . . . . ?
P3 Pt2 Ge1 C1 -57.83(17) . . . . ?
P4 Pt2 Ge1 C1 89.6(3) . . . . ?
Pt1 Pt2 Ge1 C1 121.89(17) . . . . ?
P3 Pt2 Ge1 Cl1 70.70(6) . . . . ?
P4 Pt2 Ge1 Cl1 -141.9(2) . . . . ?
Pt1 Pt2 Ge1 Cl1 -109.58(5) . . . . ?
P3 Pt2 Ge1 Pt1 -179.72(3) . . . . ?
P4 Pt2 Ge1 Pt1 -32.3(2) . . . . ?
P1 Pt1 Ge1 C1 48.59(16) . . . . ?
P2 Pt1 Ge1 C1 -169.4(2) . . . . ?
Pt2 Pt1 Ge1 C1 -124.30(16) . . . . ?
P1 Pt1 Ge1 Cl1 -80.32(6) . . . . ?
P2 Pt1 Ge1 Cl1 61.65(16) . . . . ?
Pt2 Pt1 Ge1 Cl1 106.79(5) . . . . ?
P1 Pt1 Ge1 Pt2 172.89(3) . . . . ?
P2 Pt1 Ge1 Pt2 -45.14(15) . . . . ?
P1 Pt1 P2 C22 8.14(17) . . . . ?
Ge1 Pt1 P2 C22 -134.9(2) . . . . ?
Pt2 Pt1 P2 C22 -174.60(16) . . . . ?
P1 Pt1 P2 C35 -110.68(17) . . . . ?
Ge1 Pt1 P2 C35 106.3(2) . . . . ?
Pt2 Pt1 P2 C35 66.59(18) . . . . ?
P1 Pt1 P2 C41 121.97(18) . . . . ?
Ge1 Pt1 P2 C41 -21.1(3) . . . . ?
Pt2 Pt1 P2 C41 -60.77(18) . . . . ?
P3 Pt2 P4 C48 11.35(16) . . . . ?
Ge1 Pt2 P4 C48 -136.6(2) . . . . ?
Pt1 Pt2 P4 C48 -165.83(16) . . . . ?
P3 Pt2 P4 C67 -105.85(18) . . . . ?
Ge1 Pt2 P4 C67 106.2(3) . . . . ?
Pt1 Pt2 P4 C67 76.97(18) . . . . ?
P3 Pt2 P4 C61 126.46(18) . . . . ?
Ge1 Pt2 P4 C61 -21.5(3) . . . . ?
Pt1 Pt2 P4 C61 -50.73(19) . . . . ?
P2 Pt1 P1 C23 128.36(17) . . . . ?
Ge1 Pt1 P1 C23 -59.32(17) . . . . ?
Pt2 Pt1 P1 C23 -46.0(2) . . . . ?
P2 Pt1 P1 C21 13.68(17) . . . . ?
Ge1 Pt1 P1 C21 -174.01(17) . . . . ?
Pt2 Pt1 P1 C21 -160.65(17) . . . . ?
P2 Pt1 P1 C29 -104.99(18) . . . . ?
Ge1 Pt1 P1 C29 67.33(18) . . . . ?
Pt2 Pt1 P1 C29 80.68(19) . . . . ?
P4 Pt2 P3 C55 122.42(19) . . . . ?
Ge1 Pt2 P3 C55 -62.52(19) . . . . ?
Pt1 Pt2 P3 C55 -63.0(2) . . . . ?
P4 Pt2 P3 C47 6.88(18) . . . . ?
Ge1 Pt2 P3 C47 -178.05(18) . . . . ?
Pt1 Pt2 P3 C47 -178.55(17) . . . . ?
P4 Pt2 P3 C49 -110.22(18) . . . . ?
Ge1 Pt2 P3 C49 64.85(18) . . . . ?
Pt1 Pt2 P3 C49 64.3(2) . . . . ?
C48 P4 C61 C62 71.5(4) . . . . ?
C67 P4 C61 C62 -179.8(3) . . . . ?
Pt2 P4 C61 C62 -45.2(4) . . . . ?
C48 P4 C61 C66 -54.4(4) . . . . ?
C67 P4 C61 C66 54.2(4) . . . . ?
Pt2 P4 C61 C66 -171.2(3) . . . . ?
C22 P2 C35 C40 63.6(4) . . . . ?
C41 P2 C35 C40 -46.8(4) . . . . ?
Pt1 P2 C35 C40 -177.8(3) . . . . ?
C22 P2 C35 C36 -63.9(4) . . . . ?
C41 P2 C35 C36 -174.3(3) . . . . ?
Pt1 P2 C35 C36 54.7(4) . . . . ?
C51 C50 C49 C54 -54.2(7) . . . . ?
C51 C50 C49 P3 175.4(4) . . . . ?
C55 P3 C49 C50 -40.1(5) . . . . ?
C47 P3 C49 C50 70.9(5) . . . . ?
Pt2 P3 C49 C50 -170.7(4) . . . . ?
C55 P3 C49 C54 -171.5(4) . . . . ?
C47 P3 C49 C54 -60.5(4) . . . . ?
Pt2 P3 C49 C54 57.9(4) . . . . ?
C48 P4 C67 C68 176.0(4) . . . . ?
C61 P4 C67 C68 67.7(4) . . . . ?
Pt2 P4 C67 C68 -65.6(4) . . . . ?
C48 P4 C67 C72 -60.6(4) . . . . ?
C61 P4 C67 C72 -168.8(3) . . . . ?
Pt2 P4 C67 C72 57.9(4) . . . . ?
C26 C27 C28 C23 -55.2(6) . . . . ?
C28 C27 C26 C25 55.4(6) . . . . ?
C10 C9 C8 C13 -3.5(7) . . . . ?
C10 C9 C8 C1 -175.4(4) . . . . ?
C23 P1 C21 C22 -162.8(3) . . . . ?
C29 P1 C21 C22 85.5(4) . . . . ?
Pt1 P1 C21 C22 -38.8(4) . . . . ?
C17 C18 C19 C14 1.4(7) . . . . ?
C17 C18 C19 C20 -170.4(5) . . . . ?
C15 C14 C19 C18 -4.0(7) . . . . ?
C1 C14 C19 C18 -177.4(4) . . . . ?
C15 C14 C19 C20 168.7(4) . . . . ?
C1 C14 C19 C20 -4.7(6) . . . . ?
C33 C34 C29 C30 59.4(5) . . . . ?
C33 C34 C29 P1 -170.8(3) . . . . ?
C23 P1 C29 C34 146.8(4) . . . . ?
C21 P1 C29 C34 -104.0(4) . . . . ?
Pt1 P1 C29 C34 14.8(4) . . . . ?
C23 P1 C29 C30 -86.1(4) . . . . ?
C21 P1 C29 C30 23.1(4) . . . . ?
Pt1 P1 C29 C30 141.9(3) . . . . ?
C9 C8 C13 C12 4.2(7) . . . . ?
C1 C8 C13 C12 177.1(4) . . . . ?
C9 C8 C13 C20 -168.9(4) . . . . ?
C1 C8 C13 C20 3.9(6) . . . . ?
C40 C35 C36 C37 52.2(6) . . . . ?
P2 C35 C36 C37 -177.8(4) . . . . ?
F2 C75 C74 F1 0.5(8) . . . . ?
C76 C75 C74 F1 -179.2(5) . . . . ?
F2 C75 C74 C73 179.7(5) . . . . ?
C76 C75 C74 C73 0.0(9) . . . . ?
C8 C13 C12 C11 -2.3(7) . . . . ?
C20 C13 C12 C11 170.0(5) . . . . ?
C10 C11 C12 C13 -0.5(7) . . . . ?
C27 C28 C23 C24 55.4(5) . . . . ?
C27 C28 C23 P1 -176.1(3) . . . . ?
C21 P1 C23 C28 -66.0(4) . . . . ?
C29 P1 C23 C28 46.0(4) . . . . ?
Pt1 P1 C23 C28 177.0(3) . . . . ?
C21 P1 C23 C24 61.7(4) . . . . ?
C29 P1 C23 C24 173.6(3) . . . . ?
Pt1 P1 C23 C24 -55.3(4) . . . . ?
C12 C11 C10 C9 1.1(7) . . . . ?
C8 C9 C10 C11 0.9(7) . . . . ?
C68 C69 C70 C71 52.5(6) . . . . ?
C31 C32 C33 C34 51.9(6) . . . . ?
C29 C34 C33 C32 -56.6(6) . . . . ?
C19 C18 C17 C16 1.8(8) . . . . ?
C15 C16 C17 C18 -2.4(8) . . . . ?
C68 C67 C72 C71 -59.4(5) . . . . ?
P4 C67 C72 C71 175.9(3) . . . . ?
C69 C70 C71 C72 -54.6(7) . . . . ?
C67 C72 C71 C70 57.8(6) . . . . ?
C28 C23 C24 C25 -55.7(6) . . . . ?
P1 C23 C24 C25 174.5(4) . . . . ?
C35 C36 C37 C38 -56.2(6) . . . . ?
C22 P2 C41 C42 -34.5(4) . . . . ?
C35 P2 C41 C42 78.0(4) . . . . ?
Pt1 P2 C41 C42 -150.0(3) . . . . ?
C22 P2 C41 C46 89.3(4) . . . . ?
C35 P2 C41 C46 -158.1(3) . . . . ?
Pt1 P2 C41 C46 -26.1(4) . . . . ?
F2 C75 C76 F3 -2.1(8) . . . . ?
C74 C75 C76 F3 177.5(5) . . . . ?
F2 C75 C76 C77 177.9(5) . . . . ?
C74 C75 C76 C77 -2.4(9) . . . . ?
C9 C8 C1 C2 -138.8(5) . . . . ?
C13 C8 C1 C2 49.1(5) . . . . ?
C9 C8 C1 C14 111.6(5) . . . . ?
C13 C8 C1 C14 -60.5(5) . . . . ?
C9 C8 C1 Ge1 -17.2(6) . . . . ?
C13 C8 C1 Ge1 170.7(3) . . . . ?
C15 C14 C1 C8 -112.0(5) . . . . ?
C19 C14 C1 C8 60.7(5) . . . . ?
C15 C14 C1 C2 137.0(5) . . . . ?
C19 C14 C1 C2 -50.3(5) . . . . ?
C15 C14 C1 Ge1 14.5(6) . . . . ?
C19 C14 C1 Ge1 -172.8(3) . . . . ?
Cl1 Ge1 C1 C8 61.5(3) . . . . ?
Pt2 Ge1 C1 C8 -167.3(2) . . . . ?
Pt1 Ge1 C1 C8 -71.1(4) . . . . ?
Cl1 Ge1 C1 C2 -177.4(3) . . . . ?
Pt2 Ge1 C1 C2 -46.2(4) . . . . ?
Pt1 Ge1 C1 C2 50.0(3) . . . . ?
Cl1 Ge1 C1 C14 -56.4(4) . . . . ?
Pt2 Ge1 C1 C14 74.8(4) . . . . ?
Pt1 Ge1 C1 C14 171.0(3) . . . . ?
C44 C45 C46 C41 53.8(6) . . . . ?
C42 C41 C46 C45 -55.4(6) . . . . ?
P2 C41 C46 C45 176.1(4) . . . . ?
C47 P3 C55 C60 -41.2(5) . . . . ?
C49 P3 C55 C60 71.4(5) . . . . ?
Pt2 P3 C55 C60 -159.3(4) . . . . ?
C47 P3 C55 C56 82.8(4) . . . . ?
C49 P3 C55 C56 -164.6(4) . . . . ?
Pt2 P3 C55 C56 -35.3(4) . . . . ?
P1 C21 C22 P2 47.2(4) . . . . ?
C35 P2 C22 C21 91.7(4) . . . . ?
C41 P2 C22 C21 -155.1(3) . . . . ?
Pt1 P2 C22 C21 -33.6(3) . . . . ?
C50 C49 C54 C53 54.4(7) . . . . ?
P3 C49 C54 C53 -170.4(4) . . . . ?
C46 C45 C44 C43 -53.7(6) . . . . ?
C42 C43 C44 C45 57.0(6) . . . . ?
C60 C55 C56 C57 -59.6(6) . . . . ?
P3 C55 C56 C57 171.7(4) . . . . ?
F3 C76 C77 F4 1.8(9) . . . . ?
C75 C76 C77 F4 -178.2(5) . . . . ?
F3 C76 C77 C78 -176.8(5) . . . . ?
C75 C76 C77 C78 3.2(9) . . . . ?
F5 C78 C77 F4 -2.4(8) . . . . ?
C73 C78 C77 F4 179.8(5) . . . . ?
F5 C78 C77 C76 176.2(5) . . . . ?
C73 C78 C77 C76 -1.6(9) . . . . ?
F5 C78 C73 C74 -178.4(5) . . . . ?
C77 C78 C73 C74 -0.7(8) . . . . ?
F5 C78 C73 B1 1.7(8) . . . . ?
C77 C78 C73 B1 179.3(5) . . . . ?
F1 C74 C73 C78 -179.3(5) . . . . ?
C75 C74 C73 C78 1.5(8) . . . . ?
F1 C74 C73 B1 0.6(7) . . . . ?
C75 C74 C73 B1 -178.6(5) . . . . ?
C72 C67 C68 C69 59.4(6) . . . . ?
P4 C67 C68 C69 -175.4(4) . . . . ?
C70 C69 C68 C67 -56.1(6) . . . . ?
C36 C37 C38 C39 58.3(6) . . . . ?
F8 C82 C81 F7 0.4(8) . . . . ?
C83 C82 C81 F7 179.1(5) . . . . ?
F8 C82 C81 C80 179.1(5) . . . . ?
C83 C82 C81 C80 -2.2(8) . . . . ?
F6 C80 C81 F7 0.2(8) . . . . ?
C79 C80 C81 F7 -178.8(5) . . . . ?
F6 C80 C81 C82 -178.5(5) . . . . ?
C79 C80 C81 C82 2.5(9) . . . . ?
C49 C50 C51 C52 55.7(7) . . . . ?
C53 C52 C51 C50 -57.1(7) . . . . ?
F6 C80 C79 C84 179.5(5) . . . . ?
C81 C80 C79 C84 -1.5(8) . . . . ?
F6 C80 C79 B1 -0.9(8) . . . . ?
C81 C80 C79 B1 178.1(5) . . . . ?
C27 C26 C25 C24 -56.2(6) . . . . ?
C23 C24 C25 C26 56.1(6) . . . . ?
C37 C38 C39 C40 -56.9(6) . . . . ?
C17 C16 C15 C14 -0.3(8) . . . . ?
C19 C14 C15 C16 3.4(7) . . . . ?
C1 C14 C15 C16 175.8(5) . . . . ?
C51 C52 C53 C54 57.5(7) . . . . ?
C49 C54 C53 C52 -56.2(7) . . . . ?
C44 C43 C42 C41 -59.7(6) . . . . ?
C46 C41 C42 C43 57.9(6) . . . . ?
P2 C41 C42 C43 -178.4(4) . . . . ?
C33 C32 C31 C30 -51.0(7) . . . . ?
C80 C79 C84 F10 -177.8(5) . . . . ?
B1 C79 C84 F10 2.6(8) . . . . ?
C80 C79 C84 C83 0.5(8) . . . . ?
B1 C79 C84 C83 -179.1(5) . . . . ?
C36 C35 C40 C39 -50.7(6) . . . . ?
P2 C35 C40 C39 -177.3(4) . . . . ?
C38 C39 C40 C35 54.0(6) . . . . ?
C34 C29 C30 C31 -57.4(6) . . . . ?
P1 C29 C30 C31 173.5(4) . . . . ?
C32 C31 C30 C29 53.7(6) . . . . ?
F10 C84 C83 F9 -0.6(8) . . . . ?
C79 C84 C83 F9 -178.9(5) . . . . ?
F10 C84 C83 C82 178.0(5) . . . . ?
C79 C84 C83 C82 -0.4(9) . . . . ?
F8 C82 C83 F9 -1.5(8) . . . . ?
C81 C82 C83 F9 179.8(5) . . . . ?
F8 C82 C83 C84 179.9(5) . . . . ?
C81 C82 C83 C84 1.2(8) . . . . ?
C67 P4 C48 C47 95.0(4) . . . . ?
C61 P4 C48 C47 -156.0(3) . . . . ?
Pt2 P4 C48 C47 -32.0(4) . . . . ?
P4 C48 C47 P3 39.7(4) . . . . ?
C55 P3 C47 C48 -151.8(4) . . . . ?
C49 P3 C47 C48 93.1(4) . . . . ?
Pt2 P3 C47 C48 -28.7(4) . . . . ?
C78 C73 B1 C79 -104.0(6) . . . . ?
C74 C73 B1 C79 76.1(6) . . . . ?
C78 C73 B1 C85 23.2(8) . . . . ?
C74 C73 B1 C85 -156.8(5) . . . . ?
C80 C79 B1 C73 -131.1(5) . . . . ?
C84 C79 B1 C73 48.5(7) . . . . ?
C80 C79 B1 C85 102.0(6) . . . . ?
C84 C79 B1 C85 -78.4(6) . . . . ?
C86 C85 B1 C73 -130.5(6) . . . . ?
C90 C85 B1 C73 53.3(6) . . . . ?
C86 C85 B1 C79 -6.2(8) . . . . ?
C90 C85 B1 C79 177.6(5) . . . . ?
C55 C56 C57 C58 54.9(8) . . . . ?
C59 C58 C57 C56 -52.3(10) . . . . ?
C56 C55 C60 C59 60.4(6) . . . . ?
P3 C55 C60 C59 -174.3(4) . . . . ?
C57 C58 C59 C60 53.6(8) . . . . ?
C55 C60 C59 C58 -58.2(7) . . . . ?
C8 C1 C2 C3 130.9(5) . . . . ?
C14 C1 C2 C3 -124.5(5) . . . . ?
Ge1 C1 C2 C3 4.7(6) . . . . ?
C8 C1 C2 C7 -50.4(5) . . . . ?
C14 C1 C2 C7 54.2(5) . . . . ?
Ge1 C1 C2 C7 -176.6(3) . . . . ?
C12 C13 C20 C19 -117.7(5) . . . . ?
C8 C13 C20 C19 55.2(5) . . . . ?
C12 C13 C20 C7 130.4(5) . . . . ?
C8 C13 C20 C7 -56.8(5) . . . . ?
C18 C19 C20 C13 117.6(5) . . . . ?
C14 C19 C20 C13 -54.7(5) . . . . ?
C18 C19 C20 C7 -129.6(5) . . . . ?
C14 C19 C20 C7 58.1(5) . . . . ?
C3 C2 C7 C6 -0.6(7) . . . . ?
C1 C2 C7 C6 -179.5(4) . . . . ?
C3 C2 C7 C20 177.2(5) . . . . ?
C1 C2 C7 C20 -1.6(6) . . . . ?
C13 C20 C7 C2 55.8(5) . . . . ?
C19 C20 C7 C2 -54.7(5) . . . . ?
C13 C20 C7 C6 -126.5(5) . . . . ?
C19 C20 C7 C6 123.1(5) . . . . ?
C7 C2 C3 C4 -0.2(8) . . . . ?
C1 C2 C3 C4 178.5(5) . . . . ?
C86 C85 C90 F15 179.0(5) . . . . ?
B1 C85 C90 F15 -4.3(7) . . . . ?
C86 C85 C90 C89 0.9(8) . . . . ?
B1 C85 C90 C89 177.7(5) . . . . ?
C6 C5 C4 C3 -0.2(9) . . . . ?
C2 C3 C4 C5 0.6(9) . . . . ?
C62 C61 C66 C65 54.4(6) . . . . ?
P4 C61 C66 C65 -179.6(4) . . . . ?
C4 C5 C6 C7 -0.6(8) . . . . ?
C2 C7 C6 C5 1.1(8) . . . . ?
C20 C7 C6 C5 -176.5(5) . . . . ?
C61 C66 C65 C64 -56.3(6) . . . . ?
C66 C65 C64 C63 55.8(6) . . . . ?
C62 C63 C64 C65 -54.1(6) . . . . ?
C66 C61 C62 C63 -53.1(6) . . . . ?
P4 C61 C62 C63 179.3(4) . . . . ?
C64 C63 C62 C61 53.4(6) . . . . ?
C90 C85 C86 F11 -179.7(5) . . . . ?
B1 C85 C86 F11 3.8(9) . . . . ?
C90 C85 C86 C87 -0.1(8) . . . . ?
B1 C85 C86 C87 -176.6(5) . . . . ?
F13 C88 C89 F14 -0.3(8) . . . . ?
C87 C88 C89 F14 -179.9(5) . . . . ?
F13 C88 C89 C90 -178.9(5) . . . . ?
C87 C88 C89 C90 1.5(9) . . . . ?
F15 C90 C89 F14 1.7(7) . . . . ?
C85 C90 C89 F14 179.8(5) . . . . ?
F15 C90 C89 C88 -179.8(5) . . . . ?
C85 C90 C89 C88 -1.7(9) . . . . ?
F13 C88 C87 F12 -0.3(9) . . . . ?
C89 C88 C87 F12 179.3(5) . . . . ?
F13 C88 C87 C86 179.6(5) . . . . ?
C89 C88 C87 C86 -0.8(9) . . . . ?
F11 C86 C87 F12 -0.4(8) . . . . ?
C85 C86 C87 F12 180.0(5) . . . . ?
F11 C86 C87 C88 179.7(5) . . . . ?
C85 C86 C87 C88 0.1(10) . . . . ?

_diffrn_measured_fraction_theta_max 0.973
_diffrn_reflns_theta_full        26.00
_diffrn_measured_fraction_theta_full 0.973
_refine_diff_density_max         3.424
_refine_diff_density_min         -1.977
_refine_diff_density_rms         0.156
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_naka114
_database_code_depnum_ccdc_archive 'CCDC 1055409'
_audit_update_record             
;
2015-03-23 deposited with the CCDC.
2015-05-12 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 'C90 H112 B F15 Ge P4 Pt2'  
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C72 H111 Ge P4 Pt2, C18 H B F15'
_chemical_formula_sum            'C90 H112 B F15 Ge P4 Pt2'
_chemical_formula_weight         2076.26

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_Int_Tables_number      2

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   13.4434(13)
_cell_length_b                   18.1970(17)
_cell_length_c                   18.3865(17)
_cell_angle_alpha                92.5760(10)
_cell_angle_beta                 106.1520(10)
_cell_angle_gamma                97.3110(10)
_cell_volume                     4269.9(7)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       plate
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.07
_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.03
_exptl_crystal_density_meas      'not measured'
_exptl_crystal_density_diffrn    1.615
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2080
_exptl_absorpt_coefficient_mu    3.771
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.7782
_exptl_absorpt_correction_T_max  0.8953
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1997)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'Bruker TXS fine-focus rotating anode'
_diffrn_radiation_monochromator  'Bruker Helios multilayered confocal mirror'
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean 8.333
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            21360
_diffrn_reflns_av_R_equivalents  0.0510
_diffrn_reflns_av_sigmaI/netI    0.0660
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         1.13
_diffrn_reflns_theta_max         25.50
_reflns_number_total             15558
_reflns_number_gt                11975
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEX-II'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    
'Yadokari-XG 2009 (Wakita, Nemoto et al., 2009)'
_computing_publication_material  
'Yadokari-XG 2009 (Wakita, Nemoto et al., 2009)'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0384P)²+0.0010P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         15558
_refine_ls_number_parameters     1026
_refine_ls_number_restraints     2
_refine_ls_R_factor_all          0.0508
_refine_ls_R_factor_gt           0.0376
_refine_ls_wR_factor_ref         0.0896
_refine_ls_wR_factor_gt          0.0862
_refine_ls_goodness_of_fit_ref   1.011
_refine_ls_restrained_S_all      1.011
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.198650(16) 0.326287(11) 0.243300(12) 0.02225(6) Uani 1 1 d D . .
