# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_gos18
_database_code_depnum_ccdc_archive 'CCDC 1415494'
_audit_update_record             
;
2015-07-28 deposited with the CCDC.
2015-09-04 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            '6 in manuscript'
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C60 H50 B Cl8 F4 N2 O2 P2 Rh'
_chemical_formula_weight         1366.28

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   32.934(3)
_cell_length_b                   14.4798(13)
_cell_length_c                   52.282(4)
_cell_angle_alpha                90
_cell_angle_beta                 103.448(2)
_cell_angle_gamma                90
_cell_volume                     24248(4)
_cell_formula_units_Z            16
_cell_measurement_temperature    200(2)
_cell_measurement_reflns_used    9518
_cell_measurement_theta_min      2.19
_cell_measurement_theta_max      25.20

_exptl_crystal_description       polyhedron
_exptl_crystal_colour            orange
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.497
_exptl_crystal_F_000             11072
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.18
_exptl_absorpt_coefficient_mu    0.744
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.7798
_exptl_absorpt_correction_T_max  0.8905
_exptl_absorpt_process_details   
;
Sheldrick, G. M. (2008). SADABS. University of Göttingen, Germany.
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      200(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'ImuS microsource'
_diffrn_measurement_device_type  'Bruker APEX-II Quazar area detector'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            256426
_diffrn_reflns_av_unetI/netI     0.0540
_diffrn_reflns_av_R_equivalents  0.1013
_diffrn_reflns_limit_h_min       -32
_diffrn_reflns_limit_h_max       32
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -52
_diffrn_reflns_limit_l_max       52
_diffrn_reflns_theta_min         0.636
_diffrn_reflns_theta_max         20.849
_diffrn_reflns_theta_full        20.849
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             25473
_reflns_number_gt                20758
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0530P)²+1711.7128P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         25473
_refine_ls_number_parameters     1037
_refine_ls_number_restraints     2516
_refine_ls_R_factor_all          0.2205
_refine_ls_R_factor_gt           0.1959
_refine_ls_wR_factor_ref         0.4066
_refine_ls_wR_factor_gt          0.3924
_refine_ls_goodness_of_fit_ref   1.134
_refine_ls_restrained_S_all      1.108
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1_1 Rh 0.47035(4) 0.41318(10) 0.27061(3) 0.0118(4) Uani 1 1 d D U . . .
P1_1 P 0.48322(14) 0.5021(3) 0.30840(9) 0.0124(11) Uani 1 1 d D U . . .
P2_1 P 0.42499(14) 0.3250(3) 0.28848(9) 0.0137(11) Uani 1 1 d D U . . .
Cl1_1 Cl 0.5165(3) 0.2602(9) 0.51886(14) 0.109(4) Uani 1 1 d D U . . .
Cl2_1 Cl 0.4281(4) -0.0220(9) 0.4689(3) 0.194(8) Uani 1 1 d D U . . .
Cl3_1 Cl 0.1579(2) 0.6099(8) 0.35889(19) 0.117(4) Uani 1 1 d D U . . .
Cl4_1 Cl 0.2361(5) 0.9326(9) 0.3699(4) 0.251(11) Uani 1 1 d D U . . .
C11_1 C 0.4787(3) 0.4554(8) 0.34089(15) 0.013(4) Uiso 1 1 d DG U . . .
C12_1 C 0.4400(2) 0.4314(8) 0.34526(16) 0.019(5) Uiso 1 1 d DG U . . .
C13_1 C 0.4373(2) 0.3928(9) 0.36915(19) 0.023(5) Uiso 1 1 d DG U . . .
H13_1 H 0.4109 0.3764 0.3721 0.027 Uiso 1 1 calc R U . . .
C14_1 C 0.4734(3) 0.3780(9) 0.38867(16) 0.024(5) Uiso 1 1 d DG U . . .
C15_1 C 0.5121(3) 0.4019(9) 0.38429(17) 0.022(5) Uiso 1 1 d DG U . . .
H15_1 H 0.5367 0.3919 0.3976 0.027 Uiso 1 1 calc R U . . .
C16_1 C 0.5147(2) 0.4406(9) 0.36041(19) 0.022(5) Uiso 1 1 d DG U . . .
H16_1 H 0.5412 0.4570 0.3574 0.026 Uiso 1 1 calc R U . . .
C21_1 C 0.3878(2) 0.3964(7) 0.30165(18) 0.010(4) Uiso 1 1 d DG U . . .
C22_1 C 0.3993(2) 0.4437(7) 0.32537(17) 0.012(4) Uiso 1 1 d DG U . . .
C23_1 C 0.3712(3) 0.5033(7) 0.33298(16) 0.016(4) Uiso 1 1 d DG U . . .
H23_1 H 0.3791 0.5356 0.3492 0.019 Uiso 1 1 calc R U . . .
C24_1 C 0.3316(3) 0.5156(7) 0.31687(19) 0.010(4) Uiso 1 1 d DG U . . .
C25_1 C 0.3201(2) 0.4683(8) 0.29315(18) 0.016(4) Uiso 1 1 d DG U . . .
H25_1 H 0.2930 0.4767 0.2821 0.019 Uiso 1 1 calc R U . . .
C26_1 C 0.3482(3) 0.4087(7) 0.28554(16) 0.013(4) Uiso 1 1 d DG U . . .
H26_1 H 0.3404 0.3763 0.2693 0.016 Uiso 1 1 calc R U . . .
C30_1 C 0.4449(6) 0.2745(14) 0.4185(3) 0.039(6) Uiso 1 1 d D U . . .
O30_1 O 0.4115(5) 0.2603(12) 0.4028(3) 0.060(5) Uiso 1 1 d D U . . .
N31_1 N 0.4735(5) 0.3313(11) 0.4128(3) 0.030(4) Uiso 1 1 d D U . . .
H31_1 H 0.4955 0.3414 0.4257 0.036 Uiso 1 1 calc R U . . .
C31_1 C 0.4557(5) 0.2242(10) 0.4440(2) 0.050(7) Uiso 1 1 d DG U . . .
C32_1 C 0.4806(5) 0.2632(9) 0.4665(3) 0.050(7) Uiso 1 1 d DG U . . .
H32_1 H 0.4920 0.3232 0.4658 0.060 Uiso 1 1 calc R U . . .
C33_1 C 0.4888(6) 0.2146(11) 0.4901(2) 0.068(8) Uiso 1 1 d DG U . . .
C34_1 C 0.4721(7) 0.1269(11) 0.4911(3) 0.091(10) Uiso 1 1 d DG U . . .
H34_1 H 0.4776 0.0936 0.5072 0.110 Uiso 1 1 calc R U . . .
C35_1 C 0.4472(7) 0.0878(9) 0.4686(3) 0.116(12) Uiso 1 1 d DG U . . .
C36_1 C 0.4390(6) 0.1364(11) 0.4450(3) 0.080(9) Uiso 1 1 d DG U . . .
H36_1 H 0.4220 0.1097 0.4296 0.096 Uiso 1 1 calc R U . . .
C40_1 C 0.3055(5) 0.6475(12) 0.3393(4) 0.032(5) Uiso 1 1 d D U . . .
O40_1 O 0.3393(4) 0.6858(11) 0.3459(3) 0.052(5) Uiso 1 1 d D U . . .
N41_1 N 0.2999(4) 0.5684(9) 0.3242(3) 0.020(4) Uiso 1 1 d D U . . .
H41_1 H 0.2741 0.5488 0.3185 0.025 Uiso 1 1 calc R U . . .
C41_1 C 0.2678(4) 0.6873(9) 0.3459(3) 0.042(6) Uiso 1 1 d DG U . . .
C42_1 C 0.2335(4) 0.6336(7) 0.3476(3) 0.042(6) Uiso 1 1 d DG U . . .
H42_1 H 0.2326 0.5702 0.3428 0.050 Uiso 1 1 calc R U . . .
C43_1 C 0.2007(4) 0.6727(10) 0.3564(3) 0.060(7) Uiso 1 1 d DG U . . .
C44_1 C 0.2021(4) 0.7654(10) 0.3635(4) 0.076(9) Uiso 1 1 d DG U . . .
H44_1 H 0.1796 0.7921 0.3694 0.091 Uiso 1 1 calc R U . . .
C45_1 C 0.2363(5) 0.8190(8) 0.3617(4) 0.103(11) Uiso 1 1 d DG U . . .
C46_1 C 0.2692(4) 0.7800(9) 0.3530(4) 0.074(9) Uiso 1 1 d DG U . . .
H46_1 H 0.2926 0.8166 0.3518 0.089 Uiso 1 1 calc R U . . .
C51_1 C 0.4488(3) 0.6010(7) 0.3042(2) 0.012(4) Uiso 1 1 d DG U . . .
C52_1 C 0.4182(4) 0.6098(8) 0.28103(18) 0.023(5) Uiso 1 1 d DG U . . .
H52_1 H 0.4166 0.5661 0.2673 0.027 Uiso 1 1 calc R U . . .
C53_1 C 0.3899(3) 0.6825(9) 0.2780(2) 0.036(6) Uiso 1 1 d DG U . . .
H53_1 H 0.3690 0.6885 0.2621 0.043 Uiso 1 1 calc R U . . .
C54_1 C 0.3922(4) 0.7464(8) 0.2981(3) 0.050(7) Uiso 1 1 d DG U . . .
H54_1 H 0.3729 0.7961 0.2960 0.060 Uiso 1 1 calc R U . . .
C55_1 C 0.4228(4) 0.7376(8) 0.3213(2) 0.043(6) Uiso 1 1 d DG U . . .
H55_1 H 0.4244 0.7813 0.3350 0.052 Uiso 1 1 calc R U . . .
C56_1 C 0.4511(3) 0.6649(8) 0.32433(18) 0.023(5) Uiso 1 1 d DG U . . .
H56_1 H 0.4720 0.6589 0.3402 0.027 Uiso 1 1 calc R U . . .
C61_1 C 0.5367(2) 0.5489(7) 0.3157(2) 0.014(4) Uiso 1 1 d DG U . . .
C62_1 C 0.5690(3) 0.4848(6) 0.3206(3) 0.022(5) Uiso 1 1 d DG U . . .
H62_1 H 0.5630 0.4207 0.3207 0.027 Uiso 1 1 calc R U . . .
C63_1 C 0.6102(3) 0.5146(7) 0.3254(3) 0.031(5) Uiso 1 1 d DG U . . .
H63_1 H 0.6323 0.4708 0.3288 0.037 Uiso 1 1 calc R U . . .
C64_1 C 0.6191(2) 0.6084(8) 0.3253(3) 0.032(5) Uiso 1 1 d DG U . . .
H64_1 H 0.6473 0.6287 0.3285 0.038 Uiso 1 1 calc R U . . .
C65_1 C 0.5868(3) 0.6725(6) 0.3203(3) 0.038(6) Uiso 1 1 d DG U . . .
H65_1 H 0.5929 0.7366 0.3202 0.046 Uiso 1 1 calc R U . . .
C66_1 C 0.5456(3) 0.6427(6) 0.3155(2) 0.018(5) Uiso 1 1 d DG U . . .
H66_1 H 0.5235 0.6865 0.3122 0.021 Uiso 1 1 calc R U . . .
C71_1 C 0.4537(3) 0.2533(8) 0.3153(2) 0.019(5) Uiso 1 1 d DG U . . .
C72_1 C 0.4954(4) 0.2353(10) 0.3160(2) 0.034(6) Uiso 1 1 d DG U . . .
H72_1 H 0.5079 0.2608 0.3029 0.041 Uiso 1 1 calc R U . . .
C73_1 C 0.5188(3) 0.1800(12) 0.3357(3) 0.063(8) Uiso 1 1 d DG U . . .
H73_1 H 0.5473 0.1678 0.3362 0.076 Uiso 1 1 calc R U . . .
C74_1 C 0.5005(5) 0.1427(11) 0.3548(3) 0.077(9) Uiso 1 1 d DG U . . .
H74_1 H 0.5165 0.1050 0.3683 0.092 Uiso 1 1 calc R U . . .
C75_1 C 0.4588(5) 0.1607(11) 0.3542(3) 0.060(7) Uiso 1 1 d DG U . . .
H75_1 H 0.4463 0.1352 0.3672 0.072 Uiso 1 1 calc R U . . .
C76_1 C 0.4354(3) 0.2160(10) 0.3344(3) 0.036(6) Uiso 1 1 d DG U . . .
H76_1 H 0.4069 0.2282 0.3340 0.044 Uiso 1 1 calc R U . . .
C81_1 C 0.3932(3) 0.2406(6) 0.26568(19) 0.012(4) Uiso 1 1 d DG U . . .
C82_1 C 0.3989(4) 0.1472(7) 0.2716(2) 0.029(5) Uiso 1 1 d DG U . . .
H82_1 H 0.4181 0.1282 0.2871 0.035 Uiso 1 1 calc R U . . .
C83_1 C 0.3763(4) 0.0815(6) 0.2546(3) 0.046(6) Uiso 1 1 d DG U . . .
H83_1 H 0.3802 0.0177 0.2586 0.055 Uiso 1 1 calc R U . . .
C84_1 C 0.3481(4) 0.1093(7) 0.2318(2) 0.038(6) Uiso 1 1 d DG U . . .
H84_1 H 0.3328 0.0644 0.2202 0.045 Uiso 1 1 calc R U . . .
C85_1 C 0.3425(4) 0.2027(8) 0.22591(19) 0.035(6) Uiso 1 1 d DG U . . .
H85_1 H 0.3232 0.2217 0.2103 0.042 Uiso 1 1 calc R U . . .
C86_1 C 0.3650(4) 0.2683(6) 0.2429(2) 0.023(5) Uiso 1 1 d DG U . . .
H86_1 H 0.3611 0.3322 0.2388 0.028 Uiso 1 1 calc R U . . .
C91_1 C 0.5276(4) 0.4626(10) 0.2576(3) 0.017(4) Uiso 1 1 d D U . . .
H91_1 H 0.5507 0.4847 0.2723 0.020 Uiso 1 1 calc R U . . .
C92_1 C 0.4970(5) 0.5241(11) 0.2497(3) 0.024(5) Uiso 1 1 d D U . . .
H92_1 H 0.5019 0.5833 0.2598 0.029 Uiso 1 1 calc R U . . .
C93_1 C 0.4682(7) 0.5347(13) 0.2228(4) 0.043(6) Uiso 1 1 d D U . . .
H93A_1 H 0.4433 0.5701 0.2245 0.051 Uiso 1 1 calc R U . . .
H93B_1 H 0.4827 0.5709 0.2115 0.051 Uiso 1 1 calc R U . . .
C94_1 C 0.4546(7) 0.4456(12) 0.2097(3) 0.034(6) Uiso 1 1 d D U . . .
H94A_1 H 0.4763 0.4237 0.2008 0.041 Uiso 1 1 calc R U . . .
H94B_1 H 0.4287 0.4558 0.1960 0.041 Uiso 1 1 calc R U . . .
C95_1 C 0.4466(5) 0.3692(11) 0.2287(3) 0.030(5) Uiso 1 1 d D U . . .
H95_1 H 0.4169 0.3475 0.2247 0.036 Uiso 1 1 calc R U . . .
C96_1 C 0.4734(5) 0.3061(11) 0.2405(3) 0.027(5) Uiso 1 1 d D U . . .
H96_1 H 0.4602 0.2459 0.2434 0.032 Uiso 1 1 calc R U . . .
C97_1 C 0.5181(5) 0.2982(12) 0.2391(4) 0.030(5) Uiso 1 1 d D U . . .
H97A_1 H 0.5192 0.2656 0.2226 0.036 Uiso 1 1 calc R U . . .
H97B_1 H 0.5330 0.2597 0.2539 0.036 Uiso 1 1 calc R U . . .
C98_1 C 0.5410(5) 0.3897(11) 0.2398(4) 0.025(5) Uiso 1 1 d D U . . .
H98A_1 H 0.5361 0.4146 0.2217 0.030 Uiso 1 1 calc R U . . .
H98B_1 H 0.5714 0.3785 0.2461 0.030 Uiso 1 1 calc R U . . .
Rh1_2 Rh 0.28595(9) 0.4494(3) 0.48152(5) 0.1108(15) Uani 1 1 d D U . . .
P1_2 P 0.2744(2) 0.5278(6) 0.44177(12) 0.069(3) Uani 1 1 d D U . . .
P2_2 P 0.3307(2) 0.3524(6) 0.46657(15) 0.076(3) Uani 1 1 d D U . . .
Cl1_2 Cl 0.2410(2) 0.2360(6) 0.23765(14) 0.075(2) Uani 1 1 d D U . . .
Cl2_2 Cl 0.3124(3) -0.0547(5) 0.29408(18) 0.092(3) Uani 1 1 d D U . . .
Cl3_2 Cl 0.6053(2) 0.5942(6) 0.39655(18) 0.078(2) Uani 1 1 d D U . . .
Cl4_2 Cl 0.5196(3) 0.8989(7) 0.3625(3) 0.166(7) Uani 1 1 d D U . . .
C11_2 C 0.2785(4) 0.4668(10) 0.4113(2) 0.054(7) Uiso 1 1 d DG U . . .
C12_2 C 0.3169(3) 0.4376(10) 0.4075(2) 0.037(6) Uiso 1 1 d DG U . . .
C13_2 C 0.3191(3) 0.3916(11) 0.3845(2) 0.048(7) Uiso 1 1 d DG U . . .
H13_2 H 0.3453 0.3716 0.3819 0.058 Uiso 1 1 calc R U . . .
C14_2 C 0.2829(4) 0.3748(11) 0.3653(2) 0.047(6) Uiso 1 1 d DG U . . .
C15_2 C 0.2445(3) 0.4040(11) 0.3691(2) 0.052(7) Uiso 1 1 d DG U . . .
H15_2 H 0.2198 0.3925 0.3560 0.062 Uiso 1 1 calc R U . . .
C16_2 C 0.2423(3) 0.4500(11) 0.3921(2) 0.048(7) Uiso 1 1 d DG U . . .
H16_2 H 0.2161 0.4699 0.3946 0.058 Uiso 1 1 calc R U . . .
C21_2 C 0.3685(4) 0.4182(10) 0.4519(2) 0.069(8) Uiso 1 1 d DG U . . .
C22_2 C 0.3576(3) 0.4561(10) 0.4268(2) 0.039(6) Uiso 1 1 d DG U . . .
C23_2 C 0.3862(4) 0.5093(10) 0.4176(2) 0.037(6) Uiso 1 1 d DG U . . .
H23_2 H 0.3788 0.5351 0.4004 0.044 Uiso 1 1 calc R U . . .
C24_2 C 0.4258(3) 0.5246(10) 0.4334(3) 0.044(6) Uiso 1 1 d DG U . . .
C25_2 C 0.4368(3) 0.4867(11) 0.4585(2) 0.060(7) Uiso 1 1 d DG U . . .
H25_2 H 0.4638 0.4972 0.4693 0.072 Uiso 1 1 calc R U . . .
C26_2 C 0.4081(4) 0.4335(11) 0.4678(2) 0.053(7) Uiso 1 1 d DG U . . .
H26_2 H 0.4156 0.4076 0.4849 0.063 Uiso 1 1 calc R U . . .
C30_2 C 0.3093(6) 0.2602(13) 0.3379(3) 0.036(6) Uiso 1 1 d D U . . .
O30_2 O 0.3436(5) 0.2479(13) 0.3529(3) 0.065(5) Uiso 1 1 d D U . . .
N31_2 N 0.2810(5) 0.3215(12) 0.3421(3) 0.043(5) Uiso 1 1 d D U . . .
H31_2 H 0.2589 0.3298 0.3292 0.052 Uiso 1 1 calc R U . . .
C31_2 C 0.2987(4) 0.2073(8) 0.31307(19) 0.037(6) Uiso 1 1 d DG U . . .
C32_2 C 0.2771(4) 0.2455(6) 0.2894(2) 0.034(6) Uiso 1 1 d DG U . . .
H32_2 H 0.2695 0.3088 0.2886 0.041 Uiso 1 1 calc R U . . .
C33_2 C 0.2668(5) 0.1910(8) 0.26695(19) 0.053(7) Uiso 1 1 d DG U . . .
C34_2 C 0.2781(5) 0.0983(8) 0.2681(2) 0.048(7) Uiso 1 1 d DG U . . .
H34_2 H 0.2710 0.0610 0.2528 0.057 Uiso 1 1 calc R U . . .
C35_2 C 0.2997(5) 0.0601(6) 0.2918(2) 0.043(6) Uiso 1 1 d DG U . . .
C36_2 C 0.3100(4) 0.1146(8) 0.31426(19) 0.040(6) Uiso 1 1 d DG U . . .
H36_2 H 0.3248 0.0885 0.3304 0.048 Uiso 1 1 calc R U . . .
C40_2 C 0.4528(5) 0.6434(14) 0.4068(4) 0.044(6) Uiso 1 1 d D U . . .
O40_2 O 0.4186(5) 0.6724(14) 0.3949(4) 0.074(6) Uiso 1 1 d D U . . .
N41_2 N 0.4578(4) 0.5749(11) 0.4253(3) 0.034(5) Uiso 1 1 d D U . . .
H41_2 H 0.4837 0.5604 0.4331 0.041 Uiso 1 1 calc R U . . .
C41_2 C 0.4913(3) 0.6770(9) 0.4001(3) 0.038(6) Uiso 1 1 d DG U . . .
C42_2 C 0.5275(4) 0.6246(7) 0.4031(3) 0.032(5) Uiso 1 1 d DG U . . .
H42_2 H 0.5294 0.5661 0.4115 0.038 Uiso 1 1 calc R U . . .
C43_2 C 0.5609(3) 0.6577(8) 0.3938(3) 0.036(6) Uiso 1 1 d DG U . . .
C44_2 C 0.5582(3) 0.7433(9) 0.3814(3) 0.039(6) Uiso 1 1 d DG U . . .
H44_2 H 0.5811 0.7660 0.3750 0.047 Uiso 1 1 calc R U . . .
C45_2 C 0.5221(4) 0.7957(8) 0.3784(3) 0.069(8) Uiso 1 1 d DG U . . .
C46_2 C 0.4886(3) 0.7626(9) 0.3878(3) 0.053(7) Uiso 1 1 d DG U . . .
H46_2 H 0.4639 0.7984 0.3857 0.064 Uiso 1 1 calc R U . . .
C51_2 C 0.3103(5) 0.6238(10) 0.4430(3) 0.054(7) Uiso 1 1 d DG U . . .
C52_2 C 0.3078(6) 0.6761(13) 0.4204(3) 0.086(10) Uiso 1 1 d DG U . . .
H52_2 H 0.2865 0.6637 0.4051 0.104 Uiso 1 1 calc R U . . .
C53_2 C 0.3363(7) 0.7466(13) 0.4202(4) 0.101(11) Uiso 1 1 d DG U . . .
H53_2 H 0.3345 0.7824 0.4047 0.122 Uiso 1 1 calc R U . . .
C54_2 C 0.3674(6) 0.7648(13) 0.4425(5) 0.106(12) Uiso 1 1 d DG U . . .
H54_2 H 0.3869 0.8130 0.4424 0.127 Uiso 1 1 calc R U . . .
C55_2 C 0.3700(5) 0.7125(14) 0.4652(4) 0.093(10) Uiso 1 1 d DG U . . .
H55_2 H 0.3913 0.7250 0.4805 0.112 Uiso 1 1 calc R U . . .
C56_2 C 0.3414(6) 0.6420(12) 0.4654(3) 0.071(8) Uiso 1 1 d DG U . . .
H56_2 H 0.3432 0.6063 0.4808 0.085 Uiso 1 1 calc R U . . .
C61_2 C 0.2216(4) 0.5765(13) 0.4329(4) 0.085(9) Uiso 1 1 d DG U . . .
C62_2 C 0.1874(6) 0.5178(11) 0.4300(5) 0.113(12) Uiso 1 1 d DG U . . .
H62_2 H 0.1914 0.4528 0.4306 0.135 Uiso 1 1 calc R U . . .
C63_2 C 0.1474(5) 0.5542(17) 0.4261(5) 0.135(15) Uiso 1 1 d DG U . . .
H63_2 H 0.1240 0.5141 0.4241 0.162 Uiso 1 1 calc R U . . .
C64_2 C 0.1415(5) 0.6493(18) 0.4252(5) 0.099(11) Uiso 1 1 d DG U . . .
H64_2 H 0.1142 0.6742 0.4226 0.118 Uiso 1 1 calc R U . . .
C65_2 C 0.1757(7) 0.7080(12) 0.4281(5) 0.109(12) Uiso 1 1 d DG U . . .
H65_2 H 0.1717 0.7730 0.4275 0.131 Uiso 1 1 calc R U . . .
C66_2 C 0.2157(5) 0.6716(12) 0.4319(4) 0.102(11) Uiso 1 1 d DG U . . .
H66_2 H 0.2391 0.7117 0.4339 0.123 Uiso 1 1 calc R U . . .
C71_2 C 0.3617(6) 0.2773(12) 0.4918(3) 0.092(9) Uiso 1 1 d DG U . . .
C72_2 C 0.3540(7) 0.1832(13) 0.4885(4) 0.132(14) Uiso 1 1 d DG U . . .
