# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1a'
_database_code_depnum_ccdc_archive 'CCDC 1419522'
_audit_update_record             
;
2015-08-19 deposited with the CCDC.
2015-09-21 downloaded from the CCDC.
;

#==============================================================================

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C29 H41 F3 N O3 P Pt S Si'
_chemical_formula_weight         794.84

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   P21/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   9.8511(14)
_cell_length_b                   20.837(3)
_cell_length_c                   15.443(2)
_cell_angle_alpha                90.00
_cell_angle_beta                 99.5203(17)
_cell_angle_gamma                90.00
_cell_volume                     3126.3(7)
_cell_formula_units_Z            4
_cell_measurement_temperature    123(2)
_cell_measurement_reflns_used    8863
_cell_measurement_theta_min      3.0134
_cell_measurement_theta_max      27.4816

_exptl_crystal_description       prism
_exptl_crystal_colour            colourless
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.06
_exptl_crystal_size_min          0.02
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.689
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1584
_exptl_absorpt_coefficient_mu    4.693
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.8381
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      123(2)
_diffrn_radiation_wavelength     0.71075
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  ccd
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            37567
_diffrn_reflns_av_R_equivalents  0.0345
_diffrn_reflns_av_sigmaI/netI    0.0276
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_theta_min         3.01
_diffrn_reflns_theta_max         27.48
_reflns_number_total             7148
_reflns_number_gt                6143
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0564P)²+0.9419P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         7148
_refine_ls_number_parameters     364
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0458
_refine_ls_R_factor_gt           0.0402
_refine_ls_wR_factor_ref         0.1021
_refine_ls_wR_factor_gt          0.0968
_refine_ls_goodness_of_fit_ref   1.233
_refine_ls_restrained_S_all      1.233
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.116755(16) 0.639799(7) 0.205292(10) 0.01446(7) Uani 1 1 d . . .
O1 O -0.0983(3) 0.63431(15) 0.1129(2) 0.0242(8) Uani 1 1 d . . .
S1 S -0.23928(12) 0.60857(6) 0.09561(7) 0.0229(2) Uani 1 1 d . . .
O2 O -0.3208(4) 0.62233(17) 0.1621(2) 0.0283(7) Uani 1 1 d . . .
O3 O -0.2504(4) 0.54450(17) 0.0601(3) 0.0371(9) Uani 1 1 d . . .
C1 C -0.3162(6) 0.6591(3) 0.0039(3) 0.0319(11) Uani 1 1 d . . .
F1 F -0.3125(4) 0.72077(15) 0.0261(2) 0.0461(8) Uani 1 1 d . . .
F2 F -0.2514(4) 0.65209(19) -0.0645(2) 0.0514(9) Uani 1 1 d . . .
F3 F -0.4481(3) 0.64327(15) -0.0230(2) 0.0435(9) Uani 1 1 d . . .
P1 P 0.03516(11) 0.68439(5) 0.31735(7) 0.0158(2) Uani 1 1 d . . .
C2 C -0.0976(4) 0.63000(19) 0.3472(3) 0.0172(8) Uani 1 1 d . . .
H1 H -0.1785 0.6318 0.2987 0.021 Uiso 1 1 calc R . .
C3 C -0.0434(5) 0.5610(2) 0.3521(3) 0.0236(9) Uani 1 1 d . . .
H2 H -0.0174 0.5491 0.2950 0.028 Uiso 1 1 calc R . .
H3 H 0.0403 0.5584 0.3974 0.028 Uiso 1 1 calc R . .
C4 C -0.1499(5) 0.5137(2) 0.3744(3) 0.0264(10) Uani 1 1 d . . .
H4 H -0.1091 0.4702 0.3806 0.032 Uiso 1 1 calc R . .
H5 H -0.2291 0.5126 0.3258 0.032 Uiso 1 1 calc R . .
C5 C -0.2002(5) 0.5320(2) 0.4594(3) 0.0276(10) Uani 1 1 d . . .
H6 H -0.2732 0.5018 0.4702 0.033 Uiso 1 1 calc R . .
H7 H -0.1232 0.5288 0.5092 0.033 Uiso 1 1 calc R . .
C6 C -0.2565(5) 0.6000(2) 0.4534(3) 0.0253(10) Uani 1 1 d . . .
