# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_s2120lm
_database_code_depnum_ccdc_archive 'CCDC 1056862'
_audit_update_record             
;
2015-03-30 deposited with the CCDC.
2015-09-23 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 'compound 7' 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C64 H72 Au4 Fe4 N4 O4, 2.5(C H2 Cl2)'
_chemical_absolute_configuration ad
_chemical_formula_sum            'C66.50 H77 Au4 Cl5 Fe4 N4 O4'
_chemical_formula_weight         2184.84

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           tetragonal
_symmetry_space_group_name_H-M   'P 41 21 2'
_symmetry_space_group_name_Hall  'P 4abw 2nw'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z+1/2'
'-y+1/2, x+1/2, z+1/4'
'y+1/2, -x+1/2, z+3/4'
'-x+1/2, y+1/2, -z+1/4'
'x+1/2, -y+1/2, -z+3/4'
'y, x, -z'
'-y, -x, -z+1/2'

_cell_length_a                   19.7785(10)
_cell_length_b                   19.7785(10)
_cell_length_c                   35.613(2)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     13931.4(14)
_cell_formula_units_Z            8
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    15923
_cell_measurement_theta_min      1.46
_cell_measurement_theta_max      28.36

_exptl_crystal_description       needle
_exptl_crystal_colour            orange
_exptl_crystal_size_max          0.43
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.083
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             8328
_exptl_absorpt_coefficient_mu    9.439
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.0488
_exptl_absorpt_correction_T_max  0.5423
_exptl_absorpt_process_details   'Blessing, 1995'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  Triumph
_diffrn_measurement_device_type  'Bruker Kappa APEXII Duo'
_diffrn_measurement_method       'Omega + Phi Scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        0
_diffrn_reflns_number            350477
_diffrn_reflns_av_R_equivalents  0.0524
_diffrn_reflns_av_sigmaI/netI    0.0274
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_l_min       -47
_diffrn_reflns_limit_l_max       47
_diffrn_reflns_theta_min         1.46
_diffrn_reflns_theta_max         28.36
_reflns_number_total             17390
_reflns_number_gt                15923
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEXII Software Suite, 2008'
_computing_cell_refinement       'Bruker APEXII Software Suite, 2008'
_computing_data_reduction        'Bruker APEXII Software Suite, 2008'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'SHELXTL-plus, XP (Sheldrick, 1991)'
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0271P)²+32.7854P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   -0.012(4)
_refine_ls_number_reflns         17390
_refine_ls_number_parameters     900
_refine_ls_number_restraints     171
_refine_ls_R_factor_all          0.0316
_refine_ls_R_factor_gt           0.0244
_refine_ls_wR_factor_ref         0.0561
_refine_ls_wR_factor_gt          0.0538
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_restrained_S_all      1.057
_refine_ls_shift/su_max          0.008
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au -0.060650(9) 0.561145(9) 0.899913(5) 0.01554(4) Uani 1 1 d . . .
Au2 Au -0.022778(9) 0.649192(9) 0.959476(5) 0.01635(4) Uani 1 1 d . . .
Au3 Au 0.093377(10) 0.556574(10) 1.081099(5) 0.01845(4) Uani 1 1 d . . .
Au4 Au 0.091247(10) 0.644058(10) 1.017691(5) 0.01857(4) Uani 1 1 d . . .
Fe1 Fe -0.14971(4) 0.42754(3) 0.941026(19) 0.01798(14) Uani 1 1 d . . .
Fe2 Fe -0.00346(3) 0.81473(3) 0.91523(2) 0.01735(14) Uani 1 1 d . . .
Fe3 Fe 0.14296(4) 0.39636(4) 1.04402(2) 0.02615(17) Uani 1 1 d . . .
Fe4 Fe 0.09940(4) 0.81504(4) 1.05739(2) 0.02238(16) Uani 1 1 d . . .
O1 O -0.11092(18) 0.50135(17) 1.03194(9) 0.0216(8) Uani 1 1 d . . .
O2 O -0.06586(19) 0.74021(16) 0.83306(9) 0.0214(7) Uani 1 1 d . . .
O3 O 0.1309(2) 0.47160(19) 0.95036(10) 0.0294(9) Uani 1 1 d . . .
O4 O 0.12723(19) 0.73588(19) 1.14496(10) 0.0260(8) Uani 1 1 d . . .
N1 N -0.0697(2) 0.5870(2) 0.99852(11) 0.0179(8) Uani 1 1 d . . .
N2 N -0.0746(2) 0.6425(2) 0.86391(11) 0.0175(8) Uani 1 1 d . . .
N3 N 0.1246(2) 0.5683(2) 0.98245(11) 0.0229(9) Uani 1 1 d . . .
N4 N 0.1192(2) 0.6354(2) 1.11623(11) 0.0191(9) Uani 1 1 d . . .
C1 C -0.0582(2) 0.4782(2) 0.93180(13) 0.0182(9) Uani 1 1 d . . .
C2 C -0.0732(2) 0.4712(2) 0.97123(12) 0.0168(9) Uani 1 1 d . . .
C3 C -0.0807(2) 0.4006(2) 0.97979(14) 0.0203(10) Uani 1 1 d . . .
H3 H -0.0914 0.3821 1.0037 0.024 Uiso 1 1 calc R . .
C4 C -0.0692(3) 0.3632(3) 0.94654(15) 0.0241(11) Uani 1 1 d . . .
H4 H -0.0704 0.3154 0.9441 0.029 Uiso 1 1 calc R . .
C5 C -0.0556(3) 0.4107(3) 0.91756(14) 0.0221(10) Uani 1 1 d . . .
H5 H -0.0461 0.3991 0.8922 0.026 Uiso 1 1 calc R . .
C6 C -0.2278(3) 0.4908(3) 0.92783(15) 0.0253(11) Uani 1 1 d . . .
H6 H -0.2251 0.5385 0.9253 0.030 Uiso 1 1 calc R . .
C7 C -0.2417(3) 0.4555(3) 0.96140(17) 0.0307(13) Uani 1 1 d . . .
H7 H -0.2500 0.4754 0.9852 0.037 Uiso 1 1 calc R . .
C8 C -0.2411(3) 0.3850(3) 0.95351(17) 0.0315(13) Uani 1 1 d . . .
H8 H -0.2488 0.3497 0.9711 0.038 Uiso 1 1 calc R . .
C9 C -0.2272(3) 0.3771(3) 0.91482(16) 0.0311(13) Uani 1 1 d . . .
H9 H -0.2242 0.3353 0.9018 0.037 Uiso 1 1 calc R . .
C10 C -0.2183(3) 0.4431(3) 0.89848(16) 0.0285(12) Uani 1 1 d . . .
H10 H -0.2081 0.4529 0.8730 0.034 Uiso 1 1 calc R . .
C11 C -0.0836(2) 0.5236(3) 0.99927(13) 0.0191(10) Uani 1 1 d . . .
C12 C -0.1073(3) 0.5570(3) 1.05880(14) 0.0261(11) Uani 1 1 d . . .
H12A H -0.0705 0.5497 1.0772 0.031 Uiso 1 1 calc R . .
H12B H -0.1506 0.5622 1.0725 0.031 Uiso 1 1 calc R . .
C13 C -0.0929(3) 0.6190(3) 1.03400(14) 0.0251(11) Uani 1 1 d . . .
H13 H -0.0546 0.6452 1.0452 0.030 Uiso 1 1 calc R . .
C14 C -0.1522(3) 0.6667(3) 1.02729(16) 0.0330(13) Uani 1 1 d . . .
H14 H -0.1371 0.7014 1.0087 0.040 Uiso 1 1 calc R . .
C15 C -0.2142(3) 0.6296(3) 1.0100(2) 0.0443(17) Uani 1 1 d . . .
H15A H -0.2315 0.5963 1.0280 0.066 Uiso 1 1 calc R . .
H15B H -0.2004 0.6066 0.9869 0.066 Uiso 1 1 calc R . .
H15C H -0.2497 0.6626 1.0043 0.066 Uiso 1 1 calc R . .
C16 C -0.1712(4) 0.7039(3) 1.06342(19) 0.0472(18) Uani 1 1 d . . .
H16A H -0.2045 0.7392 1.0577 0.071 Uiso 1 1 calc R . .
H16B H -0.1307 0.7247 1.0743 0.071 Uiso 1 1 calc R . .
H16C H -0.1907 0.6718 1.0814 0.071 Uiso 1 1 calc R . .
C17 C 0.0222(2) 0.7137(2) 0.92421(13) 0.0183(10) Uani 1 1 d . . .
C18 C 0.0074(3) 0.7281(3) 0.88556(14) 0.0206(10) Uani 1 1 d . . .
C19 C 0.0524(3) 0.7802(2) 0.87186(14) 0.0202(10) Uani 1 1 d . . .
H19 H 0.0530 0.7991 0.8473 0.024 Uiso 1 1 calc R . .
C20 C 0.0956(3) 0.7976(2) 0.90212(15) 0.0219(11) Uani 1 1 d . . .
H20 H 0.1308 0.8303 0.9014 0.026 Uiso 1 1 calc R . .
C21 C 0.0772(2) 0.7582(2) 0.93342(15) 0.0198(10) Uani 1 1 d . . .
H21 H 0.0984 0.7606 0.9573 0.024 Uiso 1 1 calc R . .
C22 C -0.0843(3) 0.8369(3) 0.94901(14) 0.0219(11) Uani 1 1 d . . .
H22 H -0.1046 0.8075 0.9668 0.026 Uiso 1 1 calc R . .
C23 C -0.1025(3) 0.8425(3) 0.91047(15) 0.0264(12) Uani 1 1 d . . .
H23 H -0.1366 0.8174 0.8979 0.032 Uiso 1 1 calc R . .
C24 C -0.0598(3) 0.8927(3) 0.89423(16) 0.0280(12) Uani 1 1 d . . .
H24 H -0.0610 0.9074 0.8688 0.034 Uiso 1 1 calc R . .
C25 C -0.0154(3) 0.9170(3) 0.92228(16) 0.0258(12) Uani 1 1 d . . .
H25 H 0.0187 0.9504 0.9190 0.031 Uiso 1 1 calc R . .
C26 C -0.0310(3) 0.8824(3) 0.95631(16) 0.0267(12) Uani 1 1 d . . .
H26 H -0.0093 0.8888 0.9798 0.032 Uiso 1 1 calc R . .
C27 C -0.0459(2) 0.7008(3) 0.86214(13) 0.0190(10) Uani 1 1 d . . .
C28 C -0.1189(3) 0.7045(3) 0.81311(13) 0.0220(11) Uani 1 1 d . . .
H28A H -0.1063 0.6974 0.7865 0.026 Uiso 1 1 calc R . .
H28B H -0.1619 0.7299 0.8141 0.026 Uiso 1 1 calc R . .
C29 C -0.1253(2) 0.6367(2) 0.83373(13) 0.0192(10) Uani 1 1 d . . .
H29 H -0.1111 0.5997 0.8163 0.023 Uiso 1 1 calc R . .
C30 C -0.1957(3) 0.6200(3) 0.84914(14) 0.0205(10) Uani 1 1 d . . .
H30 H -0.1928 0.5743 0.8610 0.025 Uiso 1 1 calc R . .
C31 C -0.2462(3) 0.6148(3) 0.81673(15) 0.0286(12) Uani 1 1 d . . .
H31A H -0.2565 0.6602 0.8073 0.043 Uiso 1 1 calc R . .
H31B H -0.2878 0.5933 0.8256 0.043 Uiso 1 1 calc R . .
H31C H -0.2266 0.5876 0.7965 0.043 Uiso 1 1 calc R . .
C32 C -0.2191(3) 0.6689(3) 0.87935(14) 0.0255(12) Uani 1 1 d . . .
H32A H -0.1842 0.6727 0.8988 0.038 Uiso 1 1 calc R . .
H32B H -0.2611 0.6521 0.8906 0.038 Uiso 1 1 calc R . .
H32C H -0.2272 0.7134 0.8681 0.038 Uiso 1 1 calc R . .
C33 C 0.0730(2) 0.4748(3) 1.05072(14) 0.0211(10) Uani 1 1 d . . .
C34 C 0.0870(2) 0.4599(3) 1.01141(13) 0.0207(10) Uani 1 1 d . . .
C35 C 0.0708(3) 0.3906(3) 1.00385(14) 0.0224(11) Uani 1 1 d . . .
H35 H 0.0754 0.3681 0.9804 0.027 Uiso 1 1 calc R . .
C36 C 0.0464(3) 0.3618(3) 1.03801(14) 0.0258(11) Uani 1 1 d . . .
H36 H 0.0318 0.3165 1.0414 0.031 Uiso 1 1 calc R . .
C37 C 0.0480(2) 0.4126(3) 1.06588(13) 0.0209(10) Uani 1 1 d . . .
H37 H 0.0343 0.4064 1.0912 0.025 Uiso 1 1 calc R . .
C38 C 0.2351(3) 0.4299(5) 1.0620(2) 0.051(2) Uani 1 1 d . . .
H38 H 0.2471 0.4754 1.0673 0.061 Uiso 1 1 calc R . .
C39 C 0.2074(3) 0.3812(4) 1.08793(18) 0.0460(18) Uani 1 1 d . . .
H39 H 0.1974 0.3885 1.1137 0.055 Uiso 1 1 calc R . .
C40 C 0.1979(4) 0.3200(4) 1.06752(19) 0.0494(19) Uani 1 1 d . . .
H40 H 0.1804 0.2791 1.0775 0.059 Uiso 1 1 calc R . .
C41 C 0.2185(4) 0.3301(5) 1.0304(2) 0.061(2) Uani 1 1 d . . .
H41 H 0.2174 0.2971 1.0110 0.073 Uiso 1 1 calc R . .
C42 C 0.2408(3) 0.3956(6) 1.0266(2) 0.067(3) Uani 1 1 d . . .
H42 H 0.2573 0.4152 1.0040 0.081 Uiso 1 1 calc R . .
C43 C 0.1140(3) 0.5041(3) 0.98278(13) 0.0218(10) Uani 1 1 d . . .
C44 C 0.1440(3) 0.5243(3) 0.92264(15) 0.0312(12) Uani 1 1 d . . .
H44A H 0.1045 0.5311 0.9060 0.037 Uiso 1 1 calc R . .
H44B H 0.1840 0.5131 0.9071 0.037 Uiso 1 1 calc R . .
C45 C 0.1570(3) 0.5866(3) 0.94647(14) 0.0287(12) Uani 1 1 d . C .
H45 H 0.1328 0.6261 0.9353 0.034 Uiso 1 1 calc R . .
C46 C 0.2311(4) 0.6041(3) 0.95115(17) 0.0407(16) Uani 1 1 d . . .
H46 H 0.2313 0.6436 0.9672 0.049 Uiso 0.50 1 d P A 1
H46A H 0.2529 0.5629 0.9580 0.049 Uiso 0.50 1 d P B 2
C47 C 0.2627(4) 0.6272(4) 0.91353(19) 0.0520(19) Uani 1 1 d . C .
H47A H 0.2467 0.6728 0.9074 0.078 Uiso 1 1 calc R . .
H47B H 0.2494 0.5959 0.8935 0.078 Uiso 1 1 calc R . .
H47C H 0.3121 0.6276 0.9158 0.078 Uiso 1 1 calc R . .
C48 C 0.2723(6) 0.5571(8) 0.9710(4) 0.048(4) Uani 0.50 1 d P C 1
H48A H 0.3160 0.5780 0.9768 0.072 Uiso 0.50 1 calc PR C 1
H48B H 0.2795 0.5168 0.9555 0.072 Uiso 0.50 1 calc PR C 1
H48C H 0.2497 0.5442 0.9945 0.072 Uiso 0.50 1 calc PR C 1
C48A C 0.2518(8) 0.6523(8) 0.9788(4) 0.052(3) Uani 0.50 1 d PU C 2
H48D H 0.2369 0.6373 1.0036 0.078 Uiso 0.50 1 calc PR C 2
H48E H 0.2315 0.6963 0.9731 0.078 Uiso 0.50 1 calc PR C 2
H48F H 0.3012 0.6564 0.9785 0.078 Uiso 0.50 1 calc PR C 2
C49 C 0.0556(2) 0.7199(2) 1.04863(13) 0.0180(9) Uani 1 1 d . . .
C50 C 0.0648(3) 0.7350(2) 1.08774(14) 0.0202(10) Uani 1 1 d . . .
C51 C 0.0289(3) 0.7969(3) 1.09665(16) 0.0247(11) Uani 1 1 d . . .
H51 H 0.0275 0.8186 1.1204 0.030 Uiso 1 1 calc R . .
C52 C -0.0031(3) 0.8185(3) 1.06396(16) 0.0250(11) Uani 1 1 d . . .
H52 H -0.0313 0.8572 1.0616 0.030 Uiso 1 1 calc R . .
C53 C 0.0138(2) 0.7729(2) 1.03478(15) 0.0208(10) Uani 1 1 d . . .
H53 H -0.0008 0.7771 1.0095 0.025 Uiso 1 1 calc R . .
C54 C 0.1886(3) 0.8171(4) 1.0286(2) 0.0482(17) Uani 1 1 d U . .
H54 H 0.2061 0.7816 1.0135 0.058 Uiso 1 1 calc R . .
C55 C 0.2003(4) 0.8265(4) 1.0673(2) 0.058(2) Uani 1 1 d U . .
H55 H 0.2276 0.7985 1.0828 0.070 Uiso 1 1 calc R . .
C56 C 0.1659(4) 0.8829(4) 1.0790(2) 0.059(2) Uani 1 1 d U . .
H56 H 0.1646 0.9002 1.1038 0.071 Uiso 1 1 calc R . .
C57 C 0.1330(4) 0.9103(3) 1.04770(19) 0.0464(17) Uani 1 1 d . . .
H57 H 0.1061 0.9500 1.0477 0.056 Uiso 1 1 calc R . .
C58 C 0.1463(3) 0.8697(3) 1.01637(18) 0.0420(16) Uani 1 1 d . . .
H58 H 0.1299 0.8764 0.9916 0.050 Uiso 1 1 calc R . .
C59 C 0.1051(3) 0.6987(3) 1.11576(13) 0.0207(10) Uani 1 1 d . . .
C60 C 0.1659(3) 0.6905(3) 1.16946(15) 0.0268(12) Uani 1 1 d . . .
H60A H 0.1456 0.6885 1.1948 0.032 Uiso 1 1 calc R . .
H60B H 0.2134 0.7058 1.1717 0.032 Uiso 1 1 calc R . .
C61 C 0.1619(3) 0.6209(3) 1.14974(13) 0.0233(11) Uani 1 1 d . . .
H61 H 0.1367 0.5891 1.1665 0.028 Uiso 1 1 calc R . .
C62 C 0.2292(3) 0.5885(3) 1.13929(17) 0.0312(13) Uani 1 1 d . . .
H62 H 0.2193 0.5439 1.1272 0.037 Uiso 1 1 calc R . .
C63 C 0.2688(3) 0.6309(4) 1.1112(2) 0.0468(18) Uani 1 1 d . . .
H63A H 0.2438 0.6332 1.0875 0.070 Uiso 1 1 calc R . .
H63B H 0.3131 0.6101 1.1068 0.070 Uiso 1 1 calc R . .
H63C H 0.2750 0.6766 1.1212 0.070 Uiso 1 1 calc R . .
C64 C 0.2698(3) 0.5748(3) 1.17459(18) 0.0383(15) Uani 1 1 d . . .
H64A H 0.3080 0.5452 1.1686 0.057 Uiso 1 1 calc R . .
H64B H 0.2409 0.5527 1.1933 0.057 Uiso 1 1 calc R . .
H64C H 0.2868 0.6176 1.1847 0.057 Uiso 1 1 calc R . .
C1X C 0.4517(9) 0.5813(11) 1.0069(5) 0.095(6) Uani 0.50 1 d PDU D 2
H1X1 H 0.4689 0.5355 1.0010 0.114 Uiso 0.50 1 calc PR D 2
H1X2 H 0.4830 0.6017 1.0254 0.114 Uiso 0.50 1 calc PR D 2
Cl1X Cl 0.4542(4) 0.6300(3) 0.96586(15) 0.0995(18) Uani 0.50 1 d PDU D 2
Cl2X Cl 0.3722(4) 0.5730(4) 1.0280(2) 0.120(2) Uani 0.50 1 d PDU D 2
Cl1Y Cl 0.5450(7) 0.6081(9) 1.1002(3) 0.0896(12) Uani 0.50 1 d PDU E 2
Cl2Y Cl 0.4550(3) 0.6359(3) 1.16053(17) 0.0802(14) Uani 0.50 1 d PDU E 2
C1Y C 0.4618(8) 0.6145(11) 1.1143(4) 0.078(4) Uani 0.50 1 d PDU E 2
H1Y1 H 0.4387 0.6490 1.0988 0.094 Uiso 0.50 1 calc PR E 2
H1Y2 H 0.4388 0.5707 1.1100 0.094 Uiso 0.50 1 calc PR E 2
C1Z C 0.434(2) 0.6602(11) 1.2282(5) 0.078(4) Uani 0.25 1 d PDU F 1
H1Z1 H 0.3957 0.6906 1.2335 0.094 Uiso 0.25 1 calc PR F 1
H1Z2 H 0.4746 0.6801 1.2405 0.094 Uiso 0.25 1 calc PR F 1
Cl1Z Cl 0.4178(4) 0.5822(4) 1.2500 0.097(2) Uani 0.50 2 d SPDU F 1
Cl2Z Cl 0.4479(4) 0.6611(4) 1.1811(2) 0.0523(18) Uani 0.25 1 d PDU F 1
C1U C 0.3976(8) 0.3981(7) 0.9268(5) 0.061(4) Uani 0.50 1 d PDU G 3
H1U1 H 0.3623 0.3795 0.9101 0.073 Uiso 0.50 1 calc PR G 3
H1U2 H 0.4055 0.3653 0.9473 0.073 Uiso 0.50 1 calc PR G 3
Cl1U Cl 0.3709(4) 0.4726(4) 0.9452(2) 0.121(2) Uani 0.50 1 d PDU G 3
Cl2U Cl 0.4726(6) 0.4101(6) 0.9014(3) 0.170(4) Uani 0.50 1 d PDU G 3
C1T C 0.399(3) 0.4183(14) 0.9522(8) 0.115(8) Uani 0.25 1 d PDU H 4
H1T1 H 0.3544 0.4009 0.9446 0.138 Uiso 0.25 1 calc PR H 4
H1T2 H 0.4267 0.3805 0.9621 0.138 Uiso 0.25 1 calc PR H 4
Cl1T Cl 0.3917(8) 0.4827(9) 0.9849(4) 0.125(5) Uani 0.25 1 d PDU H 4
Cl2T Cl 0.4405(5) 0.4588(6) 0.9141(3) 0.080(3) Uani 0.25 1 d PDU H 4
C1V C 0.4736(11) 0.5877(19) 1.0701(12) 0.115(8) Uani 0.25 1 d PDU I 5
H1V1 H 0.4506 0.6308 1.0761 0.138 Uiso 0.25 1 calc PR I 5
H1V2 H 0.4664 0.5779 1.0431 0.138 Uiso 0.25 1 calc PR I 5
Cl1V Cl 0.4397(6) 0.5240(5) 1.0966(3) 0.081(3) Uani 0.25 1 d PDU I 5
Cl2V Cl 0.5596(7) 0.5955(7) 1.0789(4) 0.0896(12) Uani 0.25 1 d PDU I 5
C1W C 0.5145(12) 0.6018(16) 1.0519(5) 0.050(6) Uani 0.25 1 d PDU J 6
H1W1 H 0.4972 0.5554 1.0477 0.060 Uiso 0.25 1 calc PR J 6
H1W2 H 0.4759 0.6334 1.0493 0.060 Uiso 0.25 1 calc PR J 6
Cl1W Cl 0.5730(6) 0.6199(6) 1.0181(3) 0.096(3) Uani 0.25 1 d PDU J 6
Cl2W Cl 0.5471(14) 0.6077(18) 1.0976(6) 0.0896(12) Uani 0.25 1 d PDU J 6


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C1 1.996(5) . ?
Au1 N2 2.076(4) . ?
Au1 Au2 2.8449(3) . ?
Au2 C17 2.000(5) . ?
Au2 N1 2.075(4) . ?
Au2 Au4 3.0651(3) . ?
Au3 C33 1.986(5) . ?
Au3 N4 2.064(4) . ?
Au3 Au4 2.8452(3) . ?
Au4 C49 1.991(5) . ?
Au4 N3 2.064(4) . ?
Fe1 C3 2.014(5) . ?
Fe1 C7 2.035(6) . ?
Fe1 C6 2.042(5) . ?
Fe1 C8 2.043(6) . ?
Fe1 C4 2.047(5) . ?
Fe1 C2 2.047(5) . ?
Fe1 C9 2.053(6) . ?
Fe1 C10 2.057(5) . ?
Fe1 C5 2.068(5) . ?
Fe1 C1 2.094(5) . ?
Fe2 C19 2.018(5) . ?
Fe2 C18 2.024(5) . ?
Fe2 C23 2.041(5) . ?
Fe2 C20 2.042(5) . ?
Fe2 C24 2.045(5) . ?
Fe2 C22 2.049(5) . ?
Fe2 C25 2.052(5) . ?
Fe2 C21 2.054(5) . ?
Fe2 C26 2.056(5) . ?
Fe2 C17 2.086(5) . ?
Fe3 C35 2.024(5) . ?
Fe3 C42 2.031(7) . ?
Fe3 C34 2.037(5) . ?
Fe3 C36 2.039(6) . ?
Fe3 C40 2.040(6) . ?
Fe3 C39 2.040(6) . ?
Fe3 C38 2.042(7) . ?
Fe3 C41 2.046(6) . ?
Fe3 C37 2.059(5) . ?
Fe3 C33 2.093(5) . ?
Fe4 C51 2.007(5) . ?
Fe4 C57 2.027(6) . ?
Fe4 C56 2.030(8) . ?
Fe4 C50 2.036(5) . ?
Fe4 C54 2.040(6) . ?
Fe4 C58 2.040(6) . ?
Fe4 C55 2.040(7) . ?
Fe4 C52 2.042(5) . ?
Fe4 C53 2.052(5) . ?
Fe4 C49 2.094(5) . ?
O1 C11 1.356(6) . ?
O1 C12 1.460(6) . ?
O2 C27 1.355(6) . ?
O2 C28 1.451(6) . ?
O3 C43 1.363(6) . ?
O3 C44 1.460(6) . ?
O4 C59 1.347(6) . ?
O4 C60 1.467(6) . ?
N1 C11 1.284(6) . ?
N1 C13 1.486(6) . ?
N2 C27 1.287(6) . ?
N2 C29 1.474(6) . ?
N3 C43 1.286(7) . ?
N3 C45 1.478(6) . ?
N4 C59 1.283(7) . ?
N4 C61 1.490(6) . ?
C1 C5 1.429(7) . ?
C1 C2 1.442(6) . ?
C2 C3 1.437(7) . ?
C2 C11 1.454(7) . ?
C3 C4 1.414(7) . ?
C3 H3 0.9500 . ?
C4 C5 1.420(7) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 C7 1.412(8) . ?
C6 C10 1.420(8) . ?
C6 H6 0.9500 . ?
C7 C8 1.421(8) . ?
C7 H7 0.9500 . ?
C8 C9 1.414(8) . ?
C8 H8 0.9500 . ?
C9 C10 1.440(8) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C12 C13 1.538(7) . ?
C12 H12A 0.9900 . ?
C12 H12B 0.9900 . ?
C13 C14 1.524(8) . ?
C13 H13 1.0000 . ?
C14 C16 1.530(8) . ?
C14 C15 1.554(9) . ?
C14 H14 1.0000 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 C18 1.436(7) . ?
C17 C21 1.437(7) . ?
C18 C19 1.446(7) . ?
C18 C27 1.450(7) . ?
C19 C20 1.417(7) . ?
C19 H19 0.9500 . ?
C20 C21 1.408(7) . ?
C20 H20 0.9500 . ?
C21 H21 0.9500 . ?
C22 C26 1.409(8) . ?
C22 C23 1.423(7) . ?
C22 H22 0.9500 . ?
C23 C24 1.426(8) . ?
C23 H23 0.9500 . ?
C24 C25 1.415(8) . ?
C24 H24 0.9500 . ?
C25 C26 1.426(8) . ?
C25 H25 0.9500 . ?
C26 H26 0.9500 . ?
C28 C29 1.533(7) . ?
C28 H28A 0.9900 . ?
C28 H28B 0.9900 . ?
C29 C30 1.533(7) . ?
C29 H29 1.0000 . ?
C30 C32 1.518(7) . ?
C30 C31 1.530(7) . ?