Pt2 Pt 0.221998(15) 0.171758(11) 0.272985(12) 0.02170(6) Uani 1 1 d D . .
Ge1 Ge 0.33209(4) 0.25727(3) 0.21811(3) 0.02466(14) Uani 1 1 d . . .
H1 H 0.4382 0.2835 0.2763 0.030 Uiso 1 1 calc R . .
P2 P 0.12643(11) 0.11117(8) 0.34632(8) 0.0246(3) Uani 1 1 d . . .
P3 P 0.23940(11) 0.43582(8) 0.19751(9) 0.0257(3) Uani 1 1 d . . .
P1 P 0.28348(11) 0.06392(7) 0.25927(8) 0.0244(3) Uani 1 1 d . . .
P4 P 0.05644(11) 0.37262(7) 0.26553(8) 0.0239(3) Uani 1 1 d . . .
C67 C -0.0742(4) 0.3165(3) 0.2253(3) 0.0283(13) Uani 1 1 d . . .
H101 H -0.0755 0.2714 0.2543 0.034 Uiso 1 1 calc R . .
C75 C 0.6125(5) 0.2107(3) 0.7413(4) 0.0444(17) Uani 1 1 d . . .
F8 F 0.6764(4) 0.3323(3) 0.3572(2) 0.0733(13) Uani 1 1 d . . .
F14 F 1.1398(3) 0.4456(2) 0.7240(2) 0.0531(10) Uani 1 1 d . . .
C88 C 1.1866(5) 0.3264(4) 0.7502(4) 0.0442(17) Uani 1 1 d . . .
F15 F 0.9394(3) 0.38691(19) 0.6670(2) 0.0526(10) Uani 1 1 d . . .
F3 F 0.5949(3) 0.2431(2) 0.8625(3) 0.0652(12) Uani 1 1 d . . .
F9 F 0.6195(4) 0.3838(2) 0.4790(2) 0.0696(13) Uani 1 1 d . . .
C2 C 0.2453(4) 0.2116(3) 0.0549(3) 0.0306(13) Uani 1 1 d . . .
F6 F 0.8951(3) 0.1870(2) 0.5142(2) 0.0515(10) Uani 1 1 d . . .
F11 F 1.0302(3) 0.1473(2) 0.7203(2) 0.0535(10) Uani 1 1 d . . .
F12 F 1.2310(3) 0.2082(2) 0.7748(2) 0.0648(12) Uani 1 1 d . . .
C24 C 0.1604(4) 0.0177(3) 0.1107(3) 0.0358(14) Uani 1 1 d . . .
H21 H 0.1318 0.0649 0.1132 0.043 Uiso 1 1 calc R . .
H22 H 0.1165 -0.0212 0.1285 0.043 Uiso 1 1 calc R . .
F10 F 0.7027(3) 0.3438(2) 0.6161(2) 0.0550(10) Uani 1 1 d . . .
F5 F 0.9198(3) 0.2981(3) 0.8186(2) 0.0655(12) Uani 1 1 d . . .
F13 F 1.2873(3) 0.3572(3) 0.7797(2) 0.0665(12) Uani 1 1 d . . .
C39 C -0.1960(5) 0.0410(4) 0.3182(4) 0.0483(18) Uani 1 1 d . . .
H49 H -0.2241 0.0885 0.3094 0.058 Uiso 1 1 calc R . .
H50 H -0.2309 0.0140 0.3521 0.058 Uiso 1 1 calc R . .
C77 C 0.7585(5) 0.2694(4) 0.8390(4) 0.0458(17) Uani 1 1 d . . .
C55 C 0.3717(4) 0.4877(3) 0.2399(4) 0.0356(15) Uani 1 1 d . . .
H79 H 0.4169 0.4705 0.2095 0.043 Uiso 1 1 calc R . .
F1 F 0.6292(3) 0.1796(2) 0.6225(2) 0.0524(10) Uani 1 1 d . . .
C49 C 0.2183(4) 0.4281(3) 0.0933(3) 0.0307(13) Uani 1 1 d . . .
H68 H 0.2602 0.3892 0.0831 0.037 Uiso 1 1 calc R . .
C34 C 0.4661(4) 0.1250(3) 0.3758(4) 0.0363(15) Uani 1 1 d . . .
H40 H 0.4285 0.1213 0.4151 0.044 Uiso 1 1 calc R . .
H41 H 0.4551 0.1723 0.3523 0.044 Uiso 1 1 calc R . .
C74 C 0.6753(5) 0.2095(3) 0.6941(4) 0.0397(16) Uani 1 1 d . . .
C50 C 0.1028(5) 0.3968(4) 0.0529(4) 0.0464(17) Uani 1 1 d . . .
H69 H 0.0820 0.3512 0.0757 0.056 Uiso 1 1 calc R . .
H70 H 0.0573 0.4338 0.0593 0.056 Uiso 1 1 calc R . .
C61 C 0.0597(4) 0.4015(3) 0.3641(3) 0.0255(12) Uani 1 1 d . . .
H90 H -0.0044 0.4249 0.3617 0.031 Uiso 1 1 calc R . .
C63 C 0.1497(5) 0.4846(3) 0.4830(4) 0.0428(16) Uani 1 1 d . . .
H93 H 0.2120 0.5214 0.5083 0.051 Uiso 1 1 calc R . .
H94 H 0.0868 0.5092 0.4780 0.051 Uiso 1 1 calc R . .
C23 C 0.2725(4) 0.0268(3) 0.1618(3) 0.0255(12) Uani 1 1 d . . .
H20 H 0.3137 0.0652 0.1403 0.031 Uiso 1 1 calc R . .
C73 C 0.7823(5) 0.2378(3) 0.7155(3) 0.0377(15) Uani 1 1 d . . .
C28 C 0.3198(5) -0.0446(3) 0.1573(4) 0.0346(14) Uani 1 1 d . . .
H29 H 0.2807 -0.0850 0.1770 0.042 Uiso 1 1 calc R . .
H30 H 0.3935 -0.0370 0.1892 0.042 Uiso 1 1 calc R . .
C26 C 0.2046(5) -0.0749(3) 0.0245(4) 0.0430(16) Uani 1 1 d . . .
H25 H 0.1617 -0.1163 0.0399 0.052 Uiso 1 1 calc R . .
H26 H 0.2038 -0.0874 -0.0286 0.052 Uiso 1 1 calc R . .
C90 C 1.0096(5) 0.3390(4) 0.6921(3) 0.0393(15) Uani 1 1 d . . .
C66 C 0.0577(5) 0.3357(3) 0.4119(3) 0.0317(14) Uani 1 1 d . . .
H99 H 0.1212 0.3121 0.4159 0.038 Uiso 1 1 calc R . .
H100 H -0.0041 0.2984 0.3865 0.038 Uiso 1 1 calc R . .
C89 C 1.1124(5) 0.3716(4) 0.7219(4) 0.0433(16) Uani 1 1 d . . .
C76 C 0.6543(6) 0.2404(4) 0.8144(4) 0.0488(18) Uani 1 1 d . . .
C10 C 0.5575(4) 0.1035(3) 0.1545(4) 0.0364(15) Uani 1 1 d . . .
H8 H 0.6038 0.0845 0.1960 0.044 Uiso 1 1 calc R . .
F7 F 0.8149(3) 0.2328(2) 0.3772(2) 0.0603(11) Uani 1 1 d . . .
C81 C 0.7875(5) 0.2606(4) 0.4374(4) 0.0439(17) Uani 1 1 d . . .
C86 C 1.0530(5) 0.2220(4) 0.7189(4) 0.0410(16) Uani 1 1 d . . .
C9 C 0.4932(4) 0.1529(3) 0.1683(3) 0.0320(14) Uani 1 1 d . . .
H7 H 0.4974 0.1690 0.2191 0.038 Uiso 1 1 calc R . .
C8 C 0.4222(4) 0.1794(3) 0.1077(3) 0.0255(12) Uani 1 1 d . . .
C47 C 0.1515(4) 0.4991(3) 0.2159(3) 0.0285(13) Uani 1 1 d . . .
H64 H 0.1858 0.5283 0.2652 0.034 Uiso 1 1 calc R . .
H65 H 0.1405 0.5345 0.1760 0.034 Uiso 1 1 calc R . .
C62 C 0.1550(5) 0.4591(3) 0.4035(3) 0.0346(14) Uani 1 1 d . . .
H91 H 0.1566 0.5023 0.3729 0.042 Uiso 1 1 calc R . .
H92 H 0.2199 0.4370 0.4079 0.042 Uiso 1 1 calc R . .
C84 C 0.7330(5) 0.3127(3) 0.5583(4) 0.0415(16) Uani 1 1 d . . .
C65 C 0.0532(5) 0.3596(3) 0.4918(3) 0.0418(16) Uani 1 1 d . . .
H97 H -0.0136 0.3787 0.4883 0.050 Uiso 1 1 calc R . .
H98 H 0.0556 0.3160 0.5223 0.050 Uiso 1 1 calc R . .
C56 C 0.3807(5) 0.5730(3) 0.2375(4) 0.0413(16) Uani 1 1 d . . .
H80 H 0.3476 0.5852 0.1851 0.050 Uiso 1 1 calc R . .
H81 H 0.3431 0.5934 0.2713 0.050 Uiso 1 1 calc R . .
C37 C -0.1658(5) 0.0320(4) 0.1911(4) 0.0467(17) Uani 1 1 d . . .
H45 H -0.1923 0.0797 0.1789 0.056 Uiso 1 1 calc R . .
H46 H -0.1810 0.0003 0.1430 0.056 Uiso 1 1 calc R . .
C78 C 0.8183(5) 0.2673(4) 0.7894(4) 0.0402(16) Uani 1 1 d . . .
C1 C 0.3505(4) 0.2372(3) 0.1133(3) 0.0271(12) Uani 1 1 d . . .
C87 C 1.1554(5) 0.2517(4) 0.7476(4) 0.0454(17) Uani 1 1 d . . .
C80 C 0.8274(5) 0.2374(3) 0.5091(4) 0.0376(15) Uani 1 1 d . . .
C32 C 0.6035(5) 0.0526(4) 0.4468(4) 0.0440(17) Uani 1 1 d . . .
H36 H 0.6800 0.0527 0.4659 0.053 Uiso 1 1 calc R . .
H37 H 0.5742 0.0478 0.4905 0.053 Uiso 1 1 calc R . .
C41 C 0.1547(4) 0.1549(3) 0.4448(3) 0.0285(13) Uani 1 1 d . . .
H53 H 0.1062 0.1926 0.4430 0.034 Uiso 1 1 calc R . .
C60 C 0.4193(6) 0.4705(4) 0.3207(4) 0.067(3) Uani 1 1 d . . .
H88 H 0.4135 0.4160 0.3236 0.080 Uiso 1 1 calc R . .
H89 H 0.3813 0.4908 0.3542 0.080 Uiso 1 1 calc R . .
C85 C 0.9742(5) 0.2637(3) 0.6890(3) 0.0381(15) Uani 1 1 d . . .
C21 C 0.2015(4) -0.0095(3) 0.2917(3) 0.0280(13) Uani 1 1 d . . .
H16 H 0.1372 -0.0275 0.2499 0.034 Uiso 1 1 calc R . .
H17 H 0.2403 -0.0520 0.3051 0.034 Uiso 1 1 calc R . .
F4 F 0.8009(3) 0.3005(3) 0.9106(2) 0.0672(12) Uani 1 1 d . . .
C58 C 0.5459(6) 0.5892(4) 0.3420(5) 0.075(3) Uani 1 1 d . . .
H84 H 0.5131 0.6116 0.3778 0.090 Uiso 1 1 calc R . .
H85 H 0.6209 0.6106 0.3570 0.090 Uiso 1 1 calc R . .
C19 C 0.4077(4) 0.2838(3) 0.0046(3) 0.0318(14) Uani 1 1 d . . .
C82 C 0.7173(6) 0.3101(4) 0.4272(4) 0.0515(19) Uani 1 1 d . . .
C45 C 0.1639(5) 0.1473(4) 0.5829(3) 0.0435(16) Uani 1 1 d . . .
H60 H 0.1140 0.1835 0.5798 0.052 Uiso 1 1 calc R . .
H61 H 0.1547 0.1130 0.6215 0.052 Uiso 1 1 calc R . .
C42 C 0.2658(5) 0.1971(3) 0.4687(3) 0.0393(15) Uani 1 1 d . . .
H54 H 0.2732 0.2329 0.4309 0.047 Uiso 1 1 calc R . .
H55 H 0.3159 0.1615 0.4694 0.047 Uiso 1 1 calc R . .
C51 C 0.0891(6) 0.3788(4) -0.0316(4) 0.0549(19) Uani 1 1 d . . .
H71 H 0.1307 0.3390 -0.0379 0.066 Uiso 1 1 calc R . .
H72 H 0.0146 0.3602 -0.0577 0.066 Uiso 1 1 calc R . .
C29 C 0.4212(4) 0.0611(3) 0.3159(3) 0.0264(12) Uani 1 1 d . . .
H31 H 0.4639 0.0661 0.2792 0.032 Uiso 1 1 calc R . .
C22 C 0.1713(4) 0.0200(3) 0.3612(3) 0.0289(13) Uani 1 1 d . . .
H18 H 0.2326 0.0248 0.4068 0.035 Uiso 1 1 calc R . .
H19 H 0.1149 -0.0158 0.3702 0.035 Uiso 1 1 calc R . .
C52 C 0.1237(5) 0.4463(4) -0.0674(4) 0.0486(18) Uani 1 1 d . . .
H73 H 0.0793 0.4850 -0.0640 0.058 Uiso 1 1 calc R . .
H74 H 0.1152 0.4330 -0.1218 0.058 Uiso 1 1 calc R . .
C25 C 0.1571(5) -0.0040(4) 0.0288(4) 0.0453(17) Uani 1 1 d . . .
H23 H 0.0837 -0.0117 -0.0037 0.054 Uiso 1 1 calc R . .
H24 H 0.1966 0.0366 0.0097 0.054 Uiso 1 1 calc R . .
C14 C 0.4060(4) 0.3012(3) 0.0799(3) 0.0294(13) Uani 1 1 d . . .
C64 C 0.1451(6) 0.4200(4) 0.5312(4) 0.0488(18) Uani 1 1 d . . .
H95 H 0.1375 0.4378 0.5807 0.059 Uiso 1 1 calc R . .
H96 H 0.2114 0.3987 0.5409 0.059 Uiso 1 1 calc R . .
C33 C 0.5826(4) 0.1259(3) 0.4132(4) 0.0385(15) Uani 1 1 d . . .
H38 H 0.6212 0.1348 0.3751 0.046 Uiso 1 1 calc R . .
H39 H 0.6083 0.1670 0.4539 0.046 Uiso 1 1 calc R . .
C46 C 0.1397(5) 0.1030(3) 0.5054(3) 0.0414(16) Uani 1 1 d . . .
H62 H 0.1868 0.0648 0.5091 0.050 Uiso 1 1 calc R . .
H63 H 0.0667 0.0774 0.4906 0.050 Uiso 1 1 calc R . .
C27 C 0.3147(5) -0.0666(3) 0.0749(4) 0.0406(16) Uani 1 1 d . . .
H27 H 0.3591 -0.0281 0.0569 0.049 Uiso 1 1 calc R . .
H28 H 0.3426 -0.1141 0.0723 0.049 Uiso 1 1 calc R . .
C13 C 0.4239(4) 0.1598(3) 0.0333(3) 0.0326(14) Uani 1 1 d . . .
C38 C -0.2200(5) -0.0055(4) 0.2425(4) 0.0453(17) Uani 1 1 d . . .
H47 H -0.1972 -0.0548 0.2517 0.054 Uiso 1 1 calc R . .
H48 H -0.2965 -0.0135 0.2179 0.054 Uiso 1 1 calc R . .
C15 C 0.4612(4) 0.3675(3) 0.1184(4) 0.0367(15) Uani 1 1 d . . .
H11 H 0.4642 0.3788 0.1700 0.044 Uiso 1 1 calc R . .
C36 C -0.0467(4) 0.0471(4) 0.2286(3) 0.0390(15) Uani 1 1 d . . .
H43 H -0.0129 0.0747 0.1945 0.047 Uiso 1 1 calc R . .
H44 H -0.0194 -0.0009 0.2353 0.047 Uiso 1 1 calc R . .
C17 C 0.5080(5) 0.4022(4) 0.0057(4) 0.0427(17) Uani 1 1 d . . .
H13 H 0.5407 0.4378 -0.0199 0.051 Uiso 1 1 calc R . .
C30 C 0.4393(4) -0.0130(3) 0.3511(3) 0.0339(14) Uani 1 1 d . . .
H32 H 0.4003 -0.0201 0.3893 0.041 Uiso 1 1 calc R . .
H33 H 0.4124 -0.0546 0.3110 0.041 Uiso 1 1 calc R . .
C54 C 0.2531(6) 0.4960(4) 0.0574(4) 0.0521(19) Uani 1 1 d . . .
H77 H 0.3281 0.5140 0.0825 0.063 Uiso 1 1 calc R . .
H78 H 0.2125 0.5361 0.0643 0.063 Uiso 1 1 calc R . .
C79 C 0.8015(5) 0.2615(3) 0.5731(4) 0.0370(15) Uani 1 1 d . . .
C18 C 0.4567(5) 0.3359(4) -0.0322(4) 0.0418(16) Uani 1 1 d . . .
H14 H 0.4544 0.3253 -0.0837 0.050 Uiso 1 1 calc R . .
C12 C 0.4886(5) 0.1101(3) 0.0203(4) 0.0376(15) Uani 1 1 d . . .
H10 H 0.4874 0.0958 -0.0303 0.045 Uiso 1 1 calc R . .
C44 C 0.2733(5) 0.1879(4) 0.6067(4) 0.0486(18) Uani 1 1 d . . .
H58 H 0.3233 0.1515 0.6144 0.058 Uiso 1 1 calc R . .
H59 H 0.2856 0.2176 0.6556 0.058 Uiso 1 1 calc R . .
C59 C 0.5361(6) 0.5058(4) 0.3472(6) 0.101(4) Uani 1 1 d . . .
H86 H 0.5677 0.4952 0.4004 0.121 Uiso 1 1 calc R . .
H87 H 0.5745 0.4837 0.3150 0.121 Uiso 1 1 calc R . .
C53 C 0.2363(6) 0.4766(4) -0.0282(4) 0.056(2) Uani 1 1 d . . .
H75 H 0.2570 0.5217 -0.0517 0.067 Uiso 1 1 calc R . .
H76 H 0.2812 0.4392 -0.0348 0.067 Uiso 1 1 calc R . .
C83 C 0.6893(5) 0.3359(4) 0.4877(4) 0.0452(17) Uani 1 1 d . . .
C11 C 0.5548(5) 0.0812(3) 0.0806(4) 0.0385(15) Uani 1 1 d . . .
H9 H 0.5981 0.0466 0.0715 0.046 Uiso 1 1 calc R . .
C57 C 0.4943(5) 0.6081(4) 0.2627(5) 0.056(2) Uani 1 1 d . . .
H82 H 0.5311 0.5897 0.2273 0.067 Uiso 1 1 calc R . .
H83 H 0.4990 0.6628 0.2615 0.067 Uiso 1 1 calc R . .
C40 C -0.0784(5) 0.0570(4) 0.3567(4) 0.0447(16) Uani 1 1 d . . .
H51 H -0.0654 0.0902 0.4035 0.054 Uiso 1 1 calc R . .
H52 H -0.0525 0.0097 0.3718 0.054 Uiso 1 1 calc R . .
C48 C 0.0441(4) 0.4592(3) 0.2177(3) 0.0273(13) Uani 1 1 d . . .
H66 H -0.0019 0.4476 0.1650 0.033 Uiso 1 1 calc R . .
H67 H 0.0110 0.4928 0.2446 0.033 Uiso 1 1 calc R . .
C31 C 0.5555(5) -0.0136(4) 0.3889(4) 0.0455(17) Uani 1 1 d . . .
H34 H 0.5647 -0.0601 0.4145 0.055 Uiso 1 1 calc R . .
H35 H 0.5929 -0.0131 0.3495 0.055 Uiso 1 1 calc R . .
C16 C 0.5128(5) 0.4178(3) 0.0808(4) 0.0391(15) Uani 1 1 d . . .
H12 H 0.5515 0.4632 0.1073 0.047 Uiso 1 1 calc R . .
C43 C 0.2927(5) 0.2391(4) 0.5474(4) 0.0462(17) Uani 1 1 d . . .
H56 H 0.3671 0.2618 0.5628 0.055 Uiso 1 1 calc R . .
H57 H 0.2495 0.2796 0.5449 0.055 Uiso 1 1 calc R . .
C35 C -0.0171(4) 0.0926(3) 0.3070(3) 0.0294(13) Uani 1 1 d . . .
H42 H -0.0410 0.1420 0.2969 0.035 Uiso 1 1 calc R . .
B1 B 0.8515(6) 0.2279(4) 0.6545(4) 0.0389(18) Uani 1 1 d . . .
H112 H 0.855(3) 0.167(2) 0.642(2) 0.007(11) Uiso 1 1 d . . .
F2 F 0.5109(3) 0.1832(2) 0.7170(3) 0.0651(12) Uani 1 1 d . . .
C68 C -0.0894(4) 0.2890(3) 0.1416(3) 0.0343(14) Uani 1 1 d . . .
H102 H -0.0821 0.3324 0.1120 0.041 Uiso 1 1 calc R . .
H103 H -0.0340 0.2588 0.1391 0.041 Uiso 1 1 calc R . .
C72 C -0.1660(4) 0.3548(3) 0.2315(4) 0.0359(14) Uani 1 1 d . . .
H110 H -0.1643 0.4015 0.2059 0.043 Uiso 1 1 calc R . .
H111 H -0.1581 0.3682 0.2858 0.043 Uiso 1 1 calc R . .
C7 C 0.2506(5) 0.1928(3) -0.0181(3) 0.0353(14) Uani 1 1 d . . .
C3 C 0.1476(4) 0.2067(3) 0.0668(4) 0.0362(15) Uani 1 1 d . . .
H3 H 0.1421 0.2186 0.1163 0.043 Uiso 1 1 calc R . .
C69 C -0.1970(5) 0.2422(3) 0.1058(4) 0.0410(16) Uani 1 1 d . . .
H104 H -0.2059 0.2295 0.0513 0.049 Uiso 1 1 calc R . .
H105 H -0.2007 0.1952 0.1307 0.049 Uiso 1 1 calc R . .
C4 C 0.0576(5) 0.1847(4) 0.0074(4) 0.0449(17) Uani 1 1 d . . .
H4 H -0.0088 0.1827 0.0166 0.054 Uiso 1 1 calc R . .
C70 C -0.2843(5) 0.2834(3) 0.1140(3) 0.0389(15) Uani 1 1 d . . .
H106 H -0.3523 0.2510 0.0923 0.047 Uiso 1 1 calc R . .
H107 H -0.2847 0.3280 0.0850 0.047 Uiso 1 1 calc R . .
C6 C 0.1594(5) 0.1696(3) -0.0779(3) 0.0411(16) Uani 1 1 d . . .
H6 H 0.1638 0.1565 -0.1274 0.049 Uiso 1 1 calc R . .
C20 C 0.3610(5) 0.2039(3) -0.0247(3) 0.0376(15) Uani 1 1 d . . .
H15 H 0.3643 0.1910 -0.0773 0.045 Uiso 1 1 calc R . .
C5 C 0.0625(5) 0.1659(4) -0.0640(4) 0.0446(17) Uani 1 1 d . . .
H5 H 0.0001 0.1504 -0.1040 0.054 Uiso 1 1 calc R . .
C71 C -0.2716(5) 0.3070(4) 0.1965(4) 0.0455(17) Uani 1 1 d . . .
H108 H -0.2768 0.2624 0.2249 0.055 Uiso 1 1 calc R . .
H109 H -0.3284 0.3354 0.2001 0.055 Uiso 1 1 calc R . .