H8 H -0.2855 0.6116 0.5098 0.030 Uiso 1 1 calc R . .
H9 H -0.3384 0.6021 0.4068 0.030 Uiso 1 1 calc R . .
C7 C -0.1490(5) 0.6478(2) 0.4332(3) 0.0208(9) Uani 1 1 d . . .
H10 H -0.0702 0.6483 0.4822 0.025 Uiso 1 1 calc R . .
H11 H -0.1895 0.6914 0.4277 0.025 Uiso 1 1 calc R . .
C8 C -0.0390(5) 0.76549(19) 0.3019(3) 0.0184(8) Uani 1 1 d . . .
H12 H -0.0788 0.7771 0.3554 0.022 Uiso 1 1 calc R . .
C9 C -0.1541(5) 0.7674(2) 0.2225(3) 0.0236(9) Uani 1 1 d . . .
H13 H -0.2278 0.7371 0.2316 0.028 Uiso 1 1 calc R . .
H14 H -0.1174 0.7537 0.1695 0.028 Uiso 1 1 calc R . .
C10 C -0.2147(5) 0.8355(2) 0.2081(3) 0.0302(11) Uani 1 1 d . . .
H15 H -0.2849 0.8360 0.1542 0.036 Uiso 1 1 calc R . .
H16 H -0.2608 0.8472 0.2582 0.036 Uiso 1 1 calc R . .
C11 C -0.1040(6) 0.8846(2) 0.1995(3) 0.0308(11) Uani 1 1 d . . .
H17 H -0.1453 0.9281 0.1945 0.037 Uiso 1 1 calc R . .
H18 H -0.0658 0.8760 0.1452 0.037 Uiso 1 1 calc R . .
C12 C 0.0121(6) 0.8825(2) 0.2785(3) 0.0321(11) Uani 1 1 d . . .
H19 H -0.0239 0.8957 0.3320 0.038 Uiso 1 1 calc R . .
H20 H 0.0853 0.9132 0.2694 0.038 Uiso 1 1 calc R . .
C13 C 0.0730(5) 0.8144(2) 0.2912(3) 0.0237(10) Uani 1 1 d . . .
H21 H 0.1159 0.8027 0.2398 0.028 Uiso 1 1 calc R . .
H22 H 0.1454 0.8136 0.3439 0.028 Uiso 1 1 calc R . .
C14 C 0.1670(4) 0.69155(19) 0.4142(3) 0.0166(8) Uani 1 1 d . . .
C15 C 0.1441(5) 0.7205(2) 0.4925(3) 0.0204(9) Uani 1 1 d . . .
H23 H 0.0557 0.7373 0.4966 0.025 Uiso 1 1 calc R . .
C16 C 0.2492(5) 0.7248(2) 0.5638(3) 0.0238(10) Uani 1 1 d . . .
H24 H 0.2323 0.7433 0.6172 0.029 Uiso 1 1 calc R . .
C17 C 0.3793(5) 0.7019(2) 0.5571(3) 0.0249(10) Uani 1 1 d . . .
H25 H 0.4516 0.7047 0.6060 0.030 Uiso 1 1 calc R . .
C18 C 0.4038(5) 0.6749(2) 0.4788(3) 0.0237(10) Uani 1 1 d . . .
H26 H 0.4938 0.6603 0.4743 0.028 Uiso 1 1 calc R . .
C19 C 0.2986(4) 0.6687(2) 0.4066(3) 0.0172(8) Uani 1 1 d . . .
Si1 Si 0.32422(13) 0.64337(5) 0.29316(8) 0.0143(2) Uani 1 1 d . . .
C20 C 0.4543(5) 0.7028(2) 0.2645(3) 0.0220(9) Uani 1 1 d . . .
H27 H 0.5392 0.6996 0.3074 0.033 Uiso 1 1 calc R . .
H28 H 0.4170 0.7463 0.2653 0.033 Uiso 1 1 calc R . .
H29 H 0.4743 0.6933 0.2057 0.033 Uiso 1 1 calc R . .
C21 C 0.3925(4) 0.5598(2) 0.2893(3) 0.0170(9) Uani 1 1 d . . .
C22 C 0.4342(5) 0.5214(2) 0.3636(3) 0.0223(9) Uani 1 1 d . . .
