# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_p
_database_code_depnum_ccdc_archive 'CCDC 1416081'
_audit_update_record             
;
2015-07-31 deposited with the CCDC.
2015-09-30 downloaded from the CCDC.
;
_audit_creation_date             2015-07-31
_audit_creation_method           
;
Olex2 1.2
(compiled 2015.01.26 svn.r3150 for OlexSys, GUI svn.r4998)
;
_chemical_name_common            ?
_chemical_name_systematic        Eu-bpydc
_chemical_formula_moiety         'C36 Eu2 N6 O15, 2(O1)'
_chemical_formula_sum            'C36 Eu2 N6 O17'
_chemical_formula_weight         1092.34
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   26.238(2)
_cell_length_b                   14.1876(15)
_cell_length_c                   16.8586(11)
_cell_angle_alpha                90
_cell_angle_beta                 98.014(7)
_cell_angle_gamma                90
_cell_volume                     6214.3(9)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    ?
_cell_measurement_temperature    100
_cell_measurement_theta_max      ?
_cell_measurement_theta_min      ?
_shelx_estimated_absorpt_T_max   0.821
_shelx_estimated_absorpt_T_min   0.494
_exptl_absorpt_coefficient_mu    2.052
_exptl_absorpt_correction_T_max  0.8210
_exptl_absorpt_correction_T_min  0.4939
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.168
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       needle
_exptl_crystal_F_000             2080
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0843
_diffrn_reflns_av_unetI/netI     0.1336
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -31
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            25407
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        25.000
_diffrn_reflns_theta_max         25.000
_diffrn_reflns_theta_min         3.398
_diffrn_ambient_temperature      100
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Agilent micro-focus'
_diffrn_measurement_method       ?
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                6271
_reflns_number_total             10883
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2008)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         1.708
_refine_diff_density_min         -1.436
_refine_diff_density_rms         0.207
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.060
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     550
_refine_ls_number_reflns         10883
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1507
_refine_ls_R_factor_gt           0.0870
_refine_ls_restrained_S_all      1.060
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1161P)²+51.3532P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2294
_refine_ls_wR_factor_ref         0.2762
_refine_special_details          ?
_olex2_refinement_description    
;
1. Others
 Sof(C5B)=1-FVAR(1)
 Sof(C5A)=FVAR(1)
 Sof(C6B)=1-FVAR(2)
 Sof(C6A)=FVAR(2)
 Sof(C17B)=1-FVAR(3)
 Sof(C17A)=FVAR(3)
 Sof(C18B)=1-FVAR(4)
 Sof(C18A)=FVAR(4)
 Sof(C22B)=1-FVAR(5)
 Sof(C22A)=FVAR(5)
 Sof(C23B)=1-FVAR(6)
 Sof(C23A)=FVAR(6)
 Sof(C34B)=1-FVAR(7)
 Sof(C34A)=FVAR(7)
 Sof(C35B)=1-FVAR(8)
 Sof(C35A)=FVAR(8)
 Sof(C36B)=1-FVAR(9)
 Sof(C36A)=FVAR(9)
 Sof(N1B)=1-FVAR(10)
 Sof(N1A)=FVAR(10)
 Sof(N2B)=1-FVAR(11)
 Sof(N2A)=FVAR(11)
 Sof(N6B)=1-FVAR(12)
 Sof(N6A)=FVAR(12)
 Sof(C33B)=1-FVAR(13)
 Sof(C33A)=FVAR(13)
 Sof(C8B)=1-FVAR(14)
 Sof(C8A)=FVAR(14)
 Sof(C3B)=1-FVAR(15)
 Sof(C3A)=FVAR(15)
 Sof(O10B)=1-FVAR(16)
 Sof(O10A)=FVAR(16)
 Sof(C32B)=1-FVAR(17)
 Sof(C32A)=FVAR(17)
 Sof(O10)=1-FVAR(18)
 Sof(O13)=FVAR(18)
 Sof(O16B)=1-FVAR(19)
 Sof(O16A)=FVAR(19)
;
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.3389(6) 0.3839(11) 0.1924(8) 0.042(3) Uani 1 1 d . . . . .
C2 C 0.3932(6) 0.4131(13) 0.1814(8) 0.054(4) Uani 1 1 d . . . . .
C3B C 0.4131(13) 0.381(4) 0.118(2) 0.046(11) Uiso 0.59(11) 1 d . . P A 2
C4 C 0.4892(6) 0.4734(14) 0.1656(8) 0.060(5) Uani 1 1 d . . . . .
C5B C 0.4785(13) 0.459(3) 0.2338(15) 0.030(11) Uiso 0.46(6) 1 d . . P A 2
C6B C 0.4325(18) 0.428(4) 0.241(2) 0.053(16) Uiso 0.42(8) 1 d . . P A 2
C7 C 0.4603(6) 0.0169(15) 0.3431(9) 0.065(5) Uani 1 1 d . . . . .
C8B C 0.4344(10) -0.030(3) 0.3959(17) 0.014(11) Uiso 0.45(9) 1 d . . P B 2
C9 C 0.3932(6) 0.0291(15) 0.4155(10) 0.072(6) Uani 1 1 d . . . . .
C10 C 0.3695(6) 0.0980(13) 0.3667(7) 0.053(4) Uani 1 1 d . . . . .
C11 C 0.3939(7) 0.1274(17) 0.3035(9) 0.081(7) Uani 1 1 d . . . . .
C12 C 0.3211(6) 0.1473(11) 0.3846(8) 0.048(4) Uani 1 1 d . . . . .
C13 C 0.1709(6) 0.1865(10) 0.3421(8) 0.041(4) Uani 1 1 d . . . . .
C14 C 0.1239(6) 0.1299(13) 0.3401(8) 0.056(4) Uani 1 1 d . . . . .
C15 C 0.1145(6) 0.0789(13) 0.4082(8) 0.057(4) Uani 1 1 d . . . . .
C16 C 0.0347(6) 0.0285(15) 0.3362(8) 0.068(5) Uani 1 1 d . . . . .
C17B C 0.0522(12) 0.045(3) 0.2664(14) 0.026(11) Uiso 0.46(7) 1 d . . P C 2
C18B C 0.0932(13) 0.103(3) 0.2696(16) 0.052(11) Uiso 0.60(9) 1 d . . P C 2
C19 C 0.0152(6) 0.0176(14) 0.6627(8) 0.065(5) Uani 1 1 d . . . . .
C20 C 0.0699(6) 0.1133(13) 0.5974(9) 0.057(4) Uani 1 1 d . . . . .
C21 C 0.1100(6) 0.0956(11) 0.6555(8) 0.048(4) Uani 1 1 d . . . . .
C22B C 0.1055(17) 0.016(4) 0.716(2) 0.051(14) Uiso 0.48(10) 1 d . . P D 2
C23B C 0.0573(12) -0.020(3) 0.7166(16) 0.019(12) Uiso 0.41(7) 1 d . . P D 2
C24 C 0.1639(5) 0.1254(11) 0.6481(7) 0.042(3) Uani 1 1 d . . . . .
C25 C 0.1742(6) 0.3876(11) 0.4578(9) 0.045(4) Uani 1 1 d . . . . .
C26 C 0.1231(6) 0.4220(12) 0.4742(8) 0.050(4) Uani 1 1 d . . . . .
C27 C 0.0999(6) 0.3855(13) 0.5363(9) 0.055(4) Uani 1 1 d . . . . .
C28 C 0.0262(6) 0.4824(12) 0.4964(8) 0.053(4) Uani 1 1 d . . . . .
C29 C 0.0491(6) 0.5210(12) 0.4363(8) 0.052(4) Uani 1 1 d . . . . .
C30 C 0.0961(7) 0.4888(13) 0.4267(9) 0.069(5) Uani 1 1 d . . . . .
C31 C 0.3317(6) 0.3415(14) 0.5025(9) 0.061(5) Uani 1 1 d . . . . .
C32B C 0.3854(9) 0.375(3) 0.5069(12) 0.042(8) Uiso 0.69(8) 1 d . . P E 2
C33B C 0.4010(15) 0.416(4) 0.4358(17) 0.045(13) Uiso 0.52(9) 1 d . . P E 2
C34B C 0.4780(11) 0.462(3) 0.5032(14) 0.046(10) Uiso 0.62(8) 1 d . . P E 2
C35B C 0.4687(10) 0.418(2) 0.5701(12) 0.028(9) Uiso 0.56(7) 1 d . . P E 2
C36B C 0.4202(10) 0.378(3) 0.5760(13) 0.052(9) Uiso 0.75(9) 1 d . . P E 2
O1 O 0.3070(4) 0.1211(10) 0.6309(6) 0.067(3) Uani 1 1 d . . . . .
O2 O 0.3274(4) 0.3753(9) 0.2604(5) 0.064(3) Uani 1 1 d . . . . .
O3 O 0.2489(4) 0.2822(9) 0.6725(5) 0.061(3) Uani 1 1 d . . . . .
O4 O 0.2964(4) 0.1939(8) 0.3284(6) 0.052(3) Uani 1 1 d . . . . .
O5 O 0.3008(4) 0.3428(8) 0.4407(6) 0.056(3) Uani 1 1 d . . . . .
O6 O 0.1788(3) 0.2278(7) 0.2788(5) 0.040(2) Uani 1 1 d . . . . .
O7 O 0.1865(4) 0.4003(7) 0.3892(5) 0.046(2) Uani 1 1 d . . . . .
O8 O 0.1988(3) 0.3984(6) 0.2025(5) 0.038(2) Uani 1 1 d . . . . .
O9 O 0.2635(5) 0.5049(9) 0.3271(7) 0.085(4) Uani 1 1 d . . . . .
O10B O 0.3086(7) 0.122(3) 0.4518(10) 0.020(9) Uiso 0.49(10) 1 d . . P F 2
O11 O 0.2289(5) 0.0347(9) 0.5230(6) 0.071(3) Uani 1 1 d . . . . .
O12 O 0.1691(4) 0.1736(7) 0.5873(5) 0.046(2) Uani 1 1 d . . . . .
O0AA O 0.2021(4) 0.3461(7) 0.5162(5) 0.044(2) Uani 1 1 d . . . . .
O14 O 0.2015(3) 0.1981(7) 0.4068(5) 0.045(2) Uani 1 1 d . . . . .