H72_2 H 0.3341 0.1613 0.4735 0.158 Uiso 1 1 calc R U . . .
C73_2 C 0.3754(8) 0.1209(10) 0.5071(5) 0.132(14) Uiso 1 1 d DG U . . .
H73_2 H 0.3701 0.0566 0.5048 0.159 Uiso 1 1 calc R U . . .
C74_2 C 0.4045(7) 0.1529(15) 0.5290(4) 0.112(12) Uiso 1 1 d DG U . . .
H74_2 H 0.4191 0.1103 0.5417 0.135 Uiso 1 1 calc R U . . .
C75_2 C 0.4122(6) 0.2470(16) 0.5323(3) 0.096(11) Uiso 1 1 d DG U . . .
H75_2 H 0.4320 0.2688 0.5473 0.115 Uiso 1 1 calc R U . . .
C76_2 C 0.3908(6) 0.3092(11) 0.5137(4) 0.078(9) Uiso 1 1 d DG U . . .
H76_2 H 0.3960 0.3735 0.5160 0.093 Uiso 1 1 calc R U . . .
C81_2 C 0.3028(5) 0.2728(12) 0.4408(3) 0.066(8) Uiso 1 1 d DG U . . .
C82_2 C 0.3234(5) 0.2261(15) 0.4243(4) 0.108(12) Uiso 1 1 d DG U . . .
H82_2 H 0.3525 0.2351 0.4261 0.130 Uiso 1 1 calc R U . . .
C83_2 C 0.3015(8) 0.1661(16) 0.4053(4) 0.137(15) Uiso 1 1 d DG U . . .
H83_2 H 0.3155 0.1341 0.3941 0.165 Uiso 1 1 calc R U . . .
C84_2 C 0.2589(8) 0.1528(16) 0.4028(4) 0.133(14) Uiso 1 1 d DG U . . .
H84_2 H 0.2439 0.1118 0.3898 0.160 Uiso 1 1 calc R U . . .
C85_2 C 0.2383(5) 0.1996(17) 0.4192(5) 0.108(12) Uiso 1 1 d DG U . . .
H85_2 H 0.2092 0.1905 0.4175 0.130 Uiso 1 1 calc R U . . .
C86_2 C 0.2602(5) 0.2595(14) 0.4383(4) 0.081(9) Uiso 1 1 d DG U . . .
H86_2 H 0.2462 0.2915 0.4495 0.097 Uiso 1 1 calc R U . . .
C91_2 C 0.2621(9) 0.5686(15) 0.5021(5) 0.124(14) Uiso 1 1 d D U . . .
H91_2 H 0.2604 0.6262 0.4913 0.149 Uiso 1 1 calc R U . . .
C92_2 C 0.2305(7) 0.5139(19) 0.4924(5) 0.132(14) Uiso 1 1 d D U . . .
H92_2 H 0.2099 0.5409 0.4771 0.159 Uiso 1 1 calc R U . . .
C93_2 C 0.2112(10) 0.446(3) 0.5082(9) 0.178(19) Uiso 1 1 d D U . . .
H93A_2 H 0.2104 0.4757 0.5251 0.214 Uiso 1 1 calc R U . . .
H93B_2 H 0.1820 0.4353 0.4986 0.214 Uiso 1 1 calc R U . . .
C94_2 C 0.2308(10) 0.355(2) 0.5144(9) 0.165(18) Uiso 1 1 d D U . . .
H94A_2 H 0.2158 0.3088 0.5015 0.198 Uiso 1 1 calc R U . . .
H94B_2 H 0.2282 0.3354 0.5321 0.198 Uiso 1 1 calc R U . . .
C95_2 C 0.2774(9) 0.3545(16) 0.5136(5) 0.121(13) Uiso 1 1 d D U . . .
H95_2 H 0.2869 0.2907 0.5107 0.145 Uiso 1 1 calc R U . . .
C96_2 C 0.3092(9) 0.4075(19) 0.5235(4) 0.126(14) Uiso 1 1 d D U . . .
H96_2 H 0.3366 0.3743 0.5269 0.152 Uiso 1 1 calc R U . . .
C97_2 C 0.3094(14) 0.489(2) 0.5409(5) 0.162(17) Uiso 1 1 d D U . . .
H97A_2 H 0.3385 0.4987 0.5510 0.194 Uiso 1 1 calc R U . . .
H97B_2 H 0.2926 0.4733 0.5537 0.194 Uiso 1 1 calc R U . . .
C98_2 C 0.2935(12) 0.581(2) 0.5285(6) 0.149(16) Uiso 1 1 d D U . . .
H98A_2 H 0.3174 0.6182 0.5259 0.179 Uiso 1 1 calc R U . . .
H98B_2 H 0.2800 0.6153 0.5407 0.179 Uiso 1 1 calc R U . . .
Rh1_3 Rh 0.21210(8) 0.56370(19) 0.01731(4) 0.0661(8) Uani 1 1 d D U . . .
P1_3 P 0.16716(19) 0.6573(4) 0.03366(11) 0.0420(17) Uani 1 1 d D U . . .
P2_3 P 0.2225(2) 0.4767(5) 0.05567(11) 0.058(2) Uani 1 1 d D U . . .
Cl1_3 Cl -0.0982(4) 0.3739(8) 0.10742(19) 0.142(5) Uani 1 1 d D U . . .
Cl2_3 Cl -0.0120(5) 0.0640(10) 0.1264(4) 0.303(14) Uani 1 1 d D U . . .
Cl3_3 Cl 0.27257(18) 0.7136(4) 0.26646(11) 0.0454(17) Uani 1 1 d D U . . .
Cl4_3 Cl 0.1757(3) 0.9977(4) 0.22326(14) 0.069(2) Uani 1 1 d D U . . .
C11_3 C 0.1300(3) 0.5911(9) 0.0488(2) 0.052(7) Uiso 1 1 d DG U . . .
C12_3 C 0.1421(3) 0.5504(10) 0.0735(2) 0.036(6) Uiso 1 1 d DG U . . .
C13_3 C 0.1147(4) 0.4924(10) 0.0824(2) 0.041(6) Uiso 1 1 d DG U . . .
H13_3 H 0.1229 0.4646 0.0993 0.049 Uiso 1 1 calc R U . . .
C14_3 C 0.0752(4) 0.4753(10) 0.0667(3) 0.054(7) Uiso 1 1 d DG U . . .
C15_3 C 0.0631(3) 0.5160(11) 0.0420(2) 0.053(7) Uiso 1 1 d DG U . . .
H15_3 H 0.0361 0.5043 0.0312 0.063 Uiso 1 1 calc R U . . .
C16_3 C 0.0905(4) 0.5739(10) 0.0331(2) 0.044(6) Uiso 1 1 d DG U . . .
H16_3 H 0.0823 0.6018 0.0162 0.052 Uiso 1 1 calc R U . . .
C21_3 C 0.2209(3) 0.5346(10) 0.08704(18) 0.048(6) Uiso 1 1 d DG U . . .
C22_3 C 0.1836(3) 0.5647(10) 0.09232(19) 0.028(5) Uiso 1 1 d DG U . . .
C23_3 C 0.1835(3) 0.6047(10) 0.1165(2) 0.036(6) Uiso 1 1 d DG U . . .
H23_3 H 0.1580 0.6253 0.1201 0.044 Uiso 1 1 calc R U . . .
C24_3 C 0.2207(4) 0.6146(10) 0.13535(18) 0.032(5) Uiso 1 1 d DG U . . .
C25_3 C 0.2580(3) 0.5844(10) 0.1301(2) 0.040(6) Uiso 1 1 d DG U . . .
H25_3 H 0.2834 0.5912 0.1430 0.048 Uiso 1 1 calc R U . . .
C26_3 C 0.2581(3) 0.5444(10) 0.1059(2) 0.037(6) Uiso 1 1 d DG U . . .
H26_3 H 0.2836 0.5238 0.1023 0.044 Uiso 1 1 calc R U . . .
C30_3 C 0.0518(6) 0.3490(18) 0.0919(5) 0.086(10) Uiso 1 1 d D U . . .
O30_3 O 0.0854(6) 0.3284(17) 0.1062(5) 0.109(8) Uiso 1 1 d D U . . .
N31_3 N 0.0454(5) 0.4169(12) 0.0741(3) 0.044(5) Uiso 1 1 d D U . . .
H31_3 H 0.0192 0.4267 0.0660 0.053 Uiso 1 1 calc R U . . .
C31_3 C 0.0140(5) 0.3050(11) 0.0972(4) 0.071(8) Uiso 1 1 d DG U . . .
C32_3 C -0.0215(5) 0.3565(9) 0.0976(4) 0.056(7) Uiso 1 1 d DG U . . .
H32_3 H -0.0233 0.4191 0.0920 0.067 Uiso 1 1 calc R U . . .
C33_3 C -0.0543(5) 0.3163(12) 0.1062(4) 0.098(11) Uiso 1 1 d DG U . . .
C34_3 C -0.0516(6) 0.2247(13) 0.1144(5) 0.114(13) Uiso 1 1 d DG U . . .
H34_3 H -0.0740 0.1972 0.1202 0.137 Uiso 1 1 calc R U . . .
C35_3 C -0.0161(7) 0.1732(10) 0.1139(5) 0.148(15) Uiso 1 1 d DG U . . .
C36_3 C 0.0166(5) 0.2134(11) 0.1053(5) 0.125(14) Uiso 1 1 d DG U . . .
H36_3 H 0.0409 0.1782 0.1050 0.150 Uiso 1 1 calc R U . . .
C40_3 C 0.1973(5) 0.7232(12) 0.1665(3) 0.026(5) Uiso 1 1 d D U . . .
O40_3 O 0.1653(5) 0.7482(12) 0.1505(3) 0.056(5) Uiso 1 1 d D U . . .
N41_3 N 0.2235(5) 0.6569(10) 0.1606(3) 0.028(4) Uiso 1 1 d D U . . .
H41_3 H 0.2441 0.6385 0.1735 0.034 Uiso 1 1 calc R U . . .
C41_3 C 0.2071(4) 0.7624(7) 0.19337(16) 0.025(5) Uiso 1 1 d DG U . . .
C42_3 C 0.2334(4) 0.7213(6) 0.2150(2) 0.027(5) Uiso 1 1 d DG U . . .
H42_3 H 0.2459 0.6632 0.2132 0.032 Uiso 1 1 calc R U . . .
C43_3 C 0.2415(4) 0.7651(8) 0.23934(17) 0.021(5) Uiso 1 1 d DG U . . .
C44_3 C 0.2233(4) 0.8501(8) 0.24199(16) 0.037(6) Uiso 1 1 d DG U . . .
H44_3 H 0.2289 0.8801 0.2586 0.045 Uiso 1 1 calc R U . . .
C45_3 C 0.1970(4) 0.8913(6) 0.2203(2) 0.026(5) Uiso 1 1 d DG U . . .
C46_3 C 0.1889(4) 0.8474(7) 0.19601(17) 0.023(5) Uiso 1 1 d DG U . . .
H46_3 H 0.1710 0.8755 0.1812 0.027 Uiso 1 1 calc R U . . .
C51_3 C 0.1939(4) 0.7329(10) 0.0597(3) 0.037(6) Uiso 1 1 d DG U . . .
C52_3 C 0.1724(4) 0.7769(12) 0.0762(3) 0.072(9) Uiso 1 1 d DG U . . .
H52_3 H 0.1433 0.7666 0.0740 0.087 Uiso 1 1 calc R U . . .
C53_3 C 0.1934(6) 0.8360(13) 0.0958(3) 0.085(10) Uiso 1 1 d DG U . . .
H53_3 H 0.1787 0.8661 0.1070 0.102 Uiso 1 1 calc R U . . .
C54_3 C 0.2360(6) 0.8510(13) 0.0990(3) 0.084(10) Uiso 1 1 d DG U . . .
H54_3 H 0.2504 0.8914 0.1124 0.101 Uiso 1 1 calc R U . . .
C55_3 C 0.2575(4) 0.8070(14) 0.0825(4) 0.088(10) Uiso 1 1 d DG U . . .
H55_3 H 0.2866 0.8173 0.0847 0.105 Uiso 1 1 calc R U . . .
C56_3 C 0.2365(4) 0.7480(12) 0.0629(3) 0.065(8) Uiso 1 1 d DG U . . .
H56_3 H 0.2512 0.7179 0.0517 0.077 Uiso 1 1 calc R U . . .
C61_3 C 0.1343(5) 0.7359(10) 0.0099(3) 0.058(7) Uiso 1 1 d DG U . . .
C62_3 C 0.1398(5) 0.8303(11) 0.0141(3) 0.078(9) Uiso 1 1 d DG U . . .
H62_3 H 0.1588 0.8524 0.0294 0.093 Uiso 1 1 calc R U . . .
C63_3 C 0.1173(7) 0.8924(9) -0.0041(4) 0.090(10) Uiso 1 1 d DG U . . .
H63_3 H 0.1211 0.9569 -0.0013 0.108 Uiso 1 1 calc R U . . .
C64_3 C 0.0895(6) 0.8600(12) -0.0265(3) 0.097(11) Uiso 1 1 d DG U . . .
H64_3 H 0.0741 0.9024 -0.0389 0.117 Uiso 1 1 calc R U . . .
C65_3 C 0.0840(5) 0.7656(13) -0.0307(3) 0.080(9) Uiso 1 1 d DG U . . .
H65_3 H 0.0650 0.7434 -0.0460 0.096 Uiso 1 1 calc R U . . .
C66_3 C 0.1064(5) 0.7035(9) -0.0125(3) 0.060(8) Uiso 1 1 d DG U . . .
H66_3 H 0.1027 0.6389 -0.0153 0.072 Uiso 1 1 calc R U . . .
C71_3 C 0.1848(4) 0.3830(10) 0.0523(3) 0.048(6) Uiso 1 1 d DG U . . .
C72_3 C 0.1845(6) 0.3291(13) 0.0743(3) 0.083(10) Uiso 1 1 d DG U . . .
H72_3 H 0.2052 0.3383 0.0901 0.100 Uiso 1 1 calc R U . . .
C73_3 C 0.1540(7) 0.2619(13) 0.0732(4) 0.102(11) Uiso 1 1 d DG U . . .
H73_3 H 0.1539 0.2251 0.0882 0.122 Uiso 1 1 calc R U . . .
C74_3 C 0.1238(6) 0.2485(13) 0.0501(5) 0.114(12) Uiso 1 1 d DG U . . .
H74_3 H 0.1029 0.2026 0.0493 0.136 Uiso 1 1 calc R U . . .
C75_3 C 0.1240(5) 0.3023(14) 0.0281(4) 0.096(11) Uiso 1 1 d DG U . . .
H75_3 H 0.1033 0.2932 0.0123 0.116 Uiso 1 1 calc R U . . .
C76_3 C 0.1545(5) 0.3695(12) 0.0292(3) 0.056(7) Uiso 1 1 d DG U . . .
H76_3 H 0.1546 0.4063 0.0142 0.068 Uiso 1 1 calc R U . . .
C81_3 C 0.2745(4) 0.4210(12) 0.0627(4) 0.072(8) Uiso 1 1 d DG U . . .
C82_3 C 0.3096(6) 0.4776(11) 0.0671(5) 0.099(11) Uiso 1 1 d DG U . . .
H82_3 H 0.3064 0.5428 0.0662 0.119 Uiso 1 1 calc R U . . .
C83_3 C 0.3493(4) 0.4387(17) 0.0727(5) 0.124(13) Uiso 1 1 d DG U . . .
H83_3 H 0.3732 0.4773 0.0757 0.149 Uiso 1 1 calc R U . . .
C84_3 C 0.3539(5) 0.3433(18) 0.0740(5) 0.121(13) Uiso 1 1 d DG U . . .
H84_3 H 0.3810 0.3167 0.0778 0.145 Uiso 1 1 calc R U . . .
C85_3 C 0.3189(7) 0.2867(12) 0.0697(5) 0.100(11) Uiso 1 1 d DG U . . .
H85_3 H 0.3220 0.2215 0.0705 0.120 Uiso 1 1 calc R U . . .
C86_3 C 0.2792(5) 0.3256(12) 0.0640(4) 0.093(10) Uiso 1 1 d DG U . . .
H86_3 H 0.2552 0.2869 0.0611 0.112 Uiso 1 1 calc R U . . .
C91_3 C 0.1898(6) 0.6123(14) -0.0248(3) 0.058(7) Uiso 1 1 d D U . . .
H91_3 H 0.1618 0.6428 -0.0284 0.070 Uiso 1 1 calc R U . . .
C92_3 C 0.2207(7) 0.6669(13) -0.0125(4) 0.072(8) Uiso 1 1 d D U . . .
H92_3 H 0.2111 0.7303 -0.0090 0.086 Uiso 1 1 calc R U . . .
C93_3 C 0.2665(8) 0.6629(19) -0.0134(7) 0.103(11) Uiso 1 1 d D U . . .
H93A_3 H 0.2700 0.6954 -0.0294 0.124 Uiso 1 1 calc R U . . .
H93B_3 H 0.2832 0.6964 0.0020 0.124 Uiso 1 1 calc R U . . .
C94_3 C 0.2832(9) 0.568(2) -0.0135(7) 0.121(13) Uiso 1 1 d D U . . .
H94A_3 H 0.3139 0.5704 -0.0069 0.145 Uiso 1 1 calc R U . . .
H94B_3 H 0.2773 0.5458 -0.0319 0.145 Uiso 1 1 calc R U . . .
C95_3 C 0.2648(7) 0.4986(16) 0.0032(5) 0.106(12) Uiso 1 1 d D U . . .
H95_3 H 0.2866 0.4715 0.0179 0.127 Uiso 1 1 calc R U . . .
C96_3 C 0.2323(8) 0.4450(14) -0.0042(4) 0.095(11) Uiso 1 1 d D U . . .
H96_3 H 0.2347 0.3857 0.0059 0.114 Uiso 1 1 calc R U . . .
C97_3 C 0.2023(10) 0.4396(17) -0.0303(5) 0.104(12) Uiso 1 1 d D U . . .
H97A_3 H 0.1760 0.4114 -0.0281 0.125 Uiso 1 1 calc R U . . .
H97B_3 H 0.2141 0.3984 -0.0419 0.125 Uiso 1 1 calc R U . . .
C98_3 C 0.1923(11) 0.5324(17) -0.0439(4) 0.099(11) Uiso 1 1 d D U . . .
H98A_3 H 0.1653 0.5277 -0.0570 0.119 Uiso 1 1 calc R U . . .
H98B_3 H 0.2141 0.5470 -0.0536 0.119 Uiso 1 1 calc R U . . .
Rh1_4 Rh 0.04251(5) 0.52504(11) 0.23377(3) 0.0190(4) Uani 1 1 d D U . . .
P1_4 P 0.03301(14) 0.4482(3) 0.19391(9) 0.0145(11) Uani 1 1 d D U . . .
P2_4 P 0.08608(14) 0.6271(3) 0.21938(9) 0.0142(11) Uani 1 1 d D U . . .
Cl1_4 Cl -0.0143(3) 0.7352(6) -0.01063(13) 0.076(2) Uani 1 1 d D U . . .
Cl2_4 Cl 0.0627(4) 1.0295(6) 0.0381(3) 0.160(6) Uani 1 1 d D U . . .
Cl3_4 Cl 0.36290(17) 0.3959(5) 0.14852(13) 0.0524(18) Uani 1 1 d D U . . .
Cl4_4 Cl 0.2740(3) 0.1008(6) 0.1084(2) 0.101(3) Uani 1 1 d D U . . .
C11_4 C 0.0349(3) 0.5119(7) 0.16340(16) 0.006(4) Uiso 1 1 d DG U . . .
C12_4 C 0.0720(2) 0.5488(8) 0.15949(17) 0.019(5) Uiso 1 1 d DG U . . .
C13_4 C 0.0719(2) 0.5994(8) 0.1369(2) 0.023(5) Uiso 1 1 d DG U . . .
H13_4 H 0.0973 0.6246 0.1342 0.028 Uiso 1 1 calc R U . . .
C14_4 C 0.0348(3) 0.6132(8) 0.11822(17) 0.020(5) Uiso 1 1 d DG U . . .
C15_4 C -0.0023(2) 0.5764(9) 0.12213(18) 0.024(5) Uiso 1 1 d DG U . . .
H15_4 H -0.0276 0.5859 0.1094 0.029 Uiso 1 1 calc R U . . .
C16_4 C -0.0022(2) 0.5258(8) 0.14472(19) 0.023(5) Uiso 1 1 d DG U . . .
H16_4 H -0.0276 0.5006 0.1474 0.027 Uiso 1 1 calc R U . . .
C21_4 C 0.1247(3) 0.5691(7) 0.20372(17) 0.006(4) Uiso 1 1 d DG U . . .
C22_4 C 0.1137(2) 0.5351(8) 0.17818(16) 0.013(4) Uiso 1 1 d DG U . . .
C23_4 C 0.1421(3) 0.4832(8) 0.16831(15) 0.020(5) Uiso 1 1 d DG U . . .
H23_4 H 0.1346 0.4599 0.1509 0.024 Uiso 1 1 calc R U . . .
C24_4 C 0.1816(3) 0.4653(8) 0.18398(19) 0.013(4) Uiso 1 1 d DG U . . .
C25_4 C 0.1926(2) 0.4994(8) 0.20951(18) 0.019(5) Uiso 1 1 d DG U . . .
H25_4 H 0.2196 0.4871 0.2202 0.023 Uiso 1 1 calc R U . . .
C26_4 C 0.1642(3) 0.5513(8) 0.21938(15) 0.026(5) Uiso 1 1 d DG U . . .
H26_4 H 0.1718 0.5745 0.2368 0.031 Uiso 1 1 calc R U . . .
C30_4 C 0.0572(6) 0.7297(14) 0.0898(3) 0.044(6) Uiso 1 1 d D U . . .
O30_4 O 0.0901(5) 0.7492(12) 0.1054(3) 0.059(5) Uiso 1 1 d D U . . .
N31_4 N 0.0312(4) 0.6655(9) 0.0948(2) 0.016(4) Uiso 1 1 d D U . . .
H31_4 H 0.0092 0.6538 0.0820 0.019 Uiso 1 1 calc R U . . .
C31_4 C 0.0446(5) 0.7784(9) 0.06427(19) 0.040(6) Uiso 1 1 d DG U . . .
C32_4 C 0.0212(4) 0.7361(7) 0.0418(2) 0.033(5) Uiso 1 1 d DG U . . .
H32_4 H 0.0121 0.6741 0.0425 0.040 Uiso 1 1 calc R U . . .
C33_4 C 0.0111(5) 0.7846(9) 0.01818(19) 0.048(6) Uiso 1 1 d DG U . . .
C34_4 C 0.0244(5) 0.8753(9) 0.0171(2) 0.062(8) Uiso 1 1 d DG U . . .
H34_4 H 0.0174 0.9085 0.0010 0.074 Uiso 1 1 calc R U . . .
C35_4 C 0.0478(6) 0.9176(8) 0.0396(3) 0.086(10) Uiso 1 1 d DG U . . .
C36_4 C 0.0579(5) 0.8691(9) 0.0632(2) 0.062(8) Uiso 1 1 d DG U . . .
H36_4 H 0.0739 0.8980 0.0786 0.074 Uiso 1 1 calc R U . . .
C40_4 C 0.2083(5) 0.3573(12) 0.1539(3) 0.025(5) Uiso 1 1 d D U . . .
O40_4 O 0.1740(4) 0.3407(11) 0.1394(3) 0.051(5) Uiso 1 1 d D U . . .
N41_4 N 0.2137(4) 0.4162(10) 0.1752(3) 0.025(4) Uiso 1 1 d D U . . .
H41_4 H 0.2395 0.4245 0.1844 0.030 Uiso 1 1 calc R U . . .
C41_4 C 0.2465(3) 0.3198(8) 0.1475(3) 0.023(5) Uiso 1 1 d DG U . . .
C42_4 C 0.2842(3) 0.3676(7) 0.1530(2) 0.026(5) Uiso 1 1 d DG U . . .
H42_4 H 0.2866 0.4243 0.1624 0.031 Uiso 1 1 calc R U . . .
C43_4 C 0.3183(3) 0.3324(8) 0.1448(3) 0.036(6) Uiso 1 1 d DG U . . .
C44_4 C 0.3147(3) 0.2495(9) 0.1310(3) 0.041(6) Uiso 1 1 d DG U . . .
H44_4 H 0.3381 0.2255 0.1254 0.050 Uiso 1 1 calc R U . . .
C45_4 C 0.2771(4) 0.2017(7) 0.1255(3) 0.050(7) Uiso 1 1 d DG U . . .
C46_4 C 0.2430(3) 0.2369(8) 0.1338(3) 0.033(5) Uiso 1 1 d DG U . . .
H46_4 H 0.2173 0.2042 0.1300 0.040 Uiso 1 1 calc R U . . .
C51_4 C 0.0721(3) 0.3587(8) 0.1940(2) 0.016(4) Uiso 1 1 d DG U . . .
C52_4 C 0.0733(4) 0.3128(9) 0.17087(18) 0.032(5) Uiso 1 1 d DG U . . .
H52_4 H 0.0534 0.3270 0.1551 0.038 Uiso 1 1 calc R U . . .