H30 H 0.4270 0.5380 0.4199 0.027 Uiso 1 1 calc R . .
C23 C 0.4854(5) 0.4604(2) 0.3573(3) 0.0256(10) Uani 1 1 d . . .
H31 H 0.5118 0.4354 0.4087 0.031 Uiso 1 1 calc R . .
C24 C 0.4982(5) 0.4355(2) 0.2760(3) 0.0269(10) Uani 1 1 d . . .
H32 H 0.5369 0.3941 0.2717 0.032 Uiso 1 1 calc R . .
C25 C 0.4539(5) 0.4714(2) 0.2005(3) 0.0253(10) Uani 1 1 d . . .
H33 H 0.4604 0.4537 0.1446 0.030 Uiso 1 1 calc R . .
C26 C 0.4001(5) 0.5331(2) 0.2059(3) 0.0195(9) Uani 1 1 d . . .
C27 C 0.3466(5) 0.5678(2) 0.1225(3) 0.0222(9) Uani 1 1 d . . .
H34 H 0.3685 0.5422 0.0725 0.027 Uiso 1 1 calc R . .
H35 H 0.3952 0.6093 0.1226 0.027 Uiso 1 1 calc R . .
N1 N 0.1941(4) 0.58018(17) 0.1084(2) 0.0180(7) Uani 1 1 d . . .
C28 C 0.1559(5) 0.6080(2) 0.0188(3) 0.0225(9) Uani 1 1 d . . .
H36 H 0.1834 0.5784 -0.0245 0.034 Uiso 1 1 calc R . .
H37 H 0.2031 0.6492 0.0159 0.034 Uiso 1 1 calc R . .
H38 H 0.0561 0.6147 0.0060 0.034 Uiso 1 1 calc R . .
C29 C 0.1215(5) 0.5177(2) 0.1109(3) 0.0215(9) Uani 1 1 d . . .
H39 H 0.0227 0.5239 0.0907 0.032 Uiso 1 1 calc R . .
H40 H 0.1363 0.5013 0.1712 0.032 Uiso 1 1 calc R . .
H41 H 0.1576 0.4869 0.0726 0.032 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 N1 2.177(3) . ?
Pt1 P1 2.2281(11) . ?
Pt1 Si1 2.2597(13) . ?
Pt1 O1 2.353(3) . ?
O1 S1 1.471(3) . ?
S1 O2 1.433(3) . ?
S1 O3 1.441(4) . ?
S1 C1 1.827(6) . ?
C1 F1 1.328(6) . ?
C1 F2 1.330(6) . ?
C1 F3 1.338(6) . ?
P1 C14 1.818(4) . ?
P1 C8 1.841(4) . ?
P1 C2 1.846(4) . ?
C2 C3 1.531(6) . ?
C2 C7 1.542(6) . ?
C2 H1 1.0000 . ?
C3 C4 1.519(6) . ?
C3 H2 0.9900 . ?
C3 H3 0.9900 . ?
C4 C5 1.525(6) . ?
C4 H4 0.9900 . ?
C4 H5 0.9900 . ?
C5 C6 1.518(7) . ?
C5 H6 0.9900 . ?
C5 H7 0.9900 . ?
C6 C7 1.524(6) . ?
C6 H8 0.9900 . ?
C6 H9 0.9900 . ?
C7 H10 0.9900 . ?
C7 H11 0.9900 . ?
C8 C9 1.528(6) . ?
C8 C13 1.531(6) . ?
C8 H12 1.0000 . ?
C9 C10 1.540(6) . ?
C9 H13 0.9900 . ?
C9 H14 0.9900 . ?
C10 C11 1.518(8) . ?
C10 H15 0.9900 . ?
C10 H16 0.9900 . ?
C11 C12 1.529(7) . ?
C11 H17 0.9900 . ?
C11 H18 0.9900 . ?
C12 C13 1.541(6) . ?
C12 H19 0.9900 . ?
C12 H20 0.9900 . ?
C13 H21 0.9900 . ?
C13 H22 0.9900 . ?
C14 C15 1.402(6) . ?
C14 C19 1.403(6) . ?
C15 C16 1.385(6) . ?
C15 H23 0.9500 . ?
C16 C17 1.387(6) . ?
C16 H24 0.9500 . ?