H2 H 0.147(3) 0.2437(11) 0.273(3) 0.06(2) Uiso 1 1 d D . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 P3 2.2607(14) . ?
Pt1 P4 2.3123(15) . ?
Pt1 Ge1 2.4481(6) . ?
Pt1 Pt2 2.9276(4) . ?
Pt1 H2 1.749(10) . ?
Pt2 P1 2.2543(14) . ?
Pt2 P2 2.3284(14) . ?
Pt2 Ge1 2.4527(6) . ?
Pt2 H2 1.754(10) . ?
Ge1 C1 2.033(6) . ?
Ge1 H1 1.5300 . ?
P2 C22 1.842(5) . ?
P2 C35 1.843(5) . ?
P2 C41 1.862(6) . ?
P3 C47 1.836(6) . ?
P3 C55 1.844(6) . ?
P3 C49 1.853(6) . ?
P1 C23 1.847(6) . ?
P1 C21 1.849(5) . ?
P1 C29 1.863(5) . ?
P4 C48 1.843(5) . ?
P4 C61 1.851(6) . ?
P4 C67 1.852(5) . ?
C67 C72 1.521(8) . ?
C67 C68 1.545(8) . ?
C67 H101 1.0000 . ?
C75 F2 1.335(7) . ?
C75 C76 1.361(10) . ?
C75 C74 1.369(9) . ?
F8 C82 1.353(7) . ?
F14 C89 1.347(7) . ?
C88 F13 1.345(7) . ?
C88 C87 1.366(9) . ?
C88 C89 1.378(9) . ?
F15 C90 1.367(7) . ?
F3 C76 1.349(8) . ?
F9 C83 1.344(7) . ?
C2 C3 1.383(8) . ?
C2 C7 1.394(8) . ?
C2 C1 1.521(7) . ?
F6 C80 1.361(7) . ?
F11 C86 1.358(7) . ?
F12 C87 1.367(7) . ?
C24 C23 1.522(7) . ?
C24 C25 1.526(9) . ?
C24 H21 0.9900 . ?
C24 H22 0.9900 . ?
F10 C84 1.365(7) . ?
F5 C78 1.354(7) . ?
C39 C40 1.525(8) . ?
C39 C38 1.527(9) . ?
C39 H49 0.9900 . ?
C39 H50 0.9900 . ?
C77 F4 1.347(7) . ?
C77 C76 1.373(9) . ?
C77 C78 1.375(9) . ?
C55 C60 1.509(9) . ?
C55 C56 1.545(8) . ?
C55 H79 1.0000 . ?
F1 C74 1.344(7) . ?
C49 C54 1.510(8) . ?
C49 C50 1.543(8) . ?
C49 H68 1.0000 . ?
C34 C29 1.505(8) . ?
C34 C33 1.523(8) . ?
C34 H40 0.9900 . ?
C34 H41 0.9900 . ?
C74 C73 1.403(9) . ?
C50 C51 1.528(9) . ?
C50 H69 0.9900 . ?
C50 H70 0.9900 . ?
C61 C66 1.519(7) . ?
C61 C62 1.529(7) . ?
C61 H90 1.0000 . ?
C63 C64 1.509(8) . ?
C63 C62 1.537(8) . ?
C63 H93 0.9900 . ?
C63 H94 0.9900 . ?
C23 C28 1.525(7) . ?
C23 H20 1.0000 . ?
C73 C78 1.368(9) . ?
C73 B1 1.662(10) . ?
C28 C27 1.529(8) . ?
C28 H29 0.9900 . ?
C28 H30 0.9900 . ?
C26 C27 1.497(8) . ?
C26 C25 1.518(9) . ?
C26 H25 0.9900 . ?
C26 H26 0.9900 . ?
C90 C89 1.380(9) . ?
C90 C85 1.385(9) . ?
C66 C65 1.533(8) . ?
C66 H99 0.9900 . ?
C66 H100 0.9900 . ?
C10 C9 1.385(8) . ?
C10 C11 1.390(9) . ?
C10 H8 0.9500 . ?
F7 C81 1.355(8) . ?
C81 C82 1.368(10) . ?
C81 C80 1.385(9) . ?
C86 C87 1.359(9) . ?
C86 C85 1.384(9) . ?
C9 C8 1.399(7) . ?
C9 H7 0.9500 . ?
C8 C13 1.404(8) . ?
C8 C1 1.534(8) . ?
C47 C48 1.541(7) . ?
C47 H64 0.9900 . ?
C47 H65 0.9900 . ?
C62 H91 0.9900 . ?
C62 H92 0.9900 . ?
C84 C79 1.375(9) . ?
C84 C83 1.377(9) . ?
C65 C64 1.531(9) . ?
C65 H97 0.9900 . ?
C65 H98 0.9900 . ?
C56 C57 1.513(8) . ?
C56 H80 0.9900 . ?
C56 H81 0.9900 . ?
C37 C38 1.486(9) . ?
C37 C36 1.539(8) . ?
C37 H45 0.9900 . ?
C37 H46 0.9900 . ?
C1 C14 1.546(7) . ?
C80 C79 1.386(9) . ?
C32 C31 1.519(9) . ?
C32 C33 1.520(8) . ?
C32 H36 0.9900 . ?
C32 H37 0.9900 . ?
C41 C42 1.525(8) . ?
C41 C46 1.530(8) . ?
C41 H53 1.0000 . ?
C60 C59 1.551(10) . ?
C60 H88 0.9900 . ?
C60 H89 0.9900 . ?
C85 B1 1.629(10) . ?
C21 C22 1.539(8) . ?
C21 H16 0.9900 . ?
C21 H17 0.9900 . ?
C58 C57 1.507(10) . ?
C58 C59 1.516(9) . ?
C58 H84 0.9900 . ?
C58 H85 0.9900 . ?
C19 C18 1.391(8) . ?
C19 C14 1.413(8) . ?
C19 C20 1.520(8) . ?
C82 C83 1.351(10) . ?
C45 C44 1.495(9) . ?
C45 C46 1.536(8) . ?
C45 H60 0.9900 . ?
C45 H61 0.9900 . ?
C42 C43 1.533(8) . ?
C42 H54 0.9900 . ?
C42 H55 0.9900 . ?
C51 C52 1.502(9) . ?
C51 H71 0.9900 . ?
C51 H72 0.9900 . ?
C29 C30 1.539(7) . ?
C29 H31 1.0000 . ?
C22 H18 0.9900 . ?
C22 H19 0.9900 . ?
C52 C53 1.502(9) . ?
C52 H73 0.9900 . ?
C52 H74 0.9900 . ?
C25 H23 0.9900 . ?
C25 H24 0.9900 . ?
C14 C15 1.382(8) . ?
C64 H95 0.9900 . ?
C64 H96 0.9900 . ?
C33 H38 0.9900 . ?
C33 H39 0.9900 . ?
C46 H62 0.9900 . ?
C46 H63 0.9900 . ?
C27 H27 0.9900 . ?
C27 H28 0.9900 . ?
C13 C12 1.388(8) . ?
C13 C20 1.499(8) . ?
C38 H47 0.9900 . ?
C38 H48 0.9900 . ?
C15 C16 1.398(8) . ?
C15 H11 0.9500 . ?
C36 C35 1.552(8) . ?
C36 H43 0.9900 . ?
C36 H44 0.9900 . ?
C17 C18 1.364(9) . ?
C17 C16 1.381(9) . ?
C17 H13 0.9500 . ?
C30 C31 1.525(8) . ?
C30 H32 0.9900 . ?
C30 H33 0.9900 . ?
C54 C53 1.544(9) . ?
C54 H77 0.9900 . ?
C54 H78 0.9900 . ?
C79 B1 1.641(9) . ?
C18 H14 0.9500 . ?
C12 C11 1.387(8) . ?
C12 H10 0.9500 . ?
C44 C43 1.520(9) . ?
C44 H58 0.9900 . ?
C44 H59 0.9900 . ?
C59 H86 0.9900 . ?
C59 H87 0.9900 . ?
C53 H75 0.9900 . ?
C53 H76 0.9900 . ?
C11 H9 0.9500 . ?
C57 H82 0.9900 . ?
C57 H83 0.9900 . ?
C40 C35 1.506(8) . ?
C40 H51 0.9900 . ?
C40 H52 0.9900 . ?
C48 H66 0.9900 . ?
C48 H67 0.9900 . ?
C31 H34 0.9900 . ?
C31 H35 0.9900 . ?
C16 H12 0.9500 . ?
C43 H56 0.9900 . ?
C43 H57 0.9900 . ?
C35 H42 1.0000 . ?
B1 H112 1.13(4) . ?
C68 C69 1.535(8) . ?
C68 H102 0.9900 . ?
C68 H103 0.9900 . ?
C72 C71 1.521(8) . ?
C72 H110 0.9900 . ?
C72 H111 0.9900 . ?
C7 C6 1.403(8) . ?
C7 C20 1.511(8) . ?
C3 C4 1.385(8) . ?
C3 H3 0.9500 . ?
C69 C70 1.508(9) . ?
C69 H104 0.9900 . ?
C69 H105 0.9900 . ?
C4 C5 1.364(9) . ?
C4 H4 0.9500 . ?
C70 C71 1.515(9) . ?
C70 H106 0.9900 . ?
C70 H107 0.9900 . ?
C6 C5 1.389(9) . ?
C6 H6 0.9500 . ?
C20 H15 1.0000 . ?
C5 H5 0.9500 . ?
C71 H108 0.9900 . ?
C71 H109 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P3 Pt1 P4 87.80(5) . . ?
P3 Pt1 Ge1 100.55(4) . . ?
P4 Pt1 Ge1 170.64(4) . . ?
P3 Pt1 Pt2 153.84(4) . . ?
P4 Pt1 Pt2 118.02(3) . . ?
Ge1 Pt1 Pt2 53.389(14) . . ?
P3 Pt1 H2 171.0(12) . . ?
P4 Pt1 H2 84.7(4) . . ?
Ge1 Pt1 H2 86.6(4) . . ?
Pt2 Pt1 H2 33.3(4) . . ?
P1 Pt2 P2 87.13(5) . . ?
P1 Pt2 Ge1 101.53(4) . . ?
P2 Pt2 Ge1 167.51(4) . . ?
P1 Pt2 Pt1 153.90(4) . . ?
P2 Pt2 Pt1 118.88(4) . . ?
Ge1 Pt2 Pt1 53.247(15) . . ?
P1 Pt2 H2 167.0(15) . . ?
P2 Pt2 H2 86.8(7) . . ?
Ge1 Pt2 H2 86.4(4) . . ?
Pt1 Pt2 H2 33.2(4) . . ?
C1 Ge1 Pt1 124.15(15) . . ?
C1 Ge1 Pt2 123.38(15) . . ?
Pt1 Ge1 Pt2 73.364(19) . . ?
C1 Ge1 H1 110.4 . . ?
Pt1 Ge1 H1 110.4 . . ?
Pt2 Ge1 H1 110.4 . . ?
C22 P2 C35 106.5(3) . . ?
C22 P2 C41 103.2(3) . . ?
C35 P2 C41 106.9(3) . . ?
C22 P2 Pt2 106.55(18) . . ?
C35 P2 Pt2 117.78(18) . . ?
C41 P2 Pt2 114.61(17) . . ?
C47 P3 C55 104.3(3) . . ?
C47 P3 C49 106.3(3) . . ?
C55 P3 C49 106.5(3) . . ?
C47 P3 Pt1 107.79(18) . . ?
C55 P3 Pt1 117.86(18) . . ?
C49 P3 Pt1 113.19(18) . . ?
C23 P1 C21 102.5(3) . . ?
C23 P1 C29 106.1(3) . . ?
C21 P1 C29 106.3(2) . . ?
C23 P1 Pt2 117.58(17) . . ?
C21 P1 Pt2 107.43(18) . . ?
C29 P1 Pt2 115.64(18) . . ?
C48 P4 C61 103.3(3) . . ?
C48 P4 C67 103.4(2) . . ?
C61 P4 C67 104.1(3) . . ?
C48 P4 Pt1 106.95(19) . . ?
C61 P4 Pt1 119.46(17) . . ?
C67 P4 Pt1 117.64(19) . . ?
C72 C67 C68 110.0(5) . . ?
C72 C67 P4 115.1(4) . . ?
C68 C67 P4 110.2(4) . . ?
C72 C67 H101 107.0 . . ?
C68 C67 H101 107.0 . . ?
P4 C67 H101 107.0 . . ?
F2 C75 C76 119.2(7) . . ?
F2 C75 C74 121.3(6) . . ?
C76 C75 C74 119.5(6) . . ?
F13 C88 C87 122.1(6) . . ?
F13 C88 C89 119.2(7) . . ?
C87 C88 C89 118.8(6) . . ?
C3 C2 C7 118.2(5) . . ?
C3 C2 C1 127.0(5) . . ?
C7 C2 C1 114.8(5) . . ?
C23 C24 C25 110.1(5) . . ?
C23 C24 H21 109.6 . . ?
C25 C24 H21 109.6 . . ?
C23 C24 H22 109.6 . . ?
C25 C24 H22 109.6 . . ?
H21 C24 H22 108.1 . . ?
C40 C39 C38 111.1(5) . . ?
C40 C39 H49 109.4 . . ?
C38 C39 H49 109.4 . . ?
C40 C39 H50 109.4 . . ?
C38 C39 H50 109.4 . . ?
H49 C39 H50 108.0 . . ?
F4 C77 C76 120.0(7) . . ?
F4 C77 C78 120.7(6) . . ?
C76 C77 C78 119.3(7) . . ?
C60 C55 C56 108.6(5) . . ?
C60 C55 P3 112.6(4) . . ?
C56 C55 P3 115.4(4) . . ?
C60 C55 H79 106.6 . . ?
C56 C55 H79 106.6 . . ?
P3 C55 H79 106.6 . . ?
C54 C49 C50 110.7(5) . . ?
C54 C49 P3 117.9(4) . . ?
C50 C49 P3 109.6(4) . . ?
C54 C49 H68 105.9 . . ?
C50 C49 H68 105.9 . . ?
P3 C49 H68 105.9 . . ?
C29 C34 C33 111.9(5) . . ?
C29 C34 H40 109.2 . . ?
C33 C34 H40 109.2 . . ?
C29 C34 H41 109.2 . . ?
C33 C34 H41 109.2 . . ?
H40 C34 H41 107.9 . . ?
F1 C74 C75 116.6(6) . . ?
F1 C74 C73 119.0(6) . . ?
C75 C74 C73 124.4(6) . . ?
C51 C50 C49 109.6(5) . . ?
C51 C50 H69 109.8 . . ?
C49 C50 H69 109.8 . . ?
C51 C50 H70 109.8 . . ?
C49 C50 H70 109.8 . . ?
H69 C50 H70 108.2 . . ?
C66 C61 C62 109.2(4) . . ?
C66 C61 P4 111.9(4) . . ?
C62 C61 P4 112.2(4) . . ?
C66 C61 H90 107.8 . . ?
C62 C61 H90 107.8 . . ?
P4 C61 H90 107.8 . . ?
C64 C63 C62 111.4(5) . . ?
C64 C63 H93 109.3 . . ?
C62 C63 H93 109.3 . . ?
C64 C63 H94 109.3 . . ?
C62 C63 H94 109.3 . . ?
H93 C63 H94 108.0 . . ?
C24 C23 C28 110.8(5) . . ?
C24 C23 P1 112.0(4) . . ?
C28 C23 P1 114.5(4) . . ?
C24 C23 H20 106.3 . . ?
C28 C23 H20 106.3 . . ?
P1 C23 H20 106.3 . . ?
C78 C73 C74 112.7(6) . . ?
C78 C73 B1 127.5(6) . . ?
C74 C73 B1 119.6(6) . . ?
C23 C28 C27 110.0(5) . . ?
C23 C28 H29 109.7 . . ?
C27 C28 H29 109.7 . . ?
C23 C28 H30 109.7 . . ?
C27 C28 H30 109.7 . . ?
H29 C28 H30 108.2 . . ?
C27 C26 C25 111.4(5) . . ?
C27 C26 H25 109.3 . . ?
C25 C26 H25 109.3 . . ?
C27 C26 H26 109.3 . . ?
C25 C26 H26 109.3 . . ?
H25 C26 H26 108.0 . . ?
F15 C90 C89 115.5(6) . . ?
F15 C90 C85 119.5(6) . . ?
C89 C90 C85 124.9(6) . . ?
C61 C66 C65 111.5(5) . . ?
C61 C66 H99 109.3 . . ?
C65 C66 H99 109.3 . . ?
C61 C66 H100 109.3 . . ?
C65 C66 H100 109.3 . . ?
H99 C66 H100 108.0 . . ?
F14 C89 C88 120.7(6) . . ?
F14 C89 C90 121.0(6) . . ?
C88 C89 C90 118.3(6) . . ?
F3 C76 C75 121.3(7) . . ?
F3 C76 C77 119.6(7) . . ?
C75 C76 C77 119.1(7) . . ?
C9 C10 C11 120.6(6) . . ?
C9 C10 H8 119.7 . . ?
C11 C10 H8 119.7 . . ?
F7 C81 C82 120.2(6) . . ?
F7 C81 C80 120.5(6) . . ?
C82 C81 C80 119.3(7) . . ?
F11 C86 C87 116.3(6) . . ?
F11 C86 C85 120.3(6) . . ?
C87 C86 C85 123.4(6) . . ?
C10 C9 C8 120.3(6) . . ?
C10 C9 H7 119.9 . . ?
C8 C9 H7 119.9 . . ?
C9 C8 C13 118.6(5) . . ?
C9 C8 C1 126.6(5) . . ?
C13 C8 C1 114.2(5) . . ?
C48 C47 P3 113.7(4) . . ?
C48 C47 H64 108.8 . . ?
P3 C47 H64 108.8 . . ?
C48 C47 H65 108.8 . . ?
P3 C47 H65 108.8 . . ?
H64 C47 H65 107.7 . . ?
C61 C62 C63 109.8(5) . . ?
C61 C62 H91 109.7 . . ?
C63 C62 H91 109.7 . . ?
C61 C62 H92 109.7 . . ?
C63 C62 H92 109.7 . . ?
H91 C62 H92 108.2 . . ?
F10 C84 C79 119.7(6) . . ?
F10 C84 C83 115.2(6) . . ?
C79 C84 C83 125.1(6) . . ?
C64 C65 C66 110.6(5) . . ?
C64 C65 H97 109.5 . . ?
C66 C65 H97 109.5 . . ?
C64 C65 H98 109.5 . . ?
C66 C65 H98 109.5 . . ?
H97 C65 H98 108.1 . . ?
C57 C56 C55 110.4(5) . . ?
C57 C56 H80 109.6 . . ?
C55 C56 H80 109.6 . . ?
C57 C56 H81 109.6 . . ?
C55 C56 H81 109.6 . . ?
H80 C56 H81 108.1 . . ?
C38 C37 C36 110.8(5) . . ?
C38 C37 H45 109.5 . . ?
C36 C37 H45 109.5 . . ?
C38 C37 H46 109.5 . . ?
C36 C37 H46 109.5 . . ?
H45 C37 H46 108.1 . . ?
F5 C78 C73 120.1(6) . . ?
F5 C78 C77 115.0(6) . . ?
C73 C78 C77 125.0(6) . . ?
C2 C1 C8 107.5(4) . . ?
C2 C1 C14 106.3(4) . . ?
C8 C1 C14 97.8(4) . . ?
C2 C1 Ge1 110.8(4) . . ?
C8 C1 Ge1 115.2(4) . . ?
C14 C1 Ge1 118.0(4) . . ?
C86 C87 C88 121.1(6) . . ?
C86 C87 F12 121.5(6) . . ?
C88 C87 F12 117.4(6) . . ?
F6 C80 C81 115.8(6) . . ?
F6 C80 C79 120.0(6) . . ?
C81 C80 C79 124.2(6) . . ?
C31 C32 C33 112.0(5) . . ?
C31 C32 H36 109.2 . . ?
C33 C32 H36 109.2 . . ?
C31 C32 H37 109.2 . . ?
C33 C32 H37 109.2 . . ?
H36 C32 H37 107.9 . . ?
C42 C41 C46 109.9(5) . . ?
C42 C41 P2 108.6(4) . . ?
C46 C41 P2 116.6(4) . . ?
C42 C41 H53 107.1 . . ?
C46 C41 H53 107.1 . . ?
P2 C41 H53 107.1 . . ?
C55 C60 C59 109.1(7) . . ?
C55 C60 H88 109.9 . . ?
C59 C60 H88 109.9 . . ?
C55 C60 H89 109.9 . . ?
C59 C60 H89 109.9 . . ?
H88 C60 H89 108.3 . . ?
C86 C85 C90 113.5(6) . . ?
C86 C85 B1 123.3(6) . . ?
C90 C85 B1 123.2(5) . . ?
C22 C21 P1 111.0(4) . . ?
C22 C21 H16 109.4 . . ?
P1 C21 H16 109.4 . . ?
C22 C21 H17 109.4 . . ?
P1 C21 H17 109.4 . . ?
H16 C21 H17 108.0 . . ?
C57 C58 C59 111.4(7) . . ?
C57 C58 H84 109.3 . . ?
C59 C58 H84 109.3 . . ?
C57 C58 H85 109.3 . . ?
C59 C58 H85 109.3 . . ?
H84 C58 H85 108.0 . . ?
C18 C19 C14 120.0(6) . . ?
C18 C19 C20 127.0(6) . . ?
C14 C19 C20 112.9(5) . . ?
C83 C82 F8 120.9(7) . . ?
C83 C82 C81 119.2(6) . . ?
F8 C82 C81 119.9(7) . . ?
C44 C45 C46 111.2(5) . . ?
C44 C45 H60 109.4 . . ?
C46 C45 H60 109.4 . . ?
C44 C45 H61 109.4 . . ?
C46 C45 H61 109.4 . . ?
H60 C45 H61 108.0 . . ?
C41 C42 C43 111.8(5) . . ?
C41 C42 H54 109.2 . . ?
C43 C42 H54 109.2 . . ?
C41 C42 H55 109.2 . . ?
C43 C42 H55 109.2 . . ?
H54 C42 H55 107.9 . . ?
C52 C51 C50 111.1(6) . . ?
C52 C51 H71 109.4 . . ?
C50 C51 H71 109.4 . . ?
C52 C51 H72 109.4 . . ?
C50 C51 H72 109.4 . . ?
H71 C51 H72 108.0 . . ?
C34 C29 C30 110.0(5) . . ?
C34 C29 P1 114.0(4) . . ?
C30 C29 P1 114.1(4) . . ?
C34 C29 H31 106.0 . . ?
C30 C29 H31 106.0 . . ?
P1 C29 H31 106.0 . . ?
C21 C22 P2 110.8(4) . . ?
C21 C22 H18 109.5 . . ?
P2 C22 H18 109.5 . . ?
C21 C22 H19 109.5 . . ?
P2 C22 H19 109.5 . . ?
H18 C22 H19 108.1 . . ?
C51 C52 C53 110.7(5) . . ?
C51 C52 H73 109.5 . . ?
C53 C52 H73 109.5 . . ?
C51 C52 H74 109.5 . . ?
C53 C52 H74 109.5 . . ?
H73 C52 H74 108.1 . . ?
C26 C25 C24 110.3(5) . . ?
C26 C25 H23 109.6 . . ?
C24 C25 H23 109.6 . . ?
C26 C25 H24 109.6 . . ?
C24 C25 H24 109.6 . . ?
H23 C25 H24 108.1 . . ?
C15 C14 C19 119.2(5) . . ?
C15 C14 C1 126.6(5) . . ?
C19 C14 C1 113.7(5) . . ?
C63 C64 C65 111.1(5) . . ?
C63 C64 H95 109.4 . . ?
C65 C64 H95 109.4 . . ?
C63 C64 H96 109.4 . . ?
C65 C64 H96 109.4 . . ?
H95 C64 H96 108.0 . . ?
C32 C33 C34 110.9(5) . . ?
