# Electronic Supplementary Material (ESI) for Chemical Communications.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_exp755
_database_code_depnum_ccdc_archive 'CCDC 1402657'
_audit_update_record             
;
2015-05-23 deposited with the CCDC.
2015-06-30 downloaded from the CCDC.
;
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C162 H162 Au13 F18 N4 O2 P13'
_chemical_formula_iupac          ?
_chemical_formula_weight         5502.12

_chemical_melting_point          ?

_space_group_crystal_system      monoclinic
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   25.720(2)
_cell_length_b                   21.2708(18)
_cell_length_c                   31.007(3)
_cell_angle_alpha                90
_cell_angle_beta                 96.8650(9)
_cell_angle_gamma                90
_cell_volume                     16842.(2)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    209
_cell_measurement_theta_min      2.7357
_cell_measurement_theta_max      19.5408
_cell_measurement_temperature    90.(2)

_exptl_crystal_description       block
_exptl_crystal_colour            red
_exptl_crystal_size_max          0.190
_exptl_crystal_size_mid          0.170
_exptl_crystal_size_min          0.120
_exptl_crystal_density_diffrn    2.170
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             10248

_exptl_absorpt_coefficient_mu    11.468
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS V2012/1 (Bruker AXS Inc.)'
_exptl_absorpt_correction_T_min  0.19
_exptl_absorpt_correction_T_max  0.34

_exptl_special_details           
;
;

_diffrn_ambient_temperature      90.(2)

_diffrn_source                   'sealed tube'
_diffrn_source_type              ?

_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_monochromator  graphite

_diffrn_measurement_device_type  'Bruker D8 goniometer'
_diffrn_measurement_method       'omega scans'

_diffrn_detector_area_resol_mean 8.3333

_diffrn_reflns_number            44566
_diffrn_reflns_av_R_equivalents  0.0662
_diffrn_reflns_av_unetI/netI     0.0913
_diffrn_reflns_theta_min         1.25
_diffrn_reflns_theta_max         26.37
_diffrn_reflns_theta_full        26.37
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measured_fraction_theta_full 0.996
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_h_max       32
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_l_min       -38
_diffrn_reflns_limit_l_max       38

_refine_special_details          
;
;

_reflns_number_total             17155
_reflns_number_gt                8946
_reflns_threshold_expression     'I > 2σ(I)'

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_R_factor_all          0.1457
_refine_ls_R_factor_gt           0.0651
_refine_ls_wR_factor_gt          0.1924
_refine_ls_wR_factor_ref         0.2604
_refine_ls_goodness_of_fit_ref   0.945
_refine_ls_restrained_S_all      0.916
_refine_ls_number_reflns         17155
_refine_ls_number_parameters     945
_refine_ls_number_restraints     1407
_refine_ls_hydrogen_treatment    constr
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1328P)²+1211.0684P] where P=(Fo²+2Fc²)/3'

_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap

_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_diff_density_max         4.394
_refine_diff_density_min         -5.426
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_computing_data_collection       'Bruker SMART APEXII'
_computing_cell_refinement       'SAINT V8.34A (Bruker AXS Inc., 2013)'
_computing_data_reduction        'SAINT V8.34A (Bruker AXS Inc., 2013)'
_computing_structure_solution    'SHELXS-2013 (Sheldrick, 2013)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_molecular_graphics    'XSHELL V6.3.1 (BruekrAXS)'
_computing_publication_material  'Generate Report (Bruker AXS)'

loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_refinement_flags_posn
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C C3K 0.7708(8) 0.1032(12) 0.8732(8) 0.098(9) Uani d U . G 1 . .
C C4K 0.7778(9) 0.0705(12) 0.9122(8) 0.115(11) Uani d U . G 1 . .
H H4K 0.8113 0.0544 0.9228 0.138 Uiso calc U . R 1 . .
C C5K 0.7356(12) 0.0613(13) 0.9357(7) 0.126(12) Uani d U . G 1 . .
H H5K 0.7404 0.0389 0.9624 0.152 Uiso calc U . R 1 . .
C C6K 0.6865(10) 0.0848(14) 0.9202(9) 0.132(13) Uani d U . G 1 . .
H H6K 0.6578 0.0785 0.9362 0.158 Uiso calc U . R 1 . .
C C7K 0.6796(7) 0.1176(13) 0.8811(10) 0.132(13) Uani d U . G 1 . .
H H7K 0.646 0.1336 0.8705 0.158 Uiso calc U . R 1 . .
C C8K 0.7217(9) 0.1268(12) 0.8576(7) 0.118(11) Uani d U . G 1 . .
H H8K 0.7169 0.1491 0.8309 0.141 Uiso calc U . R 1 . .
Au Au1 0.94412(3) 0.01034(5) 0.74773(3) 0.0430(2) Uani d U . . 1 . .
Au Au2 0.90360(3) 0.12104(5) 0.70092(3) 0.0452(2) Uani d U . . 1 . .
Au Au3 1.05576(3) 0.23200(5) 0.74999(3) 0.0467(3) Uani d U . . 1 . .
Au Au4 0.98932(3) 0.18995(5) 0.67335(3) 0.0455(2) Uani d U . . 1 . .
Au Au5 0.99303(3) 0.05248(5) 0.67464(3) 0.0449(2) Uani d U . . 1 . .
Au Au6 0.91404(3) 0.12231(5) 0.79527(3) 0.0454(2) Uani d U . . 1 . .
Au Au7 1.0 0.12171(6) 0.75 0.0402(3) Uani d TU P S 1 . .
C C1A 0.9124(9) -0.1529(13) 0.7413(7) 0.051(6) Uani d U . . 1 . .
C C2A 0.9098(11) -0.2030(14) 0.7127(8) 0.068(7) Uani d U . . 1 . .
H H2A 0.9004 -0.1983 0.6823 0.081 Uiso calc U . R 1 . .
C C3A 0.9222(11) -0.2604(14) 0.7318(10) 0.068(7) Uani d U . . 1 . .
H H3A 0.92 -0.2966 0.7138 0.082 Uiso calc U . R 1 . .
C C4A 0.9366(9) -0.2679(16) 0.7733(10) 0.076(8) Uani d U . . 1 . .
H H4A 0.9455 -0.3087 0.7842 0.091 Uiso calc U . R 1 . .
C C5A 0.9392(11) -0.2176(15) 0.8013(10) 0.077(8) Uani d U . . 1 . .
H H5A 0.9492 -0.2233 0.8316 0.092 Uiso calc U . R 1 . .
C C6A 0.9271(10) -0.1601(14) 0.7847(9) 0.066(7) Uani d U . . 1 . .
H H6A 0.9288 -0.1245 0.8034 0.079 Uiso calc U . R 1 . .
C C1B 0.8272(9) -0.0653(13) 0.7306(8) 0.054(6) Uani d U . . 1 . .
C C2B 0.7897(9) -0.1073(13) 0.7124(9) 0.063(7) Uani d U . . 1 . .
H H2B 0.7996 -0.1421 0.6961 0.075 Uiso calc U . R 1 . .
C C3B 0.7383(11) -0.0986(15) 0.7180(10) 0.075(8) Uani d U . . 1 . .
H H3B 0.7129 -0.1274 0.7051 0.09 Uiso calc U . R 1 . .
C C4B 0.7222(10) -0.0483(15) 0.7421(10) 0.072(7) Uani d U . . 1 . .
H H4B 0.6862 -0.043 0.7453 0.086 Uiso calc U . R 1 . .
C C5B 0.7591(10) -0.0063(15) 0.7614(10) 0.074(8) Uani d U . . 1 . .
H H5B 0.7485 0.028 0.7779 0.089 Uiso calc U . R 1 . .
C C6B 0.8117(9) -0.0149(13) 0.7564(8) 0.057(6) Uani d U . . 1 . .
H H6B 0.8373 0.0131 0.7702 0.068 Uiso calc U . R 1 . .
C C1C 0.8000(10) 0.0850(13) 0.6180(8) 0.061(6) Uani d U . . 1 . .
C C2C 0.7914(12) 0.0898(15) 0.5726(8) 0.073(8) Uani d U . . 1 . .
H H2C 0.8032 0.1257 0.5583 0.087 Uiso calc U . R 1 . .
C C3C 0.7659(14) 0.0426(17) 0.5493(10) 0.092(9) Uani d U . . 1 . .
H H3C 0.7598 0.0464 0.5186 0.11 Uiso calc U . R 1 . .
C C4C 0.7490(12) -0.0095(15) 0.5683(8) 0.073(8) Uani d U . . 1 . .
H H4C 0.7324 -0.0427 0.5513 0.088 Uiso calc U . R 1 . .
C C5C 0.7565(11) -0.0130(13) 0.6125(9) 0.069(7) Uani d U . . 1 . .
H H5C 0.7428 -0.0481 0.6264 0.083 Uiso calc U . R 1 . .
C C6C 0.7823(10) 0.0310(13) 0.6370(8) 0.063(7) Uani d U . . 1 . .
H H6C 0.7886 0.0255 0.6675 0.075 Uiso calc U . R 1 . .
C C1D 0.7817(9) 0.1848(13) 0.6794(9) 0.062(7) Uani d U . . 1 . .
C C2D 0.7829(9) 0.1857(14) 0.7228(9) 0.067(7) Uani d U . . 1 . .
H H2D 0.8108 0.1649 0.7399 0.08 Uiso calc U . R 1 . .
C C3D 0.7450(12) 0.2158(15) 0.7436(11) 0.081(8) Uani d U . . 1 . .
H H3D 0.7475 0.2169 0.7744 0.098 Uiso calc U . R 1 . .
C C4D 0.7059(11) 0.2424(16) 0.7197(11) 0.084(9) Uani d U . . 1 . .
H H4D 0.6802 0.2638 0.7338 0.101 Uiso calc U . R 1 . .
C C5D 0.7000(11) 0.2409(15) 0.6744(11) 0.076(8) Uani d U . . 1 . .
H H5D 0.6705 0.2598 0.658 0.091 Uiso calc U . R 1 . .
C C6D 0.7374(10) 0.2119(14) 0.6545(9) 0.068(7) Uani d U . . 1 . .
H H6D 0.7339 0.2095 0.6237 0.082 Uiso calc U . R 1 . .
C C1E 1.1172(11) 0.3758(13) 0.7834(9) 0.064(7) Uani d U . . 1 . .
C C2E 1.1609(12) 0.3433(15) 0.8046(9) 0.076(8) Uani d U . . 1 . .
H H2E 1.1677 0.3013 0.7965 0.091 Uiso calc U . R 1 . .
C C3E 1.1926(13) 0.3715(15) 0.8362(10) 0.080(8) Uani d U . . 1 . .
H H3E 1.2226 0.3501 0.8499 0.095 Uiso calc U . R 1 . .
C C4E 1.1816(14) 0.4300(17) 0.8483(10) 0.090(9) Uani d U . . 1 . .
H H4E 1.2044 0.45 0.8705 0.107 Uiso calc U . R 1 . .
C C5E 1.1371(12) 0.4626(17) 0.8288(11) 0.085(9) Uani d U . . 1 . .
H H5E 1.1287 0.5031 0.8388 0.102 Uiso calc U . R 1 . .
C C6E 1.1071(10) 0.4353(14) 0.7963(10) 0.072(8) Uani d U . . 1 . .
H H6E 1.0782 0.4577 0.7818 0.086 Uiso calc U . R 1 . .
C C1F 1.1056(10) 0.3488(15) 0.6902(9) 0.066(7) Uani d U . . 1 . .
C C2F 1.1065(10) 0.4057(14) 0.6699(9) 0.062(7) Uani d U . . 1 . .
H H2F 1.0914 0.4416 0.6819 0.074 Uiso calc U . R 1 . .
C C3F 1.1293(12) 0.4111(15) 0.6320(9) 0.074(8) Uani d U . . 1 . .
H H3F 1.1305 0.4509 0.6183 0.089 Uiso calc U . R 1 . .
C C4F 1.1500(14) 0.3606(16) 0.6143(10) 0.088(9) Uani d U . . 1 . .
H H4F 1.1652 0.3652 0.5881 0.105 Uiso calc U . R 1 . .
C C5F 1.1495(14) 0.3031(18) 0.6333(11) 0.094(9) Uani d U . . 1 . .
H H5F 1.1645 0.2681 0.6204 0.112 Uiso calc U . R 1 . .
C C6F 1.1274(11) 0.2957(16) 0.6707(9) 0.073(8) Uani d U . . 1 . .
H H6F 1.1266 0.2554 0.6838 0.088 Uiso calc U . R 1 . .
C C1G 1.0025(11) 0.2079(15) 0.5649(8) 0.069(7) Uani d U . . 1 . .
C C2G 1.0498(12) 0.1801(14) 0.5763(9) 0.071(7) Uani d U . . 1 . .
H H2G 1.0582 0.1675 0.6057 0.086 Uiso calc U . R 1 . .
C C3G 1.0857(14) 0.1690(16) 0.5486(10) 0.087(9) Uani d U . . 1 . .
H H3G 1.1187 0.1505 0.558 0.105 Uiso calc U . R 1 . .
C C4G 1.0712(16) 0.1867(18) 0.5052(11) 0.101(10) Uani d U . . 1 . .
H H4G 1.0951 0.1798 0.4846 0.122 Uiso calc U . R 1 . .
C C5G 1.0239(14) 0.2134(15) 0.4918(10) 0.082(8) Uani d U . . 1 . .