O10 O 0.2949(13) 0.458(2) 0.6805(17) 0.054(13) Uiso 0.34(3) 1 d . . P G 2
O16B O 0.342(2) 0.627(4) 0.282(3) 0.20(3) Uiso 0.56(5) 1 d . . P H 2
O17 O 0.3226(4) 0.3015(10) 0.5655(6) 0.069(4) Uani 1 1 d . . . . .
N1B N 0.4636(15) 0.407(5) 0.110(2) 0.055(15) Uiso 0.46(12) 1 d . . P A 2
N2B N 0.4341(18) 0.055(5) 0.286(2) 0.069(17) Uiso 0.44(11) 1 d . . P B 2
N3 N 0.0697(6) 0.0278(13) 0.4052(8) 0.080(5) Uani 1 1 d . . . . .
N4 N 0.0219(5) 0.0742(11) 0.6005(8) 0.066(4) Uani 1 1 d . . . . .
N5 N 0.0513(6) 0.4158(13) 0.5494(8) 0.081(5) Uani 1 1 d . . . . .
N6B N 0.4471(14) 0.440(3) 0.4329(18) 0.030(15) Uiso 0.32(6) 1 d . . P E 2
Eu1 Eu 0.25030(3) 0.33684(6) 0.31352(4) 0.0447(3) Uani 1 1 d . . . . .
Eu2 Eu 0.24931(3) 0.20146(6) 0.53679(4) 0.0455(3) Uani 1 1 d . . . . .
C5A C 0.4665(9) 0.508(2) 0.2322(11) 0.021(9) Uiso 0.54(6) 1 d . . P A 1
C6A C 0.4198(12) 0.477(3) 0.2393(14) 0.041(11) Uiso 0.58(8) 1 d . . P A 1
C17A C 0.0400(10) 0.090(2) 0.2728(13) 0.027(9) Uiso 0.54(7) 1 d . . P C 1
C18A C 0.0836(15) 0.148(4) 0.2739(19) 0.033(15) Uiso 0.40(9) 1 d . . P C 1
C22A C 0.0958(13) 0.058(4) 0.7254(17) 0.039(13) Uiso 0.52(10) 1 d . . P D 1
C23A C 0.0471(11) 0.024(3) 0.7288(15) 0.042(10) Uiso 0.59(7) 1 d . . P D 1
C34A C 0.4665(16) 0.509(4) 0.5038(19) 0.030(16) Uiso 0.38(8) 1 d . . P E 1
C35A C 0.4573(16) 0.471(4) 0.573(2) 0.052(14) Uiso 0.44(7) 1 d . . P E 1
C36A C 0.412(2) 0.425(6) 0.570(3) 0.03(2) Uiso 0.25(9) 1 d . . P E 1
N1A N 0.4577(13) 0.448(4) 0.096(2) 0.061(13) Uiso 0.54(12) 1 d . . P A 1
N2A N 0.4423(12) 0.101(4) 0.2933(15) 0.057(13) Uiso 0.56(11) 1 d . . P B 1
N6A N 0.4356(9) 0.493(2) 0.4368(11) 0.054(8) Uiso 0.68(6) 1 d . . P E 1
C33A C 0.3880(14) 0.458(3) 0.4393(16) 0.035(13) Uiso 0.48(9) 1 d . . P E 1
C8A C 0.4407(11) 0.007(4) 0.4123(19) 0.034(10) Uiso 0.55(9) 1 d . . P B 1
C3A C 0.4058(15) 0.418(4) 0.100(2) 0.029(15) Uiso 0.41(11) 1 d . . P A 1
O10A O 0.3117(9) 0.158(4) 0.4562(12) 0.039(8) Uiso 0.51(10) 1 d . . P F 1
C32A C 0.3779(15) 0.421(4) 0.503(2) 0.018(16) Uiso 0.31(8) 1 d . . P E 1
O13 O 0.330(3) 0.563(5) 0.645(4) 0.36(4) Uiso 0.66(3) 1 d . . P G 1
O16A O 0.397(3) 0.714(5) 0.305(4) 0.25(4) Uiso 0.44(5) 1 d . . P H 1


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.52(2) . ?
C1 O1 1.240(16) 4_565 ?
C1 O2 1.231(15) . ?
C2 C3B 1.33(3) . ?
C2 C6B 1.36(4) . ?
C2 C6A 1.44(3) . ?
C2 C3A 1.46(4) . ?
C3B N1B 1.40(4) . ?
C4 C5B 1.24(3) . ?
C4 C7 1.49(2) 2_655 ?
C4 N1B 1.43(4) . ?
C4 C5A 1.43(3) . ?
C4 N1A 1.38(3) . ?
C5B C6B 1.31(5) . ?
C7 C4 1.49(2) 2_645 ?
C7 C8B 1.37(3) . ?
C7 N2B 1.23(4) . ?
C7 N2A 1.49(4) . ?
C7 C8A 1.35(3) . ?
C8B C9 1.45(4) . ?
C9 C10 1.37(2) . ?
C9 C8A 1.30(3) . ?
C10 C11 1.38(2) . ?
C10 C12 1.52(2) . ?
C11 N2B 1.53(5) . ?
C11 N2A 1.36(3) . ?
C12 O4 1.258(17) . ?
C12 O10B 1.28(2) . ?
C12 O10A 1.27(3) . ?
C13 C14 1.467(19) . ?
C13 O6 1.260(15) . ?
C13 O14 1.271(16) . ?
C13 Eu1 3.066(13) . ?
C14 C15 1.41(2) . ?
C14 C18B 1.39(3) . ?
C14 C18A 1.45(4) . ?
C15 N3 1.37(2) . ?
C16 C17B 1.34(3) . ?
C16 C19 1.47(2) 3_556 ?
C16 N3 1.38(2) . ?
C16 C17A 1.40(3) . ?
C17B C18B 1.35(4) . ?
C19 C16 1.47(2) 3_556 ?
C19 C23B 1.43(4) . ?
C19 N4 1.35(2) . ?
C19 C23A 1.30(3) . ?
C20 C21 1.36(2) . ?
C20 N4 1.384(19) . ?
C21 C22B 1.54(4) . ?
C21 C24 1.497(19) . ?
C21 C22A 1.39(3) . ?
C22B C23B 1.37(4) . ?
C24 O8 1.250(16) 4_566 ?
C24 O12 1.255(16) . ?
C25 C26 1.49(2) . ?
C25 O7 1.256(15) . ?
C25 O0AA 1.284(17) . ?
C26 C27 1.38(2) . ?
C26 C30 1.37(2) . ?
C27 N5 1.39(2) . ?
C28 C28 1.49(3) 3_566 ?
C28 C29 1.36(2) . ?
C28 N5 1.40(2) . ?
C29 C30 1.35(2) . ?
C31 C32B 1.48(3) . ?
C31 O5 1.228(18) . ?
C31 O17 1.255(18) . ?
C31 Eu2 3.049(15) . ?
C31 C32A 1.66(5) . ?
C32B C33B 1.44(4) . ?
C32B C36B 1.38(3) . ?
C33B N6B 1.27(5) . ?
C34B C34B 1.60(6) 3_666 ?
C34B C35B 1.34(3) . ?
C34B N6B 1.37(4) . ?
C35B C36B 1.41(3) . ?
O1 C1 1.240(16) 4_566 ?
O1 Eu2 2.333(11) . ?
O2 Eu1 2.387(10) . ?
O3 Eu1 2.912(11) 4_566 ?
O3 Eu2 2.559(10) . ?
O4 Eu1 2.356(11) . ?
O5 Eu1 2.360(9) . ?
O5 Eu2 3.013(10) . ?
O6 Eu1 2.439(9) . ?
O7 Eu1 2.416(10) . ?
O8 C24 1.250(16) 4_565 ?
O8 Eu1 2.321(9) . ?
O9 Eu1 2.415(13) . ?
O10B Eu2 2.52(2) . ?
O11 Eu2 2.430(13) . ?
O12 Eu2 2.410(9) . ?
O0AA Eu2 2.397(10) . ?
O14 Eu1 2.924(10) . ?
O14 Eu2 2.369(8) . ?
O17 Eu2 2.386(11) . ?
Eu1 O3 2.912(11) 4_565 ?
Eu1 Eu2 4.2292(10) . ?
Eu2 O10A 2.35(2) . ?
C5A C6A 1.32(3) . ?
C17A C18A 1.41(4) . ?
C22A C23A 1.37(4) . ?
C34A C34A 1.80(9) 3_666 ?
C34A C35A 1.34(5) . ?
C34A N6A 1.32(4) . ?
C35A C36A 1.35(6) . ?
C36A C32A 1.34(6) . ?
N1A C3A 1.44(4) . ?
N6A C33A 1.35(3) . ?
C33A C32A 1.26(5) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 C1 C2 116.7(12) 4_565 . ?
O2 C1 C2 119.8(12) . . ?
O2 C1 O1 123.2(14) . 4_565 ?
C3B C2 C1 119.0(17) . . ?
C3B C2 C6B 108(3) . . ?
C6B C2 C1 125(2) . . ?
C6A C2 C1 117.5(16) . . ?
C6A C2 C3A 117(2) . . ?
C3A C2 C1 117.9(17) . . ?
C2 C3B N1B 118(3) . . ?
C5B C4 C7 118.8(18) . 2_655 ?
C5B C4 N1B 111(3) . . ?
N1B C4 C7 123.5(18) . 2_655 ?
C5A C4 C7 114.4(15) . 2_655 ?
N1A C4 C7 117.2(19) . 2_655 ?
N1A C4 C5A 119(2) . . ?
C4 C5B C6B 119(3) . . ?
C5B C6B C2 126(3) . . ?
C4 C7 N2A 119.5(16) 2_645 . ?
C8B C7 C4 113.0(18) . 2_645 ?
N2B C7 C4 121(2) . 2_645 ?
N2B C7 C8B 117(3) . . ?
C8A C7 C4 119.6(17) . 2_645 ?
C8A C7 N2A 116(2) . . ?
C7 C8B C9 108(3) . . ?
C10 C9 C8B 124.8(15) . . ?
C8A C9 C10 120.6(18) . . ?
C9 C10 C11 117.3(14) . . ?
C9 C10 C12 122.1(12) . . ?
C11 C10 C12 120.3(14) . . ?
C10 C11 N2B 111(2) . . ?
N2A C11 C10 123.7(19) . . ?
O4 C12 C10 116.8(12) . . ?
O4 C12 O10B 130.5(16) . . ?
O4 C12 O10A 120(2) . . ?
O10B C12 C10 111.8(17) . . ?
O10A C12 C10 121.4(17) . . ?