C53_4 C 0.1037(5) 0.2462(10) 0.1708(2) 0.048(7) Uiso 1 1 d DG U . . .
H53_4 H 0.1046 0.2149 0.1550 0.058 Uiso 1 1 calc R U . . .
C54_4 C 0.1329(4) 0.2255(10) 0.1940(3) 0.062(8) Uiso 1 1 d DG U . . .
H54_4 H 0.1536 0.1800 0.1939 0.075 Uiso 1 1 calc R U . . .
C55_4 C 0.1316(4) 0.2714(10) 0.2171(2) 0.055(7) Uiso 1 1 d DG U . . .
H55_4 H 0.1515 0.2573 0.2329 0.066 Uiso 1 1 calc R U . . .
C56_4 C 0.1012(4) 0.3380(9) 0.21715(18) 0.024(5) Uiso 1 1 d DG U . . .
H56_4 H 0.1004 0.3694 0.2330 0.029 Uiso 1 1 calc R U . . .
C61_4 C -0.0178(3) 0.3902(7) 0.1850(2) 0.017(4) Uiso 1 1 d DG U . . .
C62_4 C -0.0537(3) 0.4428(6) 0.1831(3) 0.023(5) Uiso 1 1 d DG U . . .
H62_4 H -0.0517 0.5081 0.1847 0.028 Uiso 1 1 calc R U . . .
C63_4 C -0.0924(3) 0.3999(8) 0.1790(3) 0.036(6) Uiso 1 1 d DG U . . .
H63_4 H -0.1170 0.4359 0.1777 0.044 Uiso 1 1 calc R U . . .
C64_4 C -0.0953(3) 0.3044(8) 0.1766(3) 0.035(6) Uiso 1 1 d DG U . . .
H64_4 H -0.1218 0.2750 0.1737 0.042 Uiso 1 1 calc R U . . .
C65_4 C -0.0595(4) 0.2517(6) 0.1784(3) 0.050(7) Uiso 1 1 d DG U . . .
H65_4 H -0.0614 0.1864 0.1768 0.060 Uiso 1 1 calc R U . . .
C66_4 C -0.0207(3) 0.2946(7) 0.1826(3) 0.031(5) Uiso 1 1 d DG U . . .
H66_4 H 0.0038 0.2587 0.1838 0.037 Uiso 1 1 calc R U . . .
C71_4 C 0.0583(3) 0.7090(8) 0.1953(2) 0.018(4) Uiso 1 1 d DG U . . .
C72_4 C 0.0803(3) 0.7619(9) 0.1809(3) 0.032(5) Uiso 1 1 d DG U . . .
H72_4 H 0.1098 0.7557 0.1839 0.038 Uiso 1 1 calc R U . . .
C73_4 C 0.0593(4) 0.8240(9) 0.1622(3) 0.047(6) Uiso 1 1 d DG U . . .
H73_4 H 0.0743 0.8601 0.1524 0.056 Uiso 1 1 calc R U . . .
C74_4 C 0.0162(4) 0.8331(10) 0.1578(3) 0.055(7) Uiso 1 1 d DG U . . .
H74_4 H 0.0018 0.8755 0.1450 0.066 Uiso 1 1 calc R U . . .
C75_4 C -0.0058(3) 0.7801(10) 0.1722(3) 0.049(7) Uiso 1 1 d DG U . . .
H75_4 H -0.0353 0.7863 0.1692 0.059 Uiso 1 1 calc R U . . .
C76_4 C 0.0152(3) 0.7181(9) 0.1909(2) 0.027(5) Uiso 1 1 d DG U . . .
H76_4 H 0.0002 0.6819 0.2008 0.033 Uiso 1 1 calc R U . . .
C81_4 C 0.1164(3) 0.7049(7) 0.24525(19) 0.019(5) Uiso 1 1 d DG U . . .
C82_4 C 0.1469(4) 0.6692(6) 0.2658(2) 0.026(5) Uiso 1 1 d DG U . . .
H82_4 H 0.1525 0.6047 0.2667 0.031 Uiso 1 1 calc R U . . .
C83_4 C 0.1694(3) 0.7278(8) 0.2851(2) 0.029(5) Uiso 1 1 d DG U . . .
H83_4 H 0.1902 0.7034 0.2991 0.034 Uiso 1 1 calc R U . . .
C84_4 C 0.1612(4) 0.8221(8) 0.2837(2) 0.040(6) Uiso 1 1 d DG U . . .
H84_4 H 0.1765 0.8621 0.2969 0.048 Uiso 1 1 calc R U . . .
C85_4 C 0.1307(4) 0.8578(6) 0.2632(2) 0.032(5) Uiso 1 1 d DG U . . .
H85_4 H 0.1251 0.9222 0.2623 0.038 Uiso 1 1 calc R U . . .
C86_4 C 0.1082(3) 0.7992(7) 0.2439(2) 0.023(5) Uiso 1 1 d DG U . . .
H86_4 H 0.0873 0.8236 0.2299 0.028 Uiso 1 1 calc R U . . .
C91_4 C -0.0110(5) 0.4508(11) 0.2462(3) 0.023(5) Uiso 1 1 d D U . . .
H91_4 H -0.0328 0.4263 0.2311 0.028 Uiso 1 1 calc R U . . .
C92_4 C 0.0230(5) 0.3985(11) 0.2526(3) 0.030(5) Uiso 1 1 d D U . . .
H92_4 H 0.0213 0.3422 0.2413 0.036 Uiso 1 1 calc R U . . .
C93_4 C 0.0537(8) 0.3881(14) 0.2789(4) 0.062(8) Uiso 1 1 d D U . . .
H93A_4 H 0.0429 0.3414 0.2895 0.075 Uiso 1 1 calc R U . . .
H93B_4 H 0.0806 0.3650 0.2760 0.075 Uiso 1 1 calc R U . . .
C94_4 C 0.0613(8) 0.4756(14) 0.2940(4) 0.053(7) Uiso 1 1 d D U . . .
H94A_4 H 0.0879 0.4704 0.3075 0.064 Uiso 1 1 calc R U . . .
H94B_4 H 0.0386 0.4849 0.3033 0.064 Uiso 1 1 calc R U . . .
C95_4 C 0.0635(5) 0.5611(12) 0.2765(3) 0.031(5) Uiso 1 1 d D U . . .
H95_4 H 0.0913 0.5925 0.2810 0.037 Uiso 1 1 calc R U . . .
C96_4 C 0.0326(5) 0.6174(12) 0.2655(3) 0.039(6) Uiso 1 1 d D U . . .
H96_4 H 0.0420 0.6822 0.2637 0.047 Uiso 1 1 calc R U . . .
C97_4 C -0.0124(6) 0.6110(13) 0.2663(4) 0.039(6) Uiso 1 1 d D U . . .
H97A_4 H -0.0293 0.6463 0.2513 0.047 Uiso 1 1 calc R U . . .
H97B_4 H -0.0162 0.6402 0.2827 0.047 Uiso 1 1 calc R U . . .
C98_4 C -0.0286(6) 0.5125(12) 0.2651(4) 0.029(5) Uiso 1 1 d D U . . .
H98A_4 H -0.0594 0.5134 0.2593 0.035 Uiso 1 1 calc R U . . .
H98B_4 H -0.0211 0.4854 0.2829 0.035 Uiso 1 1 calc R U . . .
B1 B 0.3160(4) 0.5146(10) 0.2136(3) 0.015(5) Uiso 1 1 d D U . . .
F11 F 0.3115(6) 0.5624(12) 0.2352(3) 0.096(6) Uiso 1 1 d D U . . .
F12 F 0.3567(4) 0.4973(12) 0.2160(3) 0.084(5) Uiso 1 1 d D U . . .
F13 F 0.2952(4) 0.4337(9) 0.2144(3) 0.060(4) Uiso 1 1 d D U . . .
F14 F 0.2983(4) 0.5616(8) 0.1914(2) 0.044(3) Uiso 1 1 d D U . . .
B2 B 0.1863(5) 0.4305(12) 0.2970(3) 0.045(8) Uiso 1 1 d D U . . .
F21 F 0.1658(7) 0.4781(15) 0.3127(4) 0.136(8) Uiso 1 1 d D U . . .
F22 F 0.1590(6) 0.4288(15) 0.2735(3) 0.125(8) Uiso 1 1 d D U . . .
F23 F 0.1964(5) 0.3460(10) 0.3076(3) 0.081(5) Uiso 1 1 d D U . . .
F24 F 0.2214(5) 0.4776(12) 0.2970(3) 0.094(6) Uiso 1 1 d D U . . .
B3 B -0.0636(7) 0.5350(15) 0.0438(4) 0.099(13) Uiso 1 1 d D U . . .
F31 F -0.0936(8) 0.4907(19) 0.0526(5) 0.182(12) Uiso 1 1 d D U . . .
F32 F -0.0806(7) 0.5768(16) 0.0209(4) 0.141(9) Uiso 1 1 d D U . . .
F33 F -0.0354(7) 0.4722(16) 0.0405(5) 0.154(10) Uiso 1 1 d D U . . .
F34 F -0.0464(7) 0.6002(16) 0.0614(4) 0.148(9) Uiso 1 1 d D U . . .
B4 B 0.4312(8) 0.5667(17) 0.5408(5) 0.19(3) Uiso 1 1 d D U . . .
F41 F 0.4015(9) 0.515(2) 0.5480(7) 0.253(18) Uiso 1 1 d D U . . .
F42 F 0.4163(8) 0.5903(19) 0.5155(4) 0.172(11) Uiso 1 1 d D U . . .
F43 F 0.4402(8) 0.6439(17) 0.5553(5) 0.169(11) Uiso 1 1 d D U . . .
F44 F 0.4654(7) 0.5141(17) 0.5432(5) 0.155(10) Uiso 1 1 d D U . . .
C1 C 0.4003(14) 0.7491(13) 0.1063(11) 0.20(2) Uiso 1 1 d D U . . .
H1A H 0.4303 0.7463 0.1153 0.235 Uiso 1 1 calc R U . . .
H1B H 0.3976 0.7532 0.0871 0.235 Uiso 1 1 calc R U . . .
Cl1 Cl 0.3722(5) 0.6496(10) 0.1146(3) 0.155(5) Uiso 1 1 d D U . . .
Cl2 Cl 0.3747(4) 0.8455(8) 0.1182(2) 0.128(4) Uiso 1 1 d D U . . .
C2 C -0.1713(6) 0.650(3) 0.2140(7) 0.153(18) Uiso 1 1 d D U . . .
H2A H -0.1792 0.6315 0.2304 0.184 Uiso 1 1 calc R U . . .
H2B H -0.1794 0.7151 0.2100 0.184 Uiso 1 1 calc R U . . .
Cl3 Cl -0.1160(3) 0.6332(8) 0.2166(2) 0.112(3) Uiso 1 1 d D U . . .
Cl4 Cl -0.1950(4) 0.5752(9) 0.1871(2) 0.125(4) Uiso 1 1 d D U . . .
C3 C 0.4232(7) 0.641(3) 0.0333(5) 0.107(12) Uiso 1 1 d D U . . .
H3A H 0.4351 0.7019 0.0303 0.128 Uiso 1 1 calc R U . . .
H3B H 0.4247 0.5994 0.0186 0.128 Uiso 1 1 calc R U . . .
Cl5 Cl 0.4503(6) 0.5922(14) 0.0646(4) 0.211(8) Uiso 1 1 d D U . . .
Cl6 Cl 0.3702(6) 0.6532(16) 0.0368(4) 0.233(9) Uiso 1 1 d D U . . .
C4 C 0.4019(10) -0.064(6) 0.3900(6) 0.26(3) Uiso 1 1 d D U . . .
H4A H 0.4188 -0.0180 0.4020 0.314 Uiso 1 1 calc R U . . .
H4B H 0.4103 -0.1270 0.3961 0.314 Uiso 1 1 calc R U . . .
Cl7 Cl 0.4047(7) -0.0456(17) 0.3560(4) 0.252(10) Uiso 1 1 d D U . . .
Cl8 Cl 0.3460(7) -0.0442(17) 0.3856(4) 0.242(9) Uiso 1 1 d D U . . .
C5 C 0.3928(6) -0.2377(14) 0.1999(4) 0.019(5) Uiso 1 1 d D U . . .
H5A H 0.4137 -0.1896 0.1989 0.023 Uiso 1 1 calc R U . . .
H5B H 0.4062 -0.2892 0.2113 0.023 Uiso 1 1 calc R U . . .
Cl9 Cl 0.3644(16) -0.277(5) 0.1677(7) 0.75(4) Uiso 1 1 d D U . . .
Cl10 Cl 0.3465(10) -0.191(3) 0.2103(8) 0.49(2) Uiso 1 1 d D U . . .
C6 C 0.0919(9) 0.350(3) 0.4660(6) 0.113(13) Uiso 1 1 d D U . . .
H6A H 0.0796 0.3016 0.4753 0.136 Uiso 1 1 calc R U . . .
H6B H 0.0964 0.4068 0.4767 0.136 Uiso 1 1 calc R U . . .
Cl11 Cl 0.1405(7) 0.3100(19) 0.4581(5) 0.291(12) Uiso 1 1 d D U . . .
Cl12 Cl 0.0595(8) 0.372(2) 0.4334(5) 0.312(13) Uiso 1 1 d D U . . .
C7 C -0.135(2) 0.734(2) 0.1523(10) 0.25(3) Uiso 1 1 d D U . . .
H7A H -0.1648 0.7315 0.1527 0.296 Uiso 1 1 calc R U . . .
H7B H -0.1178 0.7321 0.1706 0.296 Uiso 1 1 calc R U . . .
Cl13 Cl -0.1212(10) 0.6404(19) 0.1326(6) 0.341(15) Uiso 1 1 d D U . . .
Cl14 Cl -0.1238(9) 0.8373(18) 0.1356(6) 0.298(12) Uiso 1 1 d D U . . .
C8 C 0.1557(14) 1.050(9) 0.1174(8) 0.44(5) Uiso 1 1 d D U . . .
H8A H 0.1574 1.1137 0.1111 0.530 Uiso 1 1 calc R U . . .
H8B H 0.1639 1.0059 0.1050 0.530 Uiso 1 1 calc R U . . .
Cl15 Cl 0.1043(10) 1.024(3) 0.1226(8) 0.46(2) Uiso 1 1 d D U . . .
Cl16 Cl 0.1869(8) 1.034(2) 0.1507(6) 0.309(13) Uiso 1 1 d D U . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1_1 C96_1 2.229(15) . ?
Rh1_1 C92_1 2.234(15) . ?
Rh1_1 C95_1 2.241(15) . ?
Rh1_1 C91_1 2.264(14) . ?
Rh1_1 P1_1 2.314(5) . ?
Rh1_1 P2_1 2.320(5) . ?
P1_1 C51_1 1.808(8) . ?
P1_1 C61_1 1.843(8) . ?
P1_1 C11_1 1.866(7) . ?
P2_1 C71_1 1.823(9) . ?
P2_1 C21_1 1.852(7) . ?
P2_1 C81_1 1.853(8) . ?
Cl1_1 C33_1 1.701(11) . ?
Cl2_1 C35_1 1.711(12) . ?
Cl3_1 C43_1 1.705(11) . ?
Cl4_1 C45_1 1.699(11) . ?
C11_1 C12_1 1.3900 . ?
C11_1 C16_1 1.3900 . ?
C12_1 C13_1 1.3900 . ?
C12_1 C22_1 1.503(8) . ?
C13_1 C14_1 1.3900 . ?
C13_1 H13_1 0.9500 . ?
C14_1 C15_1 1.3900 . ?
C14_1 N31_1 1.431(13) . ?
C15_1 C16_1 1.3900 . ?
C15_1 H15_1 0.9500 . ?
C16_1 H16_1 0.9500 . ?
C21_1 C22_1 1.3900 . ?
C21_1 C26_1 1.3900 . ?
C22_1 C23_1 1.3900 . ?
C23_1 C24_1 1.3900 . ?
C23_1 H23_1 0.9500 . ?
C24_1 C25_1 1.3900 . ?
C24_1 N41_1 1.417(12) . ?
C25_1 C26_1 1.3900 . ?
C25_1 H25_1 0.9500 . ?
C26_1 H26_1 0.9500 . ?
C30_1 O30_1 1.228(17) . ?
C30_1 N31_1 1.334(18) . ?
C30_1 C31_1 1.486(16) . ?
N31_1 H31_1 0.8800 . ?
C31_1 C32_1 1.3900 . ?
C31_1 C36_1 1.3900 . ?
C32_1 C33_1 1.3900 . ?
C32_1 H32_1 0.9500 . ?
C33_1 C34_1 1.3900 . ?
C34_1 C35_1 1.3900 . ?
C34_1 H34_1 0.9500 . ?
C35_1 C36_1 1.3900 . ?
C36_1 H36_1 0.9500 . ?
C40_1 O40_1 1.218(16) . ?
C40_1 N41_1 1.381(16) . ?
C40_1 C41_1 1.480(15) . ?
N41_1 H41_1 0.8800 . ?
C41_1 C42_1 1.3900 . ?
C41_1 C46_1 1.3900 . ?
C42_1 C43_1 1.3900 . ?
C42_1 H42_1 0.9500 . ?
C43_1 C44_1 1.3900 . ?
C44_1 C45_1 1.3900 . ?
C44_1 H44_1 0.9500 . ?
C45_1 C46_1 1.3900 . ?
C46_1 H46_1 0.9500 . ?
C51_1 C52_1 1.3900 . ?
C51_1 C56_1 1.3900 . ?
C52_1 C53_1 1.3900 . ?
C52_1 H52_1 0.9500 . ?
C53_1 C54_1 1.3900 . ?
C53_1 H53_1 0.9500 . ?
C54_1 C55_1 1.3900 . ?
C54_1 H54_1 0.9500 . ?
C55_1 C56_1 1.3900 . ?
C55_1 H55_1 0.9500 . ?
C56_1 H56_1 0.9500 . ?
C61_1 C62_1 1.3900 . ?
C61_1 C66_1 1.3900 . ?
C62_1 C63_1 1.3900 . ?
C62_1 H62_1 0.9500 . ?
C63_1 C64_1 1.3900 . ?
C63_1 H63_1 0.9500 . ?
C64_1 C65_1 1.3900 . ?
C64_1 H64_1 0.9500 . ?
C65_1 C66_1 1.3900 . ?
C65_1 H65_1 0.9500 . ?
C66_1 H66_1 0.9500 . ?
C71_1 C72_1 1.3900 . ?
C71_1 C76_1 1.3900 . ?
C72_1 C73_1 1.3900 . ?
C72_1 H72_1 0.9500 . ?
C73_1 C74_1 1.3900 . ?
C73_1 H73_1 0.9500 . ?
C74_1 C75_1 1.3900 . ?
C74_1 H74_1 0.9500 . ?
C75_1 C76_1 1.3900 . ?
C75_1 H75_1 0.9500 . ?
C76_1 H76_1 0.9500 . ?
C81_1 C82_1 1.3900 . ?
C81_1 C86_1 1.3900 . ?
C82_1 C83_1 1.3900 . ?
C82_1 H82_1 0.9500 . ?
C83_1 C84_1 1.3900 . ?
C83_1 H83_1 0.9500 . ?
C84_1 C85_1 1.3900 . ?
C84_1 H84_1 0.9500 . ?
C85_1 C86_1 1.3900 . ?
C85_1 H85_1 0.9500 . ?
C86_1 H86_1 0.9500 . ?
C91_1 C92_1 1.336(18) . ?
C91_1 C98_1 1.539(19) . ?
C91_1 H91_1 1.0000 . ?
C92_1 C93_1 1.51(2) . ?
C92_1 H92_1 1.0000 . ?
C93_1 C94_1 1.48(2) . ?
C93_1 H93A_1 0.9900 . ?
C93_1 H93B_1 0.9900 . ?
C94_1 C95_1 1.55(2) . ?
C94_1 H94A_1 0.9900 . ?
C94_1 H94B_1 0.9900 . ?
C95_1 C96_1 1.320(19) . ?
C95_1 H95_1 1.0000 . ?
C96_1 C97_1 1.49(2) . ?
C96_1 H96_1 1.0000 . ?
C97_1 C98_1 1.52(2) . ?
C97_1 H97A_1 0.9900 . ?
C97_1 H97B_1 0.9900 . ?
C98_1 H98A_1 0.9900 . ?
C98_1 H98B_1 0.9900 . ?
Rh1_2 C96_2 2.233(18) . ?
Rh1_2 C95_2 2.237(18) . ?
Rh1_2 C92_2 2.240(17) . ?
Rh1_2 C91_2 2.267(17) . ?
Rh1_2 P2_2 2.300(7) . ?
Rh1_2 P1_2 2.321(6) . ?
P1_2 C51_2 1.816(11) . ?
P1_2 C61_2 1.835(11) . ?
P1_2 C11_2 1.856(9) . ?
P2_2 C71_2 1.828(12) . ?
P2_2 C81_2 1.846(12) . ?
P2_2 C21_2 1.868(9) . ?
Cl1_2 C33_2 1.699(10) . ?
Cl2_2 C35_2 1.711(10) . ?
Cl3_2 C43_2 1.703(10) . ?
Cl4_2 C45_2 1.702(10) . ?
C11_2 C12_2 1.3900 . ?
C11_2 C16_2 1.3900 . ?
C12_2 C13_2 1.3900 . ?
C12_2 C22_2 1.503(10) . ?
C13_2 C14_2 1.3900 . ?
C13_2 H13_2 0.9500 . ?
C14_2 C15_2 1.3900 . ?
C14_2 N31_2 1.425(13) . ?
C15_2 C16_2 1.3900 . ?
C15_2 H15_2 0.9500 . ?
C16_2 H16_2 0.9500 . ?
C21_2 C22_2 1.3900 . ?
C21_2 C26_2 1.3900 . ?
C22_2 C23_2 1.3900 . ?
C23_2 C24_2 1.3900 . ?
C23_2 H23_2 0.9500 . ?
C24_2 C25_2 1.3900 . ?
C24_2 N41_2 1.423(13) . ?
C25_2 C26_2 1.3900 . ?
C25_2 H25_2 0.9500 . ?
C26_2 H26_2 0.9500 . ?
C30_2 O30_2 1.229(17) . ?
C30_2 N31_2 1.341(17) . ?
C30_2 C31_2 1.478(16) . ?
N31_2 H31_2 0.8800 . ?
C31_2 C32_2 1.3900 . ?
C31_2 C36_2 1.3900 . ?
C32_2 C33_2 1.3900 . ?
C32_2 H32_2 0.9500 . ?
C33_2 C34_2 1.3900 . ?
C34_2 C35_2 1.3900 . ?
C34_2 H34_2 0.9500 . ?
C35_2 C36_2 1.3900 . ?
C36_2 H36_2 0.9500 . ?
C40_2 O40_2 1.226(16) . ?
C40_2 N41_2 1.369(17) . ?
C40_2 C41_2 1.474(15) . ?
N41_2 H41_2 0.8800 . ?
C41_2 C42_2 1.3900 . ?
C41_2 C46_2 1.3900 . ?
C42_2 C43_2 1.3900 . ?
C42_2 H42_2 0.9500 . ?
C43_2 C44_2 1.3900 . ?
C44_2 C45_2 1.3900 . ?
C44_2 H44_2 0.9500 . ?
C45_2 C46_2 1.3900 . ?
C46_2 H46_2 0.9500 . ?
C51_2 C52_2 1.3900 . ?
C51_2 C56_2 1.3900 . ?
C52_2 C53_2 1.3900 . ?
C52_2 H52_2 0.9500 . ?
C53_2 C54_2 1.3900 . ?
C53_2 H53_2 0.9500 . ?
C54_2 C55_2 1.3900 . ?
C54_2 H54_2 0.9500 . ?
C55_2 C56_2 1.3900 . ?
C55_2 H55_2 0.9500 . ?
C56_2 H56_2 0.9500 . ?
C61_2 C62_2 1.3900 . ?
C61_2 C66_2 1.3900 . ?
C62_2 C63_2 1.3900 . ?
C62_2 H62_2 0.9500 . ?
C63_2 C64_2 1.3900 . ?
C63_2 H63_2 0.9500 . ?
C64_2 C65_2 1.3900 . ?
C64_2 H64_2 0.9500 . ?
C65_2 C66_2 1.3900 . ?
C65_2 H65_2 0.9500 . ?
C66_2 H66_2 0.9500 . ?
C71_2 C72_2 1.3900 . ?
C71_2 C76_2 1.3900 . ?
C72_2 C73_2 1.3900 . ?
C72_2 H72_2 0.9500 . ?
C73_2 C74_2 1.3900 . ?
C73_2 H73_2 0.9500 . ?
C74_2 C75_2 1.3900 . ?
C74_2 H74_2 0.9500 . ?
C75_2 C76_2 1.3900 . ?
C75_2 H75_2 0.9500 . ?
C76_2 H76_2 0.9500 . ?
C81_2 C82_2 1.3900 . ?
C81_2 C86_2 1.3900 . ?
C82_2 C83_2 1.3900 . ?
C82_2 H82_2 0.9500 . ?
C83_2 C84_2 1.3900 . ?
C83_2 H83_2 0.9500 . ?
C84_2 C85_2 1.3900 . ?
C84_2 H84_2 0.9500 . ?