C32 C33 H38 109.5 . . ?
C34 C33 H38 109.5 . . ?
C32 C33 H39 109.5 . . ?
C34 C33 H39 109.5 . . ?
H38 C33 H39 108.0 . . ?
C41 C46 C45 110.4(5) . . ?
C41 C46 H62 109.6 . . ?
C45 C46 H62 109.6 . . ?
C41 C46 H63 109.6 . . ?
C45 C46 H63 109.6 . . ?
H62 C46 H63 108.1 . . ?
C26 C27 C28 111.0(5) . . ?
C26 C27 H27 109.4 . . ?
C28 C27 H27 109.4 . . ?
C26 C27 H28 109.4 . . ?
C28 C27 H28 109.4 . . ?
H27 C27 H28 108.0 . . ?
C12 C13 C8 120.3(5) . . ?
C12 C13 C20 126.0(6) . . ?
C8 C13 C20 113.3(5) . . ?
C37 C38 C39 111.0(5) . . ?
C37 C38 H47 109.4 . . ?
C39 C38 H47 109.4 . . ?
C37 C38 H48 109.4 . . ?
C39 C38 H48 109.4 . . ?
H47 C38 H48 108.0 . . ?
C14 C15 C16 119.4(6) . . ?
C14 C15 H11 120.3 . . ?
C16 C15 H11 120.3 . . ?
C37 C36 C35 112.5(5) . . ?
C37 C36 H43 109.1 . . ?
C35 C36 H43 109.1 . . ?
C37 C36 H44 109.1 . . ?
C35 C36 H44 109.1 . . ?
H43 C36 H44 107.8 . . ?
C18 C17 C16 120.4(6) . . ?
C18 C17 H13 119.8 . . ?
C16 C17 H13 119.8 . . ?
C31 C30 C29 110.7(5) . . ?
C31 C30 H32 109.5 . . ?
C29 C30 H32 109.5 . . ?
C31 C30 H33 109.5 . . ?
C29 C30 H33 109.5 . . ?
H32 C30 H33 108.1 . . ?
C49 C54 C53 109.9(6) . . ?
C49 C54 H77 109.7 . . ?
C53 C54 H77 109.7 . . ?
C49 C54 H78 109.7 . . ?
C53 C54 H78 109.7 . . ?
H77 C54 H78 108.2 . . ?
C84 C79 C80 112.6(6) . . ?
C84 C79 B1 127.9(6) . . ?
C80 C79 B1 119.6(6) . . ?
C17 C18 C19 120.1(6) . . ?
C17 C18 H14 119.9 . . ?
C19 C18 H14 119.9 . . ?
C11 C12 C13 120.4(6) . . ?
C11 C12 H10 119.8 . . ?
C13 C12 H10 119.8 . . ?
C45 C44 C43 111.3(5) . . ?
C45 C44 H58 109.4 . . ?
C43 C44 H58 109.4 . . ?
C45 C44 H59 109.4 . . ?
C43 C44 H59 109.4 . . ?
H58 C44 H59 108.0 . . ?
C58 C59 C60 110.3(6) . . ?
C58 C59 H86 109.6 . . ?
C60 C59 H86 109.6 . . ?
C58 C59 H87 109.6 . . ?
C60 C59 H87 109.6 . . ?
H86 C59 H87 108.1 . . ?
C52 C53 C54 111.0(6) . . ?
C52 C53 H75 109.4 . . ?
C54 C53 H75 109.4 . . ?
C52 C53 H76 109.4 . . ?
C54 C53 H76 109.4 . . ?
H75 C53 H76 108.0 . . ?
F9 C83 C82 120.3(6) . . ?
F9 C83 C84 120.2(6) . . ?
C82 C83 C84 119.5(7) . . ?
C12 C11 C10 119.5(6) . . ?
C12 C11 H9 120.3 . . ?
C10 C11 H9 120.3 . . ?
C58 C57 C56 110.1(6) . . ?
C58 C57 H82 109.6 . . ?
C56 C57 H82 109.6 . . ?
C58 C57 H83 109.6 . . ?
C56 C57 H83 109.6 . . ?
H82 C57 H83 108.2 . . ?
C35 C40 C39 113.4(5) . . ?
C35 C40 H51 108.9 . . ?
C39 C40 H51 108.9 . . ?
C35 C40 H52 108.9 . . ?
C39 C40 H52 108.9 . . ?
H51 C40 H52 107.7 . . ?
C47 C48 P4 111.5(3) . . ?
C47 C48 H66 109.3 . . ?
P4 C48 H66 109.3 . . ?
C47 C48 H67 109.3 . . ?
P4 C48 H67 109.3 . . ?
H66 C48 H67 108.0 . . ?
C32 C31 C30 112.0(5) . . ?
C32 C31 H34 109.2 . . ?
C30 C31 H34 109.2 . . ?
C32 C31 H35 109.2 . . ?
C30 C31 H35 109.2 . . ?
H34 C31 H35 107.9 . . ?
C17 C16 C15 120.6(6) . . ?
C17 C16 H12 119.7 . . ?
C15 C16 H12 119.7 . . ?
C44 C43 C42 111.6(5) . . ?
C44 C43 H56 109.3 . . ?
C42 C43 H56 109.3 . . ?
C44 C43 H57 109.3 . . ?
C42 C43 H57 109.3 . . ?
H56 C43 H57 108.0 . . ?
C40 C35 C36 110.3(5) . . ?
C40 C35 P2 117.2(4) . . ?
C36 C35 P2 109.8(4) . . ?
C40 C35 H42 106.3 . . ?
C36 C35 H42 106.3 . . ?
P2 C35 H42 106.3 . . ?
C85 B1 C79 109.7(5) . . ?
C85 B1 C73 113.0(5) . . ?
C79 B1 C73 112.7(5) . . ?
C85 B1 H112 103(2) . . ?
C79 B1 H112 107(2) . . ?
C73 B1 H112 110(2) . . ?
C69 C68 C67 112.0(5) . . ?
C69 C68 H102 109.2 . . ?
C67 C68 H102 109.2 . . ?
C69 C68 H103 109.2 . . ?
C67 C68 H103 109.2 . . ?
H102 C68 H103 107.9 . . ?
C67 C72 C71 113.1(5) . . ?
C67 C72 H110 109.0 . . ?
C71 C72 H110 109.0 . . ?
C67 C72 H111 109.0 . . ?
C71 C72 H111 109.0 . . ?
H110 C72 H111 107.8 . . ?
C2 C7 C6 121.0(6) . . ?
C2 C7 C20 113.2(5) . . ?
C6 C7 C20 125.8(6) . . ?
C2 C3 C4 120.7(6) . . ?
C2 C3 H3 119.7 . . ?
C4 C3 H3 119.7 . . ?
C70 C69 C68 111.4(5) . . ?
C70 C69 H104 109.4 . . ?
C68 C69 H104 109.4 . . ?
C70 C69 H105 109.4 . . ?
C68 C69 H105 109.4 . . ?
H104 C69 H105 108.0 . . ?
C5 C4 C3 121.3(6) . . ?
C5 C4 H4 119.4 . . ?
C3 C4 H4 119.4 . . ?
C69 C70 C71 111.3(5) . . ?
C69 C70 H106 109.4 . . ?
C71 C70 H106 109.4 . . ?
C69 C70 H107 109.4 . . ?
C71 C70 H107 109.4 . . ?
H106 C70 H107 108.0 . . ?
C5 C6 C7 119.3(6) . . ?
C5 C6 H6 120.4 . . ?
C7 C6 H6 120.4 . . ?
C13 C20 C7 107.2(5) . . ?
C13 C20 C19 103.1(5) . . ?
C7 C20 C19 107.0(5) . . ?
C13 C20 H15 113.0 . . ?
C7 C20 H15 113.0 . . ?
C19 C20 H15 113.0 . . ?
C4 C5 C6 119.6(6) . . ?
C4 C5 H5 120.2 . . ?
C6 C5 H5 120.2 . . ?
C70 C71 C72 110.1(6) . . ?
C70 C71 H108 109.6 . . ?
C72 C71 H108 109.6 . . ?
C70 C71 H109 109.6 . . ?
C72 C71 H109 109.6 . . ?
H108 C71 H109 108.1 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P3 Pt1 Pt2 P1 -11.24(12) . . . . ?
P4 Pt1 Pt2 P1 158.79(9) . . . . ?
Ge1 Pt1 Pt2 P1 -16.79(9) . . . . ?
P3 Pt1 Pt2 P2 173.99(9) . . . . ?
P4 Pt1 Pt2 P2 -15.98(6) . . . . ?
Ge1 Pt1 Pt2 P2 168.44(4) . . . . ?
P3 Pt1 Pt2 Ge1 5.55(9) . . . . ?
P4 Pt1 Pt2 Ge1 175.59(4) . . . . ?
P3 Pt1 Ge1 C1 -58.09(19) . . . . ?
P4 Pt1 Ge1 C1 94.7(3) . . . . ?
Pt2 Pt1 Ge1 C1 119.42(18) . . . . ?
P3 Pt1 Ge1 Pt2 -177.51(4) . . . . ?
P4 Pt1 Ge1 Pt2 -24.7(2) . . . . ?
P1 Pt2 Ge1 C1 52.23(19) . . . . ?
P2 Pt2 Ge1 C1 -174.6(2) . . . . ?
Pt1 Pt2 Ge1 C1 -120.32(18) . . . . ?
P1 Pt2 Ge1 Pt1 172.55(4) . . . . ?
P2 Pt2 Ge1 Pt1 -54.25(17) . . . . ?
P1 Pt2 P2 C22 8.2(2) . . . . ?
Ge1 Pt2 P2 C22 -126.1(2) . . . . ?
Pt1 Pt2 P2 C22 -174.10(19) . . . . ?
P1 Pt2 P2 C35 -111.2(2) . . . . ?
Ge1 Pt2 P2 C35 114.4(3) . . . . ?
Pt1 Pt2 P2 C35 66.5(2) . . . . ?
P1 Pt2 P2 C41 121.7(2) . . . . ?
Ge1 Pt2 P2 C41 -12.7(3) . . . . ?
Pt1 Pt2 P2 C41 -60.6(2) . . . . ?
P4 Pt1 P3 C47 7.39(19) . . . . ?
Ge1 Pt1 P3 C47 -176.88(19) . . . . ?
Pt2 Pt1 P3 C47 178.59(18) . . . . ?
P4 Pt1 P3 C55 125.0(3) . . . . ?
Ge1 Pt1 P3 C55 -59.3(3) . . . . ?
Pt2 Pt1 P3 C55 -63.8(3) . . . . ?
P4 Pt1 P3 C49 -109.9(2) . . . . ?
Ge1 Pt1 P3 C49 65.8(2) . . . . ?
Pt2 Pt1 P3 C49 61.3(2) . . . . ?
P2 Pt2 P1 C23 128.1(2) . . . . ?
Ge1 Pt2 P1 C23 -61.01(19) . . . . ?
Pt1 Pt2 P1 C23 -47.3(2) . . . . ?
P2 Pt2 P1 C21 13.3(2) . . . . ?
Ge1 Pt2 P1 C21 -175.8(2) . . . . ?
Pt1 Pt2 P1 C21 -162.15(19) . . . . ?
P2 Pt2 P1 C29 -105.3(2) . . . . ?
Ge1 Pt2 P1 C29 65.7(2) . . . . ?
Pt1 Pt2 P1 C29 79.3(2) . . . . ?
P3 Pt1 P4 C48 10.9(2) . . . . ?
Ge1 Pt1 P4 C48 -142.4(3) . . . . ?
Pt2 Pt1 P4 C48 -164.75(19) . . . . ?
P3 Pt1 P4 C61 -105.7(2) . . . . ?
Ge1 Pt1 P4 C61 100.9(3) . . . . ?
Pt2 Pt1 P4 C61 78.6(2) . . . . ?
P3 Pt1 P4 C67 126.5(2) . . . . ?
Ge1 Pt1 P4 C67 -26.8(3) . . . . ?
Pt2 Pt1 P4 C67 -49.1(2) . . . . ?
C48 P4 C67 C72 -53.6(5) . . . . ?
C61 P4 C67 C72 54.0(5) . . . . ?
Pt1 P4 C67 C72 -171.2(3) . . . . ?
C48 P4 C67 C68 71.5(4) . . . . ?
C61 P4 C67 C68 179.1(4) . . . . ?
Pt1 P4 C67 C68 -46.1(4) . . . . ?
C47 P3 C55 C60 93.2(5) . . . . ?
C49 P3 C55 C60 -154.6(5) . . . . ?
Pt1 P3 C55 C60 -26.3(6) . . . . ?
C47 P3 C55 C56 -32.2(6) . . . . ?
C49 P3 C55 C56 80.0(5) . . . . ?
Pt1 P3 C55 C56 -151.7(4) . . . . ?
C47 P3 C49 C54 68.0(5) . . . . ?
C55 P3 C49 C54 -42.8(5) . . . . ?
Pt1 P3 C49 C54 -173.9(4) . . . . ?
C47 P3 C49 C50 -59.9(5) . . . . ?
C55 P3 C49 C50 -170.7(4) . . . . ?
Pt1 P3 C49 C50 58.2(4) . . . . ?
F2 C75 C74 F1 0.2(9) . . . . ?
C76 C75 C74 F1 -179.8(5) . . . . ?
F2 C75 C74 C73 179.5(5) . . . . ?
C76 C75 C74 C73 -0.4(10) . . . . ?
C54 C49 C50 C51 57.1(7) . . . . ?
P3 C49 C50 C51 -171.1(5) . . . . ?
C48 P4 C61 C66 173.7(4) . . . . ?
C67 P4 C61 C66 66.0(4) . . . . ?
Pt1 P4 C61 C66 -67.8(4) . . . . ?
C48 P4 C61 C62 -63.1(4) . . . . ?
C67 P4 C61 C62 -170.9(4) . . . . ?
Pt1 P4 C61 C62 55.4(4) . . . . ?
C25 C24 C23 C28 -57.6(6) . . . . ?
C25 C24 C23 P1 173.1(4) . . . . ?
C21 P1 C23 C24 62.4(4) . . . . ?
C29 P1 C23 C24 173.7(4) . . . . ?
Pt2 P1 C23 C24 -55.1(4) . . . . ?
C21 P1 C23 C28 -64.9(4) . . . . ?
C29 P1 C23 C28 46.4(4) . . . . ?
Pt2 P1 C23 C28 177.6(3) . . . . ?
F1 C74 C73 C78 179.1(5) . . . . ?
C75 C74 C73 C78 -0.2(9) . . . . ?
F1 C74 C73 B1 -4.7(8) . . . . ?
C75 C74 C73 B1 175.9(6) . . . . ?
C24 C23 C28 C27 57.0(6) . . . . ?
P1 C23 C28 C27 -175.2(4) . . . . ?
C62 C61 C66 C65 58.9(6) . . . . ?
P4 C61 C66 C65 -176.3(4) . . . . ?
F13 C88 C89 F14 -0.4(9) . . . . ?
C87 C88 C89 F14 179.4(6) . . . . ?
F13 C88 C89 C90 -179.8(6) . . . . ?
C87 C88 C89 C90 0.1(10) . . . . ?
F15 C90 C89 F14 -1.2(9) . . . . ?
C85 C90 C89 F14 -178.7(6) . . . . ?
F15 C90 C89 C88 178.1(6) . . . . ?
C85 C90 C89 C88 0.7(10) . . . . ?
F2 C75 C76 F3 -0.5(10) . . . . ?
C74 C75 C76 F3 179.5(6) . . . . ?
F2 C75 C76 C77 -179.2(5) . . . . ?
C74 C75 C76 C77 0.7(10) . . . . ?
F4 C77 C76 F3 -0.1(9) . . . . ?
C78 C77 C76 F3 -179.2(6) . . . . ?
F4 C77 C76 C75 178.7(6) . . . . ?
C78 C77 C76 C75 -0.4(10) . . . . ?
C11 C10 C9 C8 2.1(8) . . . . ?
C10 C9 C8 C13 -5.4(8) . . . . ?
C10 C9 C8 C1 -176.4(5) . . . . ?
C55 P3 C47 C48 -155.2(4) . . . . ?
C49 P3 C47 C48 92.5(4) . . . . ?
Pt1 P3 C47 C48 -29.2(4) . . . . ?
C66 C61 C62 C63 -59.0(6) . . . . ?
P4 C61 C62 C63 176.4(4) . . . . ?
C64 C63 C62 C61 58.3(7) . . . . ?
C61 C66 C65 C64 -56.4(7) . . . . ?
C60 C55 C56 C57 61.2(8) . . . . ?
P3 C55 C56 C57 -171.4(5) . . . . ?
C74 C73 C78 F5 -178.9(5) . . . . ?
B1 C73 C78 F5 5.3(10) . . . . ?
C74 C73 C78 C77 0.5(10) . . . . ?
B1 C73 C78 C77 -175.3(6) . . . . ?
F4 C77 C78 F5 0.1(9) . . . . ?
C76 C77 C78 F5 179.2(6) . . . . ?
F4 C77 C78 C73 -179.3(6) . . . . ?
C76 C77 C78 C73 -0.2(11) . . . . ?
C3 C2 C1 C8 131.1(6) . . . . ?
C7 C2 C1 C8 -50.1(6) . . . . ?
C3 C2 C1 C14 -124.9(6) . . . . ?
C7 C2 C1 C14 53.8(6) . . . . ?
C3 C2 C1 Ge1 4.4(7) . . . . ?
C7 C2 C1 Ge1 -176.8(4) . . . . ?
C9 C8 C1 C2 -140.0(5) . . . . ?
C13 C8 C1 C2 48.7(6) . . . . ?
C9 C8 C1 C14 110.1(6) . . . . ?
C13 C8 C1 C14 -61.2(5) . . . . ?
C9 C8 C1 Ge1 -15.9(7) . . . . ?
C13 C8 C1 Ge1 172.7(4) . . . . ?
Pt1 Ge1 C1 C2 -45.1(4) . . . . ?
Pt2 Ge1 C1 C2 46.7(4) . . . . ?
Pt1 Ge1 C1 C8 -167.4(3) . . . . ?
Pt2 Ge1 C1 C8 -75.5(4) . . . . ?
Pt1 Ge1 C1 C14 77.7(4) . . . . ?
Pt2 Ge1 C1 C14 169.6(3) . . . . ?
F11 C86 C87 C88 -178.8(6) . . . . ?
C85 C86 C87 C88 1.6(11) . . . . ?
F11 C86 C87 F12 1.3(10) . . . . ?
C85 C86 C87 F12 -178.3(6) . . . . ?
F13 C88 C87 C86 178.7(6) . . . . ?
C89 C88 C87 C86 -1.2(10) . . . . ?
F13 C88 C87 F12 -1.4(10) . . . . ?
C89 C88 C87 F12 178.8(6) . . . . ?
F7 C81 C80 F6 0.9(8) . . . . ?
C82 C81 C80 F6 178.8(5) . . . . ?
F7 C81 C80 C79 -178.3(6) . . . . ?
C82 C81 C80 C79 -0.4(10) . . . . ?
C22 P2 C41 C42 89.0(4) . . . . ?
C35 P2 C41 C42 -158.9(4) . . . . ?
Pt2 P2 C41 C42 -26.4(4) . . . . ?
C22 P2 C41 C46 -35.8(5) . . . . ?
C35 P2 C41 C46 76.3(5) . . . . ?
Pt2 P2 C41 C46 -151.3(4) . . . . ?
C56 C55 C60 C59 -60.3(8) . . . . ?
P3 C55 C60 C59 170.7(6) . . . . ?
F11 C86 C85 C90 179.6(6) . . . . ?
C87 C86 C85 C90 -0.9(10) . . . . ?
F11 C86 C85 B1 0.4(10) . . . . ?
C87 C86 C85 B1 179.9(6) . . . . ?
F15 C90 C85 C86 -177.6(5) . . . . ?
C89 C90 C85 C86 -0.3(10) . . . . ?
F15 C90 C85 B1 1.6(10) . . . . ?
C89 C90 C85 B1 178.9(6) . . . . ?
C23 P1 C21 C22 -162.2(4) . . . . ?
C29 P1 C21 C22 86.7(4) . . . . ?
Pt2 P1 C21 C22 -37.7(4) . . . . ?
F7 C81 C82 C83 178.5(6) . . . . ?
C80 C81 C82 C83 0.6(10) . . . . ?
F7 C81 C82 F8 -1.0(10) . . . . ?
C80 C81 C82 F8 -178.9(5) . . . . ?
C46 C41 C42 C43 -55.1(7) . . . . ?
P2 C41 C42 C43 176.2(4) . . . . ?
C49 C50 C51 C52 -57.3(8) . . . . ?
C33 C34 C29 C30 58.0(6) . . . . ?
C33 C34 C29 P1 -172.4(4) . . . . ?
C23 P1 C29 C34 144.6(4) . . . . ?
C21 P1 C29 C34 -106.8(4) . . . . ?
Pt2 P1 C29 C34 12.3(5) . . . . ?
C23 P1 C29 C30 -87.9(5) . . . . ?
C21 P1 C29 C30 20.7(5) . . . . ?
Pt2 P1 C29 C30 139.8(4) . . . . ?
P1 C21 C22 P2 46.1(5) . . . . ?
C35 P2 C22 C21 93.3(4) . . . . ?
C41 P2 C22 C21 -154.3(4) . . . . ?
Pt2 P2 C22 C21 -33.2(4) . . . . ?
C50 C51 C52 C53 58.2(8) . . . . ?
C27 C26 C25 C24 -57.3(7) . . . . ?
C23 C24 C25 C26 57.1(7) . . . . ?
C18 C19 C14 C15 -5.7(8) . . . . ?
C20 C19 C14 C15 169.3(5) . . . . ?
C18 C19 C14 C1 -179.0(5) . . . . ?
C20 C19 C14 C1 -4.0(7) . . . . ?
C2 C1 C14 C15 137.1(6) . . . . ?
C8 C1 C14 C15 -112.0(6) . . . . ?
Ge1 C1 C14 C15 12.0(7) . . . . ?
C2 C1 C14 C19 -50.2(6) . . . . ?
C8 C1 C14 C19 60.7(5) . . . . ?
Ge1 C1 C14 C19 -175.3(4) . . . . ?
C62 C63 C64 C65 -55.7(8) . . . . ?
C66 C65 C64 C63 54.2(8) . . . . ?
C31 C32 C33 C34 53.0(8) . . . . ?
C29 C34 C33 C32 -56.2(7) . . . . ?
C42 C41 C46 C45 56.9(7) . . . . ?
P2 C41 C46 C45 -178.9(4) . . . . ?
C44 C45 C46 C41 -58.4(7) . . . . ?
C25 C26 C27 C28 57.1(7) . . . . ?
C23 C28 C27 C26 -56.5(6) . . . . ?
C9 C8 C13 C12 5.5(8) . . . . ?
C1 C8 C13 C12 177.6(5) . . . . ?
C9 C8 C13 C20 -167.9(5) . . . . ?
C1 C8 C13 C20 4.2(7) . . . . ?
C36 C37 C38 C39 57.7(7) . . . . ?
C40 C39 C38 C37 -57.1(7) . . . . ?
C19 C14 C15 C16 3.5(8) . . . . ?
C1 C14 C15 C16 175.9(5) . . . . ?
C38 C37 C36 C35 -55.6(7) . . . . ?
C34 C29 C30 C31 -56.7(7) . . . . ?
P1 C29 C30 C31 173.8(4) . . . . ?
C50 C49 C54 C53 -56.8(8) . . . . ?
P3 C49 C54 C53 175.9(5) . . . . ?
F10 C84 C79 C80 -177.7(5) . . . . ?
C83 C84 C79 C80 3.1(9) . . . . ?
F10 C84 C79 B1 2.8(10) . . . . ?
C83 C84 C79 B1 -176.4(6) . . . . ?
F6 C80 C79 C84 179.5(5) . . . . ?
C81 C80 C79 C84 -1.4(9) . . . . ?