C14 C13 Eu1 164.5(11) . . ?
O6 C13 C14 118.1(13) . . ?
O6 C13 O14 120.5(12) . . ?
O6 C13 Eu1 49.3(6) . . ?
O14 C13 C14 121.2(12) . . ?
O14 C13 Eu1 71.6(7) . . ?
C15 C14 C13 120.3(13) . . ?
C15 C14 C18A 121.8(18) . . ?
C18B C14 C13 123.8(16) . . ?
C18B C14 C15 113.9(18) . . ?
C18A C14 C13 116(2) . . ?
N3 C15 C14 119.2(14) . . ?
C17B C16 C19 120.2(16) . 3_556 ?
C17B C16 N3 118.1(18) . . ?
N3 C16 C19 118.6(13) . 3_556 ?
N3 C16 C17A 121.4(16) . . ?
C17A C16 C19 118.2(16) . 3_556 ?
C16 C17B C18B 116(2) . . ?
C17B C18B C14 124(2) . . ?
C23B C19 C16 115.8(18) . 3_556 ?
N4 C19 C16 119.2(14) . 3_556 ?
N4 C19 C23B 122.8(16) . . ?
C23A C19 C16 119.4(16) . 3_556 ?
C23A C19 N4 119.0(18) . . ?
C21 C20 N4 121.1(14) . . ?
C20 C21 C22B 119.5(18) . . ?
C20 C21 C24 122.3(14) . . ?
C20 C21 C22A 114.2(18) . . ?
C24 C21 C22B 115(2) . . ?
C22A C21 C24 123.1(17) . . ?
C23B C22B C21 116(3) . . ?
C22B C23B C19 119(3) . . ?
O8 C24 C21 117.9(12) 4_566 . ?
O8 C24 O12 126.4(13) 4_566 . ?
O12 C24 C21 115.7(13) . . ?
O7 C25 C26 118.5(14) . . ?
O7 C25 O0AA 125.4(14) . . ?
O0AA C25 C26 116.1(12) . . ?
C27 C26 C25 121.4(14) . . ?
C30 C26 C25 121.5(13) . . ?
C30 C26 C27 117.1(15) . . ?
C26 C27 N5 120.9(15) . . ?
C29 C28 C28 115.7(17) . 3_566 ?
C29 C28 N5 122.0(14) . . ?
N5 C28 C28 122.3(17) . 3_566 ?
C30 C29 C28 117.3(14) . . ?
C29 C30 C26 124.8(14) . . ?
C32B C31 Eu2 153.4(18) . . ?
O5 C31 C32B 123.3(15) . . ?
O5 C31 O17 123.0(14) . . ?
O5 C31 Eu2 76.7(9) . . ?
O5 C31 C32A 113.0(19) . . ?
O17 C31 C32B 113.2(16) . . ?
O17 C31 Eu2 47.4(7) . . ?
O17 C31 C32A 121.8(17) . . ?
C32A C31 Eu2 168.8(14) . . ?
C33B C32B C31 118(2) . . ?
C36B C32B C31 125(2) . . ?
C36B C32B C33B 117(2) . . ?
N6B C33B C32B 122(3) . . ?
C35B C34B C34B 126(3) . 3_666 ?
C35B C34B N6B 118(3) . . ?
N6B C34B C34B 116(3) . 3_666 ?
C34B C35B C36B 121(2) . . ?
C32B C36B C35B 117(2) . . ?
C1 O1 Eu2 153.5(12) 4_566 . ?
C1 O2 Eu1 134.6(9) . . ?
Eu2 O3 Eu1 118.0(5) . 4_566 ?
C12 O4 Eu1 137.3(9) . . ?
C31 O5 Eu1 172.3(11) . . ?
C31 O5 Eu2 80.0(9) . . ?
Eu1 O5 Eu2 103.2(3) . . ?
C13 O6 Eu1 107.7(8) . . ?
C25 O7 Eu1 136.0(10) . . ?
C24 O8 Eu1 140.8(9) 4_565 . ?
C12 O10B Eu2 129(2) . . ?
C24 O12 Eu2 125.3(9) . . ?
C25 O0AA Eu2 137.0(9) . . ?
C13 O14 Eu1 84.1(7) . . ?
C13 O14 Eu2 170.3(9) . . ?
Eu2 O14 Eu1 105.6(3) . . ?
C31 O17 Eu2 109.8(9) . . ?
C3B N1B C4 119(3) . . ?
C7 N2B C11 118(3) . . ?
C15 N3 C16 119.6(14) . . ?
C19 N4 C20 119.0(14) . . ?
C27 N5 C28 117.8(14) . . ?
C33B N6B C34B 119(3) . . ?
C13 Eu1 Eu2 57.0(3) . . ?
O2 Eu1 C13 148.0(4) . . ?
O2 Eu1 O3 75.0(3) . 4_565 ?
O2 Eu1 O6 136.0(3) . . ?
O2 Eu1 O7 143.0(4) . . ?
O2 Eu1 O9 72.1(5) . . ?
O2 Eu1 O14 144.4(4) . . ?
O2 Eu1 Eu2 123.2(2) . . ?
O3 Eu1 C13 78.1(3) 4_565 . ?
O3 Eu1 O14 95.3(3) 4_565 . ?
O3 Eu1 Eu2 117.6(2) 4_565 . ?
O4 Eu1 C13 74.6(4) . . ?
O4 Eu1 O2 77.7(4) . . ?
O4 Eu1 O3 62.3(3) . 4_565 ?
O4 Eu1 O5 73.7(4) . . ?
O4 Eu1 O6 81.1(3) . . ?
O4 Eu1 O7 130.4(3) . . ?
O4 Eu1 O9 140.8(4) . . ?
O4 Eu1 O14 67.7(3) . . ?
O4 Eu1 Eu2 65.2(2) . . ?
O5 Eu1 C13 100.9(4) . . ?
O5 Eu1 O2 86.3(3) . . ?
O5 Eu1 O3 134.8(3) . 4_565 ?
O5 Eu1 O6 123.8(3) . . ?
O5 Eu1 O7 81.3(3) . . ?
O5 Eu1 O9 79.8(4) . . ?
O5 Eu1 O14 76.6(3) . . ?
O5 Eu1 Eu2 43.9(2) . . ?
O6 Eu1 C13 23.1(3) . . ?
O6 Eu1 O3 61.0(3) . 4_565 ?
O6 Eu1 O14 47.3(3) . . ?
O6 Eu1 Eu2 79.9(2) . . ?
O7 Eu1 C13 68.9(3) . . ?
O7 Eu1 O3 135.8(3) . 4_565 ?
O7 Eu1 O6 78.3(3) . . ?
O7 Eu1 O9 71.5(4) . . ?
O7 Eu1 O14 65.1(3) . . ?
O7 Eu1 Eu2 66.9(2) . . ?
O8 Eu1 C13 93.3(4) . . ?
O8 Eu1 O2 92.3(3) . . ?
O8 Eu1 O3 67.7(3) . 4_565 ?
O8 Eu1 O4 130.0(3) . . ?
O8 Eu1 O5 155.4(4) . . ?
O8 Eu1 O6 72.8(3) . . ?
O8 Eu1 O7 85.3(3) . . ?
O8 Eu1 O9 76.4(4) . . ?
O8 Eu1 O14 116.0(3) . . ?
O8 Eu1 Eu2 144.4(2) . . ?
O9 Eu1 C13 139.7(4) . . ?
O9 Eu1 O3 129.4(4) . 4_565 ?
O9 Eu1 O6 138.1(4) . . ?
O9 Eu1 O14 132.9(4) . . ?
O9 Eu1 Eu2 112.5(3) . . ?
O14 Eu1 C13 24.3(3) . . ?
O14 Eu1 Eu2 32.65(16) . . ?
C31 Eu2 Eu1 56.2(3) . . ?
O1 Eu2 C31 92.2(4) . . ?
O1 Eu2 O3 72.1(4) . . ?
O1 Eu2 O5 113.2(3) . . ?
O1 Eu2 O10B 77.0(5) . . ?
O1 Eu2 O11 72.7(4) . . ?
O1 Eu2 O12 101.2(3) . . ?
O1 Eu2 O0AA 142.2(4) . . ?
O1 Eu2 O14 146.1(4) . . ?
O1 Eu2 O17 74.0(4) . . ?
O1 Eu2 Eu1 138.1(2) . . ?
O1 Eu2 O10A 80.0(6) . . ?
O3 Eu2 C31 88.2(4) . . ?
O3 Eu2 O5 103.9(3) . . ?
O3 Eu2 Eu1 126.4(3) . . ?
O5 Eu2 C31 23.4(3) . . ?
O5 Eu2 Eu1 32.91(17) . . ?
O10B Eu2 C31 71.0(10) . . ?
O10B Eu2 O3 141.9(5) . . ?
O10B Eu2 O5 68.6(9) . . ?
O10B Eu2 Eu1 67.5(6) . . ?
O11 Eu2 C31 140.2(4) . . ?
O11 Eu2 O3 119.5(4) . . ?
O11 Eu2 O5 134.9(3) . . ?
O11 Eu2 O10B 69.8(10) . . ?
O11 Eu2 Eu1 112.7(2) . . ?
O12 Eu2 C31 148.3(4) . . ?
O12 Eu2 O3 69.2(3) . . ?
O12 Eu2 O5 141.1(3) . . ?
O12 Eu2 O10B 139.8(9) . . ?
O12 Eu2 O11 71.5(4) . . ?
O12 Eu2 Eu1 120.2(2) . . ?
O0AA Eu2 C31 77.3(4) . . ?
O0AA Eu2 O3 71.4(3) . . ?
O0AA Eu2 O5 67.3(3) . . ?
O0AA Eu2 O10B 130.4(7) . . ?
O0AA Eu2 O11 135.8(4) . . ?
O0AA Eu2 O12 74.5(3) . . ?
O0AA Eu2 Eu1 63.2(2) . . ?
O14 Eu2 C31 97.8(4) . . ?
O14 Eu2 O3 140.2(3) . . ?
O14 Eu2 O5 74.7(3) . . ?
O14 Eu2 O10B 75.8(5) . . ?
O14 Eu2 O11 79.1(4) . . ?
O14 Eu2 O12 87.0(3) . . ?
O14 Eu2 O0AA 71.7(3) . . ?
O14 Eu2 O17 120.5(3) . . ?
O14 Eu2 Eu1 41.8(2) . . ?