C85_2 C86_2 1.3900 . ?
C85_2 H85_2 0.9500 . ?
C86_2 H86_2 0.9500 . ?
C91_2 C92_2 1.31(2) . ?
C91_2 C98_2 1.53(2) . ?
C91_2 H91_2 1.0000 . ?
C92_2 C93_2 1.52(2) . ?
C92_2 H92_2 1.0000 . ?
C93_2 C94_2 1.47(2) . ?
C93_2 H93A_2 0.9900 . ?
C93_2 H93B_2 0.9900 . ?
C94_2 C95_2 1.54(2) . ?
C94_2 H94A_2 0.9900 . ?
C94_2 H94B_2 0.9900 . ?
C95_2 C96_2 1.30(2) . ?
C95_2 H95_2 1.0000 . ?
C96_2 C97_2 1.49(2) . ?
C96_2 H96_2 1.0000 . ?
C97_2 C98_2 1.52(2) . ?
C97_2 H97A_2 0.9900 . ?
C97_2 H97B_2 0.9900 . ?
C98_2 H98A_2 0.9900 . ?
C98_2 H98B_2 0.9900 . ?
Rh1_3 C92_3 2.222(17) . ?
Rh1_3 C96_3 2.236(17) . ?
Rh1_3 C95_3 2.245(18) . ?
Rh1_3 C91_3 2.265(15) . ?
Rh1_3 P1_3 2.312(6) . ?
Rh1_3 P2_3 2.325(6) . ?
P1_3 C51_3 1.810(10) . ?
P1_3 C61_3 1.839(10) . ?
P1_3 C11_3 1.869(9) . ?
P2_3 C71_3 1.821(11) . ?
P2_3 C81_3 1.853(11) . ?
P2_3 C21_3 1.853(8) . ?
Cl1_3 C33_3 1.683(13) . ?
Cl2_3 C35_3 1.704(12) . ?
Cl3_3 C43_3 1.714(8) . ?
Cl4_3 C45_3 1.716(9) . ?
C11_3 C12_3 1.3900 . ?
C11_3 C16_3 1.3900 . ?
C12_3 C13_3 1.3900 . ?
C12_3 C22_3 1.503(10) . ?
C13_3 C14_3 1.3900 . ?
C13_3 H13_3 0.9500 . ?
C14_3 C15_3 1.3900 . ?
C14_3 N31_3 1.416(13) . ?
C15_3 C16_3 1.3900 . ?
C15_3 H15_3 0.9500 . ?
C16_3 H16_3 0.9500 . ?
C21_3 C22_3 1.3900 . ?
C21_3 C26_3 1.3900 . ?
C22_3 C23_3 1.3900 . ?
C23_3 C24_3 1.3900 . ?
C23_3 H23_3 0.9500 . ?
C24_3 C25_3 1.3900 . ?
C24_3 N41_3 1.437(12) . ?
C25_3 C26_3 1.3900 . ?
C25_3 H25_3 0.9500 . ?
C26_3 H26_3 0.9500 . ?
C30_3 O30_3 1.222(18) . ?
C30_3 N31_3 1.334(19) . ?
C30_3 C31_3 1.481(18) . ?
N31_3 H31_3 0.8800 . ?
C31_3 C32_3 1.3900 . ?
C31_3 C36_3 1.3900 . ?
C32_3 C33_3 1.3900 . ?
C32_3 H32_3 0.9500 . ?
C33_3 C34_3 1.3900 . ?
C34_3 C35_3 1.3900 . ?
C34_3 H34_3 0.9500 . ?
C35_3 C36_3 1.3900 . ?
C36_3 H36_3 0.9500 . ?
C40_3 O40_3 1.234(16) . ?
C40_3 N41_3 1.375(16) . ?
C40_3 C41_3 1.482(14) . ?
N41_3 H41_3 0.8800 . ?
C41_3 C42_3 1.3900 . ?
C41_3 C46_3 1.3900 . ?
C42_3 C43_3 1.3900 . ?
C42_3 H42_3 0.9500 . ?
C43_3 C44_3 1.3900 . ?
C44_3 C45_3 1.3900 . ?
C44_3 H44_3 0.9500 . ?
C45_3 C46_3 1.3900 . ?
C46_3 H46_3 0.9500 . ?
C51_3 C52_3 1.3900 . ?
C51_3 C56_3 1.3900 . ?
C52_3 C53_3 1.3900 . ?
C52_3 H52_3 0.9500 . ?
C53_3 C54_3 1.3900 . ?
C53_3 H53_3 0.9500 . ?
C54_3 C55_3 1.3900 . ?
C54_3 H54_3 0.9500 . ?
C55_3 C56_3 1.3900 . ?
C55_3 H55_3 0.9500 . ?
C56_3 H56_3 0.9500 . ?
C61_3 C62_3 1.3900 . ?
C61_3 C66_3 1.3900 . ?
C62_3 C63_3 1.3900 . ?
C62_3 H62_3 0.9500 . ?
C63_3 C64_3 1.3900 . ?
C63_3 H63_3 0.9500 . ?
C64_3 C65_3 1.3900 . ?
C64_3 H64_3 0.9500 . ?
C65_3 C66_3 1.3900 . ?
C65_3 H65_3 0.9500 . ?
C66_3 H66_3 0.9500 . ?
C71_3 C72_3 1.3900 . ?
C71_3 C76_3 1.3900 . ?
C72_3 C73_3 1.3900 . ?
C72_3 H72_3 0.9500 . ?
C73_3 C74_3 1.3900 . ?
C73_3 H73_3 0.9500 . ?
C74_3 C75_3 1.3900 . ?
C74_3 H74_3 0.9500 . ?
C75_3 C76_3 1.3900 . ?
C75_3 H75_3 0.9500 . ?
C76_3 H76_3 0.9500 . ?
C81_3 C82_3 1.3900 . ?
C81_3 C86_3 1.3900 . ?
C82_3 C83_3 1.3900 . ?
C82_3 H82_3 0.9500 . ?
C83_3 C84_3 1.3900 . ?
C83_3 H83_3 0.9500 . ?
C84_3 C85_3 1.3900 . ?
C84_3 H84_3 0.9500 . ?
C85_3 C86_3 1.3900 . ?
C85_3 H85_3 0.9500 . ?
C86_3 H86_3 0.9500 . ?
C91_3 C92_3 1.33(2) . ?
C91_3 C98_3 1.54(2) . ?
C91_3 H91_3 1.0000 . ?
C92_3 C93_3 1.52(2) . ?
C92_3 H92_3 1.0000 . ?
C93_3 C94_3 1.48(2) . ?
C93_3 H93A_3 0.9900 . ?
C93_3 H93B_3 0.9900 . ?
C94_3 C95_3 1.55(2) . ?
C94_3 H94A_3 0.9900 . ?
C94_3 H94B_3 0.9900 . ?
C95_3 C96_3 1.31(2) . ?
C95_3 H95_3 1.0000 . ?
C96_3 C97_3 1.49(2) . ?
C96_3 H96_3 1.0000 . ?
C97_3 C98_3 1.52(2) . ?
C97_3 H97A_3 0.9900 . ?
C97_3 H97B_3 0.9900 . ?
C98_3 H98A_3 0.9900 . ?
C98_3 H98B_3 0.9900 . ?
Rh1_4 C96_4 2.213(16) . ?
Rh1_4 C95_4 2.242(15) . ?
Rh1_4 C92_4 2.243(15) . ?
Rh1_4 C91_4 2.284(14) . ?
Rh1_4 P2_4 2.304(5) . ?
Rh1_4 P1_4 2.318(5) . ?
P1_4 C51_4 1.825(9) . ?
P1_4 C61_4 1.834(8) . ?
P1_4 C11_4 1.857(7) . ?
P2_4 C71_4 1.814(9) . ?
P2_4 C81_4 1.862(8) . ?
P2_4 C21_4 1.865(7) . ?
Cl1_4 C33_4 1.701(10) . ?
Cl2_4 C35_4 1.700(11) . ?
Cl3_4 C43_4 1.706(9) . ?
Cl4_4 C45_4 1.706(9) . ?
C11_4 C12_4 1.3900 . ?
C11_4 C16_4 1.3900 . ?
C12_4 C13_4 1.3900 . ?
C12_4 C22_4 1.503(8) . ?
C13_4 C14_4 1.3900 . ?
C13_4 H13_4 0.9500 . ?
C14_4 C15_4 1.3900 . ?
C14_4 N31_4 1.422(12) . ?
C15_4 C16_4 1.3900 . ?
C15_4 H15_4 0.9500 . ?
C16_4 H16_4 0.9500 . ?
C21_4 C22_4 1.3900 . ?
C21_4 C26_4 1.3900 . ?
C22_4 C23_4 1.3900 . ?
C23_4 C24_4 1.3900 . ?
C23_4 H23_4 0.9500 . ?
C24_4 C25_4 1.3900 . ?
C24_4 N41_4 1.436(12) . ?
C25_4 C26_4 1.3900 . ?
C25_4 H25_4 0.9500 . ?
C26_4 H26_4 0.9500 . ?
C30_4 O30_4 1.228(17) . ?
C30_4 N31_4 1.328(17) . ?
C30_4 C31_4 1.483(16) . ?
N31_4 H31_4 0.8800 . ?
C31_4 C32_4 1.3900 . ?
C31_4 C36_4 1.3900 . ?
C32_4 C33_4 1.3900 . ?
C32_4 H32_4 0.9500 . ?
C33_4 C34_4 1.3900 . ?
C34_4 C35_4 1.3900 . ?
C34_4 H34_4 0.9500 . ?
C35_4 C36_4 1.3900 . ?
C36_4 H36_4 0.9500 . ?
C40_4 O40_4 1.227(16) . ?
C40_4 N41_4 1.383(16) . ?
C40_4 C41_4 1.477(14) . ?
N41_4 H41_4 0.8800 . ?
C41_4 C42_4 1.3900 . ?
C41_4 C46_4 1.3900 . ?
C42_4 C43_4 1.3900 . ?
C42_4 H42_4 0.9500 . ?
C43_4 C44_4 1.3900 . ?
C44_4 C45_4 1.3900 . ?
C44_4 H44_4 0.9500 . ?
C45_4 C46_4 1.3900 . ?
C46_4 H46_4 0.9500 . ?
C51_4 C52_4 1.3900 . ?
C51_4 C56_4 1.3900 . ?
C52_4 C53_4 1.3900 . ?
C52_4 H52_4 0.9500 . ?
C53_4 C54_4 1.3900 . ?
C53_4 H53_4 0.9500 . ?
C54_4 C55_4 1.3900 . ?
C54_4 H54_4 0.9500 . ?
C55_4 C56_4 1.3900 . ?
C55_4 H55_4 0.9500 . ?
C56_4 H56_4 0.9500 . ?
C61_4 C62_4 1.3900 . ?
C61_4 C66_4 1.3900 . ?
C62_4 C63_4 1.3900 . ?
C62_4 H62_4 0.9500 . ?
C63_4 C64_4 1.3900 . ?
C63_4 H63_4 0.9500 . ?
C64_4 C65_4 1.3900 . ?
C64_4 H64_4 0.9500 . ?
C65_4 C66_4 1.3900 . ?
C65_4 H65_4 0.9500 . ?
C66_4 H66_4 0.9500 . ?
C71_4 C72_4 1.3900 . ?
C71_4 C76_4 1.3900 . ?
C72_4 C73_4 1.3900 . ?
C72_4 H72_4 0.9500 . ?
C73_4 C74_4 1.3900 . ?
C73_4 H73_4 0.9500 . ?
C74_4 C75_4 1.3900 . ?
C74_4 H74_4 0.9500 . ?
C75_4 C76_4 1.3900 . ?
C75_4 H75_4 0.9500 . ?
C76_4 H76_4 0.9500 . ?
C81_4 C82_4 1.3900 . ?
C81_4 C86_4 1.3900 . ?
C82_4 C83_4 1.3900 . ?
C82_4 H82_4 0.9500 . ?
C83_4 C84_4 1.3900 . ?
C83_4 H83_4 0.9500 . ?
C84_4 C85_4 1.3900 . ?
C84_4 H84_4 0.9500 . ?
C85_4 C86_4 1.3900 . ?
C85_4 H85_4 0.9500 . ?
C86_4 H86_4 0.9500 . ?
C91_4 C92_4 1.328(19) . ?
C91_4 C98_4 1.540(19) . ?
C91_4 H91_4 1.0000 . ?
C92_4 C93_4 1.52(2) . ?
C92_4 H92_4 1.0000 . ?
C93_4 C94_4 1.48(2) . ?
C93_4 H93A_4 0.9900 . ?
C93_4 H93B_4 0.9900 . ?
C94_4 C95_4 1.55(2) . ?
C94_4 H94A_4 0.9900 . ?
C94_4 H94B_4 0.9900 . ?
C95_4 C96_4 1.33(2) . ?
C95_4 H95_4 1.0000 . ?
C96_4 C97_4 1.50(2) . ?
C96_4 H96_4 1.0000 . ?
C97_4 C98_4 1.52(2) . ?
C97_4 H97A_4 0.9900 . ?
C97_4 H97B_4 0.9900 . ?
C98_4 H98A_4 0.9900 . ?
C98_4 H98B_4 0.9900 . ?
B1 F12 1.340(13) . ?
B1 F14 1.356(12) . ?
B1 F11 1.358(13) . ?
B1 F13 1.361(13) . ?
B2 F22 1.343(13) . ?
B2 F24 1.344(13) . ?
B2 F23 1.352(13) . ?
B2 F21 1.365(14) . ?
B3 F33 1.341(14) . ?
B3 F31 1.344(14) . ?
B3 F32 1.345(14) . ?
B3 F34 1.348(14) . ?
B4 F44 1.342(14) . ?
B4 F43 1.345(14) . ?
B4 F41 1.346(14) . ?
B4 F42 1.348(14) . ?
C1 Cl2 1.813(18) . ?
C1 Cl1 1.818(18) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
C2 Cl4 1.804(18) . ?
C2 Cl3 1.812(18) . ?
C2 H2A 0.9900 . ?
C2 H2B 0.9900 . ?
C3 Cl6 1.805(18) . ?
C3 Cl5 1.817(18) . ?
C3 H3A 0.9900 . ?
C3 H3B 0.9900 . ?
C4 Cl7 1.816(19) . ?
C4 Cl8 1.825(19) . ?
C4 H4A 0.9900 . ?
C4 H4B 0.9900 . ?
C5 Cl9 1.818(18) . ?
C5 Cl10 1.860(18) . ?
C5 H5A 0.9900 . ?
C5 H5B 0.9900 . ?
C6 Cl12 1.816(18) . ?
C6 Cl11 1.836(18) . ?
C6 H6A 0.9900 . ?
C6 H6B 0.9900 . ?
C7 Cl14 1.808(19) . ?
C7 Cl13 1.824(19) . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C8 Cl15 1.814(19) . ?
C8 Cl16 1.819(19) . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C96_1 Rh1_1 C92_1 93.8(6) . . ?
C96_1 Rh1_1 C95_1 34.4(5) . . ?
C92_1 Rh1_1 C95_1 79.3(6) . . ?
C96_1 Rh1_1 C91_1 80.2(6) . . ?
C92_1 Rh1_1 C91_1 34.6(5) . . ?
C95_1 Rh1_1 C91_1 85.5(6) . . ?
C96_1 Rh1_1 P1_1 164.0(4) . . ?
C92_1 Rh1_1 P1_1 90.2(4) . . ?
C95_1 Rh1_1 P1_1 161.1(4) . . ?
C91_1 Rh1_1 P1_1 94.6(4) . . ?
C96_1 Rh1_1 P2_1 92.3(4) . . ?
C92_1 Rh1_1 P2_1 162.9(4) . . ?
C95_1 Rh1_1 P2_1 97.2(5) . . ?
C91_1 Rh1_1 P2_1 162.6(4) . . ?
P1_1 Rh1_1 P2_1 88.25(17) . . ?
C51_1 P1_1 C61_1 106.0(5) . . ?
C51_1 P1_1 C11_1 102.6(5) . . ?
C61_1 P1_1 C11_1 102.7(5) . . ?
C51_1 P1_1 Rh1_1 110.6(4) . . ?
C61_1 P1_1 Rh1_1 111.0(4) . . ?
C11_1 P1_1 Rh1_1 122.5(4) . . ?
C71_1 P2_1 C21_1 107.5(5) . . ?
C71_1 P2_1 C81_1 103.5(6) . . ?
C21_1 P2_1 C81_1 106.5(5) . . ?
C71_1 P2_1 Rh1_1 110.9(4) . . ?
C21_1 P2_1 Rh1_1 112.7(4) . . ?
C81_1 P2_1 Rh1_1 115.1(4) . . ?
C12_1 C11_1 C16_1 120.0 . . ?
C12_1 C11_1 P1_1 120.7(5) . . ?
C16_1 C11_1 P1_1 119.3(5) . . ?
C13_1 C12_1 C11_1 120.0 . . ?
C13_1 C12_1 C22_1 115.9(7) . . ?
C11_1 C12_1 C22_1 124.1(7) . . ?
C12_1 C13_1 C14_1 120.0 . . ?
C12_1 C13_1 H13_1 120.0 . . ?
C14_1 C13_1 H13_1 120.0 . . ?
C15_1 C14_1 C13_1 120.0 . . ?
C15_1 C14_1 N31_1 116.6(8) . . ?
C13_1 C14_1 N31_1 123.1(8) . . ?
C14_1 C15_1 C16_1 120.0 . . ?
C14_1 C15_1 H15_1 120.0 . . ?
C16_1 C15_1 H15_1 120.0 . . ?
C15_1 C16_1 C11_1 120.0 . . ?
C15_1 C16_1 H16_1 120.0 . . ?
C11_1 C16_1 H16_1 120.0 . . ?
C22_1 C21_1 C26_1 120.0 . . ?
C22_1 C21_1 P2_1 122.7(5) . . ?
C26_1 C21_1 P2_1 117.0(5) . . ?
C21_1 C22_1 C23_1 120.0 . . ?
C21_1 C22_1 C12_1 125.0(7) . . ?
C23_1 C22_1 C12_1 114.9(7) . . ?
C24_1 C23_1 C22_1 120.0 . . ?
C24_1 C23_1 H23_1 120.0 . . ?
C22_1 C23_1 H23_1 120.0 . . ?
C25_1 C24_1 C23_1 120.0 . . ?
C25_1 C24_1 N41_1 116.3(8) . . ?
C23_1 C24_1 N41_1 123.5(8) . . ?
C24_1 C25_1 C26_1 120.0 . . ?
C24_1 C25_1 H25_1 120.0 . . ?
C26_1 C25_1 H25_1 120.0 . . ?
C25_1 C26_1 C21_1 120.0 . . ?
C25_1 C26_1 H26_1 120.0 . . ?
C21_1 C26_1 H26_1 120.0 . . ?
O30_1 C30_1 N31_1 121.5(16) . . ?
O30_1 C30_1 C31_1 120.4(15) . . ?
N31_1 C30_1 C31_1 117.9(14) . . ?
C30_1 N31_1 C14_1 129.2(13) . . ?
C30_1 N31_1 H31_1 115.4 . . ?
C14_1 N31_1 H31_1 115.4 . . ?
C32_1 C31_1 C36_1 120.0 . . ?
C32_1 C31_1 C30_1 122.1(11) . . ?
C36_1 C31_1 C30_1 117.9(11) . . ?
C31_1 C32_1 C33_1 120.0 . . ?
C31_1 C32_1 H32_1 120.0 . . ?
C33_1 C32_1 H32_1 120.0 . . ?
C34_1 C33_1 C32_1 120.0 . . ?
C34_1 C33_1 Cl1_1 117.2(9) . . ?
C32_1 C33_1 Cl1_1 122.7(9) . . ?
C35_1 C34_1 C33_1 120.0 . . ?
C35_1 C34_1 H34_1 120.0 . . ?
C33_1 C34_1 H34_1 120.0 . . ?
C34_1 C35_1 C36_1 120.0 . . ?
C34_1 C35_1 Cl2_1 121.0(10) . . ?
C36_1 C35_1 Cl2_1 119.0(10) . . ?
C35_1 C36_1 C31_1 120.0 . . ?
C35_1 C36_1 H36_1 120.0 . . ?
C31_1 C36_1 H36_1 120.0 . . ?
O40_1 C40_1 N41_1 122.0(14) . . ?
O40_1 C40_1 C41_1 121.2(14) . . ?
N41_1 C40_1 C41_1 116.7(13) . . ?
C40_1 N41_1 C24_1 126.5(12) . . ?
C40_1 N41_1 H41_1 116.7 . . ?
C24_1 N41_1 H41_1 116.7 . . ?
C42_1 C41_1 C46_1 120.0 . . ?
C42_1 C41_1 C40_1 122.4(10) . . ?
C46_1 C41_1 C40_1 117.3(10) . . ?
C43_1 C42_1 C41_1 120.0 . . ?
C43_1 C42_1 H42_1 120.0 . . ?
C41_1 C42_1 H42_1 120.0 . . ?
C44_1 C43_1 C42_1 120.0 . . ?
C44_1 C43_1 Cl3_1 118.1(8) . . ?
C42_1 C43_1 Cl3_1 121.9(8) . . ?
C45_1 C44_1 C43_1 120.0 . . ?
C45_1 C44_1 H44_1 120.0 . . ?
C43_1 C44_1 H44_1 120.0 . . ?
C44_1 C45_1 C46_1 120.0 . . ?
C44_1 C45_1 Cl4_1 118.3(10) . . ?
C46_1 C45_1 Cl4_1 121.7(10) . . ?
C45_1 C46_1 C41_1 120.0 . . ?
C45_1 C46_1 H46_1 120.0 . . ?
C41_1 C46_1 H46_1 120.0 . . ?
C52_1 C51_1 C56_1 120.0 . . ?
C52_1 C51_1 P1_1 119.0(6) . . ?
C56_1 C51_1 P1_1 120.9(6) . . ?
C51_1 C52_1 C53_1 120.0 . . ?
C51_1 C52_1 H52_1 120.0 . . ?
C53_1 C52_1 H52_1 120.0 . . ?
C54_1 C53_1 C52_1 120.0 . . ?
C54_1 C53_1 H53_1 120.0 . . ?
C52_1 C53_1 H53_1 120.0 . . ?
C53_1 C54_1 C55_1 120.0 . . ?
C53_1 C54_1 H54_1 120.0 . . ?
C55_1 C54_1 H54_1 120.0 . . ?
C56_1 C55_1 C54_1 120.0 . . ?
C56_1 C55_1 H55_1 120.0 . . ?
C54_1 C55_1 H55_1 120.0 . . ?
C55_1 C56_1 C51_1 120.0 . . ?
C55_1 C56_1 H56_1 120.0 . . ?
C51_1 C56_1 H56_1 120.0 . . ?
C62_1 C61_1 C66_1 120.0 . . ?
C62_1 C61_1 P1_1 116.6(6) . . ?
C66_1 C61_1 P1_1 123.4(6) . . ?
C61_1 C62_1 C63_1 120.0 . . ?
C61_1 C62_1 H62_1 120.0 . . ?
C63_1 C62_1 H62_1 120.0 . . ?
C64_1 C63_1 C62_1 120.0 . . ?
C64_1 C63_1 H63_1 120.0 . . ?
C62_1 C63_1 H63_1 120.0 . . ?
C63_1 C64_1 C65_1 120.0 . . ?
C63_1 C64_1 H64_1 120.0 . . ?
C65_1 C64_1 H64_1 120.0 . . ?
C64_1 C65_1 C66_1 120.0 . . ?
C64_1 C65_1 H65_1 120.0 . . ?
C66_1 C65_1 H65_1 120.0 . . ?
C65_1 C66_1 C61_1 120.0 . . ?
C65_1 C66_1 H66_1 120.0 . . ?
C61_1 C66_1 H66_1 120.0 . . ?
C72_1 C71_1 C76_1 120.0 . . ?
C72_1 C71_1 P2_1 117.3(7) . . ?
C76_1 C71_1 P2_1 122.7(7) . . ?
C71_1 C72_1 C73_1 120.0 . . ?
C71_1 C72_1 H72_1 120.0 . . ?
C73_1 C72_1 H72_1 120.0 . . ?
C74_1 C73_1 C72_1 120.0 . . ?
C74_1 C73_1 H73_1 120.0 . . ?
C72_1 C73_1 H73_1 120.0 . . ?
C73_1 C74_1 C75_1 120.0 . . ?
C73_1 C74_1 H74_1 120.0 . . ?
C75_1 C74_1 H74_1 120.0 . . ?
C76_1 C75_1 C74_1 120.0 . . ?
C76_1 C75_1 H75_1 120.0 . . ?
C74_1 C75_1 H75_1 120.0 . . ?
C75_1 C76_1 C71_1 120.0 . . ?
C75_1 C76_1 H76_1 120.0 . . ?
C71_1 C76_1 H76_1 120.0 . . ?
C82_1 C81_1 C86_1 120.0 . . ?
C82_1 C81_1 P2_1 118.2(6) . . ?
C86_1 C81_1 P2_1 121.8(6) . . ?
C81_1 C82_1 C83_1 120.0 . . ?
C81_1 C82_1 H82_1 120.0 . . ?