F6 C80 C79 B1 -0.9(8) . . . . ?
C81 C80 C79 B1 178.2(5) . . . . ?
C16 C17 C18 C19 0.7(9) . . . . ?
C14 C19 C18 C17 3.6(9) . . . . ?
C20 C19 C18 C17 -170.6(6) . . . . ?
C8 C13 C12 C11 -2.3(8) . . . . ?
C20 C13 C12 C11 170.2(5) . . . . ?
C46 C45 C44 C43 56.6(7) . . . . ?
C57 C58 C59 C60 -56.6(12) . . . . ?
C55 C60 C59 C58 58.8(11) . . . . ?
C51 C52 C53 C54 -57.7(8) . . . . ?
C49 C54 C53 C52 57.2(8) . . . . ?
F8 C82 C83 F9 0.3(10) . . . . ?
C81 C82 C83 F9 -179.1(6) . . . . ?
F8 C82 C83 C84 -179.5(6) . . . . ?
C81 C82 C83 C84 1.0(10) . . . . ?
F10 C84 C83 F9 -2.2(9) . . . . ?
C79 C84 C83 F9 177.1(6) . . . . ?
F10 C84 C83 C82 177.7(6) . . . . ?
C79 C84 C83 C82 -3.1(11) . . . . ?
C13 C12 C11 C10 -1.1(9) . . . . ?
C9 C10 C11 C12 1.2(9) . . . . ?
C59 C58 C57 C56 56.6(10) . . . . ?
C55 C56 C57 C58 -58.6(8) . . . . ?
C38 C39 C40 C35 54.4(8) . . . . ?
P3 C47 C48 P4 39.5(5) . . . . ?
C61 P4 C48 C47 95.8(4) . . . . ?
C67 P4 C48 C47 -155.9(4) . . . . ?
Pt1 P4 C48 C47 -31.1(4) . . . . ?
C33 C32 C31 C30 -53.1(7) . . . . ?
C29 C30 C31 C32 54.6(7) . . . . ?
C18 C17 C16 C15 -2.9(9) . . . . ?
C14 C15 C16 C17 0.7(9) . . . . ?
C45 C44 C43 C42 -54.2(7) . . . . ?
C41 C42 C43 C44 53.8(7) . . . . ?
C39 C40 C35 C36 -51.2(7) . . . . ?
C39 C40 C35 P2 -177.8(5) . . . . ?
C37 C36 C35 C40 51.5(7) . . . . ?
C37 C36 C35 P2 -177.9(4) . . . . ?
C22 P2 C35 C40 63.7(5) . . . . ?
C41 P2 C35 C40 -46.1(5) . . . . ?
Pt2 P2 C35 C40 -176.9(4) . . . . ?
C22 P2 C35 C36 -63.1(4) . . . . ?
C41 P2 C35 C36 -172.9(4) . . . . ?
Pt2 P2 C35 C36 56.3(4) . . . . ?
C86 C85 B1 C79 -134.3(6) . . . . ?
C90 C85 B1 C79 46.6(9) . . . . ?
C86 C85 B1 C73 99.1(7) . . . . ?
C90 C85 B1 C73 -80.0(8) . . . . ?
C84 C79 B1 C85 -106.5(7) . . . . ?
C80 C79 B1 C85 74.1(7) . . . . ?
C84 C79 B1 C73 20.3(9) . . . . ?
C80 C79 B1 C73 -159.2(5) . . . . ?
C78 C73 B1 C85 -4.3(9) . . . . ?
C74 C73 B1 C85 -179.8(5) . . . . ?
C78 C73 B1 C79 -129.3(7) . . . . ?
C74 C73 B1 C79 55.2(7) . . . . ?
C72 C67 C68 C69 -51.9(6) . . . . ?
P4 C67 C68 C69 -179.9(4) . . . . ?
C68 C67 C72 C71 53.8(7) . . . . ?
P4 C67 C72 C71 179.1(4) . . . . ?
C3 C2 C7 C6 0.1(9) . . . . ?
C1 C2 C7 C6 -178.8(5) . . . . ?
C3 C2 C7 C20 177.2(5) . . . . ?
C1 C2 C7 C20 -1.6(7) . . . . ?
C7 C2 C3 C4 -0.9(9) . . . . ?
C1 C2 C3 C4 177.8(5) . . . . ?
C67 C68 C69 C70 54.2(7) . . . . ?
C2 C3 C4 C5 1.3(10) . . . . ?
C68 C69 C70 C71 -56.7(7) . . . . ?
C2 C7 C6 C5 0.4(9) . . . . ?
C20 C7 C6 C5 -176.3(6) . . . . ?
C12 C13 C20 C7 130.2(6) . . . . ?
C8 C13 C20 C7 -56.9(6) . . . . ?
C12 C13 C20 C19 -117.1(6) . . . . ?
C8 C13 C20 C19 55.9(6) . . . . ?
C2 C7 C20 C13 55.7(7) . . . . ?
C6 C7 C20 C13 -127.3(6) . . . . ?
C2 C7 C20 C19 -54.3(6) . . . . ?
C6 C7 C20 C19 122.7(6) . . . . ?
C18 C19 C20 C13 118.8(6) . . . . ?
C14 C19 C20 C13 -55.8(6) . . . . ?
C18 C19 C20 C7 -128.4(6) . . . . ?
C14 C19 C20 C7 57.1(6) . . . . ?
C3 C4 C5 C6 -0.7(10) . . . . ?
C7 C6 C5 C4 -0.1(10) . . . . ?
C69 C70 C71 C72 57.3(7) . . . . ?
C67 C72 C71 C70 -56.7(7) . . . . ?

_diffrn_measured_fraction_theta_max 0.979
_diffrn_reflns_theta_full        25.50
_diffrn_measured_fraction_theta_full 0.979
_refine_diff_density_max         2.185
_refine_diff_density_min         -1.678
_refine_diff_density_rms         0.134
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_naka137
_database_code_depnum_ccdc_archive 'CCDC 1055410'
_audit_update_record             
;
2015-03-23 deposited with the CCDC.
2015-05-12 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 'C72 H110 Cl Ge P4 Pd2, C18 H B F15, C6 H5 F' 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C72 H110 Cl Ge P4 Pd2, C18 H B F15, C6 H5 F '
_chemical_formula_sum            'C96 H116 B Cl F16 Ge P4 Pd2'
_chemical_formula_weight         2029.42

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'P n a 21'
_symmetry_space_group_name_Hall  'P 2c -2n'
_symmetry_Int_Tables_number      33

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z+1/2'
'-x+1/2, y+1/2, z+1/2'
'x+1/2, -y+1/2, z'

_cell_length_a                   24.942(3)
_cell_length_b                   32.139(4)
_cell_length_c                   11.1842(15)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     8966(2)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       prism
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.08
_exptl_crystal_density_meas      'not measured'
_exptl_crystal_density_diffrn    1.503
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             4168
_exptl_absorpt_coefficient_mu    0.911
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.9144
_exptl_absorpt_correction_T_max  0.9307
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1997)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'Bruker TXS fine-focus rotating anode'
_diffrn_radiation_monochromator  'Bruker Helios multilayered confocal mirror'
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean 8.333
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            43897
_diffrn_reflns_av_R_equivalents  0.0784
_diffrn_reflns_av_sigmaI/netI    0.0748
_diffrn_reflns_limit_h_min       -30
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       38
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_theta_min         1.03
_diffrn_reflns_theta_max         25.50
_reflns_number_total             15938
_reflns_number_gt                13945
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEX-II'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    
'Yadokari-XG 2009 (Wakita, Nemoto et al., 2009)'
_computing_publication_material  
'Yadokari-XG 2009 (Wakita, Nemoto et al., 2009)'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0804P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   -0.016(11)
_refine_ls_number_reflns         15938
_refine_ls_number_parameters     1149
_refine_ls_number_restraints     181
_refine_ls_R_factor_all          0.0599
_refine_ls_R_factor_gt           0.0537
_refine_ls_wR_factor_ref         0.1288
_refine_ls_wR_factor_gt          0.1258
_refine_ls_goodness_of_fit_ref   1.014
_refine_ls_restrained_S_all      1.010
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pd1 Pd 0.749014(14) 0.464557(11) 0.88544(4) 0.01275(10) Uani 1 1 d . . .
Pd2 Pd 0.756573(14) 0.554595(12) 0.90420(3) 0.01317(10) Uani 1 1 d . A .
Ge1 Ge 0.82864(2) 0.506295(16) 0.85766(5) 0.01168(12) Uani 1 1 d . . .
Cl1 Cl 0.85421(6) 0.50555(4) 0.66516(12) 0.0175(3) Uani 1 1 d . . .
P2 P 0.66337(5) 0.43546(4) 0.89326(14) 0.0166(3) Uani 1 1 d . . .
P3 P 0.79755(5) 0.61687(4) 0.86326(13) 0.0157(3) Uani 1 1 d . A .
P4 P 0.68345(6) 0.59394(5) 0.97857(14) 0.0190(3) Uani 1 1 d . . .
P1 P 0.78059(5) 0.39922(4) 0.83925(13) 0.0156(3) Uani 1 1 d . . .
F6 F 0.99399(12) 0.29057(9) 0.8853(3) 0.0248(7) Uani 1 1 d . . .
C47 C 0.7447(2) 0.65654(16) 0.8772(7) 0.0252(14) Uani 1 1 d . . .
H63 H 0.7613 0.6844 0.8858 0.030 Uiso 1 1 calc R A .
H64 H 0.7224 0.6567 0.8039 0.030 Uiso 1 1 calc R . .
F7 F 1.00725(14) 0.32643(10) 1.0997(3) 0.0304(8) Uani 1 1 d . . .
F13 F 0.81105(15) 0.24934(13) 0.5910(4) 0.0419(10) Uani 1 1 d . . .
F11 F 0.99775(14) 0.24054(14) 0.5794(4) 0.0412(10) Uani 1 1 d . . .
F10 F 1.05794(18) 0.16386(12) 1.0437(4) 0.0449(11) Uani 1 1 d . . .
F15 F 0.90306(15) 0.20197(13) 0.9297(3) 0.0396(10) Uani 1 1 d . . .
C2 C 0.8863(2) 0.50302(16) 1.0839(5) 0.0134(11) Uani 1 1 d . . .
F9 F 1.06935(17) 0.19977(14) 1.2573(4) 0.0487(11) Uani 1 1 d . . .
F16 F 0.83201(17) 0.23007(14) 1.2605(4) 0.0478(11) Uani 1 1 d . . .
C18 C 1.0246(2) 0.56683(17) 0.9966(5) 0.0171(12) Uani 1 1 d . . .
H13 H 1.0537 0.5665 1.0514 0.021 Uiso 1 1 calc R . .
C3 C 0.8362(2) 0.50359(17) 1.1376(5) 0.0174(12) Uani 1 1 d . . .
H2 H 0.8048 0.5043 1.0896 0.021 Uiso 1 1 calc R . .
F12 F 0.90631(16) 0.25867(15) 0.4732(4) 0.0509(12) Uani 1 1 d . . .
C19 C 0.9842(2) 0.53765(17) 1.0060(5) 0.0151(11) Uani 1 1 d . . .
C1 C 0.8995(2) 0.50329(16) 0.9479(5) 0.0120(11) Uani 1 1 d . . .
C15 C 0.9400(2) 0.56753(17) 0.8356(5) 0.0154(11) Uani 1 1 d . . .
H10 H 0.9116 0.5673 0.7789 0.018 Uiso 1 1 calc R . .
C23 C 0.8325(2) 0.37511(16) 0.9346(5) 0.0182(12) Uani 1 1 d . . .
H19 H 0.8677 0.3814 0.8957 0.022 Uiso 1 1 calc R . .
C61 C 0.6616(2) 0.58166(18) 1.1336(5) 0.0205(13) Uani 1 1 d . A .
H89 H 0.6341 0.5592 1.1266 0.025 Uiso 1 1 calc R . .
C24 C 0.8339(2) 0.39635(19) 1.0580(5) 0.0222(13) Uani 1 1 d . . .
H20 H 0.8371 0.4268 1.0476 0.027 Uiso 1 1 calc R . .
H21 H 0.8001 0.3906 1.1012 0.027 Uiso 1 1 calc R . .
F8 F 1.04338(16) 0.28194(14) 1.2887(3) 0.0427(10) Uani 1 1 d . . .
C56 C 0.8510(2) 0.61370(18) 1.0837(5) 0.0207(12) Uani 1 1 d . A .
H79 H 0.8192 0.6230 1.1295 0.025 Uiso 1 1 calc R . .
H80 H 0.8481 0.5833 1.0719 0.025 Uiso 1 1 calc R . .
C20 C 0.9842(2) 0.50063(17) 1.0892(5) 0.0150(11) Uani 1 1 d . . .
H14 H 1.0163 0.4997 1.1425 0.018 Uiso 1 1 calc R . .
C6 C 0.9274(2) 0.50184(17) 1.2803(5) 0.0181(12) Uani 1 1 d . . .
H5 H 0.9587 0.5015 1.3287 0.022 Uiso 1 1 calc R . .
C34 C 0.7603(2) 0.4148(2) 0.5993(6) 0.0253(13) Uani 1 1 d . . .
H39 H 0.7273 0.3976 0.6018 0.030 Uiso 1 1 calc R . .
H40 H 0.7511 0.4430 0.6282 0.030 Uiso 1 1 calc R . .
C11 C 1.0117(2) 0.40121(16) 0.9075(5) 0.0186(11) Uani 1 1 d . . .
H8 H 1.0364 0.3788 0.9026 0.022 Uiso 1 1 calc R . .
C7 C 0.9318(2) 0.50168(16) 1.1575(5) 0.0142(11) Uani 1 1 d . . .
C12 C 1.0172(2) 0.43106(18) 0.9973(5) 0.0179(12) Uani 1 1 d . . .
H9 H 1.0463 0.4295 1.0518 0.022 Uiso 1 1 calc R . .
C9 C 0.9327(2) 0.43580(17) 0.8344(5) 0.0146(11) Uani 1 1 d . . .
H6 H 0.9045 0.4376 0.7774 0.018 Uiso 1 1 calc R . .
C13 C 0.9800(2) 0.46293(16) 1.0065(5) 0.0138(11) Uani 1 1 d . . .
C17 C 1.0226(2) 0.59663(17) 0.9070(5) 0.0204(12) Uani 1 1 d . . .
H12 H 1.0500 0.6171 0.9017 0.025 Uiso 1 1 calc R . .
C16 C 0.9808(2) 0.59672(17) 0.8250(5) 0.0186(12) Uani 1 1 d . . .
H11 H 0.9801 0.6166 0.7622 0.022 Uiso 1 1 calc R . .
C14 C 0.9402(2) 0.53884(15) 0.9277(5) 0.0115(10) Uani 1 1 d . . .
C41 C 0.6112(2) 0.46007(19) 0.8003(6) 0.0249(13) Uani 1 1 d . . .
H52 H 0.6023 0.4874 0.8380 0.030 Uiso 1 1 calc R . .
C10 C 0.9703(2) 0.40436(17) 0.8258(5) 0.0178(12) Uani 1 1 d . . .
H7 H 0.9677 0.3846 0.7628 0.021 Uiso 1 1 calc R . .
C96 C 0.7527(3) 0.2682(2) 1.2787(7) 0.0361(17) Uani 1 1 d . . .
H115 H 0.7605 0.2736 1.3603 0.043 Uiso 1 1 calc R . .
C55 C 0.8521(2) 0.63551(17) 0.9620(5) 0.0177(12) Uani 1 1 d . . .
H78 H 0.8863 0.6268 0.9229 0.021 Uiso 1 1 calc R A .
C49 C 0.8214(2) 0.62174(18) 0.7085(5) 0.0190(12) Uani 1 1 d . . .
H67 H 0.8540 0.6037 0.7032 0.023 Uiso 1 1 calc R A .
C8 C 0.93580(19) 0.46487(15) 0.9265(5) 0.0120(11) Uani 1 1 d . . .
C81 C 1.0176(2) 0.28605(19) 1.0859(6) 0.0238(13) Uani 1 1 d . . .
C83 C 1.0488(3) 0.2223(2) 1.1658(6) 0.0322(15) Uani 1 1 d . . .
C40 C 0.6175(3) 0.46853(19) 1.1011(6) 0.0249(14) Uani 1 1 d . . .
H50 H 0.5911 0.4834 1.0509 0.030 Uiso 1 1 calc R . .
H51 H 0.6497 0.4863 1.1088 0.030 Uiso 1 1 calc R . .
C50 C 0.8395(2) 0.66502(19) 0.6694(6) 0.0235(13) Uani 1 1 d . A .
H68 H 0.8684 0.6748 0.7234 0.028 Uiso 1 1 calc R . .
H69 H 0.8091 0.6846 0.6764 0.028 Uiso 1 1 calc R . .
C80 C 1.0102(2) 0.26616(18) 0.9773(5) 0.0192(12) Uani 1 1 d . . .
C63 C 0.6891(2) 0.54986(19) 1.3310(6) 0.0274(14) Uani 1 1 d . A .
H92 H 0.6633 0.5267 1.3231 0.033 Uiso 1 1 calc R . .
H93 H 0.7202 0.5396 1.3775 0.033 Uiso 1 1 calc R . .
C4 C 0.8320(2) 0.50316(17) 1.2607(6) 0.0200(13) Uani 1 1 d . . .
H3 H 0.7975 0.5033 1.2965 0.024 Uiso 1 1 calc R . .
C29 C 0.8028(2) 0.39544(18) 0.6823(5) 0.0204(12) Uani 1 1 d . . .
H30 H 0.8353 0.4136 0.6755 0.024 Uiso 1 1 calc R . .
C58 C 0.9099(3) 0.6698(2) 1.1694(6) 0.0280(14) Uani 1 1 d . A .
H83 H 0.9449 0.6749 1.2086 0.034 Uiso 1 1 calc R . .
H84 H 0.8814 0.6811 1.2217 0.034 Uiso 1 1 calc R . .
C5 C 0.8771(2) 0.50254(17) 1.3328(5) 0.0211(13) Uani 1 1 d . . .
H4 H 0.8735 0.5026 1.4173 0.025 Uiso 1 1 calc R . .
C86 C 0.9530(2) 0.23452(19) 0.6446(6) 0.0290(14) Uani 1 1 d . . .
C36 C 0.6711(3) 0.40268(19) 1.1209(5) 0.0265(14) Uani 1 1 d . . .
H42 H 0.6786 0.3754 1.0832 0.032 Uiso 1 1 calc R . .
H43 H 0.7054 0.4179 1.1282 0.032 Uiso 1 1 calc R . .
C64 C 0.6629(2) 0.58529(19) 1.3980(6) 0.0298(14) Uani 1 1 d . . .
H94 H 0.6895 0.6075 1.4132 0.036 Uiso 1 1 calc R . .
H95 H 0.6495 0.5752 1.4762 0.036 Uiso 1 1 calc R . .
C88 C 0.8574(2) 0.2404(2) 0.6459(7) 0.0306(15) Uani 1 1 d . . .
C42 C 0.5587(2) 0.4348(2) 0.7937(7) 0.0333(16) Uani 1 1 d . . .
H53 H 0.5664 0.4066 0.7625 0.040 Uiso 1 1 calc R . .
H54 H 0.5434 0.4318 0.8749 0.040 Uiso 1 1 calc R . .
C27 C 0.8780(3) 0.3126(2) 1.0226(6) 0.0285(15) Uani 1 1 d . . .
H26 H 0.8757 0.2821 1.0332 0.034 Uiso 1 1 calc R . .
H27 H 0.9115 0.3189 0.9790 0.034 Uiso 1 1 calc R . .
C94 C 0.6957(3) 0.2754(2) 1.1050(7) 0.0334(16) Uani 1 1 d . . .
H113 H 0.6638 0.2859 1.0692 0.040 Uiso 1 1 calc R . .
C60 C 0.8564(2) 0.68248(18) 0.9812(5) 0.0220(13) Uani 1 1 d . A .
H87 H 0.8253 0.6925 1.0278 0.026 Uiso 1 1 calc R . .
H88 H 0.8565 0.6969 0.9030 0.026 Uiso 1 1 calc R . .
C21 C 0.7235(2) 0.36306(15) 0.8532(5) 0.0165(11) Uani 1 1 d . . .
H15 H 0.7287 0.3399 0.7961 0.020 Uiso 1 1 calc R . .
H16 H 0.7236 0.3511 0.9348 0.020 Uiso 1 1 calc R . .
C51 C 0.8601(3) 0.6651(2) 0.5401(5) 0.0270(14) Uani 1 1 d . . .
H70 H 0.8674 0.6941 0.5152 0.032 Uiso 1 1 calc R A .
H71 H 0.8943 0.6495 0.5363 0.032 Uiso 1 1 calc R . .
C85 C 0.9562(2) 0.21925(17) 0.7607(6) 0.0224(13) Uani 1 1 d . . .
C52 C 0.8202(3) 0.6457(2) 0.4539(6) 0.0280(14) Uani 1 1 d . A .
H72 H 0.7877 0.6632 0.4496 0.034 Uiso 1 1 calc R . .
H73 H 0.8362 0.6444 0.3730 0.034 Uiso 1 1 calc R . .
C62 C 0.7081(2) 0.56320(19) 1.2059(5) 0.0238(13) Uani 1 1 d . . .
H90 H 0.7370 0.5842 1.2137 0.029 Uiso 1 1 calc R A .
H91 H 0.7229 0.5388 1.1631 0.029 Uiso 1 1 calc R . .
C82 C 1.0360(2) 0.2627(2) 1.1822(6) 0.0300(15) Uani 1 1 d . . .
C45 C 0.5909(3) 0.4905(2) 0.5959(7) 0.0414(19) Uani 1 1 d . . .
H59 H 0.5828 0.5184 0.6287 0.050 Uiso 1 1 calc R . .
H60 H 0.6054 0.4941 0.5142 0.050 Uiso 1 1 calc R . .
C35 C 0.6328(2) 0.42748(18) 1.0409(5) 0.0224(13) Uani 1 1 d . . .
H41 H 0.5994 0.4107 1.0299 0.027 Uiso 1 1 calc R . .
C67 C 0.6213(6) 0.5955(5) 0.8844(11) 0.030(3) Uani 0.646(10) 1 d PDU A 1
H100 H 0.6133 0.5656 0.8666 0.037 Uiso 0.646(10) 1 calc PR A 1
C22 C 0.6691(2) 0.38254(17) 0.8303(5) 0.0185(12) Uani 1 1 d . . .
H17 H 0.6409 0.3647 0.8658 0.022 Uiso 1 1 calc R . .
H18 H 0.6627 0.3838 0.7430 0.022 Uiso 1 1 calc R . .
C39 C 0.5935(3) 0.4607(2) 1.2254(6) 0.0331(16) Uani 1 1 d . . .
H48 H 0.5853 0.4876 1.2640 0.040 Uiso 1 1 calc R . .
H49 H 0.5595 0.4450 1.2169 0.040 Uiso 1 1 calc R . .
C90 C 0.9060(3) 0.21639(19) 0.8155(6) 0.0275(14) Uani 1 1 d . . .
C84 C 1.0415(3) 0.2043(2) 1.0553(6) 0.0287(15) Uani 1 1 d . . .
C87 C 0.9061(3) 0.2444(2) 0.5872(6) 0.0338(16) Uani 1 1 d . . .
C91 C 0.7864(3) 0.2456(2) 1.2096(7) 0.0332(16) Uani 1 1 d . . .
C38 C 0.6316(3) 0.4363(2) 1.3035(6) 0.0331(16) Uani 1 1 d . . .
H46 H 0.6143 0.4306 1.3815 0.040 Uiso 1 1 calc R . .
H47 H 0.6641 0.4532 1.3185 0.040 Uiso 1 1 calc R . .
C57 C 0.9017(2) 0.62353(19) 1.1542(6) 0.0257(14) Uani 1 1 d . . .
H81 H 0.8994 0.6103 1.2340 0.031 Uiso 1 1 calc R A .