O17 Eu2 C31 22.8(4) . . ?
O17 Eu2 O3 69.9(3) . . ?
O17 Eu2 O5 45.9(3) . . ?
O17 Eu2 O10B 80.7(9) . . ?
O17 Eu2 O11 139.4(4) . . ?
O17 Eu2 O12 138.2(3) . . ?
O17 Eu2 O0AA 84.6(4) . . ?
O17 Eu2 Eu1 78.8(3) . . ?
O10A Eu2 C31 59.5(14) . . ?
O10A Eu2 O3 136.4(9) . . ?
O10A Eu2 O5 57.6(13) . . ?
O10A Eu2 O11 81.4(14) . . ?
O10A Eu2 O12 150.9(13) . . ?
O10A Eu2 O0AA 121.9(11) . . ?
O10A Eu2 O14 77.4(6) . . ?
O10A Eu2 O17 70.5(12) . . ?
O10A Eu2 Eu1 60.9(8) . . ?
C6A C5A C4 117(2) . . ?
C5A C6A C2 121(2) . . ?
C16 C17A C18A 122(2) . . ?
C17A C18A C14 114(3) . . ?
C23A C22A C21 122(2) . . ?
C19 C23A C22A 119(2) . . ?
C35A C34A C34A 108(4) . 3_666 ?
N6A C34A C34A 114(4) . 3_666 ?
N6A C34A C35A 121(3) . . ?
C34A C35A C36A 115(4) . . ?
C32A C36A C35A 123(5) . . ?
C4 N1A C3A 120(3) . . ?
C11 N2A C7 112(3) . . ?
C34A N6A C33A 120(2) . . ?
C32A C33A N6A 119(3) . . ?
C9 C8A C7 120(2) . . ?
N1A C3A C2 114(3) . . ?
C12 O10A Eu2 145.1(16) . . ?
C36A C32A C31 116(4) . . ?
C33A C32A C31 121(3) . . ?
C33A C32A C36A 120(4) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 C2 C3B N1B -179(5) . . . . ?
C1 C2 C6B C5B -175(5) . . . . ?
C1 C2 C6A C5A -178(3) . . . . ?
C1 C2 C3A N1A 179(4) . . . . ?
C2 C1 O2 Eu1 178.0(11) . . . . ?
C2 C3B N1B C4 -5(9) . . . . ?
C3B C2 C6B C5B 36(8) . . . . ?
C4 C5B C6B C2 -4(9) . . . . ?
C4 C7 C8B C9 166(2) 2_645 . . . ?
C4 C7 N2B C11 -158(3) 2_645 . . . ?
C4 C7 N2A C11 175(2) 2_645 . . . ?
C4 C7 C8A C9 -167(3) 2_645 . . . ?
C4 C5A C6A C2 -1(5) . . . . ?
C4 N1A C3A C2 -3(8) . . . . ?
C5B C4 N1B C3B 38(7) . . . . ?
C6B C2 C3B N1B -28(7) . . . . ?
C7 C4 C5B C6B 175(4) 2_655 . . . ?
C7 C4 N1B C3B -171(5) 2_655 . . . ?
C7 C4 C5A C6A 175(3) 2_655 . . . ?
C7 C4 N1A C3A -171(5) 2_655 . . . ?
C7 C8B C9 C10 27(4) . . . . ?
C8B C7 N2B C11 57(7) . . . . ?
C8B C9 C10 C11 -16(4) . . . . ?
C8B C9 C10 C12 170(3) . . . . ?
C9 C10 C11 N2B 18(4) . . . . ?
C9 C10 C11 N2A -9(4) . . . . ?
C9 C10 C12 O4 -165.1(17) . . . . ?
C9 C10 C12 O10B 5(3) . . . . ?
C9 C10 C12 O10A 29(4) . . . . ?
C10 C9 C8A C7 -29(6) . . . . ?
C10 C11 N2B C7 -40(7) . . . . ?
C10 C11 N2A C7 16(5) . . . . ?
C10 C12 O4 Eu1 -141.9(12) . . . . ?
C10 C12 O10B Eu2 162.0(17) . . . . ?
C10 C12 O10A Eu2 -169(5) . . . . ?
C11 C10 C12 O4 21(2) . . . . ?
C11 C10 C12 O10B -169(2) . . . . ?
C11 C10 C12 O10A -145(3) . . . . ?
C12 C10 C11 N2B -168(3) . . . . ?
C12 C10 C11 N2A 166(3) . . . . ?
C13 C14 C15 N3 178.9(16) . . . . ?
C13 C14 C18B C17B 175(4) . . . . ?
C13 C14 C18A C17A 178(3) . . . . ?
C14 C13 O6 Eu1 169.1(11) . . . . ?
C14 C13 O14 Eu1 -170.3(14) . . . . ?
C14 C15 N3 C16 -1(3) . . . . ?
C15 C14 C18B C17B 10(6) . . . . ?
C15 C14 C18A C17A -17(5) . . . . ?
C16 C17B C18B C14 14(7) . . . . ?
C16 C19 C23B C22B 177(4) 3_556 . . . ?
C16 C19 N4 C20 -176.4(17) 3_556 . . . ?
C16 C19 C23A C22A 173(4) 3_556 . . . ?
C16 C17A C18A C14 7(6) . . . . ?
C17B C16 N3 C15 27(3) . . . . ?
C18B C14 C15 N3 -16(3) . . . . ?
C19 C16 C17B C18B 168(3) 3_556 . . . ?
C19 C16 N3 C15 -173.2(18) 3_556 . . . ?
C19 C16 C17A C18A 170(4) 3_556 . . . ?
C20 C21 C22B C23B -12(6) . . . . ?
C20 C21 C24 O8 -176.1(15) . . . 4_566 ?
C20 C21 C24 O12 5(2) . . . . ?
C20 C21 C22A C23A 13(6) . . . . ?
C21 C20 N4 C19 0(3) . . . . ?
C21 C22B C23B C19 0(7) . . . . ?
C21 C24 O12 Eu2 -163.8(9) . . . . ?
C21 C22A C23A C19 7(7) . . . . ?
C22B C21 C24 O8 -17(3) . . . 4_566 ?
C22B C21 C24 O12 164(3) . . . . ?
C23B C19 N4 C20 -14(3) . . . . ?
C24 C21 C22B C23B -172(4) . . . . ?
C24 C21 C22A C23A -174(4) . . . . ?
C25 C26 C27 N5 -177.7(16) . . . . ?
C25 C26 C30 C29 177.8(17) . . . . ?
C26 C25 O7 Eu1 -163.3(10) . . . . ?
C26 C25 O0AA Eu2 129.9(12) . . . . ?
C26 C27 N5 C28 2(3) . . . . ?
C27 C26 C30 C29 0(3) . . . . ?
C28 C28 C29 C30 -178.2(19) 3_566 . . . ?
C28 C28 N5 C27 178(2) 3_566 . . . ?
C28 C29 C30 C26 -2(3) . . . . ?
C29 C28 N5 C27 -4(3) . . . . ?
C30 C26 C27 N5 0(3) . . . . ?
C31 C32B C33B N6B -175(4) . . . . ?
C31 C32B C36B C35B -176(3) . . . . ?
C32B C31 O5 Eu2 161(2) . . . . ?
C32B C31 O17 Eu2 -158.2(18) . . . . ?
C32B C33B N6B C34B -24(8) . . . . ?
C33B C32B C36B C35B -2(6) . . . . ?
C34B C34B C35B C36B 158(5) 3_666 . . . ?
C34B C34B N6B C33B -150(5) 3_666 . . . ?
C34B C35B C36B C32B 9(6) . . . . ?
C35B C34B N6B C33B 30(7) . . . . ?
C36B C32B C33B N6B 11(7) . . . . ?
O1 C1 C2 C3B -38(4) 4_565 . . . ?
O1 C1 C2 C6B 176(4) 4_565 . . . ?
O1 C1 C2 C6A 139(2) 4_565 . . . ?
O1 C1 C2 C3A -9(4) 4_565 . . . ?
O1 C1 O2 Eu1 5(3) 4_565 . . . ?
O2 C1 C2 C3B 148(3) . . . . ?
O2 C1 C2 C6B 3(4) . . . . ?
O2 C1 C2 C6A -34(3) . . . . ?
O2 C1 C2 C3A 177(3) . . . . ?
O4 C12 O10B Eu2 -30(4) . . . . ?
O4 C12 O10A Eu2 26(8) . . . . ?
O5 C31 C32B C33B 4(5) . . . . ?
O5 C31 C32B C36B 177(3) . . . . ?
O5 C31 O17 Eu2 14(2) . . . . ?
O5 C31 C32A C36A 178(5) . . . . ?
O5 C31 C32A C33A -19(6) . . . . ?
O6 C13 C14 C15 177.1(15) . . . . ?
O6 C13 C14 C18B 14(3) . . . . ?
O6 C13 C14 C18A -18(3) . . . . ?
O6 C13 O14 Eu1 5.6(13) . . . . ?
O7 C25 C26 C27 158.7(15) . . . . ?
O7 C25 C26 C30 -19(2) . . . . ?
O7 C25 O0AA Eu2 -49(2) . . . . ?
O8 C24 O12 Eu2 17(2) 4_566 . . . ?
O10B C12 O4 Eu1 50(3) . . . . ?
O0AA C25 C26 C27 -21(2) . . . . ?
O0AA C25 C26 C30 161.6(15) . . . . ?
O0AA C25 O7 Eu1 16(2) . . . . ?
O14 C13 C14 C15 -7(2) . . . . ?
O14 C13 C14 C18B -170(3) . . . . ?
O14 C13 C14 C18A 158(3) . . . . ?
O14 C13 O6 Eu1 -7.0(16) . . . . ?
O17 C31 C32B C33B 176(3) . . . . ?
O17 C31 C32B C36B -11(5) . . . . ?
O17 C31 O5 Eu2 -10.5(18) . . . . ?
O17 C31 C32A C36A 15(6) . . . . ?
O17 C31 C32A C33A 177(4) . . . . ?
N1B C4 C5B C6B -33(6) . . . . ?
N2B C7 C8B C9 -47(5) . . . . ?
N3 C16 C17B C18B -32(5) . . . . ?
N3 C16 C17A C18A 6(5) . . . . ?
N4 C19 C23B C22B 14(5) . . . . ?
N4 C19 C23A C22A -25(5) . . . . ?
N4 C20 C21 C22B 13(4) . . . . ?
N4 C20 C21 C24 171.1(15) . . . . ?