C83_1 C82_1 H82_1 120.0 . . ?
C84_1 C83_1 C82_1 120.0 . . ?
C84_1 C83_1 H83_1 120.0 . . ?
C82_1 C83_1 H83_1 120.0 . . ?
C83_1 C84_1 C85_1 120.0 . . ?
C83_1 C84_1 H84_1 120.0 . . ?
C85_1 C84_1 H84_1 120.0 . . ?
C86_1 C85_1 C84_1 120.0 . . ?
C86_1 C85_1 H85_1 120.0 . . ?
C84_1 C85_1 H85_1 120.0 . . ?
C85_1 C86_1 C81_1 120.0 . . ?
C85_1 C86_1 H86_1 120.0 . . ?
C81_1 C86_1 H86_1 120.0 . . ?
C92_1 C91_1 C98_1 124.9(15) . . ?
C92_1 C91_1 Rh1_1 71.5(8) . . ?
C98_1 C91_1 Rh1_1 110.0(9) . . ?
C92_1 C91_1 H91_1 114.1 . . ?
C98_1 C91_1 H91_1 114.1 . . ?
Rh1_1 C91_1 H91_1 114.1 . . ?
C91_1 C92_1 C93_1 128.4(16) . . ?
C91_1 C92_1 Rh1_1 74.0(9) . . ?
C93_1 C92_1 Rh1_1 107.3(11) . . ?
C91_1 C92_1 H92_1 113.1 . . ?
C93_1 C92_1 H92_1 113.1 . . ?
Rh1_1 C92_1 H92_1 113.1 . . ?
C94_1 C93_1 C92_1 113.4(15) . . ?
C94_1 C93_1 H93A_1 108.9 . . ?
C92_1 C93_1 H93A_1 108.9 . . ?
C94_1 C93_1 H93B_1 108.9 . . ?
C92_1 C93_1 H93B_1 108.9 . . ?
H93A_1 C93_1 H93B_1 107.7 . . ?
C93_1 C94_1 C95_1 114.0(14) . . ?
C93_1 C94_1 H94A_1 108.8 . . ?
C95_1 C94_1 H94A_1 108.8 . . ?
C93_1 C94_1 H94B_1 108.8 . . ?
C95_1 C94_1 H94B_1 108.8 . . ?
H94A_1 C94_1 H94B_1 107.6 . . ?
C96_1 C95_1 C94_1 126.7(16) . . ?
C96_1 C95_1 Rh1_1 72.3(9) . . ?
C94_1 C95_1 Rh1_1 110.5(11) . . ?
C96_1 C95_1 H95_1 113.3 . . ?
C94_1 C95_1 H95_1 113.3 . . ?
Rh1_1 C95_1 H95_1 113.3 . . ?
C95_1 C96_1 C97_1 126.1(16) . . ?
C95_1 C96_1 Rh1_1 73.3(9) . . ?
C97_1 C96_1 Rh1_1 107.2(11) . . ?
C95_1 C96_1 H96_1 114.0 . . ?
C97_1 C96_1 H96_1 114.0 . . ?
Rh1_1 C96_1 H96_1 114.0 . . ?
C96_1 C97_1 C98_1 115.0(14) . . ?
C96_1 C97_1 H97A_1 108.5 . . ?
C98_1 C97_1 H97A_1 108.5 . . ?
C96_1 C97_1 H97B_1 108.5 . . ?
C98_1 C97_1 H97B_1 108.5 . . ?
H97A_1 C97_1 H97B_1 107.5 . . ?
C97_1 C98_1 C91_1 113.6(13) . . ?
C97_1 C98_1 H98A_1 108.8 . . ?
C91_1 C98_1 H98A_1 108.8 . . ?
C97_1 C98_1 H98B_1 108.8 . . ?
C91_1 C98_1 H98B_1 108.8 . . ?
H98A_1 C98_1 H98B_1 107.7 . . ?
C96_2 Rh1_2 C95_2 33.9(6) . . ?
C96_2 Rh1_2 C92_2 88.7(8) . . ?
C95_2 Rh1_2 C92_2 79.2(8) . . ?
C96_2 Rh1_2 C91_2 79.6(8) . . ?
C95_2 Rh1_2 C91_2 89.7(8) . . ?
C92_2 Rh1_2 C91_2 33.9(6) . . ?
C96_2 Rh1_2 P2_2 93.9(7) . . ?
C95_2 Rh1_2 P2_2 94.7(7) . . ?
C92_2 Rh1_2 P2_2 164.9(8) . . ?
C91_2 Rh1_2 P2_2 161.0(8) . . ?
C96_2 Rh1_2 P1_2 163.8(8) . . ?
C95_2 Rh1_2 P1_2 161.7(8) . . ?
C92_2 Rh1_2 P1_2 92.9(7) . . ?
C91_2 Rh1_2 P1_2 92.8(6) . . ?
P2_2 Rh1_2 P1_2 88.8(2) . . ?
C51_2 P1_2 C61_2 106.6(9) . . ?
C51_2 P1_2 C11_2 102.6(7) . . ?
C61_2 P1_2 C11_2 102.7(8) . . ?
C51_2 P1_2 Rh1_2 111.9(6) . . ?
C61_2 P1_2 Rh1_2 111.3(7) . . ?
C11_2 P1_2 Rh1_2 120.5(6) . . ?
C71_2 P2_2 C81_2 104.8(9) . . ?
C71_2 P2_2 C21_2 106.6(8) . . ?
C81_2 P2_2 C21_2 106.6(8) . . ?
C71_2 P2_2 Rh1_2 114.3(7) . . ?
C81_2 P2_2 Rh1_2 112.3(6) . . ?
C21_2 P2_2 Rh1_2 111.6(6) . . ?
C12_2 C11_2 C16_2 120.0 . . ?
C12_2 C11_2 P1_2 121.2(7) . . ?
C16_2 C11_2 P1_2 118.8(7) . . ?
C11_2 C12_2 C13_2 120.0 . . ?
C11_2 C12_2 C22_2 123.2(9) . . ?
C13_2 C12_2 C22_2 116.8(9) . . ?
C14_2 C13_2 C12_2 120.0 . . ?
C14_2 C13_2 H13_2 120.0 . . ?
C12_2 C13_2 H13_2 120.0 . . ?
C13_2 C14_2 C15_2 120.0 . . ?
C13_2 C14_2 N31_2 124.6(10) . . ?
C15_2 C14_2 N31_2 115.1(10) . . ?
C16_2 C15_2 C14_2 120.0 . . ?
C16_2 C15_2 H15_2 120.0 . . ?
C14_2 C15_2 H15_2 120.0 . . ?
C15_2 C16_2 C11_2 120.0 . . ?
C15_2 C16_2 H16_2 120.0 . . ?
C11_2 C16_2 H16_2 120.0 . . ?
C22_2 C21_2 C26_2 120.0 . . ?
C22_2 C21_2 P2_2 122.5(7) . . ?
C26_2 C21_2 P2_2 117.4(7) . . ?
C21_2 C22_2 C23_2 120.0 . . ?
C21_2 C22_2 C12_2 124.1(9) . . ?
C23_2 C22_2 C12_2 115.7(9) . . ?
C24_2 C23_2 C22_2 120.0 . . ?
C24_2 C23_2 H23_2 120.0 . . ?
C22_2 C23_2 H23_2 120.0 . . ?
C25_2 C24_2 C23_2 120.0 . . ?
C25_2 C24_2 N41_2 115.9(9) . . ?
C23_2 C24_2 N41_2 124.1(9) . . ?
C26_2 C25_2 C24_2 120.0 . . ?
C26_2 C25_2 H25_2 120.0 . . ?
C24_2 C25_2 H25_2 120.0 . . ?
C25_2 C26_2 C21_2 120.0 . . ?
C25_2 C26_2 H26_2 120.0 . . ?
C21_2 C26_2 H26_2 120.0 . . ?
O30_2 C30_2 N31_2 124.1(16) . . ?
O30_2 C30_2 C31_2 118.6(15) . . ?
N31_2 C30_2 C31_2 117.2(14) . . ?
C30_2 N31_2 C14_2 127.2(14) . . ?
C30_2 N31_2 H31_2 116.4 . . ?
C14_2 N31_2 H31_2 116.4 . . ?
C32_2 C31_2 C36_2 120.0 . . ?
C32_2 C31_2 C30_2 122.8(10) . . ?
C36_2 C31_2 C30_2 117.1(10) . . ?
C31_2 C32_2 C33_2 120.0 . . ?
C31_2 C32_2 H32_2 120.0 . . ?
C33_2 C32_2 H32_2 120.0 . . ?
C34_2 C33_2 C32_2 120.0 . . ?
C34_2 C33_2 Cl1_2 118.9(8) . . ?
C32_2 C33_2 Cl1_2 121.1(8) . . ?
C33_2 C34_2 C35_2 120.0 . . ?
C33_2 C34_2 H34_2 120.0 . . ?
C35_2 C34_2 H34_2 120.0 . . ?
C36_2 C35_2 C34_2 120.0 . . ?
C36_2 C35_2 Cl2_2 119.0(8) . . ?
C34_2 C35_2 Cl2_2 121.0(8) . . ?
C35_2 C36_2 C31_2 120.0 . . ?
C35_2 C36_2 H36_2 120.0 . . ?
C31_2 C36_2 H36_2 120.0 . . ?
O40_2 C40_2 N41_2 123.3(16) . . ?
O40_2 C40_2 C41_2 120.6(15) . . ?
N41_2 C40_2 C41_2 116.0(13) . . ?
C40_2 N41_2 C24_2 127.4(13) . . ?
C40_2 N41_2 H41_2 116.3 . . ?
C24_2 N41_2 H41_2 116.3 . . ?
C42_2 C41_2 C46_2 120.0 . . ?
C42_2 C41_2 C40_2 123.7(10) . . ?
C46_2 C41_2 C40_2 115.9(10) . . ?
C43_2 C42_2 C41_2 120.0 . . ?
C43_2 C42_2 H42_2 120.0 . . ?
C41_2 C42_2 H42_2 120.0 . . ?
C42_2 C43_2 C44_2 120.0 . . ?
C42_2 C43_2 Cl3_2 121.1(7) . . ?
C44_2 C43_2 Cl3_2 118.9(7) . . ?
C45_2 C44_2 C43_2 120.0 . . ?
C45_2 C44_2 H44_2 120.0 . . ?
C43_2 C44_2 H44_2 120.0 . . ?
C46_2 C45_2 C44_2 120.0 . . ?
C46_2 C45_2 Cl4_2 121.5(8) . . ?
C44_2 C45_2 Cl4_2 118.5(8) . . ?
C45_2 C46_2 C41_2 120.0 . . ?
C45_2 C46_2 H46_2 120.0 . . ?
C41_2 C46_2 H46_2 120.0 . . ?
C52_2 C51_2 C56_2 120.0 . . ?
C52_2 C51_2 P1_2 118.5(9) . . ?
C56_2 C51_2 P1_2 121.4(9) . . ?
C51_2 C52_2 C53_2 120.0 . . ?
C51_2 C52_2 H52_2 120.0 . . ?
C53_2 C52_2 H52_2 120.0 . . ?
C54_2 C53_2 C52_2 120.0 . . ?
C54_2 C53_2 H53_2 120.0 . . ?
C52_2 C53_2 H53_2 120.0 . . ?
C53_2 C54_2 C55_2 120.0 . . ?
C53_2 C54_2 H54_2 120.0 . . ?
C55_2 C54_2 H54_2 120.0 . . ?
C54_2 C55_2 C56_2 120.0 . . ?
C54_2 C55_2 H55_2 120.0 . . ?
C56_2 C55_2 H55_2 120.0 . . ?
C55_2 C56_2 C51_2 120.0 . . ?
C55_2 C56_2 H56_2 120.0 . . ?
C51_2 C56_2 H56_2 120.0 . . ?
C62_2 C61_2 C66_2 120.0 . . ?
C62_2 C61_2 P1_2 119.3(11) . . ?
C66_2 C61_2 P1_2 120.4(11) . . ?
C63_2 C62_2 C61_2 120.0 . . ?
C63_2 C62_2 H62_2 120.0 . . ?
C61_2 C62_2 H62_2 120.0 . . ?
C64_2 C63_2 C62_2 120.0 . . ?
C64_2 C63_2 H63_2 120.0 . . ?
C62_2 C63_2 H63_2 120.0 . . ?
C65_2 C64_2 C63_2 120.0 . . ?
C65_2 C64_2 H64_2 120.0 . . ?
C63_2 C64_2 H64_2 120.0 . . ?
C64_2 C65_2 C66_2 120.0 . . ?
C64_2 C65_2 H65_2 120.0 . . ?
C66_2 C65_2 H65_2 120.0 . . ?
C65_2 C66_2 C61_2 120.0 . . ?
C65_2 C66_2 H66_2 120.0 . . ?
C61_2 C66_2 H66_2 120.0 . . ?
C72_2 C71_2 C76_2 120.0 . . ?
C72_2 C71_2 P2_2 116.0(11) . . ?
C76_2 C71_2 P2_2 124.0(11) . . ?
C73_2 C72_2 C71_2 120.0 . . ?
C73_2 C72_2 H72_2 120.0 . . ?
C71_2 C72_2 H72_2 120.0 . . ?
C72_2 C73_2 C74_2 120.0 . . ?
C72_2 C73_2 H73_2 120.0 . . ?
C74_2 C73_2 H73_2 120.0 . . ?
C73_2 C74_2 C75_2 120.0 . . ?
C73_2 C74_2 H74_2 120.0 . . ?
C75_2 C74_2 H74_2 120.0 . . ?
C74_2 C75_2 C76_2 120.0 . . ?
C74_2 C75_2 H75_2 120.0 . . ?
C76_2 C75_2 H75_2 120.0 . . ?
C75_2 C76_2 C71_2 120.0 . . ?
C75_2 C76_2 H76_2 120.0 . . ?
C71_2 C76_2 H76_2 120.0 . . ?
C82_2 C81_2 C86_2 120.0 . . ?
C82_2 C81_2 P2_2 121.6(11) . . ?
C86_2 C81_2 P2_2 118.4(10) . . ?
C83_2 C82_2 C81_2 120.0 . . ?
C83_2 C82_2 H82_2 120.0 . . ?
C81_2 C82_2 H82_2 120.0 . . ?
C82_2 C83_2 C84_2 120.0 . . ?
C82_2 C83_2 H83_2 120.0 . . ?
C84_2 C83_2 H83_2 120.0 . . ?
C83_2 C84_2 C85_2 120.0 . . ?
C83_2 C84_2 H84_2 120.0 . . ?
C85_2 C84_2 H84_2 120.0 . . ?
C84_2 C85_2 C86_2 120.0 . . ?
C84_2 C85_2 H85_2 120.0 . . ?
C86_2 C85_2 H85_2 120.0 . . ?
C85_2 C86_2 C81_2 120.0 . . ?
C85_2 C86_2 H86_2 120.0 . . ?
C81_2 C86_2 H86_2 120.0 . . ?
C92_2 C91_2 C98_2 137(2) . . ?
C92_2 C91_2 Rh1_2 71.9(10) . . ?
C98_2 C91_2 Rh1_2 106.4(14) . . ?
C92_2 C91_2 H91_2 110.4 . . ?
C98_2 C91_2 H91_2 110.4 . . ?
Rh1_2 C91_2 H91_2 110.4 . . ?
C91_2 C92_2 C93_2 125(3) . . ?
C91_2 C92_2 Rh1_2 74.2(11) . . ?
C93_2 C92_2 Rh1_2 109.6(14) . . ?
C91_2 C92_2 H92_2 113.6 . . ?
C93_2 C92_2 H92_2 113.6 . . ?
Rh1_2 C92_2 H92_2 113.6 . . ?
C94_2 C93_2 C92_2 119(2) . . ?
C94_2 C93_2 H93A_2 107.6 . . ?
C92_2 C93_2 H93A_2 107.6 . . ?
C94_2 C93_2 H93B_2 107.6 . . ?
C92_2 C93_2 H93B_2 107.6 . . ?
H93A_2 C93_2 H93B_2 107.0 . . ?
C93_2 C94_2 C95_2 112.5(19) . . ?
C93_2 C94_2 H94A_2 109.1 . . ?
C95_2 C94_2 H94A_2 109.1 . . ?
C93_2 C94_2 H94B_2 109.1 . . ?
C95_2 C94_2 H94B_2 109.1 . . ?
H94A_2 C94_2 H94B_2 107.8 . . ?
C96_2 C95_2 C94_2 135(2) . . ?
C96_2 C95_2 Rh1_2 72.9(11) . . ?
C94_2 C95_2 Rh1_2 108.5(15) . . ?
C96_2 C95_2 H95_2 110.7 . . ?
C94_2 C95_2 H95_2 110.7 . . ?
Rh1_2 C95_2 H95_2 110.7 . . ?
C95_2 C96_2 C97_2 127(3) . . ?
C95_2 C96_2 Rh1_2 73.2(11) . . ?
C97_2 C96_2 Rh1_2 109.6(14) . . ?
C95_2 C96_2 H96_2 113.3 . . ?
C97_2 C96_2 H96_2 113.3 . . ?
Rh1_2 C96_2 H96_2 113.3 . . ?
C96_2 C97_2 C98_2 118.9(19) . . ?
C96_2 C97_2 H97A_2 107.6 . . ?
C98_2 C97_2 H97A_2 107.6 . . ?
C96_2 C97_2 H97B_2 107.6 . . ?
C98_2 C97_2 H97B_2 107.6 . . ?
H97A_2 C97_2 H97B_2 107.0 . . ?
C97_2 C98_2 C91_2 112.1(18) . . ?
C97_2 C98_2 H98A_2 109.2 . . ?
C91_2 C98_2 H98A_2 109.2 . . ?
C97_2 C98_2 H98B_2 109.2 . . ?
C91_2 C98_2 H98B_2 109.2 . . ?
H98A_2 C98_2 H98B_2 107.9 . . ?
C92_3 Rh1_3 C96_3 93.7(7) . . ?
C92_3 Rh1_3 C95_3 79.5(7) . . ?
C96_3 Rh1_3 C95_3 33.9(6) . . ?
C92_3 Rh1_3 C91_3 34.5(5) . . ?
C96_3 Rh1_3 C91_3 79.5(7) . . ?
C95_3 Rh1_3 C91_3 85.0(7) . . ?
C92_3 Rh1_3 P1_3 93.5(6) . . ?
C96_3 Rh1_3 P1_3 157.9(7) . . ?
C95_3 Rh1_3 P1_3 167.9(7) . . ?
C91_3 Rh1_3 P1_3 95.0(5) . . ?
C92_3 Rh1_3 P2_3 162.0(6) . . ?
C96_3 Rh1_3 P2_3 90.9(6) . . ?
C95_3 Rh1_3 P2_3 94.9(6) . . ?
C91_3 Rh1_3 P2_3 163.0(6) . . ?
P1_3 Rh1_3 P2_3 88.7(2) . . ?
C51_3 P1_3 C61_3 104.0(7) . . ?
C51_3 P1_3 C11_3 104.1(7) . . ?
C61_3 P1_3 C11_3 105.3(7) . . ?
C51_3 P1_3 Rh1_3 113.0(5) . . ?
C61_3 P1_3 Rh1_3 116.1(6) . . ?
C11_3 P1_3 Rh1_3 113.2(6) . . ?
C71_3 P2_3 C81_3 105.9(8) . . ?
C71_3 P2_3 C21_3 105.2(7) . . ?
C81_3 P2_3 C21_3 103.6(7) . . ?
C71_3 P2_3 Rh1_3 111.1(6) . . ?
C81_3 P2_3 Rh1_3 110.6(7) . . ?
C21_3 P2_3 Rh1_3 119.3(6) . . ?
C12_3 C11_3 C16_3 120.0 . . ?
C12_3 C11_3 P1_3 122.5(7) . . ?
C16_3 C11_3 P1_3 117.1(7) . . ?
C13_3 C12_3 C11_3 120.0 . . ?
C13_3 C12_3 C22_3 115.3(9) . . ?
C11_3 C12_3 C22_3 124.7(9) . . ?
C14_3 C13_3 C12_3 120.0 . . ?
C14_3 C13_3 H13_3 120.0 . . ?
C12_3 C13_3 H13_3 120.0 . . ?
C15_3 C14_3 C13_3 120.0 . . ?
C15_3 C14_3 N31_3 116.2(10) . . ?
C13_3 C14_3 N31_3 123.8(10) . . ?
C16_3 C15_3 C14_3 120.0 . . ?
C16_3 C15_3 H15_3 120.0 . . ?
C14_3 C15_3 H15_3 120.0 . . ?
C15_3 C16_3 C11_3 120.0 . . ?
C15_3 C16_3 H16_3 120.0 . . ?
C11_3 C16_3 H16_3 120.0 . . ?
C22_3 C21_3 C26_3 120.0 . . ?
C22_3 C21_3 P2_3 121.7(6) . . ?
C26_3 C21_3 P2_3 118.2(6) . . ?
C21_3 C22_3 C23_3 120.0 . . ?
C21_3 C22_3 C12_3 122.6(8) . . ?
C23_3 C22_3 C12_3 117.3(8) . . ?
C24_3 C23_3 C22_3 120.0 . . ?
C24_3 C23_3 H23_3 120.0 . . ?
C22_3 C23_3 H23_3 120.0 . . ?
C23_3 C24_3 C25_3 120.0 . . ?
C23_3 C24_3 N41_3 123.6(9) . . ?
C25_3 C24_3 N41_3 116.4(9) . . ?
C26_3 C25_3 C24_3 120.0 . . ?
C26_3 C25_3 H25_3 120.0 . . ?
C24_3 C25_3 H25_3 120.0 . . ?
C25_3 C26_3 C21_3 120.0 . . ?
C25_3 C26_3 H26_3 120.0 . . ?
C21_3 C26_3 H26_3 120.0 . . ?
O30_3 C30_3 N31_3 125.4(19) . . ?
O30_3 C30_3 C31_3 117.5(18) . . ?
N31_3 C30_3 C31_3 116.4(16) . . ?
C30_3 N31_3 C14_3 128.6(15) . . ?
C30_3 N31_3 H31_3 115.7 . . ?
C14_3 N31_3 H31_3 115.7 . . ?
C32_3 C31_3 C36_3 120.0 . . ?
C32_3 C31_3 C30_3 121.2(13) . . ?
C36_3 C31_3 C30_3 118.2(12) . . ?
C33_3 C32_3 C31_3 120.0 . . ?
C33_3 C32_3 H32_3 120.0 . . ?
C31_3 C32_3 H32_3 120.0 . . ?
C34_3 C33_3 C32_3 120.0 . . ?
C34_3 C33_3 Cl1_3 117.1(10) . . ?
C32_3 C33_3 Cl1_3 122.9(10) . . ?
C33_3 C34_3 C35_3 120.0 . . ?
C33_3 C34_3 H34_3 120.0 . . ?
C35_3 C34_3 H34_3 120.0 . . ?
C34_3 C35_3 C36_3 120.0 . . ?
C34_3 C35_3 Cl2_3 119.0(12) . . ?
C36_3 C35_3 Cl2_3 120.8(12) . . ?
C35_3 C36_3 C31_3 120.0 . . ?
C35_3 C36_3 H36_3 120.0 . . ?
C31_3 C36_3 H36_3 120.0 . . ?
O40_3 C40_3 N41_3 122.4(14) . . ?
O40_3 C40_3 C41_3 119.5(13) . . ?
N41_3 C40_3 C41_3 118.0(12) . . ?
C40_3 N41_3 C24_3 126.4(13) . . ?
C40_3 N41_3 H41_3 116.8 . . ?
C24_3 N41_3 H41_3 116.8 . . ?
C42_3 C41_3 C46_3 120.0 . . ?
C42_3 C41_3 C40_3 124.6(8) . . ?
C46_3 C41_3 C40_3 115.4(9) . . ?
C43_3 C42_3 C41_3 120.0 . . ?
C43_3 C42_3 H42_3 120.0 . . ?
C41_3 C42_3 H42_3 120.0 . . ?
C42_3 C43_3 C44_3 120.0 . . ?
C42_3 C43_3 Cl3_3 120.6(6) . . ?
C44_3 C43_3 Cl3_3 119.4(6) . . ?
C45_3 C44_3 C43_3 120.0 . . ?
C45_3 C44_3 H44_3 120.0 . . ?
C43_3 C44_3 H44_3 120.0 . . ?
C44_3 C45_3 C46_3 120.0 . . ?
C44_3 C45_3 Cl4_3 120.2(6) . . ?
C46_3 C45_3 Cl4_3 119.8(6) . . ?
C45_3 C46_3 C41_3 120.0 . . ?
C45_3 C46_3 H46_3 120.0 . . ?
C41_3 C46_3 H46_3 120.0 . . ?
C52_3 C51_3 C56_3 120.0 . . ?
C52_3 C51_3 P1_3 120.9(9) . . ?
C56_3 C51_3 P1_3 119.1(9) . . ?
C51_3 C52_3 C53_3 120.0 . . ?
C51_3 C52_3 H52_3 120.0 . . ?
C53_3 C52_3 H52_3 120.0 . . ?
C54_3 C53_3 C52_3 120.0 . . ?
C54_3 C53_3 H53_3 120.0 . . ?