H H5G 1.0147 0.2243 0.4622 0.099 Uiso calc U . R 1 . .
C C6G 0.9907(13) 0.2240(15) 0.5210(9) 0.075(8) Uani d U . . 1 . .
H H6G 0.9579 0.2431 0.5117 0.09 Uiso calc U . R 1 . .
C C1H 0.9456(10) 0.3119(13) 0.5962(8) 0.062(7) Uani d U . . 1 . .
C C2H 0.8985(12) 0.3338(15) 0.5740(9) 0.075(8) Uani d U . . 1 . .
H H2H 0.8706 0.3058 0.5648 0.09 Uiso calc U . R 1 . .
C C3H 0.8944(12) 0.3957(16) 0.5663(10) 0.081(8) Uani d U . . 1 . .
H H3H 0.864 0.411 0.5491 0.097 Uiso calc U . R 1 . .
C C4H 0.9314(12) 0.4368(17) 0.5819(9) 0.079(8) Uani d U . . 1 . .
H H4H 0.9262 0.4804 0.5764 0.095 Uiso calc U . R 1 . .
C C5H 0.9777(12) 0.4164(15) 0.6061(9) 0.074(8) Uani d U . . 1 . .
H H5H 1.0037 0.4454 0.6178 0.089 Uiso calc U . R 1 . .
C C6H 0.9842(10) 0.3526(14) 0.6124(8) 0.060(6) Uani d U . . 1 . .
H H6H 1.0156 0.3369 0.628 0.072 Uiso calc U . R 1 . .
C C1I 1.0469(10) -0.0646(13) 0.6169(7) 0.056(6) Uani d U . . 1 . .
C C2I 1.0943(9) -0.0332(15) 0.6331(7) 0.063(7) Uani d U . . 1 . .
H H2I 1.0927 0.0068 0.6465 0.076 Uiso calc U . R 1 . .
C C3I 1.1410(10) -0.0594(14) 0.6297(8) 0.066(7) Uani d U . . 1 . .
H H3I 1.1724 -0.0396 0.6422 0.079 Uiso calc U . R 1 . .
C C4I 1.1429(12) -0.1160(15) 0.6075(9) 0.077(8) Uani d U . . 1 . .
H H4I 1.1758 -0.1334 0.6029 0.093 Uiso calc U . R 1 . .
C C5I 1.0956(12) -0.1487(16) 0.5914(9) 0.077(8) Uani d U . . 1 . .
H H5I 1.0966 -0.1887 0.578 0.092 Uiso calc U . R 1 . .
C C6I 1.0500(11) -0.1202(14) 0.5962(7) 0.063(7) Uani d U . . 1 . .
H H6I 1.0184 -0.1401 0.5844 0.076 Uiso calc U . R 1 . .
C C1J 0.9499(9) -0.0131(12) 0.5730(6) 0.048(5) Uani d U . . 1 . .
C C2J 0.9683(10) 0.0385(14) 0.5500(7) 0.061(6) Uani d U . . 1 . .
H H2J 0.9972 0.063 0.5623 0.073 Uiso calc U . R 1 . .
C C3J 0.9439(12) 0.0519(14) 0.5106(9) 0.072(7) Uani d U . . 1 . .
H H3J 0.9579 0.0844 0.4944 0.086 Uiso calc U . R 1 . .
C C4J 0.9011(12) 0.0225(14) 0.4928(9) 0.073(8) Uani d U . . 1 . .
H H4J 0.8836 0.0359 0.4656 0.087 Uiso calc U . R 1 . .
C C5J 0.8822(12) -0.0293(16) 0.5149(8) 0.078(8) Uani d U . . 1 . .
H H5J 0.8537 -0.0538 0.502 0.094 Uiso calc U . R 1 . .
C C6J 0.9070(11) -0.0433(15) 0.5568(8) 0.070(7) Uani d U . . 1 . .
H H6J 0.8928 -0.0748 0.5737 0.084 Uiso calc U . R 1 . .
C C1K 0.8518(9) 0.1187(13) 0.8289(7) 0.051(6) Uani d U . . 1 . .
C C2K 0.8195(13) 0.1134(15) 0.8495(11) 0.079(8) Uani d U . . 1 . .
C C1X 0.8961(9) -0.0769(12) 0.6627(7) 0.051(6) Uani d U . . 1 . .
H H1X1 0.8703 -0.1086 0.6505 0.061 Uiso calc U . R 1 . .
H H1X2 0.8848 -0.0356 0.6502 0.061 Uiso calc U . R 1 . .
C C2X 0.9497(9) -0.0932(12) 0.6485(8) 0.056(6) Uani d U . . 1 . .
H H2X1 0.9447 -0.1267 0.6263 0.067 Uiso calc U . R 1 . .
H H2X2 0.9721 -0.1107 0.6739 0.067 Uiso calc U . R 1 . .
C C1Y 0.8532(9) 0.2060(11) 0.6152(7) 0.052(6) Uani d U . . 1 . .
H H1Y1 0.8221 0.2183 0.595 0.063 Uiso calc U . R 1 . .
H H1Y2 0.8651 0.2436 0.6324 0.063 Uiso calc U . R 1 . .
C C2Y 0.8964(9) 0.1864(12) 0.5885(7) 0.054(6) Uani d U . . 1 . .
H H2Y1 0.8852 0.1959 0.5575 0.065 Uiso calc U . R 1 . .
H H2Y2 0.9017 0.1404 0.5912 0.065 Uiso calc U . R 1 . .
C C1Z 1.0166(10) 0.3787(13) 0.7320(8) 0.064(7) Uani d U . . 1 . .
H H1Z1 1.0254 0.4229 0.7259 0.077 Uiso calc U . R 1 . .
H H1Z2 0.9953 0.3623 0.7057 0.077 Uiso calc U . R 1 . .
P P1 0.8952(2) -0.0736(3) 0.7218(2) 0.0503(15) Uani d U . . 1 . .
P P2 0.8330(2) 0.1463(3) 0.6526(2) 0.0524(16) Uani d U . . 1 . .
P P3 1.0763(2) 0.3351(4) 0.7396(2) 0.0573(17) Uani d U . . 1 . .
P P4 0.9591(2) 0.2266(3) 0.6056(2) 0.0531(16) Uani d U . . 1 . .
P P5 0.9845(2) -0.0284(3) 0.62672(18) 0.0504(15) Uani d U . . 1 . .
P P1A 0.6895(7) 0.2890(8) 0.9209(5) 0.209(8) Uani d U . D 1 . .
P P1B 0.75 0.25 0.5 0.243(14) Uani d U P DS 1 . .
F F1A 0.7492(9) 0.2646(16) 0.9347(11) 0.31(2) Uani d U . D 1 . .
F F2A 0.6293(9) 0.3128(15) 0.9079(9) 0.240(18) Uani d U . D 1 . .
F F3A 0.7105(12) 0.3451(13) 0.8921(10) 0.261(19) Uani d U . D 1 . .
F F4A 0.6839(14) 0.2429(16) 0.8786(9) 0.35(3) Uani d U . D 1 . .
F F5A 0.6681(13) 0.2325(13) 0.9500(11) 0.32(2) Uani d U . D 1 . .
F F6A 0.6950(13) 0.3349(15) 0.9635(9) 0.30(2) Uani d U . D 1 . .
F F1B 0.7318(11) 0.1786(8) 0.4870(9) 0.27(2) Uani d U . D 1 . .
F F2B 0.6911(6) 0.2754(11) 0.4897(8) 0.240(18) Uani d U . D 1 . .
F F3B 0.7616(9) 0.2633(13) 0.4509(5) 0.26(2) Uani d U . D 1 . .
N N1V 0.871(3) 0.569(4) 0.833(3) 0.33(4) Uani d U . D 1 . .
N N2V 0.112(2) 0.460(3) 0.5137(16) 0.22(2) Uani d U . D 1 . .
C C1V 0.855(2) 0.587(2) 0.757(2) 0.20(2) Uani d U . D 1 . .
H H1V1 0.8309 0.559 0.7399 0.301 Uiso calc U . R 1 . .
H H1V2 0.8914 0.5732 0.7552 0.301 Uiso calc U . R 1 . .
H H1V3 0.8511 0.6301 0.7448 0.301 Uiso calc U . R 1 . .
C C2V 0.845(3) 0.588(4) 0.802(2) 0.22(3) Uani d U . D 1 . .
C C3V 0.020(3) 0.405(4) 0.504(3) 0.35(4) Uani d U . D 1 . .
H H3V1 0.0061 0.4055 0.5317 0.528 Uiso calc U . R 1 . .
H H3V2 0.0194 0.3618 0.4924 0.528 Uiso calc U . R 1 . .
H H3V3 -0.0012 0.432 0.4831 0.528 Uiso calc U . R 1 . .
C C4V 0.075(3) 0.428(4) 0.509(3) 0.29(4) Uani d U . D 1 . .
O O1W 0.038(2) 0.613(4) 0.582(3) 0.54(4) Uani d U . D 1 . .
C C1W -0.026(2) 0.673(3) 0.6119(15) 0.29(3) Uani d U . D 1 . .
H H1W1 -0.0632 0.6647 0.6116 0.442 Uiso calc U . R 1 . .
H H1W2 -0.0197 0.694 0.5847 0.442 Uiso calc U . R 1 . .
H H1W3 -0.014 0.7009 0.6365 0.442 Uiso calc U . R 1 . .
C C2W 0.005(4) 0.612(3) 0.617(3) 0.47(4) Uani d U . D 1 . .
H H2W1 0.0257 0.6092 0.6453 0.563 Uiso calc U . R 1 . .
H H2W2 -0.0196 0.5755 0.6131 0.563 Uiso calc U . R 1 . .
C C3W 0.121(3) 0.635(4) 0.561(2) 0.29(3) Uani d U . D 1 . .
H H3W1 0.1065 0.6011 0.5416 0.438 Uiso calc U . R 1 . .
H H3W2 0.1512 0.6188 0.5801 0.438 Uiso calc U . R 1 . .
H H3W3 0.1333 0.6691 0.5429 0.438 Uiso calc U . R 1 . .
C C4W 0.080(4) 0.660(4) 0.587(4) 0.52(4) Uani d U . D 1 . .
H H4W1 0.0939 0.6641 0.6184 0.623 Uiso calc U . R 1 . .
H H4W2 0.0665 0.7014 0.5765 0.623 Uiso calc U . R 1 . .