C30 H30 1.0000 . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C33 C37 1.432(7) . ?
C33 C34 1.457(7) . ?
C34 C35 1.432(7) . ?
C34 C43 1.446(7) . ?
C35 C36 1.427(7) . ?
C35 H35 0.9500 . ?
C36 C37 1.413(7) . ?
C36 H36 0.9500 . ?
C37 H37 0.9500 . ?
C38 C42 1.437(11) . ?
C38 C39 1.442(11) . ?
C38 H38 0.9500 . ?
C39 C40 1.423(11) . ?
C39 H39 0.9500 . ?
C40 C41 1.399(10) . ?
C40 H40 0.9500 . ?
C41 C42 1.375(13) . ?
C41 H41 0.9500 . ?
C42 H42 0.9500 . ?
C44 C45 1.517(8) . ?
C44 H44A 0.9900 . ?
C44 H44B 0.9900 . ?
C45 C46 1.515(9) . ?
C45 H45 1.0000 . ?
C46 C48 1.424(15) . ?
C46 C48A 1.429(15) . ?
C46 C47 1.548(9) . ?
C46 H46 0.9681 . ?
C46 H46A 0.9531 . ?
C47 H47A 0.9800 . ?
C47 H47B 0.9800 . ?
C47 H47C 0.9800 . ?
C48 H46A 0.6134 . ?
C48 H48A 0.9800 . ?
C48 H48B 0.9800 . ?
C48 H48C 0.9800 . ?
C48A H46 0.6028 . ?
C48A H48D 0.9800 . ?
C48A H48E 0.9800 . ?
C48A H48F 0.9800 . ?
C49 C53 1.424(7) . ?
C49 C50 1.436(7) . ?
C50 C51 1.450(7) . ?
C50 C59 1.464(7) . ?
C51 C52 1.393(8) . ?
C51 H51 0.9500 . ?
C52 C53 1.416(7) . ?
C52 H52 0.9500 . ?
C53 H53 0.9500 . ?
C54 C58 1.404(10) . ?
C54 C55 1.411(11) . ?
C54 H54 0.9500 . ?
C55 C56 1.369(12) . ?
C55 H55 0.9500 . ?
C56 C57 1.399(11) . ?
C56 H56 0.9500 . ?
C57 C58 1.399(10) . ?
C57 H57 0.9500 . ?
C58 H58 0.9500 . ?
C60 C61 1.548(8) . ?
C60 H60A 0.9900 . ?
C60 H60B 0.9900 . ?
C61 C62 1.524(8) . ?
C61 H61 1.0000 . ?
C62 C64 1.516(8) . ?
C62 C63 1.522(8) . ?
C62 H62 1.0000 . ?
C63 H63A 0.9800 . ?
C63 H63B 0.9800 . ?
C63 H63C 0.9800 . ?
C64 H64A 0.9800 . ?
C64 H64B 0.9800 . ?
C64 H64C 0.9800 . ?
C1X Cl2X 1.749(15) . ?
C1X Cl1X 1.752(15) . ?
C1X H1X1 0.9900 . ?
C1X H1X2 0.9900 . ?
Cl1Y C1Y 1.724(16) . ?
Cl2Y C1Y 1.706(14) . ?
C1Y H1Y1 0.9900 . ?
C1Y H1Y2 0.9900 . ?
C1Z Cl2Z 1.700(18) . ?
C1Z Cl1Z 1.757(18) . ?
C1Z H1Z1 0.9900 . ?
C1Z H1Z2 0.9900 . ?
Cl1Z C1Z 1.757(18) 8_667 ?
C1U Cl1U 1.696(14) . ?
C1U Cl2U 1.755(14) . ?
C1U H1U1 0.9900 . ?
C1U H1U2 0.9900 . ?
C1T Cl1T 1.732(19) . ?
C1T Cl2T 1.773(19) . ?
C1T H1T1 0.9900 . ?
C1T H1T2 0.9900 . ?
C1V Cl1V 1.712(19) . ?
C1V Cl2V 1.735(19) . ?
C1V H1V1 0.9900 . ?
C1V H1V2 0.9900 . ?
C1W Cl1W 1.708(17) . ?
C1W Cl2W 1.758(18) . ?
C1W H1W1 0.9900 . ?
C1W H1W2 0.9900 . ?
Cl1W Cl1W 1.84(2) 7_557 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Au1 N2 172.65(18) . . ?
C1 Au1 Au2 94.17(14) . . ?
N2 Au1 Au2 91.22(11) . . ?
C17 Au2 N1 176.45(18) . . ?
C17 Au2 Au1 92.27(14) . . ?
N1 Au2 Au1 91.10(11) . . ?
C17 Au2 Au4 96.79(14) . . ?
N1 Au2 Au4 81.72(11) . . ?
Au1 Au2 Au4 132.672(8) . . ?
C33 Au3 N4 174.49(18) . . ?
C33 Au3 Au4 93.42(14) . . ?
N4 Au3 Au4 91.46(11) . . ?
C49 Au4 N3 175.99(18) . . ?
C49 Au4 Au3 91.40(14) . . ?
N3 Au4 Au3 92.07(11) . . ?
C49 Au4 Au2 95.11(14) . . ?
N3 Au4 Au2 81.25(12) . . ?
Au3 Au4 Au2 124.603(9) . . ?
C3 Fe1 C7 115.7(2) . . ?
C3 Fe1 C6 146.4(2) . . ?
C7 Fe1 C6 40.5(2) . . ?
C3 Fe1 C8 110.0(2) . . ?
C7 Fe1 C8 40.8(2) . . ?
C6 Fe1 C8 68.5(2) . . ?
C3 Fe1 C4 40.7(2) . . ?
C7 Fe1 C4 146.1(2) . . ?
C6 Fe1 C4 172.2(2) . . ?
C8 Fe1 C4 114.3(2) . . ?
C3 Fe1 C2 41.45(19) . . ?
C7 Fe1 C2 111.0(2) . . ?
C6 Fe1 C2 114.9(2) . . ?
C8 Fe1 C2 135.5(2) . . ?
C4 Fe1 C2 68.7(2) . . ?
C3 Fe1 C9 133.6(2) . . ?
C7 Fe1 C9 68.1(2) . . ?
C6 Fe1 C9 68.2(2) . . ?
C8 Fe1 C9 40.4(2) . . ?
C4 Fe1 C9 108.8(2) . . ?
C2 Fe1 C9 174.5(2) . . ?
C3 Fe1 C10 172.7(2) . . ?
C7 Fe1 C10 68.4(2) . . ?
C6 Fe1 C10 40.5(2) . . ?
C8 Fe1 C10 68.8(2) . . ?
C4 Fe1 C10 132.6(2) . . ?
C2 Fe1 C10 144.2(2) . . ?
C9 Fe1 C10 41.0(2) . . ?
C3 Fe1 C5 67.9(2) . . ?
C7 Fe1 C5 173.1(2) . . ?
C6 Fe1 C5 133.4(2) . . ?
C8 Fe1 C5 144.9(2) . . ?
C4 Fe1 C5 40.4(2) . . ?
C2 Fe1 C5 67.37(19) . . ?
C9 Fe1 C5 114.2(2) . . ?
C10 Fe1 C5 108.7(2) . . ?
C3 Fe1 C1 69.39(19) . . ?
C7 Fe1 C1 134.3(2) . . ?
C6 Fe1 C1 108.9(2) . . ?
C8 Fe1 C1 174.7(2) . . ?
C4 Fe1 C1 68.9(2) . . ?
C2 Fe1 C1 40.73(18) . . ?
C9 Fe1 C1 143.7(2) . . ?
C10 Fe1 C1 112.5(2) . . ?
C5 Fe1 C1 40.16(19) . . ?
C19 Fe2 C18 41.93(19) . . ?
C19 Fe2 C23 123.6(2) . . ?
C18 Fe2 C23 106.6(2) . . ?
C19 Fe2 C20 40.8(2) . . ?
C18 Fe2 C20 68.8(2) . . ?
C23 Fe2 C20 161.1(2) . . ?
C19 Fe2 C24 105.9(2) . . ?
C18 Fe2 C24 120.4(2) . . ?
C23 Fe2 C24 40.9(2) . . ?
C20 Fe2 C24 124.4(2) . . ?
C19 Fe2 C22 161.7(2) . . ?
C18 Fe2 C22 124.8(2) . . ?
C23 Fe2 C22 40.7(2) . . ?
C20 Fe2 C22 156.7(2) . . ?
C24 Fe2 C22 68.2(2) . . ?
C19 Fe2 C25 119.3(2) . . ?
C18 Fe2 C25 155.6(2) . . ?
C23 Fe2 C25 68.6(2) . . ?
C20 Fe2 C25 107.6(2) . . ?
C24 Fe2 C25 40.4(2) . . ?
C22 Fe2 C25 68.1(2) . . ?
C19 Fe2 C21 68.4(2) . . ?
C18 Fe2 C21 67.7(2) . . ?
C23 Fe2 C21 156.7(2) . . ?
C20 Fe2 C21 40.2(2) . . ?
C24 Fe2 C21 161.8(2) . . ?
C22 Fe2 C21 122.5(2) . . ?
C25 Fe2 C21 126.0(2) . . ?
C19 Fe2 C26 155.5(2) . . ?
C18 Fe2 C26 161.9(2) . . ?
C23 Fe2 C26 68.3(2) . . ?
C20 Fe2 C26 121.7(2) . . ?
C24 Fe2 C26 68.0(2) . . ?
C22 Fe2 C26 40.2(2) . . ?
C25 Fe2 C26 40.6(2) . . ?
C21 Fe2 C26 109.6(2) . . ?
C19 Fe2 C17 70.13(19) . . ?
C18 Fe2 C17 40.86(19) . . ?
C23 Fe2 C17 120.3(2) . . ?
C20 Fe2 C17 69.05(19) . . ?
C24 Fe2 C17 155.7(2) . . ?
C22 Fe2 C17 107.8(2) . . ?
C25 Fe2 C17 162.4(2) . . ?
C21 Fe2 C17 40.60(19) . . ?
C26 Fe2 C17 125.4(2) . . ?
C35 Fe3 C42 117.1(3) . . ?
C35 Fe3 C34 41.3(2) . . ?
C42 Fe3 C34 110.3(3) . . ?
C35 Fe3 C36 41.1(2) . . ?
C42 Fe3 C36 149.0(3) . . ?
C34 Fe3 C36 68.8(2) . . ?
C35 Fe3 C40 128.6(3) . . ?
C42 Fe3 C40 67.2(4) . . ?
C34 Fe3 C40 168.4(3) . . ?
C36 Fe3 C40 107.1(3) . . ?
C35 Fe3 C39 167.0(3) . . ?
C42 Fe3 C39 68.8(3) . . ?
C34 Fe3 C39 150.1(3) . . ?
C36 Fe3 C39 128.0(3) . . ?
C40 Fe3 C39 40.8(3) . . ?
C35 Fe3 C38 150.4(3) . . ?
C42 Fe3 C38 41.3(3) . . ?
C34 Fe3 C38 117.6(3) . . ?
C36 Fe3 C38 167.7(2) . . ?
C40 Fe3 C38 68.7(3) . . ?
C39 Fe3 C38 41.4(3) . . ?
C35 Fe3 C41 108.1(3) . . ?
C42 Fe3 C41 39.4(4) . . ?
C34 Fe3 C41 131.0(2) . . ?
C36 Fe3 C41 116.4(3) . . ?
C40 Fe3 C41 40.0(3) . . ?
C39 Fe3 C41 68.4(3) . . ?
C38 Fe3 C41 68.3(3) . . ?
C35 Fe3 C37 68.4(2) . . ?
C42 Fe3 C37 170.2(3) . . ?
C34 Fe3 C37 67.89(19) . . ?
C36 Fe3 C37 40.3(2) . . ?
C40 Fe3 C37 116.5(3) . . ?
C39 Fe3 C37 107.7(2) . . ?
C38 Fe3 C37 130.1(2) . . ?
C41 Fe3 C37 148.9(3) . . ?
C35 Fe3 C33 69.88(19) . . ?
C42 Fe3 C33 132.0(4) . . ?
C34 Fe3 C33 41.30(18) . . ?
C36 Fe3 C33 69.0(2) . . ?
C40 Fe3 C33 148.7(2) . . ?
C39 Fe3 C33 115.8(2) . . ?
C38 Fe3 C33 108.2(3) . . ?
C41 Fe3 C33 170.0(3) . . ?
C37 Fe3 C33 40.3(2) . . ?
C51 Fe4 C57 120.9(3) . . ?
C51 Fe4 C56 107.8(3) . . ?
C57 Fe4 C56 40.3(3) . . ?
C51 Fe4 C50 42.0(2) . . ?
C57 Fe4 C50 157.4(2) . . ?
C56 Fe4 C50 122.1(3) . . ?
C51 Fe4 C54 162.6(3) . . ?
C57 Fe4 C54 67.2(3) . . ?
C56 Fe4 C54 67.4(3) . . ?
C50 Fe4 C54 125.0(3) . . ?
C51 Fe4 C58 155.4(3) . . ?
C57 Fe4 C58 40.2(3) . . ?
C56 Fe4 C58 68.0(3) . . ?
C50 Fe4 C58 160.9(2) . . ?
C54 Fe4 C58 40.3(3) . . ?
C51 Fe4 C55 125.4(3) . . ?
C57 Fe4 C55 66.7(3) . . ?
C56 Fe4 C55 39.3(3) . . ?
C50 Fe4 C55 108.9(3) . . ?
C54 Fe4 C55 40.5(3) . . ?
C58 Fe4 C55 67.7(3) . . ?
C51 Fe4 C52 40.2(2) . . ?
C57 Fe4 C52 108.3(3) . . ?
C56 Fe4 C52 125.3(3) . . ?
C50 Fe4 C52 68.4(2) . . ?
C54 Fe4 C52 156.2(3) . . ?
C58 Fe4 C52 121.0(3) . . ?
C55 Fe4 C52 161.4(3) . . ?
C51 Fe4 C53 68.1(2) . . ?
C57 Fe4 C53 125.5(3) . . ?
C56 Fe4 C53 162.1(3) . . ?
C50 Fe4 C53 67.4(2) . . ?
C54 Fe4 C53 121.7(3) . . ?
C58 Fe4 C53 108.0(2) . . ?
C55 Fe4 C53 157.1(3) . . ?
C52 Fe4 C53 40.5(2) . . ?
C51 Fe4 C49 69.9(2) . . ?
C57 Fe4 C49 160.9(2) . . ?
C56 Fe4 C49 156.6(3) . . ?
C50 Fe4 C49 40.66(19) . . ?
C54 Fe4 C49 107.5(3) . . ?
C58 Fe4 C49 123.9(2) . . ?
C55 Fe4 C49 122.0(3) . . ?
C52 Fe4 C49 68.7(2) . . ?
C53 Fe4 C49 40.17(19) . . ?
C11 O1 C12 107.3(4) . . ?
C27 O2 C28 107.7(4) . . ?
C43 O3 C44 106.2(4) . . ?
C59 O4 C60 107.2(4) . . ?
C11 N1 C13 109.4(4) . . ?
C11 N1 Au2 133.5(3) . . ?
C13 N1 Au2 117.1(3) . . ?
C27 N2 C29 109.5(4) . . ?
C27 N2 Au1 131.8(3) . . ?
C29 N2 Au1 118.8(3) . . ?
C43 N3 C45 108.7(4) . . ?
C43 N3 Au4 131.2(4) . . ?
C45 N3 Au4 119.2(3) . . ?
C59 N4 C61 108.8(4) . . ?
C59 N4 Au3 132.5(3) . . ?
C61 N4 Au3 118.7(3) . . ?
C5 C1 C2 105.3(4) . . ?
C5 C1 Au1 124.6(3) . . ?
C2 C1 Au1 128.9(4) . . ?
C5 C1 Fe1 68.9(3) . . ?
C2 C1 Fe1 67.9(3) . . ?
Au1 C1 Fe1 117.5(2) . . ?
C3 C2 C1 108.7(4) . . ?
C3 C2 C11 122.2(4) . . ?
C1 C2 C11 129.0(4) . . ?
C3 C2 Fe1 68.0(3) . . ?
C1 C2 Fe1 71.4(3) . . ?
C11 C2 Fe1 123.9(3) . . ?
C4 C3 C2 108.3(4) . . ?
C4 C3 Fe1 70.9(3) . . ?
C2 C3 Fe1 70.5(3) . . ?
C4 C3 H3 125.9 . . ?
C2 C3 H3 125.9 . . ?
Fe1 C3 H3 124.3 . . ?
C3 C4 C5 107.1(4) . . ?
C3 C4 Fe1 68.4(3) . . ?
C5 C4 Fe1 70.6(3) . . ?
C3 C4 H4 126.5 . . ?
C5 C4 H4 126.5 . . ?
Fe1 C4 H4 126.2 . . ?
C4 C5 C1 110.6(4) . . ?
C4 C5 Fe1 69.0(3) . . ?
C1 C5 Fe1 70.9(3) . . ?
C4 C5 H5 124.7 . . ?
C1 C5 H5 124.7 . . ?
Fe1 C5 H5 127.0 . . ?
C7 C6 C10 108.7(5) . . ?
C7 C6 Fe1 69.5(3) . . ?
C10 C6 Fe1 70.3(3) . . ?
C7 C6 H6 125.7 . . ?
C10 C6 H6 125.7 . . ?
Fe1 C6 H6 126.1 . . ?
C6 C7 C8 108.4(5) . . ?
C6 C7 Fe1 70.0(3) . . ?
C8 C7 Fe1 69.9(3) . . ?
C6 C7 H7 125.8 . . ?
C8 C7 H7 125.8 . . ?
Fe1 C7 H7 125.9 . . ?
C9 C8 C7 107.6(5) . . ?
C9 C8 Fe1 70.2(3) . . ?
C7 C8 Fe1 69.3(3) . . ?
C9 C8 H8 126.2 . . ?
C7 C8 H8 126.2 . . ?
Fe1 C8 H8 125.9 . . ?
C8 C9 C10 108.5(5) . . ?
C8 C9 Fe1 69.4(3) . . ?
C10 C9 Fe1 69.6(3) . . ?
C8 C9 H9 125.8 . . ?
C10 C9 H9 125.8 . . ?
Fe1 C9 H9 126.7 . . ?
C6 C10 C9 106.8(5) . . ?
C6 C10 Fe1 69.1(3) . . ?
C9 C10 Fe1 69.3(3) . . ?
C6 C10 H10 126.6 . . ?
C9 C10 H10 126.6 . . ?
Fe1 C10 H10 126.5 . . ?
N1 C11 O1 114.9(4) . . ?
N1 C11 C2 130.7(4) . . ?
O1 C11 C2 114.5(4) . . ?
O1 C12 C13 103.5(4) . . ?
O1 C12 H12A 111.1 . . ?
C13 C12 H12A 111.1 . . ?
O1 C12 H12B 111.1 . . ?
C13 C12 H12B 111.1 . . ?
H12A C12 H12B 109.0 . . ?
N1 C13 C14 111.6(4) . . ?
N1 C13 C12 101.9(4) . . ?
C14 C13 C12 116.2(5) . . ?
N1 C13 H13 108.9 . . ?
C14 C13 H13 108.9 . . ?
C12 C13 H13 108.9 . . ?
C13 C14 C16 110.8(5) . . ?
C13 C14 C15 112.2(5) . . ?
C16 C14 C15 111.5(5) . . ?
C13 C14 H14 107.4 . . ?
C16 C14 H14 107.4 . . ?
C15 C14 H14 107.4 . . ?
C14 C15 H15A 109.5 . . ?
C14 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C14 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C14 C16 H16A 109.5 . . ?
C14 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C14 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C18 C17 C21 104.6(4) . . ?
C18 C17 Au2 129.6(4) . . ?
C21 C17 Au2 125.8(4) . . ?
C18 C17 Fe2 67.2(3) . . ?
C21 C17 Fe2 68.5(3) . . ?
Au2 C17 Fe2 126.8(2) . . ?
C17 C18 C19 109.8(4) . . ?
C17 C18 C27 128.7(5) . . ?
C19 C18 C27 121.3(5) . . ?
C17 C18 Fe2 71.9(3) . . ?
C19 C18 Fe2 68.8(3) . . ?
C27 C18 Fe2 122.6(4) . . ?
C20 C19 C18 106.7(4) . . ?
C20 C19 Fe2 70.5(3) . . ?
C18 C19 Fe2 69.2(3) . . ?
C20 C19 H19 126.7 . . ?
C18 C19 H19 126.7 . . ?
Fe2 C19 H19 125.2 . . ?
C21 C20 C19 108.2(4) . . ?
C21 C20 Fe2 70.4(3) . . ?
C19 C20 Fe2 68.7(3) . . ?
C21 C20 H20 125.9 . . ?
C19 C20 H20 125.9 . . ?
Fe2 C20 H20 126.6 . . ?
C20 C21 C17 110.7(5) . . ?
C20 C21 Fe2 69.4(3) . . ?
C17 C21 Fe2 70.9(3) . . ?
C20 C21 H21 124.6 . . ?
C17 C21 H21 124.6 . . ?
Fe2 C21 H21 126.6 . . ?
C26 C22 C23 108.5(5) . . ?
C26 C22 Fe2 70.2(3) . . ?
C23 C22 Fe2 69.3(3) . . ?
C26 C22 H22 125.7 . . ?
C23 C22 H22 125.7 . . ?
Fe2 C22 H22 126.3 . . ?
C22 C23 C24 107.2(5) . . ?
C22 C23 Fe2 69.9(3) . . ?
C24 C23 Fe2 69.7(3) . . ?
C22 C23 H23 126.4 . . ?
C24 C23 H23 126.4 . . ?
Fe2 C23 H23 125.5 . . ?
C25 C24 C23 108.5(5) . . ?
C25 C24 Fe2 70.1(3) . . ?
C23 C24 Fe2 69.4(3) . . ?
C25 C24 H24 125.7 . . ?
C23 C24 H24 125.7 . . ?
Fe2 C24 H24 126.3 . . ?
C24 C25 C26 107.6(5) . . ?
C24 C25 Fe2 69.5(3) . . ?
C26 C25 Fe2 69.8(3) . . ?
C24 C25 H25 126.2 . . ?
C26 C25 H25 126.2 . . ?
Fe2 C25 H25 126.0 . . ?
C22 C26 C25 108.2(5) . . ?
C22 C26 Fe2 69.6(3) . . ?
C25 C26 Fe2 69.5(3) . . ?
C22 C26 H26 125.9 . . ?
C25 C26 H26 125.9 . . ?
Fe2 C26 H26 126.5 . . ?
N2 C27 O2 115.1(4) . . ?
N2 C27 C18 128.9(5) . . ?
O2 C27 C18 115.9(4) . . ?
O2 C28 C29 104.5(4) . . ?
O2 C28 H28A 110.8 . . ?
C29 C28 H28A 110.8 . . ?
O2 C28 H28B 110.8 . . ?
C29 C28 H28B 110.8 . . ?
H28A C28 H28B 108.9 . . ?
N2 C29 C28 103.1(4) . . ?
N2 C29 C30 111.9(4) . . ?
C28 C29 C30 115.8(4) . . ?
N2 C29 H29 108.6 . . ?
C28 C29 H29 108.6 . . ?
C30 C29 H29 108.6 . . ?
C32 C30 C31 112.2(4) . . ?
C32 C30 C29 113.2(4) . . ?
C31 C30 C29 109.7(4) . . ?
C32 C30 H30 107.1 . . ?
C31 C30 H30 107.1 . . ?
C29 C30 H30 107.1 . . ?
C30 C31 H31A 109.5 . . ?
C30 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
C30 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
C30 C32 H32A 109.5 . . ?
C30 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C30 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C37 C33 C34 104.7(4) . . ?
C37 C33 Au3 124.3(4) . . ?
C34 C33 Au3 130.5(4) . . ?
C37 C33 Fe3 68.6(3) . . ?
C34 C33 Fe3 67.3(3) . . ?
Au3 C33 Fe3 122.1(2) . . ?
C35 C34 C43 121.9(4) . . ?
C35 C34 C33 109.4(4) . . ?
C43 C34 C33 128.7(5) . . ?
C35 C34 Fe3 68.9(3) . . ?
C43 C34 Fe3 125.1(4) . . ?
C33 C34 Fe3 71.4(3) . . ?
C36 C35 C34 107.3(4) . . ?
C36 C35 Fe3 70.0(3) . . ?
C34 C35 Fe3 69.8(3) . . ?
C36 C35 H35 126.4 . . ?
C34 C35 H35 126.4 . . ?
Fe3 C35 H35 125.4 . . ?
C37 C36 C35 107.9(5) . . ?
C37 C36 Fe3 70.6(3) . . ?
C35 C36 Fe3 68.9(3) . . ?
C37 C36 H36 126.0 . . ?
C35 C36 H36 126.0 . . ?
Fe3 C36 H36 126.0 . . ?
C36 C37 C33 110.7(4) . . ?
C36 C37 Fe3 69.1(3) . . ?
C33 C37 Fe3 71.1(3) . . ?
C36 C37 H37 124.6 . . ?
C33 C37 H37 124.6 . . ?
Fe3 C37 H37 126.8 . . ?
C42 C38 C39 106.0(8) . . ?
C42 C38 Fe3 68.9(4) . . ?
C39 C38 Fe3 69.2(4) . . ?
C42 C38 H38 127.0 . . ?
C39 C38 H38 127.0 . . ?
Fe3 C38 H38 126.4 . . ?
C40 C39 C38 106.9(6) . . ?
C40 C39 Fe3 69.6(3) . . ?
C38 C39 Fe3 69.4(3) . . ?
C40 C39 H39 126.5 . . ?
C38 C39 H39 126.5 . . ?
Fe3 C39 H39 126.1 . . ?
C41 C40 C39 108.9(8) . . ?
C41 C40 Fe3 70.2(4) . . ?
C39 C40 Fe3 69.6(4) . . ?
C41 C40 H40 125.6 . . ?
C39 C40 H40 125.6 . . ?
Fe3 C40 H40 126.2 . . ?
C42 C41 C40 108.7(7) . . ?
C42 C41 Fe3 69.7(4) . . ?
C40 C41 Fe3 69.7(4) . . ?
C42 C41 H41 125.7 . . ?
C40 C41 H41 125.7 . . ?
Fe3 C41 H41 126.5 . . ?
C41 C42 C38 109.5(8) . . ?
C41 C42 Fe3 70.9(4) . . ?
C38 C42 Fe3 69.7(4) . . ?
C41 C42 H42 125.3 . . ?
C38 C42 H42 125.3 . . ?
Fe3 C42 H42 125.7 . . ?
N3 C43 O3 114.7(4) . . ?
N3 C43 C34 131.6(5) . . ?
O3 C43 C34 113.7(4) . . ?
O3 C44 C45 103.4(4) . . ?
O3 C44 H44A 111.1 . . ?
C45 C44 H44A 111.1 . . ?
O3 C44 H44B 111.1 . . ?
C45 C44 H44B 111.1 . . ?
H44A C44 H44B 109.0 . . ?
N3 C45 C46 112.4(5) . . ?
N3 C45 C44 102.2(4) . . ?
C46 C45 C44 114.3(5) . . ?
N3 C45 H45 109.2 . . ?
C46 C45 H45 109.2 . . ?
C44 C45 H45 109.2 . . ?
C48 C46 C48A 86.0(10) . . ?
C48 C46 C45 117.3(7) . . ?
C48A C46 C45 120.3(8) . . ?
C48 C46 C47 113.1(8) . . ?
C48A C46 C47 106.4(8) . . ?
C45 C46 C47 111.3(5) . . ?
C48 C46 H46 103.4 . . ?
C48A C46 H46 19.0 . . ?
C45 C46 H46 104.6 . . ?
C47 C46 H46 105.7 . . ?
C48 C46 H46A 19.4 . . ?
C48A C46 H46A 105.4 . . ?
C45 C46 H46A 105.6 . . ?
C47 C46 H46A 107.0 . . ?
H46 C46 H46A 122.5 . . ?
C46 C47 H47A 109.5 . . ?
C46 C47 H47B 109.5 . . ?
H47A C47 H47B 109.5 . . ?
C46 C47 H47C 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
C46 C48 H46A 31.1 . . ?
C46 C48 H48A 109.5 . . ?
H46A C48 H48A 129.2 . . ?
C46 C48 H48B 109.5 . . ?
H46A C48 H48B 79.4 . . ?
C46 C48 H48C 109.5 . . ?
H46A C48 H48C 114.1 . . ?
C46 C48A H46 31.5 . . ?
C46 C48A H48D 109.5 . . ?
C46 C48A H48E 109.5 . . ?
H48D C48A H48E 109.5 . . ?