C52_3 C53_3 H53_3 120.0 . . ?
C55_3 C54_3 C53_3 120.0 . . ?
C55_3 C54_3 H54_3 120.0 . . ?
C53_3 C54_3 H54_3 120.0 . . ?
C56_3 C55_3 C54_3 120.0 . . ?
C56_3 C55_3 H55_3 120.0 . . ?
C54_3 C55_3 H55_3 120.0 . . ?
C55_3 C56_3 C51_3 120.0 . . ?
C55_3 C56_3 H56_3 120.0 . . ?
C51_3 C56_3 H56_3 120.0 . . ?
C62_3 C61_3 C66_3 120.0 . . ?
C62_3 C61_3 P1_3 117.9(9) . . ?
C66_3 C61_3 P1_3 122.0(9) . . ?
C61_3 C62_3 C63_3 120.0 . . ?
C61_3 C62_3 H62_3 120.0 . . ?
C63_3 C62_3 H62_3 120.0 . . ?
C64_3 C63_3 C62_3 120.0 . . ?
C64_3 C63_3 H63_3 120.0 . . ?
C62_3 C63_3 H63_3 120.0 . . ?
C63_3 C64_3 C65_3 120.0 . . ?
C63_3 C64_3 H64_3 120.0 . . ?
C65_3 C64_3 H64_3 120.0 . . ?
C64_3 C65_3 C66_3 120.0 . . ?
C64_3 C65_3 H65_3 120.0 . . ?
C66_3 C65_3 H65_3 120.0 . . ?
C65_3 C66_3 C61_3 120.0 . . ?
C65_3 C66_3 H66_3 120.0 . . ?
C61_3 C66_3 H66_3 120.0 . . ?
C72_3 C71_3 C76_3 120.0 . . ?
C72_3 C71_3 P2_3 118.2(9) . . ?
C76_3 C71_3 P2_3 121.5(9) . . ?
C71_3 C72_3 C73_3 120.0 . . ?
C71_3 C72_3 H72_3 120.0 . . ?
C73_3 C72_3 H72_3 120.0 . . ?
C74_3 C73_3 C72_3 120.0 . . ?
C74_3 C73_3 H73_3 120.0 . . ?
C72_3 C73_3 H73_3 120.0 . . ?
C73_3 C74_3 C75_3 120.0 . . ?
C73_3 C74_3 H74_3 120.0 . . ?
C75_3 C74_3 H74_3 120.0 . . ?
C76_3 C75_3 C74_3 120.0 . . ?
C76_3 C75_3 H75_3 120.0 . . ?
C74_3 C75_3 H75_3 120.0 . . ?
C75_3 C76_3 C71_3 120.0 . . ?
C75_3 C76_3 H76_3 120.0 . . ?
C71_3 C76_3 H76_3 120.0 . . ?
C82_3 C81_3 C86_3 120.0 . . ?
C82_3 C81_3 P2_3 118.1(11) . . ?
C86_3 C81_3 P2_3 121.9(11) . . ?
C83_3 C82_3 C81_3 120.0 . . ?
C83_3 C82_3 H82_3 120.0 . . ?
C81_3 C82_3 H82_3 120.0 . . ?
C82_3 C83_3 C84_3 120.0 . . ?
C82_3 C83_3 H83_3 120.0 . . ?
C84_3 C83_3 H83_3 120.0 . . ?
C85_3 C84_3 C83_3 120.0 . . ?
C85_3 C84_3 H84_3 120.0 . . ?
C83_3 C84_3 H84_3 120.0 . . ?
C86_3 C85_3 C84_3 120.0 . . ?
C86_3 C85_3 H85_3 120.0 . . ?
C84_3 C85_3 H85_3 120.0 . . ?
C85_3 C86_3 C81_3 120.0 . . ?
C85_3 C86_3 H86_3 120.0 . . ?
C81_3 C86_3 H86_3 120.0 . . ?
C92_3 C91_3 C98_3 128(2) . . ?
C92_3 C91_3 Rh1_3 71.0(10) . . ?
C98_3 C91_3 Rh1_3 110.0(12) . . ?
C92_3 C91_3 H91_3 113.3 . . ?
C98_3 C91_3 H91_3 113.3 . . ?
Rh1_3 C91_3 H91_3 113.3 . . ?
C91_3 C92_3 C93_3 127.8(19) . . ?
C91_3 C92_3 Rh1_3 74.5(10) . . ?
C93_3 C92_3 Rh1_3 106.6(14) . . ?
C91_3 C92_3 H92_3 113.3 . . ?
C93_3 C92_3 H92_3 113.3 . . ?
Rh1_3 C92_3 H92_3 113.3 . . ?
C94_3 C93_3 C92_3 114.1(19) . . ?
C94_3 C93_3 H93A_3 108.7 . . ?
C92_3 C93_3 H93A_3 108.7 . . ?
C94_3 C93_3 H93B_3 108.7 . . ?
C92_3 C93_3 H93B_3 108.7 . . ?
H93A_3 C93_3 H93B_3 107.6 . . ?
C93_3 C94_3 C95_3 114.1(19) . . ?
C93_3 C94_3 H94A_3 108.7 . . ?
C95_3 C94_3 H94A_3 108.7 . . ?
C93_3 C94_3 H94B_3 108.7 . . ?
C95_3 C94_3 H94B_3 108.7 . . ?
H94A_3 C94_3 H94B_3 107.6 . . ?
C96_3 C95_3 C94_3 128(2) . . ?
C96_3 C95_3 Rh1_3 72.7(11) . . ?
C94_3 C95_3 Rh1_3 110.2(13) . . ?
C96_3 C95_3 H95_3 112.6 . . ?
C94_3 C95_3 H95_3 112.6 . . ?
Rh1_3 C95_3 H95_3 112.6 . . ?
C95_3 C96_3 C97_3 129(2) . . ?
C95_3 C96_3 Rh1_3 73.4(11) . . ?
C97_3 C96_3 Rh1_3 106.9(14) . . ?
C95_3 C96_3 H96_3 113.2 . . ?
C97_3 C96_3 H96_3 113.2 . . ?
Rh1_3 C96_3 H96_3 113.2 . . ?
C96_3 C97_3 C98_3 114.1(18) . . ?
C96_3 C97_3 H97A_3 108.7 . . ?
C98_3 C97_3 H97A_3 108.7 . . ?
C96_3 C97_3 H97B_3 108.7 . . ?
C98_3 C97_3 H97B_3 108.7 . . ?
H97A_3 C97_3 H97B_3 107.6 . . ?
C97_3 C98_3 C91_3 113.5(17) . . ?
C97_3 C98_3 H98A_3 108.9 . . ?
C91_3 C98_3 H98A_3 108.9 . . ?
C97_3 C98_3 H98B_3 108.9 . . ?
C91_3 C98_3 H98B_3 108.9 . . ?
H98A_3 C98_3 H98B_3 107.7 . . ?
C96_4 Rh1_4 C95_4 34.6(5) . . ?
C96_4 Rh1_4 C92_4 93.3(6) . . ?
C95_4 Rh1_4 C92_4 78.9(6) . . ?
C96_4 Rh1_4 C91_4 79.2(6) . . ?
C95_4 Rh1_4 C91_4 84.5(6) . . ?
C92_4 Rh1_4 C91_4 34.1(5) . . ?
C96_4 Rh1_4 P2_4 94.0(5) . . ?
C95_4 Rh1_4 P2_4 96.0(5) . . ?
C92_4 Rh1_4 P2_4 158.5(4) . . ?
C91_4 Rh1_4 P2_4 167.2(4) . . ?
C96_4 Rh1_4 P1_4 162.0(5) . . ?
C95_4 Rh1_4 P1_4 162.5(4) . . ?
C92_4 Rh1_4 P1_4 90.5(4) . . ?
C91_4 Rh1_4 P1_4 94.5(4) . . ?
P2_4 Rh1_4 P1_4 88.78(17) . . ?
C51_4 P1_4 C61_4 106.1(6) . . ?
C51_4 P1_4 C11_4 101.0(5) . . ?
C61_4 P1_4 C11_4 102.7(5) . . ?
C51_4 P1_4 Rh1_4 113.0(4) . . ?
C61_4 P1_4 Rh1_4 112.0(4) . . ?
C11_4 P1_4 Rh1_4 120.6(4) . . ?
C71_4 P2_4 C81_4 101.9(6) . . ?
C71_4 P2_4 C21_4 106.0(5) . . ?
C81_4 P2_4 C21_4 106.6(5) . . ?
C71_4 P2_4 Rh1_4 113.2(4) . . ?
C81_4 P2_4 Rh1_4 114.8(4) . . ?
C21_4 P2_4 Rh1_4 113.3(4) . . ?
C12_4 C11_4 C16_4 120.0 . . ?
C12_4 C11_4 P1_4 121.5(5) . . ?
C16_4 C11_4 P1_4 118.4(5) . . ?
C11_4 C12_4 C13_4 120.0 . . ?
C11_4 C12_4 C22_4 123.8(7) . . ?
C13_4 C12_4 C22_4 116.2(7) . . ?
C14_4 C13_4 C12_4 120.0 . . ?
C14_4 C13_4 H13_4 120.0 . . ?
C12_4 C13_4 H13_4 120.0 . . ?
C15_4 C14_4 C13_4 120.0 . . ?
C15_4 C14_4 N31_4 115.5(8) . . ?
C13_4 C14_4 N31_4 124.5(8) . . ?
C14_4 C15_4 C16_4 120.0 . . ?
C14_4 C15_4 H15_4 120.0 . . ?
C16_4 C15_4 H15_4 120.0 . . ?
C15_4 C16_4 C11_4 120.0 . . ?
C15_4 C16_4 H16_4 120.0 . . ?
C11_4 C16_4 H16_4 120.0 . . ?
C22_4 C21_4 C26_4 120.0 . . ?
C22_4 C21_4 P2_4 121.9(5) . . ?
C26_4 C21_4 P2_4 117.7(5) . . ?
C21_4 C22_4 C23_4 120.0 . . ?
C21_4 C22_4 C12_4 125.0(7) . . ?
C23_4 C22_4 C12_4 115.0(7) . . ?
C24_4 C23_4 C22_4 120.0 . . ?
C24_4 C23_4 H23_4 120.0 . . ?
C22_4 C23_4 H23_4 120.0 . . ?
C23_4 C24_4 C25_4 120.0 . . ?
C23_4 C24_4 N41_4 124.2(8) . . ?
C25_4 C24_4 N41_4 115.7(8) . . ?
C26_4 C25_4 C24_4 120.0 . . ?
C26_4 C25_4 H25_4 120.0 . . ?
C24_4 C25_4 H25_4 120.0 . . ?
C25_4 C26_4 C21_4 120.0 . . ?
C25_4 C26_4 H26_4 120.0 . . ?
C21_4 C26_4 H26_4 120.0 . . ?
O30_4 C30_4 N31_4 122.7(16) . . ?
O30_4 C30_4 C31_4 120.5(15) . . ?
N31_4 C30_4 C31_4 116.8(14) . . ?
C30_4 N31_4 C14_4 127.6(12) . . ?
C30_4 N31_4 H31_4 116.2 . . ?
C14_4 N31_4 H31_4 116.2 . . ?
C32_4 C31_4 C36_4 120.0 . . ?
C32_4 C31_4 C30_4 122.5(10) . . ?
C36_4 C31_4 C30_4 117.5(10) . . ?
C33_4 C32_4 C31_4 120.0 . . ?
C33_4 C32_4 H32_4 120.0 . . ?
C31_4 C32_4 H32_4 120.0 . . ?
C32_4 C33_4 C34_4 120.0 . . ?
C32_4 C33_4 Cl1_4 122.7(8) . . ?
C34_4 C33_4 Cl1_4 117.2(8) . . ?
C33_4 C34_4 C35_4 120.0 . . ?
C33_4 C34_4 H34_4 120.0 . . ?
C35_4 C34_4 H34_4 120.0 . . ?
C36_4 C35_4 C34_4 120.0 . . ?
C36_4 C35_4 Cl2_4 120.7(9) . . ?
C34_4 C35_4 Cl2_4 119.2(9) . . ?
C35_4 C36_4 C31_4 120.0 . . ?
C35_4 C36_4 H36_4 120.0 . . ?
C31_4 C36_4 H36_4 120.0 . . ?
O40_4 C40_4 N41_4 123.0(14) . . ?
O40_4 C40_4 C41_4 120.0(13) . . ?
N41_4 C40_4 C41_4 116.8(12) . . ?
C40_4 N41_4 C24_4 126.6(12) . . ?
C40_4 N41_4 H41_4 116.7 . . ?
C24_4 N41_4 H41_4 116.7 . . ?
C42_4 C41_4 C46_4 120.0 . . ?
C42_4 C41_4 C40_4 122.4(9) . . ?
C46_4 C41_4 C40_4 117.4(9) . . ?
C43_4 C42_4 C41_4 120.0 . . ?
C43_4 C42_4 H42_4 120.0 . . ?
C41_4 C42_4 H42_4 120.0 . . ?
C42_4 C43_4 C44_4 120.0 . . ?
C42_4 C43_4 Cl3_4 120.2(7) . . ?
C44_4 C43_4 Cl3_4 119.4(7) . . ?
C45_4 C44_4 C43_4 120.0 . . ?
C45_4 C44_4 H44_4 120.0 . . ?
C43_4 C44_4 H44_4 120.0 . . ?
C44_4 C45_4 C46_4 120.0 . . ?
C44_4 C45_4 Cl4_4 118.5(7) . . ?
C46_4 C45_4 Cl4_4 121.5(7) . . ?
C45_4 C46_4 C41_4 120.0 . . ?
C45_4 C46_4 H46_4 120.0 . . ?
C41_4 C46_4 H46_4 120.0 . . ?
C52_4 C51_4 C56_4 120.0 . . ?
C52_4 C51_4 P1_4 120.0(6) . . ?
C56_4 C51_4 P1_4 120.0(6) . . ?
C53_4 C52_4 C51_4 120.0 . . ?
C53_4 C52_4 H52_4 120.0 . . ?
C51_4 C52_4 H52_4 120.0 . . ?
C54_4 C53_4 C52_4 120.0 . . ?
C54_4 C53_4 H53_4 120.0 . . ?
C52_4 C53_4 H53_4 120.0 . . ?
C55_4 C54_4 C53_4 120.0 . . ?
C55_4 C54_4 H54_4 120.0 . . ?
C53_4 C54_4 H54_4 120.0 . . ?
C54_4 C55_4 C56_4 120.0 . . ?
C54_4 C55_4 H55_4 120.0 . . ?
C56_4 C55_4 H55_4 120.0 . . ?
C55_4 C56_4 C51_4 120.0 . . ?
C55_4 C56_4 H56_4 120.0 . . ?
C51_4 C56_4 H56_4 120.0 . . ?
C62_4 C61_4 C66_4 120.0 . . ?
C62_4 C61_4 P1_4 118.5(6) . . ?
C66_4 C61_4 P1_4 121.2(6) . . ?
C63_4 C62_4 C61_4 120.0 . . ?
C63_4 C62_4 H62_4 120.0 . . ?
C61_4 C62_4 H62_4 120.0 . . ?
C62_4 C63_4 C64_4 120.0 . . ?
C62_4 C63_4 H63_4 120.0 . . ?
C64_4 C63_4 H63_4 120.0 . . ?
C63_4 C64_4 C65_4 120.0 . . ?
C63_4 C64_4 H64_4 120.0 . . ?
C65_4 C64_4 H64_4 120.0 . . ?
C66_4 C65_4 C64_4 120.0 . . ?
C66_4 C65_4 H65_4 120.0 . . ?
C64_4 C65_4 H65_4 120.0 . . ?
C65_4 C66_4 C61_4 120.0 . . ?
C65_4 C66_4 H66_4 120.0 . . ?
C61_4 C66_4 H66_4 120.0 . . ?
C72_4 C71_4 C76_4 120.0 . . ?
C72_4 C71_4 P2_4 119.6(6) . . ?
C76_4 C71_4 P2_4 120.4(6) . . ?
C73_4 C72_4 C71_4 120.0 . . ?
C73_4 C72_4 H72_4 120.0 . . ?
C71_4 C72_4 H72_4 120.0 . . ?
C72_4 C73_4 C74_4 120.0 . . ?
C72_4 C73_4 H73_4 120.0 . . ?
C74_4 C73_4 H73_4 120.0 . . ?
C75_4 C74_4 C73_4 120.0 . . ?
C75_4 C74_4 H74_4 120.0 . . ?
C73_4 C74_4 H74_4 120.0 . . ?
C74_4 C75_4 C76_4 120.0 . . ?
C74_4 C75_4 H75_4 120.0 . . ?
C76_4 C75_4 H75_4 120.0 . . ?
C75_4 C76_4 C71_4 120.0 . . ?
C75_4 C76_4 H76_4 120.0 . . ?
C71_4 C76_4 H76_4 120.0 . . ?
C82_4 C81_4 C86_4 120.0 . . ?
C82_4 C81_4 P2_4 120.4(6) . . ?
C86_4 C81_4 P2_4 119.6(6) . . ?
C83_4 C82_4 C81_4 120.0 . . ?
C83_4 C82_4 H82_4 120.0 . . ?
C81_4 C82_4 H82_4 120.0 . . ?
C82_4 C83_4 C84_4 120.0 . . ?
C82_4 C83_4 H83_4 120.0 . . ?
C84_4 C83_4 H83_4 120.0 . . ?
C83_4 C84_4 C85_4 120.0 . . ?
C83_4 C84_4 H84_4 120.0 . . ?
C85_4 C84_4 H84_4 120.0 . . ?
C86_4 C85_4 C84_4 120.0 . . ?
C86_4 C85_4 H85_4 120.0 . . ?
C84_4 C85_4 H85_4 120.0 . . ?
C85_4 C86_4 C81_4 120.0 . . ?
C85_4 C86_4 H86_4 120.0 . . ?
C81_4 C86_4 H86_4 120.0 . . ?
C92_4 C91_4 C98_4 126.3(15) . . ?
C92_4 C91_4 Rh1_4 71.3(9) . . ?
C98_4 C91_4 Rh1_4 109.9(10) . . ?
C92_4 C91_4 H91_4 113.7 . . ?
C98_4 C91_4 H91_4 113.7 . . ?
Rh1_4 C91_4 H91_4 113.7 . . ?
C91_4 C92_4 C93_4 128.9(16) . . ?
C91_4 C92_4 Rh1_4 74.6(9) . . ?
C93_4 C92_4 Rh1_4 106.3(12) . . ?
C91_4 C92_4 H92_4 112.9 . . ?
C93_4 C92_4 H92_4 112.9 . . ?
Rh1_4 C92_4 H92_4 112.9 . . ?
C94_4 C93_4 C92_4 113.1(16) . . ?
C94_4 C93_4 H93A_4 109.0 . . ?
C92_4 C93_4 H93A_4 109.0 . . ?
C94_4 C93_4 H93B_4 109.0 . . ?
C92_4 C93_4 H93B_4 109.0 . . ?
H93A_4 C93_4 H93B_4 107.8 . . ?
C93_4 C94_4 C95_4 113.2(15) . . ?
C93_4 C94_4 H94A_4 108.9 . . ?
C95_4 C94_4 H94A_4 108.9 . . ?
C93_4 C94_4 H94B_4 108.9 . . ?
C95_4 C94_4 H94B_4 108.9 . . ?
H94A_4 C94_4 H94B_4 107.7 . . ?
C96_4 C95_4 C94_4 127.6(17) . . ?
C96_4 C95_4 Rh1_4 71.5(9) . . ?
C94_4 C95_4 Rh1_4 110.8(11) . . ?
C96_4 C95_4 H95_4 113.0 . . ?
C94_4 C95_4 H95_4 113.0 . . ?
Rh1_4 C95_4 H95_4 113.0 . . ?
C95_4 C96_4 C97_4 128.0(17) . . ?
C95_4 C96_4 Rh1_4 73.9(10) . . ?
C97_4 C96_4 Rh1_4 107.7(11) . . ?
C95_4 C96_4 H96_4 113.1 . . ?
C97_4 C96_4 H96_4 113.1 . . ?
Rh1_4 C96_4 H96_4 113.1 . . ?
C96_4 C97_4 C98_4 113.3(14) . . ?
C96_4 C97_4 H97A_4 108.9 . . ?
C98_4 C97_4 H97A_4 108.9 . . ?
C96_4 C97_4 H97B_4 108.9 . . ?
C98_4 C97_4 H97B_4 108.9 . . ?
H97A_4 C97_4 H97B_4 107.7 . . ?
C97_4 C98_4 C91_4 113.1(13) . . ?
C97_4 C98_4 H98A_4 109.0 . . ?
C91_4 C98_4 H98A_4 109.0 . . ?
C97_4 C98_4 H98B_4 109.0 . . ?
C91_4 C98_4 H98B_4 109.0 . . ?
H98A_4 C98_4 H98B_4 107.8 . . ?
F12 B1 F14 113.3(12) . . ?
F12 B1 F11 108.4(13) . . ?
F14 B1 F11 110.3(13) . . ?
F12 B1 F13 109.5(13) . . ?
F14 B1 F13 109.8(12) . . ?
F11 B1 F13 105.2(12) . . ?
F22 B2 F24 113.6(15) . . ?
F22 B2 F23 114.0(15) . . ?
F24 B2 F23 109.2(14) . . ?
F22 B2 F21 103.8(15) . . ?
F24 B2 F21 107.0(15) . . ?
F23 B2 F21 108.8(15) . . ?
F33 B3 F31 108.0(17) . . ?
F33 B3 F32 110.1(17) . . ?
F31 B3 F32 109.5(18) . . ?
F33 B3 F34 111.7(18) . . ?
F31 B3 F34 109.2(17) . . ?
F32 B3 F34 108.3(17) . . ?
F44 B4 F43 110.4(18) . . ?
F44 B4 F41 108.1(18) . . ?
F43 B4 F41 112.5(19) . . ?
F44 B4 F42 109.8(18) . . ?
F43 B4 F42 109.0(18) . . ?
F41 B4 F42 106.9(18) . . ?
Cl2 C1 Cl1 103.0(15) . . ?
Cl2 C1 H1A 111.2 . . ?
Cl1 C1 H1A 111.2 . . ?
Cl2 C1 H1B 111.2 . . ?
Cl1 C1 H1B 111.2 . . ?
H1A C1 H1B 109.1 . . ?
Cl4 C2 Cl3 102.9(14) . . ?
Cl4 C2 H2A 111.2 . . ?
Cl3 C2 H2A 111.2 . . ?
Cl4 C2 H2B 111.2 . . ?
Cl3 C2 H2B 111.2 . . ?
H2A C2 H2B 109.1 . . ?
Cl6 C3 Cl5 103.3(15) . . ?
Cl6 C3 H3A 111.1 . . ?
Cl5 C3 H3A 111.1 . . ?
Cl6 C3 H3B 111.1 . . ?
Cl5 C3 H3B 111.1 . . ?
H3A C3 H3B 109.1 . . ?
Cl7 C4 Cl8 97.7(16) . . ?
Cl7 C4 H4A 112.2 . . ?
Cl8 C4 H4A 112.2 . . ?
Cl7 C4 H4B 112.2 . . ?
Cl8 C4 H4B 112.2 . . ?
H4A C4 H4B 109.8 . . ?
Cl9 C5 Cl10 96.0(15) . . ?
Cl9 C5 H5A 112.5 . . ?
Cl10 C5 H5A 112.5 . . ?
Cl9 C5 H5B 112.5 . . ?
Cl10 C5 H5B 112.5 . . ?
H5A C5 H5B 110.1 . . ?
Cl12 C6 Cl11 101.3(15) . . ?
Cl12 C6 H6A 111.5 . . ?
Cl11 C6 H6A 111.5 . . ?
Cl12 C6 H6B 111.5 . . ?
Cl11 C6 H6B 111.5 . . ?
H6A C6 H6B 109.3 . . ?
Cl14 C7 Cl13 103.7(18) . . ?
Cl14 C7 H7A 111.0 . . ?
Cl13 C7 H7A 111.0 . . ?
Cl14 C7 H7B 111.0 . . ?
Cl13 C7 H7B 111.0 . . ?
H7A C7 H7B 109.0 . . ?
Cl15 C8 Cl16 99.8(18) . . ?
Cl15 C8 H8A 111.8 . . ?
Cl16 C8 H8A 111.8 . . ?
Cl15 C8 H8B 111.8 . . ?
Cl16 C8 H8B 111.8 . . ?
H8A C8 H8B 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C51_1 P1_1 C11_1 C12_1 56.2(8) . . . . ?
C61_1 P1_1 C11_1 C12_1 166.1(7) . . . . ?
Rh1_1 P1_1 C11_1 C12_1 -68.5(8) . . . . ?
C51_1 P1_1 C11_1 C16_1 -126.7(7) . . . . ?
C61_1 P1_1 C11_1 C16_1 -16.8(8) . . . . ?
Rh1_1 P1_1 C11_1 C16_1 108.6(6) . . . . ?
C16_1 C11_1 C12_1 C13_1 0.0 . . . . ?
P1_1 C11_1 C12_1 C13_1 177.1(9) . . . . ?
C16_1 C11_1 C12_1 C22_1 -179.4(11) . . . . ?