_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix.  The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry.  An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
C3K C4K . 1.39 ?
C3K C8K . 1.39 ?
C3K C2K . 1.54(4) ?
C4K C5K . 1.39 ?
C4K H4K . 0.95 ?
C5K C6K . 1.39 ?
C5K H5K . 0.95 ?
C6K C7K . 1.39 ?
C6K H6K . 0.95 ?
C7K C8K . 1.39 ?
C7K H7K . 0.95 ?
C8K H8K . 0.95 ?
Au1 P1 . 2.275(7) ?
Au1 Au7 . 2.7673(15) ?
Au1 Au1 2_756 2.8610(16) ?
Au1 Au5 . 2.8643(12) ?
Au1 Au5 2_756 2.8776(12) ?
Au1 Au2 . 2.8940(13) ?
Au1 Au6 . 2.9524(13) ?
Au2 P2 . 2.277(6) ?
Au2 Au7 . 2.7498(8) ?
Au2 Au4 . 2.8621(13) ?
Au2 Au6 . 2.9057(12) ?
Au2 Au5 . 2.9206(13) ?
Au2 Au3 2_756 2.9325(13) ?
Au3 P3 . 2.289(8) ?
Au3 Au7 . 2.7495(15) ?
Au3 Au3 2_756 2.8681(17) ?
Au3 Au6 2_756 2.8770(14) ?
Au3 Au4 . 2.8977(12) ?
Au3 Au4 2_756 2.9075(13) ?
Au3 Au2 2_756 2.9325(13) ?
Au4 P4 . 2.288(6) ?
Au4 Au7 . 2.7705(11) ?
Au4 Au3 2_756 2.9075(13) ?
Au4 Au5 . 2.9258(14) ?
Au4 Au6 2_756 2.9354(12) ?
Au5 P5 . 2.267(7) ?
Au5 Au7 . 2.7497(11) ?
Au5 Au6 2_756 2.8735(12) ?
Au5 Au1 2_756 2.8776(12) ?
Au6 C1K . 2.01(2) ?
Au6 Au7 . 2.7570(8) ?
Au6 Au5 2_756 2.8735(12) ?
Au6 Au3 2_756 2.8769(14) ?
Au6 Au4 2_756 2.9355(12) ?
Au7 Au3 2_756 2.7494(15) ?
Au7 Au5 2_756 2.7498(11) ?
Au7 Au2 2_756 2.7499(8) ?
Au7 Au6 2_756 2.7570(8) ?
Au7 Au1 2_756 2.7674(15) ?
Au7 Au4 2_756 2.7705(11) ?
C1A C6A . 1.36(3) ?
C1A C2A . 1.38(4) ?
C1A P1 . 1.83(3) ?
C2A C3A . 1.38(4) ?
C2A H2A . 0.95 ?
C3A C4A . 1.30(4) ?
C3A H3A . 0.95 ?
C4A C5A . 1.37(4) ?
C4A H4A . 0.95 ?
C5A C6A . 1.35(4) ?
C5A H5A . 0.95 ?
C6A H6A . 0.95 ?
C1B C2B . 1.38(3) ?
C1B C6B . 1.42(4) ?
C1B P1 . 1.81(2) ?
C2B C3B . 1.36(4) ?
C2B H2B . 0.95 ?
C3B C4B . 1.40(4) ?
C3B H3B . 0.95 ?
C4B C5B . 1.39(4) ?
C4B H4B . 0.95 ?
C5B C6B . 1.39(3) ?
C5B H5B . 0.95 ?
C6B H6B . 0.95 ?
C1C C6C . 1.39(4) ?
C1C C2C . 1.40(3) ?
C1C P2 . 1.83(3) ?
C2C C3C . 1.36(4) ?
C2C H2C . 0.95 ?
C3C C4C . 1.35(4) ?
C3C H3C . 0.95 ?
C4C C5C . 1.37(3) ?
C4C H4C . 0.95 ?
C5C C6C . 1.33(3) ?
C5C H5C . 0.95 ?
C6C H6C . 0.95 ?
C1D C2D . 1.34(4) ?
C1D C6D . 1.42(3) ?
C1D P2 . 1.83(3) ?
C2D C3D . 1.39(4) ?
C2D H2D . 0.95 ?
C3D C4D . 1.31(4) ?
C3D H3D . 0.95 ?
C4D C5D . 1.39(4) ?
C4D H4D . 0.95 ?
C5D C6D . 1.35(4) ?
C5D H5D . 0.95 ?
C6D H6D . 0.95 ?
C1E C6E . 1.36(4) ?
C1E C2E . 1.41(4) ?
C1E P3 . 1.83(3) ?
C2E C3E . 1.34(4) ?
C2E H2E . 0.95 ?
C3E C4E . 1.34(4) ?
C3E H3E . 0.95 ?
C4E C5E . 1.41(5) ?
C4E H4E . 0.95 ?
C5E C6E . 1.33(4) ?
C5E H5E . 0.95 ?
C6E H6E . 0.95 ?
C1F C2F . 1.36(4) ?
C1F C6F . 1.43(4) ?
C1F P3 . 1.81(3) ?
C2F C3F . 1.38(4) ?
C2F H2F . 0.95 ?
C3F C4F . 1.34(4) ?
C3F H3F . 0.95 ?
C4F C5F . 1.36(4) ?
C4F H4F . 0.95 ?
C5F C6F . 1.36(4) ?
C5F H5F . 0.95 ?
C6F H6F . 0.95 ?
C1G C2G . 1.36(4) ?
C1G C6G . 1.40(4) ?
C1G P4 . 1.83(3) ?
C2G C3G . 1.35(4) ?
C2G H2G . 0.95 ?
C3G C4G . 1.40(4) ?
C3G H3G . 0.95 ?
C4G C5G . 1.36(5) ?
C4G H4G . 0.95 ?
C5G C6G . 1.34(4) ?
C5G H5G . 0.95 ?
C6G H6G . 0.95 ?
C1H C6H . 1.37(4) ?
C1H C2H . 1.40(3) ?
C1H P4 . 1.86(3) ?
C2H C3H . 1.34(4) ?
C2H H2H . 0.95 ?
C3H C4H . 1.34(4) ?
C3H H3H . 0.95 ?
C4H C5H . 1.40(4) ?
C4H H4H . 0.95 ?
C5H C6H . 1.38(4) ?
C5H H5H . 0.95 ?
C6H H6H . 0.95 ?
C1I C6I . 1.35(3) ?
C1I C2I . 1.43(3) ?
C1I P5 . 1.84(3) ?
C2I C3I . 1.34(3) ?
C2I H2I . 0.95 ?
C3I C4I . 1.39(4) ?
C3I H3I . 0.95 ?
C4I C5I . 1.44(4) ?
C4I H4I . 0.95 ?
C5I C6I . 1.34(4) ?
C5I H5I . 0.95 ?
C6I H6I . 0.95 ?
C1J C6J . 1.32(3) ?
C1J C2J . 1.42(4) ?
C1J P5 . 1.82(2) ?
C2J C3J . 1.33(4) ?
C2J H2J . 0.95 ?
C3J C4J . 1.33(4) ?
C3J H3J . 0.95 ?
C4J C5J . 1.41(4) ?
C4J H4J . 0.95 ?
C5J C6J . 1.41(3) ?
C5J H5J . 0.95 ?
C6J H6J . 0.95 ?
C1K C2K . 1.11(4) ?
C1X C2X . 1.54(3) ?
C1X P1 . 1.84(2) ?
C1X H1X1 . 0.99 ?
C1X H1X2 . 0.99 ?
C2X P5 . 1.82(3) ?
C2X H2X1 . 0.99 ?
C2X H2X2 . 0.99 ?
C1Y C2Y . 1.52(3) ?
C1Y P2 . 1.83(2) ?