C17 C18 1.392(6) . ?
C17 H25 0.9500 . ?
C18 C19 1.397(6) . ?
C18 H26 0.9500 . ?
C19 Si1 1.887(4) . ?
Si1 C21 1.871(4) . ?
Si1 C20 1.886(5) . ?
C20 H27 0.9800 . ?
C20 H28 0.9800 . ?
C20 H29 0.9800 . ?
C21 C22 1.403(6) . ?
C21 C26 1.416(6) . ?
C22 C23 1.378(6) . ?
C22 H30 0.9500 . ?
C23 C24 1.383(7) . ?
C23 H31 0.9500 . ?
C24 C25 1.393(7) . ?
C24 H32 0.9500 . ?
C25 C26 1.398(6) . ?
C25 H33 0.9500 . ?
C26 C27 1.495(6) . ?
C27 N1 1.505(6) . ?
C27 H34 0.9900 . ?
C27 H35 0.9900 . ?
N1 C29 1.488(6) . ?
N1 C28 1.490(5) . ?
C28 H36 0.9800 . ?
C28 H37 0.9800 . ?
C28 H38 0.9800 . ?
C29 H39 0.9800 . ?
C29 H40 0.9800 . ?
C29 H41 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Pt1 P1 169.73(10) . . ?
N1 Pt1 Si1 92.69(10) . . ?
P1 Pt1 Si1 85.79(4) . . ?
N1 Pt1 O1 86.44(13) . . ?
P1 Pt1 O1 94.98(9) . . ?
Si1 Pt1 O1 179.00(8) . . ?
S1 O1 Pt1 148.9(2) . . ?
O2 S1 O3 116.2(2) . . ?
O2 S1 O1 114.9(2) . . ?
O3 S1 O1 114.6(2) . . ?
O2 S1 C1 103.3(2) . . ?
O3 S1 C1 104.1(2) . . ?
O1 S1 C1 100.9(2) . . ?
F1 C1 F2 108.4(4) . . ?
F1 C1 F3 107.7(4) . . ?
F2 C1 F3 107.2(4) . . ?
F1 C1 S1 111.5(4) . . ?
F2 C1 S1 111.1(4) . . ?
F3 C1 S1 110.8(4) . . ?
C14 P1 C8 104.20(19) . . ?
C14 P1 C2 106.5(2) . . ?
C8 P1 C2 108.3(2) . . ?
C14 P1 Pt1 111.90(14) . . ?
C8 P1 Pt1 117.97(14) . . ?
C2 P1 Pt1 107.42(14) . . ?
C3 C2 C7 110.2(4) . . ?
C3 C2 P1 109.5(3) . . ?
C7 C2 P1 114.5(3) . . ?
C3 C2 H1 107.5 . . ?
C7 C2 H1 107.5 . . ?
P1 C2 H1 107.5 . . ?
C4 C3 C2 111.8(4) . . ?
C4 C3 H2 109.3 . . ?
C2 C3 H2 109.3 . . ?
C4 C3 H3 109.3 . . ?
C2 C3 H3 109.3 . . ?
H2 C3 H3 107.9 . . ?
C3 C4 C5 111.6(4) . . ?
C3 C4 H4 109.3 . . ?
C5 C4 H4 109.3 . . ?
C3 C4 H5 109.3 . . ?
C5 C4 H5 109.3 . . ?
H4 C4 H5 108.0 . . ?
C6 C5 C4 110.4(4) . . ?
C6 C5 H6 109.6 . . ?
C4 C5 H6 109.6 . . ?
C6 C5 H7 109.6 . . ?
C4 C5 H7 109.6 . . ?
H6 C5 H7 108.1 . . ?
C5 C6 C7 111.3(4) . . ?
C5 C6 H8 109.4 . . ?
C7 C6 H8 109.4 . . ?
C5 C6 H9 109.4 . . ?
C7 C6 H9 109.4 . . ?
H8 C6 H9 108.0 . . ?
C6 C7 C2 110.9(4) . . ?
C6 C7 H10 109.5 . . ?
C2 C7 H10 109.5 . . ?
C6 C7 H11 109.5 . . ?
C2 C7 H11 109.5 . . ?
H10 C7 H11 108.0 . . ?
C9 C8 C13 110.3(4) . . ?
C9 C8 P1 110.7(3) . . ?