N4 C20 C21 C22A -16(3) . . . . ?
N5 C28 C29 C30 4(3) . . . . ?
N6B C34B C35B C36B -22(6) . . . . ?
Eu1 C13 C14 C15 -150(3) . . . . ?
Eu1 C13 C14 C18B 47(5) . . . . ?
Eu1 C13 C14 C18A 15(5) . . . . ?
Eu2 C31 C32B C33B 138(3) . . . . ?
Eu2 C31 C32B C36B -49(6) . . . . ?
Eu2 C31 C32A C36A 30(15) . . . . ?
Eu2 C31 C32A C33A -167(8) . . . . ?
C5A C4 N1A C3A -27(7) . . . . ?
C6A C2 C3A N1A 30(6) . . . . ?
C17A C16 N3 C15 -9(3) . . . . ?
C18A C14 C15 N3 15(4) . . . . ?
C22A C21 C24 O8 12(3) . . . 4_566 ?
C22A C21 C24 O12 -167(3) . . . . ?
C23A C19 N4 C20 21(3) . . . . ?
C34A C34A C35A C36A -140(6) 3_666 . . . ?
C34A C34A N6A C33A 147(4) 3_666 . . . ?
C34A C35A C36A C32A -3(11) . . . . ?
C34A N6A C33A C32A -16(8) . . . . ?
C35A C34A N6A C33A 16(8) . . . . ?
C35A C36A C32A C31 166(6) . . . . ?
C35A C36A C32A C33A 3(12) . . . . ?
N1A C4 C5A C6A 29(5) . . . . ?
N2A C7 C8A C9 37(6) . . . . ?
N6A C34A C35A C36A -6(9) . . . . ?
N6A C33A C32A C31 -155(4) . . . . ?
N6A C33A C32A C36A 7(9) . . . . ?
C8A C7 N2A C11 -29(5) . . . . ?
C8A C9 C10 C11 13(4) . . . . ?
C8A C9 C10 C12 -161(3) . . . . ?
C3A C2 C6A C5A -29(5) . . . . ?
O10A C12 O4 Eu1 24(3) . . . . ?
C32A C31 O5 Eu2 -174(2) . . . . ?
C32A C31 O17 Eu2 176(3) . . . . ?

_shelx_SHELXL_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_exp_6314_sq
_database_code_depnum_ccdc_archive 'CCDC 1416082'
_audit_update_record             
;
2015-07-31 deposited with the CCDC.
2015-09-30 downloaded from the CCDC.
;
_audit_creation_date             2015-07-31
_audit_creation_method           
;
Olex2 1.2
(compiled 2015.01.26 svn.r3150 for OlexSys, GUI svn.r4998)
;
_chemical_name_common            ?
_chemical_name_systematic        Eu-bpydc-Cu
_chemical_formula_moiety         'C36 Cu1.02 Eu2 N6 O15'
_chemical_formula_sum            'C36 Cu1.02 Eu2 N7 O15'
_chemical_formula_weight         1139.48
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -8.9294 11.1857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu -1.9646 0.5888 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   26.531(2)
_cell_length_b                   13.617(4)
_cell_length_c                   16.4067(19)
_cell_angle_alpha                90
_cell_angle_beta                 98.040(11)
_cell_angle_gamma                90
_cell_volume                     5869.1(19)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    ?
_cell_measurement_temperature    100
_cell_measurement_theta_max      ?
_cell_measurement_theta_min      ?
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    15.990
_exptl_absorpt_correction_T_max  0.2978
_exptl_absorpt_correction_T_min  0.0605
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear reddish red'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   reddish
_exptl_crystal_colour_primary    red
_exptl_crystal_density_diffrn    1.290
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       needle
_exptl_crystal_F_000             2163
_exptl_crystal_preparation       ?
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0604
_diffrn_reflns_av_unetI/netI     0.1027
_diffrn_reflns_Laue_measured_fraction_full 0.349
_diffrn_reflns_Laue_measured_fraction_max 0.349
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            4607
_diffrn_reflns_point_group_measured_fraction_full 0.349
_diffrn_reflns_point_group_measured_fraction_max 0.349
_diffrn_reflns_theta_full        65.596
_diffrn_reflns_theta_max         65.596
_diffrn_reflns_theta_min         5.051
_diffrn_ambient_temperature      100
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.349
_diffrn_measured_fraction_theta_max 0.349
_diffrn_measurement_device_type  'Agilent micro-focus'
_diffrn_measurement_method       ?
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                2118
_reflns_number_total             3528
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2008)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         0.999
_refine_diff_density_min         -0.964
_refine_diff_density_rms         0.140
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.029
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     183
_refine_ls_number_reflns         3528
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1862
_refine_ls_R_factor_gt           0.1266
_refine_ls_restrained_S_all      1.029
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1521P)²+217.2555P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.3030
_refine_ls_wR_factor_ref         0.3609
_refine_special_details          ?
_olex2_refinement_description    
;
1. Shared sites
{N5, CN5}
{N6, CN6}
{C28, NC28}
{C34, NC34}
2. Uiso/Uaniso restraints and constraints
Uiso(N5) = Uiso(CN5)
Uiso(N6) = Uiso(CN6)
Uiso(C28) = Uiso(NC28)
Uiso(C34) = Uiso(NC34)
3. Others
 Fixed Sof: C28(0.5) N5(0.5) C34(0.5) N6(0.5) NC34(0.5) NC28(0.5) CN5(0.5)
 CN6(0.5)
 Fixed X: Cu3(0.47226)
 Fixed Y: Cu3(0.56342)
 Fixed Z: Cu3(0.379469)
4.a Fitted hexagon refined as free rotating group:
 C2(C3,N1,C4,C5,C6), C7(C8,C9,C10,C11,N2), C14(C15,N3,C16,C17,C18), C19(N4,C21,
 C20,C22,C23), C26(C27,C28,C29,N5,C30), C32(C33,C34,C35,N6,C36)
;
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.3349(11) 1.095(4) 0.690(2) 0.047(9) Uiso 1 1 d . . . . .
C2 C 0.3895(9) 0.066(4) 0.6801(19) 0.078(12) Uiso 1 1 d . . . . .
C3 C 0.4058(10) 0.045(4) 0.6050(15) 0.121(18) Uiso 1 1 d G . . . .
N1 N 0.4565(11) 0.022(4) 0.6018(14) 0.103(13) Uiso 1 1 d G . . . .
C4 C 0.4910(9) 0.019(4) 0.6738(19) 0.088(14) Uiso 1 1 d G . . . .
C5 C 0.4747(11) 0.040(4) 0.7490(15) 0.123(19) Uiso 1 1 d G . . . .
C6 C 0.4240(13) 0.063(4) 0.7522(15) 0.120(18) Uiso 1 1 d G . . . .
C12 C 0.6766(13) 0.851(4) 0.632(2) 0.064(11) Uiso 1 1 d . . . . .
C7 C 0.5351(9) 0.968(3) 0.6672(16) 0.074(12) Uiso 1 1 d . . . . .
C8 C 0.5676(13) 0.934(4) 0.7352(12) 0.123(19) Uiso 1 1 d G . . . .
C9 C 0.6145(11) 0.894(4) 0.7251(15) 0.126(19) Uiso 1 1 d G . . . .
C10 C 0.6289(9) 0.888(3) 0.6470(19) 0.072(12) Uiso 1 1 d G . . . .
C11 C 0.5965(10) 0.922(3) 0.5790(13) 0.127(19) Uiso 1 1 d G . . . .
N2 N 0.5496(9) 0.962(3) 0.5891(13) 0.065(8) Uiso 1 1 d G . . . .
C13 C 0.8343(12) 0.897(4) 0.363(2) 0.054(10) Uiso 1 1 d . . . . .
C14 C 0.8859(7) 0.935(2) 0.3502(15) 0.046(8) Uiso 1 1 d . . . . .
C15 C 0.8933(8) 0.999(2) 0.2872(14) 0.100(15) Uiso 1 1 d G . . . .
N3 N 0.9419(10) 1.033(2) 0.2801(14) 0.106(13) Uiso 1 1 d G . . . .
C16 C 0.9832(7) 1.002(2) 0.3362(16) 0.068(11) Uiso 1 1 d G . . . .
C17 C 0.9758(7) 0.938(2) 0.3992(14) 0.065(10) Uiso 1 1 d G . . . .
C18 C 0.9271(9) 0.904(2) 0.4062(13) 0.078(12) Uiso 1 1 d G . . . .
C24 C 0.8323(12) 0.706(4) 0.171(2) 0.052(9) Uiso 1 1 d . . . . .
C19 C 1.0317(8) 1.045(2) 0.3333(15) 0.068(11) Uiso 1 1 d . . . . .
N4 N 1.0387(8) 1.104(2) 0.2664(12) 0.082(10) Uiso 1 1 d G . . . .
C21 C 1.0841(9) 1.154(2) 0.2661(13) 0.078(12) Uiso 1 1 d G . . . .
C20 C 1.1225(8) 1.147(3) 0.3327(16) 0.058(10) Uiso 1 1 d G . . . .
C22 C 1.1155(8) 1.088(3) 0.3996(13) 0.121(18) Uiso 1 1 d G . . . .
C23 C 1.0701(10) 1.037(2) 0.3999(13) 0.059(10) Uiso 1 1 d G . . . .
C25 C 0.8267(13) 0.616(4) 0.539(2) 0.064(11) Uiso 1 1 d . . . . .
C26 C 0.8765(8) 0.578(3) 0.5218(16) 0.062(10) Uiso 1 1 d . . . . .
C27 C 0.9025(11) 0.514(3) 0.5785(14) 0.108(16) Uiso 1 1 d G . . . .
C28 C 0.9515(10) 0.484(3) 0.5697(17) 0.096(13) Uiso 0.5 1 d G . . . .
C29 C 0.9745(8) 0.518(3) 0.5041(19) 0.098(15) Uiso 1 1 d G . . . .
N5 N 0.9486(10) 0.583(3) 0.4474(15) 0.105(14) Uiso 0.5 1 d G . . . .
C30 C 0.8996(10) 0.613(2) 0.4563(15) 0.075(12) Uiso 1 1 d G . . . .
C31 C 0.6677(12) 0.661(4) 0.493(2) 0.056(10) Uiso 1 1 d . . . . .
C32 C 0.6181(8) 0.608(3) 0.5007(17) 0.062(10) Uiso 1 1 d . . . . .