C1Y H1Y1 . 0.99 ?
C1Y H1Y2 . 0.99 ?
C2Y P4 . 1.85(2) ?
C2Y H2Y1 . 0.99 ?
C2Y H2Y2 . 0.99 ?
C1Z C1Z 2_756 1.49(5) ?
C1Z P3 . 1.78(3) ?
C1Z H1Z1 . 0.99 ?
C1Z H1Z2 . 0.99 ?
P1A F3A . 1.621(16) ?
P1A F1A . 1.630(16) ?
P1A F4A . 1.632(16) ?
P1A F5A . 1.637(16) ?
P1A F2A . 1.633(16) ?
P1A F6A . 1.634(16) ?
P1B F2B . 1.605(14) ?
P1B F2B 7_656 1.605(14) ?
P1B F3B 7_656 1.612(15) ?
P1B F3B . 1.612(15) ?
P1B F1B . 1.625(16) ?
P1B F1B 7_656 1.626(16) ?
N1V C2V . 1.16(2) ?
N2V C4V . 1.171(19) ?
C1V C2V . 1.46(2) ?
C1V H1V1 . 0.98 ?
C1V H1V2 . 0.98 ?
C1V H1V3 . 0.98 ?
C3V C4V . 1.474(19) ?
C3V H3V1 . 0.98 ?
C3V H3V2 . 0.98 ?
C3V H3V3 . 0.98 ?
O1W C4W . 1.45(2) ?
O1W C2W . 1.45(2) ?
C1W C2W . 1.52(2) ?
C1W H1W1 . 0.98 ?
C1W H1W2 . 0.98 ?
C1W H1W3 . 0.98 ?
C2W H2W1 . 0.99 ?
C2W H2W2 . 0.99 ?
C3W C4W . 1.53(2) ?
C3W H3W1 . 0.98 ?
C3W H3W2 . 0.98 ?
C3W H3W3 . 0.98 ?
C4W H4W1 . 0.99 ?
C4W H4W2 . 0.99 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
C4K C3K C8K . . 120.0 ?
C4K C3K C2K . . 117.(2) ?
C8K C3K C2K . . 123.(2) ?
C5K C4K C3K . . 120.0 ?
C5K C4K H4K . . 120.0 ?
C3K C4K H4K . . 120.0 ?
C4K C5K C6K . . 120.0 ?
C4K C5K H5K . . 120.0 ?
C6K C5K H5K . . 120.0 ?
C7K C6K C5K . . 120.0 ?
C7K C6K H6K . . 120.0 ?
C5K C6K H6K . . 120.0 ?
C8K C7K C6K . . 120.0 ?
C8K C7K H7K . . 120.0 ?
C6K C7K H7K . . 120.0 ?
C7K C8K C3K . . 120.0 ?
C7K C8K H8K . . 120.0 ?
C3K C8K H8K . . 120.0 ?
P1 Au1 Au7 . . 160.81(16) ?
P1 Au1 Au1 . 2_756 121.78(17) ?
Au7 Au1 Au1 . 2_756 58.88(2) ?
P1 Au1 Au5 . . 104.02(16) ?
Au7 Au1 Au5 . . 58.42(3) ?
Au1 Au1 Au5 2_756 . 60.35(3) ?
P1 Au1 Au5 . 2_756 140.50(16) ?
Au7 Au1 Au5 . 2_756 58.26(3) ?
Au1 Au1 Au5 2_756 2_756 59.89(3) ?
Au5 Au1 Au5 . 2_756 107.97(4) ?
P1 Au1 Au2 . . 108.11(17) ?
Au7 Au1 Au2 . . 58.07(3) ?
Au1 Au1 Au2 2_756 . 108.91(3) ?
Au5 Au1 Au2 . . 60.95(3) ?
Au5 Au1 Au2 2_756 . 107.38(4) ?
P1 Au1 Au6 . . 130.03(17) ?
Au7 Au1 Au6 . . 57.53(3) ?
Au1 Au1 Au6 2_756 . 107.29(3) ?
Au5 Au1 Au6 . . 107.98(4) ?
Au5 Au1 Au6 2_756 . 59.04(3) ?
Au2 Au1 Au6 . . 59.60(3) ?
P2 Au2 Au7 . . 163.49(19) ?
P2 Au2 Au4 . . 105.37(18) ?
Au7 Au2 Au4 . . 59.12(3) ?
P2 Au2 Au1 . . 137.15(19) ?
Au7 Au2 Au1 . . 58.66(4) ?
Au4 Au2 Au1 . . 108.81(4) ?
P2 Au2 Au6 . . 129.13(18) ?
Au7 Au2 Au6 . . 58.27(2) ?
Au4 Au2 Au6 . . 108.31(3) ?
Au1 Au2 Au6 . . 61.20(3) ?
P2 Au2 Au5 . . 121.80(18) ?
Au7 Au2 Au5 . . 57.92(3) ?
Au4 Au2 Au5 . . 60.78(3) ?
Au1 Au2 Au5 . . 59.02(3) ?
Au6 Au2 Au5 . . 107.73(3) ?
P2 Au2 Au3 . 2_756 111.03(19) ?
Au7 Au2 Au3 . 2_756 57.77(4) ?
Au4 Au2 Au3 . 2_756 60.22(3) ?
Au1 Au2 Au3 . 2_756 108.05(3) ?
Au6 Au2 Au3 . 2_756 59.04(3) ?
Au5 Au2 Au3 . 2_756 107.63(3) ?
P3 Au3 Au7 . . 161.26(17) ?
P3 Au3 Au3 . 2_756 104.32(17) ?
Au7 Au3 Au3 . 2_756 58.56(2) ?
P3 Au3 Au6 . 2_756 128.93(18) ?
Au7 Au3 Au6 . 2_756 58.63(3) ?
Au3 Au3 Au6 2_756 2_756 109.17(3) ?
P3 Au3 Au4 . . 107.66(17) ?
Au7 Au3 Au4 . . 58.69(3) ?
Au3 Au3 Au4 2_756 . 60.56(3) ?
Au6 Au3 Au4 2_756 . 61.10(3) ?
P3 Au3 Au4 . 2_756 122.10(18) ?
Au7 Au3 Au4 . 2_756 58.57(3) ?
Au3 Au3 Au4 2_756 2_756 60.22(3) ?
Au6 Au3 Au4 2_756 2_756 107.86(4) ?
Au4 Au3 Au4 . 2_756 108.78(4) ?
P3 Au3 Au2 . 2_756 140.45(16) ?
Au7 Au3 Au2 . 2_756 57.78(3) ?
Au3 Au3 Au2 2_756 2_756 107.12(3) ?
Au6 Au3 Au2 2_756 2_756 60.02(3) ?
Au4 Au3 Au2 . 2_756 108.42(4) ?
Au4 Au3 Au2 2_756 2_756 58.69(3) ?
P4 Au4 Au7 . . 162.60(17) ?
P4 Au4 Au2 . . 105.04(17) ?
Au7 Au4 Au2 . . 58.42(2) ?
P4 Au4 Au3 . . 138.59(18) ?
Au7 Au4 Au3 . . 57.98(3) ?
Au2 Au4 Au3 . . 108.23(4) ?
P4 Au4 Au3 . 2_756 121.37(18) ?
Au7 Au4 Au3 . 2_756 57.86(3) ?
Au2 Au4 Au3 . 2_756 61.09(3) ?
Au3 Au4 Au3 . 2_756 59.21(3) ?
P4 Au4 Au5 . . 111.13(19) ?
Au7 Au4 Au5 . . 57.65(3) ?
Au2 Au4 Au5 . . 60.60(3) ?
Au3 Au4 Au5 . . 106.39(4) ?
Au3 Au4 Au5 2_756 . 108.16(4) ?
P4 Au4 Au6 . 2_756 130.76(18) ?
Au7 Au4 Au6 . 2_756 57.70(2) ?
Au2 Au4 Au6 . 2_756 107.58(4) ?