C13 C8 P1 110.3(3) . . ?
C9 C8 H12 108.5 . . ?
C13 C8 H12 108.5 . . ?
P1 C8 H12 108.5 . . ?
C8 C9 C10 111.0(4) . . ?
C8 C9 H13 109.4 . . ?
C10 C9 H13 109.4 . . ?
C8 C9 H14 109.4 . . ?
C10 C9 H14 109.4 . . ?
H13 C9 H14 108.0 . . ?
C11 C10 C9 111.5(4) . . ?
C11 C10 H15 109.3 . . ?
C9 C10 H15 109.3 . . ?
C11 C10 H16 109.3 . . ?
C9 C10 H16 109.3 . . ?
H15 C10 H16 108.0 . . ?
C10 C11 C12 111.4(4) . . ?
C10 C11 H17 109.4 . . ?
C12 C11 H17 109.4 . . ?
C10 C11 H18 109.4 . . ?
C12 C11 H18 109.4 . . ?
H17 C11 H18 108.0 . . ?
C11 C12 C13 110.6(4) . . ?
C11 C12 H19 109.5 . . ?
C13 C12 H19 109.5 . . ?
C11 C12 H20 109.5 . . ?
C13 C12 H20 109.5 . . ?
H19 C12 H20 108.1 . . ?
C8 C13 C12 110.8(4) . . ?
C8 C13 H21 109.5 . . ?
C12 C13 H21 109.5 . . ?
C8 C13 H22 109.5 . . ?
C12 C13 H22 109.5 . . ?
H21 C13 H22 108.1 . . ?
C15 C14 C19 120.1(4) . . ?
C15 C14 P1 123.3(3) . . ?
C19 C14 P1 116.6(3) . . ?
C16 C15 C14 120.5(4) . . ?
C16 C15 H23 119.8 . . ?
C14 C15 H23 119.8 . . ?
C15 C16 C17 119.8(4) . . ?
C15 C16 H24 120.1 . . ?
C17 C16 H24 120.1 . . ?
C16 C17 C18 120.0(4) . . ?
C16 C17 H25 120.0 . . ?
C18 C17 H25 120.0 . . ?
C17 C18 C19 121.2(4) . . ?
C17 C18 H26 119.4 . . ?
C19 C18 H26 119.4 . . ?
C18 C19 C14 118.4(4) . . ?
C18 C19 Si1 124.8(3) . . ?
C14 C19 Si1 116.1(3) . . ?
C21 Si1 C19 113.23(19) . . ?
C21 Si1 C20 109.96(19) . . ?
C19 Si1 C20 103.6(2) . . ?
C21 Si1 Pt1 104.14(13) . . ?
C19 Si1 Pt1 108.67(14) . . ?
C20 Si1 Pt1 117.55(15) . . ?
Si1 C20 H27 109.5 . . ?
Si1 C20 H28 109.5 . . ?
H27 C20 H28 109.5 . . ?
Si1 C20 H29 109.5 . . ?
H27 C20 H29 109.5 . . ?
H28 C20 H29 109.5 . . ?
C22 C21 C26 117.8(4) . . ?
C22 C21 Si1 124.2(3) . . ?
C26 C21 Si1 118.0(3) . . ?
C23 C22 C21 122.0(4) . . ?
C23 C22 H30 119.0 . . ?
C21 C22 H30 119.0 . . ?
C22 C23 C24 120.0(4) . . ?
C22 C23 H31 120.0 . . ?
C24 C23 H31 120.0 . . ?
C23 C24 C25 119.7(4) . . ?
C23 C24 H32 120.2 . . ?
C25 C24 H32 120.2 . . ?
C24 C25 C26 120.9(4) . . ?
C24 C25 H33 119.6 . . ?
C26 C25 H33 119.6 . . ?
C25 C26 C21 119.6(4) . . ?
C25 C26 C27 118.4(4) . . ?
C21 C26 C27 121.9(4) . . ?
C26 C27 N1 114.2(4) . . ?
C26 C27 H34 108.7 . . ?
N1 C27 H34 108.7 . . ?
C26 C27 H35 108.7 . . ?
N1 C27 H35 108.7 . . ?
H34 C27 H35 107.6 . . ?
C29 N1 C28 108.4(3) . . ?