C46 C48A H48F 109.5 . . ?
H48D C48A H48F 109.5 . . ?
H48E C48A H48F 109.5 . . ?
C53 C49 C50 104.9(4) . . ?
C53 C49 Au4 124.7(4) . . ?
C50 C49 Au4 130.4(4) . . ?
C53 C49 Fe4 68.3(3) . . ?
C50 C49 Fe4 67.5(3) . . ?
Au4 C49 Fe4 127.8(2) . . ?
C49 C50 C51 109.0(4) . . ?
C49 C50 C59 128.9(5) . . ?
C51 C50 C59 122.0(5) . . ?
C49 C50 Fe4 71.8(3) . . ?
C51 C50 Fe4 67.9(3) . . ?
C59 C50 Fe4 124.0(4) . . ?
C52 C51 C50 107.4(5) . . ?
C52 C51 Fe4 71.2(3) . . ?
C50 C51 Fe4 70.1(3) . . ?
C52 C51 H51 126.3 . . ?
C50 C51 H51 126.3 . . ?
Fe4 C51 H51 124.1 . . ?
C51 C52 C53 108.1(5) . . ?
C51 C52 Fe4 68.5(3) . . ?
C53 C52 Fe4 70.1(3) . . ?
C51 C52 H52 126.0 . . ?
C53 C52 H52 126.0 . . ?
Fe4 C52 H52 126.9 . . ?
C52 C53 C49 110.6(5) . . ?
C52 C53 Fe4 69.4(3) . . ?
C49 C53 Fe4 71.5(3) . . ?
C52 C53 H53 124.7 . . ?
C49 C53 H53 124.7 . . ?
Fe4 C53 H53 126.0 . . ?
C58 C54 C55 107.7(7) . . ?
C58 C54 Fe4 69.9(4) . . ?
C55 C54 Fe4 69.8(4) . . ?
C58 C54 H54 126.1 . . ?
C55 C54 H54 126.1 . . ?
Fe4 C54 H54 125.8 . . ?
C56 C55 C54 108.7(7) . . ?
C56 C55 Fe4 69.9(5) . . ?
C54 C55 Fe4 69.8(4) . . ?
C56 C55 H55 125.7 . . ?
C54 C55 H55 125.7 . . ?
Fe4 C55 H55 126.2 . . ?
C55 C56 C57 107.8(8) . . ?
C55 C56 Fe4 70.8(5) . . ?
C57 C56 Fe4 69.7(4) . . ?
C55 C56 H56 126.1 . . ?
C57 C56 H56 126.1 . . ?
Fe4 C56 H56 125.0 . . ?
C56 C57 C58 109.0(7) . . ?
C56 C57 Fe4 69.9(4) . . ?
C58 C57 Fe4 70.4(4) . . ?
C56 C57 H57 125.5 . . ?
C58 C57 H57 125.5 . . ?
Fe4 C57 H57 125.8 . . ?
C57 C58 C54 106.8(6) . . ?
C57 C58 Fe4 69.4(4) . . ?
C54 C58 Fe4 69.9(4) . . ?
C57 C58 H58 126.6 . . ?
C54 C58 H58 126.6 . . ?
Fe4 C58 H58 125.7 . . ?
N4 C59 O4 116.8(5) . . ?
N4 C59 C50 127.3(5) . . ?
O4 C59 C50 115.9(4) . . ?
O4 C60 C61 104.3(4) . . ?
O4 C60 H60A 110.9 . . ?
C61 C60 H60A 110.9 . . ?
O4 C60 H60B 110.9 . . ?
C61 C60 H60B 110.9 . . ?
H60A C60 H60B 108.9 . . ?
N4 C61 C62 112.4(4) . . ?
N4 C61 C60 102.8(4) . . ?
C62 C61 C60 116.1(4) . . ?
N4 C61 H61 108.4 . . ?
C62 C61 H61 108.4 . . ?
C60 C61 H61 108.4 . . ?
C64 C62 C63 111.8(5) . . ?
C64 C62 C61 109.6(5) . . ?
C63 C62 C61 112.2(5) . . ?
C64 C62 H62 107.7 . . ?
C63 C62 H62 107.7 . . ?
C61 C62 H62 107.7 . . ?
C62 C63 H63A 109.5 . . ?
C62 C63 H63B 109.5 . . ?
H63A C63 H63B 109.5 . . ?
C62 C63 H63C 109.5 . . ?
H63A C63 H63C 109.5 . . ?
H63B C63 H63C 109.5 . . ?
C62 C64 H64A 109.5 . . ?
C62 C64 H64B 109.5 . . ?
H64A C64 H64B 109.5 . . ?
C62 C64 H64C 109.5 . . ?
H64A C64 H64C 109.5 . . ?
H64B C64 H64C 109.5 . . ?
Cl2X C1X Cl1X 115.8(11) . . ?
Cl2X C1X H1X1 108.3 . . ?
Cl1X C1X H1X1 108.3 . . ?
Cl2X C1X H1X2 108.3 . . ?
Cl1X C1X H1X2 108.3 . . ?
H1X1 C1X H1X2 107.4 . . ?
Cl2Y C1Y Cl1Y 112.0(10) . . ?
Cl2Y C1Y H1Y1 109.2 . . ?
Cl1Y C1Y H1Y1 109.2 . . ?
Cl2Y C1Y H1Y2 109.2 . . ?
Cl1Y C1Y H1Y2 109.2 . . ?
H1Y1 C1Y H1Y2 107.9 . . ?
Cl2Z C1Z Cl1Z 118.3(14) . . ?
Cl2Z C1Z H1Z1 107.7 . . ?
Cl1Z C1Z H1Z1 107.7 . . ?
Cl2Z C1Z H1Z2 107.7 . . ?
Cl1Z C1Z H1Z2 107.7 . . ?
H1Z1 C1Z H1Z2 107.1 . . ?
C1Z Cl1Z C1Z 121(3) . 8_667 ?
Cl1U C1U Cl2U 110.1(9) . . ?
Cl1U C1U H1U1 109.6 . . ?
Cl2U C1U H1U1 109.6 . . ?
Cl1U C1U H1U2 109.6 . . ?
Cl2U C1U H1U2 109.6 . . ?
H1U1 C1U H1U2 108.1 . . ?
Cl1T C1T Cl2T 102.8(14) . . ?
Cl1T C1T H1T1 111.2 . . ?
Cl2T C1T H1T1 111.2 . . ?
Cl1T C1T H1T2 111.2 . . ?
Cl2T C1T H1T2 111.2 . . ?
H1T1 C1T H1T2 109.1 . . ?
Cl1V C1V Cl2V 110.5(15) . . ?
Cl1V C1V H1V1 109.6 . . ?
Cl2V C1V H1V1 109.6 . . ?
Cl1V C1V H1V2 109.5 . . ?
Cl2V C1V H1V2 109.5 . . ?
H1V1 C1V H1V2 108.1 . . ?
Cl1W C1W Cl2W 113.0(16) . . ?
Cl1W C1W H1W1 109.0 . . ?
Cl2W C1W H1W1 109.0 . . ?
Cl1W C1W H1W2 109.0 . . ?
Cl2W C1W H1W2 109.0 . . ?
H1W1 C1W H1W2 107.8 . . ?
C1W Cl1W Cl1W 136.8(12) . 7_557 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 Au1 Au2 C17 150.6(2) . . . . ?
N2 Au1 Au2 C17 -34.42(18) . . . . ?
C1 Au1 Au2 N1 -30.54(18) . . . . ?
N2 Au1 Au2 N1 144.46(15) . . . . ?
C1 Au1 Au2 Au4 49.19(14) . . . . ?
N2 Au1 Au2 Au4 -135.81(11) . . . . ?
C33 Au3 Au4 C49 147.53(19) . . . . ?
N4 Au3 Au4 C49 -35.03(18) . . . . ?
C33 Au3 Au4 N3 -30.46(19) . . . . ?
N4 Au3 Au4 N3 146.98(17) . . . . ?
C33 Au3 Au4 Au2 50.34(14) . . . . ?
N4 Au3 Au4 Au2 -132.22(11) . . . . ?
C17 Au2 Au4 C49 90.79(19) . . . . ?
N1 Au2 Au4 C49 -85.96(18) . . . . ?
Au1 Au2 Au4 C49 -169.77(14) . . . . ?
C17 Au2 Au4 N3 -87.50(18) . . . . ?
N1 Au2 Au4 N3 95.75(17) . . . . ?
Au1 Au2 Au4 N3 11.94(12) . . . . ?
C17 Au2 Au4 Au3 -173.97(14) . . . . ?
N1 Au2 Au4 Au3 9.28(11) . . . . ?
Au1 Au2 Au4 Au3 -74.524(14) . . . . ?
C17 Au2 N1 C11 -173(3) . . . . ?
Au1 Au2 N1 C11 25.9(5) . . . . ?
Au4 Au2 N1 C11 -107.1(5) . . . . ?
C17 Au2 N1 C13 7(3) . . . . ?
Au1 Au2 N1 C13 -154.7(3) . . . . ?
Au4 Au2 N1 C13 72.3(3) . . . . ?
C1 Au1 N2 C27 167.7(12) . . . . ?
Au2 Au1 N2 C27 30.5(4) . . . . ?
C1 Au1 N2 C29 -12.9(15) . . . . ?
Au2 Au1 N2 C29 -150.1(3) . . . . ?
C49 Au4 N3 C43 -117(3) . . . . ?
Au3 Au4 N3 C43 33.2(5) . . . . ?
Au2 Au4 N3 C43 -91.5(5) . . . . ?
C49 Au4 N3 C45 51(3) . . . . ?
Au3 Au4 N3 C45 -158.8(4) . . . . ?
Au2 Au4 N3 C45 76.5(4) . . . . ?
C33 Au3 N4 C59 -175.5(17) . . . . ?
Au4 Au3 N4 C59 32.1(5) . . . . ?
C33 Au3 N4 C61 4(2) . . . . ?
Au4 Au3 N4 C61 -148.7(3) . . . . ?
N2 Au1 C1 C5 59.9(16) . . . . ?
Au2 Au1 C1 C5 -163.0(4) . . . . ?
N2 Au1 C1 C2 -105.1(14) . . . . ?
Au2 Au1 C1 C2 32.0(4) . . . . ?
N2 Au1 C1 Fe1 -22.4(15) . . . . ?
Au2 Au1 C1 Fe1 114.7(2) . . . . ?
C3 Fe1 C1 C5 79.8(3) . . . . ?
C7 Fe1 C1 C5 -174.0(3) . . . . ?
C6 Fe1 C1 C5 -136.0(3) . . . . ?
C8 Fe1 C1 C5 164(2) . . . . ?
C4 Fe1 C1 C5 36.0(3) . . . . ?
C2 Fe1 C1 C5 117.5(4) . . . . ?
C9 Fe1 C1 C5 -57.3(5) . . . . ?
C10 Fe1 C1 C5 -92.7(3) . . . . ?
C3 Fe1 C1 C2 -37.8(3) . . . . ?
C7 Fe1 C1 C2 68.5(4) . . . . ?
C6 Fe1 C1 C2 106.5(3) . . . . ?
C8 Fe1 C1 C2 47(2) . . . . ?
C4 Fe1 C1 C2 -81.5(3) . . . . ?
C9 Fe1 C1 C2 -174.8(4) . . . . ?
C10 Fe1 C1 C2 149.8(3) . . . . ?
C5 Fe1 C1 C2 -117.5(4) . . . . ?
C3 Fe1 C1 Au1 -161.3(3) . . . . ?
C7 Fe1 C1 Au1 -55.0(4) . . . . ?
C6 Fe1 C1 Au1 -17.0(3) . . . . ?
C8 Fe1 C1 Au1 -77(2) . . . . ?
C4 Fe1 C1 Au1 155.0(3) . . . . ?
C2 Fe1 C1 Au1 -123.5(4) . . . . ?
C9 Fe1 C1 Au1 61.7(5) . . . . ?
C10 Fe1 C1 Au1 26.3(3) . . . . ?
C5 Fe1 C1 Au1 119.0(4) . . . . ?
C5 C1 C2 C3 -1.1(5) . . . . ?
Au1 C1 C2 C3 166.1(4) . . . . ?
Fe1 C1 C2 C3 58.0(3) . . . . ?
C5 C1 C2 C11 -178.0(5) . . . . ?
Au1 C1 C2 C11 -10.8(7) . . . . ?
Fe1 C1 C2 C11 -119.0(5) . . . . ?
C5 C1 C2 Fe1 -59.1(3) . . . . ?
Au1 C1 C2 Fe1 108.2(4) . . . . ?
C7 Fe1 C2 C3 105.5(3) . . . . ?
C6 Fe1 C2 C3 149.5(3) . . . . ?
C8 Fe1 C2 C3 65.5(4) . . . . ?
C4 Fe1 C2 C3 -38.0(3) . . . . ?
C9 Fe1 C2 C3 26(2) . . . . ?
C10 Fe1 C2 C3 -172.6(4) . . . . ?
C5 Fe1 C2 C3 -81.7(3) . . . . ?
C1 Fe1 C2 C3 -120.0(4) . . . . ?
C3 Fe1 C2 C1 120.0(4) . . . . ?
C7 Fe1 C2 C1 -134.5(3) . . . . ?
C6 Fe1 C2 C1 -90.5(3) . . . . ?
C8 Fe1 C2 C1 -174.5(3) . . . . ?
C4 Fe1 C2 C1 82.0(3) . . . . ?
C9 Fe1 C2 C1 146(2) . . . . ?
C10 Fe1 C2 C1 -52.6(5) . . . . ?
C5 Fe1 C2 C1 38.3(3) . . . . ?
C3 Fe1 C2 C11 -114.9(5) . . . . ?
C7 Fe1 C2 C11 -9.4(5) . . . . ?
C6 Fe1 C2 C11 34.6(5) . . . . ?
C8 Fe1 C2 C11 -49.4(5) . . . . ?
C4 Fe1 C2 C11 -153.0(4) . . . . ?
C9 Fe1 C2 C11 -89(2) . . . . ?
C10 Fe1 C2 C11 72.5(5) . . . . ?
C5 Fe1 C2 C11 163.4(5) . . . . ?
C1 Fe1 C2 C11 125.1(5) . . . . ?
C1 C2 C3 C4 1.1(5) . . . . ?
C11 C2 C3 C4 178.3(4) . . . . ?
Fe1 C2 C3 C4 61.2(3) . . . . ?
C1 C2 C3 Fe1 -60.0(3) . . . . ?
C11 C2 C3 Fe1 117.1(4) . . . . ?
C7 Fe1 C3 C4 148.4(3) . . . . ?
C6 Fe1 C3 C4 -174.7(4) . . . . ?
C8 Fe1 C3 C4 104.4(3) . . . . ?
C2 Fe1 C3 C4 -118.3(4) . . . . ?
C9 Fe1 C3 C4 65.0(4) . . . . ?
C10 Fe1 C3 C4 25.4(18) . . . . ?
C5 Fe1 C3 C4 -38.0(3) . . . . ?
C1 Fe1 C3 C4 -81.2(3) . . . . ?
C7 Fe1 C3 C2 -93.2(3) . . . . ?
C6 Fe1 C3 C2 -56.3(5) . . . . ?
C8 Fe1 C3 C2 -137.3(3) . . . . ?
C4 Fe1 C3 C2 118.3(4) . . . . ?
C9 Fe1 C3 C2 -176.7(3) . . . . ?
C10 Fe1 C3 C2 143.7(16) . . . . ?
C5 Fe1 C3 C2 80.4(3) . . . . ?
C1 Fe1 C3 C2 37.1(3) . . . . ?
C2 C3 C4 C5 -0.7(6) . . . . ?
Fe1 C3 C4 C5 60.3(4) . . . . ?
C2 C3 C4 Fe1 -60.9(3) . . . . ?
C7 Fe1 C4 C3 -57.6(5) . . . . ?
C6 Fe1 C4 C3 157.8(15) . . . . ?
C8 Fe1 C4 C3 -92.9(3) . . . . ?
C2 Fe1 C4 C3 38.7(3) . . . . ?
C9 Fe1 C4 C3 -136.1(3) . . . . ?
C10 Fe1 C4 C3 -175.8(3) . . . . ?
C5 Fe1 C4 C3 118.4(4) . . . . ?
C1 Fe1 C4 C3 82.5(3) . . . . ?
C3 Fe1 C4 C5 -118.4(4) . . . . ?
C7 Fe1 C4 C5 -176.0(4) . . . . ?
C6 Fe1 C4 C5 39.5(17) . . . . ?
C8 Fe1 C4 C5 148.7(3) . . . . ?
C2 Fe1 C4 C5 -79.7(3) . . . . ?
C9 Fe1 C4 C5 105.6(3) . . . . ?
C10 Fe1 C4 C5 65.9(4) . . . . ?
C1 Fe1 C4 C5 -35.8(3) . . . . ?
C3 C4 C5 C1 -0.1(6) . . . . ?
Fe1 C4 C5 C1 58.8(4) . . . . ?
C3 C4 C5 Fe1 -58.8(3) . . . . ?
C2 C1 C5 C4 0.7(6) . . . . ?
Au1 C1 C5 C4 -167.2(4) . . . . ?
Fe1 C1 C5 C4 -57.7(4) . . . . ?
C2 C1 C5 Fe1 58.4(3) . . . . ?
Au1 C1 C5 Fe1 -109.5(4) . . . . ?
C3 Fe1 C5 C4 38.3(3) . . . . ?
C7 Fe1 C5 C4 161.1(18) . . . . ?
C6 Fe1 C5 C4 -173.2(3) . . . . ?
C8 Fe1 C5 C4 -55.4(5) . . . . ?
C2 Fe1 C5 C4 83.3(3) . . . . ?
C9 Fe1 C5 C4 -91.0(3) . . . . ?
C10 Fe1 C5 C4 -134.8(3) . . . . ?
C1 Fe1 C5 C4 122.1(4) . . . . ?
C3 Fe1 C5 C1 -83.8(3) . . . . ?
C7 Fe1 C5 C1 39(2) . . . . ?
C6 Fe1 C5 C1 64.7(4) . . . . ?
C8 Fe1 C5 C1 -177.5(4) . . . . ?
C4 Fe1 C5 C1 -122.1(4) . . . . ?
C2 Fe1 C5 C1 -38.8(3) . . . . ?
C9 Fe1 C5 C1 146.9(3) . . . . ?
C10 Fe1 C5 C1 103.1(3) . . . . ?
C3 Fe1 C6 C7 -56.3(5) . . . . ?
C8 Fe1 C6 C7 37.7(4) . . . . ?
C4 Fe1 C6 C7 150.1(15) . . . . ?
C2 Fe1 C6 C7 -93.7(4) . . . . ?
C9 Fe1 C6 C7 81.3(4) . . . . ?
C10 Fe1 C6 C7 119.8(5) . . . . ?
C5 Fe1 C6 C7 -175.4(3) . . . . ?
C1 Fe1 C6 C7 -137.4(3) . . . . ?
C3 Fe1 C6 C10 -176.2(4) . . . . ?
C7 Fe1 C6 C10 -119.8(5) . . . . ?
C8 Fe1 C6 C10 -82.1(4) . . . . ?
C4 Fe1 C6 C10 30.3(17) . . . . ?
C2 Fe1 C6 C10 146.4(3) . . . . ?
C9 Fe1 C6 C10 -38.5(3) . . . . ?
C5 Fe1 C6 C10 64.8(4) . . . . ?
C1 Fe1 C6 C10 102.8(3) . . . . ?
C10 C6 C7 C8 0.0(6) . . . . ?
Fe1 C6 C7 C8 -59.6(4) . . . . ?
C10 C6 C7 Fe1 59.6(4) . . . . ?
C3 Fe1 C7 C6 149.3(3) . . . . ?
C8 Fe1 C7 C6 -119.4(5) . . . . ?
C4 Fe1 C7 C6 -173.0(4) . . . . ?
C2 Fe1 C7 C6 104.2(3) . . . . ?
C9 Fe1 C7 C6 -81.6(4) . . . . ?
C10 Fe1 C7 C6 -37.3(3) . . . . ?
C5 Fe1 C7 C6 29(2) . . . . ?
C1 Fe1 C7 C6 63.6(4) . . . . ?
C3 Fe1 C7 C8 -91.3(4) . . . . ?
C6 Fe1 C7 C8 119.4(5) . . . . ?
C4 Fe1 C7 C8 -53.6(6) . . . . ?
C2 Fe1 C7 C8 -136.4(3) . . . . ?
C9 Fe1 C7 C8 37.8(3) . . . . ?
C10 Fe1 C7 C8 82.1(4) . . . . ?
C5 Fe1 C7 C8 148.5(18) . . . . ?
C1 Fe1 C7 C8 -177.0(3) . . . . ?
C6 C7 C8 C9 -0.3(7) . . . . ?
Fe1 C7 C8 C9 -60.0(4) . . . . ?
C6 C7 C8 Fe1 59.6(4) . . . . ?
C3 Fe1 C8 C9 -134.7(3) . . . . ?
C7 Fe1 C8 C9 118.7(5) . . . . ?
C6 Fe1 C8 C9 81.2(4) . . . . ?
C4 Fe1 C8 C9 -90.8(4) . . . . ?
C2 Fe1 C8 C9 -174.6(3) . . . . ?
C10 Fe1 C8 C9 37.6(4) . . . . ?
C5 Fe1 C8 C9 -55.0(5) . . . . ?
C1 Fe1 C8 C9 143(2) . . . . ?
C3 Fe1 C8 C7 106.5(4) . . . . ?
C6 Fe1 C8 C7 -37.5(3) . . . . ?
C4 Fe1 C8 C7 150.4(3) . . . . ?
C2 Fe1 C8 C7 66.7(4) . . . . ?
C9 Fe1 C8 C7 -118.7(5) . . . . ?
C10 Fe1 C8 C7 -81.2(4) . . . . ?
C5 Fe1 C8 C7 -173.7(4) . . . . ?
C1 Fe1 C8 C7 24(2) . . . . ?
C7 C8 C9 C10 0.5(7) . . . . ?
Fe1 C8 C9 C10 -58.9(4) . . . . ?
C7 C8 C9 Fe1 59.4(4) . . . . ?
C3 Fe1 C9 C8 67.1(5) . . . . ?
C7 Fe1 C9 C8 -38.1(4) . . . . ?
C6 Fe1 C9 C8 -82.0(4) . . . . ?
C4 Fe1 C9 C8 105.7(4) . . . . ?
C2 Fe1 C9 C8 43(3) . . . . ?
C10 Fe1 C9 C8 -120.0(5) . . . . ?
C5 Fe1 C9 C8 148.9(3) . . . . ?
C1 Fe1 C9 C8 -174.6(3) . . . . ?
C3 Fe1 C9 C10 -172.9(3) . . . . ?
C7 Fe1 C9 C10 81.9(4) . . . . ?
C6 Fe1 C9 C10 38.1(3) . . . . ?
C8 Fe1 C9 C10 120.0(5) . . . . ?
C4 Fe1 C9 C10 -134.3(3) . . . . ?
C2 Fe1 C9 C10 163(2) . . . . ?
C5 Fe1 C9 C10 -91.1(4) . . . . ?
C1 Fe1 C9 C10 -54.6(5) . . . . ?
C7 C6 C10 C9 0.3(6) . . . . ?
Fe1 C6 C10 C9 59.4(4) . . . . ?
C7 C6 C10 Fe1 -59.1(4) . . . . ?
C8 C9 C10 C6 -0.5(6) . . . . ?
Fe1 C9 C10 C6 -59.3(4) . . . . ?
C8 C9 C10 Fe1 58.7(4) . . . . ?
C3 Fe1 C10 C6 163.0(16) . . . . ?
C7 Fe1 C10 C6 37.3(3) . . . . ?
C8 Fe1 C10 C6 81.3(4) . . . . ?
C4 Fe1 C10 C6 -174.7(3) . . . . ?
C2 Fe1 C10 C6 -59.1(5) . . . . ?
C9 Fe1 C10 C6 118.3(5) . . . . ?
C5 Fe1 C10 C6 -136.0(3) . . . . ?
C1 Fe1 C10 C6 -93.2(3) . . . . ?
C3 Fe1 C10 C9 44.7(18) . . . . ?
C7 Fe1 C10 C9 -81.0(4) . . . . ?
C6 Fe1 C10 C9 -118.3(5) . . . . ?
C8 Fe1 C10 C9 -37.0(4) . . . . ?
C4 Fe1 C10 C9 67.1(4) . . . . ?
C2 Fe1 C10 C9 -177.3(4) . . . . ?
C5 Fe1 C10 C9 105.7(4) . . . . ?
C1 Fe1 C10 C9 148.5(3) . . . . ?
C13 N1 C11 O1 -4.1(6) . . . . ?
Au2 N1 C11 O1 175.4(3) . . . . ?
C13 N1 C11 C2 177.9(5) . . . . ?
Au2 N1 C11 C2 -2.7(8) . . . . ?
C12 O1 C11 N1 -7.8(6) . . . . ?
C12 O1 C11 C2 170.6(4) . . . . ?
C3 C2 C11 N1 168.1(5) . . . . ?
C1 C2 C11 N1 -15.3(9) . . . . ?
Fe1 C2 C11 N1 -108.2(6) . . . . ?
C3 C2 C11 O1 -9.9(6) . . . . ?
C1 C2 C11 O1 166.6(5) . . . . ?
Fe1 C2 C11 O1 73.8(5) . . . . ?
C11 O1 C12 C13 15.3(5) . . . . ?
C11 N1 C13 C14 -111.4(5) . . . . ?
Au2 N1 C13 C14 69.1(5) . . . . ?
C11 N1 C13 C12 13.2(5) . . . . ?
Au2 N1 C13 C12 -166.3(3) . . . . ?
O1 C12 C13 N1 -16.7(5) . . . . ?
O1 C12 C13 C14 104.8(5) . . . . ?
N1 C13 C14 C16 -174.8(5) . . . . ?
C12 C13 C14 C16 69.0(6) . . . . ?
N1 C13 C14 C15 59.8(6) . . . . ?
C12 C13 C14 C15 -56.4(6) . . . . ?
N1 Au2 C17 C18 -132(3) . . . . ?
Au1 Au2 C17 C18 29.1(4) . . . . ?
Au4 Au2 C17 C18 162.6(4) . . . . ?
N1 Au2 C17 C21 46(3) . . . . ?
Au1 Au2 C17 C21 -152.8(4) . . . . ?
Au4 Au2 C17 C21 -19.3(4) . . . . ?
N1 Au2 C17 Fe2 -43(3) . . . . ?
Au1 Au2 C17 Fe2 118.7(3) . . . . ?
Au4 Au2 C17 Fe2 -107.9(3) . . . . ?
C19 Fe2 C17 C18 -37.7(3) . . . . ?
C23 Fe2 C17 C18 80.3(3) . . . . ?
C20 Fe2 C17 C18 -81.4(3) . . . . ?
C24 Fe2 C17 C18 47.0(6) . . . . ?
C22 Fe2 C17 C18 123.1(3) . . . . ?
C25 Fe2 C17 C18 -163.4(6) . . . . ?
C21 Fe2 C17 C18 -117.3(4) . . . . ?
C26 Fe2 C17 C18 163.9(3) . . . . ?
C19 Fe2 C17 C21 79.6(3) . . . . ?
C18 Fe2 C17 C21 117.3(4) . . . . ?
C23 Fe2 C17 C21 -162.4(3) . . . . ?
C20 Fe2 C17 C21 35.9(3) . . . . ?
C24 Fe2 C17 C21 164.3(5) . . . . ?
C22 Fe2 C17 C21 -119.6(3) . . . . ?
C25 Fe2 C17 C21 -46.1(8) . . . . ?
C26 Fe2 C17 C21 -78.8(4) . . . . ?
C19 Fe2 C17 Au2 -161.1(4) . . . . ?
C18 Fe2 C17 Au2 -123.4(4) . . . . ?
C23 Fe2 C17 Au2 -43.0(4) . . . . ?
C20 Fe2 C17 Au2 155.2(4) . . . . ?
C24 Fe2 C17 Au2 -76.4(6) . . . . ?
C22 Fe2 C17 Au2 -0.3(4) . . . . ?
C25 Fe2 C17 Au2 73.2(8) . . . . ?
C21 Fe2 C17 Au2 119.3(4) . . . . ?
C26 Fe2 C17 Au2 40.5(4) . . . . ?
C21 C17 C18 C19 -0.1(5) . . . . ?
Au2 C17 C18 C19 178.3(4) . . . . ?
Fe2 C17 C18 C19 58.5(3) . . . . ?
C21 C17 C18 C27 -176.3(5) . . . . ?
Au2 C17 C18 C27 2.1(8) . . . . ?
Fe2 C17 C18 C27 -117.7(5) . . . . ?