P1_1 C11_1 C12_1 C22_1 -2.3(11) . . . . ?
C11_1 C12_1 C13_1 C14_1 0.0 . . . . ?
C22_1 C12_1 C13_1 C14_1 179.4(10) . . . . ?
C12_1 C13_1 C14_1 C15_1 0.0 . . . . ?
C12_1 C13_1 C14_1 N31_1 -174.4(14) . . . . ?
C13_1 C14_1 C15_1 C16_1 0.0 . . . . ?
N31_1 C14_1 C15_1 C16_1 174.7(13) . . . . ?
C14_1 C15_1 C16_1 C11_1 0.0 . . . . ?
C12_1 C11_1 C16_1 C15_1 0.0 . . . . ?
P1_1 C11_1 C16_1 C15_1 -177.1(9) . . . . ?
C71_1 P2_1 C21_1 C22_1 46.4(8) . . . . ?
C81_1 P2_1 C21_1 C22_1 156.8(7) . . . . ?
Rh1_1 P2_1 C21_1 C22_1 -76.0(7) . . . . ?
C71_1 P2_1 C21_1 C26_1 -139.7(7) . . . . ?
C81_1 P2_1 C21_1 C26_1 -29.3(8) . . . . ?
Rh1_1 P2_1 C21_1 C26_1 97.8(6) . . . . ?
C26_1 C21_1 C22_1 C23_1 0.0 . . . . ?
P2_1 C21_1 C22_1 C23_1 173.7(9) . . . . ?
C26_1 C21_1 C22_1 C12_1 175.7(11) . . . . ?
P2_1 C21_1 C22_1 C12_1 -10.7(11) . . . . ?
C13_1 C12_1 C22_1 C21_1 -113.3(9) . . . . ?
C11_1 C12_1 C22_1 C21_1 66.1(12) . . . . ?
C13_1 C12_1 C22_1 C23_1 62.5(9) . . . . ?
C11_1 C12_1 C22_1 C23_1 -118.1(8) . . . . ?
C21_1 C22_1 C23_1 C24_1 0.0 . . . . ?
C12_1 C22_1 C23_1 C24_1 -176.1(10) . . . . ?
C22_1 C23_1 C24_1 C25_1 0.0 . . . . ?
C22_1 C23_1 C24_1 N41_1 174.1(12) . . . . ?
C23_1 C24_1 C25_1 C26_1 0.0 . . . . ?
N41_1 C24_1 C25_1 C26_1 -174.5(12) . . . . ?
C24_1 C25_1 C26_1 C21_1 0.0 . . . . ?
C22_1 C21_1 C26_1 C25_1 0.0 . . . . ?
P2_1 C21_1 C26_1 C25_1 -174.0(8) . . . . ?
O30_1 C30_1 N31_1 C14_1 -5(4) . . . . ?
C31_1 C30_1 N31_1 C14_1 171.0(16) . . . . ?
C15_1 C14_1 N31_1 C30_1 -155.0(18) . . . . ?
C13_1 C14_1 N31_1 C30_1 20(3) . . . . ?
O30_1 C30_1 C31_1 C32_1 -148.9(19) . . . . ?
N31_1 C30_1 C31_1 C32_1 35(3) . . . . ?
O30_1 C30_1 C31_1 C36_1 29(3) . . . . ?
N31_1 C30_1 C31_1 C36_1 -147.5(17) . . . . ?
C36_1 C31_1 C32_1 C33_1 0.0 . . . . ?
C30_1 C31_1 C32_1 C33_1 177.9(18) . . . . ?
C31_1 C32_1 C33_1 C34_1 0.0 . . . . ?
C31_1 C32_1 C33_1 Cl1_1 -176.3(16) . . . . ?
C32_1 C33_1 C34_1 C35_1 0.0 . . . . ?
Cl1_1 C33_1 C34_1 C35_1 176.5(15) . . . . ?
C33_1 C34_1 C35_1 C36_1 0.0 . . . . ?
C33_1 C34_1 C35_1 Cl2_1 177.1(19) . . . . ?
C34_1 C35_1 C36_1 C31_1 0.0 . . . . ?
Cl2_1 C35_1 C36_1 C31_1 -177.2(18) . . . . ?
C32_1 C31_1 C36_1 C35_1 0.0 . . . . ?
C30_1 C31_1 C36_1 C35_1 -178.0(18) . . . . ?
O40_1 C40_1 N41_1 C24_1 8(3) . . . . ?
C41_1 C40_1 N41_1 C24_1 -175.9(15) . . . . ?
C25_1 C24_1 N41_1 C40_1 -150.9(15) . . . . ?
C23_1 C24_1 N41_1 C40_1 35(2) . . . . ?
O40_1 C40_1 C41_1 C42_1 -156.2(18) . . . . ?
N41_1 C40_1 C41_1 C42_1 28(2) . . . . ?
O40_1 C40_1 C41_1 C46_1 18(3) . . . . ?
N41_1 C40_1 C41_1 C46_1 -158.6(14) . . . . ?
C46_1 C41_1 C42_1 C43_1 0.0 . . . . ?
C40_1 C41_1 C42_1 C43_1 173.7(17) . . . . ?
C41_1 C42_1 C43_1 C44_1 0.0 . . . . ?
C41_1 C42_1 C43_1 Cl3_1 -180.0(15) . . . . ?
C42_1 C43_1 C44_1 C45_1 0.0 . . . . ?
Cl3_1 C43_1 C44_1 C45_1 180.0(14) . . . . ?
C43_1 C44_1 C45_1 C46_1 0.0 . . . . ?
C43_1 C44_1 C45_1 Cl4_1 178.7(18) . . . . ?
C44_1 C45_1 C46_1 C41_1 0.0 . . . . ?
Cl4_1 C45_1 C46_1 C41_1 -178.6(18) . . . . ?
C42_1 C41_1 C46_1 C45_1 0.0 . . . . ?
C40_1 C41_1 C46_1 C45_1 -174.0(16) . . . . ?
C61_1 P1_1 C51_1 C52_1 124.6(7) . . . . ?
C11_1 P1_1 C51_1 C52_1 -128.0(7) . . . . ?
Rh1_1 P1_1 C51_1 C52_1 4.2(8) . . . . ?
C61_1 P1_1 C51_1 C56_1 -59.0(9) . . . . ?
C11_1 P1_1 C51_1 C56_1 48.3(8) . . . . ?
Rh1_1 P1_1 C51_1 C56_1 -179.4(6) . . . . ?
C56_1 C51_1 C52_1 C53_1 0.0 . . . . ?
P1_1 C51_1 C52_1 C53_1 176.4(9) . . . . ?
C51_1 C52_1 C53_1 C54_1 0.0 . . . . ?
C52_1 C53_1 C54_1 C55_1 0.0 . . . . ?
C53_1 C54_1 C55_1 C56_1 0.0 . . . . ?
C54_1 C55_1 C56_1 C51_1 0.0 . . . . ?
C52_1 C51_1 C56_1 C55_1 0.0 . . . . ?
P1_1 C51_1 C56_1 C55_1 -176.3(10) . . . . ?
C51_1 P1_1 C61_1 C62_1 177.9(6) . . . . ?
C11_1 P1_1 C61_1 C62_1 70.6(7) . . . . ?
Rh1_1 P1_1 C61_1 C62_1 -62.0(7) . . . . ?
C51_1 P1_1 C61_1 C66_1 -4.4(9) . . . . ?
C11_1 P1_1 C61_1 C66_1 -111.6(8) . . . . ?
Rh1_1 P1_1 C61_1 C66_1 115.8(7) . . . . ?
C66_1 C61_1 C62_1 C63_1 0.0 . . . . ?
P1_1 C61_1 C62_1 C63_1 177.9(9) . . . . ?
C61_1 C62_1 C63_1 C64_1 0.0 . . . . ?
C62_1 C63_1 C64_1 C65_1 0.0 . . . . ?
C63_1 C64_1 C65_1 C66_1 0.0 . . . . ?
C64_1 C65_1 C66_1 C61_1 0.0 . . . . ?
C62_1 C61_1 C66_1 C65_1 0.0 . . . . ?
P1_1 C61_1 C66_1 C65_1 -177.7(9) . . . . ?
C21_1 P2_1 C71_1 C72_1 -144.7(8) . . . . ?
C81_1 P2_1 C71_1 C72_1 102.9(9) . . . . ?
Rh1_1 P2_1 C71_1 C72_1 -21.1(9) . . . . ?
C21_1 P2_1 C71_1 C76_1 36.2(10) . . . . ?
C81_1 P2_1 C71_1 C76_1 -76.2(9) . . . . ?
Rh1_1 P2_1 C71_1 C76_1 159.8(7) . . . . ?
C76_1 C71_1 C72_1 C73_1 0.0 . . . . ?
P2_1 C71_1 C72_1 C73_1 -179.1(11) . . . . ?
C71_1 C72_1 C73_1 C74_1 0.0 . . . . ?
C72_1 C73_1 C74_1 C75_1 0.0 . . . . ?
C73_1 C74_1 C75_1 C76_1 0.0 . . . . ?
C74_1 C75_1 C76_1 C71_1 0.0 . . . . ?
C72_1 C71_1 C76_1 C75_1 0.0 . . . . ?
P2_1 C71_1 C76_1 C75_1 179.1(11) . . . . ?
C71_1 P2_1 C81_1 C82_1 -4.6(9) . . . . ?
C21_1 P2_1 C81_1 C82_1 -117.7(7) . . . . ?
Rh1_1 P2_1 C81_1 C82_1 116.6(7) . . . . ?
C71_1 P2_1 C81_1 C86_1 177.1(7) . . . . ?
C21_1 P2_1 C81_1 C86_1 63.9(8) . . . . ?
Rh1_1 P2_1 C81_1 C86_1 -61.8(8) . . . . ?
C86_1 C81_1 C82_1 C83_1 0.0 . . . . ?
P2_1 C81_1 C82_1 C83_1 -178.4(9) . . . . ?
C81_1 C82_1 C83_1 C84_1 0.0 . . . . ?
C82_1 C83_1 C84_1 C85_1 0.0 . . . . ?
C83_1 C84_1 C85_1 C86_1 0.0 . . . . ?
C84_1 C85_1 C86_1 C81_1 0.0 . . . . ?
C82_1 C81_1 C86_1 C85_1 0.0 . . . . ?
P2_1 C81_1 C86_1 C85_1 178.3(9) . . . . ?
C98_1 C91_1 C92_1 C93_1 2(3) . . . . ?
Rh1_1 C91_1 C92_1 C93_1 -99.6(17) . . . . ?
C98_1 C91_1 C92_1 Rh1_1 101.9(14) . . . . ?
C91_1 C92_1 C93_1 C94_1 39(3) . . . . ?
Rh1_1 C92_1 C93_1 C94_1 -44(2) . . . . ?
C92_1 C93_1 C94_1 C95_1 37(2) . . . . ?
C93_1 C94_1 C95_1 C96_1 -94(2) . . . . ?
C93_1 C94_1 C95_1 Rh1_1 -11(2) . . . . ?
C94_1 C95_1 C96_1 C97_1 3(3) . . . . ?
Rh1_1 C95_1 C96_1 C97_1 -99.4(17) . . . . ?
C94_1 C95_1 C96_1 Rh1_1 102.7(16) . . . . ?
C95_1 C96_1 C97_1 C98_1 40(3) . . . . ?
Rh1_1 C96_1 C97_1 C98_1 -42.0(18) . . . . ?
C96_1 C97_1 C98_1 C91_1 35(2) . . . . ?
C92_1 C91_1 C98_1 C97_1 -91(2) . . . . ?
Rh1_1 C91_1 C98_1 C97_1 -9.7(18) . . . . ?
C51_2 P1_2 C11_2 C12_2 54.8(11) . . . . ?
C61_2 P1_2 C11_2 C12_2 165.4(10) . . . . ?
Rh1_2 P1_2 C11_2 C12_2 -70.3(10) . . . . ?
C51_2 P1_2 C11_2 C16_2 -125.5(9) . . . . ?
C61_2 P1_2 C11_2 C16_2 -15.0(11) . . . . ?
Rh1_2 P1_2 C11_2 C16_2 109.4(8) . . . . ?
C16_2 C11_2 C12_2 C13_2 0.0 . . . . ?
P1_2 C11_2 C12_2 C13_2 179.6(12) . . . . ?
C16_2 C11_2 C12_2 C22_2 177.8(14) . . . . ?
P1_2 C11_2 C12_2 C22_2 -2.6(14) . . . . ?
C11_2 C12_2 C13_2 C14_2 0.0 . . . . ?
C22_2 C12_2 C13_2 C14_2 -177.9(13) . . . . ?
C12_2 C13_2 C14_2 C15_2 0.0 . . . . ?
C12_2 C13_2 C14_2 N31_2 -174.3(17) . . . . ?
C13_2 C14_2 C15_2 C16_2 0.0 . . . . ?
N31_2 C14_2 C15_2 C16_2 174.8(16) . . . . ?
C14_2 C15_2 C16_2 C11_2 0.0 . . . . ?
C12_2 C11_2 C16_2 C15_2 0.0 . . . . ?
P1_2 C11_2 C16_2 C15_2 -179.7(12) . . . . ?
C71_2 P2_2 C21_2 C22_2 156.6(10) . . . . ?
C81_2 P2_2 C21_2 C22_2 45.1(12) . . . . ?
Rh1_2 P2_2 C21_2 C22_2 -77.9(10) . . . . ?
C71_2 P2_2 C21_2 C26_2 -27.4(12) . . . . ?
C81_2 P2_2 C21_2 C26_2 -138.9(10) . . . . ?
Rh1_2 P2_2 C21_2 C26_2 98.1(8) . . . . ?
C26_2 C21_2 C22_2 C23_2 0.0 . . . . ?
P2_2 C21_2 C22_2 C23_2 176.0(13) . . . . ?
C26_2 C21_2 C22_2 C12_2 175.0(14) . . . . ?
P2_2 C21_2 C22_2 C12_2 -9.0(14) . . . . ?
C11_2 C12_2 C22_2 C21_2 66.5(15) . . . . ?
C13_2 C12_2 C22_2 C21_2 -115.6(11) . . . . ?
C11_2 C12_2 C22_2 C23_2 -118.3(11) . . . . ?
C13_2 C12_2 C22_2 C23_2 59.6(13) . . . . ?
C21_2 C22_2 C23_2 C24_2 0.0 . . . . ?
C12_2 C22_2 C23_2 C24_2 -175.4(13) . . . . ?
C22_2 C23_2 C24_2 C25_2 0.0 . . . . ?
C22_2 C23_2 C24_2 N41_2 177.4(17) . . . . ?
C23_2 C24_2 C25_2 C26_2 0.0 . . . . ?
N41_2 C24_2 C25_2 C26_2 -177.6(16) . . . . ?
C24_2 C25_2 C26_2 C21_2 0.0 . . . . ?
C22_2 C21_2 C26_2 C25_2 0.0 . . . . ?
P2_2 C21_2 C26_2 C25_2 -176.2(12) . . . . ?
O30_2 C30_2 N31_2 C14_2 -8(4) . . . . ?
C31_2 C30_2 N31_2 C14_2 174.8(17) . . . . ?
C13_2 C14_2 N31_2 C30_2 19(3) . . . . ?
C15_2 C14_2 N31_2 C30_2 -155.6(18) . . . . ?
O30_2 C30_2 C31_2 C32_2 -140.7(18) . . . . ?
N31_2 C30_2 C31_2 C32_2 37(2) . . . . ?
O30_2 C30_2 C31_2 C36_2 42(2) . . . . ?
N31_2 C30_2 C31_2 C36_2 -140.6(16) . . . . ?
C36_2 C31_2 C32_2 C33_2 0.0 . . . . ?
C30_2 C31_2 C32_2 C33_2 -177.5(16) . . . . ?
C31_2 C32_2 C33_2 C34_2 0.0 . . . . ?
C31_2 C32_2 C33_2 Cl1_2 -179.1(13) . . . . ?
C32_2 C33_2 C34_2 C35_2 0.0 . . . . ?
Cl1_2 C33_2 C34_2 C35_2 179.1(12) . . . . ?
C33_2 C34_2 C35_2 C36_2 0.0 . . . . ?
C33_2 C34_2 C35_2 Cl2_2 177.8(13) . . . . ?
C34_2 C35_2 C36_2 C31_2 0.0 . . . . ?
Cl2_2 C35_2 C36_2 C31_2 -177.8(13) . . . . ?
C32_2 C31_2 C36_2 C35_2 0.0 . . . . ?
C30_2 C31_2 C36_2 C35_2 177.7(15) . . . . ?
O40_2 C40_2 N41_2 C24_2 2(4) . . . . ?
C41_2 C40_2 N41_2 C24_2 -173.5(17) . . . . ?
C25_2 C24_2 N41_2 C40_2 -155.5(18) . . . . ?
C23_2 C24_2 N41_2 C40_2 27(3) . . . . ?
O40_2 C40_2 C41_2 C42_2 -150.6(19) . . . . ?
N41_2 C40_2 C41_2 C42_2 25(3) . . . . ?
O40_2 C40_2 C41_2 C46_2 23(3) . . . . ?
N41_2 C40_2 C41_2 C46_2 -161.4(15) . . . . ?
C46_2 C41_2 C42_2 C43_2 0.0 . . . . ?
C40_2 C41_2 C42_2 C43_2 173.1(17) . . . . ?
C41_2 C42_2 C43_2 C44_2 0.0 . . . . ?
C41_2 C42_2 C43_2 Cl3_2 -178.8(12) . . . . ?
C42_2 C43_2 C44_2 C45_2 0.0 . . . . ?
Cl3_2 C43_2 C44_2 C45_2 178.8(12) . . . . ?
C43_2 C44_2 C45_2 C46_2 0.0 . . . . ?
C43_2 C44_2 C45_2 Cl4_2 -178.5(14) . . . . ?
C44_2 C45_2 C46_2 C41_2 0.0 . . . . ?
Cl4_2 C45_2 C46_2 C41_2 178.4(15) . . . . ?
C42_2 C41_2 C46_2 C45_2 0.0 . . . . ?
C40_2 C41_2 C46_2 C45_2 -173.6(16) . . . . ?
C61_2 P1_2 C51_2 C52_2 -59.5(13) . . . . ?
C11_2 P1_2 C51_2 C52_2 48.1(12) . . . . ?
Rh1_2 P1_2 C51_2 C52_2 178.6(9) . . . . ?
C61_2 P1_2 C51_2 C56_2 124.3(12) . . . . ?
C11_2 P1_2 C51_2 C56_2 -128.1(11) . . . . ?
Rh1_2 P1_2 C51_2 C56_2 2.5(13) . . . . ?
C56_2 C51_2 C52_2 C53_2 0.0 . . . . ?
P1_2 C51_2 C52_2 C53_2 -176.2(14) . . . . ?
C51_2 C52_2 C53_2 C54_2 0.0 . . . . ?
C52_2 C53_2 C54_2 C55_2 0.0 . . . . ?
C53_2 C54_2 C55_2 C56_2 0.0 . . . . ?
C54_2 C55_2 C56_2 C51_2 0.0 . . . . ?
C52_2 C51_2 C56_2 C55_2 0.0 . . . . ?
P1_2 C51_2 C56_2 C55_2 176.1(14) . . . . ?
C51_2 P1_2 C61_2 C62_2 178.7(12) . . . . ?
C11_2 P1_2 C61_2 C62_2 71.2(13) . . . . ?
Rh1_2 P1_2 C61_2 C62_2 -59.0(13) . . . . ?
C51_2 P1_2 C61_2 C66_2 -8.4(15) . . . . ?
C11_2 P1_2 C61_2 C66_2 -115.9(13) . . . . ?
Rh1_2 P1_2 C61_2 C66_2 113.9(12) . . . . ?
C66_2 C61_2 C62_2 C63_2 0.0 . . . . ?
P1_2 C61_2 C62_2 C63_2 172.9(15) . . . . ?
C61_2 C62_2 C63_2 C64_2 0.0 . . . . ?
C62_2 C63_2 C64_2 C65_2 0.0 . . . . ?
C63_2 C64_2 C65_2 C66_2 0.0 . . . . ?
C64_2 C65_2 C66_2 C61_2 0.0 . . . . ?
C62_2 C61_2 C66_2 C65_2 0.0 . . . . ?
P1_2 C61_2 C66_2 C65_2 -172.8(15) . . . . ?
C81_2 P2_2 C71_2 C72_2 -8.2(14) . . . . ?
C21_2 P2_2 C71_2 C72_2 -121.0(12) . . . . ?
Rh1_2 P2_2 C71_2 C72_2 115.2(11) . . . . ?
C81_2 P2_2 C71_2 C76_2 173.4(13) . . . . ?
C21_2 P2_2 C71_2 C76_2 60.6(15) . . . . ?
Rh1_2 P2_2 C71_2 C76_2 -63.2(14) . . . . ?
C76_2 C71_2 C72_2 C73_2 0.0 . . . . ?
P2_2 C71_2 C72_2 C73_2 -178.5(15) . . . . ?
C71_2 C72_2 C73_2 C74_2 0.0 . . . . ?
C72_2 C73_2 C74_2 C75_2 0.0 . . . . ?
C73_2 C74_2 C75_2 C76_2 0.0 . . . . ?
C74_2 C75_2 C76_2 C71_2 0.0 . . . . ?
C72_2 C71_2 C76_2 C75_2 0.0 . . . . ?
P2_2 C71_2 C76_2 C75_2 178.3(17) . . . . ?
C71_2 P2_2 C81_2 C82_2 -72.5(14) . . . . ?
C21_2 P2_2 C81_2 C82_2 40.2(14) . . . . ?
Rh1_2 P2_2 C81_2 C82_2 162.7(11) . . . . ?
C71_2 P2_2 C81_2 C86_2 106.9(13) . . . . ?
C21_2 P2_2 C81_2 C86_2 -140.4(12) . . . . ?
Rh1_2 P2_2 C81_2 C86_2 -17.8(14) . . . . ?
C86_2 C81_2 C82_2 C83_2 0.0 . . . . ?
P2_2 C81_2 C82_2 C83_2 179.4(16) . . . . ?
C81_2 C82_2 C83_2 C84_2 0.0 . . . . ?
C82_2 C83_2 C84_2 C85_2 0.0 . . . . ?
C83_2 C84_2 C85_2 C86_2 0.0 . . . . ?
C84_2 C85_2 C86_2 C81_2 0.0 . . . . ?
C82_2 C81_2 C86_2 C85_2 0.0 . . . . ?
P2_2 C81_2 C86_2 C85_2 -179.5(15) . . . . ?
C98_2 C91_2 C92_2 C93_2 8(4) . . . . ?
Rh1_2 C91_2 C92_2 C93_2 103(2) . . . . ?
C98_2 C91_2 C92_2 Rh1_2 -95(3) . . . . ?
C91_2 C92_2 C93_2 C94_2 -83(5) . . . . ?
Rh1_2 C92_2 C93_2 C94_2 2(5) . . . . ?
C92_2 C93_2 C94_2 C95_2 23(6) . . . . ?
C93_2 C94_2 C95_2 C96_2 48(5) . . . . ?
C93_2 C94_2 C95_2 Rh1_2 -36(4) . . . . ?
C94_2 C95_2 C96_2 C97_2 3(4) . . . . ?
Rh1_2 C95_2 C96_2 C97_2 102(2) . . . . ?
C94_2 C95_2 C96_2 Rh1_2 -99(3) . . . . ?
C95_2 C96_2 C97_2 C98_2 -81(4) . . . . ?
Rh1_2 C96_2 C97_2 C98_2 2(4) . . . . ?
C96_2 C97_2 C98_2 C91_2 26(5) . . . . ?
C92_2 C91_2 C98_2 C97_2 42(5) . . . . ?
Rh1_2 C91_2 C98_2 C97_2 -39(4) . . . . ?
C51_3 P1_3 C11_3 C12_3 -47.1(11) . . . . ?
C61_3 P1_3 C11_3 C12_3 -156.2(9) . . . . ?
Rh1_3 P1_3 C11_3 C12_3 76.0(9) . . . . ?
C51_3 P1_3 C11_3 C16_3 140.7(9) . . . . ?
C61_3 P1_3 C11_3 C16_3 31.6(10) . . . . ?
Rh1_3 P1_3 C11_3 C16_3 -96.1(8) . . . . ?
C16_3 C11_3 C12_3 C13_3 0.0 . . . . ?
P1_3 C11_3 C12_3 C13_3 -171.9(12) . . . . ?
C16_3 C11_3 C12_3 C22_3 -179.2(14) . . . . ?
P1_3 C11_3 C12_3 C22_3 8.8(14) . . . . ?
C11_3 C12_3 C13_3 C14_3 0.0 . . . . ?
C22_3 C12_3 C13_3 C14_3 179.3(13) . . . . ?
C12_3 C13_3 C14_3 C15_3 0.0 . . . . ?
C12_3 C13_3 C14_3 N31_3 179.7(18) . . . . ?
C13_3 C14_3 C15_3 C16_3 0.0 . . . . ?
N31_3 C14_3 C15_3 C16_3 -179.7(16) . . . . ?
C14_3 C15_3 C16_3 C11_3 0.0 . . . . ?
C12_3 C11_3 C16_3 C15_3 0.0 . . . . ?