C29 N1 C27 108.6(3) . . ?
C28 N1 C27 107.1(3) . . ?
C29 N1 Pt1 104.9(2) . . ?
C28 N1 Pt1 110.7(3) . . ?
C27 N1 Pt1 117.0(3) . . ?
N1 C28 H36 109.5 . . ?
N1 C28 H37 109.5 . . ?
H36 C28 H37 109.5 . . ?
N1 C28 H38 109.5 . . ?
H36 C28 H38 109.5 . . ?
H37 C28 H38 109.5 . . ?
N1 C29 H39 109.5 . . ?
N1 C29 H40 109.5 . . ?
H39 C29 H40 109.5 . . ?
N1 C29 H41 109.5 . . ?
H39 C29 H41 109.5 . . ?
H40 C29 H41 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Pt1 O1 S1 106.6(4) . . . . ?
P1 Pt1 O1 S1 -63.2(4) . . . . ?
Si1 Pt1 O1 S1 77(5) . . . . ?
Pt1 O1 S1 O2 57.9(4) . . . . ?
Pt1 O1 S1 O3 -80.6(4) . . . . ?
Pt1 O1 S1 C1 168.3(4) . . . . ?
O2 S1 C1 F1 58.9(4) . . . . ?
O3 S1 C1 F1 -179.3(4) . . . . ?
O1 S1 C1 F1 -60.2(4) . . . . ?
O2 S1 C1 F2 179.9(4) . . . . ?
O3 S1 C1 F2 -58.2(4) . . . . ?
O1 S1 C1 F2 60.9(4) . . . . ?
O2 S1 C1 F3 -61.1(4) . . . . ?
O3 S1 C1 F3 60.8(4) . . . . ?
O1 S1 C1 F3 179.9(4) . . . . ?
N1 Pt1 P1 C14 76.6(6) . . . . ?
Si1 Pt1 P1 C14 -5.14(15) . . . . ?
O1 Pt1 P1 C14 174.22(16) . . . . ?
N1 Pt1 P1 C8 -162.5(6) . . . . ?
Si1 Pt1 P1 C8 115.71(17) . . . . ?
O1 Pt1 P1 C8 -64.93(18) . . . . ?
N1 Pt1 P1 C2 -39.9(6) . . . . ?
Si1 Pt1 P1 C2 -121.70(15) . . . . ?
O1 Pt1 P1 C2 57.66(17) . . . . ?
C14 P1 C2 C3 -73.7(3) . . . . ?
C8 P1 C2 C3 174.8(3) . . . . ?
Pt1 P1 C2 C3 46.4(3) . . . . ?
C14 P1 C2 C7 50.6(4) . . . . ?
C8 P1 C2 C7 -61.0(4) . . . . ?
Pt1 P1 C2 C7 170.6(3) . . . . ?
C7 C2 C3 C4 54.6(5) . . . . ?
P1 C2 C3 C4 -178.7(3) . . . . ?
C2 C3 C4 C5 -55.5(5) . . . . ?
C3 C4 C5 C6 56.0(5) . . . . ?
C4 C5 C6 C7 -57.0(5) . . . . ?
C5 C6 C7 C2 57.2(5) . . . . ?
C3 C2 C7 C6 -55.3(5) . . . . ?
P1 C2 C7 C6 -179.2(3) . . . . ?
C14 P1 C8 C9 -179.4(3) . . . . ?
C2 P1 C8 C9 -66.3(3) . . . . ?
Pt1 P1 C8 C9 55.8(3) . . . . ?
C14 P1 C8 C13 58.1(3) . . . . ?
C2 P1 C8 C13 171.2(3) . . . . ?
Pt1 P1 C8 C13 -66.6(3) . . . . ?
C13 C8 C9 C10 -56.4(5) . . . . ?
P1 C8 C9 C10 -178.9(3) . . . . ?
C8 C9 C10 C11 55.5(5) . . . . ?
C9 C10 C11 C12 -55.1(6) . . . . ?
C10 C11 C12 C13 55.7(6) . . . . ?
C9 C8 C13 C12 57.5(5) . . . . ?
P1 C8 C13 C12 -179.8(3) . . . . ?
C11 C12 C13 C8 -57.0(5) . . . . ?
C8 P1 C14 C15 48.6(4) . . . . ?