C21 C17 C18 Fe2 -58.7(3) . . . . ?
Au2 C17 C18 Fe2 119.7(4) . . . . ?
C19 Fe2 C18 C17 120.6(4) . . . . ?
C23 Fe2 C18 C17 -117.3(3) . . . . ?
C20 Fe2 C18 C17 82.1(3) . . . . ?
C24 Fe2 C18 C17 -159.6(3) . . . . ?
C22 Fe2 C18 C17 -76.4(3) . . . . ?
C25 Fe2 C18 C17 168.0(5) . . . . ?
C21 Fe2 C18 C17 38.7(3) . . . . ?
C26 Fe2 C18 C17 -46.5(8) . . . . ?
C23 Fe2 C18 C19 122.1(3) . . . . ?
C20 Fe2 C18 C19 -38.5(3) . . . . ?
C24 Fe2 C18 C19 79.8(4) . . . . ?
C22 Fe2 C18 C19 163.0(3) . . . . ?
C25 Fe2 C18 C19 47.3(6) . . . . ?
C21 Fe2 C18 C19 -82.0(3) . . . . ?
C26 Fe2 C18 C19 -167.2(6) . . . . ?
C17 Fe2 C18 C19 -120.6(4) . . . . ?
C19 Fe2 C18 C27 -114.5(5) . . . . ?
C23 Fe2 C18 C27 7.6(5) . . . . ?
C20 Fe2 C18 C27 -153.0(5) . . . . ?
C24 Fe2 C18 C27 -34.7(5) . . . . ?
C22 Fe2 C18 C27 48.6(5) . . . . ?
C25 Fe2 C18 C27 -67.1(7) . . . . ?
C21 Fe2 C18 C27 163.6(5) . . . . ?
C26 Fe2 C18 C27 78.4(8) . . . . ?
C17 Fe2 C18 C27 124.9(5) . . . . ?
C17 C18 C19 C20 0.5(6) . . . . ?
C27 C18 C19 C20 177.0(4) . . . . ?
Fe2 C18 C19 C20 60.9(3) . . . . ?
C17 C18 C19 Fe2 -60.4(3) . . . . ?
C27 C18 C19 Fe2 116.1(5) . . . . ?
C18 Fe2 C19 C20 -117.4(4) . . . . ?
C23 Fe2 C19 C20 165.6(3) . . . . ?
C24 Fe2 C19 C20 124.6(3) . . . . ?
C22 Fe2 C19 C20 -167.2(6) . . . . ?
C25 Fe2 C19 C20 83.1(3) . . . . ?
C21 Fe2 C19 C20 -37.1(3) . . . . ?
C26 Fe2 C19 C20 53.0(6) . . . . ?
C17 Fe2 C19 C20 -80.6(3) . . . . ?
C23 Fe2 C19 C18 -77.0(4) . . . . ?
C20 Fe2 C19 C18 117.4(4) . . . . ?
C24 Fe2 C19 C18 -118.0(3) . . . . ?
C22 Fe2 C19 C18 -49.8(8) . . . . ?
C25 Fe2 C19 C18 -159.6(3) . . . . ?
C21 Fe2 C19 C18 80.3(3) . . . . ?
C26 Fe2 C19 C18 170.4(5) . . . . ?
C17 Fe2 C19 C18 36.8(3) . . . . ?
C18 C19 C20 C21 -0.6(6) . . . . ?
Fe2 C19 C20 C21 59.5(3) . . . . ?
C18 C19 C20 Fe2 -60.1(3) . . . . ?
C19 Fe2 C20 C21 -119.7(4) . . . . ?
C18 Fe2 C20 C21 -80.2(3) . . . . ?
C23 Fe2 C20 C21 -159.5(6) . . . . ?
C24 Fe2 C20 C21 166.8(3) . . . . ?
C22 Fe2 C20 C21 50.2(6) . . . . ?
C25 Fe2 C20 C21 125.5(3) . . . . ?
C26 Fe2 C20 C21 83.2(3) . . . . ?
C17 Fe2 C20 C21 -36.2(3) . . . . ?
C18 Fe2 C20 C19 39.5(3) . . . . ?
C23 Fe2 C20 C19 -39.8(8) . . . . ?
C24 Fe2 C20 C19 -73.5(4) . . . . ?
C22 Fe2 C20 C19 169.9(5) . . . . ?
C25 Fe2 C20 C19 -114.8(3) . . . . ?
C21 Fe2 C20 C19 119.7(4) . . . . ?
C26 Fe2 C20 C19 -157.1(3) . . . . ?
C17 Fe2 C20 C19 83.5(3) . . . . ?
C19 C20 C21 C17 0.6(6) . . . . ?
Fe2 C20 C21 C17 59.0(4) . . . . ?
C19 C20 C21 Fe2 -58.4(3) . . . . ?
C18 C17 C21 C20 -0.3(5) . . . . ?
Au2 C17 C21 C20 -178.7(3) . . . . ?
Fe2 C17 C21 C20 -58.1(4) . . . . ?
C18 C17 C21 Fe2 57.8(3) . . . . ?
Au2 C17 C21 Fe2 -120.6(4) . . . . ?
C19 Fe2 C21 C20 37.7(3) . . . . ?
C18 Fe2 C21 C20 83.0(3) . . . . ?
C23 Fe2 C21 C20 163.3(5) . . . . ?
C24 Fe2 C21 C20 -37.1(8) . . . . ?
C22 Fe2 C21 C20 -158.9(3) . . . . ?
C25 Fe2 C21 C20 -73.6(4) . . . . ?
C26 Fe2 C21 C20 -116.2(3) . . . . ?
C17 Fe2 C21 C20 122.0(4) . . . . ?
C19 Fe2 C21 C17 -84.3(3) . . . . ?
C18 Fe2 C21 C17 -38.9(3) . . . . ?
C23 Fe2 C21 C17 41.4(6) . . . . ?
C20 Fe2 C21 C17 -122.0(4) . . . . ?
C24 Fe2 C21 C17 -159.1(6) . . . . ?
C22 Fe2 C21 C17 79.1(3) . . . . ?
C25 Fe2 C21 C17 164.4(3) . . . . ?
C26 Fe2 C21 C17 121.8(3) . . . . ?
C19 Fe2 C22 C26 -155.4(6) . . . . ?
C18 Fe2 C22 C26 166.1(3) . . . . ?
C23 Fe2 C22 C26 -119.7(5) . . . . ?
C20 Fe2 C22 C26 46.0(6) . . . . ?
C24 Fe2 C22 C26 -81.3(3) . . . . ?
C25 Fe2 C22 C26 -37.6(3) . . . . ?
C21 Fe2 C22 C26 82.1(4) . . . . ?
C17 Fe2 C22 C26 124.2(3) . . . . ?
C19 Fe2 C22 C23 -35.7(8) . . . . ?
C18 Fe2 C22 C23 -74.1(4) . . . . ?
C20 Fe2 C22 C23 165.8(5) . . . . ?
C24 Fe2 C22 C23 38.5(3) . . . . ?
C25 Fe2 C22 C23 82.2(3) . . . . ?
C21 Fe2 C22 C23 -158.2(3) . . . . ?
C26 Fe2 C22 C23 119.7(5) . . . . ?
C17 Fe2 C22 C23 -116.0(3) . . . . ?
C26 C22 C23 C24 -0.5(6) . . . . ?
Fe2 C22 C23 C24 -60.0(3) . . . . ?
C26 C22 C23 Fe2 59.5(4) . . . . ?
C19 Fe2 C23 C22 167.3(3) . . . . ?
C18 Fe2 C23 C22 124.5(3) . . . . ?
C20 Fe2 C23 C22 -162.6(6) . . . . ?
C24 Fe2 C23 C22 -118.1(5) . . . . ?
C25 Fe2 C23 C22 -80.9(3) . . . . ?
C21 Fe2 C23 C22 52.3(7) . . . . ?
C26 Fe2 C23 C22 -37.1(3) . . . . ?
C17 Fe2 C23 C22 82.2(3) . . . . ?
C19 Fe2 C23 C24 -74.6(4) . . . . ?
C18 Fe2 C23 C24 -117.4(3) . . . . ?
C20 Fe2 C23 C24 -44.5(8) . . . . ?
C22 Fe2 C23 C24 118.1(5) . . . . ?
C25 Fe2 C23 C24 37.2(3) . . . . ?
C21 Fe2 C23 C24 170.4(5) . . . . ?
C26 Fe2 C23 C24 81.0(3) . . . . ?
C17 Fe2 C23 C24 -159.7(3) . . . . ?
C22 C23 C24 C25 0.8(6) . . . . ?
Fe2 C23 C24 C25 -59.4(4) . . . . ?
C22 C23 C24 Fe2 60.2(3) . . . . ?
C19 Fe2 C24 C25 -116.8(3) . . . . ?
C18 Fe2 C24 C25 -160.0(3) . . . . ?
C23 Fe2 C24 C25 119.8(4) . . . . ?
C20 Fe2 C24 C25 -76.1(4) . . . . ?
C22 Fe2 C24 C25 81.5(3) . . . . ?
C21 Fe2 C24 C25 -48.0(8) . . . . ?
C26 Fe2 C24 C25 38.0(3) . . . . ?
C17 Fe2 C24 C25 166.4(4) . . . . ?
C19 Fe2 C24 C23 123.4(3) . . . . ?
C18 Fe2 C24 C23 80.2(4) . . . . ?
C20 Fe2 C24 C23 164.1(3) . . . . ?
C22 Fe2 C24 C23 -38.3(3) . . . . ?
C25 Fe2 C24 C23 -119.8(4) . . . . ?
C21 Fe2 C24 C23 -167.8(6) . . . . ?
C26 Fe2 C24 C23 -81.8(3) . . . . ?
C17 Fe2 C24 C23 46.6(6) . . . . ?
C23 C24 C25 C26 -0.8(6) . . . . ?
Fe2 C24 C25 C26 -59.7(4) . . . . ?
C23 C24 C25 Fe2 59.0(4) . . . . ?
C19 Fe2 C25 C24 79.9(4) . . . . ?
C18 Fe2 C25 C24 45.6(6) . . . . ?
C23 Fe2 C25 C24 -37.6(3) . . . . ?
C20 Fe2 C25 C24 122.8(3) . . . . ?
C22 Fe2 C25 C24 -81.5(3) . . . . ?
C21 Fe2 C25 C24 163.3(3) . . . . ?
C26 Fe2 C25 C24 -118.7(5) . . . . ?
C17 Fe2 C25 C24 -161.3(6) . . . . ?
C19 Fe2 C25 C26 -161.4(3) . . . . ?
C18 Fe2 C25 C26 164.3(5) . . . . ?
C23 Fe2 C25 C26 81.1(3) . . . . ?
C20 Fe2 C25 C26 -118.5(3) . . . . ?
C24 Fe2 C25 C26 118.7(5) . . . . ?
C22 Fe2 C25 C26 37.2(3) . . . . ?
C21 Fe2 C25 C26 -78.0(4) . . . . ?
C17 Fe2 C25 C26 -42.6(8) . . . . ?
C23 C22 C26 C25 0.1(6) . . . . ?
Fe2 C22 C26 C25 59.0(4) . . . . ?
C23 C22 C26 Fe2 -58.9(3) . . . . ?
C24 C25 C26 C22 0.4(6) . . . . ?
Fe2 C25 C26 C22 -59.1(4) . . . . ?
C24 C25 C26 Fe2 59.5(4) . . . . ?
C19 Fe2 C26 C22 161.7(5) . . . . ?
C18 Fe2 C26 C22 -39.3(8) . . . . ?
C23 Fe2 C26 C22 37.6(3) . . . . ?
C20 Fe2 C26 C22 -160.5(3) . . . . ?
C24 Fe2 C26 C22 81.8(3) . . . . ?
C25 Fe2 C26 C22 119.6(5) . . . . ?
C21 Fe2 C26 C22 -117.6(3) . . . . ?
C17 Fe2 C26 C22 -74.9(4) . . . . ?
C19 Fe2 C26 C25 42.1(7) . . . . ?
C18 Fe2 C26 C25 -158.9(6) . . . . ?
C23 Fe2 C26 C25 -82.0(3) . . . . ?
C20 Fe2 C26 C25 79.9(4) . . . . ?
C24 Fe2 C26 C25 -37.8(3) . . . . ?
C22 Fe2 C26 C25 -119.6(5) . . . . ?
C21 Fe2 C26 C25 122.8(3) . . . . ?
C17 Fe2 C26 C25 165.5(3) . . . . ?
C29 N2 C27 O2 -3.0(6) . . . . ?
Au1 N2 C27 O2 176.4(3) . . . . ?
C29 N2 C27 C18 -178.8(5) . . . . ?
Au1 N2 C27 C18 0.6(8) . . . . ?
C28 O2 C27 N2 3.4(6) . . . . ?
C28 O2 C27 C18 179.8(4) . . . . ?
C17 C18 C27 N2 -29.7(9) . . . . ?
C19 C18 C27 N2 154.5(5) . . . . ?
Fe2 C18 C27 N2 -122.0(5) . . . . ?
C17 C18 C27 O2 154.5(5) . . . . ?
C19 C18 C27 O2 -21.4(7) . . . . ?
Fe2 C18 C27 O2 62.2(5) . . . . ?
C27 O2 C28 C29 -2.3(5) . . . . ?
C27 N2 C29 C28 1.2(5) . . . . ?
Au1 N2 C29 C28 -178.3(3) . . . . ?
C27 N2 C29 C30 -123.8(4) . . . . ?
Au1 N2 C29 C30 56.6(5) . . . . ?
O2 C28 C29 N2 0.7(5) . . . . ?
O2 C28 C29 C30 123.2(4) . . . . ?
N2 C29 C30 C32 53.7(6) . . . . ?
C28 C29 C30 C32 -64.0(5) . . . . ?
N2 C29 C30 C31 179.9(4) . . . . ?
C28 C29 C30 C31 62.2(6) . . . . ?
N4 Au3 C33 C37 46(2) . . . . ?
Au4 Au3 C33 C37 -161.8(4) . . . . ?
N4 Au3 C33 C34 -125.1(18) . . . . ?
Au4 Au3 C33 C34 27.2(4) . . . . ?
N4 Au3 C33 Fe3 -39(2) . . . . ?
Au4 Au3 C33 Fe3 113.6(3) . . . . ?
C35 Fe3 C33 C37 80.0(3) . . . . ?
C42 Fe3 C33 C37 -171.2(4) . . . . ?
C34 Fe3 C33 C37 117.4(4) . . . . ?
C36 Fe3 C33 C37 36.0(3) . . . . ?
C40 Fe3 C33 C37 -52.6(6) . . . . ?
C39 Fe3 C33 C37 -87.2(4) . . . . ?
C38 Fe3 C33 C37 -131.3(3) . . . . ?
C41 Fe3 C33 C37 160.3(16) . . . . ?
C35 Fe3 C33 C34 -37.3(3) . . . . ?
C42 Fe3 C33 C34 71.5(4) . . . . ?
C36 Fe3 C33 C34 -81.4(3) . . . . ?
C40 Fe3 C33 C34 -169.9(5) . . . . ?
C39 Fe3 C33 C34 155.4(4) . . . . ?
C38 Fe3 C33 C34 111.3(4) . . . . ?
C41 Fe3 C33 C34 43.0(17) . . . . ?
C37 Fe3 C33 C34 -117.4(4) . . . . ?
C35 Fe3 C33 Au3 -162.0(3) . . . . ?
C42 Fe3 C33 Au3 -53.2(4) . . . . ?
C34 Fe3 C33 Au3 -124.7(4) . . . . ?
C36 Fe3 C33 Au3 153.9(3) . . . . ?
C40 Fe3 C33 Au3 65.4(6) . . . . ?
C39 Fe3 C33 Au3 30.7(4) . . . . ?
C38 Fe3 C33 Au3 -13.4(4) . . . . ?
C41 Fe3 C33 Au3 -81.7(16) . . . . ?
C37 Fe3 C33 Au3 118.0(4) . . . . ?
C37 C33 C34 C35 -0.2(5) . . . . ?
Au3 C33 C34 C35 172.2(4) . . . . ?
Fe3 C33 C34 C35 58.5(3) . . . . ?
C37 C33 C34 C43 -179.2(5) . . . . ?
Au3 C33 C34 C43 -6.8(8) . . . . ?
Fe3 C33 C34 C43 -120.4(5) . . . . ?
C37 C33 C34 Fe3 -58.7(3) . . . . ?
Au3 C33 C34 Fe3 113.6(4) . . . . ?
C42 Fe3 C34 C35 108.3(4) . . . . ?
C36 Fe3 C34 C35 -38.5(3) . . . . ?
C40 Fe3 C34 C35 32.7(15) . . . . ?
C39 Fe3 C34 C35 -169.2(5) . . . . ?
C38 Fe3 C34 C35 153.0(3) . . . . ?
C41 Fe3 C34 C35 68.6(5) . . . . ?
C37 Fe3 C34 C35 -82.0(3) . . . . ?
C33 Fe3 C34 C35 -120.4(4) . . . . ?
C35 Fe3 C34 C43 -114.9(5) . . . . ?
C42 Fe3 C34 C43 -6.6(6) . . . . ?
C36 Fe3 C34 C43 -153.4(5) . . . . ?
C40 Fe3 C34 C43 -82.2(15) . . . . ?
C39 Fe3 C34 C43 75.9(6) . . . . ?
C38 Fe3 C34 C43 38.1(5) . . . . ?
C41 Fe3 C34 C43 -46.3(6) . . . . ?
C37 Fe3 C34 C43 163.0(5) . . . . ?
C33 Fe3 C34 C43 124.7(6) . . . . ?
C35 Fe3 C34 C33 120.4(4) . . . . ?
C42 Fe3 C34 C33 -131.3(4) . . . . ?
C36 Fe3 C34 C33 81.9(3) . . . . ?
C40 Fe3 C34 C33 153.1(13) . . . . ?
C39 Fe3 C34 C33 -48.8(6) . . . . ?
C38 Fe3 C34 C33 -86.6(4) . . . . ?
C41 Fe3 C34 C33 -171.0(5) . . . . ?
C37 Fe3 C34 C33 38.4(3) . . . . ?
C43 C34 C35 C36 179.2(5) . . . . ?
C33 C34 C35 C36 0.2(6) . . . . ?
Fe3 C34 C35 C36 60.3(4) . . . . ?
C43 C34 C35 Fe3 119.0(5) . . . . ?
C33 C34 C35 Fe3 -60.1(3) . . . . ?
C42 Fe3 C35 C36 151.4(5) . . . . ?
C34 Fe3 C35 C36 -118.1(4) . . . . ?
C40 Fe3 C35 C36 69.9(4) . . . . ?
C39 Fe3 C35 C36 37.4(11) . . . . ?
C38 Fe3 C35 C36 -172.5(5) . . . . ?
C41 Fe3 C35 C36 109.6(4) . . . . ?
C37 Fe3 C35 C36 -37.5(3) . . . . ?
C33 Fe3 C35 C36 -80.7(3) . . . . ?
C42 Fe3 C35 C34 -90.5(5) . . . . ?
C36 Fe3 C35 C34 118.1(4) . . . . ?
C40 Fe3 C35 C34 -172.0(3) . . . . ?
C39 Fe3 C35 C34 155.5(10) . . . . ?
C38 Fe3 C35 C34 -54.4(6) . . . . ?
C41 Fe3 C35 C34 -132.3(4) . . . . ?
C37 Fe3 C35 C34 80.6(3) . . . . ?
C33 Fe3 C35 C34 37.3(3) . . . . ?
C34 C35 C36 C37 -0.1(6) . . . . ?
Fe3 C35 C36 C37 60.1(4) . . . . ?
C34 C35 C36 Fe3 -60.2(3) . . . . ?
C35 Fe3 C36 C37 -119.1(4) . . . . ?
C42 Fe3 C36 C37 -174.9(6) . . . . ?
C34 Fe3 C36 C37 -80.4(3) . . . . ?
C40 Fe3 C36 C37 111.1(3) . . . . ?
C39 Fe3 C36 C37 71.0(4) . . . . ?
C38 Fe3 C36 C37 43.2(14) . . . . ?
C41 Fe3 C36 C37 153.2(3) . . . . ?
C33 Fe3 C36 C37 -36.0(3) . . . . ?
C42 Fe3 C36 C35 -55.8(7) . . . . ?
C34 Fe3 C36 C35 38.7(3) . . . . ?
C40 Fe3 C36 C35 -129.9(3) . . . . ?
C39 Fe3 C36 C35 -170.0(3) . . . . ?
C38 Fe3 C36 C35 162.3(13) . . . . ?
C41 Fe3 C36 C35 -87.7(4) . . . . ?
C37 Fe3 C36 C35 119.1(4) . . . . ?
C33 Fe3 C36 C35 83.1(3) . . . . ?
C35 C36 C37 C33 0.0(6) . . . . ?
Fe3 C36 C37 C33 59.0(4) . . . . ?
C35 C36 C37 Fe3 -59.0(4) . . . . ?
C34 C33 C37 C36 0.1(6) . . . . ?
Au3 C33 C37 C36 -172.8(4) . . . . ?
Fe3 C33 C37 C36 -57.8(4) . . . . ?
C34 C33 C37 Fe3 57.9(3) . . . . ?
Au3 C33 C37 Fe3 -115.1(4) . . . . ?
C35 Fe3 C37 C36 38.2(3) . . . . ?
C42 Fe3 C37 C36 164.2(16) . . . . ?
C34 Fe3 C37 C36 82.8(3) . . . . ?
C40 Fe3 C37 C36 -85.4(4) . . . . ?
C39 Fe3 C37 C36 -128.6(4) . . . . ?
C38 Fe3 C37 C36 -169.0(4) . . . . ?
C41 Fe3 C37 C36 -51.4(6) . . . . ?
C33 Fe3 C37 C36 122.1(4) . . . . ?
C35 Fe3 C37 C33 -83.9(3) . . . . ?
C42 Fe3 C37 C33 42.1(17) . . . . ?
C34 Fe3 C37 C33 -39.3(3) . . . . ?
C36 Fe3 C37 C33 -122.1(4) . . . . ?
C40 Fe3 C37 C33 152.5(3) . . . . ?
C39 Fe3 C37 C33 109.3(4) . . . . ?
C38 Fe3 C37 C33 68.9(4) . . . . ?
C41 Fe3 C37 C33 -173.5(5) . . . . ?
C35 Fe3 C38 C42 -52.7(8) . . . . ?
C34 Fe3 C38 C42 -89.9(6) . . . . ?
C36 Fe3 C38 C42 151.2(12) . . . . ?
C40 Fe3 C38 C42 79.3(6) . . . . ?
C39 Fe3 C38 C42 117.6(7) . . . . ?
C41 Fe3 C38 C42 36.1(5) . . . . ?
C37 Fe3 C38 C42 -173.3(5) . . . . ?
C33 Fe3 C38 C42 -133.9(5) . . . . ?
C35 Fe3 C38 C39 -170.2(4) . . . . ?
C42 Fe3 C38 C39 -117.6(7) . . . . ?
C34 Fe3 C38 C39 152.5(4) . . . . ?
C36 Fe3 C38 C39 33.7(15) . . . . ?
C40 Fe3 C38 C39 -38.2(4) . . . . ?
C41 Fe3 C38 C39 -81.4(5) . . . . ?
C37 Fe3 C38 C39 69.1(5) . . . . ?
C33 Fe3 C38 C39 108.6(4) . . . . ?
C42 C38 C39 C40 0.3(7) . . . . ?
Fe3 C38 C39 C40 59.7(4) . . . . ?
C42 C38 C39 Fe3 -59.4(4) . . . . ?
C35 Fe3 C39 C40 40.0(12) . . . . ?
C42 Fe3 C39 C40 -79.3(5) . . . . ?
C34 Fe3 C39 C40 -173.4(5) . . . . ?
C36 Fe3 C39 C40 70.5(5) . . . . ?
C38 Fe3 C39 C40 -118.2(6) . . . . ?
C41 Fe3 C39 C40 -36.8(5) . . . . ?
C37 Fe3 C39 C40 110.4(4) . . . . ?
C33 Fe3 C39 C40 153.1(4) . . . . ?
C35 Fe3 C39 C38 158.2(9) . . . . ?
C42 Fe3 C39 C38 38.9(5) . . . . ?
C34 Fe3 C39 C38 -55.3(6) . . . . ?
C36 Fe3 C39 C38 -171.4(4) . . . . ?
C40 Fe3 C39 C38 118.2(6) . . . . ?
C41 Fe3 C39 C38 81.4(5) . . . . ?
C37 Fe3 C39 C38 -131.4(4) . . . . ?
C33 Fe3 C39 C38 -88.7(4) . . . . ?
C38 C39 C40 C41 -0.2(7) . . . . ?
Fe3 C39 C40 C41 59.4(5) . . . . ?
C38 C39 C40 Fe3 -59.6(4) . . . . ?
C35 Fe3 C40 C41 70.6(6) . . . . ?
C42 Fe3 C40 C41 -36.6(5) . . . . ?
C34 Fe3 C40 C41 43.5(17) . . . . ?
C36 Fe3 C40 C41 110.9(5) . . . . ?
C39 Fe3 C40 C41 -120.0(7) . . . . ?
C38 Fe3 C40 C41 -81.3(6) . . . . ?
C37 Fe3 C40 C41 153.4(5) . . . . ?
C33 Fe3 C40 C41 -171.6(5) . . . . ?
C35 Fe3 C40 C39 -169.3(4) . . . . ?
C42 Fe3 C40 C39 83.5(5) . . . . ?
C34 Fe3 C40 C39 163.5(12) . . . . ?
C36 Fe3 C40 C39 -129.1(4) . . . . ?
C38 Fe3 C40 C39 38.7(4) . . . . ?
C41 Fe3 C40 C39 120.0(7) . . . . ?
C37 Fe3 C40 C39 -86.6(5) . . . . ?
C33 Fe3 C40 C39 -51.5(7) . . . . ?
C39 C40 C41 C42 0.0(8) . . . . ?
Fe3 C40 C41 C42 59.0(5) . . . . ?
C39 C40 C41 Fe3 -59.0(4) . . . . ?
C35 Fe3 C41 C42 110.8(5) . . . . ?
C34 Fe3 C41 C42 70.5(6) . . . . ?
C36 Fe3 C41 C42 154.6(4) . . . . ?
C40 Fe3 C41 C42 -120.0(7) . . . . ?
C39 Fe3 C41 C42 -82.5(5) . . . . ?
C38 Fe3 C41 C42 -37.8(5) . . . . ?
C37 Fe3 C41 C42 -171.0(4) . . . . ?
C33 Fe3 C41 C42 33.9(18) . . . . ?
C35 Fe3 C41 C40 -129.1(5) . . . . ?
C42 Fe3 C41 C40 120.0(7) . . . . ?
C34 Fe3 C41 C40 -169.4(4) . . . . ?
C36 Fe3 C41 C40 -85.4(5) . . . . ?
C39 Fe3 C41 C40 37.5(5) . . . . ?
C38 Fe3 C41 C40 82.2(5) . . . . ?
C37 Fe3 C41 C40 -51.0(8) . . . . ?
C33 Fe3 C41 C40 154.0(14) . . . . ?
C40 C41 C42 C38 0.2(8) . . . . ?
Fe3 C41 C42 C38 59.2(5) . . . . ?
C40 C41 C42 Fe3 -59.0(5) . . . . ?
C39 C38 C42 C41 -0.3(8) . . . . ?
Fe3 C38 C42 C41 -59.9(5) . . . . ?
C39 C38 C42 Fe3 59.6(4) . . . . ?
C35 Fe3 C42 C41 -85.9(5) . . . . ?
C34 Fe3 C42 C41 -130.6(4) . . . . ?
C36 Fe3 C42 C41 -48.3(8) . . . . ?
C40 Fe3 C42 C41 37.2(4) . . . . ?
C39 Fe3 C42 C41 81.3(5) . . . . ?
C38 Fe3 C42 C41 120.3(7) . . . . ?
C37 Fe3 C42 C41 151.7(15) . . . . ?
C33 Fe3 C42 C41 -172.5(4) . . . . ?
C35 Fe3 C42 C38 153.8(5) . . . . ?
C34 Fe3 C42 C38 109.1(5) . . . . ?
C36 Fe3 C42 C38 -168.5(5) . . . . ?
C40 Fe3 C42 C38 -83.1(5) . . . . ?
C39 Fe3 C42 C38 -39.0(5) . . . . ?
C41 Fe3 C42 C38 -120.3(7) . . . . ?
C37 Fe3 C42 C38 31.4(19) . . . . ?
C33 Fe3 C42 C38 67.2(6) . . . . ?
C45 N3 C43 O3 -3.7(6) . . . . ?