Au3 Au4 Au6 . 2_756 59.10(3) ?
Au3 Au4 Au6 2_756 2_756 106.52(3) ?
Au5 Au4 Au6 . 2_756 58.72(3) ?
P5 Au5 Au7 . . 162.73(17) ?
P5 Au5 Au1 . . 105.31(17) ?
Au7 Au5 Au1 . . 59.02(3) ?
P5 Au5 Au6 . 2_756 128.07(17) ?
Au7 Au5 Au6 . 2_756 58.67(3) ?
Au1 Au5 Au6 . 2_756 109.38(3) ?
P5 Au5 Au1 . 2_756 108.20(16) ?
Au7 Au5 Au1 . 2_756 58.86(3) ?
Au1 Au5 Au1 . 2_756 59.77(3) ?
Au6 Au5 Au1 2_756 2_756 61.78(3) ?
P5 Au5 Au2 . . 122.98(17) ?
Au7 Au5 Au2 . . 57.92(2) ?
Au1 Au5 Au2 . . 60.03(3) ?
Au6 Au5 Au2 2_756 . 107.67(4) ?
Au1 Au5 Au2 2_756 . 107.73(3) ?
P5 Au5 Au4 . . 138.53(17) ?
Au7 Au5 Au4 . . 58.34(3) ?
Au1 Au5 Au4 . . 107.87(4) ?
Au6 Au5 Au4 2_756 . 60.81(3) ?
Au1 Au5 Au4 2_756 . 109.69(4) ?
Au2 Au5 Au4 . . 58.62(3) ?
C1K Au6 Au7 . . 177.4(8) ?
C1K Au6 Au5 . 2_756 119.6(7) ?
Au7 Au6 Au5 . 2_756 58.42(3) ?
C1K Au6 Au3 . 2_756 124.2(8) ?
Au7 Au6 Au3 . 2_756 58.37(4) ?
Au5 Au6 Au3 2_756 2_756 108.36(4) ?
C1K Au6 Au2 . . 122.5(6) ?
Au7 Au6 Au2 . . 58.03(2) ?
Au5 Au6 Au2 2_756 . 107.17(4) ?
Au3 Au6 Au2 2_756 . 60.94(3) ?
C1K Au6 Au4 . 2_756 122.8(6) ?
Au7 Au6 Au4 . 2_756 58.15(3) ?
Au5 Au6 Au4 2_756 2_756 60.47(3) ?
Au3 Au6 Au4 2_756 2_756 59.79(3) ?
Au2 Au6 Au4 . 2_756 108.12(4) ?
C1K Au6 Au1 . . 120.0(7) ?
Au7 Au6 Au1 . . 57.86(4) ?
Au5 Au6 Au1 2_756 . 59.18(3) ?
Au3 Au6 Au1 2_756 . 107.97(4) ?
Au2 Au6 Au1 . . 59.20(3) ?
Au4 Au6 Au1 2_756 . 107.39(3) ?
Au3 Au7 Au3 2_756 . 62.88(5) ?
Au3 Au7 Au5 2_756 . 118.43(3) ?
Au3 Au7 Au5 . . 115.97(3) ?
Au3 Au7 Au5 2_756 2_756 115.97(3) ?
Au3 Au7 Au5 . 2_756 118.42(3) ?
Au5 Au7 Au5 . 2_756 115.24(6) ?
Au3 Au7 Au2 2_756 . 64.45(3) ?
Au3 Au7 Au2 . . 116.12(5) ?
Au5 Au7 Au2 . . 64.15(3) ?
Au5 Au7 Au2 2_756 . 115.49(4) ?
Au3 Au7 Au2 2_756 2_756 116.11(5) ?
Au3 Au7 Au2 . 2_756 64.45(3) ?
Au5 Au7 Au2 . 2_756 115.49(4) ?
Au5 Au7 Au2 2_756 2_756 64.15(3) ?
Au2 Au7 Au2 . 2_756 179.40(7) ?
Au3 Au7 Au6 2_756 . 63.00(3) ?
Au3 Au7 Au6 . . 116.50(5) ?
Au5 Au7 Au6 . . 117.41(4) ?
Au5 Au7 Au6 2_756 . 62.91(3) ?
Au2 Au7 Au6 . . 63.70(2) ?
Au2 Au7 Au6 2_756 . 116.31(2) ?
Au3 Au7 Au6 2_756 2_756 116.49(5) ?
Au3 Au7 Au6 . 2_756 63.00(3) ?
Au5 Au7 Au6 . 2_756 62.91(3) ?
Au5 Au7 Au6 2_756 2_756 117.41(4) ?
Au2 Au7 Au6 . 2_756 116.31(2) ?
Au2 Au7 Au6 2_756 2_756 63.70(2) ?
Au6 Au7 Au6 . 2_756 179.47(7) ?
Au3 Au7 Au1 2_756 . 117.46(3) ?
Au3 Au7 Au1 . . 178.51(3) ?
Au5 Au7 Au1 . . 62.55(4) ?
Au5 Au7 Au1 2_756 . 62.88(4) ?
Au2 Au7 Au1 . . 63.28(3) ?
Au2 Au7 Au1 2_756 . 116.15(5) ?
Au6 Au7 Au1 . . 64.61(3) ?
Au6 Au7 Au1 2_756 . 115.89(5) ?
Au3 Au7 Au1 2_756 2_756 178.51(3) ?
Au3 Au7 Au1 . 2_756 117.46(3) ?
Au5 Au7 Au1 . 2_756 62.87(4) ?
Au5 Au7 Au1 2_756 2_756 62.55(4) ?
Au2 Au7 Au1 . 2_756 116.15(5) ?
Au2 Au7 Au1 2_756 2_756 63.28(3) ?
Au6 Au7 Au1 . 2_756 115.89(5) ?
Au6 Au7 Au1 2_756 2_756 64.61(3) ?
Au1 Au7 Au1 . 2_756 62.25(5) ?
Au3 Au7 Au4 2_756 . 63.57(4) ?
Au3 Au7 Au4 . . 63.33(4) ?
Au5 Au7 Au4 . . 64.01(3) ?
Au5 Au7 Au4 2_756 . 177.95(3) ?
Au2 Au7 Au4 . . 62.46(3) ?
Au2 Au7 Au4 2_756 . 117.90(4) ?
Au6 Au7 Au4 . . 115.54(4) ?
Au6 Au7 Au4 2_756 . 64.15(3) ?
Au1 Au7 Au4 . . 115.39(3) ?
Au1 Au7 Au4 2_756 . 117.92(3) ?
Au3 Au7 Au4 2_756 2_756 63.33(4) ?
Au3 Au7 Au4 . 2_756 63.57(4) ?
Au5 Au7 Au4 . 2_756 177.94(3) ?
Au5 Au7 Au4 2_756 2_756 64.01(3) ?
Au2 Au7 Au4 . 2_756 117.90(4) ?
Au2 Au7 Au4 2_756 2_756 62.46(3) ?
Au6 Au7 Au4 . 2_756 64.16(3) ?
Au6 Au7 Au4 2_756 2_756 115.54(4) ?
Au1 Au7 Au4 . 2_756 117.92(3) ?
Au1 Au7 Au4 2_756 2_756 115.39(3) ?
Au4 Au7 Au4 . 2_756 116.81(6) ?
C6A C1A C2A . . 122.(3) ?
C6A C1A P1 . . 117.(2) ?
C2A C1A P1 . . 120.5(19) ?
C1A C2A C3A . . 115.(2) ?
C1A C2A H2A . . 122.7 ?
C3A C2A H2A . . 122.7 ?
C4A C3A C2A . . 124.(3) ?
C4A C3A H3A . . 118.1 ?
C2A C3A H3A . . 118.1 ?
C3A C4A C5A . . 121.(3) ?
C3A C4A H4A . . 119.5 ?
C5A C4A H4A . . 119.5 ?
C6A C5A C4A . . 118.(3) ?