C33 C 0.6117(8) 0.538(3) 0.5599(14) 0.113(17) Uiso 1 1 d G . . . .
C34 C 0.5647(11) 0.493(2) 0.5595(16) 0.089(12) Uiso 0.5 1 d G . . . .
C35 C 0.5242(8) 0.517(2) 0.5000(17) 0.069(11) Uiso 1 1 d G . . . .
N6 N 0.5305(8) 0.588(3) 0.4409(14) 0.098(13) Uiso 0.5 1 d G . . . .
C36 C 0.5775(10) 0.633(2) 0.4413(15) 0.082(13) Uiso 1 1 d G . . . .
O004 O 0.7507(8) 0.739(3) 0.3330(13) 0.072(7) Uiso 1 1 d . . . . .
O005 O 0.8253(8) 0.857(2) 0.4245(14) 0.064(7) Uiso 1 1 d . . . . .
O006 O 0.8268(7) 0.744(2) 0.2314(13) 0.052(6) Uiso 1 1 d . . . . .
O007 O 0.8020(8) 0.661(2) 0.4816(13) 0.060(6) Uiso 1 1 d . . . . .
O008 O 0.7987(8) 0.920(3) 0.3024(13) 0.063(7) Uiso 1 1 d . . . . .
O009 O 0.8133(8) 0.912(3) 0.1087(14) 0.069(7) Uiso 1 1 d . . . . .
O00A O 0.6794(10) 0.893(3) 0.2425(17) 0.087(9) Uiso 1 1 d . . . . .
O00B O 0.7021(8) 0.801(2) 0.6886(13) 0.057(6) Uiso 1 1 d . . . . .
O00C O 0.7040(8) 0.657(3) 0.5577(13) 0.059(6) Uiso 1 1 d . . . . .
O00D O 0.6750(8) 0.704(2) 0.4338(14) 0.061(7) Uiso 1 1 d . . . . .
O00E O 0.7964(7) 0.702(2) 0.1077(12) 0.047(6) Uiso 1 1 d . . . . .
O00F O 0.6889(9) 0.860(3) 0.5608(16) 0.075(8) Uiso 1 1 d . . . . .
O00H O 0.7661(10) 0.979(3) 0.5083(16) 0.101(10) Uiso 1 1 d . . . . .
O00I O 0.6946(10) 0.899(3) 0.3797(16) 0.088(9) Uiso 1 1 d . . . . .
O00J O 0.7388(10) 1.026(3) 0.1670(16) 0.102(10) Uiso 1 1 d . . . . .
NC34 N 0.5647(11) 0.493(2) 0.5595(16) 0.089(12) Uiso 0.5 1 d . . . . .
NC28 N 0.9515(10) 0.484(3) 0.5697(17) 0.096(13) Uiso 0.5 1 d . . . . .
CN5 C 0.9486(10) 0.583(3) 0.4474(15) 0.105(14) Uiso 0.5 1 d . . . . .
CN6 C 0.5305(8) 0.588(3) 0.4409(14) 0.098(13) Uiso 0.5 1 d . . . . .
Eu01 Eu 0.75242(6) 0.8488(3) 0.18957(12) 0.0703(12) Uani 1 1 d . . . . .
Eu02 Eu 0.74943(6) 0.8080(3) 0.47301(12) 0.0710(12) Uani 1 1 d . . . . .
Cu1 Cu 0.5000 0.0000 0.5000 0.201(7) Uiso 1 2 d S T P . .
Cu2 Cu 0.9858(12) 0.423(4) 0.6724(18) 0.23(2) Uiso 0.43(3) 1 d . . . . .
Cu3 Cu 0.4723 0.5634 0.3795 0.18(8) Uiso 0.09(3) 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.53(4) 1_565 ?
C1 O00A 1.23(3) 3_676 ?
C1 O00I 1.29(3) 3_676 ?
C2 C1 1.53(4) 1_545 ?
C2 C3 1.3900 . ?
C2 C6 1.3900 . ?
C3 N1 1.3900 . ?
N1 C4 1.3900 . ?
N1 Cu1 2.18(2) . ?
C4 C5 1.3900 . ?
C4 C7 1.38(4) 1_545 ?
C5 C6 1.3900 . ?
C12 C10 1.41(4) . ?
C12 O00B 1.27(4) . ?
C12 O00F 1.26(4) . ?
C7 C4 1.4(4) 1_565 ?
C7 C8 1.3900 . ?
C7 N2 1.3900 . ?
C8 C9 1.3900 . ?
C9 C10 1.3900 . ?
C10 C11 1.3900 . ?
C11 N2 1.3900 . ?
N2 Cu1 1.90(2) 1_565 ?
C13 C14 1.50(4) . ?
C13 O005 1.21(4) . ?
C13 O008 1.31(3) . ?
C14 C15 1.3900 . ?
C14 C18 1.3900 . ?
C15 N3 1.3900 . ?
N3 C16 1.3900 . ?
N3 Cu2 2.33(4) 4_575 ?
C16 C17 1.3900 . ?
C16 C19 1.42(2) . ?
C17 C18 1.3900 . ?
C24 C20 1.45(8) 2_745 ?
C24 O006 1.15(4) . ?
C24 O00E 1.31(3) . ?
C24 Eu01 2.93(4) . ?
C19 N4 1.3900 . ?
C19 C23 1.3900 . ?
N4 C21 1.3900 . ?
N4 Cu2 1.97(4) 4_575 ?
C21 C20 1.3900 . ?
C20 C24 1.45(4) 2_755 ?
C20 C22 1.3900 . ?
C22 C23 1.3900 . ?
C25 C26 1.48(4) . ?
C25 O007 1.23(4) . ?
C25 O009 1.30(4) 4_576 ?
C26 C27 1.3900 . ?
C26 C30 1.3900 . ?
C27 C28 1.3900 . ?
C28 C29 1.3900 . ?
C28 Cu2 1.98(4) . ?
C29 C29 1.46(4) 3_766 ?
C29 N5 1.3900 . ?
N5 C30 1.3900 . ?
C31 C32 1.52(4) . ?
C31 O00C 1.33(3) . ?
C31 O00D 1.18(4) . ?
C31 Eu02 3.01(4) . ?
C32 C33 1.3900 . ?
C32 C36 1.3900 . ?
C33 C34 1.3900 . ?
C34 C35 1.3900 . ?
C34 Cu3 1.68(2) 3_666 ?
C35 C35 1.37(4) 3_666 ?
C35 N6 1.3900 . ?
C35 Cu3 2.33(3) . ?
C35 Cu3 2.25(3) 3_666 ?
N6 C36 1.3900 . ?
N6 Cu3 1.76(2) . ?
O004 Eu01 2.79(3) . ?
O004 Eu02 2.49(3) . ?
O005 Eu02 2.36(2) . ?
O006 Eu01 2.45(2) . ?
O007 Eu02 2.43(3) . ?
O008 Eu01 2.29(2) . ?
O009 C25 1.30(4) 4_575 ?
O009 Eu01 2.39(3) . ?
O00A C1 1.23(3) 3_676 ?
O00A Eu01 2.31(3) . ?
O00B Eu01 2.43(3) 4_576 ?
O00C Eu01 2.36(2) 4_576 ?
O00C Eu02 2.84(3) . ?
O00D Eu02 2.44(2) . ?
O00E Eu01 2.76(3) . ?
O00E Eu02 2.38(2) 4_575 ?
O00F Eu02 2.41(3) . ?
O00H Eu02 2.42(4) . ?
O00I C1 1.29(3) 3_676 ?
O00I Eu02 2.32(3) . ?
O00J Eu01 2.46(4) . ?
Eu01 O00B 2.43(3) 4_575 ?
Eu01 O00C 2.36(2) 4_575 ?
Eu01 Eu02 4.137(4) 4_575 ?
Eu02 O00E 2.38(2) 4_576 ?
Eu02 Eu01 4.137(4) 4_576 ?
Cu1 N1 2.18(2) 3_656 ?
Cu1 N2 1.9(3) 1_545 ?
Cu1 N2 1.9(3) 3_666 ?
Cu2 N3 2.33(11) 4_576 ?
Cu2 N4 1.97(18) 4_576 ?
Cu3 C34 1.68(5) 3_666 ?
Cu3 C35 2.25(4) 3_666 ?
Cu3 NC34 1.68(5) 3_666 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O00A C1 C2 123(3) 3_676 1_565 ?
O00A C1 O00I 124(3) 3_676 3_676 ?
O00I C1 C2 113(3) 3_676 1_565 ?
C3 C2 C1 124(2) . 1_545 ?
C3 C2 C6 120.0 . . ?
C6 C2 C1 116(2) . 1_545 ?
N1 C3 C2 120.0 . . ?
C3 N1 Cu1 132.8(17) . . ?
C4 N1 C3 120.0 . . ?
C4 N1 Cu1 106.9(16) . . ?
N1 C4 C5 120.0 . . ?
C7 C4 N1 114(3) 1_545 . ?
C7 C4 C5 123(2) 1_545 . ?
C6 C5 C4 120.0 . . ?
C5 C6 C2 120.0 . . ?
O00B C12 C10 118(3) . . ?
O00F C12 C10 119(3) . . ?
O00F C12 O00B 123(3) . . ?
C4 C7 C8 123(10) 1_565 . ?
C4 C7 N2 117(10) 1_565 . ?
C8 C7 N2 120.0 . . ?
C7 C8 C9 120.0 . . ?
C10 C9 C8 120.0 . . ?
C9 C10 C12 123(3) . . ?
C9 C10 C11 120.0 . . ?
C11 C10 C12 117(3) . . ?
N2 C11 C10 120.0 . . ?
C7 N2 Cu1 116.3(15) . 1_565 ?
C11 N2 C7 120.0 . . ?
C11 N2 Cu1 123.5(15) . 1_565 ?
O005 C13 C14 124(3) . . ?
O005 C13 O008 122(3) . . ?
O008 C13 C14 113(3) . . ?
C15 C14 C13 123(2) . . ?
C15 C14 C18 120.0 . . ?
C18 C14 C13 117(2) . . ?
N3 C15 C14 120.0 . . ?
C15 N3 C16 120.0 . . ?
C15 N3 Cu2 135.8(15) . 4_575 ?
C16 N3 Cu2 98.6(15) . 4_575 ?
N3 C16 C19 119(2) . . ?
C17 C16 N3 120.0 . . ?
C17 C16 C19 120(2) . . ?
C16 C17 C18 120.0 . . ?