Au4 N3 C43 O3 165.3(3) . . . . ?
C45 N3 C43 C34 176.6(5) . . . . ?
Au4 N3 C43 C34 -14.3(9) . . . . ?
C44 O3 C43 N3 -10.7(6) . . . . ?
C44 O3 C43 C34 169.0(4) . . . . ?
C35 C34 C43 N3 171.1(5) . . . . ?
C33 C34 C43 N3 -10.1(9) . . . . ?
Fe3 C34 C43 N3 -103.6(6) . . . . ?
C35 C34 C43 O3 -8.6(7) . . . . ?
C33 C34 C43 O3 170.3(5) . . . . ?
Fe3 C34 C43 O3 76.8(5) . . . . ?
C43 O3 C44 C45 19.6(6) . . . . ?
C43 N3 C45 C46 -107.2(5) . . . . ?
Au4 N3 C45 C46 82.2(5) . . . . ?
C43 N3 C45 C44 15.7(6) . . . . ?
Au4 N3 C45 C44 -154.8(4) . . . . ?
O3 C44 C45 N3 -20.9(6) . . . . ?
O3 C44 C45 C46 100.8(5) . . . . ?
N3 C45 C46 C48 51.0(10) . . . . ?
C44 C45 C46 C48 -65.0(10) . . . . ?
N3 C45 C46 C48A -51.2(10) . . . . ?
C44 C45 C46 C48A -167.1(9) . . . . ?
N3 C45 C46 C47 -176.6(5) . . . . ?
C44 C45 C46 C47 67.5(7) . . . . ?
N3 Au4 C49 C53 -1(3) . . . . ?
Au3 Au4 C49 C53 -150.8(4) . . . . ?
Au2 Au4 C49 C53 -25.8(4) . . . . ?
N3 Au4 C49 C50 180(100) . . . . ?
Au3 Au4 C49 C50 29.6(5) . . . . ?
Au2 Au4 C49 C50 154.5(4) . . . . ?
N3 Au4 C49 Fe4 -89(3) . . . . ?
Au3 Au4 C49 Fe4 121.0(3) . . . . ?
Au2 Au4 C49 Fe4 -114.0(3) . . . . ?
C51 Fe4 C49 C53 79.6(3) . . . . ?
C57 Fe4 C49 C53 -48.0(9) . . . . ?
C56 Fe4 C49 C53 167.9(7) . . . . ?
C50 Fe4 C49 C53 117.6(4) . . . . ?
C54 Fe4 C49 C53 -118.6(3) . . . . ?
C58 Fe4 C49 C53 -77.4(4) . . . . ?
C55 Fe4 C49 C53 -160.6(4) . . . . ?
C52 Fe4 C49 C53 36.4(3) . . . . ?
C51 Fe4 C49 C50 -38.1(3) . . . . ?
C57 Fe4 C49 C50 -165.7(8) . . . . ?
C56 Fe4 C49 C50 50.2(8) . . . . ?
C54 Fe4 C49 C50 123.7(4) . . . . ?
C58 Fe4 C49 C50 164.9(3) . . . . ?
C55 Fe4 C49 C50 81.8(4) . . . . ?
C52 Fe4 C49 C50 -81.2(3) . . . . ?
C53 Fe4 C49 C50 -117.6(4) . . . . ?
C51 Fe4 C49 Au4 -162.6(4) . . . . ?
C57 Fe4 C49 Au4 69.8(9) . . . . ?
C56 Fe4 C49 Au4 -74.3(8) . . . . ?
C50 Fe4 C49 Au4 -124.6(4) . . . . ?
C54 Fe4 C49 Au4 -0.8(4) . . . . ?
C58 Fe4 C49 Au4 40.4(4) . . . . ?
C55 Fe4 C49 Au4 -42.8(4) . . . . ?
C52 Fe4 C49 Au4 154.3(4) . . . . ?
C53 Fe4 C49 Au4 117.8(4) . . . . ?
C53 C49 C50 C51 -0.5(5) . . . . ?
Au4 C49 C50 C51 179.2(4) . . . . ?
Fe4 C49 C50 C51 57.9(3) . . . . ?
C53 C49 C50 C59 -177.9(5) . . . . ?
Au4 C49 C50 C59 1.8(8) . . . . ?
Fe4 C49 C50 C59 -119.5(5) . . . . ?
C53 C49 C50 Fe4 -58.4(3) . . . . ?
Au4 C49 C50 Fe4 121.3(4) . . . . ?
C51 Fe4 C50 C49 120.2(4) . . . . ?
C57 Fe4 C50 C49 167.8(7) . . . . ?
C56 Fe4 C50 C49 -158.9(4) . . . . ?
C54 Fe4 C50 C49 -75.5(4) . . . . ?
C58 Fe4 C50 C49 -41.4(9) . . . . ?
C55 Fe4 C50 C49 -117.6(4) . . . . ?
C52 Fe4 C50 C49 82.1(3) . . . . ?
C53 Fe4 C50 C49 38.3(3) . . . . ?
C57 Fe4 C50 C51 47.7(8) . . . . ?
C56 Fe4 C50 C51 80.9(5) . . . . ?
C54 Fe4 C50 C51 164.4(4) . . . . ?
C58 Fe4 C50 C51 -161.5(7) . . . . ?
C55 Fe4 C50 C51 122.3(4) . . . . ?
C52 Fe4 C50 C51 -38.1(3) . . . . ?
C53 Fe4 C50 C51 -81.9(3) . . . . ?
C49 Fe4 C50 C51 -120.2(4) . . . . ?
C51 Fe4 C50 C59 -114.6(5) . . . . ?
C57 Fe4 C50 C59 -67.0(9) . . . . ?
C56 Fe4 C50 C59 -33.7(6) . . . . ?
C54 Fe4 C50 C59 49.7(5) . . . . ?
C58 Fe4 C50 C59 83.9(9) . . . . ?
C55 Fe4 C50 C59 7.6(5) . . . . ?
C52 Fe4 C50 C59 -152.7(5) . . . . ?
C53 Fe4 C50 C59 163.5(5) . . . . ?
C49 Fe4 C50 C59 125.2(5) . . . . ?
C49 C50 C51 C52 1.5(6) . . . . ?
C59 C50 C51 C52 179.1(5) . . . . ?
Fe4 C50 C51 C52 61.8(4) . . . . ?
C49 C50 C51 Fe4 -60.3(3) . . . . ?
C59 C50 C51 Fe4 117.3(5) . . . . ?
C57 Fe4 C51 C52 81.9(4) . . . . ?
C56 Fe4 C51 C52 124.1(4) . . . . ?
C50 Fe4 C51 C52 -117.4(4) . . . . ?
C54 Fe4 C51 C52 -164.8(9) . . . . ?
C58 Fe4 C51 C52 48.2(7) . . . . ?
C55 Fe4 C51 C52 163.9(4) . . . . ?
C53 Fe4 C51 C52 -37.4(3) . . . . ?
C49 Fe4 C51 C52 -80.5(3) . . . . ?
C57 Fe4 C51 C50 -160.7(4) . . . . ?
C56 Fe4 C51 C50 -118.5(4) . . . . ?
C54 Fe4 C51 C50 -47.4(10) . . . . ?
C58 Fe4 C51 C50 165.6(5) . . . . ?
C55 Fe4 C51 C50 -78.8(4) . . . . ?
C52 Fe4 C51 C50 117.4(4) . . . . ?
C53 Fe4 C51 C50 80.0(3) . . . . ?
C49 Fe4 C51 C50 36.9(3) . . . . ?
C50 C51 C52 C53 -1.8(6) . . . . ?
Fe4 C51 C52 C53 59.2(4) . . . . ?
C50 C51 C52 Fe4 -61.0(4) . . . . ?
C57 Fe4 C52 C51 -116.5(4) . . . . ?
C56 Fe4 C52 C51 -75.0(4) . . . . ?
C50 Fe4 C52 C51 39.7(3) . . . . ?
C54 Fe4 C52 C51 168.8(6) . . . . ?
C58 Fe4 C52 C51 -158.8(3) . . . . ?
C55 Fe4 C52 C51 -45.3(9) . . . . ?
C53 Fe4 C52 C51 119.8(4) . . . . ?
C49 Fe4 C52 C51 83.6(3) . . . . ?
C51 Fe4 C52 C53 -119.8(4) . . . . ?
C57 Fe4 C52 C53 123.7(3) . . . . ?
C56 Fe4 C52 C53 165.2(4) . . . . ?
C50 Fe4 C52 C53 -80.0(3) . . . . ?
C54 Fe4 C52 C53 49.0(7) . . . . ?
C58 Fe4 C52 C53 81.4(4) . . . . ?
C55 Fe4 C52 C53 -165.1(8) . . . . ?
C49 Fe4 C52 C53 -36.2(3) . . . . ?
C51 C52 C53 C49 1.6(6) . . . . ?
Fe4 C52 C53 C49 59.8(4) . . . . ?
C51 C52 C53 Fe4 -58.2(4) . . . . ?
C50 C49 C53 C52 -0.7(6) . . . . ?
Au4 C49 C53 C52 179.6(4) . . . . ?
Fe4 C49 C53 C52 -58.5(4) . . . . ?
C50 C49 C53 Fe4 57.9(3) . . . . ?
Au4 C49 C53 Fe4 -121.8(4) . . . . ?
C51 Fe4 C53 C52 37.2(3) . . . . ?
C57 Fe4 C53 C52 -75.9(4) . . . . ?
C56 Fe4 C53 C52 -42.8(10) . . . . ?
C50 Fe4 C53 C52 82.8(3) . . . . ?
C54 Fe4 C53 C52 -159.1(4) . . . . ?
C58 Fe4 C53 C52 -117.0(4) . . . . ?
C55 Fe4 C53 C52 167.8(6) . . . . ?
C49 Fe4 C53 C52 121.5(4) . . . . ?
C51 Fe4 C53 C49 -84.3(3) . . . . ?
C57 Fe4 C53 C49 162.6(3) . . . . ?
C56 Fe4 C53 C49 -164.2(8) . . . . ?
C50 Fe4 C53 C49 -38.7(3) . . . . ?
C54 Fe4 C53 C49 79.5(4) . . . . ?
C58 Fe4 C53 C49 121.6(3) . . . . ?
C55 Fe4 C53 C49 46.3(8) . . . . ?
C52 Fe4 C53 C49 -121.5(4) . . . . ?
C51 Fe4 C54 C58 -159.5(8) . . . . ?
C57 Fe4 C54 C58 -38.3(4) . . . . ?
C56 Fe4 C54 C58 -82.2(5) . . . . ?
C50 Fe4 C54 C58 163.5(4) . . . . ?
C55 Fe4 C54 C58 -118.7(7) . . . . ?
C52 Fe4 C54 C58 45.3(9) . . . . ?
C53 Fe4 C54 C58 80.5(5) . . . . ?
C49 Fe4 C54 C58 122.1(4) . . . . ?
C51 Fe4 C54 C55 -40.8(11) . . . . ?
C57 Fe4 C54 C55 80.4(5) . . . . ?
C56 Fe4 C54 C55 36.5(5) . . . . ?
C50 Fe4 C54 C55 -77.8(5) . . . . ?
C58 Fe4 C54 C55 118.7(7) . . . . ?
C52 Fe4 C54 C55 164.0(6) . . . . ?
C53 Fe4 C54 C55 -160.9(4) . . . . ?
C49 Fe4 C54 C55 -119.2(5) . . . . ?
C58 C54 C55 C56 0.6(8) . . . . ?
Fe4 C54 C55 C56 -59.3(5) . . . . ?
C58 C54 C55 Fe4 59.9(4) . . . . ?
C51 Fe4 C55 C56 -74.0(5) . . . . ?
C57 Fe4 C55 C56 38.3(5) . . . . ?
C50 Fe4 C55 C56 -117.9(5) . . . . ?
C54 Fe4 C55 C56 119.9(7) . . . . ?
C58 Fe4 C55 C56 82.1(5) . . . . ?
C52 Fe4 C55 C56 -39.7(11) . . . . ?
C53 Fe4 C55 C56 165.7(6) . . . . ?
C49 Fe4 C55 C56 -160.9(4) . . . . ?
C51 Fe4 C55 C54 166.1(4) . . . . ?
C57 Fe4 C55 C54 -81.6(5) . . . . ?
C56 Fe4 C55 C54 -119.9(7) . . . . ?
C50 Fe4 C55 C54 122.2(4) . . . . ?
C58 Fe4 C55 C54 -37.8(4) . . . . ?
C52 Fe4 C55 C54 -159.6(7) . . . . ?
C53 Fe4 C55 C54 45.8(9) . . . . ?
C49 Fe4 C55 C54 79.2(5) . . . . ?
C54 C55 C56 C57 -1.0(8) . . . . ?
Fe4 C55 C56 C57 -60.1(5) . . . . ?
C54 C55 C56 Fe4 59.2(5) . . . . ?
C51 Fe4 C56 C55 124.6(5) . . . . ?
C57 Fe4 C56 C55 -118.3(7) . . . . ?
C50 Fe4 C56 C55 80.6(5) . . . . ?
C54 Fe4 C56 C55 -37.5(5) . . . . ?
C58 Fe4 C56 C55 -81.2(5) . . . . ?
C52 Fe4 C56 C55 165.5(4) . . . . ?
C53 Fe4 C56 C55 -161.8(7) . . . . ?
C49 Fe4 C56 C55 44.4(9) . . . . ?
C51 Fe4 C56 C57 -117.1(5) . . . . ?
C50 Fe4 C56 C57 -161.0(4) . . . . ?
C54 Fe4 C56 C57 80.8(5) . . . . ?
C58 Fe4 C56 C57 37.2(5) . . . . ?
C55 Fe4 C56 C57 118.3(7) . . . . ?
C52 Fe4 C56 C57 -76.1(5) . . . . ?
C53 Fe4 C56 C57 -43.4(11) . . . . ?
C49 Fe4 C56 C57 162.8(6) . . . . ?
C55 C56 C57 C58 1.0(8) . . . . ?
Fe4 C56 C57 C58 -59.8(5) . . . . ?
C55 C56 C57 Fe4 60.8(5) . . . . ?
C51 Fe4 C57 C56 81.1(5) . . . . ?
C50 Fe4 C57 C56 45.9(10) . . . . ?
C54 Fe4 C57 C56 -81.5(5) . . . . ?
C58 Fe4 C57 C56 -119.8(7) . . . . ?
C55 Fe4 C57 C56 -37.4(5) . . . . ?
C52 Fe4 C57 C56 123.4(5) . . . . ?
C53 Fe4 C57 C56 165.0(5) . . . . ?
C49 Fe4 C57 C56 -158.9(7) . . . . ?
C51 Fe4 C57 C58 -159.1(4) . . . . ?
C56 Fe4 C57 C58 119.8(7) . . . . ?
C50 Fe4 C57 C58 165.7(6) . . . . ?
C54 Fe4 C57 C58 38.3(4) . . . . ?
C55 Fe4 C57 C58 82.5(5) . . . . ?
C52 Fe4 C57 C58 -116.7(4) . . . . ?
C53 Fe4 C57 C58 -75.2(5) . . . . ?
C49 Fe4 C57 C58 -39.1(10) . . . . ?
C56 C57 C58 C54 -0.7(7) . . . . ?
Fe4 C57 C58 C54 -60.1(4) . . . . ?
C56 C57 C58 Fe4 59.5(5) . . . . ?
C55 C54 C58 C57 0.1(7) . . . . ?
Fe4 C54 C58 C57 59.8(4) . . . . ?
C55 C54 C58 Fe4 -59.8(5) . . . . ?
C51 Fe4 C58 C57 47.5(8) . . . . ?
C56 Fe4 C58 C57 -37.3(5) . . . . ?
C50 Fe4 C58 C57 -163.2(7) . . . . ?
C54 Fe4 C58 C57 -117.8(6) . . . . ?
C55 Fe4 C58 C57 -79.8(5) . . . . ?
C52 Fe4 C58 C57 81.7(5) . . . . ?
C53 Fe4 C58 C57 124.2(4) . . . . ?
C49 Fe4 C58 C57 165.6(4) . . . . ?
C51 Fe4 C58 C54 165.4(6) . . . . ?
C57 Fe4 C58 C54 117.8(6) . . . . ?
C56 Fe4 C58 C54 80.6(5) . . . . ?
C50 Fe4 C58 C54 -45.3(9) . . . . ?
C55 Fe4 C58 C54 38.0(5) . . . . ?
C52 Fe4 C58 C54 -160.5(4) . . . . ?
C53 Fe4 C58 C54 -118.0(4) . . . . ?
C49 Fe4 C58 C54 -76.6(5) . . . . ?
C61 N4 C59 O4 -3.4(6) . . . . ?
Au3 N4 C59 O4 175.9(3) . . . . ?
C61 N4 C59 C50 179.5(5) . . . . ?
Au3 N4 C59 C50 -1.3(8) . . . . ?
C60 O4 C59 N4 2.5(6) . . . . ?
C60 O4 C59 C50 179.9(4) . . . . ?
C49 C50 C59 N4 -28.9(9) . . . . ?
C51 C50 C59 N4 154.0(5) . . . . ?
Fe4 C50 C59 N4 -122.4(5) . . . . ?
C49 C50 C59 O4 154.0(5) . . . . ?
C51 C50 C59 O4 -23.1(7) . . . . ?
Fe4 C50 C59 O4 60.4(6) . . . . ?
C59 O4 C60 C61 -0.5(5) . . . . ?
C59 N4 C61 C62 -122.9(5) . . . . ?
Au3 N4 C61 C62 57.7(5) . . . . ?
C59 N4 C61 C60 2.7(5) . . . . ?
Au3 N4 C61 C60 -176.7(3) . . . . ?
O4 C60 C61 N4 -1.2(5) . . . . ?
O4 C60 C61 C62 121.9(5) . . . . ?
N4 C61 C62 C64 -179.7(4) . . . . ?
C60 C61 C62 C64 62.4(6) . . . . ?
N4 C61 C62 C63 55.5(6) . . . . ?
C60 C61 C62 C63 -62.4(6) . . . . ?
Cl2Z C1Z Cl1Z C1Z -116(3) . . . 8_667 ?
Cl2W C1W Cl1W Cl1W 110(2) . . . 7_557 ?

_diffrn_measured_fraction_theta_max 0.996
_diffrn_reflns_theta_full        28.36
_diffrn_measured_fraction_theta_full 0.996
_refine_diff_density_max         1.223
_refine_diff_density_min         -1.735
_refine_diff_density_rms         0.129
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_s2136lm
_database_code_depnum_ccdc_archive 'CCDC 1056863'
_audit_update_record             
;
2015-03-30 deposited with the CCDC.
2015-09-23 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 'compound 8' 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C32 H36 Au2 Cl2 Fe2 N2 O2'
_chemical_absolute_configuration ad
_chemical_formula_sum            'C32 H36 Au2 Cl2 Fe2 N2 O2'
_chemical_formula_weight         1057.16

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'P 21 21 2'
_symmetry_space_group_name_Hall  'P 2 2ab'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'-x+1/2, y+1/2, -z'
'x+1/2, -y+1/2, -z'

_cell_length_a                   10.8177(7)
_cell_length_b                   18.8289(12)
_cell_length_c                   7.6272(5)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     1553.55(17)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    3738
_cell_measurement_theta_min      2.16
_cell_measurement_theta_max      28.50

_exptl_crystal_description       prism
_exptl_crystal_colour            brown-yellow
_exptl_crystal_size_max          0.33
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.07
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.260
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1004
_exptl_absorpt_coefficient_mu    10.535
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.0844
_exptl_absorpt_correction_T_max  0.5311
_exptl_absorpt_process_details   'SADABS, Bruker 2008'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  Triumph
_diffrn_measurement_device_type  'Bruker Kappa APEXII Duo'
_diffrn_measurement_method       'Omega + Phi Scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        0
_diffrn_reflns_number            15326
_diffrn_reflns_av_R_equivalents  0.0366
_diffrn_reflns_av_sigmaI/netI    0.0427
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_theta_min         2.16
_diffrn_reflns_theta_max         28.50
_reflns_number_total             3939
_reflns_number_gt                3738
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEXII Software Suite, 2008'
_computing_cell_refinement       'Bruker APEXII Software Suite, 2008'
_computing_data_reduction        'Bruker APEXII Software Suite, 2008'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'SHELXTL-plus, XP (Sheldrick, 1991)'
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0001P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.00043(6)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   -0.006(5)
_refine_ls_number_reflns         3939
_refine_ls_number_parameters     203
_refine_ls_number_restraints     12
_refine_ls_R_factor_all          0.0217
_refine_ls_R_factor_gt           0.0192
_refine_ls_wR_factor_ref         0.0394
_refine_ls_wR_factor_gt          0.0389
_refine_ls_goodness_of_fit_ref   0.922
_refine_ls_restrained_S_all      0.923
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 1.097782(14) 0.961465(7) 0.85003(2) 0.01070(4) Uani 1 1 d . . .
Fe1 Fe 0.98138(5) 0.78284(3) 0.84086(9) 0.01294(11) Uani 1 1 d . . .
Cl1 Cl 1.28621(10) 0.89454(5) 0.88317(15) 0.0238(2) Uani 1 1 d . . .
C1 C 0.8689(4) 0.86182(19) 0.9230(5) 0.0135(8) Uani 1 1 d . . .
O1 O 0.6866(3) 0.85663(14) 0.7505(4) 0.0178(6) Uani 1 1 d . . .
N1 N 0.7919(3) 0.95870(17) 0.7412(4) 0.0144(6) Uani 1 1 d . . .
C2 C 0.9978(4) 0.8823(2) 0.9548(5) 0.0118(8) Uani 1 1 d . . .
C3 C 1.0458(4) 0.82974(19) 1.0695(5) 0.0156(9) Uani 1 1 d . . .
H3 H 1.1278 0.8289 1.1141 0.019 Uiso 1 1 calc R . .
C4 C 0.9532(4) 0.7784(2) 1.1078(5) 0.0175(9) Uani 1 1 d . . .
H4 H 0.9632 0.7383 1.1820 0.021 Uiso 1 1 calc R . .
C5 C 0.8436(4) 0.79697(19) 1.0171(5) 0.0154(9) Uani 1 1 d . . .
H5 H 0.7677 0.7715 1.0182 0.018 Uiso 1 1 calc R . .
C6 C 0.9198(5) 0.7472(2) 0.6018(6) 0.0261(11) Uani 1 1 d . . .
H6 H 0.8442 0.7597 0.5465 0.031 Uiso 1 1 calc R . .
C7 C 1.0339(5) 0.7826(2) 0.5824(5) 0.0226(10) Uani 1 1 d . . .
H7 H 1.0483 0.8233 0.5117 0.027 Uiso 1 1 calc R . .
C8 C 1.1232(4) 0.7473(2) 0.6862(5) 0.0191(9) Uani 1 1 d . . .
H8 H 1.2078 0.7601 0.6962 0.023 Uiso 1 1 calc R . .
C9 C 1.0653(5) 0.6893(2) 0.7730(6) 0.0242(11) Uani 1 1 d . . .
H9 H 1.1034 0.6568 0.8515 0.029 Uiso 1 1 calc R . .
C10 C 0.9382(5) 0.6894(2) 0.7188(6) 0.0274(12) Uani 1 1 d . . .
H10 H 0.8768 0.6564 0.7550 0.033 Uiso 1 1 calc R . .
C11 C 0.7837(4) 0.89543(19) 0.8029(5) 0.0125(8) Uani 1 1 d . . .
C12 C 0.6093(4) 0.90409(18) 0.6454(6) 0.0212(8) Uani 1 1 d . . .
H12A H 0.5336 0.9175 0.7103 0.025 Uiso 1 1 calc R . .
H12B H 0.5852 0.8811 0.5338 0.025 Uiso 1 1 calc R . .
C13 C 0.6900(4) 0.96913(19) 0.6113(5) 0.0178(9) Uani 1 1 d . C .
H13 H 0.6425 1.0128 0.6435 0.021 Uiso 1 1 calc R . .
C14 C 0.7379(5) 0.9772(2) 0.4256(6) 0.0283(11) Uani 1 1 d . . .
H14 H 0.6690 0.9777 0.3436 0.034 Uiso 0.60 1 d P A 1
H14A H 0.7841 1.0210 0.4249 0.034 Uiso 0.40 1 d P B 2
C15 C 0.8248(6) 0.9213(3) 0.3741(9) 0.0614(19) Uani 1 1 d . C .
H15A H 0.7862 0.8747 0.3913 0.092 Uiso 1 1 calc R . .
H15B H 0.8996 0.9246 0.4462 0.092 Uiso 1 1 calc R . .
H15C H 0.8469 0.9271 0.2503 0.092 Uiso 1 1 calc R . .
C16 C 0.8066(9) 1.0491(4) 0.4043(11) 0.036(2) Uani 0.60 1 d PU C 1
H16A H 0.8955 1.0418 0.4209 0.054 Uiso 0.60 1 calc PR C 1
H16B H 0.7761 1.0828 0.4920 0.054 Uiso 0.60 1 calc PR C 1
H16C H 0.7915 1.0680 0.2865 0.054 Uiso 0.60 1 calc PR C 1
C16A C 0.6317(12) 0.9906(6) 0.2998(15) 0.030(3) Uani 0.40 1 d PU C 2
H16D H 0.6557 0.9756 0.1816 0.045 Uiso 0.40 1 calc PR C 2
H16E H 0.6118 1.0414 0.2990 0.045 Uiso 0.40 1 calc PR C 2
H16F H 0.5591 0.9635 0.3377 0.045 Uiso 0.40 1 calc PR C 2


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C2 2.007(4) . ?
Au1 N1 2.091(3) 2_775 ?
Au1 Cl1 2.4097(11) . ?
Au1 Au1 2.5654(3) 2_775 ?
Fe1 C1 2.021(4) . ?
Fe1 C5 2.025(4) . ?
Fe1 C10 2.045(4) . ?
Fe1 C8 2.048(4) . ?
Fe1 C9 2.049(4) . ?
Fe1 C7 2.052(4) . ?
Fe1 C6 2.054(4) . ?
Fe1 C4 2.060(4) . ?
Fe1 C2 2.072(4) . ?
Fe1 C3 2.075(4) . ?
C1 C5 1.443(5) . ?
C1 C11 1.445(6) . ?
C1 C2 1.467(6) . ?
O1 C11 1.340(5) . ?
O1 C12 1.463(5) . ?
N1 C11 1.284(5) . ?
N1 C13 1.495(5) . ?
N1 Au1 2.091(3) 2_775 ?
C2 C3 1.419(5) . ?
C3 C4 1.422(6) . ?
C3 H3 0.9500 . ?
C4 C5 1.417(6) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 C7 1.412(7) . ?
C6 C10 1.421(7) . ?
C6 H6 0.9500 . ?
C7 C8 1.415(6) . ?
C7 H7 0.9500 . ?
C8 C9 1.422(6) . ?
C8 H8 0.9500 . ?
C9 C10 1.436(7) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C12 C13 1.526(5) . ?
C12 H12A 0.9900 . ?
C12 H12B 0.9900 . ?
C13 C14 1.516(6) . ?
C13 H13 1.0000 . ?
C14 C15 1.465(7) . ?
C14 C16A 1.518(12) . ?
C14 C16 1.553(9) . ?
C14 H14 0.9731 . ?
C14 H14A 0.9650 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 H14A 0.6028 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C16A H14 0.5771 . ?
C16A H16D 0.9800 . ?
C16A H16E 0.9800 . ?
C16A H16F 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 Au1 N1 177.70(15) . 2_775 ?
C2 Au1 Cl1 91.46(12) . . ?
N1 Au1 Cl1 86.25(10) 2_775 . ?
C2 Au1 Au1 88.62(12) . 2_775 ?
N1 Au1 Au1 93.68(9) 2_775 2_775 ?
Cl1 Au1 Au1 173.39(3) . 2_775 ?
C1 Fe1 C5 41.79(15) . . ?
C1 Fe1 C10 129.55(19) . . ?
C5 Fe1 C10 104.30(18) . . ?
C1 Fe1 C8 150.49(16) . . ?
C5 Fe1 C8 167.65(15) . . ?
C10 Fe1 C8 68.11(18) . . ?
C1 Fe1 C9 167.97(18) . . ?
C5 Fe1 C9 127.38(17) . . ?
C10 Fe1 C9 41.08(19) . . ?
C8 Fe1 C9 40.62(17) . . ?
C1 Fe1 C7 117.77(16) . . ?
C5 Fe1 C7 147.36(19) . . ?
C10 Fe1 C7 67.93(19) . . ?
C8 Fe1 C7 40.39(17) . . ?
C9 Fe1 C7 68.46(18) . . ?
C1 Fe1 C6 108.69(18) . . ?