C6A C5A H5A . . 120.9 ?
C4A C5A H5A . . 120.9 ?
C5A C6A C1A . . 120.(3) ?
C5A C6A H6A . . 119.9 ?
C1A C6A H6A . . 119.9 ?
C2B C1B C6B . . 119.(2) ?
C2B C1B P1 . . 121.(2) ?
C6B C1B P1 . . 119.9(19) ?
C3B C2B C1B . . 120.(3) ?
C3B C2B H2B . . 120.0 ?
C1B C2B H2B . . 120.0 ?
C2B C3B C4B . . 122.(3) ?
C2B C3B H3B . . 119.1 ?
C4B C3B H3B . . 119.1 ?
C5B C4B C3B . . 120.(3) ?
C5B C4B H4B . . 120.2 ?
C3B C4B H4B . . 120.2 ?
C6B C5B C4B . . 119.(3) ?
C6B C5B H5B . . 120.3 ?
C4B C5B H5B . . 120.3 ?
C5B C6B C1B . . 120.(2) ?
C5B C6B H6B . . 119.9 ?
C1B C6B H6B . . 119.9 ?
C6C C1C C2C . . 118.(2) ?
C6C C1C P2 . . 119.6(19) ?
C2C C1C P2 . . 123.(2) ?
C3C C2C C1C . . 119.(3) ?
C3C C2C H2C . . 120.4 ?
C1C C2C H2C . . 120.4 ?
C4C C3C C2C . . 122.(3) ?
C4C C3C H3C . . 118.9 ?
C2C C3C H3C . . 118.9 ?
C3C C4C C5C . . 118.(3) ?
C3C C4C H4C . . 121.0 ?
C5C C4C H4C . . 121.0 ?
C6C C5C C4C . . 122.(3) ?
C6C C5C H5C . . 118.8 ?
C4C C5C H5C . . 118.8 ?
C5C C6C C1C . . 120.(2) ?
C5C C6C H6C . . 119.8 ?
C1C C6C H6C . . 119.8 ?
C2D C1D C6D . . 117.(3) ?
C2D C1D P2 . . 122.(2) ?
C6D C1D P2 . . 121.(2) ?
C1D C2D C3D . . 123.(3) ?
C1D C2D H2D . . 118.6 ?
C3D C2D H2D . . 118.6 ?
C4D C3D C2D . . 118.(3) ?
C4D C3D H3D . . 120.9 ?
C2D C3D H3D . . 120.9 ?
C3D C4D C5D . . 123.(3) ?
C3D C4D H4D . . 118.5 ?
C5D C4D H4D . . 118.5 ?
C6D C5D C4D . . 118.(3) ?
C6D C5D H5D . . 120.9 ?
C4D C5D H5D . . 120.9 ?
C5D C6D C1D . . 120.(3) ?
C5D C6D H6D . . 119.9 ?
C1D C6D H6D . . 119.9 ?
C6E C1E C2E . . 119.(3) ?
C6E C1E P3 . . 123.(2) ?
C2E C1E P3 . . 118.(2) ?
C3E C2E C1E . . 120.(3) ?
C3E C2E H2E . . 119.9 ?
C1E C2E H2E . . 119.9 ?
C4E C3E C2E . . 119.(3) ?
C4E C3E H3E . . 120.3 ?
C2E C3E H3E . . 120.3 ?
C3E C4E C5E . . 122.(3) ?
C3E C4E H4E . . 119.2 ?
C5E C4E H4E . . 119.2 ?
C6E C5E C4E . . 119.(3) ?
C6E C5E H5E . . 120.7 ?
C4E C5E H5E . . 120.7 ?
C5E C6E C1E . . 121.(3) ?
C5E C6E H6E . . 119.5 ?
C1E C6E H6E . . 119.5 ?
C2F C1F C6F . . 119.(3) ?
C2F C1F P3 . . 124.(3) ?
C6F C1F P3 . . 117.(2) ?
C1F C2F C3F . . 120.(3) ?
C1F C2F H2F . . 120.1 ?
C3F C2F H2F . . 120.1 ?
C4F C3F C2F . . 121.(3) ?
C4F C3F H3F . . 119.6 ?
C2F C3F H3F . . 119.6 ?
C5F C4F C3F . . 121.(3) ?
C5F C4F H4F . . 119.4 ?
C3F C4F H4F . . 119.4 ?
C4F C5F C6F . . 120.(4) ?
C4F C5F H5F . . 120.0 ?
C6F C5F H5F . . 120.0 ?
C5F C6F C1F . . 120.(3) ?
C5F C6F H6F . . 120.2 ?
C1F C6F H6F . . 120.2 ?
C2G C1G C6G . . 116.(3) ?
C2G C1G P4 . . 121.(2) ?
C6G C1G P4 . . 123.(2) ?
C3G C2G C1G . . 125.(3) ?
C3G C2G H2G . . 117.7 ?
C1G C2G H2G . . 117.7 ?
C2G C3G C4G . . 116.(3) ?
C2G C3G H3G . . 122.1 ?
C4G C3G H3G . . 122.1 ?
C5G C4G C3G . . 122.(3) ?
C5G C4G H4G . . 119.0 ?
C3G C4G H4G . . 119.0 ?
C6G C5G C4G . . 119.(3) ?
C6G C5G H5G . . 120.5 ?
C4G C5G H5G . . 120.5 ?
C5G C6G C1G . . 122.(3) ?
C5G C6G H6G . . 118.8 ?
C1G C6G H6G . . 118.8 ?
C6H C1H C2H . . 121.(3) ?
C6H C1H P4 . . 116.5(19) ?
C2H C1H P4 . . 122.(2) ?
C3H C2H C1H . . 117.(3) ?
C3H C2H H2H . . 121.3 ?
C1H C2H H2H . . 121.3 ?
C2H C3H C4H . . 123.(3) ?
C2H C3H H3H . . 118.7 ?
C4H C3H H3H . . 118.7 ?
C3H C4H C5H . . 121.(3) ?
C3H C4H H4H . . 119.5 ?
C5H C4H H4H . . 119.5 ?
C6H C5H C4H . . 118.(3) ?
C6H C5H H5H . . 121.2 ?
C4H C5H H5H . . 121.2 ?
C1H C6H C5H . . 120.(2) ?
C1H C6H H6H . . 120.0 ?
C5H C6H H6H . . 120.0 ?
C6I C1I C2I . . 119.(3) ?
C6I C1I P5 . . 123.(2) ?
C2I C1I P5 . . 118.(2) ?
C3I C2I C1I . . 121.(3) ?
C3I C2I H2I . . 119.6 ?
C1I C2I H2I . . 119.6 ?
C2I C3I C4I . . 119.(3) ?
C2I C3I H3I . . 120.5 ?
C4I C3I H3I . . 120.5 ?
C3I C4I C5I . . 121.(3) ?
C3I C4I H4I . . 119.6 ?
C5I C4I H4I . . 119.6 ?
C6I C5I C4I . . 117.(3) ?
C6I C5I H5I . . 121.3 ?
C4I C5I H5I . . 121.3 ?
C5I C6I C1I . . 123.(3) ?
C5I C6I H6I . . 118.4 ?
C1I C6I H6I . . 118.4 ?
C6J C1J C2J . . 120.(2) ?
C6J C1J P5 . . 124.(2) ?
C2J C1J P5 . . 116.2(18) ?
C3J C2J C1J . . 118.(3) ?