H82 H 0.9331 0.6116 1.1122 0.031 Uiso 1 1 calc R . .
C30 C 0.8197(3) 0.3527(2) 0.6371(6) 0.0288(15) Uani 1 1 d . . .
H31 H 0.7891 0.3332 0.6428 0.035 Uiso 1 1 calc R . .
H32 H 0.8491 0.3417 0.6875 0.035 Uiso 1 1 calc R . .
C25 C 0.8815(2) 0.3803(2) 1.1318(6) 0.0268(14) Uani 1 1 d . . .
H22 H 0.9154 0.3884 1.0921 0.032 Uiso 1 1 calc R . .
H23 H 0.8808 0.3934 1.2120 0.032 Uiso 1 1 calc R . .
C37 C 0.6476(3) 0.3956(2) 1.2458(6) 0.0325(16) Uani 1 1 d . . .
H44 H 0.6157 0.3773 1.2397 0.039 Uiso 1 1 calc R . .
H45 H 0.6744 0.3814 1.2966 0.039 Uiso 1 1 calc R . .
C92 C 0.7777(3) 0.2368(2) 1.0911(6) 0.0322(16) Uani 1 1 d . . .
H111 H 0.8024 0.2204 1.0467 0.039 Uiso 1 1 calc R . .
C54 C 0.7809(2) 0.60309(19) 0.6188(5) 0.0235(13) Uani 1 1 d . A .
H76 H 0.7713 0.5745 0.6437 0.028 Uiso 1 1 calc R . .
H77 H 0.7477 0.6200 0.6185 0.028 Uiso 1 1 calc R . .
C79 C 1.0205(2) 0.22465(18) 0.9574(5) 0.0211(13) Uani 1 1 d . . .
C59 C 0.9085(3) 0.69207(19) 1.0488(6) 0.0267(14) Uani 1 1 d . . .
H85 H 0.9396 0.6831 1.0001 0.032 Uiso 1 1 calc R A .
H86 H 0.9115 0.7225 1.0617 0.032 Uiso 1 1 calc R . .
C32 C 0.7968(3) 0.3749(2) 0.4253(6) 0.0374(17) Uani 1 1 d . . .
H35 H 0.8116 0.3774 0.3435 0.045 Uiso 1 1 calc R . .
H36 H 0.7648 0.3567 0.4216 0.045 Uiso 1 1 calc R . .
C53 C 0.8048(2) 0.6022(2) 0.4939(6) 0.0280(14) Uani 1 1 d . . .
H74 H 0.8369 0.5841 0.4934 0.034 Uiso 1 1 calc R A .
H75 H 0.7783 0.5904 0.4373 0.034 Uiso 1 1 calc R . .
C46 C 0.6327(2) 0.4693(2) 0.6741(6) 0.0259(14) Uani 1 1 d . . .
H61 H 0.6647 0.4874 0.6803 0.031 Uiso 1 1 calc R . .
H62 H 0.6438 0.4429 0.6359 0.031 Uiso 1 1 calc R . .
C28 C 0.8301(2) 0.32750(18) 0.9489(6) 0.0252(14) Uani 1 1 d . . .
H28 H 0.7963 0.3196 0.9894 0.030 Uiso 1 1 calc R . .
H29 H 0.8307 0.3141 0.8692 0.030 Uiso 1 1 calc R . .
C31 C 0.8385(3) 0.3555(2) 0.5069(7) 0.0407(19) Uani 1 1 d . . .
H33 H 0.8717 0.3723 0.5035 0.049 Uiso 1 1 calc R . .
H34 H 0.8471 0.3272 0.4776 0.049 Uiso 1 1 calc R . .
C48 C 0.7095(2) 0.64767(18) 0.9850(6) 0.0290(15) Uani 1 1 d . A .
H65 H 0.6791 0.6675 0.9866 0.035 Uiso 1 1 calc R . .
H66 H 0.7305 0.6515 1.0592 0.035 Uiso 1 1 calc R . .
C33 C 0.7805(3) 0.4175(2) 0.4702(6) 0.0344(16) Uani 1 1 d . . .
H37 H 0.7518 0.4289 0.4184 0.041 Uiso 1 1 calc R . .
H38 H 0.8116 0.4366 0.4662 0.041 Uiso 1 1 calc R . .
C66 C 0.6351(3) 0.6172(2) 1.2023(6) 0.0407(19) Uani 1 1 d . . .
H98 H 0.6610 0.6403 1.2118 0.049 Uiso 1 1 calc R A .
H99 H 0.6041 0.6277 1.1560 0.049 Uiso 1 1 calc R . .
C95 C 0.7062(3) 0.2832(2) 1.2253(7) 0.0379(17) Uani 1 1 d . . .
H114 H 0.6814 0.2989 1.2713 0.046 Uiso 1 1 calc R . .
B1 B 1.0092(3) 0.2001(2) 0.8319(6) 0.0225(15) Uani 1 1 d . . .
H123 H 0.9998 0.1660 0.8553 0.027 Uiso 1 1 calc R . .
C26 C 0.8794(2) 0.3336(2) 1.1451(6) 0.0287(15) Uani 1 1 d . . .
H24 H 0.8471 0.3256 1.1912 0.034 Uiso 1 1 calc R . .
H25 H 0.9114 0.3239 1.1898 0.034 Uiso 1 1 calc R . .
C65 C 0.6161(3) 0.6030(3) 1.3249(6) 0.0414(19) Uani 1 1 d . A .
H96 H 0.5881 0.5814 1.3154 0.050 Uiso 1 1 calc R . .
H97 H 0.6000 0.6268 1.3681 0.050 Uiso 1 1 calc R . .
C44 C 0.5397(3) 0.4650(3) 0.5905(7) 0.048(2) Uani 1 1 d . . .
H57 H 0.5126 0.4801 0.5426 0.058 Uiso 1 1 calc R . .
H58 H 0.5472 0.4382 0.5499 0.058 Uiso 1 1 calc R . .
C43 C 0.5175(3) 0.4565(3) 0.7117(8) 0.052(2) Uani 1 1 d . . .
H55 H 0.4853 0.4387 0.7041 0.062 Uiso 1 1 calc R . .
H56 H 0.5064 0.4831 0.7488 0.062 Uiso 1 1 calc R . .
C70 C 0.5327(4) 0.6307(4) 0.7402(10) 0.041(3) Uani 0.646(10) 1 d PDU A 1
H105 H 0.5010 0.6277 0.6876 0.050 Uiso 0.646(10) 1 calc PR A 1
H106 H 0.5382 0.6606 0.7564 0.050 Uiso 0.646(10) 1 calc PR A 1
C71 C 0.5816(4) 0.6129(5) 0.6788(10) 0.043(3) Uani 0.646(10) 1 d PDU A 1
H107 H 0.5887 0.6286 0.6043 0.052 Uiso 0.646(10) 1 calc PR A 1
H108 H 0.5748 0.5835 0.6571 0.052 Uiso 0.646(10) 1 calc PR A 1
C72 C 0.6306(4) 0.6155(5) 0.7610(9) 0.039(3) Uani 0.646(10) 1 d PDU A 1
H109 H 0.6404 0.6451 0.7723 0.047 Uiso 0.646(10) 1 calc PR A 1
H110 H 0.6612 0.6014 0.7217 0.047 Uiso 0.646(10) 1 calc PR A 1
C69 C 0.5230(4) 0.6076(4) 0.8574(9) 0.044(3) Uani 0.646(10) 1 d PDU A 1
H103 H 0.4904 0.6187 0.8964 0.052 Uiso 0.646(10) 1 calc PR A 1
H104 H 0.5168 0.5777 0.8404 0.052 Uiso 0.646(10) 1 calc PR A 1
C68 C 0.5705(3) 0.6119(4) 0.9425(9) 0.039(3) Uani 0.646(10) 1 d PDU A 1
H101 H 0.5754 0.6415 0.9639 0.047 Uiso 0.646(10) 1 calc PR A 1
H102 H 0.5633 0.5962 1.0168 0.047 Uiso 0.646(10) 1 calc PR A 1
F1 F 1.11653(13) 0.24781(11) 0.8570(3) 0.0318(8) Uani 1 1 d . . .
F5 F 1.01990(17) 0.15182(12) 0.6181(3) 0.0387(10) Uani 1 1 d . . .
F14 F 0.81122(15) 0.22084(14) 0.8194(4) 0.0479(11) Uani 1 1 d . . .
F2 F 1.19942(16) 0.24140(14) 0.7108(4) 0.0469(11) Uani 1 1 d . . .
F4 F 1.1044(2) 0.14573(15) 0.4724(4) 0.0581(13) Uani 1 1 d . . .
F3 F 1.19484(18) 0.19119(16) 0.5157(4) 0.0583(14) Uani 1 1 d . . .
C73 C 1.0632(3) 0.20008(18) 0.7453(5) 0.0218(13) Uani 1 1 d . . .
C74 C 1.1101(3) 0.2214(2) 0.7633(5) 0.0257(14) Uani 1 1 d . . .
C77 C 1.1074(3) 0.1710(2) 0.5684(6) 0.0395(19) Uani 1 1 d . . .
C76 C 1.1526(3) 0.1942(3) 0.5913(6) 0.0400(19) Uani 1 1 d . . .
C75 C 1.1544(3) 0.2192(2) 0.6884(6) 0.0317(16) Uani 1 1 d . . .
C78 C 1.0639(3) 0.1747(2) 0.6454(6) 0.0320(16) Uani 1 1 d . . .
C89 C 0.8580(2) 0.2260(2) 0.7616(7) 0.0319(16) Uani 1 1 d . . .
C93 C 0.7315(3) 0.2525(2) 1.0382(6) 0.0322(15) Uani 1 1 d . . .
H112 H 0.7246 0.2475 0.9559 0.039 Uiso 1 1 calc R . .
C102 C 0.5954(6) 0.6453(6) 0.9161(17) 0.039(4) Uani 0.354(10) 1 d PDU A 2
H126 H 0.5908 0.6526 1.0015 0.046 Uiso 0.354(10) 1 calc PR A 2
H127 H 0.6207 0.6654 0.8799 0.046 Uiso 0.354(10) 1 calc PR A 2
C101 C 0.5411(6) 0.6476(7) 0.8516(14) 0.040(4) Uani 0.354(10) 1 d PDU A 2
H124 H 0.5159 0.6269 0.8856 0.048 Uiso 0.354(10) 1 calc PR A 2
H125 H 0.5253 0.6757 0.8607 0.048 Uiso 0.354(10) 1 calc PR A 2
C98 C 0.6248(7) 0.5914(8) 0.7716(16) 0.032(4) Uani 0.354(10) 1 d PDU A 2
H117 H 0.6408 0.5635 0.7613 0.038 Uiso 0.354(10) 1 calc PR A 2
H118 H 0.6492 0.6121 0.7349 0.038 Uiso 0.354(10) 1 calc PR A 2
C99 C 0.5697(8) 0.5931(6) 0.7096(19) 0.040(4) Uani 0.354(10) 1 d PDU A 2
H119 H 0.5728 0.5848 0.6247 0.048 Uiso 0.354(10) 1 calc PR A 2
H120 H 0.5440 0.5743 0.7499 0.048 Uiso 0.354(10) 1 calc PR A 2
C97 C 0.6178(15) 0.6009(8) 0.9050(18) 0.030(4) Uani 0.354(10) 1 d PDU A 2
H116 H 0.5915 0.5809 0.9401 0.036 Uiso 0.354(10) 1 calc PR A 2
C100 C 0.5514(10) 0.6382(6) 0.7199(15) 0.039(4) Uani 0.354(10) 1 d PDU A 2
H121 H 0.5183 0.6426 0.6729 0.046 Uiso 0.354(10) 1 calc PR A 2
H122 H 0.5795 0.6570 0.6883 0.046 Uiso 0.354(10) 1 calc PR A 2
H1 H 0.715(2) 0.5147(16) 0.930(5) 0.015(15) Uiso 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pd1 P1 2.3014(14) . ?
Pd1 P2 2.3336(13) . ?
Pd1 Ge1 2.4166(7) . ?
Pd1 Pd2 2.9075(6) . ?
Pd1 H1 1.89(5) . ?
Pd2 P3 2.2936(14) . ?
Pd2 P4 2.3700(15) . ?
Pd2 Ge1 2.4314(7) . ?
Pd2 H1 1.67(5) . ?
Ge1 C1 2.037(5) . ?
Ge1 Cl1 2.2456(15) . ?
P2 C35 1.837(6) . ?
P2 C41 1.844(6) . ?
P2 C22 1.846(6) . ?
P3 C49 1.837(6) . ?
P3 C47 1.841(6) . ?
P3 C55 1.852(6) . ?
P4 C48 1.846(6) . ?
P4 C97 1.85(3) . ?
P4 C61 1.860(6) . ?
P4 C67 1.874(17) . ?
P1 C29 1.845(6) . ?
P1 C21 1.845(5) . ?
P1 C23 1.848(6) . ?
F6 C80 1.355(6) . ?
C47 C48 1.518(9) . ?
C47 H63 0.9900 . ?
C47 H64 0.9900 . ?
F7 C81 1.332(7) . ?
F13 C88 1.341(7) . ?
F11 C86 1.348(7) . ?
F10 C84 1.369(7) . ?
F15 C90 1.361(8) . ?
C2 C3 1.387(8) . ?
C2 C7 1.402(8) . ?
C2 C1 1.556(7) . ?
F9 C83 1.355(7) . ?
F16 C91 1.366(8) . ?
C18 C19 1.380(8) . ?
C18 C17 1.387(8) . ?
C18 H13 0.9500 . ?
C3 C4 1.381(9) . ?
C3 H2 0.9500 . ?
F12 C87 1.355(8) . ?
C19 C14 1.405(7) . ?
C19 C20 1.510(8) . ?
C1 C14 1.545(7) . ?
C1 C8 1.550(7) . ?
C15 C14 1.383(7) . ?
C15 C16 1.389(8) . ?
C15 H10 0.9500 . ?
C23 C28 1.540(8) . ?
C23 C24 1.541(8) . ?
C23 H19 1.0000 . ?
C61 C66 1.527(8) . ?
C61 C62 1.533(8) . ?
C61 H89 1.0000 . ?
C24 C25 1.533(8) . ?
C24 H20 0.9900 . ?
C24 H21 0.9900 . ?
F8 C82 1.355(7) . ?
C56 C57 1.524(8) . ?
C56 C55 1.531(8) . ?
C56 H79 0.9900 . ?
C56 H80 0.9900 . ?
C20 C7 1.514(8) . ?
C20 C13 1.527(8) . ?
C20 H14 1.0000 . ?
C6 C7 1.377(8) . ?
C6 C5 1.386(8) . ?
C6 H5 0.9500 . ?
C34 C33 1.532(9) . ?
C34 C29 1.540(8) . ?
C34 H39 0.9900 . ?
C34 H40 0.9900 . ?
C11 C10 1.382(8) . ?
C11 C12 1.395(8) . ?
C11 H8 0.9500 . ?
C12 C13 1.385(8) . ?
C12 H9 0.9500 . ?
C9 C10 1.383(8) . ?
C9 C8 1.392(7) . ?
C9 H6 0.9500 . ?
C13 C8 1.422(7) . ?
C17 C16 1.389(8) . ?
C17 H12 0.9500 . ?
C16 H11 0.9500 . ?
C41 C46 1.538(9) . ?
C41 C42 1.543(8) . ?
C41 H52 1.0000 . ?
C10 H7 0.9500 . ?
C96 C91 1.355(10) . ?
C96 C95 1.390(10) . ?
C96 H115 0.9500 . ?
C55 C60 1.529(8) . ?
C55 H78 1.0000 . ?
C49 C50 1.527(8) . ?
C49 C54 1.544(8) . ?
C49 H67 1.0000 . ?
C81 C80 1.386(8) . ?
C81 C82 1.389(9) . ?
C83 C82 1.350(10) . ?
C83 C84 1.378(10) . ?
C40 C35 1.530(8) . ?
C40 C39 1.534(8) . ?
C40 H50 0.9900 . ?
C40 H51 0.9900 . ?
C50 C51 1.534(9) . ?
C50 H68 0.9900 . ?
C50 H69 0.9900 . ?
C80 C79 1.377(8) . ?
C63 C64 1.512(8) . ?
C63 C62 1.539(9) . ?
C63 H92 0.9900 . ?
C63 H93 0.9900 . ?
C4 C5 1.384(9) . ?
C4 H3 0.9500 . ?
C29 C30 1.524(8) . ?
C29 H30 1.0000 . ?
C58 C57 1.510(9) . ?
C58 C59 1.527(9) . ?
C58 H83 0.9900 . ?
C58 H84 0.9900 . ?
C5 H4 0.9500 . ?
C86 C87 1.370(9) . ?
C86 C85 1.390(10) . ?
C36 C37 1.532(8) . ?
C36 C35 1.533(9) . ?
C36 H42 0.9900 . ?
C36 H43 0.9900 . ?
C64 C65 1.534(9) . ?
C64 H94 0.9900 . ?
C64 H95 0.9900 . ?
C88 C89 1.375(10) . ?
C88 C87 1.387(9) . ?
C42 C43 1.543(10) . ?
C42 H53 0.9900 . ?
C42 H54 0.9900 . ?
C27 C26 1.528(9) . ?
C27 C28 1.528(8) . ?
C27 H26 0.9900 . ?
C27 H27 0.9900 . ?
C94 C93 1.378(10) . ?
C94 C95 1.393(10) . ?
C94 H113 0.9500 . ?
C60 C59 1.535(8) . ?
C60 H87 0.9900 . ?
C60 H88 0.9900 . ?
C21 C22 1.517(7) . ?
C21 H15 0.9900 . ?
C21 H16 0.9900 . ?
C51 C52 1.521(9) . ?
C51 H70 0.9900 . ?
C51 H71 0.9900 . ?
C85 C90 1.397(9) . ?
C85 B1 1.662(9) . ?
C52 C53 1.516(9) . ?
C52 H72 0.9900 . ?
C52 H73 0.9900 . ?
C62 H90 0.9900 . ?
C62 H91 0.9900 . ?
C45 C44 1.518(11) . ?
C45 C46 1.523(9) . ?
C45 H59 0.9900 . ?
C45 H60 0.9900 . ?
C35 H41 1.0000 . ?
C67 C68 1.518(9) . ?
C67 C72 1.540(9) . ?
C67 H100 1.0000 . ?
C22 H17 0.9900 . ?
C22 H18 0.9900 . ?
C39 C38 1.510(10) . ?
C39 H48 0.9900 . ?
C39 H49 0.9900 . ?
C90 C89 1.375(9) . ?
C84 C79 1.378(9) . ?
C91 C92 1.372(10) . ?
C38 C37 1.512(9) . ?
C38 H46 0.9900 . ?
C38 H47 0.9900 . ?
C57 H81 0.9900 . ?
C57 H82 0.9900 . ?
C30 C31 1.532(9) . ?
C30 H31 0.9900 . ?
C30 H32 0.9900 . ?
C25 C26 1.511(9) . ?
C25 H22 0.9900 . ?
C25 H23 0.9900 . ?
C37 H44 0.9900 . ?
C37 H45 0.9900 . ?
C92 C93 1.391(10) . ?
C92 H111 0.9500 . ?
C54 C53 1.520(9) . ?
C54 H76 0.9900 . ?
C54 H77 0.9900 . ?
C79 B1 1.635(9) . ?
C59 H85 0.9900 . ?
C59 H86 0.9900 . ?
C32 C33 1.513(9) . ?
C32 C31 1.519(11) . ?
C32 H35 0.9900 . ?
C32 H36 0.9900 . ?
C53 H74 0.9900 . ?
C53 H75 0.9900 . ?
C46 H61 0.9900 . ?
C46 H62 0.9900 . ?
C28 H28 0.9900 . ?
C28 H29 0.9900 . ?
C31 H33 0.9900 . ?
C31 H34 0.9900 . ?
C48 H65 0.9900 . ?
C48 H66 0.9900 . ?
C33 H37 0.9900 . ?
C33 H38 0.9900 . ?
C66 C65 1.521(10) . ?
C66 H98 0.9900 . ?
C66 H99 0.9900 . ?
C95 H114 0.9500 . ?
B1 C73 1.659(9) . ?
B1 H123 1.1500 . ?
C26 H24 0.9900 . ?
C26 H25 0.9900 . ?
C65 H96 0.9900 . ?
C65 H97 0.9900 . ?
C44 C43 1.489(11) . ?
C44 H57 0.9900 . ?
C44 H58 0.9900 . ?
C43 H55 0.9900 . ?
C43 H56 0.9900 . ?
C70 C71 1.512(9) . ?
C70 C69 1.526(9) . ?
C70 H105 0.9900 . ?
C70 H106 0.9900 . ?
C71 C72 1.533(8) . ?
C71 H107 0.9900 . ?
C71 H108 0.9900 . ?
C72 H109 0.9900 . ?
C72 H110 0.9900 . ?
C69 C68 1.526(8) . ?
C69 H103 0.9900 . ?
C69 H104 0.9900 . ?
C68 H101 0.9900 . ?
C68 H102 0.9900 . ?
F1 C74 1.357(7) . ?
F5 C78 1.355(8) . ?
F14 C89 1.344(7) . ?
F2 C75 1.354(9) . ?
F4 C77 1.349(8) . ?
F3 C76 1.355(7) . ?
C73 C74 1.371(9) . ?
C73 C78 1.384(9) . ?
C74 C75 1.388(9) . ?
C77 C76 1.375(11) . ?
C77 C78 1.392(9) . ?
C76 C75 1.351(11) . ?
C93 H112 0.9500 . ?
C102 C101 1.535(10) . ?
C102 C97 1.537(10) . ?
C102 H126 0.9900 . ?
C102 H127 0.9900 . ?
C101 C100 1.525(10) . ?
C101 H124 0.9900 . ?
C101 H125 0.9900 . ?
C98 C97 1.533(10) . ?
C98 C99 1.540(10) . ?
C98 H117 0.9900 . ?
C98 H118 0.9900 . ?
C99 C100 1.525(10) . ?
C99 H119 0.9900 . ?
C99 H120 0.9900 . ?
C97 H116 1.0000 . ?
C100 H121 0.9900 . ?
C100 H122 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Pd1 P2 87.48(5) . . ?
P1 Pd1 Ge1 101.32(4) . . ?
P2 Pd1 Ge1 168.39(4) . . ?
P1 Pd1 Pd2 154.44(4) . . ?
P2 Pd1 Pd2 117.10(4) . . ?
Ge1 Pd1 Pd2 53.383(16) . . ?
P1 Pd1 H1 172.6(16) . . ?
P2 Pd1 H1 85.5(16) . . ?
Ge1 Pd1 H1 86.0(16) . . ?
Pd2 Pd1 H1 32.9(16) . . ?
P3 Pd2 P4 86.98(5) . . ?
P3 Pd2 Ge1 100.66(4) . . ?
P4 Pd2 Ge1 169.96(4) . . ?
P3 Pd2 Pd1 152.01(4) . . ?
P4 Pd2 Pd1 120.43(4) . . ?
Ge1 Pd2 Pd1 52.918(17) . . ?
P3 Pd2 H1 168.2(18) . . ?
P4 Pd2 H1 82.6(18) . . ?
Ge1 Pd2 H1 90.4(18) . . ?
Pd1 Pd2 H1 37.9(18) . . ?
C1 Ge1 Cl1 103.18(15) . . ?
C1 Ge1 Pd1 128.52(15) . . ?
Cl1 Ge1 Pd1 110.54(4) . . ?
C1 Ge1 Pd2 124.43(15) . . ?
Cl1 Ge1 Pd2 114.97(4) . . ?
Pd1 Ge1 Pd2 73.70(2) . . ?
C35 P2 C41 105.9(3) . . ?
C35 P2 C22 104.3(3) . . ?
C41 P2 C22 103.5(3) . . ?
C35 P2 Pd1 118.0(2) . . ?