C17 C18 C14 120.0 . . ?
C20 C24 Eu01 171(6) 2_745 . ?
O006 C24 C20 119(5) . 2_745 ?
O006 C24 O00E 122(3) . . ?
O006 C24 Eu01 55(2) . . ?
O00E C24 C20 117(6) . 2_745 ?
O00E C24 Eu01 69.7(17) . . ?
N4 C19 C16 119(2) . . ?
N4 C19 C23 120.0 . . ?
C23 C19 C16 120.8(19) . . ?
C19 N4 C21 120.0 . . ?
C19 N4 Cu2 110.8(19) . 4_575 ?
C21 N4 Cu2 127.7(17) . 4_575 ?
C20 C21 N4 120.0 . . ?
C21 C20 C24 116(2) . 2_755 ?
C21 C20 C22 120.0 . . ?
C22 C20 C24 123(2) . 2_755 ?
C23 C22 C20 120.0 . . ?
C22 C23 C19 120.0 . . ?
O007 C25 C26 115(3) . . ?
O007 C25 O009 129(3) . 4_576 ?
O009 C25 C26 115(3) 4_576 . ?
C27 C26 C25 118(3) . . ?
C27 C26 C30 120.0 . . ?
C30 C26 C25 122(3) . . ?
C28 C27 C26 120.0 . . ?
C27 C28 C29 120.0 . . ?
C27 C28 Cu2 111.0(19) . . ?
C29 C28 Cu2 126.9(19) . . ?
C28 C29 C29 118(4) . 3_766 ?
N5 C29 C28 120.0 . . ?
N5 C29 C29 122(4) . 3_766 ?
C30 N5 C29 120.0 . . ?
N5 C30 C26 120.0 . . ?
C32 C31 Eu02 166(3) . . ?
O00C C31 C32 117(3) . . ?
O00C C31 Eu02 70.0(18) . . ?
O00D C31 C32 123(3) . . ?
O00D C31 O00C 119(3) . . ?
O00D C31 Eu02 51(2) . . ?
C33 C32 C31 125(2) . . ?
C33 C32 C36 120.0 . . ?
C36 C32 C31 115(2) . . ?
C34 C33 C32 120.0 . . ?
C33 C34 C35 120.0 . . ?
C33 C34 Cu3 142.9(17) . 3_666 ?
C35 C34 Cu3 94.0(16) . 3_666 ?
C34 C35 N6 120.0 . . ?
C34 C35 Cu3 165.6(12) . . ?
C34 C35 Cu3 48.0(11) . 3_666 ?
C35 C35 C34 123(4) 3_666 . ?
C35 C35 N6 116(4) 3_666 . ?
C35 C35 Cu3 70(3) 3_666 . ?
C35 C35 Cu3 76(3) 3_666 3_666 ?
N6 C35 Cu3 162.7(14) . 3_666 ?
N6 C35 Cu3 48.6(12) . . ?
Cu3 C35 Cu3 145.4(9) 3_666 . ?
C35 N6 Cu3 95.0(17) . . ?
C36 N6 C35 120.0 . . ?
C36 N6 Cu3 143.5(16) . . ?
N6 C36 C32 120.0 . . ?
Eu02 O004 Eu01 125.5(15) . . ?
C13 O005 Eu02 134(2) . . ?
C24 O006 Eu01 103(2) . . ?
C25 O007 Eu02 134(3) . . ?
C13 O008 Eu01 139(3) . . ?
C25 O009 Eu01 132(3) 4_575 . ?
C1 O00A Eu01 139(2) 3_676 . ?
C12 O00B Eu01 134(3) . 4_576 ?
C31 O00C Eu01 166.7(19) . 4_576 ?
C31 O00C Eu02 84(2) . . ?
Eu01 O00C Eu02 105.1(10) 4_576 . ?
C31 O00D Eu02 107(2) . . ?
C24 O00E Eu01 84(2) . . ?
C24 O00E Eu02 164.9(18) . 4_575 ?
Eu02 O00E Eu01 106.8(9) 4_575 . ?
C12 O00F Eu02 144(3) . . ?
C1 O00I Eu02 149(3) 3_676 . ?
C24 Eu01 Eu02 59.5(7) . 4_575 ?
O004 Eu01 C24 80.2(9) . . ?
O004 Eu01 Eu02 116.5(7) . 4_575 ?
O006 Eu01 C24 22.6(7) . . ?
O006 Eu01 O004 63.9(7) . . ?
O006 Eu01 O00E 48.4(7) . . ?
O006 Eu01 O00J 135.1(9) . . ?
O006 Eu01 Eu02 81.8(5) . 4_575 ?
O008 Eu01 C24 93.0(10) . . ?
O008 Eu01 O004 67.4(10) . . ?
O008 Eu01 O006 72.6(9) . . ?
O008 Eu01 O009 88.2(8) . . ?
O008 Eu01 O00A 88.2(9) . . ?
O008 Eu01 O00B 126.3(9) . 4_575 ?
O008 Eu01 O00C 156.7(12) . 4_575 ?
O008 Eu01 O00E 119.1(8) . . ?
O008 Eu01 O00J 76.0(11) . . ?
O008 Eu01 Eu02 149.0(6) . 4_575 ?
O009 Eu01 C24 67.9(11) . . ?
O009 Eu01 O004 138.8(7) . . ?
O009 Eu01 O006 77.6(9) . . ?
O009 Eu01 O00B 135.2(9) . 4_575 ?
O009 Eu01 O00E 68.0(9) . . ?
O009 Eu01 O00J 70.2(10) . . ?
O009 Eu01 Eu02 69.0(7) . 4_575 ?
O00A Eu01 C24 150.7(13) . . ?
O00A Eu01 O004 73.2(10) . . ?
O00A Eu01 O006 137.0(9) . . ?
O00A Eu01 O009 141.4(13) . . ?
O00A Eu01 O00B 74.6(11) . 4_575 ?
O00A Eu01 O00C 88.6(8) . 4_575 ?
O00A Eu01 O00E 143.8(10) . . ?
O00A Eu01 O00J 71.7(12) . . ?
O00A Eu01 Eu02 122.8(7) . 4_575 ?
O00B Eu01 C24 81.2(10) 4_575 . ?
O00B Eu01 O004 59.0(8) 4_575 . ?
O00B Eu01 O006 86.2(8) 4_575 . ?
O00B Eu01 O00E 70.0(8) 4_575 . ?
O00B Eu01 O00J 138.7(9) 4_575 . ?
O00B Eu01 Eu02 67.5(5) 4_575 4_575 ?
O00C Eu01 C24 100.9(10) 4_575 . ?
O00C Eu01 O004 133.1(9) 4_575 . ?
O00C Eu01 O006 123.3(9) 4_575 . ?
O00C Eu01 O009 80.0(8) 4_575 . ?
O00C Eu01 O00B 74.7(9) 4_575 4_575 ?
O00C Eu01 O00E 75.0(8) 4_575 . ?
O00C Eu01 O00J 81.2(10) 4_575 . ?
O00C Eu01 Eu02 41.5(7) 4_575 4_575 ?
O00E Eu01 C24 26.3(7) . . ?
O00E Eu01 O004 94.6(8) . . ?
O00E Eu01 Eu02 33.5(4) . 4_575 ?
O00J Eu01 C24 136.9(11) . . ?
O00J Eu01 O004 129.2(9) . . ?
O00J Eu01 O00E 134.6(8) . . ?
O00J Eu01 Eu02 113.1(6) . 4_575 ?
C31 Eu02 Eu01 59.2(7) . 4_576 ?
O004 Eu02 C31 87.4(10) . . ?
O004 Eu02 O00C 103.9(9) . . ?
O004 Eu02 Eu01 126.7(8) . 4_576 ?
O005 Eu02 C31 152.5(11) . . ?
O005 Eu02 O004 70.9(8) . . ?
O005 Eu02 O007 75.0(10) . . ?
O005 Eu02 O00C 144.0(9) . . ?
O005 Eu02 O00D 140.4(8) . . ?
O005 Eu02 O00E 88.2(7) . 4_576 ?
O005 Eu02 O00F 142.1(11) . . ?
O005 Eu02 O00H 71.0(10) . . ?
O005 Eu02 Eu01 121.4(6) . 4_576 ?
O007 Eu02 C31 82.1(10) . . ?
O007 Eu02 O004 70.2(9) . . ?
O007 Eu02 O00C 69.9(8) . . ?
O007 Eu02 O00D 88.6(9) . . ?
O007 Eu02 Eu01 65.4(5) . 4_576 ?
O00C Eu02 C31 26.0(7) . . ?
O00C Eu02 Eu01 33.4(4) . 4_576 ?
O00D Eu02 C31 22.0(7) . . ?
O00D Eu02 O004 69.7(8) . . ?
O00D Eu02 O00C 47.7(7) . . ?
O00D Eu02 Eu01 81.0(6) . 4_576 ?
O00E Eu02 C31 98.8(9) 4_576 . ?
O00E Eu02 O004 139.7(9) 4_576 . ?
O00E Eu02 O007 71.3(9) 4_576 . ?
O00E Eu02 O00C 73.1(8) 4_576 . ?
O00E Eu02 O00D 120.7(9) 4_576 . ?
O00E Eu02 O00F 76.6(7) 4_576 . ?
O00E Eu02 O00H 77.1(10) 4_576 . ?
O00E Eu02 Eu01 39.7(6) 4_576 4_576 ?
O00F Eu02 C31 65.1(11) . . ?
O00F Eu02 O004 139.5(8) . . ?
O00F Eu02 O007 129.3(10) . . ?
O00F Eu02 O00C 63.7(10) . . ?
O00F Eu02 O00D 75.3(9) . . ?
O00F Eu02 O00H 71.9(11) . . ?
O00F Eu02 Eu01 64.7(7) . 4_576 ?
O00H Eu02 C31 136.4(11) . . ?
O00H Eu02 O004 123.8(10) . . ?
O00H Eu02 O007 133.7(9) . . ?
O00H Eu02 O00C 130.8(9) . . ?
O00H Eu02 O00D 137.2(10) . . ?
O00H Eu02 Eu01 108.1(7) . 4_576 ?
O00I Eu02 C31 92.0(11) . . ?
O00I Eu02 O004 71.4(11) . . ?
O00I Eu02 O005 96.4(10) . . ?
O00I Eu02 O007 141.4(10) . . ?
O00I Eu02 O00C 116.1(9) . . ?
O00I Eu02 O00D 74.2(11) . . ?