C5 Fe1 C6 113.16(19) . . ?
C10 Fe1 C6 40.57(19) . . ?
C8 Fe1 C6 67.95(18) . . ?
C9 Fe1 C6 68.79(18) . . ?
C7 Fe1 C6 40.22(19) . . ?
C1 Fe1 C4 68.55(16) . . ?
C5 Fe1 C4 40.56(17) . . ?
C10 Fe1 C4 112.42(18) . . ?
C8 Fe1 C4 131.83(18) . . ?
C9 Fe1 C4 106.30(18) . . ?
C7 Fe1 C4 172.1(2) . . ?
C6 Fe1 C4 144.7(2) . . ?
C1 Fe1 C2 41.99(16) . . ?
C5 Fe1 C2 70.50(16) . . ?
C10 Fe1 C2 171.2(2) . . ?
C8 Fe1 C2 118.23(16) . . ?
C9 Fe1 C2 147.68(18) . . ?
C7 Fe1 C2 112.39(16) . . ?
C6 Fe1 C2 134.09(17) . . ?
C4 Fe1 C2 68.57(15) . . ?
C1 Fe1 C3 68.20(16) . . ?
C5 Fe1 C3 68.50(18) . . ?
C10 Fe1 C3 145.64(18) . . ?
C8 Fe1 C3 111.83(18) . . ?
C9 Fe1 C3 115.43(18) . . ?
C7 Fe1 C3 135.66(19) . . ?
C6 Fe1 C3 173.70(18) . . ?
C4 Fe1 C3 40.22(16) . . ?
C2 Fe1 C3 40.02(15) . . ?
C5 C1 C11 124.4(4) . . ?
C5 C1 C2 108.7(4) . . ?
C11 C1 C2 126.6(3) . . ?
C5 C1 Fe1 69.3(2) . . ?
C11 C1 Fe1 120.7(3) . . ?
C2 C1 Fe1 70.9(2) . . ?
C11 O1 C12 106.2(3) . . ?
C11 N1 C13 108.3(3) . . ?
C11 N1 Au1 124.1(3) . 2_775 ?
C13 N1 Au1 126.1(2) . 2_775 ?
C3 C2 C1 105.5(3) . . ?
C3 C2 Au1 124.5(3) . . ?
C1 C2 Au1 129.9(3) . . ?
C3 C2 Fe1 70.1(2) . . ?
C1 C2 Fe1 67.1(2) . . ?
Au1 C2 Fe1 123.40(19) . . ?
C2 C3 C4 110.0(4) . . ?
C2 C3 Fe1 69.9(2) . . ?
C4 C3 Fe1 69.3(2) . . ?
C2 C3 H3 125.0 . . ?
C4 C3 H3 125.0 . . ?
Fe1 C3 H3 127.4 . . ?
C5 C4 C3 108.8(3) . . ?
C5 C4 Fe1 68.4(2) . . ?
C3 C4 Fe1 70.5(2) . . ?
C5 C4 H4 125.6 . . ?
C3 C4 H4 125.6 . . ?
Fe1 C4 H4 127.1 . . ?
C4 C5 C1 107.0(4) . . ?
C4 C5 Fe1 71.0(2) . . ?
C1 C5 Fe1 68.9(2) . . ?
C4 C5 H5 126.5 . . ?
C1 C5 H5 126.5 . . ?
Fe1 C5 H5 125.1 . . ?
C7 C6 C10 107.8(4) . . ?
C7 C6 Fe1 69.8(2) . . ?
C10 C6 Fe1 69.4(2) . . ?
C7 C6 H6 126.1 . . ?
C10 C6 H6 126.1 . . ?
Fe1 C6 H6 126.3 . . ?
C6 C7 C8 108.4(4) . . ?
C6 C7 Fe1 70.0(3) . . ?
C8 C7 Fe1 69.7(2) . . ?
C6 C7 H7 125.8 . . ?
C8 C7 H7 125.8 . . ?
Fe1 C7 H7 126.1 . . ?
C7 C8 C9 108.8(4) . . ?
C7 C8 Fe1 70.0(3) . . ?
C9 C8 Fe1 69.7(2) . . ?
C7 C8 H8 125.6 . . ?
C9 C8 H8 125.6 . . ?
Fe1 C8 H8 126.3 . . ?
C8 C9 C10 106.6(4) . . ?
C8 C9 Fe1 69.6(2) . . ?
C10 C9 Fe1 69.3(3) . . ?
C8 C9 H9 126.7 . . ?
C10 C9 H9 126.7 . . ?
Fe1 C9 H9 125.9 . . ?
C6 C10 C9 108.4(4) . . ?
C6 C10 Fe1 70.1(2) . . ?
C9 C10 Fe1 69.6(2) . . ?
C6 C10 H10 125.8 . . ?
C9 C10 H10 125.8 . . ?
Fe1 C10 H10 126.1 . . ?
N1 C11 O1 116.7(4) . . ?
N1 C11 C1 126.5(4) . . ?
O1 C11 C1 116.8(3) . . ?
O1 C12 C13 104.9(3) . . ?
O1 C12 H12A 110.8 . . ?
C13 C12 H12A 110.8 . . ?
O1 C12 H12B 110.8 . . ?
C13 C12 H12B 110.8 . . ?
H12A C12 H12B 108.8 . . ?
N1 C13 C14 112.4(4) . . ?
N1 C13 C12 101.7(3) . . ?
C14 C13 C12 115.8(4) . . ?
N1 C13 H13 108.9 . . ?
C14 C13 H13 108.9 . . ?
C12 C13 H13 108.9 . . ?
C15 C14 C13 113.5(4) . . ?
C15 C14 C16A 115.9(6) . . ?
C13 C14 C16A 110.4(6) . . ?
C15 C14 C16 106.9(5) . . ?
C13 C14 C16 110.4(4) . . ?
C16A C14 C16 98.6(6) . . ?
C15 C14 H14 109.1 . . ?
C13 C14 H14 109.9 . . ?
C16A C14 H14 9.0 . . ?
C16 C14 H14 106.9 . . ?
C15 C14 H14A 106.3 . . ?
C13 C14 H14A 105.5 . . ?
C16A C14 H14A 104.2 . . ?
C16 C14 H14A 6.2 . . ?
H14 C14 H14A 112.6 . . ?
C14 C15 H15A 109.5 . . ?
C14 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C14 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C14 C16 H14A 9.9 . . ?
C14 C16 H16A 109.5 . . ?
H14A C16 H16A 103.8 . . ?
C14 C16 H16B 109.5 . . ?
H14A C16 H16B 104.8 . . ?
C14 C16 H16C 109.5 . . ?
H14A C16 H16C 119.4 . . ?
C14 C16A H14 15.3 . . ?
C14 C16A H16D 109.5 . . ?
C14 C16A H16E 109.5 . . ?
H16D C16A H16E 109.5 . . ?
C14 C16A H16F 109.5 . . ?
H16D C16A H16F 109.5 . . ?
H16E C16A H16F 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C10 Fe1 C1 C5 63.7(3) . . . . ?
C8 Fe1 C1 C5 -177.8(3) . . . . ?
C9 Fe1 C1 C5 28.3(10) . . . . ?
C7 Fe1 C1 C5 147.0(3) . . . . ?
C6 Fe1 C1 C5 104.2(3) . . . . ?
C4 Fe1 C1 C5 -38.3(3) . . . . ?
C2 Fe1 C1 C5 -119.6(3) . . . . ?
C3 Fe1 C1 C5 -81.7(3) . . . . ?
C5 Fe1 C1 C11 -118.5(4) . . . . ?
C10 Fe1 C1 C11 -54.8(4) . . . . ?
C8 Fe1 C1 C11 63.7(5) . . . . ?
C9 Fe1 C1 C11 -90.2(9) . . . . ?
C7 Fe1 C1 C11 28.5(4) . . . . ?
C6 Fe1 C1 C11 -14.4(4) . . . . ?
C4 Fe1 C1 C11 -156.8(4) . . . . ?
C2 Fe1 C1 C11 121.9(4) . . . . ?
C3 Fe1 C1 C11 159.8(4) . . . . ?
C5 Fe1 C1 C2 119.6(3) . . . . ?
C10 Fe1 C1 C2 -176.7(3) . . . . ?
C8 Fe1 C1 C2 -58.2(4) . . . . ?
C9 Fe1 C1 C2 148.0(8) . . . . ?
C7 Fe1 C1 C2 -93.4(3) . . . . ?
C6 Fe1 C1 C2 -136.2(2) . . . . ?
C4 Fe1 C1 C2 81.4(2) . . . . ?
C3 Fe1 C1 C2 37.9(2) . . . . ?
C5 C1 C2 C3 -0.9(4) . . . . ?
C11 C1 C2 C3 -174.5(4) . . . . ?
Fe1 C1 C2 C3 -60.0(3) . . . . ?
C5 C1 C2 Au1 174.4(3) . . . . ?
C11 C1 C2 Au1 0.7(6) . . . . ?
Fe1 C1 C2 Au1 115.2(3) . . . . ?
C5 C1 C2 Fe1 59.1(3) . . . . ?
C11 C1 C2 Fe1 -114.5(4) . . . . ?
N1 Au1 C2 C3 30(4) 2_775 . . . ?
Cl1 Au1 C2 C3 23.9(3) . . . . ?
Au1 Au1 C2 C3 -149.5(3) 2_775 . . . ?
N1 Au1 C2 C1 -145(3) 2_775 . . . ?
Cl1 Au1 C2 C1 -150.5(3) . . . . ?
Au1 Au1 C2 C1 36.1(3) 2_775 . . . ?
N1 Au1 C2 Fe1 -58(4) 2_775 . . . ?
Cl1 Au1 C2 Fe1 -63.7(2) . . . . ?
Au1 Au1 C2 Fe1 122.9(2) 2_775 . . . ?
C1 Fe1 C2 C3 117.4(3) . . . . ?
C5 Fe1 C2 C3 79.5(3) . . . . ?
C10 Fe1 C2 C3 134.3(11) . . . . ?
C8 Fe1 C2 C3 -91.0(3) . . . . ?
C9 Fe1 C2 C3 -50.7(4) . . . . ?
C7 Fe1 C2 C3 -135.4(3) . . . . ?
C6 Fe1 C2 C3 -176.8(3) . . . . ?
C4 Fe1 C2 C3 36.1(3) . . . . ?
C5 Fe1 C2 C1 -37.9(2) . . . . ?
C10 Fe1 C2 C1 16.9(13) . . . . ?
C8 Fe1 C2 C1 151.6(2) . . . . ?
C9 Fe1 C2 C1 -168.1(3) . . . . ?
C7 Fe1 C2 C1 107.2(3) . . . . ?
C6 Fe1 C2 C1 65.8(3) . . . . ?
C4 Fe1 C2 C1 -81.3(2) . . . . ?
C3 Fe1 C2 C1 -117.4(3) . . . . ?
C1 Fe1 C2 Au1 -123.7(3) . . . . ?
C5 Fe1 C2 Au1 -161.7(3) . . . . ?
C10 Fe1 C2 Au1 -106.8(12) . . . . ?
C8 Fe1 C2 Au1 27.9(3) . . . . ?
C9 Fe1 C2 Au1 68.2(4) . . . . ?
C7 Fe1 C2 Au1 -16.6(3) . . . . ?
C6 Fe1 C2 Au1 -57.9(4) . . . . ?
C4 Fe1 C2 Au1 155.0(3) . . . . ?
C3 Fe1 C2 Au1 118.9(4) . . . . ?
C1 C2 C3 C4 0.4(4) . . . . ?
Au1 C2 C3 C4 -175.2(3) . . . . ?
Fe1 C2 C3 C4 -57.7(3) . . . . ?
C1 C2 C3 Fe1 58.1(2) . . . . ?
Au1 C2 C3 Fe1 -117.5(3) . . . . ?
C1 Fe1 C3 C2 -39.8(2) . . . . ?
C5 Fe1 C3 C2 -84.9(3) . . . . ?
C10 Fe1 C3 C2 -168.8(3) . . . . ?
C8 Fe1 C3 C2 108.4(3) . . . . ?
C9 Fe1 C3 C2 152.7(3) . . . . ?
C7 Fe1 C3 C2 68.2(3) . . . . ?
C6 Fe1 C3 C2 21.7(17) . . . . ?
C4 Fe1 C3 C2 -121.9(4) . . . . ?
C1 Fe1 C3 C4 82.1(3) . . . . ?
C5 Fe1 C3 C4 37.0(2) . . . . ?
C10 Fe1 C3 C4 -46.9(4) . . . . ?
C8 Fe1 C3 C4 -129.7(3) . . . . ?
C9 Fe1 C3 C4 -85.4(3) . . . . ?
C7 Fe1 C3 C4 -169.9(3) . . . . ?
C6 Fe1 C3 C4 143.6(16) . . . . ?
C2 Fe1 C3 C4 121.9(4) . . . . ?
C2 C3 C4 C5 0.3(5) . . . . ?
Fe1 C3 C4 C5 -57.7(3) . . . . ?
C2 C3 C4 Fe1 58.1(3) . . . . ?
C1 Fe1 C4 C5 39.4(2) . . . . ?
C10 Fe1 C4 C5 -85.9(3) . . . . ?
C8 Fe1 C4 C5 -166.0(2) . . . . ?
C9 Fe1 C4 C5 -129.1(2) . . . . ?
C7 Fe1 C4 C5 -176.9(11) . . . . ?
C6 Fe1 C4 C5 -53.0(4) . . . . ?
C2 Fe1 C4 C5 84.7(2) . . . . ?
C3 Fe1 C4 C5 120.6(3) . . . . ?
C1 Fe1 C4 C3 -81.2(2) . . . . ?
C5 Fe1 C4 C3 -120.6(3) . . . . ?
C10 Fe1 C4 C3 153.5(3) . . . . ?
C8 Fe1 C4 C3 73.4(3) . . . . ?
C9 Fe1 C4 C3 110.3(3) . . . . ?
C7 Fe1 C4 C3 62.6(13) . . . . ?
C6 Fe1 C4 C3 -173.5(3) . . . . ?
C2 Fe1 C4 C3 -35.9(2) . . . . ?
C3 C4 C5 C1 -0.9(4) . . . . ?
Fe1 C4 C5 C1 -59.9(3) . . . . ?
C3 C4 C5 Fe1 59.0(3) . . . . ?
C11 C1 C5 C4 174.9(4) . . . . ?
C2 C1 C5 C4 1.1(4) . . . . ?
Fe1 C1 C5 C4 61.2(3) . . . . ?
C11 C1 C5 Fe1 113.7(4) . . . . ?
C2 C1 C5 Fe1 -60.1(3) . . . . ?
C1 Fe1 C5 C4 -117.6(3) . . . . ?
C10 Fe1 C5 C4 107.9(3) . . . . ?
C8 Fe1 C5 C4 57.3(9) . . . . ?
C9 Fe1 C5 C4 69.6(3) . . . . ?
C7 Fe1 C5 C4 179.2(3) . . . . ?
C6 Fe1 C5 C4 149.9(3) . . . . ?
C2 Fe1 C5 C4 -79.5(2) . . . . ?
C3 Fe1 C5 C4 -36.7(2) . . . . ?
C10 Fe1 C5 C1 -134.5(3) . . . . ?
C8 Fe1 C5 C1 174.9(7) . . . . ?
C9 Fe1 C5 C1 -172.8(3) . . . . ?
C7 Fe1 C5 C1 -63.2(4) . . . . ?
C6 Fe1 C5 C1 -92.5(3) . . . . ?
C4 Fe1 C5 C1 117.6(3) . . . . ?
C2 Fe1 C5 C1 38.1(2) . . . . ?
C3 Fe1 C5 C1 80.9(2) . . . . ?
C1 Fe1 C6 C7 111.2(3) . . . . ?
C5 Fe1 C6 C7 155.9(2) . . . . ?
C10 Fe1 C6 C7 -119.1(4) . . . . ?
C8 Fe1 C6 C7 -37.5(2) . . . . ?
C9 Fe1 C6 C7 -81.3(3) . . . . ?
C4 Fe1 C6 C7 -169.8(3) . . . . ?
C2 Fe1 C6 C7 71.1(3) . . . . ?
C3 Fe1 C6 C7 51.8(17) . . . . ?
C1 Fe1 C6 C10 -129.7(3) . . . . ?
C5 Fe1 C6 C10 -85.0(3) . . . . ?
C8 Fe1 C6 C10 81.6(3) . . . . ?
C9 Fe1 C6 C10 37.8(3) . . . . ?
C7 Fe1 C6 C10 119.1(4) . . . . ?
C4 Fe1 C6 C10 -50.7(4) . . . . ?
C2 Fe1 C6 C10 -169.8(3) . . . . ?
C3 Fe1 C6 C10 170.9(15) . . . . ?
C10 C6 C7 C8 0.1(5) . . . . ?
Fe1 C6 C7 C8 59.3(3) . . . . ?
C10 C6 C7 Fe1 -59.2(3) . . . . ?
C1 Fe1 C7 C6 -86.5(3) . . . . ?
C5 Fe1 C7 C6 -44.2(4) . . . . ?
C10 Fe1 C7 C6 37.8(3) . . . . ?
C8 Fe1 C7 C6 119.5(3) . . . . ?
C9 Fe1 C7 C6 82.2(3) . . . . ?
C4 Fe1 C7 C6 132.0(12) . . . . ?
C2 Fe1 C7 C6 -132.7(3) . . . . ?
C3 Fe1 C7 C6 -172.9(3) . . . . ?
C1 Fe1 C7 C8 154.0(2) . . . . ?
C5 Fe1 C7 C8 -163.7(3) . . . . ?
C10 Fe1 C7 C8 -81.7(3) . . . . ?
C9 Fe1 C7 C8 -37.3(3) . . . . ?
C6 Fe1 C7 C8 -119.5(3) . . . . ?
C4 Fe1 C7 C8 12.5(13) . . . . ?
C2 Fe1 C7 C8 107.8(3) . . . . ?
C3 Fe1 C7 C8 67.6(3) . . . . ?
C6 C7 C8 C9 -0.4(5) . . . . ?
Fe1 C7 C8 C9 59.1(3) . . . . ?
C6 C7 C8 Fe1 -59.5(3) . . . . ?
C1 Fe1 C8 C7 -51.9(4) . . . . ?
C5 Fe1 C8 C7 135.0(8) . . . . ?
C10 Fe1 C8 C7 81.2(3) . . . . ?
C9 Fe1 C8 C7 120.0(4) . . . . ?
C6 Fe1 C8 C7 37.3(3) . . . . ?
C4 Fe1 C8 C7 -177.7(3) . . . . ?
C2 Fe1 C8 C7 -92.1(3) . . . . ?
C3 Fe1 C8 C7 -135.9(3) . . . . ?
C1 Fe1 C8 C9 -171.9(3) . . . . ?
C5 Fe1 C8 C9 15.0(9) . . . . ?
C10 Fe1 C8 C9 -38.8(3) . . . . ?
C7 Fe1 C8 C9 -120.0(4) . . . . ?
C6 Fe1 C8 C9 -82.7(3) . . . . ?
C4 Fe1 C8 C9 62.3(3) . . . . ?
C2 Fe1 C8 C9 147.9(3) . . . . ?
C3 Fe1 C8 C9 104.1(3) . . . . ?
C7 C8 C9 C10 0.5(5) . . . . ?
Fe1 C8 C9 C10 59.7(3) . . . . ?
C7 C8 C9 Fe1 -59.2(3) . . . . ?
C1 Fe1 C9 C8 160.5(8) . . . . ?
C5 Fe1 C9 C8 -176.0(3) . . . . ?
C10 Fe1 C9 C8 117.8(4) . . . . ?
C7 Fe1 C9 C8 37.1(3) . . . . ?
C6 Fe1 C9 C8 80.4(3) . . . . ?
C4 Fe1 C9 C8 -136.6(3) . . . . ?
C2 Fe1 C9 C8 -61.1(4) . . . . ?
C3 Fe1 C9 C8 -94.5(3) . . . . ?
C1 Fe1 C9 C10 42.8(10) . . . . ?
C5 Fe1 C9 C10 66.2(3) . . . . ?
C8 Fe1 C9 C10 -117.8(4) . . . . ?
C7 Fe1 C9 C10 -80.7(3) . . . . ?
C6 Fe1 C9 C10 -37.4(3) . . . . ?
C4 Fe1 C9 C10 105.6(3) . . . . ?
C2 Fe1 C9 C10 -178.8(3) . . . . ?
C3 Fe1 C9 C10 147.7(3) . . . . ?
C7 C6 C10 C9 0.2(5) . . . . ?
Fe1 C6 C10 C9 -59.2(3) . . . . ?
C7 C6 C10 Fe1 59.4(3) . . . . ?
C8 C9 C10 C6 -0.4(5) . . . . ?
Fe1 C9 C10 C6 59.5(3) . . . . ?
C8 C9 C10 Fe1 -60.0(3) . . . . ?
C1 Fe1 C10 C6 71.0(3) . . . . ?
C5 Fe1 C10 C6 109.1(3) . . . . ?
C8 Fe1 C10 C6 -81.2(3) . . . . ?
C9 Fe1 C10 C6 -119.6(4) . . . . ?
C7 Fe1 C10 C6 -37.5(3) . . . . ?
C4 Fe1 C10 C6 151.1(3) . . . . ?
C2 Fe1 C10 C6 56.4(13) . . . . ?
C3 Fe1 C10 C6 -178.2(3) . . . . ?
C1 Fe1 C10 C9 -169.4(3) . . . . ?
C5 Fe1 C10 C9 -131.4(3) . . . . ?
C8 Fe1 C10 C9 38.4(3) . . . . ?
C7 Fe1 C10 C9 82.1(3) . . . . ?
C6 Fe1 C10 C9 119.6(4) . . . . ?
C4 Fe1 C10 C9 -89.4(3) . . . . ?
C2 Fe1 C10 C9 176.0(11) . . . . ?
C3 Fe1 C10 C9 -58.7(4) . . . . ?
C13 N1 C11 O1 -4.4(5) . . . . ?
Au1 N1 C11 O1 162.5(3) 2_775 . . . ?
C13 N1 C11 C1 175.4(4) . . . . ?
Au1 N1 C11 C1 -17.7(6) 2_775 . . . ?
C12 O1 C11 N1 -5.5(5) . . . . ?
C12 O1 C11 C1 174.6(3) . . . . ?
C5 C1 C11 N1 166.4(4) . . . . ?
C2 C1 C11 N1 -20.9(6) . . . . ?
Fe1 C1 C11 N1 -109.0(4) . . . . ?
C5 C1 C11 O1 -13.7(6) . . . . ?
C2 C1 C11 O1 158.9(4) . . . . ?
Fe1 C1 C11 O1 70.9(4) . . . . ?
C11 O1 C12 C13 12.6(4) . . . . ?
C11 N1 C13 C14 -112.7(4) . . . . ?
Au1 N1 C13 C14 80.7(4) 2_775 . . . ?
C11 N1 C13 C12 11.7(4) . . . . ?
Au1 N1 C13 C12 -154.8(3) 2_775 . . . ?
O1 C12 C13 N1 -14.3(4) . . . . ?
O1 C12 C13 C14 107.8(4) . . . . ?
N1 C13 C14 C15 50.3(5) . . . . ?
C12 C13 C14 C15 -65.9(6) . . . . ?
N1 C13 C14 C16A -177.7(6) . . . . ?
C12 C13 C14 C16A 66.1(7) . . . . ?
N1 C13 C14 C16 -69.7(5) . . . . ?
C12 C13 C14 C16 174.1(5) . . . . ?

_diffrn_measured_fraction_theta_max 0.997
_diffrn_reflns_theta_full        28.50
_diffrn_measured_fraction_theta_full 0.997
_refine_diff_density_max         1.191
_refine_diff_density_min         -0.650
_refine_diff_density_rms         0.114
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_s2116lm
_database_code_depnum_ccdc_archive 'CCDC 1056865'
_audit_update_record             
;
2015-03-30 deposited with the CCDC.
2015-09-23 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 'compound 8'' 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C32 H36 Au2 Cl2 Fe2 N2 O2'
_chemical_absolute_configuration ad
_chemical_formula_sum            'C32 H36 Au2 Cl2 Fe2 N2 O2'
_chemical_formula_weight         1057.16

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'P 21 21 21'
_symmetry_space_group_name_Hall  'P 2ac 2ab'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'

_cell_length_a                   10.0819(5)
_cell_length_b                   15.2950(6)
_cell_length_c                   20.4679(10)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     3156.2(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    6634
_cell_measurement_theta_min      1.66
_cell_measurement_theta_max      28.34

_exptl_crystal_description       needle
_exptl_crystal_colour            brown-yellow
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.03
_exptl_crystal_size_min          0.03
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.225
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2008
_exptl_absorpt_coefficient_mu    10.371
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.3324
_exptl_absorpt_correction_T_max  0.8012
_exptl_absorpt_process_details   'Blessing, 1995'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  Triumph
_diffrn_measurement_device_type  'Bruker Kappa APEXII Duo'
_diffrn_measurement_method       'Omega + Phi Scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        0
_diffrn_reflns_number            30871
_diffrn_reflns_av_R_equivalents  0.0663
_diffrn_reflns_av_sigmaI/netI    0.0767
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_theta_min         1.66
_diffrn_reflns_theta_max         28.34
_reflns_number_total             7791
_reflns_number_gt                6634
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEXII Software Suite, 2008'
_computing_cell_refinement       'Bruker APEXII Software Suite, 2008'
_computing_data_reduction        'Bruker APEXII Software Suite, 2008'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'SHELXTL-plus, XP (Sheldrick, 1991)'
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0382P)²+18.3844P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.012(11)
_refine_ls_number_reflns         7791
_refine_ls_number_parameters     341
_refine_ls_number_restraints     54
_refine_ls_R_factor_all          0.0623
_refine_ls_R_factor_gt           0.0478
_refine_ls_wR_factor_ref         0.0992
_refine_ls_wR_factor_gt          0.0955
_refine_ls_goodness_of_fit_ref   1.051
_refine_ls_restrained_S_all      1.050
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.41229(3) 0.50341(2) 1.015347(19) 0.01127(9) Uani 1 1 d . . .
Cl1 Cl 0.8563(3) 0.45621(16) 0.92423(19) 0.0289(8) Uani 1 1 d . . .
Fe1 Fe 0.65680(16) 0.53141(10) 1.14979(9) 0.0203(4) Uani 1 1 d . . .
Au2 Au 0.63854(4) 0.47907(2) 0.96465(2) 0.01176(9) Uani 1 1 d . . .
Cl2 Cl 0.1996(3) 0.52905(17) 1.06408(15) 0.0189(6) Uani 1 1 d . . .
Fe2 Fe 0.61302(15) 0.26606(10) 0.88235(8) 0.0151(3) Uani 1 1 d . . .
O1 O 0.7373(8) 0.7318(5) 1.0280(5) 0.0215(18) Uani 1 1 d . . .
N1 N 0.6869(8) 0.6119(5) 0.9741(5) 0.015(2) Uani 1 1 d . . .
C1 C 0.5028(11) 0.5652(7) 1.0888(6) 0.015(2) Uani 1 1 d . . .
O2 O 0.2693(7) 0.3209(5) 0.8772(4) 0.0187(18) Uani 1 1 d . . .
N2 N 0.3208(9) 0.4382(6) 0.9369(5) 0.0168(15) Uani 1 1 d U . .
C2 C 0.6076(10) 0.6287(7) 1.0864(6) 0.014(2) Uani 1 1 d . . .
C3 C 0.6283(12) 0.6645(7) 1.1501(6) 0.018(2) Uani 1 1 d U . .
H3 H 0.6906 0.7085 1.1614 0.021 Uiso 1 1 calc R . .
C4 C 0.5382(12) 0.6218(7) 1.1936(6) 0.021(3) Uani 1 1 d . . .
H4 H 0.5320 0.6311 1.2394 0.025 Uiso 1 1 calc R . .
C5 C 0.4604(11) 0.5636(8) 1.1564(6) 0.020(3) Uani 1 1 d . . .
H5 H 0.3905 0.5285 1.1732 0.024 Uiso 1 1 calc R . .
C6 C 0.6762(13) 0.4089(8) 1.1882(7) 0.027(2) Uani 1 1 d . . .
H6 H 0.6064 0.3736 1.2049 0.032 Uiso 1 1 calc R . .
C7 C 0.7213(13) 0.4100(8) 1.1225(7) 0.027(2) Uani 1 1 d U . .
H7 H 0.6887 0.3751 1.0876 0.032 Uiso 1 1 calc R . .
C8 C 0.8230(15) 0.4723(9) 1.1187(8) 0.043(3) Uani 1 1 d . . .