C41 P2 Pd1 116.9(2) . . ?
C22 P2 Pd1 106.52(18) . . ?
C49 P3 C47 104.6(3) . . ?
C49 P3 C55 107.3(3) . . ?
C47 P3 C55 104.6(3) . . ?
C49 P3 Pd2 113.99(19) . . ?
C47 P3 Pd2 105.55(18) . . ?
C55 P3 Pd2 119.37(18) . . ?
C48 P4 C97 102.4(9) . . ?
C48 P4 C61 105.4(3) . . ?
C97 P4 C61 100.5(8) . . ?
C48 P4 C67 106.7(5) . . ?
C97 P4 C67 9.3(7) . . ?
C61 P4 C67 106.7(4) . . ?
C48 P4 Pd2 104.03(19) . . ?
C97 P4 Pd2 126.2(5) . . ?
C61 P4 Pd2 116.05(19) . . ?
C67 P4 Pd2 116.9(4) . . ?
C29 P1 C21 105.7(3) . . ?
C29 P1 C23 108.1(3) . . ?
C21 P1 C23 103.2(2) . . ?
C29 P1 Pd1 112.1(2) . . ?
C21 P1 Pd1 106.96(17) . . ?
C23 P1 Pd1 119.54(19) . . ?
C48 C47 P3 110.6(4) . . ?
C48 C47 H63 109.5 . . ?
P3 C47 H63 109.5 . . ?
C48 C47 H64 109.5 . . ?
P3 C47 H64 109.5 . . ?
H63 C47 H64 108.1 . . ?
C3 C2 C7 118.4(5) . . ?
C3 C2 C1 127.8(5) . . ?
C7 C2 C1 113.8(5) . . ?
C19 C18 C17 119.9(5) . . ?
C19 C18 H13 120.1 . . ?
C17 C18 H13 120.1 . . ?
C4 C3 C2 120.0(5) . . ?
C4 C3 H2 120.0 . . ?
C2 C3 H2 120.0 . . ?
C18 C19 C14 120.3(5) . . ?
C18 C19 C20 125.7(5) . . ?
C14 C19 C20 113.9(5) . . ?
C14 C1 C8 100.5(4) . . ?
C14 C1 C2 106.6(4) . . ?
C8 C1 C2 105.6(4) . . ?
C14 C1 Ge1 117.6(3) . . ?
C8 C1 Ge1 117.9(3) . . ?
C2 C1 Ge1 107.6(3) . . ?
C14 C15 C16 120.7(5) . . ?
C14 C15 H10 119.6 . . ?
C16 C15 H10 119.6 . . ?
C28 C23 C24 110.4(5) . . ?
C28 C23 P1 116.7(4) . . ?
C24 C23 P1 110.3(4) . . ?
C28 C23 H19 106.3 . . ?
C24 C23 H19 106.3 . . ?
P1 C23 H19 106.3 . . ?
C66 C61 C62 110.6(5) . . ?
C66 C61 P4 115.9(5) . . ?
C62 C61 P4 110.6(4) . . ?
C66 C61 H89 106.3 . . ?
C62 C61 H89 106.3 . . ?
P4 C61 H89 106.3 . . ?
C25 C24 C23 110.6(5) . . ?
C25 C24 H20 109.5 . . ?
C23 C24 H20 109.5 . . ?
C25 C24 H21 109.5 . . ?
C23 C24 H21 109.5 . . ?
H20 C24 H21 108.1 . . ?
C57 C56 C55 110.5(5) . . ?
C57 C56 H79 109.5 . . ?
C55 C56 H79 109.5 . . ?
C57 C56 H80 109.5 . . ?
C55 C56 H80 109.5 . . ?
H79 C56 H80 108.1 . . ?
C19 C20 C7 107.1(4) . . ?
C19 C20 C13 104.6(4) . . ?
C7 C20 C13 105.4(4) . . ?
C19 C20 H14 113.0 . . ?
C7 C20 H14 113.0 . . ?
C13 C20 H14 113.0 . . ?
C7 C6 C5 119.6(5) . . ?
C7 C6 H5 120.2 . . ?
C5 C6 H5 120.2 . . ?
C33 C34 C29 111.4(5) . . ?
C33 C34 H39 109.3 . . ?
C29 C34 H39 109.3 . . ?
C33 C34 H40 109.3 . . ?
C29 C34 H40 109.3 . . ?
H39 C34 H40 108.0 . . ?
C10 C11 C12 119.9(5) . . ?
C10 C11 H8 120.1 . . ?
C12 C11 H8 120.1 . . ?
C6 C7 C2 121.4(5) . . ?
C6 C7 C20 124.9(5) . . ?
C2 C7 C20 113.7(5) . . ?
C13 C12 C11 119.8(5) . . ?
C13 C12 H9 120.1 . . ?
C11 C12 H9 120.1 . . ?
C10 C9 C8 120.2(5) . . ?
C10 C9 H6 119.9 . . ?
C8 C9 H6 119.9 . . ?
C12 C13 C8 120.3(5) . . ?
C12 C13 C20 125.9(5) . . ?
C8 C13 C20 113.5(4) . . ?
C18 C17 C16 120.4(5) . . ?
C18 C17 H12 119.8 . . ?
C16 C17 H12 119.8 . . ?
C15 C16 C17 119.5(5) . . ?
C15 C16 H11 120.2 . . ?
C17 C16 H11 120.2 . . ?
C15 C14 C19 119.1(5) . . ?
C15 C14 C1 126.8(5) . . ?
C19 C14 C1 113.7(4) . . ?
C46 C41 C42 110.7(5) . . ?
C46 C41 P2 110.7(4) . . ?
C42 C41 P2 113.6(4) . . ?
C46 C41 H52 107.2 . . ?
C42 C41 H52 107.2 . . ?
P2 C41 H52 107.2 . . ?
C11 C10 C9 121.0(5) . . ?
C11 C10 H7 119.5 . . ?
C9 C10 H7 119.5 . . ?
C91 C96 C95 117.4(7) . . ?
C91 C96 H115 121.3 . . ?
C95 C96 H115 121.3 . . ?
C60 C55 C56 109.2(5) . . ?
C60 C55 P3 117.1(4) . . ?
C56 C55 P3 111.7(4) . . ?
C60 C55 H78 106.0 . . ?
C56 C55 H78 106.0 . . ?
P3 C55 H78 106.0 . . ?
C50 C49 C54 111.2(5) . . ?
C50 C49 P3 116.3(4) . . ?
C54 C49 P3 111.5(4) . . ?
C50 C49 H67 105.6 . . ?
C54 C49 H67 105.6 . . ?
P3 C49 H67 105.6 . . ?
C9 C8 C13 118.7(5) . . ?
C9 C8 C1 128.0(5) . . ?
C13 C8 C1 113.0(4) . . ?
F7 C81 C80 121.6(6) . . ?
F7 C81 C82 120.0(6) . . ?
C80 C81 C82 118.3(6) . . ?
C82 C83 F9 120.1(7) . . ?
C82 C83 C84 119.7(6) . . ?
F9 C83 C84 120.2(6) . . ?
C35 C40 C39 110.7(5) . . ?
C35 C40 H50 109.5 . . ?
C39 C40 H50 109.5 . . ?
C35 C40 H51 109.5 . . ?
C39 C40 H51 109.5 . . ?
H50 C40 H51 108.1 . . ?
C49 C50 C51 111.7(5) . . ?
C49 C50 H68 109.3 . . ?
C51 C50 H68 109.3 . . ?
C49 C50 H69 109.3 . . ?
C51 C50 H69 109.3 . . ?
H68 C50 H69 107.9 . . ?
F6 C80 C79 119.6(5) . . ?
F6 C80 C81 116.0(5) . . ?
C79 C80 C81 124.3(6) . . ?
C64 C63 C62 112.0(5) . . ?
C64 C63 H92 109.2 . . ?
C62 C63 H92 109.2 . . ?
C64 C63 H93 109.2 . . ?
C62 C63 H93 109.2 . . ?
H92 C63 H93 107.9 . . ?
C3 C4 C5 121.3(5) . . ?
C3 C4 H3 119.4 . . ?
C5 C4 H3 119.4 . . ?
C30 C29 C34 110.7(5) . . ?
C30 C29 P1 117.3(4) . . ?
C34 C29 P1 109.9(4) . . ?
C30 C29 H30 106.1 . . ?
C34 C29 H30 106.1 . . ?
P1 C29 H30 106.1 . . ?
C57 C58 C59 111.0(5) . . ?
C57 C58 H83 109.4 . . ?
C59 C58 H83 109.4 . . ?
C57 C58 H84 109.4 . . ?
C59 C58 H84 109.4 . . ?
H83 C58 H84 108.0 . . ?
C4 C5 C6 119.3(5) . . ?
C4 C5 H4 120.3 . . ?
C6 C5 H4 120.3 . . ?
F11 C86 C87 114.8(6) . . ?
F11 C86 C85 120.5(6) . . ?
C87 C86 C85 124.7(6) . . ?
C37 C36 C35 111.8(5) . . ?
C37 C36 H42 109.3 . . ?
C35 C36 H42 109.3 . . ?
C37 C36 H43 109.3 . . ?
C35 C36 H43 109.3 . . ?
H42 C36 H43 107.9 . . ?
C63 C64 C65 110.1(5) . . ?
C63 C64 H94 109.6 . . ?
C65 C64 H94 109.6 . . ?
C63 C64 H95 109.6 . . ?
C65 C64 H95 109.6 . . ?
H94 C64 H95 108.1 . . ?
F13 C88 C89 120.8(6) . . ?
F13 C88 C87 121.3(7) . . ?
C89 C88 C87 117.9(6) . . ?
C43 C42 C41 110.8(6) . . ?
C43 C42 H53 109.5 . . ?
C41 C42 H53 109.5 . . ?
C43 C42 H54 109.5 . . ?
C41 C42 H54 109.5 . . ?
H53 C42 H54 108.1 . . ?
C26 C27 C28 111.3(5) . . ?
C26 C27 H26 109.4 . . ?
C28 C27 H26 109.4 . . ?
C26 C27 H27 109.4 . . ?
C28 C27 H27 109.4 . . ?
H26 C27 H27 108.0 . . ?
C93 C94 C95 119.8(7) . . ?
C93 C94 H113 120.1 . . ?
C95 C94 H113 120.1 . . ?
C55 C60 C59 109.1(5) . . ?
C55 C60 H87 109.9 . . ?
C59 C60 H87 109.9 . . ?
C55 C60 H88 109.9 . . ?
C59 C60 H88 109.9 . . ?
H87 C60 H88 108.3 . . ?
C22 C21 P1 114.6(4) . . ?
C22 C21 H15 108.6 . . ?
P1 C21 H15 108.6 . . ?
C22 C21 H16 108.6 . . ?
P1 C21 H16 108.6 . . ?
H15 C21 H16 107.6 . . ?
C52 C51 C50 112.2(5) . . ?
C52 C51 H70 109.2 . . ?
C50 C51 H70 109.2 . . ?
C52 C51 H71 109.2 . . ?
C50 C51 H71 109.2 . . ?
H70 C51 H71 107.9 . . ?
C86 C85 C90 112.4(6) . . ?
C86 C85 B1 128.6(5) . . ?
C90 C85 B1 118.6(6) . . ?
C53 C52 C51 111.0(5) . . ?
C53 C52 H72 109.4 . . ?
C51 C52 H72 109.4 . . ?
C53 C52 H73 109.4 . . ?
C51 C52 H73 109.4 . . ?
H72 C52 H73 108.0 . . ?
C61 C62 C63 110.8(5) . . ?
C61 C62 H90 109.5 . . ?
C63 C62 H90 109.5 . . ?
C61 C62 H91 109.5 . . ?
C63 C62 H91 109.5 . . ?
H90 C62 H91 108.1 . . ?
C83 C82 F8 121.7(6) . . ?
C83 C82 C81 119.5(6) . . ?
F8 C82 C81 118.7(6) . . ?
C44 C45 C46 110.9(6) . . ?
C44 C45 H59 109.5 . . ?
C46 C45 H59 109.5 . . ?
C44 C45 H60 109.5 . . ?
C46 C45 H60 109.5 . . ?
H59 C45 H60 108.1 . . ?
C40 C35 C36 110.3(5) . . ?
C40 C35 P2 112.3(4) . . ?
C36 C35 P2 109.8(4) . . ?
C40 C35 H41 108.1 . . ?
C36 C35 H41 108.1 . . ?
P2 C35 H41 108.1 . . ?
C68 C67 C72 111.3(10) . . ?
C68 C67 P4 117.3(9) . . ?
C72 C67 P4 112.9(10) . . ?
C68 C67 H100 104.6 . . ?
C72 C67 H100 104.6 . . ?
P4 C67 H100 104.6 . . ?
C21 C22 P2 112.6(4) . . ?
C21 C22 H17 109.1 . . ?
P2 C22 H17 109.1 . . ?
C21 C22 H18 109.1 . . ?
P2 C22 H18 109.1 . . ?
H17 C22 H18 107.8 . . ?
C38 C39 C40 111.3(5) . . ?
C38 C39 H48 109.4 . . ?
C40 C39 H48 109.4 . . ?
C38 C39 H49 109.4 . . ?
C40 C39 H49 109.4 . . ?
H48 C39 H49 108.0 . . ?
F15 C90 C89 116.1(6) . . ?
F15 C90 C85 118.9(6) . . ?
C89 C90 C85 125.0(6) . . ?
F10 C84 C83 116.4(6) . . ?
F10 C84 C79 119.3(6) . . ?
C83 C84 C79 124.3(6) . . ?
F12 C87 C86 121.1(6) . . ?
F12 C87 C88 118.6(6) . . ?
C86 C87 C88 120.2(7) . . ?
C96 C91 F16 118.4(7) . . ?
C96 C91 C92 124.2(7) . . ?
F16 C91 C92 117.4(7) . . ?
C39 C38 C37 111.6(6) . . ?
C39 C38 H46 109.3 . . ?
C37 C38 H46 109.3 . . ?
C39 C38 H47 109.3 . . ?
C37 C38 H47 109.3 . . ?
H46 C38 H47 108.0 . . ?
C58 C57 C56 112.0(5) . . ?
C58 C57 H81 109.2 . . ?
C56 C57 H81 109.2 . . ?
C58 C57 H82 109.2 . . ?
C56 C57 H82 109.2 . . ?
H81 C57 H82 107.9 . . ?
C29 C30 C31 110.2(6) . . ?
C29 C30 H31 109.6 . . ?
C31 C30 H31 109.6 . . ?
C29 C30 H32 109.6 . . ?
C31 C30 H32 109.6 . . ?
H31 C30 H32 108.1 . . ?
C26 C25 C24 111.1(5) . . ?
C26 C25 H22 109.4 . . ?
C24 C25 H22 109.4 . . ?
C26 C25 H23 109.4 . . ?
C24 C25 H23 109.4 . . ?
H22 C25 H23 108.0 . . ?
C38 C37 C36 111.2(5) . . ?
C38 C37 H44 109.4 . . ?
C36 C37 H44 109.4 . . ?
C38 C37 H45 109.4 . . ?
C36 C37 H45 109.4 . . ?
H44 C37 H45 108.0 . . ?
C91 C92 C93 117.9(7) . . ?
C91 C92 H111 121.1 . . ?
C93 C92 H111 121.1 . . ?
C53 C54 C49 110.3(5) . . ?
C53 C54 H76 109.6 . . ?
C49 C54 H76 109.6 . . ?
C53 C54 H77 109.6 . . ?
C49 C54 H77 109.6 . . ?
H76 C54 H77 108.1 . . ?
C80 C79 C84 113.7(6) . . ?
C80 C79 B1 125.1(5) . . ?
C84 C79 B1 121.2(5) . . ?
C58 C59 C60 111.1(5) . . ?
C58 C59 H85 109.4 . . ?
C60 C59 H85 109.4 . . ?
C58 C59 H86 109.4 . . ?
C60 C59 H86 109.4 . . ?
H85 C59 H86 108.0 . . ?
C33 C32 C31 110.9(6) . . ?
C33 C32 H35 109.5 . . ?
C31 C32 H35 109.5 . . ?
C33 C32 H36 109.5 . . ?
C31 C32 H36 109.5 . . ?
H35 C32 H36 108.1 . . ?
C52 C53 C54 110.7(5) . . ?
C52 C53 H74 109.5 . . ?
C54 C53 H74 109.5 . . ?
C52 C53 H75 109.5 . . ?
C54 C53 H75 109.5 . . ?
H74 C53 H75 108.1 . . ?
C45 C46 C41 112.0(6) . . ?
C45 C46 H61 109.2 . . ?
C41 C46 H61 109.2 . . ?
C45 C46 H62 109.2 . . ?
C41 C46 H62 109.2 . . ?
H61 C46 H62 107.9 . . ?
C27 C28 C23 109.7(5) . . ?
C27 C28 H28 109.7 . . ?
C23 C28 H28 109.7 . . ?
C27 C28 H29 109.7 . . ?
C23 C28 H29 109.7 . . ?
H28 C28 H29 108.2 . . ?
C32 C31 C30 112.7(6) . . ?
C32 C31 H33 109.0 . . ?
C30 C31 H33 109.0 . . ?
C32 C31 H34 109.0 . . ?
C30 C31 H34 109.0 . . ?
H33 C31 H34 107.8 . . ?
C47 C48 P4 110.4(4) . . ?
C47 C48 H65 109.6 . . ?
P4 C48 H65 109.6 . . ?
C47 C48 H66 109.6 . . ?
P4 C48 H66 109.6 . . ?
H65 C48 H66 108.1 . . ?
C32 C33 C34 110.4(5) . . ?
C32 C33 H37 109.6 . . ?
C34 C33 H37 109.6 . . ?
C32 C33 H38 109.6 . . ?
C34 C33 H38 109.6 . . ?
H37 C33 H38 108.1 . . ?
C65 C66 C61 111.4(6) . . ?
C65 C66 H98 109.4 . . ?
C61 C66 H98 109.4 . . ?
C65 C66 H99 109.4 . . ?
C61 C66 H99 109.4 . . ?
H98 C66 H99 108.0 . . ?
C96 C95 C94 120.7(7) . . ?
C96 C95 H114 119.7 . . ?
C94 C95 H114 119.7 . . ?
C79 B1 C73 111.2(5) . . ?
C79 B1 C85 111.7(5) . . ?
C73 B1 C85 111.5(5) . . ?
C79 B1 H123 107.4 . . ?
C73 B1 H123 107.4 . . ?
C85 B1 H123 107.4 . . ?
C25 C26 C27 110.6(5) . . ?
C25 C26 H24 109.5 . . ?
C27 C26 H24 109.5 . . ?
C25 C26 H25 109.5 . . ?
C27 C26 H25 109.5 . . ?
H24 C26 H25 108.1 . . ?
C66 C65 C64 110.7(6) . . ?
C66 C65 H96 109.5 . . ?
C64 C65 H96 109.5 . . ?
C66 C65 H97 109.5 . . ?
C64 C65 H97 109.5 . . ?
H96 C65 H97 108.1 . . ?
C43 C44 C45 112.0(7) . . ?
C43 C44 H57 109.2 . . ?
C45 C44 H57 109.2 . . ?
C43 C44 H58 109.2 . . ?
C45 C44 H58 109.2 . . ?
H57 C44 H58 107.9 . . ?
C44 C43 C42 112.1(6) . . ?
C44 C43 H55 109.2 . . ?
C42 C43 H55 109.2 . . ?
C44 C43 H56 109.2 . . ?
C42 C43 H56 109.2 . . ?
H55 C43 H56 107.9 . . ?
C71 C70 C69 109.5(10) . . ?
C71 C70 H105 109.8 . . ?
C69 C70 H105 109.8 . . ?
C71 C70 H106 109.8 . . ?
C69 C70 H106 109.8 . . ?
H105 C70 H106 108.2 . . ?
C70 C71 C72 110.6(9) . . ?
C70 C71 H107 109.5 . . ?
C72 C71 H107 109.5 . . ?
C70 C71 H108 109.5 . . ?
C72 C71 H108 109.5 . . ?
H107 C71 H108 108.1 . . ?
C71 C72 C67 113.3(11) . . ?
C71 C72 H109 108.9 . . ?
C67 C72 H109 108.9 . . ?
C71 C72 H110 108.9 . . ?
C67 C72 H110 108.9 . . ?
H109 C72 H110 107.7 . . ?
C68 C69 C70 111.7(9) . . ?
C68 C69 H103 109.3 . . ?
C70 C69 H103 109.3 . . ?
C68 C69 H104 109.3 . . ?
C70 C69 H104 109.3 . . ?
H103 C69 H104 107.9 . . ?
C67 C68 C69 110.5(10) . . ?
C67 C68 H101 109.6 . . ?
C69 C68 H101 109.6 . . ?
C67 C68 H102 109.6 . . ?
C69 C68 H102 109.6 . . ?
H101 C68 H102 108.1 . . ?
C74 C73 C78 113.8(6) . . ?
C74 C73 B1 127.4(5) . . ?
C78 C73 B1 118.7(6) . . ?
F1 C74 C73 121.8(5) . . ?
F1 C74 C75 113.9(6) . . ?
C73 C74 C75 124.3(6) . . ?
F4 C77 C76 121.4(6) . . ?
F4 C77 C78 120.0(8) . . ?
C76 C77 C78 118.6(7) . . ?
C75 C76 F3 121.2(7) . . ?
C75 C76 C77 119.9(6) . . ?
F3 C76 C77 118.8(7) . . ?
C76 C75 F2 119.3(6) . . ?
C76 C75 C74 119.3(7) . . ?
F2 C75 C74 121.4(7) . . ?
F5 C78 C73 119.5(6) . . ?
F5 C78 C77 116.5(6) . . ?
C73 C78 C77 124.0(7) . . ?
F14 C89 C88 119.0(6) . . ?
F14 C89 C90 121.2(7) . . ?
C88 C89 C90 119.8(6) . . ?
C94 C93 C92 120.1(7) . . ?
C94 C93 H112 120.0 . . ?
C92 C93 H112 120.0 . . ?
C101 C102 C97 109.0(18) . . ?
C101 C102 H126 109.9 . . ?
C97 C102 H126 109.9 . . ?
C101 C102 H127 109.9 . . ?
C97 C102 H127 109.9 . . ?
H126 C102 H127 108.3 . . ?
C100 C101 C102 107.2(16) . . ?
C100 C101 H124 110.3 . . ?
C102 C101 H124 110.3 . . ?
C100 C101 H125 110.3 . . ?
C102 C101 H125 110.3 . . ?
H124 C101 H125 108.5 . . ?
C97 C98 C99 109.2(19) . . ?
C97 C98 H117 109.8 . . ?
C99 C98 H117 109.8 . . ?
C97 C98 H118 109.8 . . ?
C99 C98 H118 109.8 . . ?
H117 C98 H118 108.3 . . ?
C100 C99 C98 105.4(17) . . ?
C100 C99 H119 110.7 . . ?
C98 C99 H119 110.7 . . ?
C100 C99 H120 110.7 . . ?
C98 C99 H120 110.7 . . ?
H119 C99 H120 108.8 . . ?
C98 C97 C102 107.7(17) . . ?
C98 C97 P4 107.9(17) . . ?
C102 C97 P4 114(2) . . ?
C98 C97 H116 109.2 . . ?
C102 C97 H116 109.2 . . ?
P4 C97 H116 109.2 . . ?
C99 C100 C101 108.1(16) . . ?
C99 C100 H121 110.1 . . ?
C101 C100 H121 110.1 . . ?
C99 C100 H122 110.1 . . ?
C101 C100 H122 110.1 . . ?
H121 C100 H122 108.4 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P1 Pd1 Pd2 P3 12.50(13) . . . . ?
P2 Pd1 Pd2 P3 -150.30(10) . . . . ?
Ge1 Pd1 Pd2 P3 21.86(9) . . . . ?
P1 Pd1 Pd2 P4 179.70(10) . . . . ?