O00I Eu02 O00E 147.1(11) . 4_576 ?
O00I Eu02 O00F 80.1(9) . . ?
O00I Eu02 O00H 73.7(12) . . ?
O00I Eu02 Eu01 141.1(7) . 4_576 ?
N1 Cu1 N1 180(4) . 3_656 ?
N2 Cu1 N1 80(10) 1_545 . ?
N2 Cu1 N1 100(10) 3_666 . ?
N2 Cu1 N1 100(10) 1_545 3_656 ?
N2 Cu1 N1 80(10) 3_666 3_656 ?
N2 Cu1 N2 180(10) 3_666 1_545 ?
N4 Cu2 N3 80(6) 4_576 4_576 ?
N4 Cu2 C28 159(7) 4_576 . ?
C28 Cu2 N3 109(4) . 4_576 ?
C34 Cu3 C35 38.0(9) 3_666 3_666 ?
C34 Cu3 C35 72.4(13) 3_666 . ?
C34 Cu3 N6 106.5(10) 3_666 . ?
C34 Cu3 NC34 0.0 3_666 3_666 ?
C35 Cu3 C35 34.6(9) 3_666 . ?
N6 Cu3 C35 36.4(6) . . ?
N6 Cu3 C35 70.3(11) . 3_666 ?
NC34 Cu3 C35 72.4(13) 3_666 . ?
NC34 Cu3 C35 38.0(9) 3_666 3_666 ?
NC34 Cu3 N6 106.5(10) 3_666 . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 C2 C3 N1 178(5) 1_545 . . . ?
C1 C2 C6 C5 -178(5) 1_545 . . . ?
C2 C3 N1 C4 0.0 . . . . ?
C2 C3 N1 Cu1 -173(4) . . . . ?
C3 C2 C6 C5 0.0 . . . . ?
C3 N1 C4 C5 0.0 . . . . ?
C3 N1 C4 C7 161(4) . . . 1_545 ?
N1 C4 C5 C6 0.0 . . . . ?
C4 C5 C6 C2 0.0 . . . . ?
C4 C7 C8 C9 -172(10) 1_565 . . . ?
C4 C7 N2 C11 172(10) 1_565 . . . ?
C4 C7 N2 Cu1 -13(10) 1_565 . . 1_565 ?
C6 C2 C3 N1 0.0 . . . . ?
C12 C10 C11 N2 -178(4) . . . . ?
C7 C4 C5 C6 -160(5) 1_545 . . . ?
C7 C8 C9 C10 0.0 . . . . ?
C8 C7 N2 C11 0.0 . . . . ?
C8 C7 N2 Cu1 175(2) . . . 1_565 ?
C8 C9 C10 C12 178(4) . . . . ?
C8 C9 C10 C11 0.0 . . . . ?
C9 C10 C11 N2 0.0 . . . . ?
C10 C12 O00B Eu01 138(3) . . . 4_576 ?
C10 C12 O00F Eu02 -168(4) . . . . ?
C10 C11 N2 C7 0.0 . . . . ?
C10 C11 N2 Cu1 -174(3) . . . 1_565 ?
N2 C7 C8 C9 0.0 . . . . ?
C13 C14 C15 N3 179(3) . . . . ?
C13 C14 C18 C17 -179(3) . . . . ?
C14 C13 O005 Eu02 170(3) . . . . ?
C14 C13 O008 Eu01 103(4) . . . . ?
C14 C15 N3 C16 0.0 . . . . ?
C14 C15 N3 Cu2 147(3) . . . 4_575 ?
C15 C14 C18 C17 0.0 . . . . ?
C15 N3 C16 C17 0.0 . . . . ?
C15 N3 C16 C19 -174(3) . . . . ?
N3 C16 C17 C18 0.0 . . . . ?
N3 C16 C19 N4 -11(3) . . . . ?
N3 C16 C19 C23 162.5(18) . . . . ?
C16 C17 C18 C14 0.0 . . . . ?
C16 C19 N4 C21 173(3) . . . . ?
C16 C19 N4 Cu2 -20(3) . . . 4_575 ?
C16 C19 C23 C22 -173(3) . . . . ?
C17 C16 C19 N4 175.6(16) . . . . ?
C17 C16 C19 C23 -11(3) . . . . ?
C18 C14 C15 N3 0.0 . . . . ?
C24 C20 C22 C23 177(4) 2_755 . . . ?
C19 C16 C17 C18 174(3) . . . . ?
C19 N4 C21 C20 0.0 . . . . ?
N4 C19 C23 C22 0.0 . . . . ?
N4 C21 C20 C24 -177(3) . . . 2_755 ?
N4 C21 C20 C22 0.0 . . . . ?
C21 C20 C22 C23 0.0 . . . . ?
C20 C24 O006 Eu01 172(7) 2_745 . . . ?
C20 C24 O00E Eu01 -174(7) 2_745 . . . ?
C20 C24 O00E Eu02 -38(13) 2_745 . . 4_575 ?
C20 C22 C23 C19 0.0 . . . . ?
C23 C19 N4 C21 0.0 . . . . ?
C23 C19 N4 Cu2 167(2) . . . 4_575 ?
C25 C26 C27 C28 -174(3) . . . . ?
C25 C26 C30 N5 173(3) . . . . ?
C26 C25 O007 Eu02 -140(3) . . . . ?
C26 C27 C28 C29 0.0 . . . . ?
C26 C27 C28 Cu2 165(3) . . . . ?
C27 C26 C30 N5 0.0 . . . . ?
C27 C28 C29 C29 -178(6) . . . 3_766 ?
C27 C28 C29 N5 0.0 . . . . ?
C28 C29 N5 C30 0.0 . . . . ?
C29 C29 N5 C30 178(6) 3_766 . . . ?
C29 N5 C30 C26 0.0 . . . . ?
C30 C26 C27 C28 0.0 . . . . ?
C31 C32 C33 C34 -178(3) . . . . ?
C31 C32 C36 N6 178(3) . . . . ?
C32 C31 O00C Eu01 -33(13) . . . 4_576 ?
C32 C31 O00C Eu02 -167(4) . . . . ?
C32 C31 O00D Eu02 164(3) . . . . ?
C32 C33 C34 C35 0.0 . . . . ?
C32 C33 C34 Cu3 -154(4) . . . 3_666 ?
C33 C32 C36 N6 0.0 . . . . ?
C33 C34 C35 C35 -174(6) . . . 3_666 ?
C33 C34 C35 N6 0.0 . . . . ?
C33 C34 C35 Cu3 35(6) . . . . ?
C33 C34 C35 Cu3 -164(2) . . . 3_666 ?
C34 C35 N6 C36 0.0 . . . . ?
C34 C35 N6 Cu3 169.1(19) . . . . ?
C35 C35 N6 C36 174(5) 3_666 . . . ?
C35 C35 N6 Cu3 -17(4) 3_666 . . . ?
C35 N6 C36 C32 0.0 . . . . ?
C35 N6 Cu3 C34 21(3) . . . 3_666 ?
C35 N6 Cu3 C35 9(2) . . . 3_666 ?
C35 N6 Cu3 NC34 21(3) . . . 3_666 ?
C36 C32 C33 C34 0.0 . . . . ?
C36 N6 Cu3 C34 -175(5) . . . 3_666 ?
C36 N6 Cu3 C35 173(4) . . . 3_666 ?
C36 N6 Cu3 C35 164(3) . . . . ?
C36 N6 Cu3 NC34 -175(5) . . . 3_666 ?
O005 C13 C14 C15 -165(3) . . . . ?
O005 C13 C14 C18 13(6) . . . . ?
O005 C13 O008 Eu01 -83(5) . . . . ?
O006 C24 O00E Eu01 16(4) . . . . ?
O006 C24 O00E Eu02 152(7) . . . 4_575 ?
O007 C25 C26 C27 -170(3) . . . . ?
O007 C25 C26 C30 16(5) . . . . ?
O008 C13 C14 C15 9(5) . . . . ?
O008 C13 C14 C18 -173(3) . . . . ?
O008 C13 O005 Eu02 -3(7) . . . . ?
O009 C25 C26 C27 3(5) 4_576 . . . ?
O009 C25 C26 C30 -170(3) 4_576 . . . ?
O009 C25 O007 Eu02 48(7) 4_576 . . . ?
O00B C12 C10 C9 17(6) . . . . ?
O00B C12 C10 C11 -165(3) . . . . ?
O00B C12 O00F Eu02 4(8) . . . . ?
O00C C31 C32 C33 -17(5) . . . . ?
O00C C31 C32 C36 165(3) . . . . ?
O00C C31 O00D Eu02 -15(5) . . . . ?
O00D C31 C32 C33 164(4) . . . . ?
O00D C31 C32 C36 -15(5) . . . . ?
O00D C31 O00C Eu01 146(9) . . . 4_576 ?
O00D C31 O00C Eu02 13(4) . . . . ?
O00E C24 O006 Eu01 -18(5) . . . . ?
O00F C12 C10 C9 -171(3) . . . . ?
O00F C12 C10 C11 7(6) . . . . ?
O00F C12 O00B Eu01 -34(6) . . . 4_576 ?
Eu01 C24 O00E Eu02 136(9) . . . 4_575 ?
Eu02 C31 C32 C33 -136(8) . . . . ?
Eu02 C31 C32 C36 46(10) . . . . ?
Eu02 C31 O00C Eu01 134(11) . . . 4_576 ?
Cu1 N1 C4 C5 175(3) . . . . ?
Cu1 N1 C4 C7 -24(4) . . . 1_545 ?
Cu2 N3 C16 C17 -158(2) 4_575 . . . ?
Cu2 N3 C16 C19 29(3) 4_575 . . . ?
Cu2 N4 C21 C20 -165(3) 4_575 . . . ?
Cu2 C28 C29 C29 20(5) . . . 3_766 ?
Cu2 C28 C29 N5 -162(3) . . . . ?
Cu3 C34 C35 C35 -10(4) 3_666 . . 3_666 ?
Cu3 C34 C35 N6 164(2) 3_666 . . . ?
Cu3 C34 C35 Cu3 -161(6) 3_666 . . . ?
Cu3 C35 N6 C36 -169.1(19) . . . . ?
Cu3 C35 N6 C36 42(5) 3_666 . . . ?
Cu3 C35 N6 Cu3 -149(5) 3_666 . . . ?
Cu3 N6 C36 C32 -162(3) . . . . ?

_shelx_SHELXL_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'