P1_3 C11_3 C16_3 C15_3 172.4(11) . . . . ?
C71_3 P2_3 C21_3 C22_3 -52.5(11) . . . . ?
C81_3 P2_3 C21_3 C22_3 -163.5(9) . . . . ?
Rh1_3 P2_3 C21_3 C22_3 73.1(10) . . . . ?
C71_3 P2_3 C21_3 C26_3 125.1(9) . . . . ?
C81_3 P2_3 C21_3 C26_3 14.2(10) . . . . ?
Rh1_3 P2_3 C21_3 C26_3 -109.3(8) . . . . ?
C26_3 C21_3 C22_3 C23_3 0.0 . . . . ?
P2_3 C21_3 C22_3 C23_3 177.6(11) . . . . ?
C26_3 C21_3 C22_3 C12_3 -175.8(13) . . . . ?
P2_3 C21_3 C22_3 C12_3 1.8(13) . . . . ?
C13_3 C12_3 C22_3 C21_3 114.8(10) . . . . ?
C11_3 C12_3 C22_3 C21_3 -65.9(14) . . . . ?
C13_3 C12_3 C22_3 C23_3 -61.1(12) . . . . ?
C11_3 C12_3 C22_3 C23_3 118.1(11) . . . . ?
C21_3 C22_3 C23_3 C24_3 0.0 . . . . ?
C12_3 C22_3 C23_3 C24_3 176.0(12) . . . . ?
C22_3 C23_3 C24_3 C25_3 0.0 . . . . ?
C22_3 C23_3 C24_3 N41_3 178.6(15) . . . . ?
C23_3 C24_3 C25_3 C26_3 0.0 . . . . ?
N41_3 C24_3 C25_3 C26_3 -178.7(14) . . . . ?
C24_3 C25_3 C26_3 C21_3 0.0 . . . . ?
C22_3 C21_3 C26_3 C25_3 0.0 . . . . ?
P2_3 C21_3 C26_3 C25_3 -177.7(11) . . . . ?
O30_3 C30_3 N31_3 C14_3 4(5) . . . . ?
C31_3 C30_3 N31_3 C14_3 175(2) . . . . ?
C15_3 C14_3 N31_3 C30_3 157(2) . . . . ?
C13_3 C14_3 N31_3 C30_3 -22(3) . . . . ?
O30_3 C30_3 C31_3 C32_3 134(3) . . . . ?
N31_3 C30_3 C31_3 C32_3 -37(3) . . . . ?
O30_3 C30_3 C31_3 C36_3 -37(4) . . . . ?
N31_3 C30_3 C31_3 C36_3 152(2) . . . . ?
C36_3 C31_3 C32_3 C33_3 0.0 . . . . ?
C30_3 C31_3 C32_3 C33_3 -171(2) . . . . ?
C31_3 C32_3 C33_3 C34_3 0.0 . . . . ?
C31_3 C32_3 C33_3 Cl1_3 179.9(19) . . . . ?
C32_3 C33_3 C34_3 C35_3 0.0 . . . . ?
Cl1_3 C33_3 C34_3 C35_3 -179.9(18) . . . . ?
C33_3 C34_3 C35_3 C36_3 0.0 . . . . ?
C33_3 C34_3 C35_3 Cl2_3 175(2) . . . . ?
C34_3 C35_3 C36_3 C31_3 0.0 . . . . ?
Cl2_3 C35_3 C36_3 C31_3 -175(2) . . . . ?
C32_3 C31_3 C36_3 C35_3 0.0 . . . . ?
C30_3 C31_3 C36_3 C35_3 171(2) . . . . ?
O40_3 C40_3 N41_3 C24_3 7(3) . . . . ?
C41_3 C40_3 N41_3 C24_3 -176.2(15) . . . . ?
C23_3 C24_3 N41_3 C40_3 -28(2) . . . . ?
C25_3 C24_3 N41_3 C40_3 151.1(16) . . . . ?
O40_3 C40_3 C41_3 C42_3 158.7(16) . . . . ?
N41_3 C40_3 C41_3 C42_3 -19(2) . . . . ?
O40_3 C40_3 C41_3 C46_3 -23(2) . . . . ?
N41_3 C40_3 C41_3 C46_3 159.7(14) . . . . ?
C46_3 C41_3 C42_3 C43_3 0.0 . . . . ?
C40_3 C41_3 C42_3 C43_3 178.2(15) . . . . ?
C41_3 C42_3 C43_3 C44_3 0.0 . . . . ?
C41_3 C42_3 C43_3 Cl3_3 177.9(11) . . . . ?
C42_3 C43_3 C44_3 C45_3 0.0 . . . . ?
Cl3_3 C43_3 C44_3 C45_3 -177.9(11) . . . . ?
C43_3 C44_3 C45_3 C46_3 0.0 . . . . ?
C43_3 C44_3 C45_3 Cl4_3 -178.1(11) . . . . ?
C44_3 C45_3 C46_3 C41_3 0.0 . . . . ?
Cl4_3 C45_3 C46_3 C41_3 178.1(11) . . . . ?
C42_3 C41_3 C46_3 C45_3 0.0 . . . . ?
C40_3 C41_3 C46_3 C45_3 -178.4(14) . . . . ?
C61_3 P1_3 C51_3 C52_3 69.3(12) . . . . ?
C11_3 P1_3 C51_3 C52_3 -40.7(12) . . . . ?
Rh1_3 P1_3 C51_3 C52_3 -164.0(9) . . . . ?
C61_3 P1_3 C51_3 C56_3 -109.6(11) . . . . ?
C11_3 P1_3 C51_3 C56_3 140.4(10) . . . . ?
Rh1_3 P1_3 C51_3 C56_3 17.1(11) . . . . ?
C56_3 C51_3 C52_3 C53_3 0.0 . . . . ?
P1_3 C51_3 C52_3 C53_3 -178.9(13) . . . . ?
C51_3 C52_3 C53_3 C54_3 0.0 . . . . ?
C52_3 C53_3 C54_3 C55_3 0.0 . . . . ?
C53_3 C54_3 C55_3 C56_3 0.0 . . . . ?
C54_3 C55_3 C56_3 C51_3 0.0 . . . . ?
C52_3 C51_3 C56_3 C55_3 0.0 . . . . ?
P1_3 C51_3 C56_3 C55_3 178.9(13) . . . . ?
C51_3 P1_3 C61_3 C62_3 7.9(12) . . . . ?
C11_3 P1_3 C61_3 C62_3 117.1(11) . . . . ?
Rh1_3 P1_3 C61_3 C62_3 -116.9(9) . . . . ?
C51_3 P1_3 C61_3 C66_3 -175.7(10) . . . . ?
C11_3 P1_3 C61_3 C66_3 -66.6(11) . . . . ?
Rh1_3 P1_3 C61_3 C66_3 59.5(11) . . . . ?
C66_3 C61_3 C62_3 C63_3 0.0 . . . . ?
P1_3 C61_3 C62_3 C63_3 176.4(13) . . . . ?
C61_3 C62_3 C63_3 C64_3 0.0 . . . . ?
C62_3 C63_3 C64_3 C65_3 0.0 . . . . ?
C63_3 C64_3 C65_3 C66_3 0.0 . . . . ?
C64_3 C65_3 C66_3 C61_3 0.0 . . . . ?
C62_3 C61_3 C66_3 C65_3 0.0 . . . . ?
P1_3 C61_3 C66_3 C65_3 -176.3(14) . . . . ?
C81_3 P2_3 C71_3 C72_3 65.1(12) . . . . ?
C21_3 P2_3 C71_3 C72_3 -44.2(11) . . . . ?
Rh1_3 P2_3 C71_3 C72_3 -174.7(9) . . . . ?
C81_3 P2_3 C71_3 C76_3 -120.3(12) . . . . ?
C21_3 P2_3 C71_3 C76_3 130.4(11) . . . . ?
Rh1_3 P2_3 C71_3 C76_3 -0.1(13) . . . . ?
C76_3 C71_3 C72_3 C73_3 0.0 . . . . ?
P2_3 C71_3 C72_3 C73_3 174.7(14) . . . . ?
C71_3 C72_3 C73_3 C74_3 0.0 . . . . ?
C72_3 C73_3 C74_3 C75_3 0.0 . . . . ?
C73_3 C74_3 C75_3 C76_3 0.0 . . . . ?
C74_3 C75_3 C76_3 C71_3 0.0 . . . . ?
C72_3 C71_3 C76_3 C75_3 0.0 . . . . ?
P2_3 C71_3 C76_3 C75_3 -174.5(14) . . . . ?
C71_3 P2_3 C81_3 C82_3 -178.0(11) . . . . ?
C21_3 P2_3 C81_3 C82_3 -67.5(12) . . . . ?
Rh1_3 P2_3 C81_3 C82_3 61.5(12) . . . . ?
C71_3 P2_3 C81_3 C86_3 1.4(14) . . . . ?
C21_3 P2_3 C81_3 C86_3 111.9(13) . . . . ?
Rh1_3 P2_3 C81_3 C86_3 -119.1(11) . . . . ?
C86_3 C81_3 C82_3 C83_3 0.0 . . . . ?
P2_3 C81_3 C82_3 C83_3 179.4(14) . . . . ?
C81_3 C82_3 C83_3 C84_3 0.0 . . . . ?
C82_3 C83_3 C84_3 C85_3 0.0 . . . . ?
C83_3 C84_3 C85_3 C86_3 0.0 . . . . ?
C84_3 C85_3 C86_3 C81_3 0.0 . . . . ?
C82_3 C81_3 C86_3 C85_3 0.0 . . . . ?
P2_3 C81_3 C86_3 C85_3 -179.4(15) . . . . ?
C98_3 C91_3 C92_3 C93_3 -2(3) . . . . ?
Rh1_3 C91_3 C92_3 C93_3 99(2) . . . . ?
C98_3 C91_3 C92_3 Rh1_3 -101.1(18) . . . . ?
C91_3 C92_3 C93_3 C94_3 -39(4) . . . . ?
Rh1_3 C92_3 C93_3 C94_3 44(3) . . . . ?
C92_3 C93_3 C94_3 C95_3 -35(4) . . . . ?
C93_3 C94_3 C95_3 C96_3 91(3) . . . . ?
C93_3 C94_3 C95_3 Rh1_3 8(3) . . . . ?
C94_3 C95_3 C96_3 C97_3 -4(4) . . . . ?
Rh1_3 C95_3 C96_3 C97_3 99(2) . . . . ?
C94_3 C95_3 C96_3 Rh1_3 -102(2) . . . . ?
C95_3 C96_3 C97_3 C98_3 -37(4) . . . . ?
Rh1_3 C96_3 C97_3 C98_3 45(3) . . . . ?
C96_3 C97_3 C98_3 C91_3 -37(4) . . . . ?
C92_3 C91_3 C98_3 C97_3 90(3) . . . . ?
Rh1_3 C91_3 C98_3 C97_3 9(3) . . . . ?
C51_4 P1_4 C11_4 C12_4 -55.8(8) . . . . ?
C61_4 P1_4 C11_4 C12_4 -165.3(7) . . . . ?
Rh1_4 P1_4 C11_4 C12_4 69.4(8) . . . . ?
C51_4 P1_4 C11_4 C16_4 126.8(7) . . . . ?
C61_4 P1_4 C11_4 C16_4 17.4(8) . . . . ?
Rh1_4 P1_4 C11_4 C16_4 -107.9(6) . . . . ?
C16_4 C11_4 C12_4 C13_4 0.0 . . . . ?
P1_4 C11_4 C12_4 C13_4 -177.3(9) . . . . ?
C16_4 C11_4 C12_4 C22_4 -178.1(11) . . . . ?
P1_4 C11_4 C12_4 C22_4 4.5(11) . . . . ?
C11_4 C12_4 C13_4 C14_4 0.0 . . . . ?
C22_4 C12_4 C13_4 C14_4 178.3(10) . . . . ?
C12_4 C13_4 C14_4 C15_4 0.0 . . . . ?
C12_4 C13_4 C14_4 N31_4 178.6(13) . . . . ?
C13_4 C14_4 C15_4 C16_4 0.0 . . . . ?
N31_4 C14_4 C15_4 C16_4 -178.8(12) . . . . ?
C14_4 C15_4 C16_4 C11_4 0.0 . . . . ?
C12_4 C11_4 C16_4 C15_4 0.0 . . . . ?
P1_4 C11_4 C16_4 C15_4 177.4(9) . . . . ?
C71_4 P2_4 C21_4 C22_4 -47.0(8) . . . . ?
C81_4 P2_4 C21_4 C22_4 -155.0(7) . . . . ?
Rh1_4 P2_4 C21_4 C22_4 77.7(7) . . . . ?
C71_4 P2_4 C21_4 C26_4 140.2(7) . . . . ?
C81_4 P2_4 C21_4 C26_4 32.2(8) . . . . ?
Rh1_4 P2_4 C21_4 C26_4 -95.1(6) . . . . ?
C26_4 C21_4 C22_4 C23_4 0.0 . . . . ?
P2_4 C21_4 C22_4 C23_4 -172.6(9) . . . . ?
C26_4 C21_4 C22_4 C12_4 179.3(11) . . . . ?
P2_4 C21_4 C22_4 C12_4 6.6(11) . . . . ?
C11_4 C12_4 C22_4 C21_4 -65.6(12) . . . . ?
C13_4 C12_4 C22_4 C21_4 116.2(9) . . . . ?
C11_4 C12_4 C22_4 C23_4 113.7(9) . . . . ?
C13_4 C12_4 C22_4 C23_4 -64.5(9) . . . . ?
C21_4 C22_4 C23_4 C24_4 0.0 . . . . ?
C12_4 C22_4 C23_4 C24_4 -179.3(10) . . . . ?
C22_4 C23_4 C24_4 C25_4 0.0 . . . . ?
C22_4 C23_4 C24_4 N41_4 -176.9(13) . . . . ?
C23_4 C24_4 C25_4 C26_4 0.0 . . . . ?
N41_4 C24_4 C25_4 C26_4 177.2(12) . . . . ?
C24_4 C25_4 C26_4 C21_4 0.0 . . . . ?
C22_4 C21_4 C26_4 C25_4 0.0 . . . . ?
P2_4 C21_4 C26_4 C25_4 172.9(8) . . . . ?
O30_4 C30_4 N31_4 C14_4 4(4) . . . . ?
C31_4 C30_4 N31_4 C14_4 -176.0(15) . . . . ?
C15_4 C14_4 N31_4 C30_4 157.6(17) . . . . ?
C13_4 C14_4 N31_4 C30_4 -21(2) . . . . ?
O30_4 C30_4 C31_4 C32_4 148.7(19) . . . . ?
N31_4 C30_4 C31_4 C32_4 -32(3) . . . . ?
O30_4 C30_4 C31_4 C36_4 -30(3) . . . . ?
N31_4 C30_4 C31_4 C36_4 149.8(16) . . . . ?
C36_4 C31_4 C32_4 C33_4 0.0 . . . . ?
C30_4 C31_4 C32_4 C33_4 -178.7(17) . . . . ?
C31_4 C32_4 C33_4 C34_4 0.0 . . . . ?
C31_4 C32_4 C33_4 Cl1_4 175.4(13) . . . . ?
C32_4 C33_4 C34_4 C35_4 0.0 . . . . ?
Cl1_4 C33_4 C34_4 C35_4 -175.6(13) . . . . ?
C33_4 C34_4 C35_4 C36_4 0.0 . . . . ?
C33_4 C34_4 C35_4 Cl2_4 -178.5(16) . . . . ?
C34_4 C35_4 C36_4 C31_4 0.0 . . . . ?
Cl2_4 C35_4 C36_4 C31_4 178.5(16) . . . . ?
C32_4 C31_4 C36_4 C35_4 0.0 . . . . ?
C30_4 C31_4 C36_4 C35_4 178.7(16) . . . . ?
O40_4 C40_4 N41_4 C24_4 1(3) . . . . ?
C41_4 C40_4 N41_4 C24_4 175.7(14) . . . . ?
C23_4 C24_4 N41_4 C40_4 -20(2) . . . . ?
C25_4 C24_4 N41_4 C40_4 162.8(15) . . . . ?
O40_4 C40_4 C41_4 C42_4 145.9(16) . . . . ?
N41_4 C40_4 C41_4 C42_4 -29(2) . . . . ?
O40_4 C40_4 C41_4 C46_4 -29(2) . . . . ?
N41_4 C40_4 C41_4 C46_4 155.6(13) . . . . ?
C46_4 C41_4 C42_4 C43_4 0.0 . . . . ?
C40_4 C41_4 C42_4 C43_4 -174.9(15) . . . . ?
C41_4 C42_4 C43_4 C44_4 0.0 . . . . ?
C41_4 C42_4 C43_4 Cl3_4 173.5(12) . . . . ?
C42_4 C43_4 C44_4 C45_4 0.0 . . . . ?
Cl3_4 C43_4 C44_4 C45_4 -173.5(11) . . . . ?
C43_4 C44_4 C45_4 C46_4 0.0 . . . . ?
C43_4 C44_4 C45_4 Cl4_4 179.4(12) . . . . ?
C44_4 C45_4 C46_4 C41_4 0.0 . . . . ?
Cl4_4 C45_4 C46_4 C41_4 -179.3(13) . . . . ?
C42_4 C41_4 C46_4 C45_4 0.0 . . . . ?
C40_4 C41_4 C46_4 C45_4 175.2(14) . . . . ?
C61_4 P1_4 C51_4 C52_4 63.6(9) . . . . ?
C11_4 P1_4 C51_4 C52_4 -43.2(8) . . . . ?
Rh1_4 P1_4 C51_4 C52_4 -173.4(6) . . . . ?
C61_4 P1_4 C51_4 C56_4 -117.9(8) . . . . ?
C11_4 P1_4 C51_4 C56_4 135.3(8) . . . . ?
Rh1_4 P1_4 C51_4 C56_4 5.1(9) . . . . ?
C56_4 C51_4 C52_4 C53_4 0.0 . . . . ?
P1_4 C51_4 C52_4 C53_4 178.5(10) . . . . ?
C51_4 C52_4 C53_4 C54_4 0.0 . . . . ?
C52_4 C53_4 C54_4 C55_4 0.0 . . . . ?
C53_4 C54_4 C55_4 C56_4 0.0 . . . . ?
C54_4 C55_4 C56_4 C51_4 0.0 . . . . ?
C52_4 C51_4 C56_4 C55_4 0.0 . . . . ?
P1_4 C51_4 C56_4 C55_4 -178.5(10) . . . . ?
C51_4 P1_4 C61_4 C62_4 -179.4(7) . . . . ?
C11_4 P1_4 C61_4 C62_4 -73.8(8) . . . . ?
Rh1_4 P1_4 C61_4 C62_4 56.9(7) . . . . ?
C51_4 P1_4 C61_4 C66_4 7.0(9) . . . . ?
C11_4 P1_4 C61_4 C66_4 112.6(8) . . . . ?
Rh1_4 P1_4 C61_4 C66_4 -116.6(7) . . . . ?
C66_4 C61_4 C62_4 C63_4 0.0 . . . . ?
P1_4 C61_4 C62_4 C63_4 -173.6(9) . . . . ?
C61_4 C62_4 C63_4 C64_4 0.0 . . . . ?
C62_4 C63_4 C64_4 C65_4 0.0 . . . . ?
C63_4 C64_4 C65_4 C66_4 0.0 . . . . ?
C64_4 C65_4 C66_4 C61_4 0.0 . . . . ?
C62_4 C61_4 C66_4 C65_4 0.0 . . . . ?
P1_4 C61_4 C66_4 C65_4 173.5(9) . . . . ?
C81_4 P2_4 C71_4 C72_4 69.2(9) . . . . ?
C21_4 P2_4 C71_4 C72_4 -42.1(9) . . . . ?
Rh1_4 P2_4 C71_4 C72_4 -166.9(6) . . . . ?
C81_4 P2_4 C71_4 C76_4 -111.6(8) . . . . ?
C21_4 P2_4 C71_4 C76_4 137.0(8) . . . . ?
Rh1_4 P2_4 C71_4 C76_4 12.2(9) . . . . ?
C76_4 C71_4 C72_4 C73_4 0.0 . . . . ?
P2_4 C71_4 C72_4 C73_4 179.1(10) . . . . ?
C71_4 C72_4 C73_4 C74_4 0.0 . . . . ?
C72_4 C73_4 C74_4 C75_4 0.0 . . . . ?
C73_4 C74_4 C75_4 C76_4 0.0 . . . . ?
C74_4 C75_4 C76_4 C71_4 0.0 . . . . ?
C72_4 C71_4 C76_4 C75_4 0.0 . . . . ?
P2_4 C71_4 C76_4 C75_4 -179.1(10) . . . . ?
C71_4 P2_4 C81_4 C82_4 -170.5(7) . . . . ?
C21_4 P2_4 C81_4 C82_4 -59.6(8) . . . . ?
Rh1_4 P2_4 C81_4 C82_4 66.8(7) . . . . ?
C71_4 P2_4 C81_4 C86_4 9.6(8) . . . . ?
C21_4 P2_4 C81_4 C86_4 120.5(7) . . . . ?
Rh1_4 P2_4 C81_4 C86_4 -113.2(7) . . . . ?
C86_4 C81_4 C82_4 C83_4 0.0 . . . . ?
P2_4 C81_4 C82_4 C83_4 -179.9(9) . . . . ?
C81_4 C82_4 C83_4 C84_4 0.0 . . . . ?
C82_4 C83_4 C84_4 C85_4 0.0 . . . . ?
C83_4 C84_4 C85_4 C86_4 0.0 . . . . ?
C84_4 C85_4 C86_4 C81_4 0.0 . . . . ?
C82_4 C81_4 C86_4 C85_4 0.0 . . . . ?
P2_4 C81_4 C86_4 C85_4 179.9(9) . . . . ?
C98_4 C91_4 C92_4 C93_4 -3(3) . . . . ?
Rh1_4 C91_4 C92_4 C93_4 98.7(18) . . . . ?
C98_4 C91_4 C92_4 Rh1_4 -101.3(15) . . . . ?
C91_4 C92_4 C93_4 C94_4 -37(3) . . . . ?
Rh1_4 C92_4 C93_4 C94_4 47(2) . . . . ?
C92_4 C93_4 C94_4 C95_4 -39(3) . . . . ?
C93_4 C94_4 C95_4 C96_4 93(2) . . . . ?
C93_4 C94_4 C95_4 Rh1_4 11(2) . . . . ?
C94_4 C95_4 C96_4 C97_4 -2(3) . . . . ?
Rh1_4 C95_4 C96_4 C97_4 100.2(18) . . . . ?
C94_4 C95_4 C96_4 Rh1_4 -102.4(17) . . . . ?
C95_4 C96_4 C97_4 C98_4 -37(3) . . . . ?
Rh1_4 C96_4 C97_4 C98_4 46.0(19) . . . . ?
C96_4 C97_4 C98_4 C91_4 -39(2) . . . . ?
C92_4 C91_4 C98_4 C97_4 92(2) . . . . ?
Rh1_4 C91_4 C98_4 C97_4 11.2(19) . . . . ?

_refine_diff_density_max         3.141
_refine_diff_density_min         -3.396
_refine_diff_density_rms         0.211


# start Validation Reply Form
_vrf_THETM01_gos18               
;
PROBLEM: The value of sine(theta_max)/wavelength is less than 0.550
RESPONSE: We have cut the dataset at a resolution of 1.00  due to 
I/sigma and R(int) criteria. Despite of using a high intensity source 
and elongated irradiation times this was the best achievable resolution. 
To compensate at least partially for the lack of information we used 
local symmetry restraints among the independent molecules (SHELX SAME 
command), rigid body constraints for the phenyl rings and isotropic 
refinement for all the light atoms including carbon. Furthermore we 
used rigid bond restraints for all atoms (SHELX RIGU command). 
We are of course aware, that we cannot take more serious information from 
the experiment than the constitution and configuration of the molecule. 
;
_vrf_PLAT201_gos18               
;
PROBLEM: Isotropic non-H Atoms in Main Residue(s) ....... 248 Report
RESPONSE: This is a very problematic structure and some of the problems 
origin in the huge lattice constants a and especially c. This lead to 
overlaps in the diffraction pattern and severe difficulties in integration 
of the affected reflections. As a result the dataset is of very low quality.
A refinement of anisotropic displacement parameters for the light atoms is 
not reasonable. 
We are of course aware, that we cannot take more serious information from 
the experiment than the constitution and configuration of the molecule. 
;
_vrf_PLAT213_gos18               
;
PROBLEM: Atom Rh1_1 has ADP max/min Ratio ..... 7.5 oblate
RESPONSE: This is a very problematic structure and some of the problems 
origin in the huge lattice constants a and especially c. This leads to 
overlaps in the diffraction pattern and severe difficulties in integration 
of the affected reflections. As a result the dataset is of very low quality.
Most atoms were treated isotropic, but for the heaviest atoms we risked an 
very restricted anisotropic refinement. Most of the obtained results seem 
reasonable, but we can not trust reliably on the results and so also don't 
worry about the poor ones. 
We are of course aware that we cannot take more serious information from 
the experiment than the constitution and configuration of the molecule. 
;
# end Validation Reply Form

#==================================================================