P2 Pd1 Pd2 P4 16.90(7) . . . . ?
Ge1 Pd1 Pd2 P4 -170.94(5) . . . . ?
P1 Pd1 Pd2 Ge1 -9.36(9) . . . . ?
P2 Pd1 Pd2 Ge1 -172.16(5) . . . . ?
P1 Pd1 Ge1 C1 -62.76(19) . . . . ?
P2 Pd1 Ge1 C1 158.5(3) . . . . ?
Pd2 Pd1 Ge1 C1 121.35(19) . . . . ?
P1 Pd1 Ge1 Cl1 64.79(6) . . . . ?
P2 Pd1 Ge1 Cl1 -74.0(2) . . . . ?
Pd2 Pd1 Ge1 Cl1 -111.10(5) . . . . ?
P1 Pd1 Ge1 Pd2 175.90(4) . . . . ?
P2 Pd1 Ge1 Pd2 37.1(2) . . . . ?
P3 Pd2 Ge1 C1 64.35(18) . . . . ?
P4 Pd2 Ge1 C1 -74.7(3) . . . . ?
Pd1 Pd2 Ge1 C1 -125.89(18) . . . . ?
P3 Pd2 Ge1 Cl1 -64.27(6) . . . . ?
P4 Pd2 Ge1 Cl1 156.6(2) . . . . ?
Pd1 Pd2 Ge1 Cl1 105.49(5) . . . . ?
P3 Pd2 Ge1 Pd1 -169.76(4) . . . . ?
P4 Pd2 Ge1 Pd1 51.2(2) . . . . ?
P1 Pd1 P2 C35 105.6(2) . . . . ?
Ge1 Pd1 P2 C35 -114.7(3) . . . . ?
Pd2 Pd1 P2 C35 -81.7(2) . . . . ?
P1 Pd1 P2 C41 -126.2(2) . . . . ?
Ge1 Pd1 P2 C41 13.5(4) . . . . ?
Pd2 Pd1 P2 C41 46.5(2) . . . . ?
P1 Pd1 P2 C22 -11.1(2) . . . . ?
Ge1 Pd1 P2 C22 128.6(3) . . . . ?
Pd2 Pd1 P2 C22 161.58(19) . . . . ?
P4 Pd2 P3 C49 -127.5(2) . . . . ?
Ge1 Pd2 P3 C49 59.1(2) . . . . ?
Pd1 Pd2 P3 C49 41.5(2) . . . . ?
P4 Pd2 P3 C47 -13.2(2) . . . . ?
Ge1 Pd2 P3 C47 173.3(2) . . . . ?
Pd1 Pd2 P3 C47 155.7(2) . . . . ?
P4 Pd2 P3 C55 103.9(2) . . . . ?
Ge1 Pd2 P3 C55 -69.5(2) . . . . ?
Pd1 Pd2 P3 C55 -87.1(2) . . . . ?
P3 Pd2 P4 C48 -10.6(2) . . . . ?
Ge1 Pd2 P4 C48 129.3(3) . . . . ?
Pd1 Pd2 P4 C48 175.4(2) . . . . ?
P3 Pd2 P4 C97 106.7(12) . . . . ?
Ge1 Pd2 P4 C97 -113.4(12) . . . . ?
Pd1 Pd2 P4 C97 -67.3(12) . . . . ?
P3 Pd2 P4 C61 -125.8(2) . . . . ?
Ge1 Pd2 P4 C61 14.1(4) . . . . ?
Pd1 Pd2 P4 C61 60.2(2) . . . . ?
P3 Pd2 P4 C67 106.8(5) . . . . ?
Ge1 Pd2 P4 C67 -113.3(6) . . . . ?
Pd1 Pd2 P4 C67 -67.2(5) . . . . ?
P2 Pd1 P1 C29 109.0(2) . . . . ?
Ge1 Pd1 P1 C29 -63.4(2) . . . . ?
Pd2 Pd1 P1 C29 -55.8(2) . . . . ?
P2 Pd1 P1 C21 -6.5(2) . . . . ?
Ge1 Pd1 P1 C21 -178.9(2) . . . . ?
Pd2 Pd1 P1 C21 -171.2(2) . . . . ?
P2 Pd1 P1 C23 -123.0(2) . . . . ?
Ge1 Pd1 P1 C23 64.6(2) . . . . ?
Pd2 Pd1 P1 C23 72.3(2) . . . . ?
C49 P3 C47 C48 162.2(4) . . . . ?
C55 P3 C47 C48 -85.1(4) . . . . ?
Pd2 P3 C47 C48 41.6(5) . . . . ?
C7 C2 C3 C4 0.5(8) . . . . ?
C1 C2 C3 C4 179.9(5) . . . . ?
C17 C18 C19 C14 -2.1(8) . . . . ?
C17 C18 C19 C20 172.5(5) . . . . ?
C3 C2 C1 C14 128.5(6) . . . . ?
C7 C2 C1 C14 -52.1(6) . . . . ?
C3 C2 C1 C8 -125.2(6) . . . . ?
C7 C2 C1 C8 54.2(5) . . . . ?
C3 C2 C1 Ge1 1.5(7) . . . . ?
C7 C2 C1 Ge1 -179.0(4) . . . . ?
Cl1 Ge1 C1 C14 60.5(4) . . . . ?
Pd1 Ge1 C1 C14 -169.1(3) . . . . ?
Pd2 Ge1 C1 C14 -72.8(4) . . . . ?
Cl1 Ge1 C1 C8 -60.1(4) . . . . ?
Pd1 Ge1 C1 C8 70.2(4) . . . . ?
Pd2 Ge1 C1 C8 166.6(3) . . . . ?
Cl1 Ge1 C1 C2 -179.3(3) . . . . ?
Pd1 Ge1 C1 C2 -48.9(4) . . . . ?
Pd2 Ge1 C1 C2 47.4(4) . . . . ?
C29 P1 C23 C28 -83.6(5) . . . . ?
C21 P1 C23 C28 28.0(5) . . . . ?
Pd1 P1 C23 C28 146.5(4) . . . . ?
C29 P1 C23 C24 149.4(4) . . . . ?
C21 P1 C23 C24 -99.0(4) . . . . ?
Pd1 P1 C23 C24 19.5(4) . . . . ?
C48 P4 C61 C66 38.1(6) . . . . ?
C97 P4 C61 C66 -68.0(9) . . . . ?
C67 P4 C61 C66 -75.1(7) . . . . ?
Pd2 P4 C61 C66 152.6(4) . . . . ?
C48 P4 C61 C62 -88.9(5) . . . . ?
C97 P4 C61 C62 165.0(9) . . . . ?
C67 P4 C61 C62 157.9(6) . . . . ?
Pd2 P4 C61 C62 25.6(5) . . . . ?
C28 C23 C24 C25 56.7(6) . . . . ?
P1 C23 C24 C25 -172.8(4) . . . . ?
C18 C19 C20 C7 128.3(6) . . . . ?
C14 C19 C20 C7 -56.8(6) . . . . ?
C18 C19 C20 C13 -120.2(6) . . . . ?
C14 C19 C20 C13 54.7(6) . . . . ?
C5 C6 C7 C2 1.3(8) . . . . ?
C5 C6 C7 C20 -179.5(5) . . . . ?
C3 C2 C7 C6 -1.4(8) . . . . ?
C1 C2 C7 C6 179.1(5) . . . . ?
C3 C2 C7 C20 179.3(5) . . . . ?
C1 C2 C7 C20 -0.2(6) . . . . ?
C19 C20 C7 C6 -124.4(6) . . . . ?
C13 C20 C7 C6 124.6(6) . . . . ?
C19 C20 C7 C2 54.9(6) . . . . ?
C13 C20 C7 C2 -56.1(6) . . . . ?
C10 C11 C12 C13 2.2(8) . . . . ?
C11 C12 C13 C8 1.2(8) . . . . ?
C11 C12 C13 C20 -172.0(5) . . . . ?
C19 C20 C13 C12 119.7(6) . . . . ?
C7 C20 C13 C12 -127.6(6) . . . . ?
C19 C20 C13 C8 -54.0(6) . . . . ?
C7 C20 C13 C8 58.8(6) . . . . ?
C19 C18 C17 C16 -1.4(8) . . . . ?
C14 C15 C16 C17 0.9(8) . . . . ?
C18 C17 C16 C15 2.0(8) . . . . ?
C16 C15 C14 C19 -4.4(8) . . . . ?
C16 C15 C14 C1 -176.8(5) . . . . ?
C18 C19 C14 C15 5.0(8) . . . . ?
C20 C19 C14 C15 -170.2(5) . . . . ?
C18 C19 C14 C1 178.4(5) . . . . ?
C20 C19 C14 C1 3.1(6) . . . . ?
C8 C1 C14 C15 113.1(6) . . . . ?
C2 C1 C14 C15 -136.9(5) . . . . ?
Ge1 C1 C14 C15 -16.2(7) . . . . ?
C8 C1 C14 C19 -59.6(5) . . . . ?
C2 C1 C14 C19 50.3(6) . . . . ?
Ge1 C1 C14 C19 171.1(4) . . . . ?
C35 P2 C41 C46 178.7(4) . . . . ?
C22 P2 C41 C46 -71.9(5) . . . . ?
Pd1 P2 C41 C46 44.9(5) . . . . ?
C35 P2 C41 C42 -56.0(5) . . . . ?
C22 P2 C41 C42 53.4(5) . . . . ?
Pd1 P2 C41 C42 170.2(4) . . . . ?
C12 C11 C10 C9 -2.7(8) . . . . ?
C8 C9 C10 C11 -0.2(8) . . . . ?
C57 C56 C55 C60 -59.3(6) . . . . ?
C57 C56 C55 P3 169.6(4) . . . . ?
C49 P3 C55 C60 82.6(5) . . . . ?
C47 P3 C55 C60 -28.2(5) . . . . ?
Pd2 P3 C55 C60 -145.9(4) . . . . ?
C49 P3 C55 C56 -150.5(4) . . . . ?
C47 P3 C55 C56 98.7(4) . . . . ?
Pd2 P3 C55 C56 -18.9(5) . . . . ?
C47 P3 C49 C50 54.3(5) . . . . ?
C55 P3 C49 C50 -56.4(5) . . . . ?
Pd2 P3 C49 C50 169.1(4) . . . . ?
C47 P3 C49 C54 -74.7(4) . . . . ?
C55 P3 C49 C54 174.6(4) . . . . ?
Pd2 P3 C49 C54 40.1(4) . . . . ?
C10 C9 C8 C13 3.6(7) . . . . ?
C10 C9 C8 C1 176.8(5) . . . . ?
C12 C13 C8 C9 -4.1(7) . . . . ?
C20 C13 C8 C9 169.9(5) . . . . ?
C12 C13 C8 C1 -178.3(5) . . . . ?
C20 C13 C8 C1 -4.3(6) . . . . ?
C14 C1 C8 C9 -113.8(6) . . . . ?
C2 C1 C8 C9 135.5(5) . . . . ?
Ge1 C1 C8 C9 15.3(7) . . . . ?
C14 C1 C8 C13 59.7(5) . . . . ?
C2 C1 C8 C13 -51.0(5) . . . . ?
Ge1 C1 C8 C13 -171.2(4) . . . . ?
C54 C49 C50 C51 -52.6(7) . . . . ?
P3 C49 C50 C51 178.3(4) . . . . ?
F7 C81 C80 F6 2.7(8) . . . . ?
C82 C81 C80 F6 -177.8(5) . . . . ?
F7 C81 C80 C79 179.5(5) . . . . ?
C82 C81 C80 C79 -1.0(9) . . . . ?
C2 C3 C4 C5 0.6(9) . . . . ?
C33 C34 C29 C30 -56.5(7) . . . . ?
C33 C34 C29 P1 172.4(4) . . . . ?
C21 P1 C29 C30 -58.2(5) . . . . ?
C23 P1 C29 C30 51.8(5) . . . . ?
Pd1 P1 C29 C30 -174.4(4) . . . . ?
C21 P1 C29 C34 69.4(5) . . . . ?
C23 P1 C29 C34 179.3(4) . . . . ?
Pd1 P1 C29 C34 -46.8(4) . . . . ?
C3 C4 C5 C6 -0.8(9) . . . . ?
C7 C6 C5 C4 -0.2(8) . . . . ?
C62 C63 C64 C65 56.3(7) . . . . ?
C46 C41 C42 C43 -53.1(7) . . . . ?
P2 C41 C42 C43 -178.3(5) . . . . ?
C56 C55 C60 C59 60.5(6) . . . . ?
P3 C55 C60 C59 -171.4(4) . . . . ?
C29 P1 C21 C22 -91.5(4) . . . . ?
C23 P1 C21 C22 155.1(4) . . . . ?
Pd1 P1 C21 C22 28.2(4) . . . . ?
C49 C50 C51 C52 52.2(7) . . . . ?
F11 C86 C85 C90 178.0(5) . . . . ?
C87 C86 C85 C90 -2.2(9) . . . . ?
F11 C86 C85 B1 -9.3(10) . . . . ?
C87 C86 C85 B1 170.4(6) . . . . ?
C50 C51 C52 C53 -54.7(7) . . . . ?
C66 C61 C62 C63 54.5(7) . . . . ?
P4 C61 C62 C63 -175.6(4) . . . . ?
C64 C63 C62 C61 -55.5(7) . . . . ?
F9 C83 C82 F8 0.2(10) . . . . ?
C84 C83 C82 F8 -178.8(6) . . . . ?
F9 C83 C82 C81 176.6(6) . . . . ?
C84 C83 C82 C81 -2.5(10) . . . . ?
F7 C81 C82 C83 -176.9(6) . . . . ?
C80 C81 C82 C83 3.6(9) . . . . ?
F7 C81 C82 F8 -0.5(9) . . . . ?
C80 C81 C82 F8 -180.0(5) . . . . ?
C39 C40 C35 C36 -55.7(7) . . . . ?
C39 C40 C35 P2 -178.5(4) . . . . ?
C37 C36 C35 C40 55.2(7) . . . . ?
C37 C36 C35 P2 179.4(4) . . . . ?
C41 P2 C35 C40 -63.2(5) . . . . ?
C22 P2 C35 C40 -172.1(4) . . . . ?
Pd1 P2 C35 C40 70.0(5) . . . . ?
C41 P2 C35 C36 173.7(4) . . . . ?
C22 P2 C35 C36 64.8(5) . . . . ?
Pd1 P2 C35 C36 -53.0(5) . . . . ?
C48 P4 C67 C68 -77.7(11) . . . . ?
C97 P4 C67 C68 -14(8) . . . . ?
C61 P4 C67 C68 34.5(12) . . . . ?
Pd2 P4 C67 C68 166.4(9) . . . . ?
C48 P4 C67 C72 53.8(11) . . . . ?
C97 P4 C67 C72 117(9) . . . . ?
C61 P4 C67 C72 166.1(9) . . . . ?
Pd2 P4 C67 C72 -62.1(12) . . . . ?
P1 C21 C22 P2 -39.4(5) . . . . ?
C35 P2 C22 C21 -94.3(4) . . . . ?
C41 P2 C22 C21 155.1(4) . . . . ?
Pd1 P2 C22 C21 31.2(4) . . . . ?
C35 C40 C39 C38 56.7(7) . . . . ?
C86 C85 C90 F15 -179.9(5) . . . . ?
B1 C85 C90 F15 6.6(8) . . . . ?
C86 C85 C90 C89 2.2(9) . . . . ?
B1 C85 C90 C89 -171.3(6) . . . . ?
C82 C83 C84 F10 176.7(6) . . . . ?
F9 C83 C84 F10 -2.4(9) . . . . ?
C82 C83 C84 C79 -1.5(11) . . . . ?
F9 C83 C84 C79 179.5(6) . . . . ?
F11 C86 C87 F12 0.6(9) . . . . ?
C85 C86 C87 F12 -179.2(6) . . . . ?
F11 C86 C87 C88 -178.6(6) . . . . ?
C85 C86 C87 C88 1.6(11) . . . . ?
F13 C88 C87 F12 1.7(10) . . . . ?
C89 C88 C87 F12 -179.9(6) . . . . ?
F13 C88 C87 C86 -179.1(6) . . . . ?
C89 C88 C87 C86 -0.6(10) . . . . ?
C95 C96 C91 F16 -179.2(6) . . . . ?
C95 C96 C91 C92 0.2(10) . . . . ?
C40 C39 C38 C37 -56.4(7) . . . . ?
C59 C58 C57 C56 -53.7(7) . . . . ?
C55 C56 C57 C58 56.1(7) . . . . ?
C34 C29 C30 C31 54.6(7) . . . . ?
P1 C29 C30 C31 -178.3(5) . . . . ?
C23 C24 C25 C26 -56.6(7) . . . . ?
C39 C38 C37 C36 55.1(8) . . . . ?
C35 C36 C37 C38 -54.8(8) . . . . ?
C96 C91 C92 C93 0.8(10) . . . . ?
F16 C91 C92 C93 -179.7(5) . . . . ?
C50 C49 C54 C53 56.1(7) . . . . ?
P3 C49 C54 C53 -172.3(4) . . . . ?
F6 C80 C79 C84 174.1(5) . . . . ?
C81 C80 C79 C84 -2.6(9) . . . . ?
F6 C80 C79 B1 -6.5(9) . . . . ?
C81 C80 C79 B1 176.8(6) . . . . ?
F10 C84 C79 C80 -174.2(5) . . . . ?
C83 C84 C79 C80 3.9(9) . . . . ?
F10 C84 C79 B1 6.3(9) . . . . ?
C83 C84 C79 B1 -175.6(6) . . . . ?
C57 C58 C59 C60 55.2(7) . . . . ?
C55 C60 C59 C58 -58.9(6) . . . . ?
C51 C52 C53 C54 58.2(7) . . . . ?
C49 C54 C53 C52 -58.8(7) . . . . ?
C44 C45 C46 C41 -55.3(8) . . . . ?
C42 C41 C46 C45 54.4(7) . . . . ?
P2 C41 C46 C45 -178.7(5) . . . . ?
C26 C27 C28 C23 57.7(7) . . . . ?
C24 C23 C28 C27 -57.1(6) . . . . ?
P1 C23 C28 C27 175.9(4) . . . . ?
C33 C32 C31 C30 56.1(7) . . . . ?
C29 C30 C31 C32 -55.2(7) . . . . ?
P3 C47 C48 P4 -53.5(5) . . . . ?
C97 P4 C48 C47 -93.9(8) . . . . ?
C61 P4 C48 C47 161.5(4) . . . . ?
C67 P4 C48 C47 -85.3(5) . . . . ?
Pd2 P4 C48 C47 38.9(5) . . . . ?
C31 C32 C33 C34 -56.0(7) . . . . ?
C29 C34 C33 C32 56.8(7) . . . . ?
C62 C61 C66 C65 -56.3(8) . . . . ?
P4 C61 C66 C65 176.7(5) . . . . ?
C91 C96 C95 C94 -0.7(10) . . . . ?
C93 C94 C95 C96 0.2(10) . . . . ?
C80 C79 B1 C73 92.9(7) . . . . ?
C84 C79 B1 C73 -87.7(7) . . . . ?
C80 C79 B1 C85 -32.3(8) . . . . ?
C84 C79 B1 C85 147.1(6) . . . . ?
C86 C85 B1 C79 124.5(6) . . . . ?
C90 C85 B1 C79 -63.3(7) . . . . ?
C86 C85 B1 C73 -0.6(9) . . . . ?
C90 C85 B1 C73 171.7(5) . . . . ?
C24 C25 C26 C27 56.6(7) . . . . ?
C28 C27 C26 C25 -57.6(7) . . . . ?
C61 C66 C65 C64 57.5(8) . . . . ?
C63 C64 C65 C66 -57.0(8) . . . . ?
C46 C45 C44 C43 56.1(9) . . . . ?
C45 C44 C43 C42 -56.1(10) . . . . ?
C41 C42 C43 C44 54.6(9) . . . . ?
C69 C70 C71 C72 -57.0(15) . . . . ?
C70 C71 C72 C67 53.7(16) . . . . ?
C68 C67 C72 C71 -51.3(18) . . . . ?
P4 C67 C72 C71 174.2(9) . . . . ?
C71 C70 C69 C68 60.4(14) . . . . ?
C72 C67 C68 C69 52.5(17) . . . . ?
P4 C67 C68 C69 -175.2(9) . . . . ?
C70 C69 C68 C67 -58.2(14) . . . . ?
C79 B1 C73 C74 -7.8(8) . . . . ?
C85 B1 C73 C74 117.5(6) . . . . ?
C79 B1 C73 C78 168.9(5) . . . . ?
C85 B1 C73 C78 -65.8(7) . . . . ?
C78 C73 C74 F1 179.9(5) . . . . ?
B1 C73 C74 F1 -3.1(9) . . . . ?
C78 C73 C74 C75 1.4(9) . . . . ?
B1 C73 C74 C75 178.3(6) . . . . ?
F4 C77 C76 C75 -179.9(6) . . . . ?
C78 C77 C76 C75 1.4(10) . . . . ?
F4 C77 C76 F3 -0.3(10) . . . . ?
C78 C77 C76 F3 -179.1(6) . . . . ?
F3 C76 C75 F2 -0.4(9) . . . . ?
C77 C76 C75 F2 179.1(6) . . . . ?
F3 C76 C75 C74 179.8(6) . . . . ?
C77 C76 C75 C74 -0.7(10) . . . . ?
F1 C74 C75 C76 -179.4(5) . . . . ?
C73 C74 C75 C76 -0.8(10) . . . . ?
F1 C74 C75 F2 0.8(8) . . . . ?
C73 C74 C75 F2 179.5(6) . . . . ?
C74 C73 C78 F5 179.8(5) . . . . ?
B1 C73 C78 F5 2.6(9) . . . . ?
C74 C73 C78 C77 -0.6(9) . . . . ?
B1 C73 C78 C77 -177.8(6) . . . . ?
F4 C77 C78 F5 0.1(9) . . . . ?
C76 C77 C78 F5 178.9(6) . . . . ?
F4 C77 C78 C73 -179.5(6) . . . . ?
C76 C77 C78 C73 -0.7(10) . . . . ?
F13 C88 C89 F14 0.1(10) . . . . ?
C87 C88 C89 F14 -178.4(6) . . . . ?
F13 C88 C89 C90 179.0(6) . . . . ?
C87 C88 C89 C90 0.6(10) . . . . ?
F15 C90 C89 F14 -0.5(9) . . . . ?
C85 C90 C89 F14 177.4(6) . . . . ?
F15 C90 C89 C88 -179.4(6) . . . . ?
C85 C90 C89 C88 -1.5(10) . . . . ?
C95 C94 C93 C92 0.9(10) . . . . ?
C91 C92 C93 C94 -1.4(9) . . . . ?
C97 C102 C101 C100 -62(2) . . . . ?
C97 C98 C99 C100 65(2) . . . . ?
C99 C98 C97 C102 -62(3) . . . . ?
C99 C98 C97 P4 174.9(16) . . . . ?
C101 C102 C97 C98 60(3) . . . . ?
C101 C102 C97 P4 179.7(14) . . . . ?
C48 P4 C97 C98 97.3(18) . . . . ?
C61 P4 C97 C98 -154.3(17) . . . . ?
C67 P4 C97 C98 -21(7) . . . . ?
Pd2 P4 C97 C98 -21(2) . . . . ?
C48 P4 C97 C102 -22.1(18) . . . . ?
C61 P4 C97 C102 86.4(17) . . . . ?
C67 P4 C97 C102 -141(10) . . . . ?
Pd2 P4 C97 C102 -140.1(12) . . . . ?
C98 C99 C100 C101 -67(2) . . . . ?
C102 C101 C100 C99 66(2) . . . . ?

_diffrn_measured_fraction_theta_max 1.000
_diffrn_reflns_theta_full        25.50
_diffrn_measured_fraction_theta_full 1.000
_refine_diff_density_max         2.086
_refine_diff_density_min         -0.927
_refine_diff_density_rms         0.087