H8 H 0.8692 0.4894 1.0803 0.052 Uiso 1 1 calc R . .
C9 C 0.8441(13) 0.5047(9) 1.1817(6) 0.035(3) Uani 1 1 d U . .
H9 H 0.9108 0.5453 1.1941 0.042 Uiso 1 1 calc R . .
C10 C 0.7501(15) 0.4669(9) 1.2234(8) 0.043(3) Uani 1 1 d . . .
H10 H 0.7395 0.4796 1.2685 0.052 Uiso 1 1 calc R . .
C11 C 0.6783(10) 0.6552(6) 1.0285(6) 0.0143(16) Uani 1 1 d U . .
C12 C 0.7559(11) 0.6652(7) 0.9247(6) 0.0143(16) Uani 1 1 d . . .
H12 H 0.8335 0.6312 0.9080 0.017 Uiso 1 1 calc R . .
C13 C 0.8077(12) 0.7418(7) 0.9653(7) 0.025(3) Uani 1 1 d . . .
H13A H 0.9049 0.7379 0.9714 0.030 Uiso 1 1 calc R . .
H13B H 0.7859 0.7984 0.9444 0.030 Uiso 1 1 calc R . .
C14 C 0.6658(11) 0.6878(8) 0.8669(6) 0.019(3) Uani 1 1 d . . .
H14 H 0.6413 0.6321 0.8443 0.023 Uiso 1 1 calc R . .
C15 C 0.7403(14) 0.7443(8) 0.8193(7) 0.027(3) Uani 1 1 d . . .
H15A H 0.7483 0.8036 0.8370 0.040 Uiso 1 1 calc R . .
H15B H 0.6922 0.7463 0.7777 0.040 Uiso 1 1 calc R . .
H15C H 0.8290 0.7199 0.8122 0.040 Uiso 1 1 calc R . .
C16 C 0.5335(11) 0.7348(9) 0.8893(7) 0.025(3) Uani 1 1 d . . .
H16A H 0.5555 0.7892 0.9121 0.038 Uiso 1 1 calc R . .
H16B H 0.4841 0.6962 0.9188 0.038 Uiso 1 1 calc R . .
H16C H 0.4790 0.7479 0.8509 0.038 Uiso 1 1 calc R . .
C17 C 0.5919(10) 0.3526(6) 0.9592(6) 0.013(2) Uani 1 1 d . . .
C18 C 0.4692(10) 0.3119(7) 0.9425(5) 0.013(2) Uani 1 1 d . . .
C19 C 0.4805(11) 0.2189(7) 0.9462(6) 0.018(3) Uani 1 1 d . . .
H19 H 0.4139 0.1775 0.9352 0.022 Uiso 1 1 calc R . .
C20 C 0.6098(10) 0.2001(7) 0.9694(6) 0.0166(16) Uani 1 1 d . . .
H20 H 0.6439 0.1439 0.9796 0.020 Uiso 1 1 calc R . .
C21 C 0.6805(11) 0.2823(7) 0.9746(6) 0.0166(16) Uani 1 1 d U . .
H21 H 0.7711 0.2885 0.9864 0.020 Uiso 1 1 calc R . .
C22 C 0.5684(13) 0.2036(8) 0.7970(6) 0.027(3) Uani 1 1 d . . .
H22 H 0.4933 0.1673 0.7899 0.032 Uiso 1 1 calc R . .
C23 C 0.6935(15) 0.1759(10) 0.8199(6) 0.032(3) Uani 1 1 d . . .
H23 H 0.7178 0.1173 0.8293 0.039 Uiso 1 1 calc R . .
C24 C 0.7774(14) 0.2503(9) 0.8265(8) 0.033(3) Uani 1 1 d U . .
H24 H 0.8659 0.2511 0.8424 0.040 Uiso 1 1 calc R . .
C25 C 0.7008(14) 0.3242(9) 0.8044(7) 0.032(2) Uani 1 1 d . . .
H25 H 0.7313 0.3830 0.8023 0.039 Uiso 1 1 calc R . .
C26 C 0.5746(14) 0.2953(9) 0.7864(7) 0.032(2) Uani 1 1 d . . .
H26 H 0.5048 0.3308 0.7700 0.039 Uiso 1 1 calc R . .
C27 C 0.3517(11) 0.3592(7) 0.9209(6) 0.018(2) Uani 1 1 d . . .
C28 C 0.2036(10) 0.4679(7) 0.9030(6) 0.017(2) Uani 1 1 d U . .
H28 H 0.1351 0.4886 0.9348 0.021 Uiso 1 1 calc R . .
C29 C 0.1581(11) 0.3810(7) 0.8694(6) 0.0168(15) Uani 1 1 d . . .
H29A H 0.0776 0.3576 0.8908 0.020 Uiso 1 1 calc R . .
H29B H 0.1388 0.3909 0.8225 0.020 Uiso 1 1 calc R . .
C30 C 0.2421(12) 0.5411(8) 0.8562(7) 0.0248(18) Uani 1 1 d U . .
H30 H 0.2795 0.5893 0.8836 0.030 Uiso 1 1 calc R . .
C31 C 0.3501(11) 0.5151(8) 0.8082(6) 0.0248(18) Uani 1 1 d . . .
H31A H 0.3288 0.4580 0.7892 0.037 Uiso 1 1 calc R . .
H31B H 0.4353 0.5116 0.8310 0.037 Uiso 1 1 calc R . .
H31C H 0.3557 0.5589 0.7733 0.037 Uiso 1 1 calc R . .
C32 C 0.1206(13) 0.5778(8) 0.8230(7) 0.030(3) Uani 1 1 d . . .
H32A H 0.1468 0.6249 0.7933 0.045 Uiso 1 1 calc R . .
H32B H 0.0594 0.6008 0.8560 0.045 Uiso 1 1 calc R . .
H32C H 0.0765 0.5313 0.7982 0.045 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C1 1.996(11) . ?
Au1 N2 2.103(10) . ?
Au1 Cl2 2.397(3) . ?
Au1 Au2 2.5333(5) . ?
Cl1 Au2 2.372(3) . ?
Fe1 C8 2.007(14) . ?
Fe1 C10 2.031(15) . ?
Fe1 C2 2.036(11) . ?
Fe1 C4 2.036(11) . ?
Fe1 C9 2.040(13) . ?
Fe1 C6 2.042(13) . ?
Fe1 C5 2.045(11) . ?
Fe1 C7 2.046(13) . ?
Fe1 C3 2.055(11) . ?
Fe1 C1 2.058(11) . ?
Au2 C17 1.994(9) . ?
Au2 N1 2.099(8) . ?
Fe2 C19 2.003(11) . ?
Fe2 C21 2.022(12) . ?
Fe2 C18 2.027(11) . ?
Fe2 C24 2.027(15) . ?
Fe2 C25 2.030(14) . ?
Fe2 C22 2.041(12) . ?
Fe2 C20 2.047(12) . ?
Fe2 C23 2.048(13) . ?
Fe2 C26 2.050(14) . ?
Fe2 C17 2.067(11) . ?
O1 C11 1.314(12) . ?
O1 C13 1.475(15) . ?
N1 C11 1.298(14) . ?
N1 C12 1.472(14) . ?
C1 C2 1.436(14) . ?
C1 C5 1.449(17) . ?
O2 C27 1.355(13) . ?
O2 C29 1.459(12) . ?
N2 C27 1.290(14) . ?
N2 C28 1.444(14) . ?
C2 C3 1.429(16) . ?
C2 C11 1.441(16) . ?
C3 C4 1.429(16) . ?
C3 H3 0.9500 . ?
C4 C5 1.410(17) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 C10 1.364(19) . ?
C6 C7 1.420(19) . ?
C6 H6 0.9500 . ?
C7 C8 1.40(2) . ?
C7 H7 0.9500 . ?
C8 C9 1.40(2) . ?
C8 H8 0.9500 . ?
C9 C10 1.40(2) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C12 C13 1.528(15) . ?
C12 C14 1.531(16) . ?
C12 H12 1.0000 . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C14 C15 1.504(16) . ?
C14 C16 1.583(16) . ?
C14 H14 1.0000 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 C18 1.427(15) . ?
C17 C21 1.433(14) . ?
C18 C19 1.429(15) . ?
C18 C27 1.457(15) . ?
C19 C20 1.417(15) . ?
C19 H19 0.9500 . ?
C20 C21 1.448(14) . ?
C20 H20 0.9500 . ?
C21 H21 0.9500 . ?
C22 C23 1.410(18) . ?
C22 C26 1.420(18) . ?
C22 H22 0.9500 . ?
C23 C24 1.42(2) . ?
C23 H23 0.9500 . ?
C24 C25 1.44(2) . ?
C24 H24 0.9500 . ?
C25 C26 1.40(2) . ?
C25 H25 0.9500 . ?
C26 H26 0.9500 . ?
C28 C30 1.524(16) . ?
C28 C29 1.565(15) . ?
C28 H28 1.0000 . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C30 C32 1.509(17) . ?
C30 C31 1.521(16) . ?
C30 H30 1.0000 . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Au1 N2 178.8(4) . . ?
C1 Au1 Cl2 91.1(3) . . ?
N2 Au1 Cl2 90.2(3) . . ?
C1 Au1 Au2 88.1(3) . . ?
N2 Au1 Au2 90.7(3) . . ?
Cl2 Au1 Au2 178.93(7) . . ?
C8 Fe1 C10 68.3(6) . . ?
C8 Fe1 C2 109.3(6) . . ?
C10 Fe1 C2 160.1(5) . . ?
C8 Fe1 C4 159.3(6) . . ?
C10 Fe1 C4 106.0(6) . . ?
C2 Fe1 C4 69.0(5) . . ?
C8 Fe1 C9 40.4(6) . . ?
C10 Fe1 C9 40.2(6) . . ?
C2 Fe1 C9 125.2(5) . . ?
C4 Fe1 C9 122.6(5) . . ?
C8 Fe1 C6 68.2(6) . . ?
C10 Fe1 C6 39.1(5) . . ?
C2 Fe1 C6 160.0(5) . . ?
C4 Fe1 C6 120.7(5) . . ?
C9 Fe1 C6 66.7(5) . . ?
C8 Fe1 C5 159.7(6) . . ?
C10 Fe1 C5 121.1(6) . . ?
C2 Fe1 C5 68.3(5) . . ?
C4 Fe1 C5 40.4(5) . . ?
C9 Fe1 C5 157.5(5) . . ?
C6 Fe1 C5 106.7(5) . . ?
C8 Fe1 C7 40.5(6) . . ?
C10 Fe1 C7 67.3(6) . . ?
C2 Fe1 C7 124.5(5) . . ?
C4 Fe1 C7 157.5(5) . . ?
C9 Fe1 C7 67.1(5) . . ?
C6 Fe1 C7 40.6(5) . . ?
C5 Fe1 C7 123.0(5) . . ?
C8 Fe1 C3 124.3(6) . . ?
C10 Fe1 C3 122.9(5) . . ?
C2 Fe1 C3 40.9(4) . . ?
C4 Fe1 C3 40.9(5) . . ?
C9 Fe1 C3 109.1(5) . . ?
C6 Fe1 C3 157.1(5) . . ?
C5 Fe1 C3 68.1(5) . . ?
C7 Fe1 C3 160.8(5) . . ?
C8 Fe1 C1 123.4(6) . . ?
C10 Fe1 C1 157.1(6) . . ?
C2 Fe1 C1 41.1(4) . . ?
C4 Fe1 C1 69.7(5) . . ?
C9 Fe1 C1 160.6(5) . . ?
C6 Fe1 C1 122.4(5) . . ?
C5 Fe1 C1 41.4(5) . . ?
C7 Fe1 C1 107.6(5) . . ?
C3 Fe1 C1 69.4(4) . . ?
C17 Au2 N1 177.9(4) . . ?
C17 Au2 Cl1 93.2(3) . . ?
N1 Au2 Cl1 87.7(2) . . ?
C17 Au2 Au1 87.3(3) . . ?
N1 Au2 Au1 91.7(2) . . ?
Cl1 Au2 Au1 176.23(9) . . ?
C19 Fe2 C21 70.1(5) . . ?
C19 Fe2 C18 41.5(4) . . ?
C21 Fe2 C18 68.4(4) . . ?
C19 Fe2 C24 150.5(5) . . ?
C21 Fe2 C24 105.4(5) . . ?
C18 Fe2 C24 165.5(5) . . ?
C19 Fe2 C25 164.0(6) . . ?
C21 Fe2 C25 122.3(5) . . ?
C18 Fe2 C25 129.6(5) . . ?
C24 Fe2 C25 41.6(6) . . ?
C19 Fe2 C22 104.0(5) . . ?
C21 Fe2 C22 158.5(5) . . ?
C18 Fe2 C22 121.6(5) . . ?
C24 Fe2 C22 69.0(6) . . ?
C25 Fe2 C22 68.2(6) . . ?
C19 Fe2 C20 40.9(4) . . ?
C21 Fe2 C20 41.7(4) . . ?
C18 Fe2 C20 68.3(4) . . ?
C24 Fe2 C20 116.4(5) . . ?
C25 Fe2 C20 155.1(5) . . ?
C22 Fe2 C20 120.7(5) . . ?
C19 Fe2 C23 115.4(5) . . ?
C21 Fe2 C23 122.2(5) . . ?
C18 Fe2 C23 153.6(6) . . ?
C24 Fe2 C23 40.9(6) . . ?
C25 Fe2 C23 68.4(6) . . ?
C22 Fe2 C23 40.3(5) . . ?
C20 Fe2 C23 102.6(5) . . ?
C19 Fe2 C26 125.2(5) . . ?
C21 Fe2 C26 158.6(5) . . ?
C18 Fe2 C26 111.7(5) . . ?
C24 Fe2 C26 68.9(6) . . ?
C25 Fe2 C26 40.0(5) . . ?
C22 Fe2 C26 40.6(5) . . ?
C20 Fe2 C26 159.6(5) . . ?
C23 Fe2 C26 67.9(6) . . ?
C19 Fe2 C17 70.4(4) . . ?
C21 Fe2 C17 41.0(4) . . ?
C18 Fe2 C17 40.8(4) . . ?
C24 Fe2 C17 126.1(5) . . ?
C25 Fe2 C17 111.3(5) . . ?
C22 Fe2 C17 158.2(5) . . ?
C20 Fe2 C17 69.6(4) . . ?
C23 Fe2 C17 161.3(5) . . ?
C26 Fe2 C17 124.8(5) . . ?
C11 O1 C13 108.5(9) . . ?
C11 N1 C12 109.8(8) . . ?
C11 N1 Au2 123.8(7) . . ?
C12 N1 Au2 125.7(7) . . ?
C2 C1 C5 105.2(10) . . ?
C2 C1 Au1 129.1(9) . . ?
C5 C1 Au1 125.2(8) . . ?
C2 C1 Fe1 68.6(6) . . ?
C5 C1 Fe1 68.8(6) . . ?
Au1 C1 Fe1 133.1(6) . . ?
C27 O2 C29 105.7(8) . . ?
C27 N2 C28 111.7(10) . . ?
C27 N2 Au1 122.2(8) . . ?
C28 N2 Au1 125.2(7) . . ?
C3 C2 C1 109.6(10) . . ?
C3 C2 C11 124.8(10) . . ?
C1 C2 C11 125.6(10) . . ?
C3 C2 Fe1 70.3(6) . . ?
C1 C2 Fe1 70.3(6) . . ?
C11 C2 Fe1 127.5(7) . . ?
C2 C3 C4 107.5(10) . . ?
C2 C3 Fe1 68.8(6) . . ?
C4 C3 Fe1 68.8(6) . . ?
C2 C3 H3 126.2 . . ?
C4 C3 H3 126.2 . . ?
Fe1 C3 H3 127.7 . . ?
C5 C4 C3 107.8(11) . . ?
C5 C4 Fe1 70.1(7) . . ?
C3 C4 Fe1 70.3(6) . . ?
C5 C4 H4 126.1 . . ?
C3 C4 H4 126.1 . . ?
Fe1 C4 H4 125.1 . . ?
C4 C5 C1 109.9(11) . . ?
C4 C5 Fe1 69.4(7) . . ?
C1 C5 Fe1 69.8(6) . . ?
C4 C5 H5 125.0 . . ?
C1 C5 H5 125.0 . . ?
Fe1 C5 H5 127.3 . . ?
C10 C6 C7 108.5(13) . . ?
C10 C6 Fe1 70.0(8) . . ?
C7 C6 Fe1 69.8(7) . . ?
C10 C6 H6 125.8 . . ?
C7 C6 H6 125.8 . . ?
Fe1 C6 H6 126.0 . . ?
C8 C7 C6 107.1(13) . . ?
C8 C7 Fe1 68.3(7) . . ?
C6 C7 Fe1 69.5(7) . . ?
C8 C7 H7 126.4 . . ?
C6 C7 H7 126.4 . . ?
Fe1 C7 H7 127.3 . . ?
C9 C8 C7 107.6(14) . . ?
C9 C8 Fe1 71.0(8) . . ?
C7 C8 Fe1 71.2(8) . . ?
C9 C8 H8 126.2 . . ?
C7 C8 H8 126.2 . . ?
Fe1 C8 H8 123.2 . . ?
C8 C9 C10 108.2(13) . . ?
C8 C9 Fe1 68.6(8) . . ?
C10 C9 Fe1 69.5(8) . . ?
C8 C9 H9 125.9 . . ?
C10 C9 H9 125.9 . . ?
Fe1 C9 H9 127.6 . . ?
C6 C10 C9 108.5(14) . . ?
C6 C10 Fe1 70.9(9) . . ?
C9 C10 Fe1 70.2(8) . . ?
C6 C10 H10 125.8 . . ?
C9 C10 H10 125.8 . . ?
Fe1 C10 H10 124.7 . . ?
N1 C11 O1 114.7(10) . . ?
N1 C11 C2 126.6(9) . . ?
O1 C11 C2 118.7(10) . . ?
N1 C12 C13 102.3(9) . . ?
N1 C12 C14 112.0(9) . . ?
C13 C12 C14 116.7(9) . . ?
N1 C12 H12 108.5 . . ?
C13 C12 H12 108.5 . . ?
C14 C12 H12 108.5 . . ?
O1 C13 C12 103.2(8) . . ?
O1 C13 H13A 111.1 . . ?
C12 C13 H13A 111.1 . . ?
O1 C13 H13B 111.1 . . ?
C12 C13 H13B 111.1 . . ?
H13A C13 H13B 109.1 . . ?
C15 C14 C12 109.5(10) . . ?
C15 C14 C16 110.3(10) . . ?
C12 C14 C16 112.2(9) . . ?
C15 C14 H14 108.2 . . ?
C12 C14 H14 108.2 . . ?
C16 C14 H14 108.2 . . ?
C14 C15 H15A 109.5 . . ?
C14 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C14 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C14 C16 H16A 109.5 . . ?
C14 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C14 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C18 C17 C21 105.4(9) . . ?
C18 C17 Au2 129.9(7) . . ?
C21 C17 Au2 124.7(8) . . ?
C18 C17 Fe2 68.1(6) . . ?
C21 C17 Fe2 67.8(6) . . ?
Au2 C17 Fe2 129.7(6) . . ?
C17 C18 C19 110.6(9) . . ?
C17 C18 C27 124.2(9) . . ?
C19 C18 C27 125.1(10) . . ?
C17 C18 Fe2 71.1(6) . . ?
C19 C18 Fe2 68.3(6) . . ?
C27 C18 Fe2 124.7(8) . . ?
C20 C19 C18 107.0(9) . . ?
C20 C19 Fe2 71.2(6) . . ?
C18 C19 Fe2 70.1(6) . . ?
C20 C19 H19 126.5 . . ?
C18 C19 H19 126.5 . . ?
Fe2 C19 H19 123.8 . . ?
C19 C20 C21 107.5(9) . . ?
C19 C20 Fe2 67.9(7) . . ?
C21 C20 Fe2 68.2(6) . . ?
C19 C20 H20 126.2 . . ?
C21 C20 H20 126.2 . . ?
Fe2 C20 H20 129.2 . . ?
C17 C21 C20 109.2(9) . . ?
C17 C21 Fe2 71.2(7) . . ?
C20 C21 Fe2 70.1(6) . . ?
C17 C21 H21 125.4 . . ?
C20 C21 H21 125.4 . . ?
Fe2 C21 H21 124.9 . . ?
C23 C22 C26 107.9(13) . . ?
C23 C22 Fe2 70.1(8) . . ?
C26 C22 Fe2 70.0(8) . . ?
C23 C22 H22 126.0 . . ?
C26 C22 H22 126.0 . . ?
Fe2 C22 H22 125.4 . . ?
C22 C23 C24 108.8(12) . . ?
C22 C23 Fe2 69.6(7) . . ?
C24 C23 Fe2 68.8(8) . . ?
C22 C23 H23 125.6 . . ?
C24 C23 H23 125.6 . . ?
Fe2 C23 H23 127.7 . . ?
C23 C24 C25 106.2(13) . . ?
C23 C24 Fe2 70.3(8) . . ?
C25 C24 Fe2 69.3(8) . . ?
C23 C24 H24 126.9 . . ?
C25 C24 H24 126.9 . . ?
Fe2 C24 H24 125.0 . . ?
C26 C25 C24 108.8(13) . . ?
C26 C25 Fe2 70.7(8) . . ?
C24 C25 Fe2 69.1(8) . . ?
C26 C25 H25 125.6 . . ?
C24 C25 H25 125.6 . . ?
Fe2 C25 H25 126.2 . . ?
C25 C26 C22 108.2(13) . . ?
C25 C26 Fe2 69.2(8) . . ?
C22 C26 Fe2 69.4(8) . . ?
C25 C26 H26 125.9 . . ?
C22 C26 H26 125.9 . . ?
Fe2 C26 H26 127.1 . . ?
N2 C27 O2 115.2(10) . . ?
N2 C27 C18 125.8(10) . . ?
O2 C27 C18 118.9(10) . . ?
N2 C28 C30 108.9(9) . . ?
N2 C28 C29 100.6(8) . . ?
C30 C28 C29 115.0(10) . . ?
N2 C28 H28 110.6 . . ?
C30 C28 H28 110.6 . . ?
C29 C28 H28 110.6 . . ?
O2 C29 C28 105.2(8) . . ?
O2 C29 H29A 110.7 . . ?
C28 C29 H29A 110.7 . . ?
O2 C29 H29B 110.7 . . ?
C28 C29 H29B 110.7 . . ?
H29A C29 H29B 108.8 . . ?
C32 C30 C31 112.8(11) . . ?
C32 C30 C28 110.4(10) . . ?
C31 C30 C28 113.3(10) . . ?
C32 C30 H30 106.6 . . ?
C31 C30 H30 106.6 . . ?
C28 C30 H30 106.6 . . ?
C30 C31 H31A 109.5 . . ?
C30 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
C30 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
C30 C32 H32A 109.5 . . ?
C30 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C30 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 Au1 Au2 C17 127.4(5) . . . . ?
N2 Au1 Au2 C17 -52.7(4) . . . . ?
Cl2 Au1 Au2 C17 162(4) . . . . ?
C1 Au1 Au2 N1 -50.7(4) . . . . ?
N2 Au1 Au2 N1 129.1(4) . . . . ?
Cl2 Au1 Au2 N1 -16(4) . . . . ?
C1 Au1 Au2 Cl1 29.6(10) . . . . ?
N2 Au1 Au2 Cl1 -150.6(10) . . . . ?
Cl2 Au1 Au2 Cl1 64(4) . . . . ?
C17 Au2 N1 C11 -8(11) . . . . ?
Cl1 Au2 N1 C11 -123.5(8) . . . . ?
Au1 Au2 N1 C11 52.8(8) . . . . ?
C17 Au2 N1 C12 161(10) . . . . ?
Cl1 Au2 N1 C12 45.3(8) . . . . ?
Au1 Au2 N1 C12 -138.5(8) . . . . ?
N2 Au1 C1 C2 37(20) . . . . ?
Cl2 Au1 C1 C2 -135.1(10) . . . . ?
Au2 Au1 C1 C2 44.2(10) . . . . ?
N2 Au1 C1 C5 -153(19) . . . . ?
Cl2 Au1 C1 C5 35.0(9) . . . . ?
Au2 Au1 C1 C5 -145.6(9) . . . . ?
N2 Au1 C1 Fe1 -60(20) . . . . ?
Cl2 Au1 C1 Fe1 128.1(7) . . . . ?
Au2 Au1 C1 Fe1 -52.5(7) . . . . ?
C8 Fe1 C1 C2 -81.1(9) . . . . ?
C10 Fe1 C1 C2 164.0(12) . . . . ?
C4 Fe1 C1 C2 80.9(7) . . . . ?
C9 Fe1 C1 C2 -51.9(17) . . . . ?
C6 Fe1 C1 C2 -164.9(7) . . . . ?
C5 Fe1 C1 C2 116.9(9) . . . . ?
C7 Fe1 C1 C2 -122.8(7) . . . . ?
C3 Fe1 C1 C2 37.1(6) . . . . ?
C8 Fe1 C1 C5 162.0(8) . . . . ?
C10 Fe1 C1 C5 47.1(15) . . . . ?
C2 Fe1 C1 C5 -116.9(9) . . . . ?
C4 Fe1 C1 C5 -36.0(7) . . . . ?
C9 Fe1 C1 C5 -168.8(14) . . . . ?
C6 Fe1 C1 C5 78.2(8) . . . . ?
C7 Fe1 C1 C5 120.3(7) . . . . ?
C3 Fe1 C1 C5 -79.8(7) . . . . ?
C8 Fe1 C1 Au1 43.0(11) . . . . ?
C10 Fe1 C1 Au1 -71.9(17) . . . . ?
C2 Fe1 C1 Au1 124.1(11) . . . . ?
C4 Fe1 C1 Au1 -155.0(9) . . . . ?
C9 Fe1 C1 Au1 72.2(17) . . . . ?
C6 Fe1 C1 Au1 -40.8(10) . . . . ?
C5 Fe1 C1 Au1 -119.0(11) . . . . ?
C7 Fe1 C1 Au1 1.3(10) . . . . ?
C3 Fe1 C1 Au1 161.2(9) . . . . ?
C1 Au1 N2 C27 64(19) . . . . ?
Cl2 Au1 N2 C27 -123.9(9) . . . . ?
Au2 Au1 N2 C27 56.7(9) . . . . ?
C1 Au1 N2 C28 -128(19) . . . . ?
Cl2 Au1 N2 C28 44.2(8) . . . . ?
Au2 Au1 N2 C28 -135.2(8) . . . . ?
C5 C1 C2 C3 0.0(12) . . . . ?
Au1 C1 C2 C3 171.7(8) . . . . ?
Fe1 C1 C2 C3 -59.5(8) . . . . ?
C5 C1 C2 C11 -177.8(10) . . . . ?
Au1 C1 C2 C11 -6.2(16) . . . . ?
Fe1 C1 C2 C11 122.7(10) . . . . ?
C5 C1 C2 Fe1 59.5(7) . . . . ?
Au1 C1 C2 Fe1 -128.8(9) . . . . ?
C8 Fe1 C2 C3 -120.5(8) . . . . ?
C10 Fe1 C2 C3 -41.2(18) . . . . ?
C4 Fe1 C2 C3 37.5(7) . . . . ?
C9 Fe1 C2 C3 -78.3(8) . . . . ?
C6 Fe1 C2 C3 160.3(14) . . . . ?
C5 Fe1 C2 C3 81.1(7) . . . . ?
C7 Fe1 C2 C3 -163.0(7) . . . . ?
C1 Fe1 C2 C3 120.4(9) . . . . ?
C8 Fe1 C2 C1 119.1(7) . . . . ?
C10 Fe1 C2 C1 -161.6(15) . . . . ?
C4 Fe1 C2 C1 -82.9(7) . . . . ?
C9 Fe1 C2 C1 161.3(7) . . . . ?
C6 Fe1 C2 C1 39.9(17) . . . . ?
C5 Fe1 C2 C1 -39.4(6) . . . . ?
C7 Fe1 C2 C1 76.6(8) . . . . ?
C3 Fe1 C2 C1 -120.4(9) . . . . ?
C8 Fe1 C2 C11 -1.2(11) . . . . ?
C10 Fe1 C2 C11 78.1(19) . . . . ?
C4 Fe1 C2 C11 156.8(11) . . . . ?
C9 Fe1 C2 C11 41.0(12) . . . . ?
C6 Fe1 C2 C11 -80.4(17) . . . . ?
C5 Fe1 C2 C11 -159.7(11) . . . . ?
C7 Fe1 C2 C11 -43.7(12) . . . . ?
C3 Fe1 C2 C11 119.3(12) . . . . ?
C1 Fe1 C2 C11 -120.3(13) . . . . ?