C3J C2J H2J . . 120.8 ?
C1J C2J H2J . . 120.8 ?
C2J C3J C4J . . 124.(3) ?
C2J C3J H3J . . 118.2 ?
C4J C3J H3J . . 118.2 ?
C3J C4J C5J . . 119.(3) ?
C3J C4J H4J . . 120.6 ?
C5J C4J H4J . . 120.6 ?
C6J C5J C4J . . 118.(3) ?
C6J C5J H5J . . 121.0 ?
C4J C5J H5J . . 121.0 ?
C1J C6J C5J . . 121.(3) ?
C1J C6J H6J . . 119.6 ?
C5J C6J H6J . . 119.6 ?
C2K C1K Au6 . . 175.(3) ?
C1K C2K C3K . . 173.(3) ?
C2X C1X P1 . . 114.3(16) ?
C2X C1X H1X1 . . 108.7 ?
P1 C1X H1X1 . . 108.7 ?
C2X C1X H1X2 . . 108.7 ?
P1 C1X H1X2 . . 108.7 ?
H1X1 C1X H1X2 . . 107.6 ?
C1X C2X P5 . . 115.7(19) ?
C1X C2X H2X1 . . 108.3 ?
P5 C2X H2X1 . . 108.3 ?
C1X C2X H2X2 . . 108.3 ?
P5 C2X H2X2 . . 108.3 ?
H2X1 C2X H2X2 . . 107.4 ?
C2Y C1Y P2 . . 115.8(17) ?
C2Y C1Y H1Y1 . . 108.3 ?
P2 C1Y H1Y1 . . 108.3 ?
C2Y C1Y H1Y2 . . 108.3 ?
P2 C1Y H1Y2 . . 108.3 ?
H1Y1 C1Y H1Y2 . . 107.4 ?
C1Y C2Y P4 . . 112.7(17) ?
C1Y C2Y H2Y1 . . 109.1 ?
P4 C2Y H2Y1 . . 109.1 ?
C1Y C2Y H2Y2 . . 109.1 ?
P4 C2Y H2Y2 . . 109.1 ?
H2Y1 C2Y H2Y2 . . 107.8 ?
C1Z C1Z P3 2_756 . 118.(2) ?
C1Z C1Z H1Z1 2_756 . 107.9 ?
P3 C1Z H1Z1 . . 107.9 ?
C1Z C1Z H1Z2 2_756 . 107.9 ?
P3 C1Z H1Z2 . . 107.9 ?
H1Z1 C1Z H1Z2 . . 107.2 ?
C1B P1 C1A . . 103.8(11) ?
C1B P1 C1X . . 106.3(11) ?
C1A P1 C1X . . 105.4(11) ?
C1B P1 Au1 . . 111.9(9) ?
C1A P1 Au1 . . 120.4(8) ?
C1X P1 Au1 . . 108.1(8) ?
C1C P2 C1Y . . 105.7(12) ?
C1C P2 C1D . . 106.0(12) ?
C1Y P2 C1D . . 104.5(13) ?
C1C P2 Au2 . . 119.7(9) ?
C1Y P2 Au2 . . 108.3(7) ?
C1D P2 Au2 . . 111.5(9) ?
C1Z P3 C1F . . 104.1(13) ?
C1Z P3 C1E . . 105.1(14) ?
C1F P3 C1E . . 106.9(11) ?
C1Z P3 Au3 . . 107.9(9) ?
C1F P3 Au3 . . 113.6(10) ?
C1E P3 Au3 . . 118.0(9) ?
C1G P4 C2Y . . 106.6(12) ?
C1G P4 C1H . . 102.9(13) ?
C2Y P4 C1H . . 105.5(12) ?
C1G P4 Au4 . . 113.0(10) ?
C2Y P4 Au4 . . 107.2(8) ?
C1H P4 Au4 . . 120.8(8) ?
C2X P5 C1J . . 105.5(12) ?
C2X P5 C1I . . 102.9(12) ?
C1J P5 C1I . . 105.3(10) ?
C2X P5 Au5 . . 110.2(9) ?
C1J P5 Au5 . . 117.5(8) ?
C1I P5 Au5 . . 114.1(8) ?
F3A P1A F1A . . 90.7(8) ?
F3A P1A F4A . . 90.1(8) ?
F1A P1A F4A . . 90.4(8) ?
F3A P1A F5A . . 179.8(11) ?
F1A P1A F5A . . 89.5(8) ?
F4A P1A F5A . . 89.9(8) ?
F3A P1A F2A . . 90.3(8) ?
F1A P1A F2A . . 179.0(10) ?
F4A P1A F2A . . 89.9(8) ?
F5A P1A F2A . . 89.5(8) ?
F3A P1A F6A . . 90.2(8) ?
F1A P1A F6A . . 89.5(8) ?
F4A P1A F6A . . 179.7(11) ?
F5A P1A F6A . . 89.8(8) ?
F2A P1A F6A . . 90.2(8) ?
F2B P1B F2B . 7_656 180.0 ?
F2B P1B F3B . 7_656 88.3(8) ?
F2B P1B F3B 7_656 7_656 91.7(8) ?
F2B P1B F3B . . 91.7(8) ?
F2B P1B F3B 7_656 . 88.3(8) ?
F3B P1B F3B 7_656 . 180.0 ?
F2B P1B F1B . . 91.7(8) ?
F2B P1B F1B 7_656 . 88.3(8) ?
F3B P1B F1B 7_656 . 89.4(9) ?
F3B P1B F1B . . 90.6(9) ?
F2B P1B F1B . 7_656 88.3(8) ?
F2B P1B F1B 7_656 7_656 91.7(8) ?
F3B P1B F1B 7_656 7_656 90.6(9) ?
F3B P1B F1B . 7_656 89.4(9) ?
F1B P1B F1B . 7_656 180.0 ?
C2V C1V H1V1 . . 109.5 ?
C2V C1V H1V2 . . 109.5 ?
H1V1 C1V H1V2 . . 109.5 ?
C2V C1V H1V3 . . 109.5 ?
H1V1 C1V H1V3 . . 109.5 ?
H1V2 C1V H1V3 . . 109.5 ?
N1V C2V C1V . . 129.(10) ?
C4V C3V H3V1 . . 109.5 ?
C4V C3V H3V2 . . 109.5 ?
H3V1 C3V H3V2 . . 109.5 ?
C4V C3V H3V3 . . 109.5 ?
H3V1 C3V H3V3 . . 109.5 ?
H3V2 C3V H3V3 . . 109.5 ?
N2V C4V C3V . . 164.(9) ?
C4W O1W C2W . . 115.(2) ?
C2W C1W H1W1 . . 109.5 ?
C2W C1W H1W2 . . 109.5 ?
H1W1 C1W H1W2 . . 109.5 ?
C2W C1W H1W3 . . 109.5 ?
H1W1 C1W H1W3 . . 109.5 ?
H1W2 C1W H1W3 . . 109.5 ?
O1W C2W C1W . . 104.9(19) ?
O1W C2W H2W1 . . 110.8 ?
C1W C2W H2W1 . . 110.8 ?
O1W C2W H2W2 . . 110.8 ?
C1W C2W H2W2 . . 110.8 ?
H2W1 C2W H2W2 . . 108.8 ?
C4W C3W H3W1 . . 109.5 ?
C4W C3W H3W2 . . 109.5 ?
H3W1 C3W H3W2 . . 109.5 ?
C4W C3W H3W3 . . 109.5 ?
H3W1 C3W H3W3 . . 109.5 ?
H3W2 C3W H3W3 . . 109.5 ?
O1W C4W C3W . . 104.8(19) ?
O1W C4W H4W1 . . 110.8 ?
C3W C4W H4W1 . . 110.8 ?
O1W C4W H4W2 . . 110.8 ?
C3W C4W H4W2 . . 110.8 ?
H4W1 C4W H4W2 . . 108.9 ?