C2 P1 C14 C15 -65.8(4) . . . . ?
Pt1 P1 C14 C15 177.1(3) . . . . ?
C8 P1 C14 C19 -128.8(3) . . . . ?
C2 P1 C14 C19 116.9(3) . . . . ?
Pt1 P1 C14 C19 -0.2(4) . . . . ?
C19 C14 C15 C16 -2.4(6) . . . . ?
P1 C14 C15 C16 -179.6(3) . . . . ?
C14 C15 C16 C17 1.8(7) . . . . ?
C15 C16 C17 C18 0.1(7) . . . . ?
C16 C17 C18 C19 -1.6(7) . . . . ?
C17 C18 C19 C14 1.1(7) . . . . ?
C17 C18 C19 Si1 171.4(4) . . . . ?
C15 C14 C19 C18 0.9(6) . . . . ?
P1 C14 C19 C18 178.3(3) . . . . ?
C15 C14 C19 Si1 -170.2(3) . . . . ?
P1 C14 C19 Si1 7.2(4) . . . . ?
C18 C19 Si1 C21 63.4(4) . . . . ?
C14 C19 Si1 C21 -126.1(3) . . . . ?
C18 C19 Si1 C20 -55.6(4) . . . . ?
C14 C19 Si1 C20 114.8(3) . . . . ?
C18 C19 Si1 Pt1 178.6(3) . . . . ?
C14 C19 Si1 Pt1 -10.9(4) . . . . ?
N1 Pt1 Si1 C21 -40.82(16) . . . . ?
P1 Pt1 Si1 C21 129.01(14) . . . . ?
O1 Pt1 Si1 C21 -11(5) . . . . ?
N1 Pt1 Si1 C19 -161.79(17) . . . . ?
P1 Pt1 Si1 C19 8.04(14) . . . . ?
O1 Pt1 Si1 C19 -132(5) . . . . ?
N1 Pt1 Si1 C20 81.08(19) . . . . ?
P1 Pt1 Si1 C20 -109.09(17) . . . . ?
O1 Pt1 Si1 C20 111(5) . . . . ?
C19 Si1 C21 C22 -6.1(4) . . . . ?
C20 Si1 C21 C22 109.2(4) . . . . ?
Pt1 Si1 C21 C22 -124.0(4) . . . . ?
C19 Si1 C21 C26 172.6(3) . . . . ?
C20 Si1 C21 C26 -72.1(4) . . . . ?
Pt1 Si1 C21 C26 54.7(3) . . . . ?
C26 C21 C22 C23 2.0(7) . . . . ?
Si1 C21 C22 C23 -179.2(4) . . . . ?
C21 C22 C23 C24 0.7(7) . . . . ?
C22 C23 C24 C25 -2.6(7) . . . . ?
C23 C24 C25 C26 1.8(7) . . . . ?
C24 C25 C26 C21 1.0(7) . . . . ?
C24 C25 C26 C27 -176.4(4) . . . . ?
C22 C21 C26 C25 -2.8(6) . . . . ?
Si1 C21 C26 C25 178.3(3) . . . . ?
C22 C21 C26 C27 174.5(4) . . . . ?
Si1 C21 C26 C27 -4.3(6) . . . . ?
C25 C26 C27 N1 114.6(4) . . . . ?
C21 C26 C27 N1 -62.7(5) . . . . ?
C26 C27 N1 C29 -56.8(5) . . . . ?
C26 C27 N1 C28 -173.7(4) . . . . ?
C26 C27 N1 Pt1 61.5(4) . . . . ?
P1 Pt1 N1 C29 32.8(7) . . . . ?
Si1 Pt1 N1 C29 113.9(3) . . . . ?
O1 Pt1 N1 C29 -65.6(3) . . . . ?
P1 Pt1 N1 C28 149.5(5) . . . . ?
Si1 Pt1 N1 C28 -129.4(3) . . . . ?
O1 Pt1 N1 C28 51.1(3) . . . . ?
P1 Pt1 N1 C27 -87.5(6) . . . . ?
Si1 Pt1 N1 C27 -6.4(3) . . . . ?
O1 Pt1 N1 C27 174.1(3) . . . . ?

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        27.48
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         5.141
_refine_diff_density_min         -2.123
_refine_diff_density_rms         0.178