C1 C2 C3 C4 1.4(12) . . . . ?
C11 C2 C3 C4 179.3(10) . . . . ?
Fe1 C2 C3 C4 -58.1(8) . . . . ?
C1 C2 C3 Fe1 59.5(8) . . . . ?
C11 C2 C3 Fe1 -122.6(10) . . . . ?
C8 Fe1 C3 C2 79.8(8) . . . . ?
C10 Fe1 C3 C2 164.5(7) . . . . ?
C4 Fe1 C3 C2 -119.7(10) . . . . ?
C9 Fe1 C3 C2 122.1(7) . . . . ?
C6 Fe1 C3 C2 -162.8(12) . . . . ?
C5 Fe1 C3 C2 -81.8(7) . . . . ?
C7 Fe1 C3 C2 47.1(18) . . . . ?
C1 Fe1 C3 C2 -37.2(6) . . . . ?
C8 Fe1 C3 C4 -160.4(8) . . . . ?
C10 Fe1 C3 C4 -75.7(9) . . . . ?
C2 Fe1 C3 C4 119.7(10) . . . . ?
C9 Fe1 C3 C4 -118.1(8) . . . . ?
C6 Fe1 C3 C4 -43.0(16) . . . . ?
C5 Fe1 C3 C4 38.0(7) . . . . ?
C7 Fe1 C3 C4 166.8(14) . . . . ?
C1 Fe1 C3 C4 82.5(8) . . . . ?
C2 C3 C4 C5 -2.3(13) . . . . ?
Fe1 C3 C4 C5 -60.4(8) . . . . ?
C2 C3 C4 Fe1 58.1(7) . . . . ?
C8 Fe1 C4 C5 170.0(15) . . . . ?
C10 Fe1 C4 C5 -119.5(8) . . . . ?
C2 Fe1 C4 C5 80.8(8) . . . . ?
C9 Fe1 C4 C5 -160.0(8) . . . . ?
C6 Fe1 C4 C5 -79.6(9) . . . . ?
C7 Fe1 C4 C5 -50.4(17) . . . . ?
C3 Fe1 C4 C5 118.3(10) . . . . ?
C1 Fe1 C4 C5 36.8(7) . . . . ?
C8 Fe1 C4 C3 51.6(19) . . . . ?
C10 Fe1 C4 C3 122.2(8) . . . . ?
C2 Fe1 C4 C3 -37.5(7) . . . . ?
C9 Fe1 C4 C3 81.6(9) . . . . ?
C6 Fe1 C4 C3 162.0(7) . . . . ?
C5 Fe1 C4 C3 -118.3(11) . . . . ?
C7 Fe1 C4 C3 -168.7(13) . . . . ?
C1 Fe1 C4 C3 -81.5(7) . . . . ?
C3 C4 C5 C1 2.3(13) . . . . ?
Fe1 C4 C5 C1 -58.1(8) . . . . ?
C3 C4 C5 Fe1 60.5(8) . . . . ?
C2 C1 C5 C4 -1.5(12) . . . . ?
Au1 C1 C5 C4 -173.5(8) . . . . ?
Fe1 C1 C5 C4 57.9(8) . . . . ?
C2 C1 C5 Fe1 -59.4(7) . . . . ?
Au1 C1 C5 Fe1 128.6(8) . . . . ?
C8 Fe1 C5 C4 -169.8(16) . . . . ?
C10 Fe1 C5 C4 77.8(9) . . . . ?
C2 Fe1 C5 C4 -82.6(8) . . . . ?
C9 Fe1 C5 C4 48.6(16) . . . . ?
C6 Fe1 C5 C4 117.9(8) . . . . ?
C7 Fe1 C5 C4 159.4(8) . . . . ?
C3 Fe1 C5 C4 -38.4(7) . . . . ?
C1 Fe1 C5 C4 -121.7(10) . . . . ?
C8 Fe1 C5 C1 -48.1(19) . . . . ?
C10 Fe1 C5 C1 -160.5(7) . . . . ?
C2 Fe1 C5 C1 39.1(6) . . . . ?
C4 Fe1 C5 C1 121.7(10) . . . . ?
C9 Fe1 C5 C1 170.3(12) . . . . ?
C6 Fe1 C5 C1 -120.4(7) . . . . ?
C7 Fe1 C5 C1 -78.9(8) . . . . ?
C3 Fe1 C5 C1 83.3(7) . . . . ?
C8 Fe1 C6 C10 81.9(10) . . . . ?
C2 Fe1 C6 C10 168.6(13) . . . . ?
C4 Fe1 C6 C10 -77.2(10) . . . . ?
C9 Fe1 C6 C10 38.1(9) . . . . ?
C5 Fe1 C6 C10 -119.0(9) . . . . ?
C7 Fe1 C6 C10 119.6(12) . . . . ?
C3 Fe1 C6 C10 -45.9(17) . . . . ?
C1 Fe1 C6 C10 -161.4(9) . . . . ?
C8 Fe1 C6 C7 -37.6(8) . . . . ?
C10 Fe1 C6 C7 -119.6(12) . . . . ?
C2 Fe1 C6 C7 49.1(17) . . . . ?
C4 Fe1 C6 C7 163.3(8) . . . . ?
C9 Fe1 C6 C7 -81.5(8) . . . . ?
C5 Fe1 C6 C7 121.5(8) . . . . ?
C3 Fe1 C6 C7 -165.4(12) . . . . ?
C1 Fe1 C6 C7 79.0(9) . . . . ?
C10 C6 C7 C8 -1.4(15) . . . . ?
Fe1 C6 C7 C8 58.1(9) . . . . ?
C10 C6 C7 Fe1 -59.5(9) . . . . ?
C10 Fe1 C7 C8 -82.6(10) . . . . ?
C2 Fe1 C7 C8 79.1(10) . . . . ?
C4 Fe1 C7 C8 -159.4(13) . . . . ?
C9 Fe1 C7 C8 -38.8(9) . . . . ?
C6 Fe1 C7 C8 -119.1(12) . . . . ?
C5 Fe1 C7 C8 164.1(9) . . . . ?
C3 Fe1 C7 C8 43.5(19) . . . . ?
C1 Fe1 C7 C8 121.2(9) . . . . ?
C8 Fe1 C7 C6 119.1(12) . . . . ?
C10 Fe1 C7 C6 36.5(8) . . . . ?
C2 Fe1 C7 C6 -161.7(7) . . . . ?
C4 Fe1 C7 C6 -40.2(17) . . . . ?
C9 Fe1 C7 C6 80.3(8) . . . . ?
C5 Fe1 C7 C6 -76.8(9) . . . . ?
C3 Fe1 C7 C6 162.7(14) . . . . ?
C1 Fe1 C7 C6 -119.6(8) . . . . ?
C6 C7 C8 C9 3.2(14) . . . . ?
Fe1 C7 C8 C9 62.1(9) . . . . ?
C6 C7 C8 Fe1 -58.9(9) . . . . ?
C10 Fe1 C8 C9 -36.9(9) . . . . ?
C2 Fe1 C8 C9 122.0(9) . . . . ?
C4 Fe1 C8 C9 41(2) . . . . ?
C6 Fe1 C8 C9 -79.2(9) . . . . ?
C5 Fe1 C8 C9 -158.4(14) . . . . ?
C7 Fe1 C8 C9 -117.0(13) . . . . ?
C3 Fe1 C8 C9 79.0(10) . . . . ?
C1 Fe1 C8 C9 165.5(8) . . . . ?
C10 Fe1 C8 C7 80.1(9) . . . . ?
C2 Fe1 C8 C7 -121.0(8) . . . . ?
C4 Fe1 C8 C7 157.5(14) . . . . ?
C9 Fe1 C8 C7 117.0(13) . . . . ?
C6 Fe1 C8 C7 37.8(8) . . . . ?
C5 Fe1 C8 C7 -41(2) . . . . ?
C3 Fe1 C8 C7 -164.1(8) . . . . ?
C1 Fe1 C8 C7 -77.5(10) . . . . ?
C7 C8 C9 C10 -3.9(15) . . . . ?
Fe1 C8 C9 C10 58.4(9) . . . . ?
C7 C8 C9 Fe1 -62.3(9) . . . . ?
C10 Fe1 C9 C8 120.3(13) . . . . ?
C2 Fe1 C9 C8 -78.2(10) . . . . ?
C4 Fe1 C9 C8 -164.2(9) . . . . ?
C6 Fe1 C9 C8 83.2(10) . . . . ?
C5 Fe1 C9 C8 160.5(12) . . . . ?
C7 Fe1 C9 C8 38.9(9) . . . . ?
C3 Fe1 C9 C8 -120.9(9) . . . . ?
C1 Fe1 C9 C8 -39.0(19) . . . . ?
C8 Fe1 C9 C10 -120.3(13) . . . . ?
C2 Fe1 C9 C10 161.5(8) . . . . ?
C4 Fe1 C9 C10 75.5(9) . . . . ?
C6 Fe1 C9 C10 -37.0(8) . . . . ?
C5 Fe1 C9 C10 40.2(17) . . . . ?
C7 Fe1 C9 C10 -81.4(9) . . . . ?
C3 Fe1 C9 C10 118.8(8) . . . . ?
C1 Fe1 C9 C10 -159.3(13) . . . . ?
C7 C6 C10 C9 -1.0(15) . . . . ?
Fe1 C6 C10 C9 -60.4(9) . . . . ?
C7 C6 C10 Fe1 59.4(9) . . . . ?
C8 C9 C10 C6 3.1(15) . . . . ?
Fe1 C9 C10 C6 60.8(10) . . . . ?
C8 C9 C10 Fe1 -57.8(9) . . . . ?
C8 Fe1 C10 C6 -81.7(9) . . . . ?
C2 Fe1 C10 C6 -168.6(13) . . . . ?
C4 Fe1 C10 C6 119.3(9) . . . . ?
C9 Fe1 C10 C6 -118.8(12) . . . . ?
C5 Fe1 C10 C6 78.0(10) . . . . ?
C7 Fe1 C10 C6 -37.9(8) . . . . ?
C3 Fe1 C10 C6 160.6(8) . . . . ?
C1 Fe1 C10 C6 43.6(18) . . . . ?
C8 Fe1 C10 C9 37.0(8) . . . . ?
C2 Fe1 C10 C9 -49.8(19) . . . . ?
C4 Fe1 C10 C9 -121.9(8) . . . . ?
C6 Fe1 C10 C9 118.8(12) . . . . ?
C5 Fe1 C10 C9 -163.2(8) . . . . ?
C7 Fe1 C10 C9 80.9(9) . . . . ?
C3 Fe1 C10 C9 -80.7(9) . . . . ?
C1 Fe1 C10 C9 162.4(11) . . . . ?
C12 N1 C11 O1 -3.4(13) . . . . ?
Au2 N1 C11 O1 166.9(7) . . . . ?
C12 N1 C11 C2 174.1(10) . . . . ?
Au2 N1 C11 C2 -15.6(15) . . . . ?
C13 O1 C11 N1 -5.1(12) . . . . ?
C13 O1 C11 C2 177.2(9) . . . . ?
C3 C2 C11 N1 162.2(11) . . . . ?
C1 C2 C11 N1 -20.3(17) . . . . ?
Fe1 C2 C11 N1 71.3(14) . . . . ?
C3 C2 C11 O1 -20.4(16) . . . . ?
C1 C2 C11 O1 157.1(10) . . . . ?
Fe1 C2 C11 O1 -111.3(10) . . . . ?
C11 N1 C12 C13 9.8(11) . . . . ?
Au2 N1 C12 C13 -160.3(7) . . . . ?
C11 N1 C12 C14 -116.0(10) . . . . ?
Au2 N1 C12 C14 73.9(11) . . . . ?
C11 O1 C13 C12 10.8(11) . . . . ?
N1 C12 C13 O1 -11.9(10) . . . . ?
C14 C12 C13 O1 110.7(11) . . . . ?
N1 C12 C14 C15 178.3(9) . . . . ?
C13 C12 C14 C15 60.9(13) . . . . ?
N1 C12 C14 C16 55.4(12) . . . . ?
C13 C12 C14 C16 -62.0(13) . . . . ?
N1 Au2 C17 C18 101(11) . . . . ?
Cl1 Au2 C17 C18 -143.8(10) . . . . ?
Au1 Au2 C17 C18 39.9(10) . . . . ?
N1 Au2 C17 C21 -77(11) . . . . ?
Cl1 Au2 C17 C21 38.5(10) . . . . ?
Au1 Au2 C17 C21 -137.8(10) . . . . ?
N1 Au2 C17 Fe2 -166(10) . . . . ?
Cl1 Au2 C17 Fe2 -50.3(7) . . . . ?
Au1 Au2 C17 Fe2 133.5(6) . . . . ?
C19 Fe2 C17 C18 -36.4(6) . . . . ?
C21 Fe2 C17 C18 -118.2(9) . . . . ?
C24 Fe2 C17 C18 171.5(7) . . . . ?
C25 Fe2 C17 C18 126.6(7) . . . . ?
C22 Fe2 C17 C18 42.4(15) . . . . ?
C20 Fe2 C17 C18 -80.1(6) . . . . ?
C23 Fe2 C17 C18 -148.2(16) . . . . ?
C26 Fe2 C17 C18 83.5(8) . . . . ?
C19 Fe2 C17 C21 81.8(7) . . . . ?
C18 Fe2 C17 C21 118.2(9) . . . . ?
C24 Fe2 C17 C21 -70.3(8) . . . . ?
C25 Fe2 C17 C21 -115.2(7) . . . . ?
C22 Fe2 C17 C21 160.6(12) . . . . ?
C20 Fe2 C17 C21 38.1(6) . . . . ?
C23 Fe2 C17 C21 -30.0(18) . . . . ?
C26 Fe2 C17 C21 -158.3(7) . . . . ?
C19 Fe2 C17 Au2 -160.8(8) . . . . ?
C21 Fe2 C17 Au2 117.4(10) . . . . ?
C18 Fe2 C17 Au2 -124.3(10) . . . . ?
C24 Fe2 C17 Au2 47.1(10) . . . . ?
C25 Fe2 C17 Au2 2.3(9) . . . . ?
C22 Fe2 C17 Au2 -82.0(15) . . . . ?
C20 Fe2 C17 Au2 155.6(8) . . . . ?
C23 Fe2 C17 Au2 87.5(17) . . . . ?
C26 Fe2 C17 Au2 -40.9(9) . . . . ?
C21 C17 C18 C19 -0.8(13) . . . . ?
Au2 C17 C18 C19 -178.9(8) . . . . ?
Fe2 C17 C18 C19 56.9(8) . . . . ?
C21 C17 C18 C27 -177.5(11) . . . . ?
Au2 C17 C18 C27 4.4(17) . . . . ?
Fe2 C17 C18 C27 -119.7(11) . . . . ?
C21 C17 C18 Fe2 -57.8(8) . . . . ?
Au2 C17 C18 Fe2 124.2(10) . . . . ?
C19 Fe2 C18 C17 122.4(9) . . . . ?
C21 Fe2 C18 C17 38.4(6) . . . . ?
C24 Fe2 C18 C17 -29(2) . . . . ?
C25 Fe2 C18 C17 -76.2(8) . . . . ?
C22 Fe2 C18 C17 -162.9(6) . . . . ?
C20 Fe2 C18 C17 83.5(6) . . . . ?
C23 Fe2 C18 C17 157.7(10) . . . . ?
C26 Fe2 C18 C17 -118.5(7) . . . . ?
C21 Fe2 C18 C19 -84.0(7) . . . . ?
C24 Fe2 C18 C19 -151(2) . . . . ?
C25 Fe2 C18 C19 161.4(8) . . . . ?
C22 Fe2 C18 C19 74.7(8) . . . . ?
C20 Fe2 C18 C19 -39.0(7) . . . . ?
C23 Fe2 C18 C19 35.3(14) . . . . ?
C26 Fe2 C18 C19 119.1(7) . . . . ?
C17 Fe2 C18 C19 -122.4(9) . . . . ?
C19 Fe2 C18 C27 -118.6(12) . . . . ?
C21 Fe2 C18 C27 157.4(10) . . . . ?
C24 Fe2 C18 C27 90(2) . . . . ?
C25 Fe2 C18 C27 42.8(12) . . . . ?
C22 Fe2 C18 C27 -43.9(11) . . . . ?
C20 Fe2 C18 C27 -157.5(10) . . . . ?
C23 Fe2 C18 C27 -83.3(14) . . . . ?
C26 Fe2 C18 C27 0.5(11) . . . . ?
C17 Fe2 C18 C27 119.0(12) . . . . ?
C17 C18 C19 C20 3.4(13) . . . . ?
C27 C18 C19 C20 -179.9(11) . . . . ?
Fe2 C18 C19 C20 62.0(8) . . . . ?
C17 C18 C19 Fe2 -58.6(8) . . . . ?
C27 C18 C19 Fe2 118.1(11) . . . . ?
C21 Fe2 C19 C20 -37.4(6) . . . . ?
C18 Fe2 C19 C20 -116.9(9) . . . . ?
C24 Fe2 C19 C20 48.9(13) . . . . ?
C25 Fe2 C19 C20 179.8(17) . . . . ?
C22 Fe2 C19 C20 121.0(7) . . . . ?
C23 Fe2 C19 C20 79.7(8) . . . . ?
C26 Fe2 C19 C20 159.6(7) . . . . ?
C17 Fe2 C19 C20 -81.1(6) . . . . ?
C21 Fe2 C19 C18 79.5(7) . . . . ?
C24 Fe2 C19 C18 165.8(10) . . . . ?
C25 Fe2 C19 C18 -63(2) . . . . ?
C22 Fe2 C19 C18 -122.1(7) . . . . ?
C20 Fe2 C19 C18 116.9(9) . . . . ?
C23 Fe2 C19 C18 -163.5(7) . . . . ?
C26 Fe2 C19 C18 -83.5(8) . . . . ?
C17 Fe2 C19 C18 35.8(6) . . . . ?
C18 C19 C20 C21 -4.6(13) . . . . ?
Fe2 C19 C20 C21 56.7(8) . . . . ?
C18 C19 C20 Fe2 -61.3(8) . . . . ?
C21 Fe2 C20 C19 120.8(9) . . . . ?
C18 Fe2 C20 C19 39.5(6) . . . . ?
C24 Fe2 C20 C19 -155.5(7) . . . . ?
C25 Fe2 C20 C19 -179.9(11) . . . . ?
C22 Fe2 C20 C19 -75.3(8) . . . . ?
C23 Fe2 C20 C19 -114.4(7) . . . . ?
C26 Fe2 C20 C19 -54.8(16) . . . . ?
C17 Fe2 C20 C19 83.3(6) . . . . ?
C19 Fe2 C20 C21 -120.8(9) . . . . ?
C18 Fe2 C20 C21 -81.3(6) . . . . ?
C24 Fe2 C20 C21 83.6(7) . . . . ?
C25 Fe2 C20 C21 59.3(14) . . . . ?
C22 Fe2 C20 C21 163.8(7) . . . . ?
C23 Fe2 C20 C21 124.7(7) . . . . ?
C26 Fe2 C20 C21 -175.7(13) . . . . ?
C17 Fe2 C20 C21 -37.5(6) . . . . ?
C18 C17 C21 C20 -2.1(13) . . . . ?
Au2 C17 C21 C20 176.1(8) . . . . ?
Fe2 C17 C21 C20 -60.0(8) . . . . ?
C18 C17 C21 Fe2 58.0(8) . . . . ?
Au2 C17 C21 Fe2 -123.9(8) . . . . ?
C19 C20 C21 C17 4.2(13) . . . . ?
Fe2 C20 C21 C17 60.7(8) . . . . ?
C19 C20 C21 Fe2 -56.5(8) . . . . ?
C19 Fe2 C21 C17 -82.8(7) . . . . ?
C18 Fe2 C21 C17 -38.2(6) . . . . ?
C24 Fe2 C21 C17 127.9(7) . . . . ?
C25 Fe2 C21 C17 85.9(8) . . . . ?
C22 Fe2 C21 C17 -160.3(13) . . . . ?
C20 Fe2 C21 C17 -119.5(9) . . . . ?
C23 Fe2 C21 C17 169.1(7) . . . . ?
C26 Fe2 C21 C17 56.4(16) . . . . ?
C19 Fe2 C21 C20 36.8(6) . . . . ?
C18 Fe2 C21 C20 81.3(6) . . . . ?
C24 Fe2 C21 C20 -112.6(7) . . . . ?
C25 Fe2 C21 C20 -154.6(7) . . . . ?
C22 Fe2 C21 C20 -40.8(16) . . . . ?
C23 Fe2 C21 C20 -71.4(8) . . . . ?
C26 Fe2 C21 C20 175.9(13) . . . . ?
C17 Fe2 C21 C20 119.5(9) . . . . ?
C19 Fe2 C22 C23 -112.9(9) . . . . ?
C21 Fe2 C22 C23 -41.7(18) . . . . ?
C18 Fe2 C22 C23 -154.1(8) . . . . ?
C24 Fe2 C22 C23 37.0(8) . . . . ?
C25 Fe2 C22 C23 81.8(9) . . . . ?
C20 Fe2 C22 C23 -72.1(9) . . . . ?
C26 Fe2 C22 C23 118.7(12) . . . . ?
C17 Fe2 C22 C23 174.8(12) . . . . ?
C19 Fe2 C22 C26 128.4(8) . . . . ?
C21 Fe2 C22 C26 -160.4(12) . . . . ?
C18 Fe2 C22 C26 87.2(9) . . . . ?
C24 Fe2 C22 C26 -81.7(9) . . . . ?
C25 Fe2 C22 C26 -36.9(8) . . . . ?
C20 Fe2 C22 C26 169.2(7) . . . . ?
C23 Fe2 C22 C26 -118.7(12) . . . . ?
C17 Fe2 C22 C26 56.1(16) . . . . ?
C26 C22 C23 C24 2.5(16) . . . . ?
Fe2 C22 C23 C24 -57.6(10) . . . . ?
C26 C22 C23 Fe2 60.1(9) . . . . ?
C19 Fe2 C23 C22 81.7(9) . . . . ?
C21 Fe2 C23 C22 163.3(7) . . . . ?
C18 Fe2 C23 C22 56.6(15) . . . . ?
C24 Fe2 C23 C22 -121.0(12) . . . . ?
C25 Fe2 C23 C22 -81.3(9) . . . . ?
C20 Fe2 C23 C22 123.0(8) . . . . ?
C26 Fe2 C23 C22 -38.0(8) . . . . ?
C17 Fe2 C23 C22 -174.0(13) . . . . ?
C19 Fe2 C23 C24 -157.3(8) . . . . ?
C21 Fe2 C23 C24 -75.8(10) . . . . ?
C18 Fe2 C23 C24 177.6(10) . . . . ?
C25 Fe2 C23 C24 39.6(9) . . . . ?
C22 Fe2 C23 C24 121.0(12) . . . . ?
C20 Fe2 C23 C24 -116.0(9) . . . . ?
C26 Fe2 C23 C24 82.9(9) . . . . ?
C17 Fe2 C23 C24 -53.0(19) . . . . ?
C22 C23 C24 C25 -2.3(16) . . . . ?
Fe2 C23 C24 C25 -60.4(10) . . . . ?
C22 C23 C24 Fe2 58.1(10) . . . . ?
C19 Fe2 C24 C23 44.9(15) . . . . ?
C21 Fe2 C24 C23 121.7(8) . . . . ?
C18 Fe2 C24 C23 -175.7(19) . . . . ?
C25 Fe2 C24 C23 -116.8(12) . . . . ?
C22 Fe2 C24 C23 -36.5(8) . . . . ?
C20 Fe2 C24 C23 78.4(9) . . . . ?
C26 Fe2 C24 C23 -80.1(9) . . . . ?
C17 Fe2 C24 C23 161.5(7) . . . . ?
C19 Fe2 C24 C25 161.7(10) . . . . ?
C21 Fe2 C24 C25 -121.5(8) . . . . ?
C18 Fe2 C24 C25 -59(3) . . . . ?
C22 Fe2 C24 C25 80.3(9) . . . . ?
C20 Fe2 C24 C25 -164.8(8) . . . . ?
C23 Fe2 C24 C25 116.8(12) . . . . ?
C26 Fe2 C24 C25 36.7(8) . . . . ?
C17 Fe2 C24 C25 -81.7(10) . . . . ?
C23 C24 C25 C26 1.2(16) . . . . ?
Fe2 C24 C25 C26 -59.8(10) . . . . ?
C23 C24 C25 Fe2 61.1(10) . . . . ?
C19 Fe2 C25 C26 -26(2) . . . . ?
C21 Fe2 C25 C26 -163.8(7) . . . . ?
C18 Fe2 C25 C26 -76.3(10) . . . . ?
C24 Fe2 C25 C26 119.9(12) . . . . ?
C22 Fe2 C25 C26 37.4(8) . . . . ?
C20 Fe2 C25 C26 153.7(11) . . . . ?
C23 Fe2 C25 C26 80.9(9) . . . . ?
C17 Fe2 C25 C26 -119.2(8) . . . . ?
C19 Fe2 C25 C24 -145.9(17) . . . . ?
C21 Fe2 C25 C24 76.3(9) . . . . ?
C18 Fe2 C25 C24 163.8(8) . . . . ?
C22 Fe2 C25 C24 -82.5(9) . . . . ?
C20 Fe2 C25 C24 33.8(16) . . . . ?
C23 Fe2 C25 C24 -38.9(8) . . . . ?
C26 Fe2 C25 C24 -119.9(12) . . . . ?
C17 Fe2 C25 C24 120.9(8) . . . . ?
C24 C25 C26 C22 0.2(16) . . . . ?
Fe2 C25 C26 C22 -58.5(9) . . . . ?
C24 C25 C26 Fe2 58.8(10) . . . . ?
C23 C22 C26 C25 -1.7(15) . . . . ?
Fe2 C22 C26 C25 58.4(10) . . . . ?
C23 C22 C26 Fe2 -60.1(9) . . . . ?
C19 Fe2 C26 C25 171.5(8) . . . . ?
C21 Fe2 C26 C25 40.3(18) . . . . ?
C18 Fe2 C26 C25 126.3(8) . . . . ?
C24 Fe2 C26 C25 -38.1(8) . . . . ?
C22 Fe2 C26 C25 -120.0(12) . . . . ?
C20 Fe2 C26 C25 -147.5(13) . . . . ?
C23 Fe2 C26 C25 -82.2(9) . . . . ?
C17 Fe2 C26 C25 82.0(9) . . . . ?
C19 Fe2 C26 C22 -68.5(9) . . . . ?
C21 Fe2 C26 C22 160.4(12) . . . . ?
C18 Fe2 C26 C22 -113.6(8) . . . . ?
C24 Fe2 C26 C22 81.9(9) . . . . ?
C25 Fe2 C26 C22 120.0(12) . . . . ?
C20 Fe2 C26 C22 -27.5(18) . . . . ?
C23 Fe2 C26 C22 37.8(8) . . . . ?
C17 Fe2 C26 C22 -158.0(7) . . . . ?
C28 N2 C27 O2 -0.6(14) . . . . ?
Au1 N2 C27 O2 169.1(7) . . . . ?
C28 N2 C27 C18 175.3(11) . . . . ?
Au1 N2 C27 C18 -15.0(16) . . . . ?
C29 O2 C27 N2 -7.8(13) . . . . ?
C29 O2 C27 C18 176.0(10) . . . . ?
C17 C18 C27 N2 -28.7(19) . . . . ?
C19 C18 C27 N2 155.1(12) . . . . ?
Fe2 C18 C27 N2 -118.4(12) . . . . ?
C17 C18 C27 O2 147.1(11) . . . . ?
C19 C18 C27 O2 -29.1(17) . . . . ?
Fe2 C18 C27 O2 57.3(14) . . . . ?
C27 N2 C28 C30 -113.3(11) . . . . ?
Au1 N2 C28 C30 77.4(11) . . . . ?
C27 N2 C28 C29 7.9(12) . . . . ?
Au1 N2 C28 C29 -161.3(7) . . . . ?
C27 O2 C29 C28 12.1(11) . . . . ?
N2 C28 C29 O2 -11.9(11) . . . . ?
C30 C28 C29 O2 105.0(10) . . . . ?
N2 C28 C30 C32 -176.4(10) . . . . ?
C29 C28 C30 C32 71.6(13) . . . . ?
N2 C28 C30 C31 56.0(13) . . . . ?
C29 C28 C30 C31 -56.1(13) . . . . ?

_diffrn_measured_fraction_theta_max 0.995
_diffrn_reflns_theta_full        28.34
_diffrn_measured_fraction_theta_full 0.995
_refine_diff_density_max         5.672
_refine_diff_density_min         -2.707
_refine_diff_density_rms         0.281
